m*> ** Xx \ \ X- V X V X x- X X X x x x \ X X v - N " ' x x \\ x x \ \ \ \ x \ \ \ XXN^XX v v \ x "x X X X X X X X \. \ \ X v x v \ x- X X X X X X X X X \ "X X X, X X X \ X X N v x X X\\\\X\\XX\XXV\Xv nxxx\x\\\\\x\xx\\\n v \ v x x X \ X X X X x \X\X\\XX xxxxx \\XX\\x\XX\\XX „ X N v. X X X X \ \ X. X. n \ X X X X X X. \ X X X "\ X ^ XX X X X x X X X X X x x » X X X X X ' \ \ X X X X X X - X v X x \ \ X X X X X x s \ X X X X X x X x. X v X X X X XX X X s x \ VXN x v N v X x X X X x • x X x X \ X v x x -N X v x x v X X X X X x \ x X k \ X N X X X X X X x N x. x X X X x X X X x^ \ x X X X x x x \ x X X x ■ x x X '• s X X ^ X x X • V X X \ X X v X " - X -. x. X X X x ■ . X . X x X \ xv x x V X I * X \ • x X x x v x \ X x w*. - X'. ■ "x x • xvJv-x v\ x, ■ x»X :-*• >y s v.-U-.-J*> V\x\ - V* x - x % x x X, . x^ v* s x x x - H x ,^<* x. < \ > v x • x--^ xJxX x X x X X X % x'x xx*.X — x^xXrxNX X y • / ■ .s\y ' x> x > x^ •»:? s . ' y y y y s y . S ' ' / / X y yy yt S • y ■ / A/ ' y y ■ / " -' y y -,' y y ' >C - / / y '' / y - ' y y \s / y y . y "A x syyyy/y./ySyyysyS ' * , y y y y y y - /v/V ' ' S / S S S A v / y y y y y y / y y / / ' / y .''< . ^ . •j y y y y y y ' ' * / S / S+./ S ,/ / VX; y y y y y y y / y y y y / / , 'y,< y y y ■' s , s y y y y y y ✓ y .x / y V y y y 'y'y'yy yy'yyy y' y yyyyy' /// X ✓ yyyyy y y y y y y y / y y y yXy y' y y y SSSSSSS-S/-S/S, ■ / y y y y y / y y y y y y y y y y y / >/// y y y y y y y y y y y y y XXX y / y y y y y y y y y y y y y y'y'/y'y y > ■/ / / / / S /_/ / /., ' y y y y s / s / .-• < A X >% «"-^ '• Jf"' ■ ARMY MEDICAL. LIBRARY WASHINGTON Founded 1836 Section. "7 T _. Number ->^--/--C?.../..^.oL. Form 113c, W. D.. S. G. O. 3—10543 (Revised June 13, 1936) .' c if- DUE TWO WEEKS FROM LAST DATE | • MAR i f •Q D. APPLETON c\ CO.'S PUBLICATIONS. SCIENTIFIC WORKS. tejjttwta. ARNOT.-GOTEIC ARCHITECTURE Applied to Modem Residences. 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"To our numerous Manufacturers, Mechanics, Engineers, and Artisans, it will be a mine of wealth." —Providence Journal. " Young men, arm yourselves with its knowledge. We can with confidence recommend our read- ers to possess themselves of its numbers as fast as they appear."—American Artisan. " We unhesitatingly commend the work to those engaged in or interested in mechanical or scieii- tine pursuits, as eminently worthy of their examination and study."— Troy Budget. " It is truly a great work, and the publishers deserve the thanks of inventors, machinists, and manufacturers, and indeed of the public generally."—Independent. " This Dictionary will be highly useful to practical mechanics, and valuable to all who wish to acquaint themselves with the progress of invention in the mechanic arts."—Daily Mercury. " Young mechanics ought to keep posted up in theoretical as well as practical knowledge, and this work will show them just how they stand."—Roxbury Advertiser. " We take it to be just the work that scores and hundreds of our intelligent mechanics have desired to possess. So ample are its descriptions, and so full and minute its specifications, that it seems to us that any mechanic might construct any machine it describes, on the strength of its engravings and instructions."—Commercial Advertiser. " All interested in mechanics should avail themselves of its advantages."—Schuylkill Journal. "A work of extensive practical utility and great importance and value to the rapidly increasing interests of the country. We regard the work as eminently calculated to proiuote the cause oi science and the mechanical arts, and to disseminate valuable information on these subjects."—Far- mer p;o (boiled) ......i Gold-leaf wetted withi muriatic acid, and I digested with heat in [ a watch-glass......J Gold-leaf moistened i with nitric acid ... i Dilute solution of ni-1 trate of silver... ... i Weak solution of iodide > of potassium ......i Solution of acetate of i lead .........\ Sulphureted hydrogen » gas or >yater ......\ Acetic Acid quite pure. Acetic Acid containing Oil of Vitriol. White precip itate insoluble in nitric acid Ditto. Pearly- white pre- cipitate. Whitish precipitate. Acetic Acid containing Nitric Acid. [ White curdy precipitate, "I soluble in am- [ monia. Decolored. j Partially < i solved. Acetic Acid containing Muriatic Acid. Partially dis- solved. ' Curdy-white precipitate, soluble in am- Turbidness. Acetic Acid containing Metals. {Yellow preci- pitate, if lead be present. Black or dark-colored precipitate. (If this be dissolved in nitric acid, and ammo- nia added, it will give a blue color if copper be present. ACETIFICATION. The oxidation of alco- hol in the process of making vinegar. To be capable of acetification or conversion into vinegar it is necessary that the liquid should contain alco- hol in some state or other, or some substance, as BUg^r, which, by the process of fermentation, is ca- pable of producing it. The presence of a ferment or vegetable matter, and a temperature between 70° and 100° F., facilitates the operation. In the conversion of wines, beer, wort, &.c. into vinegar, the sugar is first transformed by fermentation into alcohol, and in this state becomes oxidized or acidified by the absorption of atmospheric oxygen. Manufacturers should always remember that such is the true nature of this process. (See Acids, Acetic Acid, and Pyroligneous, and Vinegar.) ACETIMETER. Syn. Acetometer. An in- strument or apparatus for ascertaining the strength of acetic acid. (See the next article.) ACETIMETRY. Syn. Acetometry. The art or process of determining the strength of vinegar or acetic acid. Various methods have been pro- posed for this purpose, among which may b*e men- tioned the following: I. (The plan adopted by the Excise.) Hydrate of lime is added gradually to a sample of the vine- gar, until it is saturated, and the sp. gr. of the re- sulting clear solution of acetate of lime is taken by the acetometer, invented by Messrs. J. and P. Taylor. This instrument in construction resem- bles the common hydrometer, and stands at the mark on the stem called proof in a solution con- taining 5£ of real acid, which is the strength of No. 24 vinegar, or an acid which will saturate ex- actly 14 J grains of crystallized carbonate of soda When the vinegar is stronger than proof, the in- strument must be loaded with one or more of the small weights which are supplied with it, each of ACE 17 ACE which will indicate an additional 5°, up to 35§, which is the greatest strength at which the duty is levied by the gallon. To ascertain the per cent- age of real acid, 5$ must therefore be added to the number indicated by the acetometer. Thus : without being loaded, the instrument, on floating to a given mark, indicates a proof vinegar or one of 5°;; with one weight, a vinegar of 11)$ ; with tioo weights, 15$; with three weights, 20$, &c, &c. The reason of this is, that the starting point, or proof, is an acid of 5$. In the technical lan- guage of trade, each 5$ is called a vinegar. Thus : acid of 10$ is said to contain two vinegars ; one of 15°;, three vinegars, &c. A more common method is, however, to speak of the degrees of the acetometer as proof or overproof. Thus : No. 24 vinegar is said to be proof; one measuring 5 ace- tometer degrees—5 overproof or o. p.; one 10 de- grees—10 o. p., &c. In malt and wine vinegars, which usually contain gluten or mucilage, this method is not strictly accurate, as these substances alter the specific gravity. A small weight marked M is supplied by Mr. Bate with the acetometers made by him, and is used in trying such vinegar. Remarks. This plan, though sufficiently cor- rect for commercial purposes, is liable to a small error, especially in vinegar containing much vege- table matter. If it be pure or very nearly so, the decimal fraction of the sp. gr. will be doubled by conversion into acetate of lime. Thus : 1*0085 in vinegar becomes 1*0170 when converted into a solution of acetate of lime. In malt vinegar, how- ever, 0*005 may fairly be deducted from its sp. gr. as produced by the presence of mucilage and gluten. The quantity of foreign matter present in vinegar, may thus be approximatively ascertained, by de- ducting the decimal of the sp. gr. of the solution of acetate of lime, from double that of the decimal part of the sp. gr. of the vinegar. Thus: I find the sp. gr. of a sample of vinegar to be 1*014, and after saturating it with hydrate of lime, I again try it and find it to be 1*023, what is the sp. gr. of the pure vinegar, and what is due to foreign matter— Decimal of sp. gr. of vinegar, doubled *028 Decimal of sp. gr. of solution of ace- ) „£„ tate of lime.........)__ Quantity of foreign matter equal to ) .qq,. the difference........$ Specific gravity of vinegar .... 1*014 Deduct sp. gr. due to foreign matter . *005 Sp. gr. of a solution of acetic acid or i pure vinegar of equal strength to > 1. sample..........; 009 II. Dissolve 200 grains of pure crystallized bi- carbonate of potash in a little water, and then add enough water to make it up to exactly 1000 parts by measure; as for instance, 1000 minims. A solution is thus formed, which, when added to a sample containing 100 measures of acetic acid or vinegar, until the latter be saturated, will indicate the exact amount of real acetic acid present. The test liquor should be made and measured in a long glass tube, capable of holding the whole 1000 measures, and graduated into 100 parts, every one of which will represent 1$ of dry acid. A conve- 3 nient instrument for this purpose, is the pouret of Gay Lussac, which consists of a double tube of the shape of the following figure. Remarks. Any other method of measuring or ascertaining the exact quantity of test liquor employed, may he used, as convenience or circumstan- ces may suggest; but however this is done, it is necessary to do it in such a manner as to ensure the greatest ac- curacy. III. Dissolve 200 grains of crystal- lized bicarbonate of potassa in 800 grains of distilled water, contained in a suit- able shaped bottle, previously care- fully weighed ; when dissolved, weigh it again, and 6ee that it is exactly equal to 1000 grs. This test liquor, like the last, is used to neutralize the acid in the sample for examination, but in this case the quantity must be 100 grs. instead of 100 measures. Every grain of the test liquor consumed will, therefore, indicate 1 tenth of a grain of real acetic acid, and every 10 grs. will be equal to 1§. A very convenient shaped bottle for this pur 3se is that known as Schus- ter's Alkalimeter, which consists of a very light stoppered glass bottle, having a neck drawn out to the one side, and furnished with a very fine orifice, which admits of the liquid being poured 1 p -100 ■90 i ?w t70 r00 J50 i |>10 hm / ko i1- k k) out in small quantities with greater ease, and without the risk of an accident. The weight of the bottle and solution, after the process of neu- tralizing the acid of the sample, deducted from its previous weight, gives the exact weight of the test liquor consumed, and consequently the quantity of acetic acid that has been saturated by it. Remarks. This method admits of great accu- racy, and is preferable to the previous process, (No. II,) as it is much easier to weigh than to measure correctly, especially when the quantity is small. IV. Instead of bicarbonate of potash, in Nos. II and III, either of the following salts may be used. 104 grs. dry carbonate of soda. 135 " " carbonate of potash. 283 " crystallized carbonate of soda. Remarks. The dry carbonates of potassa and soda should be prepared by submitting the crystal- lized carbonate to a dull red heat in a crucible, when, after cooling, the proper quantity may be weighed. V. By taking the specific gravity of the sampl», (see Specific Gravity,) and seeking it. in the fol- lowing Tables, the per centage of acid may be ascertained sufficiently correct for most purposes. ACE 18 ACH Table I. The following Table is given by Messrs. Taylor, as the basis of their Acetometer. Revenue Proof Acid, called by the manufacturer No. 24. sp. gr. l-uiif.) contains real or anhydrous acid in 100, 5 1*0170 10257 1-0320 10470 10580 Table II. The following Table, from the Pharm. Central Blatt fur 1839, drawn up by M. Mohr, exhibits the sp. gr. of pure Acetic Acid of almost every strength. Percent. Per cent. Percent. of (ilHeial of Glacial of Glacial Acid, Sp.Gr. Acid, Sp.Gr. Acid, Sp.Gr. (C. 4.H.3, (C.4, H.3, (C. 4, H. 3, 0.3+A(|.) O. 3+Au.) 0.3+Aq.) 100 1-0635 66 1069 32 10424 99 1-0635 65 1-068 31 1-041 98 1*067 64 1-068 30 1-040 97 1-0680 63 1-068 29 1-039 96 1-069 62 1-067 28 1-038 95 1-070 61 1-067 27 1-036 94 1-0706 60 1-067 26 1-035 93 1-0708 59 1-066 35 1-034 92 1-071G 58 1-066 24 ]• H33 91 1-0721 57 1065 23 1032 90 10730 56 1-064 22 1-031 89 1-0730 55 1-0T4 21 1 -029 88 1-0730 54 1-063 20 1-027 87 1-0730 53 1063 19 1-026 86 1-0730 52 1-002 18 1 -025 85 1-0730 51 1-061 17 1-024 84 1-0730 50 1-060 16 1-023 83 1-0730 49 1-059 15 1-022 82 1 -0730 48 1-058 14 1-020 81 1-0732 47 1 •<).->« 13 1-018 80 1 0735 46 1-055 12 1-017 79 1-0732 45 1-055 11 1-016 78 10732 44 1-051 10 1-015 77 1073 43 1-053 9 1-013 76 1-072 42 1-052 8 1-012 75 1 -072 41 1-0515 7 1-010 74 1-072 40 1-0513 6 1-00S 73 1-071 39 1-050 5 1-0067 72 1-071 38 1-049 4 1-0065 71 1-071 37 1-048 3 1-004 70 1-070 36 1047 2 1-002 69 1-070 35 1-046 1 1-001 68 1-070 34 1-045 0 1-0000 67 1-069 33 1-044 Remarks. Table I is adapted to commercial vinegar, and is sufficiently accurate for all com- mon purposes. Table II is intended for pure acetic acid. It will be seen that above a certain per centage, the specific gravity retrogrades; it is, therefore, better in trying very strong acid, to dilute it first with a given weight of distilled water, and to allow for it afterwards. The weight of gla- cial acetic acid, multiplied by *8512, gives the weight of dry acid which it contains, and anhy- drous acid, multiplied by 1*1748, will give a num- ber representing an equivalent weight of glacial acid. Caution. As a spurious acidify is frequently given to vinegar by adding other acids to it, which would thus give it a false appearance of strength, it is, therefore, better first to ascertain whether it be adulterated. (See Acetic Acid.) The most correct, and, in many respects, the easiest method of actiiMieLry, is .No. Ill or IV. The acetic acid of the L. P. has a sp. gr. of 1*048, and contains 30-2 of dl7 acid* 'n'atof tl,e 1),lbl,n CoII,'Ke ls 1-074. and that of the Edinburgh Collefre 1*065.1 (See Specific Gravity, and Acidimetry.) ACETULE. The hypothetical radical of the acetule series; neither i'tself nor oxide has been obtained alone. Its hydrated oxide is aldehyde. The chloride of acetule is formed by the length- ened exposure of chloride of ethule to the action of chlorine and light. The oxychloride, by satu- rating anhydrous ether with perfectly dry chlorine gas, exposing to external cold, and afterwards to a gentle heat. Both this and the preceding are transparent colorless fluids. Suboxyrhloride of acetule is a gas formed by heating the last article in contact with potassium. Oxysulphurtt of acetule is made by passing sulphureted hydrogen gas through the oxychloride, until an oily liquid is formed, which, by exposure, becomes semi-crystal- line. This is dissolved in hot alcohol, and is ob- tained in crystals on its cooling. Remarks. For a knowledge of the preceding substances we are indebted to the researches of Malaguti and Regnault. The compounds of ace- tule offer beautiful examples of chemical substitu- tion, but the nature of the prese work will not permit their bein<,r enlarged on litre. ACHROMATIC. Free from color, .from the Gr. i, without, and xpupa, color,) from which also is derived the word ACHROMATISM. The destruction of the colored rings, which accompany the image of an object seen through a lens or prism. Causes, •* Di.spensatorv 10th ed.) ■' that n contains 30-75 real acid by wei/ht •' ?-7t on the next page he sasi. " that of the L. C. contain, 37» of real acid and 63S of water." "-"nmilis J/. anolher?"-^ ^ ^ '" ^ " " **** to be 1065' «•* *<* ACI 19 ACI Correction. It has been endeavored to correct the chromatic aberration of lenses, by combining two or more made of different materials, possess- ing different dispersive powers. Thus the spec- trum formed by flint glass, or glass containing lead, is longer than that formed by crown glass, for the same deviation ; and when combined, the one tends to diminish the dispersion of the other. On this principle the achromatic object glasses of telescopes are generally formed in this country. A convex lens of crown glass is combined with a weaker concave lens of flint glass, the latter coun- teracting the dispersion of the former, without ma- terially interfering with its refraction. A still better plan is, to place a concave lens of flint glass between two convex lenses of crown glass. Remarks. All the larger object glasses lately manufactured are said to consist of only two lenses; the resulting achromatism proving suffi- ciently exact for all useful purposes. The princi- pal achromatic glasses and ' telescopes recently made, have been manufactured by Dolland of London, and some of the opticians of Bavaria and Switzerland. The achromatism of prisms depends upon the same principles, and is determined and corrected in the same manner as lenses, but pre- sents less difficulty on account of the spherical aberration of the latter. (See Lenses, Tele- scope, Microscope.) ACIDS. In common language, any substance possessing sourness or acidity ; in chemistry, any electro-negative compound, capable of combining with bases to form salts. Most of the liquid acids possess a sour taste, and redden litmus paper. Hist. The chemical theory of the acids is still undecided, and the laws which regulate their com- binations with the bases, as well as the precise na- ture of the resulting salts, are involved in considera- ble obscurity. Lavoisier and the associated French chemists conceived that acidity resulted from the union of a peculiar combustible base, called a rad- ical, with a common principle of acidification, called oxygen. The inaccuracy of this hasty gen- eralization was disproved by Berthollet, who main- tained that it was " carrying the limits of analogy too far to presume that all acidity arises from oxy- gen." The early opinion of Sir II. Davy, after revised and modified by Murray, was, that inti- mately combined water was the real " acidifying principle.'' In 1810, however, this celebrated chemist published a series of dissertations in the Philosophical Transactions, which fully overthrew the hypothesis of Lavoisier. It was soon estab- lished that both oxygen and hydrogen were capa- ble of producing acids, of which the sulphuric and muriatic acids may be taken as examples. It is now generally acknowledged that no one substance or element can be regarded as the general " acid- ifying principle." The more recent theory of the acids, elaborated out of the researches of Graham, Liebig, Dumas, Clark, Fremy, Thalow, Dulong, Peligot, and others, is affirmed by its supporters, to establish the views first suggested by Sir H. Davy, respecting the chloric and iodic acids and their salts. In this scheme, all the acids are uni- ted into one series, and all the salts into another, both being so closely connected, that it is said, " that these two series may be considered as one." The existence of hydrogen in the oxygen acids, in the free or active state, is here deemed an essen- tial part of their constitution, and hence the name of hydracids has been given to them. This prin- ciple has been extended to all the acids, even the organic. Those acids that contain 1 eq. of hydro- gen, are called monobasic ; with 2 eq., bibasic; with 3 eq., tribasic, and so on; the general term polybasic, being applied to those which combine with two or more eq. of hydrogen. The muriatic may be taken as the type of the first; the tartaric that of the second ; and the citric acid that of the third. This view of the acids presents the advan- tages of simplicity and unity of classification. In the union of the acids with the bases forming salts, it presumes that the hydrogen of the acid is re- placed by the base, it having previously played the part of a base itself. Consequently acids may be viewed as the hydrogen salts of their radicals, and acids and salts, with regard to their constitution, form but one class. " The neutralizing power of an acid depends entirely on the number of eq. of hydrogen replaceable by the bases." (Liebig.) Other hypotheses have arisen respecting the acids, but have possessed little merit and obtained little notoriety. Class. The acids have been variously classed by different writers, as into organic and inorganic; metallic and non-metallic; oxygen acids, hydro- gen acids, and acids destitute of either of these elements; the names being applied according to the kingdom of nature, or class of bodies to which the radical belonged, or after the element which was presumed to be the acidifying principle. Nomen. The names of the acids end either in ic or ous; the former being given to that contain- ing the larger portion of the electro-negative ele- ment, or oxygen, and the latter to that containing the smaller quantity. As sulphuric acid, an acid of sulphur, containing 3 atoms of oxygen; sulphur- ous acid, another sulphur acid, containing only 2 atoms of oxygen. When a base forms more than 2 acid compounds with oxygen, the Greek prepo- sition hypo is added to that containing the smaller portion, as hyposulphuric and hyposulphurous acids. This system of nomenclature was originally adopt- ed under the idea that all acids contained oxygen, but the same terms are now applied, regardless of the acidifying principle, as hydrochloric acid, hy- drofluoric acid, &c. The prepositions per, hyper, and the syllable oxy are also prefixed to the names of acids, when it is intended to denote an increase of oxygen, as hypernitrous acid, perchloric acid, oxymuriatic acid, &c. Cautions. All the strong liquid acids should be kept in glass bottles, furnished with perfectly tight ground-glass stoppers ; glass vessels should be used in measuring them, and they should be dispensed in stoppered vials. ACIDS, OXYGENIZED. These are com- pounds to which an apparent surcharge of oxygen is given by means of deutoxide of barium. They were first discovered by M. Thernard, and de- scribed by him in the Ann. de Chim. et Phys. viii. 306. Proc. 1. Nitrate of baryta should first be ob- tained perfectly pure, and, above all, free from iron and manganese. The most certain means of procuring it is to dissolve the nitrate in water, to add to the solution a small excess of baryta water, to filter and crystallize. 2. The pure nitrate is to be decomposed by heat. This ought not to be done iu a common earthenware retort, because it contains too much of the oxides of iron and manga- nese, but in a perfectly white porcelain retort. Four or five pounds of nitrate of baryta may be decomposed at once, and the process will require about three hours. The baryta thus procured will contain a considerable quantity of silex and alumi- na ; but it will have only very minute traces of manganese and iron, a circumstance of essential importance. 3. The baryta, divided by a knife into pieces as large as the end of the thumb, should then be placed in a luted tube of glass. This tube should be long and large enough to contain from 2i to 31, lbs. It is to be surrounded with fire, and heated to dull redness, and then a current of dry oxygen gas is to be passed through it. However i*apid the current, the gas is completely absorbed ; srt that when it passes by the small tube, which ought to terminate the larger one, it may be con- cluded that the operation is completed. It is, however, right to continue the current for seven or eight minutes more. Then the tube being nearly cold, the deutoxide, which is of a light gray color, is taken out and preserved in stoppered bottles. When this is moistened it falls to powder, without much increase of temperature. If in this state it be mixed with seven or eight times its weight of water, and a dilute acid be poured in, it dissolves gradually by agitation, without the evolution of any gas. The solution is neutral, or has no action on turnsole or turmeric. When we add to this so- lution the requisite quantity of sulphuric acid, a copious precipitate of baryta falls, and the filtered liquor is merely water, holding in solution the oxy- genized acid, or deutoxide of hydrogen, combined with the acid itself. ACI DIMETER. An instrument or apparatus wherewith to ascertain the strength of acids. (See Hydrometer.) ACIDIMETRY. The estimation of the strength of acids. Memo. This operation must be understood to refer to the relative strengths of the same acids, (viz. quantity of real acid of the same kind con- tained in the solutions examined,) and not to the comparative strengths of acids of different compo- sitions or names. Theoretically, capacity of satu- ration is no proof of strength of affinity, or acid power in different acids in opposition to the views propounded by Berthollet. Thus, it takes 50 grs. of chalk, or 54 grs. of dry carbonate of soda to neu- tralize 37 grs. of real muriatic acid, but the same quantity is enough to neutralize 49 -jre. of the strong- est oil of vitriol, containing 40 grs. of real acid. It tlius appears that a less quantity of muriatic than su'phuric arid is equivalent to any giv/.*q weight of base, and according to Berthollet's the- ory, the former should be considered the stronger acid. The reverse is however the case, as oil of vitriol will take lime from its solution in hydro- chloric acid. No absolute criterion of the scale of power, among the different acids, has as yet been discovered. The present article will be confined to methods of acidimetry applicable to the acids generally, but directions more especially adapted to the principal acids will be found under tin ir par- ticular heads. (See Aceti.metry, Muriatic Acin, Si'lehuric Acid, &c.) Andimetrical Processes. These are founded on the capacity of the acids to saturate the bases. I. Place a weighed sample, say 100 grs. of the acid to be examined in a glass tube or other suita- ble vessel, and, if it be a strong acid, it is better to dilute it with six or eight times its weight of pure water, and if solid or crystallized, as citric or tar- taric acid, to dissolve it in a like qua.itity. A weighed portion of dry powdered carbonate of so- da or potassa prepared from the crystallized car- bonate by exposing it to a red heat, is then grad- ually and carefully added, until the acid is satu- rated, which is known by its ceasing to effervesce, and to redden litmus paper. Great care must be taken not to exceed the quantity necessary for this purpose. After adding each portion of soda the solution should be well stirred up, and as soon as the effervescence becomes languid the greatest caution must be observed in adding fresh portions of the alkali. The proper point is arrived at when the liquid ceases to redden litmus, and does not alter the color of turmeric paper; if it turns the latter brown, too much soda has been added, and the operation becomes useless. As soon as the point of saturation or neutralization is arrived at, the remaining carbonate of soda is weighed, and its present deducted from its former weight will give the quantity consumed, every 53 £ grs. of which will represent an equivalent of real acid, ac- cording to the following table, which I have ar- ranged for the purpose. Remarks. This method is sufficiently accurate for common purposes, but when greater exactness is required, the following plan is preferable: The reason for the adoption of the carbonate of potassa or soda is, that they have a uniform constitution when prepared in the way described as above. Either of the other articles mentioned in tin table may, however, be used instead, if at hapd, and known to be pure. ACI 21 ACI Table representing the quantities of the Carbonates of Soda, Potassa, Lime, Carbonic Acid, and Hydrate of Lime, equivalent to the given weights of somo of the Acids, together with the compo- sition of the latter, hydrogen being considered equal to 1. 534 grs. of decarbonate of soda, 50J grs. pure chalk, 143£ „ crystallized ditto, 374 84J » bicarbonate of ditto, 44| 694 1, dry carbonate of potassa, 1004 „ crystallized bicarbonate of ditto, are equivalent to of hydrate of lime, (fresh,) of dry carbonic acid, (when the bicarbo- nate of potassa or soda is used for test- ing in the process of Fresenius and Will.) Grains. 51*48 60*48 99*4 114*68 34*9 52*9 22*12 58*48 76*48 85*84 127*3 27-39 36-42 54*15 72-15 36*24 63-24 71*4 50*48 401 49*1 66*48 75-48 215*16 Acid, Acetic (anhydrous) -------- (crystallized or glacial) ----Arsenious (dry) — Benzoic (dry) — Boracic (dry) ---------(crystallized) Carbonic (dry Citric (dry) -----(crystallized) — Gallic ...... — Hydriodic (dry) — Hydrocyanic (dry) ----Hydrochloric (dry) — Nitric (dry) -------(liquid, sp. gr. 1*5) Oxalic (dry) ------■ (crystallized) ----Phosphoric (dry) ... ----Succinic (dry, or anhydrous crystals) ----Sulphuric (dry) ...... -------------(liquid, sp. gr. 1-845) Tartaric (dry) --------- (crystallized) Tannic 4 Carbon 3 Oxygen 3 Hydrogen 1 Dry Acid 1 Water 2 Arsenic 3 Oxygen 14 Carbon 3 Oxygen 5 Hydrogen 6*12X4) (8X3) (6*12X14) (8X3) 1 Boron = 10 3 Oxygen (8X3) = 24 1 Dry Acid .. = 34 2 Water (9X2) = 18 1 Carbon = 6 2 Oxygen (8X2) = 16 4 Carbon . (6*12x4) = 24 4 Oxygen (8X4) = 32 2 Hydrogen .. == 2 1 Dry Acid .. = 58 2 Water (9X2) = 18 7 Carbon = 42 3 Hydrogen .. = 3 5 Oxygen = 40 1 Iodine = 126 1 Hydrogen .. = 1 1 Cyanogen .. = 26 1 Hydrogen .. = 1 1 Chlorine = 35 1 Hydrogen .. = 1 1 Nitrogen = 14 5 Oxygen (8X5) = 40 1 Dry Acid .. = 54 2 Water (9X2) = 18 2 Carbon .: . (6-12x2) = 12 3 Oxygen (8X3) = 24 1 Dry Acid .. = 36 3 Water (9X3) = 27 2 Phosphorus .. = 31 5 Oxygen = 40 4 Carbon . (6*12X4) = 24 3 Oxygen (8X3) = 24 2 Hydrogen .. = 2 1 Sulphur = 16 3 Oxygen . . (8X3) = 24 1 Dry Acid .. = 40 1 Water = 9 4 Carbon . (6*12X4) =24 5 Oxygen (8X5) = 40 2 Hydrogen .. = 2 1 Dry Acid .. = 66 1 Water 18 Carbon = 9 =110 9 Hydrogen .. = 9 12 Oxygen = 96 ACI 22 ACI II. Dissolve 100 grs. of the carbonate of soda or potassa, prepared as above, in 700 or S00 mea- sures of boiling water, and when cold make the quantity up to exactly 1000 measures; this forms a test liquor, every 10 measures of which repre- sent 1 gr. of the dry carbonate, and every single measure 1 tenth of a grain. A convenient grad- uated glass tube for this purpose is Gay Lussac's pouret, described under the article Acetimetry. This liquid must be applied to neutralize the acid, as described in the last process, and the quantity consumed for that purpose may be read off on the graduated tube. Remarks. This plan allows of the alkali being added with greater ease and in smaller quantities than can possibly be done with a powder. If the graduated portion of the pouret be divided into 100 parts, each of them will represent exactly one grain of the carbonate. III. Dissolve 100 grs. of the dry carbonate of soda or potassa before described in 900 grs. of hot water, and when cold make it up to exactly 1000 grs. This forms a test liquor, capable of being applied with great accuracy, every grain of which will represent 1 tenth of a grain of alkali, and ev- ery 10 grs. will be equal to 1 gr., from which the real quantity of acid present may be ascertained from the preceding table, and by the simple rule of proportion the per centage may be found. Remarks. The solution is best made and used in a bottle known as Schuster's Alkalimeter, de- scribed under the article Aclotimetry. The ope- ration is conducted thus: The sample of acid, being accurately weighed, is diluted or dissolved in 6 or 7 parts of water, and the bottle containing the test liquor is then carefully balanced in the scales and the weight noted. The contents of the latter are then added in small and successive por- tions to the acid until the point of saturation is approached, when great care must be observed lest too much be added. As soon as the exact point of saturation is arrived at, the bottle holding the test solution must be again accurately weighed, when its loss of weight, divided by 10, will give the number of grains of the carbonate consumed. IV. ^Method of Drs. Will and Fresenius, of Giessen.) Ex plan. This method depends upon the quantity of carbonic acid gas which a given weight of acid is capable of expelling from the bicarbo- nate of soda or potassa, which is estimated by the loss of weight in the apparatus, after tho gas, ren- dered perfectly dry by passing through sulphuric acid, has escaped into the air, from which the quantity of acid present in the sample is found by a simple calculation. Oper. A determinate amount of the acid under examination is accurately weighed into the flask A, fig. p. 22 ; and if it be a concentrated acid or a solid, it is mixed with or dissolved in 6 or 8 times as much water. The little glass tube e is then nearly filled to the brim with pure bicarbonate of soda in powder, and a fine silk thread is tied round the neck of the tube, by means of which it is lowered down into the flask A, so as to remain perpendicularly suspended when the %ork is placed in the latter, the cord being held between the cork and the mouth of the flask. The flask B is about half filled with oil of vitriol, and the tubes being arranged in their places, as represented in the en- graving, the whole apparatus is accurately weij,' time having been allowed for the mixture of y the older chemists to several black powder* on account of their color. (See the following ar- ticles.) .ETHIOPS, ANIMAL. This was a powder obtained by burning various animals, as the hedge- hog, mole, sparrow, 10034 ' 10024 I 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 I 1001 1001 I 1001 1001 I 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 iooo 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 I 9984 1000 998} 1000 I 9984 1000 1000 999J 9994 9994 909| 9994 9994 9994 9994 999| 9994 9994 9994 9994 9994 9994 9994 999| 9994 9994 9994 9994 9994 9994 9994 9994 9994 9994 9994 9994 9994 9994 999| 9994 9994 9994 9994 999 999 999 999 999 999 998] 9984 9984 999 999 999 999 999 999 9984 998] 998] 998} 9984 9984 998 998 998 998 998 998 998 998 998 998 998 998 998 998 9974 997] 9974 9974 997] 0974 997] 9974 9974 997| 9974 997] 997| 997J 9974 997* 997* 9974 6 998 998 998 998 998 998 998 998 9974 9974 9974 9974 9974 9974 9974 9974 9974 9974 9974 9974 9974 9974 9974 9974 9974 997 997 997 997 997 997 997 997 997 997 997 997 9964 9964 9964 9964 99"64 9964 9964 9964 996] 996] 9964 9964 998 998 998 9974 997] 9974 9974 9974 9974 9974 997 997 997 997 997 997 997 997 997 9904 9964 99fi] 9964 9964 9904 996] 9964 9964 9964 998 9974 997 997 997 997 997 9964 996] 990] 9964 9964 9964 9964 996 996 996 996 996 996 996 996 996 9954 9954 9954 9954 9954 995] 9964 I 9954 996* 9964 990* 9964 9964 9964 9904 9954 9954 9954 9954 9954 9954 9964 9954 9964 9954 996 996 996 996 996 996 996 996 996 996 9954 9951 9954 9954 9954 9954 995 99o 995 995 995 995 995 995 995 9944 997 997 997 997 9964 9964 996* 9964 996 996 996 996 996 9954 9954 9954 9954 9954 9954 995 995 995 995 995 995 995 995 995 9944 9944 9944 9944 9944 994] 9944 9944 9944 9944 994* 9944 9944 9944 9944 9944 994 994 994 994 994 994 9935 993J 997 9964 996 990 996 9954 9954 9954 995* 9954 9954 995 995 995 995 995 9944 9944 9944 9944 9944 9944 9944 994 994 994 994 994 994 994 993J 9934 9931 993] 9934 9934 993A 9934 993* 9934 9934 9934 9934 9934 9934 993 993 993 993 993 993 9921 996 9954 995 995 9934 9924 9924 99l| 9924 ! 99l] 9924 ; 99l] 9924 \ 9914 9924 9914 9924 9914 9924 9914 9924 991* 9924 9914 9i»24 9914 992 ' 9914 992 9914 992 991 992 ! 991 992 991 992 991 9914 991 99l] : 990J ALD 42 ALE Table continued. Pure Alcohol by volume, per cent. Number of gallons which 1000 gallons of spirit at the given temperatures will measure at 59° Fahrenheit. 50° 52° 1 534° 554° 574" 59° 604° 624° 644° 664° 68° 694° 714° 734° 754° ' TV 81 82 83 84 85 86 87 88 89 90 91 92 10054 10054 10054 10054 1005* 10054 10054 10054 1005! 10054 10054 1006 10044 110034 10044 ' 10034 10044 I 10034 10044 ' 1003* 10044 I 1003* 10044 1003* 10044 1003* 10044 10034 10044 10034 10044 1003] 1004{ 1003] 1005 1004 10024 10024 10024 1002] 1002] 1002} 1002] 1002} 1002} 10024 1001 1001 1001 1001 1001 1001 1001 1001 1001 1001 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 998* 998* 9984 9984 9984 998* 998* 998* 998* 9984 9974 9974 9974 9974 997* 997* 9974 997* 997* 9974 9964 9964 9964 9904 996* 996J 9964 9904 99(54 996 9954 995] 995* 995* 9954 9954 9954 9954 9954 9944 9944 9944 9944 994* 994* 994* 9944 9944 9934 9934 9934 9934 9934 9934 9934 9934 9924 992} 9924 9924 992* 992* 9924 9924 9914 9914 991* 991* 9914 991* 991* 9914 9904 990] 990] 990* 9904 9904 9904 990 990 989) 9894 989* 989J 989| ALDEHYDAMMONIA. A compound of carbon, hydrogen, oxygen, and nitrogen, discov- ered by Doebereiner and Liebig. Prep. Sulphuric acid 6 parts; water 4 parts; alcohol, of 808, 4 parts ; hyperoxide of manganese in fine powder, 6 parts. Proc. Dilute the acid with the water, then carefully add the alcohol, and next the manganese ; agitate and distil with a gentle heat, from a spacious retort into a receiv- er surrounded with ice, and connected with the former perfectly air-tight. When six parts have distilled, re-distil this portion from its own weight of dried muriate of lime, until three parts have come over, which must be again rectified in the same manner, until 1 £ part of liquid is obtained in the receiver. This liquid must then be mixed with an equal bulk of ether, and the mixture saturated with dry ammoniacal gas; brilliant colorless pris- matic crystals will then form, which, after washing with ether and drying, are pure aldehydammonia. Prop. <$-c. Smells like turpentine ; melts at 160° ; volatilizes, unchanged at 212° ; decomposed by exposure to the air; soluble in most menstrua ex- cept ether. Use. To m^ke aldehyde. . ALDEHYDE. Syt. Hydrate of Oxide of Acetule. A compound of carbon, hydrogen, and oxygen. Discovered by Liebig. Prep. Dissolve aldehydammonia in an equal weight of water; place the solution in a retort, and add rather less than an equal quantity of sul- phuric acid, diluted with about half its weight of water; then distil as above. Rectify the product twice from its own weight of dried muriate of lime, at a heat not exceeding 86° Fahr. Prop. An ethereous liquid, boiling at 72° ; neu- tral, inflammable, mixes with water, alcohol, and ether; decomposed by exposure to the air, into liquid acetic acid ; spoils by age. ALDEHYDIC ACID. Syn. Acetulous Acid. Lampic Acid. An acid not perfectly known, but supposed by Liebig to be the lampic acid of Davy and Faraday, or at least its essen- tial part. Prep. Digest oxide of silver in aldehyde, decant and pass sulphureted hydrogen through the liquid to throw down the silver. The product is a weak acid, forming salts called aldehydates with the bases. These salts suffer decomposition during the evaporation of their solutions, and hence cannot be obtained in the dry state. ALE. Syn. Barley Wine. Ala. Cerevisia A pale-colored liquor, brewed from lightly-dried malt. It is usually described as containing more saccharine matter and mucilage than beer or por- ter ; but this is not a characteristic of the finer kinds of ale, as Old Burton, Scotch, East India, and other varieties, that have undergone a tho- rough fermentation. New or mild ale, on the contrary, abounds in undecomposed sugar and gum, and is thus rendered more nutritious, though less alcoholic, than the above varieties. Process of brewing ale. The various opera- tions of brewing are nearly the same for every spe- cies of malt liquor, the differences in the products arising from the materials employed, the heat of the water used for mashing, and the temperature at which the fermentation is conducted. (See Brewing.) For ale, pale or lightly-dried malt should be chosen, as well as pale hops, if it be de- sired to brew a liquor possessing but little color; and the fermentation should be carried on at a low temperature. Almost every county in England has its variety of ale, but the difference consists chiefly (the same quantity of malt and hops being used) in the preparation of the malt. The water may in some cases vary in quality, the boiling may be longer or shorter, or the liquor may be turned on at a different heat; but these circum- stances being considered, one general process serves for the whole, as before observed. For im- mediate use, the malt may be all pale; but if brewed for keeping, or in warm weather, one- fourth should be amber malt. 6 lbs. of Kent hops should be used to the quarter, or 8 to 10 lbs. for keeping ale. The stronger ales contain about 8jj of absolute alcohol; ordinary ales from 5 to 68- ALE, BARNSTAPLE. Boil the water, then throw two pails of cold water into the mash tun, and afterwards the boiling water ; then immediate- ly put in the malt, half a bushel at a time. After stirring it till it is soaked, cap it with malt or bran, cover it close, and let it stand three hours; then see if the mash is sunk in the middle; if so, it must be filled level with boiling water, to stand half an hour; when it should be run off in a goose-quill stream, and be returned upon the grains, by a bowl or pailful at a time, as far back as possible from the cock, until the liquor strains through the body of the grains, and at last comes very fine; otherwise the thick parts are forced ALE 43 ALE down to the cock. This is called "doubling;" continue to do so for half an hour, then stop, and let it stand half an hour longer in winter, but not in summer. Then rub four pounds of hops very fine into the sieve, for the wort to run through; do not draw it off too near before lading over more boiling water out of the copper. This is to be continued until the whole quantity of ale wort is obtained, which, with all the hops, is to be boiled till the liquor breaks or curdles. Now empty all into large tubs or coolers; work, when cold, with the same hops altogether, thus: put a little yeast, and that not a day old, to a quantity, and mix that with the rest, to work 12 or 14 hours, and then Btrain it directly into the barrel, where keep filling it until it has done working. ALE, BAVARIAN. This is a beer which has been made to ferment at a low temperature, until all the substances which favor acetification have been rendered insoluble. The fermentation is conducted in wide, open, shallow vessels, which afford free and unlimited access to atmospheric oxygen, and this in a situation where the tempe- rature does not exceed 46° to 50° Fahr. A sep- aration of the nitrogeneous constituents, i. e., the exciters of acidification, takes place simultaneous- ly on the surface and within the whole body of the liquid. The clearing of the fluid is the sign by which it is known that these matters have sep- arated. The beer obtained in this way is invaria- bly far superior, in quality and stability, to that brewed according to the common method. (Lie- big.) To be enabled to keep the temperature at the proper point, the operation is conducted in a situation removed as much as possible from the influence of atmospherical changes of tempera- ture, and at such seasons as are favorable to the same. ALE, BURTON. This is a strong species of ale, of which only a barrel and a half is drawn from a quarter of malt. Temperature for the first mash 170°, and for the second 180°, followed by a mash for table beer at 165°. It is tunned at 58°, and cleansed at 72°. The finest pale malt, ground two days -before using, together with the best Kent hops, (6 to 8 lbs. per quarter,) are em- ployed for this ale. Remarks. The " East India" ale, brewed by Bass & Co. of Burton, is perhaps as near an approach to wine as malt liquor is ca- pable of receiving; it is indeed the " wine of malt." ALE, DORCHESTER. This is made with £ pale and | amber malt, with 6 or 7 lbs. of hops to the quarter. The temperature of the first mash is 170°, and of the second 180° ; boiled for 30 minutes, and the yeast added, when a head gath- ers on the gyle-tun ; work until the head begins to fall, then cleanse and fill up the casks as long as they continue to work. Two barrels per quarter. ALE, EDINBURGH. Employ the best pale malt. 1st. Mash two barrels per quarter, at 180° ; mash three quarters of an hour, let it stand 1 hour, and allow half an hour to run off the wort. 2d. Mash 1 barrel per quarter, at 183° ; mash three quarters of an hour, let it stand three quar- ters of an hour, and tap as before. 3d. Mash one barrel per quarter, at 170° ; mash half an hour, lot it stand half an hour, and tap as before. The first and second .✓ort may be mixed together, boiling them about an hour or an hour and a quar- ter, with a quantity of hops proportioned to the time the beer is intended to be kept. The first two may be mixed at the heat of 60° in the gyle- tun, and the second should be fermented separate- ly for small beer. Remarks. The best hops should be used, in the proportion of about 4 lbs. for every quarter of malt employed. ALE, ESSEX. This ale is brewed by putting boiling water into the mash-tun, and adding there- to some cold water, and then the malt, gradually, until a cover of dry malt is left on top ; it is then allowed to stand three hours ; in the mean time a similar mash is made with half the previous quan- tity of malt, and the same measure of water, in another tun, as soon after the first as possible; both worts are drawn off simultaneously, and the latter serves as a second water for the malt used for the former. The smaller quantity of malt is then mashed a second time with water. The first wort is boiled an hour, or until it breaks into large flakes, when half of it is taken out, and the re- maining raw wort added to it, and the boiling con- tinued until it again breaks. The wort is now drained off from the grains and boiled, and a fresh mash made with the wort from the second tun, for the larger quantity of malt, and very hot water for the other; after an hour it is drawn off, and another mash made for small beer. The propor- tion of hops is 2i lbs. per quarter. This system of mashing, which has no advantage over the usual way, has been called " succession mash- ing." ALE FOR PRIVATE FAMILIES. A bush- el and three quarters of ground malt and a pound of hops are sufficient to make 18 gallons of good family ale. That the saccharine matter of the malt may be extracted by infusion, without the fa- rina, the temperature of the water should not ex- ceed 165° or 170° Fahrenheit's thermometer. The quantity of water should be divided into two portions, one of which should be poured upon the malt as speedily as possible, and the whole being well mixed together by active stirring, the vessel should be closely covered over for an hour ; if the weather be cold, for an hour and a half. If hard water be employed, it should be boiled, and the temperature allowed, by exposure to the atmosphere, to fall to about 165° Fahr.; but if rain water is used, it may- be added to the malt as soon as it reaches the point. After standing the proper time, the wort must be drawn off into another vessel, and the second portion of the water poured on, which should be allowed to mash an hour. The first wort may then be boiled with £ lb. of hops for one hour, by which time the second mashing will be ready to be drawn off, and should be boiled for half an hour, with \ lb. of fresh hops. The two liquors should now be mixed and cooled down to the tem- perature of 60° or 65°, when a pint of good thick yeast should be well stirred in, and as soon as the fermentation is completed, the liquor may be drawn off into a clean cask previously rinsed with boiling water. When the slow fermentation which will ensue has ceased, the cask should be loosely bunged for two days, after which, if the liquor be left quiet, the bung may be properly fastened. ALE 44 ALE Pale malt is the best, because, when highly dried, it does not afford so much saccharine matter. If the malt be new, it should be exposed to the air, in a dry room, for two days previously to its being used. A third mashing may be made for table beer. ALE, LONDON. I. Pale mak, 14 quarters ; hops, 112 lbs.; mash with 28, 18, and 18 barrels of water; boil with the hops, cool, and set with 36 lbs. of yeast; cleanse with salt, 3 lbs. Prod. 34 barrels, or 1| gallon for each gallon of malt employed. II. (To brew two barrels from a quarter of malt.) Turn on two barrels at 175° ; mash one hour, and let it stand for the same time. For sec- ond mash, turn on one barrel at 160° ; mash one hour, and stand one hour: boil the first wort brisk- ly for one hour ; and boil the second two hours, or till the whole is two barrels. Cool down to 60°, and tun. Cleanse on the fourth day at 72°, pre- viously mixing in 2 ounces of ginger, £ an ounce of 6alt, and a handful of flour. Keep the working tun closely covered, and just before the head be- gins to fall, skim the top, and rouse in the rest. When the blebs are large and on the fret, rouse in i an ounce of salt, a handful of malted bean-flour, and some fresh yeast, after which it will ferment more kindly, and the cleansing may soon follow, with the new head on. Take care to fill up the casks while working, and before bunging put a handful of scalded hops into each. ALE, NOTTINGHAM. This is usually brew- ed by three mashings in the common way, but a much longer time is occupied in the mashing, and after drawing off each wort, the grains are washed by pouring over them fresh water from the copper, by two or three bowlfuls at a time. The boiling is conducted in separate portions for each wort, and the hops, enclosed in a coarse canvass bag, are only allowed to boil for half an hour, when they are taken out, and the boiling continued until the bub- bles break into little ragged particles. The quan- tity of hops is divided between the boilings, and frequently the second and third worts are boiled together. ALE, RINGWOOD. This brewing produces two h-Tels and a half from the quarter. The best pale malt and j -ocket hops are used, at the rate of 6 lbs. to the quarter. Turn on first mash at 180°, and second mash at 190°. Pitch the tun at 60°, and cleanse at 80°. Mash successively one hour, and three quarters of an hour, standing an hour and a half, and two hours. Add in the tun 2 lbs. of yeast for every barrel, and coat with salt and flour after the first skimming. ALE, SCOTCH. This ale is brewed from the finest pale malt, (made from the best English bar- ley,) and the best East Kent Hops, or for long keeping, Farnham's or Country's. The brewing is restricted to the colder portions of the year, as it never succeeds so well during the months of May, June, July, August, and September. Only one mask is made, and that at a temperature of about 180°, with one-third of the quantity of the water necessary for the brewing. The mash-tun is then covered up for half an hour, when the wort is drawn off, and a quantity of water, at the same temperature as before, sprinkled uniformly over its surface. This is performed by throwing the water into a vessel with a bottom full of holes, somewhat resembling a shower-bath, from whence it de- scends and gets equally distributed over every por- tion of tho malt. After an interval of about twenty minutes, this wort is drawn off from sev- eral small cocks or holes, placed round the circum- ference of the bottom, by which means the hot water is made to percolate equally through every particle of the mass. This operation, called " sparging," is performed a second time, with a fresh portion of hot water, and after a like inter- val, is again drawn off. This process is repeated several times, until the density of the mixed worts becomes adapted to the quality of the ale required Usually eight or ten " spargings" are employed, the latter at about 5° or 10° cooler than the first The skilful brewer so divides his water that it may produce a wort of the proper gravity ; but when a very strong one is required, the latter " sparges1 are used for table beer, or as water for mashing a fresh quantity of malt. In this way, 1 quarter of malt will yield full 81 lbs. of extract. The wort is next boiled, with 4 lbs. of hops to every quarter of malt, and afterwards cooled down to 50° before adding the yeast. The latter must not exceed half a gallon for every 100 gallons of wort. The fermentation now commences and proceeds slowly, and in some brewings is accelerated by rousing up twice a day. Should more yeast be absolutely required in a few days, a little may be added. The fermentation generally continues for 15 to 20 days; and the ale is not cleansed before the de- gree of attenuation does not exceed £ lb. per diem, and not more than \ of the original gravity of the wort remains. This process is then performed by drawing off without skimming. As soon as the fermentation is finished, the ale is put into care- fully prepared casks, and stored in a cold cellar. Here it soon becomes fine, and seldom wants racking before sale. The usual gravity per barrel of the best Scotch ale is about 38 or 40 lbs., and is seldom lower than 32 lbs. or higher than 44 lbs. ALE, TABLE. This is usually made by mash- ing the grains after the wort for the strong ale or beer has been drawn off; but if a separate brew- ing be made, the following are good proportions •— Pale malt 1 quarter ; mash with 4, 3, and 2rJ bar- rels of water; boil with 5 lbs. of hops, set with 1 gallon of yeast, and cleanse by beating the head in and letting it work out. Prod. 8$ barrels, or full 4 gallons of ale for 1 of malt. ALE, WELSH. Take 3 quarters of the best pale malt and 25 lbs. of hops; turn on the first liquor at 178°. Mash for an hour and a half, and stand two hours. Turn on second liquor at 190°, and stand two hours. Boil an hour and a half; pitch the tun at 62°, and cleanse at 80°, using salt and flour. After the second mash, turn on for table beer at 150°. Mash three quarters of an hour, and stand two hours. ALE, WHITE, (DEVONSHIRE.) Boil to- gether 12 gallons of pale ale-wort, 1 handful of hops, and 4 or 5 lbs. of grouts; cool, and add of yeast 3 lbs When it is in a state of lively fer- mentation, bottle in strong stone half-pints; well cork them down, and wire them. Remarks. This is much drunk in some parts of Devonshire. It effervesces when opened. ALE, WINDSOR. This ale is brewed fro* ALK 45 ALK the best pale malt and hops. Turn on the first water at 180° ; mash 1$ hour, and stand 1 hour; boil 1 hour. Turn on the second liquor at 190°; stand | of an hour; boil 3 hours. Turn on the third liquor at 165° ; mash J of an hour; stand J of an hour. Pitch the tun at 60° ; cleanse at 80° on the third day. Skim as soon as a close yeasty head appears, until the yeast ceases to rise, then rouse in £ lb. of hops per quarter. ALE, YORKSHIRE OAT. The malt used is made from oats of the white sort, and dried with coke. Mash 1 quarter of ground malt with 44 gallons of cold soft water, and let it stand 12 hours ; then draw off the wort, and infuse therein for 3 hours 2 lbs. of hops, well rubbed between the hands; next strain ; tun it, and work it briskly with yeaet for two or three days ; cleanse, and in ten days it will be fit to bottle. It drinks very smooth, brisk, and pleasant, but will not keep. It looks very much like white wine. ALIZARINE. Syn. Pure madder red. Prep. I. Expose madder red to a gentle heat, when the alizarine will sublime, and may be collected. II. Add powdered madder cautiously to its own weight of oil of vitriol, and mix with a glass rod ; then wash the charred mass with clean cold wa- ter ; dry, and sublime a6 before. Prop. Orange-red crystals, very soluble in alka- line solutions, which it colors violet; dyes mor- danted cloth red. Remark. The name is derived from Ali-zari, the commercial name of madder, in the Levant. ALKALIS. (From the Arabic al, an essence, and kali, the plant from which soda was first ob- tained.) Substances which possess the property of forming salts with the acids, and for the most part of turning the vegetable blues to greens, and yellow turmeric paper brown. The principal alka- lis are soda, potassa, and ammonia. The first has been called the mineral, the second the vege- table, and the third the volatile alkali; but this distinction is now nearly obsolete. Soda and po- tassa have also been called the fixed alkalis, from their permauence in the fire. Hist. At the time when Lavoisier declared oxy- gen to be the universal acidifying principle, Mor- veau conjectured hydrogen to be the alkalifying principle ; but it was afterwards demonstrated by Sir H. Davy, that potassa and soda are actually the oxides of tne m»tals, potassium and sodium. Ammonia is a compound of nitrogen and hydro- gen. Dr. Murray conceived that either hydrogen or oxygen might generate alkalinity, but that a combination of the two was necessary to give this condition in its utmost energy. This theory is not, however, borne out by the observed phenomena of chemistry. Gay Lussac conceives alkalinity to be the result of "the alkalifying property of th*< met- al, and the acidifying property of the oxygen, modified both by combination and by the propor- tions ;" but this " coalition" theory is far from sat- isfactory. Of late years the list of alkalis has been greatly extended by the discovery of several vege- table principles possessing important properties and forming salts with the acids. (See Alka- loids.) Prop., Char., tyc. Potassa, soda, and ammonia, are known by the following characteristics :—An acid urinous taste ; a great degree of causticity; | turning vegetable blues green, and yellows brown; forming soaps with the fixed oils ; solubility in wa- ter, and when pure in alcohol; forming salts with the acids ; solubility of their carbonates; action of their carbonates oil vegetable colors. Caution. The pure or caustic alkalis should be kept in glass bottles, well secured from the air, as they rapidly absorb carbonic acid and become car- bonates. ALKALIMETER. A measurer of alka- linity. ALKALIMETRY. The art or method of de- termining the amount of pure alkali contained in any given sample. Remarks on the principles of alkalimetry, fyc. The common method of alkalimetry is founded on the known quantity of pure alkali, which is required to saturate a given weight of dilute sulphuric acid. The glasses, or alkalimeters, as they are called, with which the operation is performed, are usually graduated into 100 parts, for the purpose of exact- ly estimating the quantity of acid employed. As the sulphuric acid, however, acts upon the muri- ates and sulphurets usually present in the alkalis of commerce, this plan does not admit of great ac- curacy, unless proper precautions are taken to avoid the source of error. Some years ago the German soap-boilers estimated the strength of their ashes by merely pouring a quart of water on a pound of the former, and then putting in a piece of Dutch soap, added water, in small portions at a time, until it sank. The more water required to effect this object, the richer the ashes were supposed to be in alkali. This plan was also employed at no very distant period in some of the remoter parts of the United Kingdom. Alkalimetry has lately en- gaged the attention of some eminent chemists, and by following their suggestions, the " richness" of any sample of ashes, barilla, or alkalis may be obtained with great precision. The importance of this subject to the soap-maker and manufacturing chemist must at once be evident. The following are among the most approved methods of pro- cedure. I. Oper. Pulverize a little of the sample, and weigh therefrom exactly 100 grs., agitate it with about half an ounce of hot water in a vial or small tube, then allow it to settle, and pour off the clear into another tube or vial; repeat the process with a second and third portion of hot water, or until nothing soluble remains, observing each time to allow the liquid to settle before pouring it off; the mixed liquid is then tested as follows:—the test acid described below is poured into the glass tube until it reaches exactly to the line marked by the name of the alkali under examination ; water is then poured in to the line marked 1 or 1000, and the whole is well mixed by placing the thumb on the orifice of the tube and shaking it well. The measure of this dilute acid must then be carefully observed, and water added to make up the proper quantity as before ; should it be lower than the mark, agitation being again employed. The test liquor thus prepared is then to be carefully added to the solution of the alkali just described until it be perfectly neutralized. The quantity of ine test liquor used must next be read off from the graduated part of the tube, each larger divisiou of which will represent 1 gr. per cent, of the pure ALK 46 ALK alkali, or its carbonate, as the case may be, in the •sample under examination. The glass tube, or Faraday's alkalimeter, as it is called, is here represented, and is about 9£ inches long, and J of an inch wide ; it is gradua- ted into 100 parts, each of which represents 10 grs. of water. Opposite the numbers 23-44, 48-96, 54-63, and 65, are cut the words written in the margin, and indicate the quantity of test acid to be employed for each of these alkalis. The test acid being then poured in up to the proper marks, and tho tube filled up to 1000 with pure water, gives a test solution equal to 100 grs. of the given alkalis. Consequently, the number of its divisions consumed to produce saturation, will exactly ex- press the value per cent. prs- C^ 1000_•—* _j — 5 —10 —15 Potassa......_ __so Carbonate of Soda . — —55 — 60 Carbonate of Potassa .— —(s — 70 ___7S The test acid is prepared by adding pure water to pure sulphuric acid until the specific gravity is reduced to 1*127 at 60° F., (about 1 measure of acid to 4 of water.) The sp. gr. must be carefully ascertained by means of the sp. gr. bottle, and its strength checked by adding to 100 grs. of it, chlo- ride of barium until it no longer produces a precipi- tate. This, when washed and dried at a low red heat, contains 33-3 per cent, of sulphuric acid, from which the strength of the test acid may be calcu- lated. This is an easy method of alkalimetry, and admits of as -"•rtaining the quantity of alkali to the J or J, of 1 per cent. It is best to keep a quantity of the test acid always ready prepared, as it saves trouble. Should a Faraday's alkalimeter not be at hand, any other mode by which the test liquor can be accurately measured will do as well. II. Dissolve 100 grs. of alkali, as described in the last method, then take a known weight of the test acid prepared as directed below, and proceed to neutralize the alkaline solution therewith in the way above mentioned -} then again weigh the test acid and note the quantity consumed ; the loss of weight divided by 10 gives the real per c; ",*.age of pure alkali. Test acid for soda. Add pure sulphuric acid to distilled water until the sp. gr. becomes about 1-109 (about 5 water and 1 aeid.) and 100 grs. of which saturate exactly 17 grs. of pure carbonate of soda dried at a dull red heat; or which is the same, 313 grs. should contain exactly 40 grs. of real sulphuric acid, when 10 grs. will be equivalent to 1 gr. of pure soda. The strength may be also tested by chloride of barium. Test acid for potassa. This acid should be weaker than the 1st, its sp. gr. about 1*069 or 1*070 ; 471 i grs. should contain exactly 40 grs. of real sulphuric acid, and 1000 grs. should neutral- ize exactly 66J Crs. of dry carbonate of soda. Remarks. The most convenient vessel to con- tain the test acid during the operation is Schuster's alkalimeter, described under the article Acetim- etry. This method of alkalimetry admits of great accuracy. By careful manipulation the content of real alkali may be estimated to the one-tenth of 1 per cent. (C. Watt, jun., Chemist, No. 50.) The art of weighing admits of much greater accuracy than that of measuring, espe. cially where small quantities are concerned. This is the method employed at Apothecary's Hall, at the Polytechnic Institution, (by Mr. L. Thomp- son,) in the Laboratory of Messrs. Hawes, and in various other places where great precision is de- sired. III. (Method of Fresenius and Will, of Giessen.) Oper. The flask B (article Acidime- try) is about half filled with oil of vitriol, and the sample of alkali is put into the flask A, and water poured on until it be almost half full. The tubes are then fitted into the apparatus quite air-tight; the end of the tube ,b is fastened with a bit of wax, and the whole is carefully weighed. The appa- ratus is now removed from the scales, and the mouth applied to the end of the tube h, and the air in the flask B rarefied by suction; the conse- quence of which is, that the oil of vitriol in B flows over into A. The evolution of carbonic acid im- mediately commences, which, from the construc- tion of the apparatus, has to pass through the oil of vitriol, before it can escape by the tube d, by which means it is rendered quite dry. Whenever the effervescence flags, a little more acid must be sucked over, until the whole of the carbonate be decomposed, after which an additional quantity is made to pass into A sufficient to raise the temper- ature considerably, which will have the effect of expelling all the gas absorbed by the fluid during the operation. As soon as this is completed, the wax is removed from the aperture 4, and suction applied to h until all the carbonic acid gas in the apparatus is replaced by atmospheric air. The whole must now be allowed to cool, when it must be again weighed. The loss of weight gives ex- actly the amount of dry carbonic acid gas that was contained in the specimen, from which the weight of pure alkali is estimated. Every 2212 grs. of dry carbonic acid gas represent exactly 31-3 grs. of pure soda, and 47-15 grs. of pure potassa. Remarks. Should the specimen contain caustic potassa, (as many of those of commerce do,) it should be triturated, previously to testing, with an equal weight of pure quartz sand, and about $ of its weight of carbonate of ammonia added; the mix.ure is then placed in a capsule and moistened with water, and a gentle heat applied until it be quite dry, and all the ammonia expelled. Should sulphuret of potassium or caustic soda be present in the sample, the same method must be followed, except that instead of water the powder should be moistened with liquor of ammonia; and in the case of soda, the quantity of carbonate of ammo- nia should be at least equal to half the weight of the test specimen. It will thus be seen that unless for carbonates, (unmixed with sulphurets, bicar- ALK 47 ALK bonates, or caustic alkali,) this method requires several operations, and is consequently very trou- blesome and liable to error, except in expert hands. It is, however, a ready and elegant way of testing the pure carbonates. Concluding remarks on Alkalimetry. Rules for sampling, fyc. As each sample is taken from the cask, place it at once in a wide-mouth bottle, cork it up immediately and number it. The sam- ple should be drawn from as near the centre of the cask as possible. Before proceeding to the assay, throw the contents of the bottle upon a piece of clean paper, crush the lumps, and mix them with the small; reduce the whole to coarse powder as rapidly as possible, and weigh the number of grains for trial at once. In a number of casks, at least § of them should be tested. Assays of soda should never be made while warm, as it will thereby fre- quently indicate 1 or 2 per cent, more alkali than when it has been cooled down and packed in casks. The method of trying the density of the test acid by merely dropping a bead of a known sp. gr. into it, as is frequently recommended by chemical reformers, is not sufficiently accurate to be depended on. Too much care cannot be taken to ensure the test acid of the proper strength, of which the sp. gr. alone is an insufficient proof. It is always best to keep a stock of the test acid (properly made and proved) ready for use. Those desirous of entering more largely into the subject of acidimetry, alkalimetry, &.C., are re- ferred to Bullock's " Translation of Fresenius and Will;"' some valuable papers by Mr. C. Watt, jun., in the fifth volume of the " Chemist;" and to a paper by Dr. Ure, in the third volume of the " Pharmaceutical Transactions." ALKALOIDS. Syn. Vegetable Alkalis. Organic Alkalis. Organic Bases. Substances possessing basic and alkaline properties derived from the vegetable kingdom. They are compounds of carbon, hydrogen, azote, and oxygen, and have hence been distinguished by Dr. Collier, by the mnemonic word, *' chaos," the first four letters be- ing the initials of the elements, and the " s " show- ing that they are salifiable. Some of the alka- loids are the most violent poisons with which we are acquainted; one-fiftieth of a grain of pure aconitina has endangered life. (Pereira.) The greater number possess similar properties to the plant from which they are extracted, but in an eminently concentrated degree. The following table exhibits the principal alkaloids described in the body of this work, together with the plants which yield them: Alkaloids. Plants. Aconitina . . Aconitum Napellus. Aricina . . . Arica Bark. Atropia . . . Atropia Belladonna. Brucia . . . Strychnos Nux Vomica. Cinchonia . . Cinchona Lancifolia. Codeia . . . Opium. Conia .... Conia Maculatum. Corydalia. . . Corydalis Tuberosa. Cynapia . . . jEthusa Cynapium. Daturia . . . Datura Stramonium. Delphia . . . Delphinium Staphisagria. Digitalia . . . Digitalis Purpurea. Emetina . . . Cephaelis Ipecacuanha. Alkaloids. Hyoscyamia Meconia "] Morphia I Narceia { NarcotinaJ Nicotina . . Picrotoxia Quinia . . Sanguinaria . Solania . . Thebaia . . Veratria . . Plants. Hyoscyamus Niger. Opium. Nicotiana Tabacum. Meiiispermum Coculus. Cinchona Cordifolia. Sanguinaria Canadensis. Solanum Nigrum. Opium. Veratrum Sabadilla. The following general method of procuring the alkaloids will be found applicable to such as full directions are not given for under their respec- tive heads. 1. (When the base is insoluble in water, non- volatile, and existing in the plant in an insoluble form.) Proc. Boil or macerate the bruised plant in water acidulated with muriatic acid, filter, neu- tralize the acid with an alkali, (ammonia, lime, or magnesia,) and collect the precipitate, which must be purified by resolution in dilute acid, digestion with animal charcoal, and subsequent crystalliza- tion or precipitation by an alkali; or the first pre- cipitate may be purified by dissolving it repeatedly in alcohol. 2. (When the base is insoluble in water, and non-volatile, but existing in the plant in a soluble state.) Proc. Boil or macerate in hot water ns before ; filter and precipitate by adding an alkali; purify as last. 3. (When the base is soluble in water, and non-volatile.) Proc. Make an infusion with a di- lute acid, (muriatic;) concentrate by a gentle heat; treat the liquor with potassa and ether, (conjointly ;) decant and evaporate. 4. (When the base is both soluble in water and volatile.) Proc. The vegetable or its extract may be mixed with potassa and distilled ; the product, neutralized with oxalic or sulphuric acid, carefully evaporated to dryness, and digested in alcohol, and this solution agitated with potassa and ether; the ethereal solution thus formed, if carefully evapo- rated, leaves the base nearly pure. It may be further purified by cautious distillation. Remarks. The above is a mere view of the four general processes of extracting the alkaloids, which, for success, require considerable address in manipulating. The plan adopted for the extrac- tion of the principal alkaloids of commerce, will be found fully described under their respective heads. ALKALOIDS, TESTS FOR THE. Per- chloride of gold is a more decisive test of certain vegetable alkalis than the double chloride of so- dium and gold, already employed for this purpose. The following are the colors of the precipitates which it produces with the salts of the annexed alkalis dissolved in water: quinine, buff-colored; cinchonine, sulphur-yellow; morphine, yellow, then bluish, and lastly, violet; in this last state the gold is reduced, and the precipitate is insoluble in water, alcohol, the caustic alkalis, and sulphu- ric, nitric, or hydro-chloric acids; it forms with aqua regia a solution which is precipitated by pro- tosulphate of iron; brucine, milk-, coffee-, and ALK is ALK then chocolate-brown ; strychnine,canary-yellow; veratrine, slightly greenish-yellow. All these precipitates, with the exception men- tioned, are very soluble in alcohol, insoluble in ether, and slightly soluble in water. Among the reactions of chloride of gold, there are two which appear to be especially important: they are those which occur with morphine and brucine ; these are sufficiently marked to prevent these alkalis from being mistaken for each other, and also yield pretty good characteristics for dis- tinguishing brucine from strychnine. (MM. La- rocque and Thibierge.) The above authors have arrived at the following conclusions : 1st. By the aid of reagents it is possible to de- termine the presence of morphine, strychnine, and brucine in substances which, after being mixed with the salts of these alkalis, have undergone the vinous, acetic, or putrefactive fermentation. M. Orfila has already shown that the putrefactive fer- mentation does not alter morphine. 2d. Crystallized iodic acid, or a concentrated solution of this acid, is susceptible of being decom- posed by neutral azotized bodies; but a dilute so- ution of this acid cannot be decomposed by them unless there be added concentrated sulphuric acid, crystallizable acetic acid, oxalic, citric, or tartaric acid. 3d. Iodic acid should not be employed as a test of morphine without the greatest caution. 4th. Perchloride of gold produces such effects with the vegetable alkalis, as serve to distinguish morphine, brucine, and strychnine from each other. 5th. The reagents on which the greatest reli- ance may be placed as tests of morphine are, nitric acid, neutral perchloride of iron, and perchloride of gold. 6th. By the use of reagents, morphine which has been mixed with beer, soup, or milk, may be detected. 7th. It is also easy to prove by reagents the presence of meconic acid in soup or milk, espe- cially when the meconate of lead is decomposed by dilute sulphuric acid. (Phil. Mag., Dec, 1842.) ALKANET. Syn. Alkanet Root. Qual., use, /) D, Connecting Pipes. F. F, Waste Pipe and Receiver. a, Safety Tube will make a water of about 0-970, and with only 2 measures of water, one of about 0960. I have known the strongest sold so low as 9d. per lb., and the last at 1-Jd. Caution. It should be kept in well-stoppered bottles in a cool cellar. Props., Uses, 6fC. Ammonia-water is stimulant, antacid, diaphoretic, and rubefacient. Dose. 5 to 20 drops, mixed with water. It is seldom used internally. It enters into the composition of seve- ral valuable external remedies, and is employed in many chemical operations. Pur. It should neither effervesce with acids, nor form a precipitate with lime, water, or chloride of calcium. When neutralized with nitric acid, nei- ther nitrate of silver, oxalic acid, nor sesquicarbon- ate of ammonia, should produce any precipitate. Ant. When the fumes have been inhaled, ex- pose the patient to a current of fresh air, and when the liquid has been swallowed, administer vinegai or lemon-juice mixed with water. Strength. The usual method of ascertaining the strength of liquid ammonia is by taking its specific gravity ; before this is done, however, it is best to test it for its purity, as the presence of foreign matter will alter its density. (See Alkalimetry and Ammonimetry.) AMMONIA, LIQUID, FOR TESTING. Syn. Henry's Pure Ammonia Water. Prep. Add distilled water to pure liquicLammonia, until its sp. gr. be exactly 0-970. Use. For testing, in acidimetry, &c. One meas- ure of this water is exactly equal to one measure AMM 59 AMM tf sulphuric acid, sp. gr. 1*135 ; one measure of nitric acid, sp. gr. 1*143, and one measure of mu- riatic acid, sp. gr. 1-074. Useful in assaying waters. AMMONIA, MURIATE OF. Syn. Hydro- chlorate of Ammonia. Sal Ammoniac Chlo- ride of Ammonium. Chloro-amidide of Hy- drogen. Hist. This substance is said to have been known to antiquity ; it was formerly pre- pared in Egypt by the sublimation of the soot from camel's duns, which yields from J to ^ its weight. ^See Ammonia.) The sal ammoniac of commerce is now wholly prepared at the great chemical works, and never by the small consumer, by whom it is merely occasionally refined or purified. Prep. The crude ammoniacal salt of the gas- works is plar*«d in iron pots, lined with clay, and a leaden dorntf or head adapted, and heat applied until the whole has sublimed. When the crude salt is a sulphate, it is mixed with a sufficient quan- tity of muriate of soda before sublimation, and the sal ammoniac is formed by the double decomposi- tion of the ingredients. The preceding figure repre- sents the arrangement of the pots and furnace, which was adopted a few years since at the West- minster gas-works. The preparation of sal ammoniac from bone- spirit salt is nearly similar. Prop. The sal ammoniac of commerce is found under the form of large hemispherical, cup-like cakes or masses, having a semi-crystalline texture, and varying in weight from 100 to 1000 lbs. Use. It is much used in the arts, especially in the working of metals and in dyeing; it is also employed in large quantities to give a factitious pungency to snuff; in chemistry to form frigoric mixtures, &c, and in medicine, it is given as a di- uretic, stimulant, and tonic. Dose. 5 to 20 grs. (combined with bark, in agues.) 1 oz. to half a pint of water forms a good chilblain lotion. Pur. It forms a clear and colorless solution with water, and wholly volatilizes by heat. Mixed with lime or caustic potassa, it evolves the pungent •dor of ammonia; it gives a white curdy precipi- tate with nitrate of silver. Remarks. The sal ammoniac of commerce is generally sufficiently pure for all the purposes of the arts, but when wanted of greater purity, it may be broken into pieces and re-sublimed from an earthenware vessel into a large receiver of earth- enware or glass, in which state it is known as "flowers of sal ammoniac," from being in fine powder. Chemically pure hydrochlorate of am- monia may be preparedby adding the pure carbon- ate of ammonia to dilute hydrochloric acid until saturated. AMMONIA, NITRATE OF. Syn. Nitrate of Oxide of Ammonium. Nitrum Flammans. Nitrum Semi-volatile. Prep. Dilute nitric acid with 3 times its weight of water, then gradually add sesquicarbonate of ammonia in powder, to satura- tion ; evaporate and crystallize. Uses, -47 0-9476 13-46 86-54 0-9513 12*40 87-60 0-9545 11*56 88-44 0-9573 10-82 89-18 0-9597 1017 89-83 0-9619 9-60 90-40 0-9692 9-50 90-50 II. Table of the Per Centage of Pure Ammonia, and of Ammonia Water of 09000 in Water of Ammonia of the specific gravity 0-9000 to 0-9945. By Dr. Ure. Water of 0-900. Ammonia in 100. Water in 100. Sp. Gr. by experiment. 100 26-500 73 500 0-9000 95 25-175 74 825 0-9045 90 23-850 76 150 0-9090 85 22-525 77 475 0-9133 80 21-200 78 800 0-9177 75 19-875 80 125 0-9227 70 18-550 81 450 0-9275 65 17-225 82 775 0-9320 60 15-900 84 100 0-9363 55 14-575 85 425 0-9410 50 13-250 86 750 0-9455 45 11-925 88 075 0-9510 40 10 600 89 400 0-9564 35 9-275 90 725 0-9614 30 7-950 92 050 0-9662 25 6-625 93 375 0-9716 20 5-300 94 700 0-9768 15 3-975 96 025 0-9828 10 2-650 97 350 0-9887 5 1-325 98-675 0-9945 AMMONIACUM. A gum resin, the inspissa- ted juice of the dorema ammoniacum. It is stim- ulant and expectorant, and is much used in ca- tarrhs. Dose. 10 to 30 grs. in pills, or diffused through water. AMMONIACUM, STRAINED. Prep. I. Boil the ammoniacum with water, until it forms an emulsion or milk, then strain it through can- vass ; boil the refuse a second time with more water; mix the liquors, and evaporate to a proper consistence. II. Place the gum on a sieve or canvass strainer, and put it on the top of a copper pan, containing a little boiling water. The steam will soften the gum, which will then run through, leaving the impurities behind ; evaporate as before. Remarks. The first method is that usually adopted in trade; but the second preserves the odor of the gum much better. Use. To make the plaster of ammoniacum, and the plaster of ammo- niacum and mercurv. AMNIOTIC ACID. Vauquelin and Buniva gt"e this name to allantoin, which, by some un- accountable mistake, they represent to have found in the liquor amnii of th*e cow, instead of the fluitj of the allantois, as shown by Lassaigne. AMULETS. Substances worn about the per- son to protect the wearer against some real or imaginary evil. Their protective power depends entirely on the imagination ; they are therefore now wholly discarded, except by the most super- stitious and ignorant. Camphor is frequently worn as a protective against fever. AMYGDALINE. Discovered by Robiquet and Boutron Charlard. Source. The bitter al- mond and the laurocerasus. Prep. Powder bitter almonds, from which the oil has been thoroughly expressed, and boil it re- peatedly in alcohol of 93 or 94°r; mix the several tinctures, and distil off the alcohol; mix thesirupy residuum with water, add a little yeast, and fer- ment ; after the fermentation has ceased, evapo- rate in a water bath to the consistence of a sirup, and add alcohol of 94$; collect the precipitate, drain well, and purify by repeated re-solutions and crystallizations. Prod. 3 to 4§. Prop., oth in powder;) oil of aniseed 2 drops ; mix and beat then :uto a mass with sirup. Dose. 5 to 20 grains ; purgative. ANGELICA, CANDIED. Prep. Boil the fresh stalks in water, to remove their bitterness, then put them into a sirup boiled to a full candy height, and boiling hot; let them remain until nearly cold, when they may be taken out and dried. Prop. Cordial and stomachic. ANGELICA, EXTRACTOR I. (Dr.MoHR.) Macerate 2 lbs. of the bruised root in 1 gallon of rectified spirit of wine, for 7 days ; strain and press ; then macerate again in 1 gallon of proof spirit; filter each separately ; mix and distil off the spirit; lastly, evaporate the remainder in a water bath to the consistence of an extract. Remarks. Quality very fine ; odor and taste strongly balsamic. II. Macerate 2 lbs. of bruised angelica root in 1 gallon of a mixture of equal parts of rectified spirit and water for 10 days, frequently shaking ; then proceed as before. Remarks. Not so bal- samic as the former. ANGELICA, INFUSION QF. Dr. Mohr directs the use of hot water, or preferably wine. Remarks. An oil and water is also obtained from angelica, by distillation ; a tincture is prepared, (with rectified spirit,) and pills are made of the extract. ANGELIC ACID. During a recent analysis of angelica root, by L. A. Buchner, jun., he dis- covered a peculiar volatile acid, of a pungent sour smell, and biting acid taste ; sometimes fluid and oleaginous, and sometimes crystallized in striated prisms. (Schmidt's Jahrb., Aug. 1842.) ANGELIC IN E. A substance obtained from the root of angelica. The process is troublesome, and the product small. ANGEL WATER. Syn. Portugal Water. Prep. Mix together 1 pint each of orange-flower and rose-water, £ pint of myrtle water, i oz. of essence of musk, and 1 oz. of essence of amber- gris ; shake them well up, and filter through white blotting-paper. ANGOSTURA BARK. The true medicinal angostura or cusparia bark is brought from the West Indies ; but a spurious and poisonous spe- cies is imported from the East Indies, and is fre- quently sold for or mixed with the former. The following tabular view of the characteristics of each will afford a ready means of detecting this fraud ANI 62 ANI Tabular View of the Characteristits of the True and i ise Angostura Barks ; drawn up by Dr. P«. REIra, from his own researches, and thosu of Guibourt, Fee, and others. True Angostura Bark. Nux Vomica, or False Angostura Bark. Form..... Odor..... Taste..... Hardness and density. < Fracture...... Epidermoid crust Inner surface • • JjS 1 Tinct. Litmus. *5 SJS <~f*| B c A o-Vd St.-* Se • S C A small quantity makes the liquor 1 < cloudy ; a large quantity makes it a > ( transparent deep red • • • • j ( Quills or flat pieces; short; often very much | twisted, like dried horn; arched backwards None, or very slight. Intensely bitter; very persistent. (Broken, or cut with difficulty; heavy; tissue ) compact. Resinous. . Variable; sometimes a spongy rust-colored layer S at other times whitish, prominent spots, innri i or less scattered or approximated. Nitric acid ' makes it intensely dark green or blackish. (Not separable into lamina;; rendered blood red ( by nitric acid. Slightly reddened. Clear yellowish-green liquor. ! Slight turbidness, not increase* ij hydrochloric acid. ( A small quantity makes the liquor clen and j paler; a large quantity transparent red. ANGOSTURIN. Syn. Cusparin. Saladin. Bitter Extractive. Prep. Digest bruised an- gostura bark in alcohol until the latter will take up no more ; then filter and submit it to sponta- neous evaporation. Prop. Dissolves in alcohol, water, and alkaline lyes; neutral; tincture of galls precipitates it from its solutions. ANHYDROUS. (In Chemistry.) Without water; a term frequently applied to gases, salts, alcohol, acids, and some other substances, to ex- press their existence in the dry state. The gases may generally be rendered anhydrous, by passing them through a tube containing very dry pow- dered chloride of calcium, and some of them by passing through strong sulphuric acid. Salts may generally be dried by cautiously submitting them to the action of heat; and alcohol, and many other volatile fluids, by careful distillation from chloride of calcium. ANIMAL SUBSTANCES USED AS FO.OD, PRESERVATION OF. Animal sub- stances are preserved in various ways, among which may be mentioned— 1. Exposure to the sun, or in a stove, to as high a heat as possible without scorching them. 2. Exposure to the frost until they become frozen, and then keeping them in this state. Meat, fish, poultry, &,c. are generally preserved in this way in the colder parts of North America, in Russia, and in many other parts of the world. In Lower Canada, the meat killed early in the winter is frequently kept in a frozen state for summer use, to prevent the necessity of killing during the hotter portions of the year. It remains perfectly fresh, tender, and good flavored. 3. Salting in brine. This method is both easy and effectual. The best plan is to dissolve about 4 lbs. of good salt in 1 gallon of water, for brine, and to immerse the meat therein, at the same time adding a few handfuls of undissolved large grained rock salt, more than it will dissolve, for the purpose of keeping up its strength. Three to ten days, depending on the size, is sufficiently long to keep the meat in the brine; when it is taken out it should be hung up to dry, packed in barrels with coarse-grained salt, or smoked, which- ever may be desired. When the brine has been used for some time, it should be boiled with some more salt and 2 or 3 eggs, then skimmed and strained. Saltpetre added to brine gives the meat a red color, and brown sugar improves the flavor. 4. Dry salting. In many parts, as in Hamp- shire, Yorkshire, &c, the process of dry salting is adopted, which consists of merely well rubbing the salt, mixed with a little saltpetre, into the meat, and afterwards sprinkling some over it, and placing it on a board or trough in such a manner that the brine may drain off. Sometimes fresh meat is packed at once in casks, with the best coarse-grained salt. 5. Pickling. This plan is to steep the sub- stance in vinegar, or a mixture of vinegar and beer. Fish is often served in this way. 6. Pyroligneous acid brushed over animal sub- stances will keep them for any length of time. This acid imparts a smoky flavor ; but pure acetic acid may be used instead. Before use, the sub- Btance should be washed or soaked in water. 7. Immersion in olive oil. Salmon and other fish are often preserved in jars of salad oil, well corked up, and cemented over. 8. Potting. Small birds, fish, cooked meat, &c. are frequently pounded to a paste, with spices and butter, and pressed into pots until nearly full) when melted clarified butter is poured over to about $ or { of an inch in depth. This plan is called " potting." 9. Smoking. This is done on the large scale by hanging the articles up in smoking rooms, into which smoke is brought from dry wood fires, kin- dled in the cellar, for the purpose of allowing it to cool and deposite its cruder part, before it arrives at ths meat. This process requires from six dayi to ii many weeks to perform it properly, and is best done in winter. In farm-houses, where dry wood is burnt, hams, &c. are often smoked by ANI 63 ANN hanging them up in some cool part of the kitchen chimney. When the meat is cut into slices, or scored deeply with a knife, to allow the smoke to penetrate it, it is called " buccaning." This is frequently performed by hunters in the remoter parts of Europe, by placing the slices on a grating of sticks, about 3 or 4 feet high, over a fire made with the branches of trees, and continuing the drying and smoking until the meat be sufficiently cured. 10. Jerking. In some hot countries the meat, cut in thin slices, is dried in the sun, beat into a paste in a mortar, and pressed into jars for use. Sometimes meal or flour is added. This plan is called "jerking," or " charqui." 11. For sea-stores, a new and simple plan has been lately adopted. Proc. Immerse the meat, cut into slices of from 4 to 8 ounces each, for five minutes in a vessel of boiling water, and dry them on network, at a regular temperature of from 120° to 125° Fahr. Next evaporate the soup formed by washing the meat, to the consistence of a thick varnish, adding a little spice to flavor it; into this fluid immerse the perfectly dry pieces of flesh, and again expose them to the proper drying tem- perature. Repeat the operation of dipping and drying a second and a third time. Remarks. For use, the meat must be cooked in the usual way for boiling, &c. In this manner, meat may be preserved without salt, for 15 to 20 months. 12. Skins are preserved by tanning, or expo- sure to the action of oak bark and other astrin- gents, until they are converted into leather; or by tawing them, which is somewhat similar. Other methods have also been occasionally adopted for objects of natural history and ana- tomical preparations ; as dilute spirit or weak so- lution of corrosive sublimate, both of which, how- ever, harden the texture of animal substances considerably. This may be prevented in the for- mer by adding a little liquor of ammonia. (See Putrefaction.) ANIMATION, SUSPENDED. Syn. As- phyxia. Causes. Various; hence it has been di- vided into four varieties, viz.: 1. From suffocation produced by hanging and drowning. 2. From suffocation produced by the inhalation of irrespirable gases or vapors, as the fumes of charcoal, fixed air, r the whole period of the ebullition ; " f3ij of muriatic acid, to ^viij of the liquid, are generally sufficient, but if the organic matter be an animal texture in a state of decay," a much larger quantity will be required. (Chris- tison.) Copper leaf cut into small strips is the most convenient form of using that metal. When the quantity of arsenic in the suspected fluid is supposed to be small, nearly half an hour should elapse before the copper should be removed. (Christison.) By means of this test, Dr. Christison discovered arsenic in the stomach 4 months after interment Susc. Yo„loot). (Rensch.) 0 ■"" ^^= C------:—Q «, The arsenical mixture. b, Arsenical ring. X. Reduction Test. If arsenious acid be well mixed with an equal weight of newly-burnt char- coal, or half its weight of black flux, and the mix- ture be placed at the bottom of a small glass tube, and heated in the flame of a spirit-lamp or candle, metallic arsenic will sublime, and on reaching the cooler portion of the tube, again condense, in the form of a metallic crust or ring. Any common test-tube, of small diameter, may be employed for this purpose, but the reduction-tube of Berzelius is perhaps the most convenient. Care must be taken, whatever shaped tube may be used, to avoid soiling its sides in the operation of inserting the mixture ; as, unless the tube be quite clear and dry, the experiment will not succeed. The pre- ceding figures represent the kind of tubes gener- ally used in this method of testing. The metallic ring, or crust, is proved to be ar- senical,—1, by the brilliancy of its outer surface often resembling a polished steel mirror. 2. The crystalline and grayisia-white appear- ance of its inner surface. 3. Its volatility when heated, shown by its es- caping from the hot portion of the tube and resting on the cooler part, further on. 4. Its conversion into minute octohedral crys- tals of arsenious acid, when repeatedly chased up and down the tube, by the cautious application of the flame of a spirit-lamp, first! to one part, and then to another. This is best effected by holding that part of the tube to which the arsenic adheres, about J of an inch above the flame, and in such a way that the metal may be slowly sublimed. Thi character of these crystals, with respect to vola- tility, lustre, transparency, and form, is so exceed- ingly well marked, that a practised eye may safely identify them, though their weight should not ex- ceed the ,-Ag- part of a grain. (Liebig and Greg- ory.) The form of the crystals is very evident with a microscope of 4 powers, (200, Wackenro- der.) The oxide of antimony never forms octo hedrons, but only prisms. (Wackenroder.) The tube is of course broken for this purpose". 5. The film being converted into arsenious acid as in the last case, may be dissolved in hot distilled water, and tested by any of the usual chemical reagents. Remarks. The above characteristics will fully show the nature of the film deposited in the reduc- tion-tube. In operating in this way it is always necessary to heat the upper portion of the mixture first, and then to expose the bulb or bottom of the tube to the full flame. Any substance containing arsenic may be tested in this way, but if it be a sulphuret, the black flux must be employed, as charcoal alone is insufficient. This test is usually regarded as decisive, as we here actually obtain the arsenic in a solid form, which may be recog- nised by the most unequivocal characters. XI. Sulphureted Hydrogen. This substance, passed through a solution of arsenious acid, imme- diately changes it to a yellow color; a turbidness shortly ensues, and a bright yellow precipitate of sesquisulphuret of arsenic or orpiment subsides af- ter heating the liquid, and may be collected on a filter. It is necessary to acidulate the fluid with acetic or hydrochloric acid before applying the test, unless it be already very sour, when it should be first neutralized by an alkali, and then acidulated. ARS 79 ARS The transmission of the gas should be continued for at least half an hour. The precipitate is known to contain arsenic: 1, From its yellow color; 2, its solubility in liquid ammonia forming a colorless Bolution ; and, 3, by yielding metallic arsenic when mixed with the black flux and submitted to the reduction test. Remarks. When the sulphuret is very small in quantity, it is better to wash it in a little water, and to dissolve it in liquid ammonia, which may be then driven off in a watch-glass or capsule, after which it may be tested as before. (Devergie.) The engravmg represents the mode of executing this test. Mode of passing sulphureted hydrogen through an ar- tenical solution. XII. Voltaic Test. The voltaic battery, made to act by two wires on a little arsenious solution, placed on a piece of window glass, developes me- tallic arsenic at the negative pole, and if the wire be formed of copper, it will become whitened and polished like silver, in consequence of the forma- tion of a tombac alloy. XIII. Wollaston's Method was to concentrate, by heat, in a capsule, a little of the suspected liquid, having previously filtered it if necessary, then to place it in the middle of a bit of window glass, and to draw lines with the fluid in different directions, so as to form a starlike figure. To one of these a particle of weak solution of ammoniacal nitrate of silver was adcfed ; to another ammonia- cal acetate of copper; to a third the deuto-acetate of iron; to a fourth ammonio-acetate of cobalt; sulphureted hydrogen to a fifth, and lime-water to a sixth ; a drop of sirup of violets to a seventh, and the two wires of a galvanic battery to the opposite edges of the whole. Thus with one drop of solu- tion many exact experiments may be made. (Ure.) General Remarks. Detection of arsenic in organic mixtures, <$-c. Most of the previous tests are only applicable, with any degree of certainty, to pure solutions of arsenious acid, or to those that are but slightly colored or contaminated with or- ganic matter. The tests depending on the extrica- tion of arseniureted hydrogen are partial ex- ceptions to this rule ; but even in them, if the sus- pected liquid be not nearly limpid, so much frothing will ensue as to render the process impracticable. In this respect Rensch's test, perhaps, possesses the advantage over the rest, as it may at once be ap- flui to mixtures containing organic matter, with- out the latter undergoing any previous preparation. The reduction test is only applicable to solid ar- senious acid, or to some of the compounds of arsenic which are obtained by means of the other tests. It has long been an object with chemists to remove organic matter from solutions, so as to render them sufficiently clear, light colored, and limpid, to permit of the action of reagents. Va- rious means have been proposed for this purpose, some of which I shall notice below. Suppose a case of poisoning, the proceeding should be as fol- lows :—The stomach being laid open, an examina- tion should be made for any particles of powdei which it may contain in an undissolved state ; if any can be found they must be collected and tried by the reduction test as before described. Should no solid particles be discovered, the stomach should be cut into small pieces, and with its previous con- tents be boiled in a glass vessel with distilled water for half an hour, a little potassa or ammonia being added. The liquid may now be filtered, first through muslin and then through paper, and again boiled with a little acetic acid, after which it must be filtered a second time. In this state the liquid is usually clear enough to be tested with the am- monio-nitrate of silver, when, if this test act freely, the process of testing with, other reagents may be proceeded with ; but if, on the contrary, the indica- tion be feeble, the liquor should be gently evapora- ted to dryness, and redissolved by boiling in repeated portions of distilled water, when, after being once more filtered, it will generally be sufficiently limpid for the perfect application of the tests. (Christison, Devergie.) It has been recommended to add to the organic matter contained in a porcelain capsule, one-sixth of its weight of strong, pure sulphuric acid, and to heat the mixture until vapors of the acid begin to appear, constantly stirring with a glass rod during the whole time ; the heat is to be continued until the charcoal thus formed becomes friable, and almost dry, when it must be cooled a little, and strong nitric or nitro-muriatic acid added by means of a pipette ; the evaporation must then be contin- ued to dryness. The residuum boiled with distilled water, and the solution filtered, will be ready for testing. (Danger and Flandin.) Another plan is to boil the suspected fluid con- taining organic matter, with pure diluted sul- phuric acid, until it becomes limpid, and then to filter, when the usual tests may be applied. (Fownes.) When there is much gelatine in the liquid it may be got rid of by adding an infusion of nut-galls, which will precipitate it. (Fownes.) The last plan I shall mention is that of evapo- rating the suspected liquid to dryness, and then submitting it to the reduction test. The following tables, taken from the " London Dispensatory," showing the reaction of several re- agents on various organic solutions containing poison, will, in many cases, save the trouble of preparing the fluid previously to testing; or at least they offer a ready means of confirming the truth of any more exact method of analysis. ARS 80 ARS Comparative Table of the Precipitates obtained from Solutions of Arsenious Acid, of Bichloridt of Mercury, of Potassio-Tartrate of Antimony, and of Chloride of Barium, with different Tests.— By Dr. A. T. Thomson. TEST I.--WATER SATURATED WITH SULPHURETED HYDROGEN OAS. Solvents. Water .. Precipitates from Solutions of Arsenious Acid. Bright lemon yellow, deepened by the addi- tion of a few drops of strong acetic acid.* Broth .... Scarcely any at first, but on adding a few drops of strong acetic acid, a pale yellow. Milk..... Little change; but on the addition of a drop of strong acetic acid, a straw-colored precipi- tate. Tea...... At first very pale yellow; alter some time, a pale greenish yellow. The precipitate was curdy.t Madeira Turbid, pale yellow, the Wine color of the wine de- stroyed. Port Wine Turbid, pale yellow; j the precipitate slowly formed. Coffee Gruel . A deep golden yellow. Pale yellow, suspended. Precipitates from Solutions of Corrosive Sublimate. Precipitates from Solutions of Tartar Emetic. Yellow at the instant of its formation, but soon becoming blackish.— On shaking the tube it changes to a dirty white. Whitish yellow at first, quickly changing to mixed clots of yellow, black and white. Light ochre, requiring for its formation a large quantity of the test. Brownish whit* and yel- low, mixed. Muddy, gradually display- ing small floating black flocculi. Nearly as in the white wine, like clouds through the purple of the wine. Brownish black. Light brown, slowly formed. Orange, curdy, partly sus- pended, partly thrown down. Ultimately bright orange.J Pale orange at first, soon changing to a deeper bright orange. Golden yellow, with a shade of orange. Deep orange, curdy, slow- ly formed: the super- natant fluid yellow. Pale orange, long sus- pended. Dark, dirty, orange brown. Deep orange-brown. Pale orange. Precipitates from Solutions of Chloride of Barium. Heavy, and of a dirty dark brown color. Dirty pale brown, heavy. Dirty nankeen, witn a shade of brown. Dirty light brown, deep- ening as it fell. The chloride mixed with white wine is milky Not tested. Pale brown, heavy. Not tested. Not tested. II.— -SOLUTION OF SULPHURET OF POTASSIUM. Water--- White, with a faint tint of sulphur-yellow, when a large quantity of the test was used.§ Black, mottled with yel-low. Bright orange. Deep olive-green. Broth Pale, but bright, sulphur- Clotted, heavy, black, Dull orange, heavy. Pale brown, partly sus- yellow. mottled with gray. pended. Milk..... Bright golden-yellow. Black, clotted. Orange. Brown, greenish when the mixture was «ha A beautiful yellow. Brownish-black. Reddish orange, floccu-lent. Deep brownish-orange. Not tried. Coffee ... A deep golden-yellow.|| Nearly black. Not tried. Madeira Sulphur-yellow. Dirty white, or slate col- Beautiful bright orange. Vide 1st Table. Wine or. Port Wine Fawn color. Slate color, with violet, Dark brown, with a tinge Violet, heavy. supernatant fluid.IT of orange. Gruel--- Bright queen's yellow. Black dense clots.** Orange clotted. Dusky yellowish-green. * This precipitate, dried upon a filter, and heated with some caustic potassa in a slender test tube, is decomposed in a few seconds, forming a sulphuret of potassium, while the arsenic is volatilized in its metallic form, and adheres to the sides of the tube. (Orfila.) -ff f All substances containing tannic acid in solution greatly impair the solvent influence of fluids on arsenious acid. t Dr. Pereira states, that, when the solution of the tartar emetic is very dilute, and the sulphureted hydro- gen eas passed through it only for a few seconds, the precipitate is of a lemon yellow, closely resembling that produced by arsenious acid. (Med. Gaz., April, 1836.) § This sulphuret, added to a solution of the phosphates, throws down a greenish-yellow precipitate, the superna tant fluid being yellow and turbid. J| Lime water, also, added to coffee containing arsenious acid, throws down a yellow precipitate; although it pre- cipitates the watery solution of arsenious acid white. (Orfila.) IT Corrosive sublimate cannot be exhibited in port wine with an intention to commit murder, (except by a self- murderer,) as it changes the color of the wine to pal* violet ** All the precipitates by the sulphuret, when dried, and heated in a tube with iron filings, afford metallic mercury, which forms globules on the sides of the tube. ARS 81 ARS III.--SOLUTION OF AMMONIACO-SULPHATE OF COPPER. Solvents Precipitates from Solutions of Arsenious Acid. Precipitates from Solutions of Corrosive Sublimate. Precipitates from Solutions of Tartar Emetic. Precipitates from Solutions of Chloride of Barium. Water. • •. Beautiful grass-green. It | completely disappeared on the addition of a few drops of strong | acetic acid.* Broth .... Beautiful pale green, sus- | pended.f Milk.....Pale grayish-green. White, thick, and heavy. White, curdy, partly sus- pended, partly thrown down. Bluish-white, curdy. Tea ..... Obscure olive, but scarce- Dirty yellowish white, ly a precipitate. j curdy. Coffee.... Dark grass-green.J I Dirty white. Madeira 'Grayish, with a slight Heavy clotted white, with Wine ! tinee of green. j a tint of green. Port Wine Clotted, heavy, dark Heavy, clotted, bluish- i greenish-gr ly. gray- Gruel .... Beautiful grass-green. Pale bluish-white. Pale whitish-blue, very little thrown down. Pale whitish-blue, with a tint of green. Whitish-blue. Muddy, pale bluish-green. Dirty bluish-green. ^Eruginous blue. Heavy, dirty slate-blue. Pale bluish-green. Copious whitish-blue. Opaque, glaucous. Curdy white, with a tinge of blue. Grayish, heavy, superna- tant fluid, "ycliowish- green. Not tried. Vide 1st Table. Dirty violaceous-gray. Pale bluish-green. IV.---SOLUTION OF AMMOMIACO-NITRATE OF SILVER. Water... Broth ... MUk..... Tea...... Coffee.... Madeira Wine Port Wine Copious bright sulphur- yellow.fS White, (owing to the chloride of sodium.) but yellow when treated with nitric acid. White, with a tint of yellow. Yellowish white, which soon blackens. Yellow, remaining un- changed. Pale sulphur-yellow. White, becoming brown on exposure to the light. Yellowish. Dull yellowish white, clotted, changing to dirty-white. White, copious. Dirty-white. Dirty-white. White, changing to black. Dirty-white, changing to black. Idem. Dense, dirty-white clots. Pale brown. Brownish, mixed with much muriate of sil- ver. Very pale, scarcely visi- ble brown. Dirty-brown. Not tried. White. Dirty-white. Not tried. White, heavy ; soon blackening. White, dense, curdy. Not tried. Not tried. Not tried. Vide 1st Table. Heavy, dirty-white. Dense, clotted-white. Caution. The result of no single test should be depended on. Those most to be relied on are the Reduction test, Rensch's test, and with proper precautions those depending on the liberation of arseniureted hydrogen; also among the liquid tests, the ammoniacal acetate and sulphate of cop- per and nitrate of silver. Otto has lately shown that when a poisonous mass of white of egg and potatoes is boiled with a lye of potassa and after- wards acidulated with muriatic acid, no precipitate is produced by sulphureted hydrogen. This re- sults from the action of potassa on proteine bodies * This test is capable of detecting arsenious acid in a solution containing y jf,\„0 of its weight. (Orfila.) t It has been suggested that onions, boiled in broth, or eaten so as to impregnate with their qualities the contents i of the stomach, might produce the same effects on ammo- I niaco-sulphate of copper, as if arsenious acid were pres- , ent; but although the fluid is tinged a green color, yet no precipitate forms. t Dr. Porter, of South Carolina, says, that sulphate of copper with ammonia produces the same colored precipi- tate in coffee which contains no arsenious acid. (Ameri- can Journal of Science, vol. iii. p. 354.) fj A similar precipitate is formed by nitrate of silver, in a solution of any of the phosphates, and with chromate of potassa; but the fact of the precipitate being occasioned 11 forming a sulphuret of potassium, the sulphur of which being liberated by the acid, throws down the arsenic, which is then removed by filtration. Hence it would appear a bad plan to boil such substances with potassa, as recommended by Christison and Devergie. ARSEXIC, ANTIDOTES TO. The hy- drated sesquioxide of iron, in the gelatinous state, appears to be the only substance yet discovered worthy of being considered as an antidote to arse- nic. It should be given in doses of a tablespoonful every ten minutes. Lime-water and chalk and by arsenious acid is easily ascertained by testing a fresh portion of the solution with lime-water. If it contain ar- senious acid, a copious white precipitate will be thrown down; if a phosphate only, there is scarcely any change, or at the must a translucent flocculent precipitate, which remains long suspended. A method of employing this test was suggested by Dr. Paris: namely, to pnt upon a piece of clean white paper a broad streak of the suspected fluid, and then ran lightly over it a stick of lunar caustic; or the streak may be brushed lightly over with liquid ammo- nia, immediately after the application of the caustic; if arsenious acid be present, a bright queen's yellow U in- stantly produced, which remains permanent for uearly an hour: but when the lunar caustic produces a bright yel- low before the ammonia is applied, we may suspect the presence of some phosphate. ASP 82 ASP water have also been recommended. Opium, camphor, and ether, may be employed as after remedies, to recruit the nervous system. Remarks. The first endeavor, in cases of poi- Boning by arsenic, should be to remove, if possible, the poison from the stomach; for this purpose strong emetics or the stomach-pump should be had recourse to, after which the hydrated sesquioxide of iron may be administered. ARSENITES. Salts formed of the previous acid (arsenious) and the bases. The alkaline ar- senites may be prepared by saturating a solution of the acid, with another of the base, and most of the insoluble arsenites may be made by adding a soluble salt of the metal to a solution of the ar- senite of potassa or ammonia. ARSENIURETED HYDROGEN. A com- pound of arsenic and hydrogen, discovered by Scheele. Prep. Melt metallic arsenic with an equal weight of grain zinc, reduce the alloy to coarse powder, place it in a gas bottle, and pour over it strong muriatic acid. (Soubeiran.) It must be collected in the pneumatic trough. Prop. Inflammable, extinguishes combustion, and destroys life. At a red heat it depositee its arsenic in the metallic state. ARTICHOKE. This esculent resembles aspar- agus in its general properties, but it is said to be more nutritious and diuretic. It is dressed in several ways according to the fancy of the cook. See Asafcetida, p. 83. ASAFCETIDA CLYSTER. Prep. Asafcet- ida i gramme; yelk of 1 egg; water } pint. Proc. Dissolve. Use. This quantity is sufficient for 10 or 12 clysters for children under 1 year; 5 or 6 for those under 3 years ; and 2 or 3 for those under 7. Two clysters are prescribed daily in hooping-cough. Remark. M. Reiken has found this more suc- cessful in removing hooping-cough than any other remedy. To ensure success, it should not be ad- ministered until the feverish symptoms have passed. M. Reiken sometimes uses an ointment of asafcetida, as well as the clyster. ASARABACCA SNUFF. Syn. Cephalic Snuff. Prep. Asarabacca leaves and Lundyfoot snuff, of each 1 oz.; lavender flowers, 1 drachm ; essence of bergamotte and oil of cloves, of each 2 drops. Proc. Grind the lavender with the snuff and leaves to a fine powder, then add the perfume. Remarks. This is a great improvement on the old form with herbs. It is an excellent errhine, and is much recommended in headaches, dimness of sight, &c. ASARINE. A substance resembling camphor, obtained from the root of the Asarum Europaeum, (Asarabacca,) by distillation along with water. ASBOLIXE. A substance found by^Bracon- not in soot, and on which he thinks the anthel- mintic virtue of the latter depends. Berzelius regards it as impure acid pyretine. ASCARIDES. Small thread worms that pro- duce a disagreeable irritation near the extremity of the anus. They are best removed by mild pur- gatives and the use of a clvster of aloes. ASCARIDES, ELECTUARY FOR. Ing Flowers of sulphur, 4 oz.; powdered jalap, 1 oz. powdered bark, 1 oz.; sirup of buckthorn, q. s Proc. Make them into an electuary. Dose. Tw« or three teaspoonfuls every morning. ASH-BALLS. The ashes of various plants, especially ferns, damped and made into balk Use. As ; substitute for soap in washing, and to clean paiiuing. ASPARAGIN. Syn. Asparamide. Altiieink Agedoile. A substance found in the potato, marshmallow, liquorice, asparagus, and some other vegetables. Prep. Boil the expressed juice of the asparagus, filter, and evaporate. II. Macerate the bruised root of the marsbmal- low with milk of lime ; filter, precipitate with car- bonate of ammonia, and evaporate. Prop. In its purest state it forms large prismatic crystals, soluble in water and proof spirit. Alkalis and acids, with the aid of heat, convert it into aspartic acid. ASPARAGUS. Qual., fyc. A very nutritious article of food, possessing slightly diuretic proper- ties, and little disposition *o induce flatulence Asparagus is cooked by boiling, which is done at quickly as possible, without breaking the heads, and is served with melted butter. The head, or upper part, is that which is eaten. Sometimes the lower or white end is removed before boiling. Many nice little side-dishes are made with asparagus; among which the following may be classed:—Cut off the top of a French roll and take away all the crumb, then fry it brown in butter, and fill it with a hot mixture of cream and yelk of egg, previously stirred together over the fire until thickened, and then beat up with the boiled tops of asparagus, and a little salt and nutmeg. Place on the top of the roll that was cut off, and over all stick in a few of the greenest heads of asparagus. This is called " asparagus forced." ASPARAGUS, CULTIVATION OF. Choose that situation which is the longest exposed to the sun during the heat of the day. Dig a pit 5 feet deep, and sift the mould through a scarce, having about 6 holes to the inch ; then fill up the bed with the following layers: 1,—6 inches of good dung; 2,—6 inches of turf; 3,—6 inches of dung ; 4,—6 inches of sifted earth. Repeat the layers in the same order a second time. Then fill up the last foot with a mixture of equal parts of sifted earth and dung. Now divide the ground into beds, 5 feet wide, by paths made of turf, laid down 18 inches wide and 9 inches deep. The plants must be set in March, 15 inches asunder placing the bud or top of the root about l£ inchet beneath the surface, and spreading the roots out as much as possible. Mark the place where each plant is set, by placing a small piece of stick in the spot. As soon as the bed begins to sink, a few spadefuls of fine sand may be thrown over it, especially on the spots where the plants are set Should some of the plants die, their places may be supplied by others, set later in the season. The plants should be 2 years old when transplanted, and in 3 years may be cut for the table. Remarks. A bed of this kind will last 30 years or longer. The young plants are raised from se-?d, set two together, about 1 inch deep and 9 inches apart, in beds of good earth, removing the weak- est of the two plants in the ensuing spring. A little good dung may be scattered over the beds in ASS 83 ASS autumn. The male plants alone should be se- lected for transplanting. During winter, aspara- gus may be raised by the use of tan in hotbeds. ASPHALTUM, PREPARED. Syn. Liquid Asphaltum. Prep. I. Melt Scio turpentine 2 oz.; then add powdered asphaltum 1 oz. When mixed, remove the vessel from the fire, cool a little, and add oil of turpentine until it be reduced to a proper consistence. II. (Wilson's.) Melt 1 oz. of asphaltum; then add 2 oz. of balsam of copaiba. Remove it from the fire, and thin with turpentine. Remarks. The turpentine must be heated be- fore adding it to the other ingredients, as if cold, they will set before it can be mixed in. Use. As a black japan, or varnish. An excellent glazing color. ASPHALTUM, FACTITIOUS. A substance under this name, and which is also often sold for genuine asphaltum, is made from the bottoms of Barbadoes tar, by heating them until quite hard. Color and hardness inferior to asphaltum. ASSAY, (ASSAYING.) Syn. Coupella- tion, (Fr.) Atreiben auf der Capelle, (Ger.) The method of determining the quantity of pure gold and silver in the alloys of these metals. This art requires great skill and experience in its per- formance ; and from the costliness of the precious metals, and their general employment in the man- ufacture of coin, plate, jewellery, &.C., is of the ut- most importance. At the Royal Mint of England there are two assay-masters—the master's assayer and the king's assayer. The business of the for- mer is to receive and examine the gold and silver ingots brought for coinage, and of the latter to ex- amine the melted bars previously to their being coined into money. When the money is coined, it is " pixed" before being sent from the Mint. This consists in making an assay of one piece out of each "journeyweight" of coin, to ascertain if it be of the proper standard. The king's assayer thus becomes responsible for the purity of all the gold and silver coin issued from the Mint. The following is a brief notice of the art of assaying. Sectional view of the assay furnace used at the Royal tint and Goldsmiths' Hall, London. a a. Rollers on which the furnace rests. b. Ash-pit. c. One of the ash-pit dampers. d, Grate supporting the muffle-plate. e, Muffle containing the cupels. /, The mouth-pl'ite for the ignited charcoal. k, Interiijr of furnace containing charcoal. I r, Walls of the furnace. k. Moveable chimney for regulating draught. Operation of Assaying. Materials, apparatus, $c-—The furnace. Before an assay can be made, it is necessary to be provided with a suitable fur- nace, muffle, and cupel. The furnace used for assaying at the Royal Mint and Goldsmiths' Hall, London, has the following proportions, and is represented above. Dimensions. Total height 2$ feet; from the bottom to the grate, 6 inches; the grate, muffle- plate, and bed of loam that covers it, 3 inches; the space between the grate and the bottom of the funnel or chimney, 2l| inches; funnel, 6 inches. A furnace of any other shape and size may be employed, provided it will afford a sufficient heat, and allow the introduction of the muffle. The muffle is a pot of the shape of fig. 1, made of clay, and furnished with an opening to admit the introduction of the cupels, and inspection of the process. It is placed on the muffle-plate, (see preceding figure,) by which it is introduced into the furnace. 1. The cupel is a sort of shallow crucible, made of bone ashes or burnt bones. At the Royal Mint the cupels are made of the calcined cores of ox- horns. The powder is slightly moistened with water, and a circular steel mould is filled there- with, and after being pressed down tight, is fin- ished off with a rammer, having a convex face of polished steel, which is struck forcibly with a mallet, until the mass becomes sufficiently hard and adherent. The cupel is then carefully re- moved, and exposed in the air to dry, which usually takes from 14 to 21 days. Fig. 2 repre- sents a cupel in section, and fig. 3 the tongs for charging the same. The best weight for cupels is said to be 180 to 200 grs. ^7 Process of assaying. The muffle, with the cu- pels properly arranged, being placed in the fur- nace, the latter is filled up with charcoal, and lighted at the top by placing a few pieces, heated to whiteness, on last. When the cupels have been exposed for half an. hour, and have become white by heat, the lead is put into them by means of the tongs, and as soon as this becomes tho- roughly red and circulating, as it is called, the metal to be assayed, wrapped in a small piece of paper, is added, and the fire kept up strongly un- til the metal enters the lead and circulates well, when the heat may be slightly diminished, and so regulated that the assay shall appear convex and ardent, while the cupel is less red—that the un- dulations shall circulate in all directions, and that the middle of the metal shall appear smooth, sur- rounded with a small circle of litharge, which is being continually absorbed by the cupel. This treatment must be continued until the metal be- ASS 84 ASS comes bright and shining, or is said to " lighten ,*" after which certain prismatic colors, or rainbow hues, suddenly flash across the globules, and un- dulate and cross each other, and the latter metal soon after appears very brilliant and clear, and at length becomes fixed and solid. This is called the " brightening," and shows that the separation ie ended. In conducting this process, all the ma- terials used must be accurately weighed, especial- ly the weight of the alloy before cupellation, and the resulting button of pure metal. The difference gives the quantity of alloy. The preceding gen- eral description of the process of cupellation will render the following articles intelligible, without again entering into the minutiae of the operation. Assayers' weights. The richness or purity of gold is expressed in carats. Pure gold is spoken of as containing 2-1 carats, of 12 grains each; and any other sample, containing 12, 18, 22, or any other number of parts of pure gold, in 24 parts, is said to be of so many carats fine. In the process of assaying gold, the real quantity taken is very small, generally 6 or 12 grains ; and this is termed the " assay pound." It is nominally subdivided into 24 carats, and each carat into 4 assay grains, and each grain into quarters, so that there are 3*4 separate reports for gold. When the assay pound is only 6 grs., the quarter of the assay grain will only weigh the T!'l of a grain; hence the most accurate system of weighing must be adopted. The richness or purity of silver is either ex- pressed in pennyweights or lOOOths. In the first case, it is supposed that the mass of silver to be examined consists of 12 equal parts, called penny- weights ; so that if an ingot weighs an ounce, each of the parts will be l-12th of an ounce. Hence, if the mass of silver be pure, it is called silver of 12 pennyweights ; if it contain l-12th of its weight of alloy, it is called silver of 11 pennyweights ; if 2-12ths of its weight be alloy, it is called silver of 10 pennyweights ; and so on in proportion for other qualities. It must be observed here, that the assayers give the name pennyweight to a weight equal to 24 real graint>, which must not be confounded with their ideal weights. The assay- ers' grains are called fine grains. An ingot of fine silver, or silver of 12 pennyweights, contains, then, 288 fine grains ; if this ingot contain l-288th of alloy, it is said to be silver of 11 pennyweights and 23 grains ; if it contain 4-288ths of alloy, it is said to be 11 pennyweights, 20 grains, &-c._ Now a certain real weight must be taken to represent the assay-weights : for instance, 36 real grains to represent 12 fine pennyweights; this, if subdivided into a sufficient number of other smaller weights, will also represent fractions of fine pennyweights and grains. Thus, 18 real grains represent 6 fine pennyweights; 3 real grains represent 1 fine pen- nyweight, or 24 grains; a real grain and a half represents 12 fine grains; l-32d of a real grain represents a quarter of a fine grain, which is only l-752d part of a mass of 12 pennyweights. The purity of silver is now more frequently expressed in lOOOths, which admits of greater accuracy. Remarks. An assay is thought to be good when the bead is of a round form, with its upper surface brilliant, its lower one granular and dead-white, and when it separates readily from the cupel. When the surface of the bead is duU and flat, it shows that too much heat has been employed ; and if the metal bo silver, some may have been lost in the process, by fuming or absorption. When the bead is spongy, and of various colors, and scales of litharge still remain on the cupel, and the metal adheres strongly to the latter, too little heat has been used, and the button still retains some lead. To remedy this, the heat should be raised, and a little powdered charcoal, or a few small pieces of paper, thrown into the cupel, until the metal again begins to circulate freely. It is ne- cessary that the lead employed in the process of cupellation should be perfectly pure. It ought, therefore, to be procured by reducing refined litharge. ASSAY OF SILVER. I. The assay pound (usually 12 or 20 grains for silver) of the alloy for examination is accurately weighed, and then wrapped in a small piece of paper ready to under- go the process of cupellation. The quantity of lead used is not uniform ; but depends on the na- ture of the alloy. It should be 16 times the weight of the copper presumed to be present in 'he sam- ple. This, however, cannot be accurately as- certained, though an experienced assayer is gen- erally able to guess very nearly the amount. If too much lead be used, the button obtained by cupellation will be too small, owing to some of the silver being absorbed by the cupel; and if too little be used, the button will come out too large, from still containing some copper. The importance of justly proportioning the lead to the quantity of copper present in the alloy, cannot be too much insisted on. The following table exhibits the proper quantities adapted to silver of various de- grees of fineness. Assay Table, by M. D'Arcet. Fineness of the Silver. Proportion of Copper in the Alloy. Dose of Lead required, the weight of sil- Relation be-tween the Lead and Cop ver being one. per. Silver at 1000 3 T0- 950 50 3 70 to 1 900 100 7 60tol 800 200 10 50tol 700 300 12 40tol 600 400 14 35 to 1 500 500 16 to 17 32tol 400 600 do. 26-6 to 1 300 700 do. 22-8 to 1 200 800 do. 20tol 100 900 do. 17*7 to 1 pure copper. 1000 do. 16 to 1 Remarks. As the lead always carries off a small portion of the silver into the cupel, the assay gen- erally comes out too low, which was ascertained by M. D'Arcet to be equal to— For fine silver,......^qqq 900 (( _4*3 iooo "......loot 800 tf 4*9 1000 '......1000 ASS „ 500 4-2 t or ---- "......---- 1000 1000 iooo '......Tooo During the process of cupellation with silver, the button is apt to " vegetate," especially if it be fine silver, and therefore requires to be carefully watched; for which purpose the cupel is usually kept at a convenient part of the muffle, ready to be drawn forward if required. It has just been Been that to apportion the lead correctly requires that the title of the silver should be known ; when this is not the case, it may be determined approxi- matively, by exposing in the cupel 0-1 part of the sample with 1 part of lead. French gold and sil- ver coin contain T'()- of copper; British silver coin consists of i| of silver, and -'j- of copper; and British gold coin of 11 parts of gold and 1 of cop- per, or a mixture of copper and silver. II. Humid assay of silver, a. Dissolve 10 grs. of the alloy in 100 grs. of nitric acid, sp. gr. 1-28, by the aid of heat; the solution being made in a tall stoppered glass tube, furnished with a foot; then place it in a very delicate balance, which must be brought into an exact state of equilibrium, and add the test solution gradually and cautiously until the whole of the silver be thrown down ; but the utmost care must be taken not to exceed this point. The number of grains now required to re- store the equilibrium of the scales gives the exact quantity of pure silver present in 1000 parts of the sample. Test liquor. Dissolve 54-27 (54$) grs. of pure sea salt in 9945-73 grs. (or 22 oz. and 320| grs. avoirdupois) of distilled wate.-; filter, and keep the liquor in a stoppered bottle for use. Pure sea salt. Boil together for a few minutes, in a glass vessel, a solution of salt with a little pure bicarbonate of soda ; filter ; add muriatic acid un- til the liquor be neutral to litmus and turmeric pa- per ; then evaporate and crystallize. Remarks. The addition of the test liquor to the solution requires the utmost exactness. After each addition the stopper should be placed in the tube, and the latter violently agitated for a short time, when the liquor will rapidly clear and enable us to see when the operation is concluded. We must then, as a check, add a small quantity of a solu- tion of nitrate of silver to the liquor in the tube, after having first carefully taken the weight. If too much of the test liquor has been added, this will produce a fresh precipitate, and the assay can- not then be depended on. Instead of weighing the quantity of test liquor used, a tube graduated into 100 parts, and holding 1000 grs., may be used instead, every division of which required to throw down the silver, will rep- resent the Jfjth of a grain. The tube being filled to the 0, is ready for use, and from being gradua- ted downward the quantity poured out may at once be read off Generally speaking, however, measuring does not admit of the same accuracy as weighing. The termination of the operation is clearly marked, when, on adding a minute quan- tity of the test liquor to the silver solution, no cloudiness occurs. (See Alkalimetry and Acid- imetry.) 85 ASS b. The precipitate thrown down in the last ex- periment may be collected in a filter of white paper, and dried, washed, and weighed. The previous weight of the paper, deducted from the gross weight of the paper and silver, will give the quantity of chloride of silver present, which multi- plied by -7533, the weight of metal in one grain of the chloride, will give the exact weight of the pure silver contained in the sample. Remarks. Mercury is the only metal whose presence at all interferes with the process; the chloride of mercury being also thrown down by salt, as well as the chloride of silver. When no mercury is present in the precipitate, it rapidly becomes black on exposure to the light, but when it contains -j-^- or Tf)5o7T of chloride of mercury, it remains of a dead white, with -p^g-g- it is not sensi- bly discolored by the diffused light of a room, with To (W 01lly slight'y darkened, with r^ more so, but with pure chloride of silver, the effect is very rapid and intense. When mercury is present, which is however seldom the case, the assay sam- ple must be placed in a small crucible, and ex- posed to a full red heat, before solution in the acid. For the method of assaying silver by the humid way, when alloyed with gold, see Gold. Those who wish to enter fully into the subject of the humid assay of silver, are referred to Gay Lus- sac's Essay. ASSAY OF GOLD. 1. This process may be divided into five operations. I. Cupellation. Either 6 or 12 grs. of the alloy is the weight usually taken for the assay, to which is added 16 parts of lead for every 1 part of cop- per that it is presumed to contain, though consid- erably more lead may be used when the sample does not contain any silver ; but if the reverse be the case, an excess of lead would lead to the loss of the latter metal, which ought not to be separa- ted until the operation of parting. When silver is present an additional allowance of lead, equal to -Jjc of its weight, is made on that account. When, however, the quantity of silver is small, or is not required to be estimated, it becomes of little con- sequence what weight of lead is employed, so long as enough be used to carry off the base metals, at the same time that the quantity is not too large for the cupel. The sample is then submitted to cu- pellation. This process does not require so much care for gold as silver, as none of this metal is ab- sorbed by the cupel, or lost by evaporation, and it will safely bear the highest heat of the furnace without injury. In other respects the operation may be conducted in exactly the same manner as for silver. II. Quartation. After gold has passed the cu- pel, it may still retain either of the other perfect metals, particularly silver. To remove the latter it undergoes the operations of quartation and part- ing. Quartation is performed by adding 3 parts of silver to one of the cupelled sample, and fusing them 'together, by which the gold is reduced to one fourth of the mass or even less; hence the name. In this state nitric acid will dissolve out the silver, which brings us to the next operation. In many cases the operation of quartation is performed conjointly with that of cupellation, as in the processes of Nos. 2 and 3. ASS 86 ASS III. Parting. The alloy of gold and silver thus formed, is next hammered or rolled out, into a thin strip or leaf, curled up into a spiral form, and submitted to the action of nitric acid, sp. g. 1-3, diluted with half its weight of water; this being poured off, another quantity of acid, of about 1-26, and undiluted, may be employed. In each case the acid should be boiled upon the alloy for about a quarter of an hour. In the first case the quantity of fluid should be about 21foz., and in the second l$oz. The second part of the ope- ration of parting is called the " reprise." If the acid be used too strong it leaves the gold in a state of powder, otherwise the metal preserves its form throughout the process of parting. It is next carefully collected, washed, and dried. IV. Annealing. The sample of pure gold has now only to be annealed, which is done by put- ting it into a small porous crucible, and heating it to redness in the muffle. V. Weighing. The pure gold is next accurate- ly weighed. This weight doubled or quadrupled, gives the number of carats fine of the alloy ex- amined, without calculation. Re?narks. The loss of weight by cupellation gives the amount of copper in the sample; that after parting, the amount of silver, deducting of course the weight of silver used in the process, which is called the " witness." When the sample contains but very little gold, the dry method of assaying cannot be depended on, and chemical analysis must be had recourse to. 2. (M. Chaudet's process.) Submit to cupel- lation 0-500 of the sample with 1-500 of pure sil- ver, and 1*000 of pure lead. Form the button into a strip or riband 3 inches long, and roll it into a cornet. Boil for 3 or 4 minutes in a matrass with nitric acid of 22° Baume, decant and again boil for 10 minutes with acid of 32° Baume, again decant and repeat the last boiling with a fresh lot of acid, at 32 B. for 10 minutes longer. Next wash the cornet with pure water, put it into a small crucible permeable to water, and submit it to a dull red heat in the muffle. Lastly, cool, take it from the crucible, and weigh it. Remarks. The above is M. Chaudet's method of assaying fine gold. It affords very perfect results. 3. (Old French government method.) Oper. " Twelve grains of the gold intended to be as- sayed must be mixed with 30 grs. of fine silver, and cupelled with 108 grs. of lead. The cupella- tion must be carefully attended to, and all the im- perfect buttons rejected. When the cupellation is ended, the button must be reduced by lamination into a plate of 1£ inch, or rather more, in length, and 4 or 5 lines in breadth. This must be rolled up upon a quill, and placed in a matrass capable of holding about 3 oz. of liquid, when filled up to its narrow part. Two oz. and a half of very pure aquafortis, of the strength of 20° of Baume's are- ometer, must then be poured upon it; and the matrass being placed upon hot ashes, or sand, the acid must be kept gently boiling for a quarter of an hour: the acid must then be cautiously de- canted, and an additional quantity of ljoz. must be poured on the metal, and slightly boiled for 12 minutes. This being likewise carefully decanted, the small spiral piece of metal must be washed with filtered river water, or distilled water, by fill- I ing the matrass with this fluid. The vessel is then to be reversed, by applving the extremity of its neck against the bottom of a crucible of fine earth, the internal surface of which is very smooth. I The annealing must then be made, after having separated the portion of water which had fallen into the crucible: and, lastly, the annealed gold must be weighed. For the certainty of this ope- ration, two assays must be made in the same manner, together with a third assay upon gold of 24 carats, or upon gold the fineness of which is perfectly and generally known." " No conclusion must be drawn from this assay, unless the latter gold should prove to be of the fineness of 24 carats exactly, or of its known de- gree of fineness ; for, if there be either loss or surplus, it may be inferred that the other two as- says, having undergone the same operation, must be subject to the same error." 4. (When the alloy contains platina.) This alloy generally contains copper, silver, platina, and gold. The sample must be cupelled in the usual way, and the loss of weight will express the amount of copper ; the button, made into a rib- and and treated with sulphuric acid, will indicate, by the portion dissolved, the amount of silver present. By submitting the residuum to quarta- tion, the platina will become soluble in nitric acid. The loss after digestion in this menstruum will express the weight of that metal, and the weight of the portion now remaining will be that of tha pure gold. 5. Other methods. Assay of the touch. Jew- ellery, small quantities, :irometer. 6. Bernouilli's syphon ditto. 7. Aminton's conical ditto. 8. Gay Lussac's ditto. 9. Ditto, modified by M. Bunten The wheel barometer (fig. 5) is the one most commonly used, especially as a weather-glass, but it is not to be depended on, as it neither indicates the absolute height of the mercurial column, nor its variations with sufficient accuracy for any phi- losophical purpose. Even as a weather-glass it is the worst of all the common forms of the barome- ter. For travelling the las, is perhaps the most unexceptionable. The Construction of a Barometer may be divided into five operations, in each of which the utmost skill and care are required. The materials must be of the best quality. Not only must the mercury be perfectly pure and free from air, but the tube must be quite dry and clean, and its inner surface must be smooth and regular. 1. The tubes for barometers should be hermeti- cally sealed immediately after their manufacture at the glasshouse, and kept in this state until they are wanted for filling. By this plan they may be kept clean for any length of time, whereas if they are left with one end open they become sullied with dust and smoke, which, on account of the Bmallness of their diameters, can never be perfectly removed. When wanted for use they may be opened with a file, after which care must be taken not to breathe into them, and washing them out with spirit of wine, &c, especially avoided. When cleaning is absolutely necessary, it should be done by means of a clean, dry linen rag, and a piece of wire, observing not to let the end of the wire scratch the glass, as, if it does, such tubes will generally be found broken, if laid aside for a short time, or, what is worse, they will break during the process of filling them. The best tubes are perfectly cylin- a, Tube containing a column of mercury. b, Mercurial cistern. c, A column of mercury supporting another of water, A. e e, Weights, one of which floats on the surface of the mercury, and by means of the cord / moves the index ff. h, Graduated dial. k, Capillary hole drilled laterally to admit air. drical, 33 inches in length, and the diameter of their bore never less than 2 to 2£ lines, as the ca- pillary attraction and friction increases in an inverse ratio to the capacity of the tube. The thickness of the glass should not greatly exceed half a line. 2. The mercury must be perfectly pure, which should be ascertained before using it, as, if it be adulterated with common metals, as is frequently the case, its fluidity is lessened, and its tendency to oxidize increased. When it cannot be got tin- adulterated it should be rectified in an iron retort; or pure cinnabar, mixed with half its weight of iron filings, may be treated in the same way, when pure mercury will distil over. (See Mercury.) 3. Filling the tube is performed by pouring the mercury into it, having previously boiled it in a porcelain or iron vessel, to expel the air. The tube is then exposed to a gradually increasing heat over a chafing-dish of charcoal until the mercury boils, and all the air in the tube is extricated; it is now allowed to cool and again filled up with mer- cury, and the exposure over the chafing-dish re- peated ; when again perfectly cool it may be filled up with a little freshly-boiled mercury, and is then ready for fixing in its frame. 4. The tube filled as above must next be placed in its frame, for which purpose the open end is perfectly stopped, and it is inverted into a small trough of prepared mercury; or if it be of the syphon kind, simply inverted and fixed in its frame. 5. The graduated scale has now to be adjusted to the tube. This is usually done by means of » tangent screw, which permits the scale to be raised or lowered, until its zero exactly corresponds to the lower surface of the mercury ; but in many easel BAR 99 BAR the cistern is raised or lowered by means of screws arranged for that purpose. The best mode of ob- taining an exact adjustment of the surface of the mercury to the zero of the tube, is that adopted by the celebrated French artist, Fortin. An ivory needle is attached to the scale pointing downwards, its point being exactly on a level with the zero of the scale. The image of the needle is clearly reflected from the surface of the mercury in the cistern, and either the scale or cistern is raised or lowered, until the point of the needle and its image exactly coincide. Use. This instrument is employed for ascertain- ing the amount of atmospherical refraction in astro- nomical calculations, in measuring altitudes and in prognosticating the weather. For the latter pur- pose, on land, it frequently proves a false prophet, but at sea, (according to Dr. Arnot,) the case is widely different, and its monitions are worthy of attention. (Elem. Nat. Phil. i. 353.) Remarks. The above is a brief outline of the method of constructing barometers, and in propor- tion to the skill therein exercised will be the accu- racy of the instrument. However cleverly this may have been performed, it is nevertheless found that these instruments gradually suffer deterioration from the external air insinuating itself between the mercury and the glass tube, thus lessening the per- fection of the vacuum. Various plans have been proposed to remedy this inconvenience and source of error. Professor Daniels lines the bottom of the tube with platinum to the extent of about J of an inch; this has proved quite sufficient. Dr. Ure uses platinum foil for the same purpose. It is usual, as I have above described, to boil the metal after its introduction into the glass tube, but some persons disapprove of this practice in consequence of the mercury absorbing a little oxygen during the process, and instead thereof, they strongly heat the glass tube and pour in the mercury very hot. BAROMETER, PORTABLE, (Simple.) This instrument consists in general of a tube of the usual length, passing through the upper parts of a wooden cistern, to which it is glued, and the bottom of which is made of leather. The tube being filled with mercury, which has been previously well purged of air, and placed in a proper position, the superfluous mercury descends into the cistern, and assumes a level in the tube corresponding with the weight of the external air. The surface of the mercury in the cistern is adjusted to the same level by a screw, which presses more or less against the flexible leather at the bottom, and raises or de- presses it at pleasure. From the line of this level, which is called zero, the scale commences, and is reckoned upwards to the height of about 32 inches; the actual divisions of the scale begin at about 15 inches. Remarks. The most accurate portable barome- ters are those of Gay Lussac and Bunten, (Figures 8, 9.) When set on universal joints and well balanced, they are the most perfect instruments for ships that have been yet constructed. BAROMETER, TROUGHTON'S MARINE. The tube of this instrument consists of two parts, joined together about 5 inches below the top; the bore in the upper part being about T4ir of an inch, and in the lower part only T(-J-ff. By this construc- tion, partly from the difference of the bores, and partly from the greater friction in the lower end, the motion of the mercury is so much retarded, that any impulse given by the ship, having a ten- dency to raise it, will scarcely have produced a sensible effect, before an opposite impulse will be given, having a tendency to depress it. To coun- teract more effectually the effects of the ship's mo- tions, the instrume*-* is suspended in gimbals. BAROMETER, THE VIAL. Prep. Take a common vial and cut off the rim and part of the neck, by means of a piece of cord passed round it, and moved rapidly to and fro, in a sawing direc- tion ; the one end being held in the left hand and the other fastened to any convenient object, while the right hand holds and moves the vial; when heated, dip it suddenly into cold water, and the part will crack off; or separate it with a file. Then nearly fill the vial with clean water, place your finger :n the mouth and invert it; withdraw your finger dnd suspend it in this position with a piece of twine. In dry weather the under surface of the water will be level with the neck of the bottle, or even concave; in damp weather, on the contrary, a drop will appear at the mouth and continue until it falls, and is then followed by another in the same way. Barometrical corrections. Cistern barometers formed of tubes of very small diameters, require what is called "correction for capillarity." The following Table is taken from the " Ency- clopaedia Britannica." . of Tube. Depression. Inches. Inches 0-10 0-1403 0-15 0-0863 0-20 0-0581 0-25 0-0407 0-30 0-0292 0-35 0-0211 0*40 0-0153 0-45 0-0112 0-50 0-0083 0-60 0-0044 0-70 0-0023 0-80 0*0012 Remarks. It will be seen, that as the tube in- creases in diameter, so the depression of the mer- cury lessens. Syphon barometers that have each of their legs of equal size, require no correction, as the depression is equal at both ends. A correction is also made for temperature in nice observations, but this is of too scientific a nature to be entered into in the present work. BAROMETRICAL RULES FOR PROG- NOSTICATING THE WEATHER. 1. After a continuance of dry weather, if the barometer begins to fall slowly and steadily, rain will certainly ensue; but if the fine weather has been of long duration, the mercury may fall for 2 or 3 days, before any perceptible change takes place, and the longer time that elapses before rain comes, the longer the wet weather is likely to last 2. Conversely, if, after a great deal of wet weather, with the barometer below its mean BAS 100 BAT height, the mercury begins to rise steadily and slowly, fine weather will come, though 2 or 3 wot days miy first elapse ; and the fine weather will be the more permanent, in proportion to the length of time that passes before the perceptible change takes place. 3 On either of the two foregoing suppositions, if the change immediately ensues on the motion of the mercury, the change will not be permanent. 4. If the barometer rises slowly and steadily for two days together, or more, fine weather will come, though for those two days it may rain incessantly, and the reverse; but if the barometer rises for two days or more during rain, and then, on the ap- pearance of fine weather, begins to fall again, the fine weather will be very transient, and vice versa. 5. A sudden fall of the barometer in spring or autumn indicates wind; in summer, during very hot weather, a thunder-storm may be expected; in winter a sudden fall after frost of some conti- nuance, indicates a change of wind with thaw and rain ; but in a continued frost a rise of the mercury indicates approaching snow. 6. No rapid fluctuations of the barometer are to be interpreted as indicating either dry or wet weather of any continuance ; it is only the slow, steady, and continued rise or fall, that is to be at- tended to in this respect. 7. A rise of the mercury late in the autumn, after a long continuance of wet and windy wea- ther, generally indicates a change of wind to the northern quarters, and the approach of frost. BARYTA. Syn. Piiotoxide of Barium. Oxide of ditto. (See Barium.) BARYTA, SALTS OF. Prep. All the soluble salts of baryta may be made by solution of its carbonate or hydrate in the dilute acids, and the insoluble salts, generally, by the double de- composition of its muriate, by a soluble salt of the acid. BARYTA, TESTS FOR, AND ITS SALTS. I. This earth forms an alkaline solution with water. II. Baryta in solution, and all its salts, give a white precipitate in alkaline carbonates and sulphates, and sulphuric acid ; the last two being insoluble in both acid and alkaline menstrua. BARYTA, ALLOXANATE OF. Prep. Add barytic water to an aqueous solution of alloxan, neated to 140" until the precipitate formed, ceases to be redissoived on stirring ; then cool and collect the crystals, and repeat the process of add- ing barytic water to the mother liquor, which will thus furnish several crops of crystals. Use. To form some salts. BARYTIN. A new vegetable base discovered by Simon, in the rhizomes of white hellebore. It is precipitated from its solutions by sulphuric acid and the sulphates, like baryta, hence the name; and this property affords a means for its separa- tion. BASE, (in Chemistry.) A term applied to metallic oxides, (from their forming salts with acids,) and to the principal constituent of a com- pound. Thus: soda is called the base of sulphate of soda, (giauber salts;) quinine the base of disul- phate of quinine, Cyc. Forms will be found in this book for the preparation of the principal bases, as well as their salts. BASILICON, BLACK. Pre p. Yellow wax 1 lb.; black rosin and olive oil, ot each 2 lbs. Proc Melt together and strain through a piece of canvass. Remarks. This old preparation is similar to the resin cerate of the London Pharm., with the ex- ception of containing black instead of yellow rosin. Linseed oil, used instead of olive oil, comes cheaper, and is preferred by many persons. BASSORIN. S>m. Insoluble Gum. The in- soluble portion of gum tiagacanth, &c, after the soluble part has been removed with water. Prep. It is best prepared by soaking gum bassora in a large quantity of hot water, and filtering off the clear portion. BATE MAN'S PECTORAL DROPS. Prep. Paregoric 10 oz.; tincture of castor 4 oz.; lauda- num 1 oz.; tincture of saffron or cochineal £ oz.; oil of aniseed 15 drops. Mix. Dose. A teaspoon- ful or more in coughs and colds. BATE.MANS ITCH OINTMENT. Prep. Carbonate of potassa 1 oz.; red sulphuret of mer- cury i oz.; hog's lard and flowers of sulphur, of each 22 oz.; bergamotte 60 drops; rose-water 2 oz. Proc. Mix the potassa and powders w 'h a little of the lard, and rub them well together, then add the remainder of the lard, previously softened by heat, and afterwards the rose-water gently warmed : stir until cold. BATHS, BATHING. General Remarks. The practice of bathing is not only an act of cleanliness, but is eminently conducive to health. The delicate pores of the skin soon become choked by the solid matter of the perspiration and the ac- cumulation of dirt, and require frequent ablution with water, to preserve their natural functions in a state of activity. The mere wearing of flannel and washing the more exposed parts of the body, and the daily use of clean linen, is but an imper- fect attempt at cleanliness, without being accom- panied by entire submersion of the body in water. The phlegmatic Englishman, unlike his lively French neighbor, seems perfectly incredulous on this point, and would sooner spend his sixpence or his shilling in a glass of grog, or a ride to Green- wich, than in the healthy recreation of the bath. Bathing is not only conducive to cleanliness, but to both the physical and mental health. The body cannot be in a state of lively health, while the proper offices of the skin are interfered with, any more than would be the case with either of the other excretory organs, placed in a like condi tion. Nor can the mind, dependent as it is on the organization of the body, escape unharmed, when the animal functions are imperfectly performed. Intellectual and moral vigor are universally promo- ted by the imperceptible yet controlling influence of the physical system, and he who would increase the former, cannot go on a safer method than that which tends to preserve or improve the health. " On the continent, ' Maisons des Bains' or bathing-houses, are almost as numerous as the chemists and druggists are in this country. The inference necessarily is, that bathing in France is as much patronized as physic is in England. The French need the latter less, because they live more temperately, are less ground down to think and work ; and because they perform general per- sonal ablution (to the benefit of one of the mos1 important functions of life, namely, free perspira- [ tion) with as much zeal as though it were a re- BAT 101 BAT ligious duty. The inducement to such frequent use of the warm bath among our neighbors, may be fancied to be the low charges for bathing, and the little value the Messieurs attach to their own time. The first notion is a fallacy. Warm bath- ing on the continent is not cheaper in comparison with all the other necessaries or luxuries of life, viewed in connection with a fore-Tier's resources, than it is in England. With regard to the ap- parently little importance they attach to their own time, they are wise enough to discover, that life is not one jot sweeter by passing sixteen hours a day behind the desk or counter, to the exclusion of all recreation, except recreation be to count the gains of such exilement; or to indulge the hope of amassing a sufficiency to do the ' important' at the close of a wearied life, when and which the infirmities of age forbid to enjoy. A Frenchman lice?, works, and enjoys himself to the last. Prince Talleyrand died in armor; his life was a bouquet in which all but the sweetest flowers were excluded. A Frenchman takes the bath for the mental and bodily gratification it affords; he can appreciate the luxury of it, while at the same time he is sensible of its healthfulness. An Englishman is such a stiffuecked fellow, that in most things, he will only do that which pleases him best, and his standard of pleasure is estimated by that which adds most to his hoard, and which gives the great- est amount of satisfaction to the inward man. Advise him to take a warm bath; the answer is, he cannot spare the time, and he hates the bother of uncravating, &c. The waste of the»one and the trouble of the other add not to his income, whatever they may to his health. The roast beef, the brandied wines, and the London-brewed are his stomach's deities, the minor godships being blue pills and black draughts. The latter are indispens- able attendants upon the former, to temper down Mr. Bull, lest he become a giant in noses and car- buncles. A Frenchman knows no ill but what pleasure denies; he rarely has dyspepsia, gout, rheumatism, or fevers. Half his life is spent in Elysium,—half ours in Purgatory. Indigestion, headaches, restless nights—the blues when awake, and the terribles when asleep—fall to the lot of the mind-absorbed and grossly-fed Londoner, while our lively Parisian, with his light meal and still more lightsome body, finds trouble only in broken limbs, or positive starvation." The warm bath, especially, is one of the most valuable, but most neglected remedies which we possess. It is generally imagined by Englishmen, that bathing is but little fitted for their country, owing to the changefulness of the climate, and that to attempt to place a sick man in a bath in any other than the mildest weather, would be to subject him to all the horrors of " sniffling, sneez- ing, coughing, and relapse." But that such re- sults of bathing have no existence beyond the minds of the fearful, ignorant, and prejudiced, must be acknowledged by every candid person. Even the cold bath, as in the treatment termed "hydropathy," is beneficial when applied with judgment; and it is only when common discretion is not exercised, that bathing under any shape ever proves injurious. Some persons are very susceptible of taking eold, and are themselves "living barometers;" but even to them warm bathing would prove ad- vantageous. One half of the rheumatic twinges, swollen limbs, and cramped joints that occur in such persons, would give way before proper per- severance and confidence in this remedy. Whenever in delicate persons the cold bath is deemed proper, the warm, tepid, and cool bath may be used as a preparative, and when the for- mer is at length adopted, it should be at first only for one or two minutes at a time, gradually in- creased to a quarter of an hour or twenty minutes * care being taken never to remain immersed suf- ficiently long to induce a sensation of cold on com- ing out. A healthy reaction should follow the bath, and a pleasing glow of warmth should diffuse itself over the surface of the body. If this be not the case, the bath has either been indulged in too long, or been injudiciously taken. When any symptoms appear that contra-indicate the use of the cold bath, the tepid, warm, or vapor bath may be substituted, according to circumstance's. In conclusion, I may remark, that bathing, es- pecially in water at a temperature nearly similar to that of our bodies, (tepid bath,) is at once ne of the most cleanly and health-preserving luxuries, or, I should say, necessaries of life. The following short notice of each description of bath, is all the space that can be spared for this subject. I. Affusion of cold water over the surface of the body, has been adopted with success, for ar- resting the progress of some fevers. In scarlatina, &c., sponging the body with tepid water, or water mixed with vinegar, has been employed instead. II. Air bath. a. (Cold.) The mere exposure of the body in a state of nudity to the atmosphere, forms the common air bath. It has been found useful in allaying slight degrees of febrile excite- ment, and to act as a mild tonic, when not too long continued. 6. (Hot.) This consists in placing the patient in an apartment to which heated air is admitted. It is generally considered to be more stimulant than the vapor bath ; it produces a powerful per- spiration, and has been recommended in cholera, congestive fevers, rheumatism, scaly skin-dis- eases, &.C III. Chlorine bath. Water holding in solution a small quantity of chlorine gas. Its action has not been much examined. I may mention here, that I have seen several cases of itch cured by two or three immersions in a warm bath, to which a lit- tle chloride of lime has been added. IV. Cold bath. The temperature of this bath varies from 45° to 85°. It is considered tonic and stimulant, when not too long continued. To pro- duce its full effects, the patient should feel a plea- sant glow upon the surface of the body, imme- diately on coming out of the water. If a sensation of coldness or shivering follows, it should not be repeated. The duration of the immersion may vary from two minutes to a quarter of an hour, depending upon the temperature of the water, and the feelings of the bather; the latter period not being too long, provided swimming or violent ex- ercise be adopted in the bath. The temperature of the water of the rivers, and on the coast of England, varies in summer from 55° to 70°. The following hints on cold bathing may be in- teresting to the reader BAT 102 BAT 1. " In using the cold bath, it is of essential importance to know that there is no truth in the vulgar opinion, that it is safer to enter the water when the body is cool, and that persons heated by exercise, and beginning to perspire, should wait till they are perfectly cooled. " It is a rule liable to no exception, that mode- rate exercise ought always to precede cold bath- ing ; for neither previous rest, nor exercise to a violent degree, is proper on this occasion. 2. " The duration of cold bathing ought to be short, and must be determined by the bodily con- stitution and sensation of the individual; for healthy persons may continue in it much longer than valetudinarians. In summer it may be en- joyed for an hour, when in spring or autumn, one or two minutes will be sufficient. Under similar circumstances, cold water acts on aged and lean persons with more violence than on the young and corpulent; hence the former, even in the hottest days of summer, can seldom with safety remain in the bath longer than a quarter of an hour; while the latter are generally able to sustain its impres- sions for a much longer period. 3. " The head should first come in contact with the water, either by immersion, by being showered upon, or by covering it for a minute with a wet cloth, and then plunging head foremost into the water. 4. " As the immersion will be less felt when it is effected suddenly, and as it is of consequence that the first impression should be uniform over the body, the bath ought not to be entered slowly or timorously, but with a degree of boldness. A contrary method, in some constitutions, is danger- ous, as it propels the blood from the upper to the lower parts of the body, and thus predisposes to a fit of apoplexy. For these reasons, the shower bath is attended with considerable advantages, because it transmits the water quickly over the whole body. 5. " The morning is the proper time for using the cold bath, unless it be in a river; in which case the afternoon, or from one to two hours be- fore sunset, will be more eligible. On the whole, one hour after a light breakfast, or two hours be- fore, or four after dinner, are the best periods of the day for this purpose. 6. " While the bather is in the water, he should not remain inactive, but apply brisk and general friction, and move his arms and legs, to promote the circulation of the fluids from the heart to the extremities. It is extremely imprudent to con- tinue in the water till a second chilliness attacks the body. 7. " Immediately after leaving the bath, it is nscessary that the bather should quickly wipe his body dry with a coarse dry cloth. He should not afterwards sit inactive, but if the season permit, he ought to take gentle exercise, till the usual cir- culation, and the customary action of the muscles, be restored. 8. " The best place for cold bathing is in the sea, or a clear river; but where neither of these can be conveniently had, the shower bath may be used. 9. " The principal advantages to be expected from cold bathing, besides the salutary exercise, are either the reduction of excessive heat, or the producing of a salutary reaction of the system. Ij the former, it has been found useful in several t>. vers. Affusion, however, in those cases, is most advisable, and more efficacious in reducing the morbid temperature, than immersion. But the cold affusion must not be employed in the cold stage. As soon as the hot fit is formed, the cold affusion is to be used immediately, and repeated occasionally. In the sweating stage, it is to be cautiously avoided. " In nervous diseases, too, the cold bath has sometimes been of service. " In gouty and rheumatic complaints, in dis- eases of the hip-joint, lumbago, or sciatica, after the removal of those complaints by the use of tho vapor or hot bath, and in conjunction with other remedies, the alternation of the cold with the va- por bath fortifies the constitution against a return of such attacks. 10. " The best preparation for cold bathing, is to begin with a warm, then a tepid, and after- wards a cool bath; after this course the bather may in general plunge with safety into the cold bath. In most cases, a bath every second day, from the commencement of the warm bathing to the end of a fortnight, will be sufficiently frequent; afterwards the cold immersion may be continued daily." V. The douche consists in the projection of a stream of cold water from a tube upon any part of the body. It is powerfully sedative, and has been long employed in inflammation of the brain. It should1 be used with caution, as its action is so powerful that a full inflammatory pulse frequently sinks into one almost imperceptible, in a very short space of time. It is one of the principal methods of applying cold water adopted by the hydropa- thists. VI. Medicated baths. These consist of water holding in solution various medicinal substances; as wine-baths, milk-baths, soup-baths—these have been used to convey nourishment to the body; sulphureous baths, mercurial baths, &c, used in skin diseases, syphilis, &c.; aromatic and chaly- beate baths, employed as tonics; acid baths, some- times used to remove the effects of mercury, &c. VII. Nitromuriatic bath. Prep. Mix 3 fluid ounces of muriatic acid with 2 fluid ounces of ni- tric acid, and 5 fluid ounces of distilled water, and add 3 ounces of the above mixture to every gallon of water in the bath. Should the bath prick the skin, a little more water may be added. Remarks. This bath was first introduced as a remedy for liver complaints. It must be contained in a wooden vessel, and may be used as a hip, knee, or foot-bath, a knee-bath being the one gen- erally adopted in England. The inventor, Dr. Scott, once plunged the Duke of Wellington up to his chin in a bath of this kind in India, and thus cured him of a severe hepatic affection. VIII. Sulphur bath. a. The patient is placed (not including the head) in a species of box, at the bottom of which is put a piece of hot iron, on which a little sulphur is thrown, great care being taken to avoid the escape of the fumes, and the inhalation of the same by either the patient or the attendants. Another method is to dissolve a little sulphuret of potassium in the water of a comraou warm bath. The proportion is 1 oz. of the sul BAT 103 BAT phuret to 8 gallons of water. This form of the bath is not, however, quite as efficient as the gase- ous one first described. 6. (Dupuytren's gelatino-sulphurous bath.) This is formed by dissolving 1 oz. of the sulphuret of potassium and 4 oz. of Flanders glue, in every 8 gallons of the water of a warm bath. It is an imitation of the celebrated waters of Bareges, the glue supplying the place of the baregine found in the latter. Remarks. The sulphur-bath under any form is a powerful remedy in every description of skin disease. Leprosy, the most obstinate of all, has been cured by it. The common itch requires only one or two applications of the sulphur-bath to eradicate it entirely. All forms of scurf, whether on the face, head, or body, yield to its influence. Local irritation occasioned by minute pimples, or inflammatory patches of disordered skin, is speed- ily subdued and removed. Scrofula, and also those affections for which the warm or vapor baths have been recommended, will derive powerful assistance from the sulphur-bath. IX. Tepid bath. The temperature of this bath varies from 85° to 92° Fahr., 88° being considered a medium temperature. Its action on the body is intermediate between that of the warm and cold baths, and is admirably adapted for the purposes of cleanliness, and promoting the healthy action of the skin. It is frequently employed as a prepara- tive to cold bathing. X. The warm bath has a temperature of from 92° to 100° Fahr., or about that of the human body. Remarks. The warm bath is at once the most luxurious and effective mode of bathing, and if taken under proper restrictions, is highly conducive to health. If only on the grounds of personal cleanliness, this species of bathing has the highest claim on our attention. " The sensations attend- ant upon immersion in a warm bath are most de- licious. Its effect is, first to increase the circula- tion of the blood, and to determine it to the skin; after a few minutes an agreeable and universal in- crease of heat is experienced; the face, and fore- head generally, are soon bedewed with perspira- tion : a pleasing and prevailing calm is felt, men- tally and physically; and after remaining in some 12 or 15 minutes, coming out and dressing, the refreshing feeling and consciousness of personal purity give rise to associations of the most happy character. The warm bath may be taken at any time during the day: it is perhaps better to em- ploy it upon an empty stomach, or before a meal, rather than after one. The temperature should be from 98° to 100° ; the time of immersion should not exceed 15 minutes. The old idea that it is relaxing, is erroneous, except where persons re- main in for hours, as some people do, or where it is taken too often." The warm bath, in a medical point of view, is especially adapted to general torpor of the system, liver and bowel complaints, hypochondriasis, hys- terical affections, morbid suppressions, dry skin, nearly all cutaneous and nervous diseases, chronic rheumatism, &c. As a tonic or stimulant after excessive fatigue, great mental excitement, or physical exertion, it is unequalled, and furnishes one of the most wholesome, and at the same time luxurious sources of refreshment we are acquainted with. XI. The vapor-bath consists in vapor being ad- mitted to the apartment, and thus not only is tha body immersed in it, but it is inhaled as well. It is used at different temperatures, known by the name of tepid, when the temperature varies from 90° to 100° ; warm, when from 100° to 112° ; and hot, from 110° to 130° ; but when the vapor is not inhaled, the heat of the latter may be raised to 160°. Remarks. The principal action of the vapor- bath is to produce a copious diaphoresis. In fact, it is the most powerful diaphoretic agent known. It is a certain specific for a cold ; and in all those cases wherein warm bathing is recommended, the vapor-bath ranks highest. It constitutes the most powerful pharmaceutical remedy existent: com- bined with friction, or shampooing, its utility in cases requiring an additional action, as in con- tracted muscles, tendons, &c, is much increased ; " and instances are numerous, where the lame have thrown aside their crutches, and the bed- ridden have again mixed with the world, after a few applications of this bath." " It is no uncommon thing to hear a patient start and shriek with ag- ony before entering the bath, and to receive his congratulations and thanks on his coming out: they will oftentimes exclaim,—' It is wonderful! I could not hare believed it—I am well—/ can walk—/ can jump !' " The vapor-bath is administered in chronic rheu- matism, stiff joints, long-continued indigestion, gout, lumbago, sciatica, scrofulous swellings, fever, skin diseases, &c, but should be avoided in acute inflammations, and for persons of a very full and excitable habit of body. XII. The shower-bath. This may be regarded as a modification of the cold bath or plunge bath, and its effects are similar. The cold shower-bath is however less alarming to nervous persons, and less liable to produce cramp, than cold immersion: it may be considered as the best and safest mode of cold bathing, and is recommended in many ner- vous complaints. It has also afforded relief in some cases of in- sanity. Where the saving of expense is an object, or a regular shower-bath is not to be procured, a large common watering-pot filled with cold water may be used as a substitute. Let the patient sit un- dressed upon a stool, which may be placed in a large tub, and pour the water from the pot over the head, face, neck, shoulders, and all parts of the body, progressively down to the feet, until the whole has been thoroughly wetted. BATHS, TO HEAT. Various methods have been proposed for this purpose, but they are for the most part expensive and unsuited to private fami- lies. The following plan, however, is an exception to the above, and will be found at once cheap and convenient. Italian plan of warming baths. This consists in immersing in the bath a sort of u or syphon- shaped sheet iron tube, furnished with a little fire- place, near the bottom, for the purpose of burning charcoal. In the following figure is given a rep- resentation of this simple apparatus and its appli- cation. BAT a, Bath tub. *, The larger arm of the warming-tube by which the charcoal is introduced, and by which the fumes fly off". c, The smaller arm to admit air to support the com- bustion. d, The fire-grate, to support the burning charcoal. BATHS, THE SITUATION OF. This should always be, if possible, near the principal bedrooms on the same floor, for the sake of ready- access to them, and in a place where plenty of good water can be procured. BATHS, (in Chemistry.) These mostl)- con- sist of water or alkaline solutions, in which vessels are placed containing substances that it is desirous to submit to a limited degree of heat. The high- est temperature that can be given to any substance contained in a vessel placed in another of boiling water, is about 205 or 206° ; but by adding one- fifth of salt to the bath, a heat of 212° may be obtained. Baths of fusible metal, saturated solu- tions of salt, sand, and (on the large scale) steam, are also used. (See Boiling Point.) BATH METAL. Prep. Melt together, under charcoal, 1 lb. of brass, with 4 J oz. of spelter. BATH PIPE. Prep. Powdered white sugar 1 lb.; Italian juice (dissolved in a little water) 2 oz.; powdered gum arabic 1 oz. Proc. Make " • them into a stiff mass with warm water, and roll it into the usual form. BATTER, (in Cookery.) A mixture of flour, milK, eggs, oil, or butter, and frequently spices, beat together to a thin paste. Use. To cover va- rious articles during the operation of cooking, and also to form puddings. BATTERY, GALVANIC OR VOLTAIC. An instrument or apparatus for the production of an electrical current by chemical decomposition. One of the most useful forms of the galvanic battery is that proposed by Professor Daniell, and commonly known by his name. Its peculiar ad- vantages arise from its action continuing without interruption for a long time, hence the name of constant battery that has been applied to it. The following figure will explain its construction. Between the membrane and the copper cylinder is poured a saturated solution of blue vitriol, and in the aiaphragm or cylinder B, dilute sulphuric acid of the s. g. of 1*136 made with about 1 part of oil of vitriol and 7 or 8 of water. The battery is now ready to be applied to the purposes of elec- trotyping, for which one is quite sufficient; six of these simple batteries will form a circle of consid- erable power, and about 20 will produce one suf- ficiently strong for most experiments of demonstra- tion and research. 104 BEA A, A copper cylinder filled with a saturated solution of sulphate of copper. B, A smaller porous cylinder or membrane, containing a mixture of 1 part of oil of vitriol and 7 of v.iter. C, A rod of zinc supported in the smaller cylinder by the cross-piece i. D, A shelf full of'small holes, for supporting crystals of sulphate of copper, to keep up the strength of the solution. e and /, Screws and caps to connect the wires g anr1 with the battery. g, The positive wire. A, The negative wire. I." Another permanent battery of considerable powet is formed by arranging a series of cells, 2 inches in liameter, in each of which is placed a smaller cell, of 1 inch in diameter. The latter are filled with a solution of sulphuret of potassium, of the sp. gr. 1*14, and the former with nitric acid, of the sp. gr. 1-35, the pairs are then connected to- gether with small discs of platinum foil. III. Professor Jacobi has lately described a very simple, cheap, and convenient form of battery said to be discovered by a Russian prince, but wh'ch is, in reality, only an adaptation on the small scale, of the terraqueous battery of Mr. Bain, by which he works his telegraph. This new battery is formed by immersing a plate of zinc and another of copper, in common garden mould, placed in a flower-pot, when, on completing the circuit, a powerful current of electricity is pro- duced. All that is necessary to keep up the ac- tion of the battery is to moisten the earth with a little water. The plates should be placed equi- distant from each other, and the sides of the pot. The professor has had a battery of twenty of them at work for a month without their activity being apparently diminished. BEANS. Qual. A wholesome esculent, when eaten in the green state, and well cooked, but apt to produce flatulence unless combined with spices. In the dried or ripe state they are more difficult oi digestion, and are apt to distend the stomach. Beans are mostly cooked by boiling in water, to which a little salt of tartar has been added, to pre- serve their green color. BEANS, CULTIVATION OF. Beans should succeed a grain crop, provided the ground is in decent order, and not worn out by previous work- ing. Less than four bushels of seed ought not to be j used per acre, and this is best sown by running the i drill-barrow after every third plough; afterwards ™ harrowing before the young plants reach the sur- face. Dung is frequently given to beans, especially when they succeed wheat, that had not received manure. It is best applied on the stubble, before the winter ploughing is given, or it may be thrown into the drills with the seed. Beans require hoeing or earthing up, which is sometimes done by hand or plough ; they also require weeding, which must BEE 105 BEE be done by hand, after the hoeing. Before beans are cut they should be well ripened, and may be generally harvested at the end of September or beginning of October. They should be, cut with the sickle and tied in sheaves, and in stacking them a " bole," or air funnel, should be left in the centre of the stack, in such a manner that a cur- rent of air may pervade the whole. (See Barley.) BEAR'S GREASE. This fat is much esteem- ed for promoting the growth of the hair, but in reality possesses no superiority over any other ani- mal fat. The mass of that which is sold in Eng- land is hog's lard. The quantity annually con- sumed in Great Britain and exported, is estimated at several tons, being a larger quantity than all the bears at present procurable in Europe would sup- ply, if slaughtered and roasted for their fat. BEAR'S GREASE. (FACTITIOUS.) Prep. Hog's lard 16 oz.; flowers of benzoin and palm oil, of each \ oz. Proc. Melt together until com- bined, and stir until cold. Remarks. This article does not readily become rancid by age, and may be scented at pleasure. BECHAMEL, (in Cookery.) A variety of fine white broth, or consommee, thickened with cream. Proc. Cut lean veal and ham or bacon into small slices, put them into a stewpan with a good piece of butter, an onion, a blade of mace, a few mushroom-buttons, a bit of thyme, and a bay- leaf ; fry the whole over a very slow fire, but not to brown it; thicken it with flour. Add an equal quantity of good veal or mutton broth, and cream. Let it boil gently one hour, stirring it all" the time. Strain it through a soup-strainer. BE ECU WOOD MAHOGANY. Prep. Dis- solve 2 oz. of dragon's blood and 1 oz. of aloes in 1 quart of rectified spirit of wine, and apply it to the surface of the wood previously well polished. II. Wash over the surface of the wood with aquafortis, and when thoroughly dry give it a coat of the above varnish. III. Boil 1 lb. of logwood chips in 2 quarts of water, and add 2 handfuls of walnut peels ; boil again, then strain, and add 1 pint of good vinegar, as above. BEEF. Qual. The flesh of a bullock, not past the middle age, is very nutritious, and espe- cially adapted to persons of good appetite, or that labor, or take much exercise. It is also well suit- ed for persons of delicate constitutions, if not over- cooked, and left full of gravy, in which case it will sit lightly on the stomach, and its fat prove almost as digestible as that of veal. Choice. Ox beef is considered the best, and may be known by having a fine smooth open grain, a good red color, and a tender texture. The fat should look whitish yellow, or but slightly yellow. Cow beef has a closer grain than ox beef, and the lean a deeper red; bull beef is closer still, the fat hard and skinny, the lean of a deep red, and it has a stronger smell. Heifer beef resembles ox beef, except in being smaller, for which reason it is pre- ferred in some families. The best roasting pieces are the sirloin and the long ribs, but the short ribs and the silver side of the round are also sometimes roasted, but do not turn out so well. These pieces are much improved by being steeped for three or four hours in a marinade made with three par's of water and one of vinegar, before roasting. 14 BEEF A-LA-MODE. Prep. I. " Cut out the bone from the beef, and convert it, with the trimmings, into gravy; then stuff the orifice with rich forcemeat. Half roast it, and before it is put into the stewpan, lard the top with dried and pickled mushrooms, adding mushroom-powder in the orifices; then put in two quarts of gravy from the bones, a large onion stuck with cloves, and two carrots cut in slices. When the beef has stewed till it is quite tender, strain and thicken the sauce, add to it a glass of wine, mushrooms, and oysters, and sippets of fried paste: either the mushrooms or oysters may be omitted, if the fla- vor of either should not be desirable." II. " Take 3 lbs. of the rump, or any part of the beef which will stew well; trim it nicely, and out off all the fat. Chop all sorts of sweet herbs together veiy finely, with a little shalot, and a great deal of spice, and put them into a saucer of vinegar, that has been rubbed with garlic. Cut fat bacon into long slips and dip it into the herbs and vinegar; lard the beef regularly on both sides, if necessary, in order that it should be thoroughly flavored; rub the beef over with the herbs and spice ; flour the meat, cuu a piece of butter, thp size of a walnut, rolled in flour, and a pint of water. Bake the beef in an oven, strain the gra- vy, which will scarcely require either thickening or browning, and serve it up with pickles on the top. It is most excellent when cold, but should be served up hot at first. The gravy may be boiled to a glaze if necessary. It will require a good deal of spice ; a teaspoonful of cayenne pep per, one of white pepper, a saltspoonful of allspice, half the quantity of pounded cloves, and a blade of mace pounded, or the mixed spices may be used." BEEF, COLLARED. " Take the best part of a shin of beef, of which soup has been made, (for it must be stewed until very tender,) and an ox-tail, also well-stewed; cut them into small pieces, season them well, add a glass of wine and a glass of ketchup, and put it into a stewpan cov- ered with a part of the liquor in which the ox-tail has been boiled ; stew it for about twenty minutes, and then put it into a mould. It must be very cold before it is turned out. This is a good way of employing the beef and heel when soup or jelly is made ; a few chopped sweet herbs may be add- ed, and hard eggs cut into slices, or pickles, such as sliced cucumbers, intermingled. The flavoi may be varied in many ways." BEEF, DUTCH. Prep. Cover lean beef with a mixture of treacle and moist sugar, for three days, then salt it well with common salt and saltpetre, rubbed well in, and turn it well ev- ery day for a fortnight. It must then be rolled tight in a coarse cloth, and submitted to heavy pressure, after which it is to be hung up in wood smoke, and turned every day. If after boiling it be well pressed it will grate or cut in " shivers" equal to the finest Dutch beef. One pound of salt is enough for twelve pounds of beef. BEEF, HAMBURGH. Prep. This is pre- pared by pickling the beef for three weeks, with a mixture of 1£ lb. of salt, 1 lb. of treacle, and 1 Joz. of saltpetre, well rubbed in, after which it is dried in wood smoke. The ribs is the part generally BEE 106 BEE used, of which the above pickle **ill be enough for 15 to 18 lbs. BEEF, HUNG. Prep. I. Choose a piece of beef with as little bone as you can, (the flank is best,) sprinkle it, and let it drain a day; then rub it with salt and saltpetre, but only a small propor- tion of the latter; and you may add a few grains of cochineal; all in fine powder. Rub the pickle every day into the meat for a week, then only turn it. It will be excellent in eight days. In sixteen drain it from the pickle; and let it be smoked at the oven's mouth when heated with wood, or send it to the baker's. A few days will smoke it. A little of the coarsest sugar may be added to the salt. It eats well boiled tender with greens or carrots. If to be grated as Dutch, then cut a lean bit, boil it till extremely tender, and while hot put it under a press. When cold, fold it in a sheet of paper, and it will keep in a dry place two or three months, ready for serving on bread and butter. II. Rub the beef with one eighth of its weight of salt, to which a little saltpetre has been added, then put it into a tub or other suitable vessel, place a board over it, and pile heavy weights upon it; let it remain so for fourteen to twenty days, then take it out and hang it up for three weeks or a month to dry. BEEF, HUNTER'S. Prep. To a round of beef, weighing twenty-four pounds, take three ounces of saltpetre, three ounces of the coarsest sugar, an ounce of cloves and nutmeg, half an ounce of allspice, and three handfuls of common salt, all in the finest powder. Allow the beef to hang two or three days, remove the bones, then rub the spices well into it, continuing to do so ev- ery day for two or three weeks. Before dressing it, dip it into cold water to take off the loose spice. Bind it up tightly with tape, and put it into a pan with a teacupful of water at the bottom ; cover the top of the meat with shred suet, and cover the pan with a coarse crust, and brown paper over it. Let it bake five hours, and when cold take off the paste and the tape. BEEF, LEICESTER SPICED. Prep. Take a round of beef, rub in a quarter of a pound of saltpetre, finely pounded ; let it stand a day, then season it with half a pound of bay-salt, an ounce of black pepper, and the same of allspice, both pounded. Let it lie in the pickle a month, turn- ing it every day. BEEF, PICKLED. Prep. Rub each piece of beef very lightly with salt; let them lie singly on a tray or board for 24 hours, then wipe them very dry. Pack them closely in a tub, taking care that it is perfectly sweet and clean. Have the pickle ready, made thus: Boil four gallons of soft water with ten pounds of coarse salt, four ounces of saltpetre, and two pounds of coarse brown sugar; let it boil 15 minutes, and skim it while boiling very clean. When perfectly cold pour it on the beef, laying a weight oh the top to keep the meat under the pickle. This quantity is sufficient for 100 lbs. of beef if closely packed. BEEF, POTTED. Prep. Cut the beef small, add to it tome melted butter, 2 anchovies, boned and washed, and a little of the best pepper, *U pounded very fine. Beat the whole well to- gether in a marble mortar, until the paste is very smooth and yellow colored, then put it into pots and pour clarified butter over it, about J of an inch deep. BEEF, WELSH. Prep. Rub two ounces of saltpetre into a round of beef, let it remain an hour, then season it with pepper, salt, and a fourth portion of allspice ; allow the beef :o stand in the brine for 15 days, turning it frequently. Work it A*ell with pickle ; put it into an earthen vessel, with a quantity of beef-suet over and under it, cover it with a coarse paste and bake it, allowing it to remain in the oven for 6 or 8 hours. Pour off the gravy, and let the beef stand till cold. It will keep for two months in winter, and will be found useful amid the Christmas fare in the coun- try. BEER, ALE, and PORTER. Qual, $c. Pure malt liquor, which has undergone a perfect fermentation, is perhaps the most wholesome bev- erage that can be drurJc provided it be not taken in excess. Malt liquor boars different names ac- cording to its strength and solor. Ale is the most nutritious variety, but good porter frequently agrees better with bilious constitutions. The most wholesome and perhaps the least exceptionable beverages prepared from malt are those known as East India, Scotch, and Bavarian ales. A late writer has described good beer as nutritious, from the sugar and mucilage it contains; exhilarating, from its spirit; and strengthening and narcotic, from its hops. The stronger varieties of ale con- tain 7 to 8 per cent, of absolute alcohol; average strong ale 5 to 6 per cent.; brown stout 6 to 7 per cent.; London porter 3£ to 4 per cent.; and table beer 1 to 2 per cent. (See Brewing, Ale and Malt Liquor.) BEER, AMBER. Prep. Amber is now out of fashion, but formerly was drunk in great quan- tities, in London, mixed with bitters, and called purl. The proportions of malt were three qu;>r. ters amber, and one quarter pale, with six pounds of hops to the quarter. The first liquor is usually turned on at 170°, and the second at 185°. The worts are boiled together for two hours. It is tunned at 64°, and after 24 hours roused every 2 hours, till the heat is increased to 74°. It is then skimmed every hour for 6 hours and cleansed, and generally used as soon as it has done working in the barrels. BEER, BRAN. A very good article of table beer may be brewed from bran, especially if it be mashed with about •— of its weight of good malt A proportionate quantity of hops must be used, and the addition of a little moist sugar will vastly im- prove it. Bran will yield from 16 to 20 lbs. pel barrel, with proper management. BEER, CHEAP. "No production of this coun- try abounds so much with saccharine matter as * the shells of green peas. A strong decoction of them so much resembles, in odor and taste, an in* fusion of malt (termed wort) as to deceive a brew- er. This decoction, rendered slightly bitter with the wood sage, and afterwards fermented with yeast, affords a very excellent beverage. The me- thod employed is as follows: " Fill a boiler with the green shells of peas, pour on water till it rises half an inch above the shelly and simmer for three hours. Strain off the liquor. BEE 107 BEE and add a strong decoction of the wood sage, or the hop, so as to render it pleasantly bitter; then ferment in the usual manner. The wood sage is the best substitute for hops, and being free from any anodyne property is entitled to a preference. By boiling a fresh quantity of shells in the decoc- tion before it becomes cold, it may be so thoroughly impregnated with saccharine matter as to afford a liquor, when fermented, as strong as ale." BEER, POTATO. An excellent beverage may be prepared by mixing the pulped potatoes with about TV of their weight of good barley malt, and mashing with water at 160°, keeping it at the same temperature for 4 hours; after draining off this wort, a second mash must be made at 180° for 1 hour; the mixed worts must be then boiled with a little hops, cooled and fermented. BEER, SPRUCE. I. (White.) Ing. Water 10 gallons; sugar 10 lbs.; essence of spruce -J lb.; yeast £ pint. Proc. Dissolve the sugar and es- sence of spruce in the water, previously warmed ; then allow it to cool a little, and add the yeast, as in making ginger-beer; bottle immediately in half- pint bottles. II. (Brown.) For sugar use treacle. Remarks. Spruce beer is a pleasant beverage, when well pre- pared, and possesses slightly diuretic properties. BEER, SUGAR. Prep. Mash a peck of bran in 10 gallons of boiling water for 2 hours, draw off the wort, add 7 lbs. of moist sugar, and boil it with a \ lb. of hops; then cool it down and add a little yeast. It may be put into the cask the next day, and in 3 days more it may be bunged down. At the expiration of 6 or 8 days it will be fit to drink. This beer will not keep long. BEER, SUGAR AND MALT. Prep. $c. It has been found that 100 lbs. of good moist sugar, mixed with 1 quarter of malt, will produce an equal quantity of wort, and of the same quality, as 2 quarters of malt would do under similar treatment. The best plan is to add the sugar to the wort from the malt, after it is let down from the mash-tun. In other respects the brewing is the same as from malt alone. BEER, TREACLE. Prep. Boil \ lb. of hops with 14 lbs. of treacle in 36 gallons of water for 1 hour ; then strain off the wort and add, when near- ly cold, \ a pint of yeast; the next day it may be put into a cask or bottled. II. Hops 1 oz.; treacle 1 lb.; water 1 gallon. As above. Remarks. A cheap and pleasant bev- erage when well made. It will not keep for any length of time. BEER, TABLE. Prep. I. Malt 1 bushel; hops | lb. Draw off 1$ barrel of wort at three mashings. (See Brewing.) II. Malt 8 bushels ; hops 7 lbs.; sugar coloring 7 lbs.; Spanish juice 1 lb.; treacle 14 lbs. To pro- duce 10 barrels, or five times the malt. BEER, TWOPENNY (or simply, Twopenny.) Prep. Malt 3 bushels ; hops 2 lbs.; Spanish juice 2 lbs.; treacle 14 lbs; capsicum £ oz. To produce 1 barrel, or three times the malt. Drank in cold weather as a stimulant, frequently when only a '. week old. BEES. In addition to what has been said under the article Apiary, the following will no doubt ! prove interesting to the reader. Mr CobbeX t on the management of Bees. The best hives are those made of clean unblighted rye. straw. A swarm should always be put into a new hi'*e, and the sticks should be new that are put into the hive for the bees to work on; for, if the hive be old, it is not so wholesome; and a thou- sand to one but it contains the embryons of moths and other insects injurious to bees. Over the hive itself there should be a cap of thatch, made also of clean rye-straw; and it should not only be new when first put on the hive, but a new one should be made to supply the place of the former one every three or four months; for, when the straw begins to get rotten, as it soon does, insects breed in it, it smells bad, and its effect on the bees is dangerous. The hives should be placed on a bench, the legs of which mice and rats cannot creep up. Tin round the legs is best. But even this will not keep down ants, which are mortal enemies of bees. To keep these away, if they infest the hive, take a green stick and twist it round in the shape of a ring, to lay on the ground, round the legs of the bench, and at a few inches from it; and cover this stick with tar. This will keep away the ants. Besides the hive and its cap, there should be a sort of shed, with top, back, and ends, to give ad- ditional protection in winter; though, in summer, hives may be kept too hot, and in that case, the bees become sickly, and the produce light. The situation of the hive is to face the south-east; or, at any rate, to be sheltered from the north and the west, i'rom the north always, and from the west in winter. If it be a very dry season in sum- mer, it contributes greatly to the success of the bees, to place clear water near their home, in a thing that they can conveniently drink out of; for, if they have to go a great way for drink, they have not much time for work. It is supposed that bees live only a year; at any rate, it is best never to keep the same stall, or fa- mily, over two years, except it be wanted to in- crease the number of hives. The swarm of this summer should always be taken in the autumn of the next year. It is whimsical to save the bees when the honey is taken. They must be fed; and if saved, they will die of old age before the next fall; and though young ones will supply the place of the dead, this is nothing like a good swarm put up during the summer. A good stall of bees, that is to say, the produce of one, is always worth about two bushels of good wheat. The cost is nothing to the laborer. He must be a stupid countryman indeed who cannot make a bee-hive ; and a lazy one indeed, if he will not if he can. In short, there is nothing but care demanded; and there are very few situations in the country, especially in the south of England, where a laboring man may not have half a dozen stalls of bees to take every year. The main things are to keep away insects, mice, and birds, and especially a little bird called the bee-bird ; and to keep all clean and fresh as to the hives and cover- ings. Never put a swarm into an old hive. If wasps or hornets annoy you, watch them home in the day-time ; and, in the night, kill them by fire or by boiling water. Fowls should not go where bees are, for they eat them. On the different kinds of hives.—1. The com- mon hive. This hive is too well known to require BEE 108 BEL any description. It should be made of good clean dry straw, and sufficiently thick and firm to pro- tect the bees. The size of the hive should be pro- portionate to the size of the swarm placed in it. Care should be taken to avoid covering this hive with a hackle or turf, as it induces mice to build in it, and ultimately to destroy both combs and bees. 2. Glass hives. There are various modifications of this useful kind of hive. That of Mr. Moulton con- sists in placing glasses on a board furnished with holes at the upper part of a straw hive of peculiar construction; when filled with honey these may be removed without injury to the bees or disturbing the economy of the hive. The first year the glasses are only filled once, and generally produce about 8 lbs. of honey of superior quality ; but the second year and subsequent years the glasses may be worked twice or oftener. 3. The double cottage straw hive. This hive is worked by first hiving the bees in the lower hive, and after 10 days clear- ing the opening at top and affixing thereon another small hive either of glass or straw. When full, the latter may be removed. 4. The box hive and hexagon box and straw hives may be worked in the common way, or by placing a glass hive over it. The management is very similar to the pre- ceding varieties. Bee-flowers. Bees seldom fly more than a mile for their food ; it is therefore advisable to encourage the growth of such flowers as they appear to be most attached to. The following are said to be the most favorable for pasturage, and those that blossom early should be preferred: Shrubs, ts volume of oil of bitter almonds, at a temperature of about 112°, and purified by boiling in ether, for some time, when crystals will be deposited on cooling. These are again dissolved in boiling alcohol, and purified by filtering and crystallization. BEXZILE. (Discovered by Laurent, who called it benzule, with which it is isomeric.) Prep. Pass chlorine^ gas ov?r melted benzoin, until muriatic acid ceases to be formed; cool and dis- solve in hot alcohol, which, on cooling, will deposite crystals of pure benzile. Prop. Soluble in alcohol | and ether; tasteless, inodorous, volatile, and in- flammable. BENZILIC ACID. (Discovered by Liebig.) 1 Prep. Boil benzoine or benzile with a saturated alcoholic solution of potassa, adding more of the latter, as long as a blue color is produced, after the previous portion has been decolored bv boilino-. Then neutralize with muriatic acid, filter and add muriatic acid in excess; on cooling, crystals of benzilic acid will be deposited. Prop. Soluble in water; fusible; with potassa and silver it forms bcnzilates of those bases, which are crystallizable. BENZIMIDE. The pearly needles and la- mella?, which separate under certain circumstances from the essential oil of bitter almonds. It was discovered by Laurent, and has been thought by some to be dry benzoate of ammonia. BENZOIC ACID. Syn. Flowed «• Ben- zoin or Benjamin. Prep. There are two general methods of procuring this acid from gum benzoin : one by sublimation, or the " dry way," as it is com- monly called ; and the other, by dissolving it out in the form of a salt, from which the acid is after- wards procured ; this has been called the " moist way." I. By sublimation. a. Put 1 pound of coarsely triturated benzoin into an iron pot with a flat bottom, whose diameter is from 8 to 9 inches; the benzoin forming* therein a layer of from 1 to 2 inches in depth. The open end of the pot is then to be covered with a sheet of soft and loose blotting paper, (felt, Liebig,) which must be attached to the rim with paste. A cone, formed with strong and thick paper, (cart- ridge paper,) is then to be capped over the top of the pot, including the blotting paper; and this is also to be attached with paste and string. The apparatus thus prepared, should then be placed on the sand-bath, and exposed from 4 to 6 hours to a gentle heat. After this lapse of time, it may be removed from the sand-bath, inverted, and the string detached, when beautiful white needles, oi a silky lustre, possessing the agreeable odor of benzoic acid, will be found in the paper cone. Prod. From 1 lb. of good benzoin 1£ to 2 oz. of benzoic acid may be procured. The second sub- limation ordered in the London Pharm. becomes quite unnecessary when the above method is fol- lowed. The following modification of the above is highly recommended by Gauger. b. Place 12 oz. of coarsely powdered benzoin resin, mixed with sand, in a flat iron vessel capa- ble of containing from 2 to 4 lbs.; cover the mouth of-the vessel with loose blotting paper, place there- in a stick to support 4 or 5 paper discs, at some distance above the blotting paper, horizontally fixed on the stick; then tilt a paper bag in the form of a sugar-loaf, and formed of a double sheet of paper, (inward blotting paper, and outward sugar paper,) over it, and attach this apparatus by means of a string, around the brim of the vessel. After 6 or 8 hours' exposure in a sand-bath, allow it to cool; take out the benzoic acid from the bag and the paper discs, renew the paper attached over the mouth of the vessel, and again arrange the whole as before, when it must be heated for some hours to a higher temperature. It is advisa- BEN 110 BEN ble to renew the paper for a third time. The white crystals are separated from the product, the colored crystals strongly pressed between folds of blotting paper, and again sublimed as before. 12 oz. of good benzoin thus furnish from 10 to 11 drachms of fine benzoic acid. Some benzoic acid may afterwards be obtained from the papers em- ployed. (Gauger's Report, 1842.) c. (Process at Apothecary's Hall.) The best gum benzoin is put into an iron pot, set in brick- work, over a proper fire, and communicating by a conical metal neck, with a wooden box lined with paper, as a receiver for the flowers. The sublimation is conducted rather rapidly, and the acid condenses in beautiful elastic prismatic crys- tals ; but if the process be conducted more slowly, the product is proportionately scaly. Prod. 10 to 12 per cent, of flowers are thus generally procured, which, after being pressed in blotting paper, are again sublimed, and give 8 or 9 per cent, of very pure acid. II. By the moist way. a. (Scheele's process.) Mix intimately togeth- er, equal parts of finely powdered benzoin and hy- drate of lime, and boil for 1 hour, wjtli 40 parts of water; filter and evaporate to one-fifth ; saturate the lime with muriatic acid, when the benzoic acid will crystallize out as the liquor cools; it should be then either washed or sublimed, after first well drying it. Remarks. If a perfect mixture of the lime and powdered gum be not first made, the lat- ter will run into a solid mass in the boiling water, and the process will fail. 1 lb. of benjamin yields §j> 3yj, j)ij of flowers. (Gray.) By my own ma- nipulations I could never succeed in procuring this proportion of acid. The above process is similar to that of the Dublin Pharmacopoeia. 6. (Process of Stoltze.) Dissolve the resin in 3 times its weight of alcohol, introduce the solu- tion into a retort, and add thereto gradually, a so- lution of carbonate of soda in weak spirit and water, until all the free acid be neutralized ; water equal to twice the weight of the benzoin employed, must be next poured in, and the alcohol removed by distillation. The floating resin should be now skimmed off the remaining liquid, and washed with a little water, which should be added to the contents of the retort, which will deposite crystals on cooling. c. Boil hippuric acid for 15 minutes in nitric acid, sp. gr. 1*42, then add water, and allow the solution to crystallize ; collect the crystals, and purify by sublimation as above. %* Hippuric acid is manufactured from the urine of horses, which is evaporated to J of its original volume, and then mixed with muriatic acid ; after which, the liquid deposites the acid, somewhat impure, under the form of a crystalline powder. Large quantities of benzoic acid are said to be obtained by the above process, but owing to its not being generally well purified, is of inferior quality and unsaleable. It may, however, be rendered quite equal to that obtained from gum benzoin, by care- ful manipulation. " A manufactory of sal ammo- niac, near Magdeburgh, which uses urine, is able to supply flowers of benjamin by the cwt." (Gray.) Remarks. The manufacture of benzoic acid has lately assumed considerable interest from the scar- I city and high price of gum benzoin, which is now j from 40Z. to 50Z. the cwt. The low price at j which this acid has for some time past been sold, is barely sufficient to repay the expenses incurred in its manufacture. The finest gum benzoin is exported in large quantities to Spain, where it is mixed with olibanum and used as incense. Ben- zoic acid is at the present time very dear, being about Is. 7^d. to Is. 8d. an ounce, whereas, its usual price averages from Is. ^d. to Is. 2d. the oz. A large manufacturer, with whom I am ac- quainted, made a sale some time since at Is. ljo'., of about 300 oz., but has lately greedily taken back the greater portion, which remained unsold, at Is. 4d., besides paying all the expenses of tran- sit, &c. The product by the process of sublimation is generally greater than by the humid way, and is consequently the one usually adopted. Much, however, depends upon the quality of the gum employed. It is found to be the most economical to use the best benzoin, as it is richer in benzoic acid than the inferior kinds. Prop., Uses, tyc. Form; light feathery white crystals; very soluble in alcohol. It is used in making paregoric, and is sometimes administered in chronic bronchial affections; it is expectorant Dose. 10 to 20 grs. in old coughs. Pur. 24 parts of boiling water dissolve 1 part of benzoic acid, and again deposite the greater portion on cooling. Freely soluble in alcohol, and in liquor of potassa, from which it is precipitated by adding muriatic acid. When cautiously heat- ed, it wholly evaporates, with an odor of benzoin. It is inflammable. (P. L.) BENZOATES. Combinations of the bases with benzoic acid. Prep. The benzoates of ammonia, soda, and potassa, may be made by dissolving with heat benzoic acid in their respective aqueous solutions, until they become perfectly neutral. Most of the other benzoates may be formed in a similar way, or by adding a benzoate of an alkali to a salt of the base. BExNZOINAMIDE. Syn. IIydrobenzoina- mide. A white, tasteless, inodorous, volatile pow- der, obtained by heating benzoin with water of ammonia. BENZOIN. Syn. Camphor of Oil of Alm- onds. A compound isomeric with benzule, dis- covered by Robiquet and Boutron Charlard. Prep. Mix together equal parts by measure of the raw oil of bitter almonds, and a solution of caustic po- tassa in alcohol. As soon as the liquid becomes full of crystals, and apparently solid, it must be dissolved in alcohol, filtered, and crystallized Prop., tyc. Brilliant prismatic crystals ; tasteless, odorless, volatile, and inflammable ; soluble in al- cohol, and forming with oil of vitriol, and with alcoholic solution of potash, a violet-blue solution. BENZOLE. Syn. Benzine. Discovered by Faraday among the products of the destructive distillation of organic substances; it resembles ether. Prep. Submit a mixture of 1 part of ben- zoic acid and 3 parts of slaked lime, to distilla- tion, and redistil the oily product with water. BENZONE. Syn. Carbobenzide. An oily liquid, heavier than water, disco-^red by Mis- cherlieh and Peligot. Prep. The raw product o! BEZ 111 BIC the distillation of benzoate of lime, is distilled first in a water-bath, and then afterwards until the heat gradually rises to 920°, as long as benzole comes over. The product is next exposed to a cold of —5°, when the crystals of naphthaline which form must be separated from the liquid, which is pure henzone. BENZULE. The hypothetical radical of sev- eral compounds ob.'ained from the oil of bitter al- monds, and supposed to be the base of benzoic acid. Among the principal members of this group may be mentioned hydruret of benzule, obtained from a mixture of oil of almonds, milk of lime, and chlo- ride of iron, by distillation ; the chloride of benzule, obtained from the last article (rendered dry by chloride of calcium) by passing chlorine gas through it, as long as muriatic acid is formed; the bromide of benzule, also prepared like the chloride; the iodide of benzule, prepared from a mixture of iodide of potassium and chloride of benzule by dis- tillation; the sulphuret of benzule, prepared by distillation from a mixture of sulphuret of lead and chloride of benzule; and cyanuret of benzule, also prepared by distillation, from a mixture of bicyanide of mercury and chloride of benzule. The series also includes hippuric acid, amygdalinic acid, and amygdaline, as well as several other substances whose names contain (benz-) the first part of the word benzule, as indicative of their constitution. BERBERINE. A substance discovered by Buchner, in the barberry shrub, (berberis vulgaris.) It belongs to the class of azotized coloring sub- stances. It is soluble in boiling water and in alco- hol, from either of which it may be obtained in crystals. BETULINE. Sijn. Betulina. A substance discovered by Lowitz, in the bark of the white birch, (the betula alba.) It is obtained under the form of white crystalline needles, soluble in ether, alcohol, oil, and acids. It is fusible, volatile, and inflammable. BEZOARS. Preternatural concretions found in the stomach and intestines of some animals, form- erly supposed to possess alexipharmic powers, and were both taken internally and worn as amulets. They have now, however, sunk into disuse, and though ordered in the preparation of Gascoigne's ball and powder, a factitious kind is substituted. The name bezoar was formerly extended to vari- ous other substances supposed to possess similar virtues. BEZOARS, FACTITIOUS. Prep. Make tobacco-pipe clay into a paste with ox-gall, and add a little hair or wool; then form into shapes. Remarks. This will give a yellow tint to paper, rubbed with chalk, and a green one to quicklime, which tests are considered as proof of genuine bezoars. BEZOAR, MINERAL. Powder of algaroth deflagrated with nitre in a red hot crucible, and then well washed with water. Once used in doses of 5 to 15 grs. as a diaphoretic, but now obsolete. According to the mode by which the powder of algaroth was made, arose the names bezoardicum joviale and bezoardicum martiale, also applied to this preparation. BEZOAR, ARGENTINE. Syn. Bezoardi- cum LuNAitK. Made by distilling a mixture of but- ter of antimony* and nitrate of silver. Once given in epilepsy and head diseases, in doses of 6 to 12 grains. BEZOAR OF LEAD. Syn. Bezoardicum Saturni. Made by distilling a mixture of oxide of lead, butter of antimony, and nitric acid. Once given in doses of 5 or 6 grs. in diseases of the spleen. BHAURTA, (in Cookery.) An Indian dish made with mashed potatoes, onions, and capsicum, moulded into a shape and slightly baked. BIBROMISATINE AND BROMISATINE. These are formed by the action of bromine on isa- tine. Treated with potassa, they yield acids of the same names. BIC ARBONATES. Combinations of the bases with the carbonic acid, in which two atoms of the latter are united to one of the former. The follow- ing are the principal bicarbonates. BICARBONATE OF POTASSA. Syn. Aer- ated Kali. Prep. There are two methods of preparing this salt: one, by passing a stream of carbonic acid through a solution of the carbonate of potassa ; the other, by the addition of sesquicar- bonate of ammonia. The processes of the London and Edinburgh colleges offer an example of each. I. a. (Process of the L. Ph.) Ing. Carbonate of potassa lb. vj; distilled water 1 gallon. Proc. Dissolve the salt in the water, and pass carbonic acid gas through the solution, to saturation ; apply a gentle heat to redissolve any crystals that may have, been deposited, then set the liquor aside to crystallize; lastly, pour off the liquid and dry the crystals. *** The carbonic acid may be obtained from chalk or whiting, rubbed up with water to the con- sistence of a sirup, upon which oil of vitriol, diluted with an equal weight of water, is to be poured. b. (Process at Apothecaries' Hall.) Ing. Car- bonate of potassa 150 lbs.; distilled water 17 gal- lons. Proc. Dissolve 100 lbs. of the carbonate in the water; then saturate with carbonic acid gas as last, when 35 to 40 lbs. of crystals of bicarbonate of potassa may be obtained. The remaining 50 lbs. of the carbonate are now dissolved in the mother liquor, and enough water added to make it up a second time to 17 gallons, the remaining part of the operation being performed as before. This plan may be repeated again and again. Remarks. The following plan has been proposed as a substitute for the preceding process, but does not produce a pure salt. Dissolve pearlash in wa- ter ; add bran or sawdust, to soak up the liquor; put it into a crucible, lute on the cover, and heat it to redness; cool, wash out the salt, evaporate, and crystallize. Repeat tho process with the re- maining liquor. Yields a very imperfect salt. II. (Process of the Ed. Pharm. Cartheuser's Process.) a. Carbonate of potassa 6 oz.; sesquicarbonate of ammonia 3£ oz. Proc. Triturate together, and when reduced to a very fine powder and perfectly mixed, make them into a stiff paste with water. Dry this very carefully at a heat not higher than 140° Fahr. until a fine powder, perfectly devoid of ammoniacal odor, be obtained, occasionally tri- turating the mass towards the end of the process. b. (Process of Henry and Guibourt.) Dissolve 500 parts of pure carbonate of potassa in 1000 parts of water; filter, if necessary, and place the fluid in a porcelain capsule; rtt in a salt-water bath, BIC 112 BIL and add gradually 300 parts of sesquicarbonate of ammonia. Slightly agitate the liquor until ammo- niacal fumes are perceived; then filter over a heated vessel, and set it aside to cool. Remarks. The process recommended by Gei-rer is similar to the last, but the proportions are 1 lb. of carbonate of potassa and 1 lb. 6 oz. of sesquicarbonate of am- monia. Prop. Use, <$-c. It is soluble in 4 times its weight of water at 60° ; is fixed in the air, but decom- posed into a carbonate at a red heat. It possesses the general alkaline properties of carbonate of po- tassa, but in an inferior degree. It is much used as an antacid, and for making effervescing saline draughts. The dose is from 10 grains to £ a drachm. 20 grs. bicarbonate of potassa in crystals 14 grs. of crystallized citric acid ; 15 grs. " tartaric acid; and £ oz. of lemon juice. Pur. and Tests. A solution of corrosive subli- mate merely causes an opalescence, or very slight white precipitate in a solution of this salt; if it contains carbonate of potassa a brick-colored pre- cipitate will be thrown down. In other respects it may be tested like the carbonate, which see. BICARBONATE OF SODA. Syn. Aerated Soda. This is prepared in a similar way to the bicarbonate of potassa. I. a. (Sesquicarbonate of Soda, P. L.) Ing. Carbonate of soda, lb. vij.; water 1 gallon. Proc. Dissolve and pass carbonic acid through the solu- tion, in the same way as in making the bicarbonate of potassa. b. Dissolve 160 lbs. of carbonate of soda in 13 gallons of water, and pass carbonic acid through the solution. The bicarbonate falls down to the amount of about 50 lbs., and may be collected and dried by pressure in an hydraulic press. A fresh portion of soda may be then dissolved in the mother liquor, and the whole process repeated as before. (Brande.) c. Mix together 1 part of carbonate of soda, with 2 parts of dried carbonate of soda, both in powder, and surround them with an atmosphere of carbonic jcid gas, under pressure. Let the action go on till no more gas is absorbed, which will generally oc- cupy 10 to 14 hours, according to the pressure em- ployed, then remove the salt and dry it at a heat not above 120°. This process is a modification both of that of the Edinburgh Pharmacopoeia and that of Mr. Smith, described in the Philadelphia Pharmaceutical Journal. Smith, however, em- p'oys the salt in crystals. In Scotland the method just described has been adopted with perfect suc- cess, and I can, from my own experience, bear testimony to its efficiency. Remarks. A crude sesquicarbonate of soda has been prepared as follows: Calcine carbonate of soda with bran, as in making bicarbonate of po- tassa ; wash out the 6alt and crystallize: very in- ferior. II. Ing. Carbonate of potassa and water, of each 1 lb.; carbonate of ammonia \ lb. Proc. Dissolve the carbonate in the water, then add the ammonia, and drive off the ammoniacal fumes at a heat under 120° ; lastly, set the solution aside to crystallize. Remarks. The above are nearly the proportions of the P. L. of 1809. Winckler, however, directs 80 of carbonate of soda, 3 of car- bonate of ammonia, and 20 of water ; and Henry and Guibourt order 6 parts of the soda, 2 of the ammonia, and 4 of water. The processes I. b and 1. c are those adapted for commercial purposes. Prop., Use, Sf-c. These are very similar to the carbonate of soda, but it is more feebly alkaline. It loses a part of its acid by heat. The dose is from 10 to 40 grains, as an antacid and absorbent It is largely employed in the preparation of effer. vescing powders and draughts, for which purpose 20 grs. of commercial bicarbonate of soda »______.--------------------y-------------------------J are taken with either ,----------'----;--;---^ 18 grs. of crystallized tartaric acid; 17 grs. of crystallized citric acid ; or \ oz. of lemon juice. Tests and Pur. Dissolved in 40 parts of wa- ter it does not give a reddisA precipitate with a so- lution of corrosive sublimate. (P. E.) It is totally dissolved in water ; neither chloride of platina nor sulphate of magnesia throws down any thing from this solution. It is converted into the anhydrous carbonate by heat. (P. L.) The quantity of bi- carbonate any given sample contains may be pretty nearly ascertained by well washing 100 grains of the salt with an equal weight of water, and filtering the solution. The residuum left upon the filter, dried at a heat of 120° and weighed, will give the per centage of bicarbonate of soda present, (very nearly.) Dissolved in water this will give only a trifling white precipitate, with cor- rosive sublimate, as described above, while the filtered portion, which was used to wash the salt, will give a red one, if it contains the simple carbon- ate of soda. BICE, BLUE. The native blue carbonate of copper, prepared by grinding and washing. Use. As a pigment. BICE, GREEN. The native green carbonate of copper, prepared as above. Use. As a pigment. BILE, BILIOUSNESS. Treat, $c. Persons subject to bilious attacks should be particularly careful to avoid excess in eating and drinking, and should especially avoid using those articles of food which, from experience, they find to disagree will them. A mutton chop under-cooked is an excel- lent article for the breakfast or lunch of a bilious patient; and mutton or beef, either broiled or roasted, so that the gravy be retained, is better for dinner than many articles apparently more deli- cate. These, with game and venison, form a good variety from which to choose a bill of fare. New beer and porter should be particularly avoided, at well as puddings and most articles of pastry, as they are very indigestible. Hard cheese, butter, unripe fruit, and especially beans, peas, and nuts, are also objectionable. An attack of bile may frequently be prevented by the use of a saline pur- gative, and it may generally be removed by an emetic, followed by a dose of castor oil, epsoru salts, or seidlitz powders BILLS OF FARE. (In cookery and domes- tic economy.) Lists of the various articles of diet, either actually provided for use, or, beinu in sea BIL 113 BIR son, are procurable for that purpose. The follow- ing bills of fare, for which I am indebted to " The New System of Codfcery," published by Mr. Murray, exhibits at a glance the various articles in season at different periods of the year, and which are usually found at those times upon the greater number of well-provided tables. Bills of Fare for Family Dinners, &c, containing a list of various articles in season in different months of the year: First Quarter. January.—Poultry: Game, pheasants, partridges, hares, rabbits, woodcocks, snipes, turkeys, capons, pullets, fowls, chickens, tame pigeons. Fish : Carp, tench, perch, lam- preys, eels, cray-fish, cod, soles, flounders, plaice, turbot, thornback, skate, sturgeon, smelts, whit- ings, lobsters, crabs, prawns, oysters. Vegetables : Cabbage, savoys, colewort, sprouts, leeks, onions, beet, sorrel, chervil, endive, spinach, celery, gar- lic, scorzonera, potatoes, parsnips, turnips, brocoli, (white and purple,) shalots, lettuces, cresses, mus- tard, rape, salsafy, herbs of all sorts, dry and some green ; cucumbers, asparagus, and mushrooms to be had, though not in season. Fruit: Apples, pears, nuts, walnuts, medlars, grapes. February and M'irrh. Meat, fowls, and game, as in January, with the addition of ducklings and chickens; which last are to be bought in London most if not all the year, but very dear. Fish : As the last two months, except that cod is not thought so good from February to July, but may be bought. Vegetables: The same as the for- mer months, with the addition of kidney-beans. Fruits: Apples, pears, forced strawberries. Second Quarter. April, May, and June.— Meat: Beef, mutton, veal, lamb, venison, (in June.) Poultry: Pullets, fowls, chickens, duck- lings, pigeons, rabbits, leverets. Fish: Carp, tench, soles, smelts, eels, trout, turbot, lobsters, chub, salmon, herrings, cray-fish, mackerel, crabs, prawns, shrimps. Vegetables: As before; and in May early potatoes, peas, radishes, kidney- beans, carrots, turnips, early cabbages, cauliflow- ers, asparagus, artichokes, all sorts of salads forced. Fruit: In June ; strawberries, cherries, melons, green apricots, currants and gooseberries for tarts ; pears, grapes, nectarines, peaches, and s<^tne other fruit; but most of these are forced, and conse- quently very dear. Third Quarter. July, August, and Septem- ber.—Meat as before. Poultry: Pullets, fowls, chickens, rabbits, pigeons, green geese, leverets, turkey poults. Two former months plovers, wheat- eaters ; geese in September. Fish : Cod, had- dock, flounders, plaice, skate, thornback, mullets, pike, carp, eels, shellfish, except oysters, mackerel the first two months of the quarter, but not good in August. Partridge shooting begins the 1st of September; what is used before is therefore poached. Vegetables : Of all sorts, beans, peas, French beans, &c, &c. Fruit: In July ; straw- berries, gooseberries, pine-apples, plums, various ; cherries, apricots, raspberries, melons, currants, damsons. In August and September; peaches, plums, figs, filberts, mulberries, cherries, apples, pears, nectarines, grapes. Latter months, pines, melons, strawberries, medlars, and quinces; in the latter month, Morella cherries, damsons, and various plums. 15 Fourth Quarter. October, November, and De- cember.—Meat as before, and doe venison. Poul- try and Game: Domestic fowls as in former quarters ; pheasants from the 1st of October ; par- tridges, larks, hares, dotterels; the end of the month wild-ducks, teal, snipes, widgeon, grouse. Fish : Dories, smelts, pike, perch, halibuts, brills. carp, salmon-trout, barbel, gudgeons, tench, shell- fish. Vegetables: As in January, French beans, last crop of beans, &c. Fruit: Peaches, pears, figs, bullace, grapes, apples, medlars, damsons, fil- berts, walnuts, nuts, quinces, services, medlars. In November—Meat: Beef, mutton, veal, pork, house lamb, doe venison, poultry and game as the last month. Fish : As the last month. Vegeta- bles : Carrots, turnips, parsnips, potatoes, skirrets, scorzonera, onions, leeks, shalots, cabbage, savoys, colewort, spinach, chard-beets, chardoons, cresses. endive, celery, lettuces, salad-herbs, pot-herbs. Fruit: Pears, apples, nuts, walnuts, bullace, ches- nuts, medlars, grapes. In December—Meat: beef, mutton, veal, house lamb, pork, and venison. Poultry and Game : Geese, turkeys, pullets, pi- geons, capons, fowls, chickens, rabbits, hares, snipes, woodcocks, larks, pheasants, partridges, sea-fowls, guinea-fowls, wild-ducks, teal, widgeon, dotterels, dun-birds, grouse. Fish : Cod, turbot, halibuts, soles, gurnets, sturgeon, carp, gudgeons, codlings, eels, dories, shellfish. Vegetables: As in the last month. Asparagus forced, &c. Fruit : As the last, except bullace. BIRCH SUGAR. Prep. This is prepared from the juice procured by boring a hole in the trunk of the birch tree, under one of the largest branches, carrying it quite through the wood to the bark on the opposite side. The juice that flows from the wood is collected in suitable vessels, and after mixing with a little chalk and clarifying with white of e a P'ut of boiled oil; mix well, remove it from the fire, and when nearly cold, add J pint of spirit of turpentine ; mix well together. Use. To varnish metals. BLACK, IVORY. Syn. Cologne Black. Cassel Black. Prep. Put into a crucible, sur- rounded by burning coals, fragments or turnings of ivory, or of the osseous parts of animals, and cover it closely. The ivory or bones, by exposure to the heat, will be reduced to charcoal. When no more smoke is seen to pass through the joining of the cover, leave the crucible over the fire for half an hour longer, or until it has completely cooled, There will then be found in it a hard carbonaceous matter, which must be pounded and ground on por- phyry with water, washed on a filter with warm water, and dried. Before it is used it must be again subjected to grinding. Remarks. Black furnished by bones is reddish. That produced by ivory is more beautiful. It is brighter than black obtained from peach stones. When mixed in a proper dost with whitelead, it forms a beautiful pearl gray Ivory-black has a very deep and rich color. Th( Cologne and Cassel blacks are formed from ivory. BLACK, LAMP. Prep. I. Suspend over a lamp a conical funnel of tin plate, having above it a pipe to convey from the apartment the smoke which escapes from the lamp. Large mushrooms, of a very black carbonaceous matter, and exceed- ingly light, will be formed at the summit of the cone. This carbon is reduced to such a state of division, as cannot be given to any other matter, by grinding it on a piece of porphyry. This black goes a great way in every kind of painting. It may be rendered less oily and drier by calcination in close vessels. The funnel should be united to the pipe, which conveys off the smoke, by means of wire, because solder would be melted by the flame of the lamp. II. This article was originally prepared by burn- ing oil in lamps and collecting the soot in a funnel inverted over it, as above described. Hence the name. It is now, however, generally made on the commercial scale, by burning the oil of bones or common coal tar, previously freed from its ammo- nia, and receiving the smoke in a suitable cham- ber. In the patent process of Messrs. Martin and Grafton, the coal tar is violently agitated with lime water, until the two are well mixed, after which it is allowed to subside, and the lime water being drawn off, it is washed several times with hot wa- ter. After the whole of the water has been re- moved by subsidence and decantation, it is put into stills, and heat applied until the impurities have passed over, and the spirit runs clear and smooth. The receiver is then charged, and the heat raised sufficiently high to drive over the whole of the oil BLA 119 BLA and spirit, leaving only the asphaltum in the still. The tar or liquor in the receiver is then put into a long cast-iron tube, furnished with numerous large burners, underneath which is a furnace to heat the pipe to nearly the boiling point. Over each burner is a sort of funnel, which goes into a cast-iron pipe or main, and which receives the smoke in a similar way from all the burners. From this the smoke is conveyed by large pipes to a box, where the heaviest part of the black is deposited ; from this it is carried by pipes to a second box, where another deposite takes place, and from this box the pipe is continued until it passes into a series of large canvass bags, arranged side-by-side, and connected together at top and bottom alternately. Fifty or eighty of these bags are employed, the last one being left open to admit of the escape of the smoke, which has thus been made to traverse a space of about 400 yards. As soon as the bags contain any considerable quantity of black, they are re- moved and emptied. The black deposited in the last bag is the finest and best, and it becomes pro- gressively coarser as it approaches the furnace. BLACKLEAD. Syn. Plumbago. Carburet of Iron? Qual. Use, #c. The best blacklead comes from Cumberland, and is used for making pencils for artists. The coarser sorts are employed to impart a metallic lustre to other bodies, and mix- ed with grease to diminish friction. Blacklead is also used to cover the face of articles on which it is desired to deposite a coating of copper by the elec- trotype. It has been used in herpes, and some chronic skin diseases, in the form of an ointment, made with 4 times its weight of lard. BLACK, PEACHSTONE. The stones or ker- nels of peaches, cherries, and other similar kinds of fruit, burned in close vessels, then ground' and washed well. Use. It works well with oil; mixed with white lead and oil it makes old gray. BLACK, PITCOAL. The best coal for this purpose is that which has a shining fracture. It affords, perhaps, the most useful brown the artist can place on his palette ; being remarkably clear, not so warm as Vandyke-brown, and serving as a shadow for blues, reds, or yellows, when glazed over them. It seems almost certain that Titian made large use of this material. Coal, when burn- ed to a white heat, then quenched in water, and ground down, gives an excellent blue-black. BLACK REVIVER. Syn. Paris's Anticar- dium. Prep. I. Blue galls, bruised, 4 oz.; log- wood, copperas, iron filings, and sumach, of each 1 oz.; vinegar 1 quart. Proc. Macerate in a close vessel, with heat, for 24 hours, then strain off the clear, add the filings and copperas, and shake it oc- casionally for a week. Keep it in a corked bottle. II. Bruised blue galls 1$ lbs.; logwood J lb.; copperas 6 oz.; vinegar 1 quart; water 3 quarts. As above. III. Galls 1 lb.; logwood 2 lbs.; copperas $ lb.; boil for 2 hours in water 5 quarts, until reduced to a gallon, and strain. Use. To restore the color of black cloth. BLACK, RUSSIAN. Syn. Russian Lamp- Black. Prepared by burning the chips of resin- ous deals, and collecting the black matter deposited by the smoke. It is a good black pigment, but apt to take fire spontaneously if left for some time moistened with oiL BLACK, RICE. Prepared by burning rice in close vessels. The color is very poor. BLACK, SPANISH. Syn. Cork Black. Cork burnt in close vessels, and the charcoal ground and washed with water. A good color, and works very soft. BLACK, SOOT. The soot of coal fires, ground and sifted. Used as a common paint; mixed with Venetian red and oil, it makes a chocolate color; also used to make gray mortar. BLACK, SUGAR. Syn. Jamaica Black. Prepared by burning sugar in close vessels. It works free, but is deficient in body. It is a warm color for washing drawings, and equal in mellow- ness to Indian ink and bistre. BLACK, VINE TWIG. Prep. From vine twigs, by calcination as above. With whitelead and oil it produces beautiful shades of silver gray and white. BLACK, WHEAT. From wheat burnt in close vessels. Remarks. A superior black, be- tween ivory and lamp-black; it has a full body and dries hard and quickly with oil. BLADDERS. Prep. $c. These articles are prepared by cutting off the fat and loose mem- branes attached to them, and washing them first in a weak solution of chloride of lime, and after- wards in clear water ; they are then blown out and submitted to pressure by rolling them under the arm, by which they become considerably larger; they are next blown quite tight, dried, and tied up in dozens for sale. Use. Employed by druggists and oil and colormen to tie over pots, bottles, and jars, and to contain pill masses, and other similar substances. Caution. Never buy bladders unless they are perfectly dry and tight, as, if the reverse be the case, they will neither keep nor prove sound. BLANCHING OR WHITENING. An oper- ation in cookery, performed by putting tongues, palates, meat, &c, into cold water, when it is gradually brought to boil, and the article taken out and plunged into cold water, where it is left until quite cold. It is intended to impart whiteness, plumpness, and softness. BLANC, (in Cookery.) A compound, formed by mixing 1 lb. of grated bacon, 1 lb. of suet, £ lb. of butter, 2 lemons, 3 or 4 carrots cut into dice, 3 or 4 onions, and a little water, and boiling them until done, BLANCMANGE, (in Cookery.) Jelly, sea- soned and made up into forms. Prep. I. Isin- glass 1 oz.; sweet almonds, 12 in no.; bitter do. 6 in no.; milk 1 quart. Proc. Boil the isinglass and almonds grated in the milk, until of a proper consistence when cold; then strain it, and when nearly cold pour it into the moulds, previously rubbed with a little salad oil, and then wiped out again. II. To the above add \ lb. of lump sugar and 4 tablespoonfuls of cream ; when cold, remelt it and add a tablespoonful of orange flower water, after which it may be moulded as before. III. Use calves' feet jelly instead of isinglass. IV. (Mrs. Hoffman's.) Isinglass \ lb.; rose- water \ pint; milk 2 quarts; milk of almonds j pint. V. (Rice.) Ground rice 2 oz.; milk 1 pint; lump sugar 3 oz.; a little lemon peel and cinnamon ; dis- solve the rice in the milk by boiling; reduce it to a BLE proper consistence, then add the spice and sugar, boil for 1 minute, and strain, and when nearly cold mould as above. Caution. The powdered rice must be rubbed up with a little cold water pre- viously to adding it to the milk, to prevent it run- uing into lumps. VI. (West Indian.) Make a jelly with arrow- root, and to every pint, when nearly cold, add a glass of sherry, a spoonful each of brandy and orange flower water, and 2 oz. of lump sugar. Vll. (Transparent.) Instead of milk use water, and clarify with the white of an egg. BLANQUENINE. A name given by Dr. Mills to a uew vegetable alkali, which he thought he had discovered in white cinchona bark. (Quar. Jour. Science, Ap. 1828.) BLANQUETTE, (in Cookery.) A sort of white fricasee. BLEACHING. Syn. Blanchissage. (Fr.) Bleichk.n. (Ger.) The operation by which the natural colors of substances are discharged, and they become white or colorless. Bleaching may be performed either by natural means, as exposure to light, air, and moisture, or by chemical agents, as chlorine, chloride of lime, sulphurous acid, &c. In many of the processes adopted for this purpose, both methods are combined. The most important application of the art of bleaching in the United Kingdom, is in the manufacture of textile fabrics. The celerity with which this is performed in the most perfect manner, and the trifling expense thereby incurred, contribute, in no small degree, towards inducing that preference universally shown to the productions of the looms of Great Britain. Cotton, from its original whiteness, and little at- traction for coloring matter, is more easily bleached than most other substances. On the old plan, it is first well washed in warm water to remove the weaver's paste or dressing, then " bucked" (boiled) in a weak alkaline lye, and after being well washed is spread out upon the grass, or bleaching ground, and freely exposed to the joint action of light, air, and moisture. The operation of " bucking" and exposure is repeated as often as necessary, when the goods are " soured" or immersed in water acid- ulated with sulphuric acid, after which they re- ceive a thorough washing in clean water, and are dried. From the length of the exposure upon the bleaching ground, this method has been found to injure the texture of the cloth, and from the num- ber of operations required, necessarily becomes ex- pensive, and produces considerable delay; it has therefore very generally given place to the improved system of chemical bleaching, by means of chloride of lime. In this method, after the first operation of washing and bucking, as in the common process, the cotton is submitted to the action of weak solu- tions of chloride of lime, and afterwards passed through soured water, when it has only to be tho- roughly washed and dried. Linen is bleached in a similar way to cotton, but the operation is more troublesome, from its greater affinity for coloring matter. Wool is first exposed to the joint action of ful- ler's earth and soap, in the fulling mill, to remove adherent grease and dirt, and is then well washed and dried, when it is usually found sufficiently white for the purposes of the dyer; but should the ■light yellow tint it retains prove objectionable, it is BLE run through water tinged blue with indigo, or it ii exposed to the fumes of burning sulphur ; the latter method gives it a harsh feel, which is best removed by a bath of soap and water, but this will repro- duce its previous yellowishness. Silk is bleached by boiling it in white soap and water, to remove the natural yellow varnish that covers it, after which it is subjected to repeated rinsings. Articles that are required to be very white, as gloves, stockings, &c, are also submitted to the action of sulphurous acid, or the fumes of burning sulphur. Straw is also bleached by the fumes of sulphur; hence arises the sulphurous smell emitted by new straw hats and bonnets. They may, however, be bleached in a much better manner by the use of a little oxalic acid, or chloride of lime. Old Rags, for the manufacture of paper, and paper pulp, are generally bleached with chlorine. Printed Books, Engravings, &.c, may be whi- tened by first subjecting them to the action of weak chloride of lime water, next to water soured with sulphuric acid, and, lastly, to pure water, to re- move any adhering acid or chlorine. Remarks. The theoretical principles of bleach- ing are but little understood; it is thought 'o de- pend upon the action of oxygen, in a nascent state, on the particles of coloring matter, but this is un- supported by direct experiment. It is, however, an art eminently indebted to chemistry for its pres- ent efficiency, and is based on the practical appli- cation of facts which that science has called to light. BLEEDING FROM THE NOSE. When this occurs under common circumstances, and without violence, it may be regarded as a natural effort to relieve the body from an excess of blood; but when it becomes habitual, or is the result of violence, remedial measures should be had recourse to. A simple means of arresting the haemorrhage is to introduce, by means of a probe, a small piece of lint or soft cotton, previously dipped into some mild styptic, as a solution of alum, white vitriol, or creosote, or even cold water. This will generally succeed, but should it not, cold water may be snuffed up the nostrils, or a small piece of ice placed in the nose. Should the bleeding be very profuse, or persistent, medical advice should be had recourse to. I once saw a person (an inn- keeper) lose his life in the course of a few days from a voluntary haemorrhage from the nose, which it was found impossible to stop or lessen. A plan has been lately proposed by Dr. Negrier, of Angiers, which, he says, is simple and certain. "It is preferable to the occlusion of the nostrils, as that is difficult to maintain, especially in sleep. During three years that, in numerous cases, he has tried this method, which is simply elevating the patient's arm, he has never found it to fail. After detailing several cases, he thus explains the ra- tionale of the plan. When the person is standing with the arms at the side, the blood which escapes from the upper part of the arch of the aorta, takes two directions, viz., towards the head, and towards the arms, and that which goes to the head is al- most equal in quantity to that which is received by both superior extremities. If, however, the individual who was formerly hanging his arms, raised them, the blood which was flowing horizon- U BLI 121 BLO tally and without effort from the subclavian into the brachial arteries, must then ascend against the weight of the column of blood contained in the latter; and as there is nothing in the act of raising the arm to increase the force of the circulation, it follows, that part of the force formerly expended in sending the blood up the carotids, must now be subtracted, and added to that which drives it through the brachial arteries. This explanation may or may not be confirmed by experiments. The subject is worth investigation." (Archives generates de Medecine. June, 1842.) BLENORRHCEA. An increased discharge of mucus from the urethra or vagina. Treat Ad- minister mild aperients and tonics. Cold bathing, and general habits of cleanliness, powerfully pro- mote a cure. BLIND, WRITING FOR THE. If an iron style or pencil, with a moderately fine point, be used to write with upon paper, and a little more pres- sure be employed than in using a common pen, characters will be produced which may easily be read by blind persons after a little practice, by passing their fingers over them, either on the side on which they were written, where they will ap- pear in intaglio, or by reversing the paper, where they will appear in relief. BLISTER, EXTEMPORANEOUS. I. A piece of lint dipped into vinegar of cantharides, and immediately after its application to the skin, covered over with a piece of strapping, to prevent evaporation, will speedily raise a blister. II. Concentrated acetic acid, applied in the same way, will have a similar effect. III. The following method, proposed by Dr. Darcq, is very simple and convenient: Into a flat watch-glass, pour from 8 to 10 drops of very con- centrated ammonia ; cover the liquid with a small piece of linen, of a rather less diameter than that of the glass, and slowly apply this little apparatus to the previously shaved skin. Keep the whole in its place by means of moderate pressure with the fingers. As soon as a red ring, about 2 centimetres in breadth, is observed round the glass, it is certain that vesication is effected. Sometimes scarcely 30 seconds is necessary for obtaining this result. It remains only to remove the apparatus, to wash the part, and to tear away with a pair of nippers the epidermis, which comes off easily and in one piece. The dressing is according to the object in view, —to the indications of the endermic method, for example. (Bull, de Their. & Chem., No. L. 88.) BLISTER, LIQUID. Prep. I. Spanish flies 2 oz.; boiling water 1 pint; spirits of wine 4 oz.; corrosivo sublimate \ oz.; spirits of salts \ oz. Proc. Digest tho flies in the water, in a warm place, for 24 hours, then add the corrosive subli- mate, dissolved in the spirits of wine, and lastly, the spirits of salts. It may either be strained, or used as it is. II. Rectified spirit, and liquid ammonia, of each 2 oz.; oil of origanum 1 oz.; mix. Add finely powdered Spanish flies 1 oz. III. Strongest blistering plaster 2 oz.; oil of tur- pentine 1 oz.; mix with a gentle heat. IV. Linseed oil, resin cerate, and oil of turpen- tine, of each 2£ oz.; powdered flies 1 oz.; as above. Use. For horses and cattle. 16 BLISTER, PERPETUAL. A common blis- ter, raised in the usual way, but instead of allow- ing the surface to heal up, after the discharge of the water, it is kept open by dressing it with savine or cantharides ointment. BLISTERING TISSUE. Thin paper, or silk, spread over with a thin coat of alcoholic, acetic, or ethereal extract of Spanish flies. BLOOD, BULLOCK'S. This article is em- ployed for the clarification of wines and sirups ; in the preparation of adhesive cements ; coarse paint for out-door work ; as a manure ; as a bleaching powder; and for several other purposes. The blood of sheep, pigs, and bullocks, mixed with flour or oatmeal, and seasoning, is used as an ali- ment by the common people, but it is rather indi- gestible, and consequently cannot prove nourishing. BLOOD, POWDERED. Prep. Dry the blood, by free exposure in thin layers to a current of air, at a heat under 125°, until it becomes suf- ficiently dry to powder. Use. For exportation to the colonies, where it is Uted hi the sugar works. Remarks. Bullock's blood, dried at a temperature from 212° to 225°, and coarsely powdered, is much used by fraudulent dealers to adulterate musk. BLOOD, SPITTING OF. (See Hemop- tysis.) BLOOD, SPITTING OF. Popular Reme- dy for. Prep. Infusion of red roses 5J oz.; sirup of poppies ■} oz.; diluted sulphuric acid 20 drops; mix. Dose. One or two tablespoonfuls four times a day. BLOOM, ALMOND. Prep. Boil 1 oz. of ground Brazil wood in 3 pints of water, for 15 minutes, strain and add ^ oz. of isinglass, \ oz. of powdered cochineal, 1 oz. of alum, and \ oz. of bo- rax ; boil again for 3 minutes, or until the whole is dissolved, and strain through a piece of fine cloth. BLOWPIPE. An instrument by means of which the flame of a candle or lamp is directed upon any substance placed to receive it, which is thus subjected to an intense heat. The hottest portion of the flame produced by the action of the blowpipe, is at the tip of the out- er white flame, which has also the property of rapidly burning or oxidizing any substance placed in it, which is capable of such an action; hence it has been called the " oxidizing flame." The interior blue flame has also been called the " re- ducing flame," from the property it possesses of abstracting oxygen from most substances placed in it. App. " The substance to be submitted to the action of the blowpipe, must be placed on a piece of charcoal, or in a small spoon of platina, gold, or silver ; or, according to Saussure, a plate of cyanite may sometimes be used. Charcoal from the pine is to be preferred, which should be well ignited and dried, that it may not crack. The sides, not the ends, of the fibres must be used ; otherwise the substance to be fused spreads about, and a round bead will not be formed. A small hole is to be made in the charcoal, which is best done by a slip of plate iron bent longitudinally. Into this hole the substance to be examined must be put, in very small quantity; if a very intense heat is to be used, it should not exceed the size of I half a peppercorn. BLO 122 BLU " Metallic spoons are used when the substance to be examined is intended to be exposed to the ac- tion of heat only, and might undergo some change by immediate contact with the charcoal. W hen the spoon is used, the flame of the blowpipe should be directed to that part of it which contains the substance under examination, and not be imme- diately applied to the substance itself. The han- dle of the spoon may be inserted into a piece of charcoal; and if a very intense heat is re- quired, the bowl of the spoon may be adapted to a hole in the charcoal. Small portions may be taken up by platina forceps. Salts and volatile substances are to be heated in a glass tube closed at one end, and enlarged according to circumstan- ces, so as to form a small matrass." When the behavior of the substance has been observed in this way, it is melted with various fluxes, as microcosmic salt, borax, &c, and their action examined, both in the interior and exterior flame, by which means its composition may be generally ascertained, by reference to any work on mineralogy. Beginners are usually unable to maintain a con- tinual stream of air from the jet, which is, how- ever, very simple to accomplish. The operation depends upon a little artifice in blowing through the pipe, which is in reality more difficult to de- scribe than to acquire. " The effect intended to be produced is a continual stream of air for many- minutes, if necessary, without ceasing. This is done by applying the tongue to the roof of the mouth, so as to interrupt the communication be- tween the mouth and the passage of the nostrils; by which means the operator is at liberty to breathe through the nostrils, at the same time that by the muscles of the lips he forces a continual stream of air from the anterior part of the mouth through the blowpipe. When the mouth begins to be empty, it is replenished by the lungs in an instant, while the tongue is withdrawn from the roof of the mouth, and replaced again in the same manner as in pronouncing the monosyllable tut. In this way, the stream may be continued for a long time without any fatigue, if the flame be not urged too impetuously ; and even in this case no other fatigue is felt thai? that of the muscles of the lips." (Ure.) For producing extreme degrees of heat, the flame is blown with a jet of oxygen gas, and the instrument is then called an " oxygen blowpipe;" or a mixture of oxygen and hydrogen is burned, when it is called an " oxy-hydrogen" blowpipe. The heat produced by the last is so great that no substance can stand before it The most refrac- tory native compounds, as rock crystal, quartz, flint, chalk, plumbago, &c, are'-immedi.itely fused. Gold is volatilized, and iron is rapidly consumed the instant it is placed in the flame. To use this wonderful instrument with safety, and to prevent an explosion, a peculiarly constructed jet is re- quired. The principal blowpipes in general use are figured in the accompanying engravings. The shape of the common blowpipe adopted by the experimentalist may depend upon the fancy of its employer. This apparatus is also furnished with valves and springs. Beside the following there are several other va- ], Oxy-hydrogen blowpipe. 2, Black's do. 3, Bergman's do. 4, Pepy's do. 5, Wollaston's do. 6, Heniining's safety jet for the oxy-hydrogen ditto. a, Pipe conveying oxygen gas. 6, Do. do. hydrogen gas. c, Bnll stuffed with tine wire gauze. e, Jet, (internal diameter l-80th of an inch.) rieties of blowpipes, in which the air is expelled by the pressure of a column of water, (hence called " hydrostatic blowpipes,") or the flame blown with the vapor of boiling alcohol, (" spirit blow- pipe.") Use. The blowpipe is of most extensive appli- cation in qualitative analysis, especially of min- erals, and its use cannot be too highly recom- mended to the young chemist. For further information on this subject the reader is referred to Gahn on the Blowpipe; to Ure's Dictionary of Chemistry; to Campbell's Translation of Kobell's Instructions for the Dis- crimination of Minerals; and to the Chemist, iv. 462. BLUBBER. This substance, which is so plen- tiful on some parts of the coast of England, forms a very rich manure for pasture and arable land, when used at the rate of 1 ton to every 20 or 30 loads of mould, together with a chaldron of lime per acre. It must be well turned over, and after lying 3 or 4 months the land will be in prime con- dition. BLUE, CHARCOAL. Prep. Triturate car- bonized vine stalks with an equal weight of pot- ash, then put it into a crucible and place it over the fire, until the mixture ceases to swell, keeping it well stirred all the time ; next allow it to cool, dissolve it in water, and saturate the excess of alkali with dilute sulphuric acid; the liquid be- comes blue, and a dark precipitate falls down, which turns of a brilliant blue color when dried and heated. BLUE, COBALT. Prep. I. Dissolve Zaffre 1 lb. in } lb. of nitric acid, diluted with an equal weight of water, by digestion for some hours, evaporate nearly to dryness, then dissolve in warm water, filter and add a solution of phosphate of soda as long as any precipitate falls down *, col- lect this on a filter and wash it with cold water, then mix it while still moist with 8 times its weight of freshly precipitate hydrate of alumina, also well washed and still moist. Stir them to- gether until dry; lastly, expose the mixture to a cherry red heat in a crucible, after which cool the mass, and reduce it to a fine powder. II. Precipitate a solution of nitrate of cobalt as above, and proceed as before. III. Make a strong solution of neutral nitrate BLU 123 BOI of obalt, and mix it with pure moist alumina, then dry it and proceed as before. IV. Precipitate a solution of nitrate of cobalt with ammonia alum, collect the precipitate, wash, dry, and heat it to a cherry red as before. Use. A beautiful blue pigment, very perma- nent. BLUE, CHEMIC. Syn. Saxon Blue. Li- quid Blue. Sulphate of Indigo. Prep. I. Indigo 1 lb.; oil of vitriol 8 lbs. Proc. Put the acid into an earthenware pan, placed in a tub of water to keep it cool, and add the indigo, pre- viously reduced to fine powder, in small succes- sive portions, carefully stirring to prevent it heat- ing. When all the indigo has been added, cover up the vessel and let it stand for 4 hours, occa- sionally stirring it during the time; lastly, dilute it with an equal weight of water. II. Indigo 1 oz.; oil of vitriol 4 oz.; dissolve as before ; the next day add 1 oz. of dry potash ; let it stand a day longer, then dilute it with 12 oz. of water. Use. In dyeing greens and blues, either with- out preparation or with a mordant of alum and tartar. BLUE, CHINA. Syn. Royal Smalts. Prep. Grind together oxide of cobalt or zaff're, with an equal weight of potash, and 8 times its weight of feldspar. Then submit the mixture to fusion in a crucible. Use. To paint pottery, and as a pig- ment. BLUE, IRON. Prep. Precipitate a filtered solution of protosulphate of iron, with another of phosphate of soda. Collect the powder, wash and dry it. Use. A lively sky-blue. BLUE, MOLYBDENUM. Prep. Dissolve sulphuret of molybdenum in nitric acid, then add some tki filings and a little muriatic acid. After digestion for some time, pour off the clear and evaporate to dryness. Mix the powder thus ob- tained with moist hydrate of alumina, as in ma- king cobalt blue, and heat it to nearly a dull red. BLUE, MOUNTAIN. Carbonate of copper, mixed with earthy matter. BLUE, SAXON. Prep. Dissolve 1 oz. of sul- phate of iron and 8 oz. of alum in 1 gallon of water, then add simultaneously, separate solutions of prussiate of potash and common pearlash, un- til they cease to produce a precipitate; lastly, allow the liquid to deposite, decant the clear por- tion, wash the remainder well with water, and dry it. Or a solution of the sulphate of iron may be first made and precipitated with the prussiate of potash, and instantly mixed with the solution of alum and a solution of pearlash, added until it ceases to produce a precipitate. BLUE, SUPERB LIQUID. Prep. Put into a small matrass or common vial 1 oz. of pure Prussian blue reduced to powder, and pour over it from 1J oz. to 2 oz. of concentrated mur'atic acid. The mixture produces an effervescence and the prussiate soon assumes the consistence of thin paste. Leave it in this state for 24 hours, then dilute it with 8 or 9 oz. of water, and preserve the color thus diluted in a bottle well stopped. The intensity of this color may be lessened, if necessary, by new doses of water. If the whole of this mixture be poured into 1 quart of water, it will still exhibit a color sufficiently dark for wash- ing prints. BLUE, STONE. Syn. Fig Blue. Thumb Blue. Knob Blue. Crown Blue. Mecklen- burg Blue. Queen's Blue. Prep. Mix finely powdered indigo with starch paste until a proper color be produced, then make it into small lumps. II. Instead of starch use whiting and a little weak size. Z7se. Employed by laundresses to give a faint blue tinge to linen. BLUE DYE. Proc. First give the goods a mordant of alum, then rinse them well and boil them in a bath of logwood, to which a small quantity of blue vitriol has been added. II. Boil in a bath of logwood, then add 1 oz. each of tartar and verdigris to every pound of logwood employed, and boil again. III. Bilberries, elder-berries, mulberries, privet- berries, and several other vegetable blue sub- stances, may be used to dye blue as above instead of logwood. Remarks. By increasing the proportion of alum the color verges on purple, and by employing a little acetate of iron or green copperas, the darker shades are produced. Verdigris, blue vitriol, and alkalis turn it more on the blue, and a mordant of tin imparts a violet cast. None of these dyes, however skilfully managed, are so permanent as those produced with indigo and Prussian blue. (See Indigo, Prussian Blue, and Dyeing.) BOARDS, MARBLE, &c, TO TAKE OIL AND GREASE OUT OF. I. Make a paste with fuller's earth and hot water, cover the spots therewith, let it dry on, and the next day scour it off with soft or-yellow soap. II. Make a paste with soft soap, fuller's earth, and a little pearlash, and use it as above. III. Make a paste of fresh slaked lime, wa- ter, and pearlash, and use it as above. Remarks. Observe not to touch the last mixture with the finger, as it is very caustic unless it be largely di- luted with water. BOERHAAVE'S RULES FOR PRESERV- ING HEALTH. " Keep the feet warm ; The head cool; and The body open." These rules are very concise, and convey di- rections which, though valuable, are too often neg- lected. BOILING POINT. The boiling point of wa- ter may be raised considerably above 212° Fahr. by the addition of saline matter. Thus, 60 parts of dry acetate of soda added to 40 of water raise the boiling point to 256° Fahr., and 30 parts of muriate of soda added to 70 of water raise it to* 224 Fahr. As in practice, however, it proves in- convenient to employ a saturated solution for a bath, from the evaporation of the water continually inducing the salt to crystallize, it is usual to keep it considerably below that point. By means of such solutions the chemist is enabled to evaporate fluids and desiccate solids at any required temper- ature. The boiling point of baths containing dif- ferent salts may be seen below. BOL 124 BON Taiile of the Boilinir Points of several Saline So- lutions, abridged from the Table of Mr. T. Griffiths. (Jour. Science, xviii. 89.) Names of Salts. Dry Salt in 100. Acetate of soda, . . . Nitrate of soda, . . . Rochelle salt, .... Nitre,...... Muriate of ammonia, . Tartrate of potash, . . Muriate of soda, . . . Ditto,...... Muriate of lime, . . . Sulphate of magnesia, . Supersulphate of potash, Borax....... Phosphate of soda, . . Carbonate of soda, . . Muriate of baryta, . . Alum,...... Sulph^e of potash, . . Bitai trate of potash, Sulphate of soda, . . Remarks. From 5 to 9 degrees are usually lost by passing through the vessel, depending on its thickness and materials. The boiling point of water in glass vessels, under common circum- stances, varies from 212-54° to 215-6°, and in per- fectly pure and smooth glass vessels, water may be heated to 221° F. without boiling. (M. F. Marcet.) BOILS. Treat. When these appear, suppura- tion should be promoted by poultices of bread and linseed meal, to which a little 'fat or oil may be added, to prevent their getting hard. When poul- tices are inconvenient, exposure to the vapor of hot water, or the application of stimulating plas- ters, may be adopted instead. When sufficiently ripe, the matter should be evacuated, and the wound dressed with a little simple ointment spread on a piece of clean lint or linen. The diet may be full and liberal until the maturation of the tumor and the discharge of the matter, when it should be lessened, and the bowels opened by some saline purgatives, as salts or cream of tartar. When there is a disposition in the constitution to the for- mation of boils, the bowels should be kept regular, and tonics, as bark or steel, taken, with the fre- quent use of sea-bathing, if possible. BOLAS. Prep. Into 2 lbs. of flour pour f pint of warm milk, a small teacupful of yeast, and 6 eggs; make them into a dough, add 1 lb. of but- ter, by degrees, and let it rise for 1 hour, then mix . in 1 lb. o/ powdered sugar, and make the mass into cakes; put these into cups or tins previously well buttered, and ornament the top with candied or- ange or lemon peel ; lastly, bake them. BOLUS OF ALUM. Prep. Powdered alum and conserve roses, of each 15 grs.; sirup of or- ange peel or saffron to mix. Used in fluxes, &c. BOLUS OF MUSK. Prep. I. Musk 15 grs.; camphor 5 grs.; powdered gum 3 grs.; mix with sirup of saffron. Use. In convulsions and typhus fever. II. Musk and carbonate of ammonia of each 10 grs.; conserve of roses q. s.; to make a bolus, Use. Sometimes given every three hours in morti- fication accompanied with spasms. BOLUS, PURGING, (for Dogs.) Prep. Ja. lap and rhubarb, of each 15 grs.; ginger 1 grs.; soap 10 grs.; water q. s.; if this does not open the bowels, add aloes half a drachm, or 3 or 4 grs. of culomel. Use. In the distemper ; it must be pre-ceded by copious bleeding, and abstinence from food for a dav or a night. BOLUS OF SULPHATE OF ZINC. Prep. Sulphate of zinc 20 to 2.3 grs. ; conserve of roses q. s. to make a bolus. Use. As an emetic where poison has been taken, to be followed by copious draughts of warm water or weak tea. BOLETIC ACID. An acid discovered by Bracounot in the juice of the boletus pseudo-ignia- rius. Prep. Concentrate the expressed juice to a sirup by means of a gentle heat, then digest it in strong alcohol, and dissolve the residuum in water ; add t solution of nitrate of lead as long as any precipitate falls, which must be washed with water, diffused through water in a tall glass vessel, and in this state a current of sulphureted hydrogen must be passed through it, until the lead is thrown down; filter, evaporate, and crystallize ; lastly, purify by resolution and crystallization from alcohol. Remarks. This acid dissolves in 45 parts of al- cohol and 180 of water, and is volatile. It is doubt- ful whether it be a distinct acid principle. BOLOGNA VIAL. The bologna, or philoso- phical vial, is a small vessel of glass which has been suddenly cooled, open at the upper end, and rounded at the bottom. It is made so thick at the bottom that it will bear a smart blow against a hard body without breaking; but if a little pebble, or piece of flint, is let fall into it, it immediately cracks, and the bottom falls into pieces; but un- less the pebble or flint is large and angular enough to scratch the surface of the glass, it will not break. BOLOGNIAN PHOSPHORUS. Syn. Bo- lognian Stone. This is a phosphorescent stone that once excited great attention. It was acci- dentally discovered by a shoemaker of Bologna in the 17th* century. A family of the name of Lo- gani, who were very successful in making it, ac- quired a large fortune by selling it to the curious throughout Europe. Prep. Powder native sulphate of baryta that has been previously ignited, and make it into a paste with mucilage of gum arabic ; roll this into pieces a quarter of an inch thick, and dry them in a moderate heat; then expose them to the heat of a wind furnace by placing them loose among the charcoal. Prop., Use, tyc. Placed in a vial and exposed for a few minutes to the sun's rays, it will give light enough in the dark to see the figures on the dial-plate of a watch. BOMBIC ACID. An acid which M. Chaus- sier extracted from the silkworm in 1781. It has since been found not to be a distinct acid. BON-BONS. Prep. Provide leaden mould* which must be of various shapes, and be oiled with oil of sweet almonds. Take a quantity of brown- sugar sirup in the proportion to their size, in that state called a blow, which may be known by dip- ping the skimmer into the sugar, shaking it, and BON 125 BON blowing through the holes, when parts of light may be seen ; add a drop of any esteemed essence. If the bon-bons are preferred white, when the su- gar has cooled a little, stir it round the pan till it grains, and shines on the surface ; then pour it into a funnel and fill the little moulds, when it will take a proper form and harden: as'soon as it is cold take it from the moulds; dry it for two or three days, and put it upon paper. If the bon- bons ure required to be colored, add the color just as the sugar is ready to be taken off the fire. BONES. The bones of animals are employed for various purposes in the arts, manufactures, and domestic economy. (See the succeeding articles.) BONE ASH. Syn. Impure Phosphate of Lime. Prep. Calcine bones to whiteness, and re- duce the ash to fine powder. Use. To make pure phosphate of lime, and to form cupels. It is sold for burnt hartshorn. BONE BLACK. Syn. Animal Charcoal. Ivory-Black. Bones burnt in close vessels. Prep. On the large scale, two different process- es are adopted to produce bone black. I. (From bones as the sole product.) The bones broken to pieces are put into small cast-iron pots of the shape of the engraving, and varying from j to £ an inch in thickness. Two of these being filled, are dexterously placed with their mouths together and then luted with loam. A number of vessels, thus prepared, are placed side by side and over each other, in an oven resembling a potter's kiln, to the number of 100 to 150. The fire is then kindled, and the heat kept up strongly for 10 or 12 hours, according to circumstances, until the process is completed. The whole is allowed to cool before opening the pots. II. (The residuum of the manufacture of Bone Spirit.) The bones are here introduced into re- torts similar to those used at the gas works, and boat being applied, the volatile products are con- veyed away by iron pipes to cisterns where its condensable portion is collected. As soon as the process of distillation is finished, the solid residuum in the retorts, while still red hot, is removed through their lower ends into wrought-iron canisters, which are instantly closed by air-tight covers, and luted over. 'These are then raised to the ground by a crane and allowed to cool. Remarks. Previously to distillation or calcina- tion, the bones are boiled for their grease, which is sold to the candle and soap makers. They are then sorted, the finest pieces being selected for making handles for knives, tooth-brushes, buttons, &c.; the next sort for making into bone black ; while the smallest and worst description is reserved for grinding into manure. The bones lose about $ their weight by the process of burning. After this they are ground in a mill, sorted by sieves into two kinds, one granular, somewhat resembling gun- powder, and the other quite fine. The one is sold under the name of animal charcoal, for decoloring liquors, the other as a pigment. This article pos- sesses tho valuable property of taking lime from sirups, at the same time that it decolors them. Its power as a decolorizer may be tested by adding it to a solution of brown sugar or molasses, or wa- ter containing T,r,Jnr part of indigo dissolved in sul- phuric acid. The test should be made in a small glass tube. By well washing and careful reburn- ing, this charcoal may be used any number of times as a decolorizer. BONES AND IVORY, DYES FOR. 1. (Red.) a. Make an infusion of cochineal in water of ammonia, then immerse the pieces therein, hav- ing previously soaked them for a few minutes in very weak aquafortis and water. 6. Boil the bones with 1 lb. of Brazil dust, in 1 gallon of water, for 3 hours, then add \ lb. of alum and boil for 1 hour more. 2. (Black.) a. Immerse i..e pieces in a weak solution of nitrate of silver, for a short time, then expose them to the sunlight. 6. Steep for 2 or 3 days, in a decoction made with 1 lb. of galls and 2 lbs. of logwood, then steep for a few hours in iron liquor, (acetate of iron.) 3. (Green.) a. Steep in a solution of verdigris to which a little aquafortis has been added. 6. Dissolve distilled verdigris in weak vinegar, and steep the pieces therein. c. Steep in a solution of 2 parts of verdigris, and 1 of sal ammoniac. Observe not to use a metallic vessel for the above. 4. (Purple.) a. Steep in a weak solution of terchloride of gold. 6. Boil for 6 hours in a decoction of 1 lb. of log- wood in ^ gallon of water, adding more water, as it wastes by boiling, then add 2 oz. of alum, and boil for 1 hour more. 5. (Yellow.) a. Boil for 1 hour in a solution made with 1 pound of alum in 1 gallon of water, then take out the pieces and steep them in a de- coction made with £ lb. of turmeric in 2 quarts of water; lastly, mix the two liquors and boil them therein for 1 hour. b. Steep the pieces for 24 hours in a solution of sugar of lead, then take them out, and when dry, immerse them in a solution of chromate of potassa. c. Dissolve as much of the best orpiment in wa- ter of ammonia or hartshorn, as it will take up, then steep the pieces therein for twenty-four hours; lastly, take them out and dry them, when they will turn yellow. Remark. By diluting the solu- tion with water, any shade of yellow may be made. 6. (Blue.) a. Stain them green, then steep them in a hot and strong solution of pearlash. b. Boil them in a strong decoction of logwood, and afterwards steep them in a solution of blue vitriol. c. Steep them for a sihort time in a weak solu- tion of sulphate of indigo, to which a little salt of tartar has been added ; or, still better, boil them in a dyer's green indigo vat. Remarks. The bones of living animals may be dyed by mixing madder with their food. The bones of young pigeons may thus be tinged of a rose color in 24 hours, and of a deep scarlet in 3 days; but the bones oLadiilt ani- mals take a fortnight to acquire a rose cfflor. The bones nearest the heart become tinged soeuest. In the same way extract of logwood will tinge the bones of young pigeons purple. (Mr. Gibson.) BONE GREASE. Prep. By bruising and boiling the refuse bones of the kitchen, and skim- ming the broth when cold, from \ (?) to \ of their BOO 126 BOO weight of good fat may be obtained, fit for culina- ry purposes when fresh, but always excellent for making soap and candles. (Proust.) BONE GLUE. Syn. Gelatine. Prep. This is made by dissolving out the earth of bones, pre- viously boiled for the grease, washing the remain- ing jelly with water, then boiling it with a little water, and forming it into cakes for sale. (See Glue.) BONE MANURE. For this purpose the bones arc ground to a coarse powder in a mill, and sowed along with the seed in a drill. It is said that wheat thus treated yields 30 to 50 per cent, more in weight of straw and grain than by the common methods. It is usually applied to light or turnip soils, which it renders more than ordinarily pro- ductive. Bone manure is much used in the west of Yorkshire, Holderness, and Lincolnshire. The usual quantity per acre is 70 bushels, when used alone ; but when mixed with ashes, as common manure of any sort, 30 bushels per acre is thought quite enough. It is applied at the same periods as other manure, and has been found in this way to remain 7 years in the ground. The rough part of this manure, after being 5 years in the ground, has been gathered off one field and thrown upon another of a different soil, and has proved, even then, good manure. BONES, (in Cookery.) The bones of good meat form most excellent materials for making soups and gravies, as is well known to every good cook. In France, soup is extensively made by dis- solving bruised bones in a steam heat of 2 or 3 days' continuance, and also by dissolving out the earthy part by digestion in weak muriatic acid, when a lump of gelatine is obtained, which after being well washed with water will dissolve by boil- ing, and is equal to isinglass for all the purposes of making soups and jellies. Proust has recommended the following process for making the best of bones, in hospitals, jails, and similar establishments:— Crush the bones small, then boil them for 15 min- utes in a kettle of water, cool, and skim the fat off, which varies from § to \ (?) of the weight of the bones employed, and when fresh is fit for all common purposes. The bones are then ground, and boiled in 8 to 10 times their weight of water, of which that already used must form a part, until } is wasted, when a very nutritious jelly is obtained. A copper vessel should not be used, as the jelly acts upon this metal. An iron Papin's digester is the most*suitable. The bones of boiled meat are nearly as productive as those of fresh meat, but roasted meat bones scarcely afford any jelly. (Dr. Young.) As boning meat before cooking is now a very general practice, a quantity of fresh bones may always be had. BONE SHAVINGS. Syn. Bone Dust. Bone Turnings. These yield a beautiful jelly by boil- ing with water, nearly equal to that produced from hartshorn shavings, for which they are very fre- quently sold. BOOKBINDING. The process of binding books may be divided into several distinct opera- tions, which, in large establishments, are usually performed by different persons, such a method being found to produce greater expedition and bet- ter work, than when the whole is done by one person. The sheets received from the hands of tho printei are— 1. Folded, which is done correctly by observing the marks or catchwords at the bottom of the pages. As the sheets are folded they are laid upon each other in proper order, and are ready to un- dergo— 2. The operation of beating. This is performed by laying them upon a large stone, and striking them with a heavy smoothed-faced hammer, or by passing them through a rolling press. The former method is usually adopted in the small way, and the latter on the large scale. 3. The sheets are next fastened to bands, which is done by taking the folded sheets up one by one, and sewing them to piec-?«i of cord, stretched in a little frame screwed or fastened to the counte' or table, called the sewing-pressi (See eng.) The C 3 number of bands used, is generally 6 for a folio, 5 for a quarto, and so on proportionally, less than 4 seldom being employed even for small sizes. The ends of the cords being cut off to within about 2 inches of the back, the sheets are ready for— 4. Glueing. The back being knocked into shape with a hammer, and the sheets placed in the cutting press, which is then slightly screwed up, melted glue is thinly and evenly applied. After a short time the book is removed from the precs, and the back properly adjusted with a hammer, when it is again put into the cutting pre. s, where it is screwed up very tight, and is then ready for— 5. Cutting. The instrument employed for this purpose is of a peculiar shape, and called a plough or plough-knife. 6. Affixing the boards. The bands are now scraped out fine at the ends, and the pasteboard to form the covers is fastened thereto, and is then properly adjusted, and shaped with a large pair of shears. The edges now undergo the operation of— 7. Sprinkling, or other adornment. The first is performed by a stiff brush of hog's bristles, dip- ped in the color; the brush being held in the one hand, and the hairs moved with the other. 8. The external covering of leather, fancy cloth, or paper, is now applied, having been pre- viously well soaked in paste, to make it properly adhere. One or more of the blank leaves of the book are next pasted against the inside of the cover, to screen the ends that are turned over, when the book is finished; or for choice work, is handed to a "finisher" for— 9. Lettering, gilding, <$-c. Gold-leaf is applied by means of white of egg, the pattern being givon by pressure with heated brass tools, having the design or letters on their surfaces. The whole il then glazed over and poljphed. Remarks. The succession of some of the above operations sometimes varies with the workmen and BOO 127 BOO the nature of the binding. The above must there- fore only be regarded as a short and general out- line of the process. If the reader will accompany the perusal by an examination of a bound book, the whole will be rendered quite familiar. The following varieties of binding may be notic- ed: a. Boards. A book, loosely done up without cutting the edges, and covered with paper or cloth, is said to be in boards. 6. Cloth-binding. This style of binding is that in which the majority of works are now issued. It admits of great neatness and even beauty, and is very durable and cheap. Proc. The prepared cloth, cut by a pattern to the size suited to the volume, is passed rapidly through a rolling press, between engraved cylinders of hardened steel, which print the pattern in relief. Paste is now applied to the cloth, when it is placed over the volume, previously prepared to receive it. Books in cloth-binding are not commonly cut at the edges, unless highly finished. c. Dutch binding. This species of binding is distinguished by the backs being of vellum. d. French binding. This consists in pasting a piece of parchment over the back of the book, be- tween each band, and pasting the ends upon the inside of each cover. e. Half-binding. Books forwarded in boards, and finished with leather backs and corners, are called " half-bound." f. Hancock's patent binding. In this method the sheets are folded in double leaves, and being properly placed together and adjusted, the book is subjected to the action of a press, and a strong so- lution of Indian rubber is smeared over the back with the finger. The operation is repeated, as often as necessary, when fil'ets of cloth are ce- mented on with the varnish, and the book is ready to have the boards attached. Thus several of the common operations of binding are dispensed with. I willingly bear testimony to the strength and durability of this method, and the great conve- nience it affords in allowing the books to open per- fectly flat upon a table, or to be distorted in any possible manner, without injury to their backs. It is the best way of binding books for travellers. I once had a large trunk of books, among which was one bound on Hancock's plan. All the rest were nearly torn to pieces by a few months' jour- ney, but this one was uninjured. g. Law binding. A strong method applied to law books. h. Leather binding. Proc. Immerse the lea- ther in water; after which wring it, and stretch it on a board; place the book with the boards extend- ed thereon, and cut out the cover, allowing about half an inch larger than the book, to turn over the inside of the pasteboards. Pare the edges of the cover very thin all round on a marble slab, and paste it well; glue the back of the book, and spread the cover on the board. Let the pasteboards be properly squared and even; put the book on the cover, which draw on very tight. Rub the" cover smooth with a folding- stick, and turn it over on the inside of the paste- boards on tho fore edge. The corners on the in- side must be cut and neatly pressed down; tie a piece of thread round the book, between the boards and head-bands, draw up the leather on the back, if necessary, to cover the top of the head-bands; rub the back very smooth with a flat folding-stick, and place it at a distance from the fire to dry. Rough calf must be damped on the grain side with a sponge and water before pasting and coverincr. Russia leather must be well soaked in water fo an hour, taken out, well beaten, and rubbed : afte- which the paste must be well worked into the flesi side before covering. Morocco must be grained by rubbing it on e board, with the grain side inside, and after being pasted, left to soak for a quarter of an hour, and the cover then drawn on with a piece of woollen cloth to preserve the grain. Roan may be either soaked in water or left to soak when pasted. i. Italian binding. This is a common variety of binding employed in Italy, (hence its name,) in which the books are covered with a kind of thick coarse paper. In Italy it is called " alia rustica." k. Marble binding. Named from the design of the exterior. I. Palmer's patent binding. This consists in applying small brass bars, linked together, to the back of the book, in such a manner that they make the different sections of the book, when open, parallel with each other, and thus admit of writ- ing, without inconvenience, on the ruled lines near the back. m. School binding. The following is a strong method for school books:—When the books have been cut, colored, and backed, cut off the part of the bands intended to be laced to the pasteboards, and glue on the back a piece of strong smooth linen cloth, which must reach within half an inch of the head and foot, turning on the sides about an inch ; paste the boards on each side of the cloth, fixing them close in at the groove, and give the books a firm pressing in the standing-press till dry. Square the boards, glue the backs, and cover and finish in the usual manner. This method will secure and give strength to the joints, so as effectually to prevent the leather from breaking, and require no more time than lacing in the bands. The edges may now be colored, sprinkled, or marbled, as required. n. William's patent binding. This consists in placing a back, of a curved form, turned a little at the edges, and made of iron, copper, brass, wood, ivory, or any other material of sufficient firmness. This back is adjusted to the book before it is bound, in such a manner that it may just cover, but not press upon the edges, and is fastened on by enclos- ing it in vellum or ferret wrappers, which are past- ed down upon the boards or drawn through them. The effect is, to make the book open evenly and free- ly, and to prevent it from spreading on either side. BOOTS, TO CLEAN. To do this in the best style always use " boot-trees," employ but little blacking, and brush it off while damp. The dirt should, of course, be carefully brushed off before applying the blacking. BOOTS AND SHOES, WATERPROOF COMPOSITION FOR. Prep. Boiled oil 1 pint; oil of turpentine, black rosin, and bees' wax, of each 3 oz. Proc. Melt the wax and rosin, then stir in th» oil, remove the pot from the fire, and when it has cooled a little, add the turpentine. BOR 128 BOR II. Take 3 oz. of spermaceti, and melt it in a pipkin, or other earthen vessel, over a slow fire ; add thereto 6 drachms of Indian rubber, cut into slices, and these will presently dissolve. Then add seriatim of tallow 8 oz.; hog's lard 2 oz.; amber varnish 4 oz. Mix, and it will be fit for use im- mediately. App. The boots or other material to be treated,.are xo receive two or three coats, with a common bladkiug brush, and a fine polish is the result. BOOT-TOP LIQUID. Prep. I. Oxalic acid and white vitriol of each 1 oz.; water 1£ pints. Proc. Dissolve and apply with a sponge to the leather previously washed with water, then wash the composition oft' with water, and dry. This liquid is poisonous. II. Mix in a vial, 1 drachm of oxymuriate of potass, with 2 oz. of distilled water; and when the salt is dissolved, add 2 oz. of muriatic acid. Then shake well together, mix in another vial 3 oz. of rectified spirit of wine with J an oz. of the essen- tial oil of lemon, unite the contents of the two vials, and keep the liquid, thus prepared, closely corked for use. This liquid should be applied with a clean sponge, and dried in a gentle heat; after which, the boot-tops may be polished with a pro- per brush, so as to appear like new leather. III. Sour milk 1 quart; gum arabic 1 oz.; juice of 2 lemons; white of 2 eggs; oil vitriol 2 oz. Mix. IV. Sour milk 1 quart; butter of antimony, cream of tartar, tartaric acid, and burnt alum, of each 2 oz. Mix. BORACIC ACID. Syn. Sedative Salt. Sed. Salt of Vitriol. Sed. Salt of Hom- berg. Prep. Dissolve borax in 4 times its weight of boiling water, then add sulphuric acid to the so- lution until it acquires a distinct acid reaction, (about i the weight of the borax.) As the solution cools, crystals of boracic acid will be deposited. These crystals must be then placed on a filter, and washed with a little cold water. They may be still further purified by solution in boiling water and recrystallization. Remarks. Even after this treatment, the crys- tals are apt to retain a little sulphuric acid or sul- phate of soda, which can only be got rid of by heating them in a platinum.crucible, before redis- solving them and crystallizing the second time, as above described. When wanted perfectly pure for chemical analyses, this plan must be always adopted. The boracic acid of commerce is extracted from the acid lagoons of Tuscany. Prep. As thus obtained, this acid is soluble in 25 times its weight of cold, and 3 times its weight of boiling water. Very soluble in alcohol, which then burns with a bright green flame, offering a sure test of the presence of boracic acid. Odor- less, and tastes bitter. Reddens litmus, but browns turmeric paper. It was once administered inter- nally in large doses, (by Cullen,) but is now scarcely ever employed as a medicine. BORATE. A compound, formed of the prece- ding acid and one of the bases. Prop. The boracic acid has but a feeble affinity for the bases; most of the borates being decom- posed by the stronger acids, the former being liber- ated in u free stats. Prep Many of them mav be formed by digestion of the hydrate of the base in a solution of the acid, with the assistance of heat, or by double decomposition. Tests. I. By digestion in slight excess of oil of vitriol, evaporating to dryness, powdering, and dis- solving in alcohol, the latter will acquire the pro- perty of burning with a green flame. II. If to a strong and a hot solution of a borate, sulphuric acid be added in excess, crystals of boracic acid will form as the liquor cools. BORATE OF MERCURY. Prep. I. Neu- tral borate of soda 265 grs.; calomel 222 grs.; grind together in a mortar, with a little water, then fill the mortar up with hot water ; collect the red precipitate ; wash and dry. II. Add a solution of borax to a solution of quick- silver in nitric acid. Collect the precipitate as be- fore. (White.) BORATE OF SODA. I. (Neutral borate.) Prep. Saturate boracic acid in solution with car- bonate of soda, at a boiling heat. (Berzelius.) II. (Biborate.) This salt, often erroneously call- ed borate and subborate, is the borax of commerce, and is a natural production. (See Borax.) BORAX. Syn. Biborate of Soda. Borate of Soda. Subborate of Soda. Refined Borax. Crude borax is a natural production, and after be- ing refined, forms a large portion of the borax of commerce. In its rough state it is called crude borax, tincal, tincar, &c. It is found crystallized on the edges and shallows of a brackish lake in Thibet, during the winter. It is also prepared by saturating the native boracic acid of Tuscany with soda. The market being literally overloaded with the former article, its price has fallen so low as to allow of its employment for this purpose with great advantage. A valuable paper on this subject, by M. Payen, appeared in the " Ann. de Chimie et de Phys." for July, 1841; and a translation of the same in " The Chemist," vol. ii. 363, to which the reader is referred for a complete account of this process. The best Tuscany boracic acid contains only 50 per cent, of real boracic acid, and yields no more than 140 to 150 per cent, of good borax. Prop., Use, See. It is extensively employed as a flux for metals, for soldering, and in medicine. In- ternally it is diuretic, sedative, emmenagogue, and cooling, in doses of 15 to 40 grains ; externally as a gargle for sore throat, and in powder as a deter- gent in aphthae, and ulcerations of the mouth. Dis- solved in rose-water, it is used as a cosmetic, and mixed with 8 times its weight of lard, forms a use- ful piles ointment. Tests. These are the same as for the borates, which see. It reddens turmeric paper, and, be- fore the blowpipe, fuses into glass, which may be tinged red by terchloride of gold, and blue by co- balt. Pur. The purity and strength of borax are best ascertained by determining the quantity of sul- phuric acid required to neutralize a given weight, as indicated by litmus paper. Common salt and alum are frequently mixed with borax to lower the value. The former may be detected by dissolving the borax in hot water, when a solution of lunar caustic will give a curdy white precipitate, soluble in ammonia; and the latter by water of ammonia, which will give a bulky white precipitate. Th« BOU 129 BOX former must be distinguished from the white pul- verulent precipitate of borate of silver, which will be thrown down from pure borax. BORAX, GLASS OF. Prep. Dry borax with a gentle heat, breaking down the froth as it rises, then melt it by increasing the heat until it runs into a glass. Use. In soldering, and as a blow- pipe flux. BORO-FLUORIDE OF HYDROGEN.— Prep. Pass fluoboric acid gas through water, and afterwards carefully concentrate the solution; cool and separate the crystalline powder from the solu- tion, which is the boro-fluoride of hydrogen. Prop., tyc. With most of the protoxides it interchanges bases, and metallic boro-fluorides result. BORO-FLUORIDE OF BARIUM. Prep. Add carbonate of baryta to boro-fluoride of hydro- gen, until it ceases to be dissolved; evaporate to the consistence of a sirup, when crystals will form. Remarks. The boro-fluoride of calcium, magnesi- um, and lead, may be formed in a similar way. BORO-FLUORIDE OF POTASSIUM — Prep. Drop boro-fluoride of hydrogen into a solu- tion of carbonate of potassa, collect the white pow- der that falls, and wash it with cold water. BORO-FLUORIDE OF SODIUM. Prep. Dissolve fluoride of sodium in boro-fluoride of hy- drogen, and crystallize. Remarks. Boro-fluoride of lithium may also be formed in a similar way. BORON. The base of boracic acid, discovered by Sir H. Davy, in 1807, by means of the gal- vanic battery of the Royal Institute. Prep. Potassium, and perfectly dry boracic acid, or still better, boro-fluate of potassa, intimate- ly mixed together, are to be placed in an adopter, or glass tube, and submitted to a low red heat. When cool, remove the loose cork that fastened its mouth, and pour in successive portions of hot wa- ter, until the whole matter is detached and dis- solved. Collect the liquid and allow it to settle, then wash the precipitate, first with a solution of sal ammoniac, and finally, with alcohol; next dry the boron in a capsule, and put it into a well-stop- ped vial. Prop., 6cc. A solid, tasteless, and inodorous pow- der, of grayish-brown color. With sulphur it unites at high temperatures, forming sulphurets; and when placed in chlorine gas it spontaneously in- flames, and a gaseous chloride is produced. This gas may also be made by exposing calcined borax and charcoal at a red heat to the action of dry chlorine. BOTTLE, RED. Syn. Taylor's Red Bot- tle. Whitworth Doctor's Red Bottle. Prep. British brandy 1 quart; powdered cochineal \ oz.; oil of origanum 10 drops. Digest for 24 hours and filter. BOUGIE. Syn. Candela. Candela cerea. Candelula. Virga cerea. Cerea.. Cereola. Cereus. Cereolus. A long ^lender instrument, introduced into the urethra, oesophagus, or rectum, to overcome strictures of those canals. The word bougie is the French for a wax candle. Prep. I. Add 3 parts of boiled linseed oil to 1 part of melted amber, and when mixed add 1 part of oil of turpentine; spread the mixture at 3 suc- cessive intervals upon loose spun silk cord or web, dry in a heat of 150°, and repeat the process until the instrument has acquired the proper size, then 17 polish, first with pumice-stone, and afterwards with tripoli and oil. Remarks. The above is the original receipt of the French professor Picket, and is still generally used, slightly modified, on the continent. II. Add to the oil and amber melted together, as last, caoutchouc in the proportion of -*ff of^the weight of the oil employed; when dissolved, re- move the vessel from the fire and proceed as be- fore. Remarks. This is the plan usually adopted at Paris, and for the best elastic bougies this process usually occupies from 6 to 8 weeks. When the bougie is wanted to be hollow, a piece of polished metallic wire is introduced into the axis of the silk, or tinfoil is rolled round the wire and the composi- tion applied as before. When dry and hard the wire is withdrawn. III. (Caoutchouc, or elastic gum bougies.) a. In France these are made by applying a solution of Indian rubber in ether, to the silk or foil pre- pared as above. b. In England, where ether is expensive, naphtha is employed, or slips of Indian rubber previously boiled in water, or that have had their edges softened with ether, are wound round the wire or foil, and kept in their place by a piece of tape applied over them, as in making elastic tubes. They are afterwards carefully smoothed off IV. A common kind of bougie is made by dip- ping pieces of catgut or soft linen into lead plaster, melted, and rolling it while yet warm upon a slab. Very inferior. V. (White.) Prep. Yellow wax 1 lb.; sperma- ceti 1 oz.; finely-powdered sugar of lead J oz.; melt and spread upon slips of old linen, then roll them up while warm with the spread side out- wards. VI. (Bell's.) Lead plaster 1 lb.; yellow wax 8 oz. ; olive oil 2 oz.; as last. Very inferior. BOUILLI. (French for boiled meat.) This name has been applied by cooks to several dishes of boiled meat, as a refinement on the plain Eng- lish. Thus " beef bouilli, beef in bouilli, &c," means, stewed or boiled beef, &c. As, however, the name is a la francais, so must be the accom- paniments, which generally consist of herbs and vegetable seasoning in greater quantity and varie- ty than is usually deemed essential to a plain- spoken piece of boiled or stewed meat! BOULES DE NANCY. Equal parts of iron filings and red tartar, made up into balls with spirit. Use. As a tonic dissolved in hot water. BOUQUET DE LA REINE. Prep. I. Es- sence of bergamotte 1 drachm; English oil of lavender 23 drops; oil of cloves and aromatic vinegar, of each 8 drops; essence of musk 10 drops ; alcohol £ oz. Mix. II. Oils of bergamotte and lavender 30 drops each; neroli 15 drops ; oils of verbena and cloves, of each 5 drops. Essences of musk, ambergris, and jasmin, of each £ drachm ; rectified spirit of wine (strongest) 1 oz. Mix. BOX WOOD MAHOGANY. Prep. Warm the wood by the fire, then wash it over with aqua- fortis, let it stand 24 hours to dry, and polish it with linseed oil reddened with alkanet root, or give it a coat of varnish, made by dissolving aloes and annotto in spirit of wine. BRA 130 BRA BOYLE'S FUMING LIQUOR. Hydrosul- phuret of ammonia is usually employed and sold for this article, but the liquor prepared by Boyle's process contains an excess of sulphur. (Gay Lus- sac.) The properties of both are however the same. Prep. Mix 4 parts of fresh slaked lime ; 2 of sal ammoniac, and 1 of sulphur, then submit the mixture to distillation. BRA GRAS. Tar, black rosin, and the dregs of strained rosin, melted together. BRAIN CAKES. Prep. Clean, wash, blanch, and soak the brains, then beat them up with a little white pepper and salt, a sage-leaf or two, scalded and finely chopped, and the yelk of an egg; make them into small cakes or fritters, and fry them. BRAN. The husk of wheat which immediate- ly covers the grain, and which is left in the bolting machine. Use. It is largely employed by the calico printers, when diffused through hot water, to remove the coloring matter from those parts of their goods which are not mordanted. A handful mixed with a pail of warm water, forms an excel- lent emollient foot-bath. Infused in water, (bran tea,) and sweetened, it forms a popular demulcent, much used in coughs and hoarseness, and, taken in quantity, proves gently laxative. It also forms an excellent manure, and, from containing the ammoniaco-magnesian phosphate, is especially adapted for potatoes. It is frequently mixed with flour and made into bread, by the poorer orders. BRANDY. Syn. Eau de Vie. Aqua Vitm. Spiriti s Gallicus. Brandy-wine. The spiritu- ous liquor obtained by the distillation of wine. When first distilled it is colorless, and only acquires a yellowish tint from the wood of the casks, in which state it is known and sold as pale or white brandy. The deep color that it usually possesses, is imparted to it by adding a little spirit coloring, (burnt sugar or caramel,) and occasionally a little red sanders wood as well, and is intended to imitate the appearance acquired by brandy from great age, when kept in wood. The natural color, how- ever, which the spirit receives from the cask, no matter how long it may have been in it, never ex- ceeds an amber tint, about the common color of pale Jamaica rum ; but the public taste has been gradually vitiated in tins respect, until only a spirit of a lively and full " brandy color" (unless for a pale brandy) will sell. The brandies most esteemed in England are imported from France, and are those of Cognac and Armagnac, the preference being generally given to the former. The brandies of Rochelle and Bordeaux may be reckoned next in quality, while those obtained from Portugal, Spain, and Italy are very inferior. The constituents of brandy are alcohol and wa- ter, and small quantities of volatile oil, acetic acid, acetic ether, cenanthic ether, coloring matter, and tannin. It is from the presence of the last six of these substances that the spirit derives its dis- tinguishing smell and flavor. Tha quantity of alcohol present in brandy varies from 48 to 55 per cent. When first imported, it is generally 1 or 2 overproof, but by age its strength is lessened, and by the time it is usually taken from the bond store for sale, seldom exceeds 3 or 4 underproof. From considerable personal acquaintance with the cognac trade, I feel confidence in asserting, that brandies of the best quality seldom exceed proof, and are generally below it, and that it is a common prac- tice in France to add spirit of wine and coloring to raise the strength to any given point desired by the English purchaser, and to charge the same in the invoice; or where the purchaser is not well acquainted with the subject, and desires a strong spirit at a low rate, to sell him brandy so mixed as genuine. The very finest brandies average from 5 to 10 u. p., and never exceed about 2 u. p.; they then contain more than £ their weight of water, and from their boiling point being higher, they come over more highly charged with essential oil, and other volatile and fragrant principles of the, grape, and thus possess in a greater degree that peculiar aroma and flavor for which they are so much esteemed. French brandy or wine, distilled at a low temperature in a water bath, yields a very pure and scarcely flavored spirit. The quality of the brandy imported from France varies considerably from that which is druiJi on the continent, principally from its being prepared, or, as it is technically termed, " made up," for the London market, which means lowering it by the addition of spirit, coloring, &c. above described The common strength at which foreign brandy is sold in England is about 11 or 12 u. p., and below 17 u. p. it becomes seizable by the excise. The strength at which it is sold and permitted in trade, is generally 10 u. p., to which it is reduced by add- ing water, and never less than 12 u. p., unless it be specially agreed upon. In large quantities and from bond, of course the strength depends much upon the age and quality of the spirit. A fine old brandy being, perhaps, 8 or 10 u. p., while one of the last year's vintage of a commoner quality may be as strong as 2 or 1 u. p. But these distinctions are familiar to every experienced brandy dealer. In France there are several varieties of this spirit distilled, which are known by names descrip- tive both of their quality and source. The " eau de%vie superieure," or cognac brandy, is generally obtained from pale wliito wines, by careful distil- lation, and is remarkable for its superior flavor. When kept in glass or stone bottles, it is called white cognac brandy, and the same term is also generally applied when it has been kept in casks, but has not been artificially colored ; in the latter case, however, it generally acquires a pale amber tint. The " eau de vie ordinaire," or common brandy, is distilled from high-colored white or red wines, and has generally a sp. gr. of 0-948, and varies from 22 to 27 u. p. The " eau de vie de marc" is obtained from the lees of vinegar and other wines, the marc or cake of grapes from which the juice has been pressed, and the commonest red wines, fermented and dis- tilled together by .a quick fire, to drive over as much essential oil and flavoring as possible. The " eau de vie seconde" is the weak spirit that passes over after the stronger spirit has been drawn off, and the receiver changed. It is used for common drinking, or mixed with other brandy. The " eau de vie a preuve d'Hollaude" is bran- dy about 19° Baume, or sp. gr. *9420, the common strength at which it is retailed in France, and will stand the "proof" or " bead " BRA 131 BRA The " eau de vie a preuve d'huile" is the strong- sst brandy usually drunk ; it is about 23° Baume, or sp. gr. -918 ; pure olive oil will just sink in it; hence the above term. The " eau de vie fort" is usually prepared by the redistillation of common brandy, keeping the first portion separate. It answers to our spirit of wine. It is made of 12 different strengths, distin- guished by names, exhibiting the quantity of water required to reduce the sample to the "preuve d'Hollande." The weakest is called cinq-six, or |, and the strongest trois-neuf, or %, the difference between the numerator and the denominator being the quantity of water the 3 parts of the former will take to reduce it to the " preuve," when it would make 9 parts. Its sp. gr. is about -839. The esprit de vin is brandy or spirit rectified to 0-890 and upwards. The general method of distilling brandy in France differs in no important particular from that practised in England, for grain or molasses spirit. Neither are the French workmen more skilful nor more cleanly in their operations than the English. It is the materials alone that, in this case, conduce to the superiority of the product. The quality of the brandy varies with that of the wine from which it has been distilled. Every soil, every climate, every kind of grape, produces a wine possessing some peculiarity confined to itself, and this wine on distillation produces a spirit possessing like dis- tinctions. A large quantity of brandy is prepared in France soon after the vintage, as the juice of the poorer grapes that is unfit for wine is ferment- ed and at once distilled. It is a general rule, in France, to distil only such wines as are unsaleable, as the profits on the wine, sold as such, are much greater than when it is converted into brandy. The Strength of Brandy may be ascertained in the same way as alcohol, for which purpose Sike's hydrometer is used in England. In France, from the value of spirit being less, it is frequently tested by simpler methods, though great accuracy obtains, in this particular, where necessary. Pur. Very little perfectly pure French brandy is obtained by the small consumer in England, as it is not only generally lowered a little by the wholesale dealer, but undergoes a like process at the hands of the retailer. The safest method is either to procure it direct from the bond store, without its even entering a private cellar, or to buy of some known respectable party, and to pay a price that will offer no inducement to dishonesty. If this be not done, by all means buy British bran- dy, which is now made of excellent quality by many of the leading houses, as Betts, Bretts, Booth, and Grimble. From the two former a sin- gle sealed bottle may be procured at the same price as by the gallon. The importation of foreign brandy for home con- sumption amounts to about 1,400,000 gallons a year. BRANDY, (REDUCED.) I. To 20 gallons of Cognac brandy add 5 gallons of the best British brandy. II. To 72 gallons of full-flavored French brandy, add 10 gallons of spirit of wine, (56 o. p.,) 8 gal- lons of water, and 1 pint of good coloring. Rum- mage well up and let it stand until the next day. hemarks. The above reduction is generally adopted in trade, and is known by the name of " improving" But such is the poverty of the pal- ate of the English brandy drinker, that the adul- teration is often not suspected, even when it is carried to double the extent of the above, whiah rf generally exceeded in the hands of the retailer. So long, however, as the foreign spirit constitutes about half of the mixture, and was at first of de- cent quality and age, the infatuated Englishman smacks his lips, and cunningly holding up his glass between the light and his eye, exclaims, " Ah ! this is a drop of the real." BRANDY, (BRITISH.) Syn. British Co- gnac. Imitation Cognac, &c. From the heavy duty levied on French brandy imported into Eng- land for home consumption, it has become a de- sideratum with the distiller (rectifier) to produce an English spirit of a similar description. For some time the attempt proved quite unsuccessful, but of late years much capital and talent have been em- barked in the pursuit, and the result has proved very satisfactory. An article of British manufac- ture may now be purchased, at a very reasonable rate, of really respectable quality, and possessing much of the flavor and aroma of foreign brandy, while, as a beverage, it is equally wholesome. Much of the British brandy, however, that is com- monly met with, is of such a wrei.hed quality as to be quite undeserving of the name, which is evi- dence of the fact, that much skill and experience is required to ensure success in its manufacture. For a long time this liquor was distilled from spoilt wine and dregs of wine, both British and foreign, mixed with beer bottoms and similar articles; and .when, instead of these, corn, malt, and molasses spirit were employed, it was considered as an unpar- donable and wicked misuse of those articles. Mod- ern experience has proved, however, that perfectly pure and tasteless malt spirit is the best article to form into an imitation brandy. The following formula?, by skilful management, will produce very good brandy, but it must be re- collected that much depends on the quality of the materials employed, as well as on the operator. As the strength and quality of the ingredients, and the methods of manipulation vary, so will the re- sult ; much must therefore be left to the judgment and discretion of the artist. It offers a profitable pursuit to the ingenious and industrious chemist and rectifier. Prep. I. Take 12 gallons of the finest flavorless malt spirit at proof, (or if of a different strength a proportionate quantity;) add thereto 5 gallons of water, \ lb. of the best crude red tartar or wine- stone, previously dissolved in 1 gallon of boiling water; \ pint of acetic ether; 2 quarts of good French wine vinegar; 7 lbs. of bruised French plums, and 1 or 2 gallons of wine bottoms or flavor stuff from Cognac, mix them in a fresh-emptied sherry cask, and let them stand together for 14 days, frequently rummaging up the liquor with a stick; next draw over 15 gallons of the mixture from a still furnished with an agitator. Put the rectified spirit into a clean, fresh-emptied Cognac brandy cask, and add thereto £ pint of tincture of catechu, 1 lb. of fresh and clean oak shavings, and about a pint of good spirit coloring. Bung close, and agitate occasionally for a few days. Remark*. Age improves tha above article, and renders it BRA 132 BRA (pro\ ided the process be well managed) cf a very superior quality. The above receipt yields 15 gal- lons of brandy 17 u. p. The following forms may also be recommended:— M. Perfectly pure spirit, pf. 99 gallons ; red tar- tar, dissolved, 7 lbs.; acetic ether 3 lbs.; wine vin- egar 3 gallons : bruised raisins, or French plums, 7 lbs.; bitter ajinonds, bruised, 1 oz.; water suffi- cient. Dissolve the tartar in the water, then add the other ingredients, macerate as before, and draw over 120 gallons; lastly, add a few lbs. of oak shavings, 1 lb. of powdered catechu made into a paste with water and burnt-sugar coloring as be- fore. Remarks. This yields 120 gallons of spirit fully 17 u.p. III. Clean spirit 17 u. p., 100 gallons; nitric ether 2 quarts; cassia buds, ground, 4 oz.; bitter almond meal 2 oz.; orris root, sliced, 6 oz.; pow- dered cloves 1 oz.; capsicum 1J oz.; good vinegar 2 gallons ; brandy coloring 1 quart; powdered ca- techu 1 lb.; full-flavored Jamaica rum 2 gallons. Mix well in an empty Cognac cask, and let them macerate for a fortnight, occasionally stirring. Remarks. The proportion of the ingredients may be varied by the skilful brewer, as much depends on their respective strengths. IV. Good plain malt spirit, 17 u.p., 100 gal- lons ; finely-powdered catechu 12 oz.; tincture of vanilla 4 oz.; burnt-sugar coloring 1 quart; good rum 3 gallons, or more; acetic or nitric ether 2 quarts. Mix well. V. Clean spirit, 17 u.p., 89 gallons; high-fla- vored cognac 10 gallons ; oil of cassia 1^ drachms ; oil of bitter almonds, essential, £ a drachm ; pow- dered catechu 10 oz.; cream of tartar, dissolved, 16 oz.; Beaufoy's concentrated acetic acid 3 lbs.; sugar coloring 1 quart, or more ; good rum 1 gal- lon. Put the whole into a fresh emptied brandy piece, and let them remain a week together, with occasional agitation, then let them stand to settle. If this mixture be distilled, the French brandy, rum, coloring, and catechu, should not be added till afterwards. VI. To colored plain spirit at 17 u.p., add a little tincture of catechu, and a sufficient quantity of essential oil, distilled from wine lees, to give it a proper flavor. This oil is obtained by distillation from the wine lees, either dried and made up into cakes, or in their wet state mixed with about 7 times their weight of water. It should be dis- solved in alcohol, and kept in this state, as it is apt to lose its flavor. Remarks. When this pro- cess is well managed a very capital article results, but it requires considerable address to conduct it well. The spirit produced by this plan is better for distill ation. The brandy from any part of the world may thus be imitated, by distilling the oil from the lees of the wines produced in the par- ticular district. This is the only method of pro- ducing an exact imitation. A pound each of finely-powdered charcoal and ground rice has been recommended to be digested in a gallon of spirit for a fortnight. Where black tea is cheap, as in America, it is very commonly employed to impart the roughness and flavor of brandy to colored spirits. BRANDY, CHERRY. Prep. I. To every gallon of brandy put an equal measure of cher- ries, bruised between the fingers; steep for 3 days, then express the liquor; add 2 As. of lump sugar, and strain for use. II. To the above add 1 quart of raspberries, and £ a pint of orange-flower water. %* Qual- ity very fine. III. Treacle 1 cwt.; spirit (45 u.p.) 41 gal- lons ; bruised bitter almonds (more or less, to taste) 5 oz.; cloves 1 oz.; cassia 2 oz. Put the ingredients into a large cask, well mix and let them lie a month, occasionally stirring. Remarks. Equal parts of fully ripe Morello and black cherries produce the richest cordial. BRANDY, CARAWAY. Prep. I. Steep 4 oz. of bruised caraway seeds and 2 lbs. of sugar in 1 gallon of British brandy, for a fortnight. II. Sugar 1 lb.; caraways 1 oz.; 3 bitter al- monds; spirits of wine and water, of each 1 quart; (or spirit 22 u. p. £ a gallon.) Macerate as above. BRANDY, DANTZIC. This .s distilled from rye, ground with the root of calamus aromaticus. It has a mixed flavor of orrice and cinnamon. BRANDY, LEMON. Prep. I. Steep J lb. of fresh lemon peel and £ a dozen lemons, cut in slices, in 1 gallon of brandy, for a week, then add 1 lb. of lump sugar. II. Proof spirit 7 gallons; essence of lemon 3 drachms; sugar 5 lbs.; tartaric acid 1 oz., dis- solved in water 2 gallons; coloring q. s. Mix, and rummage repeatedly for 14 days. Remarks. Sometimes milk is added to the above, in the pro- portion of 1 quart (boiling hot) to every gallon. BRANDY, MALT. Malt spirit, flavored with sweet spirits of nitre and terra Japonica, and col- ored with treacle, or spirit coloring. (See Brit Brandy.) BRANDY, ORANGE. This may be made in a similar way to lemon brandy. BRANDY, PEACH. Prep. 1. From peaches, by fermentation and distillation. Much used in the United States, where peaches are very cheap II. Bruise the peaches, then steep them in twice their weight of British brandy, or malt spirit; lastly, express the liquor. III. Bitter almonds (bruised) 2 oz.; proof spirit (light) 10 gallons; water 3 gallons; sugar 5 or 6 lbs.; orange-flower water \ a pint. Mix, and macerate for 14 days. *»* Color with brandy coloring, if (required darker. BRANDY, RASPBERRY. Prep. I. Pour as much brandy over raspberries as will just cover them ; let it stand for 24 hours, then drain it off, and replace it with a like quantity of fresh spirit; after 24 hours more, drain this off and replace it with water ; lastly, drain well, and press the rasp- berries quite dry. Next add sugar to the mixed liquors, in the proportion of 2 lbs. to every gallon, along with a -J of a pint of orange-flower water. II. Mix equal parts of mashed raspberries and brandy together, let thenv stand for 24 hours, then press out the liquor. Sweeten as above, and add a little cinnamon and cloves, if agreeable; lastlyi strain. BRASS. An alloy of copper and zinc. Hist, and Prep. Brass was formerly manufac- tured by cementing granulated copper, or copptr clippings, with calcined calamine and charcoal, in crucibles, exposed to a bright heat. The alio] BRA 133 BRA was found in lumps at the bottom of the crucible on cooling. These were remelted and cast into ingots. At the present day, brass is generally made by direct union of the metals. This process requires much care, owing to the different degrees of fusibility of copper and zinc. The proper quan- tity of zinc is first melted, and slips of copper plunged into it, which are rapidly dissolved, as it were, and the addition is continued until an alloy- is formed, somewhat difficult of fusion, when the remainder of the copper is added. The brass thus formed is typken into pieces, and remelted under charcoal, a.'°Jf a proper addition of either zinc or copper made, to bring it up to the color and qual- ity desired. It is next cast into plates, or other forms, in moulds of granite. When submitted to the rolling-press for reduction to thin plates, it re- quires to undergo the operation of annealing sev- eral times. Prep. I. (Fine Brass.) 2 parts of copper to 1 part of zinc. Remarks. This is nearly 1 equiv- alent each of copper and zinc, if the equivalent of the former metal be taken at 63*2 ; or 2 equiv- alents of copper to 1 equivalent of zinc, if it be taken, with Liebig and Berzelius, at 31*6. II. Copper 4 parts, zinc 1 part. An excellent and very useful brass. III. (Gold-colored Brass.) Syn. Red Brass. Dutch Gold. Tombac. Similor. Prince's Metal. Pinchbeck, &c. a. Copper and zinc, equal parts. b. Copper 2 parts; zinc 1 or 1J parts. This is Manheim gold. c. Copper 3 to 5$ parts; zinc 1 part. Deep colored. Remarks. The proportion of zinc in this alloy is altered to suit the color and other properties to the purposes for which it is intended, and often varies from £ to ^, or £ of the weight of the alloy. At the celebrated works of Hegermiihl, near Pots- dam, the proportions are 11 parts of copper to two of zinc, which produces a metal which is after- wards rolled into sheets for the purpose of making Dutch leaf-gold. BRASS, BUTTON. (Best.) I. Copper 8 parts ; zinc 5 parts, as above. II. (Common.) Copper 50 parts; zinc40 parts; tin 4 parts ; lead 6 parts. BRASS, FOR SOLDER. Syn. Hard Sol- der. I. 12 parts of brass ; 6 parts of zinc, and 1 of tin, melted together. II. 2 parts of brass, and 1 of zinc. III. (Very strong.) 3 parts of brass, and 1 of zinc. BRASS, TURNER'S. 98 parts of brass, and 2 of lead. Remarks. The addition of lead im- proves the brass for the uses of the turner, but lessens its malleability. BRASS, CLEANING OF. Brass and cop- per are best cleaned with sweet oil and tripoli, powdered bath-brick, rotten-stone, or red brick- dust, rubbed on with flannel and polished with leather. A strong solution of oxalic acid in water gives brass a fine color. Vitriol and spirits of salts make brass and copper very bright, but they very soon tarnish, and consequently require more fre- quent cleaning. A strong lye of roche-alum and water will also improve brass. Brass inlaid work may be cleaned as follows:— Mix tripoli and linseed oil, and dip into it a rubbei of hat, with which polish the work. If the wood' be ebony or rosewood, polish it with a little finely- powdered elder-ashes ; or make a paste of rotten- stone, a little starch, sweet-oil, and oxalic acid, mixed with water. The ornaments of a French clock are, however, best cleaned with bread- crumb, carefully rubbed, so as not to spoil the woodwork. Ormolu candlesticks, lamps, and branches, may be cleaned with soap and water. They will bear more cleaning than lacquered ar- ticles, which are spoiled by frequent rubbing, or by acids, or strong alkalis. BRASS COATING. I. Brass plates and rods may be covered with a superficial coating of brass, by exposing *!aem in a heated state to the fumes of melted zinc, at a high temperature. Use. For rolling into thin plates, or drawing into wire. The celebrated spurious gold wire of Lyons is thus made. II. Vesse* of copper may be coated with brass, internally, by filling them with water strongly acidulated with muriatic acid, adding some amal- gain of zinc and cream of tartar, and then boiling for a short time. BRASS-COLORED PIGMENT. Syn. Brass Bronze. Prep. I. (Red.) Grind copper filings, or precipitated powder of copper, with a little red ochre. II. (Yellow or gold-colored.) Gold-colored brass, or Dutch leaf reduced to a very fine pow- der. Remarks. Both these powders are mixed up with varnish, and used as a paint. No more should be mixed at a time than wanted for imme- diate use. They are also used by dusting them over any surface, previously covered with varnish to make them adhere. (See Oxide of Copper.) BRASS-COLORED VARNISH. Prep. Dis- solve 1 oz. each of pale shell lac and gum sanda- rach, in £ a pint of rectified spirit of wine. Use. To mix up the preceding powders. BRASS, PASTE FOR CLEANING. Prep. I. Soft soap 2 oz., rotten-stone 4 oz.; beat them to a paste. SI I. Rotten-stone made into a paste with sweet . III. Rotten-stone 4 oz.; oxalic acid 1 oz.; sweet oil 1J oz.; turpentine enough to make a paste. Use. To clean brass. The first and last are best applied with a little water. The second, with a little spirits of turpentine, or sweet oil. Both require friction with soft leather. BRASS ORNAMENTS, PRESERVATION OF. Brass ornaments, when not gilt or lacquered, may be cleansed, and a fine color given to them by two simple processes. The first is to beat sal ammoniac into a fine powder, then to moisten it with soft water, rubbing it on the ornaments, which must be afterwards rubbed dry with bran and whiting. The second is to wash the brass- work with roche alum boiled to a strong lye, in the proportion of an ounce to a pint; when dry, it must be rubbed with fine tripoli. Either of these processes will give to brass the brilliancy of gold. BRASS STAIN. I. Cut sheet-brass into small pieces, and expose it to a strong heat for 2 or 3 days, then powder it, and again expose it for several days to a like heat; again powder and sift, BRA 134 and expose it a third time to heat, testing it occa- sionally, to see if it be properly burnt. When this is the case, a little of it fused with glass will make the latter swell and froth up. Uses, fyc It imparts to glass a green tint, passing into torquoise. II. Calcine equal parts of plate-brass and sul- phur, stratified together in a crucible, until they become friable; then powder and expose them again, as last. Use. Imparts a calcedony red or yellow tinge to glass by fusion, according to the mode of using it. BRAWN, CHOICE. When young, the horny parts feel moderately tender; if the rind be hard, it is old. BRAWN, MOCK. Prep. Take the head and belly piece of a young porker, well saltpetred; split the head and boil it; take out the bones and cut it to pieces; then take four ox-feet boiled ten- der, and cut them in thin pieces; lay them in the belly piece, with the head cut small; roll it up tight with sheet tin, and boil it four or five hours. When it comes out, set it up on one end, put; a trencher on it within the tin, press it down with a large weight, and let it stand all night. The next morning take it out of the tin, and bind it with a fillet, put it into cold salt and water, and it will be fit for use; it will keep a bug time, if fresh salt and water are put into it every four days. BRAZIL WOOD. Syn. Sapan Wood. Saint Martha Wood. Fernambuca. This wood is much used in dyeing. A decoction is made by boiling for some hours in hard spring water, and this is generally kept for some time, or until it un- dergoes a species of fermentation, as it is thus found to yield more permanent and beautiful colors than when employed quite new. Use. To dye red. BRAZIL WOOD DYE. I. (For cotton and linen.) a. First boil the goods in a bath of su- mach, next work them through a weak mordant of solution of tin, and then run them through the Brazil bath, lukewarm. This gives a bright red. 6. First alum the goods and rinse them, then give them a mordant of solution of tin, rinse again, and turn them through the dye-bath. This gives a rose color. Remarks. The shades of this dye may be va- ried by the strength of the bath, mordant, &c. A little alum added to the Brazil-bath, gives a pur- ple tint. 1 lb. of Brazil wood, £ oz. of alum, and 2 oz. of tartar will dye 20 to 25 lbs. of cotton. II. (For silk.) The silk, after being well al- umed in the same way as wool, but at a lower temperature, is rinsed, and passed through the de- coction of Brazil, just lukewarm. Remarks. By adding a little alkali to the bath, or by passing the silk through a water holding a little alkali in solution, after it is dyed, will produce what is called the false crimson. When wanted uf a very deep crimson, a little logwood is added to the Brazil-bath. In this way any shade of color may be produced. III. (For wool.) Boil the wool in water hold- ing in solution 5 parts of alum and 1 of tartar, for 1 hour; then let it lie in the cold liquor for several days, frequently moving it about; lastly, boil it in a decoction of Brazil for £ an hour. BRAZILINE. Syn. Breziline. The color. ing principle of Brazil wood, obtained by Ghevreul in small orange-colored needles. It is soluble in both water and alcohol; alkalis turn it violet, acids yellow. With alum it dyes red. BRAZING. The operation of uniting the edges of pieces of copper, brass, iron, &c, by means of hard solder. Proc. The edges, after being filed quite clean, are covered with a mixture of hard solder and powdered borax, made into a paste with water. The whole is then allowed to dry, apt! afterwards exposed in a clear fire to a heat suf?.-. n»nt to melt the solder. Remarks. In some cases a little silver is added to the solder, when it receives the name of " sil- ver solder." BREAD. Principles of bread-making, d}c. This most important article of food is made of the flour of different grains, but only those that con- tain gluten admit of conversion into light spongy bread. Hence it is that wheat flour is best calcu- lated for this purpose. When flour is made into a stiff paste or dough with water, and rolled into cakes and baked, it forms biscuits, or unleavened bread, which was once the only description known. When the dough, previously to baking, is left for some time in a moderately warm place, varying from 80° to 120°, a state of fermentation cornea on, formerly called the panary fermentation, but which is, in reality, the sugar of the flour gradu- ally undergoing the process of conversion into al- cohol, and resembles in every respect the same change which takes place in the manufacture of wine, beer, &c. During this process, a large quantity of carbonic acid gas is liberated, and the toughness of the dough preventing its escape, the whole mass becomes puffed up and spongy, and a light porous paste is formed, ready for baking into bread. The natural process of fermenting the dough just described, is, however, subject to much uncertainty, and is inconvenient from the time it occupies to complete it, and the tendency the dough has to run into the acetous fermentation, when it acquires a sour and disagreeable taste, and is rendered less nutritious and easy of digestion. This has led to the use of a ferment, which at once excites a proper state of fermentation throughout the mass, and speedily renders it light and spongy. Leaven or dough, already in a state of fermentation, was originally employed for this purpose, and the bread so made was hence called leavened bread. But this has been wholly super- seded by barm or yeast. Thus it will be seen that all that is essential to make a loaf of bread, is to add a proper quantity of yeast to the dough, and to allow it to remain for a short time in a warm place, until it rises or becomes sponge when it must be subjected to the operation of ba- king. If the process be well managed, and the flour be good, bread of superior quality will Le produced. Process of making bread. In preparing hi* dough, the modern baker takes a part of the water needed for the batch, and having warmed it to a temperature of about 80° or 90°, dissolves his sal". therein, and then adds the yeast and a portion of the flour. These he works up into a dough, which he sets aside in a warm place usually provided foi BRE 135 BRE the purpose, nnd called the " kneading trough," where it soon begins to ferment and swell up. This process is called " setting the sponge," and according to the proportion the water in it bears to the whole quantity that is to be used, it re- ceives the name of " whole," " half," or " quarter sponge" The evolution of carbonic acid in the process of fermentation, causes the sponge to heave and swell, and when the surface bursts, it subsides, and then swells again and again in a similar manner. This action would go on for some time, if not interfered with ; but the baker is careful to stop it before it has communicated a sourness to the mass. After the first, or at the furthest, after the second or third " dropping of the sponge," he adds the remaining quantity of flour, water, and salt, necessary to form the batch. These he incorporates by long and laborious kneadings, until the entire mass acquires uniform- ity, and is sufficiently tough and elastic to bear' the pressure of the hand without adhering to it. The dough is now left to itself for a few hours, during which time fermentation goes on, after which the inflated mass is again kneaded, when it is ready to be cut into pieces and weighed. These pieces are then shaped into loaves, and set aside for an hour or two, during which time they swell up to nearly double their former size; they are then placed in the oven and baked. During this operation they continue for a time to increase in size, in consequence of the dilation of the pent-up gas by the heat of the oven, until at length the fermentation is checked, and the dough becomes too solid to admit of further alteration. Remarks. A number of other processes are used by cooks and confectioners to make the different varieties of fancy bread, cakes, puddings, &c, most of which vary according to the peculiar char- acteristic it is desired to communicate to them. Thus some kinds of cakes and pastes are made to eat "short," as it is called, or are rendered less tenacious, and a species of brittleness imparted to them by the addition of starch and sugar. In pastry a similar effect and peculiar lightness is produced by butter or lard, while in some articles, white of egg, gum-water, isinglass, and other ad- hesive substances are added to produce an exceed- ingly light and porous mass. The different varieties of bread made in Eng- land vary chiefly in their quality, according to the flour of which they are formed. The best white bread is made from the purest wheat flour ; ordi- nary wheaten bread, of flour to which a little of the finest bran has been added; seconds, from flour containing a still larger portion of bran ; and common household bread, from flour produced by grinding the whole substance of the grain without any separation of the bran. Symnel bread, man- chet or roll bread, and French bread are varieties made of the purest flour, from the finest wheat, a little milk being usually added for rolls, and butter and eggs for choicer purposes. Several other minor kinds of bread are also made, varied by the addi- tion of 6undry trifles, as sugar, currants, and other palatable ingredients. The Scotch " short bread" is made from a very thick dough, to which butter, ■ugar, orange-peel, and spices, are added. (See Gingerbread.) In France a number of different kinds of bread are made. The " pain bis" is the coarsest sort, and is made of a mixture of groats and wheat flour; the "pain bis blanc" is made of a mixture of oatmeal and wheat flour; the "pain blanc" of flour from which the finest portion has been sifted ; the " pain mollet," or soft bread, is made of the purest wheat? flour, from the finest grain; the "pain chaland," made from the same materials as the last, but the paste is pounded ; the " pain chapale" is a small variety of bread, similar to the French or roll bread of England ; the " pain cornu" is a kind of small bread, named from being done up into four-cornered pieces; the "pain de la reine" is another variety of small bread, and the "pain gruau" is abroad which has been*made of late years in Paris, prepared from the small granular particles separated from the best wheat after a slight grinding. The French have also their soup bread and their country white bread, ' besides several other varieties, not mentioned in the above list. In the manufacture of white bread from dam- aged or inferior flour, a large quantity of alum is employed by the bakers, but with the best flour no alum is required. The utmost beauty, sponginess, and sweetness, may be given to bread without the addition of one particle of alum, provided the best materials are employed. As such is not, however, generally the case, it is a common practice with the bakers to introduce 4 or 5 oz. of alum to every sack of flour, or about 1 oz. to each bushel. The method of detecting this adulteration will be pres- ently explained. The proper quantity of salt to be used is 6 or 7 lbs. to the sack, or 1-J lbs. to the bushel. 1 sack of the best flour, and 6 lbs. of salt, ought to yield about 360 lbs. of good bread, and a sack of seconds 345 to 350 lbs. of bread. Wheaten bread, made of pure materials, is one of the most wholesome articles of food, and has been justly termed the staff of life. When well fermented and baked, it is very easy of digestion. It should never be eaten till it has stood 24 hours after being taken out of the oven, as newer bread is apt to disagree with the stomach, frequently pro- ducing flatulence, heartburn, and indigestion. Adult. This is often carried to a fearful extent: Mr. Accum says, " The bakers' flour is very often made of the worst kinds of damaged foreign wheat, and other cereal grains mixed with them in grinding the wheat into flour. In this capital, no fewer than six distinct kinds of wheaten flour are brought into the market. They are called fine flour, seconds, middlings, fine middlings, coarse middlings, and twenty-penny flour. Common gar- den beans and peas are also frequently ground up among the London bread flour. " The smallest quantity of alum that can be employed with effect to produce a white, light, and porous bread, from an inferior kind of flour, I have my own baker's authority to state, is from 3 to 4 oz. to a sack of flour weighing 240 lbs." " The following account of making a sack of five bushels of flour into bread, is taken from Dr. P. Markham's ' Considerations on the Ingredients used in the Adulteration of Flour and Bread,' (p. 21:) 5 bushels of flour; 8 oz. of alum; 4 lbs. of salt; £ gallon of yeast, mixed with about 3 gal- Ions of water. "Another substance employed by fraudulent BRE 136 BRE bakers is subcarbonate of ammonia. With this salt they realize the important consideration of producing light and porous bread from spoiled, or, what is technically called, sour flour. This salt, which becomes wholly converted into a gaseous substance during the operation of baking, causes the dough to swell up into air bubbles, which carry before them the stiff dough, and thus it renders the dough porous; the salt itself is at the same time totally volatilized during the operation of baking. . . Potatoes are likewise largely, and perhaps con- stantly, used by fraudulent bakers, as a cheap in- gredient, to enhance their profit. . . . There are instances of convictions on record, of bakers hav- ing used gypsum, chalk, and pipeclay, in the man- ufacture of bread." A gentleman, lately writing from the north of England, says that he found in one sample of flour which he recently examined, upwards of 16 per cent, of gypsum, and in another 12 per cent, of the same earth. Sometime since it was discovered that some of the bakers in France and Belgium added blue vitriol to their dough to make it take more water. It is said that they dissolved 1 oz. of this sulphate in a quart of water, and added a wine-glassful of this solution to the water necessary to make about 50 41b. loaves. To the credit of the English ba- ker, no such poisonous materials have ever been found mixed with his bread. This fraud may be discovered by boiling a little of the bread in water, to which 5 or 6 drops of nitric acid have been added, and testing the filtered liquor with prussiate of potash, which will give a brown precipitate if copper be present. Alum may be detected by boiling the bread in water, and adding a little chloride of barium or lime water, or a little water of ammonia, either of which will produce a white precipitate. Chalk, whiting, burnt bones, plaster of Paris, and similar substances are easily detected by burn- ing a little of the flour or bread in a clean open vessel, when the amount of ashes left will indicate the quantity of adulteration. The quantity of ashes left by genuine flour is very trifling indeed. Caution. If you purchase bread from the ba- kers, by all means buy the best. When you make it yourself, however, various additions may be made of a wholesome kind, that will render it cheaper. Thus mashed potatoes, ground bran, potato farina, and several other articles may be added at pleasure. Mixing the flour up with a decoction of bran, pumpkins, Iceland moss, and some other similar substances, has been recom- mended, and it is said that flour so mixed will yield one quarter more bread than when water alone is used, and that it will keep good for some time. BREAD, BEE. This is the matter collected by the bees to form the bottom of the hive ; it re- sembles a mixture of rosin and wax; its fumes are thought to be anti-asthmatic. BREAD, BRAN. Prep. I. Mix with i, a peck of flour, containing the whole of the bran, a -J of a pint of small-beer yeast, and a quart of lukewarm water; stir it well with a wooden spoon until it becomes a thick batter, then put a napkin over the dough, and set it about three feet from the fire, until it rises well. Add, if requisite, a little more warm water, strew over it a tablespoonful of salt, and make the whole into a stiff paste. Put it to the fire, and when it rises, again knead it into tha dough. If baked in tins, the loaves will be im- proved. II. To every pound of flour add \ lb. of braa, and proceed as above. BREAD, EXTEMPORANEOUS. Prep. I. (Ammoniacal Bread.) Dissolve 1 oz. of sesqui- carbonate of ammonia in water, sufficient to make 7 lbs. of flour into a dough, which must be formed into loaves and baked immediately. II. Divide the flour (8 lbs.) into two portions; mix up the first with water, holding in solution 2 oz. of bicarbonate of soda, and the second with the other portion, to which 1 oz. of muriatic acid has been added. When each mass of dough has been separately well kneaded to a proper consist- ence, mix them together (perfectly) as quickly as possible ; form the mass into loaves, and bake im- mediately. Remarks. This bread is considered very whole- some. It contains no yeast. BREAD, FRENCH. Prep. I. i nt 1 pint of milk into 3 quarts of water. In winter let it be scalding hot, but in summer, little more than milk- warm: put in salt sufficient. Take \\ pints of good ale yeast, free from bitterness, and lay it in 1 gallon of water the night before. Pour off the yeast into the milk and water, and then break in rather more than \ lb. of butter. Work it well till it is dissolved ; then beat up 2 eggs in a basin, and stir them in. Mix about 1^ pecks of flour with the liquor, and, in winter, make the dough pretty stiff, but more slack in summer ; mix it well, and the less it is worked the better. Stir the liquor into flour, as for pie-crust, and after the dough is made cover it with a cloth, and let it lie to rise, while the oven is heating. When the rolls or loaves have lain in a quick oven about a quarter of an hour, turn them on the other side for about a quarter of an hour longer. Then take them out and chip them with a knife, which will make them look spongy, and of a fine yellow, whereas rasping takes off this fine color, and renders their look less inviting. II. Proceed as for the best bread; use the finest flour, and moisten it with a little milk. BREAD, FRENCH COUNTRY WHITE This is made without yeast. BREAD, FRENCH SOUP. This is made by adding 1 lb. or more of salt to each sack, in the place of yeast; and it is baked in thin loaves, so as to be nearly all crust, by which means it be- comes more soluble in the hot soup. BREAD, FROM AMERICAN FLOUR- This flour requires nearly twice as much water to make it into bread, as that made from English wheat, and is therefore much more economical. 14 lbs. of American flour will make 21 i lbs. of bread, but the best sort of English flour produces but 184 lbs. (Mrs. Rundell.) BREAD, FROM GRAINS. " Birkenmayer, a brewer of Constance, has succeeded in manufac- turing bread from the farinaceous residue of beer. 10 lbs. of this species of paste, 1 lb. of yeast, 5 lbs. of ordinary meal, and a handful of salt, produce 12 lbs. of black bread, both savory and nourishing.* BREAD, (For one sack.) Flour 1 sack; salt BRE 137 BRE 4 lbs.; water, sufficient quantity ; yeast 4 pints.! Dissolve the salt in 3$ gallons of the water, (warm,) then add a little of the flour and the whole of the yeast; make a dough, and keep it in a warm place until it ;ises, then add more flour and warm water in the same way, and work again ; after 3 or 4 hours add the remainder of the flour, and sufficient water to bring the dough to a proper consistence. When the whole mass of dough is in a proper state, it is to be cut into loaves and baked. Remarks. The bakers employ alum in making their bread, as it not only makes the dough more retentive of moisture, but improves the color of the bread. The proportion is usually 6 or 8 oz. of alum per sack, or even more. By this process a sack of flour will produce from 345 to 351) lbs. of M>eZZ-baked bread, or if slack- baked, from 370 to 385 lbs. of crumbling bread. BREAD, HICK'S PATENT. This is merely bread made in the common way, but baked in an oven so arranged that the vapors arising during the process may be condensed in a suitable re- ceiver. The condensed liquor is a crude, weak spirit, produced during the fermentation of the bread. The product will not pay the expense and trouble of the collection. B It E A D, HOUSEHOLD. (Economical Bread.) Prep. I. Remove the flake bran from the flour, and boil 5 lbs. of it in 4 gallons of water, until it is reduced to 3J gallons ; strain. With this liquor knead 56 lbs. of the flour, adding salt and veast as for other bread. Bake the loaves for 2^ hours. (Rev. Mr. Haggett.) II. Mix 7 lbs. of flour with 3 lbs. of mealy po- tatoes, previously well mashed, add 2 or 3 spoon- fuls of salt, and make a dough with water; then well work it with 3 or 4 spoonfuls of yeast, and af- ter 4 hours bake it. BREAD, IMPROVEMENT OF. A i oz. of carbonate of magnesia added to the flour, for a 4 lb. loaf, materially improves the quality of the bread, even when made from the worst new sec- onds flour. (Professor E. Davy.) This addition is perfectly innocent. BREAD, ICELAND MOSS. This vegetable may be made into bread, either alone, or mixed with flour. It is used, in the first case, in the state of meal, in the same way as flour; in the second case, 7 lbs. of it are directed to be boiled in 12 or 13 gallons of water, and employed to make 70 lbs. of flour into dough, which is then fermented and baked in the usual way. It, is said that the above quantity of flour will produce, in this way, 160 lbs. (?) of good household bread, whereas the same flour, treated in the usual way, would not produce more than 80 lbs. A simpler mode of making this bread, is to mix 1 lb. of lichen meal with 3J; to 4 lbs. of flour. The bitterness of the lichen is extracted by soaking it in cold water. BREAD, LEAVENED. Prep. Take about 2 lbs. of dough of the last making, which has been raised by barm ; keep it in a wooden vessel, cov- ered well with flour. This will become leaven when sufficiently sour. Work this quantity into a peck of flour with warm water. Cover the dough close with a cloth, or flannel, and keep it in a warm place ; further, mix it next morning with 2 or 3 bushels of flour, mixed up with warm water and a little salt. When the dough is thoroughly made, cover it as before. As soon as it rises, well knead it into loaves. Observe in this process, that the more leaven is put to the flour, the lighter the bread will be, and the fresher the leaven, the less sour will it taste. BREAD, PARIS WHITE. Prep. To 80 lbs. of the dough, before the yeast was added, from yesterday's baking, add as much lukewarm water as will make 320 lbs. of flour into a thin dough ; as soon as this has risen, 80 lbs. are to be taken out and reserved in a warm place as leaven for the next baking, and 1 lb. of dry yeast, dissolved in warm water, is to be added to the remaining por- tion, which is immediately made into loaves, and shortly afterwards bated, the loaves being placed in the oven without touching each other, that they may become crusty all round. BREAD, POTATO. Prep. I. To mealy po- tatoes, well milled, add an equal quantity of dough, made with flour, then add a proper quan- tity of yeast, and mix in as much potato farina, or • wheat flour, as will suffice to bring it to a proper consistence. Ferment and bake, as usual. II. Mix equal parts of potato starch and finely- pulped potatoes, and work them into a dough over night, adding the proper quantity of yeast; the next morning work in the same quantity of potato starch, mashed potatoes, and wheat flour, adding as much hot water as may be required ; let it stand to rise, then work it well, cut it into loaves, and in 2 hours put them into the oven. BREAD, SOURNESS IN. (To rectify.) When the dough has become sour from the fer- mentation proceeding too far, or the flour being of inferior quality, the addition of about a \ oz. of carbonate of magnesia, or a little carbonate of soda, will remove it. When it arises from the sourness of the yeast, this method is especially applicable. BREAD, STEAM-BAKED, (a la Vienne.) It has been known for some time at Vienna, that if the hearth of an oven be cleaned with a moisf- ened wisp of straw, bread baked therein imme- diately afterwards presents a much better appear- ance, the crust having a beautiful yellow tint. It was thence inferred that this peculiarity must be attributed to the vapor, which being condensed on the roof of the oven, fell back on the bread. At Paris, in order to secure with certainty so desirable an appearance, the following arrangement is prac- tised :—The hearth of the oven is laid so as to form an inclined plane, with a rise of about 11 inches in 3 feet, and the arched roof is built lower at the end nearest the door, as compared with the far- thest extremity. When the oven is charged, the entrance is closed with a wet bundle of straw. By this arrangement the steam is driven down on the bread, and a golden-yellow crust is given to the bread, as if it had been previously covered with the yelk of an egg. (Hbgen Correspondent, Sept. 27. Ann. of Chym. and Prac. Pharm.) BREAD, TO SWEETEN, (without Su- gar.) It is not generally known that pure starch added to flour and made into dough, will be par- tially converted into a species of sugar during the process of fermentation and baking, and produces sweet wholesome bread. From the experiments of Dr. Colquhoun, it appears that starch arrow- root, farina of potatoes, or similar amylaceous sub- stances, made into a jelly with hot water, may be BRE 138 BRE employed for this purpose with advantage. It is only necessary to mix the flour up with the jelly, instead of mere water, to add yeast and salt, and to bake in the common way- Dr. Percival has re- commended .the addition of salep for this purpose. 1 oz. of salep dissolved in 1 quart of water ; 2 lbs. of flour ; 80 grains of salt, and 2 oz. of yeast, gave 3 lbs. 2 oz. of good bread ; but the same weight of materials, without the salep, gave only 2| lbs. If too much salep be added, however, it will give its flavor to the bread. BREAD, WHITING'S, (Patent.) This is made by dividing the dough into two portions; to the one a little carbonate of soda is added, to the other, a little dilute muriatid acid ; they are both well kneaded separately, then mixed together, formed into loaves, and baked immediately. No yeast is used. BREATH, FCETID. Scarcely any thing is more disagreeable or disgusting than a stinking breath. Various means have been proposed to re- move this annoyance, depending principally on the administration of aromatics, which by their odor might smother it for a time ; but these require con- tinual repetition, and are liable, to interfere with the functions of digestion. The real cause of a stinking breath is either a diseased stomach or ca- rious teeth; when the former is the case aperients should be administered ; and if these do not suc- ceed, an emetic may be given, followed by a dose of salts, or castor oil occasionally. When rotten teeth are the cause, they should be removed; or, if this be impossible, they should be kept clean. Dirty teeth often cause the breath to smell. The use of the tooth-brush should be a daily habit. Occa- sionally rinsing out the mouth with a little clean water, to which a few drops of a solution of chlo- ride of lime, or chloride of soda, has been added, is an effective method. The following lozenges have also been recommended:— Gum catechu 2 oz.; white sugar 4 oz.; orris powder 1 oz.; make them into a paste with mucil- age, and add a drop or two of neroli. One or two may be sucked at pleasure. BREAKFAST POWDER. Syn. Rye Cof- fee. DlLLENIUs's DITTO. Hunt's ECONOMICAL Breakfast Powder. Rye roasted along with a little fat. Use. As a substitute for foreign coffee, of which it is one of the cheapest and best. BREE'S ANTI-ASTHMATIC PLASTER. Prep. Simple diachylon 1 oz.; powdered camphor and powdered opium, of each -J oz.; sweet oil ^ a teaspoonful. Proc. Melt the plaster with the oil, then remove the vessel from the fire, and stir in the powders; spread it on leather before it gets cold. Remark. It is better made with only half the above quantity of opium. BREWING. The art of making beer. General notice. Before entering on a description of the process of brewing, it will be necessary to notice the apparatus and materials required for its conduct. The apparatus consists of, 1. A copper or boiler capable of holding fully two-thirds of the quantity proposed to be brewed; with a gauge-stick to determine the number of gallons of fluid at any given depth therein. A cop- per holding about 140 gallons is a convenient size for brewing a quarter of malt. 2. A mash-tub, or tun, capable of containing rather more than tho copper. 3. One or more tuns, or vessels, to ferment the beer in. 4. Three or four shallow coolers to reduce the wort as rapidly as possible to a proper temperature for fermenting. 5. One or two copper or wooden bowls, for bail- ing, &c. 6. A thermometer with a scale reaching from zero to above the boiling point of water. 7. A suitable number of casks (clean) to con- tain the beer. 8. One or more large funnels, or tunners. 9. Two or more clean pails. 10. A hand-pump of a size proportionate to the brewing. These articles will vary in value from .£10 up- wards, to many hundreds, according to the extent of the brewing ; but the whole of them, necessary for a privato family, may be bought for Itss than the former amount. By proper care they will last for 30 or 40 years, and still be in a useful state. The place where these vessehi are kept, and the operations carried on, is called the " Brewhouse." The materials necessary to brew beer are, good malt, hops, and water, and a little yeast. The malt is bruised or crushed in a mill before brewing, that it may be acted on the more readily by the water. It should not be ground too small, as it would then make the wort thick ; the crush- ed malt may advantageously lie for a few days in a cool situation, by which it will attract a consider- able quantity of moisture from the air, and conse- quently its soluble portion will be the moro easily dissolved out by the water used in mashing. Pale malt may be used coarser than amber or brown malt. A bushel of malt should make a bushel and a quarter when ground, and a quarter should yield between 9£ and 10 bushels, the quantity slightly varying according to the degree of bruising it has undergone. On the large scale, malt is ground in crushing mills, furnished with iron rollers ; and on a small scale, by wooden rollers or small mills worked by hand. For private brewing, the malt is generally bought ready ground, for convenience sake. (See Malt.) The hops should be those of the previous season, and for general purposes grown in Kent; but for the finer sorts of malt liquor, East Kent hops should be used; and where it is intended to be kept for some long time, those known by the names of Country's, Alton's, or Farnham Hops must be employed. The quantity of hops required to a given measure of malt varies from 2 lbs. to 8 lbs. of the former, to 1 quarter of the latter, according to the nature of the brewing. For good strong beer, 4 lbs. or 4$ lbs. is usually sufficient, but when the liquor is very strong, and it is intended to be highly aromatic, aDd to be kept for a long period, 1 lb. of hops may be used to every bushel of malt, or 8 lbs. to the quarter. Mild porter has about 3 lbs. to the quarter, and weak common beer has fre- quently only about \ lb. of hops to the bushel of malt. A portion of hops is also frequently added to the finer sort of beer, after it is casked, as we shall presently explain. The water should be soft and clear, the yeast sweet and good, and all the vessels and casks both BRE 139 BRE tweet and clean. If this be not the case, with the latter especially, the best brewing in the world will be useless. Process of brewing. This may be divided into I. 7 he mashing. This operation consists in placing the ground or bruised malt in a large tub or " tun," known by the name of the " mash-tun," macerating it for some time in hot water, and lastly drawing off the wort from a hole in the bottom, over which a bunch of straw, or a strainer, or false bottom, is placed, to prevent the malt passing out along with the liquor. During the process of mash- ing, a peculiar principle, called by chemists dias- tase, reacts upon the starch also contained in the malt, and converts it first into a species of gum, called by the French chemists " dextrine," and then into a species of sugar resembling that pro- duced by the action of sulphuric acid. The greater the quantity of starch converted into sugar in this way, the stronger and finer will be the wort. It therefore becomes a desideratum with the brewer to mash at a temperature that will most fully pro- mote this object. It has been found that the best temperature for this purpose varies from 157° to 160°, but when more than one liquor is used, the first should be something lower than the former, the next may be between the two, and the third may slightly exceed the latter, or be about 165° or 170°. The action of the first mash is merely to extract the sugar contained in the malt already formed ; that of the second to convert the starch into sugar by the action of the diastase ; the third to fully complete this object, as well as to carry away the remaining portions of extract. The mashing is usually performed by filling the copper with water, and as soon* as it acquires the temperature of 145° in summer, or 167° in winter, 45 gallons are run off into the mash-tun, and 1 quarter of crushed malt gradually thrown in and well mixed by laborious working, until it be- comes thoroughly incorporated and no lumps re- main ; the agitation is then continued for 30 or 40 minutes, when 36 gallons of water from the boiler, at a temperature of 200°, are added, and the whole again well agitated until thoroughly mixed. The mash-tun is now closely covered up, and allowed to stand for an hour or an hour and a half. At the end of this time the tap is set, and the wort is drawn off into tho " underback," and generally amounts to about 50 to 52 gallons: 60 gallons of water, at a temperature of 200°, aro next added to tho mash-tun, previously drained well, and after being well worked, the whole is covered up as be- fore. This mash is allowed to remain for an hour, when it is drawn off, and the malt again drained ready for the third mash. This time only 35 gal- Ions of water are added at 200°, and allowed to stand for J an hour, when it is run off in the same manner as before, and the malt allowed to drain. The worts are now ready for boiling. In some cases only the first and second mash is used for strong beer, and the third kept for table, or as water to mash a fresh quantity of malt with. In Scotland (see Scotch Ale) the brewer only mashes once, and afterwards washes his malt by frequent showers or " sparges" of water, by which he gets a wort of greater strength in proportion to its quantity. In operating as above, the average or mean temperature of the first mash is 145°, of the second 170°, and of the third 180°. In win- ter the mean temperature may be reckoned as 6 or 7° lower. A quarter of malt in this way will produce a wort having a specific gravity by the saccharometer of 1-234, or equal to 84 lbs. of ex- tract. (See Saccharometer.) It is calculated that 32 gallons of the water employed in the mashing remain in the grains af- ter the wort is drawn off. II. Boiling. The wort is next transferred to the copper, and heated to the boiling point as soon as possible. In large breweries where several cop- pers are employed, the first mash is no sooner run into the underback, than it is transferred to the wort copper, and immediately boiled, and the suc- cessive mashings added as soon as drawn off; but in private-houses, where there is only one copper, the boiling cannot be commenced until the water for the last mashing is removed. In some cases the worts are brewed separately, thus producing 2 or 3 qualities of beer, viz. strong ale or stout, beer, and table beer. No sooner has the boiling commenced than the hops may be added, and the boiling continued for 2 or 3 hour« or more. In some breweries the beer is boiled for several hours, and in Belgium it is said that this is even con- tinued for 10 or 12 hours, but too much boiling drives off the flavor of the hops. In general, two hours good boiling will be found sufficient. In small brewings the first wort should be sharply boiled for 1 hour, and the second for 2 hours. But if intended for beer of long keeping, the time should be extended half an hour. The hops should be strained from each preceding wort, and re- turned into the copper with the succeeding one. Between the boilings the fire should be damped with wet cinders, and the copper door set open. For small-beer only half an hour is necessary for the first wort, 1 hour for the second, and 2 hours for the third. It is reckoned that ^ to A_ part 0f the wort is dissipated in steam during the process of boiling, but this must of course depend altogether on the evaporative power of the boiler and the length of time the boiling is continued. III. Cooling. The boiling being finished, the wort is run off from the copper into the hopback, which is furnished with a strainer to keep back the hops. It is then pumped into large square shallow vessels called " coolers," where it is ex- posed to a good current of air to cool it down to a proper fermenting temperature as quickly as pos- sible*. This is of the utmost importance for the success of the brewing. The wort should be laid so shallow as to cool within 6 or 7 hours to the temperature of about 60°. In warm weather, the depth should not exceed 3 or 4 inches; but in cold weather it may be 5 or 6 inches. As soon as the heat has fallen to about 60°, it should be in- stantly tunned and yeasted. It is reckoned that by the joint evaporation from the boilers and coolers, there is a loss of about 40 gallons per quarter. In private families a good way is to bring the wort from the copper in pails, and to pour it into a basket or a hamper, set over the coolers, by which means the hops will be retained, and the beer run through clear. BRE 140 BRE IV. Fermentation. Wrhen the wort is suffi- ciently cool, it is run into the fermenting tuns or vessels, which in small brewings may be casks, with one of their heads removed. These are called " gyle tuns," and should not be more than § full. The yeast, previously mixed with a little wort, and kept until this latter has begun to fer- ment, may now be added, uud the whole agitated well: the tun should then be covered up, until the fermentation is well established. During this pro- cess the temperature rises from 9° to 15°. The qup.i.tity of yeast employed, and the tem- perature of the wort when it is added, differ in different breweries and for different kinds of beer. From £ to 1°; of yeast, taken from a previous brewing of the same kind of beer, is the quantity usually employed. The higher the temperature the less yeast necessary. In England, the tem- perature at which the yeast is usually added, varies from 55° to 65° Fahr. In cold weather, the heats in the coolers should be 5° or 6° higher than in mild and warm weather. For ale, in cold weather, it should be tunned as soon as it has fallen to 60° in the coolers. For porter, to 64°, and for table be.er to 70° ; and in warm weather, strong beer should be 4° or 5° less, and table beer 7° or 8°. Care should be also taken that the worts do not get cold before the yeast is mixed to produce fermentation. The common rule for mix- ing the yeast is 1 £ lbs. to every barrel of strong beer wort, and 1 lb. to every barrel of table beer wort. 'The commencement of the fermentation is in- dicated by a line of small bubbles round the sides of the tun, which, in a short time, extends over the surface. A crusty head follows, and then a fine rocky one, followed by a light frothy head. In the last stage, the head assumes a yeasty ap- pearance, and the color is yellow or brown, the smell of the tun becoming strongly vinous. As 60011 as this head begins to fall, the tun should be skimmed, and the skimming continued every two hours till no more yeast appears ; this closes the operation, and the beer should then be put into casks, or, in technical language, " cleansed." A minute attention to every stage of this process is necessary to secure a fine flavor and a brilliant beverage. In Scotland the temperature at which the yeast is added, is generally much lower than in Eng- land ; for ale, it is from 51° to 52°, and the whole process is conducted in the cooler part of the year, so that the temperature seldom rises higher than 65° or 66°. The Bavarian beer, so much oele- brated on the continent, as well as the finest kinds of East India ale, are fermented at very low tem- peratures. It may be generally regarded as a rule, that the lower the temperature, and the slower, more regular and less interrupted the process of fermen- tation, the better will be the product and the less likely to change by age. More yeast is required in winter than in summer. Should the fermenta- tion become slack in the v\ le tun, a little more yeast is frequently added, and the whole is roused up ; but on the contrary, should the temperature rise considerably, or the fermentation become too active, the wort should be cooled a little and skimmed, or at once cleansed. V. Cleansing. When the fermentation hat proceeded to a certain extent, the liquor under- goes the operation called " cleansing." This con- sists in drawing it off from the gyle tun into other vessels, or casks, set sloping, so that the yeast, as it forms, may work off the one side of the top, and fall into the vessel placed below to receive it. In small brewings, the beer is often at once trans- ferred from the gyle tun to the store casks, which are sloped a little until the fermentation is over, when they are skimmed, filled, and bunged up. When the operation of cleansing is not employed, the yeast is removed from the surface of the gyle tun with a skimmer, and the clear liqua drawn off into the store casks. The process of cleansing should always com- mence as soon as the gravity of the liquor falls to 10 or 11 lbs. per barrel, which it usually does in about 48 hours, provided the fermentation has been well conducted. Some brewers add $ to J lb. of wheat or bean flour to the beer in the gyle-tun, shortly before cleansing, to quicken the discharge of yeast, but it is not clearly ascertained whether such a plan be advantageous or the con- trary. VI. Storing. As soon as the fermenta. on is concluded, which generally takes from 6 to 8 days, or more, the clear liquor is drawn off into the store casks, or vats, which are then closely bunged down, and deposited in a cool cellar. VII. Ripening. After a period, varying from 1 to 12 months, or more, according to the nature of the brewing, the liquor will have become fine, and sufficiently ripe for use. All the attention re- quired during this interval, is to look occasionally to see that there is no leakage, and to open the vent holes, should any oozings appear between the staves of the casks. VIII. Fining. It frequently happens that malt liquor, especially porter, with all the care bestow- ed upon it in brewing, will not turn out sufficiently fine to meet the taste and eye of the consumer, in which case it is usually subjected to the opera- tion of " clarifying." For this purpose 1 oz. of isinglass is put into 1 quart of weak vinegar, or still better, hard beer, and when dissolved, a suf- ficient quantity of good beer may be added to make it measure 1 gallon. This mixture is called " finings;" 1 to 2 pints of which is the proper quantity for a barrel. The method of using it, is to put the finings into a bucket, and to gradually add some of the beer, until the bucket is three parts full, during which time it is violently agitated with a whisk, and this is continued until a good frothy head is raised upon it, when it is thrown into the barrel of beer, and the whole well rum- maged up, by means of a large stick shoved in at the bunghole. In a few days the beer will usual- ly become fine. In some bad sorts of beer isinglass will have no effect. This may be ascertained beforehand, by trying some in a long glass tube, or vial, with a little of the finings. These should be well shaken together, and then set aside for a short time, when it will be found that the finings will rise to the top, leaving the central portion of the beer clear, if it be in a proper condition for clarifying; but if, on the contrary, they sink to the bottom, and the liquor still keeps foul, no quantity of finings, how- BRE 141 BRE ever great, will ever clarify it. This latter defect may be remedied by proceeding to fine it after the manner above described, and then adding, after the finings have been well rummaged up, either 1 spoonful of oil of vitriol, or gum catechu, dissolved in ^ a pint of warm water, again rummaging well for a quarter of an hour. Or 1 or 2 oz. of tincture of catechu may be used instead, mixed with a lit- tle water. Either of these additions acts chemical- ly on the finings, in the same way as good beer does, precipitating them along with the foulness, and thus brightening the liquor. The addition of a handful of hops, previously boiled for 5 minutes in a little of the beer, and then added to the barrel, and the whole allowed to stand for a few days, before proceeding to clarify it, will generally have the same effect. Concluding Remarks. The nature and varie- ties of beer, cj-c. The numerous varieties of beer met with in commerce, arise either from a differ- ence in the materials, or the management of the brewing. Thus the water, but more generally the nature of the malt, or the temperature of the lashing or the fermentation, decides the character of the liquor. The difference between ale and porter arises from the color of the malt, and the distinctions between the same class of liquor, brew- ed from similar materials, may be referred to the mashing or the fermentation. Scotch ale and Bavarian beer differ in style from other ales, as before explained, from being fermented at lower temperatures; and porter differs from either of these, because it has been made with higher dried malt. This is the cause of the almost endless varieties of malt liquor met with in England. Every countny—nay, every town and every brew- er, is distinguished by the production of a different flavored beer. Besides the varieties arising from difference of quality or manipulation in the brew- ing of similar kinds of liquor, there are certain leading features which distinguish some of them, which has led them to be considered in the light of distinct members of the same family. These are ale, beer, and porter. Ale is a pale liquor, brewed from lightly-dried malt, and is usually met with, abounding in undecomposed saccharine mat- ter and mucilage ; beer is a fine, strong, well-fer- mented liquor, darker, less saccharine, and more alcoholic than ale. The finer class of Scotch, Bavarian, and East India ales, properly belong to this class; porter is a dark brown colored liquor, originally prepared from high-dried malt, but now generally made from pale malt, and colored and flavored by patent or burnt malt. Small or table beer is a weak liquor, containing 3 or 4 times the quantity of water that is used for ordinary beer. Stout, brown stout, &c. are varieties of porter, differing only in their strength. See Ale, Beer, and Porter, in their alphabetical order. Qualities. The characteristics of good beer are transparency and a fine color, to whatever variety it may belong ; and if it has been properly brewed, this will usually be the case. Hence color and transparency become a proof of good beer. Good beer is pleasant, wholesome, and nutritious, at the same time that it is strengthening and ex- hilarating. Season for brewing. The best times of year for browing are the spring and autumn, as at those periods the temperature of the air is such as to permit the cooling of the worts sufficiently low, without having recourse to artificial refrigeration, or the use of machinery for that purpose. Adulteration. Laws respecting brewing, $c By the laws of England, which have existed, with slight modifications, ever since the days of Queen Anne, nothing is allowed to enter into the compo- sition of beer but malt and hops. The cupidity of the fraudulent brewer has, however, frequently induced him to introduce other ingredients with the view of imparting a false strength to his liquor, or as a substitute for one or other of its constituents. Thus, to impart bitterness, and to lessen the quan- tity of hops required for the beer, quassia, gentian, wormwood, and broom-tops have been used; to give pungency and flavor, capsicum, and grains of paradise, (in concentrated, tinctures,) ginger, corianders, orange-peel, and caraways; to give intoxicating properties—opium, cocculus indicus, nux vomica, tobacco, extract of poppies and tinc- ture of henbane; as a substitute f^r malt—molas- ses, coloring and sugar ; to impart i false appear- ance of age—sulphuric acid, alum, green vitriol, and common salt. The following is a list of the unlawful substances seized at different breweries, and brewers' druggists' laboratories in London, as copied from the minutes of the committee of the House of Commons. " Cocculus indicus, mu I turn, (an extract of the cocculus,) coloring, honey, hartshorn shavings, Spanish juice, orange pow- der, ginger, grains of paradise, quassia, liquor- ice, caraway seeds, copperas, capsicum, mixed drugs." Sugar and coriander seeds may be mentioned as a very common addition to beer. It is said that 6 lbs. of the former, and 1 lb. of the latter, are equal in strength and intoxicating quality to a bushel of malt. The sugar is employed in a roast- ed state, for the sake of its color ; even coffee has been used for this purpose. Publicans generally reduce their strong beer with water, or table beer, and add treacle, (which they call "foots,") and a mixture of copperas, salt, and alum, (which they call " heading,") to make it bear a frothy head, and in many cases, gentian, sugar, or other similar ingredients, are added to keep up an appearance of strength, and to impart a flavor. The " cheap beer" sold by some taverns in Lon- don, is made by dividing the contents of two butt9 among three butts, filling them up with water, and adding a bladder of porter extract (technically termed p. e.) to each. The desire of evading the duty on malt, led to the discovery of its being only necessary to malt J or less of the grain, this portion being sufficient to convert the starch of the other part into sugar, in the process of mashing. This plan answers well when the wort is merely intended for the produc- tion of "grain spirit," but beer so made is infe rior in quality to that brewed wholly from malt Inferior kinds of beer have also been made from other ingredients than barley malt; thus, the grain of other cereals may be used for this purpose, as wheat, oats, &c, and many other vegetable sub stances that contain starch and sugar. Potatoes, turnips, beet root, carrots, parsnips, and other similar roots and seeds, will all produce beer by peculiar management, but the liquor must be con- BRI 142 BRO fined to private consumption, as the law does not permit its sale. Some of the above articles pro- duce very wholesome beer, if mashed with about yl0- or A- of their weight of good barley malt. The densities of the worts employed for different kinds of beer vary considerably, as will be seen by the following table. Table exhibiting the densities of different kinds of Beer. Description. Pounds per Barrel. Specific Gravity. 40 to 43 1-111 to 1120 35 to 40 1-097 to 1-111 28 to 33 1-077 to 1-092 25 to 27 1-070 to 1-073 21 1-058 40 to 44 1*111 to 1*1-2-2 33 to 40 1-092 to 1-111 18 1-050 18 to 21 1-050 to 1-058 20 to 22 1-055 to 1-060 23 1004 26 1072 12 to 14 1-033 to 1-039 6 1-014 Burton Ale, 1st Class Do. 2d " Do. 3d " Ordinary Ale . . . Common Ale . . . Scotch Ale, 1st Class Do. 2d " Porter (ordinary) . Do. (good) . . Do. (double) . . Brown Stout . . Do. (best) . Table Beer . . . Table Beer (common BREWING UTENSILS, TO CLEAN AND PRESERVE. In cleaning them before being put away, avoid the use of soap, or any greasy mate- rial, and use only a brush and scalding water, be- ing particularly careful not to leave any yeast or fur on the sides, then place them away in a clean, and moderately dry situation. Should they become tainted or mouldy, take a strong lye of pearlash, which spread over the bottoms of the vessels scald- ing hot, and then with the broom scrub the sides and other parts. Or, take common salt and spread it over the coolers, &.c, and strew some on their wet sides, turn in scalding water and scrub them with a broom. Or, throw some quicklime into water in the ves- sel, and scrub over the bottom and sides with it; in each case well washing afterwards with clean water. Or, wash well first with oil of vitriol diluted with 8 times its weight of water, and afterwards with clean water. Remarks. Brewing utensils with care will last for many years. Mr. Cobbett says: " I am now in a farm-house, where the same utensils have been used for forty years ; and the owner tells me that they may last for forty years longer." BRINE, RED CABBAGE. Prep. Steep red cabbage leaves in a strong solution of salt. Use. As a test for acids and alkalis. BRINE, VIOLET. Prep. The same as the above, but made from the petals of the blue violet. BRIOCHE PASTE, (in Cookery.) Prep., $c. A paste made of eggs and flour, fermented with a . ttle yeast, to which a little salt, a large quantity of sugar, and half as much butter as the weight of the flour used, are afterwards added and well worked m. Use. As an addition to soup, a casing for lobsters, patties, eggs, &c. BRITANNIA METAL. Syn. Tutania. A fine species of pewter. Prep. Melt together equal parts of plate brass, bismuth, antimony, and tin, and add the mixture at discretion to melted tin, until it acquires tha proper degree of color and hardness. II. To the last add an equal part, or \ of its weight of metallic arsenic. To be used as before. III. Melt together 1 part of antimony, 4 parts of brass, and 5 or more parts of tin. This may be used at once, as Britannia metal. (See Pewter.) BRITISH GUM. When starch is exposed to a temperature of 300°, (Ure,) 600°, (Brande,) it becomes brown, soluble in cold water, and ceases to strike a blue color with iodine. It is largely employed by the calico printers, as a substitute for gum. BRISTLES AND HORSE HAIR, TO DYE. These readily take any of the usual dyes applied to cotton or wool. BROMAL. A compound discovered by Lo. wig, produced by the action of bromine on alcohol, hence the name, from the first portion of the name of each constituent. (See Chloral.) BROMATES. Compounds of the bases with bromic acid, which see. Char., Tests, <$rc. When heated they evolve oxygen, and become bromides; with nitrate of silver and the proto-salts of mer- cury, they give white precipitates; that with the former is insoluble in nitric acid, but very soluble in ammonia. If a few drops of muriatic acid be added to a bromate, and it be then shaken with a little ether in a glass tube, a solution of bromine is obtained. BROMBENZOIC ACID. A new acid, dis- covered by Peligot, and prepared by exposing ben- zoate of silver to the vapors of bromine, until they cease to be absorbed, when the acid is dissolved out with ether and obtained by evaporation. BROMIC ACID. An acid composed of oxy- gen and brome. Prep. Add sulphuric acid to a solution of bro- mate of baryta, until all the earth be thrown down, particularly avoiding an excess of acid; then concentrate the liquor by heat, until it be of the consistence of a sirup. Prop. If the evaporation be carried too far, the acid will be* decomposed. This acid forms salts with the bases, called bromates, which are very similar to the chlorates and iodates. Bromate of potassa may be made by agitating bromine with a concentrated solution of caustic potassa, collecting the crystalline white powder that falls down, and purifying it by solution in boiling water, and crys- tallization. Bromate of silver is formed by adding a solution of bromate of potassa to another of ni- trate of silver. BROMIDE. A compound form of a base and bromine. (See Bromine.) Char, and Tests. The soluble bromides give white precipitates with nitrate of silver, acetate of lead, and protonitrate of mercury. That from the first of these is insoluble in ammonia water, unless concentrated. A few drops of liquid chlorine poured upon a bromide, and the mixture agitated with a little sulphuric ether, yields an ethereal so- lution of bromine. BROMIDE OF AMMONIA, may be formed by the mixture of ammoniacal and hydrobromic acid gases, or liquid hydrobromic acid and liquor of ammonia, or by putting bromine into water of ammonia. Prop. This salt may be obtained by evaporation BRO 143 BRO in the form of solid white prismatic crystals. It is volatile and easily decomposed. BROMIDE OF CARBON. (Discovered by M. Serullas.) Prep. Brome 2 parts; periodide of carbon 1 part, mix; just enough solution of po- tassa is added to make the liberated iodine disap- pear. The liquid bromide of carbon, which col- lects at the bottom of the solution, is then separa- ted from the supernatant portion, and allowed to Btand until it becomes clear. A few crystals of j iodide of potassium rise to the surface, and may be removed. The clear liquid is then put into a little water slightly alkalized with potassa, to remove a little remaining iodide of carbon, after which it is quite pure. BROMIDE OF IODINE. Bromine and io- dine unite rapidly by mere mixture. By careful distillation a red vapor is obtained, which, on cool- ing, condenses into red crystals, of a form resem- bling fern leaves. This is said to be the protobro- mide. By adding more bromine, these crystals are converted into a fluid, said to be the bibromide. BROMIDE OF SULPHUR. This is made by dissolving sublimed sulphur in bromine ; it is a red- dish, oily-looking fluid, easily decomposed, espe- cially by water. BROMINE. Syn. Brome. An elementary substance, discovered by M. Balard, of Montpel- lier, in 1826. Prep. A current of chlorine is passed through the uncrystallizable residuum of sea-water, called bittern, which then assumes an orange tint, in consequence of bromine being set free from its combinations; sulphuric ether is then agitated with it, and the mixture is allowed to stand until the ethereal portion, holding the bromine in solu- tion, floats upon the surface. This is then care- fully decanted, and agitated with a solution of po- tassa, by which means bromide of potassium and bromate of potash are formed. The whole is next evaporated to dryness, and submitted to a dull red heat; the residuum is then powdered, mixed with pure peroxide of manga- nese, and placed in a retort; sulphuric acid, di- luted with half its weight of water, is now poured in. Red vapors immediately arise, and condense into drops of bromine, and are collected by plung- ing the. neck of the retort to the bottom of a small receiver, containing cold water. The bromine forms a stratum beneath the water, and may be collected and further purified, by distillation from dry chloride of calcium. Prop., Use, should be well beaten in a basin, and strained. The butter should be melted, by being placed in a basin, set in hot water, and afterwards well beaten up with a little warm milk. The lemon- peel should be cut very thin, and beaten in a mortar to a paste or powder, with lump-sugar. The caraways, ginger, and other similar flavoring ingredients, are best used in the form of a fine powder, or under that of an essence, made by di« gesting them in spirits of wine ; the former tat, CAK 151 CAK however, frequently used whole. The milk and water should be each of a good warmth. After all these things are ready, they should be put into a pan, one after another, in proper order, and well beaten up, as the lightness of the cakes will be thereby increased. In plum-cakes, if a little yeast be added after the butter, and the mass be allowed to rise a little, and then again well kneaded, not only less butter and eggs may be used, but the product will be much lighter. It is therefore a great improvement in various kinds of cakes, to introduce a little yeast, even where it is not custo- mary to do so. Good stale bread, well soaked in hot milk or water, and then beaten to a paste, and passed through a fine sieve, forms an excellent thing to mix up the ingredients with, and produces a light and very nutritious cake. Cakes wetted up with milk are richer, but do not keep so well as those without it: they get stale sooner. Pres. Cakes keep best in tin canisters ; wooden boxes, unless well seasoned, are apt to give them a disagreeable taste. Brown paper should be avoided for the same reason. CAKES, ALMOND. Prep. I. Take sweet almonds, flour, and powdered sugar, of each £ lb., eggs 7 in number, and the outside yellow peel of 4 lemons, shredded small. Pound the almonds, previously blanched, until they are very smooth, adding gradually the sugar and lemon-peel, then take them out, add the eggs, and beat the whole until it be as white as sponge paste; next add the flour, work well, put it into well-buttered moulds, and bake in a slack oven, with 8 or 10 thicknesses of paper under them and one over them. II. Almonds 1 lb.; sugar $ lb.; rose, or orange- flower water, £ pint; flour £ lb. ; eggs 3 in num- ber, as above. Remarks. Some persons ice these cakes with powdered sugar, beat up with a little white of egg. CAKES, BANBURY. Prep. Work butter 1 lb. into the same weight of dough, made for white bread, as in making puff paste, then roll it out very thin, and cut it into oval pieces, or as the cakes are wanted. Mix some good moist sugar with an equal weight of currants, and wet them with brandy, then put a little upon each piece of paste; close them up, and place them on a tin with the closed side downwards, and bake them. Flavor some powdered sugar with candied peel, grated, or essence of lemon, and sift a little over the cakes as soon as they come out of the oven. CAKES, BATH. Prep. Mix well together i lb. of butter, 1 lb. of flour, 5 eggs, and a cupful of yeast. Set the whole before the fire to rise, which effected, add 4 oz. of finely-powdered sugar, and 1 oz. of caraways; roll the paste out into little cakes. Bake them on tins. CAKES, BENTON TEA. Prep. Make a paste with flour 1 lb., butter 4 oz., and milk suf- ficient ; roll it out very thin, cut it into shapes, and bake on a hot hearth or slow oven-plate. II. To the last add 4 tablespoonfuls of yeast, and prick the cakes all over with a fork. CAKES, CHEESE. Prep. Curdle some new milk previously warmed, with rennet, drain the curd in a linen bag, then beat it as fine as butter, and add £ of its weight, each, of sugar and butter, 6 eggs, some grated nutmeg, and a little orange- flower or rose water; work the whole well to- gether. II. (Almond.) To the above add as much blanched almonds, beaten to a smooth paste, as there is butter, along with an equal weight of ma- caroni. Beat well together. III. (Lemon.) To the first form add lemon-peel grated fine, or a little essence of lemon CAKES, DIET. Prep. Dissolve sugar 1 lb. in milk i pint, add 6 eggs, and whisk to a full froth, then cautiously stir in flour 1 lb., beat it for 1 hour, and immediately bake it in a quick oven. It may be baked whole or divided into small forms. CAKES, DIET BREAD. Prep. Make a paste with equal parts of fine flour and powdered sugar, 6 eggs, and the juice and rind (grated) of 1 lemon. Bake in a slow oven. CAKES, DROP. Prep. Eggs 1 dozen ; rose- water 1 tablespoonful; powdered sugar ^ lb.; beat them together for 1 hour, then add \ lb. of fine flour, and £ oz. of caraways. Drop it on wafer paper, and bake. CAKES, GINGER. Prep. Make a paste with sugar 1 lb.; powdered ginger 4 oz.; flour 2 lbs.; water 1 pint; butter £ lb.; and 8 caps of candied orange peel, grated; form them into cakes, and prick them with a foTk before baking them. CAKES, ICING FOR. Prep. Beat the white of eggs to a full froth, with a little rose or orange- flower water; then add, gradually, as much fine- ly powdered sugar as will make it thick enough, beating it well all the time. Use. Dust the cake over with flour, then gently rub it off, lay on the icing with a flat knife, stick on the ornaments while it is wet, and place it in the oven for a few minutes to harden, but not long enough to dis- color it. CAKES, LEMON. Prep. Flour and sugar, of each 1 lb.; eggs 1 dozen ; grated peal and juice of four lemons ; whisk the eggs to a high froth, then gradually add the rest. Bake in small oval tins, well buttered, and place six thicknesses of paper beneath each tin. Thinly ice them. CAKES, MARLBOROUGH. Prep. Beat 8 eggs and 1 lb. of pounded sugar three-quarters of an hour ; then by degrees mix in 1 lb. of fine flour well dried; add 2 oz. of caraway seeds, and bake in soup plates or tin pans, in a brisk oven. CAKES, PLAIN. Prep. I. Flour 4 lbs.; cur- rants 2 lbs.; butter £ lb.; caraway seeds £ oz.; candied lemon peel, grated, 1 oz.; wet it up with milk, and J a pint of yeast. Let it rise well before baking. II. Baker's dough 2 lbs.; currants 1 lb.; butter £ lb.; 3 eggs ; milk (hot) £ pint. As above. III. " The following is a receipt for making a good plain cake, fit to be given to children at breakfast, instead of buttered bread. " Take as much dough as will make a quartern loaf, (either made at home or procured at the ba- ker's,) work into this a £ pound of butter, a £ pound of moist sugar, and a handful of caraway seeds When well worked together, pull into pieces the size of a golden pippin, and work it together again. This must be done three times, or it will be in lumps, and heavy when baked" IV. (Rich.) Equal weights of flour, butter, sul- tana raisins, eggs, currants, and brown sugar, CAK 152 CAK mixed up with milk, and seasoned with candied peel, nutmeg, &c. Bake in a quick oven. OAKES, PLUM. Prep. I. (Good.) Mix $ lb. of butter in 3 lbs. of dry flour and 8 oz. of fine Lis- bon sugar; add plums and currants, of each £ lb., washed and dried, and some pimento, finely pow- dered. Put 3 spoonfuls of yeast into a Winchester pint oi new milk warmed, and mix it into a light dough with the above. Make it into a cake, and bake on a floured tin half an hour. II (Excellent.) Beat 1 lb. of fresh butter with a strong wooden fork until it resembles cream ; add 1 lb. of sifted sugar, and mix them very completely ; have ready the whites of 10 eggs beaten, and pour them into the butter and sugar; then add the yelk of 18 eggs, also well beaten, and beat them all up for 10 minutes. Take 1 lb. of flour, 2 oz. of pounded and sifted spices, viz. cloves, mace, cinnamon, nut- meg, and allspice, and mix them by degrees with the other ingredients, then beat the cake 10 minutes longer; and when the oven is ready, add 1 lb. of currants, 4 oz. of sliced almonds, 4 lb. of raisins stoned and chopped, and a large glass of brandy. Bake the cake in a hot oven. When sufficiently baked, let the oven cool, and afterwards put in the cake and allow it to remain for several hours to dry. (Rundell.) III. (Rich.) Take fresh butter and sugar, of each 1 lb.; of flour 1£ lb.; of currants 2 lbs.; a glass of brandy, 1 lb. of sweetmeats, 2 oz. of sweet almonds. 10 eggs, £ oz. each of allspico and cinna- mon. Melt the butter to a cream, and put in the sugar; stir it till quite light, adding the allspice and pounded cinnamon; in a quarter of an hour take the yelks of the eggs, and work them in, 2 or 3 at a time; and the whites of the same must by this time be beaten into a strong snow quite ready to work in, as the paste must not stand to chill the butter, or it will be heavy; work in the whites gradually ; then add the orange peel, lemon, and citron, cut in fine stripes, and the currants, which must be mixed in well, with the sweet almonds; then add the sifted flour and glass of brandy. Bake this cake in a tin hoop in a hot oven for 3 hours, and put 12 sheets of paper under it to keep it from burning. (Mackenzie.) CAKE, POUND. Prep. I. As the above; but use 1 lb. each of all the ingredients, except the spices. II. Use equal parts of sugar, flour, currants, and Hultana raisins, and half that quantity each of but- ter, brandy, and candied peel, with spices as re- quired. CAKES, PORTUGAL. Prep. Flour, pow- dered sugar, and fresh butter, of each 1 lb.; work it well up until it crumbles, then add 10 eggs, cur- rants 4 lb., and a little white wine. Bake it in small tins only half filled. CAKES, QUEEN. Prep. Mix 1 lb. each of dried flour, sifted sugar, washed clean currants, and butter, with 8 eggs, beaten separately; beat the whole an hour ; butter little tins, teacups, or saucers, and bake the batter in, only half filling them. Sift a little fine sugar over, just before you bake them. A little nutmeg, mace, and cinnamon are sometimes added. CAKES, RATIFIA. Prep. Beat 4 lb. of sweet and 1 oz. of bitter almonds in fine orange, rose, or ratafia water; mix in 4 lb. of fine pounded and sifted sugar with the same ; add the whites of 4 eggs, well beaten, to it ; set it over a moderate fire in a preserving-pan ; stir it one way until it is pretty hot, and when a little cool form it into small rolls, and cut it into thin cakes ; shake some flour lightly on them, give each a light tap, and put them on sugar papers; sift a little sugar on them, and put them into a thorough slack oven. CAKES, ROUT. Prep. Mix together flour 2 lbs.; butter, sugar, and currants, of each 1 lb.; wet them up with 3 eggs well beaten, 4 pint of milk, 2 glasses of white wine, and 1 glass of brandy; drop on a tin plate, and bake them. They are soon done. CAKES, SAVOY. Prep. To 1 lb. of fine sifted sugar put the yelks of 10 eggs, (have the whites in a separate pan,) and wt it, if in summer, in cold water; if there is any ice set the pun on it, as it will cause the eggs to be beat finer ; then beat the yelks and sugar well with . wooden spoon for 20 minutes, and put in the rind oi a lemon grated; beat up the whites with a whisk until they become quite stiff, and white as snow; stir them into the batter by degrees, then add 1 lb. of well-dried flour. Finally, put it into moulds, and bake in a slack oven. CAKE, SEED. Prep. I. (Plain.) Mix £ peck of flour with 4 lb. of sugar, £ oz. of allspice, and a lit- tle ginger ; melt 4 lb. of butter with 4 pint of milk; when just warm, put to it £ pint of yeast, and work up to a good dough. Let it stand before the fire a few minutes before it goes to the oven: add seeds, or currants; bake an hour and a half. II. (Good.) To the preceding add butter and sugar, of each 4 lb., and wet it up with milk pre- viously mixed with 6 eggs. III. (Rich.) Take of flour 1$ lb., well dried, butter and sugar, of each 1 lb., 8 eggs, and 2 oz. of caraway seeds, 1 grated nutmeg, and its weight in cinnamon. Beat the butter into a cream, put in the sugar, beat the whites of the eggs and the yelks separately, then mix them with the butter and su- gar. Beat in the flour, spices, and seed, a .ittle before sending it away. Bake 2 hours in a puick oven. IV. (Scotch.) Eggs 9 in number; sugar and butter, of each 4 lb.; mix well together, then add a little cinnamon, grated nutmeg, and cloves, £ oz of caraway seeds, 1 lb. of candied citron, £ lb. of candied orange peel, and 4 lb. of blanched almonds, pounded fine ; mix well; then add flour 3 lbs., and brandy £ pint; work well and bake it CAKES, SHREWSBURY. Prep. Flour 3 lbs.; sugar 1 lb.; a little cinnamon and nutmegs; eggs 3 in number; a little rose water and melted butter, enough to make it into a dough. Roll it thin, and cut it into shapes. CAKES, SODA. Prep. Flour 1 lb.; bicar- bonate of soda £ oz.; sugar and butter, of each i lb.; currants | lb.; make a paste with milk, and add candied orange, lemon, or citron peel, or the fresh peek grated, according to fancy. Remarks. A £ oz. of carbonate of magnesia, used instead of the soda, also makes good cakes, very suitable to delicate stomachs, especially if the candied peels be omitted. CAKE, SPONGE. Prep. 8 eggs, £ lb. of lump sugar; 4 lb. of flour; £ pint of water; the peel of a lemon: mix as follows:—Overnight pan CAL 153 CAL a good-sized lemon thin, and put the peel into the water ; when about to make the cake, put the su- gar into a saucepan, pour the water and lemon peel to it, and let it stand by the fire to get hot. Break the eggs into a deep earthen vessel that has been made quite hot; whisk the eggs for a few minutes with a whisk that has been well soaked in water; make the sugar and water boil up, and pour it boiling-hot over the eggs; continue to whisk them briskly for about a quarter of an hour, or till they become quite thick and white, which is a proof of their lightness. Have the flour well dried, and quite warm from the fire, just stir it lightly in, put the cake into tins, lined with white paper, and bake them immediately in a moderately hot oven. (Mrs. Rundell.) CAKES, STAINS FOR. Prep. I. (Red.) a. Boil £ oz. of cochineal in powder, 4 oz. of cream of tartar, and a piece of alum as large as a pea in 4 a pint of water, for 4 an hour. /?. Shred beet root into a little water, let them stand a short time, then express the juice. y. Dissolve a few grains of*%armine in spirits of hartshorn. This gives a fine color, and also tends to make the cake light. II. (White.) Use almonds, blanched and beat- en very fine ; or use cream. III. (Yellow.) a- Use yelk of egg. 0. A little saffron, steeped in hot water. Y. A little turmeric, steeped in a little gin or hot water. <5. Infuse marygold or stertian flowers in hot water. IV. (Green.) The juice of spinach or beet leaves, obtained by pounding and expression. V. (Blue.) a. A little finely-pounded indigo diffused in water. /?. A few drops of liquid blue, added to water. y. The juice of mulberries, elderberries, privet berries, &lc, to which a little salt of tartar has been added. <5. An infusion of logwood, mixed with a little salt of tartar. £. The juice of any of the blue flowers. CAKES, TIPSY. Prep. Steep small sponge cakes in brandy, then cover them with grated al- monds and candied peel, or almonds cut into spikes and stuck in them ; pile them in a dish, surround them with a custard, and cover them with pre- serves, drained as dry as possible. CAKES, WIGG. Prep. Put 4 pint of warm milk to £ lb. of fine flour, and mix in 2 or 3 spoon- fuls of light yeast. Cover it up, and set it before the fire 1 hour, in order to make it rise. Work into it 4 oz. each of sugar and butter, make it into cakes, or wiggs, with as little flour as possible, and a few caraway seeds, and bake them quickly. CALAMINE. Syn. Calamina. Lapis Cala- minaris. Crude Carbonate of Zinc. Source and Prep. Native carbonate of zinc occurs in great abundance in various parts of England and Ger- many. For medicinal purposes, it is ground in mills until reduced to fine powder, and then sub- mitted to the process of elutriation, or washing over, as in the preparation of chalk. In this state it constitutes the " prepared calamine," (P. L.,) the '•impure carbonate of zinc," (P. E.,) and the " la- pis calaminaris praparatus," (P. D.) Prop., Use, 6cc. It is drying and astringent; 20 frequently used as a dusting Dowder for children, for excoriations and ulcers, and as an ingredient in calamine cerate. It is also largely used in metal- lurgy to furnish zinc and to make brass. Pur. The article generally sold in the shops as lapis calaminaris, does not contain a particle of this substance. It is a mixture of heavy sulphate of baryta (cawk) and chalk, colored with American bole. Mr. Brett found it to contain 75g to 87*5°j of sulphate of baryta. Tests. It should be wholly or nearly soluble in dilute sulphuric acid, evolving only a few bubbles of gas during the solution. On the addition of li- quor of ammonia or potassa, a white precipitate is formed, which is redissolved in excess of the pre- cipitant. CALCINATION. Calx, Calcis, (in Chemis- try.) The operation of the fire on any substance, or the process of burning, is called calcination, and the residuum, or cinder, was formerly called the calx or calces, (plur.) Thus,—chalk, by burning, is converted into lime; gypsum into plaster of Paris; wood into charcoal, and bones into ivory- black. Proc. The method of conducting the pro- cess of calcination depends upon the nature of the body operated on. Many substances, for delicate experiments, are calcined over a spirit-lamp in a platina spoon, or crucible ; others in iron vessels or earthen crucibles, placed in a common furnace. When the action of the air would prove injurious, as in the manufacture of charcoal, 'the process is performed in close vessels or chambers. In some cases, the fuel is mixed with the article, and they are both burnt together, as in the manufacture of lime, in the common kiln,—in the roasting some kinds of ores, &c. The process of drying salts, or driving off their water of crystallization, is also frequently called calcination ; thus we have cal- cined copperas, alum, &c. CALCIUM. This is the metallic base of lime. It was discovered by Davy, and is prepared in the same way as the metal Barium. Prop. It is a whiter metal than either barium or strontium, and, by oxidation, yields quicklime. It also forms a peroxide with an additional dose of oxygen, which may be made in the same way as peroxide of ba- rium. .. It unites with bromine, forming a bromide; with fluorine, a. fluoride ; with iodine, an iodide ; and with phosphorus, a phosphoret of calcium. CALCIUM. CHLORIDE OF. Syn. Hydro- chlorate of Lime. Muriate of Lime. Prep. Saturate dilute muriatic acid with chalk or white marble ; then filter, evaporate, and crystallize. Remark. The London College orders the salt to be evaporated to dryness, then placed in a crucible, fused with a quick fire, and poured out on a clean flat stone. WThen cold, it is to be broken to pieces, and kept in close bottles. The Edin. Ph. directs white marble to be used, and the salt to be crys- tallized. The Dublin Ph. orders the residual liquor of the preparation of liquor of ammonia, from sal ammoniac and lime, to be filtered and evaporated. This is the cheapest method. Props., Use, $c. From the strong affinity this salt has for water, it is much used for drying gases and absorbing the water from ethereal and oily li- quids, in organic analyses. For this purpose it is used in the dry state. In its hydrous or crjstal- lized form, it is much used in the preparation of CAL 154 CAL freezing mixtures with snow. In this case, the evaporation need only be conducted so far that the whole becomes a solid mass on removal from the fire. For both this and the last-mentioned use it is reduced to powder. It is also much used as a test for sulphuric acid, with which it produces a white precipitate insoluble in nitric acid; in the rectification of alcohol, and for forming a water- bath with a high boiling point. As a medicine, it has been given in some scrofulous and glandular diseases, and has also been used as a bath in the same cases. CALCIUM, SULPHURET OF. Prep. I. (Bi- sulphuret.) Boil together for 1 hour slaked lime 3 parts, sulphur 1 part, and water 20 parts ; set aside the solution (sediment and all) in a corked flask for a few days, when orange-colored prismat- ic crystals will be deposited. II. (Protosulphuret.) Fuse equal parts of sul- phur and lime, or sulphate of lime and charcoal, mixed together in a crucible. Props., ticc. Acrid and caustic ; yields pure sul- phur on the addition of muriatic acid. Used to make precipitated sulphur. CALICO FURNITURE, PRESERVATION AND CLEANING OF. Curtains, bed-hangings, &.C., when taken down for the summer, should be well shaken, to remove the loose dust; after which they should be brushed with a long-haired clothes' brush; and lastly, rubbed with pieces of stale crumb of bread which are not too hard. They may now be folded up and placed away in any dry closet or cupboard. While colored calico furniture is up, it should be screened as much as possible from the light, which makes it fade, and the dust which accumu- lates on it may be blown off with a pair of strong bellows. CALICO PRINTING. The art of producing figured patterns upon calico, by means of dyes or mordants topically applied by wooden blocks, cop- per-plates, or engraved cylinders, by which the goods are either directly printed or receive their color by being run through a coloring or mor- dant bath, when the dye is only produced upon that portion of the ground previously prepared for it. The mordants are thickened by some glutinous substance, as flour, starch, gum, &c, to render them adhesive and to prevent their spreading. There are eight styles of calico-printing, each requiring a different method of manipulation. 1. The madder, or chintz style. In this meth- od the mordants are applied to the white cloth, and the colors brought out in the dye-bath. In this way the patterns on permanent prints are pro- duced. 2. The padding, or plaquage style. Here the whole cloth is passed through a bath of the mor- dant, and different mordants afterwards printed on it before submitting it to the dye-bath. By this means the color of the ground and pattern is varied. 3. The reserve style, in which white or colored spots are produced on a blue ground, by covering those parts with a composition called resist paste, before passing it through the dye-bath, which is usually done cold. 4. The discharge, or rongeant style, is the re- verse of the preceding; it exhibits bright figures on a dark ground. It is performed by printing with acidulous or discharge mordants before the cloth is passed through the coloring-bath. 5. China blue, or a style resembling that on blue stone-ware. 6. The decoloring or enlavage style, which is performed by the topical application of chlorine oi chromic acid to the surface of the goods previously dyed, by which the color is discharged. (See Ban- danna.) 7. Steam-color printing. A 6tyle in which a mixture of dye exti.-cts and mordants are printed on the calico, and afurwards exposed to the ac- tion of steam. 8. Spirit-color printing. A method by which brilliant colors are produced, by a mixture of dye extracts and solution of tin, called by the dyers " spirits of tin." For further information on this subject, the reader is referred to Ure's " Dictionary of Arts, Manufactures, and Mines," where he will find the several processes of calico printing fully treated on. To enter largely into the subject in this work might amuse the reader, but would be of no prac- tical utility, as calico-printing is an art only prac- tised on the large 6cale, and by men who obtain their whole knowledge of it hi the laboratories and printing rooms of the factories. CALOMEL. Syn. Chloride of Mercury. Protochloride of do. Subchloride of do. dlchloride of do. muriate of do. submu- riate of do. Sweet Mercury. Sweet Sub- limate. Sweet Precipitate. Hydrargyrum Chloridum, (P. L.) Chlorure de Mercure, (Fr.) Versusstes-zucksilber, (Ger.) A com- pound of chlorine and metallic mercury. The word is probably derived from icaXds fair, and uiXas black. Prep. There are two methods of preparing cal- omel, viz. by sublimation and by precipitation. I. (By sublimation.) a. (Process of the London Ph.) Ing. Mer- cury lb. iv; sulphuric acid lb. iij; chloride of so- dium lb. iss; distilled water q. s. Proc. Boil half the mercury with the sulphuric acid in a proper vessel until the bipersulphate thus formed remains dry; let it cool, and rub it with the remaining half of the mercury in an earthen mortar until they be perfectly mixed ; next add the chloride of sodium, and again triturate, until globules are no longer visible, then sublime ; lastly, rub the subli- mate to a very fine powder, wash it with boiling distilled water, and dry it. The processes of the P. E. and P. D. are nearly similar. 0. (Process employed at Apothecaries' Hall, London.) Mercury 50 lbs.; sulphuric acid 70 lbs.; boil to dryness in a cast-iron vessel; tritu- rate 62 lbs. of the dry salt thus formed with 404 lbs. of mercury, until the globules disappear, and add 34 lbs. of common salt, and again triturate until perfectly mixed; then sublime. Grind the sublimate to an impalpable powder, well wash it with distilled water, and dry it. Prod. 95 to 100 lbs. y. (Jewel's patent process.) This consists in keeping the receiver filled with steam, so that the calomel vapor is condensed in it under the form of an impalpable powder. CAL 155 CAL The annexed engraving represents M. O. Hen ry's modification of this plan. a, Furnace. b, An eartlienware retort, having a short and wide neck, containing the ingredients for making calomel. c. An earthen receiver having 3 tubulatures. d, A vessel containing water. e, A steam boiler. S. Soubeiran proposes the following method ai better than that with steam, being easier to exe^ cute and producing a beautiful preparation. The calomel is heated in an earthen tube in a furnace, and a current of air is directed uninterruptedly into the tube by means of a small ventilator. This sweeps away, as it were, the vapors of calo- mel, and in a straight tube will carry them a dis- tance of 60 feet, to avoid which the end of the recipient enters into water, by which means the calomel is moistened and falls down. (Compt. Rend., 1842, 665.) Remark. The long-continued action of steam on calomel in a state of minute division is attend- ed by the formation of a small quantity of corro- sive sublimate. (Rhighini.) II. (By precipitation.) Digest 9 parts of pure quicksilver in 8 parts of nitric acid, sp. gr. 1*20 to 1-25, until no more metal will dissolve; then mix it with a boiling solution of 8 parts of com- mon salt in 32 times its weight of water, to which a little muriatic acid has been added. The pre- cipitate must be collected, well washed in distilled water, and dried. Remarks. The last is not only the best but the cheapest process for making calomel. That by sublimation is, however, generally adopted. To produce a fine article of calomel in the dry way is somewhat difficult, and the process frequently fails in the hands of unskilful operators. It is only lately, and that through the exertions of the per- severing and talented Soubeiran, that the French manufacturers have at all succeeded in producing calomel of equal quality to that made in England. This will show that much practical experience is required to ensure success. The solution of the quicksilver is best made in an iron vessel, and the sublimation should be conducted (preferably) in an earthenware retort, having a short but very wide neck, and fitted to a spacious receiver, hav- ing a large flat bottom, also of earthenware. A little cold water is put into the latter. For small quantities the heat may be applied by means of a sand-bath. The form above given for calomel, by precipitation, produces a large product, perfectly free from corrosive sublimate and subnitrate of mercury, and is consequently free from the objec- tions frequently raised against that mode of prep- aration. " The form in which ca'.omel sublimes depends much upon the dimensions and temperature of the subliming vessels. In small vessels it generally condenses in a crystalline cake, the interior sur- face of which is often covered with beautiful quadrangular prismatic crystals, transparent, and of a texture somewhat elastic or horny. In this state it acquires, by the necessary rubbing into powder, a decidedly yellow or buff color, more or less deep, according to the degree of trituration it has undergone. If, on the contrary, the calomel be sublimed in a very capacious and cold receiver, it falls in an impalpable and perfectly white pow- der, which requires only one elutriation to fit it for use, it then remains perfectly colorless. " This accounts for the various appearances un- der which calomel is met with in commerce. It may be added, that the buff aspect of this sub- stance indicates the absence of corrosive subli- mate ; though it by no means follows, as a con- sequence, that when snow-white it contains it When the surface of massive sublimed calomel is scratched, it always exhibits a buff color; it also becomes yellow when heated, but loses its tint as it again cools." (Brande.) 100 parts of mercury, if well managed, will produce 118 parts of calomel. Pur. Calomel is frequently contaminated with small quantities of the bichloride or subnitrate of mercury. The former may be detected by di- gesting a little of it in alcohol, decanting the clear portion, and testing it with a drop or two of liquor of potassa, when a reddish precipitate will be formed, if any bichloride be present. The sub- nitrate may be detected by digestion in dilute nitric acid, and the addition of a little liquor of potassa, as before, when a similar precipitate will fall down if it be contaminated therewith. In " The London Pharmacopoeia," the follow- ing are mentioned as tests of its purity:—Black- ened by potassa, and forms into globules by the application of heat. Heat totally dissipates it. Water in which it has been washed should give no precipitate with either nitrate of silver, lime- water, or sulphureted hydrogen. The Ed. College states, that ether agitated with calomel, filtered, and evaporated to dryness, leaves no crystalline residuum, and what may be left is not turned yellow with liquor of potassa. Tests. Calomel may be recognised by—1. It turns greenish-yellow when digested in a solution of iodide of potassium. 2. Intensely black when digested in liquor of potassa, or ammonia in ex- cess. 3. Digested in strong nitric acid, it dissolves, and the solution gives a red precipitate, both with iodide of potassium and liquor of potassa, and a cloudy white one with nitrate of silver, the latter being rapidly darkened in the light, and insoluble in nitric acid, but readily so in liquor of ammonia. Use, Sec. Calomel is one of the most valuable of the mercurials, and, perhaps, of all medicines as an alterative. It is frequently given in doses of 4 to 1 gr., generally combined with antimonials, as in Plummer's pill. As a purgative 2 to 5 grs. either combined with or followed by other purga- tives, as jalap, rhubarb, senna, colocynth, Epsom salts, &c. As a vermifuge, 2 to 5 grs. overnight, followed by a dose of castor oil next morning. Combined with opium, it is frequently used in va- rious complaints to produce salivation. It is also employed as a sialogogue, sedative, and errhine. CAM 15b CAM It is, perhaps, more frequently used, and in a greater variety of complaints, than any other medicine. CALUMBINE. Syn. Calombine. The bit- ter principle of calumba root. It is extracted by alcohol or ether from the root, reduced to a coarse powder, and is purified by repeated resolutions and evaporations. When pure, it forms prismatic crys- tals, or delicate white needles ; it readily combines with acetic acid, and the compound is intensely bitter; hence vinegar, or sour wine, would be the best menstruum to make infusion of calumba with. The properties of calumbine are similar to those of calumba root. CALVES' FEET JELLY. Prep. For each foot take 3 pints of water, and boil it to one-half; then let it cool, and skim off the fat. It must now be boiled for 2 or 3 minutes, with the peel of a lemon, and a little spice, when it should be re- moved from the fire, strained through a flannel bag, and the juice of a lemon and a glass of wine added; wheii cooled a little, it may be put into glasses or forms. Remarks. If wanted very transparent, the jelly, after the fat is removed, should be gently warmed, just enough to melt it, and then well beaten with the white of an egg and the seasoning, after which it must be brought to a boil for a minute or two, when it will be ready for straining, and being mixed with the wine. The addition of a little beet- root juice will give it a beautiful color. The calf's feet should not be bought ready boiled, but only scalded. Cows' feet or heels make as good jelly as that from calves' feet, and are much more eco- nomical. CALX OF ANTIMONY. Syn. Diaphoretic Antimony. Impure antimonious acid, prepared by deflagrating crude antimony with 3 times its weight of saltpetre. CAMELEON, MINERAL. Prep. Heat to redness a mixture of equal parts of black oxide of manganese, and nitre or potassa. Prop., Sec. When dissolved in water, its solu- tion, at first green, passes spontaneously through all the colored rays to the red, when, if potassa be added, the color retrogrades until it reaches the original green. The addition of oil of vitriol, or chlorine, renders the solution colorless. The addi- tion of a weak acid, or even boiling or agitating the liquid, will turn it from green to red. CAMERA LUCIDA. An instrument invent- ed by Dr. Wollaston, for the purpose of enabling persons ignorant of drawing or perspective, to trace the outlines of distant objects or landscapes with accuracy. Prin. and Cons. When a ray of light (r) falls upon a quadrangular glass prism, (a,) it is bent by two reflections, (at c and d,) and thrown upwards where it may be received by the eye, to which it will appear described on the table or sheet of pa- Per» (/>) placed to receive it. The point of a pencil used to trace any object on the paper, can also be seen, and by its means the picture may therefore be easily copied. Various modifications of this in- strument exist. When the prism is mounted on a stand, and a thin brass plate, with a small hole through it for the eyepiece, adjusted thereto, it forms the instrument sold by the opticians. The image may be magnified or lessened by placing a lens, so as either to intercept the rays before they strike the prism, or before they reach the eye. An ingenious person will readily be able to set up this instrument. CAMERA OBSCURA Literally, a daik chamber. An optical app^iatus, by which the im- ages of external objects are thrown upon any white surface, placed in an obscure situation to receive them, whereby they are represented in their natu- ral forms and colors. Prin. and Cons. A convex lens (B) is placed in a hole admitting the light into a darkened box or chamber, (A,) which, falling on a white ground (D) within the room, produces an inverted picture of every object within its range. The image thus formed may be restored to its natural position, by allowing the rays of light to pass through two lenses instead of one, or by receiving the rays on a mirror placed at an angle of 45°, when the im- age will be thrown on the floor in its original posi- tion. The picture may be viewed through an ob- long aperture cut in the box, or the experiment may be performed in a darkened room, by placing the lens in a hole in the shutter, allowing the im- age to fall on the wall, (white,) or a sheet of paper stretched to receive it. The following engraving will explain the construction of this instrument. A, A box formed of two parts, to slide one within ths other, to adjust the screen or hind wall to receive the imnge. B, Convex lens. C, External object. D, Ditto painted in a reversed position on a screen or wall. When intended as an instrument for taking views or portraits, the image is thrown upon a mirror placed* at an angle of 45°, and resting on the bottom of the box, by which means it is thrown upwards against a plate of glass, also placed at a similar angle. On this is laid a piece of semi- transparent paper, when the object is seen painted on it, and may be traced out with a pencil. CAMPHOR. Syn. Camphire. Kampkuk. Camphora, (Lat.) Hist, and Source. The cam- phor of commerce is a natural production. It is principally extracted from the laurus camphora, or laurel camphor tree, but it is also found il several other members of the vegetable kingdom CAM 157 CAM It is occasionally found in small masses, between the bark and the wood, in a perfectly pure slpte. The Chinese and Japanese extract the camphor by cutting the wood into small pieces, and boiling it with water in iron vessels,—which are covered with large earthen capitals or domes.—lined with rice straw. As the water boils, the camphor is volatilized along with the steam, and condenses on the straw, under the form of grayish granulations. In this state it is collected and transported to Eu- rope, when it undergoes the process of refining into white camphor. Proc. of Refining. 100 parts of crude camphor are mixed with 2 parts each of quicklime andt ani- mal charcoal, and placed in a thin globular glass vessel, sunk in a sand-bath. The heat is then cautiously applied, and the vessel gradually and carefully raised out of the sand as the sublimation goes on. When this "is completed, the whole is allowed to cool. Remarks. If the process be conducted too slow- ly, or at a heat under 375° Fahr.. the product will be flaky, and consequently unsaleable, with- out remelting or subliming. An improvement on this process would be, simply to sublime the above mixture in any convenient vessel, furnished with a large and well-cooled receiver, and to remelt the product in close vessels under pressure, when it hould be cooled as rapidly as possible. Prop., Uses, tyc. A white semi-crystalline solid, very volatile at common temperatures. Soluble in alcohol, ether, oils, and acetic acid, and suffi- ciently so in water (about 1£ grs. to 1 oz.) to im- part its characteristic smell and taste. It is stim- ulant, narcotic, anodyne, and diaphoretic, and is given in doses of 2 to 20 grs., in the form of pills or bolus, or made into an emulsion with yelk of egg, mucilage, or almonds. An overdose of cam- phor is accompanied with symptoms of poisoning. The best antidote is opium. Camphor is frequent- ly put into wardrobes and clothes-trunks, to keep away insects, and it is used to make the white stars and fire of the pyrotechnist. Mixed with copal, it renders that gum soluble in some essential oils and alcohol. (See Copal.) Mixed with six times its weight of clay, and distilled, it undergoes decomposition, and yields a yellow aromatic oil, smelling strongly of thyme and rosemary, which, I am told, is much used to adulterate some of the more costly essential oils. CAMPHOR, ARTIFICIAL. Kind first dis- covered, and Trommsdorff and Boullay confirmed the fact, that rectified oil of turpentine, exposed to the action of muriatic acid, absorbs that gas with the production of a white crystalline mass resem- bling camphor. CAMPHOR FROM ESSENTIAL OILS. Prep. tf-c. By careful distillation of \ of the oil, the remaining portion, on being cooled, will be found to contain a species of camphor, on separating which, and redistilling the remainder of the oil, 2 or 3 times, the whole of the camphor may be obtained. Oil oj rosemary, treated in this way, yields about 10$ of camphor; oil of sweet marjoram the same ; oil of sage yields 13g; oil of lavender 25}}. That from sage oil forms cubical crystals, insoluble in nitric acid ; that from marjoram oil is scarcely vola- tile or inflammable. By keeping the oils loosely corked, and in a cool place, they produce a larger portion of this pseudo-camphor. The substance called aniseed camphor is procured by pouring off the liquid portion of the oil, after it has been par- tially frozen by exposure to a cool atmosphere. CAMPHOR CAKE. Prep. I. Campho- lini- ment, (P. L.,) 1 oz.; melted spermaceti 1 drachm; mix. II. White almond oil 4 oz.; spermaceti £ oz.; melt, add camphor, (cut small,) 1 oz.; stir until melted, then pour it into shapes and allow it to crystallize. CAMPHOR JULEP, CONCENTRATED Syn. Essence of Camphor. Prep. Camphor 1 oz.; rectified spirit 10 oz. by weight; dissolve. Use. 20 drops, added to 1 fluid oz. of pure cold water, makes transparent camphor julep. CAMPHOR, TO POWDER. Camphor may be beaten in a mortar for some time, without being reduced to powder, but if it be first broken with the pestle, and then sprinkled with a few drops ." spirit of wine, it may be readily pulverized. Pow- dered camphor is much used in tooth powders, fire- works. &c. CAMPHORATED ACETIC ACID. Prep. Dissolve fss of camphor, in ^viss of acetic acid, (P. E.) Use. Similar to aromatic vinegar. CAMPHORATED CHALK. Syn. Creta- ceous Tooth Powder. Prep. I. Precipitated chalk 3 oz.; camphor 1 oz. Proc. Add a few drops of spirit of wine to the camphor, then reduce it to a fine powder, and mix it .(perfectly) with the chalk ; lastly, pass it through a clean sieve of suffi- cient fineness. II. Prepared chalk (not precipitated) 7 oz.; camphor 1 oz.; as last. Use. Extensively employed as a dentifrice. It should be kept in corked bottles, to prevent the camphor flying off. CAMPHORIC ACID. Prep. Put 1 part of camphor and 4 parts of nitric acid, sp. gr. 1*33, into a glass retort, connected with a receiver, and apply a gradually increasing heat, until vapors cease to be extricated ; then add the camphor that has been volatilized to the acid in the retort, along with 4 or 5 parts more of nitric acid. Repeat the process, again and again, until 20 parts of nitric acid have been consumed. When the whole of the camphor is acidified, it will crystallize in the remaining liquor. When the whole is perfectly cold, it must be thrown upon a filter and well washed with dis- tilled water, after which it must be dissolved in boil- ing water, evaporated to a pellicle, and set aside to crystallize. Prop. The crystals somewhat resemble those of muriate of ammonia. They are soluble in alcohol, and are not precipitated from it by water, by which camphoric acid may be distinguished from benzoic acid. With the bases it fonns salts called cam- phorates. The soluble camphorates may be made by digesting the carbonate or hydrate of the base in a hot solution of the acid, and the insoluble ones, by double decomposition. CAMPHORIC ETHER. Syn. Camphorate of Oxide of Ethule. Prep. By heating cam- phoric acid, sulphuric acid, and alcohol together, a colorless, sirupy liquid is formed, which must be submitted to distillation, and the product dissolved in alcohol. When the liquid ceases to deposite crys- tals of camphoric acid, water must be added, when CAN 158 CAN the ether will separate under the form of an cly liquid, and may be collected. Prop. It is heavier than water, and boils at 545°. CAMPHRONE. When the vapor of cam- phor is passed over quicklime at a red heat, and then into a cool receiver, a peculiar volatile liquid is condensed, to which the name of camphrone has been given. CANDLES. Candles are made of various ma- terials, but the first operation, in all cases, is the preparation of the wicks. The best candle wicks are made of cotton rovings, imported from Turkey in skeins. 4 or more of these, according to the in- tended thickness of the wick, are wound on a reel, from which they are again run off, and cut of the proper lengths. They are then dipped into melted tallow, and after rubbing with the hands, are placed straight and allowed to harden. They are next arranged upon the broaches ready for dipping. For mould and other candles that do not undergo the process of dipping, this last operation is omitted. In some cases the wicks are formed by twisting or plaiting the cotton together, or winding it round wires, which are withdrawn after the candles are made, thus leaving the wicks hollow ; this was the method patented by Gay Lussac, for his stearine candles. In some instances, the cotton is steeped in metallic solutions. The object in all these pro- cesses is to produce a wick that will consume itself, and thus prevent the necessity of snuffing. Great care is taken to select a cotton that will yield the least possible quantity of ashes, or non- volatile matter after burning. I. Tallow candles, a. (By dipping.) Proc. The broaches being covered with wicks, are ar- ranged in frames ready for dipping. The dipping cistern being filled with tallow of a proper temper- ature from the boiler, one of the frames is placed upon the end of the dipping beam, and pressed down gently into the melted fat; it is next with- drawn, the bottoms of the candles just touched against a board placed on one side of the cistern for the purpose, and then removed to the rack. Another is now taken and treated in the same manner, and the process is continued with fresh frames until those first dipped are sufficiently cool to undergo a second immersion. This operation is repeated until the candles acquire a sufficient size, when they are finally cooled, sorted, weighed, and strung in pounds for sale. The dipping beam is simply aj>iece of wood hung from the ceiling by the centre, and arranged with weights at one end, and at the other with supports to receive the frames with the wicks. It is so balanced that a slight pressure with the fingers is sufficient to depress it so as to immerse the wicks or partly formed can- dles into the tallow of the dipping cistern. On withdrawing the pressure, the beam again assumes the horizontal position, and thus raises the candles out of the melted fat. The dipping-room, or shop, is usually situated in the coldest part of the pre- mises, and furnished with a species of Venetian shutters throughout the entire length of walls, (if possible,) after the manner of breweries, to pre- serve a constant current of cool air. b. (By moulding.) Proc, § of alkali. It may be purified by solution in water, defecation, evaporation, and crystallization. A purer article is yielded by a mixture of 5 parts of sulphate of soda, and 4 parts of chalk or lime, and 1 or 2 parts of powdered charcoal, treated as above. The annexed engra- ving represents a vertical paction of the soda fur nace employed in Scotland. II. (From the ashes of marine plants.) This process consists in simple lixiviation with water, allowing the impurities to subside, and evaporating, III. (From common salt.) Dissolve 2 parts of' common salt in water, then add 6 parts of finely- pulverized litharge, and 1 part of chalk ; agitate well together; decomposition gradually ensues, and a solution of carbonate of soda is formed, and crystallizes out of the liquid. The product is tol- erably pure. IV. (Sod(e carbonas, P. L.) " Take of impure carbonate of soda lb. ij ; distilled water 4 pints. Boil the impure carbonate of soda in the water for half an hour, and filter the solution while it is hot Finally, set it apart that crystals may be formed." V. (Chemically pure.) This is best prepared by heating the pure bicarbonate or acetate of soda to redness in a platinum crucible. Prop., Use, . his gustful appetite. Cut the cheese into slices of moderate thickness, and put them into a tinned copper saucepan, with a little butter and cream, simmer very gently until quite dissolved, then re- move it from the fire, allow it to cool a little, and add some yelk of egg, well beaten ; make it into a shape, and brown it before the fire. CHELTENHAM SALTS. Prep. Glauber salts 1 oz.; Epsom salts £ oz.; culinary salt a tea- spoonful ; sulphate of iron 2 grs.; reduce them separately to fine powder, then mix them. II. Glauber salts and Epsom salts, of. each 28 lbs.; common salt 7 lbs.; sulphate of iron \\ oz.; mix. Remarks. The above salts must be dried in an oven, or over the fire, before reducing them to powder. The Glauber's should be dried by itself, as it liquefies when slightly heated. Cathartic and tonic. Dose. 4 oz. to 14 oz. CHELSEA PENSIONER. Prep. Gumgua- iacum -J oz.; rhubarb 4 oz- > cream of tartar 2 oz.; flowers of sulphur 4 oz.; nutmegs 2 in num- ber, (all in powder;) honey 14 lb.; make them into a confection by beating them together in a mortar. Remarks. The dose is two tablespoonfuls, night and morning, in rheumatism. The name is said to have been given to it from the circumstance of a Chelsea pensioner having cured Lord Amherst with it. CHILBLAIN. An inflammatory swelling, of a purple or lead color, produced by the action of cold. Children, especially those of a scrofulous habit, and elderly persons, are generally most lia- ble to chilblains. The common cause of chilblains is holding the hands or feet to the fire, after expo- sure to cold. The sudden change of temperature partially destroys' the vitality, and prevents the proper flow of blood through the part. The best preventives of chilblains are woollen socks or stockings, good waterproof shoes, woollen gloves, exercise, and friction. When chilblains have once formed, the best treatment is friction, with stimu- lants, as spirits of wine and camphor, turpentine, opodeldoc, dilute spirits, camphorated oil, &c. Linnaeus recommends bathing the part with dilute muriatic acid, just strong enough to faintly prick the skin. When the inflamed parts have ulcera- ted, they are commonly called kibes. In this stat* they should be dressed with a little resin cerate, 01 elemi ointment, and if fungous granulations ap- pear, they must be removed by touching them with nitrate of silver or blue vitriol. CHILBLAINS, LOTIONS FOR, (POPU- LAR.) I. Dissolve white copperas 1 oz. in water 1 pint, and occasionally apply it to the affected parts. II. Dissolve sal ammoniac 1 oz. in vinegar \ pint; as above. III. Mix compound soap liniment 2 oz. with tincture of Spanish flies 1 oz.; as above. IV. Vinegar and spirit of wine, (or rum,) 01 each \ pint; sal ammoniac, in powder, 1 oz.; mix and shake until the latter dissolves. V. Spirits of salts 1 oz.; water J pint; mix ; as above. CHI 183 CHL CHILBLAINS, OINTMENT FOR. Prep. Ointment of nitrate of mercury 1 oz.; camphor 1 dr.; oil of turpentine 2 drs.; oil of olives 4 drs.; mix well together. To be applied, by gentle fric- tion. 2 or 3 times daily. II. Calomel and camphor, of each 1 dr.; sper- maceti ointment 4 drs.; oil of turpentine 2 drs.; as last. Remarks. All the preceding lotions and oint- ments are intended for chilblains before they break. CHILBLAINS, RUSSIAN REMEDY FOR. A common remedy for chilblains among the peas- ants in Russia is the rind of perfectly ripe cucum- bers, dried with the soft parts attached, and placed with the inner side, previously soaked in warm water, over the sore parts. Dumitriefsky confirms the efficacy of this remedy. (Med. Zeitung.) CHIMNEYS ON FIRE maybe readily extin- guished in several ways, without having recourse to throwing water down them from the top, by which much damage is frequently done to the fur- niture in the rooms. One of the simplest methods is, to scatter a handful of flowers of sulphur over the dullest part of the burning coals, the mephitic vapors arising from which will not support com- bustion, and consequently extinguish the flames. Another method is, to shut the doors and windows, and to stop up the bottom, of the chimney with a piece of wet carpet or blanket, throwing a little water or flowers of sulphur, or salt, on the fire im- mediately before doing so. By this means the draught is stopped, and the burning soaH must be extinguished for want of air. If the chimney be stopped at top, instead of the bottom, the whole of the smoke must, of course, be driven into the apartment. If every fireplace were provided with a damper, or shutter of sheet-iron or tin plate, suf- ficiently large to choke it thoroughly, fires in chim- neys would become of little consequence, as it would only be necessary to apply this damper to put them out. CHINA, (CHOICE OF.) In purchasing chi- na, glass, and earthenware, care should be taken to select those sets that in case of breakage can be readily matched. Peculiar or rare patterns should be avoided, for if any such be broken, it will gen- erally be found very difficult and expensive, and frequently impossible, to replace them. Cleaning. China (when very dirty) is best cleaned with finely-powdered fuller's earth and warm water, afterwards rinsing it well in clean water. A little clean soft soap may be added to the water instead of fuller's earth. The same plan is recommended for cleaning glass. Packing. As there is considerable art in pack- ing brittle hollow-ware, in such a way that it will stand exposure to the jolting, blows, and agitation of land-carriage, it is better, where it is of much value, or in quantity, to have it done by a person used to the job. A man, accustomed to packing such articles, may be readily procured at any glass-works, or china warehouse, for a trifling con- sideration. CHINA-ROOT STARCH. A reddish-colored farina, procured from the smilax china. CHINESE SHEET-LEAD. The Chinese em- ploy large quantities of sheet-lead in packing their tea., which they make in the following way:— Melted lead is poured from a crucible upon a large flat stone, placed upon the ground, and immedi- ately another stone is dashed upon t le fluid lead, which is thus pressed out into a very thin plate or leaf. This is instantly removed, and the operation repeated as rapidly as possible. The rough edges of the plates are afterwards cut off, and then sol- dered together for use. The Chinese employ two men in this process; one to pour on the melted lead, and the other to work the stone. A similar method has been adopted for some years in Eng- land, to form the plates of zinc for galvanic batte- ries. CHIRAYITINE, SULPHATE OF. The substance sold under this name is sulphate of quina. Chirayita yields no alkaloid, but merely a bitter matter. CHLORAL. A substance prepared by the ac- tion of chlorine on alcohol. Prep. Place anhydrous alcohol in a tubulated retort, and pass dry chlorine gas through it, at first in the cold, but afterwards with the application of a gentle heat. As soon as the chlorine passes un- decomposed through the liquor at the boiling tem- perature, the process is complete. On cooling, the liquid in the retort solidifies, forming a crystalline mass of hydrated chloral. This must be melted by gentle heat, and agitated with thrice its volume of oil of vitriol, when, on increasing the heat a lit- tle, an oily stratum of impure chloral will rise to the surface. This must be removed, boiled for some time, to drive off some free hydrochloric acid and alcohol, and next distilled with an equal vol- ume of oil of vitriol; lastly, it must be rectified from finely-powdered quicklime, stopping the pro- cess as soon as the surface of the lime becomes dry. Remarks. The chlorine is best introduced by a tube inserted into the tubulature of the retort, and a long tube, bent upwards, should be connected with the beak to convey away the hydrochloric acid gas extricated, and to allow the volatilized alcohol and chloral to condense and flow back into the retort. Prop. Chloral is an oily liquid, possessing an ethereal smell; it is soluble in alcohol, ether, and water, but its solution in the latter rapidly changes into a semi-solid crystalline mass of hydrate of 1 chloral, soluble in a larger quantity of water. [ Chloral boils at 202°, and has a sp. gr. of 1-502. CHLORATE. A compound of chloric acid with a base. The chlorates are very similar to the nitrates, both in their properties and composition. i They are all decomposed at a red heat, metallic | chlorides being formed, and oxygen gas given off I Like the nitrates, they deflagrate with infiamma- ' ble substances, but with greater facility and vio- | lence. A mixture of this kind will detonate with a slight blow or friction. All the chlorates are so- luble in water. Tests. Rubbed with sulphur, or phosphorus, they 1 explode violently; mixed with muriatic acid, and [ then with water, a liquid is formed, possessing [ bleaching properties. When heated, they evolve oxygen. Thrown on red-hot coals, they defla- grate like nitre. Sulphuric acid turns them orange red. The following simple method of testing the commercial chlorates has been proposed by M* Choron: Cni, 184 CHE The protoxide of lead, heated with chlorate of potassa in a glass tube closed at one end, gives puce oxide of lead, (Pb O2,) mixed with a small quantity of minium. On this new reaction is founded the test which I propose with relation to the chlorates. It consists in slowly heating to fu- sion an intimate mixture of the chlorate and li- tharge in suitable proportion, covering it with a layer of chloride of sodium ; in treating the fused mass with dilute nitric acid; then in collecting on a filter the puce oxide obtained, by aid of which the quantity of chlorate employed may be ap- proximately calculated. " This prompt and cheap process appears to me sufficiently accurate to be employed hi the arts." (Comptes Rendus, xiv.) CHLORATE OF BARYTA. (Wheeler's process.) Digest for a few minutes a concentra- ted solution of chlorate of potassa, with a slight excess of silicated hydro-fluoric acid. A precipi- tate of double fluoride of silicon and potassium will subside, and chloric acid remain in soluu.n. Filter, neutralize with carbonate of baryta ; again filter, when prismatic crystals of chlorate of bary- ta may be obtained by cautious evaporation. Prop., c)[-c. Soluble in 4 parts of cold water. Used to make chloric acid. This salt may also be formed by passing chlorine through a strong milk of hydrate or carbonate of baryta, in the same way as in making chlorate of potassa. CHLORATE OF POTASSA. Syn. Hyper- OXYMUIUATE OF POTASH. OxYMURIATE OF DITTO. Prep. I. Transmit chlorine gas through a solution of pure potassa, or its carbonate, until the alkali be completely neutralized, then boil for a few min- utes, gently evaporate until a pellicle forms on the surface, and set it aside, where it will cool very slowly. Crystals of the chlorate will form as the liquor cools, and must be collected, carefully washed with a little cold water, and purified by re-solution and crystallization. The mother liquor, by evaporation, will yield more crystals, or it may be saved for a future operation. Remarks. This operation is best conducted in a Woolf s apparatus, or similarly arrnnged vessels. When the process is about half completed, as in- dicated by litmus paper, ceasing to be darkened, and beginning to be blanched, it is better to inter- rupt the operation, and to remove any chloride of potassium that may have fallen down ; this may be washed with a little water, and the washings added to the liquor, when the chlorine should be again passed through the solution. When the bub- bles of gas pass through without any being sensi- bly absorbed, the process is completed. The gas tube should be of large dimensions at the end im- mersed in the 6aline solution, and care should be taken that it does not get stopped up with crystals. In general the pure chlorate obtained from the second crystallization, amounts to about -f\ of the weight of the potash employed. The smallness of the product arises from a large portion being converted into chloride of potassium. II. (Graham's process.) This consists in sub- mitting equal equivalents of carbonate of potassa, and hydrate of lime mixed with water, to the ac- tion of chlorine, in a similar way to the above. III. (Liebig's process.) a. The chlorine is passed into a mixture of one equivalent of chlo- ride of potassium, and 6 cquiv lents of hydrate of lime, previously stirred with water to the consist- ence of a thin paste, whereby the lime unites, with the chlorine, forming chloride of calcium, and the chloride of potassium is converted into chlorate potassa ; the latter is then separated bjr crystallization. (Buchner's Re pert.) b. Heat chloride of lime in water until it ceases to affect vegetable colors, then dissolve it in hot water, concentrate by evaporation, and add chlo- ride of potassium. After cooling, a quantity of crystals of chlorate of potassa are obtained. Chlo- ride of lime, of so bad a quality as to be worthless for other purposes, may be employed; hence this is a very economical process. IV. (Vee'sprocess.) Heat a solution of chlo- ride of lime, marking. 18 or 20° Baume, in a leaden or cast-iron vessel, and when hot, dissolve therein enough chloride of potassium, to raise the hydrometer 3 or 4 degrees; then concentrate quickly, but cautiously, until the gravity 6f 30 or 31° Baume be obtained, and set it aside to crys- tallize. The mother water, concern.-ted to 36°, will yield more crystals. By re-solution in water, concentrating to 15 or 16°, filtering and again cooling, pure chlorate of potassa will be obtained This is a good and economical process. V. (Patent process of M. Rumer.) This con- sists in placing pure carbonate of potassa on shelves in an air-tight chamber, communicating with a retort, filled with the materials for generating chlorine, by which the alkali becomes surrounded with an afcmosphere of chlorine. The operation is allowed to proceed for 12 hours without interfe- rence, after which, the heat of a water bath is applied to the retort for 6 hours longer. The ap- paratus is now opened, and the chlorate of potassa thus formed, is purified and freed from muriate by solution and crystallization. The materials for generating the chlorine, arc—^crystallized peroxide of manganese, in fine powder, 10 lbs.; plumbago 10 lbs.; common salt 30 lbs.; strongest oil of vit- riol 20 lbs.; water 16 lbs.; the weight of the car- bonate of potassa placed upon the shelves is 10 lbs Not being acquainted with the product obtained by this process, I cannot speak as to its value. Prop., Uses, <£c. Crystallizes in four and six sided pearly scales; dissolves in 16 parts of water at 60°, and in 24 parts at 212°. At about 450°, it undergoes the igneous fusion, and on increasing the heat almost to redness, effervescence ensues, and pure oxygen gas is given off. It yields 39*15j by weight of this gas, (Ure,) and becomes changed into chloride of potassium. It will bear a heat of 600° rahr. without undergoing any change. When mixed with inflammable substances, and triturated, heated, or subjected to a smart blow, it explodes with great violence. It also fulminates when thrown into strong acids. As a medicine, it is stimulant and diuretic. Dose. 5 to 15 gr. or more. It is principally used in the manufacture of fireworks, oxygen gas, Inciter matches, &c, and was formerly used to fill percus.4on caps, but was abandoned for fulminating mercury, as it was found to rust the nipples of the guns, which ths latter does not do. The following experiments with this salt, which are mentioned in most chemical works, may amuse the young experimentalist.—Rub 2 gr. into powder CHL 185 CHL in a mortar, add 1 gr. of sulphur, mix them well by gentle trituration, then collect the powder into a heap, and press upon it suddenly and forcibly with the pestle ; a loud detonation will ensue. If the mixture be wrapped in strong paper, and struck with a hammer, tho report will be still louder. 5 gr. of the salt, mixed in the same manner with 24 of charcoal, will be inflamed by strong tritura- tion, especially if a grain or two of sulphur be added, but without much noise. If a little sugar be mixed with half its weight of the chlorate, and a little strong sulphuric acid poured on it, a sudden and vehement inflammation will ensue ; but this experiment requires caution, as well as the follow- ing. To 1 gr. of the powdered salt in a mortar, add J a gr. of phosphorus; it will detonate with a loud report, on the gentlest trituration. In this experiment the hand should be defended by a glove, and great care should be taken that none of the phosphorus get into the eyes. Phosphorus may be inflamed by it under water, by putting into a wine glass 1 part of phosphorus and 2 of the chlorate, nearly filling the glass with water, and then pouring in, through a glass tube reach- ing to tlie bottom, 3 or 4 parts of sulphuric acid. This experiment, too, is very hazardous to the eyes. If olive or linseed oil be taken instead of phosphorus, it may be inflamed by similar means on the surface of the water. This 6alt should not be kept mixed with sulphur, or perhaps any in- flammable substance, as in this state it has been known to detonate spontaneously. The addition of sulphuric acid to such mixtures immediately causes them to inflame and explode ; but this ex- periment does not succeed with diamond powder. (Chenevix.) Pur. The usual impurity is muriate of potash. This is readily detected by adding a few drops of a solution of nitrate of silver, which will give a curdy white precipitate soluble in liquor of ammo- nia, if a muriate be present, whereas the solution will remain clear, if the salt be pure. The tests are the same as those mentioned under chlorate. The salt may be known to contain potash, by the tests described under the article potassa, and may thus be distinguished from chlorate of soda. CHLORATE MATCHES. Prep. Chlorate of potassa 30 grs. ; flowers of sulphur 10 grs.; powdered lump sugar 8 grs. ; powdered gum ara- bic 5 grs. ; vermilion enough to color. Proc. Re- duce the chlorate to fine powder in a marble or wedgewood-ware mortar, then place it on a stone slab, add the other ingredients, and mix them all together with a wooden or bone knife, adding just sufficient water to make a paste. Into this mix- ture the points of matches, made of slips of thin wood or pasteboard, are to be dipped, and after- wards carefully dried in a moderately warm situa- tion. Remarks. These matches, dipped into a little sulphuric acid, or exposed to smart friction, imme- diately enflame. The risk of spilling the acid may bo avoided by placing a little asbestos in the bottle, and pouring thereon only as much sulphuric acid as the asbestos will absorb. It is only the compo- sition on the match that should be touched with the acid, for if the wood be well wetted it will not burn. To ensure success it is best to dip them into melted brimstone to the height of about | of an 24 inch before applying the composition. Thesf matches once occupied the place that Lucifers did a few years since, and that Congreves do now. CHLORATE, PRIMING, (for Guns.) Prep. Pulverize the best gunpowder, and make it into a paste with water ; then add half its weight of chlo- rate of potassa, and, while semi-fluid, drop it into the empty copper caps; place them aside in a warm situation to dry. Remarks. The same precautions must be ob- served in mixing the ingredients, as directed in the last article. This priming is now superseded by fulminating mercury, which, as before observed, does not rust the nipple and foul the touchhole, like the chlorate mixture. CHLORATES, (PER-.) Salts formed by the union of perchloric acid with the bases. 'The per- chlorate of potassa may be formed by adding well- dried and finely-powdered chlorate of potassa, in small portions at a time, to an equal weight of con- centrated oil of vitriol, gently warmed in an open vessel. The bisulphate of potassa formed must then be washed off with a little cold water, and the residuum of perchlorate dissolved in boiling water and crystallized. Remarks. These salts are distinguished from the chlorates by not turning yel- low with hydrochloric acid. The other perchlorates may be formed by neutralizing the acid with the base. The perchlorate of potassa requires 65 times its weight of cold water for its solution, while the chlorate only requires 16. CHLORIC ACID. An acid composed of chlorine and oxygen. Prep. Dissolve chlorate of baryta in 16 times its weight of water; then add dilute sulphuric acid until all the baryta be precipitated as sulphate. The clear liquid may then be concentrated by eva- poration until it acquires a thin oily consistence. Props. In this state it has a yellowish tint, emits a smell like nitric acid, and sets fire to pa- per and other dry organic matter thrown into it. By heat it is resolved into chlorine and oxygen. It may be readily detected by its forming chlorate of potassa with that of alkali. CHLORIC ACID, (PER-.) A compound of chlorine and oxygen, containing 2 eq. more of the latter than the last acid. Prep. Put any quantity of powdered perchlorate of potassa into a retort, and pour thereon 4 'ts weight of strong sulphuric acid, previously diluted with an equal weight of water. Heat must now be applied, and as it rises to 284° F., vapors of this acid will pass over and condense as a color- less liquid in the receiver. Remarks. This is a more stable compound than chloric acid, and does not inflame organic sub- stances. By distilling it from concentrated sul- phuric acid, Serullas obtained it in a solid form. In this state it hisses when thrown into water, like red-hot iron. CHLORIDES. Compounds of chlorine with the bases in definite proportions. The test3 for the chlorides are the same as for chlorine. (See Chlo- rine.) CHLORIDES OF CARBON. Prep. I. (Per- chloride.) Expose the oily compound formed by mixing equal volumes of moist chlorine and ole- fiant gas, to the direct solar rays in a vessel full of chlorine gas. Hydrochloric acid is given off and CHL 186 CHL perchloride of carbon formed. Props. Solid; smells strong muriatic acid with half of its weight of somewhat like camphor; it is twice as heavy as water, fusible, volatile; soluble in alcohol, ether, and oils, and slightly so in water ; combustible. II. (Protochloride.) When tho perchloride of carbon is passed through a glass or porcelain tube filled with fragments of glass or rock crystal heat- ed to redness, chlorine is separated, and a vapor formed, which must be condensed by the applica- tion of cold. This is the protochloride of carbon. Prop. Liquid, limpid, and colorless ; vaporizes at 165° F. CHLORINE. Syn. Oxvmuriatic Acid. An elementary substance discovered by Scheele in 1774, and named by him dephlogisticated marine acid. It was afterwards called by the French chemists oxygenized and oxymuriatic acid, on the supposition of its being a compound of muriatic acid and oxygen. In 1809, Gay Lussac and Ther- nard suggested that it might be regarded as a sim- ple substance : but it was reserved for Sir H. Davy to prove the truth of this suggestion. After some researches, in which every method of decomposing it was tried that genius and experience could sug- gest, he declared it to be a simple body, and gave it its present name, (from x*W*s■ green,) on account of its color. Prep. I. Mix together in a glass flask or retort Brand .... 4 water Liebig .... 2 " Thernard . . . 4 " finely-powdered peroxide of manganese. Chlorine gas is immediately evolved even in the cold, but much more rapidly on the application of a gentle heat. Remarks. This gas must be collected in clean dry bottles by displacement. The tube con- ducting the gas must reach to the bottom of the bottle, when the chlorine, being heavier than the air, will displace the latter, without mixing with it. The bottle is known to be full by the gas over- flowing the mouth, which is easily perceived by its green color. The bottle must now be closed up with an accurately-fitting stopper, previously greased, and an empty one put in its place, which must be subsequently treated in like manner. To free the gas entirely from muriatic acid, it may be passed through water; and to render it dry, it may be passed over dry chloride of calcium. Chlorine gas may also be collected . ver a saturated solution of common salt in the pneumatic trough. II. Pour common muriatic acid, diluted with an equal weight of water, upon half its weight of chloride of lime, and proceed as before. III. Pour sulphuric acid, diluted with water upon a mixture of common salt and binoxide of manganese previously placed in a retort. The proportions ordered by different authorities vary; the following are the principal: 5 acid . 3 oxide 8 salt. 2 " 1 " 3 " 4 " . 2 " 3 " Graham as much dilute acid as contains 13 of oil vitriol Remarks. The first or second process is the most convenient for small experiments in the la- boratory, and the latter may be adopted where peroxide of manganese cannot be procured. The third is the cheapest method, and that employed on the large scale. Mr. Julius Seybel has lately taken out a patent for improvements in the manu- facture of sulphate of soda and chlorine, which are formed by one operation. This is done by decom- posing common salt by sulphuric acid, in closed vessels of lead, or lined with lead, having heat ap- plied externally; and in employing the vapor of the muriatic acid thus formed to act on manga- nese immersed in water, such vapor being con- ducted below and permitted to escape upwards through the water and manganese. Prop. Chlorine is a gaseous substance, possess- ing a yellowish green color, a pungent suffocating odor, and an astringent taste. Its most remarka- ble properties are, its power of destroying almost all vegetable and animal colors, and the putrid odor of decomposing organic matter; hence its value as a bleaching agent, and as a disinfectant and fumigant. Water absorbs twice its volume of this gas, and acquires a yellowish color. Under a pres- sure of about four atmospheres it condenses into a yellow transparent liquid. With the bases, chlorine forms an important series of compounds, called chlorides, chlorurets, or muriates, of which calomel and common salt may be taken as examples, the first being a chloride of mercury, and the second of sodium. The metallic chlorides are mostly solid at common temperatures, and all, save two, (mer- cury and silver,) soluble in water. They are fusi- ble, and often crystalline. The chlorides of tin, antimony, arsenic, and mercury, are volatile and sublime unchanged. The chlorides are generally colorless, and resemble the salts in appearance. They are mostly decomposed by a strong heat They are not decomposed by pure anhydrous sul- phuric acid, but readily so by oil of vitriol. The metallic chlorides may generally be formed by the direct action of chlorine on the metals at common temperatures, and in many instances the union is accompanied by the evolution of light and heat They may also be frequently formed by dissolving the oxides, carbonates, or hydrates of the bases, in muriatic acid, and crystallizing, or applying heat, until all the water is expelled. Chlorine has such a strong attraction for the metals that it displaces oxygen in nearly all cases at a red heat. Tests. This gas is readily distinguished from other gases by its color, odor, and bleaching prop- erties. It forms a white curdy precipitate with nitrate of silver, (chloride of silver,) which is inso- luble in nitric acid, but readily so in liquid ammo- nia, and is blackened by light. Its aqueous solu- tion dissolves gold leaf, and instantly blackens a piece of silver plunged into it. It rapidly destroys the color of iodide of starch, solution of indigo, lit- mus, and turmeric. The soluble chlorides may be readily detected by acidulating their solutions with nitric acid, and then adding a solution of nitrate of silver, when chloride of silver will be precipitated, and may be recognised in the way just mentioned. The insoluble chlorides may be tested by digesting them in a little liquor of potassa, when a solution of chloride of potassium will be formed, which may be treated as a liquid chloride ; or the chloride may be dissolved in nitric acid, and tested with nitrate of silver as before. A simple method of detecting free chlorine is to hold a rod, dipped in CHL 187 CHL water of ammonia, over it, when white fumes of sal ammoniac will be formed ; this, coupled with the property of bleaching colors, may, in most cases, be taken as evidence of the presence of this substance. (See Chlorometry.) Ant. When the fumes of chlorine are inhaled, it proves an irritative poison. The best antidotes are said to be ammoniacal gas or the vapors of warm water, of wine, or of ether. The writer of this ar- ticle once suffered severely from getting a full in- spiration of this gas, by the bursting of a large ves- sel employed in its manufacture, and which was full at the time. For a minute or two he was completely overcome ; but, on being removed into the fresh air, he rapidly recovered, and, with the exception of a violent and convulsive cough, which lasted several hours, felt even better than he did before. The gas appeared to have acted both as a mental and bodily stimulant. Every known an- tidote was tried in this case, but without any ap- parent advantage. The effects gradually wore off, after the lapse of seven or eight hours. CHLORINE, LIQUID. Syn. Oxymuriatic Acid Oxymuriatic Water. Solution of Chlo- rine. Chlorine Water. Dephlogisticated Spirit of Salt. Prep. I. (Aqua Chlorinii, P. D.) Mix h7 parts of sulphuric acid with 124 of water, and pour it upon 100 parts of dried muriate of soda and 30 parts of oxide of manganese, previously mixed together and placed in a retort. Conduct the gas evolved into 200 parts of distilled water. II. (Aqua Chlorinei, P. E.) Muriate of soda 60 grs.; red oxide of lead 350 grs.; triturate to- gether, and put them into f^ viij of distilled water contained in a stoppered bottle ; then add 2 fluid drachms of sulphuric acid, put in the stopper, and agitate occasionally until the oxide of lead turns white. The clear liquid (after subsidence) is to be poured off into another stoppered bottle. III. Pass chlorine gas, procured by any of the methods mentioned under Chlorine, into water, until it will absorb no more. CHLORITES. Salts formed of the chlorous, acid with the bases. The alkaline chlorites may be formed by passing a current of chlorous acid gas into a solution of the pure alkalis. They are so- luble and remarkable for their bleaching and ox- idizing properties. CHLORITES, (HYPO-.) These are formed by the action of chlorine gas on the salifiable bases. Chloride of lime, soda, and potash are said by some to be hypochlorites, but this is undecided ; in fact, tho very existence of the hypochlorites has been denied. CHLORO-CARBONIC ACID. Syn. Phos- gene. Chloro-carbonous Acid. Prep. Expose equal volumes of caibonic oxide and dry chlorine to the rays of the sun, or diffused daylight. In the first case combination ensues in a few minutes, in the second after a few hours. Prep. A colorless gas, having a disagreeable odor; easily decom- posed, especially by water. CHLOROMETER. Syn. Chlorimeter. An instrument for testing the strength of chlorides. CHLOROMETRY. Syn. Chlorimetry. Chlo- rimetrie, (Fr.) The process or operation of test- ing the decoloring power of the compounds of chlo- rine. It is principally applied to those met with in commerce,—the chlorides of lime, potash, and so- da. Among the numerous tests proposed for this purpose, the following appear to be those most worthy of notice. • I. (Dalton's test.) Weigh exactly 78 grs. of pure proto-sulphate of iron, previously dried by strong pressure between the folds of cloth, and dis- solve it in 2 oz. of distilled water, to which add a few drops of muriatic or sulphuric acid. Next weigh out exactly 50 grs. of the chloride of lime, well mix it in a mortar with 2 oz. of tepid water, and pour the mixture into a graduated tube or al- kalimeter. Then fill the measure up to 0 with the washings of the mortar. The whole should be now well mixed, by placing the thumb over the orifice and shaking it. The solution of chloride of lime is next to be gradually and cautiously added to the solution of sulphate of iron, until the latter be com- pletely peroxidized, which may be known when it ceases to be affected by the red prussiate of potash. The latter test is applied by putting a drop of its solution upon a white plate, and touching it with the point of a glass stirrer or rod, dipped in the liquor under examination. As soon as the test in- dicates that enough of the solution of the chloride has been added, the number of measures poured from the alkalimeter must be carefully observed, from whence the richness of the sample may be estimated, as follows:—As 100 of the alkalimeter divisions contain exactly 50 grs. of the chloride, each measure will contain half a grain, and, con- sequently, any number of measures consumed, will represent half that number of grains of the chlo- ride under examination ; and the weight of the chloride thus used will have contained 10 grs. of chlorine—the constant quantity of that substance required to peroxide the given solution of sulphate of iron. Thus ;—If 80 measures of the liquor in the alkalimeter be consumed, this quantity will have contained 40 grs. of the chloride and 10 grains of chlorine. By dividing 1000 by this number, the per centage of chlorine will be obtained, thus : The above method admits of 'much greater ac- curacy, if the chloride of lime be dissolved in tepid water, placed in a Schuster's alkalimeter, previ- ously weighed, and the solution made up to ex- actly 1000 grs. when cold. The quantity con- sumed may hure be ascertained with great exact- ness. Every grain of the solution will be only equal to Jff of a grain of the chloride. The quan- tity of the solution consumed is determined by weighing the alkalimeter before and after the opr eration. The difference is the quantity that has been used. A modification of this plan has been suggested by Mr. Crum. He proposes to make the solution of the sulphate of iron in a stoppered bottle, and to add the chloride in the state of powder from a weighed quantity. II. (Crum's process.) Mix equal weights of wa- ter and muriatic acid, and dissolve therein cast- iron bffrings until saturated. To eusure perfect saturation a large excess of iron is employed, and the liquid kept at the heat of boiling water for some time. One measure of the solution, marking 40° on Twaddle's scale, (sp. gr. 1*200,) is mixed with an equal quantity of acetic acid, (sp. gr. 1*048.) CHL 188 CHL This forms the proof solution, which, if mixed with 6 or 8 parts of water, is quite colorless, but chloride of lime occasions the production of peracetate of iron, which gives it a red color. The above proof-solution is then poured into 12 two-oz. vials, of exactly equal diameters, to the amount of i of their capacity; these are filled up with bleaching liquid of various strengths ; the first at TV of a degree o'f Twaddle, the second f^, and so on up to || or 1°. They are then well corked up, and, after agitation, arranged side by side on a tray, furnished with holes to receive them, in the maimer represented in the engraving. A se- ,1'Mlijl #ft ft 00»o(ot*>t=J^=J Lat^slcJ Icjc^^y [If'.lli,. ries of test vials are thus formed, showing the vari- ous shades of color that the solutions of the given strengths are capable of producing. To ascertain the strength of an unknown sample of bleaching liquor, the proof solution of iron is put into a vial, exactly similar to the 12 previously used, and in precisely the same proportion, ('.) The vial is then filled up with the bleaching liquor, well shaken, and placed beside that one of the 12 al- ready prepared which it most resembles in color. The number on that vial expresses the strength of the sample under examination, in TVths of a de- gree of Twaddle's hydrometer. Table exhibiting the quantity of Bleaching Liquid, at 6° on Twaddle's scale, (sp. gr. 1*030,) requi- red to be added to a weaker liquor, to raise it to the given strengths. Adapted from Mr. Crum's table by Mr. Cooley. Strength of sample in Ty>. Required Strength. Proportions Given Sample. required. Liquor at 6°. • Parts. Part. Water. 8 0 8 1 1 do. 94 1 2 do. 11 1 3 do. 134 1 4 do. 17 1 5 do. 23 1 6 do. 35 1 7 do. 71 1 Water. 6 O 11 1 1 do. 134 1 2 do. 17 1 3 do. 23 1 4 do. 35 1 5 do. 71 1 Water. 4 O 17 1 1 do. 23 1 2 do. 35 1 3 do. 71 1 Water. 3 0 1 3 23 1 1 do. 35 1 2 do. 71 1 Remarks. The preceding method is admirably suited for weak solutions, such as are employed for bleaching textile fabrics, and is well adapted (from its simplicity) to the purposes of practical men. It is employed in many of the Scotch bleaching houses. According to Mr. Crum, the range of strength within which cotton is safe, is very limited. A solution at 1° of Twaddle's scale, (sp. gr. 1-005,) is not more than safe, while one at 4° is scarcely sufficiently strong for the first operation on stout cloth, unless it be packed more loosely than usual. (Trans. Glasgow Phil. Soc.) III. (Ure's test.) This consists in adding watei of ammonia of a known strength, tinged with litmus, to a solution of a given weight of the chlo- ride, until the whole of the chlorine be neutralized, which is known by the color ceasing to be destroy- ed. From the quantity of ammonia consumed, the strength is estimated. During the above process azote is evolved, and the estimation cf the volume thus liberated has been proposed as a^. ether easy method of chlorimetry by Dr. Ure. This gentleman recommends the two substances to be mixed in an inverted and graduated syphon tube over mercury. (See Engraving.) " The shut end a and the open end 6, are both f\c graduated to one scale ; for example, to T^f of an inch, or to grain or 10 grain measures. The tube is to be filled with mercury, and then 10 measures of it are to be displaced at the open end, by in- serting a wooden plug. This space being filled with a solution of a given weight of chloride of lime, is to be turn- ed up into the shut end, by covering the open end with the finger and inverting the tube; a few drops of water may be sent through to wash the mercury. The ammonia being now let up will cause a reaction, and evolve a quantity of azote, equivalent to the chlorine pres- ent. The action may be accelerated by holding the sealed end of the tube over the flame of a spirit-lamp. The mercury is protected from the chlorine by the ammonia; and should any notion be entertained of such an action, the ammonia may be let up first. I have made innumerable researches over mercury, with a detached appa- ratus of this kind, which combines precision with rapidity of result." (Ure's Diet. Arts.) IV. (Process of M. Gay Lussac.) One part of the best indigo is dissolved in 9 parts of strong sulphuric acid, by the aid of a gentle heat. This solution is then mixed with distilled water, in such proportion, that 1 volume of chlorine gas shall ex- actly decolor 10 volumes of this solution. Each measure so decolored is called a degree, and each degree is divided into fifths. 5 grains of the best chloride of lime, dissolved in 500 grain measures of water, will possess the above power, and indicate 10° or proof, and will decolor 10 times its volume of the indigo solution. The objections to this meth- od of chlorimetry are, that the indigo solution alters by keeping, and that it is not adapted for testing strong solutions of chloride of lime. " I have tried the indigo test in many ways, but never could confide in it." (Ure.) CHLORO-NITROUS GAS. A gaseous com- pound, discovered by E. Davy. It is obtained CHO 189 CHO by treating fused chloride of sodium, potassium, or calcium, in powder, with as much strong nitric acid as is sufficient to wet it, when this gas is evolved. Prop. It has an orange color, smells like chlorine, and bleaches. Soluble in water. CHLOROPHYLL. Syn. Chlorophile. Chlorophyle. The green coloring matter con- tained in the leaves, stalks, unripe fruit, and juices of most plants. It is extracted by ether, and pu- rified by successive solutions in alcohol and muriatic acid ; from the last it is precipitated pure by water. Prop. A dark green mass, producing a grass. green powder. It is soluble in ether, alcohol acids, alkalis, and oils. If an earthy or metallic salt be mixed with the alcoholic solution, and an alkaline carbonate be added, the earth or oxide is thrown down in combination with this coloring matter, forming a green lake, possessing consider- able permanency. Pelletier and Caventou, who first discovered chlorophyll, obtained it by simply pressing the leaves, washing in water, and after- wards treating it with alcohol. CHLOROUS ACID. Syn. Peroxide of Chlorine. A compound of oxygen and chlorine Prep. Chlorate of potassa in fine powder, made into a paste with strong sulphuric acid, is put into a retort and heated in a water-bath, hot but not boiling. A yellowish green gas is given off, which may either be collected in dry bottles, or passed into water, when it will form liquid chlorous acid Props., tyc. Its aqueous solution undergoes gradual decomposition, yielding chlorine and chlo- ric acid. It possesses powerful oxidizing and bleaching properties, and unites with the bases forming salts called chlorites. These are all solu- ble in water, and possess bleaching powers like the acid. They may be recognised by the evolution of chlorous acid gas when acted on by an acid. CHOCOLATE. Syn. Chocolada. Choco- Lat, (Fr.) The roasted cacao nut made into a paste by triturating it in a heated mortar, with sugar and aromatics, and cast in tin moulds, in which it concretes into cakes on cooling. The term is derived from two Indian words, choco, sound, and atte, water ; because of the noise made in its preparation. (Dr. Alston.) Qual. Chocolate is nutritive and wholesome, if taken in moderation, but is sometimes apt to disa- gree with weak stomachs, especially those that are easily affected by oily substances or vegetable food. The quantity of aromatics mixed with the richer varieties, improve the flavor, but render them more stimulant and prone to produce nervous symptoms, and complaints of the head. Prep. The nuts are first roasted, (on the small scale this may be done in a frying-pan,) and after beina* cleared from the husks, reduced to coarse powder ; they are then beaten in an iron mortar, the bottom of which is heated, until they are re- duced to a paste, which is effected by the action of the heat on the oil or butter they contain. This paste or semi-fluid mass is then poured out into moulds, and left until cold, when it forms cake chocolate, or chocolate paste; or it may be re- duced to coarse powder, by grinding, when it is known under the name of chocolate powder. Remarks. Chocolate, prepared as above, with- out the addition of aromatics, is known in the trade as plain chocolate. Tho Spaniards flavor it with vanilla, cloves, and cinnamon, and frequently scent it with musk and ambergris. In general, they add too large a quantity of the last four arti- cles. The Parisians, on the contrary, use but lit- tle flavoring, and that principally vanilla. They employ the best caracca nuts, and add a consider- able quantity of refined sugar. The mass of the common chocolate sold in Eng- land, is prepared from the cake left after the ex- pression of the oil, and this is frequently mixed with the roasted seeds of ground peas, and maize or potato flour, to which a sufficient quantity of inferior brown sugar, or treacle and mutton suet is added, to make it adhere together. In this way is made the article commonly marked in the shops at 8d., 9, I flow. Celsus.) A disease characterized by bilious vom- iting and purging, accompanied by great pain and debility. It most frequently occurs towards the end of the summer and the beginning of autumn, and appears to be produced by sudden changes of temperature, checked perspiration, and the exces- sive use of indigestible fruit, &c. It is usually ac- companied by fever, thirst, and severe abdominal pains, and sometimes by cold sweats, extreme de- bility, feeble pulse, &c, under which the patient sinks in 24 hours. Treat. In most cases this complaint is not dan- gerous, and yields to proper treatment in a few days. As soon after the commencement of the attack as possible, some mild aperient, as castor oil, should be administered, and its action acceler- ated by drinking copiously of diluents, as barley- water, toast and water, water gruel, &.c. Opiates may be employed, both topically and by the mouth. A teaspoonful of laudanum rubbed over the region of the stomach and bowels, is a simple method, and will generally allay the pain. 15 or 20 drops of laudanum, mixed with a tablespoonful of good brandy, may also be taken every hour, if the pain be severe. Should the stomach reject it, or the vomiting be apparently increased by drink- ing copiously, the same treatment should be per- severed in. When the violence of the symptoms has abated, tonics and bitters, as gentian, calom- ba, orange-peel, &c., may be had recourse to. CHROMATE. A saline compound, formed by the union of the chromic acid with a base. The chromates are characterized by their yellow or red color, the latter predominating when the acid is in excess. Prep. The insoluble salts of chromic acid, as those of baryta, zinc, lead, mercury, silver, &c, may be made by mixing a soluble salt of those bases, with neutral chromate of potassa. The first three are red, the fourth orange, and the fifth deep red or purple. Tests. 1. On boiling a chromate in hydrochloric acid, mixed with alcohol, chromic acid is first set * " It is quite immaterial whether the lime 1>« in a state of carbonate, or otherwise; but I think, generally sp.Mk- in», it will be found quite as advantageous to employ thTal which has been burnt, as it will gave trouble and expense in grinding." CHR 191 CHR portance, so long as carbonaceous matters from the fire are entirely excluded, and the required temperature is attainable. Unless strong heat is employed, no decomposition will take place; the temperature already employed in manufacturing this article from the nitrates, will be sufficient, and the furnaces used in every way suitable. The mass should be well raked about every half hour, to ensure the whole of it being sufficiently heated. " Proceeding thus, the manufacturer may ascer- tain whether the process is complete by taking out a sample from the furnace, and treating it with a slight preponderance of dilute pure nitric acid, then adding chloride of barium; if, on this addition, much precipitate of sulphate is formed, the opera- tion is not completed ; but if, on the other hand, only a slight milkiness is produced, the ' batch' may be considered as finished. " I have found, from numerous analyses, that different samples of the ore vary considerably in the quantity of oxide of chromium which they con- tain, and I therefore advise every manufacturer to analyze a fair average sample before he makes a purchase." The following is the plan which Mr. Watt has adopted for this purpose:— " Take a given weight of the ore, say 200 gr., previously reduced to a fine powder, and intimately mix it with twice its weight of the nitrate of po- tassa or soda,* adding a little slaked lime to pre- vent it from fluxing; place it in an iron crucible, and subject it to a strong red heat for about 3 or 4 hours; then treat the mass with water to dissolve out the chromate. The insoluble matter having been washed several times until the water has ceased to come off colored, the washings are to be added together and evaporated to concentrate the solution. This being done, it is to be treated with an excess of dilute sulphuric acid to liberate the chromic acid, and then treated with spirit of wine, by which the chromic acid will be reduced to the state of green oxide, which will remain in solution in the preponderance of sulphuric acid em- ployed. A solution of caustic ammonia in excess is then to be added, which will precipitate the oxide of chromium; the mass is then boiled to evaporate the superabundance of ammonia. " It must now be passed through a filter to col- lect the oxide, and a little fresh water poured on it to free it from any saline matter: then gently dry on the filter, when it may be eitirely removed with ease, as the oxide, which was previously of a very bulky nature, contracts very considerably. It may then be subjected to a dull red heat in a silver, platinum, or porcelain crucible, and after- wards its weight ascertained, from which the per centage of oxide of chromium which the ore con- tains, and, consequently, the amount of sulphate required to convert it into a chromate, may be cal- culated." (Chemist, iv. 70.) Prop., Uses, <$-c. The commercial chromate of potash has a bright yellow color, but in other re- spects, resembles coarse culinary salt. It is used in various processes in the arts,—in dyeing, bleach- ing, the manufacture of chromic acid, bichromate of potassa, and several other chromates. * " It will be as well to use a nitrate in the analy-is; the quantity being small, it will be of no consequence." Pur. Chromate of potash is very commonly adulterated with sulphate and muriate of potash, it therefore becomes important to the manufacturer to be able to test its purity. I. (Tesr of M. Zuber.) Add tartaric acid, dis- solved in 50 parts of water, to a like solution of the sample. As soon as the decomposition is complete, and the color verges towards the green, the super- natant liquor should afford no precipitate with either the nitrate of silver or baryta, whence the absence of muriates and sulphates may be inferred. The proportions are, 8 parts of tartaric acid to 1 ' part of the chromate, both in solution. If saltpetre be the adulterating ingredient, the sample will de- flagrate when thrown upon burning coals. Mr. Watt says, " A short time ago, I was sup- plied with a sample which was nothing but sul- phate of soda and chloride of sodium, colored with a strong solution of the chromate, and which caused a white precipitate in any of the soluble salts of lead. For the benefit of the purchaser, I subjoin the following method of examining the chromates of potassa and soda. " First ascertain the quantity of moisture con- tained in the sample, by weighing out a certain portion, drying it on a sand-bath, and again weigh- ing ; the loss of weight will give the quantity of water: then dissolve it in distilled water, and add any soluble salt of lead until it ceases to give a precipitate. The mass is then to be boiled, and more distilled water added; the supernatant liquor is then to be poured off, and if the sample under examination contain any chloride of sodium, small shining crystalline needles of chloride of lead will form in the liquor as it cools. The remaining pre- cipitate is then to be treated with strong nitric acid, which will decompose the chromate ; by adding distilled water, the nitrate of lead, formed by the decomposition of the chromate of lead, will be dissolved, and the remaining sulphate of lead, if any, may be dried, and its amount ascertained, from which the quantity of sulphate in the chro- mate may be calculated. " If it be required to ascertain the quantity of chloride, this may be done by redissolving the chloride of lead by means of heat, and operating on it by any of the soluble salts of silver." (Chem- ist, iii. 388. CHROMATE OF POTASH, (BI- or SU- PER-.) Prep. Acidulate a concentrated solution of the neutral chromate with sulphuric, or, still better, the acetic acid. Then heat the liquid and allow it to cool slowly, when beautiful red crystals of bichromate of potash will be deposited. Its Prop., Uses, and Tests are the same as the neu- tral salt. CHROMATE OF POTASH, SOLUTION OF. Prep. Dissolve neutral chromate of potash 1 oz., in distilled water 1 lb. Use. As a test li- quor for metals, especially lead. CHROMATE OF SODA. This salt may be prepared in the same way as chromate of potash, by employing a salt of soda instead of potassa in the preceding processes. It may also be made on the small scale for experiment, by neutralizing chromic acid with carbonate of soda. Remarks. This salt has been proposnH as a sub- stitute for chromate of potassa, and has the ad- vantage in cheapness. " Why nitrate of potassa CHR 192 CHR has been so long employed in this manufacture, I am at a loss to discover; for it must be obvious that chromate of soda would answer all the pur- poses of chromate of potassa, the base being of little consequence, so long as it forms a soluble salt with the chromic acid, as it is merely useful as a vehicle for the chromic acid." (C. Watt, jun.) CHROME RED. Syn. Dichromate of Lead. Subchromate of ditto. Red Chromate of dit- to. Prep. I. Boil carbonate of lead with chro- mate of potash, in excess, until it assumes a prop- er color; wash well with pure water and dry in the shade. II. Boil neutral chromate of lead with a little water of ammonia or lime water. III. (Process of Liebig and Wohler.) Fuse saltpetre at a low red heat in a crucible, and throw in chrome yellow, by small portions at a time, until the nitre be nearly exhausted. A strong ebullition takes place upon each addition of the pigment, and the mass becomes black and remains so while hot. After it has settled for a minute or two, the fluid part should be poured off, and the mass remaining in the crucible washed with water, and dried by a gentle heat. Remarks. Great care must be taken in con- ducting the last process, not to employ too much heat, or to allow the saline matter to stand long over the newly-formed chrome-red, as the color is thus apt to change to a brown or orange. When well managed, the product has a crystalline tex- ture, and so beautiful a red color, that it vies with cinnabar. It has been proposed as a pigment. CHROME YELLOW. Syn. Chromate of Lead. Yellow Chromate of ditto. Prep. I. Add a filtered solution of nitrate or acetate of lead, to a like solution of neutral chromate of pot- ash ; collect the precipitate, wash it well, and dry it out of the reach of sulphureted vapors. II. To the lye of chromate of potash, prepared by roasting* the chrome ore with nitre, and lixivia- tion with water, add a solution of'acetate of lead, and proceed as before. Remarks. This substance is the beautiful pig- ment employed by painters. Four shades are usually met with in the shops, viz.: Pale yellow or straw color, yellow, full yellow, and orange. The former are made by adding a little alum or sulphuric acid to the solution of the chromate be- fore mixing it with the solution of lead ; the latter, by the addition of a little subacetate of lead. The darker color appears to arise from a little dichro- mate being thrown down intimately mixed with the neutral chromate, and the paler shades from a slight excess of acid. I found a little alumina in some samples of pale chrome yellow, which I lately examined, and in one instance a little sul- phate of lead. CHROMIC ACID. A compound of the metal chromium and oxygen. Prep. I. Pure chromic acid may be prepared by transmitting the gaseous fluoride of chromium into water contained in a vessel of platinum or sil- ver, and evaporating the liquid to dryness. II. Bv conducting gaseous fluoride of chromium into a silver or platinum vessel, the sides of which are just moistened with water, and the aperture eovered with a piece of moist paper, the acid will be deposited under the form of red acicular crys- tals, which will fill the vessel. III. "The principle upon which this is based is, that nitrate of baryta, which results from the decomposition of the chromate of baryta by nitric acid, is quite insoluble in concentrated nitric acid, which I have verified by many experiments, and which fact was, I believe, first observed by Mr. Reuben Phillips. " The chromic acid may* be separated from the nitrate of baryta by decantation, or, which is still better, by filtration through asbestos. Care must be taken not to let it come in contact witn any organic matter, or it will be decomposed. " The chromic acid is then to be evaporated to dryness, when the nitric acid will be volatilized, leaving pur* chromic acid. " When the quantity of chromic acid prepared by this plan is considerable, to reduce the expense as much as possible, it will be as well to carry on the evaporation so that the superabundance of ni- tric acid which has been used may be condensed, which may again be used for the same purpose. " The only precautions necessary to ensure the purity of the chromic acid prepared by this plan, are the following:—to use a sufficient quantity of nitric acid, and to take care that the nitric acid is sufficiently concentrated, and that it is pure, oth- erwise the impurities which it contains will remain in the chromic acid. " The chromate of baryta may be easily pre- pared by mixing together solutions of the chloride of barium, and any of the soluble chromates; be- fore it is used for the preparation of pure chromic acid, it should be washed several times." (Chem- ist, iii. 266.) On the commercial scale, crude chromic is pre- pared by either of the following plans: IV. To a saturated solution of 100 parts of chro- mate of potash in water, add 49 parts of sulphuric acid, (sp. gr. 1*845.) This is the common process, but the product contains sulphate of potash. V. Digest chromate of baryta in an equivalent proportion of sulphuric acid,.diluted with water; after a few hours decant the clear liquid. VI. Digest chromate of lead in sulphuric acid in equivalent proportions. Mr. Charles Watt, jun., recommends chro- mate of lime as a source of chromic acid. This salt he prepares from the oxide of chromium, con- tained in the "residual liquor of the process of bleaching with chromic acid, and this he effects by a very inexpensive process. The chromic solution is placed in a wooden vessel, and slaked lime cau- tiously added until the sulphuric or muriatic acid present is saturated, carefully avoiding excess, as oxide of chrome would be then precipitated. After an hour's repose the clear portion is decanted, and finely-slaked lime added, until all the oxide is thrown down ; which may be known by the liquor becoming clear when allowed to settle. During the addition of the lime, constant agitation must be employed. The oxide of chromium must now be allowed to settle, and after the liquid portion is de- canted, washed with a few pailfuls of clean water. After the latter has drained off, the residual mix- ture of oxide of chromium and lime must then be placed about 2 inches thick upon a laige flat iron plate, set evenly over a fire, and turned every half CHR 193 CID hour until the process be completed, which may be known by the mass assuming a yellow color, in- stead of the grayish one it previously possessed. Care must be taken not to employ too much heat, as the product of this process (chromate of lime) is readily decomposed, and assumes a green color, in which case it is rendered useless. From the chro- mate of lime the acid is procured by the action of an equivalent proportion of sulphuric acid. This process has the great recommendation of cheap- ness, and Mr. Watt says that he has employed it in the factory of Messrs. Haws, for nearly two years, with perfect success. Prop., Uses, cj-c. Pure chromic acid forms red crystals, and is soluble in water and alcohol. It is readily decomposed by the action of light and con- tact with organic matter. Hence it should be kept in stoppered glass bottles, and its solution filtered through asbestos. The ease with which it parts with a portion of its oxygen constitutes its value as a bleaching agent It is largely employed in the arts, in calico-printing, bleaching of textile fabrics, tallow, oils, &c. CHROMIUM, (from xpu/ia, color.) A metal discovered by Vauquelin in 1797. Prep. I. Mix dry chloride of chromium with oil, place the paste in a crucible lined with charcoal, lute on the cover, and expose it for an hour to an intense heat. (Vauquelin.) II. Heat the compound of terchloride of chro- mium and ammonia to redness, and expose it to a current of dry ammoniacal gas. (Liebig.) Remarks. The product of the first process has a whitish-yellow color, and a metallic lustre; that of the second is a black powder. Metallic chro- mium has not been applied to any use in the arts. CHROMIUM, CHLORIDE OF. Syn. Ses- tauiciiLORiDE of Chromium. Prep. I. Dissolve the hydrated oxide in muriatic acid, and evaporate to dryness. If. Digest chromate of lead in muriatic acid mixed with a little alcohol, and throw down the excess of lead with sulphureted hydrogen. III. Pass dry chlorine over a mixture of chrome oxide and charcoal heated to redness, in a porce- lain tube. The chloride collects as a sublimate, of a peach or purple color. Remarks. By the first process the product is a green powder, which, when heated to 400°, be- comes purplish red, and then forms pure, dry chlo- ride of chromium. This process should be per- formed in a tube filled with carbonic acid gas. CHROMIUM, OXIDE OF. Syn. Sesqui- oxide of Ditto- P>ep. To a solution of chromate of potash, add another of protonitrate of mercury as long as any precipitate falls down. This must be well washed in water, and heated to redness in an earthen crucible. II. Expose bichromate of potash to a strong red heat, then wash out the potassa with water. III. Expose bichromate of potash, mixed with half its weight of sulphur, as above. Prop. A green powder, insoluble in water. Fused with borax or glass, it imparls a beautiful green color. The emerald owes its color to this oxide. With the acids it forms salts which also have a green color. These compounds may be made by adding equal parts of muriatic acid and alcohol to a boiling solution of chromate of potassa, | 25 in water, in small portions at a time, until the red tint disappears, and the liquid assumes a green color. Pure ammonia, in excess, should now be added, when a hydrated green oxide will subside, which, after being washed with water, may be dissolved in the acids. Oxide of chrome is much used in the manufacture of colored glasses and enamels, and in dyeing. Remarks. The above appears to be the only ox- ide of chromium, in opposition to the assertion of Berzelius, that there is a protoxide and deutoxide. CHRYSAMMIC ACID. Prep. Add 1 part of aloes to 8 of nitric acid of sp. gr. 1-37, and heat the mixture in an open vessel. When the first violent action is over, introduce the whole into a retort, and distil to two-thirds. Then add 4 parts more of nitric acid, and keep the mixture nearly at the boiling point for some days, or as long as ga« is disengaged. Water should next be added, which will throw down impure chrysammic acid, while chrysolepic acid and oxalic acid will remain in so- lution. The precipitate must be well washed with water combined with potash, and purified by re- crystallization. The crystals are next dissolved in water, and nitric acid added, when a golden yel- low powder will be deposited, which is chrysammic acid. Prop. Soluble in alcohol, ether, and hot acids; explodes by heat, and forms salts, called chrysam- mates, with the bases. The salt of potash, pre- pared as above, is a beautiful crystalline carmine red powder, and when slowly produced it forms beautiful small greenish golden crystals. The salts of soda and magnesia are similar. Ammonia forms, with chrysammic acid, a deep purple solution, which deposites dark green crystals. The other salts of this acid are all of great beauty, and mostly of various shades of red, and exhibit a golden lus- tre under the polishing steel. CIDER. Syn. Cyder. Pomatium. Cidre, (Fr.) The fermented juice of the apple. Cider and per- ry were known to antiquity, and are mentioned by Pliny, who calls them the wine of apples and pears. Modern Europe is, however, indebted to the Moors of Biscay, who introduced its manufac- ture into Normandy, whence it spread into the other provinces of France, into England, Germa- ny, Russia, and America. The best cider made at the present day is that of Normandy, Hereford- shire, and^New Jersey, (U. S.,) and, next, that of Devonshire and Somersetshire. The last is, how- ever, very inferior. Cider is made in all the tem- perate climates of the world, where the heat is insufficient to produce the grape, and the cold not so great as to interfere with the growth of the apple. The process of making cider varies in different parts of England, but in every case essentially consists of—the collection of the'fruit; the expres- sion and fermentation of the juice ; and the storing and management of the fermented liquor. The apples are crushed or ground in a mill, and the pulp placed in haircloth or coarse canvass bags, and subjected to powerful pressure : tlj,e liquor which runs off is put into casks, and freely ex- posed to the air in the shade, and allowed to fer- ment. This part of the process is carefully watched, and as soon as the sediment has subsided, the liquor is racked off into clean sasks. Before winter the CID 194 CID tasks are stored in a cellar, or other cool place, ivhere the temperature is low and regular, and by the following spring the liquor is fit for use or bot- tling. Remarks. Much of the excellence of cider de- pends upon the temperature at which the ferment- ation is conducted ; but this is a point utterly over- looked by the manufacturers of this liquor. Instead of the apple-juice, as soon as expressed from the fruit, being placed in a cool situation, where the temperature should not exceed 50° of Fahr., it is frequently left exposed to the full heat of autumn. In this way much of the alcohol formed by the decomposition of the sugar is converted into vine- gar, by the absorption of atmospheric oxygen, and thus the liquor acquires that peculiar and unwhole- some acidity, known in the cider districts by the name of " roughness." On the contrary, if the fermentation be conducted at a low temperature, nearly the whole of the sugar is converted into alcohol, and this remains in the liquor instead of undergoing the process of acetification. The ace- tous fermentation, or the conversion of alcohol into vinegar, proceeds most rapidly at a temperature of 95° Fahr., and at lower temperatures, the ac- tion becomes slower, until at 46° 50" Fahr., no such change takes place. (Liebig.) It is therefore quite evident that if the saccharine juice of apples, or any other fruit, be made to undergo the vinous fermentation in a cool situation, less of the spirit resulting from the transformation of the sugar will be converted into acetic acid, and consequently more will be retained in an unaltered state in the liquor, and tend not only to improve its quality, but by its conservative and chemical action, to precipitate the nitrogenous substances, or exciters of future change. Independently of differences in the quality of the fruit, this is the principal cause of the superiority of the cider made by one person over another, living in the same district. The one has probably a cooler barn and cellar than the other to store his cider in. In practice it has been found that sour and rough-tasted apples produce the best cider. This arises because they contain less sugar and more malic acid, and the presence of the latter impedes the conversion of alcohol into vinegar. But cider made with such apples can never equal in quality that prepared at a tow tem- perature from fruit abounding in sugar. In De- vonshire the pressing and fermentation are con- ducted in situations where the temperature varies but little from the external air, and fluctuates with all its changes ; the result is that Devonshire cider, of the best class, will rarely keep more than 5 or 6 years, and seldom improves after the second or third year, while the cider of Herefordshire and Worcestershire, where these operations are more carefully attended to, will keep for 20 or 30 years. In the cider counties the culture of the apple engages especial attention. Dry rising ground, sheltered from the northerly and easterly winds, is best suited for an orchard. The fruit, after be- ing gathered, is usually left for 14 or 15 days, in a barn or loft, to mellow or mature, during which time a considerable portion of the mucilage is de- composed, and alcohol and carbonic acid developed. The spoiled apples should then be separated from the sound ones, as they not only impart a bad fla- vor to the cider, but prevent its spontaneous clari- fication. Unripe apples should also be avoided, as they do not contain sufficient sugar to undergo the vinous fermentation, while they contribute to ren- der the liquor rough and acidulous. Sour and rough-tasted apples are usually preferred by fann- ers for making cider, but fruit abounding in sugar would be preferable, provided the same skill were exercised in the manufacture of cider as in the process of brewing malt liquor. As the juice of apples contains less sugar in pro« portion to the amount of acid and nit/ogenizea matter than that of grapes, the addition of some of this article would render it more suitable for the production of a vinous liquor. Good West India sugar is the best for this purpose. I have tasted cider made in this way, and that had been stored in fresh emptied rum puncheons, that had all the pungency and vinosity of foreign wine. The best cider yields about 9 or 10$ of real alco- hol. Ordinary cider from 4 to 6$. CIDER, DEVONSHIRE. The ap; **, after being plucked, are left in heaps in the orchard for some time, to complete their ripening, and ren- der them more sacch^ jne. They are then crushed between grooved cylinders, surmounted by a hop- per, or in a circular trough, by two vertical edge- wheels of wood moved by a horse ; after passing through which, they are received into large tubs or cives, and are then 'called pommage. They are afterwards laid on the vat in alternate layers of the pommage and clean straw, called reeds. They are then pressed, a little water being occa- sionally added. The juice passes through a hair sieve, or similar strainer, and is received in a large vessel, whence it is run into casks or open vats, where every thing held in mechanical suspension is deposited. The fermentation is often slow of being developed; though the juice be set in No- vember or December, the working sometimes hardly commences till March. Till this time the cider is sweet; it now becomes pungent and vi- nous, and is ready to be racked for use. If the fermentation continue, it is usual to rack it again into a clean cask that has been well sulphured out, and to leave behind the head and sediment; or two or three cans of cider are put into a clean cask: and a match of brimstone burned in it: it is then agitated, by vwhich the fermentation of that quan- tity is completely stopped. The cask is then nearly filled, the fermentation of the whole is checked, and the cider becomes fine. If, on the first opera- tion, the fermentation is not checked, the process of racking is repeated until it becomes so, and is continued from time to time till the cider is in a quiet state and fit for drinking. A common practice in Devonshire is to add a stuff called " stum," sold by the wine-coopers, or • an article called " anti-ferment," sold by the drug- gists, for the purpose of checking the fermentation, but a much better plan is to rack, as above de- scribed, into a well-sulphured cask, and to add 5 or 6 oz. of mustard-seed, and £ oz. cloves, both well bruised ; racking into a fresh-emptied spirit cask ii also a good plan. About six sacks, or twenty-four bushels of ap- ples, are used for a hogshead of 63 gallons. If the weather be warm, it will be necessary to carry on the process in the shade, in the open air, and by every means to keep the juice as cool as jwssible CID 195 CIN In nine months it will usually be in condition for bottling or drinking ; if it continues thick use some isinglass finings, and if at any time it fer- ments and threatens acidity, the cure is to rack it, and leave the head and sediment behind. CIDER, CHAMPAGNE. Prep. Good pale vinous cider 1 hogshead ; proof spirit (pale) 3 gal- lons ; honey or sugar 14 lbs.; mix, and let them remain together in a temperate situation for 1 month; then add orange-flower water 1 quart ; and fine it down with skimmed milk 4 a gallon. Remarks. This will be very pale ; and a simi- lar article, when bottled in champagne bottles, silvered, and labelled, has been often sold to the ignorant for champagne. It opens very brisk, if managed properly. C1DEK CHEESE. The residuum or cake of pommage or bruised apples, from which the juice has been expressed. It forms excellent food for pigs, and is very acceptable to them. CIDER, FRENCH. After the fruit is mashed in a mill, between iron cylinders, it is allowed to remain in a large tun or tub for 14 or 15 hours, before pressing. The juice is placed in casks, which are kept quite full, and so placed upon gawntrees, or stillions, that small tubs may be put under them, to receive the matter that works over. At the end of 3 or 4 days, for sweet cider, and 9 or 10 days for strong cider, it is racked into sul- phured casks, and then stored in a cool place. CIDER, MANAGEMENT OF. Cider should be stored in a cool place, and should not be drunk before it becomes sufficiently mature. To improve the flavor of a hogshead of cider, 14 gallons of good brandy or rum are frequently added, with 2 oz. of powdered catechu, (dissolved in water,) 7 lbs. of good moist sugar or honey, 4 oz. each of bitter almonds and cloves, and 4 oz. of mustard seed. These must be well rummaged in, and oc- casionally stirred up for a fortnight, after which it must be allowed to repose for 3 or 4 months, when it will usually be found as bright as wine. Should this not be the case, it must be fined with a pint of isinglass finings, or a dozen eggs, and in a fort- night more it will be fit for use. If the cider be preferred pale, omit the catechu, and instead of isinglass fine with a quart of skimmed milk. If wanted of a light reddish, or rose tint, use 4 oz. of cochineal, and omit the catechu. Preparatory to bottling cider it should be exam- ined, to see whether it be clear ai»d sparkling. If not it should be clarified in a similar way to beer, and left for a fortnight. The night before it is in- tended to put it into bottles, the bung should be taken out of the cask, and left so until the next day, when it may be bottled, but not corked down until the day after, as, if this be done aft once, many of the bottles will burst by keeping. The best corks, and champagne-bottles should be used, and it is usual to wire and cover the corks with tinfoil, after the manner of champagne. A few bottles may be kept in a warm place to ripen, or a small piece of lump sugar may be put into each bottle before corking, if the cider be wanted for immediate use, or for consumption during the cooler portion of the year, but for warm weather and for long keeping this is inadmissible. The bottled stock should be stored in a cool cellar, when the quality will be greatly improved by age. Cider for bottling should be of good quality, and at least 18 months old. CIDER, MADE. An article under this name is made in Devonshire, for the supply of the Lon- don market, it having been found that the ordi- nary cider will not stand a voyage to the metrop- olis without some preparation. The finest quality of made cider is only ordinary cider racked into a clean cask, and well sulphured; but the mass of that which is sent to London, is mixed with water, treacle, and alum, and then fined down, after which it is racked into well-matched casks. The larger portion of the cider sold in London, profess- ing to be Devonshire cider, would be rejected even by the farmers' servants in that county. CIDER MOIL. Syn. Water Moil. A weak cider or liquor, prepared by adding water to the pressed cake, and fermenting. Very inferior. CIDER, RAISIN. This is made in a similar way to raisin wine, but without employing sugar, and with only 2 lbs. of raisins to the gallon, or even more, of water. It is usually fit for bottling in 10 days, and in a week more is ready for use. CIDER-SPIRIT. Syn. Cider Brandy. Ob- tained from cider by distillation. It is largely manufactured in America, where a very decent article may be purchased for about 50 cents per gallon, at proof. An illicit distillation of this spirit is frequently carried on by the farmers in the west of England. CIGARS, MERCURIAL. M. Paul Bernard lately proposed to the Academie de la M6decine the use of cigars impregnated with a weak solu- tion of bichloride of mercury, for persons afflicted with syphilitic affections of the throat and palate, as a mode of conveying mercurial fumigation. It has been proposed first to deprive the tobacco of its nicotin by frequent washings. (Lancet, May 13, 1843.) CINCHONA BARK. There are three kinds of cinchona bark employed in medicine ; the cor- tex cinchonas lancifolias, (of the London and Dub- lin Pharmacopoeias,) or the cortex cinchonas con- daminea, (of the Ed. Ph.,) commonly known in commerce as pale, crown, loxa, or quillbark; the cortex cinchonas cordifolias, (Lond. and Dub.,) or the cortex cinchonas flavas, (Edin.,) commonly known as yellow or royal yellow bark ; and the cortex cinchonas oblongifolias, (Lond. and Dub.,) or red cinchona bark, (Edin.:) medically considered, they are all tonic and febrifuge, and may be given in powder, from 20 grs. to 3ij, every two or four hours, so as to get down an ounce between each fit of intermittent fever ; used also to stop the progress of gangrene ; they are also given in infu- sion and decoction. Since the introduction of the cinchona alkaloids, the employment of bark in substance has considerably lessened. Pur. The officinal species of cinchona bark are frequently imported mixed with other kinds, that contain less of the febrifuge principle. The most common adulteration is, however, the admixture of the same drug that has been exhausted of its active portions. This method consists in employ- ing the bark, but slightly broken, (or generally whole, as imported,) for the manufacture of sul- phate of quinine, cinchonine, and tincture, infu- sion, decoction, and extract of bark, after which it is carefully dried, without injury to its color, and CIN 196 CIN mixed up with fresh bark for sale, or is sent to the mill to be ground into powder. The greater amount of adulteration is generally practised on the powder, on account of the fraud being less easily detected when the drug is in the pulveru- lent state. Not only is the worst description of bark chosen for grinding, frequently largely ad- mixed with exhausted balk, as just mentioned, but " the roots of bistort, calamus aromaticus, avens, water-avens, and tormentil; oak bark, that of sev- eral kinds of willow, horse-chesnut, ash, and the sloe bush ; mahogany sawdust, the dried herbs of yellow loosestrife, bugle, wa.ter-horehound, and self-heal, are used either as substitutes or to re- duce the price of the ground bark ; as is also the root of Geum montanum. The barks of Pinknea ^ubescens, Unnona febrifuga, Swietenia febrifuga, Cedrela tuna, Magnolia glauca, M. acuminata, M. tripetala, Aehras sapota, Rubus trivialis, and R. villosus, are also used as substitutes,'' (Gray ;) and, in fact, any trash that will possibly produce a powder at all resembling that of bark, or that can be made so by grinding and the addition of coloring. Tests. The simplest and only certain method of ascertaining the quality of cinchona bark, and of detecting fraudulent admixture, is by an assay for the alkaloid. (See Qcinometry.) The tannic acid which exists in every species of cinchona bark, may be recognised by its precipitating the sesquichloride of iron of a green color, gelatine of a whitish color, and a solution of tartar emetic of a dirty white. CINCHONIA. Syn. Cinchonine. Cinciio- nina. Cinchonium. An alkaline principle ex- tracted from pale cinchona bark, in the same way as quinine is from yellow cinchona bark. Prep. I. Add ammonia to a dilute solution of sulphate of cinchonine, as long as any precipitate falls. Wash with cold water, dissolve in «alcohol and crystallize. II. A pound of bruised bark is boiled in about a gallon of water, to which 3 fluid drachms of sul- phuric acid have been previously added. A simi- lar decoction is repeated with about half the quan- tity of liquid, and so on till all the soluble matter is extracted. The decoctions are then mixed to- gether, and strained ; and powdered slaked lime is added, in a proportion somewhat greater than necessary to saturate the acid ; the precipitate that ensues (a mixture of cinchonina and sulphate of lime) is collected, dried, and boiled for some minutes- in strong alcohol, which is then decanted off while still hot, and fresh portions successively added for the repetition of the same operation, un- til it ceases to act on the residuum, which is then merely sulphate of lime. The different alcoholic solutions are then put into a retort or still, and considerably evaporated, during which, and espe- cially on cooling, acicular crystals of cinchonina are deposited. When the whole is thus collected, the crystals, if yellow or discolored, must be again dissolved in boiling alcohol, and thus, by recrystal- lization, they will be obtained colorless. (Brande's Manual of Pharm.) III. Boil Peruvian bark in alcohol until all the bitterness is extracted; distil to dryness, dissolve the extract in boiling water, rendered very sour, with muriatic acid; add calcined magnesia, boil for a few minutes till the liquor is clear; when cold, filter, wash the sediment left on the filter with cold water, dry it, boil alcohol upon it until all the bitterness is extracted; pour off the alcohol, and, as it cools, the cinchonine will crystallize. It may be purified by solution in a very weak acid, and the addition of an alkali. Prop, and Uses. These are similar to quinine. It is, however, rather less soluble in water than that alkaloid, as it requires 2500 parts of water, at 60°, for its solution. It forms salts with the acids, all of which may be made in the samo manner as those of quinine. The neutral sul- phate, bisulphate, disulphate, muriate, nitrate, io- dide, iodate, &c. have been formed and examined. Purity and Tests. (See Quinine.) CINNAMMIC ACID. A substance discovered by Dumas and Peligot in oil of cinnamon. It crys- tallizes out of the oil when long exposed to the at- mosphere: Prep. Dissolve oil of balsam of Peru in potassa water, evaporate to dryness, tI:ssolve the residuum in boiling water, and add an excess of muriatic acid. The cinnammic acid is deposited in crys- tals as the solution cools, and may be purified by re-solution and crystallization. II. By cautious distillation of balsam of Tolu by a gentle heat it fuses, and a little water and vola- tile oil first comes over, followed by cinnammic acid, in the form of a heavy oil, which condenses on the cool parts of the neck of the retort, as a white crystalline mass. Towards the end of the process, some empyreumatic oil distils over. The acid must be purified by pressure between the folds of*filtering paper and solution in boiling wa- ter. On cooling, minute colorless crystals of cin- nammic acid will be deposited. Pure balsam of Tolu yields about J of its weight of this acid. (Mr. Heaver in the Ann. Chym.) Prop. Colorless transparent scales, or prisms, scarcely soluble in water, but freely so in alcohol. Fuses at 240° ; volatilizes unchanged at 555°. It forms salts with the bases, called cinnammates, which generally resemble the benzoates. CINNAMEINE. Syn. Oil of Balsam of Peru. Prep. Add an alcoholic solution of bal- sam of Peru, to a like solution of potassa. A com- pound of resin and potassa is precipitated, and cinnammate of potassa and cinuttmeine are left in solution. On adding "water, the latter separates and floats uponjtfie surface. II. Add 2 measures of balbam of Peru to 3 of liquor of potassa, (sp. gr. 1*300,) apply a gentle heat, when a yellowish brown oil will separate and float above a heavy black liquid, containing the potash. The former must be collected, and may be purified by cautious distillation. Prep., 6fC It dissolves in alcohol and ether, and by the action of alkalis is converted into cin- nammic acid. CINNAMON. From the high price of this drug, it has become a general practice to substitute cassia for it, which so exceedingly resembles it that most persons, unacquainted with the drug, regard them as the same. Cassia is, however, not only thicker and coarser than cinnamon, but its frac- ture is short and resinous, and its flavor is more biting and hot, while it lacks the peculiar sweetish taste of the latter spice. The thickness of cinna CIT 197 CIT mon seldom exceeds that of good drawing paper. The same remarks are also applicable to the oil and powder. In pharmacy it is a general practice to employ cassia and its preparations whenever those of cinnamon are ordered. Both these drugs are wholesome aromatics. The principal con- sumers of genuine cinnamon are the chocolate- makers of France, Spain, Italy, and Mexico. The Germans, Turks, and Russians prefer chocolate flavored with cassia. " Some cinnamon, sent to Constantinople by mistake, proved unsaleable at any price, while cassia, worth about sixpence per pound, was in great request." (Pereira.) CITRATES. Salts formed of the citric acid and the bases. ^ Prep. Those in general use may be all made by the addition of either the hydrate, oxide, or carbonate of the base, to a solution of the acid in water, until the latter be neutralized, when crys- tals may generally be obtained by evaporation. Prop., tf-c. The citrates are mostly soluble, and when heated, froth, blacken, and are decomposed. When an anhydrous citrate is decompose^ by an alcoholic solution of hydrochloric acid, the . trie acid is principally transformed into hydrated aconi- tic acid. Char, and Tests. The citrates are character- ized by giving a white precipitate with acetate of lead, soluble in ammonia, and also a white precip- itate with nitrate of silver, which, by the applica- tion of heat, froths up, deflagrates, and leaves an abundant ash, which, on increasing the heat, be- comes pure silver. Remarks. The principal citrates are citrate of ammonia, (soluble and crystallizable ;) citrate of potash, (very soluble and deliquescent;) citrate of soda, (large crystals, soluble ;) citrate of baryta, (beautiful shining silvery bushes, scarcely soluble ;) citrate of lime, (see Citric Acid ;) magnesia, alumina, and protoxide of manganese, each form 2 salts with citric acid, one soluble, the other insolu- ble ; citrate of protoxide of iron, (scarcely soluble and crystallizable ;) percitrate of iron, (soluble and brown ;) ammonio-citrate of iron, (garnet colored, very soluble ;) citrate of zinc, (scarcely soluble ;) citrate of lead, (insoluble white powder;) citrate of copper, (green powder ;) citrate of silver, (bril- liant white powder ;) potassio-citrate of antimony, (dazzling white prisms.) CITRATE, OR AMMONIO-CITRATE OF IRON. Syn. Ammonio-Citrate of Peroxide of Iron. Ferro-Citrate of Ammonia. Percitrate of Iron and Ammonia. There are three salts generally known under this name—two, having the peroxide for their base, and one, the protoxide. There is also a fourth, formed from the magnetic oxide of iron, which has scarcely been introduced into this country, though commonly employed in France, and highly recommended by Beral. The salt at present so much advertised as citrate of iron, is a double citrate of iron and ammonia—an ammonio-citrate, and as such I shall describe it. I find that several other double citrates of iron may be prepared, but they are possessed of inferior qualities to those just mentioned. They therefore offer no inducement for their manufacture. I. This-salt is most conveniently formed by dis- solving moist hydrated peroxide of iron in liquid citric acid, (pure,) assisting the solution by heat, and then bringing it to a perfectly neutral state by the addition of a little sesquicarbonate of ammonia. It must then be filtered, cooled, and spread very thinly on warm sheets of glass to dry, which it ,will rapidly do, and may then be easily detached from the glass, in thin scales, or lamellas, of great brilliancy and beauty. Only a gentle heat must be employed, not exceeding that of a water-bath. This is the mystery of producing those beautiful transparent ruby-colored scales which are so much admired. II. Competition in the sale of this article has in- duced the manufacturer to adopt a cheaper for- mula than that originally published by Beral and employed by many houses. It is now generally prepared by placing together, for some days, in a warm situation, a mixture of iron, filings, and citric acid in powder, with barely sufficient water to co- ver them, occasionally stirring and replacing the water as it evaporates. A saturated solution is made in distilled water, there being previously ad- ded more citric acid, (about half the weight of the acid first used,) if required ; it is the. eutralized with liq. ammon. fort, (about 1^ oz. of liquor of am- monia, sp. gr. -882, to every gallon of the solution of sp. gr. 1-025,) and concentrated by evaporation: the same plan mentioned above is then followed, to complete the process. The first part of this pro- cess produces a salt of the protoxide of iron, which is afterwards converted, by exposure to the atmo- sphere, into a citrate of the magnetic oxide, and lastly into citrate of peroxide of iron. Remarks. This beautiful salt is of a rich ruby color, and may be obtained under the form of glis- tening transparent scales, very soluble in aqueous menstrua, while its solution is not so easily decom- posed as that of many other salts of iron. It is ntarly tasteless, and highly deliquescent. The ab- surd statements put forth in advertisements re- specting this preparation being compatible with the volatile and fixed alkalis and their carbonates, &c, I find to be ipcorrect; for on adding some liquor potassas to a solution of this salt, it imme- diately became turbid, exhaled ammonia in large quantities, and deposited oxide of iron. I found the same take place with the carbonate ; and no doubt, had I extended the experiments to the other arti- cles mentioned as compatible, I should have met with another similar result. It is doubtful whether this article has not obtained a larger sale from its pleasing appearance, than from its medicinal vir- tues. I know several parties who have prepared this salt in lumps or powder, by simple evapora- tion of the solution to dryness, who have been un- able to sell it under that form, even at a lower price. M. Beral, in his directions for the preparatiori of this salt, directs a platina capsule to be used, as well as attention to other minutias, which I find quite unessential to the success of the operation. Glass, Wedgewood ware, or even metallic vessels, may be employed; the former, however, are pref- erable. I find that boiling water will dissolve about twice its weight of citric acid, and retain 4■» of this quantity in solution when cold, and that it takes rather more than twice the weight of the citric acid, in most hydrated protoxide of iron, to produce saturation. We may, therefore, with great advantage, em- CIT 198 CIT ploy the following formula, which contains nearly the proportions recommended by Beral, but which has the advantage of employing the protoxide for the peroxide, and thus saving the nitric acid neces- sary to form the latter. Crystals of citric acid, . 1 part. Boiling distilled water, . . 2 do. Dissolve; add Moist hydrated protoxide of iron, . 2 J do. Continue the heat until the acid is saturated, then add ammonia q. s. Filter, &c. It is better to use more oxide than the acid will dissolve, as the remainder may be employed in a future operation. Less water may be used, or even a larger quantity than that mentioned; but in the first case, the liquid will become difficult to filter—in the latter, it will require more evap- oration. CITRATE OF IROx\. Syn. Citrate of Peroxide of Iron. Percitrate of Iron. Prep. As the last, omitting the ammonia. It resembles the ammonio-citrate, but is only slightly soluble in water. CITRATE OF PROTOXIDE OF IRON. Syn. Protocitrate of Iron. Prep. This salt is easily formed by digesting iron filings or wire in liquid citric acid. It presents the appearance of a white powder, nearly insoluble in water, and rap- idly passing to a higher state of oxidation under the influence of light, damp, or warmth, or mere exposure to the air under most ordinary circum- stances. Its taste is very metallic, and it is best exhibited under the form of pills, mixed with gum and simp, or sirup alone, to prevent it from being prematurely decomposed. CITRATE OF MAGNETIC OXIDE OF IRON. Prepared from the magnetic oxide of iron, in the same way as the last It may be formed into beautiful transparent scales, or la- mella?, in a similar manner to the ammonio- citrate. Its solution is of a lively green color, permanent in the air, but possessing an intensely ferruginous taste. For this reason, this citrate can only be exhibited in pills or sirup. CITRIC ACID. Syn. White Citric Acid. Concrete Acid of Lemons. Crystallized ditto. Acid citrique, (Fr.) Citronensaure, (Ger.) An acid peculiar to the vegetable kingdom, and found in the juices of several kinds of fruit, espe- cially those of the genus citrus. The process of its manufacture consists in sep- arating it from the mucilage, sugar, and other foreign matter with which it is combined. Prep. Each of the British Colleges gives a formula for the preparation of citric acid. I. (Acidum citricum, P. L.) Take of lemon juice 4 pints; prepared chalk ^'vss; diluted sul- phuric acid f %xxviiss; distilled water 2 pints. Add the chalk by degrees to the lemon juice, heated, and mix; set by, that the powder may precipitate; afterwards pour off the supernatant liquor Wash the citrate of lime frequently with warm water; then pour upon it the diluted sul- phuric acid and the distilled water, and boil for 15 minutes; press the liquor strongly through a linen cloth, and filter it. Evaporate the filtered liquor with a gentle heat, and set it aside that crystals may form. To obtain the crystals pure, dissolve them in water a second and a third time; filter each solution, evaporate, and set it apart to crys- tallize. The process of the Dublin and Edinburgh Colleges is similar, but the latter orders the washed citrate of lime to be squeezed in a powerful press, and also the filtered solution of citric acid to be tested with nitrate of baryta, and if " the precipi- tate is not nearly all soluble in nitric acid, edd a little citrate of lime to the whole liquor, till it stand this test." Remarks. The preparation of citric acid has be- come an important branch of chemical manufac- ture, from the large consumption of this article in various operations in the arts. In conducting this process, some .little expertness and care are neces- sary to ensure success. The chalk employed should be dry, and in fine powder, and be added to the juice until it be perfectly neutralized, and the quantity consumed must be exactly noted. The precipitated citrate of lime should be well washed, and the sulphuric acid diluted with 6 or 8 times its weight of water, poured upon it while still warm, and thoroughly mixed with it. The agitation must be occasionally renewed for 8 or 10 hours, when the dilute citric acid must be poured off, and the residuum of sulphate of lime thorough- ly washed with warm water, and the washings added to the dilute acid. The latter must then be poured off from the impurities that may have been deposited, and evaporated in a leaden boiler, over the naked fire, until it acquires the gravity of 1*13, when the process must be continued by steam heat until a pellicle appears upon the surface. This part of the process requires great attention and judgment, as, if not properly conducted, the whole batch may be carbonized and spoiled. The proper time for withdrawing the heat is in- dicated by the liquid assuming a sirupy aspect, and by a film or pellicle appearing, first in small patches, and then gradually creeping over the whole surface. At this point the evaporation must be stopped, and the concentrated solution emptied into warm and clean crystallizing vessels, set in a dry apartment, where the thermometer does not fall below temperate. At the end of 4 days the crystals will be ready to remove from the pans, when they must be well drained, redissolv- ed in as little water as possible, and after being allowed to stand for a few hours to deposite impuri- ties, again evaporated and crystallized. When the process has been well managed, the acid of the second crystallization will usually be suffi- ciently pure; but if this be not the case, a third, or even a fourth crystallization must be had re- course to. The mother liquors from the several pans are collected together, and, by evaporation, yield a second or third crop of crystals. Citric acid crystallizes with great ease, but in some cases, where all the citrate of lime has not undergone de- composition by the sulphuric acid, a little of that salt is taken up by the free citric acid, and mate- rially obstructs the crystallization. This is best avoided by exactly apportioning the quantity of the sulphuric acid to that of the chalk used, al- ways remembering that it requires a quantity of liquid sulphuric acid, containing exactly 40 parts of dry acid, to decompose 50 parts of carbonate of lime. Commercial sulphuric acid is usually of the sp. gr. of 1-845, it will therefore take exactly 49 lbs. of this acid for 50 lbs. of chalk. CIT 199 CLA Sulphuric acid of sp. gr. 1-8418 contains exactly 80 per cent of real acid; it is, consequently, a very convenient way to use it of this strength, when the quantity of chalk and acid may be ex- actly the same. In practice it is found that a very slight excess of sulphuric acid is better than leaving any citrate of lime undecomposed. This excess must, however, be very trifling. This may be ascertained by nitrate of barytes, which will give a white precipitate, insoluble in nitric acid if oil of vitriol be present. The first crop of crystals is called " brown citric acid," and is much used by the calico printers. Sometimes a little nitric acid is added to the solution of the colored crystals, for the purpose of whitening them. Good lemon-juice yields fully 5$ of lemon acid, or 2 gallons yield about 1 lb. of crystals. If the im- ported citrate of lime be used," a given quantity must be heated to redness, and then weighed, when the per centage of limt present will be ascertained ; every 28 lbs. of which will require 49 lbs. of sulphuric acid of 1-845, (or a quantity containing exactly 40 parts of dry acid,) for its complete decomposition. Prop., Uses, tyc. Form, rhomboidal prisms; clear, colorless, odorless, sour, and deliquescent in a moist atmosphere. It is an agreeable acid, at once cooling and antiseptic. It is much used in medicine as a substitute for lemon juice, and to form effervescing draughts, citrates, &c. 20 grs. commercial citric acid in crystals, are equivalent to .------------*-----------, 29 grs. crystals of bicarbonate of potassa; 24 grs. of commercial carbonate of do.; 17 " sesquicarbonate of ammonia; 41 " crystals of carbonate of soda ; 24 " commercial sesquicarbonate of soda. The bicarbonate of potassa is that generally used for making saline draughts with citric acid, and flavored with tincture of orange peel and sim- ple sirup, or sirup of orange peel alone, forms a most delicious effervescing beverage. Pur. and Tests. Citric acid is frequently adul- terated with tartaric acid. This may be easily detected by dissolving a little in a small quantity of water, and adding cautiously a solution of car- bonate of potash, taking care that the acid be in excess. ' If any tartaric acid be present, a white precipitate of cream of tartar will be formed. The London College states that "it is entirely soluble in water, and what is thrown down by acetate of lead from this solution, is entirely soluble in dilute nitric acid. No salt of potassa, except the tar- trate, yields a precipitate with the aqueous solu- tion. It is entirely destroyed by heat." (P. L.) " When a few drops of a solution of citric acid are added to lime water, a clear liquid results, which, when heated, deposites a white powder, soluble in acids without effervescence." (Liebig.) CITRONELLE. Syn. Eau de Barbades. Prep. I. Fresh orange peel 2 oz.; fresh lemon peel 4 oz.; cloves 4 drachm; corianders and cinna- mon, of each 1 drachm ; proof spirit 4 pints. Di- gest for 10 days, then add water 1 quart, and dis- til 4 gallon. To the rectified cordial add white sugar 2 lbs. II. Add of essence of orange 4 drachm ; essence of lemon 1 drachm; oil of cloves and cassia, of each 10 drops; oil of coriander 20 drops to 5 pints of spirit—at 58 o. p. Agitate until dissolved, then add distilled or clear soft water 3 pints; well mix, and if the liquor be not clear, shake it up with a spoonful of magnesia, and filter it through blotting paper, placed on a funnel; when it has all run through and is clear, add a sufficient quantity of sugar. Remarks. This last form does not require distil- lation. CITRONS. The fruit of the citron tree (the citrus medica) is acidulous, antiseptic, and antiscor- butic ; it excites the appetite and stops vomiting. Mixed with cordials, it is used as an antidote to the manchineel poison. The rind of the fruit is odorous, aromatic, and tonic, and yields the es- sence de cedrat, so much esteemed by the liqueur- ist and perfumer. The fragrant essence of the rind may be easily obtained by the following sim- ple process:—After'cleaning off any speck in the outer rind of the fruit, break off a large piece of loaf sugar, and rub the citron on it till the yellow rind is completely absorbed. Those parts of the sugar which are impregnated with the essence are, from time to time, to be cut away with a knife, and put into an earthen dish. The whole being thus taken off, the sugared essence is to be closely pressed, and put by in pots, where it is to be squeezed down hard; have a bladder over the pa- per by which it is covered, and tied tightly up. It is at any time fit for use, and will keep for many years. Exactly in the same manner may be ob- tained and preserved the essences of the rinds of Seville oranges, lemons, bergamots, &c. CITRON PEEL, CANDIED. Prep. Soak the peels in water, which must be frequently changed, until the bitterness is extracted, then drain and place them in sirup, until they become soft and transparent; the strength of the sirup be- ing kept up by boiling it occasionally with fresh sugar. When they are taken out, they should be drained and placed on a hair sieve to dry, in a dry and warm situation. Use. Stomachic; much used as a sweetmeat, and by the confectioner and pastry-cook. CIVET. Syn. Zibethum. A perfume, ob- tained from the civet cat, a fierce carnivorous quadruped, somewhat resenfbling a fox, found in China, and the East and West Indies. " Several of these animals have been brought into Holland, and afford a considerable branch of commerce, es- pecially at Amsterdam. The civet is squeezed out in summer every other day, in winter twice a week ; the quantity procured at once is from 2 scruples to 1 drachm or more. The juice thus collected is much smoother and finer than that which the an- imal sheds against trees and stones in its native climate." (Ure.) It is frequently adulterated with spermaceti and butter, and a similar sub- stance to civet, but of a darker color, and obtained from the polecat, is frequently mixed with it. CLAIRET. Syn. Rossalis des six graines. Prep. Aniseed, fennel seed, coriander seed, cara- way seed, dill seed, and seeds of daucus creticus, of each 1 oz.; bruise them in a clean mortar, then steep^them in 4 a gallon of proof spirit for 1 week, strain, and add 1 lb. of loaf sugar. CLARET RAGS. Syn. Tournesol en Dra- CLE 200 CLd peau. Bezetta Ccerulea. Prep. I. Color pieces of clean linen with auvergne or ground archel, (lichen parellus.) II. Dip pieces of clean linen into the juice of mulberries, blood-red grapes, lees of red wine, &c. Use. To color jellies and confectionary, and the rind of cheeses. CLARIFICATION. This word (from clarus, clear, and facio, I make) means, properly, any process of freeing a fluid from heterogeneous mat- ter, and thus includes filtration. In its commoner sense, however, it is applied to the process of clear- ing liquids by the addition of some substance that either inviscates the feculous matter, and subsides with it to the bottom, or, that induces such a change in its nature or bulk, that it subsides by its own density, in each case leaving the liquor transparent Albanum, gelatin, acids, certain salts, blood, lime, plaster of Paris, alum, heat, alcohol, &-c, serve in many cases for this purpose. The first is used under the form of white of egg, for the clarification of sirups, as it combines with the liquid when cold, but on the application of heat, rapidly coagulates and rises to the surface, carrying the impurities with it, forming a scum which is easily removed with a skimmer. It is also much used for fining wines and liqueurs, particularly the red wines and more limpid cordials. Gelatin, under the form of isinglass, dissolved in water, or weak vinegar, is used to fine white wines, beer, cider, and similar liquors, that contain a sufficient quantity of either spirit or astringency (tannin) to induce its precipi- tation. Sulphuric acid is frequently added to weak liquors for a similar purpose, either alone, or after the addition of white of egg, or gelatin, both of which it rapidly throws down in an insoluble form. A pernicious practice exists among some unprinci- pled parties, of using certain salts of lead and pot- ash to clear their liquors, especially those that are expected to sparkle in the glass, as cordial, gin, &c. For this purpose, a little sugar of lead, dis- solved in water, is first mixed up with the fluid, and afterwards about half its weight of sulphate of potash, also dissolved in water, is added, and the liquor is again roused up. By standing, the sul- phate of lead, formed by this mixture, subsides, and leaves the liquor clear. Blood is used in the same way as isinglass or white of eggs, for fining red wines, beer, and porter. Lime, alum, alcohol, and heat, act by curdling or coagulating the feculen- cies, and thus, by increasing their density, induce their subsidence. Plaster of Paris acts partly like the above, and partly like albumine, or gelatin, by enveloping and forcing down the suspended matter. Sand is often sifted over liquors for the simple purpose of acting by its gravity, but appears to be quite useless. The juices of plants are clari- fied by heat, which coagulates the albumine they contain. Marl, or clay, is frequently used to clear cider and perry. A strip of isinglass is generally employed to clarify coffee. (See Wines, Brew- ing, Cordial, Coffee, Infusion.) CLEANING. The best way to clean a house is to keep it dean by a daily attention to small things, and not allow it to get into such a state of dirtiness and disorder as to require great and periodical cleanings. Some mistresses, and also some ser- vants, seem to have an idea that a house should undergo " regular cleanings," or great washing and scrubbing matches once every three or six months, on which occasions the house is turned almost in- side out, and made most uncomfortable. All this is bad economy, and indicates general slovenliness of habits. (Chambers.) CLEAR-STARCHING. This is practised as follows: " Rinse the articles in three waters, dry them, and dip them in a thick starch, previously strained through muslin; squeeze them, shake them gently, and again hang them up to dry ; and when dry, dip them twice or thrice in clear water, squeeze them, spread them on a linen cloth, roll them up in it, and let them lie#an hour before iron- ing them. Some persons put sugar into the starch to prevent it sticking while ironing, and others stir the starch with a candle to effect the same end ; we object to these practices as injurious to the ar- ticle starched, or as very nauseous. The best plan to prevent sticking is to make the starch well, and to have the irons quite clean and highly polish* ' " CLOTH, CLEANING AND SCOUUIN, OF. The common method of cleaning cloth is by beating and brushing, unless when very dirty, when it undergoes the operation of scouring. This is best done on the small scale, as for articles of wearing apparel, &c., by dissolving a little curd soap in water, and, after mixing it with a little ox- gall, to touch over all the spots of grease, dirt, &c, with it, and to rub them well with a stiff brush un- til they are removed, after which the article may be well rubbed all over with a brush or sponge dipped into some warm water, to which the pre- vious mixture and a little more ox-gall has been added. When this has been properly done, it only remains to thoroughly rinse the article in clean water until the latter passes off uncolored, when it must be hung up to dry. For dark-colored cloths the common practice is to add some fuller's earth to the mixture of soap and gall. When nearly dry, the nap should be laid right, and the article carefully pressed, after which a brush, moistened with a drop or two of olive oil, should be several times passed over it, which will give it a superior finish. Cloth may also be cleaned in the dry way as follows:—First, remove the spots as above, and, when the parts have dried, strew clean damp sand over it, and beat it in with a brush, after which brush the article with a hard brush, when the sand will readily come out, and bring the dirt with it Black cloth which is very rusty, should receive a coat of reviver after drying, and be hung up until the next day, when it may be pressed and finished off as before. Scarlet cloth requires considerable caution. After being thoroughly rinsed, it should be repeatedly passed through cold spring water, to which a tablespoonful or two of solution of tin has been added? If much faded, it should be dipped in a scarlet dye-bath. Buff cloth is generally cleaned by covering it with a paste made with pipe-clay and water, which, when dry, is rubbed and brushed ofE Fruit spots and similar stains may frequently be removed by holding the part over a common brimstone match, lighted, or by water acidulated with a little salt of lemons, oxalic or muriatic acid ; but care must be taken not to apply this liquid to colors that it will injure. The stains of acids may be removed by wash- ing the part with a little spirits of hartshorn or CLO 201 COB liquid ammonia ; those of alkalis, by water acidu- lated with lemon juice or tartaric acid. Grease spots may generally be taken out by means of a little soft soap ; or, if the color be deli- cate, or a false dye, a little ox-gall or curd soap will be better. These must be used as above de- scribed Stains of painters' oils, wax, paints, or varnishei, will not usually yield to the above plan; in these cases, a simple way is to soak the part in spirits of turpentine, and, when softened, to wash it off with the same fluid. Ether or essential oil of lemons will also quickly remove these spots, but is too expensive for general use. CLOTH, INCOMBUSTIBLE. Th - s made of fibres of asbestos by weaving. It will bear a considerable heat without injury. Cotton and linen fabrics prepared with a solution of sal ammoniac, or phosphate of ammonia, may be placed in contact with ignited bodies without danger. They will carbonize, but not inflame. Solutions of alum, sea salt, &.c, have been used for the same pur- pose. It is by a knowledge of this property of culinary salt, that jugglers are enabled to perform the common trick of burning a thread of cotton while supporting a ring or a key, without the lat- ter falling to the ground. The cotton is reduced to a cinder, but, from the action of the salt, its fibres still retain sufficient tenacity to support a light weight CLOTH, RENOVATION OF. The article undergoes the process of scouring before described, and, after being well rinsed and drained, it is put on a board, and the threadbare parts rubbed with a half-worn hatter's card, filled with flocks, or with a teazle or a prickly thistle, until a nap is raised. It is next hung up to dry, the nap laid the right way with a hard brush, and finished as be- fore. When the cloth is much faded, it is usual to give it a " dip," as it is called, or to pass it through a dve-bath, to freshen up the color. « CLOTHES, BRUSHING AND PRESER- VATION OF. If very dusty, hang them on a horse or line, and beat them with a cane; then lay them on a clean board or table, and well brush them, first with a stiff brush, to remove the spots of mud and the coarsest of the dirt, and next with a softer one, to remove the dust and to lay the nap properly. If clothes be -wet and spotted with dirt, dry them before brushing, and then rub out the spots with the hands. The hard brush should be used as little as possible, and then with a light hand, as it will, if roughly and constantly employed, soon render the cloth threadbare. Should there be spots of tallow-grease on the clothes, take it off with the nail, or, if that cannot be done, have a hot iron with some thick browh paper, lay the paper on the part where the grease is, then put the iron upon the spot; if the grease comes through the paper, put on another piece, till it ceases to soil it. After the clothes are brushed, they should be hung up in a clean place, free from dust, if want- ed for immediate use ; but if intended to remain unused for some time, they should be placed away on the shelves of the clothes' closet or wardrobe. The latter should always be in the driest situation possible, as if the clothes be exposed to the least damp, they not only acquire an unpleasant smell, but gradually become rotten. CLOVES. The flower buds of the eugenia caryophyllata, dried and smoked. It is a common practice to adulterate this spice in the same man- ner as cinchona bark. Cloves from which the oil has been distilled are dried and rubbed between the hands, previously moistened with a little sweet oil, to brighten their color, after which they are mixed up with fresh spice for sale. COACH ACCIDENTS. " Should the horses run off, in defiance of all restraint, while you are in a coach, sit perfectly still, and in anticipation of the possible overturn, keep your legs and arms from straggling. Sit easily and compactly, so that, when upset, you will gently roll over in the direc- tion you are thrown. We have seen ladies in these circumstances scream wildly, and throw their arms out of the windows, thus exposing themselves to the chance of broken limbs. If run away with in a gig, either sit still collectedly*, or drop out at the back, so as to fall on your hands. Never jump from a rapidly-moving vehicle, unless (supposing it impossible to slip down behind) you see a precipice in front, in which case any risk of personal dam- age is preferable to remaining still. The Duke of Orleans lost his life by neglecting these simple pre- cautions." COAK. Syn. Coke. Charred Coal. Min- eral Charcoal. Carbonized coal. The princi- ple of its manufacture is similar to that of charcoal. There are three varieties of coak, viz. I. (Kiln-made coak. Stifled coak.) Made by burning the coal in a pile, kiln, or stove. It has a dull black color, and produces an intense heat when used as fuel. The coal is frequently burnt in a series of shallow stoves, with as little access of air as will support the combustion, and the smoke conducted through proper horizontal tun- nels to a capacious brick chamber, 100 yards or more in length, kept as cool as possible by a stream of water passing over its roof, or by a shal- low pond resting on it. Here the bituminous va- pors are condensed in the form of tar, along with a considerable quantity of crude ammoniacal salt. Common coal yields about 3§ of tar when treated in this way, but some strong bituminous coal will give J}- or | of its weight. This tar, when inspis- sated, gives 75§ of pitch, and 20 to 24§ of a crude species of naphtha, that is excellent for out-door painting. The ammonia is made into sal ammo- niac. The screenings, or dust-coal, separated from the better kinds of bituminous coal, is the sort commonly used for making coak in ovens. II. (Gas coak. Distilled coak.) The cinder left in the retorts after the gas has "been distilled off Its color is gray, and it only produces a weak heat in burning, not sufficient to smelt iron. III. (Slate coak. Carbon mineral.) From bi- tuminous slate, burned in covered iron pots, in a similar way to that adopted for making bone-black Also burnt in piles. It is black and friable. Used to clarify liquids, but vastly inferior to bone-black, and does not abstract the lime from sirups. COBALT. Syn. Regulus of Cobalt. A met- al discovered by Brandt, in 1733. It is found in ores, associated with arsenic and other rnetals, and is constantly present in meteoric iron. Prep. Dissolve oxide of cobalt in muriatic acid, and pass sulphureted hydrogen gas through the solution, until all the arsenic is thrown down ; filter, and boil with a little nitric acid, then add an ex- COB 202 COC cess of carbonate of potassa, and digest the pre- cipitate in a solution of oxalic acid to remove any oxide of iron; wash and dry the residuum, which is the pure oxalate, and expose it to heat, either in a retort or crucible, from which the air is ex- cluded, when pure metallic cobalt will be ob- tained. . II. Mix equal parts of oxide of cobalt and soft soap, and expose them to a violent heat in a cov- ered crucible. III. Roast Cornish cobalt ore, then powder it, and smelt it with twice its weight of soft soap. Remarks. Cobalt is seldom employed in the metallic state, from the great difficulty of reducing its ores, but its oxide is largely used in the arts. It has been said to form three compounrie with oxygen, but only one—the black or peroxide—is employed. It forms salts with the acids, which are interesting from the remarkable changes of color which they exhibit. The sulphate is formed by boiling sulphuric acid on the metal, or by dis- solving the oxide in the acid. It forms reddish crystals, soluble in 24 parts of water. The nitrate, made in a similar way, forms deliquescent crystals. The muriate may be made by dissolving the oxide 41 muriatic acid; the neutral solution is blue when rjoncentrated, and red*»when diluted; the addition :f a little acid turns it green. Dissolved in water, t forms a sympathetic ink, the traces of which be- some blue when heated, but if the salt be contam- inated with iron, they become green. (Klaproth.) The addition of a little nitrate of copper to the above solution, forms a sympathetic ink, which by heat gives a rich greenish-yellow color. (Ure.) The addition of a very little common salt makes the traces disappear with greater rapidity, on the withdrawal of the heat. The acetate forms an ink which turns blue when heated. The oxalate and phosphate may be formed by digesting the oxide in a solution of the acid, or by double decom- position. The latter salt is. an insoluble purple powder, which, when heated along with 8 times its weight of gelatinous alumina, produces a blue pig- ment, almost equal in beauty to ultramarine. With sulphur cobalt unites, forming a sulphuret, and with phosphorus a phosphuret. Char, and Tests. The neutral salts of cobalt form red solutions, turning green on the addition of an excess of the acids, and giving a blue-colored precipitate with the alkalis, unless arsenic be pres- ent, when the color will be brown. Their solu- tions are unaffected by sulphureted hydrogen, but hydro-sulphuret of ammonia throws down a black powder, soluble in an excess of the precipitant If the solution contain arsenic, a yellow powder is first precipitated, after which the filtered fluid will remain unaffected by sulphureted hydrogen gas. Tincture of galls gives a yellowish-white precipi- tate, and the solution of oxalic acid a red one. COBALT, OXIDE OF. Syn. Black Oxide of Cobalt. Cobalt Black. Prep. Trf a solution of muriate of cobalt, add another of carbonate of potassa as long as it produces a precipitate ; filter, wash, and dry. . II. Boil powdered bright-white cobalt ore (from Cornwall) in nitric acid; dilute with a large quantity of water, and add a solution of carbonate of potassa, very gradually, until the clear liquor, after the impurities have settled, becomes of a rose color: then add the potash water as long as a pre cipitate falls ; wash and dry. Use. To make blue colors for painters, enamel- lers, and potters. In medicine it has occasionally been used as a remedy for rheumatism. COCCULUS INDICUS. The fruit of a shrub (the menispermum cocculus) which abounds on the sandy shores of Malabar, and other parts of tha East Indies. It contains about 20 of picrotoxin, a peculiar vegetable principle, possessing very poi- sonous properties. It also contains menispermine and paramenispermine. (Pelletier and Couerbe.) A small portion of this dangerous drug is used by poachers, and a still smaller quantity to destroy vermin, the remaining, and by far the greater part, being used to adulterate beer and wine. It forms a profitable article of trade to the wholesale drug- gist, who is enabled to sell it at a high price to brewers, from its being a contraband article. The use of cocculus indicus in brewing is no secret, as several writers have openly recommended its use. One of these conscientious gentlemen states, that " it is impossible with pure malt and i..ps alone, to produce a strong-bodied porter ;" he therefore re- commends the use of " cocculus indicus, grains of Paradise, and mix vomica." (Childe, on Brewing.) Another author, with the most unblushing effront- ery, actually gives full directions for its use. He orders 3 lbs. of cocculus to be used for every 10 quarters of malt, and adds, " it gives an inebriating quality, which passes for strength of liquor ; it pre- vents second fermentation in bottled beer, and consequently, the bursting of the bottles in warm climates." (Morrice's Treatise on Brewing.) It is really disgusting to find that men can so degrade themselves, as thus publicly to recommend a whole- sale system of slow poisoning. The conscientious brewer, who understands the art which he pro- fesses, finds no difficulty in producing " a strong- bodied porter" from malt and hops alone. It is only persons whose cupidity induces them to reduce the quantity of malt and hops required for the pro- duction of good liquor, that encounter any difficulty in so doing. There is a penalty of 200/. upon the brewer for purchasing or having in his possession any ingredient for the adulteration of beer, and there is a penalty of 500/. upon the seller of such ingredients. Yet, in defiance of these heavy fines, the trade in these articles is unabated, though car- ried on in a clandestine manner. The general way this is managed, is to pack the drug in com- mon soda barrels, and to place 3 or 4 inches of small crystals of Scotch soda at the bottom and top of the cask. In this way the package readily passes off as a cask of common soda, and even should it be opened, the alkali would first present itself to view, and thus satisfy the examiner. An- other way commonly adopted, is to form it into an extract, known by the name of B. E., or black ex- tract, which is ostensibly prepared for tanners, but its real destination is the beer cask. The store of a certain druggist, which came under my ex- amination some short time since, contained an im- mense number of bags of this article ; in f ict, it formed at least one fourth of the entire stock. COCIIENILLIN. Syn. Cochineal Red. Carminium. Carminia. Ti nn Carmine. The coloring principle of cochineal. The carmine of commerce consists of cochenillin, combined with a COD 203 COF little animal matter and an acid, from which it may be nearly purified by solution in liquid am- monia, and precipitations by acetic acid, mixed with alcohol. Cochenillin may also be prepared by evaporating a watery infusion of cochineal to the consistence of sirup, dissolving this in proof spirit, filtering, again evaporating, and dissolving the residuum in liquid ammonia as before. It is turned orange by acids, and violet by alkalis. It has been obtained under the form of reddish-purple crystalline grains. COCKLE POWDER. Cockles pulped through a sieve, made into a paste with flour, and a little salt, and then rolled out into thin pieces and dried. It is next reduced to powder, sifted, and packed in well-corked bottles. Use. To make sauce, (about 4 oz. to 4 pint.) COCOA. I. The roasted husks of the cacao, or chocolate bean, reduced to powder by grinding. II. The cake left after expressing the oil from the beans. COCOA, PATENT. The cacao nut roasted and ground, (including the husks.) COCOA, FLAKED. Ground cocoa strongly compressed, and flaked with a sharp knife or ma- chine. COCOA, SOLUBLE. Cocoa ground to a very fine powder, and mixed with sugar. It is thus rendered miscible with boiling water. Remarks. Cocoa forms a very wholesome bev- erage, especially for breakfast. Much of the cheap stuff sold under this name is very inferior, being made with damaged nuts that have been pressed for the oil, mixed with potato flour, mutton suet, &c. Trash of this kind is frequently ticketed in the shop windows of London at 6d. to 8d. a pound. (See Chocolate.) The nut of the palma cocos is commonly confounded with that of the theo- broma cacao. The latter is the small chocolate bean, while the former is the large nut, filled with a refreshing milky juice. COD. This excellent fish is in season from the beginning of October to the end of April. It should" be chosen by the redness of the gills, freshness of the eyes, and the whiteness and firmness of the flesh. The best fish are very thick about the neck. It is generally cooked by boiling, but is sometimes baked, or cut into slices and broiled or fried. Cod's head and shoulders, with oyster sauce, is a favorite dish. Shrimp and anchovy sauce are also good additions. The flesh of the cod is often split and dried, (dried cod,) or salted. The fish so largely imported from Newfoundland are cod, beheaded, split open, gutted and salted. They are caught by millions on the " Grand Bank." Cod-sounds are pickled in brine and also made into isinglass. The liver is boiled for its oil, and the spawn made into caviare. CODEIA. Syn. Codeine. An alkaloid dis- covered by Robiquet associated with morphia. Prep. Dissolve commercial hydro-chlorate of morphia in water, precipitate with ammonia, evap- orate and crystallize. The product is a double salt of morphia and codeine, and when digested with warm liquor of potassa gives up its morphia. It may be further purified by solution in ether, and by the addition of a little water and spontaneous evaporation may be obtained quite pure and in a erysti lline state. Prop. Soluble in alcohol, ether, and water. Its solution in the latter, by slow evaporation, yields large transparent octohedrons. With the acids it forms crystallizable salts. These possess the sin- gular property of producing a general and v»lent itching of the surface of the body when adminis- tered internally. The same symptoms frequently follow the exhibition of opium and muriate of mor- phia, and are referred to the presence of a salt of codcia. (Gregory.) The commercial muriate fre- quently contains 3 to 4§ of codeia. Char, and Tests. It is distinguished from mor- phia by not becoming blue on the addition of the sesquichloride of iron, nor turning red with nitric acid, and by not being precipitated by ammonia, when dissolved in muriatic acid and mixed with a large quantity of water. TJnlike morphia, it is in- soluble in liquor of potassa and is soluble in ether. The salts of codeia may also be known by tincture of galls throwing down a copious precipitate from their solutions, but this does not occur in the salts of morphia. It may be distinguished from meeo- nine by its aqueous solution showing an alkaline reaction with test paper. COFFEE. The berry of tffe coffasa Ara- bica. II. A decoction or infusion prepared there- from. Qual. Coffee promotes digestion and exhilarates the spirits, and when strong generally occasions watchfulness, but in some phlegmatic constitutions induces sleep. Drunk in moderation, especially if combined with sugar and milk, it is perhaps the most wholesome beverage known. The various qualities that have been ascribed to it by some per- sons, such as dispelling or causing flatulency, re- moving dizziness of the head, attenuating the blood, causing biliousness, &c, appear to be wholly imaginary. In a medical point of view it has been regarded as diuretic, sedative, and a corrector of opium. It should be given as medicine in a strong infusion, and is best cold. In spasmodic asthma it has been particularly serviceable; and it has been recommended in gangrene of the extremities arising from hard drinking. (See Caffein.) Pur. The most common adulteration of ground coffee is chicory, which is added not only to cheap- en the article, but to improve the flavor of dam- aged or inferior berries. This adulteration may be readily detected by shaking a spoonful of the sus- pected coffee with a wine-glassful of water, when, if it be pure, it will swim and scarcely color the liquid, but if chicory be present, it will sink to the bottom, and the water will be tinged of a deep red. Roasted corn is another common adultera- tion. This may be detected by the cold decoction striking a blue color with tincture of iodine. COFFEE CREAM. Prep. Add a teacupful of very clear strong coffee to 1 pint each of clarified calf's feet jelly and good cream ; sweeten with lump sugar, give it one boil up, and pour it into shapes or glasses, when nearly cool. The calf's feet jelly should be thick enough to render the whole lightly solid but not stiff. COFFEE DROPS. Prep. Make an infusion with 1 oz. of coffee, clarify it, and moisten 1 lb. of sugar therewith, in the way directed for confec- tionary drops. COFFEE, ESSENCE OF. A concentrated infusion of coffee prepared by percolation, to whicn COF 204 COF is added about 5g of perfectly tasteless rectified spirit of wine. COFFEE FOR ICING. Syn. Shorbet au Cafe. Cream for icing 1 quart; strong infusion of coffee a small teacupful; sugar 2 oz.; yelks of 4 eggs. Mix, and ice as wanted. COFFEE FOR THE TABLE. To produce the beverage called coffee, in perfection, it is ne- cessary to employ the best materials in its manu- facture. The finest kind of coffee is that called mocha, and should be used when a very fine flavor is desired; but for common use, the better sorts of British plantation coffee may be employed. The berries should be carefully roasted by a gradual application of the heat, until the aroma be well developed, and the toughness destroyed. If too much heat be used, the volatile and aromatic p'rop- erties of the coffee will be injured and the flavor inferior ; while, on the other hand, if the berries be too little roasted, they will produce a beverage with a raw, green taste, very liable to induce sick- ness and vomiting. Properly roasted coffee should have a lively chocolate brown color, and should not have lost more than 18§ of its weight by the process. If the loss exeeds 20§ the flavor will be materially injured. As soon as roasted, the cof- fee should be pla*ced in a very dry situation, the drier the better, and the sooner it is consumed the finer will be the flavor, as it powerfully absorbs a certain amount of moisture from the atmosphere by reason of its hygrometric power. This arises from the presence of a newly-discovered principle called assamar. (Reichenbach.) The berries should not be ground until a few minutes before being made into liquid coffee, for the same reason, and should more be reduced to powder at once than is wanted for immediate use, the surplus portion should be kept in a tin canister or glass bottle. The shape or description of the coffee-pot ap- pears of little consequence, though one furnished with a percolator or strainer, that will permit a moderately rapid filtration, is perhaps preferable. At least 1 oz. of coffee should be used to make 4 common sized coffee-cupfuls, and if wanted strong, this quantity should be doubled. The prevailing fault of the coffee made in England, arises from using too little of the powdered berry. The cof- fee-pot should be heated previously to putting in the coffee, which may be done by means of a little boiling water. The common practice of boiling coffee is quite unnecessary, for all its flavor and aroma is readily extracted by boiling hot water. Should it, however, be placed upon the fire, it should be only just simmered for a minute, as long or violent boiling injures it considerably. Hot water is capable of removing all the soluble aro- matic portion of coffee, even at a temperature so low as 195° Fahr. I have often proved this by actual experiment with one of Beart's pneumatic filters, when a fluid, deliriously aromatic and spark- ling, has been produced, and the grounds have only yielded a nauseous bitter flavor and faint co- lor to fresh water, even when boiling hot. When coffee is prepared in a common pot, the latter being first made hot, the boiling water should be poured over the powder, and not, as is com- monly the plan, put in first. It should then be kept stirred for 4 or 5 minutes, when a cup should be poured out and returned again, and this opera- tion repeated 3 or 4 times, after which, if allowed to repose for a few minutes, it will usually be fine. Coffee is sometimes clarified, which is done by adding a shred of isinglass, a small piece of clean eel or sole-skin, or a spoonful of white of egg. An excellent plan, common in France, is to place the vessel containing the made coffee upon the hearth, and to sprinkle over its surface a cupful of cold water, which from its greater gravity descends, and carries the foulness with it. Another plan sometimes adopted is to wrap a cloth, previously dipped in cold water, round the coffee-pot. This method is commonly practised by the Arabians in the neighborhood of Yemen and Moka, and is said to rapidly clarify the liquor. The Parisians, who are remarkable for the su- perior quality of their coffee, generally allow an ounce to each large coffee-cupful of water, and they use the cqffee both newly ground and roast- ed. A shred of saffron, or a little vanilla, is fre- quently added. The coffee-pot called a grecque, the cafe tier e a la belloy, or coffee-biggin, is com- monly employed. This consists of a "arge coffee- pot, with an upper receptacle made to fit close into it, the bottom of which is perforated with small holes, and contains in its interior two moveable metal strainers, over the second of which the pow- der is placed, and immediately under the third; upon this upper strainer boiling water is noured un- til it bubbles up through the strainer ; tmr cover of the machine is then shut close down, and it is placed near the fire; so soon as the water has drained through the coffee the operation is repeat- ed, until the whole intended quantity be passed through. Thus the fragrance and flavor will be retained, with all the balsamic and stimulating powers, and in a few moments will be obtained— without the aid of hartshorn-shavings, isinglass, or whites of eggs—a perfectly transparent infusion of coffee. When the Parisian uses a common coffee- pot, he generally divides the water into 2 parts. The first portion he pours on boiling hot, and al- lows it to infuse for 4 or 5 minutes, he then pours this off as clear as possible, and boils the grounds for 2 or 3 minutes with the remaining half of the water. After the latter has deposited the sediment it is decanted, and mixed with the infusion. The object of this process is to obtain the whole of the strength, as well as the flavor. The infusion is conceived to contain the latter, and the decoction the former. This plan has been recommended, with some modifications, by Mr. Donovan, and more recently by Dr. Davidson, in L'Experience. COFFEE, MILK. Boil a dessert-spoonful of ground coffee in about a pint of milk, a quarter of an hour; then put into it a shaving or two of isinglass, and clear it; let it boil a few minutes, and set it on the side of the fire to fine. This is a very fine breakfast, and should be sweetened wi'h real'Lisbon sugar. " Those of a spare habit, and disposed towards affections of the lungs, would do well to make this their breakfast." COFFEE, SEARLE'S PATENT. This is prepared by evaporating skimmed milk mixed with one-fortieth part of sugar, at a low temperature, and, when nearly solid, adding a very concentrated essence of coffee, and continuing the evaporation COI 205 COL at a very low temperature, (in vacuo if possible,) until the mixture acquires the consistence of a sirup, paste, or candy. (The latter may be pow- dered.) COFFEE, SUBSTITUTES FOR. These are numerous, but the principal are the following: I. (Rye coffee. Dillenius's ditto. Hunt's break- fast-powder.) Rye, roasted along with a little butter, and ground to powder. A good substitute. II. (German coffee. Succory ditto. Chicory ditto.) From succory, as above. Used either for or mixed with foreign coffee. The most common adulteration of the latter. III. (Rice coffee.) From rice, as above. A good substitute. IV. (Currant coffee.) From the seeds washed out of the cake left m making currant wine. V. (Gooseberry coffee.) From gooseberry seeds, as the last. VI. (Holly coffee.) From the berries. VII. (Egyptian coffee.) From chickpeas. VIII. (Rosetta coffee.) From fenugreek seeds moistened with lemon juice. IX. (Corsican coffee.) From the seeds of the knee-holly. X. (Sassafras coffee.) From the fruit or nut of the sassafras tree, or from the wood cut into chips. Very wholesome. Much recommended in skin diseases, &c. XL (Raspings.) The raspings of the crust of loaves, procured at the baker's. Equal to rye coffee. XII. (Beech-mast coffee.) From beech-mast or nuts. Very wholesome. XIII. (Acorn coffee.) From acorns, deprived of their shells, husked, dried, and roasted. A good substitute. XIV. (Beet-root coffee.) From the yellow beet- root, sliced, dried in a kiln or oven, and ground with a little foreign coffee. A good substitute. XV. (Bean coffee.) Horse-beans roasted along with a little honey or sugar. When removed from the fire, a small quantity of cassia-buds is fre- quently added, and the whole is stirred until cold. Said to be a good substitute. XVI. (Almond coffee.) Rye or wheat roasted along with a few almonds. A very small quan- tity of cassia-buds improves it. A good substitute. COINS, IMPRESSIONS FROM. A very easy and elegant way of taking the impressions of medals and coins, not generally known, is as fol- lows : Melt a little isinglass glue with brandy, and pour it thinly over the medal, so as to cover its whole surface ; let it remain on for a day or two, till it has thoroughly dried and hardened, and then take it off, when it will be fine, clear, and as hard as a piece of Muscovy glass, and will have a very- elegant impression of the coin. It will also resist the effects of damp air, which occasions all other kinds of glue to soften and bend if not prepared in this way. (Shaw.) If the wrong side of the isin- glass be breathed on, and gold-leaf applied, it will adhere, and be seen on the other side, producing a very pleasing effect. Isinglass glue, made with Water alone, will do nearly as well as if brandy be used. Remarks. Medals may also be copied by sur- rounding them v. ith a hoop of paper, and pouring on them plaster of Paris (mixed with water to the consistence of cream) to the depth of about 4 an inch. Melted wax, stearine, fusible metal, or any similar material, may be used in the same way. If it be desired to copy the metal in copper, a mould should be first formed in the above manner, and the metal deposited on its surface by the agen- cy of electricity. (See Electrotype.) COLCHICINE. Syn. Colchicina. Colchia. A peculiar principle discovered by Gieger and Hesse in the seeds of the colchicum autumnale, or com- mon meadow saffron. It also exists in the cormi or bulbs. Prep. Macerate the crushed seeds in boiling al- cohol, add hydrate of magnesia to throw down the alkaloid, digest the precipitate in boiling alcohol, and filter. By cautious evaporation colchicine will be deposited. It may be purified by re-solu- tion. Prop., ifC. Odorless; tastes bitter ; forms salts with the acids. It 5 very poisonous. One-tenth of a grain, dissolved in spirit, killed a cat in 12 hours. It differs from veratrine in being soluble in water, crystalline, and the non-production of sneez- ing when applied to the nose. Strong oil of vitriol turns this alkaloid of a yellowish browr * nitric acid of a deep violet, passing into indigo blue, green, and yellow. COLCHICUM, POWDER OF. I. (Collier.) Seeds of colchicum 2 grs.; rhubarb 6 grs.; mag- nesia 10 grs.; mix for 1 powder, to be taken every six hours in acute rheumatism, inflammatory gout, &c, washing it down with a glass of Seltzer wa- ter, during high febrile action only. II. (Collier.) Seeds of colchicum 3 grs.; mu- riate of ammonia 5 grs.; for 1 powder. For check- ing a paroxysm of gout, but its use requires cau- tion. " After all that has been said respecting colchicum in gout, and admitting that it rarely fails to allay pain and check a paroxysm, I would record my opinion that he who would wish to ar- rive at a good old age, should eschew it as an or- dinary remedy, and consider that he is drawing on his constitution for a temporary relief, with a cer- tainty of becoming prematurely bankrupt in his vital energies." COINDET'S PILLS. Prep. Protiodide of mercury 1 gr.; extract of liquorice 20 grs.; mix, and divide into 8 pills. Dose. 2 to 4 twice or thrice daily, as an alterative in scrofulous tumors, ulcers, &c. COLD. When the body of an animal is im- mersed in an atmosphere at a temperature below tho healthy standard, a sensation of coldness is experienced, produced by the passage of the calo- ric or heat of the body into the colder medium. If this withdrawal of caloric exceed the quantity pro- duced by the vital system, the temperature of the body decreases, until it sinks below the point at which the functions of life can be performed. This declination is gradual; the extreme sensation of coldness changes into a disinclination for voluntary motion ; next comes on drowsiness, followed by numbness and insensibility. In this state, if the sufferer be not rescued, and remedial measures had recourse to, death must rapidly follow. Prevention of the effects of excessive cold.— The extremities of the body first suffer from the action of cold, owing to the circulation of the blood being less vigorous in those parts; they should, COL 206 COL therefore, be properly protected from its action. Woollen stockings or socks, with good shoes or boots, should be worn on the feet, and the body should be clad in thick woollen fabrics, proportion- ed to the inclemency of the weather, and the habits of the wearer. The circulation of the blood should be promoted by active exercise, and any disposition to sleep shaken off by increased bodily exertion. If the situation be such that exercise cannot be had recourse to, drowsiness is more likely to be experienced, and must be warded off, if possible, by keeping the mind incessantly and actively en- gaged. The principal endeavor should be to keep the extremities warm, as, if this be accomplished, no danger need be feared. In travelling by coach or on horseback, recourse may be had to hay and straw, which may be thrown over the feet and legs, and will materially ward off the effects of the weather. Remedial measures for asphyxia produced by intense cold.—The patient should be laid in a room remote from the fire, and bathed with cold salt and water, after which the body should be wiped dry, and friction applied by the hands of the attendants, (warmed ;) as many operating at once as can con- veniently do so. Gentle stimulants should be ad- ministered by the mouth, and the bowels excited by some mild stimulating clyster. The lungs should also be inflated. (See Asphyxia.) As soon as symptoms of returning animation are evinced, and the breathing and circulation restored, the patient should be laid in a bed between blankets, and a little wine and water administered, and perspiration promoted by heaping an ample quantity of clothing on the bed. Should the patient have suffered from hunger as well as cold, the appetite may be ap- peased by the administration of a limfted quantity of light food, taking especial care to avoid excess, or any thing indigestible or exciting. • COLIC. (From koiAov, the colon, the supposed seat of the disease.) The colic or bellyache. This name is commonly given to all severe griping ab- dominal pains, whatever may be the cause. This disease has been distinguished by nosologists into several varieties, as follows:— I. (The spasmodic colic.) This kind is marked by a fluctuating pain about the navel, which goes away and returns by starts, often leaving the pa- tient for some time. The belly is usually soft, and the intestines may often be felt in lumps, which move about under the hand, or wholly vanish for a time. It is unaccompanied by flatulency. The remedies are, warm fomentations, warm clysters, and carminatives, accompanied by small doses of camphor and opium. II. (The stercoraceous colic.) This is marked by severe griping pains and constipation of the bowels. The remedies are powerful cathartics, as full doses of calomel, aloes, colocynth, jalap, &c., followed by purgative salts, as sulphate of magne- sia or soda. III. (Bilious colic.) In this variety the pain is intermittent and transient, accompanied by con- stipation, nausea, and vomiting. The fasces, if any, are bilious, dark-colored, and offensive. The remedies are, a full dose of blue pill, calomel, colo- cynth, or aloes, followed by a sufficient quantity of epsom or glauber salts. Warm fomentations are also serviceable. IV. (Flatulent colic.) Marked by constipation, and the irregular distension of the bowels by gas, accompanied by a rumbling noise, &.c. It is com- monly produced by the use of flatulent vegetables and slops. The remedies are, a full dose of tine- ture of rhubarb combined with a few drops of es- sence of peppermint. If this does not afford relief, a pill made of 3 grs. of blue pill and 2 grs. of com- pound extract of colocynth, may be taken, washed down with a glass of any cordial water, as pepper- mint, cinnamon, or caraway. If the pain be ex- treme, warm fomentations to the belly, or a car- minative clyster may be adopted. V. (Accidental colic.) Produced by improper food and poisons. The treatment differs but little from the last variety. VI. (Colica pictonum. Devonshire colic. Plumber's do. Painter's do. Lead do.) The dry bellyache. This species of colic is marked by obstinate costiveness, acrid biliou" vomitings, vio- lent pains about the region of the ns rel, convulsive spasms in the intestines, and a tendency to para- lysis in the extremities. It is most prevalent in the cider counties, and among persons exposed to the fumes of lead. The n medies are the same as for the spasmodic variety. Should these fail, aftei the bowels have been thoroughly evacuated, small doses of camphor and opium may be administered. Mr. Benson, the managing director of the British Whitelead Works at Birmingham, strongly recom- mends the use of sulphuric acid ; he says : " I met with a statement some time since that sulphuric lemonade has been successfully used at a white lead manufactory in France as a preventive of the injurious effects of white lead ; and it occurred to me that by adding sulphuric acid to the treacle- beer then used by our people, its supposed efficacy might be tested. This idea was carried into effect in the summer of 1841, and the results have proved most gratifying, as, although during several weeks after the addition of the sulphuric acid to the trea- cle beverage, little advantage seemed to be derived, yet the cases of lead colic became gradually less frequent, and since October of that year, or during a period of fifteen months, not a single case of lead colic has occurred among the people." (Lancet.) The following is Mr. Benson's form for his trea- cle or sulphuric beer:—Take of treacle 15 lbs.; bruised ginger 4 lb.; water 12 gallons; yeast 1 quart; bicarbonate of soda 14 oz.; sulphuric acid (oil of vitriol) 14 oz. by weight: boil the ginger in 2 gallons of water; add the treacle and the re- mainder of the water, hot; when nearly cold trans- fer it to a cask, and add the yeast to cause fer- mentation ; when this has nearly ceased, add the sulphuric acid, previously diluted with eight times its quantity of water, and then add the bicarbonate of soda, dissolved in one quart of water. Close up the cask, and in three or four days the beer will be fit for use. As acetous fermentation speedily takes place, particularly in hot weather, new supplies Bhould be prepared as required. COLOCYNTHINE. Syn. Colocynthite. Colocynthium. The purgative bitter principle of the colocynth. Prep. Digest the aqueous extract or the pulp of colocynth in alcohol, filter and evaporate the tinc- ture. The residuum is colocynthine combined with acetate of potassa. By agitation with a little CON 207 CON water the latter is removed. It may be purified by e-solution in alcohol, and eVaporation. Prop. It yellowish brown translucent resinous Bubstance, very soluble in alcohol, less so in ether, and only slightly so in water. It is intensely bit- ter, and acts as a drastic purgative. COLORING. Syn. Brewer's Coloring, Brandy do. Spirit do. Essentia Bina. Cara- mel. Prep. Melt brown sugar in an iron vessel over the fire, until it grows black and bitter, stir- ring it well all the time, then make it into a sirup with water. Remarks. Some use lime-water to dissolve the burnt sugar. Care must be taken not to overburn it, as a greater quantity is thereby rendered inso- luble. The heat should not exceed 430°, nor be less than 400°. The process for nice experiments is best conducted in a bath of melted tin, to which a little bismuth has been added to reduce its melt- ing point to about 435° ; a little powdered resin or charcoal, or a little oil being put upon the surface of the metal to prevent oxidizement COLORS, COMPOUND. (In Dyeing.) The mixture of blue and yellow dyes produces greeny red and blue, violet, purple, lilacs, ifC.; red and yellow, orange, cinnamon, fyc.; red, yellow, and blue, olives; red and blues, or green or black, browns of all shades; black mixed with other dyes produces various shades of brown and olive, and when pale it constitutes gray, either by itself or the addition of a faint blue. COLOMBIUM. A rare metal, discovered by Mr. Hatchet in 1801, in a black mineral belonging to the British Museum. Supposed to have been brought from America, hence the name. (See Tantalum.) COLUMBIC ACID. The preceding metal ex- ists in its ores in the form of an acid, united to iron, manganese, or yttria. From these it may be ob- tained by fusion with 3 or 4 parts of potash, solu- tion in water, and precipitation with an acid. It falls as a white powder or hydrate. CONCENTRATION. (In Chemistry.) The volatilization of part of a liquid in order to increase the strength of the remainder. The operation can only be performed on solutions of substances of greater fixity than the menstrua in which they are dissolved. Many of the liquid acids, solutions of the alkalis, &c, are concentrated by distilling off their water. (In Pharmacy.) The term " concentrated" is very commonly applied to any liquid preparation possessing more than the usual strength. Thus we have " concentrated" infusions, decoctions, liquors, solutions, tinctures, and essences, most of which are made of 8 times the common strength. This is generally effected by using 8 times the usual quantity of the ingredients, with a given por- tion of the menstruum, and operating by digestion or percolation; the latter being generally adopted when the articles are bulky. When the men- struum is water, a little spirit is added to make the product keep. CONCRETE. (In Architecture.) A com- pact mass, composed of pebbles, lime, and sand, employed in the foundations of buildings. The best proportions are 60 parts of coarse pebbles, 25 of rough sand, and 15 of lime. CONDIMENTS. Substances taken with the food, to improve its flavor, or to render it more wholesome or digestible. The principal condi- ments are common salt, vinegar, lemon juice, spices, aromatic herbs, oil, butter, sugar, honey, and sauces. Most of these, in moderation, pro- mote the appetite and digestion, but their excessive use tends to injure the stomach, and vitiate the gastric juice. CONFECTIONS. (In Pharmacy.) Medi cines, usually pulverulent, mixed up to the consist- ence of a paste with powdered sugar, sirup, or ho- ney. In the " London Pharmacopoeia," both con- serves and electuaries are included under this head, though there appears to be some little distinction between them. As remedial agents, the officinal confections possess but little value, and are chiefly useful as vetycles for the administration'of more active medicines. In making confections, the su- gar requires the same attention as for sirups. They should be kept in stone jars, covered with writing paper, and placed in a cool and dry situation. Without this precaution, they are apt to mould on the top. All the dry ingredients employed in making confections should be reduced to a very fine powder, and passed through a sieve not coarser than 80 holes to the inch. CONFECTION OF ALMONDS. Prep. (Confectio Amygdalee, P. L.) Sweet almonds §viii; white sugar §iv; powdered gum arabic fj. Macerate the almonds in cold water, then remove the skins, and beat them with the other ingredients until reduced to a smooth confection. Use. To prepare milk of-almonds. A little of this paste or powder, triturated with a sufficient portion of water, and strained through a piece of calico, forms emulsion of almonds. CONFECTION OF ALKERMES. Prep. White sugar 1 lb.; rose-water \ pint; clarified juice of alkermes 3 lbs.; oil cinnamon 10 or 12 drops. Mix. It was formerly a common practice to add a little gold-leaf, rubbed small, 60 as to float about in it; also musk and ambergris. CONFECTION OF ALUM. Prep. (Conf. Aluminis, St. B. H.) Alum in fine powder, 80 grs.; conserve of roses, enough to mix. Use. As an astringent CONFECTION, AROMATIC. Syn. Sir Walter Raleigh's Cordial. Confectio Ra- leighana, (P. L. 1720.) Ditto Cardiaca, (P. L. 1745.) Ditto Aromatica, (P. L. 1788, and since.) Prep. I. (P. L.) Nutmegs, cinnamon, and hay saf- fron, of each §ij; cloves ^j', cardamoms §ss; pre- pared chalk ^xvj ; white sugar lbs. ij. Reduce the whole to a very fine powder, and keep it in a closed vessel. When wanted for use, mix it with water to the consistence of a confection. Remarks. On the large scale the above form is seldom adhered to. Less saffron is commonly used, cassia is substituted for cinnamon, and, generally, the essential oil for the powder of cloves. Should there be any deficiency of color, this is brought up by a little tincture or infusion of turmeric. When a very smooth and fine powder is desired, it should be passed through a gauze sieve, not coarser than 80 holes to the inch, and precipitated chalk should be employed. The saffron should be dried with as little heat as possible, and care should be taken not to waste any in powdering. The following formula, which is employed by a large whole- CON 208 • CON sale druggist in the city, produces an excellent arti2le. • II. Hay saffron, cassia, and turmeric, of each 4 oz.; cardamoms 1 oz.; starch 8 oz.; precipitated chalk 2 lbs.; white sugar 4 lbs.; oil of nutmegs 2 drachms; oil of cloves 3 drachms. Reduce the dry ingredients to fine powder, and pass it through an !-0 hole sieve, then add the oils, and after well mixing, pass it through a coarse sieve, (about 40 holes to the inch,) to ensure the whole being per- rectly mixed. The following form produces a powder possess- ing great depth and brilliancy of color. III. Hay saffron 4 oz.; turmeric 3 oz.; pow- dered starch 8 oz.; precipitated chalk 2 lbs.; white sugar 4 lbs.; oils of cloves and cassia, of each 3 drachms; oil of nutmegs 2 drachms; essence of cardamoms 1 oz. jProc. Boil the saffron and tur- meric in 1 gallon of water, placed in a bright cop- per pan, for 10 minutes, then, without straining, add the chalk, starch, and sugar; mix well, and continue stirring until the mixture becomes quite stiff, then break it up and dry it until fit for pow- dering. This must be performed in a water or steam bath. To the powder, passed through a fine sieve, as before, the oils and tincture must be added, and after being well mixed, and passed through a coarse sieve, it should be placed in a jar or bottle, and bunged up close. Remarks. In the wholesale trade this article is kept under two forms: one in powder, as ordered by the College, and commonly called, for distinc- tion sake, " pulvis confectionis aromaticce ;" the other mixed up ready for use. In preparing the latter, it is a common plan to make a strong infu- sion or decoction of the saffron, and to use it to mix up the other ingredients. Some persons follow the method described in the last formula, mixing up the powder to a proper consistence with water be- fore adding the aromatics. When the price of precipitated chalk is an objection to its use, pre- pared chalk may be used instead. This confec- tion is cordial, stimulant, and antacid. Dose. 10 to 60 sts. CONFECTION OF BLACK PEPPER. Syn. Ward's Paste. Prep. (Confectio Piperis Nigri, P. L.) Black pepper and elecampane root, of each lb. j; fennel seed lb. iij ; honey and white sugar, of each lb. ij; mix. Remarks. The common practice is to keep the dry ingredients ready mixed in a bottle, and only to add the honey as wanted. The proportions are 2 parts of the latter te 7 of the mixture. The dose is 1 to 2 drachms 2 or 3 times a-day, in piles, fis- tula, &c. It should be persevered in for 2, 3, or 4 months, (Sir B. Brodie ;) and as it is apt to accu- mulate in the bowels, its use should be accompa- nied by mild aperients. (Pereira.) CONFECTIONS OF CASSIA. Syn. Elec- tuarium Cassls, (P. L. 1788.) Prep. (Confectio Cassia, P. L.) Fresh cassia pulp lb. ss.; manna §ij; tamarind pulp Jj; sirup of roses fjviij. Bruj* e the manna and dissolve it in the sirup, then add the pulps and evaporate to a proper consistence. CONFECTION OF HExMLOCK. (Dr. Os- borne.) Prep. Fresh leaves of hemlock and moist sugar equal parts; beat them to a confection in a mortar. CONFECTION OF OPIUM. Syn. Philo- nium Romanum, (P. L. 1720.) Ditto Londi- nense, (P. L. 1745.) * Confectio Opiata, (P. L. 1788.) Ditto Oph, (P. L. 1809, and since.) Prep. (P. L.) Powdered opium 3vj ; long pepper $j; ginger 309, and since.) Prep. (P. L.) Pulp of the dog rose lb. j ; powdered refined sugar fxx ; mix by a gen- tle heat in an earthen vessel. II. Pulped hips 2 cwt.; fine white sugar 2£ cwt.; incorporate them without applying heat. Remarks. Both this and the following confec- tion has a brighter color, if made without heat, or touching metallic vessels. On the small scale it is made by beating the ingredients together in a marble mortar, but in large quantities by grinding in a mill. It is slightly laxative, and is principally used for forming pills. It candies by keeping. CONFECTION OF THE RED ROSE. Syn. Conserva Rosarum Rubrarum, (P. L. 1745.) Ditto Ros.e, (P. L. 1788.) Ditto Ros.e Galli- cs, (P. L. 1809 and 1824.) Confectio Ros.e Gallics, (P. L. 1836.) Prep. (P. L.) Petals of the red rose lb. j; refined sugar lb. iij; beat the petals in a stone mortar, then add the sugar, and again beat until thoroughly incorporated. Remarks. On the large scale this is prepared like the confection of hips. It is astringent and tonic, and principally used for forming pills. If '.iken alone, the dose is 1 to 2 drachms. CONFECTION OF RUE. Syn. Electua- *..um e Boccis Lauri, (P. L. 1720, 1745.) Con- fectio Rut.*, (P. L. 1809, and since.) Prep. (P. L.) Dried rue, caraway, and laurel berries, of each %'iss; sagapenum (true) §ss ; black pepper 3ij; honey §XVJ- Reduce the dry ingredients to very fine powder, and when wanted for use, make them into a confection with the honey. Use, $c. It is antispasmodic; in enemas 30 to CON 209 CON 60 grs., with half a pint of gruel, for flatulent fcolic, &c. CONFECTION OF SCAMMONY. Syn. Elect uarium Caryocostinum, (P. L. 1720.) Ditto e Scammonio, (P. L. 1745.) Ditto Scam- moxii, (P. L. 1809 and 1788.) Confectio Scam- mone*:, (P. L. 1809 and 1824.) Prep. (Confectio Scammonii P. L.) Scammony ^iss; cloves and ginger, of each, 3vj; oil of caraway f3ss. Re- duce the ingredients to a very fine powder, and when wanted for use, make them into a confec- tion with sirup of roses, and lastly add the oil. Use, <$rr. Cathartic in doses of 10 to 30 grs. CONFECTION OF SENNA. Syn. Leni- tive Electuary. Electuarium Senn^e, (P. L. 1788.) Confectio Senna, (P. L. 1809, and since.) Prep. (P. L.) Senna ^viij; figs lb. j ; pulp of tamarinds, prunes, and cassia, of each, lb. ss.; coriander seeds ^iv; liquorice ^i'j ; sugar lb. iiss; ivater 3 pints. Proc. Rub the senna and corian- ders in a mortar, and separate by sifting ^x of the, mixed powders. Boil the figs and liquorice in the water, until reduced to one half; then press and strain the liquor. Evaporate the strained liquor until only 24 fluid ounces remain, then add the sugar, and when dissolved, mix in the pulps, and lastly the powder. Use, Dose, tyc. Confection of senna is a gentle and pleasant purgative, and well adapted for per- sons suffering from piles, and as a laxative during pregnancy. The dose is \ to £ oz. taken at bed- time or early in the morning. Remarks. Perhaps there is no one pharmaco- poeial preparation which it is more difficult to ob- tain of good quality than the above. The absolute cost of an article prepared according to the direc- tions of the College, will be somewhere about Is. 9d. per lb. ; but there are many wholesale drug houses vending confection of senna, which they warrant as genuine, at from 9d. to Is. a pound. Dr. Paris (in his Pharmacologia) very truly remarks, that " the directions of the Phar- macopasia are very rarely followed." I under- stand that considerable quantities are manufac- tured, into which unsound and spoiled apples enter as a principal ingredient. The following forms are, to my knowledge, employed by some mem- bers of the trade. II. Powdered senna, pulp of tamarinds, cassia, and prunes, of each, 14 lb.; powdered corianders J lb.; Spanish juice £ lb.; simple sirup 12 lbs. III. As the above, omitting the cassia pulp, and adding 2 lbs. more tamarind pulp. Both these articles are labelled P. L., and sent out as genuine, and that when no competition as to price exists. The cheaper article is made as follows: • IV. Common prunes and tamarinds, of each, 16 lbs.; treacle | cwt.; species (a compound of senna dust and small senna, mixed with 3 lbs. of 27 coriander seeds, and strengthened with jalap, at ground to a fine powder) 18-Hbs. To this is fre- quently added \ cwt. of rotten or inferior apples, which are pulped with the prunes and tamarinds. This article is not unfrequently labelled " Conf. Senn.b Ver." by the conscientious tradesman. CONFECTION OF SULPHUR, (COM- POUND.) Prep. (St. B. H.) Precipitated sul- phur 5s8 j cream of tartar 3j; honey |j; mix As a laxative in piles, &c. Dose. §ss. CONFECTION OF STEEL. Syn. Con- fection of Carbonate of Iron. Prep. Confec- tion of orange-peel and sesquioxide of iron, (P. L.,) of each, 4 oz.; powdered white sugar 6 oz.; sim- ple sirup 2 oz.; mix. Aromatic and tonic. Dose A teaspoonful to 4 oz. twice or thrice daily. CONGELATION, (from congelo, to freeze.) In Chemistry. The conversion of a liquid into a solid state, by the action of cold. The production of an extreme degree of cold is often of the utmost importance in chemical opera- tions, and an easy method of doing so is con- sequently a desideratum. The means hitherto adopted for this purpose have either depended upon the sudden liquefaction of solids, or the ab- straction of heat by rapid evaporation. The loss of sensible heat, by the first method, is the basis of the various processes of producing cold by what are commonly called freezing mixtures, all of which act upon the principle of liquefying solid substances without supplying heat. The caloric of liquidity being in these cases derived from that previously existing in the solid itself ill a sensible state, the temperature must necessarily fall. The degree of cold produced, depends upon the quan- tity of heat which is thus diffused through a larger mass, or which, as it were, disappears, and this is dependent on the quantity of solid matter lique- fied, and the rapidity of the liquefaction. Saline compounds are the substances most frequently em- ployed, and those which have the greatest affinity for water,\and thus liquefy the most rapidly, pro- duce the greatest degree of cold. Thus it is, that chloride of calcium and nitrate of ammonia, when dry and in fine powder, if suddenly mixed with water, produce extreme cold. The latter, sud- denly mixed with an equal weight of water at 50°, will sink the thermometer to +4°, or 28° below the freezing point. The most common and convenient freezing mixture, when snow can be procured, is formed by mixing 2 parts of that sub- stance with 1 part of sea-salt This will sink the thermometer to —5°, or 37° below the freezing "point of water. Equal parts of these substances produce a degree of cold marked by the zero of Fahrenheit's thermometer, and is the standard ta- ken for graduating that instrument. Mr. Walker, a gentleman who fully investigated this subject, recommends the following proportions for the pro- duction of extreme cold. CON 210 CON TABLES exhibiting a collective View of all the Frigorific Mixtures contained in Mr. Walkih'i Publication, 1808. Table I. Consisting of Frigorific Mixtures, composed of Ice, with Chemical Salts and Acids- Mixtures i Snow or pounded ice . 1 Muriate of soda Snow or pounded ice . Muriate of soda Muriate of ammonia . Snow or pounded ice Muriate of soda . Muriate of ammonia Nitrate of potash. Snow or pounded ice Muriate of soda . Nitrate of ammonia Snow ..... Diluted sulphuric acidt . Snow ..... Muriatic acid (concentrated) Snow ..... Concentrated nitrous acid Snow..... Muriate of lime Snow ..... Crystallized muriate of lime Snow..... Potash .... 2 parts 1 " 5 " 2 " 1 " 24 " 10 " 5 " 5 " 12 " 5 " 5 " 3 " 2 " 8 " 5 " 7 « 4 « 4 " 5 « 2 " 3 « 3 « 4 " Thermometer sinks. Degree of cold produced. rto—5° » at to —12° » P. s r to —18° • e o i-i fe to —25° • From +32° to —23° 55° From +32° to —27° 59 From +32° to —30° 62 From +32° to -^0° 72 From +32° to —50° 82 From +32c ' to —51° 83 N. B. The reason for the omissions in the last column of this table is, the thermometer sinking in these mixtures to the degree mentioned in the preceding column, and never lower, whatever may be the temperature of the materials at mixing. Table II. Consisting of Frigorific Mixtures, having the power of generating or creating Cold, with- out the aid of Ice, sufficient for all useful and philosophical purposes, in any part m the world at any season. Mixtures. C Muriate of ammonia 2 Nitrate of potash ( Water . Muriate of ammonia \ Nitrate of potash . i Sulphate of soda 1 Water. ( Nitrate of ammonia ( Water. C Nitrate of ammonia. 1 Carbonate of soda I Water . { Sulphate of soda . I Diluted nitrous acidt Sulphate of soda . \ Muriate of ammonia J Nitrate of potash. Diluted nitrous acid. Thermometer sinks. 5 parts 5 16 5 5 8 16 From +50° to 4-10° From +50° to +4° I From +50° to 4-4° > From +50° to —7° I From +50° to —3° \ i From +50° to —10° Degree of cold produced. 40° 46 46 57 53 60 t Strong acid 2 parts; water or snow 1 part, by weight. I Fuming nitrous acid 2 parts; watei 1 part, by weight. CON 211 CON Table II. continued. Mixtures. C Sulphate of soda . < Nitrate of ammonia. ( Diluted nitrous acid ( Phosphate of soda . I Diluted nitrous acid t Phosphate of soda . 1 Nitrate of ammonia ( Diluted nitrous acid. \ Sulphate of soda . \ Muriatic acid . ^ Sulphate of soda . ( Diluted sulphuric acid* Thermometer sinks. 6 parts 5 4 9 4 9 6 4 8 5 5 4 From +50° to —14° I From 4-50° to —12° From +50° to —21° j From +50° to 0° I From +50° to +3° Degree of cold produced. 64° 62 71 50 47 N. B. If the materials are mixed at a warmer temperature than that expressed in the Table, the effect will be proportionately greater; thus, if the most powerful of these mixtures be made when the air is +85°, it will sink the thermometer to +2°. Table III. Consisting of Frigorific Mixtures selected from the foregoing Tables, and combined so as to increase or extend Cold to the extremest Degrees. Mixtures. Thermometer sinks. Degree of cold produced. i Phosphate of soda < Nitrate of ammonia. ( Diluted nitrous acid . 5 3 . 4 sarts j " 5 From 0° to —34° 34° C Phosphate of soda . 2 Nitrate of ammonia ( Diluted mixed acids. 3 . 2 4 (C From —34° to —50° 16 \ Diluted nitrous acid. . 3 2 " i From 0° to —46° 46 < Diluted sulphuric acid ( Diluted nitrous acid . 8 3 . 3 EC ' il \ From —10° to —56° 46 ( Snow .... 1 Diluted sulphuric acid . 1 . 1 " ) " i From —20° to —60° 40 ( Snow .... 1 Muriate of lime . 3 . 4 " / " ( From +20° to —48° 68 ( Snow .... \ Muriate of lime . 3 4 « i From +10° to —54° 64 J Snow \ Muriate of lime . 2 . 3 From —15° to —68° 53 S Snow .... \ Crystallized muriate of lime. < Snow .... ( Crystallized muriate of lime. 1 . 2 1 . 3 " i " ) " t From 0° to —66° From —40° to —73° 66 33 < Snow .... ( Diluted sulphuric acid . 8 . 10 From —68° to —91° 23 Remarks. The above artificial processes for the production of cold are more effective when the ingredients are first cooled by immersion in other freezing mixtures. In this way Mr. Walker suc- ceeded in producing a cold equal to 100° below the zero of Fahrenheit, or 132° below the freezing point of water. The materials in the first column are to be cooled, previously to mixing, to the temperature required, by mixtures taken from either of the preceding tables. * Equal weights of strong acid and water. CON 212 CON II. (By evaporation.) When heat passes from the sensible to the insensible state, as in the for- mation of vapor, cold is generated. This may be illustrated by pouring a few drops of ether, or highly rectified alcohol, on the palm of the hand, when a strong sensation of cold will be produced. In like manner, if the bulb of a thermometer be covered with lint, and the latter moistened with ether, the quicksilver will rapidly fall. Even in hot climates water is frozen by the joint operation of evaporation and radiation. The natives of In- dia procure ice when the temperature of the air much exceeds the freezing point. On the open plains, near Calcutta, this is effected by exposing a thin stratum of water to the atmosphere, during the fine clear nights of December, January, and February. The pans are made of porous earthen- ware, and water is poured in to the depth of about 1£ inches. A large number of vessels of this kind are arranged in an excavation in the ground, 30 or 40 feet square and 2 feet deep, the bottom of which is covered, to the depth of 10 or 12 inches, with sugar canes or the stalks of Indian corn. At sunrise the pans are visited, the ice separated from the water, and packed as tight as possible in a deep cavity or pit, well screened from the heat. It has been found that evaporation proceeds much more rapidly from the surface of fluids in a vacuum than in the atmosphere. Dr. Cullen was the first person to apply this practically. In 1755 he plunged a vial of ether into a tumbler of water, and on placing it under a receiver and exhausting the air, the ether boiled and the water was speedily frozen. In 1777, Mr. Nairne published his method of rendering the rarefied atmosphere of an exhaust- ed receiver free from aqueous vapor by means of sulphuric acid. By the application of this discov- ery, Professor Leslie in 1810 succeeded in freezing water with great ease. This he effected by intro- ducing a surface of sulphuric acid under the re- ceiver of an air-pump, over which he placed a watch-glass filled with water, so that the vapor arising from the latter was rapidly absorbed by the former. After a few strokes of the piston the wa- ter was converted into a solid cake of ice, which on being left in the rarefied medium continued to evaporate, and in about an hour totally disappear- ed. Professor Leslie found that when the air was rarefied 250 times, the surface of evaporation was cooled down 120° in winter, and when only 50 times, a depression of 80° or even 100° took place. A pleasing philosophical toy, illustrative of the evaporative power of a vacuum, is the Cryophorus, or frost-bearer of Dr. Wollaston. This instrument consists of two small glass globes united by a tube, one of which is partly filled with water, but the apparatus is perfectly free from air. The part of the apparatus unoccupied by the water, though apparently empty, is in reality filled with aqueous vapor, and thus checks evaporation by its pressure on the surface of the water. No sooner is the pressure removed, as by plunging the empty ball into a freezing mixture, (which con- denses the vapor,) than rapid evaporation com- mences, and the water in the other ball is frozen in two or three minutes. To succeed well in the production of cold in this way, it is necessary that the surfaces of the two fluids should be pretty near together, and that the acid should have the greater amount of surface of the two. The acid should be poured to the depth of £ an inch into a broad shallow dish or capsule, and the water into another vessel of a similar kind, but having only half the diameter of the former, and proportionally shallow. The smaller capsule may be supported ovei the surface of the larger one by means of 3 slender feet. As soon as the acid has acquired one-tenth of its weight of water, its absorbent power is diminished -p1^ ; when this di- lution reaches \ the reduction is ^, and when it reaches £ the cooling power has diminished about 50$. " Sulphuric acid is capable of congealing more than 20 times its weight of water before it has imbibed nearly its own bulk of that liquid, or has lost about J of its refrigerating power." (Ure.) Sulphuric acid, which has become diluted in this way, may be reconcentrated by heat. It has been discovered that oatmeal, dried near- ly to brownness before a common fire, and cooled in close vessels, may be substituted for sulphuric acid. With a quantity of this substance, one foot diameter, and 1 inch deep, Professor Leslie froze 1 imperial pint of water, contained in a hemispheri- cal porous cup. Ignited chloride of calcium, in porous pieces, has also been successfully used for the same purpose. Dr. Ure has found that a re- quisite vacuum may be produced by the agency of steam, in the following manner, without the use of an air-pump: " A cast-iron drum of considera- ble dimensions being filled with steam by heating a small quantity of water in it, will sufficiently ex- pel the air. When it is cooled by the affusion of water, a transferrer plate being attached to the stopcock on its upper surface would easily enable us, without any air-pump, to effect congelation by means of sulphuric acid in the attenuated atmo- sphere. Suppose the capacity of the receiver to be one-sixtieth of the iron cylinder, an aeriform rare- faction to this degree would be effected in a mo- ment by a turn of the stopcock ; and, on its being returned, the moisture below would be cut off, and the acid would speedily condense the small quan- tity of vapor which had ascended." Many curious experiments may be performed over sulphuric acid, in the receiver of an air-pump, among which one of the most instructive and amu- sing is the congelation of quicksilver, a metal which requires, for this purpose, a temperature of 39° be- low zero, or 71° below the freezing point of water. This is readily effected by suspending the metal in a capsule of ice by means of threads, near to the surface of the sulphuric acid, and urging the rare- faction as much as possible. Mercury so frozen may be kept in the solid state for several hours. The processes of congelation above detailed ad- mit of being applied to several useful purposes, especially in domestic economy, and the arts of the cook and confectioner, as in the making of 1CGS &.C. CONGREVE MATCHES. I. (Process of M. Joblonouski.) Put phosphorus 40 grammes into a wide-mouthed vial, with enough oil of tur- pentine to cover it, add flowers of sulphur 10 gr., CON 213 CON and put the vial into hot water, (using great cau- tion,) until the phosphorus is melted. Then cork close and agitate until cold, when any supernatant spirits of turpentine must be poured off Into this pulpy mass the extremities of the matches are dipped, and when they have become rather dry, they are again dipped into the following mixture: Gum arabic 30 grammes, (dissolved in a little wa- ter ;) chlorate of potassa 20 grammes; soot, or vermilion, (rubbed up with a few drops of alco- hol,) 10 gr.; mix, and dip the tips of the matches therein as before, then dry them cautiously in a warm apartment. These matches inflame without fulmination (noise) on being rubbed against any rough surface. II. (Joblonouski.) Chlorate of potassa 2 parts ; phosphorus 4 parts; gum arabic 7 parts; gelatin 2 parts. Proc. The phosphorus is divided in the gum brought to the state of thick mucilage, and warmed; the gelatin is melted and added to the phosphoreted mucilage. The chlorate of potassa is bruised in a mortar, and at the same time moist- ened with the mucilage. When it is bruised the whole is mixed together, and a paste is obtained, with which matches, tipped with sulphur, may be embued. They are then dried in the air. III. (Process of Dr. R. Boettger.) Gum ara- bic and vermilion, of each 16 parts; phosphorus 9 parts; saltpetre 14 parts. Proc. The phospho- rus must be reduced to a state of fine division, by agitating it with fresh urine, or, still better, a solu- tion of pure urea, which, in consequence of the discovery by Liebig, of a process of preparing that substance artificially, may now be easily procured or made. Hot water must be employed to melt the phosphorus, and this part of the process is sim- ilar to that previously detailed. The minutely di- vided phosphorus thus formed, is mixed with the other articles made into a paste, with the gum dissolved in the least quantity of water, and the matches dipped into the mingled ingredients and dried. They are then dipped into a dilute varnish of copal, or a thin solution of gum arabic contain- ing saltpetre, and again dried. (Boettger's Beitrage.) These matches are very superior, and explode without noise. Remarks. The matches formerly made, explo- ded with a crackling noise, and frequently threw out small sparks of fire, which rendered them dan - gerous. This arose from their containing too large a quantity of chlorate of potassa. An opposite plan is now generally followed, and a less proportion of the chlorate is used, or instead thereof saltpetre. The quantity of the igniting ingredients has also been greatly lessened, so as to avoid any danger on that account. This plan answers very well, when the body of the matches, whether of wood or pasteboard, is properly prepared ; but if this be not the case, frequent disappointment will occur, from their going out again immediately after in- flaming. To prevent this, the matches should be dipped into sulphur previously to coating them with the composition, unless intended for cigar fusees, when they should be prepared by soaking them in water holding some saltpetre, bichromate of potash, or acetate of lead in solution, preference being usu- ally given to the first of these articles. Different coloring substant es are employed to tint the com- position, according to the fancy of the manufac-1 turer, as smalts, red lead, vermilion, black oxide of manganese, soot, &c. A very elegant method of reducing phosphorus to a state of minute divi- sion, is to melt it in rectified spirit, and agitate until cold, as above. The manufacture and sale of matches, contain- ing sulphur and phosphorus, as in the first formula, have been forbidden in Paris, in consequence of the extreme facility with which they ignite, having led to several accidents. (See Chlorate Matches, and Lucifers.) •CONIA. Syn. Coneine. Conicin. Cicutine, &c. A poisonous alkaloid, discovered by Gieseke in hemlock. Prep. Distil the seeds of hemlock, or their al- coholic extract, with water and potassa. During this process, the conia passes over into the receiver and floats upon the top of the water, which also contains a little conia in solution. It must be pu- rified in the way directed for the volatile bases. (See Alkaloid.) If the alcoholic extract be em- ployed, about £ its weight of potassa should be used. Remarks. 6 lbs. of fresh and 9 lbs. of dried seeds yielded 1 oz. of conia. (Gieger.) 40 lbs. of the ripe but green seeds yielded 2^ oz. of hydrated co- nia. (Christison.) It is remarkably poisonous. One drop, placed in the eye of a rabbit, killed it in 9 minutes. Five drops, poured into the throat of a dog, killed it in less than a minute. It has been employed in some convulsive and spasmodic dis- eases. " The plaintive cries, the contortions, and the rigidity of the limbs, which have always pre- ceded death, (caused by conia,) leave no doubt as to the cruel pains which this kind of poisoning brings on." (Boutron-Chalard and Henry.) CONSERVES. (From conservo, to keep.) In pharmacy, a composition of some recent vegetable matter and sugar, beat together to the consistence of a paste. The object aimed at in the prepara- tion of conserves, is to preserve the properties of the active ingredient, which would otherwise be liable to change. In the last edition of the London Pharmacopoeia, conserves, as well as electuaries, are included under the head of confections. The term confection appears, however, less appropriate to some of them, than the word conserve or elec- tuary. The word confection has a more general application, and implies any sweetmeat or compo- sition, in which sugar is the principal ingredient. CONSERVE OF ALMONDS. (Conserva Amygdalarum, P. D.) Confection of almonds. CONSERVE, ANTISCORBUTIC. (Con- serva Antiscorbutica. Selle.) Horseradish, wa- ter-cress, water-trefoil, radish juice, and orange juice, of each equal parts ; white sugar enough to make a confection. CONSERVE OF ARUM. (Wakerobin.) Prep. Fresh arum roots j lb.; white sugar 1 i lb.; beat together. Diuretic and attenuant CONSERVE OF LAVENDER. Prep. Lav- ender flowers 1 part; lump sugar 3 parts; beat together. Remarks. In a similar way conserves are made from various other leaves and flowers; but mostly with only twice their weight of sugar. The above is frequently used to sweeten the breath. CONSERVE OF LEMON-PEEL. Prep Rasp off the external rind of the lemon, and beat COP 214 COP it in a mortar with three times its weight of pow- dered white sugar. (See Confection of Orange- Peel.) Tonic and stomachic. CONSERVE OF ORANGE-PEEL. (Con- serva Aurantii, P. E.) The same as the confec- tion of orange-peel, P. L. CONSERVE OF RED ROSES. (Conser- va Rosa, P. E. and D.) That of the Dublin Pharmacopoeia is the same as the confection of roses, P. L.; that of the Edinburgh has only 2 lbs. of sugar to 1 lb. of rose petals. CONSERVE OF ROSEMARY. Prep. *1 part of the leaves or tops, beaten up with 3 parts of sugar. CONSERVE OF SCURVY GRASS. Syn. Conserva Cochlears Hortf.nsis. Prep. Beat 1 lb. of the leaves with 3 lbs. of lump sugar. Stim- ulant and antiscorbutic. CONSERVE OF SLOES. Syn. Conserva Pruni Sylvestris, (P. L. 1788.) Pulp of sloes 1 part; sugar 3 parts ; mix. CONSERVE OF SQUILLS. Syn. Conser- va Scill.e, (P. L. 1788.) Fresh squills Jj 5 white sugar ^v ; mix. Diuretic ; attenuant. CONSERVE OF TAMARINDS. Syn. Con- serva Tamarindorum. Prep. (P. Cod.) Pulp of tamarinds 4 oz.; white sugar 6 oz.; heat by a water-bath in an earthen vessel, until mixed and of a due consistence. CONSERVE OF WORMWOOD. Syn. Con- serva Absinthii Maritimi, (P. L. 1788.) Prep. Beat fresh-picked leaves of sea wormwood in a marble mortar, with a wooden pestle, first alone, and then with 3 times their weight of refined sugar. CONSTIPATION, (OF THE BOWELS.) Costiveness. When this is merely accidental or occasional, a dose of some cathartic is the only treatment necessary, but when it is habitual, it calls for further attention. The common causes of constipation are—The use of bread containing alum, and water containing lime ; and the want of sufficient exercise. The treatment should con- sist in adopting a diet free from astringents, and consisting of a large portion of green vegetables and ripe fruit. Brown bread is frequently eaten for this purpose, and acts by the laxative nature of the bran it contains. The occasional use of laxative and emollient enemata may be had re- course to, but their habitual administration, as well as that of purgative medicines, by the mouth, is not to be recommended. The bowels, accus- tomed to the continual use of stimulants, act but languidly, or scarcely at all, without their applica- tion. In females, especially of the higher classes, the want of proper exercise is generally the chief cause of constipation. With such persons, a short walk two or three times daily will often do won- ders, particularly if a little ripe fruit, a few raisins or tamarinds, or 2 or 3 drum figs, be occasionally eaten. COPAIBA. Syn. Capivi. Balsam of Capivi. The best copaiba is that imported from Maracaibo and St Martha, and is packed in casks containing from 1 to 1£ cwt. each, in large bottles, or in cyl- indrical tin Iwxes. Considerable variation exists in the color, consistence, and sp. gr., as well as in the proportion of oil and resin yielded by different samples, scarcely any two of which exactly agree. Even the odor, taste, and transparency vary con- siderably. Brazilian capivi is thin, clear, and pale; while the West Indian is thick, golden yellow, less transparent, and has a less agreeable and some- what terebinthinate smell. Some varieties are opaque, and continue so, unless filtered. This is a most troublesome operation, unless well managed, and without proper precautions, frequently proves useless. The opacity generally arises from the presence of water, which is frequently found mixed with copaiba when first imported. This it retains with great tenacity. The following is the plan I have found to answer on the large scale. Place the casks upon their ends in a warm situation, and leave them so for a fortnight, or longer, if conve- nient. They may then be tapped a little above the bottom, when some of them will generally be found quite transparent, and may be drawn off and vatted, care being taken to avoid shaking up the bottom. Those that are foul must be filtered through one or more long Canton flannel bags, sunk in the bottom of a tin cistern, placed over a suitable receiver; a few pounds of coarsely-pow- dered charcoal being mixed up with the first 5 or 6 gallons thrown in. This will rapidly fill up the pores of the bag, and make the balsam flow clear and pale. The first runnings should be returned until it becomes perfectly transparent. The bot- toms of the casks, containing the water or impu- rities, may be poured into a large can or jar, and allowed to deposite for a few days, when the co- paiba may be poured off the top, and filtered. A sudden change of temperature will frequently turn a brilliant sample of this article opaque or milky; it is not, therefore, deemed fit to send out by the wholesale trade, unless it will " stand" this test. To ascertain this point, a common practice is to fill a small bottle with the copaiba, and to leave it out of doors all night in an exposed situation. (See also Balsam of Copaiba.) COPAIBA, ALKALINE TINCTURE OF. (Lewis Thompson.) Prep. Dissolve 2 oz. of car- bonate (formerly subcarbonate) of potassa in 1 pint of water, and add to this, balsam of copaiba in a thin stream, constantly stirring the mixture, until this, at first white and milky, becomes clear like jelly or amber, which will generally take place when about a pint of balsam has been added; set the mixture aside for two or three hours, then pour in two pints of spirit of wine, and mix the whole together ; the solution is then fit for use, and may be flavored with any of the essential oils. Sweet spirit of nitre may be substituted for spirit of wine; but it is necessary to destroy its acidity by distilla- tion from lime or potassa, otherwise a decomposi- tion will take place. This solution is compatible with iodide of potas- sium and nitrate of potassa, but is decomposed by all earthy, metallic, and ammoniacal salts, such as sulphate of magnesia, chloride of iron, acetate of ammonia, &c, which must not, therefore,'be ad- ministered in conjunction with it. (Chemist, iv 510.) COPAIBA AND KALI. Prep. Carbonate of potassa and water, of each equal parts ; dis- solve, and add gradually transparent balsam of co- paiba until the fluid, at first milky, turns quite clear COPAIBA CAPSULES. Gelatinous capeuki filled with balsam of copaiba. COP 215 COP COPAIBA AND JtHATANY, CAPSULES OF. Ricord has recommended capsules of co- paiba, coated with extract of rhatany, as much superior to the common ones of copaiba alone, in the treatment of blenorrhcea. They may be easily prepared by either of the two following meth- ods: 1. By immersing, for an instant, the common capsule in the following composition: or, 2. By forming the bodies of the capsules with the composition, instead of with gelatin, and fol- lowing the same manipulations as for the manu- facture of the common gelatin capsules. The Rhatany Composition. Extract of rhatany, newly prepared from the root, 3 parts ; sirup of moist sugar 1 part; mucilage of gum arabic 1 part. Melt the extract and reduce it in a water bath until sufficiently stiff, when cold; do the same with the sirup and gum; then mix them together while hot, but only in such quantity as may be used at one time. These capsules are said to sit well upon the stomach, the tone of which they contribute to improve. COPAIBA, MISCIBLE. Prep. Mix trans- parent balsam of copaiba with half its volume of liquor of potassa of double strength. Remarks. Different samples of balsam often re- quire slightly different quantities of the solution of potassa; it is therefore best to mix them gradually and cautiously together. Should the mixture be opaque, a little more, of one or other of the ingredi- ents, as the case may be, will render it clear. No heat should be used. This article is miscible with water, with which it forms a kind of milk ; and from containing all the volatile oil of the copaiba is a very valuable preparation. Its activity is con- sidered equal to the balsam itself, and it is given in similar doses. COPAIBA, MIXTURE OF. (Chopart.) Prep. Copaiba, alcohol, sirup of Tolu, peppermint water, orange-flower water, of each fij ; sweet spirits of nitre 3ij. Proc. Rub the copaiba with the sirup until perfectly mixed, then add the spirits, and lastlv the waters. COPAIBA, SOLUBLE. Prep. I. Heat mis- cible copaiba to the boiling point, pour it while hot into a " separator," and place it in some situation where it will cool slowly. After a few days draw off the clear portion from a cock or hole placed near the bottom of the vessel, observing to stop the stream before any of the floating oil begins to flow through. A very little concentrated liquor of potassa added before applying the heat, will render it more soluble. Prod. Thick, clear, and soluble in pure water. Resembles copaiba in appearance. II. Agitate balsam of copaiba with an equal measure of liquor of potassa, (P. L.;) boil for a few minutes in a clean tinned copper pan, then pour it into a separator, and proceed as before. Thinner than the last. COPAIBA, SPECIFIC SOLUTION OF. (Frank's.) Prep. I. Balsam of copaiba 2 parts; liquor of potassa (P. L.) 3 parts; water 7 parts; boil it for 2 or 3 minutes, put it into a separator, and allow it to stand for 5 or 6 days, then draw it off from the bottom, avoiding the upper stratum of oil. To the clear liquid add 1 part of sweet ■pints of nitre, perfectly free from acid, to which a few drops of liquor of potassa has been added, until it slightly browns turmeric paper ; should it turn foul or milky, a very little liquor of potassa will usually brighten it; if not, place it in a clean separator for a few days, and draw it off from the bottom as before, when it will be perfectly brilliant without filtering. Remarks. Some persons add the sweet spirits of nitre while the solution is still hot, mix it in as rap- idly as possible, and immediately cork or fasten up the vessel. This is a good way when the article is wanted in a hurry, but is objectionable from the loss of spirit thereby occasioned, and the danger, without care, of bursting the separator. A receipt for this article, upon the authority of Battley, has been going the round of the pharma- ceutical works for some years, but which produces a preparation not at all resembling " Frank's spe- cific solution." It is as follows: " Take 12 oz. of balsam of copaiba and 6 oz. of calcined mag- nesia ; rub together, add a pint of proof spirit, fil- ter, and then add i oz. of sweet spirits of nitre." (Gray's Supplement.) I have tried this formula, and I find the product to be a white tincture, scarcely flavored with copaiba, and perfectly lim- pid. No sooner is balsam of copaiba mixed with half its weight of magnesia, than the two unite, and produce a compound insoluble in spirit of wine. Such is the. affinity of this earth for copaiba, (co- paibic acid,) that it will even take it from caustic potassa. Thus I find the solution of this balsam, (containing potassa,) if filtered through blotting- paper, with a little magnesia, becomes so strongly alkaline as to materially injure its quality, while a glutinous mass is deposited upon the sides and bottom of the paper. I have been led to a notice of this subject, from well knowing that many drug- gists have adopted this formula, and have been disappointed with the results, which are, however, only such as might be reasonably anticipated. COPAIBA, SALT OF. Syn. Sal Copaiba There are two preparations bearing this name, the one, copaibic acid, and the other, copaibate of an alkali. They are both sold at ridiculously high prices. The advertisement of one of these prep- arations is heralded in with the following pseudo- philosophical announcement :• " This preparation of copaiba, in its chemical and medical analogies, may be compared to qui- nine from bark, the former being the tonic of the mucous membranes, and the latter that of the der- moid structures. " This salt contains all the properties of the balsam of copaiba in a very concentrated form, without its nauseating qualities, and from this cir- cumstance it may be administered to the most deli- cate constitution." It is the general opinion of medical men, that the active properties of copaiba reside in a volatile or essential oil, of which the aooi;e preparation is destitute. It is therefore difficult to conceive how, in this instance, the reverse should be the case. I can speak from my own experience, and that of several high authorities to whom I have referred, that both the viscid and acid resins of copaiba are almost inert, and that all the alkaline preparations of these substances are nearly similar. I have taken the " sal copaibas" myself, and have watch- ed its action on others, but have not been able to COP 216 COP perceive any good effects to result from its ad- ministration. COPAIBIC ACID. Syn. Capivic Acid. The yellow brittle resin of balsam of copaiba. It is prepared by digesting the resin (left after distilling the oil from the balsam) in alcohol, which dis- solves the acid resin, but leaves the viscid one. It may be purified by re-solution in alcohol. It forms about 50°f of the balsam. Prop. An amber-colored, brittle, semi-crystal- line, resinous substance, soluble in alcohol, ether, and oils, reddens litmus paper, and forms salts with the bases, called copaivates. These may gene- rally be made by dropping into a solution of the acid in alcohol, an alcoholic solution of a soluble salt of the base. The copaivates of potash, soda, and ammonia are easily prepared, by adding to an al- coholic solution of the acid another of the pure alkali, until it be neutralized, when the salts may be ob- tained by careful evaporation. Copaivate of silver is formed by neutralizing the acid with nitrate of silver, both being dissolved in alcohol, and then adding a little liquor of ammonia, when a white crystalline precipitate will subside. The copai- vates of lead, lime, and iron, as well as several others, may be made in a similar manner. Copaivate of magnesia may be made by adding copaivate of potassa to a solution of epsom salts. All these salts are easily decomposed by acids. COPAL. Syn. Gum Copal. A resinous sub- stance, which exudes spontaneously from the Rhus copallinum, and the Elsocarpus copalifer. When of good quality, it is too hard to be scratched by the nail, and has a conchoidal fracture. It dissolves with difficulty, and this, combined with its extreme hardness, renders it very valuable for making var- nishes. Solvents. I. Caoutchoueine; sparingly. II. Equal parts of caoutchoueine and alcohol, of -825; freely soluble in the cold. III. Absolute alcohol, added gradually to the copal, previously rendered gelatinous by water of ammonia, assisting the union with heat. IV. Alcohol added to the co- pal, previously softened with ether. V. Absolute alcohol 1£ parts, digested on copal 1 part for 24 hours. (Unverdorben.) VI. Alcohol, to which a little camphor has been added. VII. Ether; and this solution may be diluted with alcohol. VIII. Oils of rosemary and lavender, (spike;) too ex- pensive for general use. IX. Copal, heated until it fuses, acquires the property of dissolving in tur- pentine and alcohol. X. Copal, reduced to pow- der and exposed for some time to the air, also be- comes soluble in alcohol and turpentine. XL Dry- ing linseed oil, at nearly the boiling point, dis- solves copal, and will bear dilution with spirits of turpentine as soon as it has cooled sufficiently. This is the common way of making copal varnish. XII. Ammonia enables oil of turpentine to dissolve copal; but it requires such nice management of the fire, that it seldom succeeds completely. (Lewis.) XIII. Powdered copal, triturated with a little camphor, softens and becomes a coherent mass; and camphor, added either to alcohol or oil of turpentine, renders it a solvent of copal. $ oz. r»f camphor is sufficient for 1 quart of oil of turpen- tine, which should be of the best quality ; and the copal, about the size of a large walnut, should be broken into very small pieces, but not reduced to ! a fine powder. The mixture should be set on a I fire so brisk as to make it boil almost immediately The vessel should be of tin or other metal, strong, shaped like a wine-bottle with a long neck, and capable of holding 2 quarts. The mouth should be stopped with a cork, in which a notch is cut to prevent the vessel from bursting. (Sheldrake.) XIV. A good varnish may be made by pouring upon the purest lumps of copal, reduced to a fine mass in a mortar, colorless spirits of turpentine, to about one third higher than the copal, and tritura- ' ting the mixture occasionally in the course of the day. Next morning it may be poured off into a bottle for use. Successive portions of oil of turpen- tine may thus be worked with the same copal mass. (Varley, Tilloch's Mag. 51.) *„* In all the above cases the copal should be reduced to a coarse powder. A fine powder is apt to stick together and form hard lumps. The solu- tion of copal, even in its most ready solvents, is at- tended with some difficulty, and frequently mis- carries in the hands of the inexperienced. A mix- ture of caoutchoueine and alcohol (as in No. II.) is an exception. COPAL, MELTED. Obtained by holding the gum before a good fire, so that as soon as the copal melts, it may drop into a pan of water: a kind of oil separates from it, and the copal becomes soluble in spirits of wine, and still more so if the melting is repeated. COPAL, POWDERED. Copal reduced to powder and exposed to the air in a thin stratum, on sieves covered with paper, for 3 or 4 months. Soluble iu alcohol. COPPER. (From cuprum, a corruption of ««;Tpof, from the island of Cyprus, whence it was formerly brought.) A red-colored metal, too well known to require description. Hist. Copper and its alloys appear to have been known to the most remote ages of antiquity. Brass, an alloy of copper, is mentioned by Moses (Job, xxviii.) upwards of 1600 years before the birth of Christ. (Hales.) This metal is found in the me- tallic state, and in combination with oxygen, sul- phur, acids, and other minerals, and in the organic kingdom, in the ashes of plants, and in the blood of animals. (Sarzeau.) The copper of commerce is principally prepared from copper pyrites, a mixed sulphuret of iron and copper, found in Cornwall, and other parts of the world. Prep. Copper is only prepared from its ores on the large scale. The copper pyrites is first roasted, and then smelted, by which process " coarse metal" is produced ; this is again submitted to calcination and smelting, when "fine metal" is obtained. It afterwards undergoes the process of refining and toughening. Prop. This metal is malleable and ductile. It has a specific gravity of 88 to 89, fuses at about 2000° Fahr., and volatilizes at higher tempera- tures. It forms numerous compounds, all of which are more or less poisonous. Char, and Tests. The solutions of copper pos- sess a blue or green color, and yield a blue precip- itate with 6oda or potassa. Ammonia produces a bluish-white precipitate, soluble in an excess of the precipitant, forming a deep blue solution. Prussiate of potash gives a reddish-brown precipitate, sul- phureted hydrogen and hydrosulphurets, a black COP 217 COP 9ne. A polished iron plate, immersed in an acidu- lous solution of copper, becomes coated with that metal. Estim. The quantity of copper present in any compound, may be estimated by throwing it down from its solution by pure potassa, after which it must be carefully collected, washed, dried, ignited, and weighed. This will give the quantity of the oxide from which its equivalent of metallic copper may be calculated ; every 5 parts of the former being (as near as possible) equal to 4 of the latter. Copper may also be precipitated at once in the metallic stat^, by immersing a piece of polished steel into the solution, but this method will not give very accurate results. Copper may be separated from lead by adding sulphuric acid to the nitric solution, and evaporating to dryness, when water digested on the residuum will dissolve out the sul- phate of copper, but leave the sulphate of lead be- hind. From this solution the oxide of copper may be thrown down as before. Copper may be sepa- rated from zinc by sulphureted hydrogen, which will throw down a sulphuret of copper, which may be dissolved in nitric acid, and treated as above. Uses. The applications of copper in the arts are too well known to require notice. In medicine, 3 or 4 grains of the filings were formerly given hi rheumatism, and to prevent hydrophobia. Ant. Copper in the metallic state appears to be inert, but most of its compounds are poisonous. The antidotes are, the white of egg, milk, or flour mixed with water. Iron filings (Payen, Chevallier, Dumas) and the prussiate of potash have also been recommended. A drachm or more of the latter may be taken dissolved in water, and ^ oz. or more of the former, ad libituir. Sugar has also been proposed as an antidote. (Duval, Postel.) COPPER, ALLOVS OF. With zinc copper forms brass; with tin, bronze, bell, and cannon metal. An alloy made with 100 parts of copper and 50 of tin, forms speculum metal. White cop- per is formed by the addition of metallic arsenic, and German silver is a mixture of nickel, zinc, and copper. See these articles in their alphabetical places. COPPER, ACETATES OF. I. (Neutral Acetate. Syn. Distilled Verdigris. Binacetate of Copper. Crystallized Verdigris.) Prep. Dis- solve verdigris in vinegar, with the aid of heat, and crystallize. It forms dark green or blue crystals. II. (Diacetate. Syn. Verdigris. AUruro.) Formed by exposing sheets of copper to the vapor of acetic acid, in a warm situation. (See Verdi- gris.) It forms a green or bluish-green powder. III. (Sesquibasic Acetate.) The blue portion of verdigris, soluble in water. IV. (Trisacetate.) The green insoluble portion of verdigris. COPPER, ARSENITE OF. Syn. Scheele's Green. Prep. Mix a solution of 2 parts of sul- phate of copper in 44 of water, with a solution of 2 parts of potash of commerce, and 1 of pulverized arsenious acid, also in 44 of water. Both solu- tions being warm, the first is to be gradually poured into the second. The grass-green insoluble precipitate is to be washed with water. COPPER, AMMONIURETED. Syn. Cu- PRO-SULPHATE OF A.MMONIA. Am.MONIATED COPPER, (P. E.) Prep. 'Ammonio-sulphate oj Copper, I 28 P. L.) Sulphate of copper ^j; sesquicarbonate of ammonia ^iss. Rub them together until carbonic acid ceases to evolve, then wrap it up in bibulous paper and dry it in the air. Prop. By heat ammonia is evolved, and oxide of copper remains. Its aqueous solution changes the color of turmeric, and a solution of arsenious acid renders it green. (P. L.) Uses. Employed in pyrotechny. It has been given in doses of ^ to 5 grs. in chorea, epilepsy, hysteria, &c., but it is principally employed as an injection and as a collyrium, in opacity of the cor- nea. Remarks. Great care must be taken in drying this article, as it is apt not only to lose a large por- tion of its weight, but become of an inferior color. Both the ingredients should be separately reduced to powder before mixing. COPPER, BEAN-SHOT. Prep. Melt cop- per, and pour it in a small stream into boiling wa- ter. It is in small lumps like peas or beans, hence its name. COPPER, BLANCHED. Prep. Fuse cop- per with y1^ of its weight of neutral arsenical salt, under a flux of calcined borax, charcoal, and pow- dered glass. COPPER, CARBONATE OF. Syn. Di- CARBONATE OF COPPER. MlNERAL GREEN. Prep. Add a solution of carbonate of soda or potassa to a hot solution of protosulphate of copper. Remarks. The beautiful green mineral called malachite, is a hydrated dicarbonate of copper. If the solution of copper in the above formula be em- ployed cold, the precipitate has a bluish-green color. (See Verditer.) COPPER, CHLORIDES OF. Prep. I. (Sub- chloride. Syn. Dichloride of Copper. Renin of ditto. White muriate of ditto.) Distil a mix- ture of 1 part of copper filings, witli iwo parti, of corrosive sublimate. II. (Chloride. Syn. Muriate of Copper. Hy- drochlorate of ditto. Protochloride of ditto.) Dissolve protoxide of copper iii muriatic arid, evaporate and crystallize. Remarks. This salt forms green needles, is de- liquescent, soluble in alcohol, and when heated, (under 400°,) loses its water, and becomes anhy- drous chloride of copper, and assumes the form of a yellow powder. The first of these preparations is sometimes called the protochloride or muriate ; the second the deutochloride. COPPER, CHROMATE OF. Prep. Pre- cipitate a salt of copper, with neutral chromate of potash ; or dissolve hydrated peroxide or car- bonate of copper in chromic acid. Caustic ammo- nia dissolves this salt, forming a magnificent dark- green liquid, from which, by the admixture of spirit of wine, ammonio-chromate of copper, or cupro-chromate of ammonia, is disengaged in the form of a powder of a splendid, rather dark-green appearance. The readiest way of preparing this permanent and beautiful color, is to add solution of chromate of potash to ammoniacal sulphate of copper. COPPER, FEATHER-SHOT. Prep. Melt- ed copper, poured in a small stream into cold water. It forms small pieces, with a feathered edge, hence the name. It is used to make solu- tion of copper. COP 218 COP COPPER GREEN. Syn. Oxv-chloride of Copper. Bremen Green. Brunswick ditto. Friezland ditto. Prep Pour a saturated so- lution of muriate of ammonia over copper filings or shreds in a close vessel, keeping the mixture in a warm place, and adding more of the solution from time to time, till 3 parts of muriate and 2 of copper have been used. After' standing a few weeks, the pigment is to be separated from the unoxidized copper, by washing through a sieve; and then it is to be well washed, and dried slowly in the shade. This green is almost always adul- terated with ceruse, which improves the color. Remarks. A mixture i/f cream-tartrate, or car- bonate of copper, with carbonate of lime and mag- nesia, is also sold under the name of Brunswick green. COPPER, IN FINE POWDER. Prep. A solution of sulphate of copper is heated to the boiling-point, and precipitated with distilled zinc. The precipitated copper is then separated from the adherent zinc by diluted sulphuric acid, and dried by exposure to a moderate temperature. From recently precipitated chloride of silver, an exceed- ingly fine silver-dust may also be obtained by boil- ing it with water, acidulated with sulphuric acid and zinc. (Boettger's Beitrage.) COPPER, IODIDE OF. I. (Iodide.) When iodide of potassium is added to a solution of a salt of copper, a diniodide of copper falls down, and an iodide remains in solution. It is but little known. II. (Diniodide.) To a solution of 4 parts of protosulphate of copper, and 5 parts of protosul- phate of iron, add a solution of iodide of potassium, wash and dry the precipitate. R*»i irks. The last preparation is that common- ly known in trade by the name of iodide of copper. COPPER, OXIDES OF. I. (Black Oxide. Syn. Protoj ide of Copper.) Prep. This may be formed by calcining metallic copper, nitrate of copper, or the hydrate, thrown down from solu- tions of the salts of copper by means of pure po- tassa. This preparation was formerly called the deutoxide of copper. It is not changed by heat, but readily gives out its oxygen when heated with combustible matter; hence its general use in or- ganic analysis for supplying oxygen. II. (Red Oxide. Syn. Dioxide of Copper.) Prep. a. Mix 316 parts of copper filings with 39*6 parts of black oxide of copper, and heat them to- gether in a covered crucible. b. Boil a solution of the acetate of protoxide of copper with sugar; collect the red powder, wash it with water, and dry it. c. Mix dichloride of copper with an equal weight of carbonate of soda, and fuse it at a low red heat, then well wash the mass with water, and dry the red powder. d. Mix 100 parts of sulphate of copper with 57 parts of carbonate of soda, (both in crystals,) and fuse them at a gentle heat; cool, pulverize, add 25 parts of fine copper filings, ram the mixture into a crucible, cover it over, and expose it for 20 minutes to a white heat. e. A saturated solution of 6ugar of milk, con- taining some carbonate of soda, is poured over re- cently prepared moist hydrated oxide of copper, and heated to boiling. A dark orange-colored p. iripitate of hydrate of protoxide of copper soon appears, from which saccharine matter is removed by washing in distilled water, and then dried. /. (Magnificently red anhydrous protoxide of copper.) A solution of 27 parts of cane-sugar, in 60 parts of water, is poured over 9 parts of hy- drate of oxide of copper, (weighed in the com- pressed and still moist state ;) a solution of 18 parts of caustic potassa, in 60 parts of water, is added; the whole mass well agitated together at the ordinary temperatures, and strained through linen. If the dark-blue liquid, after being passed through the strainer, is heated, continually stirring over the water-bath, anhydrous protoxide of cop- per is disengaged, and the liquid becomes colorless. (Boettger's Beitrage.) Remarks. Red oxide of copper resembles me- tallic copper in appearance. It is used as a pig. ment and a bronze. By heat it is converted into the black oxide. With ammonia it forms a color- less solution, but rapidly becomes bluo from the action of the air. This preparation was formerly called protoxide of copper. III. (Peroxide.) Formed by the action of per- oxide of hydrogen water, on the hydrated black oxide. (Thernard.) It is very liable to spontane- ous decomposition. Remarks. According to the opinions of Berze- lius, Thompson, Liebig, Gregory, and others, the eq of copper is 31-6, and consequently the red oxide is a sub- or di-oxide, and the black the oxide oi protoxide. The former containing 63-2 parts of copper and 8 of oxygen, and the latter 31-6 of copper and 8 of oxygen. But if the eq. of copper be taken at 63-2, as is done by some persons, the first of these preparations must be regarded as the protoxide, and the second as the deuto- or bin- oxide. The latter terms were generally applied to them in chemical works, until within the last few years. The black oxide has also been called the peroxide. This explanation is called for, to prevent the tyro in chemistry mistaking the one preparation for the other. COPPER, SALTS OF. These are more or less poisonous, and may be recognised in the man- ner as described under the article Copper. COPPER VESSELS. Culinary and pharma- ceutical vessels are very commonly made of cop- per, but too much caution cannot be exercised-in their employment. Acid sirups, vegetable juices, aqueous extracts, soups, stews, &.c, prepared in copper saucepans, or boilers, receive a metal- lic contamination proportional to the length of time they are exposed to the action of the metal. Such vessels are frequently tinned, for the purpose of protecting the copper from contact with their contents, but this film of tin is necessarily very thin, and rubs off by constant use. When acids or acidulous fluids are boiled in vessels of imper- fectly tinned copper, a portion of the tin is taken up by the liquid, and deposited upon the abraded or exposed part, thus protecting the copper from the farther action of the menstruum ; but the pro- tective power of such a deposite is limited, and it has been proved that when a coating of metal is extremely thin, though appearing quite perfect to the eye, it has a certain porosity, that permits the action of acids on the metal beneath. This has been proved to be the case, even when the deposite is of silver. (W*irruigton.) When copper vessels COR 219 COR are allowed to remain wet or dirty, and especially greasy, a poisonous green matter forms upon their surface, somewhat similar to verdigris, and if ar- ticles prepared in them without their being first properly cleaned, be taken as food, serious conse- quences may ensue. Cases of poisoning from this cause are frequently met with, and instances of vomiting following the use of such articles are still more common. I have known extracts prepared in copper pans deposite a coating of that metal upon the knives used to stir them, and the ashes of the inspissated juices of fresh vegetables, and especially the pulps of fruit, prepared in vessels of the same metal, have exhibited the presence of copper on the application of chemical tests. The most wholesome material for culinary utensils is thin sheet iron or tin plate, which is very durable if kept clean and dry when not in use. Copper vessels of every kind should be cleaned out, im- mediately before use, even though they may not appear to want it, and on no account should they be employed for any fluids that are the least acidulous, or that are required to remain long in them. COPPERAS. Syn. Green Copperas. Green Vitriol. Vitriol of Iron. Commercial Sul- phate of Iron. Crude sulphate of iron, made by allowing iron pyrites to effloresce in the air, wash- ing out the salt, boiling along with scraps of old iron, evaporating and crystallizing. COPPERAS, CALCINED. Syn. Dried Sulphate of Iron. Calcined ditto. Prep. Heat green vitriol in an unglazed earthen pot, or spread it out in a warm situation, until it becomes white and dry. Use. It is astringent and drying, and is sometimes used in making ink, and in dyeing. CORAL, FACTITIOUS. Prepared chalk dried, colored with a little sesquioxide of iron, or rose pink, and passed through a sieve. This is al- most universally sold by the druggists for powdered coral. It possesses similar properties. CORDIAL, (in Medicine.) Any warm stim- ulant that tends to raise the spirits and promote the circulation. The principal cordial medicines are the aromatized tinctures. CORDIAL, (in the art of the Rectifier.) Aromatized and sweetened spirit, employed as a beverage. Cordials are prepared by either infusing the aro- matics in the spirit, and drawing off the essence by distillation, which is then sweetened, or without distillation, by flavoring the spirit with essential oils, or simple digestion on the ingredients, adding sugar or sirup, as before. Malt or molasses spirit is the kind usually employed, and for this purpose should be perfectly flavorless; as, if this be not the case, the quality of the cordial will be inferior. Rectified spirit of wine is generally the most free from flavor, and when reduced to a proper strength with water, forms the best and purest spirit for cordial liquors. Spirit which has been freed from its own essential oil, by careful rectification, is commonly called 'pure,' 'flavorless,' 'plain,' or 'silent spirit.' The solid ingredients should be coarsely pounded or bruised, before digestion in the spirit, and this should be done immediately before putting them into the cask or vat; as, after they are bruised, they rapidly lose their aromatic prop- •rties by exposure to the air. The practice of drying the ingredients before pounding them, adopted by some workmen for the mere sake of lessening the labor, cannot be too much avoided, as the least exposure to heat tends to lessen their aromatic properties, which are very volatile. The length of time the ingredients should be digested in the spirit, should never be less than 3 or 4 days, but a longer period is preferable when distil- lation is not employed. In either case, the time allowed for digestion may be advantageously ex- tended to 10 days or a fortnight, and frequent agi- tation should be had recourse to. When essential oils are employed to give the flavor, they should be first dissolved in a little strong alcohol, or recti- fied spirit of wine, so as to make a perfectly trans- parent solution; and when added to the spirit, they should be mixed up with the whole mass as rapidly and as perfectly as possible, by laborious and long-continued agitation. In managing the still, the fire should be proportioned to the ponder- osity of the oil or flavoring, and the receiver should be changed before the faints come over, as the latter are unfit to be mixed with the cordial. The stronger spirit may be reduced to the desired strength by means of clear soft water, or the clar- ified sirup used for sweetening. The sugar em- ployed should be of the finest quality, and is pref- erably made into capillaire or sirup before adding it to the aromatized spirit; and this should not be added until the latter has been rendered perfectly fine by filtering or fining. Some spirits, as aniseed, &c, frequently require this treatment, which is best performed by running them through a fine and clean wine-bag, having previously mixed them with a spoonful or two of magnesia. By good management, cordials thus made'will be perfectly " clear" and transparent; but should this not be the case, they may be fined with the whites of about 12 or 20 eggs to the hogshead, or by adding a little alum, either alone, or followed by a little carbonate of soda or potassa, both dissolved in wa- ter. In a week or a fortnight the liquor will be clear. (See Clarification.) A most convenient and easy way of manufac- turing cordials, especially where it is wished to avoid keeping a large stock, is always to keep two casks of sweetened spirit ready prepared, at the strength of 60 or 64 u. p. The one should contain 1 lb. of sugar to the gallon, the other 3 lbs. per gallon. From these may be made spirit of any intermediate sweetness, which may be flavored with any essential oil dissolved in alcohol, or any aromatic spirit, prepared either by digestion or dis- tillation. As a general rule, the concentrated es- sences may be made by dissolving 1 oz. of the es- sential oil in 1 pint of the strongest rectified spirit of wine. This solution should be kept in well- corked bottles, and used by dropping it cautiously into the sweetened spirit, until the desired flavor is produced. During this operation, the cordial should be frequently and violently shaken, to produce a perfect admixture. Should sufficient essence to foul the liquor be added by accident, the transpa- rency may be restored by the addition of a little more spirit, or by clarification. The most frequent cause of failure in the manu- facture of cordials, is the addition of too much fla- voring. Persons unaccustomed to the use of strong aromatics and essential oils, seldom sufficiently es- COR 220 COR timate their power, and consequently, generally add too much of them, and thus not only is the liquor rendered disagreeably high flavored, but the quantity of oil present turns it 'milky,' or 'foul,' on the addition of the water. This again is an- other source of annoyance, as from the consist- ence or viscidity of the fluid, it is less readily 'fined down' than unsweetened liquor, and often gives much trouble to clumsy and inexperienced Operators. The most certain way to prevent this fa to use toolittle,rather than too much flavoring; for if the quantity prove insufficient, it may readily be ' brought up,' even after the cordial is made. A careful attention to the previous remarks will render this branch of the rectifier's art far more perfect and easy of performance than it is at pres- ent, and will, in most cases, produce at once a sat- isfactory article, 'fine, sweet, and pleasant.' It may be observed, before concluding this short notice, that the majority of cordials may be made with the pure essential oils, of nearly equal flavor to those prepared by distillation ; and for such as are colored, simple digestion of the ingredients is almost universally employed. Inferior lump, or even good brown sugar is used for some dark and strong-flavored articles. Ingredients that are not volatile, are, of course, always added after distil- lation. Though I have said that very excellent cordials may be made without distillation, yet the still should be always employed to impart the flavor and aroma of volatile aromatics to spirits, when the expense, labor, and time are of no im- portance compared to the production of a superior article. The strength at which cordials are usu- ally sent out by permits is 60 or 64 u. p. CORDIAL, ANISEED. Prep. I. Aniseed (bruised) 1 lb.; proof spirit 6 gallons; macerate for a week ; then distil 5 gallons; add 2 gallons of clear soft water, and 1 gallon of clarified sirup. ' This will make 8 gallons of cordial 24 u. p., which is as weak as " aniseed" should ever"be made. It may be reduced by sweetened water. II. Instead of distilling off the spirit, merely pass it through a wine-bag, to take off the seed, lower it with clear soft water, and sweeten as before. III. Instead of 1 lb. of aniseed, add enough of the essential oil, dissolved in spirit of wine, to pro- duce the desired flavor; 2 drachms of the oil is fully equal to 1 lb. of the seeds. CORDIAL, BILIOUS, (CHAMBER- LAIN'S.) An American medicine, prepared from the inner bark of the juglans cinerea, mixed with spices. CORDIAL FOR CALVES. Prep. I. Car- aways, powdered, £ oz.; ginger and carbonate of soda, of each a spoonful; gin or brandy, | of a wineglassful; water 6 oz. II. Brandy £ oz.; cow's urine 4 oz.; mix. (Gray.) Use. As a stimulant for looseness, &c, in calves. CORDIAL, CARAWAY. Prep. Bruised caraway seeds 3 lbs., or, essential oil of caraway 1£ oz.; sugar 56 lbs.; clean spirit, at proof, 40 gallons ; water q. s. Remarks. The addition of 30 drops of oil of cas- sia, and 20 drops each of essence of lemon and orange-peel, to the above quantity, improves the flavor; also a larger quantity of sugar must bo used, if the cordial is to be much lowered. II. Seeds $ lb., or oil 1 drachm; proof spirit 1 gallon ; sugar 3 lbs.; water q. s. As last. CORDIAL, CEDRAT. Prep. I. Essence of cedrat \ oz.; dissolve in pure proof spirit 1 gallon; add water 3 pints, agitate well ; draw off 3 quarts, and add an equal measure of clarified sirup. Remarks. This is a most delicious cordial. II. Cut 12 lemons in pieces, and digest in spirit of wine 1 gallon; add water 1 quart; draw off 1 gallon, and add an equal weight of capillaire. In- ferior to the last. CORDIAL, CINNAMON. This is seldom made with cinnamon, but with either the essential oil, or bark of cassia. It is preferred colored, and therefore may be very well prepared by simple di- gestion. If the oil be used, 1 dr. will be found to be enough for 2 or 3 gallons of spirit. The addi- tion of 2 or 3 drops each of essence of lemon and orange peel, with about a spoonful of essence of cardamoms to each gallon, will improve it. Some persons add to the above quantity 1 drachm of cardamom seeds and 1 oz. each of dried orange and lemon peel. 1 oz. of oil of cassia is considered to be equal to 8 lbs. of the buds, or bark. If wanted dark it may be colored with burnt sugar. The quantity of sugar is 1 *j lb. to the gallon. CORDIAL, CITRON. Prep. Yellow rind of citrons 3 lbs.: orange peel 1 lb. ; nutmegs bruised 2 oz.; proof spirit 13 gallons; distil ,.1 nacerate, add water sufficient, and 2 lbs. of fine lump sugar, for every gallon of the cordial. CORDIAL, CLOVE. Prep. Bruised cloves 1 oz., or essential oil, 1 dr. to every 4 gallons of proof spirit. If distilled it should be drawn ovei with a pretty quick fire. It is preferred of a very deep color, and is therefore strongly colored with poppy-flowers or cochineal, or more commonly with brandy coloring, or red sanders wood. It should have 3 lbs. of sugar to the gallon, and this need not be very fine. The addition of 1 drachm of bruised pimento, or 5 drops of the oil for every ounce of cloves, improves this cordial. CORDIAL, CORIANDER. Prep. 1 lb. of coriander seeds; 1 oz. of caraways, and the peel and juice of 1 orange to every 3 gallons of proof spirit. CORDIAL, GOLD. Prep. Angelica root, sliced, 1 lb.: raisins £ lb.; coriander seeds 2 oz.; caraway seeds and cassia, of each 1£ oz.; cloves £ oz.; figs and sliced liquorice root, of each 4 oz.; proof spirit 3 gallons; water 1 gallon. Digest 2 days, and draw off 3 gallons by a gentle heat; to this add 8 lbs. of sugar dissolved in 1 quart each of rose-water and clear soft water, and stee;; 1$ oz. of hay saffron in the liquid until it acquires a proper color. Remarks. The above is the form for a cordial once in much esteem, and which derived its name from a small quantity of gold leaf being added to it It is now but little drunk, and this addition seldom made. CORDIAL, GODFREY'S. Prep. I. Mo- lasses 15 lbs.; distilled water 2| gallons; dissolve; add oil of sassafras 1 oz. dissolved in rectified spirit of wine £ gallon, bruised ginger J oz.; cloves £ oz.; laudanum 8 oz.; macerate for 14 days, and strain through flannel. COR 221 COR II. Sassafras chips 1 lb.; ginger bruised 4 oz.; water 3 gallons; simmer until reduced to 2 gal- lons; then add treacle 16 lbs., rectified spirits 7 pints, and laudanum 1 pint. III. Opium £ oz.; treacle 5 lbs.; boiling water 1 gallon; dissolve, and add.rectified spirit £ pint; oil of sassafras £ dr.; cloves, mustard seed, of each -J oz.; corianders and caraway seeds, of each 1 dr.; digest for a week. IV. Caraway, corianders, and aniseed, of each 1 lb.; water 6 gallons; distil 5 gallons, and add treacle 28 lbs.; mix, then, add laudanum 1 quart, and oil of sassafras 1 oz. previously dissolved in rectified spirit 1 gallon. Remarks. The above forms are those commonly current in the drug trade. This cordial is anodyne and narcotic, and is commonly given to children troubled with wind or colic. Its frequent and ex- cessive use has sent many infants prematurely to the grave. Gray says, " It is chiefly used to pre- vent the crying of children in pain or starving." The dose is £ of a teaspoonful and upwards, ac- cording to the age of the child. CORDIAL, GOUT. Prep. Rhubarb, senna, coriander seed, sweet fennel seed, and cochineal, of each 2 oz.; liquorice root and saffron, of each 1 oz.; raisins 2£ lbs.; rectified spirit of wine 2 gal- lons ; digest for 14 days. Used in gout and rheu- matism. Dose. 1 tablespoonful to £ oz. It is aromatic and slightly laxative. • CORDIAL, HORSE. Prep. Compound tinc- ture of benzoin 1 pint; compound spirit of ammo- nia, and sweet spirits of nitre, of each 8 oz.; mix ; put it up in Bateman's bottles, and seal them. CORDIAL LEMON. Prep. Digest 2 oz. each of fresh and dried lemon peel, and 1 oz. of fresh orange peel in 1 gallon of proof spirit for a week ; strain with expression, add clear soft water to reduce it to the desired strength, and lump su- gar, in the proportion of 2£ lbs. to 3 lbs. to the gal- lon. The addition of a little orange-flower or rose- water improves it. CORDIAL, LOVAGE. Prep. Fresh roots of lovage 2 oz.; fresh roots of celery and sweet fen- nel, of each 1 oz.; essential oil of caraway \ oz.; proof spirit 3 gallons; digest for 7 days, add wa- ter 1 gallon ; distil off 2£ gallons; add water to make it of the desired strength, and sweeten with loaf sugar. To the above ingredients some per- sons add, before distillation, £ oz. of fresh valerian root, and 1 drachm of oil of savine. CORDIAL, NERVOUS. (Brodum's.) Prep. Tinctures of gentian, calumba, cardamoms, and cinchona, compound spirits of lavender, and steel vine, of each equal parts. Tonic and stomachic. CORDIAL, ORANGE. Like lemon cordial. £ lb. fresh orange peel to the gallon. CORDIAL, PEPPERMINT. Syn. Sports- man's Cordial. Eau de Chasseurs. Prep. Add English oil of peppermint 2 oz. to rectified spirit of wine 1 quart, agitate well in a corked bottle, ca- pable of holding 3 pints or more, then pour it into a cask having a capacity of upwards of 100 gal- lons ; add 36 gallons of perfectly white and fla- vorless proof spirit, agitate well for 10 minutes, then add 2 cwt. of the best refined lump sugar, previously dissolved in twice its weight of pure filtered rain water; rummage well, and further add sufficient clear rain water tc make up the whole quantity to exactly 100 gallons; again rum- mage well; add 2 oz. alum, dissolved in 1 quart of rain water, and a third time agitate for 15 min- utes, after which put in the bung and let it stand for a fortnight, when it will be fit for sale. Remarks. The above produces a beautiful arti- cle, provided the oil of peppermint be of good quality, the sugar double refined and stove-dried, and the cask one that will not give color. To ensure the first, the oil should be purchased of some known respectable dealer. That prepared at Mitcham, Surrey, and hence called " Mitcham oil of peppermint," is not only the strongest but best flavored, and though more than double the price of the foreign oil, is, in the long run, much the cheapest. The sugar should be sufficiently pure to dissolve in a wine glassful of clear soft water, without injuring its transparency, and the cask should be a fresh-emptied gin pipe, or one properly prepared for gin, as if it give color it will spoil the cordial. If these particulars be attended to, the product will be a clear transparent liquor as soon as made, and will not require fining; but should there be the slightest opacity, some alum may be added as above, which will clear it down. Some persons add more oil of peppermint, others less, than the quantity I have ordered, but this, as well as the weight of sugar, must depend upon the taste of the purchasers, and the price the liquor is to be sold at The product is 100 gallons of cor- dial at 64 u. p., which is the strongest usually sent out. A similar plan may be followed for the manu- facture of any other cordial liquor, the same prin- ciples and operations being common to all. CORDIAL, Sir WALTER RALEIGH'S. Syn. Sir W. Raleigh's Confection. Aromatic do. Prep. Fresh summits of rosemary and juni- per berries, of each 1 lb.; cardamom seeds, zedoa- ry, and saffron, of each £ lb.; proof spirit 1 £ gal- lons ; digest for a fortnight, express and strain; evaporate to 2£ lbs. and add Gascoigne's powder 1 lb.; cinnamon and nutmegs, of each 2 oz.; cloves 1 oz., white sugar 2 lbs., mix well together. Remarks. The above formula is that for the original aromatic confection. Sir Walter Ra- leigh's own receipt was far more complicated. CORDIAL, SPORTSMAN'S. Syn. Eau de Chasseurs. Prep. Peppermint water and recti- fied spirits of wine, of each 1 pint; lump sugar £ lb. Dissolve the sugar in the water and add it to the spirit. CORDIAL, WARNER'S. Prep. Rhubarb •jj; senna §iss; saffron 3j; liquorice root 3iv ; rai- sins lb. j; rectified spirit lb. iij: digest for a fort- night. Laxative. CORK. Syn. Corker. The lichen omphalodes made into balls. Used to dye wool. CORKS. The common practice of employing inferior corks for the purpose of stopping the mouths of bottles, is often productive of considera- ble loss, from the air being only partially excluded, and the contents suffering in consequence. I once saw a large " bin" of valuable wine become, in less than a year, little better than sour Cape, from the parsimony of its owner on this point, and I have frequently had to regret the loss of valuable chem- ical preparations from a similar cause. The best corks are those called " velvet corks," and of these the finest qualities are imported from France. COR 222 COR CORNS. Round, horny, cutaneous extuber- ances, with central nuclei, very sensitive at the base, arising from continued pressure over the pro- jection of the bones, from tight or stiff 6hocs or boots. Corns are of two kinds, hard and soft. The former grow on the exposed portions of the joints, the latter between the toes. Treat. First soak the feet in warm water for a few minutes, then pare the corns as close as possi- ble with a sharp knife, taking care not to make them bleed. They may now be touched over with a little lunar caustic, or nitric acid. The for- mer is used by merely rubbing it on the corns, previously slightly moistened with water ; the lat- ter by moistening them with it, by means of a strip of wood, or preferably a rod of glass. This treat- ment adopted every other day for 10 or 12 days, accompanied by the use of soft, loose shoes, will generally effect a cure. Concentrated acetic acid may be used instead of nitric acid, and is preferred by some persons from not staining the skin, but it is less active, and requires to be more frequently applied. It has been recommended to remove large corns by ligatures of silk, applied as close to the base as possible, and tightened daily un- til they drop off; but this plan is tedious, and is not always successful. Another mode of extirpa- tion is the application of a small blister, which will frequently raise them with the skin out of their beds. In this case the exposed surface must be dressed with a little simple ointment. Soft corns may also be easily removed by applying ivy leaf previously soaked in strong vinegar, changing the piece every morning; or by placing a dressing of soap cerate, spread on a bit of lint or old rag, be- tween the toes. One of the simplest and best rem- edies for hard corns, and which has lately received the sanction of high medical authority, is to wear upon the toe or part affected a small circular piece of soft leather, or still better, a piece of amadou, spread with diachylon or other emollient plaster, and having a hole cut in its centre the size of the corn. (Sir B. Brodie.) By this means the pressure of the boot or shoe is' equalized, and the corn pro- tected. Prevention. This consists in keeping the feet clean, by frequent ablutions with warm water, and the use of easy, soft shoes or boots. Without the latter precaution, corns will generally return, even after they appear to have been perfectly removed, CORNS, POPULAR REMEDIES FOR. I. (Lotion.) Sal ammoniac 1 oz., spirit 4 oz.; dissolve. Moisten the corn with this lotion every morning and evening. II. (Powder.) Savine leaves 2 oz.; verdigris 1 oz.; red precipitate £ oz.; all in powder. Mix. Ap- plied by means of a piece of rag to the corn nightly. III. (Plaster.) White diachylon and yellow rosin, of each 2 oz.; melt and add finely-powdered verdigris 1 oz. For use, spread it on paper, linen, or leather, and apply a small piece to the corn. CORN SOLVENT, SIR H. DAVY'S. Prep. Potash 2 parts, salt sorrel 1 part; each in fine powder. Mix and lay a small quantity on the corn for four or five successive nights, binding it on with a rag. CORRECTING PROOFS. (In Typography.) The operation of marking on the proof sheets of a work any errors of orthography, punctuation, ar- rangement, or language, they may contain, and also any alterations that may appear necessary. The following specimen will explain the method generally adopted for this purpose, and with a little attention will enable any person to superintend a work through the press, as far, at least, as de- pends upon the correction of the proofs: COR 223 COR 1 ■Ja 2 i> 3 >/ 4 »/ 5 ^V 6 4 7 Twm 8 fr 9 faf 10 fthfyj 12 Oft// 13 fa/ 14 ^e/ 15 KmonJ 16 •>l 17 1 .18 1V& 19 J/efi 20 Wff/iecr 21 ^ 22 l.c 23 Jm.orAj 24 25 Of 26 (jy a 27 °? 28 W [Proof.] As the vine, which has long twined its graceful foliage about the oak/ and been lifted by it into sunshine, will when the hardy plant is rift ed by the thunderOD°ll- cling round/ it with its caressing tendrils, and bind /\its shattered boughs up) so is it ^ordered ^beautifully^ by providence, that woman, who is the mere depend yfyLt and ornament of man in 4te* happier hours, should ^ his stay and solace. J (_ When smitten by sudden calamity/ winding herself ~ into the rugged recesses of his Mature, ten- derly supporting the droop- ing head , and binding up the broken heart. [ It also is ^interesting to notice how some minds seem almost to create themselves, springing up under ^, and working their solitary butjirresistible way, A through/a thousand obsta- cles / / Nature seems, &c. IRWING. __ewrte c/b/attfvtmfizGes The same corrected : As the vine, which has long twined its graceful foliage about the oak, and been lifted by it into sunshine, will, when the hardy plant is rifted by the thunderbolt, cling round it with its caressing tendrils, and bind up its shattered boughs, so is it beautifully ordered by Providence, that WOMAN, who is the mere dependant and ornament of man hi his happier hours, should be his stay and solace when smitten by sudden calamity; winding herself into the rugged recesses of his nature, ten- derly supporting the drooping head, and binding up the broken heart. It also is interesting to notice how some minds seem almost to create themselves, springing up under every disadvantage, and working their " sol- itary but irresistible way," through a thousand ob- stacles. Nature seems, &c Irving. Explanation of the marks. 1. When a letter or word is to be in italics. 2. When a letter is turned upside down. 3. The substitution of a comma for another point or letter. 4. The insertion of a hyphen ; also marked -/ 5. When letters should be close together. 6. When a letter or word is to be omitted. 7. When a word is to be changed to Roman. 8, 9. Two methods of marking a transposition ; when there are several words to be transposed, and they are much intermixed, it is a common plan to number them, and to put the usual mark in the margin. 10. Substitution of a capital for a small letter. 11. When a word is to be changed from small letters to capitals. 12. The transposition of letters in a word. 13. The substitution of one word for another. 14. When a word or letter is to be inserted. 15. When a paragraph occurs improperly. 16. The insertion of a semicolon. 17. When a space or quadrat stands up, and is seen along with the type. 18. When letters of a wrong fount are used. 19. When words crossed off are to remain. 20. The mark for a paragraph, when its com- mencement has been neglected. Sometimes the sign [, or f, or the word " break," is used, instead of the syllables " New Par." 21. For the insertion of a space when omitted. 22. To change capitals to small letters. 23. To change small letters to small capitals. 24. When lines or words are not straight. 25, 26. The insertion of inverted commas. The apostrophe is similarly marked. 27. The insertion of a period when omitted, or in place of another point or letter. 28. Substitution of one letter for another. 29. The method of marking an omission or in- sertion when too long for the side margin. COS 224 COU CORROSION, PREVENTION OF. The best means of preventing the corrosion of metals is first to dip the articles into very dilute nitric acid, and afterwards to immerse them in linseed oil, al- lowing the superfluity of oil to drain off; they are by this means very effectively preserved from rust or oxidation. (W. J. Lander.) COSMETICS. (Cosmetica, from Koo-//fa>, / adorn.) Any external application used for the purpose of preserving or restoring the beauty. The term is generally understood to refer to sub- stances applied to the cuticle, to improve the color and clearness of the complexion; but some wri- ters have included under this head, every topical application to promote the personal appearance. Hence cosmetics may be divided into three kinds, viz.:—Cutaneous cosmetics, or those applied to the skin ; hair cosmetics, or such as are employed to promote the growth and beauty of the hair ; and teeth cosmetics, or such as are used to cleanse and beautify the teeth. The present article will be confined to a short notice of the first of these divisions, referring the reader to the separate heads —hair dyes, pomatums, pommades, depilatories, dentifrices, tooth powders, fyc, for infonr.ation respecting the remainder. Cutaneous Cosmetics. The most simple and universally employed cosmetics are soap and wa- ter, which at once cleanse and soften the skin. Soap containing a full proportion of alkali, exer- cises a solvent power upon the cuticle, a minute portion of which it dissolves ; but when it contains a small preponderance of oily matter, as the prin- cipal part of the milder toilet soaps now do, it mechanically softens the skin and promotes its smoothness. Almond, Naples, and Castile soaps are esteemed for these properties, and milk of roses, cold cream, and almond powder, (paste,) are used for a similar purpose. To produce an opposite effect, and to harden the cuticle, spirits, astringents, acids, and astringent salts are com- monly employed. The frequent use of hard wa- ter has a similar effect. The application of these articles is generally for the purpose of strengthen- ing or preserving any given part against the action of cold, moisture, &c.; as the lips, or mammas, from chapping, or the hands from contracting chil- blains; but in this respect, oils, pommades, and other oleaginous bodies, are preferable. Another class of cutaneous cosmetics are em- ployed to remove freckles and eruptions. Among the most innocent and valuable of these, is Gow- Iand's lotion, which has long been a popular arti- cle, and deservedly so, for it not only tends to im- part a delightful softness to the skin, but is a most valuable remedy for many obstinate eruptive dis- eases, which frequently resist the usual methods of treatment. Bitter almonds have been recom- mended to remove freckles, (Celsns,) but moisten- ing them with a lotion made by mixing I oz. of rectified spirit of wine, and a teaspoonft/ of mu- riatic acid, with 7 or 8 oz. of water, is said to do this more effectually. A safe and excellent cos- metic is, an infusion of horseradish in cold milk. (Withering.) Skin paints and stains are employed to give an artificial bloom, or delicacy to the skin. Rouge and carmine are the articles most generally used to communicate a red color. The former is the only cosmetic that can be employed, without in jury, to brighten a lady's complexion. The latter, though possessing unrivalled beauty, is apt to im- part a sallowness to the skin by frequent use Starch powder is employed to impart a white tint, and is perfectly harmless. The American ladies who are very fond of painting their necks white, use finely-powdered magnesia, which is another very innocent substance. Several metallic com- pounds, as trisnitrate, subchloride, and oxide of bismuth, (pearl white, Fard's white, &c.,) carbo- nate of lead, (flake white,) white precipitate, &c, are frequently used to revive faded complexions; but they are not only injurious to the skin, but act as poisons, if taken up by the absorbents. Tris- nitrate of bismuth, (pearl white,) probably the least injurious of these articles, has caused spas- modic tremblings of the muscles of the face, end- ing in paralysis. (Vogt. Pharm.) The employment of liquid preparations, containing sugar of lead, which are commonly sold under the name of milk of roses, cream of roses, &c., is equally injurious. Another disadvantage of these white metallic preparations is, that they readily turn black, when exposed to the action of sulphureted hydrogen gas, or the vapors of sulphur, which frequently escape into the apartment from coal fires. There are many instances recorded, of a whole company being suddenly alarmed, by the pearly complexion of one of its belles being suddenly transformed into a sickly gray or black. A friend of the wri- ter's was once startled at a Christmas party by observing the one side of a lady's face and neck, which was exposed to the fire, become discolored in this way, and was so amused on learning the cause, that he has since played two or three jokes of the kind on some petulant old ladies, remark- able for the great attention they pay to their toi- let. In conclusion it may be remarked, that the best purifiers of the skin are soap and water, followed by the use of a coarse cloth, in opposi- tion to the costly and soft diapers that are com- monly employed; and the best beautifiers, are health, exercise, and GOOD TEMPER. COSMETIC, SIMPLE. Prep. Soft soap J lb.; melt over a slow fire with a gill of sweet oil, add half a teacupful of fine sand, and stir the mixture together until cold. The shelly sea-sand, sifted from the shells, has been found better than that which has no shells. Remarks. This simple cosmetic has, for several years past, been used by many ladies who are re- markable for the delicate softness and whiteness of their hands, which they, in a great measure, attribute to the use of it. Its cheapness is a strong recommendation. COUGH. The sudden and violent expulsion of air from the lungs. It is generally sympto- matic of other affections, but is sometimes idiopa- thic. Many cases of cough depend upon the ex- tension of catarrh to the trachea and bronchia, which thus become loaded with mucus or phlegm, which they endeavor to throw off by the convul- sive effort called coughing. In some cases it is caused by a vitiation and inspissation of the secre- tions, arising from the imperfect action of the ab- sorbents; this is the common cause of the dry cough of old people. Idiopathic cough is not con- sidered dangerous in itself, or while running it* COW 225 COW regular course, but it is often productive of most serious consequences, by superinducing the inflam- mation of some organ, or laying the foundation of phthisis. Cough is sometimes attended by copious expec- toration, and at other times exists without any ; it has hence been distinguished into moist or mucous cough, and dry cough. Treat. The treatment of common catarrhal cough consists in allaying the irritation as much as possible, by demulcents and expectorants, as mucilaginous drinks and lozenges, which act upon the glottis, and sympathetically upon the trachea and bronchia?. Among the first may be men- tioned, almond milk, barley water, refined Spanish juice, gum arabic, and a mixture of the last two made into lozenges; among the second, the most innocent and convenient is ipecacuanha, in the shape of lozenges, 2 or 3 of which may be sucked whenever the cough is troublesome. A light diet should be adopted, the bowels kept slightly re- laxed by mild aperients, and a mild and equable temperature sought as much as possible. When this plan does not succeed, recourse may be had to an emetic, followed by small doses of Dover's powders, and extract or tincture of henbane, or squill pill. When a cough is troublesome at night, and unattended with fever, a small dose of lauda- num, or tincture of henbane, taken on going to rest, will generally procure sleep. In the treat- ment of dry cough the more stimulating expecto- rants are useful, as garlic, ammoniacum, styrac, and benzoin, combined with narcotics and seda- tives, as henbane, hemlock, and opium. A dia- phoretic opiate is also very useful, especialiy in the cough of old people. COUGH, POPULAR REMEDIES FOR. I. (Draughts.) a. Sirup of poppies 1 dessert- spoonful ; antimonial wine 20 drops ; mix for a dose, to be taken in a little warm tea on going to bed. 6. Laudanum 30 drops; vinegar and honey, of each, a dessert-spoonful; ipecacuanha wine 25 drops ; mix for one dose, as last. II. (Emulsion.) Milk of almonds 4 oz.; sirup of squills and tolu, of each, 1 oz.; mix. Dose. A tablespoonful every 2 hours. III. (Mixtures.) a. Tincture of tolu \ oz.; Daregoric elixir and tincture of squills, of each, £ oz. ; sirup of white poppies 1 oz. ; mix. Dose. 1 teaspoonful in barley water, whenever the cough is troublesome, b. Milk of ammoniacum 4 oz.; sirup of squills 2 oz.; mix. A tablespoonful 3 or 4 times daily, for the cough of old persons, c. (Dr. Munro's.) Paregoric £ oz.; sulphuric ether and tincture of tolu, of each, \ oz.; mix. Dose. A teaspoonful night and morning, or when the cough is troublesome, in a little warm water, d. (Dr. Radcliff's.) Sirup of poppies, sirup of squills, and paregoric, of each, £ oz.; mix. Dose. As last. COUMARIXE. The fragrant volatile princi- ple of the tonka bean, the diptera odorata of Wil- denow. It is dissolved out by ether, and purified by alcohol. It crystal izes in small prisms. COWHAGE. Syn. Cowitch. Dolichis pubes. The down which grows upon the pods of the mu- cuna pruriens. (Dolichos pruriens.) It occasions violent itching, when it comes in contact with the skin, which can only be allayed by a solution of 29 given vitriol or oil. It is frequently administered as a vermifuge, made into a confection, by scraping the hair off a pod into treacle, sirup, or honey, for a morning dose, which is repeated for 3 or 4 suc- cessive days, followed by a brisk purge. COWS, MILCH, (CHOICE OF.) As to a choice of breeds for a private family, none in Eng- land, (says Mr. Lawrence,) probably combine so many advantages as the Suffolk dun-cows. They excel both in quantity and quality of milk ; they feed well after they become barren ; they are small- sized, and polled or hornless; the last a great con- venience. The horns of cows which butt and gore others, should be immediately broad tipped. There is a breed of polled Yorkshire, or Holderness cows, some of them of middling size, great milkers, and well adapted to the use of families, where a great quantity of milk is required, and where price is no object, and food in plenty. If richer milk and a comparison of the two famous breeds be desired, one of each may be selected, namely, the last men- tioned, and the other of the midland county, or long-horned species. Color is so far no object, that neither a good cow nor a good horse can be of a bad color; nevertheless, in an ornamental view, the sheeted and pied stock of the Yorkshire shorthorns make a picturesque figure in the' grounds. The Alderney cows yield rich milk upon less food than larger stock, but are seldom large milk- ers, and are particularly scanty of produce in the winter season. They are, besides, worth little or nothing as barreners, not only on account of their small size, but their inaptitude to take on fat, and the ordinary quality of their beef. Feeding. There is nothing equal to rich pastu- rage for milch cows, but at such seasons, and du- ring such weather that this cannot be procured, good hay, with turnips, carrots, potatoes, or man- gel-wurzel, must be given instead, along with a sufficient quantity of clean water. The principal cowkeepers of the metropolis have dairy-farms in the suburbs, where the animals are turned out a portion of every day in the year, except during heavy rains, or when the ground is covered with snow. They are also well supplied with brewers' grains, tares, beet-root, &c, and great care is taken that they get fresh air, and exercise suffi- cient for their health. Such cows yield a large quantity of wholesome milk, very different to much that is sold in London, obtained from cows kept in stables, cellars, and other confined situations, and which are seldom supplied with green food. It has lately been shown by Boussingault, that man- gel-wurzel, so commonly used for feeding cattle, is insufficient as an article of food. He found that a cow fed. on this substance ceases to give her usual quantity of milk, and that even when other food was given along with it, the animal yielded less than her ordinary quantity. Before giving turnips to cows, the rotten or bad ones should be picked out, as it is said that even the presence of a sin- gle damaged one will flavor the milk, and perhaps spoil a whole dairy of cheese or butter. Economy of a cow. The annual consumption of food per cow, if turned to grass, is from an acre to an acre and a half in the summer, and from a ton to a ton and a half of hay in the win- ter. A cow may be allowed 2 pecks of carrota CRA 226 CRA per day. The grass being cut and carried, will economize it full £. The annual product of a good fair dairy cow, during seven months after calving, and either in summer or winter, if duly fed and kept in during the latter season, will be an average of 7 lbs. of butter per week, from 3 to 5 gallons of milk per day. Afterwards, a weekly average of 3 or 4 lbs. of butter from barely half the quautity of milk. It depends on the constitution of the cow, and how nearly she may be milked to the time of her calving, some giving good milk until within a week or two of that period, others re- quiring to be dried 8 or 9 weeks previously. I have heard (says Mr. Lawrence) of 20 lbs. of butter, and even 22 lbs., made from the milk of 1 long- horned cow in 7 days; but I have never been for- tunate enough to obtain one that would produce more than 12 lbs. per week, although I have had a Yorkshire cow which milked 7 gallons per day, yet never made 5 lbs. of butter in one week. On the average, 3 gallons of good milk will make 1 lb. of butter. CRACKNELS. Prep. Mix a pint of flour with a little grated nutmeg, the yelks of 2 eggs, 2 or 3 spoonfuls of rose-water, and cold water suffi- cient to make a paste ; then roll in £ lb. of butter, and make it into shapes. In 1 hour put them into a kettle of boiling water, and boil them until they swim, then throw them into cold water ; take them out, and when dry bake them on tins. CRACKNUTS. Prep. Flour 1 lb.; sugar | lb. ; melted butter £ lb.; 6 or 7 eggs, well beaten ; make a paste with a glassful of raisin wine and a little water ; add caraways, roll it out as thin as paper, cut it into shapes with a tumbler, wash the pieces with the white of egg, and dust them over with powdered sugar. CRAMP. Spasmodic or involuntary contrac- tions of the muscles, generally of the extremities, accompanied with great pain. The muscles of the legs and feet are those most commonly affected with cramp, especially after great exertion. The best treatment is immediately to stand upright, and to well rub the part with the hand. The ap- plication of strong stimulants, as spirits of ammo- nia, or of anodynes, as opiate liniments, has been recommended. When cramp occurs in the stom- ach, a teaspoonful of sal volatile in water, or a dram glassful'of sfood brandy, should be swallowed immediately. When cramp comes on during cold bathing, the limb should be thrown out as sudden- ly and violently as possible, which will generally remove it, care being also taken not to become flurried nor frightened ; as presence of mind is very essential to personal safety on such an occasion. A common cause of cramp is indigestion, and the use of acescent liquors ; these should be avoided, and bitters and absorbents had recourse to. CRAYONS. Small cylinders or pencils of coloring substances, used for drawing upon paper, &c. Prep. Crayons are commonly prepared by mix- ing up the color with some substance that will dilute it to a proper shade, and give it the neces- sary softness and tenacity to adhere readily to pa- per, when rubbed against it. The cylindrical form is generally given to them by means of a cylinder of 2 or 3 inches diameter, having one end open, and the other firmly secured to a perforated plate, having holes of the same size as the intended cray- ons. The crayon-composition, in the state of n stiff paste, is introduced into tho open end, and is driven down and through the holes, by means of a small plug or piston, that exactly fits the inside of the cylinder. To impart an equable motion, whicJo is essential to the formation of well-shaped crayons, a small screw is employed. The pieces that pass through the holes are cut into lengths and dried All the materials employed in making crayons are previously reduced to the state of an impalpable powder, and those that are gritty are elutriated or washed over. The following are among the best formula? for making crayons: I. Spermaceti 3 oz.; boiling water 1 pint; agi- tate together till they form a species of emulsion, with which mix up bone ashes 1 lb., (previously reduced to an impalpable pow.wr,) and coloring matter as much as is required to give the proper tint. When half dry form the mass into crayons. II. Pipeclay, and the finest prepared chalk, equal parts; or pipeclay alone, q. s.; coloring a sufficient quantity. Make them into a paste with pale mild ale. III. (Process of the brothers Joel, of Paris.) Shellac 3 parts ; spirits of wine 2 parts; oil of turpentine 1 part; coloring matter,and blue clay, of each 6 parts. The shellac is dissolved in the spirit, and well mixed by trituration with the clay, (previously elutriated and dried,) the colored pow- der, and the turpentine; the mass is then made into crayons, which are dried by a stove heat. IV. White curd or Castile soap, cut into thin shavings, 1 oz.; boiling water 1 pint; dissolve, and when cold add gradually as much rectified spirit of wine as will barely render the liquid transparent With this fluid make the coloring matter into a paste, along with £ its weight each of the finest elutriated clay and chalk. V. Shellac 5 parts; wood naphtha 10 parts; dissolve, and with this fluid mix up the coloring powder, previously stirred up with an equal weight of fine blue clay. Dry the crayons by a stove heat. If this process be well managed, it will produce crayons equal to those of the best Parisian houses. VI. (Colored crayons.) Crayons may be made of any color or shade, by employing suitable pig- ments, and diluting them with a proper quantity of elutriated or prepared chalk. White crayons are made of this substance, by simply combining it with a suitable quantity of pure clay, or by mix- ing it up in either of the ways just described. Black crayons are made of prepared blacklead, ivory-black, lamp-black, &c. Black chalk is fre- quently made into crayons by simply sawing it into suitably-sized pieces. Red crayons have, as their coloring ingredients, carmine, carminated lakes, vermilion, and any of the earthy or mineral colors commonly used as pigments. General Lo- met has proposed, as a superior red cravon, the softest hematite, elutriated, drjed, and made into a paste with water holding in solution a little gum and soap. Blue crayons aro made of indigo, smalts, Prussian blue, verditer, &.c. Green crayons of a mixture of king's yellow, or yellow ochre, with blues. Yellow crayons of kin must then be heated to the boiling point, by which time the stopper will in most cases be loosened by the pressure of the air confined within the vessel, which will be greatly expanded by the heat. This plan should, however, never be adopted but as a last resource, as if the vessel be not sufficiently strong to resist the internal pres- sure, it must of course be broken. A piece of cloth should be tied over the stopper, in 6iich a way as to permit it to become well loosened, but to prevent it being blown out, because in the lat- ter case it would most likely be broken on falling to the ground. DECARBONIZATION. This operation is performed on cast iron, to convert it into steel or soft iron. The articles to be decarbonized are packed in finely-powdered hrematite, or native oxide of iron, to which iron filings are often added, | and exposed for some time to a strong red heat, by which the excess of carbon is abstracted or burnt out. The process somewhat resembles an- nealing or cementation. DECOCTION. Syn. Decoction, (Fr.) Ab- kochung, (Ger.) Decoctum, (Lat.) From decoquo, to boil. (In Pharmacy.) An aqueous solution of the active principles of vegetables, obtained by boiling. (In Chemistry.) A continued ebullition with water, to separate such parts of bodies as are only soluble at the boiling temperature. The effect of boiling water differs greatly from that of infusion. At the heat of 212°, the i-sen- tial oils and aromatic principles of vegetables are dissipated or decomposed ; while by infusion in hot water, in covered vessels, they remain for tha DEC 237 DEC most part uninjured. The solvent powers of boil- ing water are, however, much greater than those of hot water ; and many vegetable principles scarcely acted on by the latter, are freely soluble in the former. This is the case with many of the alkaloids, on which the medicinal virtues of several vegetables, depend. On the other hand, it must be recollected that the solutions of many sub- stances, though more readily made by boiling, are speedily weakened or rendered inert by ebullition, in consequence of the active principles being either volatilized along with the steam, or oxidized, or decomposed by exposure to the atmosphere. This is particularly the case with substances abounding in extractive or astringent matter. When the medicinal properties of vegetables are volatile, or arc injured by a strong heat, infusion should be had recourse to, in preference to boiling; but when a solution of the fixed constituents is alone sought, decoction is preferable. In preparing com- pound decoctions, those ingredients should be boil- ed first which least readily impart their active principles, and those which most readily impart them should be added afterwards. In many cases it will be proper simply to infuse the more aromatic subs.^.^ces in the hot decoction of the other in- gredients, by which means their volatile principles will be preserved. Some of the preparations in the pharmacopoeias are injudiciously ordered to be boiled, while others that would not suffer by ebul- lition u'jjng with water, are directed to be infused. As examples of the former, may be mentioned the compound decoctions of aloes, chamomile, and sarsaparilla, and the simple decoctions of mezereon, cinchona bark, &c.; as examples of the latter, the infusions of quassia and rhatany may be no- ticed. For making decoctions, the substances should be well bruised, or reduced to a very coarse pow- der, or, if fresh and soft, they should be sliced small. In the former case, any very fine powder or adhering dust should be removed with a sieve, as its presence would tend to make the product thick and disagreeable, and also more troublesome to strain. The vessel in which the ebullition is conducted should be furnished with an accurately fitting cover, the better to exclude the air; and the application of the heat should be so conducted that the fluid may be kept " simmering," or only gently boiling, as violent boiling is not only quite unnecessary, but absolutely injurious. In every case the liquor should be strained while hot, but not boiling, and the best method of doing this is to employ a fine hair sieve, or a coarse flannel bag. In general it is found, that as decoctions cool, a sediment is formed, in consequence of the boiling water dissolving a larger portion of vege- table matter than it can retain in solution when cold. This deposite for the most part consists of the active principles of the solution, and should be mingled with the clear liquid by agitation, when the decoction enters into extemporaneous compo- sitions, or when the dose is taken. It will thus be seen that the common practice of leaving the filtration until the liquid has become cold, and also of rejecting the sediment, is injudicious, and should be scrupulously avoided ; as, however, much decoc- tions so prepared may please the eye, they are not only inferior in strength, but, in many cases, nearly inert It may be further remarked, that long boiling is in no case necessary, and should be avoided, especially in decoctions prepared from aromatic vegetables, or those abounding in extrac- tive. The colleges, in such cases, direct the in- gredients " to be boiled for a short time," (P. D Art. Dec. Chamomeli Co.;) or "for 10 minutes," (P. L. Art. Dec. Cinchona-;) or they limit the period of the ebullition by stating the quantity that must be volatilized, as—" boil to a pint, and strain," (P. L. Art. Lee. Cetraria?;) the latter method being generally employed for those substances that do not suffer by lengthened boiling. Distilled water, or perfectly clean rain water, should alone be used for decoctions. Spring and river water, from containing lime, have less solvent powers. The aqueous solutions of organic matter, from the nature of their constituents, rapidly ferment, or putrefy. Vegetable substances, from ..bounding in sugar and starch, mostly undergo the former change, and this takes place, under common cir- cumstances, after the lapse of only a few hours. At the ordinary temperature of the atmosphere, neither decoctions nor infusions are fit to be used in dispensing, unless made the same day; they should, consequently, be only prepared in small quantities at a time, and any unconsumed portion should be rejected. Some of these preparations will keep for 48 hours, in temperate weather, but as the ingredients are mostly of little value, and the menstruum (water) valueless, it would be im- prudent for the dispenser to risk his own reputation, and the welfare of the patient, by employing an article of dubious quality. It has of late years become a general practice for the wholesale houses to vend preparations un- der the name of " concentrated decoctions," which, with the exception of the compound decoc- tion of aloes, are stated to bo- of 8 times the phar- macopoeial strength; so that one drachm of these liquids, added to seven drachms of water, form ex- temporaneous decoctions, professedly resembling those of the pharmacopoeia. The decoction of aloes is made of only four times the usual strength, as the nature of its composition would not permit further concentration. I feel it to be, however, a bounden duty to the sick, to state, that such prep- arations are but very imperfect substitutes for the decoctions of the Colleges, and in the usual man- ner. The extreme difficulty of forming concen- trated solutions of vegetablo matter with bulky ingredients, too often leads to the omission of a portion of the materials, or to the practice of con- centrating the liquid by evaporation; in the first case, the strength is of course less than it should be, and in the second, the quality is injured, and perhaps the preparation is rendered nearly inert by the lengthened exposure to heat, and the con sequent volatilization or decomposition of its active constituents. The common practice of adding a considerable portion of spirit to these preparations, which is absolutely necessary to make them keep, is also objectionable, as, in many cases in which decoctions are prescribed, this article, even in small quantities, would have a prejudicial effect. Be sides, tho object in employing aqueous decoctions or infusions is to avoid the use of spirituous prepa- rations. Some concentrated decoctions have been DEC 238 DEC recently offered for sale which do not contain a particle of alcohol, being preserved by the addition of sulphurous acid, or the sulphite of lime ; but on lately examining a sample of one of these, I found it perfectly worthless; it possessed a strong odor of bark, but it contained barely a trace of cincho- nine. (See Concentration, Infusion, Essence, Extracts, Liquor.) DECOCTION, COOLING. Prep. Barley water 1 pint; muriatic acid 1 drachm; sirup or lump sugar to sweeten. Use. A common drink in putrid fevers, taken ad libitum. DECOCTION, DIAPHORETIC. Prep. De- coction of bark 1 pint; liquor of acetate of ammo- nia 4 oz.; aromatic confection 1 oz. Dose. 2 or 3 tablespoonfuls every 3 hours. DECOCTION FOR FOMENTATION. Syn. Decoctum pro Fomento, (P. L. 1788.) Prep. Leaves of southernwood, sea wormwood, and chamomile flowers, of each 1 oz.; laurel leaves £ oz.; water 5 pints ; boil, and strain. DECOCTION, MERCURIAL. Prep. Cor- rosive sublimate gr. j ; (dissolved in) spirits of wine 30 drops ; extract of sarsaparilla 3iij; decoction of sarsaparilla f ^viij; mix.' Dose. One large table- spoonful 3 times a day. DECOCTION OF ALOES. (COMPOUND.) Syn. Decoctum Aloes compositum, (P. L. & E.) Balsam of Life. Baume de Vie. Prep. I. Ex- tract of liquorice 3vij ; carbonate of potassa 3j; aloes, myrrh, and saffron, of each 3iss ; compound tincture of cardamoms f^vij; water 1£ pints. Boil the first five ingredients in the water, until the fluid be reduced to a pint, strain, cool, and add the tincture. (P. L.) Remarks. The preceding instructions, which are those of our Phunnacopceia, appear to be objec- tionable, as there cannot possibly be any advan- tage in boiling ther.«LilIVon, while by such an opera- tion the whole of its fr.ij'iunce is dissipated. A better plan is to macerate the saffron in the tinc- ture for a few days, previously to adding the latter to the decoction of tho other ingredients. After the tincture has been strained off from the saffron, the latter may be washed with a little water, to remove any adhering color and odor, and this may be added to the decoction. The addition of the tincture produces a deposite of mucilaginous and feculent matter, which has been dissolved out of the liquorice, for which reason some houses omit the latter altogether, and supply its place with an equal quantity of lump eugur, and a little coloring. By this method the liquid, after being once ren- dered fine by decanting or filtering, will continue so for any length of lime. The full quantity of saffron ordered by the College, is seldom used in making this preparation, a small fraction of it only being employed. The following formula is used by a wholesale London drug house, that does very largely in this article. II. Solazzi juice 1£ lb.; kali (carbonate of pot- assa) 3 oz.; aloes (hepatic) 4£ oz.; myrrh (small) 4 oz.; water 4£ gallons; boil to 3 gallons, strain through flannel, cool, and add 10 pints of com- pound tincture of cardamoms, that has been di- gested for 10 days on saffron, 1 £ oz.; mix well, and add essential oil of nutmeg 15 drops, oils of cassia and caraway, of er.ch 10 drops, and oils of cloves and pimento, of each 5 drops. Agitate well to- gether, and allow it to repose for a week, then de- cant the clear portion from the sediment, and pre- serve it in a cool place. DECOCTION OF ALOES, (CONCEN. TRATED COMPOUND.) In preparing thir article, there is considerable advantage in sulisti tuting sugar for the liquorice, as, if the latter be used, there is a large deposite from which the last portion of tho liquid is separated with difficulty The following form may be used with advantage. I. Lump sugar 8 oz.; burnt sugar coloring \ pint; carbonate of potash 2 oz. ; aloes, myrrh, and saffron, of each 3 oz.; compound tincture of car- damoms £ a gallon ; water 3 pints ; boil the firsl five in the water, until the liquid be nearly re- duced to one half; cool and add the tincture, pre- viously digested for a week, on the saffron ; then prooeed as directed in the last article. Remarks. The proportion of saffron usually employed in the drug trade for the above quantity, is £ oz.; and some fragrant oils are frequently ad- ded to bring up the smell, as before described. The high price of saffron, for some time past, has led many unprincipled persons to omit it altogether. Should it be preferred to use extract of liquorice, 14 oz. of solazzi juice must be added to the above, and the sugar and coloring omitted. Tho price at which many houses offer this preparation, is abso- lutely less than the bare cost of the ingredients or- dered by the College. I am in the habit of prepa- ring this article by digesting the aloes, myrrh, li- quorice, and pntassa, all reduced to powder, along with the saffron, in the tincture, for a fortnight, employing frequent agitation. In this case the proportion of the tincture in the above formula should be 5$ pints, and the water should be omit- ted. In this way a very odorous and beautiful preparation is produced, which has been much admired. DECOCTION OF APOCYNUM. Syn. De- coctum Apocyni. Prep. (Dr. Griscom.) Root of apocynum cannabinum and juniper berries, of each ^j ; water 3 pints; boil to 1 quart and strain. DECOCTION OF ASPARAGUS. .Syn. Dec. Asparagi. Prep, asparagus root §j; water lb. ij ; boil for 5 minutes and strain. DECOCTION OF AVENS. Syn. Dec Gei Urbani. Prep. (Thompson.) Avens root (herb bennet) §j» water 1 pint; boil for 15 minutes. DECOCTION OF BALLOTA LANATA. Prep. Leaves and flowers 2 oz.; water 2 lbs.; boil to 1 lb. and strain. Dose. 1 or 2 oz., 3 or 4 times a dav ; as a diuretic in dropsy. DECOCTION OF BARK. Syn. Dec. op Cinchona. I. (Dec. of Lanced-leaved Cinchona or Pale Bark. Decoctum Cinchona, P. L. 17b3, 1809, and lb:24. Dec. Cinchona. Lancifolia, P. L. 1836.), Prep. Lance-leaved cinchona bark, well bruised, §j; water, sufficient to leave 1 pint when strained; boil for 10 minutes, (P. L.) Be- fore dispensing or pouring out the dose, the sedi- ment should be shaken up with tho liquid, as it consists of the most active portion of the bark. II. (Decoction of Heart-leaved Cinchona oi Yellow Bark. Syn. Dec. Cinchona Cordifolia, P. L.) Prep. Heart-leaved cinchona, or yellow bark, bruised, 3x ; distilled water 1 pint; boil fot 10 minutes, and strain while hot. III. (Decoction of Oblong-leaved Cinchona or DEC 23U DEC Red Bark. Syn. Dec. Cinchona Oblongifolia, P. L.) As the decoction of yellow bark. Dose, fyc. Either of the above is given in doses of 1 to 2 oz., 3 or 4 times daily, as a tonic, stomachic, and febrifuge, where the stomach will not bear the administration of bark in powder, in cases of dys- pepsia, convalescences, &c. DECOCTION OF BARLEY. Syn. Barley Water. Plain ditto. Ao.ua Hordeata. Dec Hordei, (P. L.) Prep. Pearl barley §iiss; water 4£ pints. First wash the barley with some water, thou boil in £ pint of the water for a little time, throw this away, pour on the remaining 4 pints, boiling hot, boil down to 1 quartj and strain. DECOCTION OF BARLEY, COMPOUND. Syn. Barley Water. Pectoral Decoction. Ptisana communis. Dec. Hordei compositum, (P. L.) Prep. Barley water 1 quart; sliced figs and stoned raisins, of each §iiss ; liquorice root, sliced and bruised, 3v; water 1 pint; boil down to 1 quart, and strain. Remarks. Both the above are used as demul- cents in fevers, phthisis, strangury, &c, taken ad libitum. They are slightly laxative, and where Uiis would be an objection to their use, a few drops of laudanum may be added. Mixed with an equal quantity of decoction of bark, barley water forms an excellent gargle in cynanche maligna, (ulcer- ated 6ore throat,) and, with a like quantity of milk and a little sugar, a good substitute for the breast in dry-nursing infants. DECOCTION OF THE BLUE CARDI- NAL FLOWER. Syn. Dec Lobelle Syphili- tic*. Dec Lobelia. Prep. (P. C.) Root of the lobelia syphilitica 1 handful; water 12 lbs.; boil to 7 lbs., and strain. Remarks. This decoction is purgative, and was once thought to possess alterative virtues. It was strongly recommended by Swediaur, in certain com- plaints ; he gave half a pint at first twice daily, and afterwards 4 times a day, unless it acted too strongly on the bowels, when the frequency of the dose was diminished, or it was discontinued for 3 or 4 days, and then had recourse to again, until the cure was effected. It is now seldom employed. DECOCTION OF BROOM TOPS. Syn. Dec Spartii Cacumnium. Dec Scoparii. Prep. Tops of broom (cut small) 1 oz.; water 1 pint; boil to one half, and strain. As a diuretic in dropsy. DECOCTION OF BROOM, COMPOUND. Syn. Dec. Spartii Cacumnium co. Dec ^Sco- parii compositum, (P. L.) Prep. Broom tops, juniper berries, and dandelion root, of each §ss; water 1£ pint; boil to 1 pint, and strain. Remarks. The Edinburgh •preparation, in addf- tion to the above, contains 2£ drs. of cream of tar- tar, and is hence said to be preferable to that of the London Pharmacopoeia. Both the above are diuretic, and are chiefly administered in dropsy, especially ascites, (dropsy of the belly.) DECOCTION OF BURDOCK. Syn. Dec Bardan^e. Prep. (P. C.) Bardana root fvj; wa- ter 5 pints; boil to 3 pints, and strain. Use. As an alterative, a pint to a quart daily, or ad libitum, in all those cases in which sarsaparilla is recommended. ' DECOCTION OF BURNT SPONGE. Syn. Dec. SpoNGiiE. Deo. Sponqlk Ust^e. Prep. (Hufeland.) Burnt sponge (powdered) Jj; water 1 pint; boil a little, digest 12 hours, strain, and add of cinnamon water §ij. Remarks. Burnt sponge was once much recom- mended in scrofula, but has fallen into disuse. If it possesses any virtue, it must depend upon the very small quantity of iodine it generally con- tains. DECOCTION OF CABBAGE TREE BARK. Syn. Dec Geoffroy^e, (P. D.) Bark of the cabbage tree bruised § j ; water 1 quart; boi' t: one half, strain, and add ^ij of sirup of orange pee Uses, DECOCTION OF DANDELION. Syn. Dec Taraxaci, (P. D.) Prep. Fresh herb and root fiv; (gvii P. E.;) water lb. ij; (2 pints P. E.;) boil to one half, and strain. Remarks. This decoction is aperient, tonic, and stomachic. The dose is 2 to 3 oz. 2 or 3 times daily. Its virtue is increased by combination with saline medicines, as bitartrate of potassa, &c. The root has considerably the most virtue when duff up in autumn, as it is then full of milky juicd DECOCTION OF DEADLY NIGHT- DEC 240 DEC SHADE. Syn. Dec Digitalis. Prep. Dried eaves of deadly nightshade 3ij; boiling water 1 pint; macerate for half an hour, then gently boil for two minutes and strain. DECOCTION OF ELDER BARK. Syn. Dec Sambuci. Prep. I. (Sydenham.) Elder bark §j; water and milk, of each 1 pint; boil to a pint and strain. II. (Collier.) Elder bark Jj; water f £xvj; boil to £ a pint and strain. Dose, f §ij three times a day in dropsy and some cutaneous affections. DECOCTION OF ELECAMPANE, COM- POUND. Syn. Dec Inul* comp. Prep. (Ra- tier.) Elecampane root ^j "> hyssop and ground- , ivy, of each 3ij ; water 1 pint; boil \ of an hour, strain, and add of honey §ij. DECOCTION OF ERGOT OF RYE. Syn. Dec Ergot.e. Dec Secale Cornuti. Prep. (Pereira.) Ergot of rye 3j; water f ^vj ; boil for 10 minutes and strain. Dose. $ of the above re- peated everv half hour, until the whole be taken. DECOCTION OF ELM BARK. Syn. Dec Ulmi, (P. L.) Fresh elm bark bruised, ^iiss; dis- tilled water 1 quart; boil to a pint and strain. Uses, tj-c. Bitter, mucilaginous, and diuretic. It is given with advantage in herpetic eruptions. Dr. Lettsom states that he cured a case of lepra ichthyosis by means of elm bark.—? Dose. 4 to 6 oz. twice a day. DECOCTION OF ELM BARK, COM- POUND. Syn. Dec Ulmi comp. Prep. (Jef- frey.) Simple decoction of elm bark 8 pints; liquorice root, sassafras, and guaiacum chips, of each §j; mezereon root 3iij ; boil for 1 hour and DECOCTION OF GALLS. Syn. Dec Gal- LiE. Prep. I. Aleppo galls, bruised, £ oz.; water 1£ pint; boil to a pint and strain. II. Galls, bruised, £ oz.; water 2£ pints; boil to a quart, strain, cool, and add of tincture of gall 1 oz. Use, 6fC. As a fomentation, enema, or injec- tion, in prolapsus ani, piles, and leucorrhcea. DECOCTION OF WATERDOCK. Syn. Dec Rumicis. Prep. (A. T. Thomson.) Root of the common waterdock (Rumex Obtusifolius) §j; water 1 pint; boil for 10 minutes and strain. Uses, SfC. This decoction is astringent, and was once much celebrated as a remedy for scurvy and some other cutaneous diseases. " It is the only remedy which proves efficacious in that disease, when the ulcers are healed, and the patient is nttacked with asthma." (Linnreus, on the scurvy of the Laplanders.) DECOCTION OF GUAIACUM. Syn. De- coction of the Woods. Dec. Guaiaci, (P. E.) Prep. Guaiacum turnings Jiij; sassafras, rasped, (chips,) and liquorice root, bruised, of each §j ; raisins Jij; water 1 gallon ; boil the guaiacum and raisins w*ith the water down to 5 pints, adding the liquorice and sassafras towards the close; then DECOCTION OF GUAIACUM, COM- POUND. Syn. Dec of the Woods. Dec Guaiaci compositum, (P. D.) Prep. Guaiacum wood (rasped) 5»j 5 sassafras shavings 3x ; liquor- 'ce root, bruised, ^'ss; water 10 old wine pints. Boil the guaiacum in the water until the liquid be reduced to £, then add the liquorice and sassafras: boil a little longer and strain. Dose. A teacupful 3 or 4 times daily, or oftener, in chronic rheumatism, some cutaneous diseases, after a course of mercury, &,c. Its virtues are of a very dubious kind. DECOCTION OF HELLEBORE. Syn Dec Helebori Albi, (P. L. 1788.) Dec Vera tri, (P. L. 1836.) Root of white hellebore, bruised, 3x; water 1 quart; boil to one half, strain, and add rectified spirit of wine f ^iij- Use, tyc. As a wash, in itch, ringworm, leprosy, psoriasis, &c, either alone, or mixed with wato;, also to destroy vermin in the hair, &c. DECOCTION OF HEMEDESMUS IND1 CUS. Syn. Dec Hemedebmi Indici. Prxp (Pereira.) Hemedesmus root ^ij ; water 1£ pmt boii to 1 pint. Used in similar cases to sarsaparilla. Tt is d< urelic and tonic. DECOCTION OF IRISH MOSS. Syn Dec Condri. Prep. (Pereira.) Carrageen mo-s 1 oz.; macerate in lukewarm water for 10 min- utes, then boH in water 3 pints for 15 minutes, aid strain through linen, Remarks. Milk may be used instead of water., and if twice the above weight of moss be employed, a mucilage will be produced, which may be fla- vored with lemon juice, spices, &.c, and forms a most nutritious article of spoon-diet It is com- monly taken in pulmonary complaints, scrofula, chronic diarrhoea, cough, &c, and Is frequently employed in cookery, as a substitute for animal jelly, in the preparation of blancmanges, jellies, soups, &.c. DECOCTION OF JAMAICA DOGWOOD. Syn. Dec. Corni Florid.*. Prep. (Dr. Coxe.) Jamaica dogwood ^j 5 water f §xvj; boil for 20 minutes. DECOCTION OF JUNIPER BERRIES, (COMP.) Syn. Dec Juniperi comp. Prep. (St. B. H.) Juniper berries §ij ; cream of tartar 3iij ; water 4 pints; boil to a quart, strain, and add compound spirit of juniper f^ij. Diuretic. DECOCTION OF LIQUORICE. Syn. Dec GlycyrrhizjE, (P. D.) Prep. Bruised liquorice root ^iss ; water 1 pint; boil 10 minutes and strain. A mild demulcent; it is taken either alone, or is used as a vehicle for more aetive remedies. DECOCTION OF LIVERWORT. Syn. Dec of Iceland Moss. Dec. Lichems, (P. L. 1809 and 1824.) Dec Cetrari*, (P. L. 1636.J Prep. Liverwort 3v; water 1 £ pints ; boil down to a pint, and strain. Remarks. This is given in doses of 1 to 4 oz., three or four times a day, in pulmonary com- plaints, &c. The addition of vinegar, lemon juice, or sulphuric acid, barely enough to acidulate it, with a little sugar or sirup, has been highly rec- ommended. This preparation is intensely bitter and nauseous, when made according to the above : formula, but if the moss be soaked for a few hours in cold water before making the decoction, most of the bitterness will be extracted, while the other properties will remain uninjured. DECOCTION OF LOGWOOD. Syn. Dec. J HjEmatoxyli, (P. E. and D.) Prep. Logwood chips 5J> (3188 P* D.;) powdered cinnamon 3j; I water 1 pint, (2 old wine pints, P. D.;) boil to one- DEC 241 DEC half, adding the cinnamon towards the close of the operation, and strain. Use. Astringent and tonic. Dose. 1 to 4 or 5 tablespoonfuls, in diarrhoea. DECOCTION OF MALLOWS, COM- POUND. Syn. Common Decoction. Dec pro Enemate, (P. L. 1787.) Dec commune. Dec Malvas compositum, (P. L. 1836.) Prep. Mal- lows, dried, ^j j chamomile flowers, dried, 3s8 j water 1 pint; boil for 15 minutes, and strain. Use. For fomentations and enemas. DECOCTION OF MALT. Syn. Sweet- wort. Dec Malti. Prep. (Fr. H.) Barley malt 4 oz.; water 3 pints; boil for 10 minutes, add liquorice root 3j ; boil down to a quart, and strain. Demulcent; laxative. DECOCTION OF MARSHMALLOWS. Syn. Dec Altile.e, (P. D.) Prep. Dried root and herb of marshmallow S^iv *, raisins, stoned, §ij; water 7 pints, (wine measure;) boil down to 5 pints, strain, allow it to deposite the sediment, and decant the clear liquid. Use, <£c. It is demulcent. Dose. A cupful ad libitum, in coughs, colds, calculous affections, and other diseases of the urinary organs. DECOCTION OF MEZEREON. Syn. Dec Mezkrei, (P. D. and E.) Prep. Mezereon root, in chipe, 3ij; liquorice root, bruised, 5SS j water 1 quart, (3 old wine pints, P. D.;) gently boil to 1£ pint, (2 old wine pints, P. D.,) and strain. Dose, f ^iij to a teacupful, two or three times a day, in chronic rheumatism, scrofula, lepra, and some other cutaneous affections. Much boiling in- jures the virtues of mezereon. DECOCTION OF OAK BARK. Syn. Dec Quercus. Prep. Oak bark 3x; water 1 quart; boil to one-half, and strain. Uses, .anov as an anti-febrile. DECOCTION, VULNERARY. Syn. Dec Vulnerarium. Prep. (E. H.) Ground ivy, and broad-leaved plantain, of each $ss ; water 3 pints; boil to 1 quart, strain, and add sugar §ss. DECOCTION OF WALNUT BARK. Syn. Dec Juglandis. Prep. (P. Gen.) Green bark of walnuts ^j j water 1 pint; boil for 15 minutes and strain. DECOCTION OF WALL-PELLITORY. Syn. Dec Parietari^e. Prep. (Ratier.) Root of wall-pellitory ^j; water 1 £ pints; boil to 1 pint. DECOCTION OF WHORTLEBERRIES. Syn. Dec Uvas Ursi, (P. L.) Prep. Whortleber- ry leaves, bruised, ^j j water 1£ pints; boil to 1 pint and strain. Dose. 1 to 4 tablespoonfuls, in phthisis and pu- rulent affections of the urinary organs. DECOCTION OF WILLOW BARK. Syn. Dec Salicis. Prep. (Wilkinson.) Willow (salix latifolia) bark, bruised, fiss ; macerate in water lb. ij, for 6 hours, then boil for 15 minutes and strain. Tonic, astringent, and febrifuge. DECOCTION OF WOODY NIGHT- SHADE. Syn. Dec of Bitter-sweet. Dec Dulcamara, (P. L.) Prep. Stalks of the herb, sliced, 3x ; water 1£ pints; boil to 1 pint and strain. Dose. 1 to 3 oz. It is diaphoretic, diuretic, and narcotic, and is given in dropsy, asthma, and sev- eral scaly skin diseases. Its narcotic action may be obviated by the addition of £ an oz. of com- pound spirits of lavender. (Collier.) DECOCTION OF WORMSEED. Syn. Dec Santonici. Prep. Wormseed, bruised, §ij ; water 1 pint; boil down to f^xvj, and strain. Stomachic, vermifuge. It is principally used as an injection against ascarides. DECOCTION OF YELLOW MULLEIN. Syn. Dec Verbasci Thapsi. Prep. (Dr. Home.) Yellow mullein 5j '■> water 1 pint; boil for a short time. DECOLORATION. The blanching or loss of the natural color of any substance. Sirups, and many animal, vegetable, and salino solutions, are decolored or whitened by agitation with ani- mal charcoal, and subsequent subsidence or filtra- tion. Many fluids rapidly lose their natural color oy exposure to light, especially the direct rays of the sun. In this way, castor, nut, poppy, and several other oils, are whitened. By the joint action of light, air, and moisture, cottons and linens are commonly bleached. The peculiar way in which light produces this effect, has never been satisfactorily explained. That it is not de- pendent on the absorption of oxygen, appears evident, from the fact, that contact with air is not always necessary. I find that raw castor oil, ex- posed to the sun in a bottle closely corked, will whiten with as much rapidity as that in another similar sized bottle, placed beside it and left un- corked. There is, however, a small quantity of gaseous matter given off, which has an odor re- sembling carbureted hydrogen ; but in the open bottle, oxygen is continually absorbed, certain oily acids formed, and some impure carbonic acid evolved. When this action is permitted to go on for some time, the oil becomes thick and rancid, but may be partially restored to its former state, by filtration through coarsely-powdered and fresh- ly-burnt animal charcoal. The latter substance is commonly employed to deprive fish oils of their disagreeable odor, as well as to lessen their color. The decoloration of textile fabrics and solid bodies generally, is called bleaching. (See Oils, Tal- low, Sirup, Sugar, &c.) DECOMPOSITION. Syn. Decomposition, (Fr.) Zersetzung, (Ger.) In Chemistry. The resolution of compounds into their elements, or the alteration of their chemical constitution in such a manner that new products are formed.—Thus: the gas that illuminates our streets, is the --suit of the decomposition of pit-coal; and vinegar and brandy, the result of the decomposition of the sac- charine matter of grape juice. The decomposition of bodies may be either simple or complicated, ac- cordingly as one or more compounds are produced. —Thus: when the vapor of water, (steam,) which is a compound of % parts of oxygen and 1 of hy- drogen, is passed over red-hot iron, the latter unites with the oxygen, and the hydrogen is liberated in an uncombined state. This resolution of the ele- ments of one body, and the formation of a new compound, is called by chemists, simple or single decomposition. The above change may be rep- resented by the following diagram :— Materials. Composition. Products. ^ Hydrogen . Hydrogen gas Iron When, however, two bodies suffer mutual altera- tion, and an interchange of their elements takes place, producing new compounds, it is called dou- ble decomposition. Thus: when sal ammoniac and chalk are mixed together and distilled, as in the preparation of smelling salts, (sesquicarbonate of ammonia,) the hydrochloric acid of the former unites to the lime of the latter, forming hydrochlo- rate of lime ; while the ammonia of the sal ammo- niac unites with the carbonic acid of the chalk, form- ing sesquicarbonate of ammonia, which passes over and is condensed in the receiver. This mutual de- composition is exhibited in the following diagram :— Materials. Composition. Products Sal Am- I Hydrochloric Acid i moniac } Ammonia . . 1 [ HydrocM.of r.tme. JK j ■ \ \ Sesquicarbonate of CaTbonicAcid S Amm°nia- For the sake of simplicity, no notice is taken in Vapor of Watee - yg * * ( Oxide of Iron. Iron . . . . $ J DEC 244 DEC the above diagram of the water formed by the hy- drogen of the hydrochloric acid and tho oxygen of the lime, one portion of which is dissipated along with an atom of ammonia, and another is condensed along with the newly-formed carbonate of ammonia. An intimate acquaintance with the order in which decompositions take place among com- pounds, is of vast importance to the chemical man- ufacturer, and, in fact, forms the ground-work of operative chemistry. The tyro in this art is, there- fore, recommended to pay especial attention to the subject A knowledge " of the elective affinities of bodies, simple and compound, imparts to its pos- sessor an irresistible power over the unions and dis- unions of the elements, which he can exercise with certainty in effecting innumerable transforma- tions in the arts." (Ure.) The following tables will be found to contain much valuable informa- tion on this subject, in a very condensed form, and will enable the reader to understand the nature of many of the decompositions that take place in the chemical operations detailed in this work, as well as to anticipate the effects resulting from the ad- mixture of numerous substances. I. Table of simple Affinity. The following table, drawn up from the re- searches of Geoffroy, Bergman, Vauquelin, Four- croy, and others, has been arranged in alphabeti- cal order for the convenience of reference. The Bubstance, the attractions of which are to be shown, is placed at the commencement of each paragraph, and the substances to which it has an attraction, follow in the order of the forces of attraction. Acetic Acid. Baryta ; Potassa ; Soda ; Stron- tia; Lime ; Ammonia; Magnesia ; Metallic oxides ; Glucina; Alumina; Zirconia. As.cohol. Water; Ether ; Volatile oil; Alkaline sulphurets. Alumina. Acids—Sulphuric, Nitric, Hydrochlo- ric, Oxalic, Arsenic, Fluoric, Tartaric, Suc- cinic, Mucic, Citric, Phosphoric, Lactic, Benzoic, Acetic, Boracic, Sulphurous, Nitrous, Carbonic, Hydrocyanic. Ammonia. Acids—Sulphuric, Nitric, Hydrochlo- ric, Phosphoric, Fluoric, Oxalic, Tartaric, Ar- senic, Succinic, Citric, Lactic, Benzoic, Sulphur- ous, Acetic, Mucic, Boracic, Nitrous, Carbonic, Hydrocyanic ; Oil; Water ; Sulphur. Arsenic Acid. The same as Fluoric Acid, omit- ting Silica. Baryta. Acids—Sulphuric, Oxalic, Succinic, Fluoric, Phosphoric, Mucic, Nitric, Hydrochlo- ric, Suberic, Citric, Tartaric, Arsenic, Lactic, Benzoic, Acetic, Boracic, Sulphurous, Nitrous, Carbonic, Hydrocyanic ; Sulphur ; Phosphorus; Water; Fixed Oils. Benzoic Acid. White oxi'de of arsenic ; Potassa ; Soda; Ammonia; Baryta ; Lime ; Magnesia; Alumina. Boracic Acid. The same as Fluoric Acid, omit- ting Silica, and adding Water and Alcohol. Camphoric Acid. Lime; Potassa; Soda ; Ba- ryta ; Ammonia ; Alumina; Magnesia. Carbon. Oxygen ; Iron; Hydrogen. Carbonic Acid. Baryta ; Strontia ; Lime; Po- tassa ; Soda; Magnesia ; Ammonia; Glucina ; Zirconia; Metallic oxides. Citric Acid. Same as Oxalic acid, excepting that Zirconia should be inserted after Alu- mina. Fixed Oils. Lime ; Baryta; Potassa; Soda ; Magnesia ; Oxide of Mercury ; Metallic oxides; Alumina. Fluoric Acid. Lime ; Baryta; Strontia; Mag- nesia ; Potassa ; Soda; Ammonia; Glucina; Alumina ; Zirconia ; Silex. Hydrochloric Acid. The same as Nitric acid, excepting that Ammonia should stand above Magnesia. Hydrocyanic Acid. Baryta ; Strontia; Potassa; Soda ; Lime ; Magnesia ; Ammonia. Hydrogen. Oxygen ; Sulphur ; Carbon; Phos- phorus : Nitrogen. Lactic Acid. The same as Acetic acid. Lime. Acids—Oxalic, Sulphuric, Tartaric, Suc- cinic, Phosphoric, Mucic, Nitric, Hydrochloric, Suberic, Fluoric, Arsenic, Lactic, Citric, Malic, Benzoic, Acetic, Boracic, Sulphurous, Nitrous, Carbonic, Hydrocyanic; Sulphur; Phosphorus; Water; Fixed oil. Magnesia. Acids—Oxalic, Phosphoric, Sulphuric, Fluoric, Arsenic, Mucic, Succinic, Nitric, Hy- drochloric, Tartaric, Citric, Malic, Lactic, Ben- zoic, Acetic, Boracic, Sulphurous, Nitrous, Carbonic, Hydrocyanic ; Sulphur. Nitric Acid. Baryta ; Potassa ; Soda; Strontia; Lime ; Magnesia ; Ammonia; Glucina; Alu- mina ; Zirconia ; Metallic oxides. Nitrogen. Oxygen ; Sulphur ; Phosphorus; Hy- drogen. Oxalic Acid. Lime ; Baryta ; Strontia ; Mag- nesia ; Potassa; Soda; Ammonia; Alumina; Metallic oxides ; Water ; Alcohol. Oxide of Antimony. Acids—Gallic, Hydro- chloric, Benzoic, Oxalic, Sulphuric, Nitric, Tar- taric, Mucic, Phosphoric, Citric, Succinic. Fluo- ric, Arsenic, Lactic, Acetic, Boracic, Hydro- cyanic ; Fixed alkalis ; Ammonia. Oxide of Arsenic Acids—Gallic, Hydrochlo- ric, Oxalic, Sulphuric, Nitric, Tartaric, Phos- phoric, Fluoric, Succinic, Citric, Acetic, Hy- drocyanic ; Fixed alkalis; Ammonia; Fixed oils; Water. Oxide of Copper. Acids—Gallic, Oxalic, Tar- taric, Hydrochloric, Sulphuric, Mucic, Nitric, Arsenic, Phosphoric, Succinic, Fluoric, Citric, Lactic, Acetic, Boracic, Hydrocyanic, Carbonic; Fixed alkalis ; Ammonia ; Fixed oils. Oxide of Gold. Acids—Gallic, Hydrochloric, Nitric, Sulphuric, Arsenic, Fluoric, Tartaric, Phosphoric, Acetic, Hydrocyanic; Ammonia; Sulphureted Hydrogen. Oxide of Iron. Acids—Gallic, Oxalic, Tartaric, Camphoric, Sulphuric, Mucic, Hydrochloric, Nitric, Phosphoric, Arsenic, Fluoric, Succinic, Citric, Lactic, Acetic, Boracic, Hydrocyanic, Carbonic. Oxide of Lead. Acids—Gallic, Sulphuric, Mu- cic, Oxalic, Arsenic, Tartaric, Phosphoric, Hy- drochloric, Sulphurous, Suberic, Nitric, Fluoric, Citric, Malic, Succinic, Lactic, Acetic, Benzoic, Boracic, Hydrocyanic, Carbonic ; Fixed oils; Ammonia. Oxide of Mercury. Acids—Gallic, Hydrochlo- ric, Oxalic, Succinic, Arsenic, Phosphoric, Sul- phuric, Mucic, Tartaric, Citric, Mafic, Sulphur- DEC 245 DEC ous, Nitric, Fluoric, Acetic, Benzoic, Boracic, Hydrocyanic, Carbonic. Oxide of Platina. Acids—Gallic, Hydrochloric, Nitric, Sulphuric, Arsenic, Fluoric, Tartaric, Phosphoric, Oxalic, Citric, Acetic, Succinic, Hydrocyanic, Carbonic ; Ammonia. Oxide of Silver. Acids—Gallic, Hydrochloric, Oxalic, Sulphuric, Mucic, Phosphoric, Sulphur- ous, Nitric, Arsenic, Fluoric, Tartaric, Citric, Lactic, Succinic, Acetic, Hydrocyanic, Carbon- ic ; Ammonia. Oxide of Tin. Acids—Gallic, Hydrochloric, Sulphuric, Oxalic, Tartaric, Arsenic, Phosphor- ic. Nitric, Succinic, Fluoric, Mucic, Citric, Lac- tic, Acetic, Boracic, Hydrocyanic ; Ammonia. Oxide of Zinc Acids—Gallic, Oxalic, Sulphu- ric, Hydrochloric, Mucic, Nitric, Tartaric, Phosphoric, Citric, Succinic, Fluoric, Arsenic, Lactic, Acetic, Boracic, Hydrocyanic, Carbo» ic ; Fixed alkalis ; Ammonia. Oxygen. Carbon ; Charcoal; Manganese ; Zinc ; Iron ; Tin ; Antimony ; Hydrogen ; Phosphorus; Sulphur; Arsenic ; Nitrogen ; Nickel; Cobalt; Copper; Bismuth; Caloric? Mercury; Silver; Arsenious acid; Nitrous oxide ; Gold; Plati- num ; Carbonic oxide ; Hydrochloric acid; White oxide of manganese; White oxide of lead. Oxygen.* Titanium; Manganese; Zinc; Iron; Tin ; Uranium ; Molybdenum ; Tungsten ; Co- balt ; Antimony; Nickel; Arsenic ; Chrome ; Bismuth ; Lead; Copper; Tellurium ; Platinum; Mercury ; Silver ; Gold. Phosphoric Acid. Baryta ; Strontia ; Lime ; Po- tassa ; Soda ; Ammonia; Magnesia ; Glucina ; Alumina ; Zirconia ; Metallic oxides; Silica. Phosphorous Acid. Lime ; Baryta ; Strontia ; Potassa ; Soda; Ammonia ; Glucina; Alumina ; Zirconia; Metallic oxides. Phosphorus. The same as Sulphur. Potassa. The same as Ammonia. Silica. Fluoric acid; Potassa. Soda. The same as Ammonia. Strontia. Acids—Sulphuric, Phosphoric, Oxalic, Tartaric, Fluoric, Nitric, Hydrochloric, Succin- * Vauquelin's table of the affinity of the metals for oxy- gen, according to the difficulty with which their oxides are decomposed by heat. Y ttna ; Alumina ; zarconia ; Metallic oxides. Sulphurous Acid. Baryta ; Lime ; Potassa ; So- da ; Strontia ; Magnesia; Ammonia ; Glucina : Alumina ; Zii\ snia; Metallic oxides. Sulphureted Htdroge*!. Baryta; Potassa; So- da ; Lime ; Ammonia ; Magnesia ; Zirconia. rp._______a___ t,___. „„ (\„-i;„__:j ic, Acetic, Arsenic, Boracic, Carbonic; Wa- ter. Suberic Acid. Baryta; Potassa; Soda; Lime; Ammonia ; Magnesia ; Alumina. Succinic Acid. Baryta; Lime ; Potassa; Soda; Ammonia; Magnesia; Alumina; Metallic ox- ides. Sulphur. Potassa; Soda; Iron; Copper; Tin ; Lead; Silver; Bismuth ; Antimony ; Mercury; Arsenic; Molybdenum. Sulphuric Acid. Baryta; Strontia ; Potassa; Un/lo « T i,no • \TnfrnnctQ • A .....-.i.^n . / * I__*__. Arsenic; Molybdenum. Sulphuric Acid. Baryta; Strontia ; Potassa; Soda ; Lime ; Magnesia ; Ammonia ; Glucina ; Yttria ; Alumina ; Zirconia ; Metallic oxides. Sulphurous Acid. Baryta ; Lime ; Potassa ; So- da ; Strontia ; Magnesia; Ammonia ; Glucina ; Alumina ; Zii\ snia; Metallic oxides. ua ; oironua ; luagnesia ; Ammonia ; -jiuc Alumina ; Zii\ wiia; Metallic oxides. sulphureted HfDROGE**. Baryta ; Potassa da ; Lime ; Ammonia ; Magnesia ; Zirconia rARTARic Acid. Same as Oxalic acid. fu.NGSTic Acid. The same as Fluoric acid. II. Table of the order of Decomposition among some of the Metallic Oxides, according to the researches of Prof. Persoz. nitric ACID. Oxide of magnesium. " silver. " ' cobalt. " nickel. Protoxide of cerium. Oxide of zinc. Protoxide of manganese. Oxide of lead. " cadmium. " copper. " glucinum. " aluminum. " uranium. " chromium. Protoxide of mercury. Oxide of mercury. " iron. " bismuth. MURIATIC ACID. Oxide of magnesium. " chromium. " nickel. Protoxide of mercury. " cerium. Oxide of zinc. Protoxide of manganese. " iron. " uranium. " copper. " tin. Oxide of glucinum. " aluminum. " uranium. " chromium. " iron. " tin. " bismuth. " antimony. *#* Oxide of copper separates the oxides of alu- minum, uranium, chromium, titanium, and vana- dium, from all the oxides which are precipitable, as sulphurets by hydrosulphuret of ammonia. III. Table of the Sequences of the Bases with the different Acids, by Dr. Young. In all mixtures of the aqueous solutions of two salts, each acia remains united to the base which stands nearest to it in this Take. SULPHURIC ACID. Baryta Strontia Lime (Silver ?) (Mercury?) Potnssa Soda Zinc 1 Iron > Copper J Magnesia Ammonia* Glucina Alumina Zirconia Nitric Baryta Strontia Lime Potassa Soda (Mercury ?) (Iron ?) Magnesia Ammoniat Glucina Aluminaf Zirconia (Copper ?) Baryta Potassa Soda Ammonia Strontia Magnesia} Glucina Alumina Zirconia Lime Baryta Potassa Soda Strontia Ammonia Magnesia Glucina Alumina Zirconia Lime Baryta Potassa Soda Strontia Ammonia? Magnesia§ Glucina Alumina Zirconia Lime Baryta Potassa Soda Strontia Ammoniafl Magnesia Lime Glucina Alumina Zirconia Potassa Soda Baryta Strontia Ammoniall Lime Magnesia Glucina Alumina Zirconia Baryta Strontia Lime Potassa Soda Magnesia ? Ammonia Glucina Alumina Zirconia Baryta uead Potassa Mercury Soda flron Ammonia J Potassa Strontia | Soda Magnesia IMagnesia Glucina Alumina Lead Zirconia Zinc Lime? Copper Mt riatic Phosphoric Fluoric Sulphurous Boracio Carbonic Nitrous Phosphorous Acetic • Ammonia stands above magnesia when cold. t A triple salt is formed. ...„j. .k„„. .„___.•„ t Perhaps magnesia ought to stnnd lower. § A compound salt is formed, and when hot, magnesia stands above ammonia. IFourcroy says that sulphate of strontia is decomposed by borate of ammonia. IT With heat, ammonia stands below lime and magnesia. DEM 246 DEN DEFECATION. Syn. Defecation, (Fr.) Klaren, (Ger.) From Lat. de and fax, dregs. In chemistry, the separation of a liquid from its fseces or impurities. This is usually performed by subsidence and decantation, and is commonly ap- plied to the purification of saline solutions, on the large scale, in preference to filtration ; than which it is both more expeditious and inexpensive. DEFLAGRATION. Syn. Deflagration, (Fr.) Verpuffung, (Ger.) Deflagratio, (Lat., from defiagro, to burn.) In chemistry, the rapid combustion of any substance, for the purpose of producing some change in its composition, by the joint action of heat and oxygen. The process of oxidizing substances by means of nitre, is common- ly called deflagration, and is performed by project- ing a mixture of equal parts of the nitrate and the inflammable or oxidizable body into a red-hot cru- cible, in small portions at a time. Several articles mentioned in this work are prepared in this way. DELIQUESCENCE. Syn. Zerfliessen, (Ger.) Diliquescentia, (Lat., from diliquesco, to melt down.) The attraction of the moisture of the atmosphere, and solution therein. The term is applied to certain salts, that by exposure gradu- ally assume the liquid state. Such salts are said to be deliquescent. DELPHINE. Syn. Delphina. Delphinia. Delphinium. An alkaloid, discovered by Las- saigne and Feneulle in the delphinium staphysa- gria, or stavesacre. Prep. I. The husked seeds are ground to pow- der, boiled in a little water, and pressed in a cloth. The filtered decoction is then boiled for a few min- utes with a little pure magnesia, and refiltered, and-the residuum, after being well washed, is dis- solved in boiling strong alcohol, which dissolves out the alkali, and gives it up again by gentle evaporation and cooling. II. Digest the bruised but unshelled seeds in di- lute sulphuric acid, strain, precipitate with carbon- ate of potassa, and digest the precipitate in alcohol as before. Prep., Uses, 6fC. A semi-crystalline white odorless powder, having an acid bitter taste. It is scarcely soluble in water, but dissolves in ether, and readily in alcohol. It forms salts with the acids, which are very bitter, and crystallize with difficulty. As commonly procured, it is mixed with an acrid resin called staphysain. (Couerbe.) Its alcoholic solution produces a burning and tin- gling sensation, when rubbed on the skin, and a similar sensation is produced in various parts of the body, when it is taken in doses of a few grains. It has been exhibited in neuralgia and rheumatism, by Dr. Turnbull. DEMULCENTS. (From demulceo, I sooth.) Bland, emollient substances that obviate irritation by covering the expdsed part, and protecting it from the action of acrid matter. The principal demulcents are, gum arabic, gum tragacanth, lin- seed, liquorice, arrow-root, pearl barley, isinglass, almonds, spermaceti, almond and olive oils, and most mucilaginous and oily substances. For in- ternal use these are made into mucilages, decoc- tions, emulsions, or milks, with water, and form suitable beverages in dysentery, diarrhoea, catarrh, diseases of the urinary organs, and all other dis- eases where diluents are useful. DENSITY. (From densus, thick.) The quan- tity of matter contained in a given space. It is commonly used synonymously with specific grav- ity. Thus, quicksilver is said to have a greater density than copper, and alcohol a less density than oil of vitriol. DENTIFRICE. (Dentifricum, Lat., from dens, a tooth, and frico, I rub.) Substances ap- plied to the teeth, to cleanse and beautify them. The most usual form of dentifrices is that of pow- der; but washes and electuaries are also some- times employed. The ingredients employed in dentifrices should not be too hard or gritty, lest they injure the enamel of the teeth ; nor should they be too soft or adhesive, for in that case they would adhere to the gums, and be disagreeable Finely-powdered pumice-stone is one of those sub- stances that act entirely by mechanical attrition, and is hence an objectionable ingredient in tooth- powder, intended for daily use. It is, however, very generally present in the various advertised dentifrices, which are remarkable for their rapid action in whitening the teeth. Finely-powdered Bath brick is another substance of a similar nature to pumice, and, like that article, should only be occasionally employed. Cuttle-fish bone, coral, and prepared chalk are also commonly used for the same purpose, but the latter is rather too soft and absorbent, to form the sole ingredient of a tooth-powder. Charcoal, which is so very gener- ally employed as a dentifrice, acts partly mechan- ically, and partly by its chemical properties of destroying foul smells, and arresting putrefaction. For this purpose it should be newly burnt, and kept in well-closed vessels, as by exposure to the air it rapidly loses its antiseptic powers. Powder- ed rhatany, cinchona bark, and catechu are used as astringents, and are very useful in foulness 01 sponginess of the gums. Myrrh and mastich are employed on acount of their odor, and also because of their presumed preservative action, and power of fixing loose teeth. Insoluble powders have been objected to on account of their being apt to accumulate between the folds of the gums, and in the cracks of the teeth, and thus impart a disa- greeable appearance. To remedy this defect, a reddish or flesh-colored tinge is commonly given to them with a little rose pink, or similar coloring substance, when any small portion that remains unwashed off will be less conspicuous. Some persons employ soluble substances as tooth-pow- ders, which are free from the above objection. Thus, sulphate of potash and cream of tartar are used for this purpose, because of the grittiness of their powders and their slight solubility in water. Phosphate of soda and common salt are also em- ployed as dentifrices, and possess the advantage of being readily removed from the mouth by means of a little water. Among those substances that chemically decolor and remove unpleasant odors, the only ones employed as dentifrices are charcoal and the chlorides of lime and soda. The first I have already noticed ; the others may be used by brushing the teeth with water, to which a little of their solutions has been added. A very weak solution of chloride of lime is commonly employed by smokers to remove -the odor and color imparted by tobacco to the teeth. Electuaries made of honey and astringent substances are frequently DEX 247 DIA employed in diseases of the gums. The juice of the common strawberry has been recommended as an elegant natural dentifrice, as it readily dis- solves the tartareous incrustatioue on the teeth, and imparts an agreeable odor to the breath. (See Electuary.) DEPILATORY. Syn. Depilatoire, (Fr.) Enthaarensmittel, (Ger.) Depilatorius, (Lat., from de, from, and pilus, the hair.) A term ap- plied to any application that removes hair from the human skin. Depilatories act either mechanical- ly or chemically. To the first belong adhesive plasters, that on their removal from the skin bring away the hair with them; equal parts of pitch and resin, spread on leather, have been used for this purpose. To the second class belong those sub- stances which act upon the bulbous roots of the hairs, and destroy their vitality. The former me- thod is more painful, but less dangerous, than the lattei one. The following are the principal depil- atories at present employed in the fashionable world. I. (Delcroix's Poudre Subtile.) Prep. Orpi- ment 1 part; finely-powdered quicklime and starch, of each 11 parts ; mix. Remarks. It should be kept from the air. For use, make it into a paste with a little warm water, and apply it to the part, previously shaved close. As 60on as it has become thoroughly dry, it may bo washed off with a little warm water. II. (Oriental Rusma.) Prep. Quicklime 2 oz.; orpiment £ oz.; strong alkaline lye 1 lb.; boil to- gether until a feather dipped into it loses its flue. It is applied to the skin, previously soaked in warm water, by gentle friction, for a very short time, followed by washing with warm water. This is one of the most certain and powerful depilatories made, but rapidly loses its strength unless kept in a well-stoppered glass bottle. III. (Chinese Depilatory.) Quicklime lib.; pearlash and sulphuret of potassium, of each 2 oz.; reduce thein to a fine powder, and keep it in well- corked bottles. Use like Poudre Subtile. IV. (Plenck's Pasta Epilatoria.) Orpiment 1 part; quicklime 12 parts; starch 10 parts. As last. V. (Rayer's Depilatory^) Lime 1 oz.; carbon- ate of potash 2 oz.; charcoal powder 1 drachm. As last. This and No. Ill are preferred by those persons who do not approve of the use of arsenic. VI. (Roseate Depilatory.) Like IV, but slight- ly colored with rose-pink. VII. (Turkish Depilatory.) Quicklime 7 oz.; orpiment 1 oz.; mix. As above. VIII. (Depilatory Paste.) Quicklime 1 oz.; orpiment and orris-root, of each, 3 drachms ; salt- petre and sulph; r, of each 1 dr.; soap-lees k a pint; evaporate to a proper consistence. It should be kept from the air. IX. (Depilatory Soap.) Turkish depilatory and soft soap, equal parts ; mix. DETERGENT, COLLIER'S. Prep. Liquor of potassa f3ij ; rose-water f^vss ; spirits of rose- mary f^ss ; mix. Frees the head from scurf. DEXTRINE. A substance formed by the action of dilute acids at the boiling temperature, and by infusion of malt, at about 150° F. on starch. It resembles gum. Its name is derived from the action of is solution on ptlarized light; it causes the plane of polarization to deviate to the right (See Diastase.) DIAMONDS, PARISIAN. These beautiful imitations of the "priceless gem," which have lately attracted so much attention, are made by a chemist in Paris, and are only the oxide of tin. It is to be regretted that the brilliancy which has rendered this imitation so famous, cannot be de- pended upon, as, after exposure for some tirr.e, they become as dull as common glass. (Mining Journal.) DIAPENTE. Prep. Laurel berries and mus- tard, of each 3 lbs.; gentian root 2 lbs.; turmeric 4 lbs.; all in fine powder; mix well. Used by farriers as a tonic. DIAPHORETICS. (Diaphoreticus, Lat, from Staipopiu), I carry through.) Medicines that increase the perspiration. Those that produce this effect in a powerful degree, are generally called sudorifics. The principal diaphoretics are warm diluents, as gruel, tea, barley-water, &c.; salts of the alkalis, as the citrates of potassa and soda, acetate and carbonate of ammonia, sal am- moniac, nitre, &c.; preparations of antimony, as tartar emetic, antimonial powder, &.c.; also Do- ver's powder, opium, camphor, ipecacuanha, al- cohol, wine, &c. The use of diaphoretics is indicated in most diseases accompanied by fever, and a dry skin. DIAPHRAGM. (Diaphragma, Lat, from Sta>, I separate by a partition.) This term has been applied to the porous cell or vessel that separates the fluid containing the positive plate from the fluid that surrounds the negative plate, in constant galvanic batteries. (See Battery.) The most convenient diaphragms for all common purposes, are those composed of thin biscuit-ware* they are also frequently made of plaster of Paris, animal membrane, coarse and tightly-wove can- vass, &c. Those of plaster may be easily formed by surrounding an oiled cylinder of wood with a hoop of paper, and pouring plaster of Paris, mixed up with water, into the space between the two. DIARRHCEA. (From Siafreu,, I flow through.) A purging or looseners of the bowels. The causes of diarrhoea are various, but among the most com- mon is the presence of irritating matter, worms, or acidity in the stomach or bowels. In general, it will be proper to administer an aperient, for which purpose rhubarb is usually preferred. The dose may be from 20 to 30 grains, on sugar, or made into a bolus. After the due operation of this med- icine, opium, astringents, and absorbents may be taken with advantage. The first and second are indicated when great irritability exists, and the third, in cases of diarrhoea arising from the pres- ence of acidity. Chalk mixture, to which a few drops of laudanum have been added, or the com- pound powder of chalk and opium, aie excellent medicines, and will generally quiet the bowels. A small piece of catechu, or hard extract of logwood, sucked in the same way as a lozenge, is a pleasant method of taking either of those powerful astrin- gents. DIASTASE. A peculiar substance, contained in malt, which effects the conversion of starch into dextrine and grape sugar. It may be procured from a cold infusion of malt, by adding alcohol, which precipitates it under the form of a tasteless DIE 248 DII. white powder. In this state it is freely soluble in water. It appears from experiments, that 1 part of diastase will convert 2000 parts of starch into grape sugar. Malted barley is said to contain ^o i part of this substance; yet this small portion is quite sufficient to convert the starch of the malt into sugar during the operation of mashing, provi- ded this be properly conducted. " The most favor- able temperature for this conversion is 140° to 149° . Fahr. It is also of the utmost importance that the saccharification should take place as speedily as possible, so that the sugar produced may not re- main in contact with much gummy matter, in which case the diastase will not convert the latter into sugar. In fact, the liquefaction and sacchar- ification should proceed simultaneously." (M. Gue- rin Varry.) Hence it would appear that the Scotch system of ale-brewing is, in this latter respect, most excel- lent, and if the mashing were conducted at a low- er temperature, would be almost perfect. It has been proved by experience, that the richest and sweetest extracts of malt are obtained by employ- ing water at a heat ranging from 157° to 160° F., beginning at the lowest of these temperatures. Where three mashings are made, the mean tem- perature of each mash should be respectively,— 145°,—1 GO0,—175° F. (See Brewing, and* Fer- mentation.) DIET. " The dietetic part of medicine is no inconsiderable branch, and deserves a much great- er share of regard than it commonly meets with. A great variety of diseases might be removed by the observance of a proper diet and regimen, with- out the assistance of medicine, were it not for the impatience of the sufferers. On all occasions, it may come in as a proper assistant to the cure, which sometimes cannot be performed without a due observance of the non-naturals." The follow- ing tables will convey to the reader the meaning c" s.e, terms, low diet, full diet, &c. Low Diet. Breakfast and Tea.—Warm new milk and wa- ter ; weak black tea, its astringent properties cor- rected by a due addition of milk. Gruel, toasted bread, at least one day old, and without butter. Rusks sopped in the above fluids. Dinner.—Gruel, new milk and arrow-root, sago, or tapioca ; chicken and veal broths; roasted ap- ples ; light bread puddings. Pastry of every de- scription must be avoided. Supper.—Gruel, arrow-root. Occasional drinks.—Filtered or spring water; toast-and-water made with toasted bread or brown- ed biscuit; barley-water ; whey; lemonade, of Rubdued acidity. Sweet oranges may be freely taken, if the sense of thirst be oppressive. Middle Diet. Breakfast and Tea.—Same as in low diet, with the addition of mixed tea. Luncheon, (if required.)—A cup of arrow-root, sago, tapioca, with biscuit, or two or three bars of toasted (stale) bread ; or these with oranges. Dinner.—In addition to " low diet," boiled chick- ens ; calves' and sheep's feet, stewed; mutton broth; beef tea; boiled soles, whiting, turbot, &c.; lamb; potatoes, asparagus, light bread or rice pud- ding, roasted apples. After the repast, may be ta- ken one glass of port, old sherry, or madeira wine diluted with at least twice its quantity of water. Supper.—A cup of gruel, sago, tapioca, or ar- row-root Full Diet. Breakfast and Tea.—Same as in " middle diet;" in addition to which may be taken coffee or chocolate. Stale or toasted bread, sparingly but- tered. Luncheon—A biscuit and a glass of table-ale or porter. Dinner.—The " middle diet" bill of fare may be augmented by mutton-chops, rump-steaks, roast or boiled fresh meats, fruit pies, (avoiding the pas- try,) baked or boiled rice or tapioca puddings. At this meal table-beer or porter may be taken as common drink, and after it, one or two glasses of port, old sherry, or Madeira. Supper.—Same as in " middle diet." An additional glass of wine at dinner or lunch- eon, will convert this "full" into " generous" diet. Milk, Farinaceous, Vegetable, and Fruit Diet. The articles of food within this range are milk, eggs lightly boiled, gruel, sago, arrow-root, tapio- ca, isinglass, wheaten and barley bread, rice, po- tatoes, carrots, parsnips, turnips, artichokes, peas, cauliflowers, cabbage, spinage, water-cress, cele- ry. Fruit may be regarded rather as a luxury than as nutriment; however, when taken in mod- eration, it is wholesome; when to excess, poison- ous. Stone fruit, as nectarines, apricots, peaches, plums, and cherries, are the least digestible, and should never be taken but when ripe ; apples and pears are not so apt to run into the acetous fer- mentation as stone fruit, but, unless ripe and well- masticated, had better be eaten cooked. Oranges, gooseberries, (avoiding the skins,) grapes, without the husks and seeds, currants, ripe strawberries and raspberries, follow consecutively in the order in which they are here enumerated, the first being most easy of digestion. Notwithstanding such an ample store of materials, the selection must of course depend upon season, appetite, and the known effects of each upon individual constitu- tions. DIETETIC COMPOSITION. Prep. Pow- dered sago and patent cacao, equal parts; mix. It is used like arrow root. DIGITALIN. Syn. Digitalia. Digitalina. An alkali discovered by M. Royer in the digitalis purpurea. Prep. Digest 1 lb. of foxglove in ether, first in the cold and then heated under pressure; when it has again become cold, filter, and distil off the ether, dissolve in water, and again filter; treat the solution with hydrated oxide of lead, gently evap- orate the whole to dryness, and again digest in ether. From this solution the alkali may be ob- tained by evaporation. By repeated re-solutions it may be procured in a crystalline state. Remarks. As obtained above, it forms a brown mass, faintly alkaline to test paper. It is power- fully poisonous, and is said to possess the same properties as digitalis, but in a very concentrated degree. DILUENTS. (From diluo, I wash away.) Aqueous liquors, so named because they increase DIS 249 DIS the fluid portion of the body. Tea, barley-water, water gruel, and similar articles are the most com- mon diluents, after pure water. The copious use of liquids of this class is recommended in all acute inflammatory diseases, and to promote the action of diuretics and sudorifics. DIOSMIN. A bitter extractive matter obtained by Brande, from buchu leaves. It is very soluble in water, but not in alcohol and ether. DISINFECTANTS. Agents which destroy miasmata. The principal of these are chlorine, the chlorides of lime and soda, the fumes of nitric and nitrous acids, heat, and ventilation. The last two are the most efficient and easily applied. The clothing, bedding, &c. of patients laboring under contagious diseases, may be effectually disinfected by exposure to a temperature of about that of boil- ing water. Neither the texture nor color of textile fabrics is injured even by a heat of 250° Fahr. It is a practice at some of the workhouses to bake the clothes of the paupers who have the itch, or are infested with vermin. Quicklime rapidly ab- sorbs carbonic acid,' sulphureted hydrogen, and several other noxious gases, and is therefore com- monly used as a wash for the walls of buildings. Acetic acid, camphor, fragrant pastiles, cascarilla, and other similar substances, are frequently burnt or volatilized by heat, for the purpose of disguising unpleasant odors. The sulphates of iron and lime have the property of rapidly, destroying noxious effluvia. A quantity of either of these sulphates thrown into a cesspool, for instance, will in a few hours remove the fetid smell. DISTILLATION. Syn. Distillation, (Fr.) Branntweinbren.nerei, (Ger.) In Chemistry:— The evaporation and subsequent condensation of fluid, by means of a still and refrigerator, or other similar apparatus. In commercial language, the term is applied to the manufacture of spirituous liquors The discovery of the art of distillation is usu- ally ascribed to the alchemists, but there appears to be good reason to suppose that it was known in more remote ages to the Arabians and other eastern nations, to whom it probably descended from the ancient Babylonians. Certain it is, however, that a rediscovery of the process was made by some of the northern nations of Europe, and that the first notice of it appears in the writings of Arnoldus de Villa Nova, and his pupil Raymond Lully, by whom spirit, or aqua vita, as itwas called, was declared to be " an emanation of the deity; an element newly revealed to man, and destined to restore the energies of modern decrepitude," and that the discovery of this fluid indicated the con- summation of all things, and the end of the world. The process of distillation, as carried on in the distilleries of Great Britain, may be di- vided into four general operations, viz.—The mashing or formation of a saccharine infusion, from certain vegetable matters, as malt, barley, oats, rye, &c.;—the cooling of this wort or liquor; the fermentation or process by which the sugar of the coded wort is converted into alcohol; and the separation of the spirit so formed by means of a rrtill and refrigerator. By the first operation, the materials for the formation of the alcohol are ob- tained ; by the second, they are brought to a tem- perature most favorable to the transformation that o2 ! takes place in the third, after which it only re- mains to free the product of the last operation from the foreign matter with which it is associated: this is done in the fourth, and, correctly speaking, constitutes the only part of the process which can be called distillation. The general principles of the first three of the preceding operations, are noticed in the articles Brewing, Diastase, and Fermentation. It will there be seen, that the amylaceous or starchy mat- ter of the grain is first saccharified and afterwards converted into alchohol, and that certain precau- tions are necessary to render the process success- ful and economical. In many of the distilleries of Great Britain, molasses and analogous saccharine ! substances are employed, in which case the vege- table principle (sugar) essential to the formation of alcohol, is already present, and merely requires simple solution in water of a proper temperature, I to be ready to be subjected to immediate fermen- tation. In general, hov »ver, the sources of spirit in England are the various kinds of grain ; barley, wheat, and rye, are those commonly employed These are ground and mixed with bruised malt in various proportions, and are mashed in a similar manner to malted grain. The fermentation is car- ried on until the density of the liquor ceases to lessen, or attenuate, which is determined by an instrument called a saccharometer. When this point is arrived at, it is submitted to distillation, to prevent the access of the acetous fermentation, which would lessen its alcoholic value. During the process of distilling off the spirit of the fermented " wash" or wort, a-hydrometer is employed to ascertain its strength, and as soon as the liquor that passes over acquires a certain de- gree of weakness, the operation is stopped and the spent wash removed. The spirits obtained by the first distillation are generally called " low wines," and have a specific gravity of about *975. By rectification or " doubling," a crude milky spirit, abounding in oil, at first comes over, followed by clear spirit,, which is received in a separate vessel. The process is continued until the alcoholic con- tent of the distilled liquor diminishes to a certain degree, when the remaining weak spirit that comes over, called "faints," is caught separately and mixed with the low wines, preparatory to another distillation. The strongest spirit passes over first, and the condensed liquor gradually becomes weaker, until it ceases to contain alcohol. It will thus be seen, that by receiving in separate vessels any given portion of the product, spirit of any re- quired strength within certain limits' may be ob- tained. It is found from experience, and is readily accounted for by theory, that the lower the tem- perature at which the distillation is conducted, the stronger will be the product, and the less quantity of oil or other volatile matter will come over along with it. To promote this, it has been proposed to carry on the process in vacuo, but on the large scale this has never been adopted. The distilla- tion of the " wash" is usually carried on in a sep- arate set of stills, to those employed for the rec- tification of the low wines. For very strong and tasteless spirit, a third, and even a fourth rectifica- tion takes place, conjointly with other methods to abstract the water, and to remove any foreign matter that vitiates its odor or flavor. A portion DRA 250 DRA of soap is put into the still with the wash to pre- vent excessive frothing. The quantity of spirit obtained from various sub- stances, and even from pure sugar, depends upon the skill with which the several operations are con- ducted. By theory, pure sugar should yield 51°; of alcohol, but in practice 1 gallon of proof spirit is the utmost obtained from 1U lbs. of sugar. Ac- cording to Harmstaedt, 100 lbs. of starch yield 3.") lbs. of alcohol, or 7-8 gallons of proof spirit; and 100 lbs. of the following grains, produce the ac- companying quantities by weight of spirit of sp. gr. ■9427, or containing 45 per cent, of pure alcohol; wheat, 40 to 45g ; rye, 36 to 42g ; barley, 40% ; oats, 36$ ; buckwheat, 4Ug; maize, 40g; the mean being, 3-47 gallons of proof spirit. It is found that a bushel of good malt yields 2 gallons of proof epirit, and that the maximum quantity of proof spirit obtained from raw grain, mashed with one- fifth or one-sixth of malt, does not exceed 22 gal- lons per quarter. By the excise laws, the distiller is restricted in the density of his worts, \p sp. gr. between 1050 and 1090 ; and in Scotland, between 1030 and 1075 ; nor is a distiller allowed to mash and distil at the same time. (See Alcohol, Fermentation, Still, Brandy, Gin, &c.) DIURETICS. (Diuretica, from Sia, through, and ovpov, the urine.) Medicines which promote the secretion of urine. The principal diuretics are aqueous fluids,—which act by increasing the watery portion of the blood,—and certain sub- stances which promote the secretion of urine, by stimulating the kidneys. Among the former may be classed nearly all aqueous liquids, as most of them produce diuresis, if the skin be kept cool. Among the latter, may be mentioned the nitrate, acetate, and bitartrate of potassa; oils of juniper, turpentine, cajeput, and copaiba ; dilute spirit, and sweet spirits of nitre ; decoction of common broom, &c. DOORS. Much annoyance is sometimes ex- perienced from the creaking of doors. This may be prevented by rubbiug a little soap, or a mixture of tallow and blacklead on the hinges. DRACINE. Syn. Draco.mn. A red vegeto- alkaline body, discovered by M. Melandre in drag- on's blood. Prep. Dissolve dragon's blood in alcohol, filter, concentrate, add cold water, and collect the spongy precipitate. Wash this well, neutralize with di- lute sulphuric acid, and again wash well with water. Prop., fyc. Dracine has a fine red color; is tasteless, inodorous, flexible, and fuses at 131° F. The most remarkable property is, that the smallest quantity of carbonate of lime in filtering-paper, may be detected by sulphate of dracine, the yellow color instantly turning red. DRAGON'S BLOOD, (FACTITIOUS.) Prep. Shellac 4 lbs.; melt, remove from the fire, and add Canada balsam 5 oz.; and coarsely-pow- dered gum benzoin 2 oz.; when well mixed, stir in red sanders wood and Venetian red, (both in fine powder,) of each 1 lb.; blend well together, and form into sticks. Remarks. The above may be distinguished from genuine dragon's blood, by its partial solubility in alcohol. It makes, however, a very fine colored powder, but for varnishes is better without the Ve. netian red. DRAUGHT. Syn. Haustus, (Lat.) In Phar- macy : a single dose of liquid medicine. Draughts are almost exclusively extemporaneous, and differ from mixtures only in quantity. They are gener- ally dispensed in two-ounce vials. DRAUGHT, ANTACID. Syn. Haustus An- tacidus. Prep. I. (Collier.) Compound tincture of cardamoms f3j; solution of bicarbonate of mag. nesia (fluid magnesia) f 3ix ; mix. II. (Thomson.) a. Magnesia 3j; peppermint water f^iss ; tincture of orange-peel f3j ; mix. In heartburn, and acidity of the stomach. 6. Liquor of ammonia 16 drops ; almond mix- ture f3ij; laudanum 10 drops. In acidities of the primse vioe, 2 or 3 times daily. III. Carbonate of soda 20 grs.; compound in- fusion of gentian and water, of each f3vj ; tincture of hops f3j; mix. In dyspepsia, heartburn, &&, twice a day. DRAUGHT, ANTI-EML PIC. Syn. Hacs- tub Anti-Emeticus Rivieri. (P. Cod.) Prep Bicarbonate of potassa 3ss ; water 13 iij ; lemon sirup f^j ; lemon juice f^ss ; mix, and cork secure- ly in a strong bottle. DRAUGHT, ANTISEPTIC. Prep. (Collier.) Decoction of yellow cinchona bark fjj ; laudanum 5 drops; spirit of pimento f3iij mix. In putrid fevers, gangrene, &c. ™ DRAUGHT, ANTISPASMODIC. Prep. I. (Collier.) Tincture of castor f3j; sulphuric ether 10 drops ; peppermint water f^iss ; mix. In hys- teria, and that species of irregular muscular action dependent on debility. II. (Thomson.) a. Musk mixture f3xiv ; liquor of ammonia 16 drops ; tincture of castor f3j ; sirup of poppies f3ss ; mix. Three or four times daily, in hysteria and convulsive affections, after the bowels have been well cleared out. b. Oil of aniseed 10 drops; magnesia 20 grs.; tincture of senna f3ij; peppermint water f3x; mix. In flatulence and spasms of the stomach. DRAUGHT, APERIENT. I. (Haustus ape- riens niger, Paris.) Infusion of senna fjj; tinc- tures of senna and jalap, of each f3j ; tartrate of potash 3j; sirup of senna f3j; mix. II. (Haustus aperiens effervescens, Dr. Young.) Prep. Crystals of carbonate of 6oda 3iiss; watel 8 oz.; cream of tartar 3iij ; mix, in a soda-watel bottle, and cork instantly. It should be drunk while effervescing. III. (Seidlitz.) Sesquicarbonate of soda 50 grs.; potassio-tartrate of soda 2 dr.; water 6 oz. dissolve, and add tartaric acid 40 grs. DRAUGHT, AROMATIC. Syn. Haustus Aromaticus cum Rheo. Prep. (St. B. H.) Aro- matic confection 3j.; infusion of rhubarb and cin- namon-water, of each, f3vj; mix. In diarrhoea, &c. DRAUGHT, ASTRINGENT. Prep. I. (Dr. Paris.) Chalk mixture fiss ; laudanum 15 drops; tincture of cateclm f3j ; mix. Both this and the last are excellent in diarrhoea, after the bowels have been first cleared out with a purgative. Out may be taken after each motion. II. (Thomson.) Extract of logwood 12 grs.; cinnamon water f3xv; tincture of catechu f3j. In diarrhoea, dysentery, &c.; as last DRA 251 DRA DRAUGHT, CATHARTIC. Prep. I. (Dr. Thomson.) a. Tartrate of potash |j ; tincture of senna f3j ; infusion of senna fSxivss; sirup of saf- fron f3ss ; mix. In acute diseases, taken early in the morning. b. Epsom salts and manna, of each, 3ij; infu- sion of roses f3xiv ; dilute sulphuric acid 10 drops ; mix. In inflammatory affections, and to check vomiting in low fevers. . c. Carbonate of magnesia 3j ; powdered rhubarb 20 grs.; peppermint water f3xij ; mix. In dys- pepsia, attended with costiveness and acidity, taken an hour before dinner. d. Castor oil f3v ; powdered gum 20 grs.; rose- water f 5j s compound tincture of lavender 8 drops; sirup of poppies f3j ; mix. In colic and calculus. DRAUGHT, DIAPHORETIC. Prep. I. (Collier.) Infusion of serpentary f^iss; tincture of ditto f3j; mix. Tonic and diaphoretic. II. (Thomson.) a. Sesquicarbonate of potassa 20 grs.; fresh lemon juice f3iv; tartrate of anti- mony one-sixth gr.; water f3xj ; sirup of poppies f3j; mix. b. Liquor of acetate of ammonia f3vj; camphor mixture f3x ; nitrate of potassa 10 grs.; sirup of tolu f3ss ; mix. In inflammatory affections. DRAUGHT, DIURETIC. I. (Collier.) Tinc- ture of jalap f3ij ; vinegar of squills f3j ; pepper- mint water f3x ; mix. II. (Copland.) Acetate of potassa 3ss ; infusion of quassia and cinnamon water, of each f3vj; vinegar of squills and sweet spirits of nitre, of each, f3ss ; mix. III. (Thomson.) Nitre 8 grs.; tincture of di- gitalis 16 drops; infusion of roses f3xiij ; sirup of roses f3j ; mix. In dropsy ; three times daily. DRAUGHT, EFFERVESCING. Prep. (G. H.) Sesquicarbonate of soda 30 grs.; water or peppermint water f^iss ; sirup of orange-peel f3ij; tincture of calumba f3ss ; tartaric or citric acid 25 grs.; add the acid last, and drink while efferves- cing. Stomachic, tonic, anti-emetic, &c. DRAUGHT, EMETIC. Prep. I. (Thomson.) a. Ipecacuanha powder 20 grs.; ipecacuanha wino f3ij; water f3vj; mix. For unloading the stomach in ordinary cases. b. Sulphate of zinc 30 grs ; water f3x; dissolve. In cases of poisoning, and the commencement of an intermittent fever. c. Sulphate of copper 10 grs.; water ffij; mix. As an emetic when laudanum has been taken as a poison. DRAUGHT, EXPECTORANT. Prep. (Col- lier.) Mixtures of ammoniacum and almonds, of each, f3vj; tincture of squills 10 drops; mix. DRAUGHT, LAXATIVE. (Haustus Lax- ans cum Taraxaco, Dr. Copland.) Infusion of senna, and compound infusion of gentian, of each, f3vj; sulphate of potassa 20 to 30 grs.; extract of taraxacum 30 to 40 grs.; compound tincture of cardamoms 3iss ; mix. Aperient, stonichic, and alterative. DRAUGHT, NARCOTIC. Prep. (Thom- son.) a. Camphor mixture f^iss; laudanum 35 drops ; sulphuric ether and sirup of saffron, of each f3j; mix. In intermittent headache. b. Carbonate of ammonia 15 grs.; fresh lemon juice fjss; water f^j; spirit of nutmeg f3j; sirup of orange-peel f3ss ; tincture of hemlock 10 drops mix. In diseases of increased irritability. c. Carbonate of potassa 20 grs.; fresh lemon juice f^ss; peppermint water f£j; laudanum 25 drops ; sirup of tolu f3ss ; mix. To procure sleep in the majority of diseases. DRAUGHT OF ACETATE OF AMMO- NIA. Prep. (Paris.) Camphor mixture fgiss; liquor of acetate of ammonia f3iv; antimonial wine 20 drops ; mix. DRAUGHT OF AMMONIA. Prep. (Brande.) Liquor of ammonia 20 to 30 drops; compound tinctures of cardamoms and gentian, of each f3ss ; camphor mixture f§iss ; mix. DRAUGHT OF BISMUTH. Prep. (Dr. Paris.) Trisnitrate of bismuth 8 grs.; almond mixture fjj ; tincture of henbane 20 drops ; mix. DRAUGHT OF BALSAM OF PERU. Prep. (Haustus Balsami Peruviani. St. B. II.) Bal- sam of Peru f3ss ; mucilage of acacia f3iv; pi- mento water f3iij; water f3v ; mix. DRAUGHT OF BALSAM OF TOLU. As the last. DRAUGHT OF CAJEPUT. (OIL.) Prep (Paris.) Oil of cajeput 3 drops; white sugar 10 grs.; infusion of calumba f3ix; tincture of ditto f3j ; mix. DRAUGHT OF CAMPHOR. Prep. (Haus- tus Camphora. G. II.) Powdered camphor 6 grs. ; rectified spirit q. s.; white sugar 3j; muci- lage of gum acacia 3iij ; water f^iss ; mix. DRAUGHTOFCHLORIDEOFCALCIUM. Prep. (Collier.) Liquor of chloride of calcium 20 drops; compound infusion of gentian f3x ; mix. DRAUGHT OF CINCHONA. Prep. (Dr. Joy.) Decoction of cinchona f^iss ; extract of cin- chona 15 grs.; tincture of cinchona f3j ; aromatic spirit of ammonia 30 drops ; mix. DRAUGHT OF COLCHICUM. Prep. (Brande.) Wine of colchicum 30 drops ; carbon- ate of magnesia 15 grs ; cinnamon water ffss ; water f|j ; mix. DRAUGHT OF COPAIBA. (St. B. II.) The same as Draught of Balsam of Peru. DRAUGHT OF HEMLOCK AND HEN- BANE. (Haustus Conii et Hyosciami, Paris.) Extracts of hemlock and henbane, of each, 5 grs.; mucilage 3ij; liquor of acetate of ammonia f3iv ; sirup of red poppies f3j ; water §j ; mix. DRAUGHT OF IODIDE OF POTASSIUM. Prep. (Collier.) Iodide of potassium 10 grs ; compound infusion of orange-peel f3x ; mix. DRAUGHT OF IODIDE OF IRON. Prep. (Thomson.) Iodide of iron 1 to 2 grs. ; tincture of orange-peel foj; water f3xi; mix. Tonic. DRAUGHT OF JALAP AND SQUILLS. Prep. (Copland.) Tincture of jalap f3ij ; vinegar of squills f3j ; peppermint water f^iss ; mix. DRAUGHT OF NITRATE OF POTASSA. Prep. Nitre 15 grs.; powdered gum 10 grs.; al- mond mixture f§iss ; mix. DRAUGHT OF TURPENTINE. The same as Draught of Balsam of Tolu. DRAUGHT, REFRIGERANT. Prep. I Carbonate of potassa 20 grs.; sirup of orange-peel f3j ; spirit of nutmeg t"3ss ; water f.fiss ; mix. II. (Thomson.) Nitre 12 grs.; almond mixture f^iss; sirup of tolu f3j ; mix. Both the above, in fevers and inflammatory diseases. DRO 252 DRO DRAUGHT, SALINE. I. (Collier.) Carbon- ate of potassa 20 grs.; antimonial wine 20 drops ; sirup of orange-peel f3j ; tincture of orange-peel f3ss ; water fjiss ; mix and add a large tablespoon- ful of lemon juice. In inflammatory diseases. DRAUGHT, TONIC. I. (Collier.) Disulphate of quinine 2 grs. ; tincture of orange-peel f 3j ; diluted sulphuric acid 5 drops ; laudanum 10 drops ; infusion of cascarilla f fiss ; mix. In pyrosis, &c, 1 hour before dinner. II. (Thomson.) a. Infusion of yellow bark f 3iss; compound tincture of cinchona f 3j ; powdered cin- chona 40 grs.; sirup of orange-peel f 3ss ; mix. In intermittents and acute rheumatisms. b. Infusion of cascarilla f§iss; tinctures of cas- carilla and ginger, of each f 3j ; mix. In dyspepsia, arising from intemperance. DRAUGHT, VERMIFUGE. Prep. (M. Le- vacher.) Castor oil 60 grammes; essence of tur- pentine 16 ditto; mint water 64 ditto ; sirup 32 ditto; powdered gum 8 ditto; mix. For tape- worm. DRAWINGS, CHALK and PENCIL. These may be fixed so as not to suffer from abrasion, by washing them with skimmed milk, or with water holding in solution a little isinglass. When the former is used, great care must be taken to deprive it of the whole of the cream, as, if the latter sub- stance be present, it will grease the drawing. An easy way of applying these fluids, is to pour them into a shallow vessel, and to lay the drawing flat upcA the surface, then to place it on blotting paper in an inclined position to drain and dry. DROP, BLACK. Syn. Bkaithwait's genuine Black Drop. Lancaster's do. Quaker's do. Toustall's do. Armstrong's do. Gutta Nigra, (Lat.) The following account of the origin and composition of this well-known medicine, is taken from Dr. Armstrong's Work on Typhus Fever:— " The black drop was originally prepared up- wards of one hundred years ago, by Edward Toustall, a medical practitioner in the county of Durham, and one of the Society of Friends. The recipe passing into the possession of a near relative, John Walton, of Shildon, was found among his brother's papers, and, by the permission of Thomas Richardson, of Bishop's Wearmouth, one of his executors, it is here inserted. " Prep. Take £ lb. of opium, sliced ; 3 pints of good verjuice ; l1 oz. of nutmeg; £ oz. of saffron ; boil them to a proper thickness, then add \ lb. of sugar and two spoonfuls of yeast Set the whole in a warm place, near the fire, for 6 or 8 weeks, then place it in the open air until it becomes of the consistence of a sirup; lastly, decant, filter, and bottle it up, adding a little sugar to each bottle. These ingredients ought to yield, when properly made, about 2 pints of the strained liquor." The article sold in trade under the name of Black Drop, is, however, seldom, or scarcely ever, made in the above way. It is generally prepared by macerating opium £ lb. in distilled vinegar 2 lbs., for about a fortnight. Black drop is considered to be four times the strength of laudanum, and to be milder and less exciting. DR^OP, TASTELESS AGUE. Prep. White arsenic 1 gr.; water 1 oz.; dissolve. ' Dose. 1 teaspoonful night and morning. DROPS. Syn. Gutt*, (Lat.) This term is commonly applied to compound medicines that are only taken in small doses. The plan of directing* liquids to be measured by dropping is objectionable. because tho drops of different fluids vary in size, and are also further influenced by the size of the bottle and the shape of its neck, as well as the quantity of liquid it contains. In Confectionary, lozenges formed by dropping melted sugar on any mooth surface, are cajled drops. DROPS, ACIDULATED. Syn. Acidulated Lemon Lozenges. Trociusci Acidi Tartarici, (P. E.) Prep. Tartaric acid \ oz.; white sugar 8 oz., both in powder; oil of lemon 10 drops ; mix thoroughly, then beat them into a mass with mu- cilage, and form into lozenges. Remarks. The above are the instructions of the Edinburgh College, but a^.v^lated drops are seldom prepared by the druggist, being generally pur- chased of the confectioner, who makes them in the way described under Confectionary Drops. They form an agreeable lozenge for coughs, sore throats, &c. DROPS, ABBE ROUSSEAU'S. Syn. Abbe Rousseau's Laudanum. Wine of Opium, pre- pared by Fermentation. Prep. Honey ^xij; boiling water lb. iij ; set it in a warm place, and as soon as fermentation commences, add opium ^iv, dissolved in water f ^xij ; let it work for a month; strain, evaporate to §x ; again strain, and add rec- tified spirit of wine f §ivss. Remarks. This preparation is similar to the Lancaster Black Drop. DROPS, ACOUSTIC. Prep. I. Almond oil 1 oz. ; oil of turpentine and laudanum, of each 1 drachm ; mix. II. (Dr. Hugh Smith.) Ox gall 3iij; balsam of Peru 3j ; mix. In deafness. DROPS, iETHER AND TURPENTINE. Prep. (Gutta Mtheris Terebinthinata, M. Du- rande.) Sulphuric ether 2 parts ; oil of turpentine 1 part ; mix. For gall-stones. DROPS, ANODYNE. Prep. Acetate of morphia 16 grs.; acetic acid 8 drops; rectified spirit of wine 3j ; water §j; mix. Anodyne ; dose 6 to 25 drops. The muriate or sulphate of mor- phia may be used for a change, instead of the DROPS, ANTACID. Prep. (U. C. H.) Liquor of potassa f^iij ; liquor of ammonia f§j myrrh §j ; triturate together, and strain. DROPS, CONFECTIONARY. Prep. Pound and sift double-refined sugar through a hair sieve, but not too fine vand then sift it through a gauze sieve, to take our all the fine dust, which would destroy the beauty of the drop. Put the sugar into a clean pan, and moisten it with any favorite aro- matic ; if rose-water, pour it in slowly, stirring it with a paddle, which the 6ugar will fall from, as soon as it is moist enough, without slicking Color it with a small quantity of liquid carmine, or any other color, ground fine. Take a small pan with a lip, fill it three parts with paste, place it on a small stove, the half-hole being of the size of the pan, and stir the sugar with a little ivory or bone handle, until it becomes liquid. When it almost boils, take it from the fire and continue to 6tir it; if it be t;o moist, take a little of the powdered sugar, and add some to the paste, and stir it till it is of such a consistence as to run without too much ex- DRO 253 DRO tension. Have a tin plate, very clean and smooth; take the little pan in the left hand, and hold in the right a bit of iron, copper, or silver wire, 4 inches long, to take off the drop from the lip of the pan, and let it fall regularly on the tin plate ; 2 hours afterwards take off the drops with the blade of a knife. DROPS, DUTCH. Syn. Balsam of Turpen- tine. The imported or genuine Dutch drops are the residue of the rectification of oil of turpentine. It is also prepared by distilling rosin, and collecting the product in different portions. At first a white, then a yellow, and lastly a red oil, comes over. The latter is the balsam. The article commonly sold under this name is prepared as follows:—oil of turpentine, tincture of gum guaiacum, and sweet spirits of nitre, of each 1 oz.; oil of amber and cloves, of each 15 drops ; mix. Another prepara- tion, made by mixing balsam of sulphur with 5 times its weight of oil of turpentine, is also sold as Dutch drops. Each of the above is diuretic, stimulant, and detergent. DROPS, FIT. Syn. Soot Drops. Tinctura Fuliginis. Prep. Wood-soot §ij ; subcarbonate of potassa lb. ss ; sal ammoniac §j ; soft water lb. iv ; digest for three days, and strain. Said to be anti- spasmodic. DROPS, GOLDEN, (DE LA MOTTE'S.) Syn. Bestucheff's Nervous Tincture. Elixir d' or. Chloride of iron (obtained by distilling iron pyrites with twice its weight of corrosive sublimate) 3 oz. ; alcohol £ oz.; expose for some time to the rays of the sun. These drops have the remarkable property of losing their yellow color in the sun, and recovering it in the shade. They are taken in gout, hypochondriasis, and nervous complaints. DROPS, GINGER. Prep. Add finely-pow- dered Jamaica ginger, or a few drops of the es- sence, or a strong infusion, to the sugar, as in Con- fectionary Drops. DROPS, JESUITS'. Syn. Elixir Antivene- reum. Balsamum Polychrestum. Prep. Gum guaiacum ^vij ; balsam of Peru 3iv ; root of sar- saparilla %v ; spirit of wine lb. iiss ; digest for 14 days. (See also Compound Tincture of Ben- zoin.) DROPS, LAVENDER. (The same as Com- pound Tincture of Lavender.) DROPS, LEMON. Prep. Confectionary drops acidulated with tartaric acid, and flavored with es- sence of lemons. They may be colored with an infusion of turmeric. DROPS OF LIFE, SALMON'S. Syn. Gvttm VitjB. Prep. Tincture of castor ^viij ; antimonial wine and water, of each lb. j; opium ^iij ; saffron ^ss ; cochineal, camphor, and nut- megs, of each 3ij ; digest for 10 days. Anodyne and diaphoretic. Dose. 20 to 60 drops. DROPS, NORRIS'S. An aqueous solution of tartar emetic, mixed with spirit of wine, and col- ored. DROPS, ODONTALGIC. Prep. (Dr. Blake.) Alum, in fine powder, 3j ; sweet spirits of nitre 3vij ; dissolve. DROPS, PECTORAL, (BATEMAN'S.) Prep. Castor 1 oz.; oil of aniseed 1 dr.; camphor 5 dr.; cochineal 1 "j dr.; opium £ oz.; treacle 1 lb.; proof spirit 1 gallon ; digest for a week. DROPS, PEPPERMINT. Confectionary drops | flavored with essence or oil of peppermint, or pep- permint water. The whitest sugar should be used, and English oil of peppermint DROPS, SCOURING. Prep. Spirits of tur pentine and oil of lemons, equal parts ; mix. Used to remove grease and paint from cloth. Both of the ingredients must be pure and newly-distilled. DROPS, SPILBURY'S. Prep. Corrosive sub- limate, gentian root, and dried orange peel, of each 3ij ; crude antimony and red sanders wood, of each 3j ; spirit of wine and water, of each ^viij ; mace- rate for 10 days. Antiscorbutic. DROPS, TONIC. Prep. (Collier.) Elixir of vitriol f 3ij; tincture of calumba f 3vj ; mix. Dose A teaspoonful three times a day in cold water. DROPS, WARD'S WHITE. Prep. Quick- silver 4 oz.; nitric acid 1 lb.; dissolve, add carbon ate of ammonia 7 oz.; evaporate and crystallize then dissolve the salt in four times its weight of rose-water. Poisonous. DROPSY. (From iSup, water.) An unnatural collection of aqueous fluid in any part of the body Dropsy has been divided into different kinds, and has received different names, according to the part of the body affected by the disease. When it oc- curs in the cellular membrane it is called anasarca; when in the cavity of the abdomen, ascites; in the cavity of the cranium, hydrocephalus; in the scro- tum, hydrocele; in the uterus, hydrometra ; and in the chest, hydrothorax. Dropsy is mostly a symptom of extreme debility and a broken-down constitution. The treatment of dropsy, perhaps, more than any other disease, depends upon the circumstances with which it is connected, and more especially those which have caused it. The acute inflamma- tory forms of dropsy generally require depletion; in some other cases tonics are administered, and to promote the absorption of the accumulated flu- ids, diuretics are commonly resorted to. Confirm- ed dropsy, especially hydrocephalus and hydrotho- rax, are seldom cured. DROWNING. The cause of death from sub- mersion in water is but little understood by per- sons generally. It is commonly thought to arise from the introduction of water into the lungs in- stead of air; and hence the vulgar and dangerous practice adopted by the ignorant, of holding the body of a drowned person in an inverted position, under the idea of allowing the inhaled water to flow out. The actual cause of death is, however, the exclusion of air from the lungs, by which the proper aeration of the venous blood is prevented, and consequently the latter circulates through the arterial system, while the pulmonary vein ceases to convey oxygenized blood to the heart. The con- sequences are, the rapid extinction of the vital functions, and the loss of animal heat, so that gen- erally, in the course of 4 or 5 minutes after the access of air has been cut off, life becomes extinct, Many cases have nevertheless occurred, where persons have been submerged for 15 or 20 minutes, and even longer, and where perfect insensibility has existed, and yet recovery has been effected by long and skilful exertion. Prevention. It is a well-established fact that the specific gravity of the human body is less than that of water, so long as the lungs are partially filled with air; and that this difference is suffi- DRO 254 DRO cient to permit of the body floating with the mouth and nostrils free for respiration, provided the face be turned upwards, or the head thrown back, so that the greater portion of the latter may be im- mersed, and its weight sustained by the water. It is also a well known fact, that if a person throw himself into the water, the body will rapidly rise to the surface and assume nearly the erect position, and that the upper part of the head, down to a lit- tle below the eyes, will remain above the surface. This position is occasioned by the greater density of the legs and thighs compared to that of the chest, which acts as a species of float or buoy to the rest of the body. In this situation, however, it would'of course be found impossible to breathe, but if the head be thrown back, so that the face may become the exposed portion, as before men- tioned, respiration may be carried on without in- convenience. The truth of the above I have frequently de- monstrated in practice; I found that at each in- spiration a larger portion of the face became ex- posed, and at each expiration, the water rose very nearly to the corners of the mouth, but still not sufficiently high to run into it, unless a forced and hurried respiration was purposely had recourse to. Thus a continual rising and sinking of the body takes place, and these motions are synchronous with the inflations and contractions of the lungs. When a hand and part of the forearm is raised above the water, the face becomes instantly im- mersed. From the above it appears evident, that if a person fall into the water, and exercise but common presence of mind, he may readily float for some time, or until assistance can reach him, even though he be not able to swim. Unfortu- nately, however, the state of alarm and agitation into which persons are thrown on falling into the water, and their ignorance of the general means which should be resorted to in such an emergency, as well as want of presence of mind, lead them to neglect those obvious measures that are essential to their preservation. Persons suddenly submerged in the water should endeavor to preserve them- selves as collected as possible, and should avoid splashing and throwing themselves about, as this will naturally increase the danger. They should allow the body to assume its natural position, and if they cannot swim, should patiently wait until assistance be afforded them. Another point which should be remembered by every person under such circumstances is, that there is always a considera- ble amount of residual air in the lungs in a nearly deoxidized state, and that if this be expelled by two or three forced inspirations, and a deep inspira- tion be then taken, a larger quantity of vital air will be introduced to the lungs, and the blood will continue aerated for a proportionally longer time, and consequently a longer period will elapse be- fore another inspiration will be required. J.t will be found, that if, in the ordinary course of breathing, we suddenly hold our breath, we shall only be able to do so for a space of time varying from 20 to 30 seconds ; but if, on the contrary, we prepare our- selves by taking two or three forced inspirations, and then take a full inspiration, we may remain for 1J or 2 minutes before a second attempt at res- piration need be mi de. This is the plan adopted by the pearl fishers, and other divers who are re- markable for remaining beneath the surface of tha water for some time. A person in danger of ship- wreck, or expecting immediate submersion in any other situation, should have recourse to this meth- od, as it would permit the breath to be held until the body rises to the surface of the water, and would prevent the dreadful effects of attempting respiration while the mouth is covered with that fluid. The writer of this article nearly lost his life"a few years since, from not exercising the precau- tions which he is now recommending to others. He had been swimming for about a quarter of an hour, as was his daily custom at the period alluded to, and was returning to the bank, when a species of paralysis seized both extremities, and instead of preserving his presence of mind, and patiently waiting until the fit went off", he exhausted him- self in fruitless endeavors to reach the and. The result was, that after a few vain struggles he sunk, and vividly present to his mind, even at this mo- ment, are the feelings he then experienced. The recollection of a comrade that was drowned a few days before, near the same spot, and the convic- tion of inevitable death, passed across his mind like an electric shock,—life, death, and eternity—the dread of leaving his friends in ignorance of his fate, and a thousand other subjects, were idealized in a moment, and were followed by others in incessant and rapid succession. Space and time seemed an- nihilated,—they presented no visible horizon to the mind's eye,—all was present,—all the events of life seemed collected and performing at the same moment—as in a day-dream, where individual dis- tinctness is blended with general confusion. A pleasing state of mental serenity ensued ; the pros- pect gradually changed, and surrounding 6pacc seemed covered with verdure of the softest green; and illuminated with green light of the most sub- dued tone, which gradually faded into twilight, and—here consciousness ceased. During the whole of this time, which occupied about 3$ minutes, nc great bodily suffering was experienced; after the first sensations of suffocation were passed, none at all are recollected to have been felt. Many years have now passed over since the occurrence of the accident above alluded to, but though time has erased from the memory of the writer many events of more recent date, and with a busy hand has scattered trials and afflictions in his path, yet tho incidents that occurred on the morning of----, still occasionally slart up before the mind, as dis- tinctly as the doings of yesterday. Treatment of persons apparently drowned. The first object is the restoration of the anima! heat. For this purpose, the wet clothes are to be removed without delay, and the body, after being well dried, is to be surrounded with warm air The heat should at first be moderate, and gently increased. In the absence of a warm-air bath; the body should be laid in a well-heated bed or blankets, and bottles of hot water laid to the feet and armpits. A warming-pan or heated bricks should be passed over the body, or gentle friction exercised with other warm substances. Mean- while, continual though gentle attempts should be made to excite respiration artificially; and. if the apparatus be at hand, slight shocks of electricity should be kept up at the same time. If there be DRU 255 DRU any signs of returning life, such as sighing or con- vulsive twitching, a vein may be opened. The throat may be tickled to excite a propensity to vomit, and a teaspoonful of warm water adminis- tered to test the power of swallowing. If it exist, a tablespoonful of warm diluted wine or brandy may De given. Even if no vestige of returning ani- mation be discovered, these means of recovery should be persisted in for three or four hours. In the treatment of this species of asphyxia, nasal stimulants, as ammonia, aromatic vinegar, and similar pungent and volatile applications, should be avoided, as well as the injection of to- bacco smoke, which would prove injurious to a healthy person, and, in the present case, would most likely render all attempts at the restoration of animation ineffectual. The practice of holding the body with the head downwards, which is some- times adopted by the vulgar and ignorant, under the idea of allowing the water to run out by the mouth, should be equally avoided. The supposi- tion that water is inhaled by drowning persons, instead of air, though very plausible, is perfectly fallacious. The peculiar mechanism of the glottis, or upper portion of the windpipe, is such as to pre- vent, by the spasmodic closure of the epiglottis, the entrance of more than a very trifling and ac- cidental quantity of water, which is altogether too insignificant to produce any very injurious effects. (See Asphyxia.) DRUNKENNESS. The disordered condition of the intellectual functions and volition, produced by taking excessive quantities of alcoholic or intox- icating liquors. The word is also commonly ap- plied to habitual inebriety. The action of spirituous and fermented liquors on the human body, in all the numerous relations of causes and effects, has been ably and eloquently treated of, in the " Anatomy of Drunkenness," and it would afford to the editor and reader much pleasure and instruction, would our space permit us to avail ourselves of the mass of facts and judi- cious remarks collected in that work. As how- ever such is not the case, the present article will be confined to a short notice of the means of re- moving the " fit of drunkenness," and the vicious habit that produces its frequent repetition. The pernicious influence of intoxicating liquors upon individuals and society, and the beneficial effects of temperance, cannot be better illustrated than by reference to,the general longevity of the Qua- kers. From the registers of this sect, it may be seen that, as a consequence of their habitual tem- perance and the regularity of their lives, " one half of those that are born live to the age of 47 years; whereas, Dr. Price tells us, that of the general population of London, half that are born live only 2| years !* Among the Quakers, 1 in 10 arrives at 80 years of age; of the general population of London, only 1 in 40." Never did a more power- ful argument support the practice of temperance and virtue. Among the remedies employed to remove the "fit of drunkenness," the preparations of ammo- nia, and the vegetable acids, are the most impor- tant. About 2 or 3 drachms of aromatic spirits of * Since the time that this calculation was made, the health of the metropolis has slightly improved, and, con- sequently, the expectation of life has increased. ammonia, (spirits of sal volatile,) or a like quantity of solution of acetate of ammonia, (mindererus spirit,) mixed with a wine-glassful of water, will in general neutralize or greatly lessen the action of intoxicating liquors. In some cases these fluids produce vomiting, which is, however, a good symp- tom, as nothing tends to restore an inebriated person so soon as the removal of the liquor from the stomach. Hence tickling the fauces with the finger or a feather, until sickness be produced, is a method very commonly adopted by drunkards to restore themselves to a sober state, and also by those wretches who are so far sunk in the scale of humanity, as to be eager, like a certain Roman emperor, to free their stomachs of one batch of liquor, that they may gratify their appetites by swallowing another. The use of aromatic water of ammonia was first suggested by Mr. Broomley. With a like intention, some persons have recourse to soda-water, which acts by the free carbonic acid it contains, as well as a diluent, and from its coldness, as a tonic on the coats of the stomach. The carbonates and bicarbonates of soda And po- tassa are also favorite remedies with habitual drunkards. Among the vegetable acids, the acetic is the one that appears to possess the greatest power of removing intoxication ; aud after this follow the tartaric, citric, malic, and carbonic acids. The above property of these substances is well known to habitual drunkards, and they are hence commonly taken by soldiers before going to parade. The usual dose is a small teacupful of vinegar. In the West Indies, where, from the low price of rum, no inconsiderable number of the soldiers are per- petually tipsy when off duty, lime juice, or lemon juice, is had recourse to. Both these juices act from the citric acid they contain. To cure the " habit of drunkenness," various means have been proposed, many of which are more ingenious than useful. Among several that have come under my attention, the following de- serve notice:— I. In a small treatise on Naval Discipline, late- ly published, the following whimsical and inge- nious mode of punishing drunken seamen is re- commended : " Separate for one month every man who is found drunk from the rest of the crew ; mark their clothes ' drunkard;' give them six- water grog, or, if beer, mixed with one-half water ; let them dine when the crew have finished ; em- ploy them in every dirty and disgraceful work, &c. This had such a salutary effect, that in less than six months not a drunken man was to be found in the ship. The same system was intro- duced by the writer into every ship on board which he subsequently served. When first lieutenant of the Victory and Diomede, the beneficial conse- quences were acknowledged ; the culprits were heard to say, that they would rather receive six dozen lashes at the gangway, and be done with it, than be put into the ' drunken mess' (for so it was named) for a month." II. Dr. Pitcairn, in attempting to break the habit in a highland chieftain, one of his patients, exacted a promise that the latter would every day drop as much sealing-wax into his glass as would receive the impression of his seal. He did so, and as the wax accumulated, the capacity of the glaw diminished, and consequently, the quantity of DRU 256 DYE whiskey it was capable of containing. By this plan he was cured of his bad habit altogether. In mentioning such a whimsical proceeding, I do not mean particularly to recommend it for adoption, al- though I am satisfied that the principle on which its eccentric contriver proceeded was substantially correct. (Coombe.) III. Dr. Kain, an American physician, recom- mends tartar emetic for the cure of habitual drunk-* enness. " Possessing," he observe*, " no positive taste itself, it communicates a disgusting quality to those fluids in which it is dissolved. I have often seen persons who, from taking a medicine in the form of antimonial wine, could never after- wards drink wine. Nothing, therefore, eeems bet- ter calculated to form our indication of breaking up the association in the patient's feelings, between his disease and the relief to be obtained from stimu- lating liquors. These liquors, with the addition of a very small quantity of emetic tartar, instead of relieving, increase the sensation of loathing of food, and quickly produce in the patient an indomitable repugnance to the vehicle of its administration. My method of prescribing it has varied according to the habits, age, and constitution of the patient. I give it only in alterative and slightly nauseating doses. A convenient preparation of the medicine is 8 grains dissolved in 4 oz. of boiling water, £ an oz. of the solution to be put into a i pint, pint, or quart of the patient's favorite liquor, and to be taken daily in divided portions. If severe vomit- ing and purging ensue, I should direct laudanum to allay the irritation, and diminish the dose. In every patient it should be varied according to its effects. In one instance, in a patient who lived ten miles from me, severe vomiting was produced, more, I think, from excessive drinking than the use of the remedy. He recovered from it, how- ever, without any bad effects. In some cases, the change suddenly produced in the patient's habits has brought on considerable lassitude and debility, which were of but short duration. In a majority of cases, no other effect has been perceptible than slight nausea, some diarrhoea, and a gradual but very uniform distaste to the menstruum." A sim- ilar plan has been proposed by Mr. Chambers. IV. Infuse a little of the star-shoot plant in the liquor, at drinking which disgust will be gradually excited. V. The following singular means of curing habitual drunkenness is employed by a Russian physician, Dr. Schreiber, of Brzese-Litewski: it consists in confining the drunkard in a room, and in furnishing him at discretion with his favorite spirit diluted with two thirds of water; as much wine, beer, and coffee as he desires, but containing one third of spirit; all the food—the bread, meat, and the legumes, are steeped in spirit and water. The poor devil is continually drunk and ' dort.' On the fifth day of this regima he has an extreme disgust for spirit; he earnestly requests other diet; but his desire must not be yielded to, until the poor wretch no longer desires to eat or drink ; he is then certainly cured of his penchant for drunkenness. He acquires such a disgust for brandy, or other spirits, that he is ready to vomit at the very sight of it. {Bulletin de Therapeutique.) Tho same treatment it equally adapted to the Wine or beer drunkard, but in such cases the fa- vorits liquor, whatever it may be, must be the on* employed to soak the victuals in. DRY DISTILLATION. Syn. Df.structivi Distillation. The distillation of substances with- out the addition of water or any other fluid matter. Thus, wood is exposed to destructive distillation in the preparation of pyroligneous acid ; and coal un- dergoes a like process, in the manufacture of the gas that lights our streets. DRYING OIL. Syn. Boiled Oil. Linseed oil boiled along with oxide of lead, (litharge,) by which it acquires the property of drying quickly when exposed in a thin stratum to the air. It is much used in the preparation of paints and var- nishes. DRY-ROT. A peculiar disease that attacks wood, and renders it brittle and rotten. It prin- cipally occurs among the timbers of ships and of damp and ill-ventilated houses. It has been as- cribed to the formation of fungi. Various means have been proposed to prevent the attacks of dry- rot, and to arrest its progress when it has com- menced, among which the process called " Kyani- sing," (after Kyan, the name of the patentee,) is most generally known, and has been most exten- sively adopted. It consists in immersing the tim- ber in a bath of corrosive sublimate. A solution of pyrolignite of iron has also been used for tha same purpose and in a similar way, with the besl effect. It is asserted, however, that " Kyanised" wood, that has been exposed for a considerable time in some unfavorable situations, has suffered from the dry-rot in nearly an equal degree with unprepared wood. Lately, the process termed " Paynising" (after Mr. Payne, the inventor) has been adopted, and appears likely to supersede every other method. This plan consists in first filling the pores with a solution of muriate of lime, and next forcing in a solution of sulphate of iron, by which an insoluble sulphate of lime is formed in the body of the wood, and the hitter is rendered nearly as hard as stone. Wood so prepared has already been adopted in several public works. DYEING. Syn. Teinture, (Fr.) Farberei, (Ger.) The art of fixing coloring matters uni- formly and permanently in the fibres of wool, silk, linen, cotton, and other substances. Dyeing is a chemical process, and the mode of its performance depends upon the substance operated on. Thus, it is found that the process by which wool is dyed black, would only impart a rusty brown to linen. Wool unites with almost all coloring matters with great facility, silk in the next degree, cotton less easily than silk, and linen with even more diffi- culty. Preparatory to the operation of dyeing, each of these substances undergoes a species of preparation to free the fibres from adhering foreign matter, as dirt, grease, &c, which would prevent the absorption of the aqueous fluid to be afterwards applied, as well as impair the brilliancy of the edge. Wool is cleaned or scoured by means of a weak alkaline lye, soap and water, or putrid urine ; the latter being very generally used for this purpose. Silk is cleaned from the natural varnish that covers it, by boiling with white soap and water. Cotton and linen are cleaned with alka- line lyes of more or less density. The substances so prepared are ready to undergo the various ope- rations of dyeing. DYE 257 DYS Among the various coloring materials employed by dyers, some impart their tints to different sub- stances by simple immersion in their infusions or decoctions, and have hence been called " substan- tive colors;'' but by far the greater number only impart a fugitive dye, unless the fibres of the stuff have been previously filled with some substance, which has a strong affinity for the latter on the one hand, and the coloring material on the other. The substances applied with this intention are called "'Mordants," and generally exercise the double property of "fixing" and " striking" the color. Thus, if calico be dyed with a decoction of madder, it will only receive a fugitive and dirty red tinge, but if it be first run through a solution of acetate of alumina, dried at a high temperature, washed, and then run through a madder bath, it will come out of a permanent and lively red. The principal mordants are the acetates of iron and alumina, sulphate of iron, alum, and some other chemical salts. A perfect knowledgo of the beha- vior of mordants, with different coloring substances, is of paramount importance to the dyer. After having received the proper mordants, the goods are dried and rinsed, after which they are passed for a shorter or longer time through an in- fusion, decoction, or solution of the dyeing mate- rials, which constitute the " dye-bath;" they are again dried and rinsed. In many cases, the im- mersion in the dye-bath is repeated^, either with the same materials or with others to vary or modify the color. After the substances have been proper- ly dyed, they are subjected to a thorough rinsing or washing in soft water, until the latter runs off uncolored. The modification of the art of dyeing called " calico printing," consists in the application of the mordants, and sometimes the colors, by means of blocks of wood or engraved copper cylinders, the calico being either subsequently passed through a dye-bath, or a solution of a mordant, as the case may be. It was my intention to have given in this article a concise history of the arts of dyeing and calico printing, and an outline of the scientific principles and mechanical operations employed therein, but from want of space I am compelled to omit the paper I had prepared on the subject. I must therefore conclude with the following con- densed description of the fast dyes employed by the calico printers, for which I am indebted to Dr. Ure. Dye-stuffs used by the calico-printers for pro- ducing fast colors. The mordants are thickened with gum, or calcined starch, when applied with the block, roller, plates, or pencil. 1. Black. The cloth is impregnated with acetate of iron, (iron liquor,) and dyed in a bath of madder and logwood. 2. Purple. The preceding mordant of iron, di- luted ; with the same dyeing bath. 3. Crimson. The mordant for purple, united with a portion of acetate of alumina, or red mor- dant, and the above bath. 4. Red. Acetate of alumina is the mordant, (see Alumina,) and madder is the dye-stuff. 5. Pale red of different shades. The preceding mordant diluted with water, and a weak madder bath. 6 Brown or Pompadour. A mixed mordant, 33 containing a somewhat larger proportion of the red than of the black ; and the dye of madder. 7. Orange. The red mordant; and a bath first of madder, and then of quercitron. 8. Yellow. A strong red mordant; and the quercitron bath, whose temperature should be con- siderably under the boiling point of water. 9. Blue. Indigo, rendered soluble and greenish- yellow colored, by potash and orpiment It re- covers its blue color by exposure to air, and there- by also fixes firmly on the cloth. An indigo vat is also made, with that blue substance diffused in water with quicklime and copperas. These sub- stances are supposed to deoxidize indigo, and at the same time to render it soluble. Golden-dye. The cloth is immersed alternately in a solution of copperas and lime water. The protoxide of iron precipitated on the fibre, soon passes, by absorption of atmospherical oxygen, into the golden-colored deutoxide. Buff. The preceding substances, in a more dilute state. Blue vat, in which white spots are left on a blue ground of cloth, is made by applying to those points a paste composed of a solution of sulphate of cop- per and pipeclay ; and after they are dried, im- mersing it, stretched on frames, for a definite number of minutes, in the yellowish-green vat, of 1 part of indigo, 2 of copperas, and 2 of lime, with water. Green. Cloth dyed blue, and well washed, is imbued with the aluminous acetate, dried, and subjected to the quercitron bath. In the above cases, the cloth, after receiving the mordant paste, is dried, and put through a mixture of cow-dung and warm water. It is then put into the dyeing vat or copper. (Ure's Diet, of Chem. and Min.) DYSPEPSIA. (From 6vs, with difficulty, and ir/jrru, / digest.) Indigestion. This com- plaint, of all others, is of the most common occur- rence, and pervades every rank of society. The usual symptoms are want of appetite, sudden and transient distensions of the stomach, frequent eruc- tations, heartburn, stomachic pains, occasional vomiting, and frequently costiveness and diarrhoea. Sometimes the head is affected, and dimness of sight, double vision, muse® volitantes, and slight vertigo, are experienced, along with a multitude of other symptoms, depending on a disarrangement of the functions of the nervous system. The causes of dyspepsia are numerous. In the higher ranks of society, it is a common consequence of over indulgence in the luxuries of the table, or of the want of proper exercise, both bodily and men- tal. In the studious, and those who lead a seden- tary life, it is usually caused by excessive mental exertion oi anxiety, or by the fatigues of business, and the want of sufficient bodily exertion and pure air. In the lower orders of society, it generally results from inebriety, or a deficiency of proper food and clothing. Treat. The treatment of dyspepsia depends less on medicine than on the adoption of regular habits of life. Moderation in eating, drinking, and the indulgence of the passions; early rising, due ex- ercise and retiring to rest at an early hour, will do much to restore the tone both of the stomach and nerves Excessive study and mental exertion EAR 258 EAU should be avoided, and recourse should frequently be had to society, and amusements of a lively and interesting character. If the bowels are confined, mild aperients should be taken, and if diarrhoea be present, antacids and absorbents may be had re- course to with advantage. The stomach should be strengthened by the use of mild bitters, tonics, and stimulants, and sea-bathing, or the tepid bath may be taken when convenient Where dyspepsia is a secondary or symptomatic disease, the cause should be sought into, and the treatment varied accordingly. Among the aperient medicines most suitable to dyspepsia, may be mentioned—Epsom salts, phosphate of soda, and Seidlitz powders, either of which should be taken largely diluted with water. An occasional dose of the Abeniethy Medicines, noticed on our first page, has also been recommended. Among antacids, are the bicar- bonates and carbonates of potassa and soda, either of which may be taken in doses of half a teaspoon- ful dissolved "in water, or if the spirits be low, one or two teaspoonfuls of spirits of sal volatile will be more appropriate, and in cases accompanied by dhtrrhoea, a little prepared chalk. As bitters, compound infusion of orange-peel, or gentian, is excellent. As tonics, small doses of bark, or disulphate of quinine, to which chalybeates may be added, if there be no disposition to fever or headache. EARTHS. Syn. Terras, (Lat.) Terres, (Fr.) Erden, (Ger.) In Agriculture: soils wholly or nearly destitute of organic matter. In Chemistry : certain metallic oxides that constitute the principal portion of the various stony and pulverent masses that form our mountains, valleys, and plains, and the whole crust of the globe we inhabit, as far as the researches of man have penetrated. The prim- itive earths are nine in number, viz. baryta, strontia, lime, magnesia, alumina, glucina, zir- conia, yltria, and thorina. The first four have been denominated alkaline earths, from their partial solubility in water, their alkaline taste, and their action on vegetaW '• colors; the remainder have been called earths proper, from their insolu- bility in water, and their imperfect neutralization of the acids. Silica and lithia have also been classed with the earths, but the former is more correctly placed among the acids, from its power of neutralizing bases, and the latter with the al- kalis, from its behavior with the acids, and the solubility of its carbonate in water. All the above earths were regarded as elementary substances, until Sir H. Davy, in 1808, proved them to be metallic oxides. In a state of purity they are white and incombustible, but they exist in nature in combination with other substances, mostly acids and oxides of the common metals, which alter their appearance. Baryta is the mineral constituent of rat's stone and heavy spar; Lime, combined with carbonic arid, forms chalk, marble, and the shells of fish, and with phosphoric acid, the earthy por- tion of the bones of animals ; alumina constitutes clay, in which state it is usually combined with oxide of iron and carbonate of lime; the other earths play a less important part in the economy of the globe. The metals of which the earths are the oxides, are obtained with difficulty, and possess but an evanescent existence. (See Barium. Axo- minium, &c.) • EATON'S STYPTIC. A spirituous solution of sulphate of iron, disguised by the addition Of some other ingredients. EAU. (Fr.) Water. Eau douce, fresh or river water. Eau de mer, sea or salt "water. Eau de fontaine, spring water. Eau de source, do. Eau de puits, well water. Eau de riviere, river wa- ter. Eau de rose, eau rose, rose water. Eau de vie, brandy. Eau d'Hongrie, Hungary water. Eau benite, holy water. Eau forte, aquafortis. The word eau is applied to numerous substances, differing in their composition, sensible properties, and uses, as will be seen above. In perfumery, it is generally used to . esignate solutions of the fra- grant essential oils in spirit, as eau de Cologne, eau de bouquet, &c, or to distilled waters, largely charged with the odorous principles of plants, as eau de rose, eau de fleurs d'oranges, &lc. In the art of the liqueuriste, it is frequently applied to aromatized spirits, or cordial liqueurs. (See Water.) EAU D'ANGE DISTILLEE. Prep. Ben- zoin 4 oz.; storax 2 oz.; cloves J oz.; calamus and cinnamon, of each -j oz.; coriander seeds 1 dr.; all bruised ; water 5 pints; draw off 2 quarts. Fragrant. EAU D'ANGE DISTILLEE ET MUS- QUEE. Prep. Benzoin 4 oz.; storax 2 oz.; cin- namon £ oz.; cloves and calamus \ oz.; 2 fresh emptied musk bags; water 3 pints ; digest in a gentle heat for 2 hours, then draw over 1 quart Fragrant. EAU D'ANGE BOUILLEE. Prep. Rose water and orange-flower water, of each 3 pints; benzoin 1 lb.; storax £ lb.; cinnamon 1 oz.; cloves £ oz.; 3 fresh emptied musk bags; digest in a securely-covered vessel at nearly the boiling heat for 2 hours, then allow it to cool; strain off the clear, and press the remainder; lastly filter for use. Fragrant. EAU D'ANSERINE. Distilled from the herb, 2 lbs. to water 5 quarts, drawing off only 1 gallon. It is scentless and tasteless. Used by the French in dressing gauzes. EAU D'ARQUEBUSADE. Syn. Vulne- rary Water. Aqua Vulneraria. Ao.. Vul. Spirituosa. Ao.. Sclopetaria. Prep. Dried tops of sage, wormwood, fennel, hyssop, marjoram. savory, thyme, rosemary, calamint, balm, pepper- mint, schordium, angelica leaves, (fresh,) basil leaves, and lavender flowers, of each 4 oz.; proof spirit 2 gallons ; digest for 14 days, and distil over 1£ gallons. II. Rosemary leaves 1£ lbs.; leaves of thyme and summits of millefoil, of each J lb.; proof spirit 2 gallons ; distil over 5 quarts. This water is stimulant and vulnerary, and is used as a cosmetic and cordial. EAU DE BELLOSTE. Prep. Brandy 1 pint; muriatic acid £ pint; hay saffron and sirup of saf- fron, of each 2 oz.; digest for 14 days and filter Formerly used as a resolvent. EAU DE BOUQUET. Prep. Rectified spirit of wine 1 quart; spirits of rosemary and essence of violets, of each 1 oz.: essences of bergamotte and jasmine, of each 1 dr. ; oils of verbena and lavender i dr.; eau do rose J pint; orunga-rlowei EAU 259 EAU water 1 oz.; mix well and filter. An agreeable perfume. EAU DE COLOGNE. Syn. Cologne Wa- ter. Aqua Coloniensis. Spiritus do. Prep I. (P. Cod.) Oils of bergamotte, lemons, and cedrat, of each 3»j ; oils of rosemary, lavender, and neroli, of each §iss ; oil of cinnamon 3vj ; rectified spirit 3 gallons ; spirits of rosemary 1 quart; compound spirit of balm (eau de melisse des Cannes) 3 pints; digest for 8 days, then distil 3 gallons. II. (Cadet Gassincourt) Neroli, essences (oils) of cedrat, orange, lemon, bergamotte, and rosema- ry, of each 24 drops ; lesser cardamom seeds \ oz.; spirit at 32° B. (0*869) 2 quarts; digest, then dis- til 1J pint III. (Farina.) Rectified spirit 5 gallons; cala- mus aromaticus, sage, and thyme, of each £ dr.; balm mint and spear mint, of each 1 oz.; angelica root 10 grs.; camphor 15 grains; petals of roses and violets, of each 3 drs.; lavender flowers 1£ dr.; orange flowers 1 dr.; wormwood, nutmeg, cloves, cassia lignea# and mace, of each 20 grs.; oranges and lemons, sliced, of each 2 in number; bruise or slice the solids, macerate with agitation for 48 hours, then distil off §, and add to the pro- duct—essences of lemons, cedrat, balm mint, and lavender, of each 1 dr.; pure neroli and essence of the seeds of anthos, of each 20 drops ; essences of jasmine and bergamotte, of each 1 oz.; mix well, and filter, if necessary. IV. (Trommsdorff.) Oils of neroli, citron, ber- gamotte, orange, and rosemary, of each 12 drops; Malabar cardamoms, bruised, 1 dr. ; rectified spirit of wine 1 quart; mix, and after standing 2 or 3 days distil. V. Essence of bergamotte 40 drops ; essence of lemons 45 drops; oil of rosemary 6 drops; oil of orange 22 drops ; finest neroli 12 drops ; essence of musk 1 drop; rectified spirit of wine 6 oz., (fluid ;) mix. Excellent without distillation, if the oils be good. VI. Rectified spirit of wine 1 pint; oils of ber- gamotte, orange, and rosemary, of each 1 dr.; car- damom seeds 1 dr.; orange-flower water 1 pint; mix, digest for a day, then distil. VII. Neroli, essences of cedrat, orange, citron, bergamotte, and rosemary, of each "j dr.; oil of verbena 20 drops; lesser cardamoms 1 dr.; recti- fied spirit of wine, at 32° B. J gallon; orange- flower water J pint; digest and distil 3 pints. VIII. To the last add, before distillation, es- sences of musk and ambergris, of each 10 drops; powdered benzoin 15 grs ; otto of roses 8 drops. IX. Essence of bergamotte 3 oz.; essence of lemon 3 drs.; essence of cedrat 2 drs.; neroli 1£ dr.; oil of rosemary 1 dr.; spirit of wine 1 £ gal- lon ; rosemary tops 4 oz.; balm J dr.; distil. Remarks. In the preparation of eau de Cologne, it is essential that the spirit be of the purest de- scription, both tasteless and scentless, and that the oils be not only genuine, but recently distilled, as old oils are less odorous and contain a considerable quantity of resin and camphor, which would prove injurious. To produce an article of the finest qual- ity, distillation should be had recourse to, as di- rected above ; but a very excellent eau de Cologne may be produced by simple solution or maceration of the ingredients in the spirit, provided all the es- sences be new, pale-colored, and pure. When pre- pared in the latter way, any article that would im- part a color should be avoided, as eau de Cologne should be both transparent and colorless. The mass of the eau de Cologne prepared in England, some of which possesses the most delicate fragrance, and is nearly equal to the best imported, is made with- out distillation. In the shops two kinds of this ar- ticle are generally kept, viz., French and German. That prepared by Farina of Cologne is esteemed the best, and is preferred in the fashionable world. Eau de Cologne is principally used as a per- fume, but a very large quantity is consumed by fashionable ladies, as a cordial and stimulant to drive away the vapors. For this purpose it is dulcified with sugar. A piece of linen dipped *in Cologne water, and laid across the forehead, is a fashiona- ble remedy for headache. EAU DIVINE. Prep. Essences of lemon and bergamotte, of each 1 dr.; dissolve in rectified spirit of wine 1 gallon ; distil or filter ; then add clarified sirup 3 quarts; distilled water 5 quarts; mix well and add orange-flower water 6 oz. A pleasant and fragrant cordial. EAU DE FRAMBOISES. Prep. Strawber- ries, bruised, 16 lbs.; spirits of wine 1 gallon; dis- til to dryness in a salt-water or steam bath. EAU DE HUSSON. Syn. Eau Medicinale. Aqua Medicinalis Hussonii. This is a nostrum which was originally prepared by M. Husson, a French military officer, and which has acquired great reputation for allaying the pain and remov- ing the paroxysms of gout. It was submitted to a chemical investigation by Cadet and Parmentier, in 1782, but without eliciting further information than that it is a purely vegetable solution. Alyon has asserted that it is prepared with gratiola ; Mr. Moore that it is an infusion of hellebore and lauda- num ; and Mr. Want that it is a vinous infusion of colchicum. The general opinion coincides with that of the latter gentleman, and the wine of col- chicum is commonly substituted for it, and pro- duces like effects. Dr. Collier has given the fol- lowing form for the eau medicinale de Husson:— " Colchicum root, sliced, §ij ; cherry wine f §iv ; macerate." This preparation is 2^ times as strong as the " vinum colchici" of the Pharmacopoeia, and the dose should consequently be from 8 to 24 drops. EAU DE LAVANDE. Syn. Lavender Wa- ter. Double Distilled do. Prep. I. Picked flowers 7 lbs. ; rectified spirit 2 gallons; macerate for a week, then distil. II. Flowers 7 lbs.; rectified spirit 1£ gallons; water i gallon ; as before. III. Mitcham oil of lavender 8 oz.; essence of bergamot 1£ oz.; essence of musk 4 oz.; rectified spirit 2 gallons; mix well. Very fine. IV. To the last, add 3 quarts of distilled water, and after well mixing, filter through blotting pa- per, with a few grains of magnesia. Remarks. Both this and the preceding are better for distillation, and in that case, the musk should be added to the distilled spirit. The oils should be of the best quality, and newly distilled, and the spirit should be perfectly scentless. Eau de Lavande is a most agreeable perfume. The article produced by the third form has been used bv her majesty and many of the nobility. EAU DE MARESCHALE. Prep. I. Musk EAU 260 EGG (grain) and ambergris, of each 20 grs.; oils of ber- gamot, lavender, and cloves, of each 1 oz.: oil of sassafras 10 drops; oil of origanum 20 drops ; rec- tified spirit 2 quarts ; macerate. II. Rectified spirit 1 pint; essence of violets 1 oz.; essences of bergamot and ceillets, of each \ oz.; orange-flower water £ pint. As last. EAU DE MELISSE DES CARMEN. Syn. Eau des Carmes. Aqua Melissa comp. Spiritus Melissa co. Prep. (P. Cod.) Fresh balm flow- ers %xxiv; fresh lemon-peel §iv; cinnamon, cloves, and nutmegs, of each §ij; coriander seed and dried angelica root, of each |j ; rectified spirit lb. viij ; macerate for 8 days, and distil in a water-bath to dryness. II. Take of spirit of balm 8 pints; lemon-peel 4 pints; nutmegs and coriander seeds, of each 2 pints; rosemary, marjoram, thyme, hyssop, cinna- mon, sage, aniseed, cloves, angelica, (roots,) of each 1 pint. Mix, distil, and keep it for a year in an ice-house. This is the original receipt of the barefooted Car- melites, now in the possession of the Company of Apothecaries of Paris, who sell a vast quantity of this celebrated water. It is much esteemed in France as a stomachic, a cosmetic, and a stimu- lant. EAU DE MILLEFLEURS. Prep. I. Musk 10 grs.; essence of lemon 1£ oz.; essence of am- bergris 2 oz.; oils of cloves, and lavender, (Eng- lish,) of each 1 oz.; neroli and oil of verbena, of each 15 drops ; rectified spirit 2 quarts. Macerate in a close vessel in a warm situation for a fort- night. II. Rectified spirit 1 pint; essence of bergamot J oz.; eau lavande and essence of jasmine, of each 1 oz.; orange-flower water 8 oz.; mix. III. Grain musk 15 grs.; essence of ambergris 1 drachm ; eau d'ange 1 quart. As before. EAU DE NAPHRE. Syn. Eau de Naphe. Aqua Napha. Double distilled Orange-flow- er Water. Prep. This article is distilled in Lan- guedoc from the leaves of the bigarade or bitter orange-tree, but the preparation sold in England under this name, is commonly prepared as fol- lows : orange-flowers 7 lbs.; yellow peel of the bigarade or Seville orange £ lb.; white wine 5 quarts; spirits of wine 1 pint. Macerate in a warm place for three days, then distil. " EAU D'OZILLET. Prep. Cloves, bruised, 1 lb.; water 5 quarts ; macerate for 24 hours, then distil 1 gallon. EAU DE RABEL. Syn. Aqua Rabelii. Prep. Strong oil of vitriol 1 part; alcohol 3 parts. Used as an astringent. EAU D' HONGRIE. Syn. Eau de la Reine d'Hongrie. Aqua Hungarica. Hungary Wa- ter. Prep. I. Rosemary tops, in blossom, 4 lbs.; fresh sage £ lb.; bruised ginger 2 oz.; rectified spirit 1£ gallon ; water £ gallon. Macerate for 10 days, then distil 11 pints. II. Fresh rosemary flowers 2 lbs.; lavender flowers 2 oz.; rectified spirit 3 pints. Distil 3 lbs. Hungary water is fragrant and stimulant, and is much esteemed by some persons as a cosmetic, and, sweetened with sugar, as a liqueur. EAU SANS PAREILLE. Prep. I. Essence of bergamotte 5 drachms; essence of lemon 8 drachms; essence of citron 4 drachms; Hungary water 1 pint; rectified spirit 6 quarts. Macercii and distil. II. Grain musk 20 grs.; ambergris 25 grs.; oils of lavender and cloves, of each 1 oz.; essence of bergamot J oz.; oils of sassafras and origanum, of each 20 drops ; rectified spirit 1 gallon. Macerate for 14 days. A fragrant cosmetic. EAU DE TAIN. Prep. Lemon thyme 1 lb.; water 5 quarts. Distil 1 gallon. Fragrant. EAU DE VIE D'ANDAYE. Prep. Brandy or proof spirit 1 gallon ; simple sirup 1 lb.; aniseed water J pint; mix. EBONY. Pale-colored woods are stained in imitation of ebony, by washing them with or steep ing them in a strong decoction of logwood or galls, allowing them to dry and then washing them over with a solution of the sulphate or acetate of iron. When dry they are washed with clean water, ana the process repeated if required. They are lastly polished or varnished. EDULCORATE. Syn. Ehicorer, (Fr.) AussiisEN, (Germ.) From edulco, to make sweet (In Chemistry.) The affusion of water on any sub- stance for the purpose of removing the portion so- luble in that fluid. Edulcoration is usually per- formed by agitating or triturating the article with water, and removing the latter after subsidence by decantation or filtration. It is the method com- monly adopted to purify precipitates and other powders which are insoluble in water. EGGS. Syn. Qlufs, (Fr.) Ovum, an egg; Al- bumen Ovi, white of egg ; Vitellus Ovi, yelk of egg ; (Lat.) The eggs of birds are nutritious and easily digestible ; and when" lightly cooked by boil- ing, and eaten with a little salt, are admirably adapted as an aliment for the sick, and for persons with delicate stomachs. When boiled hard or fried, they are rendered less easily digestible, and have no advantage in this respect over good meat A new-laid egg, broken into a cup of tea, coffee, or chocolate, and well beaten up, is an excellent in- gredient in the breakfast of a person having a de- ficient appetite, and will be found very supporting. A glass of wine, beer, or porter, similarly treated, along with a biscuit, has been recommended as a light and nutritious luncheon or supper, well suited to the debilitated and the dyspeptic. The average weight of a new-laid egg is about 3£ oz.; the white generally weiglis 1| oz.; the yelk li, and the shell and skin £ oz. Choice. The larger end of a new-laid egg fee- cold, when placed against the tongue. New-Iaio. eggs appear semi-transparent when placed be- tween the eye and a strong light, and have a small and perceptible division of the skin from the shell, which is filled with air. When they shake the) are stale. The eggs of the large black fowls called Minorcas or Spanish, and which have a very white and rough shell, are those that possess the mos*. delicate flavor. The eggs of turkeys are much es- teemed for some purposes; those of ducks anc geese are coarse and inferior. Pres. Eggs may be preserved for any length ol time by excluding them from the air. One of the cleanest and easiest methods of doing this, is to pack them in clean dry salt, in barrels or tubs, and to place them in a cool and dry situation. I have eaten eggs thus preserved that were a twelvemonth old, and that had Deen some montlis aboard ship, EGG 261 ELA in a tropical climate, and yet retained all the pe- culiar sweetness of new-laid eggs. With a like intention, eggs are placed in vessels containing milk of lime, or strong brine, or rubbed over with butter, lard, or gum-water ; all of which act by excluding the air. Eggs may be preserved for some weeks in a cold situation, by placing them in a cabbage or potato-net, and hanging them to a nail, observ- ing to hang them up by a fresh mesh of the net every day. Some persons place eggs which they wish to preserve in a netting, or on a sieve or col- ander, and immerse them for an instant in a cal- dron of boiling water, before packing them away. The practice of packing eggs in damp straw, or any thing else that can convey a flavor, should be avoided. The shells of eggs are porous, and readi- ly admit the passage of gaseous substances and fetid odors. It is from inattention to this point that a large portion of the eggs imported from the coast of France have a less delicate flavor than those of our poultry yards. Damp chopped straw, as well as most other organic substances exposed to warmth and moisture, readily ferment, and during fermentation, a considerable increase of tempera- ture takes place, as any one may readily perceive by examining the common hotbeds in our gardens; which are merely masses of organic matter in a state of decomposition. Eggs, as long as they re- tain the vital principle or embryo of the future chick, in a living state, (if I may be allowed the term,) possess in themselves a certain degree of warmth, which tends materially to promote the decomposition of the substance they are packed in, if moisture be present. The importation of foreign eggs, during the year 183H, amounted to nearly 84,000,000, and the duty paid on them to upwards of £211,000. Since that time the number annually imported has, I believe, immensely increased. EGGS and BACON, ARTIFICIAL. " Make clear blancmange in a white dish, cut it into rounds with the top of a teacup, and lay them on the dish on which it is to be served ; make yellow Dutch flummery, run it into a small teacup, in the form of the yelk of an egg, and place one on each round of the blancmange. Cut six straight pieces of blancmange, on which lay three streaks of pre- served damsons, and serve all on the same dish." EGG FLIP. Beer 1 pint; eggs 3 in no.; su- gar 2 oz.; nutmeg and ginger sufficient. Break the eggs into one half of the beer, add the sugar, and beat well together; then place it in a clean " warmer," and heat it over the fire to nearly the boiling point, stirring it all the time, but do not let it boil; next add the other portion of the beer and the spices, and mix well together. Some persons add a glass of spirits. Care must be taken not to let it boil, as, if it does, the eggs will separate. EGG WINE. Like the last, using equal parts of white wine and water instead of beer. EGGS, GLAIRE OF. Prep. Separate the whites from the yelks, and whisk them to a froth, let them stand 24 hours, and strain them through muslin. Used as a glaze or varnish. EGGS IN SALADS, &c. (Substitute.) Prep. Cream 1 tablespoonful; unflavored calves' feet jelly 2 do.; a piece of salt the size of a bean ; hot water, stained yellow with turmeric, 1 dessert- spoonful ; mix well. ELAIDIC ACID. An acid compound formed by the action of nitrous acid or nitrate of mercurj on oleic acid. Prep. Pass a current of nitruu.-. gas through pure oleic arid, at a low temperature, for 5 min- utes ; wash the crystalline mass, that shortly af- terwards forms, with hot water *. and then dissolve it in an equal volume of hot alcohol. On cooling, crystals will form, and must be purified by pres- sure, re-solution, and crystallization. (Meyer.) Prop., $-c. Elaidic acid, prepared as above, re- sembles sublimed benzoic acid; melts at 113° Fahr., and is soluble in alcohol and ether ; with the alka- lis and their carbonates it forms hydrated salts, which yield strong soapy solutions. ELAIDIN. A compound of elaidic acid and glycerine, formed by the action of nitrate of mer- cury on olive oil. It is one of the components of citrine ointment ELATERINE. Syn. Momordicine. The ac- tive principle of elaterium. It was discovered by Dr. Clutterb^rk in 1819, but first obtained in a state of purity in 1830, by the late Mr. Hennel. Prep. I. Digest elaterium in hot alcohol, evapo- rate the tincture to the consistence of thin oil, then throw it into boiling distilled water, and allow the whole to cool; collect the precipitate, and puri- fy by re-solution in alcohol and precipitation by water as before. (Dr. Morries.) II. Digest the alcoholic extract of elaterium in ether, and dissolve the residuum in hot alcohol; crystals will form as the solution cools. (Hennel.) Remarks. Elaterine forms delicate silky crys- tals, having a bitter taste. It is a drastic purga- tive. Dose. One-sixteenth gr. ELATERIUM. (From eXawu, I stimulate or urge forward.) The term IXarrjpiov was applied by the Greeks to any drastic purgative, but prin- cipally to the juice of the wild or squirting cucum- ber. The word elaterium, according to present usage, means the deposite obtained from the juice of the wild cucumber. Prep. I. (Dr. Clutterbuck.) Gather the cucum- bers when as ripe as possible, but without violence that might endanger their bursting. Then wet them by the affusion of cold water, cut them through longitudinally, and allow the juice to strain through a fine sieve into an earthenware vessel. Scoop out the seeds and surrounding pulp, plaee them c-- the sieve, and wash them re- peatedly with cold water. The same process may afterwards be applied to the split cucumbers. The several waters being received in the same vessel with the juice, the whole is to be allowed to re- pose for a few hours, when the clear portion must be decanted and the sediment spread thinly on fine linen and exposed to the air to dry. Exposure to sunshine or a bright light should be avoided, but gentle warmth may be employed without injury. Quality very fine, but the product small. Forty fruits yielded Dr. Clutterbuck only 6 grains of elaterium. . II. (Process followed at Apothecaries Hall.) The fruit cut longitudinally into halves, is placed in hempen or horse-hair bags, and submitted to slight pressure in a tincture press. The juice, as it runs off, passes through a fine hair sieve into a cylindrical glass jug or jar, where it is allowed to remain for two hours, when the clear supernatant ELE 262 ELE liquor is poured off, and the thick portion contain- ing the sediment is placed on a bibulous paper fil- -er, supported on linen, and allowed to drain, after which it is dried by a gentle heat in a stove. The product has a green color, and constitutes the finest elaterium. A paler and inferior article is obtained from the mother liquor, poured from the first sediment by placing it in shallow pans and al- lowing it to deposite. Remarks. To procure a fine article of elaterium it is necessary to remove it as soon as it is depos- ited, as a heavy mucilage falls down soon after- wards, which materially injures its quality and appearance. Good elaterium yields from 50 to 60$ of its weight to strong alcohol, and from 25 to 44$ of elaterin. (See Extract of Elaterium.) ELECTROTYPE. Electrometallurgy. The art of working in metals by means of voltaic electricity. The most simple and easily managed electrotype apparatus, is formed in a similar man- ner to the common constant battery, but instead of employing a plate of copper for the negative element, a mould of the object to be copied, the face of which has been covered with plumbago, is substituted. An electrograph of this kind may be made of any well-glazed earthen jar or vessel, and the following arrangement will be found conve- nient for most of the purposes to which this art is applied by the amateur; viz. copying medals, multiplying plates, &c. a. An oval vessel of salt glazed earthenware or wood, nearly filled with a concentrated solution of sulphate of copper. b, A porous diaphragm, containing the cylinder of zinc c, and filled with dilute sulphuric acid. d, A small bar of brass or copper, fastened to the vessel by the binding screws e, e, and supporting the cylinder of r.inc c, by the hook ef copper wire f, and the mould g, by the hook h. j, A small shelf or partition to support crystals of sul- phate of copper, to keep up the strength of the solution. Another method is to employ a trough or de- composition cell connected with a constant batte- ry, by which means several moulds may be coated at once. This arrangement will be understood by refer- ence to the annexed engraving: «, A constant battery. (See Battery.) k, Decomposition cell; a cubical vessel made of wood, or earthenware, and filled with a mixture of 1 jart of di- lute sulphuric acid and 2 paru of concentrated solotlon of sulphate of copper. c, c, e, Moulds suspended to the brass rod /, and con nected with the copper or negative element of the b.iltcry a, by means of the screw g. d, d. Pieces of sheet copper suspended on the brass rod A, and connected with the zinc, end of the battery, by means of the screw i, employed to keep up the strength of the cupreous solution in the decomposition cell. When it is desired to copy any object by either of these apparatuses, an exact mould must be first procured. Supposing the article to be a medal, for instance, a hoop of paper is commonly placed round it, and white wax, or any similar substance, poured on it in a melted stato, and then allowed to cool, when it is removed, a small piece of cop- per wire to suspend it by is attached, and its face brushed over with finely-powdered plumbago, by means of a camel-hair pencil; the excess and loose portion being carefully removed. The mould so prepared is next suspended in the apparatus, to receive a deposite of metal on its surface. Some persons experience considerable difficulty in pro- curing moulds free from air bubbles, but this in- convenience is readily avoided, by removing with a camel-hair pencil any that may be observed on the surface of the medal, after the melted wax is poured on, and while it remains liquid and trans- parent. Stearine, hard tallow, shellac, rosin soft- ened with a little oil, plaster of Paris, sealing wax, fusible metal, and numerous other substances are employed as materials for moulds. When plaster of Paris is used, it is necessary to imbue its surface with melted wax, to enable it to retain the plum- bago. Fusible metal requires no preparation. After the mould has received a sufficiently thick deposite, the latter is separated, washed in a little clean water, and bronzed. Any of the methods mentioned under " Bronzing of Metals," may be employed for this purpose, but either the first or second will be found the simplest and most con- venient The length of time required to produce a deposite of any given thickness, depends upon the temperature of the solution and the state of the battery. Other things being equal, this takes place more rapidly the higher the temperature, within given limits. In very cold water, the ope- ration proceeds exceedingly slowly. The tyro in electrotype manipulation, frequently experiences much annoyance from the metal being deposited on the surface of the mould, undei the form of a powder, or in a very friable or brittlo state. This generally arises from the battery be- ing in too active a condition. It is found that tho slower the deposite is formed, the tougher and more perfect it will be. Air-bubbles may be avoided by brushing them off the face of the mould after im- mersion in the decomposition cell, and by properly regulating the action of the battery. The dilute sulphuric acid employed to excite the zinc end of the battery, should never be stronger than 1 part of concentrated acid, to 8 or 9 parts of water. Iron may be substituted for zinc, and is more econom- ical. In gilding, silvering, or platinizing the common metals, by electricity, solutions of gold, silver, oi platina, are placed in the decomposition cell, or around the moulds, and plates of those metals, instead of copper, suspended in the solution. ELECTUARY. Syn. Electuarium, (Lat, ELE 263 ELE from 'v.*\sKr6v.) Vegetable and light earthy pow- ders, mixed up with honey, sirup, or sugar, to the consistence of a thick paste. In the present Phar- macopoeia, electuaries are included under the title Confection, but this arrangement is manifestly improper, as these words are not synonymous. " In Conserves (or confections) the addition of the sac- charine matter is in much larger proportion, and is designed to preserve the vegetable matter; in Electuaries the sirup is designed merely to com- municate the required form." (Dr. Murray.) The preparation of electuaries is similar to that of confections and conserves, and the same pre- cautions must be observed to reduce the dry in- gredients to veiy fine powder, and vegetable sub- stances to a minutely divided state. Care must also be taken to diffuse the ingredients equally through every portion of the mass, by patient and laborious pounding or stirring. An inattention to this point has often led to disagreeable conse- quences, from some portion of the electuary being nearly inert, while another portion has possessed increased activity. (See Conserves and Confec- tions.) ELECTUARY, AROMATIC. Syn. Elec- tuarium Aromaticum, (P. E.) Prep. Aromatic powder (P. E.) 1 part; sirup of orange-peel 2 parts ; mix. Remarks. This preparation differs from the aro- matic confection of the other British Colleges, in not containing chalk. It is aromatic and sto- machic, but not antacid or absorbent. ELECTUARY, BLACK. Syn. Elect. Nigrum. Trousseau's Black Tonic Prep. Perchloride»of iron 3iv ; tannin 3j; confection of roses §ij ; sirup of orange §j ; mix. Tonic and astringent. ELECTUARY, CATHARTIC. Syn. E. Catharticum. Confection of senna ^iss j flow- ers of sulphur §ss; sirup of roses or orange peel q s. Pose. A teaspoonful 3 or 4 times a day in piles. A mild and excellent medicine. ELECTUARY, DEMULCENT. Syn. E. Demulcens. Prep. Spermaceti, sirup of poppies, and sirup of tolu, of each 3ij ; powdered gum tragacanth 3j ; confection of roses 3vj ; nitre 3ss ; mix. Dose. A piece the size of a small nutmeg fre- quently. ELECTUARY, EMMENAGOGUE. Syn. E. Emmenagogicum. Prep. Myrrh 1 dr.; ammo- niated iron 1 scruple ; ginger sirup to mix. Dose. A piece the size of a nutmeg, night and morning. ELECTUARY, FEBRIFUGE. Syn. E. Febrifugum. Prep. (E. II.) Powdered cinchona ^j ; sal ammoniac 3j; sirup of lemon juice q. s. In fevers. ELECTUARY FOR DYSENTERY. Syn. E. Anti-dysentericum. Prep. (P. E. 1744.) Electuary of catechu, mixed with half its weight of Locatel's balsam. ELECTUARY FOR EPILEPSY. Syn. E. Anti-epilepticum. Prep. (Dr. Mead.) Powdered cinchona §j; valerian and tin (both in powder) of each 5s8 i sirup to mix. ELECTUARY FOR THE CHOLERA. Syn. E. Anti-cholericum. Prep. Mix together equal parts of finely-powdered and newly-burnt char- coal, lard, and maple sugar. A popular remedy ELECTUARY FOR THE PILES. Syn. E Hamourhoidale. Prep. (Dr. Copland.) Cream of tartar 5j; precipitated sulphur 3iij ; confection of senna jij ; sirup of orange or ginger to mix. Remarks. An excellent medicine for piles. Dose. A teaspoonful 3 or -4 times a day. From the difficulty experienced in procuring pure pre- cipitated sulphur, the flowers of sulphur may be advantageously substituted. ELECTUARY FOR THE TEETH. Syn. E. Dentifricum. Prep. I. (Coral dentifrice. E. Gingivale.) a. Red coral 4 oz.; cuttle-fish bone 1 oz.; cream of tartar 2 oz.; cochineal 1 dr.; alum £ dr.; (all in fine powder ;) clarified honey 10 oz.; mix. b. Clarified honey 12 oz.; tincture of myrrh 3 oz.; oil of cajeput 10 drops ; oil of cassia or cin- namon 20 drops; tincture of cochineal 1 dr.; cream of tartar £ oz. ; mix. II. Myrrh 3 oz.; cream of tartar and cochineal, of each 1£ oz.; powdered cloves 1 oz.; honey 4 oz.; mix. III. To the last add 1 dr. of powdered orris root and 5 drops of otto of roses. Remarks. All the above are used to whiten and preserve the teeth, but are most serviceable in foul or scorbutic gums. ELECTUARY FOR WORMS. Syn. E. Vermifugum. E. Anthelminticum. Prep. I. (Bresmer.) Worm seed and tansy seed, of each 3iv ; powdered valerian root 3ij ; ditto jalap and sulphate of potash, of each 3iss to 3ij ; oxymel of squills to mix. II. Powdered tin §iij; confection of red roses §ss ; orange sirup to mix. Dose. A tablespoonful early in the morning for 3 or 4 successive days, followed by a cathartic. III. (Dr. Cheston.) Powdered tin §iv; confec- tion of wormwood ^iij 5 carbonate of iron §j ; mix. ELECTUARY OF ANTIMONY. Syn. E. Antimonii. Prep. (P. C.) Prepared sulphuret of antimony, gum guaiacum, and black sulphuret of mercury, of each 3j; confection of senna 3ij; sirup to mix. Diaphoretic and alterative. Dose. 1 to 2 drachms twice a day in chronic cutaneous diseases, combined with sarsaparilla or decoction of elm bark. ELECTUARY OF CASSIA. Syn. E. Cas- sia. Prep. (P. D.) Fresh cassia pulp and sirup of orange, of each lb. ss ; manna §ij ; tamarind pulp Jj ; mix and evaporate to a proper consist- ence. Dose. 2 dr. to 1 oz. It is gently laxative, and is chiefly used as a purge for children, or as a vehicle for other cathartics. It is commonly made with equal parts of tamarind and cassia pulps, mixed with £ of manna, and flavored with a few drops of tincture of orange peel, without any evap- oration. r _ ELECTUARY OF CATECHU. Syn. E. Catechu. Prep. (P. E.) Powdered catechu, and kino, of each ?iv ; cinnamon and nutmegs, of each S ; opium (dissolved in a little sherry) 3iss ; sirup of red roses (evaporated to the consistence of honey) ^ELECTUARY OF CATECHU, COM- ELE 264 ELE POUND. Syn. E. Catechu compositum. Prep. (P. D.) Catechu %\v ; kino f iij ; cinnamon ^ij; ginger sirup (boiled as above) lb. ij, ^iij; hard re- fined opium (diffused in wine as above) 3iss ; mix. Remarks. Both the above are astringent and aromatic. Dose. 3j to 3ij in diarrhoea, dysentery, ELECTUARY OF CHARCOAL. Syn. E. Carbonis. Prep. Newly-burnt and finely-pow- dered charcoal and carbonate of soda, of each 3ij ; confection of senna ^iv; mix. ELECTUARY OF CINCHONA AND SODA. Syn. E. Cinchona cum Soda. Prep. (P. C.) Powdered cinchona §j; carbonate of soda 3ij ; thin mucilage to mix. Dose. 2 dr. 2 or 3 times a day. ELECTUARY OF COPAIBA. Syn. E. Co- paiba. Prep. (Caspar.) Blanched almonds 3vj; powdered althaea 3j ; catechu 3ss; balsam of co- paiba 3iij ; mix. ELECTUARY OF COWHAGE. Syn. E. Doliciii. E. Mucuna. Prep. (Chamberlain.) Dip the pods into treacle, withdraw, and scrape off the hairs, repeating the process with fresh pods till sufficiently thick. Dose. One teaspoonful in the morning fasting, followed by a purgative a day or two afterwards. Vermifuge. (See also E. for Worms.) ELECTUARY OF HELLEBORE. Syn. E. Hellebori Albi. Prep. Bruised white hellebore root lb. j ; water 1 gallon ; boil to one half, strain, add honey lb. iij ; and evaporate to a proper con- S1SL611CC ELECTUARY OF IRON. Syn. E. of Steel. E. Chalybeatum. Prep. (Collier.) a. Potassio- tartrate of iron §ss; confection of red roses §j ' sirup to mix. b. Precipitated sesquioxide of iron ^j; honey ^ij ; ginger sirup §ss ; mix. Both the above are tonic. Dose. One tea- spoonful thrice a day. ELECTUARY OF LAUREL BERRIES. Syn. E. e Baccis Lauri. Prep. Leaves of rue, caraway seeds, parsley seed, and laurel berries, of each ^j j gum sagapenum 3ss ; black pepper and Russian castor, of each 3ij ; honey %xv; mix. (See Confection of Rue.) ELECTUARY OF MUSTARD. Syn. E. Sinapis. Prep. (P. C.) Flour of mustard and con- serve of roses, of each 3iv ; ginger sirup to mix. ELECTUARY OF OLIBANUM. Syn. E. Olibani. Prep. (P. C.) Powdered olibanum, and balsam of copaiba, of each 3iv ; confection of hips ?j ; sirup to mix. ELECTUARY OF OPIUM. Syn. E. The- baiacum. E. Opii. E. Opiatum. Prep. (P. E.) Aromatic powder §iv ; senega §iij ; opium (diffused in a little sherry) §ss ; sirup of ginger lb. j ; mix. ELECTUARY OF PEPPER. Syn. F Pi- peris. Prep. (P. E.) Black pepper and liquorice root, in fine powder, of each lb. j; fennel lb. iij ; honey and white sugar, of each lb. ij; mix. Use, jfre. Same as confection of black pepper. ELECTUARY OF SCAMMONY. Syn. E. Scammonii. Prep. (P. D.) Powdered scammony |iss ; cloves, bruised, and ginger, in powder, of each 3vj; oil of caraway 3ss; sirup of roses to mix. A stimulant cathartic. Dose. 10 grs. to £ dr. ELECTUARY OF SULPHUR. Syn. E. Sulphuris. Prep. Flowers of milphur 1 oz, and honey or treacle 2 oz; mix. Gently laxative Dose. A teaspoonful night and morning in piles and some skin diseases. ELECTUARY OF SULPHUR, COM- POUND. Syn. E. Sulphuris co. Prep. I. (St. B. H.) Precipitated sulphur ^ss ; cream of tartar 3j; honey §j ; mix. An excellent laxative in piles. Flowers of sulphur may be substituted for preoipitated sulphur in the above form. Dose. 3j to 3ij. II. Flowers of sulphur ^ss ; cream of tartar 5j; confection of senna §ij ; confection of black pep- per ^iss ; sirup of ginger f £j ; mix. This is an ex- cellent medicine. Dose and Use. As last. ELECTUARY OF SULPHUR AND BO- RAX. Syn. E. Sulphuris cum Borace. Prep. Flowers of sulphur §j ; cream of tartar ^iss ; borax jss ; confection of senna §iiss ; sirup of orange peel to mix. Dose. 1 to 3 teaspoonfuls in diseases of the uterine organs and lower bowels. ELECTUARY OF TURPENTINE. Syn. E. Terebinthina. Prep. (St. B. II.) Common turpentine §j ; honey §ij ; mix. Dose. 1 to 2 tea- spoonfuls in complaints of the urinary organs, worms, &c. ELECTUARY, PECTORAL. Syn. E. Pec torale. Prep. I. (P. E. 1744.) Conserve of roses §ij ; compound tragacanth powder §ss ; benzoic acid 3j ; sirup of tolu q. s. II. Oxymel of squills, sirup of marshmallows, mucilage of gum arabic and sirup of tolu, of each ?ss ; powdered lump sugar §ij ; mix. ELECTUARY, STIMULANT. Syn. E. Stimulans. Prep. Gum ammoniacum (strained) §j ; vinegar of squills ^as ; mix with a gentle heat and spread on leather. As an application to the chest or pit of the stomach. ELECTUARY, STOMACHIC. Green pep- permint, lump sugar, and confection of orange- peel, of each equal parts; mix. Dose. A tea- spoonful. ELEMI. This resin is the produce of an unas- certained tree, respecting which there have beer various conjectures. The London and Dublir, Colleges assign it to the amyris elemifera, but the Edinburgh College, with greater discretion, state it to be the " concrete resinous exudation from one or more unascertained plants." Dr. Pereira has suggested, that it may be tho produce of the icica icicaribo, the canarium zephyrinum, or the cana- rium balsamiferum, but the question is still unde- cided. The elemi of commerce is of a pale yellow color, exteriorly brittle, but soft and tough within ; it has a warm bitter taste, and a fragrant aromatic smell, "partaking of fennel and juniper. It is only par- tially transparent even in thin plates, is very fusi- ble, and has a density a little greater than that of water. According to Bonastre, it consists of 84 per cent, of resin, 12*15 of a fragrant essential oil and a little bitter .extractive. In medicine it is only employed in the preparation of the elemi ointment of the Pharmacopoeia. The elemi of the shops is often adulterated, but more frequently a factitious kind is sold for the genuine gum. This is formed by adding 1 part of balsam of Canada to 4 parts of yellow resin, in the melted state, but removed from the fire, after ELI 265 ELL which about 1J p. c. of oil of juniper, and half this quantity of oil of fennel are stirred in. This fraud may be detected by exposing the suspected article to heat, along with a little water, when its fra- grance will evaporate, and the coarse terebinthi- nate smell of the resin will become readily distin- guishable. ELIXIR. (From the Arabic Elekser, quintes- sence.) A name formerly applied to various com- pound tinctures. ELIXIR, ANTISCROFULOUS. Syn. E. Antiscrofulosum. Ammoniated tincture of gen- tian. ELIXIR, ASTHMATIC. Prep. Opium, oil of aniseed and camphor, of each 1 oz.; proof spirit 1 gallon. Digest a week. ELIXIR, BOERHAAVE'S ANTI-ASTH- MATIC. Syn. Elixir Antiasthmaticum Boer- haavii. A tincture made with aniseed, orris-root, assarabacca, sweet flag, liquorice, and elecampane. Dose. 20 to 40 drops. ELIXIR, DAFFY'S. Syn. E. Salutis. Com- pound Tincture of Senna. Prep. I. Jalap root 5 oz. ; East India senna 1£ lbs.; coriander seeds and aniseed, of each £ lb.; rhubarb \ lb.; shavings of red sanders wood 2 oz.; treacle 7 lbs., and sub- carbonate of potash 2 oz., both dissolved in water 3^ gallons ; rectified spirit of wine 2£ gallons. All the solids must be well bruised, and macerated in the mixed fluids for 14 days,-when the whole must be pressed, and strained through a fine flannel bag. It is too glutinous to run through filtering paper. II. (Dicey's.) Senna lb. j ; guaiacum shavings, elecampane root, (dried,) aniseed, caraway seed, coriander seed, and liquorice root, of each lb. ss ; stoned raisins lbs. ij ; proof spirit or brandy 9 quarts. As last. III. (Swinton's.) Jalap 3 lbs.; senna 1 lb.; coriander seeds, caraway seeds, liquorice root, and elecampane root, of each 4 oz.; moist sugar 2 lb.; rectified spirit of wine and water, of each 1 gallon. As last. IV. Jalap and caraways, of each 1 lb.; senna, rhubarb, and aniseed, of each 2 lbs.; red sanders wood £ lb.; brown sugar 7 lbs.; proof spirit 10 gallons. As last. V. Rhubarb (East India) 14 lbs. senna 56 lbs.; aniseed 7 lbs. ; coriander seeds t bs.; caraway seeds and red sanders wood, of each 5 lbs.; cassia bark and jalap, of each 3 lbs.; proof spirit 100 gal- lons. Digest for 14 days, press, strain, and add molasses 84 lbs. Mix well, and either -clarify, or strain through flannel. VI. For proof spirit in the preceding formulae, use equal parts of spirit of wine and water. Remarks. Daffy's elixir is a favorite purge with drunkards, and is a common and very popular remedy in flatulent colic, dyspepsia, &c. Dose. 1 to 4 tablespoonfuls. ELIXIR, THE DEVIL'S. Prep. Pods of capsicum and cloves, (bruised,) of each f); ginger and saffron, of each §iij; cantharides 3v ; proof spirit lbs. vij. Digest for 10 days. Dose. 3ss to 3iij, in mixtures. It is stimulating and aphrodisiac. ELIXIR OF GARLIC. Syn. E. Allii. Prep. Garlic roots rtO in number; rectified spirit 1 pint. Distil to dryness, and repeat the process with the same spirit from fresh roots a second and a third 34 time, then add camphor 3ij. Diaphoretic. Dost A teaspoonful twice a day. ELIXIR DE GARUS. Prep. Myrrh ^ss; aloes and saffron, of each 3ij; cinnamon, cloves, and nutmegs, of each 3ss; proof spirit 1 quart. Digest for 7 days, strain, and add sirup of maiden- hair lbs. ij ; orange-flower water ^iss. ELIXIR OF JALAP. Syn. E. Jalapa com- positum. Prep. Jalap §iv ; scammony 3iv ; gam- boo-e 3ij; rectified spirit 1 quart. ELIXIR OF LONG LIFE. Syn. E. Long* Vita. Tincture of rhubarb and aloes. ELIXIR OF MYRRH. Tincture of savine. (comp.) P. L. 1788. ELIXIR D'OR. Syn. Elixir of Gold. De La Motte's golden drops. ELIXIR, PAREGORIC. Tincture of cam- phor (co.) and ammoniated tincture of opium. ELIXIR PROPRIETATIS. Compound tincture of aloes. ELIXIR PROPRIETATIS CUM ACIDO. The last article acidulated with sulphuric arid. ELIXIR PROPRIETATIS TARTARIZA- TUM. The elixir proprietatis alkalized with salts of tartar. ELIXIR, PECTORAL. Syn. E. Pectorale. Prep. (P. E. 1744) Balsam of tolu §ij; gum benzoin ^iss ; saffron fss; rectified spirit ffxxxij. Digest in a sand heat for 4 days. ELIXIR POLYCHRESTUM. Prep. (P. E 1744.) Gum guaiacum ^vj ; balsam of Peru §ss; rectified spirit 1 quart. Digest 4 days and strain. ELIXIR SACRUM. Tincture of aloes and rhubarb. ELIXIR SALUTIS. Tincture of senna. ELIXIR, SQUIRE'S. Prep. Opium 2 oz.; camphor and cochineal, of each £ oz.; sweet fen- nel 1 drachm; tincture of serpentary 10 oz. ; spi- rits of aniseed 1 gallon; water 1 pint; aurum musivum 3 oz.; mix. ELIXIR, STOMACHIC. Compound tincture of gentian. ELIXIR OF VITRIOL. Syn. E. Vitrioli. Water strongly acidulated with sulphuric acid. See Aromatic Sulphuric Acid, which is also frequently called elixir of vitriol. ELIXIR OF VITRIOL, SWEET. Syn. E. Vitrioli Dulce. Prep. (P. E. 1744.) Spirit of sulphuric ether lbs. ij; oil of peppermint %S9; es- sence of lemons and oil of nutmegs, of each 3ij; mix. See Aromatic Spirit of ^Ether, which is also called by this name. ELIXIR OF VITRIOL, MYNSICHT'S. Syn. Acid E. of Vitriol. E. Vitrioli Myn- sichti. Prep. Cinnamon, ginger, and cloves, of each3iij; calamus aromaticus Jj; smaller galan- gal ^iss; sage and peppermint leaves, (dried,) of each ^ss ; cubebs and nutmegs, of each 3ij; aloes wood and lemon-peel, of each 3j; sugar candy lw ; rectified spirit lbs. iss; oil vitriol lb. j. Digest for three weeks. . „ ELIXIR OF VITRIOL, VIGAM S. Prep. Spirits of sulphuric ether gviij; aromatic tincture lb. j; mix. • _ „ ,. ELLAGIC ACID. (From Galle reversed.) When an aqueous infusion of nut galls is left for some time exposed to the atmosphere, the tannic acid gradually disappears, and is replaced by gal- lic acid, and an insoluble gray powder, to which EMB 266 EME the term ellagic acid was applied by Chevreul. It is soluble in alkalis, forming salts, and is precipi- tated by acids. ELUTRIATION. Syn. Elutriatio, (Lat, from elutrio, to cleanse.) In Chemistry, the ope- ration of washing insoluble powders with water, to separate them from foreign matter, or the coars- er portion. It is usually performed by grinding or triturating the mass with a little water, until reduced to a very fine powder, and this paste is suddenly diffused through a large quantity of wa- ter, in a deep vessel, from which, after the subsi- dence of the grosser portion, the liquid is poured into another vessel, and allowed to deposite the fine powder it still holds in suspension. 'When this has taken place, the clear supernatant liquor is de- canted, and the sediment drained and dried. The coarse sediment deposited in the first vessel is now submitted to a fresh grinding and diffusion through water, and the entire operation is repeated, until the whole of the pulverizable portion is washed over. The proper length of time for the liquid to remain in the first vessel, depends solely on the density of the powder, and the degree of fineness required in the product; heavy powders subsiding almost immediately, while light ones often take several minutes to deposite their coarsor portion. Sometimes three or more vessels are employed, and the muddy liquor, after remaining a short time in the first, is poured into the next one, and this, in a short time longer, into the third, and so on, until the last vessel is filled, by which means, pow- ders of different degrees of fineness are obtained ; that deposited in the last vessel being in the minu- test state of division. (See Chalk, Bistre, De- cantation, Edulcoration, &.c.) EMBROCATION. Syn. Embrocatio, (Lat, from t/ifipt^w, / moisten.) A fluid medicine rubbed on any part of the body. EMBROCATION, COMMON. Syn. Em- brocatio Communis. Prep. (U. C. H.) Sesqui- carbonate of ammonia ^iv; distilled vinegar 6£ pints ; mix, and add proof spirit 3 pints. EMBROCATION, GUESTONIAN. Syn. Emb. Terebinthina. Prep. Oil of turpentine and olive oil, of each ^iss ; dilute sulphuric acid f 3iij ; mix well. For rheuinatis-n. EMBROCATION FOR BRUISES. Prep. I. Soap liniment 5 oz.; liquor of ammonia 1 oz. ; mix. II. Soap liniment 3 oz.; oil of turpentine 2 oz.; camphor 1 oz. ; mix. III. Tincture of cantharides and rectified spirit, of each 1 oz.; camphor and oil of origanum, of each £ oz.; mix. IV. Sal ammoniac 1 oz.; distilled vinegar £ pint; dissolve. V. Sugar of lead £ oz.; distilled vinegar and water, of each £ pint; dissolve. EMBROCATION for HOOPING COUGH, ROCHE'S. Prep. Sweet oil 2 oz.; oil of amber 1 oz.; oil of cloves 1 drachm ; mix. EMBROCATION FOR STRAINS. (In Horses.) Prep. I. Soft soap and oil of turpen- tine, of each 4 oz.; oil of rosemary and camphor, of each 1 drachm ; mix. II. Olive oil, oil of turpentine, and elder-flower ointment, of each 2 oz.; mix, and add oil of origa- num 3 drachms. EMBROCATION, LYNCH'S. Pup. Steep alkanet root in sweet oil until the latter becomes sufficiently colored, then scent with essential oils. EMBROCATION OF ACETATE OF AM MONT A AND SOAP. Syn. Emb. Ammonia Acetatis cum Sapone. Prep. (P. C.) a. Soap liniment and solution of acetate of ammonia, of each 1 oz. ; mix. b. To the last add liquor of ammonia f 3iij. For sprains, bruises, <&c. EMBROCATION OF ALUM. Syn. Emb. Aluminis. Alum £ oz.; distilled vinegar and proof spirit, of each £ pint; mix. For chilblains, dis- eased joints, &c. EMBROCATION OF AMMONIA. Syn. Emb. Ammonia. Prep, "-iquor of ammonia 1 oz.; proof spirit and water, of each 5 oz. As last EMBROCATION OF AMMONIA, CAM- PHORATED. Syn. Emb. Ammonia Acetatis Camphorata. Prep. I. Soap liniment and liquor of acetate of ammonia, equal parts; mix. For sprains, bruises, chilblains, &.c. II. To every ounce of the above, add 2 drs. of liquor of ammonia. EMBROCATION OF CAMPHOR. Syn. Emb. Camphora. Prep. I. Soap liniment and camphorated spirit of wine, equal parts.' II. (Collier.) Camphorated spirit of wine, essen- tial oil of amber, and laudanum, equal parts. EMBROCATION OF CANTHARIDES. Sun. Emb. Lytta. Emb. Cantharidis. Prep. Tincture of cantharides and camphorated spirit, of each 1 oz.; mix. Stimulant It should be used with caution, lest the absorption of the cantharides induce strangury. EMBROCATION OF SOAP. Soap liniment The following is also a common form : soft soap 3 oz.; camphor 1 oz.; soap liniment £ pint; water and spirit of wine, of each G oz. ; spirits of harts- horn 4 oz.; mix. For -sprains, bruises, chilblains, &.C. EMBROCATION, STIMULANT. Syn. Emb. Stimulans. Prep. (Thompson.) a. Liquoi of ammonia f 3ij ; olive oil f 3vj ; mix. Used in sore throat, &c. b. Compound camphor liniment f 3ix; tincture of cantharides f3j ; laudanum f3ij ; mix. Rubbed over painful joints, and over the bowels in colic and cramp. It is stimulant and anodyne. EMBROIDERY. Gold and silver fancy work of this description may be easiest cleaned with a little spirit of wine, either alone, or diluted with an equal weight of water. The common prac- tice of using alkaline or acidulous liquors is very injurious, and frequently destroys the beauty of the articles instead of cleaning them. EMERALD. Syn. Emeraude, (Fr.) Smaragd, (Ger.) A precious stone of a beautiful green color, and ranking next to the diamond in value. A fine emerald of 4 or 5 grains is worth as many pounds, one of 10 grs. about 21. per gr.; one of 15 grs. 3/. to 41. per gr., and so on in proportion to the in- crease in size. One of 24 grs. fetched 100/. Ac- cording to Vauquelin, the emerald consists of 65$ of silica, 16g of alumina, 13$ of glucina, (about) 3g of oxide of chromium, and a trace of lime. The finest emeralds are obtained from Peru. EMERALDS, FACTITIOUS. The follow- EME 267 EMU ing method of obtaining artificial rubies and emer- alds is exceedingly simple and inexpensive, and offers an ample field for the ingenious experiment- alist Recently precipitated and well washed hy- drate of alumina is moistened with a few drops of neutral chromate of potassa, and kneaded so that the mass assumes a tinge scarcely perceptible ; it is then rolled out into small sticks, about the thick- ness of a finger, and slowly dried, taking the pre- caution to fill the fissures that form during desicca- tion with fresh hydrate of alumina. When per- fectly dry, one end of these sticks is brought into the termination of the flame of an oxyhydrogen blowpipe, until a portion of the mass is fused into a small globule. After the lapse of a few minutes, Beveral minute balls, of some millimetres diameter, and of such intense hardness, that quartz, glass, to- paz, granite, can be easily and perceptibly scratch- ed therewith, will form. When cut and polished, they appear, however, slightly opaque. By em- ploying nitrate of nickel in lieu of chromate of potassa, green-colored globules resembling the emerald were obtained. (Boettger.) By the substitution of oxide of chromium for chromate of potassa, the editor of this work has procured factitious gems of considerable hardness and beauty, though slightly opaque in some por- tion of the mass. But this might doubtless be avoided by more careful manipulation. From some experiments in which a little silica was added, there was less opacity, though in other respects the stones were inferior. EMETIC. Syn. Emetique, (Fr.) Emeticus, (Lat.) E/ieriKot, (Gr., from tpm, I vomit) A med- icine which excites vomiting. The principal emetics are Ipecacuanha and Tartarized Anti- mony, and their preparations ; and the sulphates of zinc and copper. The first of these is commonly employed either in substance or infused in wine, (wine of ipecacuanha,) when it is merely wished to evacuate the contents of the stomach, when that viscus is in a disordered state, or overloaded with food. At the beginning of fevers and other inflammatory disorders, the timely administration of an emetic will frequently induce copious dia- phoresis and produce a cure, or at least greatly mitigate the severity of the symptoms. For this purpose emetic tartar or antimonial wine is pref- erable, either alone or combined with ipecacuanha. When poison has been taken, and the stomach- pump is not at hand, the sulphate of zinc or copper should be administered. £ dr. of either of thes*e substances should be dissolved in 3 or 4 oz. of wa- ter, and a third should be taken every ten minutes until vomiting is induced. The operation of emet- ics is powerfully promoted by drinking copiously of diluents, especially warm water. The latter, in fact, is itself an emetic, when taken in quantity. Its use will also prevent that dreadful straining and retching, which make emetics so much dread- ed by some persons. Small and repeated doses of emetics are frequently administered to** produce nausea, in many diseases of the lungs and stomach. Emetics should be avoided in plethoric habits, in hernia, pregnancy, and whenever an inflamma- tory diathesis exists. They should also be given with great caution to young children, and in such cases, wine or powder of ipecacuanha should alone be employed. Some chronic and obstinate dis- eases, especially rheumatism, are sometimes re* lieved by emetics. EMETINE. Syn. Emetina. Emetin. La Matiere Vomitive. Prep. I. Digest coarsely- powdered ipecacuanha root, first in ether and then in alcohol. Evaporate the latter tincture to dryness, dissolve in water, and precipitate with acetate of lead. Wash the precipitate, diffuse it in distilled water, in a tall glass vessel, and pass sulphureted hydrogen through it, to throw down the lead ; filter and evaporate to dryness. Prod. Brownish red, deliquescent scales. Emetic in doses of i to £ a gr. (Ann. de Chimie et de Physique.) II. The powder of ipecacuanha is digested in water with calcined magnesia. The deposite is thrown on a filter, washed carefully with very cold water, and dried. The emetin is then taken up by alcohol. It may be afterwards combined with an acid, and the salt may be purified with animal charcoal. When the emetin is once more thrown down by magnesia, alcohol redissolves it in a color- less state. Emetin thus obtained is yellowish- white and pulverulent, but may be obtained per- fectly white, by repeating the latter part of the process. White and pure emetin is emetic in doses of one-sixteenth of a grain. Props. Emetin is pulverent, inodorous, and bit- ter ; fusible at 122° F. ; very soluble in alcohol, but only slightly so in ether, oils, and water. It partially neutralizes the acids, forming scarcely crystallizable salts. Tincture of iodine produces a reddish precipitate in an alcoholic solution of eme- tin. With tincture of galls this solution behaves like morphia ; but, unlike the last substance, the salts of iron produce no change of color in it. EMULSION. Syn. Emulsion, (Fr.) Emulsio, (Lat, from emulgeo, to milk.) A milky fluid, formed by the mechanical admixture of oil and water, by means of some other substance that possesses the power of combining with both. The emulsions of the London Pharmacopoeia, are in- cluded under the same head as mixtures. In the preparation of emulsions, the oily or resinous in- gredients are usually suspended by means of mu- cilage of gum arabic ; almonds, or new-laid eggs; 1 drachm of the first, made with equal parts of gum and water ; 1 oz. of the second, (usually 26 in number,) and one in no. of the last, will form two drachms of any oil into an emulsion with about 1 oz. of water. EMULSION, FARRIERS'. Prep. I. (Simple.) Sweet oil 2 oz.; honey or moist sugar 3 oz.; salts of tartar \ oz.; warm soft water 1 pint; mix and shake till quite cold. II. (Pectoral.) Camphor 2 dr.; spirit of wine 1 oz.; oil of aniseed 20 drops ; dissolve, then add of simple emulsion £ pint. EMULSION OF ASAFCETIDA. Syn. Emulsio Assafcstida. Prep. (Duclow.) Asa- foetida gviij ; powdered gum ^xvj ; oil of almonds 1£ pints ; water 1 quart; make an emulsion, strain through linen, and keep it in a well-corked bottle. Antispasmodic. EMULSION OF CAMPHOR. Syn. Mistura Camphora. E. do. E. Camphorata. Prep. (P. E. 1830.) Camphor 9j ; lump sugar ^ss ; tritu- rate together, and add blanched almonds 3SS ; beat well, then gradually add water 1 pint. Stimulant, antispasmodic, and diaphoretic. ENA 268 ENA EMULSION OF COPAIBA. Syn. E. Co- paiba. Prep. Balsam of copaiba, mucilage of gum, and simple sirup, of each 3ij; water £xij; mix. Dose. £ oz. to an ounce 2 or 3 times a day in certain complaints. EMULSION, CATHARTIC. Syn. E. Pur- gans cum Resina Jalapa. Prep. (P. Cod.) Resin of jalap 10 grs.; white sugar 5J; £ the yelk of an egg ; orange-flower water 3ij; water f |iv ; mix. EMULSION OF GUM. Syn. E. Acacia. Mistura Acacia. Prep. (P. E., 1839.) Sweet almonds, blanched, 3x ; white sugar 3v ; mucilage '^■'J ? water 1 quart. In coughs, &c. EMULSION OF OIL OF ALMONDS. Syn. E. Olei Amygdala. Prep. Oil of almonds 3iij; thick mucilage and simple sirup, of each ^ss ; rose water f Jj; distilled water ^iij or 5'v 5 m'x* Remarks. When well made, this is an elegant and efficient substitute for almond milk. EMULSION OF PERUVIAN BALSAM. Syn. E. Balsamica. E. Balsami Peruviani. Prep. (Ger. H.) Balsam of Peru 3iv; oil of almonds 3vj ; powdered gum §j ; mix, and add cautiously rose water f 5vj- EMULSION, PURGATIVE. Syn. E. Pur- gans cum Scammonio. Prep. (P. Cod.) Virgin scammony 10 grs ; milk f ^iv ; sugar 3iv; cherry- laurel water f 3ij; mix. EMULSION OF SPERMACETI. Syn. E. Cetacei. Prep. (F. H.) as emulsion of wax. De- mulcent. EMULSION OF TURPENTINE. Syn. E. Terebinthina. Prep. Chio turpentine 3ij ; white sugar ^j j yelk of 1 egg; milk of almonds f ^iv ; mix. In gleets. EMULSION OF OIL OF TURPENTINE. Syn. E. Olei Terebinthina. Prep. Oil of tur- pentine 9j ; white sugar §j; yelk of one egg; mix. For nephritic pains. EMULSION OF WAX. Syn. E. Cera. E. C. Alba. Prep. (Guibourt.) White wax §j ; pow- dered gum 3iss; water f §xxiv ; simple sirup f ^iv ; put the wax with the sirup and gum into a warm mortar, triturate with a warm pestle until united, then add the water (warm) gradually, and con- tinue the agitation till quite cold. Demulcent. ENAMELS. Syn. Emaux, (Fr.) Schmelzglas, (Ger.) Transparent or opaque substances, usually formed of glass colored with metallic oxides, and applied in a thin stratum to brightly polished me- tallic surfaces, (copper or gold,) on which they are fused by the flame of a lamp urged by the blow- pipe, or by the heat of a small furnace, an 1 in cooling form a sort of vitreous varnish. The art of enamelling acquired the greatest perfection in ancient times, and very beautiful specimens are still preserved, which the moderns are unable to equal, and with the materials of which they are totally unacquainted. At the present day, this pleasing and useful application of human industry is carried on with the greatest success by the Ve- netians, and, after them, by the French. The limits of this work will not permit a description of the various operations of enamelling, which essen- tially depend on skilful manipulation ; a knowledge of which can only be obtained by long practice. The preparation of enamels being, however, en- tirely dependent on chemistry, I deem it proper to present the following formula to the reader. It is nevertheless right to remark, that almost every artist has his own receipts. (See Cems, and Pastes.) The basis of all enamels is a highly transparent and fusible glass, which readily receives a color on the addition of metallic oxides. As this is required in the preparation of many of those that follow, it is placed first ENAMELS, BASE OR FLUX FOR. Prep. Red lead 16 parts; calcined borax 3 parts ; pow- dered flint glass 12 parts ; powdered flints 4 parts; fuse in a Hessian crucible for 12 hours, then pour it out into water, and reduce it to jt powder in a biscuit-ware mortar. (Wynn. Trans. Soc. Arts, 1817.) II. Powdered flints 10 parts; nitre and white arsenic, of each 1 part; as last. (Wynn.) III. Flint glass 3 oz.; red lead 1 oz.; as last (Wynn.) IV. Red lead 18 parts ; borax (not calcined) 11 parts ; flint glass 16 parts ; as last. (Wynn.) V. Flint glass 6 parts; flux No. II. (above) 4 parts ; red lead 8 parts ; as last. (Wynn.) VI. Tin 2 to 5 parts ; lead 10 parts; calcine in an iron pot at a dull cherry-red heat, and scrape off the oxide as it forms, observing to obtain it quite free from undecomposed metal: when enough of the dross is obtained, reduce it to fine powder by grinding and elutriation, then mix 4 parts of this powder with an equal weight of pure sand or pow- dered flints, and 1 of sea-salt, or other alkaline matter, fuse the mixture in a Hessian crucible, and proceed as before. The best proportions of the tin and lead, for all ordinary purposes, are about 3 cf the former to 10 of the latter. The calcined mixed oxides are commonly called " calcine." VII. Lead and tin, equal parts; calcine as above ; and take of the mixed oxides, or calcine and ground flints, of each 1 part; pure subcarbon ate of potash 2 parts ; as before. (Chaptal.) VIII. Lead 30 parts; tin 33 parts; calcine as before, then mix 50 parts of the calcine with an equal weight of flints, in powder, and 1 lb. of salts of tartar; as before. A fine dead white snamel. (Neri. Kunckel.) Remarks. The precise qualities of the products of the above processes depend greatly upon the duration and degree of heat employed. By in- creasing the quantity of sand, glass, or flux, the enamel is rendered more fusible, and the opacity and whiteness is increased by the addition of oxide of tin. The use of borax should be avoided, or used very sparingly, as it is apt to make the enamel effloresce and lose color. (Tilloch.) ENAMELS, BLACK. Prep. I. Pure clay 3 parts ; protoxide of iron 1 part ; mix and fuse. A fine black. (Clouet.) II. Calcined iron (protoxide) 12 parts ; oxide of cobalt 1 part ; mix and add an equal weight of white flux. III. Peroxide of manganese 3 parts; zaffre 1 part; mix and add it as required to white flux. ENAMELS, BLUE. Prep. Either of the fluxes colored with oxide of cobalt. II. Sand, red lead, and nitre, of each 10 parts ; flint glass or ground flints 20 parts ; oxide of cobalt 1 part, more or less, the quantity wholly depend- ing on the depth of color required. ENAMELS, BROWN. Prep. I. Red lead ENA 269 ENE and calcined iron, of each 1 part; antimony, litharge, and sand, of each 2 parts; mix and add it in any required proportion to a flux, according to the color desired. A little oxide of cobalt or zaffre is frequently added, and alters the shade of brown. II. Manganese 5 parts; red lead 16 parts; flint powder 8 parts ; mix. III. Manganese 9 parts; red lead 34 parts; flint powder 16 parts. (Wynn.) ENAMELS, GREEN. Prep. I. Flux 2 lbs.; black oxide of copper 1 oz.; red oxide of iron £ dr.; mix. II. As above, but use the red oxide of copper. Less decisive. III. Copper dust and litharge, of each 2 oz.; nitre 1 oz.; sand 4 oz.; flux as much as required. IV. Add oxide of chrome to a sufficient quantity of flux to produce the desired shade: when well managed, the color is superb, and will stand a very great heat; but in common hands, it fre- quently turns on the dead-leaf tinge. V. Transparent flux 5 oz.; black oxide of cop- per 2 scruples ; oxide of chrome 2 grs. Resem- bles the emerald. VI. Mix blue and yellow enamel in the requir- ed proportions. ENAMELS, OLIVE. Prep. Good blue enamel 2 parts ; black and yellow do., of each 1 part; mix. (See also Brown Enamels.) ENAMELS, ORANGE. Prep. I. Red lead 12 parts; red sulphate of iron and oxide of anti- mony, of each 1 part; flint powder 3 parts ; cal- cine, powder, and melt with flux, 50 parts. IL Red lead 12 parts; oxide of antimony 4 parts; flint powder 3 parts; red sulphate of iron 1 part; calcine, then add flux 5 parts to every 2 parts of this mixture. (Wynn.) ENAMELS, PURPLE. Prep. I. Flux color- ed with oxide of gold, purple precipitate of cassius, or peroxide of manganese. II. Sulphur, nitre, vitriol, antimony, and oxide of tin, of each 1 lb. ; red lead 60 lbs.; mix and fuse, cool and powder, add rose copper 19 oz.; zaffre 1 oz.; crocus martis 1£ oz.; borax 3 oz.; and 1 lb. of a compound formed of gold, silver, and mercury ; fuse, stirring the melted mass with a copper rod all the time, then place it in crucibles, and submit them to the action of a reverberatory furnace for 24 hours. (Phil. Mag.) Remarks. This is said to be the purple enamel used in the mosaic pictures of St. Peter's at Rome. ENAMELS, RED. Prep. I. Sulphate of iron (calcined dark) 1 part; a mixture of 6 parts of flux (IV.) and 1 of colcothar, 3 parts; dark red. (Wynn.) II. Red sulphate of iron 2 parts; flux (No. I.) 6 parts ; white lead 3 parts ; light red. (Wynn.) III. Paste or flux colored with the red or pro- toxide of copper. Should the color pass into the green or brown, from the partial peroxidizement of the copper, from the heat being raised too high, the red color may be restored by the addition of any carbonaceous matter, as tallow, or charcoal. IV. The most beautiful and costly red, inclining to the purple tinge, is produced by tinging glass or flux with the oxide or salts of gold, or with the purple precipitate of cassius, which consists of gold and tin. In the hands of the skilful artist, any of these substances produce shades of red of the most exquisite hue: when most perfect, the enamel comes from the fire quite colorless, and afterwards receives its rich hue from the flame of a candle or lamp, urged by the blowpipe. ENAMELS, ROSE-COLORED. Prep. Purple enamel, or its elements, 3 parts; flux 90 parts; mix and add silver-leaf, or oxide of silver, 1 part or less. ENAMELS, TRANSPARENT. Either of the fluxes, except the last three. (See also Pastes.) ENAMELS, VIOLET. Prep. Saline or al- kaline frits or fluxes colored with small quantities of peroxide of manga, ese. As the color depends on the metal being at the maximum of oxidation, contact with all substances that would abstract any of its oxygen should be avoided. The same remarks apply to other metallic oxides. ENAMELS, YELLOW. Prep. I. Red lead 8 oz. ; oxide of antimony and tin, calcined toge- ther, of each 1 oz.; mix and add flux (No. IV.) 15 oz. ; mix and fuse. (Wynn.) By varying the proportion of the ingredients, various shades may be produced. II. Lead* tin ashes, litharge, antimony, and sand, of each 1 oz.; nitre 4 oz.; mix, fuse, and powder; and add the product to any quantity of flux according to the color required. III. White oxide of antimony, alum, and sal ammoniac, of each 1 part; pure carbonate of lead 1 to 3 parts, as required; all in powder; mix, and expose to a heat sufficiently high to decompose the sal ammoniac. Very bright. IV. Flux fused with oxide of lead, and a little red oxide of iron. V. Pure oxide of silver added to the metallic fluxes. The salts of silver are also used, but are difficult to manage. If a thin film of oxide of silver be spread over the surface of the enamel to be colored, exposed to a moderate heat, then with- drawn, and the film of reduced silver on the sur- face removed, the part under will be found tinged of a fine yellow. Remarks. Superior yellow enamels are less easi- ly produced than most other colors; they require but little flux, and that mostly of a metallic na- ture. ENAMELS, WHITE. Prep. I. Calcine, (from 2 parts of tin and 1 part of lead calcined together) 1 part; fine crystal or frit 2 parts; a very trifling quantity of manganese ; powder, mix, melt, and pour the fused mass into clean water; dry, powder, and again fuse, and repeat the whole process 3 or 4 times, observing to avoid contami- nation with smoke, dirt, or oxide of iron. A fine dead white. II. Washed diaphoretic antimony 1 part; fine glass (perfectly free from lead) 3 parts; mix, and proceed as before. Very fine. Remarks. For white enamel, the articles must be perfectly free from foreign admixture, as this would impart a color. When well managed, either of the above forms will produce a paste that will rival the opal. ENEMA. (From evvpw, to inject.) A clyster, glyster, lavement, or injection. Medicine usually liquid (sometimes gaseous) thrown into the rectum or lower bowels. The number of substances era • ENE 270 ENE ployed in the preparation of enemata is very great; the following are some of them, arranged accord- ing to their effects. I. (Aperients or Cathartics.) Aloes, colocynth, senna, various purging salts, gruel, decoction of marshmallows, decoction of linseed, warm water, &c, are commonly employed to promote the peristaltic action of the bowels, and to destroy worms. II. Tobacco infusion or smoke is employed to relax the powers of the body, to remove spasms, and to produce syncope. III. Demulcents, as decoction of starch, gum, isinglass, glue, &,c. either alone or combined with opium, are used to protect the coats of the intes- tines and to allay irritation; as also to restrain diarrhoea, especially when combined with astrin- gents, as logwood, catechu, or oak bark. IV. Animal jelly, soups, broths, milk, &c. are frequently used as injections to convey nourish- ment to the body. V. Anodynes and narcotics, as opium, henbane, &c., are employed to allay spasms of the bowels, stomach, uterus, bladder, &.c. It is generally regarded that the susceptibility of the rectum is only A of that of the stomach, and that to exert a like absorbent action, it occu- pies 5 times as long as that viscus; and that, con- sequently, the dose and the interval between its repetition should be proportionally increased. This has been shown, however, not to be universally correct, for according to Orfila, and some other authorities, narcotics, as opium, tobacco, &c, are more readily absorbed by the rectum than the stomach. Others deny this altogether, and assert that 2 or 3 times the ordinary dose of opium may be exhibited per anum, without producing any remarkable effect. (Pereira, Christison.) Clysters usually consist of some weak glutinous or mucilaginous fluid, to which the active ingre- dients are added ; or a decoction or infusion is made of the medicaments. In either case the fluid is administered warm. The quantity for an adult may vary from £ to £ of a pint; that for an infant within a month old, should be about 1 oz.; for a chi.~ 1 year old, about 2£ oz.; from 1 to 7 years, from 3 oz. to 4 oz.; and from that age to 12 or 14, from 6 to 7 oz.; after that age to puberty, £ a pint may be employed. Clysters are usually administered by means of a syringe, bladder, or elastic bag, furnished with a rectum tube. Great care should be taken to avoid injuring the coats of the rectum by the use of an improperly shaped pipe, or one that is too long. A neglect of this point often produces very serious consequences in young children. The extremity of the pipe or tube should be perfectly smooth, well rounded, and rather spherical than pointed, and in using it no force should be employed. I once witnessed a case where a young infant lost its life, from an ignorant nurse forcibly thrusting the tube of a sy- ringe through the upper parts of the rectum, in her attempt to administer a clyster. Tobacco smoke may be administered by means of a double pair of bellows, supplied with air from a small funnel under which the herb is burning,— and gaseous matter, by connecting the rectum tube with a small gasometer, exerting a trifling pressure on the confined gas. The injection of large quantities of liquid mat- ter into the bowels, as well as the constant use of clysters, (even of warm water,) is deemed by the highest medical authorities to be injurious. The bowels, continually accustomed to a stimulant, cease to act without one. ENEMA, ANODYNE. Syn. Enema Anody- num. Prep. Starch jelly £ pint; laudanum 40 to 60 drops; mix. In dysentery, diarrhoea, cholera, colic, &c. II. (For horses.) Opium 1£ dr., (or laudanum 1£ oz.;) water gruel 2 or 3 pints ; mix. » E N E M A, ANTISPASMODIC. Syn. E. Antispasmodicum. Prep. Tincture of asafoetida ^ss ; laudanum 40 drops; thin gruel half a pint; mix. For spasmodic affections of the bowels. ENEMA, ASTRINGENT. Sy„. E. Astrin- gens. Prep. (H.) Electuary of catechu 3ij; lime water f%v; water 5 or 6 oz.; mix. In diarrhoea, &c, arising from a relaxed state of the coats of the intestines. II. Any of the astringent decoctions ■'as pome- granate, cinchona, oak bark, galls, &c, 3 oz.; water or barley water 6 or 8 oz.; mix. As the last. ENEMA, CATHARTIC. Syn. E. Cathar- ticum. (Purging clyster.) Prep. I. (P. D.) Manna §j; compound decoction of chamomile £ pint; add olive oil §j; Epsom salts ^ss ; mix. II. (P. E.) Senna §ss; water f^xvj; infuse, add Epsom salts ^ss ; sugar and olive oil, of each §j ; mix well. Both the above are purgative. III. Epsom salts §j ; dissolve in water gruel or barley water §xj ; then add sweet oil Jj ; mix well. Purgative. IV. Compound decoction of mallows £ pint; Epsom salts 3j', sweet oil f ^ij; mix, as above. V. (For horses.) Common salt 8 oz.; warm water 1 gallon ; dissolve. VI. (For cows.) Common salt 12 oz.; water 10 pints; dissolve. ENEMA. COMMON. Syn. E. Commune. Prep. (St. B. H.) Barley water 1 pint; com- mon salt §j ? dissolve. Purgative. Decoction of mallows, linseed tea, or water gruel, may also be used as the solvent. ENEMA, DOMESTIC. Syn. E. Domesti- cum. Prep. (E. H.) Milk £ pint; sugar or ho- ney and olive oil, of each ^j ; mix. Laxative and nutritive. II. Mutton broth and oil, of each 4 oz.; brown sugar 1 oz.; dissolve. As last. ' ENEMA, EMOLLIENT. Syn. E. Emol- liens. Prep. (H.) Decoction of linseed, barley, or starch, 1 pint; linseed or olive oil 1 oz.; mix. Emollient; demulcent. ENEMA FOR COLIC. Syn. E. Anticoli- cum. Prep. Infusion of chamomile f§x; oil of cajeput or peppermint 5 drops; (dissolved in) sweet spirits of nitre 40 drops; laudanum 10 drops; mix. ENEMA FOR FEVER. Syn. E. Febrifu- gum. Prep. (Collier.) Thin gruel f ^xij ; sugar ^j *, mix. In low fevers. ENEMA FOR WORMS. Syn. E. Vermifu- gum. Prep. (Collier.) Oil of turpentine f£j; olive oil £ pint; mix. In ascarides. ENEMA, LAXATIVE. Syn. E. L^xativum. Prep. (Richard.) Linseed and senna, of each ^ss *i ENE 27 water 1 £ pint; boil to a pint, strain and add glau- ber or Epsom salts 3ij to 3iij. ENEMA, NOURISHING. Syn. E. Nutri- ens. Prep. Strong beef tea 12 oz.; thicken with hartshorn shavings or arrow-root. To nourish the body when aliments cannot be received by the tnouth or retained by the stomach. ENEMA OF ALOES. Syn. E. Aloes. (P. L.) Prep. Aloes 3ij ; carbonate of potassa 15 grs.; barley water f§x; mix. In ascarides, atonic amenorrhcea, &c. It should not be employed when irritability of the rectum, bladder, or genitals ex- ists, nor in piles. ENEMA OF ASAFGETIDA. Syn. E. Fce- tidum. (P. E. & D.) Prep. Add f 3ij of tincture of asafcetida to the cathartic clyster. Stimulant, antispasmodic, carminative, and purgative. An excellent remedy in hysteria, flatulent colic, in- fantile convulsions, worms, hooping-cough, &c. ENEMA OF CAMPHOR. Syn. E. Cam- phora. Camphor Clyster for Horses. Prep. Camphor £ oz. ; dissolve in sweet oil by heat; add \ oz. of subcarbonate of potash, mix well together, and add gradually warm water 1 quart. Diuretic. In difficult or obstructed micturition. ENEMA OF COPAIBA. Syn. E. Copaiba. Prep. (Collier.) Balsam of copaiba 3ij ; oil of tur- pentine 3iv ; extract of opium 1 gr.; make an ene- ma with the yelk of egg. In ascarides and cer- tain complaints. ENEMA OF COLOCYNTH. E. Colocyn- thidis. (P. L.) Prep. Compound extract of colo- cynth 3ij ; soft soap ^j j warm water 1 pint; carefully mix the first two by trituration, then gradually add the water. A strong purgative in colic and constipation without spasms. ENEMA OF OPIUM. Syn. E. Orn. E. Opiatum. E. Anodynum. Prep. (P. L.) De- coction of starch f fiv; laudanum 30 drops ; mix. II. (P. E.) Starch §ss; laudanum 30 to 60 drops; water f3ij ; make the starch into a muci- lage with the water, boiling; and when cooled suffi- ciently, add the tincture. III. (P. D.) Laudanum 3j; water §vj ; mix. Remarks. The above are the orders of the Col- leges, but in practice the quantity of laudanum is frequently doubled ; this should, however, be done with great care. Opium clysters are used in dys- entery, colic, cholera, and various painful affec- tions of the intestines, bladder, &c. The bowels should be emptied before its administration, and in inflammatory complaints it should not be used for the first 48 hours. Clysters containing opium, even in small quantities, are dangerous remedies for young children. ENEMA OF TOBACCO. Syn. E. Tabaci. (P L.) Prep. Tobacco 3j; boiling water 1 pint; macerate for 1 hour, and strain. Violently depress- ing and relaxing; producing fainting. It is ex- hibited in strangulated hernia, &c.: 3 parts of Vir- ginian tobacco are equal to 7 parts of any other kind. (Davy.) ENEMA OF TURPENTINE. Syn. E. Te- rebinthina. (P. Ii.) Prep. Oil of turpentine fjj ; yelk of egg, a sufficiency ; rub together until uni- ted, then add barley water f f xix ; mix. In calcu- lus, flatulent colic, ascarides, &c. (See Enema for Worms.) ENEMA OF SOAP. Syn. E. Saponis. Prep. ERU (St. B. H.) Soft soap 3vj; hot water 1 pint; dis- solve. ENEMA, STIMULANT. Syn. E. Stimulans. (F. H.) Colocynth pulp 3j; boil in water 1 pint till reduced to two-thirds, then add common salt and sirup of buckthorn, of each 3j. Cathartic. II. (For Horses.) Common salt and linseed oil, of each 8 oz.; hot water 1 gallon; gum arabic 1 oz.; mix. In stomach staggers. ERGOT. Syn. Spurred Rye. Secale Cor- nutum. Ergota. Diseased grains of rye, much used as an emmenagogue in small doses, and to accelerate the contraction of the uterus in protract- ed labor. The dose is 10 to 15 grs. every 10 or 15 minutes, either in powder, or made into an infu- sion. Pres. Ergot of rye deteriorates greatly by age. It is fed on by a description of acarus resembling the cheese mite, but much smaller, and this insect in time destroys the whole of the internal portion of the grain, leaving nothing but the shell, and a considerable quantity of excrementitious matter. To prevent this the ergot should be we!! dried, and then placed in bottles or tin canisters, and closely preserved from the air. The addition of a few cloves, or drops of the oil of cloves, or strong acetic acid, or a little camphor, or camphorated spirit of wine, will preserve this substance for years in close vessels. The following method has been proposed by M. Martin, and is likely to prove efficacious, but is somewhat troublesome:— Ergot in good condition and very dry is steeped in a concentrated solution of gum arabic, and dried on a sheet of white iron. When it is dry the op- eration is repeated: two or three immersions are sufficient. When the last layer of gum is perfect- ly dry, the ergot is kept in a very dry and well- corked flask. Gum arabic cannot be prejudicial to the effect of ergot of rye. (Jour, de Chimie Med. 1841.) Ergot is mostly kept in large well covered tin canisters or boxes, by the wholesale druggists, and these are placed in a dry situation. ERGOTINE. Syn. Ergotina. A substance discovered by Wiggers in ergot of rye, and of which it appears to be the active constituent. Prep. Submit ergot (previously ground in a coffee-mill, not powdered) to the action of ether to remove the fatty portion, then digest it in boil- ing alcohol, and evaporate the latter solution to the consistence of a sirup ; treat this fluid extract with water, which will dissolve the foreign matter, and leave the ergotine behind. It may be further purified by re-solution in hot alcohol. Props., Uses, fyc. Ergotine, as thus prepared, has a brownish red color, an acrid bitter taste, and a peculiar unpleasant odor when warmed. Nine grs. are said to be equivalent to 1£ oz. of ergot ERGOT, ESSENTIAL SOLUTION OF. (Lever's.) Prep. Ergot, coarsely powdered, 5'V ; ether f^iv; digest for 7 days; submit to sponta- neous evaporation, and dissolve the residuum in ether f^ij. Dose. 15 to 30 drops on sugar. It exercises a similar action on the uterus to the crude ergot. ERUCINE. A yellowish white substance, dis- covered by Simon in white mustard, (sinapis alba.) It is soluble in ether and essential oils, and in boiling alcohol. ESP 272 ESS ERYTHRIN'E, Pseudo-erythrine, Erythri- LINE, Amarythrine, Telerythrine. Substances obtained by Kane and Heeren from parmelia roc- cella and leconara Tartarea. The names have been differently applied by these authorities, and hence has arisen some confusion. They are of little interest except in a theoretical point of view. ERYTHROLEINE, Erythrolitmine, Azo- litmine, Azoerythrine, Spamolitmine, Ery- throleic Acid. Substances obtained from litmus and archil by Kane. They are but little known, and have not been applied in the arts. ESCHAROTIC. Syn. Escharoticus. (Lat, from ta%apou), to scab over.) Any substance that destroys the texture of living organic sub-tances, with the production of an eschar ^m^upa) or scab. Escharotics have been divided into eroding eschar- otics; as blue vitriol, red precipitate, burnt alum, &c.; and into caustic escharotics; as lunar caus- tic, pure potassa, strong sulphuric acid, nitric acid, &c. All caustics that produce a scab, or eschar, are properly escharotics. (See Caustics.) ESCHAROTIC SOLUTIOxN. (Freyburg's.) Prep. Camphor 30 grs.; corrosive sublimate 460 grs.; strong alcohol 450 grs.; dissolve. This is employed in the Hospital of Charity at Berlin in syphilitic vegetations, and especially against con- dylomes. It is spread over the diseased surface, either at once, or after the application of a liga- ture. ESCULENTS. (Esculentus, Lat.) Animal and vegetable substances used for food. ESCULIC ACID. A peculiar acid found by M. Bussy in the bark of the horse-chesnut. It is but little known, and has not been applied to any use. ESENBECKINE. An alkaloid found by Buchner in the esenbeckia febrifuga. ESPRIT. (Fr.) Spirit. This term is applied to alcoholic solutions of the essential oils and to various odorous and aromatic essences. Sold by the perfumers. ESPRIT DE BERGAMOTTE. Syn. Spi- rit of Bergamotte. Prep. Peel of the Berga- motte orange 2 lbs.; proof spirit 1 gallon ; digest for a week, add water 1 quart, and distil 1 gal- lon. II. Essence of bergamotte (best) 5 oz.; essence of ambergris (pale) 2 oz.; essence of musk £ oz.; oil of verbena \ oz.; rectified spirit of wine 1 gal- lon ; mix. An elegant perfume. ESPRIT DE LA ROSE. Syn. Spirit of Roses. Prep. I. Fresh petals of roses 8 lbs.; rectified spirit of wine £ gallon; macerate for a week, and distil to dryness in a water bath. II. Salted petals 14 lbs.; spirit of wine 4£ pints; distil £ gallon. III. Attar of roses 2 dr.; neroli 20 drops ; spirit of wine 1 gallon; dissolve, add chloride of cal- cium, well dried and in powder, 1 lb.; agitate well, and distil 7 pints. Very fine. IV. Spirit of wine 1 quart; otto £ drachm; mix, place the bottle in hot water so as to warm the spirit, then cork close, shake until cold, and the next day filter if required. ESPRIT DE SAVON. Syn. Spirit of Soap. Essence of do. Shaving Fluid. Prep. Vene- tian soap | lb.; subcarbonate of potash 1 oz.; ben- zoin £ oz.; spirit of wine 1 gallon; digest for a week, or until the whole is dissolved, then filter. II. Best soft soap $ lb.; boiling water 1 pint; dissolve, cool, and add oils of cinnamon, (cassia,) verbena, and neroli, of each, 4 drops; dissolved in rectified spirit of wine 1 pint; mix well, and if not perfectly transparent, filter through blotting paper. Remarks. Instead of the above perfumes, 15 drops of essence of musk or ambergris, or 30 drops of any of the perfumed spirits, or 3 drops of attar of roses, or 6 drops of any of the aromatic essen- tial oils, may be added, when a corresponding name is given to the preparation, as esprit de Sa- von de la rose, &c. This alcoholic solution of soap is used for sha- ving, and is very convenient in travelling, as a good lather may be instantly produced without the trouble of employing a soap-box. ESPRIT DE SUAVE. Prep. Essences of cloves and bergamotte, of each, 1 £ dr.; neroli £ dr.; essence of musk 1 oz. ; eau de rose, spirits of tuberose, and the strongest spirits of wine,-of each, 1 pint; spirits of jasmin and cassia, of each, 1 quart; dissolve the essences in the spirit of wine, then add the other spirits, and when well mixed add the rose-water. A most delicious per- fume. ESPRIT DE TAIN. Syn. Spirits of Lem- on Thyme. Spiritus Thymi. Prep. Tops of lemon thyme 1 lb. ; proof spirit 1 gallon ; distil 7 pints. " ESPRIT DE VIOLETTES. Syn. Spirit of Violets. Essence of do. Essence of Or- ris. Prep. I. Florentine orris root, reduced to coarse powder, \ lb.; rectified spirit of wine 1 pint; digest for 14 days, and strain with expres- sion. II. Orris (as above) 5 lbs.; rectified spirit 1 gal- lon ; digest as before and submit the root to pow- erful pressure in a tincture press, to extract the last portion of the liquor; filter. Very fragrant This may be advantageously prepared by percola- tion. ESSENCE. Syn. Essence. Esprit, (Fr.) Essentia, (Lat., from esse, to be, or exist) That part of a substance on which its most remarkable properties depend. The term has been very gen- erally applied to preparations of vegetables or organic substances, that contain their active prin- ciples in a concentrated form, but it is more properly restricted to the volatile oils obtained from vegetables by distillation, or to a solution of these oils in alcohol. In Pha-rmacy the word es- sence is very commonly applied to concentrated preparations that vastly differ from each other. Thus, concentrated infusions, decoctions, liquors, and tinctures are frequently called essences by the druggists, but the term "fluid extracts" would be more appropriate. The present article will be confined to a short notice of the principal compound essences, or those that undergo some preparation, beyond being merely extracted from vegetables by distillation aiong with water. The latter will be considered under the article Oils. Prep. The Concentrated preparations of the pharmaceutist, termed essences, are mostly pre- pared by digesting the active ingredient in recti- fied spirit of wine, either with or without tho addi- ESS 273 ESS tion of a certain portion of water; or they are extemporaneously formed by dissolving a certain portion of the essential oil of 6uch substances in the spirit. In this way are made the essences of lavender, of musk, and of ginger. When it is desired only to obtain the aromatic and volatile portion of the ingredients, the latter are usually first digested in the spirit for a few days, and then submitted to distillation, when the alcohol comes over fragrant, and loaded with aromatic essential oil, or other volatile matter. In this way are pre- pared most of the fragrant essences of the per- fumer and druggist, when simple solution of the essential oils in alcohol is not resorted to. In many cases the active principles of the ingredients are partly volatile, and partly fixed, or at least do not readily volatilize at the temperature a}, which alcohol distils over. This is the case, for instance, with the active portion of cubebs and Jamaica ginger. In such cases digestion alone-should be adopted. When the principles of organic sub- stances, of which it is desired to obtain a concfen- trated solution, are resinous, oily, or but little solu- ble in weak spirit, which is mostly the case, the strongest rectified spirit of wine should alone be employed. In the preparation of essences, with- out distillation, the method by percolation is pref- erable to that of simple maceration and expression, as it is not only.more economical, but a more con- centrated solution may thereby be obtained. The ingredients for the preparation of essences must undergo the same operations of bruising, powder- ing, or slicing, as is directed under Tinctures, previous to digestion in the spirit, or other men- struum ; and the length of time they should be allowed to infuse, when this method alone is adopted, should not be less than ten days; but this time may be advantageously extended to a fortnight, or longer. During the whole of this pe- riod frequent agitation should be employed, and when the ingredients are so bulky as to absorb the whole of the fluid, the vessel which contains the mixture should be securely fastened by a bung covered with bladder, and inverted every alternate day. By this means, the fluid will equally extract the virtue of every portion of the ingredients. In all such cases percolation is preferable. For the essences used as perfumes and flavoring, not only must the spirit be perfectly tasteless and scentless, but it must be also quite devoid of color. (See Concentrated Decoctions, Infusions, Liquors, Spirit, and Percolation.) ESSENCE, ANODYNE. Syn. Essentia Anodyna. Prep. (Germ. Ph.) Aqueous extract of opium ^i ; spirits of cinnamon fjix ; dissolve. ESSENCE, ANTI-HYSTERIC. Syn. Ess. Anti-hysterica. Prep. (P. Cod.) The same as fetid spirit of ammonia. ESSENCE, BITTER. Syn. Ess. Amara. Prep. (Ph. Den.) Wormwood 4 parts; gentian root, bitter orange peel, and blessed thistle, of each 1 part; alcohol 45 parts ; digest for a week. Dose. £ dr. to 2 drs., combined with mixtures. Tonic and stomachic. ESSENCE, CEPHALIC. Syn. E. Cephali- CA. Prep. (Dr Ward.) The same as the com- pound camphor liniment, P. L. ESSENCE D'OZILLETS. Prep. Cinnamon 3 oz.; cloves li oz., (both well bruised;) rectified spirit 2 quarts; digest for a week. Oil of clove* also bears this name. ESSENCE D'ORIENT. A pearly-looking substance, found at the base of the scales of the blay or bleak, a small fish of the genus cyprinus. It is employed in the arts for the manufacture of factitious pearls. Prep. The scales are scraped from the fish into a tub containing water, and after agitation and re- pose, the fluid is poured off, and its place supplied with fresh water, and this in its turn, after agita- tion and repose, is also poured off. This part of the operation is repeated till the essence aud scales are perfectly freed from impurities, when the whole is thrown on a sieve, which retains the latter, but allows the former to flow through. The essence is then obtained as a deposite at the bottom of the vessel. Remarks. This substance has a bluish white and pearly aspect, and is employed to cover the interior of glass bubbles and beads, in imitation of pearls, or mother of pearl. Its tendency to putre- faction, while in the moist state, may be obviated by the addition of a little water of ammonia. ESSENCE DE MYRTE. Syn. Essence of Myrtle Blossoms. Prep. Myrtle tops (in blos- som) 1£ lb.; proof spirit 9 pints; digest 3 days, then distil 1 gallon. A pleasant perfume. ESSENCE DE TUBEROSE. Prep. The flowers are stratified with sheep's or cotton wool, impregnated with the purest oil of ben or olives, in an earthen vessel, closely covered, and kept for 12 hours in a water bath; the flowers are then re- moved and fresh ones substituted, and this is re- peated until the oil is sufficiently scented. The wool or cotton is then mixed with the purest spirit of wine, and distilled in a water bath, or else di- gested in a warm situation, and in a well closed vessel, for several days ; during the whole of which time frequent agitation should be had recourse to. In a similar way may be made the essences of jasmine, violets, and other flowers. (See Spirit.) ESSENCE DES VIOLETTES. (See Es- prit des Violettes, and Spirit of Violets.) ESSENCE FOR THE HEADACHE. (WARD'S.) Prep. Liquor of ammonia, 4 oz.; English oil of lavender £ dr.; camphor 1 oz.; spirit of wine 1 pint; dissolve. Stimulant; rube- facient ; used for local pains, as headache, colic, &.c. Compound camphor liniment is usually sold for it. ESSENCE OF ALLSPICE. Syn. Ess. of Pimento. Ess. Pimenta. Prep. Essential oil of allspice 1 oz.; spirit of wine 1 quart; dissolve Used as a flavoring by cooks and confectioners ESSENCE OF ALLSPICE, CONCEN- TRATED. Oil of allspice 1 oz.; strongest spirit of wine 1 pint; mix. As last. ESSENCE OF AMBERGRIS. Syn. Ess Ambra Grisea. Tinctura do. Prep. I. Am- bergris £ oz.; rectified spirit of wine 1 pint; cut the ambergris into small fragments, place it in a strong vessel, secure the mouth very firmly, and expose it to the heat of the sun or in an equally warm situation for 1 or 2 months, frequently sha- king it during the time; lastly decant, and filter through paper. II. To the last add a fresh emptied musk bag and proceed as before. ESS 274 ESS III. Ambergris 2 oz.; bladder musk 1 *oz.; spirit of ambrette 1 gallon ; as before. IV. Ambergris £ oz.; musk 3 drs.; lump sugar 2 drs.; grind together in a smooth Wedgwood- ware mortar, add 10 drops of oil of cloves, 20 drops of true balsam of Peru, and enough essence of jasmine or tuberose to convert it into a perfectly smooth paste; then put it into a strong bottle with 1 quart of rectified spirit of wine, observing, before adding the whole of the last, to raise the mortar out well with it, that nothing may be lost; lastly, digest for 6 or 8 weeks, as above. Remarks. Essence of ambergris is used as a perfume, and is added in small quantities to sweet- scented spirits and wines, to improve their flavor and aroma. The last two formulas produce re- markably fine products. A very small quantity of either of these added to lavender water, eau de Cologne, tooth-powder, hair-powder, wash-balls, or a hogshead of claret, communicates a delicious fragrance. ESSENCE OF AMMONIACUM. Syn. Ess. Ammoniaci. Prep. I. Ammoniacum in tears 1 lb.; bruise it in a very cold marble mortar with half its weight of coarse and well-washed silicious sand or powdered glass; add gradually rectified spirit of wine £ pint, work the whole to a smooth paste, then place it in a wide-mouthed bottle, and further add spirit of wine 1£ pints; cork down close, digest for a week with constant agitation, allow it to repose until quite settled, then pour off the supernatant transparent liquid into another bottle for use. II. Reduce 1 lb. of gum ammoniacum to a cream with f pint of boiling water, cool a little, place it in a strong bottle, and add cautiously 1$ pint of rectified spirits of wine, cork down close, and macerate for a few days ; lastly, place the bottle in a moderately warm situation that the sediment may subside, after which pour off the clearest portion through flannel into another bottle. Remarks. Both the above are used as substi- tutes for the gum in substance, for extemporane- ously preparing the milk and mixture of ammo- niacum, &c. They are said to possess equal medicinal virtue, with the same weight of solid gum. The product of the first process, when well managed, is a beautiful pale brownish-colored transparent tincture ; that of the second is milky. ESSENCE OF AMMONIACUM, (CON- CENTRATED.) The preparation usually sold under this name, and represented as twice as strong as the gum in substance, is generally pre- pared with the same quantity of ingredients as the first of the above. A stronger article may be pre- pared by a similar process by using 1 lb. of ammo- niacum to a pint of the strongest rectified spirit. As, however, a clear liquid at this strength is somewhat difficult to produce, it is very seldom attempted by druggists; they therefore generally content themselves with sending out the liquid at half the professed strength, leaving the label to confer the additional concentration. ESSENCE OF ANCHOVIES. Prep. I. An- chovies 7 lbs.; pulp through a fine hair or brass- wire sieve ; boil the bones and portion that will not pass through in water 5 quarts; strain, add to the clear liquid the pulped fish, and salt and flour, of each 1 lb-, along with red bole, or infusion of co- chineal, sufficient to color, and again pass the whole through the sieve. The product will be about 20 lbs. II. To the last add Cayenne pepper \ oz.; the grated peel of a lemon, and mushroom catsup, 4 oz. III. Use British anchovies (pickled sprats) oi young pilchards, along with herring liquor, or the drainings of anchovy barrels. Use. As a sauce and condiment; when well prepared it has a fine flavor. ESSENCE OF BITTER ALMONDS. (See Almond Flavor.) ESSENCE OF BITTER ALMONDS, (CONCENTRATED.) Prep. Essential oil of almonds 2 oz.; rectified st.rit of wine 1 pint; dis- solve. Very powerful. (See page 49.) ESSENCE OF CHAMOMILE. Prep. Es- sential oil of chamomile £ oz. to 1 oz.; spirit of wine 1 pint; mix. White. II. Gentian root, sliced or bruised, 1 lb.; dried orange peel \ lb.; spirit of wine 1 gallon; essen- tial oil of chamomile 5 oz.; macerate a week. Slightly colored. Some persons use £ lb. of quas- sia wood, instead of the gentian and orange peel. Both the above are stomachic and tonic. ESSENCE OF CAMPHOR. Syn. Ess. Camphora. Do. Concentrated. Prep. Cam- phor (clean) 4£ oz.; rectified spirit of w ae 1 gal- lon ; dissolve. Remarks. There is a large quantity of this so- lution of camphor sold by the wholesale druggists, who charge a considerable price for it. It is very convenient for preparing extemporaneous camphor julep or mixture. About £ dr. added to 7£ drs. of distilled water forms 1 oz. of a transparent aque- ous solution of camphor. (See Camphor Julep, p. 156.) ESSENCE OF CAPSICUM. The same as Essence of Cayenne. ESSENCE OF CARAWAY SEEDS. Syn. Ess. Carui. Concentrated Ess. of Caraways. Prep. Essential oil of caraway 1 oz.; spirit of wine 1 pint Used in dispensing, and by confectioners and cooks as a flavoring. ESSENCE OF CARAWAY SEEDS, (dou- ble distilled.) Essential oil 2 oz.; spirit of wine 1 pint. ESSENCE OF CAYENNE. Syn. Ess. Cap- sici. Concentrated Essence of Cayenne Pep- per. Prep. Capsules of capsicum, bruised, 3 IBs.: rectified spirit 1 gallon; digest for 14 days, then press and filter. Remarks. This liquid has an intensely burning taste ; one drop is sufficient to deprive a person of the power of speech for several seconds. It is used as a flavoring, and for making soluble cayenne pepper; also in dispensing. ESSENCE OF CASSIA. Syn. Ess. C assize Prep. Oil of cassia 1 oz.; spirit of wine 1 pint j mix. Used as a flavoring, &c. ESSENCE OF CARDAxMOMS. Syn. Ess. Cardamomi. Do. do. concent. Prep. Lesser cardamom seeds 5£ lbs. ; spirit of wine 1 gallon; digest for a fortnight; press and filter. Remarks. This preparation is very convenient for flavoring cordials, pastry, &c. It is very pow- erful. In the druggist's laboratory it is frequently substituted for powdered cardamoms in making ESS 275 ESS compound extract of colocynth, and for this pur- pose has the advantage of adding no inert matter, while it imparts the characteristic odor of the seeds in a remarkable degree. When used in this way, it is added to the Extract when nearly cold and about to be taken from the pan. Cardamom seeds are very difficult to bruise in a mortar, and seldom get perfectly crushed, even after long beating. It will be found much the best plan to grind them in a pepper-mill. The tests should be separated from the kernels, as the for- mer are quite inert, and if used occasion a loss of Bpirit for no purpose. ESSENCE OF CELERY SEED. Syn. Con- centrated Ess. of Celery. Prep. Celeryseeds, bruised, 4 oz.; proof spirit 1 pint; digest 10 days or more. Use. As a flavoring. It is better if pre- pared with rectified spirit, when double the weight of seed may be used. ESSENCE OF CINNAMON. Syn. Ess. Cinnamo.mi. As Essence of Cassia. Used in con- fectionery and cookery. ESSENCE OF ClVETTE. Syn. Ess. Zi- bethi. Prep. I. Civette 1 oz.; spirit of wine 1 pint ; as essence of musk. II. Instead of spirit of wine use spirit of am- brette. Used as a perfume. ESSENCE OF COLTSFOOT. Prep. I. Bal- sam of tolu 1 oz.; compound tincture of benzoin and rectified spirit of wine, of each 2 oz.; dissolve. II. Tincture of tolu, compound tincture of ben- zoin, and spirit of wine, of each equal parts. Remarks. This balsam is pectoral and stimu- lant. It is a quack remedy for consumption and most diseases of the lungs, but is more likely to kill than cure in these complaints. ESSENCE OF CUBEBS. Syn. Ess. Cube- ba. Prep. Cubebs 4 lbs., (bruised, or preferably ground in a pepper-mill;) rectified spirit 1 gallon; digest 14 days, press and filter. This essence has a very large sale, and if carefully prepared from a good sample of the drug, is a most excellent prep- aration. It is generally called " Concentrated Es- sence of Cubebs." II. (Dublanc.) Oleo-resinous extract of cubebs ^j; rectified spirit ^iij; dissolve. This is a very active and concentrated form of administering cu- bebs, but must not be confounded with the pre- ceding. The former is the one always meant when " Essence of Cubebs" is ordered. ESSENCE OF DILL. Syn. Ess. Anethi. Prep. I. Oil of dill (anethum) ffj ; spirit of wine f fxix ; mix ; white. II. Oil of dill, extract of dill, and salt of tartar, of each 5s8 > spirit of wine j pint; digest and strain. Remarks Both the above are aromatic and flatulent The first is commonly us°d as an ad- junct to other medicines, especially purgat:ves for children. ESSENCE OF ERGOT. Syn. Ess. Ergota. Ess. Secali Cornuti. Concentrated Ess. of Ergot of Rye. Prep. Ergot, reduced to coarse powder by pounding, or preferably by grinding in a pepper-mill, 1 lb.; boiling distilled water 4 lbs.; mix in a close vessel, and digest with agitation until cold, then put it into a wide-mouthed bottle, and add rectified spirit 2 lbs.; macerate for a week, Dress and filter. Remarks. 4 dr. of this essence are equal to 1 dr. of ergot in substance. It is 8 times the strength of the infusion, (as usually prepared according to the formula of Pereira and others,) and 2£ times the strength of the tincture of ergot of the London Apothecary's Hall. ESSENCE OF GINGER. Syn. Ess. Zingi- bers. Concentrated. Ess. of Ginger. Prep. I. Unbleached Jamaica ginger 4 oz., (well bruised ;) rectified spirit of wine 1 pint; digest for a fortnight, press, and filter. II. (Oxley's concentrated Essence of Jamaica Ginger.) The same as the preceding, with the addition of a very small quantity of essence of cayenne. III. Bruised unbleached Jamaica ginger 12 lbs.; rectified spirit of wine 2£ gallons; digest 14 days, press, strain, and reduce the essence by distilla- tion to 1 gallon ; cool and filter. Remarks. This produces a most beautiful article. A certain me- tropolitan drug-house that does very extensively in this preparation, employs this form. It is at once inexpensive and easily performed, as the spi- rit distilled off may be used with advantage for preparing the common tincture of ginger, and sev- eral other articles; 2 oz. of this essence are re- garded as equivalent to 3 oz. of the finest ginger. A single drop swallowed will almost produce suf- focation. IV. Digest 12 lbs. of ginger in 3 galls, of spirit of wine, as last, and reduce the tincture by distil- lation to 4 pints, then cool as quickly as possible out of contact with the air, and add, of the strong- est rectified spirit of wine £ a gallon ; lastly, filter if required. Quality remarkably fine. V. Ginger and animal charcoal, both in coarse powder, equal parts ; add enough rectified spirits of wine to perfectly moisten them, and after 24 hours put the mass into a " percolator," return the first runnings 2 or 3 times, then change the re- ceiver, and pour on spirit gradually as required, and at intervals, until as much essence is obtained as there was ginger employed. Remarks. Quality excellent The mass remaining in the percolator may be treated with fresh spirit until exhausted, and the tincture so obtained may be advantageous- ly employed, instead of spirit, in making more es- sence with fresh ginger. The last portion of spirit in the mass may be obtained by adding a little water. (See Percolation.) ESSENCE OF GUAIACUM. Syn. Ess. Guaiaci. Concentrated Ess. of Guaiacum. Fluid Extract of do. Prep. Guaiacum shavings, from which the dust has been sifted, 3 cwt. Exhaust the wood by boiling with water, as in preparing an extract, using as little of that fluid as is absolutely necessary; evaporate to exactly 1| gallons; let it stand until cold, stirring it a!l the time to prevent the deposite of resinous matter ; put the whole into a bottle, add spirit of wine 5 pints; agitate repeat- edly for a week, then allow it to settle for 7 or 8 davs, and decant the clear into another bottle. R, marks. This preparation is frequently substi- tuted for guaiacum shavings in the preparation of compound aeroction of sarsaparilla. 1 pint of this essence is considered equivalent to 19 lbs. of guaia- cum in substance. ESSENCE OF LEMON-PEEL. Syn. Ess, Corticis Limonis. Quintessence of Lemon-rind ESS 276 . ESS Prep. I. Yellow peel of fresh lemons £ lb.; spirit of wine 1 pint. Digest for a week, press, and filter. Very fragrant. II. Yellow peel of fresh lemons 1 lb.; boiling water £ gallon. Infuse 1 hour, express the liquor, boil down to £ a pint, cool, and add essence of lemon \ oz., dissolved in spirit of wine 1£ pints; mix well, and filter. Remarks. The above are used by cooks and confectioners as a pleasant flavorinf. Essence of orange-peel is made in the same way. ESSENCE OF MUSK. Syn. Ess. Moscm. Tinctura do. Prep. I. Grain musk 2 oz. ; boil- ing water 1 pint. Digest in a close vessel until cold, then add rectified spirit of wine 7 pints ; car- bonate of potassa £ dr. Cork close, and digest in a matrass, in the sunshine, for 2 months, if in sum- mer, or in winter in an equally warm situation. A water-bath may be employed to facilitate the pro- cess. II. Substitute 1 oz. of liquor of ammonia for the carbonate of potassa in the last formula. III. Grain musk 2 drs.; spirit of wine 2 pints ; essence of ambergris 1 oz. As above. IV. Musk from the bladder, cut small, 5 oz.; civet 1 oz.; essence of ambergris 1 pint; spirit of ambrette 1 gallon. As before. Remarks. All the preceding formula? yield fine essences, but the product of the last is of the very finest quality, and such as is seldom sold except by the most celebrated houses, when it fetches a very high price. It is powerfully and deliriously odorous. ESSENCE OF MUSTARD, (WHITE- HEAD'S.) Prep. Oil of turpentine 1 pint; cam- phor, oil of rosemary, and flower of mustard, of each £ oz. ; mix. ESSENCE OF NEROLI. Prep. I. Neroli 2 dr.; spirit of wine 1 pint; mix. A pleasing per- fume. II. Oil of orange 2 drs.; orris root, bruised, £ oz.; ambergris 10 grs.; neroli 15 drops; spirit of wine 1 pint; digest 14 davs. Very fragrant. ESSENCE OF NUTMEG. Syn. Ess. My- ristica. Ess. Nucis Moschata. Prep. Essen- tial oil 1 oz. ; rectified spirit 1 pint; dissolve. Use. As a flavoring in the arts of the cook, liqueurist, and confectioner. ESSENCE OF ORANGE, YELLOW. Prep. Fresh orange-peel, spirit of wine, and water, of each £ pint Digest for 1 week, press, filter, and add sherrv wine 2 or 3 pints. A pleasant liqueur. ESSENCE OF ORANGE PEEL, (SAC- CHARINE.) Syn. Oleo-saccharum of Orange. The yellow rind rubbed off with hard white sugar. In a similar way may be prepared essences or oleo- sacchara of every variety of lemons, citrons, oranges. &c. (See Citrons, p. 199.) ESSENCE OF PATCHOULI. Syn. Spirit of Patchouli. Prep. Indian patchouli leaves 2 lbs.; rectified spirit of wine 9 pints; water 1 gal- lon. Macerate for 1 week, frequently shaking the vessel, then distil over exactly 1 gallon. A very fashionable perfume. ESSENCE OF PENNYROYAL. Syn. Ess. Pulegh. Spiritus Pulegii. Spirit of Penny- royal. Prep. Oil of pennyroyal 3 oz. ; green spinage or parsley 1 oz.; spirit of wine 1 quart ; mix. Digest until sufficiently colored, and strain. Aromatic, stimulant, emmenagogue. ESSENCE OF PEPPERMINT. Syn. Ess Mentha Piperita. Prep. Oil of peppermint 1 oz; herb peppermint £ oz. ; spirit of wine 1 pint Digest for a week, or until sufficiently colored. Palish-green, and very strong of the peppermint Remarks. Essence of peppermint is not con- ceived to be good by the ignorant unless it has a pale tint of green, which they presume is a proof of its being genuine. The most harmless way is to steep a little of the green peppermint in the spirit for this purpose, (as above,) or if this is not at hand, a little parsley will do equally as well, and in fact improve the flavor. Some persons use spinage for the same purpose, and others add a few grains of sap green, dissolved in a spoonful of hot water. All these are quite innocent. The practice of using cupreous salts, adopted by some lazy and unprin- cipled makers, is unpardonable, and admits of no excuse, even a lame one, $ not the least advan- tage, either of convenience, or cost, or appearance, results from such a practice, while the coloring matter, though small in quantity, is nevertheless sufficient to impart a noxious quality to the liquor, This fraud may be detected by the addition of liquor of ammonia in excess. Essence of peppermint is cordial, s. piulant, and stomachic. A few drops on sugar, or mixed with water, or wine, is an excellent remedy in flatu- lence, colic, sickness, &c. It is also used as a fla- voring. Dose. 10 drops to a teaspoonful. ESSENCE OF QUININE. Syn. Alkalink Ess. of Quinine. Prep. Diluted sulphuric acid 1 dr.; alcohol 1 oz.; add sulphate of quinine to saturation. ESSENCE OF RATIFIA. Prep. Essential oil of almonds 1 oz.; spirit of wine 1 pint; mix. Used to make noyeau, &.c. (See Almond Fla- vor, and Essence of Bitter Almonds.) ESSENCE OF ROSES, (ODOROUS.) Prep. I. Attar of roses 1 oz.; spirit of wine 1 gallon. Mix in a close vessel, and assist the solution by placing it in a bath of hot water. As soon as the spirit gets warm, take it from the water and shake till quite cold. The next day filter. Unless the spirit of wine be of more than the common strength, it will not retain the whole of the otto in solution in very cold weather '(See Esprit de la Rose.) II. Petals of roses 3 lbs.; digest in spirit of wine 5 quarts for 24 hours; distil to dryness in a water- bath ; digest the distilled spirit on 2 lbs. of fresh rose petals, as before, and repeat the whole pro- cess of maceration and distillation a third, fourth, fifth, and sixth time, or oftener, the last time only drawing over 1 gallon, which is the essence. Very fine. ESSENCE OF ROSES, i^RED.) Syn. Spirit of Red Roses. Tincture oi- do. Prep. Ross leaves 1 lb.; spirit of wine and water, of each 2 quarts. Digest for 14 days, press, strain, add di- luted sulphuric arid 2 drs.; mix well, and the next day filter. Use. To make extemporaneous sirup and honey of roses, &c. Smells, colors, and tastes strongly. ESSENCE ROY ALE. Syn. Royal Essence. Ess. Regalis. Prep. (Soubeiran.) Ambergris 3ij; musk 3j; civet and subcarbonate of po- tassa, of each 10 grs.; oil of cinnamon 6 drops; oil of rhodium and otto of roses, of each 4 drops; rectified spirit of wine 4 fluid ounces. Macerate ESS 277 ETC for 10 days, or longer. Antispasmodic and aphro- disiac. A few drops on sugar, or in sirup of capil- laire. ESSENCE ROYALE POUR FAIRE LA BARBE. Prep. Castile soap, in shavings, 4 oz.; proof spirit 1 pint; dissolve. As Esprit de Savon. ESSENCE OF SAVORY SPICES. Prep. Black pepper 2 oz.; allspice 1 oz.; nutmegs £ oz.; cloves, cassia, coriander and caraway seeds, of each 1 drachm, (all bruised ;) rectified spirit of wine 1 pint. Digest for 14 days, press, and filter. Used as a flavoring. When made with proof spirit, and only £ the above weight of spice, it is called " Tincture of Savory Spices." ESSENCE OF SOUP HERBS, (KITCH- INER'S.) Syn. Spirit of Soup Herbs. Con- centrated Tincture of do. Prep. Lemon thyme, winter savory, sweet marjoram, and sweet basil, of each L oz.; lemon-peel, grated, and shalotes, of each £ oz.; bruised celery seed \ oz.; proof spirit 1 pint. Digest for 10 days, or a fort- night. A superior flavoring essence for soups, gravies, &c. ESSENCE OF SOAP. Syn. Ess. Saponis. Prep. (P. Cod.) White soap §iij; carbonate of potassa 3j; proof spirit ^xij. Dissolve and filter. ESSENCE OF SMOKE. Syn. Ess. Fuli- ginis. Smoking Fluid, &c. Rough pyroligneous acid. Used to impart a smoky flavor to meat and fish, by washing it over them, or immersing them in it for 2 or 3 minutes. ESSENCE OF SPEARMINT. Syn. Ess. Mentha Viridis. Ess. Mentha Sativa. Prep. 1 oz. of essential oil to 1 pint of spirit of wine, tinged green. Process, use, and dose, the same as Essence of Peppermint. ESSENCE OF SPRATS. Syn. Solid Es- sence of Sprats. Extract of do. Prep. Es- sence of anchovies (made with sprats) 7 lbs.; add wheat flour to thicken to the consistence of cream, then gently evaporate to a stiff paste. Sold for solid essence of anchovies. ESSENCE OF SPRUCE. Syn. Ess. Abie- tis. This is prepared by boiling the twigs of the spruce or Scotch fir in water, and evaporating the decoction. It is stimulant and tonic. Used to make spruce beer. ESSENCE OF TURTLE. Prep. Essence of anchovies and shallot wine, of each 3 oz.; basil wine £ pint; mushroom ketchup i pint; the juice of 2 lemons ; the yellow peel of 1 lemon ; curry powder \ oz. Digest for 1 -week. Use. To im- part the flavor of turtle to soups and gravies. ESSENCE OF VANILLA. Prep. I. Va- nilla, cut small, 1 lb.; spirit of wine £ gallon. As Essence of Musk. II. Vanilla (best) f lb.; spirit of ambrette 1 quart; cloves 30 grs.; grain musk 7 grs. As last. Very superior. Used as a perfume and flavoring. ESSENCE OF WORMWOOD. Syn. Ess. Absinthii. Prep. (Van Mons.) Salt of worm- wood 3v; extract of wormwood 3j; tincture of wormwood 1 pint. Digest and filter. ESSENCES FOR KITCHEN USE. Syn Culinary Essences. Flavoring do. Spice do. Essences for the Table. The principal of these are the Esiences of Allspice, Cassia, Celery, Cinnamon, Cloves, Mace, Marjoram, Nutmegs, Ginger, Cayenne, Garlic, Lemon-peel, Orange- peel, Peppermint, Spearmint, Caraway seeds Cardamom seeds, Coriander seeds, <$-c, fyc.; the whole of which are generally made by either dis. solving £ oz. of the essential oil of the spice in a pint of rectified spirit of wine, or by macerating 4 oz. of the bruised spice in a like quuntity'of the same fluid for a week. When made with only £ or \ the above quantity of spice or flavoring, and with proof spirit, or brandy, instead of spirit of wine, they are commonly called " Culinary Tinc- tures," or " Tinctures for Kitchen Use." The whole of these are employed to flavor gravies, soups, pastry, mulled wine, &c. See also Con- centrati-.d Essences, before described. ESSENTIA BINiE. (Literally, Essence of Malt.) The brewer's name for coloring, or burnt sugar. (See Coloring.) ESSENTIA ODORIFERA. Prep. I. Grain musk and balsam of Peru, of each 11 grs.; civet and oil of cloves, of each 5 grs.; oil of rhodium 2 grs.; salt of tartar 30 grs. ; alcohol 2 oz. Mace- rate for 14 days, then pour off the clear. A beau- tiful perfume. II. Oil of rhodium and balsam of Peru, of ea^. £ dr.; oil of cloves 1 dr. ; spirit of ammonia \ oz.; essence of civet 2 oz.; essence of musk 5 oz.; ne- roli, oils of lavender, verbena, and cassia, of each 5 drops. Mix. dissolve, and filter. Very fine ESSENTIAL SALT OF BARK. Extrs*t of Peruvian bark, prepared with cold water, and evaporated bv a gentle heat. ESSENTIAL SALT OF LEMONS. The preparation sold under this name is made by mix- ing cream of tartar (bitartrate of potassa) with twice its weight of salt of sorrel, (binoxalate of po- tassa,) both in fine powder. It is used to remove fruit stains from linen, by rubbing a little of it on the part moistened with warm water. It is poison- ous. ETCHING. A species of engraving, in which the design is formed on the plate by the action of an acid, or some other fluid, instead of the graver. Proc. The plate is covered with a ground or varnish capable of resisting the action of the etch- ing fluid, the design is next scratched on the metal by means of a species of needle or pointed tool of steel. A border of wax is then placed round the plate, and the "biting" menstruum poured on, and allowed to remain till the lights or finest portion of the design is sufficiently " bit in." The etching fluid is then poured off, the plate washed, and the light parts " stopped up" with wax or varnish, when the solvent is again poured on, and allowed to remain until the finest portion of the exposed lines are sufficiently deep, when the acid is again poured off, and the whole process is repeated till the very darkest lines or shadows are sufficiently formed. The plate is then cleaned, and is printed from in the same way as a common engraved cop- per-plate. The most approved way of laying the design on the etching ground, is first to draw it with a black-lead pencil on paper, then to damp the paper, place it with the design next the wax or varnish, and to pass the whole through a rolling- press, by which means the picture will be trans- ferred from the paper to the ground. There are several varieties of etching, among which may be named etching with a dry point, performed entirely with the point, without any ETC 278 ETH ground, the burr being removed with the scraper ; etching with a soft ground, when a coating of lard or tallow is employed, and the design is drawn on a piece of paper, laid evenly on the ground, by which means the fatty matter adheres to the paper, on the parts pressed on by the pencil, and the cop- per beneath becomes exposed. This method is employed to produce imitations of chalk or pencil drawings. Stippling, or executing the design in dots instead of lines. Aquatinta, in which a weak spirituous solution of gum mastich is poured over the plate, placed in a slanting direction, by which a granulated surface is formed, and small interstices left, exposing the naked metal: a wall of wax is next placed round the margin of the plate, the etching fluid poured on, and the lighter parts suc- cessively " stopped out" until the design is com- pleted. Aquatinta etchings bear a great resem- blance to Indian ink drawings. The fineness or coarseness of the grain depends entirely upon the quantity of matter dissolved in the spirit employed to form the ground. The fluids employed for " biting" in the designs vary considerably; almost every etcher having his own receipt. Aquafortis, more or less diluted, is, however, generally employed for copper, and this, with the addition of pyroligneous acid, for etching on steel; but any fluid that will rapidly dissolve the metal may be used for this purpose. The etching varnish or ground may be formed of any substance capable of resisting the action of the etching fluid, and, at the same time, sufficiently soft to allow of the free use of the needle or point, and sufficiently solid to prevent an injury to the design during the " scratching in." (See Fluids and Varnishes.) In etching on glass, the ground is laid on, and the design scratched out in the usual way, when liquid hydrofluoric acid is applied, or the glass is exposed to the action of hydrofluoric acid gas. The former renders the surface of the etching transpa- rent, the latter opaque. A very simple way of performing this operation is to wet the design with sulphuric acid, and then to sprinkle on some finely- pulverized fluor spar, (fluoride of calcium,) by which means hydrofluoric acid is set free and at- tacks the glass. This may be very easily applied to the graduation of glass vessels, thermometer tubes, &c. A most rapid method of etching on iron or steel, capable of very general application, is as follows : Warm the metal until it is capable of melting a piece of beeswax, or etching varnish, which must then be carefully rubbed over it, so as to form a thin and even coating; allow the whole to cool, and scratch out the design in the common way, with a needle or point; then sprinkle on a little powdered iodine, and at the same time add a few drops of water with a camel-hair pencil, and work them into a liquid paste, which must be moved about over the intended engraving, for a period varying from one to five minutes, accordiug to the depth of lines required to be produced. After- wards wash the whole in clean water. Persons acquainted with the properties of iodine will read- ily perceive that the same etching-paste, by being kept for a few days, will again acquire the prop- erty of dissolving iron. I have thus successfully employed the same materials three or four times. persede the use of acids for the above purpose, or account of its portability and convenience. To travellers and amateurs who amuse themselves with the delightful art of etching, it will, I think, prove invaluable. [I published this method of etching some two or three years since, and have since adopted it with considerable success.] ETHAL, (from eth and al, the first syllables of ether and alcohol, from its composition resembling those liquids.) A substance discovered by Chev- reul, and formed during the saponification of sper- maceti. ETHER. Syn. Sulphuric Ether. Oxide of Ethule. Ether, (Fr.) ^Ether, (Lat.) ./Ether vitriolicus, (P. L. 1788.) jEther rectificatus, (P. L. 1809 and 18-24.) jEther sulphuricus, (P. L.) Vitriolic Naphtha. Naphtha Vine (From aiQns, pure air, or any highly subtile fluid.) In Chemistry, a volatile, fragrant,/inflammable, and intoxicating liquid, obtained by distilling a mixture of sulphuric acid and alcohol. Hist. Ether, in combination with alcohol, is said to have been known to Raymond Lully in the ,13th, and to Basil Valentine in the 15th century; but the precise directions for its preparation were first published by Valerius Cordus in 1544, by whom it was called Oleum Vitrioli dulce. The term ether was first employed by Froberus about the year 1730. It is only within the present cen- tury that ether has been obtained in a state of absolute purity. Principles of ether;firation. When a mixture of alcohol and sulphuric acid is heated to a certain temperature, a series of complicated changes en- sue, among which is the conversion of the former into ether, which passes over along with some wa- ter and undecomposed alcohol, and condense*-, in the receiver. According to Liebig, ether is the oxide of a hypothetical radical called "ethulr;" and alcohol is the hvdrate of this oxide. On the admixture of sulphuric acid and alcohol, a hydra- ted bisulphate of ether (oxide of ethule) is formed, and this is subsequently decomposed by heat into ether, water, and sulphuric acid. " If we consider each particle of the hydrated bisulphate of oxide of ethule, as composed of ether, (oxide of ethule,) anhydrous sulphuric acid, and water, it is clear that the anhydrous acid, at the moment of its separa- tion from the ether, must seize on all water, free or combined, in the vicinity of the ether. Thus, at the moment the ether becomes free, the anhy- drous acid, also set free, prevents it from uniting with water to form alcohol. But when the gaseous ether passes through the undecomposed hydrated bisulphate of oxide of ethule, a certain portion of the water of that compound must evaporate in the dry gas ; and under these circumstances the ether and water do not combine together. The surface of the effervescing liquid has the temperature at which the hydrated bisulphate of oxide of ethule is decomposed ; but at this temperature C2840) the water of that compound is gaseous- There are thus produced simultaneously,—water, in the gas- eous form, and ether, also gaseous, by decomposi- tion ; which, as both are in the nascent state, unite to form alcohol. Thus, the alcohol, always ob- served to distil over with the ether, is derived from the surface; and the ether and*water which dis- Iodine will, doubtless, at no very distant period, su-1 til over, proceed from the decomposition in the ETH 279 ETH interior of the liquid. This explains why no ether is obtained, when the liquid is not in a state of brisn. ebullition, no matter how high the temper- ature may be ; it explains further why more alco- hol is obtained when a current of dry air passes through the liquid; as, in that case, the same de- composition goes on in the interior of the liquid as generally occurs at the surface." (Liebig.) According to the opinion of some, ether is the first hydrate of defiant gas, and alcohol the sec- ond ; and the conversion of the latter into the for- mer consists in the mere abstraction of the second equivalent of water. This hypothesis-has been principally held in France, and the former in Ger- many ; and the elaborate investigations into the composition of ethereal compounds, induced by these conflicting opinions during nearly a dozen years, has led to the enrichment of organic chem- istry with a multitude of new compounds- and new facts, which might otherwise have been lost to science. These opposite opinions are, however, essentially the same ; and, as it has been justly observed by Liebig, " men disputed about them because they were not agreed on the interpreta- tion of phenomena." A similar opinion to the preceding, is that ether is the hydrate of a quadrihydrocarbon, to which the name etherin has been given. The late Mr. Hennel, of Apothecaries' Hall, held this view. He considered that in the conversion of alcohol into ether, a compound of sulphuric acid and etherin (sulphovinic acid) is first formed with part of the alcohol, and that during the ebullition this com- pound is decomposed ; its dihydrate of carbon uni- ting with the remaining alcohol to form ether, which distils over, mixed with undecomposed alco- hol and water. Thus ether has been regarded by different au- thorities as a a dihydrate of olefiant gas; a hy- drate of etherin; and as an oxide of ethule, or ethereum ; but it must appear to an impartial ob- server that these opinions do not so grea"tly differ, as their advocates have represented; and if, as suggested by Kane and Malaguti, acetule be taken as the hypothetical radical of the series, this will be very evident, as may be seen by mere inspec- tion of the following table: Acetule = C4HS unknown. Olefiant gas =C4H 3 + H Ethule =C4H3-(-H2 = unknown. Ether = C4II H3+0 = oxide of ethule. Chloride of ethule. = C4H3Ha-f-CZ = chloric ether. Iodide of ethule . . . = C4H3H2-f-I = hydriodic do. Acetate of oxide of ethule = C4H3 H 50-(-A= acetic do. From the above table the formation of other compounds of ethule may be readily explained, by mere substitution, which view is supported by the actual constitution of the ethers, according to the most correct analysis. * During the distillation of a mixture of sulphuric acid and alcohol, the relative proportions of the ingiedients are constantly varying, occasioned by the decomposition of the alcohol, and evaporation of the newly-formed ether and undecomposed al- cohol, by which means the relative quantity of sulphuric acid increases, the boiling point rises, and new reactions take place. Olefiant gas, sulphur- ous acid, water, carbon, and other products are formed, some of which pass over into the receiver. The distillation of i'ier is, however, usually stop- ped before this po.u. is arrived at. . According to theory, 2 equivalents, or 46 parts of absolute alcohol, should produce 1 eq., or 37 parts of pure ether, but in practice no such product can ever be obtained. The greatest product, by operating according to Boullay's method, which produces more ether than any other, does not ex- ceed 33£ parts for the preceding quantity of alco- hol, or 7f-5§. (Geiger.) Prep. There are only two methods employed for the preparation of ether, viz. I. By mixing the whole of the ingredients at once, and immediately subjecting them to distillation. II. By adding the alcohol in a slender streamlet to the acid, previ- ously raised to the etherifying temperature. The former, though less economical, is the one more generally employed. " Ether is also formed bv the decomposition of the bisulphate, biphosphate, and biarseniate of oxide of ethule, (sulphovinic, phosphovinic, andarseniovinic acids,) and by the ac- tion of fluoride of boron, chloride of zinc, chloride of tin, and other chlorides on alcohol." (Liebig.) I. a. (Process of the L. Ph.) Rectified spirit lb. iij ; sulphuric acid lb. ij ; carbonate of potassa, previously ignited, ^j ; pour rb. ij of the spirit into a glass retort, add the acid, place it on a sand- bath, so that the liquor may boil as quickly as pos- sible, and the ether pass into a receiver cooled by ice or water ; and distil until a heavier fluid begin to pass over. Then lower the heat, add the re- mainder of the spirit, and distil as before. Mix the distilled liquors together, pour off the super- natant portion, add the carbonate of potassa, and agitate occasionally for one hour; finally, distil the ether from a large retort, and keep it in a well- stoppered bottle. 0. (Liebig.) Mix 5 parts of alcohol of 90g with 9 parts of oil of vitriol, in a vessel of copper or iron, immersed in cold water; introduce the mix- ture into a still, connect it with a refrigerator, and a well-cooled receiver, and raise it to a state of ebullition as rapidly as possible. Next add to the liquid in the still a fresh quantity of alcohol, equal in bulk to the liquid distilled over, and repeat the operation. To the distilled liquid, add as much concentrated alcoholic solution of potassa as will give it a perceptible alkaline reaction, then rectify it by distillation in a water-bath as long as the ether, which distils over, has a sp. gr. of 0-720 to 0-725 at 80° Fahr. Instead of the potassa, a lit- tle milk of lime may be used, along with its own bulk of water, rectifying the ether as before. By allowing the product to stand for some days over chloride of calcium or quicklime, and again recti- fying along with one of these substances, perfectly pure ether will be obtained. II. a. (Process of the Edinburgh Ph.) Rec- tified spirit f §L ; sulphuric acid f ^x ; pour f §xij ol the spirit gently over the acid contained in an open vessel, mix well ; transfer the mixture imme diately into a glass matrass connected with a re- frigeratory, and raise the heat quickly to about 280°. As soon as ether begins to distil over, sup- ply fresh spirit tlirough a tube into the matrass, in. ETH 280 ETH a continued stream, and in such quantity as to equal that of the fluid which distils over This is best done by connecting one end of the tube with a graduated vessel containing the spirit, passing the other end through a cork fitted into the mat- rass, and having a stopcock on the tube, to regu- late the discharge. When f-^xlij have distilled over, and the whole spirit has been added, the pro- cess may be stopped. Agitate the product with f^xvj of a saturated solution of muriate of lime, containing ^ss of lime recently slaked, pour off the supernatant liquor, and distil it with a very gentle heat, so long as the liquor which passes over has a density not above *735. More ether of the same strength is then to be obtained from the so- lution of muriate of lime. From the residuum of both distillations a weaker ether may be obtained in a small quantity, which must be rectified by gently distilling it again. Remarks. This process is a mere modification of that first pointed out by Boullay, and which has since been described and recommended by Mitscherlich, Liebig, and others. /?. (Process employed at Apothecaries' Hall.) The apparatus consists of a leaden still, having a pewter head, and connected by means of about 6 feet of tin pipe, with a powerful worm condenser, surrounded by a constant stream of cold water, and which is connected with pewter receivers, fur- nished with glass lids. The still is heated with a coil of lead pipe, supplied with high pressure steam, and the alcohol is supplied to the acid as required,by means of a small pipe entering the upper part of the still. y. (Process of Boullay.) Three parts of the strongest oil of vitriol are mixed with sufficient al- cohol to reduce its sp. gr. to 1-780, (about 2 parts of alcohol of -830,) which may be easily regulated by distilling off some of the ether, if required. The still or retort is then connected with a vessel full of alcohol, of 90$, by means of a small syphon fur- nished with a stopcock; the longer limb of the syphon, which should be of glass, being so arranged that it just dips into the mixture of acid and alco- hol. Heat is next applied, and the contents of the still raised to the boiling point as rapidly as possi- ble, and as soon as full ehullition commences, the stopcock of the syphon is turned, so as to allow the alcohol to flow down in such a manner as to keep the boiling liquid exactly at the same level; or, in Other words, to supply a quantity of alcohol exactly equal to that of the liquid which distils over. By a, Condenser tube, japanned zinc 28 inches long; b. c, glass tube, 36 inches long; d, funnel by which cold water runs in from the water bottle, h; e.pipe by which water es- capes through/into the bottle g; t, retort; k, adapter con- necting the retort with the condenser; I, adapter, connect- ing the condenser with the bottles, t, t. A, Black wooden tressel, with moveable arms, n, o, for supporting and ad- justing the height of the condenser; B, black wooden careful manipulation the whole of the alcohol which enters the retort will pass over as ether and water, and this decomposition proceeds for some time, and would continue for an unlimited period, but that the sulphuric acid ultimately becomes too weak to form ether, from the gradual absorption of the superfluous water contained in the alcohol. Were it convenient or practicable to use absolute alcohol, a given weight of sulphuric acid, of the proper strength, would maintain the power of pro- ducing ether for an indefinite period. In practice, the quantity of alcohol that may thus be etherefied is twice or thrice as much as by the common pro- cess, while neither sulphurous acid, su'phovinic acid, (Geiger,) nor sweet oil of wine is generated, and the residual liquid of the distillation continues limpid, and has only a pale brown color A mix- ture of 9 parts of oil of vitri 1 and 5 parts of alco- hol of 90$, ceases to produce ether, after 31 parts of such alcohol have been added. Sulphuric acid containing more than 4£ atoms of water to 1 atom of dry acid, is too weak for the etherification of alcohol, and 3£ to 4 atoms of water appears to be the limit of dilution, fixed by experience, for the productive preparation of ether. (Liebig.) Remarks. The mixture of alcohol with strong oil of vitriol requires some caution. It may be best done by introducing the alcohol into a suitable vessel, and imparting to it a rapid whirling motion, by which a considerable conical cavity will be formed in the centre, and into which the acid may be gradually poured with perfect safety. The mixed fluids should be brought to a state of rapid ebullition as quickly as possible, as without this precaution much of the alcohol will distil over be- fore the liquor acquires the proper temperature for etherification. On the small scale, a tubulated retort, connected with a Liebig's condensing tube, and two globular receivers surrounded with a freez- ing mixture, or very cold water, may be employed as the distillatory apparatus. The second receiver should be* connected with the first by means of a bent glass tube, reaching nearly to the bottom of the latter; and the whole of the joints should be securely luted as soon as the expanded air has been allowed to escape. The following convenient little apparatus has been employed by the writer for the preparation of small quantities of ether, and will be found very suitable for the distillation of most volatile fluids. stool for supporting the water bottle, (the legs unscrew for travelling:) q, furnace ; r, support for the furnace;?, gutter for carrying off water that overflows the funnel d, and preventing its escape along the pipe c ; m. leg of sypboa connected with bottle containing alcohol; t, t, glass globes, placed in the basins v, v, and surrounded with ice-cold water; id, safety tube containing a little mercury at x. ETH 281 ETH This apparatus may be purchased of Messrs. Griffin and Co., or their agents, at a very reasona- ble price. By connecting the neck of a flask or digester containing volatile fluids with the lower instead of the upper end of the refrigerator, ebulli- tion may be carried on without loss, as the vola- tilized fluid will be condensed, and run back into the vessel from which it had just distilled. This arrangement will be found useful for boiling mix- tures of alcohol and organic acids, described further on, or for any similar purpose. (See Ethers, or- ganic.) For the rectification of ether a water-ba*h should be employed, and the neck of the retort may be advantageously connected with the above simple refrigerator, and the receivers should be surrounded by freezing mixtures. Pres. Ether rapidly evaporates at common tem- peratures when kept in corked bottles, and even in bottles secured with ground-glass stoppers and tightly tied over with bladder and leather; it also becomes sour by age. To prevent this waste, the stoppers should fit very accurately, and the bottles should be placed in as cool a situation as possible. Bottles furnished with ground-glass caps (see engraving) as well as stoppers, are frequently employed. Dewar's ether vial is formed on a similar principle. The shoulder is surrounded with a cir- cular rim not rising quite so high as the mouth of the bottle, and a capsule sim- ilar to the one in the engraving is in- verted and fitted into it. Mercury is then poured into the rim, and hermeti- cally closes it. I have seen bottles of ether accu- rately stoppered, tied over with bladder and waxed, which have yet become quite empty by a voyage to the tropics, though they still appeared to be as firmly secured as when they were first put up. Prop., tyc. Pure ether is a colorless, transpa- rent, and very limpid fluid, having a penetrating and agreeable smell, and a taste at first burning and sweetish, followed by a sensation of coolness. Its specific gravity has been variously stated. Ac- cording to Liebig and Gregory it is 0-7119 at 75° ; 0-7154 at lis0 ; and 0*7237 at 55° Fahr. Others state it to be 0-713 to 0-715 at 60°, (Ure, &c.;) or 0*713 at 68°, (Dumas, Boullay.) It is said to be- gin to crystallize in brilliant white plates when cooled to —24° F., and at —46° or —47° it be- comes a white crystalline mass, (Ure, Liebig, Fourcroy, Vauquelin,) but, according to others, absolutely pure ether cannot be solidified by any degree of cold that can be produced, (Thenard and Bussy.) It remained fluid when placed in contact with solid carbonic acid, at a temperature of about —148° Fahr., (Pereira.) It boils at 96° or 97° Fahr. ; is very combustible, is soluble in 10 parts of distilled water, and mixes with alcohol in all proportions. It abstracts corrosive sublimate, terchloride of gold, and sesquichloride of iron from their watery solutions. It readily dissolves the volatile and fixed oils, most fatty matters, as well as sulphur and phosphorus, ill small quantities. By exposure to light and air it absorbs oxygen, and Water and acetic acid are formed. Ether may be recognised by its volatility, odor, taste, sparing solubility in water, admixture with alcohol in all proportions; its inflammability, 36 burning with a yellowish white flame, and by itl power of dissolving fats and resins. Pur. The ether of the shops, generally, contains alcohol, water, or acetic acid, and sometimes al of them. Its usual specific gravity fluctuates be- tween -733 and -765. The London College states that it should be -750, while the Edinburgh Col- lege fixes it at -735 or under. " It totally evapo- rizes in the air, and slightly reddens litmus." (P. L.) Pure ether should, however, be neutral to test paper. " When shaken in a minim measure with half its volume of concentrated solution of muriate of lime, its volume is not lessened." (P. E.) Ten fluid ounces of water should only dissolve one fluid ounce of ether, and should remain transparent. Uses, Sec. Ether is powerfully stimulant, nar- cotic, and antispasmodic, and externally refrige- rant, and is used in various diseases. Applied to the forehead by means of the fingers or a strip of linen, it will generally relieve nervous headache. In pharmacy it is employed in the preparation of several tinctures, alkaloids, spirits, &c. ; and in chemistry is frequently used in organic analyses. It is also employed as a solvent of resins, Indian rubber, &c, in the preparation of varnishes, and for several other useful purposes. Dose. 20 drops to f 3ij in water or wine. Excessive doses of ether produce intoxication resembling that from alcohol, and require similar antidotes. It is commonly taken as a.stimulant by fashionable ladies, and though generally disguised by Cologne water, may be often distinguished in the breath of persons be- longing to the higher ranks of society. Caution. The vapor of ether is very inflamma- ble, and when mixed with atmospheric air it forms a violently explosive mixture. The density of this vapor is 2-586, that of air being 1, (Gay Lussac;) hence it rapidly sinks, and frequently accumulates in the lower parts of buildings, especially cellars which are badly ventilated. Every crack, every joint in the floors of rooms, the space beneath doors, &.c, offer a road for the passage of this vapor, which, though invisible, as surely runs out of every orifice and finds its level, as a stream of water would do. The only remedy is thorough ventilation. Many serious accidents have arisen from this cause, for no sooner is a light carried into an apartment where such vapor is present, than an explosion takes place. In this respect the vapor of ether resembles fire-damp and light gas. A late extensive fire in Upper Thames-street arose from a small bottle of ether being broken in the opera- tion of packing. I have heard Dr. Reid particu- larly call attention to this point at his lectures ; and Dr. Pereira, in his excellent work on Materia Medica, mentions the case of an apothecary at Bern, whose house was blown up in consequence of a lighted candle being taken into the cellar, in which a bottle of ether had been broken. ETHER, ACETIC. Syn. Acetate of Oxide of Ethule. Pyroligneous Ether. jEther Aceticus. A compound of acetic acid and ether, discovered by the Count de Lauraguais in 1759. (Thomson.) Prep. I. (Liebig.) a. Dry acetate of lead 32 parts ; alcohol 9 parts; oil of vitriol 12 parts ; mix and distil. 0. Crystallized acetate of soda 10 parts; oil of vitriol 15 parts ; alcohol of 80 or 85§, 6 parts ; as before. ETH 282 ETH II. (Ure.) a. Acetate of lead 40 parts ; alcohol 20 parts; concentrated sulphuric acid 23 parts; as before. fi. Anhydrous acetate of lead 16 parts; sulphu- ric acid 5 parts ; absolute alcohol (or its equivalent in alcohol of bO or 85$) 4£ parts ; as before. III. Acetate of potassa 3 parts, (or an equiva- lent proportion of acetate of soda ;) alcohol of 85§, 3 parts ; strong oil of vitriol 2 parts ; as before. An economical process. IV. (P. Cod.) Rectified spirit fxxx ; acetic acid f §xx; sulphuric acid Jvj 3ij; distil §xl ; agitate with carbonate of potash and redistil. Remarks. The distillation should be conducted in a glass retort, or earthenware still, connected with a well-cooled receiver, and the product should be rectified along with chloride of calcium to ab- sorb the water, and slaked lime to remove the acid, (Liebig;) or the distilled liquid may be agitated along with a weak lye of potassa, and after repose the supernatant ether may be decanted and recti- fied along with magnesia and powdered charcoal. (Ure.) The rectified acetic ether will be equal in weight to the alcohol employed. (Liebig.) Prop. Acetic ether is colorless, and bears a con- siderable resemblance to ether, (sulphuric ether,) but has a much more agreeable and refreshing odor. It boils at 165°, (Liebig —166° Ure ;) has a sp. gr. of 0-89 at 60° Fahr., (Liebig —0-866 at 45° Fahr., Ure ;) dissolves in 7 parts of water, (Liebig. —8 parts, Ure ;) and mixes in all propor- tions with alcohol and ether. It is decomposed by alkalis and oil of vitriol. According to the acetule- theory this ether is properly an acetate of other, (oxide of ethule.) and may consequently be regard- ed as a salt of acetic acid. Uses. Acetic ether is diaphoretic, stimulant, antispasmodic and narcotic, and has been given in doses of f oss to f 3ij, in similar cases to those in which sulphuric ether is employed. Its principal consumption is in the manufacture of British brandv- ETHER, BENZOIC. Syn. Bknzoate of Ether. Benzoate of Oxide of Ethule. A colorless oily liquid, having an aromatic odor and taste, and a sp. gr. slightly exceeding that of wa- ter. It boils at 410° Fahr., and is miscible with alcohol and ether. It was discovered by Scheele. Prep. Alcohol of -&30, 4 parts ; crystals of ben- zoic acid 2 parts; concentrated muriatic acid 1 part; mix, distil, and as soon as the product turns milky when mixed with water, change the receiver and collect the liquid that distils over. To the product add water, separate the supernatant ether, boil with water and a little oxide of lead, (to sepa- rate benzoic acid,) and lastly, free it from water by allowing it to stand over chloride of calcium. (Liebig.) See Ethers, organic ETHER, CARBONIC. Syn. Carbonate of Ether. Carbonate of Oxide of Ethule. Mther Carbonicus. An ethereal liquid, dis- covered by Ettling, and somewhat resembling ox- alic ether. Prep. Add gradually, fragments of potassium to oxalic ether, gently warmed, as long as bub- bles of gas are formed ; remove the excess of metal from the semisolid mass, add water and distil. The carbonic ether will float on the surface of the liquid in the receiver, and must be collected, dried by contact with chloride of calcium, and rectified along with some potassium or sodium, till it ceases to yield acetate of potassa when acted on by caus- tic potassa. (Liebig.) ETHER, CHLORIC. Syn. Chloride of Ethule. Chlorhydric Ether. Hydrochloric do. Muriatic do. Marine do. jEther Muriaticub. Do. Ciiloricus. Do. Hydrochloricus. Prep. I. (P. Cod.) Alcohol and muriatic acid equal parts by weight; distil by a gentle heat, into a series of re- ceivers, the first of which should contain a little warm water, and the others should be surrounded with ice. II. (Medicinal Chloric Ether.) This is usually prepared by putting dry chloride of lime into a glass or earthenware retort, with just enough al- cohol to moisten and cover it, and distilling by a gentle heat into a receiver, surrounded with ice or a freezing mixture. III. (Pure.) Saturate alcohol with muriatic acid gas, carefully distil, purify the product from alcohol and water by neans of chloride of calcium, and preserve it in inverted stoppered bottles, in a cool place. Remarks. Chloric ether requires the same care in its distillation as sulphuric ether, previously de- scribed, and the same apparatus may be advanta- geously employed. It has a penetrating, garlic- like smell, a sp. gr. of *874 at 40°, dissolves in 24 parts of water, is neutral, boils at 51°, and burns with a greenish flame and the production of mu- riatic acid. Its physiological action is similar to the other ethers. It has been given in dyspepsia, hepatic diseases, hectic fever, &c, in doses of f 3ss to f'3iij. The spiritus salis dulcis (P. E. 1735) was a mixture of this ether and alcohol, but Gehlen first brought it into notice in 1804. (Thomson.) It is but little employed in England, judging from the demand for it; a very large metropolitan drug- house having only sold about 16 ounces in the last twelve months. ETHER, CHLORO-CARBOMC. Dumas has given this name to a peculiar liquid formed by saturating absolute alcohol with chloro-carbonic acid, (phosgene gas.) The lower stratum that forms is the ether. It must be purified by stand- ing over oxide of lead and muriate of lime, and by subsequent rectification. It has a disagreeable smell, is heavier than water, and boils at 200° Fahr. It is decomposed by water. ETHER, CYANIC. Syn. Bicyanurate of Ether. Do. of Oxide of Ethule. -Ether Cyanicus. Prep. Saturate a mixture of alcohol and ether with hydrated cyanic acid, in vapor. In 24 hours collect the crystals, and purify by solu- tion and crystallization in hot alcohol or water. Tasteless, inodorous, colorless, transparent needles and prisms. (Wohler and Liebig.) ETHER, HYDRIODIC. Syn. Iodide of Ethule. A colorless liquid, discovered by Gay Lussac, and obtained by saturating alcohol with hydriodic acid and distilling. It is about as dense as oil of vitriol, has an ethereal smell, and boils at 150° to 160° Fahr. ETHER, HYDROBROMIC. .s,„. Bromide of Ethule. A volatile ethereal l.qn.d di>co\cred by Serullas. It is prepared by dissolving H parts of bromine in 32 parts of alcohol, add n- one part of phosphorus, and distilling the mixture by a gentle ETH 283 ETH heat as soon as it becomes cold. The ether is sep- arated from the distilled liquid by the addition of water ; it is heavier than the latter. ETHER, HYDROTELLURIC. Thismaybe prepared by distilling the mixed aqueous solutions of sulphovinate of baryta and telluret of sodium. The latter is prepared by calcining tellurium, or telluret of bismuth with carbonate of soda and char- coal, and must be used as soon as made. Hydro- telluric ether has a yellowish red color, like bro- mine, and is heavier than water. (Wohler.) ETHER, METHYLIC. Syn. Hydrate of Methylene. A colorless gas, prepared by distil- ling a mixture of »qual measures of oil of vitriol and pyroxilic spirit ETHER, MURIATIC, (HEAVY.) A name given to a liquid obtained by Scheele, by distilling a mixture of oil of vitriol, peroxide of manganese, chlo- ride of sodium and aicohol. It is more conveniently prepared by saturating alcohol of 80 to 85g, in the cold, with chlorine, adding water, collecting the oily fluid that separates, and washing it with wa- ter as long as any of it is dissolved. This fluid boils at about 245° Fahr., and is heavier than wa- ter. This ether enters into the composition of the spiritus muriatico-ethereus, a remedy occasionally used on the Continent. (Liebig.) ETHER, NITROUS. Syn. Hyponitrous Ether. Hyponitrite of Oxide of Ethule. Do. of Ether. It is said that sweet spirit of nitre was known to Raymond Lully in the 13th century, and that Basil Valentine, in the 15th century, taught an improved method of preparing it, (Dulk, quoted by Dr. Pereira;) but nitric ether was first mention- ed by Kunckel in 1681. (Thomson.) Prep. I. (Process of the Edinburgh Ph.) Rec- tified spirit 1 quart, and f^vj; pure nitric acid of 1-500 f^vij ; put f^xv of the spirit into a quart matrass, fitted with a cork and safety tube, reach- ing to within an inch of the spirit, and a second tube leading to a refrigeratory. Fill the safety tube with the nitric acid, then add through it, gradually and cautiously, f ^iiiss of the acid. When the vio- lent action that ensues is nearly over, gradually add the remaining portion of the acid, f |ss at a time, and at intervals. The ether that distils over must be agitated first with a little milk of lime, till it ceases to redden litmus paper, and then with half its volume of concentrated solution of muriate of lime. " The pure hyponitrous ether should have a densi- ty of 0-899." II. The Dublin College orders purified nitrate of potash, dried and in powder, lb. iss; sulphuric acid lb.j ; rectified spirit of wine f fxix; the acid and spirit are to be first mixed, and then poured very gradually on the powdered nitrate placed in a tubulated retort, and connected with a well- cooled receiver, by means of a bottle, containing a pound of spirit of wine, adopting the usual precau- tions ; the product is to be shaken with about a drachm of dried and finely-powdered carbonate of pot'wsa, and the ether decanted after a time. III. (Process of M. Pedroni.) Crystallised ni- trate of ammonia 11 parts ; oil of vitriol 8 parts; alcohol 9 parts ; mix the last two, and pour them on the salt contained in any suitable distillatory vessel, connected with a well-cooled receiver. Ni- trous ether will gradually distil over by the appli- cation of heat. A common fire may be employed without danger, as the liberation of the ether pro- ceeds gradually, and not almost instantaneously, as in operating in the usual way. Sulphate of am- monia is left in the retort. (Comptes Rendus, 1«43.) IV. Alcohol of 85§, 9 parts; water 4 parts; fuming nitric acid 8 parts; introduce the spirit into a strong cylindrical glass vessel, 3 times as high as wide, capable of holding one-fifth more than the liquid to be placed in it, and by means of a funnel tube reaching to the bottom of the vessel, and having a small orifice ; add the water cautiously, so that it may form a stratum beneath the alcohol, without mixing with it; in like manner add the acid, taking care that the three strata do not mix ; then tightly stop the vessel, and allow it to repose at a temperature of 53° Fahr., for 2 or 3 days, when the stratum of ether which has formed must be collected and purified by rectification. (Turner's Chem., 7th ed.) V. (Liebig's Process.) Starch 1 part; nitric acid, sp. gr. 1-30, 10 parts ; alcohol of 85g, 2 parts; water 1 part; introduce the starch and acid into a capacious retort, connected with a wide tube 2 or 3 feet long, bent at right angles, and terminating near the bottom of a two-necked bottle, contain- ing the alcohol and water mixed together, and surrounded with a freezing mixture or very cold water. The other neck of the bottle must be con- nected by a wide and long glass tube, with a good refrigerator or condenser. The heat of a water bath must be cautiously applied to the retort, when pure hyponitrous acid will be set free, and passing into the alcohol will form hyponitrite of oxide of ethule, (ether,) which will distil in a gentle stream. The tube connecting the retort and bottle must be cooled by means of a rag or moist paper, wetted from time to time with ice-cold water; for if the tube and the alcohol be not carefully cooled, the latter becomes spontaneously hot, and boils vio- lently, when the product is vitiated. This process is very productive and economical, and yields per- fectly pure hyponitrous ether. Prop., Uses, fyc. Pure hyponitrous ether has a pale yellow color, a mixed odor of apples and Hun- gary wines, a sp. gr. of 0-947 at 60° Fahr., and boils at 62° Fahr. That prepared by the ordinary pro- cesses contains aldehyde, boils at 70°, has a sp. gr. of 0*886 at 40° Fahr., has a similar odor to the for- mer, but at times suffocating, and turns brown when mixed with an alcoholic solution of potassa, while the former remains white. It also becomes acid by age, while pure hyponitrous ether remains neutral. The ether prepared by the last formula is chemi- cally pure, (Liebig,) and that by the third, nearly so. The Others contain aldehyde. Ordinary hy- ponitrous ether dissolves in about 48 parts of wa- ter, and mixes in all proportions with alcohol and sulphuric ether. (Liebig.) Hyponitrous ether is refrigerant, diaphoretic, and diuretic, but is seldom employed alone, though, when largely diluted with alcohol, under the name of " sweet spirits of nitre," it is a common remedy. It is also used in the manufacture of British bran- dy. (See Spirits of Nitre, sweet.) ETHER, CENANTHIC. Syn. (Enanthate of Oxide of Ethule. This is the oil obtained towards the end of the distillation of fermented liquors, especially wines Tt is purified by agita- ETH 284 ETH tion with a weak solution of carbonate of potassa, repose, and decantation. It is lighter than water, boils at 425° Fahr., and has an odor# resembling an empty wine cask or bottle that has been ex- posed to the air for some time. As obtained by dis- tillation, it is uuited with a little cenanthic acid. 2200 imperial gallons of wine (about 35 hogsheads) only yielded 2\ lbs. of the mixed oil. ETHER, OXALIC. Syn. Oxalate of Ox- ide of Ethule. Neutral do. A colorless oily liquid, slightly heavier than water, boiling at 370° Fahr., and having an aromatic smell. It was dis- covered by Thenard. Prep. Biuoxalate of potassa, and alcohol of 90$, of each 4 parts; oil of vitriol 5 parts ; mix in a glass retort and distil with a quick fire; as soon as the product becomes turbid when mixed with wa- ter, change the receiver, agitate the subsequent product with 4 or 5 times its weight of water, and repeat the agitation with fresh water until the ether becomes neutral to test paper ; then rectify it in a dry retort that it will about nine-tenths fill, and as soon as the boiling proceeds smoothly, in- stead of by jerks, change the receiver; the remain- ing product will be pure anhydrous oxalic ether. (Ettlinsr.) See Ethers, organic ETHER, PHOSPHORATED. Syn. jEther Phosphoratus. Prep. (P. Cod.) Phosphorus, cut small, 1 part; ether 50 parts; digest with occa- sional agitation for 1 month, and decant the clear. ETHER, SULFURIQUE IODURE. Syn. Ethereal Tincture of Iodine. Prep. Iodine 40 grs.; sulphuric ether Jj; dissolve. Dose. 5 to 10 drops, where the use of iodine is indicated. ETHER, SULFURIQUE avec le Deuto- iodure de Mercure. Syn. Ethereal Tincture of Bin-iodide* of Mercury. Prep. Biniodide of mercury 16 grs.; sulphuric ether §iss ; dissolve. Dose. 5 to 12 drops. ETHERS, ORGANIC. The preparation of some of the organic ethers has been found to be attended with considerable difficulty, and hence have arisen various contrivances to induce the or- ganic acids to combine with the ethereal base. Among the methods generally adopted until lately, may be mentioned the admixture of a salt of the organic acid with alcohol, to which some strong inorganic acid is added, when the acid of the salt being liberated in the nascent state, it enters into a new combination, forming ether. In this way acetic and oxalic ethers are commonly prepared. Or the organic acid being mixed with alcohol, sul- phuric or hydrochloric acid is added, by which an oiganic ether is produced. Benzoic ether may be taken as an instance of this mode of operating. Ethers have also been formed by the simple dis- tillation of some of the organic acids with alcohol, but this method is usually tedious, and requires the repeated return of the products of distillation into the retort, as well as considerable time for its per- formance, to which several other objections may be added. More recently it has been shown that when the organic acids are heated nearly to their point of decomposition, and alcohol is gradually and cautiously dropped on them, ethers of those acids are readily formed. In this way many of the acids which are wholly or partly volatile—as the oxalic, benzoic, and succinic acids,—yield large quantities of ether. (Gaultier de Claubry.) This method is applicable to most acids that do not suf" fer decomposition a a low temperature, but id other cases the prodi 3t would be vitiated and un- certain. Thus, citric acid under this treatment might yield citric, itaconic, citraconic, or aconitic ether, or a mixture of two or more of them, and this in a way entirely beyond the power of the operator to influence. Another method recom- mended, and very suitable to the preparation of the ethers of the fatty acids, is—to dissolve the organic acid in alcohol, and to pass a current of muriatic acid gas through the solution. A still simpler plan, and which appears likely to super- sede most others, at least in the majority of cases, is to mix- equal parts of alcohol and the organic acid, with ith or |th of oil of vitriol, and to place it in a flask or digester, fitted with a cork, through which passes an upright thin glass tube, 5 or 6 feet long, and after luting the joint quite se- curely, to submit the mixture to gentle ebu'ition in a sand-bath, or over a spirit lamp for several hours. In this way the spirituous and ethereal vapors are condensed in the cool portions of the tube, and fall back again into the matrass, by which means no loss of either can possibly occur A Liebig's refrigerator reversed may also be used for this purpose. (See Ether.) By this method some ethers may be readily formed that can scarcely be obtained pure in the usual way. Thus mucic ether may be obtained by this process, which will become perfectly white by crystallization, while by Malagutti's method, the product is quilt black, and is purified with difficulty. One or othei of the above plans may be adopted for the prepara- tion of those ethers for which formulae are not in- serted in this volume. ETHERIN. A name applied by some chem- ists to a hydrocarbon, assumed to be the base of ether. Its atomic constitution, according to this hypothesis, is 4 equivalents each of hydrogen and carbon. ETHERINE. Syn. Camphor of Oil of Wine. A peculiar substance obtained by exposing ethe- role for a long time to a low temperature. It forms brilliant prisms and plates, and is tasteless, soluble in alcohol and ether, fuses at 230°, boils at 500°, and is a little lighter than water. The crys- tals are purified by pressure between the folds of bibulous paper, solution in ether, and evaporation. ETHEROLE. Syn. Light Oil of Wine. A hydrocarbon discovered by Hennel. It is pre- pared by gently heating ethereal oil with water, se- parating the supernatant light oil, and washing this with water till it becomes quite neutral, after which it is dried by means of chloride of calcium. Ethe- « role is a colorless oily liquid, lighter than water, boiling at 536°, and soluble in absolute alcohol and ether. ETHIOPS. (See jEthiops.) ETHIOPS, MARTIAL. Syn. jEthiops Mar- tialis. Oxide of iron prepared by keeping iron filings under water, and occasionally shaking them. I It must be washed with water, and dried as quickly as possible to prevent its rusting. It was formerly much esteemed as a tonic. ETHIOP'S MINERAL, (TYSON'S.) Prep. Oxide of mercury, (prepared by decomposing calo- mel with an equivalent proportion of liquor of po- tassa, to which a little liquor of ammonia has been EVA 285 EXP added,) and flowers of sulphur, equal parts. Tri- turate together till perfectly mixed. Remarks. Mr. Tyson has recommended this as an efficient substitute for the old and uncertain preparation commonly sold under the name of Ethiop's mineral. Mr. Tyson's ethiops is, how- ever, of more than double the usual strength, and should therefore be taken in proportionate doses. (Fharm. Journ.) ETHIOPS, VEGETABLE. Syn. ./Ethiops Vegetabius. Pulvis Quercus Marin.e. Blad- der wrack (fucus vesiculosus) burned in a'close vessel till it becomes black and friable. It has been used in bronchocele, &c.; and, like burnt sponge, probably owes any little virtue it may possess to the presence of a very small quantity of iodine. EUGENIN. Syn. Stearoptene of Oil of Cloves. Thin, white, pearly scales, found by Bonastre in oil of cloves. It smells and tastes of cloves, and is soluble in alcohol and ether EUPHORBIUM. PREPARED. Syn. Eu- phorbium prjBparatum. Prep. Euphorbium 2 oz.; len. .: juice, or vinegar, 1 pint. Dissolve, strain, and evaporate to drvness. EVAPORATION. Syn. Evaporatio, (Lat.) Evaporation, (Fr.) Abdunsten, Abdampfen, KGcr.) The dissipation of a fluid by means of heat. In Chemistry and Pharmacy evaporation is had recourse to, either for the purpose of recov- ering a solid body from its solution, as in the pre- paration of extracts, chemical salts, &c, or to strengthen a solution by the expulsion of some of the fluid matter that forms the menstruum. Evap- oration is also employed, though less frequently, to purify liquids, by dissipating the volatile matters which may contaminate them. Under ordinary circumstances, evaporation is confined to the sur- face of the heated liquid, and is therefore slower or quicker in proportion to the extension of that surface. Hence has arisen the adoption of wide ohallow vessels for containing fluids during their exposure to heat for this purpose. It has been found that evaporation proceeds most rapidly when a current of air is made to pass over the surface of the fluid, as, in this case, the vapor *ls prevented resting upon the surface, and impeding the process by its pressure. On the small scale, shallow capsules of glass, Wedgwood- ware, porcelain, or metal, are commonly employed as evaporating vessels, and these are exposed to heat by placing them over a lamp, or naked fire, or in a water-bath, or sand-bath, according to the temperature at which it is proper to conduct the process. On the large scale, high-pressure steam is usually employed as the source of the heat. The term "spontaneous evaporation" is applied to the dissipation of a fluid by mere exposure in open vessels, at the common temperature of the atmosphere, and without the application of artifi- cial heat The celerity of this species of evapora- tion wholly depends on the degree of humidity of the surrounding air, and differs from the former, in which the rate of evaporation is proportionate to the degree of heat at which the process is con- ducted, and the amount of pressure upon the sur- face of the liquid. Evaporation in vacuo (as it is called) is conducted under the receiver of an air- pump, or in an attenuated atmosphere, produced I by filling a vessel with steam, by which means the air is expelled, when all communication with the external atmosphere is cut off, and the vapor con- densed by the application of cold. Fluids are also evaporated in air-tight receivers over sulphuric acid, by which they are continually exposed to the action of a very dry atmosphere. When such a receiver is connected with an air-pump in action, evaporation proceeds with increased rapidity, and intense cold is produced. (See Congelation, Dis- tillation, Extracts, &c.) EXCORIATION. Syn. Excoriatio, (from excorio, to flay, or to cut off the skin.) An abra- sion. Young children are very apt to be chafed under the arms, behind the ears, between the thighs, and in the wrinkles -jid folds of the skin, unless great attention is paia ,o cleanliness, and wiping the skin perfectly dry after washing. Whenever there is a tendency to excoriations of this kind, either in adults or children, a little finely powdered starch, or violet powder, applied by means of a puff, or a small bag of muslin, once or twice a day, will generally remove them, and pre- vent their occurrence in future. Mild unguents, as cold cream, or spermaceti cerate or ointment, may also be used with advantage. The prefer- ence should, however, be given to the former remedies from their not soiling the linen. Exco- riations arising from the removal of the skin by friction or external violence, have already been noticed under the head Abra*sion. EXPECTORANTS. (From expectorare, to expectorate.) Medicines that promote the secre- tion of the tracheal and bronchial mucus. Ac- cording to Dr. Good, true expectorants are " those medicines which rather promote the separation of the viscid phlegm with which the bronchiae are loaded, than simply inviscate and dilute it; though these are also treated as expectorants by many writers." Numerous articles of the materia medica have been denominated expectorants, of which the following are the principal:—Tartarized antimony, ipecacuanha, squills, garlic, asafoetida, ammonia- cum, the oily resins, the balsams of tolu and Peru, benzoin, styrax, benzoic acid, the fumes of vine- gar, tar, and of many of the volatile oils, and the smoke of tobacco and stramonium. Chlorine and ammoniacal gases have also been called expecto- rants. Medicines of this class are commonly em- ployed in pulmonary complaints and affections of the air-tubes, attended by a vitiated state of the mucus, or an imperfect performance of the natural functions of the secretory vessels. " Of all classes of the materia medica, none are more uncertain in their action than expectorants." (Pereira.) The act of ejecting matter from the chest is called expectoration. EXPRESSION. Syn. Expressio, (Lat., from exprimo, to press out.) A mechanical operation, by which any fluid contained in the pores or cells of a solid is expelled. Many of the fluid sub- stances employed in pharmacy and chemistry are obtained by expression. Thus, the unctuous vege- table oils, as those of almonds, linseed, &c. &c, are procured by submitting those substances to powerful pressure between iron plates, which are either made warm, or the bruised seeds are previ- ously exposed in bags to the steam of boiling wa- I ter. The juices of fresh vegetables are also ob« EXT 286 EXT tained by expression. The substances are first bruised in a marble mortar, or, on the large scale, in a mill, and immediately submitted to the press, to prevent them passing into the state of fermenta- t tion, which would injure the quality of the product. Fruits which contain highly-flavored seeds, or which have rinds containing essential oil, should be deprived of them before pressing. The subacid fruits should also be allowed to lie together for some days before being pressed, as the quantity and quality of the product are thereby increased. The fluid matter absorbed by the ingredients em- ployed in the preparation of tinctures, infusions, decoctions, extracts, &.c, is generally obtained by powerful pressure. Expression is also frequently employed for the purpose of obtaining solids in a state of purity, as in the expulsion of oleine from stearine, and water from the bicarbonate of soda. On the small scale, the common screw-press, or one of like construction, is usually employed ; but the power thus obtained is insufficient to expel the whole of a fluid diffused through the pores of a solid. Hence has arisen the use of the hydraulic press, which is alone employed on the large scale. In all these cases, the substances are placed in bags made of hair-cloth, or coarse canvass, previ- ously to their being submitted to pressure. EXSICCATION. Syn. Exsiccatio, (Lat, from exsicco, to dry up.) The evaporation of the aqueous portion of solid bodies. In Chemistry and Pharmacy, this term is commonly applied to the operation by which plants and chemical prepara- tions are deprived of their humidity. This is done by exposure to the sun, a current of dry air, an atmosphere rendered artificially dry by sulphuric acid, or by the direct application of heat by means of a water-bath, a sand-bath, or a common fire. EXTRACTS. Syn. Extraits, (Fr.) Ex- tracten, (Ger.) Extracta, (Lat., from extraho, to draw out) In Chemistry, the residuum from the evaporation of aqueous decoctions, or infusions of vegetable matter. In Pharmacy, preparations obtained by evaporating the expressed juices, or the decoctions, infusions, or tinctures, of vegeta- ble substances, until a mass, of a solid or semi- solid consistence, is formed. Extracts vary in their nature and composition with the substances from which they are prepared, and the fluids em- ployed as solvents. When water is used for ma- king the solution, the extract will usually consist of gum, starch, sugar, albumen, and saline and other matter, along with a peculiar vegetable prin- ciple, which, from its occurrence in most plants, has received the name of extractive. This sub- stance was discovered by Fourcroy, and presumed by him to be the common basis of all extracts; but it has since been proved by Chevreul, and sev- eral other chemists, to be a heterogeneous com- pound, varying in composition with the plant from which it is extracted. This substance has a brown color, speedily putrefies, and becomes oxidized, and is rendered insoluble by long exposure to air, and by repeated solutions and evaporations. In its unaltered state it is soluble in vater, and in alco- hol, and is precipitated from its solutions by the acids and metallic oxides. With alumina it forms the basis of several brown dyes. In the prepara- tion of the greater number of extracts, water is employed as the menstruum, and these prepara- tions are called, by way of distinction, " watery extracts." When spirit is employed as the solv- ent, the extract may contain most of the sub- stances above enumerated, except gum, which is insoluble in strong spirit. Besides these, spirit dis- solves out many substances which are either whol- ly or nearly insoluble in water, as resins, essential oils, and the proximate principles of vegetables. Extracts prepared with alcohol, either alone, or diluted with water, are termed " spirituous ex- tracts," and, with scarcely an exception, are con- siderably more powerful than the aqueous extracts of the same vegetables. In some cases, dilute acid, (the acetic,) or acidulated water, is employed as the menstruum, and such preparations are hence called " acetic extracts." The extracts of aco- nite, hemlock, henbane, stramonium, and colchi- cum, as well as of all other plants containing alka- loids, possess greater activity when prepared with vinegar than with water. Thus, a quantity of either the alcoholic or acetic extract of colchicum, equal to the common dose of the aqueous extract, would most probably produce death. Still more active extracts may be obtained by a combination of the last two menstrua. According to Ferrari, plants treated with rectified spirit of wine, mixed with one-thirty-sixth part of pyroligneous (acetic) acid, yield extracts of remarkable activity. (Prov Med. Jour., 1843.) To the preceding may be added, that the term simple extract is applied to one prepared from a single plant, or vegetable substance, and the term compound extract to one prepared from two or more of such substances. The above are the principal varieties of extracts employed in British Pharmacy, all of which are classed under the general head Extracta, (ex- tracts,) in the London Pharmacopoeia ; but on the Continent, ether is sometimes used as the men- struum for the active principles of certain substan- ces, as cantharides, cubebs, sem. cinae, &c. Of all the foreign Pharmacopoeias, that of Ba- den is most prolific of extracts; its pages contain •directions for 58 or 60 of these preparations, of which the following is a brief notice:— I. Watery Extracts. a. (By displacem-nt with cold water.) Ext. absinthii; cardui b-'.e- dicti; %centaurii min.; chamomilla? ; china? fiucffi, (cinchona? ;) china? regia? ; dulcamara? ; fuma.iae; gentianre ; glycyrrhizoe ; graminis ord., (liquid and solid ;) ligni campech.; marrubii alb. ; mil'.efolii; rhatania?; rad. saponar; taraxaci, (ordinary and fluid ;) tormentilla? ; trifolii fibr. /?. (By the ordinary method of maceration.) Ext. aloes ; myrrhae; opii; scillae, valerianse; chi- na* fuscae. II. Spirituous Extracts, a. (Prepared with spirit of sp. gr. 0-944, by 24 hours' maceration, or by the method of displacement.) Ext. cort aurantii; angelica?; rad. arnica? ; calami; calen- dula?, (marygold ;) cascarillae ; -calumba? ; colo- cynth. ; inula? ; hellebori nigri; levistici, (Lovage ;) quassia?; rha?i. P. (Prepared in a similar way to the last with spirit of sp. gr. 0-841.) Ext. aconiti; belladon- na? ; chelidonii maj., (great celandine :~\ conii mac.; digitalis ; gratiola?, (hedge hyssop:) hyoscyami; lactuca? virosa? ; Pulsatillas, (Pasque fh.wer ;) herb. taxi baccatae, (yew ;) rad. artemisme, nucis vom- ica?. EXT 287 * EXT III. Ethereal Extracts. Cubebs; sem. cina?; and the roots of male-fern ; prepared as the last. IV. Compound Extracts. Ext. ferri pom.; ext rhsei co. To the above may be added fel. tauri inspiss. Though many of the above extracts may be su- perfluous, yet the directions for their preparation are doubtless very judicious, and it would promote in no small degree the success of the medical prac- titioner, if a like exactness pervaded the instruc- tions of the London Pharmacopoeia, and equal care and skill obtained in the pharmaceutical laboratory in England to that which is general in France and Germany. Prep. The preparation of medicinal extracts may be conveniently considered under two divi- sions, viz.: the production of a solution of the soluble portion of the substances operated on, and the reduction of this solution by evaporation to the consistence of an extract. When water is employed as the menstruum, the vegetable matter subjected to its action should be well bruised or reduced to coarse powder, or other- wise divided by slicing with a knife, that every portion may be fully exposed to the solvent powers of the fluid. The ingredients should then be treat- ed with water until all the soluble matter that it is desired to obtain is dissolved out. There are several methods of effecting this object, depending upon the nature of the vegetable substance acted on. In some cases, maceration in cold water is resorted to;—at other times, percolation with that fluid in a displacement apparatus; but more gen- erally, boiling water is poured on the substance, or it is boiled along with water, as in the preparation of infusions and decoctions. After the ebullition or infusion has continued a sufficient time, the heat is removed, and the liquid portion drawn off. The ingredients are then pressed to extract the remaining liquid, or, they are washed with hot water, which expels it by displacement In the majority of cases, however, a second quantity of water is poured On after the firot has been thorough- ly drained off, and the infusion or decoction is re- peated a second and a third time, or until the in- gredients are perfectly exhausted of their soluble portion. The several liquors, being allowed to re- pose for 15 or 20 minutes, for the purpose of de- positing the sand or other gritty and heavy matter that is mechanically mixed with them, are then carefully decanted from the sediment, and, after being run through a fine sieve, or flannel bag, are ready for concentration. The reduction of the solution to the proper con- sistence is effected by evaporation ; but the mode in which this is performed varies for different ex- tracts. The London College directs that, " unless otherwise ordered, the evaporation should be con- ducted as quickly as possible, in a broad shallow pan, placed in a water-bath, until a proper con- sistence is acquired for forming pills; stirring as- siduously with a spatula towards the end of the operation." Though the water-bath has the sanc- tion of the British colleges, it is doubtful whether it will be well adapted for ordinary purposes, as, from its low evaporative power, the advantages which are derived from its equable temperature, ere vastly overbalanced by the lengthened expo- sure of the solution in a heated state to the action of the atmosphere. It is doubtful whether a vege- table solution so prepared is not inferior in quality to a similar one, evaporated in a shallow pan over a naked fire, or placed in a sand-bath, provided proper care be taken, and assiduous stirring be adopted during the whole time of the exposure td heat. In practice, however, the use of a naked fire is perfectly inadmissible, as the least neglect on the part of the operator would probably lead to the incineration of the whole ; but the water-bath may readily be rendered available by the addition of one-fifth part of salt, which will raise its boiling point to 21b|° Fahr., and the temperature of the contained extract to 212° ; the remaining 6|° be- ing lost by the interposition of the substance of the evaporating vessel. ')u the large scale the evaporation of -extracts is usjally conducted in very wide, shallow copper or tinned-copper pans, having steam-tight jackets of cast iron, and heated by allowing steam to play between the two. In this way a very high evapo- rative power is obtained, and a degree of heat which may be regulated at the will of the operator, and which will at no time much exceed the temper- ature of boiling water. The rapid deterioration wnich vegetable juices and solutions undergo by exposure to the air, especially at high temperatures, has led to the in- troduction of apparatus, by which they may be concentrated without contact with the atmosphere, and at a less degree of heat than is required for that purpose in open vessels. Such is the method, commonly called Barry's process, in which the air is removed from certain air-tight refrigerators by the introduction of steam, which is then con- densed.by the application of cold, by which means a partial vacuum is obtained. Another process for attenuating the atmosphere over the surface of fluids during evaporation, is by the action of an air- pump. • This plan was introduced by Howard, and is commonly applied to the concentration of sirups in our sugar refineries. Extracts obtained by either of these methods are said to be prepared " in vacuo," and are found in practice to be im- mensely superior to the common extracts of the shops, and consequently require to be exhibited in proportionably small doses. When water, acidulated with acetic acid, is employed in the preparation of extracts, the vege- table substances are usually macerated in it, in the cold, or the dilute acid is sprinkled over the bruised plant in the fresh or recent state, and the whole is then submitted to strong pressure, to ex- pel the juice, which is strained and evaporated in the usual way, but preferably in a tin or plated- copper pan. Spirituous extracts are prepared by evapora- ting a concentrated tincture of the vegetable sub- stance in any suitable vessel, by which the volatil- ized spirit may be saved. Ethereal extracts are obtained in a similar manner; but being merely prepared in small quantities at a time, the process may be conveniently performed in glass vessels. When it is required to boil either of the above fluids, or any other volatile liquid on the ingredients, a vessel fitted with a long tube, or a Liebig's refri- gerator reversed, may be used to prevent any loss of the menstruum. (See Ether and Ethers, or- ganic) EXT . 288 EXT The inspissated vegetable juices are classed with extracts by the London College, and are ordered to be prepared by evaporating the expressed juice without filtration in a water-bath ; but in this way a considerable portion of their activity is lost. Some of these juices, as that of aconite, are impaired in so short a time as scarcely to compensate for the trouble of preparing them. This deterioration does not, however, take place in any remarkable degree, if the expressed juice from the recent vegetable be evaporated by exposing it in a thin stratum to a current of very dry air, as adopted by Mr. Squire. This may be managed by putting the juice into small flat trays or dishes, placed on shelves in a suitably arranged apparatus, alternated with simi- lar vessels of concentrated sulphuric acid, and by causing a current of dry air, at the common tem- perature of the atmosphere, to pass over them, by which means the moisture continually exhaling from the one will be absorbed by the other. Prac- tical experiments have fully demonstrated the superiority of this method of inspissating vegetable juices over every other plan at present in use ; " for it was shown that 10 grains of extract, thus prepared, were more than equal to 20 grains pre- pared in vacuo; and to more than 60 grs. of that prepared by the common process of boiling down the juice to an extract." The Dublin College directs that all simple ex- tracts, (extracta simpliciora,) unless otherwise or- dered, are to be prepared by boiling the vegetable matter in 8 times its weight of water till the liquid is reduced to one half; the liquor is then to be expressed, and after a short time allowed for defe- cation, to be decanted, filtered, and evaporated in a water-bath, until it begins to thicken, and then finally inspissated by a reduced heat, continually stirring until a consistence for forming pills be at- tained. I have already mentioned that it is proper to al- low the infusion or decoction to purify itself by defecation, and to pass it through a flannel or horse-hair strainer previously to concentration. This- may be regarded as a general rule for all ordinary extracts. But in some cases, this method will be found insufficient to render the liquid clear. Such solutions may be rendered transparent by clarification with a little white of egg, skimming off the scum as it rises, and straining through flan- nel in the common way; or they may be filtered through a bag made of very fine Welsh flannel, or of twilled cotton cloth, both of which should be soaked in clean water for at least an hour before use. Ill the small way, filters of linen or paper are sometimes employed ; but as all media sufficient- ly fine to renderjregetable solutions transparent soon choke up, such filters are objectionable, from the length of time the liquid has to be exposed to the air when they are employed. In this respect, the method of clarifying first mentioned is vastly preferable, and is inexpensive, expeditious, and easy of performance, and hence has been adopt- ed by many large manufacturers. In some houses, the aqueous infusion or decoction is allowed to repose for 24 hours, and then decanted and evaporated *. but such a plan is objectionable ; as, however smooth and glossy extracts so prepared may appear, their medicinal virtues are lessened by the lengthened exposure to the atmosphere. Spirituous tinctures should be filtered through r»per, and acetic solutions through linen, or paper supported on linen. Ethereal tinctures are pref- erably clarified by repose and decantation, as tin volatility of ether precludes its filtration, except in close vessels. Wrhen about one half of an aqueous solution*has evaporated, it is often advantageous to repass it through a flannel or horse-hair strainer, to remove the flocculi that generally form by the action of the heat and air. This is especially necessary with vegetable solutions prepared without boiling, and should be adopted whenever a smooth and sightly extract is desired. The directions previously given for " finishing off" extracts should be scrupulously attended to. Towards the end of the process, the heat should be lessened, and as soon as the extrifct acquires the consistence of thick treacle, it should be re- moved altogether, and the remainder of fluid mat- ter evaporated by the heat retained by the copper pan, the process being promoted by assiduous and laborious stirring with a suitably-shaped wooden spatula ; and this stirring should be continued until a proper consistence is attained and the extract is nearly cold. It must be carefully observed not to commence the stirring until the heat (steam) has been withdrawn, as, if an extract having a temper- ature of about the boiling point of water, or even a few degrees below it, be agitated, it becomes full of bubbles, and appears rough and puffy, and this appearance cannot be removed by subsequent stir- ring, or by any method but re-solution in water and re-evaporation. This is especially the case with the extracts of sarsaparilla, (simple and com- pound,) gentian, liquorice, and most others of a similar class. A good workman knows from expe- rience the proper time for the removal of the heat, but unpractised persons often fail in this particular. In such cases, should the heat retained by the evaporating pan, and by the extract, prove insuffi- cient to complete the process, a little more may be cautiously applied. Without assiduous and laborious stirring in the way described, a very smooth and glossy extract cannot be produced. To promote this artificial appearance, some per- sons add 3 or 4 per cent each of olive oil and gum arabic, dissolved in water, with about 1 or 2 per cent, of spirit of wine. In conclusion, it may be observed, that the great desiderata to be aimed at in the preparation of ex- tracts are, to suit the menstrua and the methods of manipulating to the peculiar characteristics of the active constituents of the vegetable sub- stances operated on. The pharmaceutist should always bear in mind that a perfect extract should be " a concentrated, solid mass, exactly repre- senting in medicinal efficacy the materials from whichJt has been prepared, and capable of being redissolved, so as to form a solution exactly similar to that whence it has been derived." (G. M. Mowbray.) An extract possessing equal strength to the whole mass of the ingredients from ^ which it has been prepared, is almost next to an impossibility, however desirable such a degree of perfection may be. The operator may deem him- self fortunate, if, after the exercise of the utmost skill and judgment, and accuracy of manipulation! he obtain a product only approximating to the ideai EXT 289 EXT picture of a perfect extract above quoted. It is a fact that is proved by practical experience, and is readily accounted for by chemical science, that the medicinal properties of all solutions of vegeta- ble matter are injured by being reduced to the solid state; arid this deterioration, more or less, takes place, whether the solvent be water, proof spirit, or alcohol. Thus the volatile portions, the essential oils, the aroma, &c, are nearly or wholly dissipated, and though these do not always form the principal or active ingredients of the vegetables from which extracts are prepared, yet it cannot be denied that they generally exercise a modify- ing and controlling influence over the other ingre- dients, which considerably alters their therapeuti- cal action. That the essential oils which mostly constitute the fragrant portion of vegi-tables are devoid of efficacy, it would be the height of folly to assert; examples to the contrary may be in- stanced in the oils of cloves and chamomile. The power of small doses of the former to lessen or prevent the griping properties of some acrid cathar- tics, and of the latter as a stomachic, are instances familiar to every one who has tried them. Yet in extractum anthemidis, no odor of chamomiles can be perceived, or, at least, if such exists, it is pro- duced by the addition of the essential oil after the solution has been evaporated. But this is a mere trifling deficiency, compared to that in the extracta aconiti, hyoscyami, belladonna?, conii, &.c, pre- pared according to the pharmacopoeia! process. In these cases, it is well known that the inert prep- arations are wholly deficient of the odor of the recent plant, and that in proportion as the odor is developed so is their activity preserved. Compare the powerful smell of the recently expressed juice of hemlock with the scarcely perceptible odor of the extractum conii, P. L. Yet the dose of the one often reaches 20 or 30 grs., while that of the other seldom exceeds 5 or 10 drops, or a portion equivalent in dry ingredients to considerably less than J a grain. Though I have mentioned some processes as preferable to others, and have noticed the inferi- ority of some of the officinal extracts, yet it is proper to observe that when extracts are ordered in prescriptions, those of the London Pharmaco- poeia should be alone employed by the dispenser, as the substitution of others would not only be vio- lating faith with the prcscriber, but might produce consequences alike injurious to the dispenser and the patient. Many medical gentlemen prefer ex- tracts prepared by particular processes or persons, but such is always indicated in their prescriptions. A serious accident of this sort lately came under my notice. A druggist had prepared a number of prescriptions from an extract which he had pur- chased of a wholesale drug house, and which was labelled P. L., but was in reality almost inert, and in consequence of the presumed insensibility of the patient to its narcotic action, the medical practi- tioner had gradually increased the quantity to an enormous extent. In the mean time, the druggist's small stock of extract was exhausted, and another pot purchased of the same parties, which was of an average quality: in came the receipt as usual; but this time it was prepared from the new extract I need scarcely mention the consequences:—loss •f speech, coma, delirium, and death ensued. 37 Pres. Extracts should be put into pots as soon as taken from the pan, and, after being securely tied over with bladder, should be placed in a dry situation. The London College orders " a small quantity of rectified spirit to be sprinkled upon all the softer extracts, to prevent them becoming mouldy." A better way is, however, to employ a little spirit, holding in solution a few drops of o I of cloves, or a still less quantity of creosote. This should be added to them the last thing before re- moving them from the evaporating pan, and when they are nearly cold. Hard extracts should be kept in bladders or gut skins, placed in stone pots, and well covered over. With care, extracts pre- pared from recent vegetable substances may be preserved twelve months, or from season to season ; and those from dry ingredients, or such as are 'ess inclined to spoil, for perhaps double that time ; but beyond these periods their virtues cannot be relied on, and they should consequently be discarded, if remaining unused or unsold. Qual., pur., tyc. The quality of an extract can not be ascertained by mere inspection, nor can it be readily discovered by chemical tests. A know- ledge of these facts has induced the mercenary and fraudulent manufacturer to employ damaged and inferior drugs in their preparation, regardless of their slight medicinal virtues and the welfare of the patient. The production of a smooth, bright, and glossy article is all that is usually attempted by these individuals, and all that is sought after by the mass of purchasers, who mistake the mere ex- ternal appearances of good quality for its actual existence. But it is a fact, which I can verify from extensive experience in the laboratory, and from years of observation on this point, that the mass of extracts, faithfully prepared from good materials, do not possess such a sightly and pleas- ing appearance as those commonly vended by the wholesale druggists. I have with great care, for some years, compared the. extracts prepared by different metropolitan houses, and, without being desirous of making any remarks hurtful to the feelings, or injurious to the interests of any individ- ual in particular, I feel bound to state, that those extracts that have come under my notice, and which exhibited a remarkably bright and glossy appearance, I have found to be uniformly inferior, and sometimes nearly inert, while those that ap- peared less prepossessing were generally of good quality. This is also well established by reference to the extracts of those houses and institutions that are remarkable for the superior quality of theii preparations, and by comparing them with the common extracts of tho shops supplied by the wholesale trade. Without naming any private individual or establishment in particular, I will only instance the extracts last mentioned, and those of Apothecaries' Hall. It is a common practice with some manufac- turers, not only to pick out the least expensive va- riety of every drug for the preparation of their extracts, but the most inferior, and often damaged and worthless portion of this already inferior arti- cle. I have seen rubbish employed for this pur- pose that an honest man would not pick off a dunghill; and yet, because the worthless product obtained from this stuff has been " finished off in such a manner as to exhibit a smooth and glossy EXT 290 EXT appearance, it has been sold at a good price, and been deemed of superior quality by the purchaser. A good extract should be free from grit, and wholly soluble in 20 parts of the menstruum em- ployed in its preparation, forming a nearly clear solution; it should have a uniform texture and color, and be of a proper consistence. The ex- tracts prepared from the expressed juices of plants, without straining off the coagulated albumen, are of course exceptions to the second particular. The best mode of ascertaining the medicinal value of extracts is to assay them for the proxi- mate vegetable principles contained in the plants from which they have been prepared, or, where this is impossible, they may be exhibited in proper doses, and the effects carefully watched. Unfor- tunately, however, these tests are not easily per- formed, and are inapplicable to those extracts that exercise no very marked physiological action, un- less when taken in repeated doses, and long con- tinued. This want of a ready means of accurately testing the qualities of extracts, has enabled the fraudulent manufacturer to sell inferior articles with impunity, and without even the fear of de- tection. Prop, and Uses. The extracts of the shops are generally acknowledged to be the most varying, imperfect, and uncertain class of medicines con- tained in the pharmacopoeia. They are mostly used in the same cases as the plants from which they are prepared, but in smaller doses. EXTRACT, BLACK. Syn. Ext. Nigrum. Extract of cocculus indicus. It is used by fraudu- lent brewers to impart an intoricating property to EXTRACT OF ACONITE. Syn. Ext. of Monkshood. Do. of Wolfsbane. Extrait d'- Aconit, (Fr.) Eisenhutlein-extrakt, (Ger.) ESTHATTO DI AcONITO, (Ital.) R -'.ark. The extract of the root is said to be 12 times as strong as that of the leaves. EXTRACT OF ALOES. Syn. Purified Aloes. Alof.s Lota. Gummi Aloes. Extract- um Aloes, (P. L. 1H09.) Ext. Aloes purifica- tum, (P. L. lis-21, and since.) Ext. Aloes He- patic*,, (P. D.) Extrait d'Aloes, (Fr.) Aloe- extrakt, (Ger.) Estratto d'Aloe, (Ital.) Prep. (P. L.) Hepatic aloes, in powder, §xv ; boiling water 1 gallon; macerate for 3 days in a gentle heat, strain, defecate, decant the clear, and evap- orate. Remarks. The object of this process is to de- prive the aloes of resin, on which its acrid and griping qualities have been erroneously supposed to depend. When made with the juice, it formed the old Aloes Depurata, and with the juice of borage, bugloss, &c, the old Aloe Insuccata. Dose. 5 to 15 grs., in the same cases as powdered aloes. EXTRACT OF ANEMONE. Syn. Ext. Anf.monib Prate.nsis. Prep. The undepurated expressed juice of the anemone pratensis, evapo- rated to a proper consistence. It is said to be resolvent, and has been given in some chronic dis- eases, especially amaurosis, cataract, opacity of the cornea, nocturnal pains, suppressions, &c. fStoerck.) EXTRACT OF BARD AN A. Syn. Ext. of Burdock. Ext. BardanjE. Prep. (P. Cod.) Grind the root moderately fine with half its weight of dis tilled water, macerate for 12 hours, then put it into a percolator, and pass temperate water through it until exhausted; filter, and evaporate in a wa- ter-bath EXTRACT OF BARK. Syn. Ext. of Cin- chona Bark. Extrait de Quinquina, (Fr.) Es- tratto di China, (Ital.) China-extrakt, (6rer.J Prep. I. (Ext. Cinchona, P E. Ext. Corticis Peruviana. Ext. Cinchona Resinosum. Ext Corticis Cinchona cum Resina.) Any variety of cinchona bark, reduced to fine powder, ^iv proof spirit f^xxiv ; percolate, distil off most of tha spirit from the tincture, and then evaporate in a water-bath to a proper consistence. (P. E.) Remarks. The ext. cinchona? (P. D.) is an aqueous extract of lance-leaved cinchona bark. The aboJve extract is kept in two forms ; one hard and dry for powdering ; the other of a pillular con- sistence. The one is called Extractum Cin- chonas molle ; the other Ext. Cinchona durum. The ext. cinchona cum resina, (F. T- 1788,) and the resinous extract of bark of the shops, are pre- pared in the same way as extract of cascarilla. II. (Extract of lance-leaved cinchona bark; ext. of pale do.; ext. corticis Peruviani, P. L 1745, 1788. Ext cinchona, P. L. 1809, 1824. Ext. cinchona lancifolia, P. L. 1^-36.) Prep. Pale bark, bruised, ^xv; water 4 gallons; boil with 1 gallon of water till reduced to 45 pints, and strain while warm; repeat the same process wun eacii remaining gallon of the water, and finally evapo- rate the mixed solutions. III. (Extract of yellow cinchona bark. Ext, of heart-leaved do. Extractum cinchona cordi- folia, P. L.) Prep. The same as the last. Nei- ther this extract nor the following is kept in the shops; and, as far as my knowledge extends, is never employed or asked for. IV. (Extract of red. ciwhona bark. Ext. of oblong-leaved do. Ext. cinchona oblong ifolia, P. L.) Prep. The same as the last. V. (Essential salt of bark. Extractum cincho- na per aquam< frigidam.) Prep. (P. Cod.) Ex- haust the bruised bark by maceration in successive portions of cold water, evaporate the mixed infu- sions to the consistence of a soft extract, spread it thinly on earthen or porcelain dishes, dry by a gentle heat, and chip off the extract Remarks. The aqueous extracts of cinchona bark possess little medicinal virtue, and this prin- cipally arises from the insolubility of the alkaloids, (quinine, cinchonine,) or their most valuable por- tion, in water, and also from the rapid oxidation of their extractive matter, when exposed in solution to the joint action of heat and atmospheric oxygen. The spirituous extract of the P. E. is less objec- tionable. Dose. 5 grs. to 3ss, dissolved in water, faintly acidulated with sulphuric acid. Cinchona bark yields about 25°. of aqueous extract. EXTRACT OF BELLADONNA. Syn. Ext. of Deadly Nightshade. Ext. Belladonna, (P. L. and E.) SuccusSpissatub Belladonna, (P. D.) Extrait de Belladonne, (Fr.) Bella donna- extrakt, (Ger.) Estratto di l'Erba di Bella- donna, (Ital.) Prep. I. (P. L. and D.) As ex- tract of aconite. II. (P. E.) Bruise the plant in a marble mor- EXT 291 EXT th w tar, express the juice, sprinkle the residuum with water, and again press, mix the two liquids, filter, and evaporate in a water-bath. Remarks. This extract is an acro-narcotic. Dose, i gr. to 5 grs. It is principally employed to allay pain and nervous irritation in neuralgia, tic-douloureux, &.c.; as an antispasmodic to re- lieve rigidity and spasms of the muscular fibre in various affections of the uterus, rectum, urethra, bladder, &,c., and in hooping-cough ; in various maladies of the eyes ; and as a resolvent and dis- cutient in several glandular diseases. It has been recommended by some German physicians as a preservative against scarlet fever. It is most fre- quently employed externally, under the form of a plaster, ointment, or lotion. It is poisonous. Fresh belladonna yields about 5-g of extract. (Brande. \ GraY-) EXTRACT OF BISTORT. Syn. Ext. Bis- tort.*:. (P. Cod.) Prep. As extract of bardana. It is astringent and tonic. EXTRACT OF BLACK HELLEBORE. Syn. Ext. IIellebori Nigri, (P. L. 1788.) Ext. Radicum Hf.lleb. Nig. Prep. Macerate the bruised root in 10 parts of boiling water for 24 hours, express the liquid, strain, and evaporate. Remarks. When prepared by coction with wa- ter till exhausted of soluble matter, black hellebore root yields about 40$ of extract. It is alterative, cathartic, and resolvent Dose. 2 to 20 grs. EXTRACT OF BITTER-SWEET. Syn. Ext. of Woody Nightshade. Ext. Dulcamara?:. Prep. (P. Cod.) As the last. It is diuretic, dia- phoretic, and narcotic. EXTRACT OF BROOM TOPS. Syn. Ext. Cacuminum Genistas. Ext. Spartii Scoparii, (P. D.) Boil the tops of broom in 8 times their weight of water, till reduced to one half, express the liquid, strain, and evaporate. Dose. J a dr. to 1 dr., as a diuretic in dropsy. Seldom used. EXTRACT OF CALAMUS. Syn. Ext. of Common Sweet Flag. Ext. Acori. Ext. Cal- ami Aromatici. From the Rhizomes of the acorus calamus. EXTRACT OF CALUMBA. Syn. Ext. Ra- dicisCalu.mbas. Prep. From calumba root, in the same way as extract of dandelion. Bitter, tonic, stomachic. EXTRACT OF CANTHARIDIS. Syn. Ext. of Spanish Flies. Ext. Cantharidis. Ext. Lytt.e. Prep. (P. Cod.) Evaporate a tincture made with proof spirit. EXTRACT OF CASCARILLA. Syn. Ext. Cascarillas. Ext. Corticis Cascarillai. Prep. (P. L. 1788.) Cascarilla lb. iiss; rectified spirit of wine 1 gallon; macerate for 4 days, and express the liquid; boil the residue in water 2 gallons, and strain. Distil off the spirit from the tincture till the latter acquires the consistence of honey, then mix it with the decoction, also brought to the same con- sistence by evaporation, and continue stirring until the whole is reduced to a proper consistence. Remarks. This extract is tonic and stomachic. oat. 5 to 15 grs., or more, 2 or 3 times a day. 28 lbs. of bark yield 5} lbs. of extract. EXTRACT OF CATECHU. Prepared from the wood of the mimosa, or acacia catechu. It is "wholly imported, and is commonly known as Japan earth, terra Japonica, &c. It is astringent and tonic. Dose. 5 grs. to 3ss, or more. It is mostly used in dyeing and tanning. EXTRACT OF CHAMOMILES. Syn. Ext Florum Chamasmeli. Ext. Chamasmeli, (P. D.) Ext. Anthemidis, (P. E.) Ext. Anthemidis Mo- bilis. Extrait de Ca.mo.mille Romaine, (Fr.) Kamillen-extrakt, (Ger.) Est-iatto di fiori di Camomillo, (lial.) Prep. From the flowers, as extract of dandelion. Bitter, tonic, and sto- machic. Dose. 10 to 20 grs. Remarks. This extract contains all the bitter portion of the chamomile, but none of the aromat- ic volatile oil; the latter being dissipated during the evaporation. It is usually prepared from flow- ers that have lost their smell from age, and are thus rendered unsaleable. The extract of chamo- mile that has been lately offered for sale by some houses, and which smells strongly of the flowers, is prepared by adding 1 drachm of the essential oil to every pound of extract, when nearly cold, and just before removing it from the evaporatioii pan. The mass of this extract met with in the shops is nothing but extract of gentian flavored with oil of chamomile. 1 cwt. of chamomiles yields about 48 lbs. of extract. EXTRACT OF COCCULUS. Syn. Hard Multum. Black Extract. Ext. Cocculi In- dici. Prep. By decoction with water. It is nar- cotic and poisonous. Employed by fraudulent brewers to give a false strength to their liquor. EXTRACT OF COLCHICUM. Syn. Ext. of the corms of colchicum. ext. of meadow Saffron. Ext. Colchici. Ext. Colchici Cormi, (P. L.) Prep. As extract of aconite, P. L. (See page 24.) It is given in the usual cases in which colchicum is employed. Dose. 1 to 4 grs. every third or fourth hour. (Thomson.) " This is a fa- vorite remedy of Dr. Hue of St. Bartholomew's Hospital, in the early stages of acute rheumatism. The dose is 1 gr. every four hours." (Pereira.) EXTRACT OF COLCHICUM, (ACETIC.) Syn. Acetic Ext. of Colchicum. Do. of Mea- dow Saffron. Ext. Colchici Aceticum, (P. L.) Prep. Fresh colchicum (cormi) lb. j ; acetic arid f^iij ; bruise the corms, sprinkle on the acid, ex- press the juice, and evaporate in a Wedgewood- ware or salt-glazed earthen vessel. Dose. 1 to 3 grs. two or three times a day. It is stronger than the common extract. Remarks. The above extracts are generally prepared from the dried corms, and hence the va- rying activity and inferior qualify of those com- monly met with. The simple extract is made by decoction with water and evaporation ; but the product rapidly gets dry and crumbly, and will scarcely keep a week in warm weather without becoming mouldy, unless spirit be added. It has not above \ of the activity of the ext colchici, P. L. The following form is employed by several wholesale houses, and, I believe, a similar one is adopted by the majority of persons to the exclu- sion of that of the college:—colchicum (cormi, dried) 14 lbs.; pyroligneous acid (acetic) 6 pints; distilled water 5i gallons; digest 14 days, filter, and evaporate. Product. 2$ to 3 lbs. Inferior to the ext. colchici aceticum, P. L. The same quan- tity of colchicum treated with water, by decoction, yields more than half its weight of simple extract, which is considerably more than that procured by EXT 292 EXT the process of the college; hence its adoption by the druggists. EXTRACT OF COLOCYNTH. Syn. Ext. of Bitter Apples. Ext. Colocynthidis Molle. Ext. Colocynthidis, (P. L., E.. & D.) Prep. Co- locynth pulp, sliced, lb. j ; water 2 gallons ; boil for 6 hours, adding more water as it wastes, strain and evaporate. Remarks. This extract rapidly gets hard,crum- Dly, and mouldy by keeping ; but this may be pre- vented by adding a little spirit, holding in solution a few drops of oil of cloves. Dose. 5 grs. to 3j, as a cathartic. Colocynth pulp yields 65g of extract EXTRACT OF COLOCYNTH, (COM- POUND.) Syn. Compound Ext. of Bitter Ap- plies. Ext. Cathartici m, (P. L. 1745.) Ext. Colocynthidis compositum, (P. L. 1788, and since.) Prep. I. (P. L. 1836.) Colocynth pulp, sliced, §vj ; purified extract of aloes (ext. aloes purif., P. L.) §xij; powdered scammony §iv ; pow- dered cardamoms ^j 5 hard soap (Castile) ^''j j proof spirit 1 gallon ; digest the colocynth in the spirit, with a gentle heat, for 4 days, express the tinc- ture, filter, add the aloes, scammony, and soap, evaporate (distil) to a proper consistence, and to- wards the end add the powdered cardamoms. II. (P. D.) The same as the London form, except using hepatic aloes for the aqueous extract. Remarks. There are few formula? which have undergone so many alterations in the hands of the College as that for the ext. coloc. co. Before 1809, proof spirit was ordered to be employed as the menstruum, and the preparation resembled that of the present Pharmacopoeia, omitting the soap ; but in 1809, the College directed water to be used instead of spirit, and added a certain quantity of soap.—Colocynth 3vj ; water lb. ij; aloes (socc.) §iss; scammony 3SS > hard soap §iij ; cardamoms 3j. (P. L. 1809.) In the next edition of the Phar- macopoeia, or that of 1815, the soap was again omitted; but in the edition of 1824, the formula of 1809 was again adopted, substituting, however, proof spirit lb.j for the water. These directions were also continued in the edition of 1836, as will be seen by reference to the above formula, (No. I.,) which is that of the present Pharmacopoeia. Compound extract of colocynth, when faithfully prepared, is a most valuable medicine, but that which is commonly met with in trade is a very in- ferior and uncertain preparation. This inferiority of the extracts of the shops, chiefly arises from the substitution of water for the proof spirit ordered by the College, and the use of inferior scammony and aloes. There are, however, many establishments where this extract may be procured of most ex- cellent quality, but these are the exceptions, not the rule. As a proof, however, of the proverb, " honesty is the bc->t policy," it may be mentioned that a certain metropolitan druggist, remarkable for the superiority of his compound extract of colo- cynth, has obtained no inconsiderable fortune by the sale of this preparation alone ; while the miser- able host of venders of the evaporated decoction of colocynth seeds, Cape aloes, worthless scammony, and scentless cardamoms, sold under this name, attempt to ruin each other by offering their rub- bish at a price that prevents the possibility of a large profit, or even the establishment of a re- spectable connection. The following forms are employed by a whole- sale house that does very largely in this prepara- tion : III. Turkey colocynth 18 lbs.; hepatic aloes 40 lbs.; Castile soap 10 lbs.; powdered scammony 6 lbs.; essence of cardamoms 2 lbs.; moist sugar 4 lbs.; boil the colocynth in 20 times its weight of water for six hours ; strain and add the aloes; boil until dissolved, and decant the solution. In the mean time exhaust the colocynth with a second quantity of water, less than the first, strain and add this to the undissolved residuum of the aloes, boil again for a few minutes, then draw it off, mix it with the former decoction of aloes, and allow the mixed liquors to stand until the next day, to depos- ite the resinous portion. Next draw off'the liquor, evaporate as quickly as possible, and as soon as the consistence of treacle is arrived at, allow the whole to cool considerably, and add the soap (pre- viously melted with a little water) and the scam- mony. Sift the latter in gradually, while the ex- tract is assiduously stirred by a second person. Lastly, moderate the heat and continue the stir- ring until a rather harder consistence is acquired than is proper for the extract, then, as soon as the whole has become sufficiently cool to prevent any considerable evaporation of the spirit, add the es- sence, mix thoroughly, and immediately put it into stone jars or pots for use. The extract is usually labelled Ext. Colocynth. Comp. Opt. It looks well, and smells very aromatic. IV. Turkey colocynth 2\ lbs.; hepatic aloes 5i| lbs.; powdered scammony 1 "j lbs. ; powdered car- damoms 6 oz.; (or essence 8 oz. ;) Castile soap (genuine) 1 lb. 2 oz.; pale moist sugar i lb.; as the last. This certainly products a beautiful ar- ticle, and of excellent quality, though of course inferior to the extract of the College. It is labelled and sent out as Ext. Colocynth. Comp. P. L. The compound extract of colocynth, and the simple and compound extracts of sarsaparilla, are in greater demand in the wholesale trade, and are sold in larger quantities at a time, than all the other medicinal extracts put together. Qual. and Tests. This extract is often adulter- ated with powerful and acrid cathartics to make up for the deficiency or inferiority of its proper in- gredients, and foreign matter often becomes mixed with it by the use of impure scammony. The presence of Cape aloes may usually be detected by the odor ; chalk, (an article frequently present in bad scammony,) by placing a little ball of the e 'ract in a glass tube, and pouring over it some dilute muriatic or acetic acid, when an efferves- cence will ensue, if that substance be present; jalap, scammony adulterated with fecvla, and other starchy substances, by the filtered decoction of the extract turning blue on the addition of tincture of iodine ; gamboge, by the decoction be- coming deep red on the addition of liquor of potassa, and by a filtered alcoholic solution of the extract forming a yellow emulsion with water, which be- comes transparent and assumes a deep red coior on the addition of caustic potassa, and by this solu- tion (if the alkali be not in excess) giving a yellow precipitate with acids and with acetate of lead, a brown precipitate with sulphate of copper, and a very dark brown one with the salts of iron. The ethereal solution dropped on water yields an opaque EXT 293 EXT yellow film, also soluble in caustic potassa, if gam- boge be present. Dose. 5 grs. to 3j. It is a safe, mild, yet cer- tain purgative. It may be mixed with calomel without the latter being decomposed. 2\ grs. mixed with an equal weight of blue pill and taken overnight, forms an excellent aperient in dyspepsia, liver complaints, &c. EXTRACT OF CUBEBS. (OLEO-RESI- NOUS.) Syn. Ext. Cubebas Oleo-resinosum. Prep. (M. Dublanc.) Mix the oil obtained by distillation, with the resinous extract obtained by evaporating a spirituous tincture of the dried resi- duum. Possesses the whole of the virtues of cubebs in a very concentrated form. EXTRACT OF DANDELION. Syn. Ext. of Taraxacum. Ext. Taraxaci, (P. L. & E.) Ext. Herba?. et radicis Taraxaci, (P. D.) Low- enzahn-extrakt, (Ger.) Estratto di Taras- saco, (Ital.) Extrait de Pissenlit, (Fr.) Prep. Macerate the fresh root of taraxacum in 10 or 11 times its weight of boiling distilled water for 24 hours, then boil down to £, strain and evaporate to a proper consistence. Remarks. The above are the orders of the Col- lege, but the extract is better when prepared by rapidly inspissating the expressed juice in a current of dry air. The extract of the shops is usually prepared by exhausting the root by coction with water. The first of the above has a faint and agreeable odor, and a sweet, bitter taste ; the second smells strongly of the recent root, has a pale and lively brownish yellow color, and a bitter acidulous taste without any trace of sweetness; the third is devoid of odor, and possesses a coffee- brown color, and a sweetish, burnt taste, not much unlike a solution of burnt sugar. The medicinal virtue of this extract is greatest when the aroma and bitter taste of the recent root are well develop- ed, and when sweet, its efficacy as a remedy is impaired. (Squire.) The Dublin College directs tho employment both of the herb and root. Tarax- acum root should be gathered during the winter months, as then a given weight of the juice yields more extract, but in summer and autumn it pos- sesses more bitterness and aroma ; 4 lbs. of juice from roots gathered in November and December yielded 1 lb. of extract, while it took from 6 to 9 lbs. of juice from the root, gathered in spring or summer, to yield a like quantity. (Squire.) The herb yields by the evaporation of its expressed juice, about 5§ of extract. Good extract of tarax- acum should be wholly soluble in water. Dose. 10 grs. to 3ss, as a resolvent, aperient, and tonic in liver and stomach complaints, &c. EXTRACT OF DANDELION. Syn. Ext. Foliorum Taraxaci. From the leaves, as the last. EXTRACT OF ELATERIUM. Syn. Ext. of Squirting Cucumber. Elaterium. Ext. ElATERII, (P. L.) SUCCUS SPISSATUS M0M0RDICA5 Elaterii. Prep. (Process of the L. Ph.) Slice ripe wild cucumbers, very gently express the juice, strain through a fine hair sieve, and set it aside for some hours, until the thicker part has subsided; then decant the supernatant liquor, and dry the remainder by gentle heat. (See Elaterium.) Remarks. Good elaterium should have only a light greenish hue, and should be light and easily pulverized by pressure. Elaterium obtained as a second deposite, is dark and inferior, and hence called elaterium nigrum. The English elaterium is the best. The foreign is uniformly adulterated with chalk, and colored with sap green. Dose. One-sixth gr. to 2 grs., as a hydragogue and cathar- tic, in dropsies. EXTRACT OF ELATERIUM, (WHITE.) Syn. White Elaterium. Elaterium Album. Prep. From the half-ripe fruit of the squirting cucumber, as last. Its properties are similar EXTRACT OF ELECAMPANE. Syn Ext. Inul.e. Ext. Radicum Inul.e Campan.e. Prep. From elecampane root, like extract of dan- delion. EXTRACT OF FOX-GLOVE. Syn. Ext. Digitalis, (P. L. & E.) Prep. From the leaves of digitalis purpurea as extract of aconite, P. L. (See page 24.) , Remarks. The juice of foxglove is readily in- jured by exposure to air and heat. The evap- oration should therefore be conducted as rapidly as possible, but at a low temperature. It spoils by keeping. Dose, "j gr. to 3 grs. It is narcotic, sedative, and diuretic, and is powerfully poisonous. It is principally given in fevers, dropsy, diseases of the heart, pulmonary consumption, epilepsy, scro- fula, and asthma. EXTRACT OF FUMARIA. Syn. Ext Fumarias. Prep. From the leaves of the com- mon fumitory, like extract of dandelion. It has been recommended in some diseases of the leprous kind. EXTRACT OF GENTIAN. Syn. Ext. Gentianas Molle. Ext. Radicis Gentianas. Ext. Radicis Gentianas lutf.as, (P. D.) Ext. Gentianas, (P. L. and E.) Extrait de Gentiane, (Fr.) Estratto di Gentiane, (Ital.) Exzian- extrakt, (Ger.) Prep. From gentian root sliced, as extract of dandelion. Remarks. The Edinburgh College directs the powdered root to be exhausted by percolation with temperate water. On the large scale this extract is almost universally prepared by exhausting the root by coction with water. When well prepared it is one of the smoothest and liveliest-looking ex- tracts of the pharmacopoeia. Good gentian root yields by the process of the College fully 50$ by weight of extract, and by decoction about 60$. Dose. 10 grs. to 3ss, as a bitter stomachic and tonic. The great consumption of extract of gen- tian is by the brewers. EXTRACT OF GENTIAN, (HARD.) Syn. Ext. Gentianaj Durum. The last extract re- duced to a proper consistence for powdering. EXTRACT OF GUAIACUM. Syn. Ext. Ligni Vitas. Ext. Guaiaci. Ext. Ligni Guaiaci Molle. Prep. (P. L. 1746.) From lignum vita? shavings or sawdust, bv decoction with water. EXTRACT OF HELLEBORE, (ALKA- LINE.) Syn. Ext. Hellebori Alkalinum. Ext. Hellebori Bacheri. Prep. (P. Cod.) Black hellebore lb. j ; carbonate of potassa £iv; proof spirit and white wine, of each 3 pints ; digest 12 hours, strain and evaporate. (See Ext. of Black Hellebore.) EXTRACT OF HEMLOCK. Syn. Succus spissatus Conii maculate Succus Cicutas spis- satus, (P. L. 1788.) Extractum Conii, (P E. EXT 294 EXT and P. L. 1809, and since.) Succus inspissatus Conii, (P. D.) Estratto del Erba della Ci- cuta, (Ital.) Estrait de Cigue, (Fr.) Schier- lings-extrakt, (Ger.) Prep. (P. L.) From hemlock leaves, like extract of aconite, P. L. Remarks. The Edinburgh College directs the filtered juice to be evaporated in vacuo, or by means of a current of dry air. Of all the inspis- sated juices (excepting aconite) that of hemlock is most readily injured by exposure and heat. Its active principle is a volatile alkaloid named conia, and in proportion as the extract smells of this sub- stance, so is its medicinal value. Good extract of hemlock should have a green color, a strong odor of the fresh bruised plant, and should develop a strong " mouse odor" when triturated with caustic potassa. On the large scale the whole of the green portion of the plant is pressed for juice. 1 cwt. of hemlock yields from 3 to 5 lbs. of extract. Dose. 2 grs. to 3ss, as an alterative and resolvent in various obstinate disorders. EXTRACT OF HENBANE. Syn. Ext. of Hyoscyamus. Ext. Hyosciami, (P. L. and E.) Succus spissatls Hyoscyami, (P. D.) Succus spissatus Hyoscyami nigri. Extrait de Jusqui- ame, (Fr) Hyoszyamis-extrakt, (Ger.) Es- tratto di Giusquia.ma nera, (Ital.) Prep. (P. L.) From the leaves of henbane, as the extract of aconite, P. L. (See page 24.) Remarks. The Edinburgh Ph. directs this ex- tract to be prepared in the same way as the ex- tract of hemlock, P. E. 1 lb. of the fresh leaves yielded 8 to 10 drs. of extract, (Geiger;) 1 cwt. yielded 4 to 5 lbs., (Brande ;) 1 cwt. of the recent plant yielded by an ordinary screw press 59J lbs. of juice, and this evaporated in a water-bath gave 5 lbs. 9 oz. of extract. (Squire.) If cwt. of the green herb yielded 11 pounds of extract. (Gray.) Dose. 2 to 20 grs. as an anodyne, and antispas- modic. It is narcotic and poisonous. EXTRACT OF HOPS. Syn. Ext. Lupuli, (P. L. aud E.) Ext. Humuli, (P. L. 1809, 1824, and P. D.) Prep. From the strobiles of hops, in the same way as extract of dandelion. Remarks. 1 cwt. of ordinary hops yield about 40 lbs. of extract. (Brande.) The druggists usu- ally employ hops 2 or more years old, called by the dealers " yearlings," " olds," or " old olds," because these may be purchased at § to ^ the price of those of the last season's growth. The first of the above are estimated to have only § the strength of new hops ; the second about \ ; and the last little or none, at least in a medical point of view. Dose. 5 to 20 grs., as an anodyne, in cases that do not admit of the use of opium. EXTRACT OF INDIAN HEMP. Syn. Ext. Cannabis Indici. Prep. (O'Shaughnessy.) Boil the resinous tops of the dried gunjah, (the Indian hemp plant, which has flowered, and from which the resin has not been removed,) in rectified spirit of wine until all the resin is dissolved, then distil off the spirit, and finish the evaporation in a water-bath. Remarks. It is anodyne, stimulant, and aphro- disiac, and, in over doses, produces catalepsy. (O'Shaughnessy.) 10 to 20 grs. of this preparation have been recommended in hydrophobia ; but, ac- cording to the above authority, 1 grain produced catalepsy in a rheumatic patient. The extract prepared with the plant grown in our botanic gar- dens has quite a different effect to that of the Indian plant. This hemp is known in India as the " increaser of pleasure," the " exciter of desire,' the " cementer of friendship," the " causer of a T3eling gait," the "aughter-mover," &c. (For a fuH examination i. xo the merits of this plant, and the opinions of preceding writers, see Dr. Pereira'a valuable work on Materia Medica, 2d ed.) EXTRACT OF IPECACUANHA. Syn. Ext. Ipecacuanhas. Prep. (P. Cod.) Evaporate a tincture prepared from powdered root of ipecacu- anha lb. ij, and proof spirit lb. vij, by the method of displacement. EXTRACT OF JALAP. Syn. Ext. Jalapii, (P. L. 1745, 17t--t\) Ext. Jalap/e, (P. L. 1809, and since.) Ext., sive Resinas Jalapa*:, (P. E.) Ext. Jalapii Molle. Ext. Jalapas Resinosum. Ext. Radicis Jalapas. Ext. Convolvuli Jalapas. Extrait de Jalap, (Fr.) Prep. I. (P. L.) From the root of the ipomrra jalapa, in the same way as extract of cascarilla,' P. L. 17b8. Product. About 66-g- of the weight of the jalap employed. (Brande.) 18 lbs. of jalap yield, in this way, 16 lbs. (7) of extract. (Gray.) II. (P. E.) Moisten finely-powdered jalap with rectified spirit, put it into a percolator, and exhaust it with more spirit; filter, recover the greater part of the spirit by distillation, and finish the evapora- tion in a water-bath. This is an impure resin of jalap. Product. 16$. III. (P. D.) Similar to the London form, and produces, like that, a mixture of resin of jalap and gummy extractive matter. Remarks. The extract of the London and Dub- lin Colleges is purgative in doses of 10 to 20 grs.; that of the Edinburgh in doses of 2 to 6 grs. The) should be well beaten up with a little sulphate ol potassa, sugar, or some aromatic powder, to pre- vent griping. Extract of jalap is kept in the soft state, or of a pilular consistence, and in a hard state fit for pow- dering- The latter is termed Hard Extract of Jalap, or Extractum Jalapas durum. The substance commonly sold as extract of jalap in the shops, is prepared by boiling jalap root for 3 or 4 hours in water, when it is taken out, and well bruised or sliced, and again boiled with water until exhausted of soluble matter. The mixed de- coctions are then allowed 12 or 14 hours for defe- cation, after which the supernatant portion is de- canted and evaporated. EXTRACT OF JALAP. Syn. Ext. Jalapa! Alkalinum. Prep. (P. E. 1744.) Add 1 oz. of subcarbonate of potash to the water used for ma- king the extract of jalap, P. L. EXTRACT OF JUNIPER. Syn. Ext. Ju- niperi. Prep. (P. Cod.) Macerate juniper ber- ries in warm water (about 85° F.) for 24 hours, strain, repeat the process with a fresh quantity of water : mix the liquors, filter, and evaporate. EXTRACT OF LETTUCE. Syn. Succus spissatus Lactucas Sativas. Ext. Lactucas, (P. L.) Extrait de Laitue, (Fr.) Pttfip. (P. L.) From the expressed juice of the common garden lettuce, like Extract ok Aconite, P. L. Remarks. This extract is anodyne, antispas- modic, sopon ic, and sedative. Dose. 3 to 5 grs., or more, gra lually increased, in cases where the EXT 295 EXT ise of opium is objectionable. 1 cwt. of lettuce yields 4 to 5 lbs. of extract. (Brande.) " The proper juice, collected by incisions into the flower- ing stem when the plant is in flower, is preferable to this extract. A good plant of garden lettuce will yield 3ss of dried juice *. of lactuca virosa will yield 3j." (Thomson.) See Lactucariu.vi. EXTRACT OF LILY OF THE VALLEY. Syn. Ext. of May-lily. Ext. Convallarias. Prep. From the flowers or roots, like extract of dan- delion. Aperient and laxative. Dose. 15 grs. to 3j. EXTRACT OF LIQUORICE. Syn. Ext. Glycyrrhizas. (P. L. E. & D.) Ext. Glycyr- rhizas molle. Prep. (P. L.) From liquorice root, sliced, as extract of dandelion. Remarks. The Edinburgh College directs this extract to be prepared 'ike'its extract of gentian, by percolation with disulled water, and the Dublin College according to the general rule for simple extracts. It is, however, seldom prepared by the English druggists, being principally imported in the dry state, and only softened down in England. The extract prepared from the fresh root is usually preferred to the best foreign, as the latter has a less sweet and agreeable taste. Foreign extract of liquorice is commonly called Spanish or Italian Juice, being chiefly imported from those countries, that from Solazzi being most esteemed. It is also termed Black Sugar, Liquorice Juice, Succus Glycyrrhizas simplex, &.c. A great deal of the foreign extract is mixed with fa?cula, or the pulp of plums ; hence its inferior quality. Refined juice is prepared by dissolving the foreign juice in water, filtering and evaporating. Pontefracl cakes, or lozenges, are made of re- fined juice, to which some sugar is added. By the following process an extract of superior quality may be prepared from the imported juice :—A layer of straw is placed in the vessel about half a line above the cock ; it is then filled with rolls of liquorice, and water poured over them. After 48 hours this is drawn off, fresh water added, and again drawn off after 24 hours, and this is repeated until the water passes through nearly colorless. On the whole, about 1£ time the weight of the liquor- ice juice in water is consumed. The residue, when stirred with water, imparts to it but a very faint color. (Mohlenbrock. Buch. Rept. xxviii, 198.) Soft extract of liquorice is often employed as a pill basis, and the hard extract is used as a lozenge to allay tickling cough. The mass of the latter is, however, consumed by the porter brewers. EXTRACT OF LOGWOOD. Syn. Ext. Ligni Campechensis, (P. L. 1745.) Ext. ILema- toxyli, (P. L. and E.) Ext. Scobis Hasmato*yli Campechiani, (P. D.) Campecheholze-extrakt, (Ger.) Prep. The College orders this extract to be prepared from the chips, in the same way as the extracts of dandelion, gentian, and liquorice. On the large scale it is prepared by decoction. 1 cwt. of wood yields about 20 lbs. of extract, (Brande ;) 80 lbs. yield 14 lbs. of extract, (Gray.) It is kept in two states, hard and soft The Dose of the first is 10 to 20 grs. dissolved in wine, or any cordial water, after each motion in diarrhoea ; the second may be employed as a lozenge in the same disease. EXTRACT OF LUPULINE. Syn. Ext. Lupulini. Estrait de Lupuline, (Fr.) Prep. From lupuline by infusion in cold water. EXTRACT DE LUPULINE avecleDecoc tion. Syn. Ext. Lupulini Coctione Paratum Prep. By boiling with water and evaporating Both this and the preceding are similar to extract of hops, but stronger. EXTRACT OF MAHOGANY. Prepared by decoction from the chips or sawdust. It is astrin- gent, and is frequently sold for kino. It is also employed in tanning. EXTRACT OF MALE FERN. (ETHE- REAL.) Syn. Ext. Filicis /Ethereum. Bal- samum Filicis. Oleum Filicis Pesciueri. Prep. (Peschier.) From the rhizomes, or buds of the male shield fern, (Aspidiutn filix mas, P. L.) EXTRACT OF MALE FERN. (Alcoholic) Syn. Ext. Filicis Alcoholice. Prep. As last, but using alcohol. Remarks. Both the above are given for tape- worm, in doses of 3ss to 3j, made into an electuary with powdered sugar, followed in 1 or 2 hours by a strong dose of castor oil. Madame Nouffer's cele- brated Swiss remedy for tapeworm, for which Louis XVI. gave 18,000 francs, consisted of 2 of 3 drachms of powdered male fern, taken in \ pint of water in the morning, fasting, followed in 2 hours by a bolus made of calomel and scammony, of each 10 grs.; gamboge 6 or 7 grs. (Pereira.) Heaven help the man who swallowed the whole of this bolus ; for it would certainly assist him to the grave! EXTRACT OF MILLEFOIL. Syn. Ext. Achilleas Millefolii. From the achillea mille- folium. As Extract of Dandelion. Astringent and tonic. EXTRACT OF MIMOSA BARK. Imported from New Holland. Said to be much superior to oak bark for tanning. EXTRACT OF MYRRH. Syn. Ext. Myrrhas. Prep. (P. Cod.) As extract of squills. EXTRACT OF MYRRH. (AQUEOUS.) Syn. Ext. Myrrhas Aquosum. Prep. Digest coarsely-powdered myrrh in warm water, filter and evaporate. EXTRACT OF NOSEGAY. Syn. Extrait de Bouquet. Prep. Flowers of benzoin 1 drachm; essence of ambergris 2 oz.; spirit of jasmine and extract of violets, of each 1 pint; spirits of cassia, roses, orange, and gillyflower, of each £ pint; mix. A most delightful perfume. EXTRACT OF NUX VOMICA. (ALCO- HOLIC.) Syn. Ext. Nucis Vomicas, (P. E. and D.) Prep. I. (P. D.) Nux vomica, rasped, 5V'U j proof spirit 3£ pints ; make a tincture, express the liquid, filter, distil off most of the spirit, and evap- orate. II. (P. E.) By percolation, or boiling with rec- tified spirit. III. (P. Cod.) As extract of squills. Remarks. This extract consists of impure igas- urate of strychnia, and is exhibited in similar cases to that alkaloid. Dose, i gr. gradually increased to 2 or 3 grs. It is very poisonous. EXTRACT OF OAK BARK. Syn. Ext. Quercus. Ext. Corticis Quercus, (P. D.) Es- tratto DELLA QUERCIA, (It'll.) ExTRAIT D - Ecorce de Cheyne, (Fr.) Prep. By evaporating an aqueous decoction. Astringent. Dose. 3ss to 3ij. Seldom used. EXTRACT OF OPIUM. Syn. Ext Opii, EXT 296 EXT (P. E.) Ext. Opii Aquosum, (P. D.) Opium Colatum. Ext. Thebaicum, (P. L. 1720-1715.) Opium purificatum, (P. L. 1788.) Ext. Opii, (P. L. 1809-1*^24.) Ext.'Opii purificatum, (P. L. 1836.) Extrait d'Opium, (Fr.) Opiums-ex- trakt, (Ger.) Estratto d'Oppio, (Ital.) Prep. (P. L.) Opium, sliced, ^xx ; water (temperate) 1 gallon; macerate in a little of the water for 12 hours, triturate with the rest added gradually, un- til perfectly mixed, allow it to repose to deposite impurities, decant, strain, and evaporate. Remarks. The Edinburgh formula is similar, but the Dublin College orders boiling water, and the exposure of the infusion for two days to the air before evaporation. Good opium yields from 60 to 70° of its weight of extract, but much depends upon the variety of opium- Dose, i gr. to 3 grs., as an anodyne, sedative, and hypnotic. It is less stimulant than ordinary opium. It is kept both in the hard and soft state. A solution of the former, in distilled water, with the addition of a little spirit to keep it, forms Battley's liquor opii sedativus. EXTRACT OF OPIUM, EXHAUSTED OF NARCOTINE. Syn. Extractum Opii absque Narcotina. Prep. (P. Cod.) Reduce the last extract with hot water to the consistence of a sirup, cool, and agitate with repeated portions of ether, then evaporate to a proper consistence. Remarks. The above form was first proposed by M. Robiquet, in lb21. It is said that the ex- tract so prepared consists entirely of impure meco- niate of morphia, gum, and extractive. It is less exciting than the last. EXTRACT OF OX-GALL. Syn. Ext. Fel- lis Bovini. Prep. (P. Cod.) Strain fresh or-gall, and e\ aporat** i a water-bath. EXTRACT OF f AREIRA. Syn. Ext. Pa- reiras, (P. L. and E.) Ext. Pareiras Bravas. Prep. As Extract of Dandelion, from the root. Dose. 10 to 30 grs. In vesical catarrh, and ob- structions of the urinary organs. EXTRACT OF PEACH BLOSSOMS. Prep. Essence of lemon 1 oz. ; pure balsam of Peru and essence of bitter almonds, of each 1 dr.; bitter al- monds 1A lb.; rectified spirit of wine 3 pints; spirits of orange flowers 1 pint; spirit of jasmine \ pint; macerate. Very odorous. EXTRACT OF PEPPER. Syn. Ext. Piperis nigri. Prep. From bruised black pepper by decoc- tion and evaporation. Stimulant. Stronger tasted than pepper. Sometimes given in ague. EXTRACT OF POPPIES. Syn. Ext. of White Poppies. Ext. Papaveris, (P. L. and E.) Ext Papaveris albi. Ext. Capitum Papaveris Sommferi. Extrait de Pavot, (Fr.) Prep. From the bruised ripe capsules of the papaversom- niferum, (white poppy heads,) without the seeds, as Extract of Dandelion. Remarks. The medicinal action of this extract resembles opium, but in a considerably weaker de- gree. It is less prone to produce headache and de- lirium. Dose. 2 grs. to 9j. It is usually prepared by the large manufacturers, by exhausting the capsules, by coction with water; hence the infe- rior quality of the extract of the shops. EXTRACT OF PYROLA. Syn. Ext. Py- rolas Umbellatas. Prep. From the leaves, as Extract of Dandelion. It is strongly diuretic. EXTRACT OF QUASSIA. Syn. Ext. Quassias, (P. E.) Ext. Quassia*. Lic.ni. Prep From the wood, (chips,) as Extract of Dandelion. Remarks. This extract is usually prepared by decoction, and is principally consumed by the brewers, who employ it as a substitute for hops The wood yields about 5 or (>g of it' weight of ex- tract. The bark is frequently substituted for the wood, but is considerably less bitter. Dose. 5 to 15 grs. EXTRACT OF QUINCE SEEDS Syn Ext. Cydonias. Ext. Cydonias Seminum. Prep As Extract of Dandelion. EXTRACT OF RHATANY. Syn. Ext. Rhatanias. Ext. Kramerias, (P. E. and D.) Prep. From rhatany root, like Extract of Dande- lion. Remarks. This extract is astringent and tonic. Dose. 10 grs. to 9ij. A large quantity of this ex- tract, of very inferioi .-/uality, is imported from Brazil, &c. It is kept in two states, hard and soft: the former resembles kino, and is often sold for it; the latter is chiefly consumed by the manu- facturers and improvers of port wine. The Edin- burgh College evaporates a cold infusion, obtained by percolation. EXTRACT OF RHUBARB. Syn. Ext. Rhasi. Extrait de Rhubarbe, (Fr.) Rhabar- ber-extrakt, (Ger.) Prep. (P. L.) Rhubarb (bruised or sliced) §xv; proof spirit 1 pint; water 7 pints; macerate for 4 days, with a gentle heat, strain, and evaporate. The Dublin form is simi- lar, but the Edinburgh omits the spirit. Remarks. This extract is usually prepared by decoction from inferior and damaged rhubarb, picked out from the chest on purpose; hence the inferior quality of the extract of the shops. When made of good Turkey, or even East India rhu- barb, it is a very valuable preparation. It should be evaporated as rapidly as possible, at a low heat in vacuo, or by means of a current of dry air. Dose. As a stomachic 5 to 10 grs.; as a purgative 10 grs. to 3ss. It is seldom exhibited alone. By the London process, good rhubarb yields about half its weight of extract. EXTRACT OF RHUBARB, (COMPOUND.) Syn. Ext. Rhasi compositum. Prep. (Prus. Ph.) Extract of rhubarb 3iij ; extract of aloes, and soap of jalap, of each 3j ; mix. EXTRACT OF RUE. Syn. Ext. Rut*. Ext. Foliorum Rutas, (P. D.) Ext. Foliorum Rutas Graveolentis. Prep. From rue leaves, like Extract of Dandelion. It is stomachic, car minative, and emmenagogue. Dose. 10 to 20 grs twice a day. It is usual to add a little of the es- sential oil to the extract, just before taking it out of the evaporating-pan, and when nearly cold. EXTRACT OF SABADILLA, (ALCO- HOLIC.) Syn. Ext. of Cebadilla. Ext. Sab- adillas Alcoholicum. Prep. Evaporate a satu- rated tincture of the seeds. Dose. ^ of a grain in rheumatism, neuralgia, &,c. Poisonous. EXTRACT OF SAFFRON. Syn. Ext. Croci. Polychroite. Prep. Infuse hay-saffron in hot water, strain, and repeat the process until it ceases to give color. Used principally as a col- oring and flavoring substance by cooks, confec- tioners, wine and cordial brewers, &,c. EXTRACT OF SAMBUCUS NIGRA Syn. Elder Rob. Ext. Sambuci. Prep. I. (P EXT 297 EXT L. 1788.) The expressed and depurated juice of wider berries, evaporated to the consistence of tone v. II." (P. E. 1744.) Add to the above £ of su- gar. EXTRACT OF SARSAPARILLA. Syn. Ext. Sarsaparillas, (P. D. & P. L. 1809 & 1824.) Ext. Sarzas, (P. L. 1836.) Extrait de Salse- pareille, (Fr.) Prep. (P. L.) From sarsaparilla root, sliced, as Extract of Dandelion. The direc- tions of the Dublin Ph. are the same as for the other simple extracts. For the method of man- aging this process on the large scale, see Decoc- tion of Sarsaparilla. Dose. 10 grs. to 3j, in pill, or dissolved in water, or decoction of sarsa- parilla. EXTRACT OF SARSAPARILLA, (FLU- ID.) Syn. Ext. Sarzas fluidum, (P. E.) Ext. Sarsaparillas fluidum, (P. D.) Prep. Sarsapa- rilla root lb. j ; water 9 or 10 pints. Boil for 1 hour, express the liquor, and repeat the process with fresh water; mix the decoctions, and after defecation, strain, and evaporate to the consistence af a thin sirup, (P. E.; " to gxxx" P. D.,) and When cold add enough spirit to make f §xvj, (P. E.; " §ij of rectified spirit" P. D.) See Sarsa- parilla. EXTRACT OF SARSAPARILLA, (COM- POUND.) Syn. Ext. Sarzas comp. Ext. Sar- saparillas comp. There is no form for this preparation in the Pharmacopoeias, but it is nev- ertheless in immense demand in the wholesale trade, from its great convenience in dispensing. 3vj, dissolved in a pint of water, form a similar preparation to the Compound Decoction of Sarsa- parilla of the London College. The dose, in sub- stance, is the same as that of the simple extract. The following formula? are employed by one of the wholesale houses that does largest in this prepara- tion. I. Guaiacum shavings, from which the small has been sifted, 30 lbs.; Italian juice 24 lbs.; me- zereon root 6 lbs. Boil with water for 1 hour, strain, and repeat the process with fresh water a second and a third time; mix the decoctions, and allow them to deposite for 12 or 15 hours, then de- cant the clear, strain through flannel, evaporate, and when the consistence of treacle is reached, add extract of sarsaparilla 9 lbs.; continue the evaporation, and just before removing the extract from the pan, and when nearly cold, add essential oil of sassafras 2 drs., dissolved in rectified spirit 1 quart. Prod. About 45 lbs., depending on the quality of the juice employed. This produces a very showy article if well managed. It is labelled Ext. Sarzas comp. The product of the following formula is labelled and sent out as Ext. Sarzas comp. Opt. II. As the last, but only using 15 lbs. of juice, and that Solazzi. Prod. About 35 lbs. Remarks. Each of the above extracts of sarsa- parilla, (simple, fluid, and compound,) when of good quality, dissolves in water, forming a deep reddish-brown solution, perfectly transparent, and depositing but little sediment, even by standing seme days. See Sarsaparilla. EXTRACT OF SAVINE. Syn. Ext. Sa- binas. Ext. Foliorum Sabinaj. Prep. (P. L. 1788.) From the plant, as Extract of Dandelion. 38 Sometimes prepared in small quantities, but it il very seldom asked for. It is usual to add a little essential oil of savine in " finishing it off," to give it an odor of the recent herb. EXTRACT OF SCAMMONY. Syn. Resik of Scammony. Ext. Scammonii. Ext. Sive Re- sina Scammonii, (P. E.) Prep. Boil finely-pow- dered scammony, in successive portions of proof spirit, till all the soluble matter is dissolved, filter, and distil the liquid until little but water passes over ; then pour off the remaining water from the resin at the bottom of the vessel, and wash it with successive portions of boiling water ; lastly, dry at a temperature under 240° F. (P. E.) Remarks. As thus prepared it is translucent, brownish, fusible, and combustible ; soluble in al- cohol, ether, and oil of turpentine. It may be rendered white by means of animal charcoal. It is a drastic purgative. Dose. 8 to 12 grs. " When pure or virgin scammony can be procured, it is an unnecessary preparation." (Pereira.) EXTRACT OF SENNA. Syn. Ext. Sen- nas. Ext. Foliorum Cassias Sennas. Prep. (P. Cod.) By percolation with temperate water, as Extract of Rhatany, P. E. It is principally used as a basis for purgative pills. When prepared by decoction it is nearly inert. EXTRACT OF SMOKE, (AQUEOUS.) Syn. Ext. Fuliginis. Ext. Fuliginis Aquosum. Prep. Wood-soot ^ij ; water 1 pint Boil to f ^xvj, filter, and evaporate. EXTRACT OF SMOKE, (ACETIC.) Syn. Ext. Fuliginis Aceticum. Prep. Wood-soot §ij; water and distilled vinegar, of each, *• pint As last. EXTRACT OF SPRUCE. See Essence of Spruce. EXTRACT OF SQUILLS. Syn. Ext. Scil- la:. Prep. (P. Cod.) Squill root, dried, lb.j ; proof spirit lb. iv. Digest for some days, express the spi- rit, add proof spirit lb. ij, again macerate, mix the two tinctures, filter, distil off the spirit, and evap- orate to an extract. EXTRACT OF STRAMONIUM. Syn. Ext. of Thornapple. Ext. Stramonii, (P., L. E. &. D.) Prep. (P. L.) Stramonium seeds §xv; boiling distilled water 1 gallon. Macerate for 4 hours in a lightly-covered vessel, then take out the seeds, bruise them in a stone mortar, return them to the liquor and boil to one half, strain while hot, and evaporate. The Dublin form is similar. Prod. About 12°j. (Barker.) II. (P. E.) Rub stramonium seeds (ground in a coffee-mill) to a thick mass with proof spirit, put the pulp into a percolator, and exhaust it of solu- ble matter by transmitting proof spirit through it; filter the tincture thus obtained, and evaporate. The Paris form is similar. 1 lb. avoirdupois of seeds yields about 2\ oz. of this extract. (Recluz.) Remarks. On the large scale, this extract is prepared by expressing the juice of the fresh herb, boiling the remainder in water, mixing the juice and decoction, filtering and evaporating. 1$ cwt. of stramonium yielded 37 lbs. of juice, and this, with the decoction, gave 31 lbs. of extract. (Gray.) Stramonium has been used in neuralgia, mania, epilepsy, &c. Dose. Of the extract \ gr., cautiously and gradually increased to 2 or 3 gra It is inferior to the tincture. EXT 298 FAR EXTRACT OF STYRAX. Syn. Ext. of Storax. Ext. Styracis, (P. E.) Prep. Boil powdered storax in successive portions of rectified spirit till exhausted, filter the mixed tinctures, dis- til off the greater part of the spirit, and evaporate the remainder to the consistence of a thin extract. (P.E.) EXTRACT OF TANZY. Syn. Ext. Tana- ceti. Prep. From the herb, as Extract of Dan- delion. It is said to be tonic, stomachic, anthel- mintic, emmenagogue, and febrifuge. Dr. Clark says that in Scotland it was found to be service- able in various cases of gout. The infusion is preferable. EXTRACT OF TEA. Syn. Ext. Theas. Prep. Evaporate an infusion of any of the rough- er kinds of black tea. Astringent Has been recommended in diarrhoea, formed into pills. A hard black-looking substance, smelling and tasting faintly of tea, is imported under the same name from China. EXTRACT OF VALERIAN. Syn. Ext. Valeriana;. Prep. From valerian root, as Ex- tract of Dandelion, but in a covered vessel. It is usual to add to this extract a little of the essential oil of valerian, dissolved in a small quantity of rectified spirit, just before removing it from the evaporating pan, and when nearly cold. Dose. 10 grs. to £ dr. Antispasmodic. Valerian yields about 40°; of soft extract. EXTRACT OF WALNUTS. Syn. Ext. Juglandis immaturi. Rob diacaryon sine Mel- LE. Prep. Evaporate the expressed juice of un- ripe walnuts to a soft extract. Vermifuge. Ta- ken in cinnamon water. EXTRACT OF WHITE BRYONY. Syn. Ext. Radicis Bryonias albas. Prep. From the bruised root, as Extract of Dandelion. Dose. 3j to 3j, as a purgative, diuretic, and emmenagogue. Once a common remedy in asthma, dropsy, epi- lepsy, &.C. EXTRACT OF WHITE HELLEBORE. Syn. Ext. Hellebori albi. Prep. As Extract of Dandelion; from the root. Emetic and pur- gative. EXTRACT OF WHORTLEBERRY. Syn. Ext. of Bear's Whortleberry. Ext. of Bear- berry. Ext. Uvas Ursi, (P. L.) From the leaves, as Extract of Dandelion. Dose. 5 to 15 grs., twice or thrice a day, in ch-Miic diseases of the bladder and kidneys, attended with increased se- cretion of mucus, without inflammation. EXTRACT OF WILD LETTUCE. Syn. Ext. Lactucas Virosas. Succus spissatus Lac- tucas Virosas. Prep. From strong-scented wild lettuce, as the last. It is laxative and diuretic. Dose. 3 to 15 grs., in dropsies. EXTRACT OF WORMWOOD. Syn. Ext. Absinthu. Ext. Cacuminum Absinthii. Ext. Artemisia* Abbi-stiiii, (P. D.) Extrait d'Ab- sinthe, (Fr.l Estratto Assenso, (Ital.) Wer- huth-extraxt, (Ger.) Prep. As the other simple extracts of the Dublin Pharmacopoeia. (See page 2b8.) Bitter and stomachic. Dose. 10 grs. to 3j, 2 or 3 times daily. It is usual to add a few drops of oil of wormwood to the extract before taking it from the pan. EXTRACTS. (In Perfumery.) These are mostly spirituous solutions of the essential oils, or odorous principles of plants, andof-other {.vfum** They are generally termed Uxtraits by the por- fumers, in imitation of the French, who commonly called their concentrated perfumed spirits by thtt name. See Extract of Nosegay. Iv\t.of Pekch- BLOSSOMS. ESPRITS. ESSENCES. SPIRITS, &,C. FALLTRANCK. (Ger., from fall, a fall, and tranck, drink.) Syn. Vulneraire Suisse. Especes Vulneraire. The Suisse. An infusion, or tea, prepared with a mixture of the herbs alchemilla, creeping bugloss, betony, periwinkle, philosella, golden rod, vervain, artemisia, mint, and veronica, gathered among the Alps. It is believed to be of great efficacy for removing the effects of falls and blows. FARM. (In Agriculture) A portion of land, with suitable buildings, fences, hedges, and other arrangements necessary for its cultivation, and the rearing of live stock, let or leased to the occupier for a valuable consideration termed rent. FARMERY. (In Agriculture.) The build- ings and yards necessary for carrying on the trade or occupation of the farmer. Among the first are the barns, stables, &c.; and among the second the principal are the rick yard, yard for watering live stock, and for poultry, &c. The spot and build- ings constituting the farmery, should be conve- niently and centrally situated, for the purpose of abridging, as much as possible, the labor of cart- age to and from the more remote portions of the farm. FARMING. (In Agriculture.) The busi- ness of the farmer. The cultivation of lands held on lease, or for a valuable consideration. Under the head Agriculture the reader has been pre- sented with a compendious general outline of tho history, principles, and practice of cultivating the soil, and rearing live stock, which constitute the operations of farming; the present article will therefore be confined to a short notice of some of the details. Our remarks may be conveniently distributed under the divisions of—Implements— Preparation of Lands—Fertilization of the Soil—Cultivation of Vegetables—Rearing of Animals—and the Rotation of Crops. I. On the perfection of agricultural implements and machines depends much of the improvement of which this art is susceptible. Among the prin- cipal of these are the carr, wagon, and wheel- barrow, employed for the purposes of transportation; the axe and saw, employed for felling and cutting trees; the shears for clipping hedges; the plough for turning up the ground, as an economical and expeditious substitute for the spade ; the harrow for pulverizing the soil and smoothing its surface : the hoe and spade for planting, weeding, and dig- ging ; the shovel, for removing earth and other loose substances, as in carting, clearing, &c ; the drill, a machine for sowing seed; and the culti- vator, a similar machine employed for weeding, harrowing, &c. Most of the preceding are used in the clearing and tilling of land, and preserving it in a proper state ; the following are principally used in the immediate collection of the produce oi harvest, and its preparation for the marke\ The scythe and rake are employed in hay-mak—-**. the sickle and cradle in harvesting corn ; the '.«•-' for thrashing, anc ihe fan for winnowing graii ' ^»e FAR 299 FAR horse-rake and mowing, reaping, winnowing, and thrashing machines, are mostly worked by horse- power, and are intended as substitutes for manual labor. II. The preparation of the land for tillage consists principally in clearing it of superfluous trees; in fencing and hedging it into convenient portions, or, when this has already been done, in keeping the fences and hedges ill a state of repair; in draining it of water when too wet; and in irri- gating it when too dry, and water is accessible for that purpose. Clearing forms the first and one of the most important operations of the farmer in newly-settled and thickly-wooded countries, but in those that have been long under cultivation is sel- dom required: it is intended to permit the free ac- cess of air and sunlight to the soil. The object of fencing and hedging is either to prevent the en- croachment of the larger animals, or to confine them within given limits ; and boundary fences and hedges are also intended to prevent trespassing, and to preserve the land to the use of the owner or occupier. The object of draining is the removal «f superfluous water, which lessens the fertility of the soil; and of irrigation to supply plants and vegetables with sufficient water to promote their growth. The draining of marshy or wet land is commonly effected by blind drains, or such as are beneath the soil, and filled with loose stones; or box drains, which are covered drains, having a free passage, and surrounded with permeable ma- terials ; or by open drains, or mere troughs or trenches, ploughed or dug along the surface of the ground. On sloping lands, drains should run obliquely.along the sides, that their descent may not be too rapid. III. The fertilization of soils is suggested partly by chemical analysis, practical experience, and geological observations. The soil is the up- permost stratum of the earth's surface, and con- sists principally of pulverulent earthy matter, re- sulting from the decomposition of the under strata, mingled with organic substances chiefly derived from the vegetable kingdom. Gravel, sand, clay, silica, chalk, and oxide of iron, are the principal mineral constituents of soils. The most fertile soils are those which consist of an admixture of clay and sand, with a due proportion of chalk and other mineral ingredients, along with a large supply of decomposed animal and vegetable matter. Such soils are commonly termed " loam." Soils are classified by agriculturists according to their chief ingredients; as loamy, clayey, sandy, chalky, and peaty soils. Of these the first is the best, but the others may be improved by the addi- tion of the mineral constituents of which they are deficient. Sand and lime, or chalk, are the proper additions to clayey soils, and clay, gypsum, or loam, to sandy and gravelly ones. Clayey soils are expensive to bring into a fertile state, but when this is once effected, and they are well manured, they yield immense crops of wheat, oats, beans, clover, most kinds of fruits and flowers of the rosaceous kinds. The most fertile soils in Great Britain and on the Continent, especially for wheat, are calcareous clays. The fertility of the soil is also powerfully promoted by comminution and Jabor, and by the addition of manure. Among the first may be menlioned ploughing, rolling, harrowing, &c., all of which render the soil more porous, and easily permeable to the roots of plants, and more susceptible of the action of the atmo- sphere. Of manures it may be remaiked that their nature varies with the constitution of the soil. Lime and sand are the best manures for clayey soils, gypsum and marl for sandy ones. Besides, every kind of soil requires a proper quantity of vegetable or animal manure, without which it will soon become exhausted and infertile. Among manures'of this class the principal are rotten dung and other organic matter, bone dust, nitrate of soda» and sulphate of ammonia. The first is ap- plicable to all soils, the second is especially valua- ble for wheat, and the third and fourth have been used in various cases with apparent advantage, but require further experiments to establish their pre- cise value. In the application of manures, refer- ence must be always had to the intended crop, as certain plants are found to require nourishment of a different description to what is fitted for others, and will grow feebly or not at all, when this is absent. Wheat, for example, will not produce a full kernel on soils destitute of lime. IV. The cultivation of vegetables consists in sowing or planting the seed in properly prepared ground, and in fostering its growth, and that of the resulting young plants, hy hoeing, weeding, &c.; and finally, in the collection and preservation of the mature plants, seeds, or fruits. The plants mostly cultivated by farmers, are the cereal grasses, or such as produce bread corn, esculent roots, grasses for the food of domestic animals, and flux, hemp, and other plants employed in the arts, or used as food, or in pharmacy. Wheat, rye, bar- ley, and oats, which constitute the most important of the cereals, are cultivated by ploughing, mow- ing, and harrowing the land ; then scattering the seed over the whole surface, and lightly covering it with the soil by harrowing. When ripe it is harvested by cutting with the sickle, tying in bun- dles, drying, and storing in barns or stacks. Among the esculent roots the potato and turnip are the most useful and generally cultivated. The former is cultivated by setting the buds or eyes of the tu- bers, a short distance apart in rows, in holes made by a small stick, or in furrows. The seed of the turnip is commonly set by merely scattering it over the surface of well-tilled ground, and cover- ing it over. In the cultivation of grasses, the sort chosen must be adapted to the nature of the soil and its situation. Grass is harvested by mowing with a scythe, drying by spreading it out so as to expose it to the joint action of the sun and air, and storing it in ricks or barns. In this state it is called " Hay." Flax and hemp are generally sown " broadcast," and without further tillage are left to mature, when the plants are pulled up by the roots, and allowed to undergo a species of rot- ting, previously to being handed over to the man- ufacturer. V. The rearing of live-stock, or domestic ani- mals, is chiefly confined to horses, cattle, sheep, and swine. Among the first, the Arabian may be mentioned as the fleetest, and the Dutch and Scotch as the hardiest and most suited to draught Among cattle, the Dutch, or short-horned, the Lancashire, or long-horned, the Galloway, or hornless, and the Highland breed, may be named FEB 300 ver a8 the most useful. Among horned cattle those should be preferred that produce the most milk, and that fatten well and produce the best beef, and that are suited to the climate and situation of the land. Among sheep the two grand divisions are short-wooled and long-wooled, both of which include numerous other breeds. The Merino breed, introduced into England from Spain in 1787, have the finest wool and are most valued. Sheep are sheared in the spring when the weather is settled and warm. Both sheep and cattle do best and fatten quickest when well sheltered from the weather, provided there be a proper amount of ventilation. Of swine a preference should be given to those breeds which fatten best, and pro- duce the finest flavored pork. The common prac- tice of confining pigs in dirty sties cannot be too much avoided; they should be kept clean, and permitted to take sufficient exercise to promote their health, without allowing them to run at large, as in the latter case they are difficult to fatten. In some farms the rearing of poultry constitutes a most profitable object of attention. The Spanish fowls, commonly called Minorcas, are the largest and hardiest, and are good layers. To promote their power in this respect, they should be supplied with a proper quantity of azotized food, as grain, &c, and should be kept dry and well sheltered from the weather. The management of cows has been already noticed. VI. The rotation or succession of crops is abso- lutely necessary for the successful and economical cultivation of the soil. Crops have been divided by agriculturists into exhausting ctops—restoring crops—and cleaning crops. The most exhaust- ing crops are usually considered to be those of corn, but all those that are allowed to ripen their seed, and which are carried off the ground, are also exhausting, but in different degrees. Even clover, tares, and grass cut green, are considered as ex- hausting, but in a less degree than those that are allowed to ripen. Restoring crops are such as are allowed to decay upon the ground, or are con- sumed upon it by domestic animals. Cleaning crops are such as are grown in drills, and undergo the usual operations of weeding, hoeing, &c.; the majority of these may also be regarded as exhaust- ing crops. An exhausting crop should always be followed by a restoring or a cleaning crop; or where possible, by both combined. Crops should also succeed each other in such a way that the Boil may not be exhausted of any one particular kind of nutriment. This is best effected by so ro- tating the crops that plants which are nearly allied should not succeed each other, as the same or similar kinds of plants cultivated successively on the same soil, soon become sickly. This may, however, be obviated by supplying such plants with a proper quantity of the substances which enter into their composition, by applying it to the Boil in the shape of manure ; but the expense of so doing so greatly exceeds that of the ordinary method of manuring with the proper rotation of crops, as to preclude the introduction of this plan on the large scale. See Agriculture, Cows, Dury, Butter, Cheese, Cream, Manures, &c. FAT, CURRIERS'. Fat or tallow boiled until it is very hard and blackish when cold. FEBRIFUGE. Syn. Fibrifugus. (Lat, from febris, a fever, and fugo, I drive away.) That which possesses the power of mring or alleviating fever. The term is principally upplied to medi- cines used against the ague, as bark, arsenical acid, and their preparation* FEET, the. To preserve the feet in a proper condition, they should be frequently soaked, and well washed in warm or tepid water. The nails of the toes should be pared to prevent their be- coming inconveniently long, and from growing into the flesh. Many persons suffer severely from tender feet. This generally arises from the use of thin cotton or silk stockings, and tight boots or shoes, that are not sufficiently porous to permit of the escape of the perspiration. The best treat- ment is the immediate adoption of worsted stock- ings or socks, and light easy shoes of buckskin, goatskin, or some other equally soft kind of leather. It is highly necessary, for the preservation of health, to preserve the feet dry ; persons who are, there- ' fore, exposed to the wet, or who are frequently passengers through the public streets in bad weather, should regard sound and good boots sad shoes as the most essential portion of their clothing. In fact, in a hygienic point of view, a wet back should be less shunned than wet feet. Many per- sons frequently experience extreme coldness and numbness of the feet; the best remedies for such are exercise and friction. In these cases stockings of flannel or worsted alone should be worn, and should be kept on throughout the night if required. The peculiar and disagreeable odor which is evolved by the feet of some individuals in hot weather, may be removed by the observance of ex- treme cleanliness, and by occasionally soaking the feet in warm water, to which a small quantity of chloride of lime has been added. FERMENTATION. Syn. Fermentation, (Fr.) Gahrung, (Ger.) Fermentatio, (Lat, from fermento, to ferment.) The spontaneous decom- position of the proximate principles of organic sub- stances, under the joint influence of warmth, air, and moisture, and the reunion of their elements forming new compounds. Fermentation, accord- ing to Liebig, is nothing else but the putrefaction of a substance containing no nitrogen; or a meta- morphosis, by which the elements of a complex molecule group themselves so as to form more in- timate and stable compounds. It is excited by the contact of all bodies, the elements of which are in a state of active decomposition or fermentation. " In nitrogenized substances of a very complex constitution, putrefaction or fermentation is spon- taneously established when water is present, and the temperature sufficiently high, and it continues till the original compounds are wholly destroyed. Substances destitute of nitrogen, on the contrary, require, in order to their undergoing this metamor- phosis, the presence of a nitrogenized substance, already in a state of putrefaction, (fermentation.") The substances which promote this change are termed ferments; and among these, the principal are gliadine, gluten, vegetable albumen, and all substances in a state of spontaneous decomposition or fermentation. Yeast, the ferment most com- monly employed for inducing the vinous ferrr enta- tion, is such a substance in an active state of pu- trefaction, and whose atoms are in continual mo- tion. Putrefying animal substances are equally FER 301 FER capable of exciting the same action. It is only in complex organic molecules of a higher order that fermentation or putrefaction takes place. The immediate cause of fermentation in such bodies as are not sufficiently complicated to undergo this change by the mere action of water and caloric, is most rationally presumed to arise from immediate contact with the atoms of these bodies, which are undergoing this change. Thus, the motion, or conflict of the elements of the body in a state of decomposition, as those of yeast, when employed to excite the vinous fermentation, destroys the equilibrium of the atoms of the sugar, and these, grouping themselves according to their special at- tractions, enter into new combinations, and form new compounds. The charcoal (carbon) of the sugar partly unites itself to the oxygen, forming carbonic acid, and partly to the hydrogen, forming alcohol. A similar kind of decomposition and in- terchange of elements takes place in all organic substances during the state of fermentation; the proportions of the t>' tments liberated, and the com- pounds formed by their reunion, varying, of course, according to the precise composition of such sub- stances. Chemists have distinguished fermentation into five kinds, viz.: 1. The saccharine fermentation, by which starch and gum are converted into sugar. 2. The alcoholic or vinous fermentation, by which sugar is converted into alcohol. 3. The viscous or mucilaginous fermentation, which converts sugar into slime or mucilage, instead of alcohol. 4. The acetous fermentation, by which alcohol is convert- ed into vinegar. 5. The putrid fermentation, or putrefaction, which is exhibited in its most marked form in the putrefaction of animal substances. 1. The saccharine fermentation occurs during the germination and kiln-drying of grain in the operations of malting, and in the mashing of malt in brewing, and the sweetening of bread during its exposure to heat in th * oven. The substance which most powerfully excites the sugar fermentation has been discovered by Payen and Persoz to be a pe- culiar principle, to which they have given the name of diastase. It forms about one per cent, of good barley malt, and possesses the singular property of converting starch into gum (dextrine) or sugar, at the temperature of from 149° to 168° Fahr. When in a state of absolute purity, 1 part of diastase will, in a few hours, effect the conversion of 2000 parts of starch into sugar, provided the temperature be not higher than 158° F. During the action of this substance on starch, it is itself decomposed ; and when the sugar fermentation ceases, it has entirely disappeared. It is the presence of diastase in malt, which alone converts the starch of the grain into sugar during the operation of mashing with hot water ; and hence will be seen the neces- sity of employing water of a proper temperature, as on this depend the strength and sweetness of the wort, and consequently its fitness for undergo- ing the vinous fermentation, and for making beer. Vegetable albumen and gluten also possess the property of exciting the saccharine fermentation, bu in a considerably inferior degree to diastase. A decoction of 2 parts of potato starch in 20 of w titer, mixed with I part of wheat gluten, and set aside for b or 9 hours at a temperature of about 150°. wi1' be found ti have become thin, trans- parent, and sweet, and to consist of sugar, gum, and some unchanged starch, and sour gluten which has lost the power of acting on fresh starch A decoction of 1 oz. of starch in 1 lb. of water ex- hibits like phenomena by mere exposure to the air for 6 or 8 weeks in warm weather, provided fresh water be occasionally stirred in to supply the loss occasioned by evaporation. In all these cases, the starch is first transformed into gum before its con- version into sugar ; and if the process be stopped at the proper point, a solution of that substance may be obtained. For this purpose 10 to 25 parts of starch should be mixed with about 400 parts of water u 77D to 86° F., and the temperature raised to 140°, when 100 parts of starch must be added, and the heat increased to 158°, and kept about that point for 20 or 30 minutes, or until the turbid fluid becomes limpid and transparent. The starch is now converted into mucilage, and by rapidly raising the heat to the boiling point, any further change will be prevented. A solution of gum or dextrine will be thus obtained. The sugar formed during the germination of seeds containing starch results from the action of diastase, and disappears as soon as the woody fibre, (lignine,) which has a similar constitution, is de- veloped, forming the skeleton of the young plant. (Liebig.) See Diastase, Dextrine, &c. 2. The alcoholic or vinous fermentation is the peculiar decomposition which sugar in solution un- dergoes, under certain circumstances, and by which carbonic acid is eliminated, and alcohol obtained. The presence of a ferment is essential to excite this fermentation, as a solution of perfectly pure sugar will remain unaltered, even though exposed to a temperature of from 70° to 75° F., which is that most favorable for its production. Bui if a small portion of yeast, or of a similar saccharine solution, whose molecules are in a state of motion, be added, the usual symptoms of fermentation will rapidly occur, and will continue until nearly the whole of the sugar is decomposed, when the liquid will become clear, and will be found to consist of diluted alcohol, while the yeast will have precipi- tated to the bottom of the vessel, and have lost its power of exciting fermentation in fresh sirup. In the juices of sweet fruits, and in those vegeta- ble solutions that spontaneously run into the state of fermentation, the ferment is supplied by nature, and is intimately associated with the saccharine matter. In such cases, the nitrogenous matters present are the first to suffer decomposition or fer- mentation, and this peculiar motion of their atoms is communicated to the sugar, and contiuues till the latter has entirely disappeared from the liquid, or the former are wholly precipitated in the shape of decomposed yeast or ferment. In those vegeta ■ ble solutions which scarcely pass into the state of fermentation, or among whose molecules such changes progress slowly and irregularly, there is a deficiency of nitrogenized matters, or exciters of fermentation, and it becomes necessary to add a ferment. Recently-expressed grape-juice (Must) offers a lively instance of the former class of sub- stances, and infusion of malt (Wort) of the lattei When grapes are squeezed in the air, the limpid juice soon manifests the usual symptoms of fer- mentation, the liquid becomes turbid, carbonic acid gas is evolved, and the nitrogenized principles FER 302 FER which the juice previously contained are decom- posed and precipitated under the form of a ferment, (yeast,) which immediately induces the decompo- sition of the sugar; and this state continues until either the whole of the yeast is precipitated in an insoluble and inert form, or the whole of the sugar is decomposed. In the juice of those grapes that produce the more perfect wines, the relative pro- portions of the exciters of fermentation and the sugar, are so accurately apportioned by nature, that the whole of the former are decomposed, and nearly the whole of the latter converted into alco- hol ; so that the liquid (wine) is left in a state not liable to future change. When an infusion of malt is exposed to the atmosphere at a temperature suitable for fermentation, no such a change takes place in its constitution as that just described. Here the nitrogenized matters (gluten, gliadine, vegetable albumen, &c.) are absent, or at least present in too small quantities to excite the vinous fermentation ; the result is, that this infusion ulti- mately undergoes a mixed species of fermentation or decomposition, with the Droduction of products widely different from tnose that result from the true vinous fermentation ; or, in other words, the liquid becomes spoiled. But if a ferment (yeast) be added to this infusion of malt under the above circumstances, and in the proper proportion to the *^V sugar present, the true vinous fermentation will speedily commence, and the liquid will become converted into beer. This is what actually takes place in the process of brewing ; and'the scientific brewer endeavors to employ a proper quantity of ferment to decompose the whole of the saccharine matter of his wort, but, at- the same time, as equally endeavors to avoid the use of an excess. The. chief product of the vinous fermentation is alcohol, but there are other substances simultane- ously produced, and which remain associated with the fermented liquor. Among the principal of these are oenanthic acid, cenanthic ether, oil of potato spirit, oil of grain, &c.; none of which exist previ- ously to fermentation, and are generally supposed to result from the action of the nitrogenized matters of the solution on the sugar. Under certain cir- cumstances these extraneous products are formed in much larger quantities than under others ; and as these substances injure the value of the alcohol with which they are associated, a knowledge of the peculiar circumstances favorable and unfavor- able to their production, is a desideratum to the brewer and distil' *r. It has been Si., vn, by the researches of MM. Colin and Th<5nard, and more recently by those of Boutron-Chalard, Fremy, and Rousseau, that the peculiar condition of the nitrogenous matter con- stituting the ferment, materially influences the nature of the fermentation. The essential condi- tion ot a ferment, to be able to excite the vinous fermentation, is to be sufficiently acidulous to act on colored papers; and this acidity should arise from the presence of certain vegetable acids and salts, capable of conversion into carbonic acid and carbonates by their spontaneous decomposition. Those acids and salts which are found to pre-exist in fermentable fruits and iiquors, as the tartaric, citric, malic, and lactic acids, and their salts, should be chosen ; and of these the preference should be given to the bitartrafe ot potassa, from its Dresence in the grape. The addition of any of these sub- stances to a saccharine solution renders its fer- mentation both more active and complete. Tin favorable influence of cream of tartar on fermenta- tion was first pointed out by Thenard and Colin; and the addition of a little of this article has o»ei: adopted in practice, with manifest advantage, by the manufacturers of British wine. When the acidity caused by these acids, or their acidulous salts, in a ferment, is considerable, the animal and mineral poisons, the essential oils, and various other substances, cease to modify the fermentation; while, at the same time, the resulting alcohol is obtained in a purer state, as the extraneous pro- ducts which we have just mentioned are either not formed at all, or only in small and unimportant quantities : but the contrary takes place if the fer- ment be rendered neutral by washing with water. When the ferment has partially undergone spon- taneous decomposition, and exercises an alkaline reaction on test paper, it ceases to excite the alco holic fermentation in solutions to-stilphate if iron by another of red prussiate of t oiash. (Fer- ridcyanide of potassium.) Remarks. This is a variety of Prussian blue, of remarkably beautiful color, and may be distin- guished from the ordinary Prussian blue of com- merce by its action on the yellow prussiate of pot- ash. When boiled in a solution of the latter it is decomposed, a portion is dissolved, and a gray res- idue remains. FERRIDCYANIDE OF POTASSIUM. Syn. Red Prussiate of Potash. Hydro-ferrid- CVANATE OF PoTASSA. RED FERROCYANIDE OF PO- TASSIUM. Prep. Pass chlorine gas through a very dilute solution of ferrocyanide of potassium, evapor- ate it when the oxidation is complete, and add to the boiling liquor, when it is near its crystallizing point, a few drops of solution of potash ; the screen substance is then decomposed, and flocks of perox- ide of iron separate. It is very easy to observe the moment at which the object is attained, and care must be taken not to add too much potash, because an excess of it would convert the ferridcyanide of potassium into ferrocyanide. The solution is to be filtered hot to separate the peroxide of iron ; it pos- sesses a deep purplish red color, is to be cooled very slowly, and then fine crystals of the salt are ob- tained. (M. Posselt) FERRID-CYANOGEN. A compound formed by treating ferrocyanide of potassium with chlo- rine. It unites with 3 eq. of hydrogen, forming a tribasic acid, termed hydro-ferrid cyanic acid. FERROCYANIC ACID. Syn. Ferrochyazic Acid. Hydro-ferrocyanic Acid. Prep. I. Dis- solve yellow prussiate of potash in water, and add a solution of hydrosulphuret of baryta, as long as a precipitate falls, filter, wash the powder with cold water, dry, dissolve 100 parts in cold water, add 30 parts of concentrated sulphuric acid, mix well, and after repose decant the clear. (M. Por- rett.) II. Diffuse recently precipitated ferrocyanide of lead or copper through water, decompose it by passing a stream of sulphureted hydrogen through the liquid, and filter. (Berzelius.) III. Agitate with ether a concentrated aqueou? solution of ferrocyanic acid as obtained by t lie de- composition of ferrocyanide of lead by means of sulphuric or hydrosulphuric acid ; the acid separ- ates immediately, and may be obtuined by filtra- tion ; this remarkable separation of the acid from FER 307 FEV the water which holds it in solution, requires but litt.e ether. If the solution is moderately concen- trated, the whole forms a thick mass by agitation, and after some time the ferrocyanic acid suspend- ed in the ether separates from the water saturated with ether, and swims on the surface. The water is to be removed by a pipette ; the thick mass is to be put on a filter and washed repeatedly with a mix- ture of alcohol and ether, containing a considera- ble portion of the latter; it is then to be pressed between the folds of absorbent paper to remove the moisture, and afterwards to be perfectly dried over Bulphuric acid in the air-pump.— Or prepare concentrated solution of ferrocyanide of potassium with boiled water, cool without con- tact with the air, add an excess of hydrochloric acid, also deprived of air, and agitate with ether as before ; dissolve the separated acid in alcohol, to which a little sulphuric acid has been added, filter if not clear, and agitate with ether ; the separated acid is to be dried as before described. (M. Pos- selt) Remarks. The lemon-colored solutions obtained by the first two processes, should be cautiously evaporated over sulphuric arid, in vacuo, when ferrocyanic acid will be obtained under the form of a crystalline mass. By the last method it is procured in the state of a white powder, frequently with a slight blue or yellow tint. This acid is de- composed by heat and moisture, when in contact with the air. With the metallic oxides it forms the compounds termed ferrocyanides, ferrocyanates, hydroferrocyanates, or prussiates. The insolubles, ferrocyanides, may all be formed by the mixture of a soluble salt of the metal with a solution of the prussiate of potash. (See Prussian Blue and Prussiate of Potash.) FERROCYANIDE OF AMMONIUM. Syn. Hydro-ferrocyanate of Ammonia. Ferro- cyanate of do. Prussiate of do. Prep. Digest ferrocyanide of lead in a solution of sesquicarbon- ate of ammonia at a gentle heat, filter, evaporate, and crystallize. FERROCYANIDE OF BARIUM. Prep. Digest pure Prussian blue in powder, in baryta wa- ter. It forms efflorescent prismatic crystals by evaporation. Soluble in 4£ parts of water. FERROCYANIDE OF COPPER. Syn. Prussiate of Copper, &c. Prep. Precipitate a solution of a salt of copper with another of prus- siate of potash ; collect the powder, wash it with water and dry. Has a beautiful reddish brown color. FERROCYANIDE OF IRON is only known in the double ferrocyanides of iron. FERROCYANIDE OF LEAD. Syn. Prus- siate of Lead, &c. Prep. From a soluble salt of lead by the addition of a solution of prussiate of potash. A yellowish white powder. FERROCYANIDE OF MERCURY. Prep. From a salt of mercury, as the last. A white powder, which undergoes decomposition as soon as precipitated. FERROCYANIDE OF ZIXC. A white powder precipitated from a solution of a soluble salt of zinc, by adding ferrocyanic acid, or a solution of prussiate of potash. The latter solution also pre- cipitates white ferrocyanides from solutions of the salts of silver and bismuth, a greenish white one from those of nickel, a green one turning red from the salts of cobalt, and a white one, chang- ing to a peach-color, from the salts of the pro- toxide of manganese.* FEVER. Syn. Fievre, (Fr.) Febris ; Py- rexia, (Lat.; the former from ferveo, I burn, whence the English word ; the latter from *vp,fire.) The name of an extensive and important class of diseases, one of the most general symptoms of which is an increased heat of the body. Fevers have been divided by nosologists into intermittents, (intermittentes,) and continued fevers, (continua?.) The first of these are generally known by the name of agues, and the latter have been divided into synocha, or inflammatory fever; typhus, putrid or low fever; and synochus, or the common continued or mixed fever, which commences with symptoms allied to the former, but terminates with those of typhus. The terms hectic, nervous, bilious, in- flammatory, &c., have also been applied to partic- ular varieties of fever, and names indicative of certain cutaneous appearances connected with them have been given to others ; as scarlet fever, yellow fever, &c, from the color of the skin in those diseases. The usual symptoms of incipient fever are chilli- ness, quick pulse, hot and dry skin, languor, de- pression of spirits, alternate fits of shivering and heat, hurried and uneasy respiration, flying pains in various parts of the body, as the head, back, and loins ; loss of appetite, nausea or vomiting ; dry mouth, furred tongue, costiveness, urine small in quantity, and usually of a deep color, &c When any of these symptoms appear, their pro- gress may often be arrested by the timely exhibi- tion of an emetic, followed by a saline purgative, and diaphoretics ; at the same time promoting the action of these remedies by a low diet and drink- ing copiously of diluents, and carefully avoiding animal food, spirits, fermented liquors, or any thing at all stimulant. Whenever symptoms of fever be- come established, medical advice should be sought and implicitly followed. In visiting or attending persons laboring under fevers, it is advisable to avoid immediate contact with themselves or clothing, or standing near them in such a position as to inhale their breath, or the effluvia evolved (in some cases) by their bodies; and when remaining for some time in the apart- ment, it is preferable to sit or stand near the fire- place, or between the window and door, as in such parts ventilation is most perfect. The greatest purifier of the atmosphere of a room is a good fire, because it occasions a continual current of the im- pure air up the chimney, and a corresponding in- flux of fresh air from without. Chloride of time, or its solution, is also a good purifier of the atmo- sphere of a sick chamber, but should not be used in quantity, as the evolved chlorine might, in that case, impede the respiration of the patient. A small quantity of the powder spread on a flat dish or plate^and placed on the chimney piece, and a like quantity in an opposite part of the room, will con- tinue to evolve sufficient chlorine to disinfect the air of an apartment for a week or longer. The evolution of chlorine is promoted by occasionally renewing the exposed surface, by stirring it with a piece of stick, and after it becomes scentless, by, the addition of a little acid, as. strong vinegar, FIL 308 FIL or spirits of salts or oil of vitriol, largely diluted with water. It is advisable to avoid entering the room of a patient laboring under contagious dis- eases, when the stomach is empty, or the spirits depressed ; and it has been recommended to clear the mouth of the saliva immediately after quitting the chamber. FIBRINE. A peculiar proteine substance, forming the coagulable portion of fresh-drawn blood, and the principal constituent of the mus- cular or fleshy parts of animals. It also occurs in vegetable juices, the gluten of wheat, and in the seeds of the cereals generally. It is eminently nutritious, and capable of yielding in the animal body, albumen, caseine, and the tissues derived from them. (Liebig.) It is a modification of pro- teine, and as **.uch contains in itself the elements of all the softer portions of animals, and is hence capable of supporting life without the addition of any other aliment. This is what no other sub- stances but albumen and caseine (also modifica- tions of proteine) can do. FILICINA. Syn. Filicia. A peculiar sub- stance, possessing alkaline properties, discovered by Batso in the rhizomes of the male shield-fern, (Aspidium filix mas.) FILTER. Syn. Filtrum, (Lat.) Filtre, (Fr.) An instrument for filtering or straining. FILTRATION. Syn. Filtriren, (Ger.) Filtration, (Fr.) Filtratio, (Lat., from fil- trum, a filter.) The separation of liquids from substances mechanically suspended in them, by passing them through the pores of media suffi- ciently fine to retain or keep back the solid mat- ter. Filtration is one of the most common and useful chemico-mechanical operations of the arts, but under some circumstances, requires consider- able address for its successful performance. It is usually resorted to for the purpose of freeing fluids from feculence, dirt, and other foreign matter, and for obtaining them in a clear or transparent state ; but,, in some cases, it has for its object the collec- tion of the suspended substances, as precipitates, &c, and in others both these intentions are com- bined. The word filtration is absolutely synony- mous with straining, but, in the language of the laboratory, the former is usually applied to the operation of rendering liquids transparent, or near- ly so, by passing them through fine media, as fil- tering paper, for instance; the latter to the mere separation of the grosser portion, by running them through coarse media, as flannel, horse-hair cloth, &,c, through which they flow with considerable rapidity. Filtration is distinguished from clarifi- cation, by the former removing the solid matter, or cause of opacity or foulness, by mere mechani- cal means, whereas the latter consists in the clear- ing of a liquid by depuration, or the subsidence of the suspended substances or faeces, arising from their gravity being naturally greater than the fluid with which they are mixed, or being rendered so by the application of heat, or the addition oLsome foreign substance. The apparatus, vessels, or media, employed for filtration, are called filters, and are commonly distinguished from strainers by the superior fine- ness of their pores, as above noticed. Both strainers and filters act on the same prin- ciples ai the common sieve on powders; they all, in like manner, retain or hold back the conrsei matter, but pennit the liquid, or smaller and more attenuated particles to pass through. The term medium has been applied to the substance thiough the pores of which the liquid percolates. The forms of filters, and the substances of which they are composed, are various, and depend upon the nature of the liquids for which they are in- tended. On the small scale, funnels of tin, zinc, copper, Wedgewood ware, earthenware, glass, or porcelain, are commonly employed as the containing vessels. (See en- graving.) The filtering medium may be any substance of a suffi- ciently spongy or porous nature to allow of the free percolation of the liquid, and whose pores are, at the same time, sufficiently fine to ren- der it limpid or transparent. Un- sized paper, flannel, linen, calico, cotton-wool, felt, sand, coarsely-powdered charcoal, porous ston«? or earthenware, and numerous other substances of a similar kind, are employed for this purpose. For many liquids that easily filter, and whose suspended matter is of a coarse and porous na- ture, it is sufficient merely to place a little cotton wool or tow, or a small piece of sponge in the neck of a funnel, as at (a) in the above engra- ving ; but such materials, from the small extent of the filtering surface, soon get choked up. Fil- ters of unsized paper are well suited for all liquids that are not of a corrosive or viscid nature, and are universally employed for filtering small quantities of liquids in the laboratory. A piece of the paper is taken of a size proportionate to the quantity of the substance to be filtered, and is first doubled from corner to corner into a triangle, (see eng.,) which is again doubled into a smaller triangle, and the angular portion of the margin being rounded off with a pair of scissors, constitutes a paper cone, which is placed on a funnel, and nearly filled with the li- quid. A piece of paper so cut, when laid flat upon a table, should be near- ly circular. Another method of form- ing a paper filter, preferred by some persons, is to double the paper once, as above, (see fig. 2,) and then to fold it in a similar way to a fan, observing so to open it and lay it on the funnel, that a suffi- cient interval be left between the two, to permit of the free percolation of the liquid. (See eng.) To promote the same object, a funnel should be deeply ribbed inside, or small rods of wood oi glass, or pieces of straw, or quills, should be placed between it and the paper. The neck of a funnel should also be deeply ribbed or fluted outside, to permit of the free passage of the air, when it is placed in a narrow-mouthed bottle or receive. Without this is the case, the filtration will proceed but slowly, and the filtered liquid will be driven up the outside of the neck of the funnel by the con- fined air, and will be continually hissing and flow- ing over the mouth of the vessel. The breadth of a funnel, to filter well, should be about thre« FIL 309 FIL fourths of its height, reckoning fi om the throat a. When deeper, the paper is liable to be continually ruptured from the pressure of the fluid ; and when shallower, filtration proceeds slowly, and an un- necessarily large surface of the liquid is exposed to evaporation. To lessen this as much as possi- ble, the upper edge of the glass is frequently ground perfectly smooth, and a piece of smooth plate-glass is laid thereon. When paper filters are of large dimensions, or for aqueous fluids that soften the texture of the paper, or for collecting heavy powders, or metallic precipitates, it is usual to support them on linen or calico, to prevent their breaking. This is best done by folding the cloth up with the paper, and cutting the filter out of the two, in the same way as would be done with doubled paper, observing so to place it in the fun- nel that the paper and calico may remain close together, especially towards the bottom. The filtration of small quantities of liquids, as in chemical experiments, may often be conveniently performed by mere- ly placing the paper on the circular top of a recipient, as in the engra- ving ; or on a ring of glass or earth- enware laid on the top of any suit- able vessel. A filter of this kind that will hold one fluid ounce, will filter many ounces of some liquids in an hour. Good filtering paper should contain no soluble matter, and should not give more than ^-i^ to ^^ of its weight of ashes. The soluble matter may be removed by washing it, first, with very dilute muriatic acid, and secondly, with distilled water. For filtering a larger quantity of a liquid than can be conveniently managed with a funnel, and also for substances that are either too viscid or too much loaded with fecu- lence to allow them to pass freely through paper, conical bags made of flannel, felt, twilled cotton cloth or Canton flannel, linen, or calico, and suspended to iron hooks by rings or tapes, are commonly employed. The first two of the above substances are preferable for saccharine, mucilagi- nons, and acidulous liquids; the third for oily ones; and the remainder for tinctures, weak alkaline lyes, and similar solu- tions. These bags have the disadvantage of suck- ing up a considerable quantity of the fluid poured into them, and are therefore objectionable, except for large quantities, or when 'continued in actual use as filters for some time. On the large scale, a number of them are usually worked together, and are generally enclosed in cases to prevent evaporation, and to exclude dirt from the filtered liquor that trickles down their outsides; some of these arrangements will be noticed farther on. A very simple mode of filtering aqueous fluids, which are not injured by exposure to the air, is to draw them off from one vessel to an- other, by means of a number of threads cf loosely twisted cotton or worsted, ar- ranged in the form of a syphon. (See the figure in the margin.) The little cotton rope at once performs the oper- ations of decantation and filtration. This method is often convenient for sucking off the water from small quantities of precipitates. When solid substances, as porous stone or earth. enware, are used as the media for filtration, ves- sels of metal, wood, or stoneware, are employed to contain them and the supernatant liquid. In thesfl cases, the filtering medium is usually arranged as a shelf or diaphragm, and divides the vessel into two compartments ; the upper one being intended to contain the dirty liquid, and the under one tc receive the same when filtered. Such an appara- tus is set in operation by merely filling the upper chamber, and may at any time be readily cleaned out by reversing it, and passing clean water through it in an opposite direction. When pulverulent sub- stances, as sand, coarsely-powdered charcoal, &,c., are employed, a similar arrangement is followed; but in this case, the shelf or diaphragm must con- sist of any convenient substance pierced with nu- merous holes, over which must be placed, first a stratum of coarse pebbles, next some of a finer description, and on this a proper quantity of the sand, charcoal, or other medium. Over the whole should be placed another layer of pebbles, or a board or plate of metal or earthenware, pierced with a number of holes, to allow the liquid to be poured into the filter without disturbing its arrange- ment. Apparatus of this kind of a permanent de- scription, and arranged for filtering large quantities of liquids, are properly denominated "filtering machines." Among the liquids usually submitted to filtration, the following may be mentioned as the principal: water, oils, sirups, tinctures, vegetable juices, infusions, and decoctions. The water of our wells is presented by nature ready filtered to the hand of man, and often ex- hibits a desirable degree of transparency and pu- rity. It acquires this state by percolating through the mineral strata of the earth, which deprive it of the organic matter it derives from the soil and subsoil, but, at the same time, it dissolves a por- tion of the saline and earthy media through which it passes, and hence acquires that peculiar " hard- ness" which is constantly found in spring water. On the large scale, this natural system of filtra- tion has been imitated by some of the commercial companies that supply our cities and towns with water. Extensive beds of sand and gravel have been employed, with variable success, as the filter- ing media, and were it not that filters gradually lose their porosity by the accumulation of the re- tained matter in their pores, such a method would be excellent But the great expense of such fil- ters precludes the possibility of frequently cleaning or renewing them, by which means they can alone be kept in an efficient state. A filter that appears to possess the advantages of being easily and cheaply cleaned when dirty, and which filters wa- ter in the most perfect manner, and with immense rapidity, may be formed by placing a stratum or sponge between two perforated metallic plates, united by a central screw, and arranged u such a manner as to permit of the sponge being com- pressed to any required degree. Water, under gentle pressure, flows with such rapidity through the pores of compressed sponge, that it is said that a few square feet of this substance will perfectly filter several millions of gallons of water per day FIL 310 FIL This method of filtration has been made the sub- ject of a patent, and has been favorably noticed by the legislature. A few barrels or hogsheads of water may be easily filtered daily, by the arrangement repre- sented in the engraving. A, A common water-pipe, or cask. b, A fiiNe bottom, fitting in perfect- ly water-tight. c, A perforated wooden or metallic vessel or box, covered with a bag of felt, or other filtering substance, (not shown in the engraving.) d, A small tube, fitting water-tight into the false bottom, and uniting the interior of the filter with the lower portion of the cask. It is evident that when water is poured into the upper portion B, of a vessel so arranged, it will sink through the filter c, and pipe d, into the lower chamber C, and this filtration will go on as long as the supply continues, and water is drawn from the cock e. By uniting the cock e with a tank or casks, and by keeping the upper portion B al- ways full by means of a ballcock, a considerable quantity of water may be thus filtered. The ad- vantage of this plan is, that the filter c can be always readily got at, and easily cleaned or re- newed. For filtering water on the small scale, or for domestic use, alcarrhazas or porous earthen- ware, filtering-stone, and layers of sand and char- coal, are commonly employed as the filtering me- _______ dium. The filtering power of the first two may be greatly in- creased by adopting the arrange- ment represented in the margin, which consists in making the diaphragm of the shape of a disc, (d,) supporting plates of the same material, the whole forming but one piece. The platylithic water-fil- ters, which are formed of porous stone cut on this plan, present 200 to 300 square inches of filtering surface, and may be purchased at from 9«. to 13s. 6d. each. They are perhaps the best portable fil- ters made ; they impart great brilliancy to the water, and filter rapidly. The portable artificial filters, set up in stone-ware, that are commonly sold in the shops, contain a stratum of sand, or coarsely-powdered charcoal; before, however, hav- ing access to this, the water has to pass through a sponge, to remove tho coarser portion of the im- purities. ■- Oils are filtered, on the | ^ small scale, through cotton- v s wool, or unsized paper, ar- |j g ranged in a funnel; and on s.x the large scale, through long sl bags, made of twilled cotton - | j cloth, (Canton flannel.) These = .2 bags are usually made about = 1 12 or 15 inches in diameter, tag and from 4 to 8 feet long, (see S? engraving,) and are enclosed s 5 in bottomless casings, or bags, (QT% I - of coarse canvass, about 5 or § 6 inches iff diameter, for the pur] ose of condensing a great extent of filtering surface into the smallest possible space. A num.- u ber of these double bags (from 1 to 50 or 60) are connected, with corresponding holes, in the bottom of a block-tin, or tinned-copper cistern, into which the oil to be filtered is poured. The mode in which these bags are fastened to the cistern is of the ut- most importance, as on the joint being close and secure depends the integrity of the apparatus. Three methods of doing this are figured in the engraving, which, with the references, will explain themselves, the same letters referring to .he same parts of each. a, Bottom of cistern. b, Filtering bag. c. Screw of the conical nozzle fitting into the cistern. d, Binding cord connecting the bag and nozzle. e. Binding cord connecting bag and lower nozzle. /, Bayonet-catch, connecting the lower portion of the nozzle fastened to the bag with the upper and fixed part,g. i, The thick hem at the top of the bug, (purposely made large by enclosing a piece of thick cord therein,) resting on the shoulders, k. I, A metallic cylinder, loosely fitting the hole in the cis- tern, and over which the top of the hag is drawn, before being put into its place; when fitted, as in the engraving, it retains the hem i securely in its place above the shoul- der k. The second is the least expensive, and certainly the most convenient method, and when the cylin- der I fits the hole closely, (allowing for the bag,) e as safe, or safer, than an ordinary screw. The bags are surrounded by a wooden scr?en furnished with doors for the purpose of keeping '■& the dust, and the bottom of the apartment is fur- nished with large steam-pipes, by which a proper temperature may be kept up in cold weather. In practice it is more convenient to have a number of small cisterns at work, (say 50 or 100 gallons each,) than one or two larger ones; as any acci- dent that may occur is more easily remedied, and that without stopping the whole operation. When cotton cloth bags are employed without being creased, or enclosed in others of canvass, they should not be longer than about 3 or 4 feet, and not wider than about 5 or 6 inches when filled. When larger they are dangerous. A convenient method of filtering a single cask of oil is to insert the pipe of one of Beart's patent filters into the cork-hole, by which means the whole will be fil- tered as drawn off, without any trouble on the part of the operator. The filter consists of a porous bag stretched over a perforated metallic vessel, nearly the shape and size of the exterior casing, and its edge is tightly screwed be- tween the sides and bottom of the latter, so as to be quite water-tight. The cock communicates with the interior of the perforated plate and filter, and the supply-pipe and the exterior. By this means the interior chamber, which occupies five- sixths of the vessel, rapidly fills with filtered oil, and continues full as long as any liquor remains in FIL 311 FIL the cask. This arrangement is also well adapted to the filtration of wines, beer, cordials, porter, and various other liquors. It is unequalled in sim- plicity The filtration of sirups is now generally effect- ed Oil the large scale by passing them through the " creased bag filter" just described. On the small scale, as by confectioners and druggists, they are usually passed through conical flannel bags. The filtration of thick sirups is, however, attended with some difficulty, and it is therefore a good plan to filter them in a somewhat dilute state, and after- wards to reduce them to a proper consistence by evaporation in clean vessels of tinned copper, by steam heat. Sirups, when filtered in a heated state, run well for a time, but the pores of the bag rapidly get choked, from the thickening of the sirup and partial crystallization of the sugar, occa- sioned by the evaporation of the aqueous portion from the surface of the bag. This may be par- tially prevented by enclosing the bag in a metallic casing. On the whole, clarification is preferable for sirups to filtration, on the small scale. They need only to be well beaten up while cold with a little white of egg, and then heated ; a scum rises which must be removed as soon as it becomes con- sistent, and the skimming continued until the liquid becomes clear. Any floating portions of scum that may have escaped notice are easily re- moved by running the sirup through a coarse flan- nel strainer, while hot. The most extensive ap- plication of the process of filtration in the arts is in the refining of sugars. Tirctures and dilute spirits are usually filtered through bibulous paper placed on a funnel, or through thin and fine cotton bags. In general, tinctures clarify themselves by the subsidence of the suspended matter, when allowed to repose for a few days. Hence it is the bottoms alone that require filtering; the supernatant clear portion need only be run thiough a small hair sieve, a piece of tow or cotton placed in the throat of a funnel, or some other coarse medium, to remove any floating substances, as pieces of straw, &c. Spirits largely loaded with essential oil, as those of '■niseed, &,c, run rapidly through paper or cali- co ^ut usually require the addition of a spoonful or two J magnesia before they will flow quite clear. When possible, tinctures, spirits, and all similar volatile fluids, are better cleared by subsidence or clarification than by filtration, as, in the latter way, a portion is lost by evaporation. Vegetable juices should be allowed to deposite their feculous portion before filtration. The su- pernatant liquid will then be often quite clear, but if not so, may be readily filtered. If the quantity be small, paper supported on a piece of coarse cali- co placed on a funnel is the best medium ; if large, one of the conical bags before described. The bottoms from which the clear portion has been decanted, should be placed on a separate filter, or else added afte*- the whole of the latter has drain- ed through. Vegetable juices are often rendered clear by simply heating them to about 180° or 200° Fahr., by which their albumen is coagulated ; they are also frequently clarified by the addition of a little white of egg and heat, in the same way as ■irups; but many of them (as those of hemlock, henbane, aconite, &c.) are injured by heat, and must consequently be filtered In all cases they should be exposed to the air as little as possible, as they rapidly suffer decomposition. Vegetable infusions and decoctions may be cleared by defecation followed by filtration. The conical bags of flannel before described are usually employed for this purpose. When the liquid is to be evaporated to an extract, they are commonly suspended by a hook over the evaporating pan. A convenient method of straining these fluids is to stretch the square of flannel on a frame or ' horse,' securing it at the corners by pieces of string, (see eng.) Such a frame may be laid across the mouth of a pan, and is more easily fed with fresh liquid than a bag, whose mouth is 30 or 40 inches higher. The same purpose is effected by laying the flannel across the mouth of a coarse hair sieve. The con- centrated infusions and decoctions, being usually weak tinctures, may be filtered in the same way as the latter. (See tinctures, above.) Many vegetable solutions, that from the viscidity of the suspended matter can scarcely be filtered, may be readily clarified with white of egg in the cold, or pass the filter rapidly, if a very small quantity of sulphuric, or other strong arid, be previously add- ed. (See the latter part of the article Brxwing.) Corrosive liquids, as strong acids, are filtered through powdered glass, or silicious sand, sup- ported on pebbles in the throat of a glass funnel, or through asbestos placed in the same manner. Charcoal has also been employed for the same purpose, but is not fit for some • acids. Strong caustic alkaline lyes are also filtered through pow- dered glass or sand. Weak alkaline lyes may be filtered through fine calico, stretched across the mouth of a funnel. Many corrosive liquids, as liquor of potassa, &c, require to be excluded from the air during filtration. The simplest apparatus that can be employed for this purpose is that figured in the margin : a is a globular bottle fitted with the ground stopper d, and hav-» Oil ing a perforated neck/ground to the bottle b ; c is a small tube, wrapped round with as much asbestos, linen, or calico as is required to make it fit the under-neck of the bottle through which it passes. The tube c may also be fixed by placing pebbles and powdered glass or sand round it, as before described. For use, the solu- tion to be filtered is poured into the bottle a nearly as high as the top of the tube c, and the stopper placed in. The liquid then descends into b, and a similar quantity of air passes up the tube into a. The liquor potassa? P. L. may be always obtained fine by depuration and filtering tne sediment of lime through calico fixed across the mouth of a funnel. When precipitates, or the suspended matter, is the object of the filtration, the filter should be of such a nature that the powder may be easily separ- ated from it when dry, and that withdtat much loss. Linen filters are for, this reason preferable for large quantities, and smooth bibulous paper for small ones. The powder should be washed down. FIL 312 FIL the sides of the filter, and collected, by means of a small stream of water, in one spot at the bottom, and, when dry, should be swept off the paper or cloth with a camel-hair brush, and not removed by a knife, as is commonly done, unless it be of a very adherent kind. The first portion of liquid that runs through a filter is commonly foul, and should be pumped back or returned until it runs clear, when it may be caught in a proper receiver. In many cases, the liquid will not readily become transparent by simply passing through the filter ; hence has arisen the use of filtering powders, substances which rap- idly choke up the pores of the media in a suffi- cient degree to make the fluid pass clear. See Powder. These powders should not be in too fine a state of division, nor used in large quantities, as they then wholly choke up the filter, and absorb a large quantity of the liquid. For some liquids, these substances are employed for the purpose of decoloring or whitening them. In such cases, it is preferable, first to pass the fluid through a layer of the substance in coarse powder, from which it will run but slightly contaminated into the filters; or, if the substance be mixed with the whole body of the liquid, to pass it through some coarser me- dium, to remove the cruder portion before allowing it to run into the filter. Granulated animal char- coal is used, according to the first method, to de- color sirups, oils, &c.; and filtering powder by the seco.id, to remove a portion of the color, and to clarify castor oil. The common plan of mixing large quantities of filtering powder with this oil, and throwing the whole into the filter, as adopted by the druggists, is injudicious. When simple filtration is required, it is better to use but little or no powder, and to continue returning the oil that runs through until it filters quite clear. By this plan the same filters may be used for a long period of time, and will continue to work well; but by the usual method, they rapidly decline in power, and soon scarcely deliver their contents at all. It is often of great advantage to render a filter self-acting, or to construct it in such a way that it may feed itself, so that it may continue full and at work withont the constant attention of the oper- ator. On the small scale, this may be readily effected on the principle of the common fountain lamp, (see eng.;) and on the large scale, by placing the ves- sel containing the unfiltered li- quid on a higher level than the filter, and by having the end of the supply-pipe fitted with a ballcock, to keep the liquid in the filter constantly at the same height. The rapidity of filtration depends upon the po- rosity of the filtering medium—the extent of fil- tering surface—the relative viscidity or limpid- ness of the filtering liquid, and the porosity and fineness of the substances it holds in suspension. The most efficient filter is produced, when the first two are so graduated to the latter, that the liquid filters rapidly, and is rendered perfectly transparent. To the preceding causes that influence filtration may be added the pressure or force by which the liquid is impelled through the pores of the filter In the common method of filtration no pressure is exerted beyond that of the weight of the column of the liquid resting on the filtering medium, but in same cases additional pressure is employed. This is done for the purpose of producing more rapid filtration, or for filtering liquids that, from their viscidity, will scarcely pass through the pores of substances sufficiently fine to remove their foul- ness in the ordinary way. One of the easiest means of employing pressure in filtration is to in- crease the height of the column of the filtering liquid. From the peculiar properties of fluids, by which they transmit pressure in all directions, this column need not be of equal diameter throughout, but may be conveniently contracted to the size of a small pipe, as in the accompanying engraving, which represents a small filter on this construction at work, a is the funnel or reservoir of foul liquid; 6 a small pipe conveying the liquid (Z2^< to the filter ; c c a chamber, of which the upper portion d is filled with the descending liquid, and the lower por- tion e with the filtering media; i i are screws by which the bottom plate is fastened on; which plate is re- moved to clean out or renew the fil- ter. For use, the cocks k and / are closed, and the liquid poured into the funnel a; the cock k is next opened, and, in a few minutes after, the cock I, when an uninterrupted flow of filtered liquor will be obtained as long as any fluid remains in the fun- nel a, and the tube 6. The length of the latter determines the degree of pressure. Care must be taken to pass the foul liquid through a hair sieve, or some other strainer, to remove any sub- stance that might choke up the pipe b. Another mode of employing pressure in filtration is the with- drawal of the air from the receiving vessel, as in the vacuum filter, by which a pressure of about 14£ lbs. to the inch becomes exerted on the surface of the liquid by the atmosphere. The vacuum in the receiving vessel may be produced by the air- pump or by steam. > S«S SPECIES or COMBUSTIBLE. > 0.**--3 "o « ~ e* ■S*S-S« mnds o ing Witl poriited pound. „ o.tu a. Poun wh cnn Ot CLi '"-' ~ ,-t C > .2 « 2=8 *-**3 Perfectly dry wood 35*00 6*36 5*96 Ordinary wood . 26*00 4-72 4*47 Wood charcoal . 7300 13-27 11*46 Pit coal .... 60*00 10-90 9*26 Coke .... 65*00 11*81 11*46 Turf .... 3000 5*45 4*60 Turf charcoal 64-00 11-63 14*58 Oil, wax, and tallow 78-00 14*18 1500 Alcohol of the shops 52-60 9-56 11*60 1 he above results can never be obtained in prac- tice, as a large portion of the heat (probably \ to }) passes up the chimney, and is wasted. 1 li. of coal is usually reckoned sufficient to convert 1\ lbs. (9 lbs. Watt.) of boiling water into steam, oi to heat 41$ lbs. of water from 32° to 212°. 1 lb. of fir wood will evaporate 4 lbs. of water, or heat 22 lbs. to 212°. FUEL, ECONOMICAL. Prep. I. Mix coal, charcoal, or sawdust, 1 part; sand, of any kind, 2 parts; marl or clay, 1 part, in quantity as thought proper. Make the mass up wet into balls of a con- venient size ; and when the fire is sufficiently strong, place these balls according to its size a lit- tle above the top bar, and they will produce a heat considerably more intense than common fuel, and ensure a saving of one-half the quantity of coals. A fire thus made up will require no stirring, nor fresh fuel for ten hours. II. In places where coal is scarce and dear, a tolerably good fuel may be made, by mixing the culm or refuse dross of coal with c jcy, and moist- ening the whole with water; masses in the form of bricks or balls may be made, which, when dry, will burn with an intense heat. Where peat pre- vails, that article may be easily charred by burn- ing in a covered pit or stove ; and this charred peat will be found to give a great heat when used in an open fire ; the Dutch make much use of their turf in this manner. Another economical fuel, easily procurable wh_ere then, are woods of Scotch firs, consists of fir cones or tops, which contain a great quantity of solid woody matter, in addition to the resinous, and are excellently adapted for domestic fires. FUEL. (Dominic Frick Albert's Patent.) Materials:—bituminous schist, which is a slate or dark-colored stone, partaking of the nature of both coal and charcoal; aluminous clay—a refuse, or the bottoms of the acetate of alumina, in red- liquor works; ground coal—a refuse from coal- pits, which should be quite free from sulphur; vegetable gelatin, or tar—a refuse from pyroligne- ous acid works, or wood distilleries ; mineral gela- tin or tar—a refuse from coal-tar distillation ; and mineral oil—a refuse from naphtha distillation. In manufacturing fuels from these materials, the patentee proceeds as follows:—5 parts of the vege- table gelatin, and the like quantity of mineral gel- atin, are heated in a pan until they are brought to a proper consistence ; and then 10 parts of schist, ground to a powder; 10 parts of ground coal, and 5 parts of aluminous clay, well dried, and mixed with 4 per cent, of mineral oil, are added to the gelatin. The ingredients are worked into a paste, which is deposited in a hole in the ground, near the pan, and, when cold, forms a cake or flag, without the employment of a press or mould. (Lon- don Journ. & Repert of Arts, April, 1843.) FULIGOKALI. A preparation of soot and potassa, invented by Dr. Polya. Prep. Caustic potassa 20 grammes ; soot 100 grammes ; boil with a little water for 1 hour, di- lute with more water, filter, evaporate to dryness, and put the product into warm, dry bottles. FULIGOKALI, SULPHURETED Prep. Fuligokali 60 grammes; caustic potassa 14 grammes ; sulphur 4 grammes ; heat the last two with a little water, and when combined, add the fuligokali, evaporate to dryness, and preserve it in dry, well-corked bottles. Remarks. M. Gibert has tried fuligokali on hw FUM 326 FUN patients at the hospital Siint-Louis, both internal- ly and externally. He made a pommade of 30 grammes of lead ointir snt, and 1 or 2 grammes of fuligokali, in which he recognised resolutive, de- tersive, and stimulant properties. (Gaz. des Ho- pitaux, June, 1842.) See Anthrakokali. FULMINATING POWDER. Prep. Nitre 3 parts ; carbonate of potash 2 parts; flowers of sulphur 1 part; dry, and reduce them separately to fine powder, then carefully mix them. About 20 or 25 grs., slowly heated on a shovel over the fire, first fuses and becomes brown, and then ex- plodes with a deafening report. FULMINATION. Syn. Fulminatio, (Lat.) Fulmination, (Fr., from fulmen, a thunderbolt.) Detonation. The term is applied in chemistry to the violent explosion of a fulminate. FLUMINIC ACID. A peculiar acid known only ;n a state of combination, composed of 2 eq. or 52 parts of cyanogen, and 2 eq. or 16 parts of oxygen; thus having exactly the same ultimate composition as cyanic acid. Its existence was first pointed out by Gay-Lussac and Liebig. Its salts are the metallic fulminates. (See Gold, Silver, MercurTv, and Zinc) FULMINATE OF COPPER. Prep. Digest fulminate of mercury or silver with metallic cop- per. It forms soluble green crystals, that ex- plode with a green flame. FULTON'S DECORTICATED PEPPER. Black pepper deprived of its husks by mechanical trituration, or bleached with chlorine. FUMARIC ACID. A peculiar arid produced by the action of heat on malic acid. It was dis- covered by Lassaigne. Malic acid is kept heated a little higher than its melting point for some time until it forms a crystalline mass, which is then powdered, and washed with cold water, to remove any undecomposed malic acid. It forms salts with the bases termed fumarates. FUMIGATION. Syn. Fumigation, (Fr.) Suffumigatio ; Fumigatio, (Lat., from fumigo, I smokej 1. The diffusion of gaseous matter or vapors through the atmosphere, for *he purpose of destroying contagion and infection. 2. The ex- posure of solid bodies to such fumes or vapors to remove the miasm of contagion from their pores. 3. The substances employed for fumigation. Chlo- rine is the most powerful and certain agent for the destruction of miasmata, both in the atmo- sphere and the pores of solid bodies, and admits of ready and easy application. The hypochlorites (chlorides of lime, soda, and potassa) are the most convenient forms of employing it in in- habited apartments, as they evolve the gas slowly, and in quantity insufficient to affect the organs of respiration, unless large quantities of them are employed. Chloride of lime is the most com- monly used of the hypochlorites, and is either sprinkled about the floor, or exposed in shallow vessels, as earthen dishes or plates, in various parts of the apartment. It is used both in the state of powder and solution in water. Gaseous chlorine, evolved from a vessel containing the materials for its production, is generally formed too fast to admit of its application to inhabited apartments, but is the most efficient fumigation that can be employed, either for disinfecting the atmosphere, walls, and floors of rooms, or goods and furniture placed in them. It will al»o destioy every species of vermin contained therein. For this purpose, the chimney, door, and windows should be closed up, to prevent the escape of the gas. The vapors of nitric acid and muriatic acid, and the fumes of burning sulphur, are also em- ployed as disinfectants in the same way as chlorine, but are less to be depended on. The smoke of gunpowder, and the fumes of vinegar, camphor, benzoin, A:c., are popular disinfectants, but de- serve little confidence. Of all common diseases, scarlet fever appears to be the one most requiring fumigation. For this purpose, chlorine gas or heat should be employed. The infectious matters of certain diseases, especially scarlet fever, are either dissipated, or destroyed, at a heat about that of boiling water. (Dr. Henry.) Contagious dis- eases are very commonly propagated in the me- tropolis by persons having their linen washed by laundresses who perform their operations in the same sinks of dirt and misery in which they live. (See Chlorine, Disinfectants, Muriatic and Nitric Acids, Pastilles, and the following ar- ticles -1 FUMIGATION, BALSAMIC. Syn. Fumi- gatio Balsamica. Prep. (Dr. Dohrn.) Gum olibanum lb. ij ; gum benzoin and storax, of each lb. ss ; flowers of roses and lavender, of each §vj; mix. Used in hooping-cough. FUMIGATION, CHLORINE. Syn. Disin- fecting Fumigation. Guytonmorveau's do. Fu- migatio Oxymuriatica. Suffumigatio Guyton- iana. Prep. (P. Cod.) Common salt 3 parts; water and oil of vitriol, of each 2 parts; black oxide of manganese 1 part; mix in a shallow vessel, placed in the centre of the apartment This must onlv be used for unoccupied looms. FUMIGATION, NITROUS. Syn. Nitric Fumigation. Nitric Acid do. Fumigatio Ni trosa. Suffumigatio cum Acido Nitrico. Prep (P. Cod.) Put sulphuric acid diluted with ar equal weight of water into a porcelain cup, (any shallow vessel of glass or earthenware will do,) and add to it from time to time small quantities ol powdered nitre. Remarks. Heat causes the gas to be evolved more rapidly, and thus renders the fumes more offensive, without increasing their efficacy, i oz. of nitre is said to be sufficient for a small room. (Dr. Bateman.) The vessel containing the in- gredients should be placed in the centre of the apartment. FUMIGATION, TAR. Syn. Suffumigatio Picea. Prep. (Sir A. Crichton.) Norway tar 1 lb.; powdered carbonate of potash i oz. or 1 oz.: mix, and heat it by a spirit lamp. The potash is added to neutralize the acid. (See Inhalation.) FUNGIC ACID. A peculiar acid obtained by Braconnot from certain fungi—the boletus juglan- dis, boletus pseudoigniarius, phallus impudicns, merulius cantharellus, peziza nigra. It may be prepared by boiling the expressed juice, filtering, evaporating to the consistence of sirup, and di- gesting in alcohol. The residuum must be dis- solved in water, and precipitated with acetate of lead ; and the precipitate, after being washed. must be decomposed with dilute sulphuric arid at a gentle heat; the remaining solution must be filtered and evaporated. It is a sour deliquescent FUS 327 GAL mass, forming salts with the bases, termed fun- gates. The fungate of ammonia crystallizes in prisms. FUNGIN. (From fungus, a mushroom.) The fleshy portion of mushrooms, deprived of soluble matter by digestion in both water and alcohol. FURNISHING. " When you design to furnish a house, take care to set out on a right principle in the selection of articles. It is essential, for the sake of neatness, and for a pleasing effect to the eye, that there should be a harmony of colors, and also a similarity of style in the main articles of furniture. Therefore, if you do not exercise a little taste and judgment in your first selections, you may find that you have committed a blunder which will cost you much subsequent annoyance. For example, let the tints of the carpet, of the paper or paint of the walls, and of the window curtains, be all in harmony in each room, that is, either possess a general resemblance of color, or various colors in pleasing contrast and harmony with each other. If the color of your curtains be scarlet, and the color of your walls or carpet blue, a most inharmonious and unpleasing effect will be produced ; but brown and green, or green and gold, will be in harmony, and may therefore be placed together. Carpets being the most ex- pensive articles, it is safest to buy them first, and then to let their color lead the tone and style of curtains, paper-hangings, chair-covers, hearth- rugs, and all other articles. It is also a good economical plan to buy carpets of the same pat- tern for several rooms, because, in the event of removal to a house with different sized apart- ments, a piece of one carpet may be taken to eke out another." FURNITURE, VARNISHED. This may be finished off so as to look equal to the best French polished wood, in the following manner, which is also suitable to other varnished surfaces.—Take two ounces of tripoli powdered, put it into an earthen pot, with just enough water to cover it; then take a piece of white flannel, lay it ovei a piece of cork or rubber, and proceed to polish the varnish, always wetting it with the tripoli and water. It will be known when the process is finished by wiping a part of the work with a sponge, and observing whether there is a fair even gloss. When this is the case, take a bit of mutton suet and fine flour, and clean the work. FURS may be preserved from moths and in- sects by placing a little colocynth pulp, (bitter apples,) or spices, as cloves, pimento, &c, wrapped in muslin among them ; or they may be washed in a very weak solution of corrosive sublimate in warm water, (10 or 15 grs. to the pint,) and after- wards carefully dried. Furs, as well as every other species of clothing, should be kept in a clean, dry place. FUSIBLE METAL. Prep. I. Bismuth 8 parts ; lead 5 parts ; tin 3 parts ; melt together. Melts below 212° Fahr. II. Bismuth 2 parts ; lead 5 parts ; tin 3 parts. Melts in boiling water. Ill (Onion's.) Lead 3 parts ; tin 2 parts ; bis- muth 5 parts ; mix. Melts at 197° F. Remarks. Tho above are used to make toy- spoons, to surprise children by their melting in hot liquors ; and to form pencils for writing on asses' skin, or paper prepared by rubbing burnt hartshorn into it. FUSION. Syn. Fusion, (Fr.) Fusio, (Lat, from fundo, I pour out.) In Chemistry, the lique- faction of solid bodies by the action of heat. The term aqueous fusion has been applied to the melt- ing of salts in their combined water when heated * and the term igneous fusion to the liquefaction of bodies by heat alone. The vessels in which substances are fused are formed of various materials and shapes, according to the properties of the solid operated on, and prin- cipally with reference to the heat required for its fusion. In every case the containing vessel should be capable of sustaining the proper degree of heat without melting or cracking, and should also be capable of resisting the action of the substances melted in them. Crucibles, made of very refrac- tory clay, are employed for high temperatures, and metallic or earthenware vessels for lower ones. FUSTIC. Syn. Old Fustic. Lignum Mori TiNCTORiiE, (Lat.) Gelbholz, (Ger.) Bois jaune, (Fr.) The wood of the "norus tinctoria. Its decoction dyes woollens yel. ow of different shades, according to the mordant. Alum, tartar, and spirits of tin brighten the tint; acetate and sulphate of iron and common salt darken it; with sulphate of iron it gives olives and browns ; with the indigo vat and sulphate of indigo green. These colors are very permanent. Its yellow turns on the lemon when pale, and orange when darker. 1 lb. of fustic will dye 3 to 5 lbs. of wool. The fustet, or yellow fustic of the dyers, does not give permanent colors. GALL. Syn. Bile. Bilis ; Fel ; (Lat.) Fiel ; Bile ; (Fr.) A bitter fluid secreted by the liver; in part flowing into the intestines, and in part regurgitating into the gall-bladder. Ox Gall (fel bovis) is largely employed in the arts. White Bear Gall (fell ursi) has been occasionally ex- hibited as an anti-epileptic ; Hare's Gall, (fel leporis,) and the Gall of the JSiluris, have been used as collyria in cataract; the Gall of Eels (fel anguillarum) has been given to facilitate labor. The virtues ascribed to the above are chief- ly imaginative. Crude ox-gall is largely employed by the scourers of cloth, &c. GALL, REFINED, (OX-.) Syn. Fel Bovis purificatum. Prep. I. Allow fresh ox-gall to repose for 12 or 15 hours, decant the clear, and evaporate to the consistence of a thick sirup, in a water-bath ; then spread it thinly on a dish, and expose it before the fire, or to a current of dry air, until nearly dry. It will then keep for years in wide"-mouthed bottles or pots, covered over with bladder. For use, a little is dissolved in water. II. Fresh gall 1 pint; boil, skim, add pounded alum 1 oz. ; boil again, until the alum is dissolve*., and when sufficiently cool, pour it into a bottle, and loosely cork it down ; in a similar manner boil and skim another pint of gall, and add to it 1 oz. of common salt, boil till dissolved, and cool and bottle as above. In three months decant the clear from both bottles, and mix them iu equal quanti- ties ; the clear portion must then be separated from the coagulum by subsidence or filtration. Use. It is employed by artists to fix chalk and pencil draw- ings before tinting them, and to remove the greasi GAL 328 GAR ness from ivory, tracing paper, &c. It is also used to extract grease and oil from clothes : for the latter purpose it answers admirably. GALLATES. Salts formed of the gallic acid with the bases. GALLIC ACID. Syn. Acidum Gallicum. (Lat, from galla, galls.) Prep. I. Bruised galls 1 oz.; water 1 lb.; boil to 8 oz. and strain; dis- solve 2 oz. of alum in water, precipitate the alumina with carbonate of potassa, and after edulcoration, mix it with the decoction, frequently agitate with a glass rod, and the next day filter ; then wash the precipitate with water, until the latter ceases to blacken sulphate of iron ; mix the washings with the filtered liquor and evaporate, when gallic acid, in fine needles, will be obtained. II. Expose a filtered decoction of galls in an open vessel; it will grow mouldy, and become covered with a thick glutinous pellicle, and glutin- ous flocks will fall down. In two or three months, the sides of the vessel and the under portion of the pellicle will be covered with small yellow crystals of gallic acid. III. Add a strong aqueous solution of tannic acid (tannin) to sulphuric acid, as long as a pre- cipitate falls ; collect the powder, wash, and dis- solve it by the aid of heat in diluted sulphuric acid ; boil for a few minutes, cool, and collect the crystals of gallic acid which will form in consid- erable quantity. (Liebig.) Remarks. Gallic acid, as obtained by either of the above forms, is never quite pure ; but it may be purified by combining it with oxide .of lead, and decomposing the compound (gallate of lead) by sulphureted hydrogen. The sulphuret of lead acts like animal charcoal in removing the color. (Liebig.) The principal use of pure gallic acid is in the art of photography. Props., 6fC. Brilliant prismatic crystals, of a pale yellow color, soluble in both water and alco- hol. Its aqueous solution decomposes by exposure to the air. It blackens the salts of iron. Dis- solved in hot oil of vitriol, it forms a deep, rich, red solution, which when thrown into water, drops the gallic acid, deprived of some of its water. (C7 H2 O 4, Robiquet) This substance is soluble in the alkalis, and dyes cloth like madder. When strongly heated, gallic acid is converted into meta- gallic acid, pyrogallic acid, <$-c. With the bases, gallic acid forms salts, called gallates:—Super-gallate of Ammonia is made by neutralizing 1 part of gallic acid with ammonia, then adding 1 part of acid more, and crystallizing; Gallate of Lead is obtained by either adding acetate of lead to a warm solution of gallic acid in excess, or by adding the former to the latter at the boiling point. The first is a supergallate, the latter a basic salt. The alkaline gallates, and those of cobalt, iron, manganese, nickle, and zinc, are soluble, the rest insoluble. The following summary of some recent and valuable researches on gallic acid may prove in- teresting to the reader:— " 1. Tannin may be converted into gallic acid under several influences ; first, as M. Pelouze ob- served, under that of oxygen, and under that of a ferment. " 2. Certain chemical bodies prevent, for a cer- tain time, the conversion of tannin into gallic acid. " 3. It is not to the phenomenon of eremacausii that this conversion must be attributed. " 4. The ferment of nutgalls converts sugar into alcohol and carbonic acid, as does that of beer. " 5. Beer, yeast, muscular flesh, and caseous matter, change tannin into gallic acid. " 6. Finally, in the conversion of tannin into gallic acid, the quantity of gas disengaged is scarcely perceptible." (M. Antoiue Larocque, Chem. ii. 195.) GALLS. Syn. Gallnuts. Galla:, (I.at) Gallatff.l, (Ger.) Noix de Galle, (Fr.) The best galls are those imported from Aleppo, known in commerce as black or blue galls, (Galla ni- gra seu coerulea,) and after them Green Galls, (Gallavirides.) Both these are gathered before the insect has escaped, are styptic and powerfully astringent. White Galls (Galla alba) are lighter, less astringent, and inferior. Galls are ex- tensively used in the art of dyeing, as they consti- tute one of the principal ingredients in all the shades of blacks, and are also employed to fix or improve several other colors. A decoction of galls, to which a little green copperas and gum arabic has been added, forms common writing ink. GALLSTONE. Syn. Calculus cysticus bo- vinus. Formed in the gall-bladder of neat cattle in winter, when they are fed upon dry Mod. Used as a yellow pigment, and in medicine. Dose, 1 gr. in dyspepsia and flatulency. GAMBOGE. Syn. Cambogia. Gambogia, (Lat.) Gomme Gutte, (Fr.) Gutti, (Ger.) This drug is a drastic purgative, and in quantity a vio- lent poison. " The deaths which have occurred from the use of enormous quantities of Morrison's pills, are mainly ascribable to the gamboge con- tained in those medicines." (Pereira.) It is hence of much importance, in medico-legal researches, to be able readily to recognise the presence of this drug. This may be done in the way described under the head, Extract of Colocynth, (comp.) GAMBOGIC ACID. Syn. Gambodic Acid. Gamboge Resin. Prep. Digest gamboge in ether and evaporate. An orange or red-colored resin, very soluble in ether and alcohol, giving an ap- preciable yellowness to 10,000 times its weight of the latter. With the caustic alkalis it forms dark red solutions, which are alkaline gambogi- ates, from which the acid is precipitated unchanged by alkalis. Added to a solution of acetate of lead, it throws down a yellow gambogiate of lead, and from solutions of the salts of iron and copper, gam- bogiates of those metals. GARGLE. Syn. Gargarism. Gargarisme, (Fr.) Gargarisma, Gargarismus, Gargarismum, (Lat, from yapyapfyiv, to gargle.) A gargle, or wash for the throat. Gargles are applied by allowing a small mouthful to run as much as possible over the affected parts, by holding the head backwards, and breathing through it, by which means the liquid is agitated and its action promoted. They should not be swallowed. GARGLE, ANTISCORBUTIC. Syn. Gar- garisma Antiscorbuticum. Prep. (P. Cod.) Bit- ter species 3j ; boiling water §viij; macerate 1 hour, strain, and add sirup of honey ^ij J antiscor- butic tincture Jj. GARGLE, ANTISEPTIC. Syn. G. Antisep- GAR 329 GAS ticum. Prep. (Fr. H.) Decoction of bark ^vj; camphor 20 grs.; sal ammoniac 5 to 15 grs.; mix. For putrid sore throat, &c. GARGLE, ASTRINGENT. Syn. G. As- tringens. Prep. I. (Collier.) a. Tincture of galls f 3ij; honey ^ss; water f §vj ; mix. In re- laxation of the uvula and fauces. b. Honey 3iv ; tincture of myrrh 3iij; powder- ed alum 3ij ; injusion of roses (co.) f gvss; mix. Antiseptic and astringent. As last. II. (Dr. A. T. Thomson.) Infusion of roses ^vij; dilute sulphuric acid f 3j; tincture of catechu f3vj; laudanum f 3iss; mix. For relaxation of the uvula. III. (Sir A. Cooper.) Alum 3ij; decoction of bark §xij ; honey of roses §iss; mix. IV. (U. C. H.) To the last add alum 9j GARGLE, COMMON. Syn. G. commune. Prep. I. (E. H.) Water ^vj; nitre 3j ; honey of roses ^j ; mix. For ordinary sore throat II. Instead of nitre use borax 3ij. GARGLE, DETERGENT. Syn. G. Deter- gens. Prep. (Dr. A. T. Thomson.) Nitre 3ij ; honey of roses f 3iv ; infusion of roses f §vss ; mix. In inflammatory sore throat. ' GARGLE, EMOLLIENT. Syn. G. emol- liens. Prep. (Buchan.) Althaea root 1 oz.; figs 2 oz.; water 1 quart; boil to a pint and strain. Demulcent; soothing. GARGLE, MERCURIAL. Syn. G. Hy- drargyri. G. Hydrargyri Bichloride G. Sub- limati Corrosivi. Prep. (P. C.) Corrosive sub- limate 2 grs. ; barley water 1 pint; honey of roses §ij ; mix. For syphilitic ulcers in the throat. GARGLE OF ALUM. Syn. G. Aluminis. Prep. I. (P. C.) Alum 3ij ; infusion of roses jfvj ; honey of roses §j ; mix. II. (Grant) Alum §j ; tincture of myrrh §ss • peppermint water f §vij ; mix. Both the above are astringent, and used in relaxation of the uvula, GARGLE OF BORAX. Syn. G. Boracis. Prep. (Fr. H.) Borax 3ij ; rose water f Jvij; ho- ney §j. In thrush, &c. GARGLE OF CAPSICUM. Syn. G. Cap- sici. Prep. I. (St B. H.) Capsicum 3iij ; com- mon salt §j ; boiling water 1 pint; macerate for 12 hours, strain, and add distilled vinegar 1 pint. II. (U. C. H.) Tincture of capsicum f3j; wa- ter f Jyj; vinegar ffj; mix. Used in ulcerated sore throat and scarlet fever. GARGLE OF CHLORIDE OF SODA. Syn. G. Sod.« Chlorinate. Prep. (Copland.) Liquor of chloride of soda f 3xij; honey ^ss; water f §vj; mix. In putrid sore throat and scarlet fever. GARGLE OF CHLORINE. Syn. G. Chlo- rinii. Prep. (Fr. H.) Chlorine water f ss; sirup ?j ; water f giv to f §yj; mix. Used as the last. GARGLE OF CINCHONA BARK. Syn. G. Cinchona. (For. H.) Decoction of cinchona f gvij ; simple oxymel §j; mix. Antiseptic and astringent. GARGLE OF CYANURET OF MERCU- RY. Syn. G. Hydrargyri Cyanureti. Prep. (Cullerier.) Cyanuret of mercury 10 grs.; linseed tea f 5 xx ; mix. In the same cases as mercurial gargle, above. GARGLE OF HORSERADISH. Syn. G. Armor acie. Prep. (Collier.) Compound spirit 42 of horseradish ffj ; honey gij ; water f§iv ; mix A good gargle for scurvy of the fauces and pha« rynx, vulgarly called the inward scurvy. GARGLE OF MURIATIC ACID. Syn. G Acidi Muriatici. G. Acidi Hydrochlorici. G. Spiritus Salis. Prep. I. (Guy's H.) Muriatic acid 30 drops; honey of roses |ij ; barley water fgvj ; mix. II. (St. B. H.) Red rose leaves 3ij ; boiling wa- ter 1 pint; muriatic acid f 3iss; digest for 1 hour. In inflammatory sore throat GARGLE OF MYRRH Syn. G Myrrhas. Prep. (P. C.) Tincture of myrrh §ss; honey of roses ?;iss ; lime water f ^vj ; mix. GARGLE OF NITRE. Syn. G. Salis Ni- tri. G. Nitri. G. Potasse Nitratis. Prep. Nitre 3ij ; honey or sirup 3iv or 3v ; rose-water f §vj ; mix. In inflammatory sore throat. GARGLE OF OAK BARK. Syn. G. Quer- cus. G. Corticis Quercus. Prep. I. Oak bark 3ij; boiling water f ^vj ; mi cerate 1 hour and strain. II. To the last add alnm 9ss, and oil of vitriol 15 to 30 drops. Both are used in relaxation of the uvula. GARGLE OF PELLITORY OF SPAIN. Syn. G. Pyrethri. Prep. I. (P. C.) Pellitory root 3iv; water §xvj; boil to f§viij, and add liquor of ammonia 3ij. II. (Swediaur.) Infusion of pellitory 1 pint; vinegar §iij ; sal ammoniac ^iij ; mix. GARGLE OF ROSES. Syn. G. Rose. G. Rosarum. Prep. (Kendrick.) Conserve of roses §iij ; boiling water §xvj ; infuse 1 hour; add di- lute sulphuric acid 3ij, and strain. Antiseptic; astringent. GARGLE OF VERDIGRIS. Syn. G. Mkv- ginis. Prep. (Guy's H.) Oxymel of verdigris 3iv; honey of roses §ij ; barley water f §iiiss; mix. Used as a detergent for ulcers in the throat If swallowed it will produce violent vomiting. The addition of 2A, oz. of water to the above, forms a gargle sufficiently strong for most cases. GARGLE OF VINEGAR. Syn. Oxymel Gargle. G. Aceti. G. Acidi acetici. Prep. (St. B. H.) Barley water f §xij ; acetic acid f ^iss ; honey 3vj ; mix. Antiseptic. For ordinary sore throat. GASCOIGNE'S POWDER. Syn. Pulvis Gascoigni. Prep. Powdered crabs' claws 1 lb.; oriental bezoar 1 oz. ; mix. When made into balls it forms Gascoigne's Balls. This powder was once held in great repute as an absorbent, &c.; it is, however, no better than the less costly prepared chalk of modern pharmacy. GARNET. Syn. 'Granat, (Ger.) Grenat, (Fr.) The finest specimens of noble garnet are brought from Pegu, and according to chemical analysis consist of 42g of silica, 20g of alumina, 34}} of lime, and 4% of protoxide of iron. GARNET, FACTITIOUS. Prep. Purest white glass or paste 2 oz.; glass of antimony 1 oz.; powder of cassius and black oxide of manganese, of each 1 gr.; mix and fuse. (See Gems, Fac- titious ; Paste, Enamels, and Foils.) GAS. Syn. Gas ; Gaz, (Fr.) Gaz, (Ger., fom Geist, Teutonic, air or spirit.) Any aeriform or permanently elastic fluid, excepting the compomid of oxygen and nitrogen, constituting atmospheric" GEL 330 GEL air. The principal gases are oxygen, hydrogen, nitrogen, carbonic acid, carbonic oxide, carbureted hydrogen, ammonia, and sulphureted hydrogen. All of these are noticed in their alphabetical order, as well as several others of less importance. (See Index.) GAS, "^AL. Syn. Light Gas. Obtained from coal '-rf u.stillation in iron cylinders or retorts. This g. it in the oven. It should not be kept longer than two or three hours at the ut- most, before being baked. This receipt produce! superior thin gingerbread. II. Flour and treacle, of each 1 lb.; butter 1 oz.; carbonate of magnesia 1 oz. to 1$ oz.; add spices, (ginger, cinnamon, nutmeg, allspice, Cay- enne, corianders, &c, to taste ;) mix as last. Fit for baking in from four to six hours. III. Flour 2 lbs.; carbonate of magnesia J oz.; mix ; treacle 1£ lb.; butter 2 oz.; spice to palate; tartaric acid i oz.; mix as above. Ripe for the oven in half an hour to one hour. IV. Instead of tartaric acid in the last form, use cream of tartar dissolved in water, 2 oz.; mix as last. Ripens in 40 or 50 minutes. V. Flour or fine pollard 1 lb.; treacle J lb.; potash, dissolved in a little water, i oz.; butter 1 oz.; spice to palate; mix as before. Takes sev- eral days to ripen; sometimes a fortnight. VI. To the last, after it has stood 1 or 2 days, add volatile salt, (carbonate of ammonia,) Jissolved in a little water, \ oz. May be baked at once. VII. Flour 6 lbs.; powdered ginger 2 oz. or 3 oz.; caraway seeds 1 oz.; (and other spices to palate ;) candied lemon and orange peels, of each 1 to 2 oz.; moist sugar and melted butter, of each i lb.; treacle 4 lbs.; volatile 6alt, dissolved in a little water, IJ oz. to 2 oz. ; mix as above. May be baked at once. The upper surface of this bread is very dark and glossy. Remarks. The preceding may be either rolled out into thin sheets and cut into cakes or puts (gingerbread nuts) with the top of a wine-glass or canister, or may be formed into thick cakes. They require a pretty brisk oven; the thin varieties j (nuts, &c.) must be baked crisp, without being burnt. The varieties called lemon gingerbread, caraway do., &c, have a perceptible predominance of those flavoring ingredients. The addition of a little alum, dissolved in water, makes the bread both lighter and crisper, as well as ripen quicker. This should not, however, be added until the whole of the other ingredients are made into a dough, when it may be well kneaded into the mass. GINGER CANDY. Prep. Coarsely powder- ed ginger 2 oz.; boiling water l\ pints; macerate in a warm place for 2 hours, strain, and add it to lump and brown sugar, of each 7 lbs. Remarks. Ginger Drops are made in the same wav, only using all lump sugar. GINGER, MOCK, (Preserved.) Pret CvS. off the stalks of lettuces just going to seed, and peel off the strings. Cut them in pieces 2 or 3 inches long, and throw them into water. After washing them, put them into sugar and water, mixed in the proportion of 1 lb. of sugar to 5 pints of water; add to this quantity 2 large spoonfuls of pounded ginger. Boil the whole together for 20 minutes, and set it by for 2 days. Then boil it again for half an hour, and renew this 5 or 6 times in the same sirup. Then drain the stalks upon a sieve and wipe them dry ; have ready a thick sirup boiled, and made strong with whole ginger. Pour I it upon the stinks boiling hot; boil them in it twice GLA 339 GLA or thrice, or until they look clear and taste like the West India ginger. GLASS. -Syn. Vitrum, (Lat.) Verre, (Fr.) Glas, (Ger.) A transparent, insoluble, and brittle substance, formed by the union of the silicic acid with a rrretallic oxide. Hist. The date of the invention and the early history of the manufacture of glass are involved in considerable obscurity. According to Pliny, it originated from the following accident: A mer- chant ship, laden with natron, being driven upon the coast of the mouth of the river Belus, in tem- pestuous weather, the crew were compelled to cook their victuals ashore; and having placed mmps of the natron on the sand, as supports to the kettles, found, to their surprise, masses of transpa- rent stone among the cinders. Considering the trifles that have led to the most important discov- eries, this anecdote is very probably founded in truth. The Phoenicians were the earliest manu- facturers of glass, and long held an exclusive com- merce of this article; afterwards Alexandria and Sidon became celebrated for the same manufac- ture. (Pliny, Strabo.) Glass was employed by the Romans for windows, and for various other purposes, as specimens discovered among the ruins of Herculaneum amply testify. " The Phoenician processes seemed to have been learned by the Crusaders, and transferred to Venice in the 13th century, where they were long held secret, and formed a lucrative commercial monopoly." (Ure's Diet of Arts, &c.) The manufacture of window glass was not introduced into England until the middle of the 16th century, and was soon followed by that of Flint Glass. During the ensuing 80 or 90 years, this art acquired great perfection in this country; and at the present day, the different varieties of glass of English manufacture are equal to any in the world. Even plate glass is now made in England that is fully equal to the best foreign. GLASS, BOTTLE. Prep. I. (Dark green.) Fused glauber salts 11 lbs.; Soaper's salts 12 lbs.; waste soap ashes £ bushel; silicious sand £ cwt.; glass skimmings 22 lbs.; broken green glass 1 cwt to 1$ cwt.; basalt 25 lbs. to \ cwt. II. (Pale green.) a. Pale sand 100 lbs.; kelp 35 lbs.; lixiviated wood ashes 1 i cwt.; fresh do. 40 lbs.; pipeclay | cwt.; cullet or broken glass 1 cwt. o. Yellow or white sand 120 parts ; wood ashes 80 parts; pearlashes 20 parts; common salt 15 parts ; white arsenic 1 part. Very pale. GLASS, CROWN. Syn. White Window Glass. Prep. I. Sand 300 parts ; soda ash 200 parts; lime 30 to 35 parts; 200 to 300 parts of broken glass. II. (Bohemian.) Pure silicious sand 63 parts; potash 22 parts ; lime 12 parts ; oxide of manga- nese 1 part. III. (Professor Schweigger.) Pure sand 100 parts; dry sulphate of soda 50 parts ; dry quick- lime in powder 17 to 20 parts ; charcoal 4 parts. Product. White and good. IV. White sand 60 lbs.; good pearlashes 30 lbs.; saltpetre 15 lbs.; borax 1 lb ; white arsenic £ lb.; if it is tinged at all, add a little manganese. GLASS, CRYSTAL. Prep. I. Refined pot- ashes 60 lbs. ; sand 120 lbs.; chalk 24 lbs.; nitre and white arsenic, of each 2 lbs.; oxide of manga- nese 1 to 2 oz. II. Pure while sand 120 parts; refined ashes 70 parts; saltpetre 10 parts; white arsenic £ part; oxide of manganese $ part. III. Sand 120 parts ; red lead 50 parts ; puri- fied pearlash 40 parts; nitre 20 parts; manganese J part. IV. White sand 15 parts; red lead 10 parts; refined ashes 4 parts ; nitre 1 part; arsenious acid and manganese, of each a very little. GLASS, FLASK. (Of St. Etienne.) Purs silicious sand 61 parts ; potash 3£ parts; lime 21 parts; heavy 6par 2 parts; oxide of manganese q. s. GLASS, FLINT. Syn. Crystal Glass. Prep. I. (Korner.) Quartz (first treated with muriatic acid) 100 parts; litharge, or red lead, 80 parts; cream of tartar 30 parts. Excellent. II. White sand 120 parts ; purified pearlash 40 parts; litharge, or red lead, 35 parts; nitre 13 parts ; oxide of manganese, a little, if required. HI. Good Lynn sand 100 parts; oxide of lead 60 parts ; purified pearlashes 30 parts ; manganese, as before. IV. (Geddes.) White sand 300 parts ; red lead, or litharge, 200 parts ; refined pearlashes 80 parts; nitre 20 parts ; arsenic and manganese, of each a little. V. (M. Payen.) Silicious sand 3 parts ; red lead 2 to 2\ parts; carbonate of potash 1 £ to 1 § parts. Both this and the last contain too much lead. VI. (Guinand's.) Ground quartz and pure red lead, of each 100 parts; refined potash 35 lbs.; nitre 2 to 3 lbs. Heavy ; used by opticians. GLASS, PLATE. Prep. I. Pure sand 40 parts; dry carbonate of soda 26£ parts; lime 4 parts; nitre 1£ part; broken plate-glass 25 parts. II. (Vienna.) Sand 100 parts; calcined sul- phate of soda 50 parts; lime 20 parts; charcoal 2J parts. III. (Kirn.) Sand 61 parts; calcined sulphate of soda 27 parts; lime lOf parts; charcoal 2\ parts. IV. (Ure.) Quartz sand 100 parts; calcined sulphate of soda 24 parts ; lime 20 parts ; cullet of soda glass 12 parts. V. (Kirn.) Quartz sand 60 to 65 parts ; calcined carbonate of potash 18 parts ; common salt 9 parts ; lime 13 to 13£ parts. VI. (French.) White quartz sand and cullet, of each 300 parts ; dry carbonate of soda 100 parts ; slaked lime 43 parts. VII. Pure sand 72 parts ; refined soda 45 parts: quicklime 8 parts ; nitre 2£ parts ; cullet 45 parts. GLASS, WINDOW. Syn. Broad Glass. Prep. I. Dried sulphate of soda 11 lbs.; Soaper salts 10 lbs.; lixiviated soap waste £ bushel ; sand 50 to 56 lbs.; glass pot skimmings 22 lbs.; broken pale green glass 1 cwt II. (Paler.) White sand 60 lbs.; pearlashes 30 lbs. ; common salt 10 lbs.; arsenic 2 lbs.; oxide of manganese 2 to 4 oz. III. (Very pale.) White sand 60 lbs.; good pot- ashes 25 lbs. ; common salt 10 lbs. ; nitre 5 lbs.; arsenic 2 lbs. ; manganese 2 to 4 oz., as required; broken pale window plass 14 lbs. Remarks. The limits of this work will not per- mit of the operations of glass-making being enter- GLA 340 3LI ed into The method of employing the preceding formulae will, however, be evident to every person practically acquainted with this branch of the manufactures ; and by such alone is information of this kind required. The quality of glass is denoted by its trans- parency, strength, and power of resisting* the action of water, air, light, and the strong acids and alka- lis. Those glasses which contain a predominance of alkali are acted on by water, and when this is in great excess, are perfectly soluble in that fluid. Hence ordinary crystal glass is affected by long coction in water, while crown glass, which con- tains less alkali, is unaltered by that trial. Glasses that contain any considerable quantity of lead, are acted on by sulphureted hydrogen ; this is the 3ause of the surface of flint glass, under certain rircumstances, becoming opaque and iridescent. It is also said that glasses made of siliea and alkalis alone, are incapable of resisting the action of wa- ter, but that the addition of lime or oxide of lead is necessary for that purpose. The power of glass to resist the action of menstrua is readily tried by exposing it to boiling oil of vitriol, and hot, but di- lute solution of caustic potassa. Neither of these tests should cause the glass to lose its transparency, or to become dim. Glasses that have a slight greenish or bluish tint, may be often whitened, or rendered colorless, by exposure to light and air; " in consequence, undoubtedly, of the peroxidize- ment of the iron, to whose protoxide they owe their Lint; other glasses become purpled from the pe- -oxidizement of the manganese." (Ure.) The extreme brittleness of glass arises from its not having been annealed. This defect may be remedied on the small scale, by immersing such glass in a bath of oil, or a concentrated solution of chloride of calcium, or common salt, and heating the whole gradually and cautiously to the boil- ing point, and letting it cool very gradually ; the slower the better. By this treatment, the glass will be enabled to bear any alternations of tem- perature between the two extremes to which it has been exposed. GLASS-CLEANING. Glass Windows, Look- ing-Glasses, &c, may be cleaned as follows:— Dip a moistened rag or flannel into indigo, fuller's earth, ashes, or rotten-stone, in impalpable powder, with which smear the glass, and wipe it off with a dry soft cloth. Powder-blue or whitening, tied up hi muslin and dusted upon the glass, and cleaned off with chamois-leather, also gives glass a fine polish. The spots in the silvering of old looking- glasses are caused by damp at the back. The Vauxhall plates are no longer prized, for the glass made in the present day is whiter and better. Window-panes may be made to resemble ground glass by daubing them with putty, or a brush with a little thin paste. GLASS-CUTTING, &c. A description of the various operations of glass-cutting and grinding belongs entirely to a work on the mechanical arts; but it may not be out of place here to mention, that glass may be easily cut with a common well- hardened steel file, provided it be moistened with turpentine, or plunged under water. It may also be perforated with a common steel brad-awl in the same way. Glass vessels, as bottles ar.d tubes, may be readily cut or shortened, by placing a heated iron ring over the spot, or a piece of Ioos« Btring or cotton dipped in turpentine and set on fire, and immediately on the withdrawal of either, applying cold water to the part. Glass vessels or tubes thus treated will crack round, and may be readily divided into two parts. GLASS. GROUND. The frosted appearance of ground glass may be very nearly imitated by gently dabbing the glass over with a piece of gla- zier's putty, stuc< on the ends of the fingers. When applied with a light and even touch, the resemblance is considerable. Another method is to dab the glass over with thin white paint, or flour paste, by means of a brush ; but this is much infe- rior to the former. Used for windows. GLASS, POWDERED. Syn. Vitrum pul- verisatum. Prep. Heat the glass red hot, throw it into cold water, dry and powder. Used to filter acids ; also glued upon paper as a polishing pow- der, and to wear down corns upon the feet, after the feet have been well soaked and dried ; like- wise to blow into the eyes to wear down excres- cences. GLASS. (In Chemistry.) This term was for- merly very commonly applied to preparations to which a vitreous appearance is given by heat It is now obsolete. GLASS OF ANTIMONY. Syn. Vitrum Antimonii. Antimonium vitrificatum. Oxydum Antimonii vitrificatum. Oxydum Antimonii cum Sulphure vitrificatum. Prep. Roast powdered common antimony in a shallow vessel over a gen- tle fire, until it turns whitish gray, and ceases to emit fumes at a red heat; then heat it in a cruci- ble until it fuses into a clean brownish red glass. If calcined too much, a little more common anti- mony must be added to make it run well. It is e crude oxysulphuret, (Liebig,) and violently emetl: in doses of 1 to 2 grs.: it is now but seldom used. GLASS, STORM. Prep. Camphor 3ij; ni tre 3iss ; sal ammoniac 3ss ; rectified spirit of wine §ij ; dissolve, and keep it in a long bottle or glass tube covered with bladder. Used to foretell changes of the weather. GLAUCIC ACID. A peculiar acid discovered by Dr. Runge in several species of dipsacus and scabiosa. It is obtained by adding ether to the tincture of the dry plant, dissolving the precipitated flocculi in water, treating the solution with acetate of lead, decomposing the precipitated glaucate of lead with sulphureted hydrogen, and evaporating to expel the water and acetic acid. A brittle yel- low mass, forming salts with the bases. GLAUCINE. Syn. A peculiar substance forming pearly scales, soluble in hot water, alco- hol, and ether ; discovered by Probst in glauceum luteum. It forms neutral salts with the acids. GLAUCOPICRINE. White scales, soluble in hot water, alcohol, and ether, and having a bitter taste; also discovered by Probst in glauceum lu- teum. It forms neutral crystallizable salts with the acids. GLAZE. (In Cooking.) Gravy or soup boiled until it becomes gelatinou-, on cooling. It is used as a species of varnish to cover various dishes for the table. It may be spiced and flavored accord- ing to the fancy of the cook. (See Soup, Porta- ble.) GLIADINE, (from y\ia, glue) A peculiai GLU 341 GLTJ substance contained in the gluten of wheat, and so named by M. Taddei, an Italian chemist. Prep. Rub fresh-made gluten of wheat flour with alcohol, and evaporate to dryness ; the gliadine thus ob- tained may be purified by extracting the coloring matter by means of sulphuric ether, which does not dissolve the gliadine. Used to form a test liquor. GLOBULINE. A species of albumen consti- tuting the principal portion of the blood-globules. It exists in the clot, in combination with hamato- sine. GLUCIC ACID. Prep. Saturate grape sugar with lime or baryta, and set it aside. After some weeks, precipitate the solution with acetate of lead, filter, wash the precipitate with water, diffuse it in water, and decompose it by sulphureted hydro- gen. GLOVES, TO CLEAN. I. (Dry cleaning.) Lay them out flat; then rub into them a mixture of finely-powdered fuller's earth and alum ; sweep it off with a brush, sprinkle them with dry bran and whiting ; lastly, dust them well. This will not do if they are very dirty. II. Wash them with soap and water; then stretch them on wooden hands, or pull them into shape without wringing them; next rub them with pipe-clay, or yellow ochre, or a mixture of the two in any required shade, made into a paste with beer; let them dry gradually, and when about half dry, rub them well, so as to smooth them and put them into shape ; then dry them, brush out the superfluous color, cover them with paper, and smooth them with a warm iron. Other colors may be employed to mix with the pipe-clay beside yel- low ochre. GLOVES, TO DYE. Leather gloves, if not greasy, may be dyed with any of the ordinary dyes by brushing the latter over the gloves stretched out smooth. The surface alone should be wetted, and a second or third coat may be given after the for- mer one has become dry. When the last coat has become thoroughly dry, the superfluous color should be well rubbed out, a smooth surface given them by rubbing with a polished stick or piece of ivory, and the whole gone over with a sponge dipped in white of egg. GLUCINA. Syn. Glucine, (Fr.) Beryll- erde, (Ger.) Oxide of Glucinum. (From y\vKvs, sweet, because the salts it forms with the acids have a sweet taste.) A pulverulent white substance, discovered by M. Vauquelin in 1798, in the aqua marina and the emerald. It is classed with the earths. Prep. Finely pulverize the beryl, and expose it to a strong red heat for half an hour along with 3 times its weight of carbonate of potassa, dissolve in muriatic acid, evaporate to dryness, redissolve in very dilute muriatic acid, and precipitate with pure ammonia; wash the precipitate well, digest with a large quantity of carbonate of ammonia, fil- ter, and boil; carbonate of glucina subsides. By exposure to a red heat the carbonic acid may be expelled. Prep., fyc. 1. It forms salts with the acids. 2. Caustic potassa and soda precipitate it from the solutions of its salts, and redissolve it when added in excess. 3. Pure ammonia throws it down as a hydrate, and the carbonates of potassa and soda as a carbonate; neither of which redissolve in ex- cess of the precipitant. 4. Carbonate of ammonia water dissolves it when cold, and from this solu- tion it is precipitated by boiling. In this respect it differs from alumina, and hence these earths may be readily separated. The beryl contains 14 per cent, of glucina, combined with silicic acid and alumina. GLUCINIUM. The metallic base of the earth glucina. It was first obtained by Wohler in 1828, by a similar process to that adopted for Aluminium. It forms a grayish black powder,, which acquires a metallic gloss under the burnisher. It is but little known. Its oxide is Glucina. See Aluminium. GLUE. Syn. Colle forte, (Fr.) Leim ; Tischlerleim, (Ger.) Gluten; Glutinum, (Lat., from y^ia, glue.) Inspissated animal jelly or gela- tin. Glue is principally prepared from the parings and waste-pieces of hides and skins, the refuse of tanneries, and the tendons and other offal of slaugh- ter-houses. All these should be preferably obtain- ed and kept in the dry state, to prevent decomposi- tion. For use, they are first steeped for 14 or 15 days in milk of lime, then drained and dried ; this constitutes the " cleaning," or the "preparation." Before conversion into glue, they are usually again steeped in weak milk of lime, well washed in wa- ter, and exposed to the air for 24 hours. They are then placed in a copper boiler § filled with water, and furnished with a perforated false bottom, to prevent them from burning, and as much is* . 'led on as will fill the vessel and rest on the top of it. Heat is next applied, and gentle boiling continued until the liquor on cooling forms a firm gelatinous mass. The clear portion is then run off into an- other vessel, where it is kept hot by a water-bath, and allowed to repose for some hours to deposite, when it is run into the congealing boxes, and placed in a cgol situation. The next morning the cold gelatinous masses are turned out upon boards wetted with water, and are cut horizontally into thin cakes with a stretched piece of brass wire, and then into smaller cakes with a moistened flat knife. These cakes are next placed upon nettings to dry, after which they are dipped one by one in- to hot water, and slightly rubbed with a brush wetted with boiling water, to give them a gloss ; they are lastly stove-dried for sale. During this time the undissolved portion of skins, &c., left in the copper is treated with fresh water, and the whole operation is repeated again and again, as long as any gelatinous matter is extracted. The first runnings produce the palest and best glue. The refuse matter from the tanners and leather dressers yields on the average, when dried, 50$ of its weight of glue. The following are varieties:— 1. (Cake glue, Colle forte, Gluten commune.) Prepared from the skins of animals, by soaking them for two or three weeks in lime water, boiling them with water (sometimes adding a little alum) down to a thick jelly, as before described. Used as a cement by carpenters, &.c. 2. (Flemish glue, Dutch glue.) The skins are rinsed in several waters, and left to soak for some time, that they may require less boiling to be dis- solved ; cakes very thin, transparent; used by cab inet-makers for fine work. 3. (French glue.) Simmered for a long time with a small fire, until the skins are dissolved; then GLY 342 GOL made to boil, and alum, gr. ij to*the pint added, to clear it for moulding; transparent and very brittle. 4. (Hatmaker's glue.) From the tendons of the legs of neat cattle and horses ; brown, opaque, soft; grows moist in damp weather, but it does not render the felt brittle. 5. (Fish glue, Colle de poisson.) Is made in like manner from various membranous and solid parts of cetaceous animals. 6. (Parchment glue.) Shreds or shavings of parchment, vellum, white leather, &.C., dissolved by boiling in water, forming a nearly colorless glue. GLUE, PORTABLE. Prep. Best glue 1 lb.; water sufficient; boil it in a double gluepot, and strain ; add fine brown sugar J lb., and boil it pretty thick ; then pour it into moulds ; when cold cut into small pieces and dry them. This glue is very useful to draughtsmen, architects, &c, as it immediately dilutes in warm water, and fastens the paper, without the process of damping, and may be softened for many purposes with the tongue. GLUTEN. Syn. Colle Vegetable, (Fr.) Kleber, (Ger.) Vegetable Gluten. (From gelo, to congeal, and gluten, glue.) A peculiar sub- Btance found in bread corn ; and principally in wheat. M. Taddei has divided this substance into two others, differing from each other in their prop- erties. One of these is Gliadine, which has been already noticed; the other, Zimome, will be found in its alphabetical situation. By more re- cent analysis it appears that wheat gluten consists of albumen, mucin, (a substance soluble in alcohol while boiling,) and gluten. Gluten is believed to be highly nutritive, and to impart to wheat its superiority as an aliment over the grains of the other cereals. " It is the pres- ence of gluten in wheaten flour that renders it pre- eminently nutritious, and its viscidity or tenacity confers upon that species of flour its peculiar ex- cellence for the manufacture of macaroni, vermi- celli, and similar pastes, which are made by a kind of wire-drawing, and for which the wheat of the south of Europe (more abundant in gluten than our own) is particularly adapted. The superiority of wheaten over other bread depends upon the greater tenacity of its dough, which in panary fer- mentation is puffed up by the evolved carbonic acid, and retained in its vesicular texture, so as to form a very light loaf." (Brande.) Prep. Mix flour with a little water into a stiff paste, as for pastry, and knead this paste in water, until the starch and saccharine matter are washed out. Gray, extensible while fresh and moist, like elastic gum: turns blue when mixed with guaia- cum. GLYCERINE. (From yXvKvs, sweet.) A sweet substance formed in the process of saponify- ing oils and fats. It is the hydrated oxide of the theoretical organic radical glycerule. (Liebig.) Prep. Digest equal parts of ground litharge and olive oil, along with a little water at the boiling temperature, constantly stirring and replacing the water as it evaporates. When the compound has acquired the consistence of a plaster, wash it well with hot water, decant the latter and filter ; then pass sulphureted hydrigen through it, to throw down the lead; again filter and evaporate to a si- rup, in a water-bath. It may be decolored witfc animal charcoal. The product much resembles sirup in taste and appearance. Remarks. This substance may now be procured in solution, by hogsheads at a time, from the stearine makers, who obtain it by the saponification of tallow. It is evaporated and largely employed to adulterate moist sugar. GLYCYRRHIZIN. Syn. Glycion. Licor- ice Sugars. An uncrystallizable sugar, unsuscep- tible of vinous fermentation, contained in liquorice root. (Glycyrrhiza glabra.) It is soluble both in water and alcohol, and possesses basic properties. GOLD. Syn. Aurum, (Lat.) Or, (Fr.) Gold, (Ger.) This metal appears to have been known to the remotest ages of antiquity, and to have been then as much esteemed as at the present day. According to the writings of Moses, the art of work- ing both in gold and silver must have reached a considerable degree of advancement at that peri- od ; for these metals were commonly worked up into ornaments to decorate the person. " Speak now in the ears of the people, and let every man borrow of his neighbor, and every woman borrow of her neighbor, jewels of silver and jewels of gold." (Exodus, xi. 2.) The date of this injunction, ac- cording to the best authorities, must have been about 1500 years before Christ, or fully 3300 years ago. A description of the uses of gold in the arts, and its influence on society in all ages, as a sym- bol of wealth and an article of ornament and utili- ty, would embrace the whole history of mankind. At the present day it alike contributes to the con- veniences, comforts, and luxuries of life ;—as often exciting the baser passions of the human heart as promoting the cause of benevolence and virtue. Prep. The preparation of gold consists merely in its purification. It is usually found alloyed with silver. The latter metal is removed by the pro- cess termed "parting," either in the dry way, by fusion along with sulphur or sulphuret of antimo- ny, or in the wet way, by quartation. (See As- baying and Ores.) Prop. The most marked properties of gold are its ductility, malleability, and insolubility in all menstrua, except aqua regia and aqueous chlorine, and its slight affinity for oxygen. It is the only simple metal that possesses a yellow color. Its sp. gr. is 19*2 to 19*4. Tests. Gold is characterized by its yellow color, its insolubility in nitric acid, and ready solution in nitromuriatic arid, forming a yellow liquid that stains the skin purple. Protosulphate of iron throws down metallic gold from this solution, and pro- tochloride of tin and protonitrate of mercury, dark or black precipitates. Uses. In medicine, has been given in the form of powder, in scrofula and syphilis, by Chrestien, Niel, and others, with apparent advantage, \ gr. to 1 gr., 3 or 4 times a day, in pills. An ointment made of 1 gr. of powdered gold and 30 grs. of lard, has been applied by Niel to the skin deprived of the epidermis, (endermically.) GOLD-BEATER'S SKIN, is prepared from the peritoneal membrane of the efficum, which, as soon as it is detached, is pulled out to the extent of 2 feet or upwards, then dried. The dried mem- brane, which has the appearance of a piece of packthread, is then soaked in a very weak solu- GOL 343 GOL tion of potash, and spread out flat on a frame ; another membrane is then taken and applied to the other, so that the two surfaces which adhered to the muscular membrane of the intestine may adhere together; they unite perfectly, and soon dry. The skins are then glued on a hollow frame, washed with alum water, dried, washed with a solution of isinglass in white wine, to which spices, such as cloves, nutmegs, ginger, or camphire, have been added, and varnished with white of egg. Used to separate the leaves of gold while being beat thinner, and as a defensive for cuts. GOLD, CHLORIDE OF. Syn. Terchloride of Gold. Muriate of Gold. Chloride d'Or. Aur^iChloridum. Auri terchloridum. Auri CHLoi*ii$ETUM. Auri murias, &c. Prep. (P. Cod.) Gold 1 part; nitromuriatic acid 3 parts; dissolve ; evaporate till vapors of chlorine begin to be disengaged, then set the solution aside to crystallize. Prop., Uses, .) Graufarbe, (Ger.) Proc. I. Sumach 2 lbs.; logwood 1 lb.; make a decoction with water, pass the stuff through it, and afterwards through a weak iron water, (sulphate or acetate ;) lastly, add GRE 316 GUA a littlu iron liquor to the decoction, and again turn the stuff through it. This gives a pearl gray. II. Dissolve 1 lb. of tartar in 4 gals, of water, turn the stuff through the liquor for half an hour; add a decoction of galls -} lb., and sumach 1A lb.; put in the stuff and boil for half an hour; then take out the stuff, add sulphate of iron 1 lb., and when dissolved again, put it in, and work it well for half an hour longer. Ash gray. This will dye 15 to 25 lbs. of wool. III. Galls bruised 2 lbs.; winestone 1 lb.; wa- ter 16 gallons; boil for 30 minutes.then put in the stuff, and work it well for half an hour; take it out, add 3 lbs. of green copperas, and when dis- solved again, put in the goods and work them well. Ash gray. This will dye 60 to 70 lbs. of wool. The addition of a little alum converts this into a mouse gray. IV. Pass the stuff through a weak fustic bath, and next through a very weak decoction of galls, to which a little alum has been added; then re- move the goods, refresh the bath with a little log- wood, boil half an hour, add some blue and green vitriol, and when dissolved, finish the stuff therein. Yellowish gray. V. Give the stuff a pale blue tint in the indigo :ath, then pass it through a weak decoction of galls and sumach, take it out, add a little iron liquor to the bath, and work the stuff well through it. In this way may be given every shade of iron gray, slate gray, and the other shades that turn upon the blue. GREEK FIRE. This is supposed to have consisted of a mixture of asphaltum or pitch, nitre, and sulphur. GREEN DYES. Proc. First dye the stuff blue, observing to regulate the shade according to that of the intended green; dry and rinse ; then give it a bath of yellow dye, until the desired shade is produced. (See Blue Dyes, Indigo, Yellow Dye.) GREEN PIGMENTS. Syn. Couleurs ver- tes, (Fr.) Grune Pigments, (Ger.) Any shade of green may be produced by the mere mechan- ical admixture of blue and yellow pigments. The bright blues and yellows produce the liveliest greens; orange, or red and blue, and the yellow- ish browns and blue, the more dingy greens. Among the green pigments of the shops, may be mentioned the following: Green bice, or mountain green, is the mineral substance called Malachite. It is a green carbon- ate of copper. It is also prepared artificially. Brunswick green, or Bremen green. Several preparations are sold under this name. When prepared according to the formula given at page 218, it is an oxychloride of copper, but as com- monly made, it is a carbonate of copper, mixed with variable quantities of chalk, white lead, alu- mina, magnesia, or ammonia. The following is a good and cheap form for this article:—Dissolve blue vitriol and alum in a large quantity of water, and precipitate with a solution of carbonate of am- monia, or bone spirits ; collect the powder, wash it with water, and dry it. The clear liquor may be used to make sal ammoniac. Brunswick green, prepared as above, is a mixed carbonate of copper and alumina. The proportion of alum em- ployed modifies the shades of green, and also cheapens it. Bremen green is properly green ver* diter, but the names are usually confounded. Th« same may be said of Brunswick green, which is, properly a crude oxychloride of copper, prepared according to the formula in page 218. Friese green, or Friesland green, is an oxy- chloride of copper. (See p. 218.) Iris green, prepared by grinding tho juice of the petals of the blue flag (iris nostras) with quick- lime. This green is not gene*-ally kept, and is fu- gitive. Mitt is green, or Scheele's, is an arsenite of cop- per, made by mixing a solution of sulphate of cop- per with arsenite of potassa. (See Scheele'b Green.) Mineral green, the same as mountain green, or green bice, just noticed. (See page 217.) Prussian green, the sediment of the process of making prussian blue from bullock's blood or horns, before it has had the muriatic acid added to it. It is also prepared by pouring liquid chlorine upon freshly precipitated prussian blue. Sap green, prepared from the juice of buck- thorn berries. The berries are allowed to ferment for a week or eight days in a wooden tub. The juice is then pressed out, strained, a little alum added, and the whole evaporated to a proper con- sistence ; it is then run into pigs' bladders, and hung up in a dry situation, to harden. An infe- rior article is also made from the juice of black alder, and of evergreen privet. It is a comiron practice to add J pint of lime-water and £ oz. of gum arabic, to every pint of either of the above juices. Schweinfurt green is a superior description of Scheele's green, or an arsenite of copper. (See Schweinfurt Green) Verditer (green,) is a mixture of oxide of cop- per and whiting. (See Verditer.) Verona green. The mineral called green earth. GREGORY'S SALT. The crude hydrochlo- rate of morphia, prepared by Gregory's process. It is a double hydrochlorate of morphia and co- deia. GRINDSTONES, ARTIFICIAL. Prep. Washed silicious sand 3 parts; shellac 1 part; melt, and form it into the proper shape while warm. The fineness of the sand must depend on the work the stone is intended for. Powdered emery may be substituted for sand. The same composition is formed upon pieces of wood, for the purpose of sharpening knives, and cutting stones, shells, &c. GRUEL. (In Cookery.) Oatmeal or groats boiled with water to a proper consistence, and strained. It is variously flavored to suit the palate ; but the addition of a little white sugar, and finely powdered Jamaica ginger, with or without a glana of wine, is least likely to offend the stomach. Nutmegs, cinnamon, &c, frequently disagree with invalids. GUAIACINE. Syn. Guaiacic Acid. A pe- culiar substance, discovered by Trommsdorff in the wood and bark of guaiacum officinale. Prep. Treat tincture of guaiacum with hydrate of lime, when a guaiacate of lime is formed, from which the acid may be obtained by sulphuric acid. GUAIACUM. Syn. Gum Guaiacum. This rt GUT 347 ILEM ■ubstance is sometimes adulterated. The Edin- burgh College states that its " fresh fracture is red, slowly passing to green; the tincture slowly strikes a lively blue color on the inner surface of a thin paring of a raw potato." (P. E.) Adultera- tion with resin may be generally discovered by the odor evolved when the guaiacum is heated. An alcoholic tincture of guaiacum, rendered milky with water, recovers its transparency on the addi- tion of caustic potassa in excess; but this is not the case when resin is present. One of the most marked properties of guaiacum is its turning blue by contact with gluten, and several other substances in the air; nitric acid and aqueous chlorine turn it successively green, blue, and brown. A delicate photogenic paper may be formed by first washing with an alcoholic solution of guaiacum resin, and afterwards with one of neutral acetate of lead. (Johnston.) GUT, FISHING. Syn. Silkworm Gut. Prep. Steep silkworms, when just ready to spin, in strong vinegar for 12 hours, in warm weather, or 2 or 3 in cold ; then take them out, break them in half, stretch them out as far as possible on a * It is right to caution the reader of the dangerous na- ture of all cnmpmnds contMining either gunpowder, or nitre, or chlorate of potash, in contact with combu t:ble ■ulj-Mnres, as seriou-i accidents h tve arisen from handling them c relessly The use of metallic implements or uten- g'.ls should be avoided, and the ingredients should be mixed and kept at a distance from a fire or candle. j These powders also contained frou. -5 tr. 1*1 of water. GUM. Syn. Gummi, (Lat.) Gomme, (Fr.) Gummi ; Pflanzenschleim, (Ger.) Inspissated vegetable mucilage. The purest substance of this kind is that called gum arabic, or gum acacia. The gums are employed as demulcents in medi- cine, and are used as cements. GUM-RESINS. .Syn. Gummi resina*., (Lat) GOMME-RESINES, (Fr.) SciILEIMHARZE, (Ger.) Inspissated vegetable juices, consisting of extrac- tive and resinous matter. They are partly soluble in water and in alcohol. The principal gum-resins are frankincense, scammony, asafcetida, aloes, euphorbium, galbanum, myrrh, olibanum, opopo- nax, ammoniacum, and gamboge. GUNPOWDER. Under this head will be given the proportions of the ingredients employed in the manufacture of the most celebrated pow- ders, reserving a description of their preparation for the article Pyrotechny.* board, furnished with slits or pegs to hold them, and dry them in the sun. Used by anglers. The worms may be known to be going to spin by re- fusing food, and by having a fine silken thread hanging from their mouths. (Nobb's Art of Troll- ing.) ______ H^EMATOSINE. A species of albumen on which the color of the blood is supposed to depend. It may be obtained from blood, previously well stirred to separate the fibrine, by mixing it with 6 times its volume of a saturated solution of sulphate Table showing the Relative Proportions of Charcoal, Nitre, and Sulphur, contained in some of the most celebrated Gunpowders: Authorities, or place of manufacture. Nitre. Charcoal. Sulphur. English : Royal Mills, Waltham Abbey 75 15 10 Sporting powder, (Marsh).... 78 12 10 do. (Marsh) .... 76 15 9 tdo. Hall, Dartford, (Ure) . 76-2 14 9 tdo. Pigou & Wilks, (Ure) 77-4 13*5 8-5 tdo. Curtis &, Harvey, (Ure). 76-7 12-5 9 tBattle powder, (Ure)..... 77 13-5 8 Miners' do. (Marsh) .... 65 15 20 Common do. (Marsh) 75 12-5 12*5 French: Government powder..... 75 12-5 12*5 Sporting do...... 78 12 10 65 15 20 Gunpowder of Bale..... 76 14 10 do. of Grenelle .... 76 12 12 do. of M. Guyton Morveau 76 15 9 do. do. 77-33 13-44 9*24 do. of M. Riffault .... 77-5 15 7*5 United SS. Government powder . 75 12-5 12*5 Russia do. 73-78 13-59 12-63 Prussia do. 75 13-5 11-5 Austria do. ... 72 17 16 Spain do. 76*47 10-78 12-75 Sweden do. 76 15 9 Switzerland do. 76 14 10 China do. ... 75 14-4 9*9 Theoretical proportion for the best gunpowder 75 13-23 11-77 HAI 348 HAN of soda, filtering, boiling the globules with alcohol acidulated with sulphuric acid, again filtering, adding carbonate of magnesia to separate the sul- phuric acid, and after filtering, evaporating to dry- ness. A dark reddish-brown mass. HAEMOPTYSIS, (from i,M, blood, and xrvo,, I spit.) Spitting of blood. It generally arises from extreme fulness of the blood-vessels of the lungs, or the jupture of blood-vessels, as a conse- quence of ulceration. Bleeding, aperients, acidu- lous and astringent drinks, and nauseants, are the usual remedies. Sugar of lead, in small doses, has been recommended for this affection. It should be accompanied with a sufficient quantity of free acetic acid, to prevent its being converted into the poisonous carbonate of lead in the system. HEMORRHAGE. Syn. Hasmorrhagia, (from iipa, blood, and fcayv, rent.) A bleeding or flow of blood. Bleeding may be divided into ac- tive, passive, and accidental. Active hamor- rhage is that arising from a full state of the vessels, or plethora; passive hamorrhage from general debility of the system, and the blood-ves- sels in particular; accidental hamorrhage from external violence, as blows, wounds, &c. The first generally requires depletion, and the second the usual treatment to establish the general health and vigor of the body. The bleeding from wounds, if extensive, should be arrested by tying the rup- tured blood-vessels, or where this cannot be done, and in less important cases, by the application of styptics, as creosote, sulphate of iron, infusion of galls, compound tincture of benzoin, &c. HAIR DYES. Prep. I. (Dr. Hanmau.) Li- tharge 275 grs.; quicklime 1875 grs.; hair pow- der (starch) 930 grs.; all in fine powder; mix. For use, this powder is made into a paste with warm water or milk, and immediately applied to the hair by means of the fingers, observing to rub it well into the roots. The whole must be then covered with a moist leaf of cotton wadding, sev- eral times doubled, and allowed to remain so for 3 hours, or preferably all night. The powder may then be removed by rubbing it off with the fingers, and afterwards washing it with warm soap and water. A little pomatum or hair oil will restore the usual gloss to the hair. This is one of the most innocent preparations of the kind. Like all other hair dyes, it must be reapplied as soon as the hair by growing begins to expose an undyed surface underneath. A piece of oil skin, or even a cabbage leaf, may be used instead of cotton wadding. II. (Orfila's.) Litharge 6 parts; quicklime 5 parts; starch 1 part. As last. III. (Delcroix's.) Acetate of lead 2 oz.; pre- pared i.halk 3 oz.; quicklime 4 oz. As before. IV. (Spencer's.) Sap green £ dr.; nitrate of silver 1 dr.; hot water 1 oz.; dissolve. Applied to the hair by means of a comb moistened with it. Stain>; the skin as well as the hair. V. (Hewlet's.) Similar to the last. VI. (Pomade dye.) Nitrate of silver 1 part; nitric acid 2 parts; iron filings 2 parts; mix, and let them stand together for 4 or 5 hours, then pour them on oatmeal, 2 parts; next add lard 3 parts; »nd mix well together. Stains the skin without great care. VII. (Instantaneous) Moisten the hair first with a solution of nitrate of silver in water, (1 U 7 or 8 ; and then with a weak solution of hydro- sulphuret of ammonia. The color of the hair, before unaltered, instantly turns black. VIII. The juice of the bark of green walnut* (Paulus jEgineta.) IX. Employ a leaden comb. Remarks. All the preceding are for dyeing livhif hair, (human ;) horse-hair and other dead hair may be colored by steeping them in any of the ordinary dyes. HAMS. (In Domestic Economy.) These are usually prepared from the legs of pigs, but those of the sheep are also sometimes used for the same purpose. Smoked ham is strong eating, and ra- ther fit for a relish than for diet. Choice. Stick a sharp knife under the bone, if it has a pleasant smell when withdrawn, the ham is good; but if the contrary, it should be rejected. The recently cut fat should be hard and white, and the lean fine-grained, and of a lively red. Legs of pork short in the hock should alone ba chosen for making into hams, as the lanky sort not only look less sightly, but are deficient in flavor. Curing. Hams are prepared in the usual way for salting, either by immersion in the pickle, or by rubbing the salt over them. A little powdered saltpetre should be well rubbed over them an hour before salting them: moist sugar is frequently mixed with the salt, or treacle is put into the brine to improve the flavor; a little spice (pow- dered allspice) and black pepper are also occa. sionally used for a like purpose. An ordinary sized ham will require nearly three weeks, if wet salted, and about a month if dry salted, to cure it perfectly. At the expiration of this time, they are ready for smoking. Mutton hams are pre- pared in a similar manner, but should not lie in pickle longer than 12 days or a fortnight. (See Animal Substances used as Food, and Salt- ing.) Cooking. Preparatory to the cooking of hams, they should be well soaked in water, to which a little vinegar or milk may be added. They are also preferably boiled in milk and water, or water alone, along with some heads of celery, 2 or 3 tur- nips, 5 or 6 onions, and a handful of sweet marjo- ram, thyme, and basil. Hams should be put into • the water cold, and should be gradually heated. A ham of 16 lbs. will take 4£ hours, and one of 20 lbs. 5J hours to dress it properly. (See Baking.) HAMS, PRESERVATION OF. Most gro- cers, dealers in hams, and others, who are particu- lar in their meat, usually take the precaution to case each one, after it is smoked, in canvass, for the purpose of defending it from the attacks of the little insect, the dermestes lardarius, which, by laying its eggs in it, soon fills it with its larvae, or maggots. This troublesome and expensive process may be altogether superseded by the use of pyro- ligneous acid. With a painter's brush, dipped in the liquid, one man, in the course of a day, may effectually secure two hundred hams from all dan- ger. Care should be taken to insinuate the liquid into all the cracks, &c, of the under surface. This method is especially adapted to the preservation of hams is. not climates. HANDS. Dirty and coarse hands are no less HAR 349 HEA the marks of slothfulness and low breeding, than clean and delicate hands are those of cleanliness and gentility. To promote the softness and white- ness of the skin, mild emollient soaps, or those abounding in oil, should alone be used, by which means chaps and chilblains will generally be avoided. The coarse, strong kinds of soap, or those abounding in alkali, should for a like reason be rejected, as they tend to render the skin rough, dry, and brittle. The immersion of the hands in alkaline lyes, or strongly acidulated water, has a like effect When the hands are very dirty, a lit- tle good soft soap may be used with warm water, which will rapidly remove oily and greasy matter. Fruit and ink stains may be taken out by im- mersing the hands in water slightly acidulated with oxalic acid, or a few drops of oil of vitriol, or to which a little pearlash or chloride of lime has been added, observing afterwards to well rinse them in clean water, and not to touch them with soap for some hours, as any alkaline matter will bring back the stains, after their apparent removal by all the above substances, except the last. The use of a little chloride of lime and warm water, or Gow- lamd's Lotion, will impart a delicate whiteness to the skin ; but the former should be only occasion- ally used, and should be well washed off with a little clean water to remove its odor. The use of a little sand, or powdered pumice-stone, with the soap, will generally remove the roughness of the skin, frequently induced by exposure to cold. The hands may be preserved dry for delicate work, by rubbing a little club moss, (lycopodimn,) in fine powder, over them. A small quantity of this sub- stance sprinkled over the surface of a basin of wa- ter, will permit the hand to be plunged to the bot- tom of the basin without becoming wet. (See Cosmetic, simple.) HANNAY'S LOTION. Syn. Hannay's pre- ventive Wash. A solution of potash in water. Used to prevent infection. HARDNESS. Syn. Durete, (Fr.) Hartf. ; Festigkeit, (Ger.) Duritia ; Durities, (Lat) In Physics, the power possessed by bodies of re- sisting abrasion. In Mineralogy, mineral sub- stances are frequently distinguished and identified by their relative hardness. This is ascertained by their power to scratch or be scratched by one an- other. A valuable table on' this subject will be found under the article Gem, p. 331. HARMALINE. A basic substance, forming yellow-brown crystals, discovered by Gobel in the seeds of peganum harmala. It has a bitter astrin- gent and acrid taste, and forms yellow soluble salts with the acids. It has been proposed as a yellow dye. By oxidation it yields a magnificent- ly red dye-stuff, which is easily prepared and ap- plied. (Gobel.) The seeds are produced abundantly in Russia, so that it appears probable that, ere long, they may become an article of commerce. HARTSHORN, BURNT. Syn. Cornu Us- tum, (P. L.) Pulvis Cornu Cervini Ustum, ^P. D.) Cornu Ustum Album. Prep. (P. L.) Burn pieces of harts' horns until perfectly white, then grind and prepare them in the same way as directed for Prepared Chalk. Remarks. Finely-powdered bone-ash is usually •sold for burnt hartshorn, and possesses exactly the same properties. Dose. 10 grs. to 3ss 2 or 3 times a day, in rickets, &c. (See Phosphate of Lime.) HARTSHORN SHAVINGS. Syn. Harts horn Raspings. Rasura Cornu Cervi. Ramen-i * jCornu Cervi. Obtained from the turners. By boiling in water they yield a nutritive jelly. Used by straw-plait workers to stiffen bonnets, &c. HATS. In purchasing a hat, choose one pos- sessing a short, smooth, fine nap, and a good black color; and that is light and sufficiently elastic t3 resist ordinary wear and tear, without breaking or giving way. The hat brush for daily use should be made of long soft hairs, but a stiffer one should be employed occasionally, to lay the nap smooth and close. HEADACHE. Syn. Cephalalgia, (Lat.) The symptoms of this very general complaint are too well known to require any description. According to pathologists, headache arises, either from a sym- pathy with the stomach and chylopoietic (chyle- forming) viscera, or from a weakness or exhaus- tion of the power of the encephalon. The former may be called sympathetic, and the latter nervous headache. The treatment of the first should con- sist in restoring the healthy action of the stomach by the administration of aperients, and the use of proper food and exercise, or when that viscus is overloaded with undigested food, by the exhibition of an emetic. For this purpose \ to J an oz. of ipecacuanha wine may be taken in a cupful of warm water, which will generally relieve the stomach, especially if its action be assisted by drinking copiously of warm water. (See Emet- ics.) Headache is a common accompaniment of indigestion and stomach diseases, and in general it will be found that whatever will remove the lat- ter will also cure the former. (See Dyspepsia.) Nervous headaches are relieved by nervous tonics and stimulants ; as bark, cascarilla, calumba, gen- tian, camphor, ammonia, ether, and wine; the latter in a state of considerable dilution. A cup of strong coffee or strong green tea often acts like a charm in removing this species of headache. Small doses of tincture of henbane will also have a like effect. 20 or 30 drops of laudanum, or preferably, half that number of liquor opii seda- tivus, may be taken with advantage as an ano- dyne, and to induce sleep. Among popular rem- edies may be mentioned " nasal stimulants," as snuff, (cephalic,) smelling salts, and aromatic vinegar, the use of which is familiar to every one ; and local applications, as very cold water, ether, vinegar, strong spirits, Cologne water, &c, all of which are rubbed over the part of the head af- fected, with the fingers ; or a linen rag dipped in them is laid thereon instead. Pressure on the head has also been used with advantage. Silence, darkness, and repose, are also powerful remedies, alike suitable to every variety of headache ; and change of air, scene, and occupation, are espe- cially beneficial to those resulting from excessive mental anxiety or exertion. Blisters are some- times applied behind the ears in cases of violent headache. Headache is often symptomatic of ot.ier diseases, especially those of the inflammatory and nervous kind, rheumatism, &c. In all these cases, the primary disease should be sought out and attempt- ed to be cured. Headache in pregnancy may HEM 350 HIE generally be removed by proper attention to the bowels; observing to assist their action, should they require it, by the use of some mild aperient, as castor oil, lenitive electuary, seidlitz powders, &c. Where the constitution is very robust, blood may be taken. Headache in bed may frequently be relieved by washing the head with cold water, and discontinuing the use of a nightcap ; at the same time preserving the feet warm by wearing worsted socks or stockings. HEADING. Syn Beer Heading. Cauli- flower do. Prep. I. Alum and green copperas equal parts, both in fine powder ; mix. II. Alum, copperas, and common 6alt, of each equal parts; mix. Used by brewers ;to make their beer keep its head. HEARTBURN. Syn. Cardialgia ; Cordo- lium, (Lat) Anxiety and pain about the region of the stomach, generally attended by a sense of gnawing and heat; hence called heartburn. Faint - ness, nausea, and eructation of a thin, acidulous, watery liquid, especially in the morning, are com- mon symptoms of this complaint. The usual causes of heartburn are excess in eating or drink- ing, the use of improper food, and sedentary habits. A good remedy is a teaspoonful of carbonate of magnesia, or carbonate of soda, in a glass of pep- permint or cinnamon water, to which a little pow- dered ginger may be added with advantage. This dose may be taken 2 or 3 times daily until the disease is removed. Articles of food that easily undergo fermentation should at the same time be avoided, and a dry diet had recourse to as much as possible. Soda-water, toast and water, and weak spirits and water, are the most suitable bev- erages in this complaint. HELENINE. Syn. Elecampane Camphor. A peculiar substance obtained from the fresh root of inula Helenium, by digestion in hot alcohol or distillation along with water. It is crystalline, so- luble in alcohol, ether, and essential oils, melts at 162°, and boils about 530° F. HEMATINE. Syn. HiEMATiNE. Hematox- ylin. A peculiar principle obtained by Chevreul from common logwood, (Haematoxylon campechi- anum,) and on which its color appears to depend. Prep. I. Infuse logwood chips in water, at a temperature of about 130° F., for 12 hours, filter, evaporate to dryness in a water-bath, digest in al- cohol of 0-835 for 24 hours, again filter and evapo- rate ; then add a little water, again gently evapo- rate and set aside the solution in a cold place that crystals may form; these must be washed in alco- hol and dried. II. Digest powdered hard extract of logwood in alcohol of 0835 and proceed as last. Prop., <$-c. It forms brilliant reddish-white crys- tals, soluble in boiling water, forming an orange- red solution which turns yellow as it cools, but re- sumes its former color on being heated. Alkalis in excess change its color successively into purple, Violet, and brown ; with the metallic oxides it forms compounds, having a blue, purple, or violet color. HEMIDESMIC ACID. Syn. Smilasperic Acid. A volatile and crystallizable substance ob- tained by Mr. Garden from the root of hemidesmus indicus. It possesses the taste and odor of the root. HEPAR, (Lat, from 'Hirap, the liver.) A nam* given by the older chejrnists to various combina- tions of sulphur, from their brown color; as hepar sulphuris, (sulphuret of potassium,) hepar anlimo. nii, (crude oxysulphuret of antimony,) &c. HERBS for medical purposes should be col. lected as soon as they begin to flower, and on a dry day, after the dew and moisture deposited on them during the night have evaporated. The bien- nial narcotic plants should not be collected untl the second year of their growth, as, during the first year, they are mucilaginous and nearly inert. The younger plants possess, however, the brightest green color, and make the most showy extracts, for which reason they are frequently purchased by the druggists of the herb collectors, without an ex- amination being made into their value as remedies. This is one of the causes of the general inferiority of the extracts of the shops which are prepared from the expressed juices of narcotic plants. Color alone is cared fori Chlorophyle, which constitutes the green portion of vegetables, is a resinous substance, which has been fully proved to be wholly destitute of medicinal virtue. Herbs are dried by spreading them thinly on trays, and exposing them to the heat of the sun, or a current of dry air, or by placing them in a stove-room ; observing in either case to turn them repeatedly. When dried in the sun they should be covered with thin paper to prevent their color being injured by the light. The quicker they are dried the better, as " heating" or " fermentation" will be thereby prevented. When sufficiently dried, they should be shaken in a coarse sieve to remove any sand or the eggs of insects that may be mixed with them. Aromatic herbs should be dried very quickly, and by a gentle heat, that their odor may be preserved. Tops and leaves are dried in the same way as whole plants. In every case discol- ored and rotten leaves and branches should be re- jected, and earth and dirt should be screened off before proceeding to dry them. HESPERIDIN. A peculiar substance obtained from the white portion of the rind of oranges, lem- ons, &c. It forms crystalline silky needles, is odorless, tasteless, fusible, soluble in alcohol, and reddened by oil of vitriol. HICCOUGH. Syn. Hiccup. Singultus, (Lat.) A convulsive motion of the diaphragm and parts adjacent. The common causes are flatulency, indigestion, acidity, and worms. It may usually be removed by the exhibition of warm carmina- tives, cordials, cold water, weak spirits, camphor julep, or spirits of sal volatile. A sudden fright or surprise will often produce the like effect. An in- stance is recorded of a delicate young lady that was troubled with hiccough for some months, and who was reduced to a state of extreme debility from the loss of sleep occasioned thereby, who was cured by a fright, after medicines and topical ap- plications had failed. A pinch of snuff, a glass of cold soda-water, or an ice-cream, will also fre- quently remove this complaint. HIERA PICRA. Syn. Powder of aloes and canella. Pulvis aloes cum canella. (From icpos, holy, and ir«cpoj, bitter.) Holy bitter. This name was formerly applied to an aloetic electuary, made of honey. It is now kept in the form of a dry powder. HOL 351 HOL Prep Hepatic aloes 4 lbs.: white canella 1 lb.; reduce to fine powder. Remarks. Inferior aloes are commonly used for this preparation. It is cathartic in doses of 10 to 20 grs. HIPPOCRAS. Prep. Lisbon and canary wine, of each 12 pints ; cinnamon 2 oz.; white canella, )f oz.; cloves, mace, nutmeg, ginger, and galgan- gal, of each 1 dr.; bruise the spices, and digest them in the wine for 3 or 4 days; strain, and add lump sugar 2£ lbs. An aromatic wine formerly much used in England. HIPPURIC ACID. (From iTr-roj, a horse, and ovpov, urine.) A new arid, discovered by Liebig, in the urine of the horse, cow, and other gramini- vora. Prep. Concentrate the urine by a gentle heat, acidulate with muriatic acid, and set it aside to crystallize. It may be decolored by re-solution in boiling water, and treating it with animal charcoal, or chloride of lime, along with a little muriatic acid, and recrystallizing. Remarks. This acid is soluble in 400 parts of cold water, but is easily dissolved by boiling water. When strongly heated, benzoic acid and benzoate of ammonia distil over in a liquid state, accompa- nied by a strong odor of Tonka beans, and after- wards by hydrocyanic acid. " The urine of horses or cows, left to itself for some time, or evaporated at a boiling temperature, yields not a trace of hip- puric acid, but only benzoic acid." Nitric acid converts hippuric into benzoic acid. (See Ben- zoic Acid.) HIRCIC ACID. A name given by Chevreul to an oily liquid, obtained by saponifying the fat of goats. It is prepared in the same way from goat fat, as capric, caproic, and butyric acids are from butter. It is soluble in alcohol, and possesses a mixed smell of vinegar and goats. With the bases, it forms salts called hircates. HIRCINE. (From hircus, a he-goat) An oily fluid extracted by Chevreul from goat-fat, and which may also be obtained from mutton suet. It smells strongly of the male goat. By saponifica- tion it yields Hircic Acid. HOLLANDS. Syn. Hollands Gin. Geneva. Jennever Branpewyn, (Ger.) Spirit of Juni- per. Spiritus Juniperi. Prep. I. The following description of the manufacture of hollands comes on the authority of Robert More, Esq., formerly of Underwood, distiller, " who, after studying the art at Schiedam, tried to introduce that spirit into general consumption in this country, but found the palates of our gin-drinkers too much corrupted to relish so pure a beverage." " The materials employed in the distilleries of Schiedam are, two parts of urtmalted rye from Riga, weighing about 54 lbs. per bushel, and one part of malted bigg, weighing about 37 pounds per bushel. The mash tun, which serves also as the fermenting tun, has a capacity of nearly 700 gal- lons, being about 5 feet in diameter at the mouth, rather narrower at the bottom,-and 4£ feet deep; the stirring apparatus is an oblong rectangular iron grid, made fast to the end of a wooden pole. About a barrel (36 gallons) of water, at a temperature of from 162° to 168°, (the former being the best heat for the most highly-dried rye,) is put into the mash tun for every 1£ cwt. of meal, after which the malt is introduced and stirred, and lastly the rye ■ added. Powerful agitation is given to the magma till it becomes quite uniform; a process which a vigorous workman piques himself upon executing in the course of a few minutes. The mouth of the tun is immediately covered over with canvass, and further secured with a coarse wooden lid, to con- fine the heat; it is left in this state for two hours The contents being then stirred up once more, the transparent spent wash of a preceding mashing is first added, and next as much cold water as will reduce the temperature of the whole to about 85° F. The best Flanders yeast, which had been brought, for the sake of carriage, to a doughy con- sistence by pressure, is now introduced to the amount of 1 lb. to every 100 gallons of the mashed materials. The gravity of the wort is usually from 33 to 38 lbs. per Dicas' hydrometer; and the fer- mentation is carried on for from 48 to 60 hours, at the end of which time the attenuation is from 7 to 4 lbs.; that is, the sp. gr. of the supernatant wash is from 1*007 to 1*004. On the third day after the fermenting tun is set, the wash containing the grains is transferred to the still, and converted into low wines. To every 100 gallons of this liquor, 2 lbs. of juniper berries, from 3 to 5 years old, being added, along with \ lb. of salt, the whole are put into the low-wine still, and the fine Hollands spirit is drawn off by a gentle and well-regulated heat till the magma becomes exhausted ; the first and last products being mixed together, whereby a spirit 2 to 3 per cent above our hydrometer proof is obtained, possessing the peculiar fine aroma of gin. The product varies from 18 to 21 gallons per quarter of grain; this large quantity being partly due to the employment of the spent wash of the preceding fermentation ; an addition which contributes at the same time to improve the fla- vor." (Ure's-Diet of Arts, &c, pp. 571—2.) To the preceding it may be added that the yeast is skimmed off the fermenting tuns and sold to the bakers ; which is said to lessen the production of spirit, but to improve its quality. The ingredients are also reduced to the state of coarse meal before mashing them. Remarks. It will be seen from the preceding statement, to the accuracy of which the writer of this article bears willing testimony, that the supe- rior flavor of hollands spirit depends more on the peculiar mode of its manufacture than on the quantity of juniper berries employed ; 2 lbs. of that substance, when new, being equivalent to less than 5 drachms of the essential oil, and when old, only to about 2 drachms-; a quantity wholly insuf- ficient to flavor 100 gallons of spirit. Besides, as already noticed, the flavor of hollands differs con- siderably from that of juniper ; the latter being merely employed as a modifying ingredient. Most of the Dutch distillers add a little pure Strasburgh turpentine, and a handful or two of hops to the spirit, along with the juniper berries, before rectifi- cation. The former substahice has a pale yellow- ish brown color, and a very fragrant and agreeable smell, and tends materially to impart that fine aroma for which the best Geneva is so much dis- tinguished. The principal part of the secret lies, however, in the careful management of the process. The numerous published receipts for hollands gin, in which 2 or 3 oz. of oil of juniper, and as many HON 352 HON pounds of juniper berries, are ordered to only 20 or 25 gallons of proof spirit, tend only to deceive those who adopt them. At Rotterdam sweet fen- nel seeds are occasionally added as a flavoring ; and at Weesoppe, Strasburgh turpentine, fennel seeds, or the essential oil, are frequently wholly substituted for juniper berries. Schiedam hollands is considered the best; the next quality is that of Rotterdam ; and afterwards, that of Weesoppe. Hollands spirit pays a duty of 22s. &d. per proof gallon, which is the same as that on French brandy. See Gin. II. (Best hollands. Brandewyn von Koorn voorloof drie quart.) Hollands rectified to the strength of 24° Baume, (sp. gr. 09125.) The strength of this spirit alone is no proof of its supe- rior quality. III. Digest 2 or 3 lbs. of good old juniper berries in 1 or 2 gallons of rectified spirit of wine for a week or 10 days, then express the liquor, filter it through blotting paper, add it to 90 or 100 gallons of good corn spirit at 2 or 3% over proof, and mix them by thorough agitation. IV. Juniper berries 2 to 4 lbs.; sweet fennel seeds 4 or 5 oz.; caraway seeds 3 or 4 oz.; spirit of wine I or 2 gallons ; corn spirit 90 or 100 gal- lons. As last V. Juniper berries, fennel seeds, caraways, and spirit, as last; Strasburgh turpentine, a little. Pro- ceed as in No. III. Remarks. The last three forms produce very pleasant spirits, if kept for some time to mellow ; age is one of the reasons of the creaminess of for- eign gin, which usually lies in bond for some time before being consumed. The product is, however, much superior if the ingredients are put into a still along with 20 gallons of water, and the spirit drawn over by a moderate heat. In this case, it will be an improvement to employ some good plain- flavored English gin. instead of plain corn spirit, if the expense is no object. I have mentioned cer- tain quantities of the flavoring ingredients to be employed, as a guide to the reader ; but the actual quantities required in practice depend on their quality, and the taste of the consumer. The same remark also applies to the following. The imita- tion of hollands, like that of brandy, chiefly de- pends on the experience and discretion of the work- man. VI. Oil of juniper 4 oz.; oil of turpentine 5 oz.; oils of caraways and sweet fennel, of each 1 oz., (all quite pure ;) rectified spirit of wine 1 gal- lon ; dissolve by occasionally agitating them well together in a corked bottle for 2 or 3 days, then add it gradually to clean corn spirit or plain gin until the required flavor is produced, observing not to use too much. Product. Good, if kept for some time. HONEY. Syn. Mel, (Lat. and Fr.) Honig, (Ger.) The sweet substance elaborated by the bee from the juices of the nectaries of flowers, and deposited in the cells of wax forming the honey- comb. Pure honey consists of a sirup of uncrys- tallizable sugar and crystalline saccharine grains, resembling grape sugar. Virgin honey is that which flows spontaneously from the comb ; ordi- nary honey, that obtained by heat and pressure. The former is pale and fragrant; the latter darker, and possessing a less agreeable taste and smell. English honey (Mel Anglican) is chiefly collected from furze and broom flowers, and is more waxy than that from the South of Europe ;—Narbonnt honey, (Mel Narbonense,) chiefly from rosemary, and other labiate flowers, very fine ;—Minorca honey, (Mel Minorcense ;)—East country honey, inferior and bad tasted ;—Poisonous honey, found near Trebisond, in Asia, narcotic and poisonous. Uses, 6fC. Honey is nutritive and laxative, but very apt to gripe. It is employed in the prepara- tion of oxymels and gargles, and also to cover the taste of nauseous medicines, which it does better than sugar. Clarified honey is alone ordered to be used in medicine. Pur. Honey is frequently adulterated with trea- cle, starch, and wheat flour. The first may be detected by the color and odor, and the others by the honey not forming a nearly clear solution with cold water, and striking a blue color with iodine. HONEY, CLARIFIED. Syn. Mel despu- matum. Prep. I. (P. L. and D.) Melt the honey in a water-bath, remove the scum, and pour off the clear. Less agreeable than raw honey, but not so apt to ferment and gripe. II. (Siller.) Any quantity of honey is dissolved in an equal part by weight of water. The liquid is allowed to boil up 4 or 6 times without skim- ming ; it is then removed from the fire, and after being cooled, brought on several strong linen strain- ers, stretched horizontally, and covered with a layer of clean and well-washed sand an inch in depth. When the solution has passed through the strainers, it is found to be of the color of clear white wine ; the sand being allowed to remain on the strainers, is rinsed with cold water, and the whole of the liquor is finally evaporated to the thickness of sirup. III. Dissolve the honey in water, clarify with the white of egg, and evaporate to a proper con- sistence. IV. Dissolve in water, add IJ lb. of animal charcoal to every \ cwt of honey, gently simmer for 15 minutes, add a little chalk to saturate excess of acid, if required ; strain or clarify, and evaporate. Remarks. Honey acquires a darker color if heated in copper or iron vessels; the above pro- cesses should therefore be conducted in earthen or well-tinned copper pans. HONEY, HELLEBORE. Syn. Mel IIelle- boratum. Prep. (P. L. 1746.) Hellebore root, bruised, lb. j ; water 4 pints; digest for 3 days; boil, strain, and add honey lb. ij ; boil to a sirup. Cathartic, in mania. HONEY, LIQUORICE. Syn. MelGlycy*- rhizatum. Prep. (Hamb.-Ph.) Honey and a strong infusion of liquorice boiled to a proper con- sistence. HONEY, MERCURIAL. Syn. Mel mer curiale. Prep. (P. L. 1746.) Juice of the her* mercury and honey, of each equal parts; boil to t proper consistence. HONEY OF BORAX. Syn. Mel Borvcis (P. L.) Mel Subboracis. Prep. (P. L.) Pow dered borax 3j; clarified honey Jj', mix. Astrin- gent, detersive, and cooling. It is employed in aphthae of the mouth and excessive salivation. It is incompatible with acids, and is decomposed by compound infusion of roses, with which it is com- monly ordered. HOR 353 HUI HONEY OF MERCURY. Syn. Mel Hy- drargyri. Prep.' (Bell.) Quicksilver 3j; honey Jj; triturate till the globules disappear. Proper- ties similar to mercurial pill. HONEV OF MERCURY, COMPOUND. Syn. Mel Hydrargyri compositum. Prep. (PC.) Quicksilver 3ij; clarified honey ^ij; oil of cloves 3ij; as last. HONEY OF ROSES. Syn. Mel Rosas. Prep. (P. L.) Dried petals of the red rose %\v ; boiling water 2£ pints; macerate for 6 hours, strain, add honey lb. v; and evaporate in a water- bath to a due consistence. Used to make astrin- gent gargles. It mu#t not be boiled in a copper or iron vessel, as they will spoil the color. HONEY OF SQUILLS. Syn. Mel Scillas. Prep. Clarified honey lb. iij ; tincture of squills lb. ij; mix well. Properties and uses the same as oxymel of squills. HOP. Syn. Houblon, (Fr.) Hopfen, (Ger.) Humulus Lupulus, (Lat.) The hop or hops of commerce, are the strobiles or catkins of the hop plant. In the choice of hops, care should be taken to select those that have large cones or strobiles, that are the most powerfully odorous, and most free from leaves, stems, scaly fragments, and sticks, and which, when rubbed between the hands, impart a yellowish tint and glutinous feel- ing to the skin. The tightness with which they are packed should also be noticed; as without be- ing very firmly pressed together, and quite solid, they soon spoil by keeping. The finest flavored hops are those grown in East Kent, and termed the " golden bine;" these possess a lively golden yellow color, and are principally employed for the finer class of ales. Mid Kent and Sussex hops are also used for ale, but have an inferior color and flavor. Countrys and Farnham hops have a greenish yellow color, and are more expensive than any other variety; but are only used for malt liquor that it is intended to keep for a long time, as they do not impart their flavor to the beer be- fore it has been kept at least a year. They are chiefly used for ale. The best hops are packed in sacks of fine canvass, termed "pockets," weighing from 14; cwt to 1J cwt. each ; and the inferior qualities in coarse " bags," of about double the size. The former are mostly purchased by the ale, and the latter by the porter brewers. When hops are older than of the last season's growth, they are termed " yearlings,"—when of the sec- ond season's growth, " olds,"—and when three years, or older, " old olds." (See Extract of Hors, and Brewing.) HORDEINE. (From hordeum, barley.) This name was given by Proust to the peculiar starchy matter of barley meal; but according to Raspail, it is merely bran more minutely divided than that which remains in the sieve. HOREHOUND. Syn. White Horehound. Marrubium vulgare. This herb is a popular rem- edy in chronic pulmonary complaints, especially catarrh, and in uterine and liver affections. Hore- hound ea (thea vel infusum marubii) is prepared by infixing 1 oz. of the herb in boiling water for an hour; sirup of horehound, (syrupus marubii,) by thickening the infusion or tea with sugar; can- died horehound, (marrubium conditum,) by mix- ing horehound juice 1 pint, with white sugar 4 lbs., 45 and moist sugar 6 lbs., or white sugar alone 10 lbs., boiling to a candy height, and pouring it, while warm, into moulds or small paper cases, well dust- ed with finely-powdered lump sugar; »r it is poured out on a dusted slab, and cut into squares. HORN is dyed with the same dyes, and in a similar manner to bones and ivory. (See page 125.) Horn is softened, bent, and moulded by means cf heat and pressure. HUILE ACOUSTIQUE. Prep. Bullock's 'garlic and bay leaves, of each 3iv ; olive oil lb. ss ; boil for 15 minutes, and strain. Used for earache and deafness ; a little dropped on cotton wool and placed in the ear. HUILE D'ANIS. Aniseed, bruised, 4, lb.; spirit of wine 1 gallon ; digest a week, strain, and add sugar Ik, lb. It may be made of star anise seed, and proof spirit may be substituted for spirit of wine. Cordial and pectoral. HUILE ANTIQUE. Prep. I. (Plain.) a. Ol- ive oil 1 pint; oil of vitriol \ oz. ; mix, agitate well in a corked bottle for 1 hour, then allow it to repose in the sun, or a moderately warm situation, for 12 or 14 days, after which time decant the clear portion from the sediment 6. Oil of ben nuts filtered; this never gets rank. c. Olive oil filtered. All the above keep the hair moist, and may be scented at pleasure. II. (Huile antique a la rose.) a. Either of the above scented with otto of roses. 6. Rose leaves and blanched sweet almonds, equal parts; grind them together, then express the oil, and either filter it through blotting paper, or allow it to de- posite in a closely-corked bottle, c. Use blanched bitter almonds instead of sweet ones. Remarks. The first two keep the hair moist; the last one dries it. The same is the case with all those that follow where bitter almonds are used. III. (Huile antique a la tuberose.) As the last IV. (Huile antique a la fleur d'orange.) Plain Huile antique scented with Neroli, or orange flowers and almonds pressed together, as in No. II. V. (Huile antique au jasmin.) From oil of jasmin, or jasmin flowers, as the last. VI. (Huile antique a la violette.) Plain huile antique, scented with powdered orris root, by keep- ing them together at a gentle heat in a covered vessel for 24 hours, and filtering when cold. VII. (Huile antique aux mille fleurs.) Plain huile antique, scented with several perfumes, so that none may predominate. VIII. (Huile antique verte.) Plain huile an- tique 1 pint; gum guaiacum, bruised, \ oz.; dis- solve by placing the bottle in a water-bath ; when cold, filter through paper, and scent to your pleas- ure. IX. (Huile antique rouge a la rose.) Plain huile antique 1 pint; alkanet root 1 dr.; digest in a gentle heat until sufficiently colored, then strain. and add otto of roses 20 drops, oil of rosemary and oil of neroli, of each 5 drops. HUILE LIQUEREUSE DE LA ROSE, Prep. Rose water and simple sirup, equal partf, A pleasant and fragrant sweetening for grog, liqueurs, &c. HUILE LIQUEREUSE DES FLEURS HYD 354 HYD D'ORANGES. Prep. Orange-flower water and simple sirup, equal parts. More fragrant and agreeable than the last. Gives a delicious fla- vor to grog, liqueur, &c, and to perfume the breath. HUILE DE VANILLE. Prep. Spirit of wine and simple sirup, of each 1 quart; essence or tincture of vanilla, a sufficient quantity to fla- vor; mix. This should be kept in a decanter. Used to flavor liqueurs, &c. HUILE DE VENUS. Prep. I. Flowers of the wild carrot 5 oz.; spirit of wine 1 gallon ; water 1 pint; macerate 24 hours, then distil 1 gal- lon, and add an equal measure of capillaire or sim- ple sirup. II. Wild carrot flowers 4 oz.; spirit of wine 1 gallon ; macerate for 1 week, strain, and add cap- illaire 1 gallon. If preferred colored, steep \ oz. of cochineal in it. A pleasant cordial. HUMUS. When wood, or woody fibre, is ex- posed to the joint action of air and moisture, it suffers decay or eremacausis, and moulders down into a dark-brown or black powder, commonly called Mould, and to which chemists have given the name Humus. By the action of alkalis, it is converted into humic acid, which is soluble, and forms salts called humates. HUSBANDRY. This term is applied to the joint operations of farming and gardening on the small scale, and it is also sometimes used synony- mously with agriculture. (See Agriculture, Farming, Manures, and Soil.) HYDRARGYRO-CHLORIDES. Salts in which the bichloride of mercury plays the part, of an acid. The only one that has been applied to any useful purpose, is the hydrargyro-chloride of ammonia, or the sal alembroth of pharmacy. Per- haps white precipitate may also belong to the same class. Similar salts have been formed with the chlorides of other metals, to which the names auro-chlorides, cupro-chlorides, ferro-chlorides, cobalto-chlorides, &c. &c, have been applied. HYDRARGYRO-IODO-CYANIDE OF POTASSIUM. Prep. Add a concentrated solu- tion of bicyanide of mercury to a solution of iodide of potassium, as long as a white, pearly, crystal- line precipitate is formed. Used to ascertain the purity of prussic acid; if a small portion be put into this acid, in a dilute state, red biniodide ot mercury will immediately be formed, if any foreign acid be present. HYDRARSINE. An ethereal, volatile sub- stance, having an intolerably fetid odor, formed by the action of air on alkarsine. HYDRAT.E. (From Map, water.) In Chem- istry ; a compound containing water, in definite proportion. Thus, slaked lime is a hydrate of lime; caustic potassa, a hydrate of potassa; and oil of vitriol, a hydrate of sulphuric acid. HYDRATED. (In Chemistry.) Chemically combined with water. Thus, the crystallized ve- getable acids, (citric, tartaric, oxalic,) and salts (epsom salts, carbonate of soda, &c.) that contain combined water, are called hydrated acids and hydrated salts. The term hydrated is used as an adjective, in the same way as hydrate is as a substantive. The former is, however, usually ap- plied to compound names, as hydrated acetic acid, hydrated oxide of iron, &c., and the latter. for the sake of euphony, to simple names, as Ay. drate of lime, hydrate of potassa, &c. HYDRIODATE. Syn. Hydriodas, (Lat.) A compound formed of the hydriodic acid with a base. The hydriodates may be easily formed by- saturating the acid with the oxides or hydrates oi the bases, or more economically, by acting on the bases in water, with iodine. (See Iodine, Iodides, and Hydriodic Acid.) HYDRIODIC ACID. Syn. Acidum Hydrio- dicum. Prep. Pour a little water over some per- iodidi of phosphorus, previously put into a small glass retort, and apply a gentle heat, when hy- driodic acid will be evolved, and phosphoric acid remain behind. The gas may be either collected over mercury or passed into water, when liquid hydriodic acid will be formed. II. (F. D'Arcet.) Evaporate hypophosphoric acid until it begins to yield phosphoreted hydro- gen, then mix it with an equal weight of iodine placed in a retort; apply a gentle heat as before, and collect the evolved gas. The products of both this and tho former process possess great purity. III. (Dr. Glover.) Place iodide of barium in a retort, and decompose it with sulphuric acid, when pure hydriodic acid will be evolved. IV. (Liquid.) Pass sulphureted hydrogen through a mixture of iodine and water, in a YVoolf's bottle, until saturated, then gently heat the liquid until the excess of sulphur flies off. An economical process, but does not yield the pure acid. V. (Dr. Buchanan's medicinal hydriodic acid.) Tartaric acid 264 grs.; pure iodide of potassium 330 grs.; dissolve each separately in water f §iss, mix the solutions, and when settled, decant the clear liquid and add water to make up f Jvj 3ij. This liquid acid retains a little bitartrate of potassa in solution, but which does not interfere with its medicinal properties. (See Iodine and Hydrio- date.) HYDRO. (In Chemistry.) A prefix employed to designate the compounds of hydrogen; as Ay- drochloric acid, hydrobromic acid, acids formed of chlorine, bromine, and hydrogen. It is some- times, though improperly, used synonymously with the word hydrated. (See Hydrate and Hy- drated.) HYDROBENZAMIDE. A substance discov- ered by Laurent, and prepared by mixing pure hydruret of benzule with 20 times its volume of concentrated water of ammonia, in a stoppered bottle, a/'.l keeping the mixture for some hours at a heat oi .00 to 120°. The crystalline mass thus formed is washed with cold ether, when pure hy- drobenzamide is left, and may be obtained in crys- tals by re-solution in alcohol, and spontaneous evaporation. HYDROBROMATE. Syn. Hydrobromas. A compound of hydrobromic acid and a base. HYDROBROMIC ACID. Syn. Acidum Hy- drobromicum. An acid compound of hydrogen and bromine. It may be prepared from the bro- mide of phosphorus in a similar way to that foi forming hydriodic acid from periodide of phospho rus. It may also be prepared by decomposing bromide of barium with sulphuric acid, when pure hydrobromic acid will be evolved. (Dr. Glover.) It should either be collected in dry glass bottle3, in the manner directed for chlorine, or over mercury, HYD 355 HYD in the pneumatic trough. When passed into wa- ter it forms liquid hydrobromic acid. The pure liquid acid cannot be made by passing sulphureted hydrogen through water mixed with bromine, as is commonly practised. Prop., fyc. A colorless, acidulous, and pungent gas, or a limpid fluid. With the bases it forms salts called hydrobromates. These are formed in a similar way to the hydriodates. (See Bro- mine.) HYDROCARBURETS. Syn. Hydrocarbons. Compounds of hydrogen and carbon. The princi- pal of these are—1. Light carbureted hydrogen, or the fire-damp of miners, consisting of two equiv- alents of hydrogen, and one equivalent of carbon, and burning with a pale blue flame. 2. Olefiant gas, consisting of two equivalents of hydrogen and two equivalents of carbon. It burns with a very white and luminous flame. 3. Light gas or coal gas, consisting of a mixture of the preceding in no definite proportions. 4. Quadricarbureled hy- drogen, quadrihydrocarbon, or etherin, consisting of 4 equivalents each of carbon and hydrogen, and produced during the destructive distillation of oil. It burns with a dull fuliginous flame. 5. Bi- carbureted hydrogen, also obtained by the de- structive distillation of oil, and consisting of 3 eq. of hydrogen and 6 eq. of carbon. (See Hydro- gen, Carbureted Hydrogen, Etherin, Naph- tha, &c.) HYDRO-COBALTO-CYANIC ACID. Pr-.p. Pass sulphureted hydrogen through a solu- tion of cobalto-cyanide of lead, separate the lead by filtration, evaporate and crystallize. White, fibrous, acidulous, deliquescent crystals, soluble in water. With the metals it forms compounds termed cobalto-cyanides. The cobalto-cyanide of potassium is formed by gently heating the carbonate, or pure protoxide of cobalt, in a solu- tion of caustic potassa, which has been treated with an excess of hydrocyanic acid, until dissolved, evaporating and crystallizing. It forms soluble, reddish yellow crystals, which are rendered color- less, or only slightly yellow, by recrystallization. The cobalto-cyanide of lead is made by treating a solution of acetate of lead with cobalto-cyanide of potassium, and adding ammonia, when a white granular precipitate is formed. Cobalto-cyanide of silver is prepared by mixing a solution of ni- trate of silver with another of cobalto-cyanide of potassium; a white granular precipitate subsides. In a similar way several other cobalto-cyanides may be formed. HYDRO FERRIC ACID. (See Ferric Acid.) HYDRO-FERRIDCYANIC ACID. Pre-k pared by decomposing recently precipitated ferrid- cyanide of lead by sulphureted hydrogen, or by sulphuric acid carefully added. A yellow solution is thus obtained, which yields a deep brown pow- der when evaporated by heat, or yellow crystals by spontaneous evaporation. With the oxides of the metals it forms ferridcyanides. These may be made by adding a solution of the ferridcyanide of potassium to another of a soluble salt of the base. (See the Ferridcyanide of Potassium and Iron.) HYDROFLUORIC ACID. Syn. Fluoric Acid. Stygian Water. Acidum fluoricum. Acidum hydrofluoricum. Aqua Stygis. An acid compound of hydrogen and fluorine. It was first procured in a pure state by Gay Lussac and Thdnard in 1810. Prep. Pour concentrated sulphuric acid on half its weight of fluor spar, carefully separated from silicious earth, and reduced to fine powder. The mixture must be made in a capacious leaden re- tort, and a gentle heat applied, when hydrofluoric acid gas will be evolved, and must be collected in a leaden receiver, surrounded with ice. Props., Uses, <$•£. A colorless fluid below 59° Fahr., when preserved from the air, but speedily evaporating in dense white fumes when exposed. Its affinity for water exceeds that of sulphuric arid, and its combination with that fluid is accom- panied with a hissing noise, and a considerable increase of its sp. gr. up to a certain point It readily dissolves glass and silica, forming fluosili- cic acid, for which reason it cannot be preserved in glass vessels. Bottles of lead are hence gener- ally used for this purpose, but silver and platinum are more suitable materials. It is highly corro- sive, instantaneously destroying the skin on con- tact, and producing deep and serious ulcerations ; its vapor is pungent, irritating, and irrespirable. With the metals it unites to form hydrofluorates, fluorates, or metallic fluorides. Hydrofluorate of ammonia is obtained by heating together, over a lamp, 1 part of dry sal ammoniac, with a little more than 2 parts of hydrofluorate of soda, in a platinum crucible, with its lid turned upward, and filled with cold water. The hydrofluorate sublimes and adheres to the lid, forming a mass of small prismatic crystals. It peadily acts on glass. The hydrofluorates of the alkalis, earths, and metals may mostly be prepared by saturating hydrofluoric acid with the recently precipitated oxide, or car- bonate of the base. In the arts, hydrofluoric acid is used for etching on glass. HYDROGEN. Syn. Hydrogenium, (Lat.) Wasserstoff, (Ger.) Hydrogen, (Fr.) Inflam- mable air. (From SSiop, water, and ytvvau, 1 generate.) A chemical element, first correctly described by Cavendish in 1766, having previously been confounded with other gases, and by some called phlogiston, from being supposed to be the matter of heat. The term hydrogen was first ap- plied to it by Lavoisier, because it is the radical or base of water. In the pure state it only exists as a gas, and is the lightest substance known. New opinions have lately been* promulgated by one of the most celebrated continental chemists respect- ing hydrogen. At the termination of his fourth lecture at the Sorbonne, M. Dumas announced the following striking views:—" Whatever it may cost me, gentlemen, in thus giving my opinion, I ought to express it fully. We ought no longer to con- sider hydrogen as a metalloid, or as merely ap- proaching to a metal in any form—it ought to be classed by the side of metals, or among metals. It is a gaseous metal, even as mercury is a liquid metal. If we suppose that it is impossible to liquefy the vapor of mercury—that it is colorless, inodorous, and transparent as hydrogen—we shall have a correct idea of the views I wish to estab- lish. By degrees you will learn to appreciate the correctness of this new theory—when, for instance, HYD 356 HYD you study the different compound bodies of which hydrogen is a constituent. The ensemble of its properties approaches, in fact, to mercury and potassium." (Echo du Monde Savant, Nov. 20, 1842.) Prep. I. Place iron wire in a gun-barrel, or a porcelain tube, open at both ends, to one of which attach a retort containing water, and to the other a bent tube, connected with a pneumatic trough. The gun-barrel must now be heated to redness, and the water in the retort brought into a state of brisk ebullition, when the vapor will be decom- posed, the oxygen being absorbed by the iron, and the hydrogen escaping into the gas receiver. II. Oil of vitriol 1 part; water 5 parts; mix, and pour the dilute acid on iron or zinc wire, or filings placed in a retort or gas bottle. Hydrogen will be evolved as before. This is the more con- venient method of the two, and the one usually adopted in practice. Remarks. To render the gas quite pure, distilled zinc should be employed, and the gas should be passed, first through alcohol, and then through a concentrated solution of pure potassa. Prop., Uses, dfc. A colorless, tasteless, odorless (when pure) combustible gas, having the sp. gr. 0-0694 ; being 16 times lighter than oxygen gas, and nearly 14J times lighter than atmospheric air. Combined with oxygen it forms water; with chlo- rine, muriatic acid; with iodine, hydriodic acid; with bromine, hydrobromic acid; with fluorine, hydrofluoric acid; with cyanogen, prussic acid; with carbon, several hydrocarburets or hydrocar- bons; with nitrogen, ammonia; with phosphorus, phosphoreted hydrogen ; .with sulphur, sulphuret- ed hydrogen; and with arsenic, tellurium, and potassium, arseniureted, tellurcted, and potas- siureted hydrogens. It also enters into the com- position of all compounds containing water, (hy- drates, &.c.,) numerous acids and salts, and the various proximate organic principles both of the animal and vegetable kingdoms. It forms one of the ingredients of coal gas, and of all bodies that possess the power of burning with flame. From its extreme lightness it 's used to fill balloons, but its carburet, (coal gas,, from being cheaper and more easily procured in large quantities, is general- ly employed for this purpose. 100 cubic inches, at 60° F., and 30 inches of the barometer, weigh 2-1371 grs. Mixed with atmospheric air or oxygen it explodes with extreme violence on the approach of flame, or sudden compression. (Biot.) When brought into contact with spongy platinum, the latter instantly becomes red hot, and the gas is kindled. A small apparatus, arranged upon this principle, constitutes the popular little instrument for the instantaneous production of light, 6old by the philosophical instrument makers. One meas- ure of hydrogen and 5 or 6 of air, or 2 of hydro- gen and 1 of oxygen, are the proportions that ex- plode with the greatest violence. (Doebereiner.) A mixture of 1 volume of hydrogen and 9 volumes of air explodes feebly, and one of 4 volumes of hydrogen and 1 volume of air does not explode at all. (Cavendish.) The electric spark, spongy platinum, the black powder of platinum, (Garden,) clean platinum foil, (Faraday,) and some other substances, produce combination, and generally explosion, of the mixed gases. A jet of hydrogen, burnt in oxygen gas, or a jet of these gases (mixed) burnt in the air, with proper precautions, produce* the most intense heat known. On this property is formed the oxy-hydrogen blowpipe. This instru- ment can only be used with safety when furnished with Ilemming's safety jet, or other arrangement to prevent an explosion. (See Blowpipe.) Prof Daniell's method of fixing a jet of oxygen within another jet of hydrogen, or coal-gas, so that a cur- rent of oxygen may be mtroduced into the middle of the flame, is very safe and convenient. (The figures 1 and 6, at page 122, are wrongly number- ed ; they should be reversed.) HYDROGEN, BINOXIDE. Syn. Deutoxidr of Hydrogen. Peroxide of do. This singular fluid was discovered by M. Thenard in 1818. Prep. I. Mix deutoxide of barium, with about twice its weight of water, then graddally add sul- phuric acid until all the deutoxide is converted into sulphate of baryta, observing to avoid excess of acid. II. Water 6 or 7 oz.; deutoxide of barium 230 grs.; mix, and add gradually as much pure con- centrated hydrochloric acid as is required to ren- der the deutoxide soluble ; then place the contain- ing vessel, which should be of glass, in a freezing mixture, or vessel of ice, and add gradually and cautiously 185 grs. of powdered deutoxide of ba- rium, stirring with a glass rod, after each addition; as soon as dissolved, add sulphuric acid to precipi- tate the whole of the baryta, and then a second portion of 185 grs. of deutoxide of barium, as be- fore. This must also be precipitated with sulphuric acid, the solution filtered, and the same process re- peated, until about 3 oz. of deutoxide of barium have been employed. The hydrochloric acid must then be separated by means of sulphate of silver, cautiously added, and the sulphuric acid after- wards separated by pure solid baryta. (Ann. de Chim. et de Phys. and M. Thenard's Traite de Chimie.) Remarks. The liquid prepared by the last for- mula contains 25 to 30 times its volume of oxygen, and also much simple water. To remove the lat- ter it must be placed over sulphuric acid, under the exhausted receiver of an air-pump, where it must be kept until the sp. gr. becomes 1-452, beyond which it cannot be concentrated ; as at this point it begins itself to volatilize slowly. In this state it is a colorless and limpid fluid, having a metallic taste, and is stable at low temperatures, but re- solved into oxygen and water, at 59° F. It mixes with water in all proportions, and becomes more permanent The same may also be said of the acids. It bleaches organic substances. All the metals, except iron, tin, antimony, and tellurium, decompose it with more or less facility, and this action is promoted by the substances being in a state of minute division. A similar decomposition is produced by many of the metallic oxides. The peroxides of lead, mercury, gold, platinum, man- ganese, and cobalt, .effect this change instantane- ously, and accompanied with extreme violence, during which the glass tube holding the liquid be- comes red hot Its action on oxide of silver is also exceedingly violent. Every drop of the liquid let fall on the dry oxide produces a real explosion; and so much heat is evolved, that if the experi- ment be made in a dark place, there is a very sen- HYD 357 HYD sible disengagement of light. Gold, in a state of extreme division, acts with great force on pure oxygenated water; yet it has no action on that liquid if it be mixed with a little sulphuric acid. Fibrin, (recently extracted from the blood,) the tissue of the lungs, kidneys, and spleen, and the skin and veins, also deoxydize the liquid. Peroxide of hydrogen has been applied in the arts to restore the blackened lights of paintings, which have become darkened, from the lead they contain being acted on by the sulphureted hydro- gen frequently present in the atmosphere. It has been lately proposed by M. de Sondala, as a means of supplying oxygen to the confined air of diving bells and other limited places; the carbonic acid formed by the lungs being at the same time ab- sorbed by passing the air through hydrate of lime. HYDROLEIC ACID. A peculiar compound obtained by evaporating the alcohol used in the preparation of hydromargaritic acid. HYDROMARGARIC ACID. A compound formed by melting together one equivalent each of meta-margaric and hydromargaritic acids, and crystallizing the mass from alcohol. HYDROMARGARITIC ACID. Obtained by boiling the mother liquor of meta-margaric and metoleic acids, when a mixture of hydromargaritic and hydroleic acids rises to the surface, which, af- ter being washed with cold alcohol, leaves the former pure. By heat it is converted into meta- margaric acid and water. Soluble in alcohol and ether. HYDROMELLONIC ACID. Prepared by dissolving mellonide of potassium in boiling water, adding muriatic, sulphuric, or nitric acid, and col- lecting and drying the precipitate. A yellow powder, soluble in water. It forms mellonides with the metallic oxides. HYDROMEL. Prep. (P. Cod.) Honey 2 oz.; boiling water 32 oz.; dissolve and strain. HYDROMETER. (From «So. Lacca Florentina. Prep. I. Boil the residuum of cochineal, left in making carmine, with repeat- ed portions of water till n\ ceases to yield color ; filter ; mix it with the liquor decanted off the car- mine ; filter ; add some recently-precipitated alu- mina, apply a gentle heat, and agitate well. As soon as the alumina has absorbed sufficient color, allow the mixture to settle ; decant the clear liquid, collect the lake on a filter, and carefully dry it. The decanted liquor, if still colored, may now be treated with fresh alumina until exhausted, and thus a lake of a see.id quality may be obtained. Very fine. II. To the colored liquor obtained from the car- mine and cochineal as above, add a solution of alum, mix well, filter, and precipitate with a solution of potash ; collect the lake and dry it as before. Not quite so good as the last. Remarks. Some makers add a little solution of tin to the colored liquor before adding the alum or alumina; this brightens the color. The above lake is a good glazing color with oil, but has little body. LAKE, GREEN. Made by mixing bin- and yellow lakes together. Seldom used. LAKE, MADDER. Syn. Lacca Con. m bin a. Prep. I. (Sir H. C. Inglefield.) Dutch grappe or crop madder 2 cz.; tie it up in a cloth, beat it well in a pint of water in a stone mortar, and re- peat the process with fresh water (about 5 pints) till it ceases to yield color ; boil the mixed liquors in an earthen vessel, pour it into a large basin ; add alum 1 oz.; dissolve in boiling water 1 pint; stir well, and while stirring pour in gradually of saturated solution of carbonate of potash (oil of tartar) about 14 oz.; let it stand to settle until cold, then pour off the supernatant yellow liquor, drain, agitate the residue with boiling water 1 quart; decant, drain, and dry. Product, 4 oz. The Society of Arts voted their gold medal to the author of the above formula. II. (Ure.) Ground madder 2 lbs.; water 1 gallon ; mix, macerate with agitation for 10 min- utes, strain off the water, and press the remainder quite dry ; repeat the same process a second and a third lime ; then add water 3 qts., and alum 4 lb., arid heat in a water-bath for 3 or 4 hours, add- ing water as the liquor evaporates; filter, first through a flannel, and when sufficiently cold, through paper ; then add a solution of carbonate of potash as long as a precipitate falls, which must be washed, till the water comes off colorless, and then dried. If the alkali be added in 3 successive doses, 3 different lakes will be obtained, successively diminishing in beauty. III. Add acetate of lead to a decoction of mad- der, to throw down the brown coloring matter, fil- ter, then add a solution of tin or alum, and pre- cipitate with a solution of carbonate of soda or potash. LAKE, ORANGE. Prep. Best Spanish an notto 4 oz.; pearlash lib. or less ; water 1 gallon; boil for half an hour, strain, precipitate with alum 14 lbs., dissolved in water 1 gallon, observing not to add the latter 'solution when it ceases to pro- duce an effervescence or a precipitate ; strain, and dry the sediment in small squares or lozenges. The addition of solution of tin turns this lake on the lemon yellow; acids redden it. LAKE, RED. Prep. I. Coarsely-powdered cochineal 1 oz.; water and rectified spirit of wine, of *--*ich 2 oz.; digest for a week, filter, and pre- cipitate with a few drops of solution of tin, added every (4 hours, till the whole of the color is thrown down; wbsh in distilled water, and dry. Very- fine. II. Coarsely-powdered cochineal 1 lb.; water 2 gallons ; boil 1 hour, decant, strain, add a solution of pearlash 1 lb. or more, and precipitate with a solution of alum. If the alum be added first, and the lake precipitated with the alkali, the color will be slightly varied. Some persons use a solution of cuttlefish-bone in muriatic or nitric acid ; but this increases the expense, and yields an inferior pro- duct. III. Pearlash 1 lb.; clean shreds of scarlet cloth 3 or 4 lbs.; water 4 or 5 gallons; boil til! LAU 391 LEA the cloth is decolored, filter, and precipitate with a solution of alum. LAKE, YELLOW. Prep. Boil French ber- ries, quercitron, or turmeric 1 lb. and potash 1 oz.; in water 1 gallon, till reduced to one half, strain, and precipitate with a solution of alum.—Or boil 1 lb. of the dye-stuff with alum 4 lb.; water 1 gallon, as before, and precipitate with a solution of carbonate of potash. (See Lake, Orange.) LAMPIC ACID. When the wick of a spirit- lamp is surrounded with a spiral coil of platinum wire, and after burning for a short time, is blown out, combustion still goes on, and a peculiar acid product results, which has been called lampic acid. It was first examined by Prof. Daniell. It may be more easily collected by placing a small bottomless retort over a heated platinum capsule, and gradually dropping in, from time to time, a little alcohol or ether. (R. F. Marchand.) It consists of a mixture of acetic, formic, and alde- hydic acids, in variable proportions. (MM. Stass and Marchand.) Its most remarkable property is its power of reducing certain metallic solutions. With the bases it forms salts called lampates, which may be prepared by saturating the acid with the hydrated oxides or carbonates. (See Aldehydic Acid.) LAMPS. To prevent or lessen the smoking of lamps, the^wicks should be well soaked, either in dilute muriatic acid, well washed in water, and dried, or in strong vinegar, when they will merely require drying. Large lamps, that emit much smoke, should be burnt under a funnel, to carry it off; or a large sponge, dipped in water, may be suspended over them ; in all cases, the wicks should not be put up too high. LANTANIUM, (from Xavdavu, I lurk.) A rare metal, recently discovered by Mosander, associated with the oxide of cerium. (See Cerium.) LAPIS DIVINUS. Syn. Lapis ophthalmi- cus. Prep. Blue vitriol, nitre, alum, and cam- phor, equal parts, melted together, adding the camphor last. (Woolfuss.) Verdigris, nitre, and alum, equal parts, melted together. (Beer.) Alum, nitre, and blue vitriol 3 oz.; camphor 1 dr. ; as last. (P. Cod.) Used to make an eyewater ; 1 oz. to water 1 pint. LAPIS MEDICAMENTOSA. Prep. (P. L. 1746.) Alum, litharge, Armenian bole, and colcothur, of each 3 oz.; vinegar 4 oz. ; mix and evaporate. Used to make a lotion : 1 oz. to water 1 pint. Astringent, detergent; once a popular application to ulcers. LARD. Syn. Hogs' Lard. Auxunge. Aux- ungia. Adeps. Adeps Suillus. Adeps Porci. Adeps praparatus. The fat of the pig, melted by a gentle heat, and strained through a hair sieve or flannel. The fat about the loins yields the whitest and hardest lard. Used to make oint- ments, and in cookery. LARD, OXYGENATED. See Nitric Acid Ointment. LAUDANUM, QUINCE. Syn. Extractum Opii sku Laudanum Cydoniatum. Prep. Opium 4 lb.; quince juice 6 lbs. ; digest, filter, evaporate to an extract, and add **hile warm, oils of cinna- mon, cloves, and mace of each 10 drops. Milder than crude opium ; seldom used. LAUDANUM, FORD'S. Prep. Opium £j; cinnamon and cloves, of each 3j ; rectified ppirit of wine and water, of each, ^viij ; digest for a week, and filter. This is merely an aromatized tincture of opium. Dose. 10 to 80 drops. LAUDANUM, LIQUID. Prep. 1. (Liquid quince laudanum. Laudanum liquidum cydo- niatum. Laudanum liquidum cydoniatum para- tum fermentatione.) Opium §iv ; saffron ^ij ; quince juice 1 quart; yeast 4 spoonfuls ; ferment, express the liquor, filter, and add cinnamon §ij ; cloves, aloes wood, and yellow sandal wood, oi each, 3ij ; digest for 14 days, filter, and evaporate to one half. Narcotic, anodyne ; similar to black drop. Dose. 10 to 30 drops. Seldom used. 2. (Neuman's.) Opium fermented with water, and evaporated to the consistence of honey. Similar to the aqueous extract of opium. 3. (Sydenham's. Laudanum liquidum Syden- hami.) Opium ?ij ; saffron |j ; cinnamon and cloves, of each, 3j ; white wine f§xvj ; digest Contains J of opium. See Wine of Opium, P. L., which is always substituted. 4. (Laudanum tartarized. Laudanum liquidum tartarizatum.) Opium f ij ; saffron Jj; cinnamon, cloves, mace, nutmegs, and aloes wood, of each, 3j ; tincture of salt of tartar f^xxxij ; digest, strain, and evaporate to one half. Seldom used. LAVENDER, SMITH'S BRITISH. Syn. Smith's Lavender Water. Prep. English oil of lavender 2 oz.; essence of ambergris 1 oz.; eau de Cologne 1 pint; rectified spirit 1 quart; mix. Very fragrant. LEAD. Syn. Plomb, (Fr.) Blei, (Ger.) Plumbum, (Lat.) /i<5Ai/3io?, (Gr.) Saturn, (Ale.) This metal, like gold, silver, and iron, appears to have been known in the most remote ages of an- tiquity : " Oh that my words were now written ! Oh that they were printed in a book ; that they were graven with an iron pen and lead in the rock for ever !" (Job, xix. 23-4.) Prep. Lead is only prepared on the large scale. It is usually extracted from galena, a natural sul- phuret of lead, by roasting the ore in a reverbera- tory furnace, and afterwards smelting it along with coal and lime. Prop. The common properties of lead are too well known to require notice. Its sp. gr., in a state of absolute purity, is 11-38 to 1144, but or- dinary lead seldom exceeds 11-352 to 11-353. It melts at 612° Fahr.,(Crighton, 634° Kupfer,) and when very slowly cooled, crystallizes in octohe- drons. It is malleable and ductile, but devoid of elasticity. Lead is not dissolved by muriatic, sul- phuric, or the vegetable acids, unless by free con- tact with air, and then very slowly ; but nitric acid rapidly oxidizes it, forming a solution of nitrate of lead. Pure water, put into a leaden vessel, and exposed to the air, soon corrodes it, and dis- solves the newly-formed oxide; but river and spring water exerts no such influence, the carbon- ates and sulphates in such water destroying its solvent power. Many other neutral salts act in the same way. Among these, the most powerful preservatives are the phosphates, sulphates, chlo- rides, and iodides ; their power being in proportion to the relative insolubility of the compound which their acid is capable of forming with lead. It has been found that l-30,000th part of phosphate of soda or iodide of potassium, dissolved in dis- LEA 392 LEA tilled water, prevents its corrosive action. (Chris- tison.) The lead in contact with such water, gradually becomes covered with a superficial film of an insoluble salt of lead, which adheres te- naciously, and all further clnro-e ceases. Thus ordinary water, which abounds m mineral suits, may be safely kept in leaden cistern* ; but dis- tilled and rain water, and water that contains scarcely any saline matter, speedily corrode, and dissolve a portion of lead, when kept in vessels of that metal. When, however, leaden cisterns have iron or zinc fastenings or braces, a galvanic action is set up, the preservative power of saline matter ceases, and the water speedily becomes contaminated with lead. Water containing free carbonic acid*«also acts on lead ; and this is the reason why the water of some springs, kept in leaden cisterns, or raised by leaden pumps, pos- sesses unwholesome properties. Free carbonic acid is evolved during the fermentation or decay of vegetable matter, and hence the propriety of preventing the leaves of trees falling into water- cisterns formed of lead. The neglect of this pre- caution gave rise to the violent ravages of colic that are recorded to have visited Amsterdam about the middle of the last century. (Dr. Frouchin.) The eau de rose and the eau d'orange of com- merce, which are pure distilled water, holding in solution small quantities of essential oil, and are imported in leaden canisters, always contain a small quantity of lead, and deposite a sediment, which is not the case when they are kept in glass or incorrodible vessels. Lead and all its prepara- tions are poisonous. Uses. The uses of lead in the arts are well Known. Some of its preparations are employed in medicine, generally externally. Ant. Administer an emetic of sulphate of zinc or copper, and tickle the fauces with the finger or a feather to induce vomiting. Epsom or glauber sa^'.s, or alum, dissolved in water, tea, water gruel, 01 barley water, are the proper antidotes, and should be taken as soon after the poison has been swallowed as possible. When the symptoms are those of lead colic, the treatment recommended at page 206 should be adopted. In paralysis arising from lead, small doses of strychnia, brucia, and their preparations, should be cautiously ad- ministered. A symptom of poisoning by lead is the formation of a narrow leaden blue line, about one-twentieth of an inch thick, bordering the edges of the gums, attached to the neck of two or more teeth of either jaw. (Dr. Burton.) Tests. 1. The salts of lead placed on charcoal all yield, by the blowpipe, a butter of lead.—2. So- lutions of the salts of lead may be recognised by the color of the precipitates produced by the following tests:—o. Alkalis, alkaline carbonates, sulphatee, prussiate of potash, infusion of galls, gallic acid, and sulphuric acid, produce white precipitates.— 6. Chromate of potash, and iodide of potassium, yellow precipitates.—c. Hydrosulphates, sulphu- rets, and sulphureted hydrogen, black precipitates. —d. A piece of polished zinc precipitates metallic lead in an arborescent form, hence called the " leaden tree." *** A solid supposed to contain lead should be dissolved in, or treated with nitric acid, evaporated to dryness, and redissolved in water, when it may be tested as above. The susceptibility of sulphureted hydrogen as a tesl for lead ceases when the dilution reaches 500,000 times,—chromate of potash at 100,000 times,— carbonates of soda and potassa at 60,000 times, —potassa at 20,000 times,—prussiate of potash at 18,000 times,—iodide of potassium at 10,000 times,—and sulphate of soda at 5000 times. (Devergie, MeU Leg. ii. 779.) (See Ores.) LEAD, ACETATE. Syn. Neutral Ace- tate of Lead. Sugar of Lead. Acetated Ceruse. Superacetate of Lead. Acetate df. Plomb ; Sel de Saturne, (Fr.) Essigsaures Bleioxyd ; Bleizucker, (Ger.) Saccuarum Sa- turni, (P. L. 1720.) Cerussa Acetata, (P. L. 17c-.*--.) Plumbi Superacetas, (P. L. Ib09.) Plum- bi Saccharum. Plumbi Acetis. Plumbi Ace- tas, (P. L. E. and D.) Prep. (P. L) Oxide of lead in powder (litharge) lb. iv ^'j ! acetic acid and distilled water, of each 4 pints ; mix the fluids, add the oxide, dissolve by a gentle heat, strain, evapo- rate, and crystallize. The Edinburgh form is similar. II. (P. D.) Carbonate of lead 1 part; distilled vinegar 10 parts ; as last. Prop., Use, fyc. Acetate of lead should be completely soluble in distilled water, and when the lead is exactly precipitated with dilute sul- phuric acid, or by sulphureted hydrogen, the clear supernatant liquid should be wholly volatilized by heat without residue. Sulphuric acid poured on acetate of lead evolves acetic vapors. (P. L.) Its tests have been already noticed. Acetate of lead is powerfully astringent. Dose. 4 gr. to 2 grs., (Collier;) 1 or 2 grs. to 8 or 10 grs., twice or thrice a day, (Pereira;) 3 grs. to 10 grs. every 6 or 8 hours. (A. T. Thomson.) In pulmonary, uterine, and intestinal haemorrhage, colliquative diarrhoea, and phthisical sweats. It is usually combined with morphia or opium, or with acetic acid, to prevent it passing into the state of the poisonous carbonate in the 6tomach. Externally, as a collyrium, 10 grs. to water 8 oz., (A. T. Thomson,) as a lotion 20 grs., (A. T. Thomson,) 3j (Collier) to water 8 oz.; as an injection 40 grs. to rose water 8 oz. The lotion is cooling, and is common^ used in excoriations, &c. Acetate of lead is employed in calico printing. Remarks. Acetate of lead is usually prepared on the large scale by gradually sprinkling oxide of lead into strong vinegar, heated in a copper boiler rendered negative-electric by having a large flat piece of lead soldered within it, constant stir- ring being employed until the acid is saturated, when the mother liquors of a former process may be added, the whole heated to the boiling point, allowed to settle till cold, decanted, evaporated to about the sp. gr. 1*266 or 1*267, and then run into salt-glazed stoneware vessels to crystallize. The best proportions are, finely powdered litharge 13 parts, and acetic acid sp. gr. 1*0482 to 1*0484, 23 parts. These ingredients should produce about 384 parts of crystallized sugar of lead. A very slight excess of acid should be preserved in the liquid during the boiling and crystallization, to prevent the formation of any basic acetate, which would impede the formation of regular crystals. Subacetate of Lead, (Trisacetate of Lead, Tersubacetate of Lead, Diacetate of Lead,) is formed when a cold saturated solution of neutral LEA 393 LEA acetate of lead is mixed with one-tenth of its volume of liquor of ammonia, and set aside ; anhy- drous crystalline needles are deposited. A solution of this salt is formed when a solution of the neutral acetate is digested on finely powdered litharge, till the undissolved oxide turns white. By evapora- tion out of contact with air, small crystals may be obtained. Goulard's extract, and the liquor of diacetate of lead of the pharmacopoeia, are solu- tions of this salt. Sesquibasic Acetate of Lead is prepared by gently fusing the neutral acetate of lead till it spontaneously forms a white porous mass. By solution in water, evaporation to a sirup, and cool- ing slowly, crystals may be obtained. Sexbasic Acetate of Lead (sexsubacetate of lead) is a white crystalline precipitate, which forms when a solution of subacetate of lead is treated with liquor of ammonia. A hot saturated solution in water crystallizes on cooling. All the prece- ding acetates are soluble in water. The last two are neither employed in the arts nor in medicine. LEAD, ARSENIATE OF. Syn. Triarse- niate of Lead. Plumbi Arsenias. Prep. Grad- ually add a solution of acetate of lead to another of arseniate of soda. A white insoluble powder. LEAD, BROMIDE. Syn. Plumbi Bromidum. A white crystalline powder, sparingly soluble in water, formed by precipitating a solution of neutral acetate or nitrate of lead, with a solution of bro- mide of potassium. It fuses by heat into a red liquid, which turns yellow when cold. LEAD, CHLORIDE OF. Syn. Muriate of Lead. Patent Yellow. Horn Lead. Plumbi Corneum. Plumbi Murias. Plumbi Chloridum, (P. L.) Prep. Precipitate a solution of §xix of acetate of lead in 3 pints of boiling distilled water, with a solution of §vj of chloride of sodium in 1 pint of boiling water ; when cold wash and dry the precipitate, (P. L.) Remarks. Employed in the preparation of muriate of morphia. It is totally dissolved by boil- ing water, the chloride concreting almost entirely into crystals as the solution cools. (P. L.) LEAD, CHROMATE OF. In addition to the remarks on this article at page 192, it may be in- teresting to add that Anthon has found that wh*n hot solutions of equal equivalents of acetate of lead (190 parts) and chromate of potash (100 parts, both neutral and in crystals) are mixed, the yellow precipitate when dried is anhydrous; but when the mixture is made at ordinary temperatures, the precipitate has a paler yellow, and when dried con- tains 1 eq., or nearly b\ per cent, of water. (Buch. Rept.) It thus appears that the shades of color of chrome yellow may be varied without any for- eign addition. LEAD DUST. Syn. Pulvis Plumbi. By melting new lead, adding bruised charcoal, and diffusing the lead among it, then pounding and washino- awav the charcoal; used by potters. LE YD, FLUORIDE. A white powder form- ed by precipitating a solution of neutral acetate of lead with hydrofluoiic acid. It is very sparingly soluble in water. LEAD, GRANULATED. By melting new lead, pouring it in small stream, from an iron ladle with a hole drilled in its bottom, into a pail of wa- ter. Used to make solutions and alloys. 50 LEAD, IODIDE OF. Syn. Ioduret ot Lead. Plumbi Iodidum, (P. L.) Plumbi Iodu- retum. Prep. I. (P. L.) Acetate of lead fix water 6 pints ; dissolve ; iodide of potassium (pure) §vij; water 2 pints, dissolve. Add the latter solu- tion to the former, wash and dry the precipitate. II. (P. E.) Iodide of potassium and nitrate of lead, of each f j ; dissolve each separately in J pint of water, mix. collect the precipitate in a calico or linen filter, and wash it with water ; then boil it in 3 gallons of water, soured with pyroligneous (acetic) acid f f iij, let the solution settle (still keep- ing the liquid near the boiling point,) and decant the clear; as the water cools, the iodide will sub- side in brilliant golden yellow lamellae, or minute crystals. Remarks. The latter is the best process, as any adhering oxide of lead is dissolved out by the acid. " It is totally dissolved by boiling water, and, as it cools, separates in shining yellow scales. It melts by heat, and the greater part is first dissipated in yellow, and afterwards in violet vapors." (P. L.) The residuum is quite soluble in nitric acid. " 5 grs. of iodide of lead are entirely soluble (by boil- ing) in f3j of pyroligneous acid, diluted with f^iss of water ; and golden crystals are abundantly de- posited as the solution cools." (P. E.) Dose. \ gr. to 4 grs. or more, made into a pill, in enlargements of the cervical, axillary, and mesenteric glands, and in scrofulous affections and scirrhous tumors, as a deobstruent and resolvent. (See Ointment, Iodide of Lead.) LEAD, NITRATE OF. Syn. Plumbi ni- tras. Prep. (P. E.) Litharge fivss; diluted ni- tric acid 1 pint; dissolve by a gentle heat, and set the solution aside to crystallize. Used to make the iodide of lead, P. E. LEAD, OXIDES OF. Prep. I. (Dioxide. Suboxide. Gray oxide.) Prepared by heating dry oxalate of lead to a low red in a glass tube out of contact with the air. Dark-gray, nearly black, It is also formed on the surface of metallic lead long exposed to the air. II. (Oxide. Protoxide. Yellow oxide.) This oxide is prepared on the commercial scale by heat- ing the gray film or dross that forms on the surface of melted lead exposed to the air, until it acquires a uniform yellow color, when it is called " massi- cot;" when the heat is still further increased until it fuses or partially vitrifies, the term " litharge" is applied to it. It is obtained perfectly pure by expelling the acid from nitrate of lead, by exposing it to heat in a platinum crucible; or, still better, by adding ammonia to a cold solution of nitrate of lead until the liquid becomes faintly alkaline, washing the precipitate with cold water, drying, and heating it to moderate redness for one hour, as above. Pure protoxide of lead has a lemon- yellow color, and is the base of all the salts of lead. It may be obtained in a crystalline state by expo- sing a concentrated solution of it in caustic soda to the air for some months, (M. Houton Labadilliere ;) or, still easier, by mixing an aqueous solution of neutral acetate of lead with a great excess of liquor of ammonia, filtering, and exposing the liquid for a few hours in a well-corked bottle to the sun's rays. If the same solution be kept in the dark for some days, stellated crystals of basic ace- tate of lead, with five atoms of base, are deposited LEE 394 LEM instead of oxide. (W. Behrens.) See Litharge and Massicot. III. (Red oxide. Plumbeous suroxide. Red lead. Minium.) See Minium. IV. (Sesquioxide.) An insoluble reddish-yellow powder, formed by adding a solution of hypochlo- rite of soda to another of protoxide of lead in liquor of potassa. (Wiukelblech.) V. (Peroxide. Puce oxide. Plumbic suroxide.) Obtained by putting red lead into chlorine, or di- lute nitric acid ; or by fusing a mixture of protox- ide of lead and chlorate of potassa, at a heat a lit- tle below redness, and washing the powdered mass in water; or by transmitting a current of chlorine gas through a solution of neutral acetate of lead. LEAD, OXIDE, (HYDRATED.) Syn. Plumbi oxydum hydratum. Prep. (P. L.) Solu- tion of diacetate of lead 6 pints; distilled water 3 gallons; mix, and add liquor of potassa as long as a precipitate forms, avoiding excess ; wash well with water. Remarks. This is dihydrated oxide of lead. (Mitscherlich.) It is used in preparing disulphate of quinine. It is totally soluble in dilute nitric acid, (P. L.,) and in an excess of liquor of potassa. LEAD, OXY-IODIDE. Prepared by precip- itating subacetate of lead by iodide of potassium. LEAD, TANNATE. Syn. PurtviBi tannas. Prep. Precipitate a solution of acetate of lead with an infusion of galls ; wash and dry the precipitate. Astringent. Dose. 1 gr. and upwards made into a pill. *¥* Besides the preceding, various other prepara- tions of lead have been formed by chemists, but possess little importance in a practical point of view. (See Salts.) LEECHES. App. Leeches are most conveni- ently applied by means of a common pill box or a wine-glass. The part should be previously washed perfectly clean, and if covered with hair should be closely shaved. Sometimes leeches will not/readily bite: in such cases, allowing them to crawl over a piece of dry linen or calico, rolling them in porter, moistening the part with a little milk or sweetened milk, or drawing a little blood by a slight puncture or scratch, will usually make them bite freely. To stop the bleeding from leech- bites, various plans are adopted, among which cauterizing with nitrate of silver, tne application of creosote, and gen*le pressure for some hours, are most successful. (See Mattico.) Pres. Leeches are best preserved in water ob- tained from a pond, and occasionally changed ; when kept in spring water they soon die. The in- troduction of a hand, to which an ill-flavored med- icine or odor adheres, into the water in which they are kept, is often sufficient to poison them. The application of saline matter to the skin of leeches, even in very small quantities, immediately occa- sions the expulsion of the contents of the stomach: hence, a few grains of common salt are frequently sprinkled over them to make them disgorge the blood they have swallowed. According to Dr. Wagner, the taste of blood is necessary to render them fit for the purposes of reproduction. He re- commends the employment of two tanks, with the bottom of loam, clay, or turf, surrounded by an in- ner border of a similar substance, and an outer one of sand. Two such tanks should be kept—the one for leeches fit for medical use,—and the othei for breeding, or for such leeches as have been ap- plied. No leeches are to be taken fr< m the breed- ing tank until a year has elapsed after their having been applied and fed with human blood ; and their removal to the first tank should take place in Sep- tember or October, as by this time the breeding season is over. By this plan all leeches that have been applied are to be carefully restored to the breeding tank, without making them disgorge the blood they have swallowed. Leeches, to be able to grow and propagate, must, at least once a yar, receive a plentiful supply of living blood. These conditions can only be fulfilled by restoring those that have been already employed. All artificial methods of feeding by bladders or sponges of blood have been found to fail. (Allgemeine Anzeiger der Deutschen.) II. (J. R. Kenworthy.) Make pure clay, ren- dered plastic with water, into balls, or preferably, irregularly-shaped lumps, about 24 inches in di- ameter ; place them in a deep, square, wooden box, or a clean five-gallon keg. The leeches on being put in will creep down the sides of the balls, and there remain. No cover is necessary. Chang« the balls once a week. This method is simple and successful. (Ann. of Chym. and Pract Phar.) III. (Fee.) Lay 7 inches of a mixture of moss, turf, and charcoal in a marble or stone trough, over which place some small pebbles. At one end of the trough, and about half way up, place a thin shelf of stone or marble, pierced with small holes, on which put first some moss, or portions of the equisetum palustre, or horse tail, and on this a layer of pebbles to keep it down ; then pour in water sufficiently high just to moisten the moss and pebbles, put in the leeches, and tie over the mouth of the trough with a cloth. %* The frequent changing of the water in which leeches are kept is injudicious. Once a month in winter, and once a week in summer, is deemed sufficiently often by the large dealers, un- less the water becomes discolored or bloody, when it should be changed every day, or every other day. Clean pond water is preferable ; but where this cannot be got, clean rain water, that has been well exposed to the air, should alone be employed. LEMON JUICE, ARTIFICIAL. Syn. Suc- cus Limonum factitius. Prep. I. Citric or tar- taric arid 2\ oz.; gum 4 oz-; pieces of fresh lemon peel \ oz.; loaf sugar 2 oz.; boiling water 1 quart; macerate with occasional agitation till cold, and strain. Excellent II. Water 1 pint; sugar 1 oz.; essence of lemon 30 drops; pure acetic acid to acidulate. Inferior. Both are used to make lemonade. (See Ginger Beer.) LEMONADE. Syn. Lemon Sherbet. King's Cup. Prep. I. 2 lemons, sliced ; sugar 2 oz.; boil- ing water 1 pint. Very fine. II. White sugar 5 oz. ; yellow peel of 1 lemon; water 1 quart; squeeze in the juice of 3 lemons, macerate 2 hours, and strain. Used as a pleasant cooling beverage and astringent drink in fevers and putrid diseases. III. (Lemonade for icing. Lemon S'/erbet.) Yellow peel of 3 or 4 lemons, rubbed off with hard sugar, as described at p. 199, (art. Citrons;) loaf sugar 4 oz.; juice of 3 or 4 lemons; water 1 quart; LIG 395 LIM ice as wanted. Orangeade, or Orange Sherbet for icing, is made in the same way with oranges. LEMONADE, AERATED. Syn. Lemon- ade gazeuse. Limonadum aeratum. Prep. (P. Cod.) Water, charged with 5 times its volume of carbonic acid gas, 1 pint; sirup of lemon ^ij 5 mix. Delicious. LEMONADE, LACTIC. Syn. Limonadum lacticum. Prep. (Magendie.) Lactic acid 3j to 3iv ; snip ^ij; water 1 pint; mix. LEMONADE, PORTABLE. Prep. I. Tar- taric or citric arid 1 oz.; finely-powdered loaf su- gar 4 lb.; essence of lemon 20 drops; mix ; 2 or 3 teaspoonfuls make a very pleasant glass of extem- poraneous lemonade. II. Powdered sugar 4 lbs.; citric or tartaric acid 1 oz.; essence of lemon 2 dr.; mix well. As last. Very sweet and agreeable. LENSES. A description of these articles be- longs to a work on optics. It may, however, be useful to the chemical student to remark, that the Coddington or Stanhope lenses, which may now be bought at any of the opticians, neatly mounted and of great power, for a few shillings, will be found of the greatest service in examining minute crystals, precipitates, &c.; and for all ordinary pur- poses offer a cheap and efficient substitute for more complicated microscopes. LEROY'S VOMITIF-PURGATIF. Prep. Tartar emetic, in fine powder, 3j ; white wine 4 pint; sugar candy to color; dissolve, and label the bottle" Vomifif." Next dissolve 3vij of resin of jalap, in alcohol 4 P'nt; and label the bottle " Purga- tif." A popular nostrum in France, but its use requires caution. LEUCIN. (From Wof, white.) M. Bracon- not has given this name to a white pulverulent substance, obtained by the action of dilute sulphuric acid on muscular fibre. It combines with nitric acid, forming nitro-leucic acid. LEV1GATION. Syn. Levigatio, (Lat, from lavigo, to make smooth.) The process of redu- cing substances to fine powder, by making them into a paste with water, and grinding the mass up- on a hard smooth stone or slab, with a conical piece of stone having a flat, smooth under-surface, called a " mutter." Levigation is resorted to in the preparation of paints on the small scale, and in the elutriation of powders. LICHENIC ACID. A variety of malic acid found in some species of lichens. LICHEN IN. A species of starch extracted from Iceland moss. (Citraria Islandica.) LICHEN GUM. A strained infusion or de- coction of several species of lichen, evaporated to dryness. It resembles gum arabic: 1 cwt. of lichen coralloides yields 14 lbs. ; lichen esculentus, about 13 lbs. (Grav.) LIGHT, INSTANTANEOUS. (See Chlo- rate Matches, Congreves, Lucifers, &c.) LIGNINE. Pure woody fibre. It forms about 95°; of baked wood, and constitutes the woody por- tion of all vegetables ; its composition resembles starch, and by the action of oil of vitriol it is con- verted into dextrine, or sugar, and a new acid, (ligno-sulphuric acid.) Strong nitric acid dis- solves sawdust, and when the solution is diluted with water, a white insoluble powder is deposited, UFhich explodes when heated. (Robiquet) LIGNONE. A light inflammable fli...., t'-ju-JBi- ed with other products during the destructive dis- tillation of wood. It is a mixture of pyroxilic spirit and acetate of methule. (Berzelius.) LILACINE. Prep. (M. Meillet) The leaves, or, preferably, the seed vessels, of syringa vulgaris, are bruised, boiled twice with water, the decoction is evaporated to one half, basic acetate of lead ad- ded, the liquor evaporated to a sirup, and treated with calcined magnesia in excess; the whole is then dried, pulverized along with a little carbonate of magnesia, digested in water at from 86° to 104°, and the undissolved portion treated with boiling alcohol, sp. gr. 0-8295. The solution thus obtained is decolored with animal charcoal, filtered, evapo- rated to one half, and placed aside ; the lilacine crystallizes out as the spirit cools. Lilacine forms white fasciculi of acicular crystals, or prisms; it has a bitter taste, and is insoluble in water and many acids. (Jour, de Pharm., 1842, p. 25.) LIME. Syn. Oxide of Calcium. Calx, Calx viva, Calx recens usta, (Lat., from kalah, Ara- bic, to burn.) An oxide of calcium, obtained by exposing limestone or chalk, which are carbonates of lime, to a red heat. The substance thus obtained is called " quicklime," or " stone lime." When water is sprinkled on quicklime it becomes very hot, and crumbles down into a dry white powder, which is '* hydrate of lime," popularly known as " slaked" or " slacked lime." Oyster-shells, and other fish shells, are also converted into quick- lime by burning, which is then called " shell-lime," (calx e testis.) Milk of lime is slaked lime mixed up with water. Prop. Pure lime has a sp. gr. of about 2-3, and is soluble in 635 parts of water at 32°, but requires 77^ parts at 60°, 972 parts at 130, and 1270 parts at 212°, for its solution. (Wollaston.) A pint of water at 32° dissolves 13*25 grs.; at 60°, 11*6 grs; and at 212°, 6-7 grs. (Phillips.) Hence will be seen the propriety of employing cold water for the solution of lime. Its aqueous solution is caus- tic and alkaline. When strongly heated, lime be- comes phosphorescent, and emits a brilliant light; and on this account is sometimes employed for il- lumination, as in the Gurney, or Lime Light. Lime readily unites with the acids, and forms salts, nearly all of which may be made by directly neutralizing the acid with the hydrate or carbon- ate (chalk) of lime. They may also be made by double decomposition. Tests. 1. The alkaline carbonates, phosphates, oxalates, and sulphates, occasion white precipi- tates in solutions of lime. The precipitates occa- sioned by the first three tests are soluble in dilute nitric or muriatic acid ; that by the last is insolu- ble in those menstrua, but soluble in solution of salt, and not reprecipitated by dilute sulphuric acid. (Wackenroder.) Oxalate of ammonia or potassa is the most delicate test of lime. If the substance under examination be a solid, dissolve it in muriatic acid, filter, evaporate to dryness, re- dissolve in water, and test as above. All the solu- ble salts of lime tinge the flame of alcohol of an orange color. Uses. Lime is corrosive, antacid, and depilato- ry. It is employed to make lime water ; to ren- der the alkalis caustic, and to make several cal- careous salts. It is largely used to make moitnrs LIN 396 LIN and cements, in farming, &c. In large doses it is poisonous. The London College orders the lime of commerce in its Materia Medica, (calx recens usta,) but under the head of preparations of calci- um, (Preparata e calcio,) directs it to be prepared by burning chalk broken into pieces for 1 hour. LIME, CHLORIDE OF. Syn. Oxymuriate of Lime. Chloruret of Lime. Chloride or Chlorurf.t of Oxide of Calcium. Chlorite of Lime. Chlorinated Lime. Hypochlorite of Lime. Tennants' bleaching Powder. Calx Chlorinata, (P. L. and E.) Calcis Hypochloris. Prep. (P. L.) Hydrate of lime lb. j ; spread it in a proper vessel and expose it to an atmosphere of chlorine gas until it is saturated. Remarks. The above are the instructions of the London College ; but chloride of lime is never made on the small scale, as it can be purchased of the large manufacturer of better quality and cheaper than it could possibly be made by the druggist. On the large scale the chlorine is gener- ated in leaden vessels, heated by steam, and the gas, after passing through water, is conveyed by a leaden tube into an apartment built of silicious sandstone, and arranged with shelves or trays, con- taining fresh-slaked lime, placed one above an- other, about an inch asunder. The process must be continued for 4 days to produce a good article of chloride of lime. During this time the lime is occasionally agitated by means of iron rakes, the handles of which pass through boxes of lime placed in the walls of the chamber, which act as valves. Tennants, of Glasgow, are the largest manufac- turers of this article in the United Kingdom. The exact chemical constitution of chloride of lime is undetermined. Qual. " Pale grayish white; dry ; 50 grains are nearly all soluble in f ^ij of water, forming a solution of the density 1*027, and of which 100 measures, treated with an excess of oxalic acid, give off' much chlorine, and if then boiled, and al- lowed to rest for 24 hours, yield a precipitate which occupies 19 measures of the liquid." (P. E.) Good chloride of lime should contain 25 to 30§ by weight of chlo.ine. Uses. It is principally employed as an antisep- tic and disinfectant. An ointment of chloride of lime has been used in scrofula, (Cima,) and a lo- tion or bath, moderately dilute, is one of the clean- est and readiest ways of removing the itch, and several other skin diseases. (See Chlorine, Dis- infectants, Fumigation, &c.) LIME, SULPHURET OF. (See Calcium, SuLrHURET OF.) LINEN. Fruit stains, iron-moulds, and other spots on linen, may be removed by applying to the part, previously washed clean, a weak solution of chlorine, chloride of lime, spirits of salts, oxalic acid, or salts of lemons, in warm water, and fre- quently by merely using a little lemon juice. The part should be again thoroughly rinsed in clear warm water (without soap) and dried. Linen that has acquired a yellow or bad color by careless washing, may be restored* to its former whiteness by working it well in water to which some strained solution of chloride of lime has been added, ob- serving to well rinse it in clean water, both before and after the immersion in the bleaching liquor. Never attempt to bleach unwashed linen, and avoid using the liquor too strong, as in that case the linen will be rendered rotten. (See Ciiloro- metry.) The presence of cotton in linen fabrics may easily be ascertained by immersing for 2 or 3 minutes a small strip (a square inch, for instance) of the suspected cloth in a mixture of equal parts of hydrate of potassa and water, when strongly boiling, after which it must be taken out and pressed between the foldsiof blotting paper. By separating 8 or 10 threads in each direction, their color may be readily seen. The dark yellow threads are linen, the white or bright yellow ones are cotton. A vessel of silver, porcelain, or hard glass, must be employed to contain the alkali. This process is simple and certain. (Dr. Boettger.) LINCTUS. (From lingo, I lick.) Syn. Loch. Loiiocii. Lambative. Eclegma. Elegma. Elexis. Eclectos. Ecleitos. Illinctus. (In Pharmacy.) A medicine of the consistence of honey, intended to be licked off a spoon. This form of medicine is well adapted to females and children, but is not much used in England. (See Lohoch.) LINCTUS, ACID. Syn. Linctus Acidus. L. Acidi Muriatici. Prep. (Dr. Copland.) Honey of roses 3x ; sirup of red poppies 3ij ; muriatic acid 20 drops ; mix. Refrigerant. In putrid fever, sore LINCTUS, DEMULCENT. Syn. L. De- mulcens. Prep. Spermaceti and powdered traga- canth, of each ^ss; sirup of poppies, q. s. Dose. As last. LINCTUS, EXPECTORANT. Syn. L. Ex- pectorans. Prep. Oxymel of squills, sirup of al- thea, and mucilage of gum arabic, (thick,) of each, ^ss. In coughs, &c. Dose. A spoonful occasion- ally. LINCTUS OF BORAX. Syn. L. Bohacicus Prep. (Dr. Copland.) Spermaceti 3iiss; com- pound powder of tragacanth 3iij ; sirup of tolu §j ; borax, in fine powder, 3iiss ; conserve of roses 3v ; sirup of althea, to mix. In sore throat. Dose. As last LINCTUS OF CACAO. Syn. Creme de Tronchin. Prep. Cocoa-nut butter Jij; white sugar and sirups of capillaire and tolu, of each, 5j- Mix. LINCTUS OF IPECACUANHA. Syn. L. Ipecacuanha. Prep. (Dr. Copland.) Oil of almonds and sirup of lemons, of each, f 5j ; pow- dered ipecacuanha 6 grs. ; confection of hips §j i compound powder of tragacanth 3iij ; make a linctus. Expectorant. In irritating coughs, &c. LINCTUS OF NITRE. Syn. L. Potass* Nitratis. Prep. (Dr. Copland.) Powdered nitre 3iss ; honev of roses f Jj; oxymel f ^iss. Mix. LINCTUS, OILY. Syn. L. Oleosus. Prep. Oil of almonds or olives, oxymel of squills, and sirup of poppies, equal parts. Demulcent Dose. A teaspoonful ad libitum, in troublesome coughs, LINCTUS OF OPIUM. Syn. L. Opiatus. Prep. Sirup of poppies f^ij ; thick mucilage fjj; confection of hips jfiss ; laudanum 30 drops ; dilu- [ ted sulphuric acid 3j. Mix. To allay irritation. | LINCTUS OF ROSES. Syn. L. Rosa. Prtp. Confection of red roses ^'ij : diluted sulphuric acid 3j: compound tincture of camphor ^iss. Mix Anodyne and refrigerant. A spoonful occasionally LIN 397 LIN LINCTUS OF SQUILLS. Syn. L. Scilla. Prep. Oil of almonds §ij; oxymel of squills and honey, of each §j ; mix. Expectorant. As last. LINCTUS OF TURPENTINE. Syn. L. Stimulans. L. Terebinthina. Prep. (Recam- bier.) Oil of turpentine 3ij ; honey of roses §j to §iv ; mix. Dose. A teaspoonful night and morn- ing, followed by a draught of any weak drink. In worms. LINIMENT. Syn. Linimentum. (Lat, from lino, I anoint.) A semifluid ointment, or soapy application to painful joints, swellings, burns, &c. The term is also extended to various spirituous and stimulating external applications. A medicine of a thinner consistence, but similarly employed, is called an " embrocation." These terms are, how- ever, frequently confounded together, and are often misapplied. Liniments are applied by fric- tion with the fingers, or by laying a piece of linen rag dipped in them on the part. LINIMENT, ANODYNE. Syn. Linimentum Anodynum. Prep. (P. D.) Soap liniment f §iv; tincture of opium f §iij. (See Liniment of Opium.) LINIMENT, ACID. Syn. Lin. Acidum. Lin. Acidi Muriatici. Prep. (P. C.) Honey of roses §j ; muriatic acid 20 drops ; mix. LINIMENT, ALKALINE. Syn. Lin. Al- kalinum. Prep. (Plenck.) Liquor of carbonate of potassa §ij; olive oil %iv; yelks of 2 eggs; make a liniment. LINIMENT, DIURETIC. Syn. Lin. Diu- reticum. Prep. I. (Dr. Guibert.) Tinctures of squills, digitalis, and colchicum seeds, of each §ss; liquor of ammonia §ss ; camphorated oil Jj ; mix. II. (Dr. Calini.) Powdered squills 3j; gastric juice of a calf §ij ; vinegar of squills §ss ; mix. LINIMENT, ESCHAROTIC. Prep. Honey 4 oz. ; spirit of salt and verdigris, of each 1 oz.; mix. Used by farriers. LINIMENT for AMAUROSIS, (WARE'S.) Prep. Camphor liniment fj; solution of carbonate of potassa 3j ; mix. LINIMENT FOR BURNS. Syn. Liniment of Lime. Carron Oil. Lin. Calcis. Prep. (P. E.) Linseed (olive P. D.) oil and lime water, equal parts; mix, and agitate well. For severe burns. LINIMENT FOR INFLAMED GLANDS. Prep. Spermaceti ointment 8 oz.; camphor 1 oz.; oil of origanum 4 oz. ; mix. Used by farriers to promote the suppuration of inflamed glands. LINIMENT FOR THRUSHES AND CAN- KER. Prep. Tar 4 oz.; melt, and add verdigris 4 oz.; dissolved in spirits of salts f oz. Used by far- riers. LINIMENT, HUNGARIAN. Syn, Lin. Hungaricum. Prep. (Soubeiran.) Powdered cantharides and sliced garlic, of each 3j ; camphor, bruised mustard seed, and black pepper, of. each 3iv; strong vinegar fvj; rectified spirit %x\) ; macerate a week, and filter. Stimulant; irritant. LINIMENT OF AMBER, (OPIATE.) Syn. Lin. Succi.m Opiatum. Prep. (P. C.) Rectified oil of amber and tincture of opium, of each §ij ; lard ?;j ; mix. Anodyne and stimulant. LINIMENT OF AMMONIA. Syn. Ammo- mated Oil. Ammoniacal Liniment. Volatile Liniment. Oil and Hartshorn. Lin. Ammonia, (P. L. E. &, D.) Lin. Ammonia Fortius. Oleum Ammoniatum. Prep. (P. L.) Liquor of ammonia f i) (f 3ij» P- D.;) oil of olives f §ij; mix and agitate well. Stimulant and rubefacient Used in rheu- matism, lumbago, neuralgia, sore throat, spasms, bruises, &c. When the skin is irritable, more oil should be added, or it should be diluted with a little water. (See Liniment of Sesquicarbonate of Ammonia.) LINIMENT OF AMMONIA, (CAMPHOR- ATED.) Lin. Ammonia Camphoratum. Prep, (P. C.) Camphorated oil "%\x ; liquor of ammonia |iij ; mix well. Used as the last. LINIMENT OF AMMONIA, (COMP.) Syn. Dr. Granville's Counter-Irritant or Antidy- nous Lotion. Lin. Ammonia compositum. Prep (P. E.) Liquor of ammonia (sp. gr. 0-880) ffv; tincture of camphor f §ij ; spirits of rosemary f §j mix well. Counter-irritant, rubefacient, vesicant and cauterizing, according to the length of its ap plication; in rheumatism, cramp, neuralgia, dis eased joints, headache, &c. A powerful and speedy remedy. It may be diluted with a mixture of equal parts of the spirits of camphor and rose* mary. LINIMENT OF AMMONIA AND TUR PENTINE. Syn. Lin. Ammonia cum Terebin- thina. Prep. (Dr. Copland.) Liniment of am- monia (P. L.) ?iss ; oil of turpentine §ss ; mix. LINIMENT OF SESQUICARBONATE AMMONIA. Syn. Lin. Ammonia sesquicar- bonatis. Lin. Ammon. carbonatis. Prep. Solu- tion of the sesquicarbonate of ammonia, P. L. f §j ; olive oil §iij; mix, and agitate well. This resem- bles the liniment of ammonia, P. L., in its general properties, but it is much less active, owing to the alkali being carbonated. It is the "oil and harts- horn" and the " volatile liniment" of the sht 38. LINIMENT OF ARCEUS. Syn. Lin. Ar- cai. Compound elemi ointment. LINIMENT OF BELLADONNA. Syn. Lin. Belladonna. Prep. I. (Guy's H.) Soap liniment f gviij ; extract of belladonna §j ; mix. II. (Lin. belladonna cum calce. Cazenave.) Lime-water gviij ; oil of almonds §iv ; extract of belladonna 3ij ; mix. Both the above are excel- lent narcotics, stimulants, and resolvents, in vari- ous rheumatic complaints, affections of the skin and joints, tumors, &c. LINIMENT OF BITUMEN. Syn. Tar Liniment. Lin. Bituminis. Prep. (P. C.) Barba- does tar §iss; melt, and add liquor of ammonia Sss; mix well. Stimulant, irritant, and dispersive. LINIMENT OF CAJEPUT OIL. -Syn. Lin. Cajeputi. Lin. Cajeputi stimulans. Prep. (Dr. Copland.) Soap and compound camphor liniment, of each f §iss; oil of cajeput f §j ; mix. Stimu- "lINIMENT OF CAJEPUT, (ETHERE- AL.) Syn. Lin. Cajeputi ethereum. Prep. (Tortuel.) Camphor 3j; oil of cajeput 3ij ; sul- phuric ether Jj; mix, and keep it in a stoppered bottle in the cold. Very volatile. LINIMENT OF CAMPHOR. Syn. Cam- phor Liniment. Camphorated Oil. Oleum camphoratum, (P. D.) Lin. Camphora, (PL. & E ) Prep. (P- L.) Camphor 3j; olive oil ffiv; (jentiy heat the oil, add the camphor, cut small, and agitate until dissolved. The Dublin College orders only 4 the above camphor Stimulant, an- LIN 398 LIN odyne, and resolvent; in sprains, bruises, and rheumatic pains, glandular enlargement, &c. LINIMENT OF CAMPHOR, (COM- POUND.) Ward's Essence for the Headache. Lin. Camphora compositum, (P. L. & D.) Prep. I. (P. L.) Liquor of ammonia f^viiss; spirits of lavender 1 pint; distil off 1 pint, add camphor ^iiss, and dissolve. On the large scale this prep- aration is more conveniently made as follows:— II. Camphor (clean) 21 oz.; English oil of lav- ender 3$ oz.; liquor of ammonia 2| lbs.; mix, .close the vessel, and agitate occasionally until the camphor is dissolved. Powerfully stimulant and rubefacient. LINIMENT OF CANTHARIDES. Syn. Lin. Lytta. Lin. Cantharidis. Prep. I. (P. U. S.) Powdered Spanish flies 3j ; oil of turpen- tine f 3jj; digest 2 hours, and filter. II. (Collier.) Tincture of cantharides and soap liniment, equal parts; mix. Both the above are irritant and stimulant, but should be used cau- tiously, lest they produce strangury. LINIMENT OF COD-LIVER OIL. Syn. Lin. Olei aselli. Prep. (Dr. Brach.) Cod-liver oil Jj; liquor of ammonia §ss; mix. Resolvent, dispersive ; applied to glandular tumors. LINIMENT OF CROTON OIL. Syn. Lin. Crotonis. Prep. I. (Pereira.) Croton oil 1 part; olive oil 5 parts ; mix. II. (Collier.) Croton oil 3j; olive oil 3ij ; mix. Both the above are used as counter-irritants ; re- peatedly rubbed on the skin, redness and a pustu- lar eruption ensue. LINIMENT, GREEN. Syn. Lin. of Hem- lock. Lin. Viride. Lin. Conii. Prep. (Dr. Campbell.) Powdered camphor and extract of hemlock, of each, §j', compound spirit of ammo- nia §ij; oiive oil and liquor of ammonia, of each, §vj ; mix. LINIMENT OF IODINE. Syn. Lin. Iodi- nii. Prep. I. ^Dr. Manson.) Tincture of opium f§j ; tincture of iodine f3j. II. (Dr. Copland.) Soap liniment §j; iodine 8 to 10 grs.; dissolve. In scrofula, glandular en- largements, rheumatism, &c. LINIMENT OF LEAD. Syn. Lin. Plumbi. Prep. (Gaozey.) Acetate of lead 40 grs.; soft water lb-j ; olive oil lb. ss; mix, and agitate well. Astringent, refrigerant Useful in excoriations, especially when accompanied with inflammation. LINIMENT OF LIME. Syn. Lin. Calcis camphoratum. Prep. (VV.Cooley.) Camphorated oil §ij; lime water §j; mix, and agitate well. For burns, chiiblains, &,c. LINIMENT OF LIME AND OPIUM. Syn. Lin. Calcis Opiatum. Prep. (W. Cooley.) Lime-water and camphorated oil, of each, ^j ; ex- tract of opium 5 grs.; mix. For severe burns, to allay pain, &c. LINIMENT OF MERCURY. Syn. Mer- curial Liniment. Compound do. Lin. Hydrar- gyri, (P. L. 1809.) Lin. Hydrargyri composi- tum, (P. L. 1824, and since.) Prep. (P. L.) Camphor Jj; spirit of wine 3j ; sprinkle the latter on the former, powder, add lard and stronger mer- curial ointment, of each, %\x ; rub well together, then further add liquor of ammonia f giv; mix well. Excitant; resembles mercurial ointment, but is quicker in its operations. LINIMENT OF MURIATIC ACID. Syn Lin. Muriaticum. Lin. Acidi Muriatici. Prep. I. (Fr. H.) Olive oil ^ij; white wax 3ij ; dissolve by heat, cool, add balsam of Peru 3j ; muriatic acid 3ij ; mix well. An excellent application to chilblains before they break. II. (W. Cooley.) Olive oil ^iij; white wax and camphor, of each, 3ij; mix as last, then add mu- riatic acid f 3iij; mix well. Quite equal to the last and cheaper. LINIMENT OF MUSTARD. Syn. Lin. Sinapis. Whitehead's Essence of Mustard. Prep. I. (P. C.) Bruised mustard seed lb.ss; oil of turpentine lb. j ; camphor %iv ; digest Stimu- lant. A popular application in rheumatisms, chil- blains, &c. II. Flour of mustard 2 oz.; liquor of ammonia 1 oz.; mix, and add enough water to reduce it to a cream. Used by farriers to rub on the bellies of horses, &c, in inflammation of the bowels. LINIMENT OF NUX VOMICA. Syn. Lin. Nucis Vomica. Prep. (Majendie.) Tinc- ture of nux vomica f §j ; liquor of ammonia f 3ij; mix. LINIMENT OF OPIUM. Syn. Anodyne Liniment. Lin. Opii, (P. L. & E.) Lin. Saponis cum Opio, vel Lin. Anodynum, (P. D.) Prep. (P L.) Soap liniment f ^vj ; tincture of opium f ^ij; mix. An excellent anodyne in local pains, rheu- matism, neuralgia, sprains, &c. LINIMENT OF PHOSPHORUS. -Syn. Lin. Phosphoratum. Prep. (Hamb. Ph.) Camphor 10 grs.; phosphorus 6 grs.; oil of almonds §j; dis- solve with a gentle heat, cool, and add liquor of ammonia 10 drops; mix. LINIMENT OF SOAP. Syn. Soap Lini- ment. Opodeldoc Balsam of Soap. Compound Tincture of Soap. Balsamum Saponis. Tinc- tura Saponis composita. Tinctura Saponis cam- phorata. Lin. Saponaceum, (P. L. 1745.) Lin. Saponis compositum, (P. L. 1788 to 1824.) Lin. Saponis, (P. L. 1K16, P. E. & D.) Prep. I. (P. L.) Castile soap §iij ; camphor ^j ; spirit of rose- mary f fxvj ; mix and digest till dissolved. II. (P. E.) Castile soap ^iv; camphor ^ij ' oil of rosemary f3v; rectified spirit of wine 1 pint, and f§xij; mix and dissolve. Remarks. When Castile soap is employed, the liniment is apt to become gelatinous in cold wea- ther, it is therefore a*general plan with the drug- gists to substitute soft soap. The following for- mula is adopted by some wholesale druggists, and produces a very good article, though weaker than that of the pharmacopoeia:—Camphor, cut small, H lb.; soft soap 6 lbs.; oil of rosemary 2 oz.; rectified spirit of wine and water, of each, 34 gal- lons ; digest with occasional agitation for a week and filter. Soap liniment is stimulant, discutient, and lubri- cating, and is used in rheumatism, local pains, swellings, bruises, sprains, &c. LINIMENT OF SOAP AND LEAD. Syn. Lin. Saponis cum Plumbo, (P. C.) Soap liniment §ij ; liquor of diacetate of lead 3j ; mix. LINIMENT OF SOAP, (IODURETED.) Syn. Lin. Ioduretum Saponaceum. Prep. (Gui- bourt.) White soap 3x ; oil of almonds 3v ; melt together and add iodide of potassium 3j, dissolved in water 3j. LIQ 399 LIQ LINIMENT OF SOAP, (STIMULANT.) Syn. Lin. Saponis Stimulans. Prep. Soap lini- ment §iiss ; tincture of lytta §ss ; mix. LINIMENT OF SOAP, (SULPHURET- ED.) Syn. Lin. Sulphuro-saponaceum. Prep. (Jadelot.) Sulphuret of potassium 3-iij; soap lb.j; water q. s.; melt together, and add, olive oil lb.j; oil of thyme f 3j ; mix well. An excellent remedy for the itch and some allied skin diseases. LINIMENT OF SULPHUR AND SOAP. Syn. Lin. Sulphuris cum Sapone. Prep. (Lu- gol.) Soap giij; water §vj; dissolve by heat, and add flowers of sulphur Jiij. (See Lin. of Soap, Sulphureted.) LINIMENT OF TURPENTINE. Syn. Lin. Terebinthina. 'Prep. (P. L.) Soft soap f\j ; camphor Jj *, oil of turpentine f ^xvj; shake them together until mixed. Stimulant in lumbago and cholera. II. (P. L 1824.) Resin cerate lb.ss; oil of tur- pentine f giv; mix An excellent application to burns. LINIMENT OF TURPENTINE, (VITRI- OLIC.) Syn. Lin. Terebinthina Vitriolicum. Prep. (P. C.) Olive oil fx ; oil of turpentine f§iv ; oil of vitriol 3iij; mix well. In chronic affections of the joints and old sprains and bruises. LINIMENT OF VERATRINE. .Syn. Lin Veratria. Prep. (Brande.) Veratria 8 grs.; al- cohol ffss; dissolve and add, soap liniment f^ss. In neuralgic and rheumatic pains, gout, &c. LINIMENT OF VERDIGRIS. Syn. Mel jEgyptiacum, (P. L. 1746.) Unguentum jEgyp- tiacum, (P. L. 1720.) Oxymel ^Eruginis. (P. L. 1788.) Oxymel Cupr. Subacetatis, (P. D.) Li- nimentum JEruginis, (P. L. 1809, and since.) Prep. (P. L.) Powdered verdigris ^j j vinegar f^vij; dissolve, strain, add clarified honey %x'\v, and boil to a proper consistence. Stimulant, de- tergent, and escharotic. Applied to indolent ul- cers, especially of the throat, by means of a camel hair pencil, and diluted with water used as a gargle. *** Avoid swallowing it, as it will induce vomit- ing and excessive purging. LINIMENT, SIMPLE. Syn. Lin. Simplex. Prep. (P. E.) White wax §j; olive oil f §iv ; melt together and stir till cot Emollient; resembles spermaceti ointment in all except its consistence. LINIMENT, VERMIFUGE. Syn. Lin. An- thelminticum. Prep. Castor oil 32 grammes ; essential oils of wormwood and tansy, of each 15 grammes ; Dr. Peschier's ethereal tincture of pen- nyroyal buds 20 drops ; mix. Employed in fric- tions on the abdomen in cases of worms in chil- dren. Its activity may be still further increased by macerating a little bruised garlic in the oil of tansy (Jour, de Me"decine.) An excellent medi- cine. LINIMENT, WHITE. Syn. Lin. Album. LINIMENTUM TRIPHARMACUM. Prep. (P. L. 1746.) Lead plaster and olive oil, of each |iv ; melt, and add vinegar Jj; stir till cold. Cool- ing ; desiccative. LI PIC ACID. One of a new series of acids, discovered by Laurent, and obtained by the action of nitric acid on oleic acid. See Adipic Acid. LIQUEUR DE PRESSAVIN. Prep. Oxide at mercury freshly precipitated from a solution of nitrate of mercury, and cream of tartar, of each 1 oz.; hot water 1 quart; dissolve. For use add 2 spoonfuls of this liquor to 1 quart of wateB and take a wine-glassful (2 oz.) 3 or 4 times a day avoiding the use of common salt at the same time This is simply a solution of potassio-tartrate of mercury, and may be taken where the use of mer cury is indicated. LIQUEURS, (Fr.) Dilute alcohol, aromatized and sweetened. The French liqueuristes are pro- verbial for the superior quality, creamlike smooth- ness, and delicate flavor of their cordials. This chiefly arises from the employment of very pure spirit and sugar, and the judicious application of the flavoring ingredients. The French liqueuristes distinguish their cordials into two classes, viz.— waters, or liqueurs which, though sweetened, are I perfectly devoid of viscidity—and creams, oils, and balms, which contain sufficient sugar to impart to them a considerable degree of consistence. The first part of the process is the preparation of the aromatized or flavoring essences. These are usu- ally prepared by infusion or maceration in very pure spirit, at about 2 to 4 u. p., (sp. gr. 0-922 to 0-925,) placed in well-corked glass carboys, or stoneware bottles. The maceration is continued, with occasional agitation, for 4 or 5 weeks, when the aromatized spirit is drawn off, and either dis- tilled or filtered ; usually the former. These spirits are called, by the French, " infusions." The outer peel of cedrats, lemons, oranges, limettes, bergamottes, &c, is alone used, and is obtained either by carefully peeling the fruit with a knife, or by rubbing it off with a lump of hard white sugar. (See Citrons.) Aromatic seeds and woods are bruised by pounding before being submitted to infusion. The substances employed by the French to color their liqueurs are,—for blue, sulphate c. indigo nearly neutralized with chalk, or the juice of blue flowers or berries ;—fawn and brandy color, burnt sugar ;—green, spinage or parsley leaves digested in spirit; also by mixing blue and yellow ;—red, powdered cochineal, either alone or mixed with a little alum ;—violet, blue violet pe- tals, or litmus ;—yellow, an aqueous infusion of safflowers or French berries, or a spirituous tincture of turmeric. See Cordials. LIQUID COLORS, (Lacca fluida.) Prep. I. (Blue.) a. Dissolve litmus in water, and add 4 of spirit of wine.—b. Dilute Saxon blue or sulphate of indigo with water. If required for delicate work, neutralize the acid with chalk.—c. To an aqueous infusion of litmus add a few drops of vine- gar, till it turns full blue. II. (Purple.) a. Steep litmus in water and strain.—b. Add a little alum to a strained decoc- tion of logwood.—c. Add a solution of carmine (red) to a little blue solution of litmus or Saxon blue. III. (Green.) a. Dissolve crystallized verdigris in water.—6. Dissolve sap green in water, and add a little alum.—c. Add a little salt of tartar to a blue or purple solution of litmus, till it turns green.—d. Dissolve equal parts of crystallized verdigris and cream of tartar in water, and add a little gum arabic. Used as an ink for writing. IV. (Yellow.) a. Dissolve gamboge in water, and add a little gum arabic and alum. Used for ink, to stain paper, color maps, &c.—6. Dissolve LIQ 400 LIQ gamboge in equal parts of proof spirit and water. Golden colored.—c. Steep French berries in hot water, strain, and add a little gum and alum.—d. Steep turmeric, round zedoary, gamboge, or an- notto, in spirits of wine.—e. Dissolve annotto in a weak lye of subcarbonate of soda or potash. All the above are used by artificial florists. V. (Red.) a. Macerate ground Brazil in vine- gar, boil a few minutes, strain, and add a little alum and gum.—6. Add vinegar to an infusion of litmus till it turns red.—c. Boil or infuse powdered cochineal in water ; strain, and add a little alum and gum.—d. Dissolve carmine in liquor of am- monia, or in weak carbonate of potash water; the former is superb. Remarks. All the preceding, thickened with a little gum, are used as inks for writing, as colors to tint maps, foils, paper, artificial flowers, &,c, and to paint on velvet. Some of them are very beau- tiful. It must be observed, however, that those made with strong spirit do not mix well with gum, unless diluted with water. LIQUID COLORS, (for druggists' show- bottles.) Prep. I. (Blue.) a. Blue" vitriol 1 lb. ; water 1 gallon; dissolve.—b. To the last add alum 1 lb., and oil of vitriol to strike the color. Very dark.—c. Dissolve indigo in sulphuric acid, and dilute with water.—d. Dissolve pure Prussian blue in oxalic or muriatic acid,- aud dilute with water. (See Blue Inks and Writing-Fluids.) II. (Purple.) a. Verdigris 1 oz.; spirits of harts- horn 1 lb.; water 6 lbs.; dissolve.—b. Infusion of logwood 1 gallon ; spirits of hartshorn q. s.—c. Sugar of lead 3 oz.; powdered cochineal 1 dr.; water q. s.—d. Add sulphate of indigo, nearly neutralized with chalk, to an infusion of cochineal, till it turns purple. III. (Green.) a. Verdigris 4 oz.; water 2 quarts ; mix, and add oil of vitriol or nitric acid q. s.—6. Crystallized verdigris 4 oz.; strong vinegar 4 pint; dissolve, and dilute with water.—c. Add distilled verdigris and blue vitriol to a strong decoc- tion of turmeric.—d. Dissolve blue vitriol in water, and add nitric acid till it turns green. IV. (Red.) a. Dissolve carmine in liquor of ammonia, and dilute with water.—b. Digest pow- dered cochineal in spirits of hartshorn or solution of sal ammoniac ; and when colored, dilute with water. V. (Yellow.) a. Sesquioxide or rust of iron 4 lb.; muriatic acid 1 quart; dissolve and dilute with water.—6. To a strong decoction of Freuch berries add a little alum.—c. Dissolve gamboge or annotto in liquor of potassa ; dilute with water, and add a little spirit Orange or deep orange, depending on the quantity of alkali present. Remarks. All the above require filtering through paper placed in a glass funnel, and usually need a second filtration after being exposed to the light for some weeks. LIQUID, SHAVING. Syn. Liquid Soap. Prep. Best soft soap 1 lb.; rectified spirit of wine li pint.; mix. Used to raise a lather in shaving, by merely rubbing a few drops on Ine beard, and applying a little hot water with the finger or sha- ving-brush. Stronger than the esprit de savon and essence royal pour la barbe, sold for tRe same purpose. Some persons substitute proof spirit for •spirit of wine, and others use equal parts of water and spirit of wine as the menstruum. All answer well. LIQUODILLA. Prep. Yellow peel of 6 oranges and 6 lemons; brandy or plain spirit 1 gallon ; digest a week, filter, and add loaf sugar 4 lbs., dissolved in water 1 gallon, and the juice of the oranges and lemons which were peeled. Let it stand a month, and then bottle. A pleasant and refreshing cordial. LIQUOR. -Syn. Liqueur, (Fr) Liquob, (Lat, from liqueo, I become liquid.) This term is upplied in the London Pharmacopoeia to those aqueous solutions commonly, though improperly, called waters ; as, liquor of ammonia, (liquor am- monia,) liquor of potassa, (liquor potassa,) &.c, which are simple solutions of pure potassa and gaseous ammonia, and would therefore be more correctly and intelligibly called " solutions." (See Solution.) The term " liquor" has also been applied of late years to some concentrated preparations, more cor- rectly termed "fluid extracts," as they merely differ from good extracts in their less consistence, and from ordinary extracts in containing less starchy matter, albumen, and gum. There is also usually a little spirit added to them, to prevent de- composition. Liquors of this kind may be made of the finest quality, by the same processes that are required for the preparation of good soluble ex- tracts ; observing to stop the evaporation as soon as the consistence of treacle is acquired, and when cold, to add l-4th or l-5th, part of their then weight in rectified spirit of wine. The addition of 3 or 4 drops of the oils of cloves and mustard seed, dis- solved in the spirit, will secure them from any risk of moulding or fermentation ; in fact, with this addi- tion many of them will keep well without spirit, provided they be evaporated sufficiently, and kept in a cool place. The liquors which are merely concentrated infusions or decoctions, and which in their consistence do not even approximate to ex- tracts, may be made in the same manner as those preparations. (See Infusions and Decoctions, concentrated, and Essences.) The following formula? are introduced to illustrate the preparation of this class of medicines :— LIQUOR OF PALE CINCHONA. Syn Liquor Cinchona pallida. Prep. I. Pale cin- chona bark, bruised, 56 lbs.; boiling water, holding in solution 1 lb. of sulphuric acid, q. s.; macerate, with occasional agitatnon in a covered earthen vessel for 48 hours; press out the liquid, wash the residue with water, mix the liquors, strain, evapo- rate as rapidly as possible in earthenware, to ex- actly 6 lbs.; add rectified spirit 1 lb.; set it aside for a week, and decant the clear. Very rich in cinchona. It is 96 times as strong as the decoc- tion of cinchona, P. L., and 12 times as strong as the concentrated infusion or decoction of cinchona. This preparation resembles the liquor cinchonas pallidse sold by Battley, at 24s. per lb., whole- sale. II. Exhaust the bark as above, by maceration in 3 successive waters without acid, filter, evapo- rate the mixed liquors to 7 lbs., and proceed as be- fore. Inferior to the last, and loss rich in cin- chona. .Very thick ; scarcely liquid. LIQUOR OF ERGOT OF RYE. Syn. Es- sence of Ergot. Liquor Ergota. Liquo« LIT 401 LIT Secalis cornuti. Concentrated Infusion of Ergot of Rye. Prep. Ergot 3 lbs.; grind in a pepper-mill, add water 8 lbs.; macerate for 12 hours, add rectified spirit 2 quarts; macerate for a week in a corked bottle, press out the liquor, and filter. Contains ^th ergot, is 8 times as strong as the ordinary infusion, and 24 times as strong as the tincture of ergot of Apothecaries' Hall. *»* In the formula given at Ergot, the quantity of ergot is wrongly stated. LIQUOR OF SARSAPARILLA. Syn Fluid Extract of Sarsaparilla. Liquor Sar- za, &,c. Either the simple or the compound li- quor of sarsaparilla may be prepared by evapo- rating the corresponding decoction, carefully pre- pared, to a proper consistence, straining through flannel, and adding a little spirit. Jamaica sarza should be alone employed, as the other varieties, especially the Honduras, not only possess less virtue, and yield less extract, but are very liable to ferment, and get mouldy. LIQUOR OF TARAXACUM. Syn. Fluid Extract of Taraxacum. Do. do. of Dandelion. Liquor Taraxaci. Prep. I. Dried dandelion roots 28 lbs.; rinse them in clean cold water, to remove dirt, slice them small, macerate in enough cold watei to cover them, for 24 hours, press out the liquid, allow the fecula to subside, decant the clear, heat it to ltfO0 or 190°, to coagulate the al- bumen, filter while hot, and evaporate by steam, or preferably by a current of warm air, or in vacuo, till the liquid be reduced to 22 lbs. ; to this add rectified spirit of wine 6 lbs.; mix well, set it aside in a corked bottle for a week or a fortnight, and decant the clear from any sediment that may have formed. A very fine article. It represents an equal weight of the roots. II. lloat the expressed juice of dandelion to near the boiling point, strain, evaporate as last, to a proper consistence, then add \ or I of spirit of wine, and proceed as before. Very odorous, and pale colored; stronger, and preferable to the pre- ceding. (See Extract of Dandelion.) LIRIODENDRINE. A white crystalline substance, resembling boracic acid, found in the bark of the root of liriodendron tulipifera. It has a bitter taste, and is soluble in alcohol, and slightly so in water. LISBON DIET DRINK. Prep. Sliced sar- saparilla and china roots, of each ^j j the dried peels of 20 walnuts coarsely powdered ; antimony ^ij ; powdered pumice stone §j; water 10 pints; the antimony and pumice are to be tied in a cloth and boiled with the other ingredients, till the liquid be reduced to one half, when it must be strained. The above is said to be the original receipt for the Lisbon diet drink, but compound decoction of sarsaparilla is now universally used instead. LITHARGE. -Syn. Lytharge. Oxide of Lead. Protoxide of Lead. Semi-vitrified Oxide of Lead. Litharge, (Fr.) Glatte, Bleiglatte, (Ger.) Litargiro, (Ital.) Litar- gireo, (Span.) Lithargyrum, (P. E.) Plumbi Oxydum, (P. L.) Plumbi Oxydum Semi-vitreum, (P. D.) LlTHARGYRUS. MoLYBDENA, (Pliny.) AiSdpyvpov, (Hippocrates.) Litharge is prepared by scraping off the dross that forms on the surface of melted lead exposed to a current of air, (dross of lead, plumbum ustum,) and heating it to a full red to melt out any undecomposed metal. The fused oxide in cooling forms a yellow or reddish semi- crystalline mass, which' readily separates into scales; these when ground constitute the powder- ed litharge of the shops. Litharge is also prepared by exposing red lead to a heat sufficiently high to fuse it, and English litharge is obtained as a sec- ondary product by liquefaction, from argentiferous lead ore. The litharge of commerce is distinguish- ed by its color into Litharge of Gold, (Lithar- gyrum Auri,) which is dark colored and impurei and Litharge of Silver, (Lithargyrum Argenti,) which is purer, and paler colored. The dark co- lor of the former is chiefly owing to the presence of red lead. In grinding litharge about 1 lb. of olive oil is usually added to each 1 cwt, to prevent dust. Use. Litharge is employed in pharmacy, to make plasters and sevenl other preparations ot lead ; by painters as a ' drier' for oils, and for various other purposes in the arts. Pur. " Almost entirely soluble in dilute nitric acid. The matter thrown down from this solution by liquor of potassa is white, and is redissolved by excess of it." (P. L.) "50 grs. dissolve entirely, and without effervescence, in f^iss of pyroligneous acid; and the solution precipitated by 53 grs. of phosphate of soda, remains precipitable by more of the test." (P. E.) Both of the above solutions should be colorless. It is of great importance to the pharmaceutist to obtain pure litharge, as the slightest impurity will often color and spoil his lead plaster, (emp. plumbi,) and solution of diacetate of lead, (liq. plumbi diacetatis.) LlTHIA, (from Xtdttos, lapideus.) Syn. Oxide of Lithium. An alkali or alkaline earth, discov- ered in 1818, by M. Arfwedson, in a mineral called petalite. It has since been found in a few other minerals. Prep. (Berzelius.) Finely powdered petalite oi spondumene 1 part; fluor spar 2 parts; mix, add oil of vitriol 10 parts, and heat the mixture as long as acid vapors are evolved. The residuum must be dissolved in pure water of ammonia, boiled, fil- tered, the solution evaporated to dryness, and the dry mass heated to redness. The matter left is pure sulphate of lithia, from which pure lithia may be obtained by decomposing it by acetate of baryta, and by expelling the acetic acid from the filtered solution by heat. Prop., fyc. Lithia is caustic, alkaline, and spa- ringly soluble in water. It is distinguished from potassa and soda by its phosphate and carbonate being scarcely soluble in water,—from baryta, strontia, and lime, by forming soluble salts with sulphuric and oxalic acids,—and from magnesia, by the solution of its carbonate exhibiting an al- kaline reaction. Heated on platinum it tinges the flame of the blowpipe red. With the acids, lithia forms salts, most of which may be made by its direct solution in the former. LITHIC ACID. (See Uric Acid.) LITHIUM. The metallic base of lithia, obtained by Sir II. Davy by exposing lithia, oi oxide of lithium, to galvanic action. Its existence as a metal was so transient, that its properties could not be examined. It is white colored, like Sodium. LITHOCHOLIC ACID. A new acid di* LIT 402 LOB covered by Wohler in a biliary concretion. It possesses no practical interest. LITHOFELLIC ACID. An acid recently discovered by Gobel, in a biliary concretion. It forms the chief portion of the substances called be.zoar stones. It was obtained by digesting the calculus in boiling alcohol of 98$, evaporating, and redigesting the residue first in cold and then in boiling alcohol; from the latter solution the acid was obtained by 6low evaporation. Colorless and crystalline when pure, forming salts with the bases. LITHOGRAPHIC INK. Prep. I. Mastich in tears 8 oz.; shellac 12 oz.; Venice turpentine 1 oz.; melt together, add wax 1 lb., tallow 6 oz.; when dissolved, further add hard tallow soap, in shavings, 6 oz.; when the whole is combined, add lampblack 4 oz.; mix well, cool a little, and then pour it into moulds or on a slab, and when cold cut it into square pieces. II. (M. Lasteyrie.) Dry tallow soap, mastich in tears, and common soda in fine powder, of each 30 parts; shellac 150 parts; lampblack 12 parts; mix as last. Both the above are used for writing on lithographic stones. III. (Autographic.) a. White wax 8 oz., and white soap 2 to 3 oz.; melt, when well combined add lampblack 1 oz.; mix well, and heat it strong- ly ; then add shellac 2 oz.; again heat it strongly ; stir well together, cool a little, and pour it out as before. With this ink lines may be drawn of the finest to the fullest class, without danger of its spreading, and the copy may be kept for years be- fore being transferred. 6. White soap and white wax, of each 10 oz.; mutton suet 3 oz.; shellac and mastich, of each 5 oz.; lampblack 34 oz.; mix as above. Both the above are used for writing on lithographic paper. When the last one is employed, the transfer must be made within a week. Remarks. The above inks are rubbed down with a little water in a cup or saucer for use, in the same way as common water-color cakes, or Indian ink. In winter, the operation should be performed near the fire, or the saucer should be placed over a basin containing a little warm or tepid water. Either a steel-pen or camel's hair pencil may be employed with the ink. (See Lith- ography.) LITHOGRAPHIC PAPER. Prep. I. Starch 6 oz.; gum arabic 2j3z.; alum 1 oz.; make a strong solution of each separately, in hot water, mix, and apply it while still warm to one side of leaves of paper, with a clean painting-brush. When dry, a second and a third coat may be given ; lastly, press it, to make it smooth. II. Give the paper three coats of thin size, one coat of good white starch, and one coat of a solu- tion of gamboge in water; the whole to be applied with a sponge, and each coat to be allowed to dry before the other is applied. The whole of the so- lutions should be fresh made. Remarks. Lithographic paper is used to write on with lithographic ink. The writing may be trans- ferred by simply moistening the back of the paper, and evenly pressing it on the stone, when a re- versed copy is obtained, which may be used to print from, and will yield corrected copies, resem- bling the original writing or drawing. LITHOGRAPHY. (From Mos, a stone, and ypafttv, to write or draw.) The art of engraving on stone. Want of space must limit our notice of this beautiful art to the following remarks, which are inserted to explain the method of using litho- graphic crayons, ink, and paper. There are two modes of lithography in general use. For the one a drawing is made on the litho- graphic stone, with a lithographic crayon, (see Crayons, Lithographic,) or with lithographic ink, and when the design is dry, a very weak so- lution of oil of vitriol, or muriatic acid, is poured upon the stone, which acts by removing the alkali from the chalk or ink used to draw the design, and thus leaves them in a permanent and insoluble form. The acid also removes a very small portion of the surface of the stone occupied by the lights of the drawing, and renders it more absorbent. In the other method, the design is made on litho- graphic paper, (see the last article,) which paper, on being moistened, laid on the stone, and passed through the press, leaves its design on the stone, which is then acted on by acid as before described. To print from stones so prepared, water is thrown on them, and the roller, charged with printing ink, passed over them, when the paper is applied, and a copy is obtained by the action of the press. The same process must be had recourse to for each copy. The nature of the stone is such that it re- tains with great tenacity the resinous and oily sub- stances contained in the ink or crayon employed to form the design, and also absorbs water freely; this, combined with the peculiar affinity between resinous and oily substances, and their mutual power of repelling water, occasions the ink on the printing roller to adhere to the design, or resinous portion, and to leave untouched the lights or wa- tered parts of the stone. The stones are prepared by polishing in the ordinary way ; the style of work for which they are intended determining the de- gree of labor bestowed upon them. For crayon drawings, the surface should have a fine grain, but the finish of the stone must depend upon the de- sired softness of the intended drawing; for writing or drawing on in ink, the surface must receive a higher polish, and must be finished off with pum- ice stone and water. The best lithographic stones are obtained from Solenhofen, near Munich, and from Pappenheim, on the banks of the Danube. The white lias which lies immediately under the blue, near Bath, also yields good lithographic stones. LIVER OF ANTIMONY. Syn. Hepar An- timonii. A crude oxysulphuret of antimony, pre- pared by roasting crude antimony to a dull gray, and then melting it. Another preparation, made by mixing and melting common antimony with twice its weight of potash, is also called liver of antimony, and is used by farriers as a strong purgsr for grease in horses' heels. LIVER OF SULPHUR. Fused s.ilphuret of potassium. LOBELIANIN. This name has been given by Dr. Pereira to the butyraceous volatile oil ob- tained by distilling Indian tobacco 'lobelia inflata) along with water. LOBELIC ACID. This name has been given to the acid existing in decoction of lobelia. The decoction reddens litmus, and is precipitated bf several metallic salts. LOH 403 LOT LOBELINA. Syn. Lobelin. A soft brown substance, found by Colhoun in lobelia inflata. It is soluble in alcohol, and forms salts with the acids, and is said to resemble the nicotin of Berzelius. It may be obtained by the action of alcohol, evapora- tion, digestion of the residue in an arid, and subse- quent precipitation. LOBSTERS. The heavier fish are the best. When fresh, they have a lively color and pleasant smell. When boiled, the tail will be stiff, and pull up with a spring, if fresh. The cock lobster is pre- ferred, though smaller than the hen, and may be known by the narrow back part of his tail, and the two uppermost fins within it being stiff and hard ; those of the hen are softer and broader. LOCKSOY. Rice boiled to a paste and drawn into threads. Used to thicken soups. It is im- ported from China. LOCOFOCOS, (from loco foci, instead of a fire.) The American name for Congreve matches. From the following accident, these matches have given their name to the ultra-democratical party of America :—During a meeting of some of that party in 1834, at Tammany Hall, New York, the lamps suddenly became extinguished, when several per- sons present drew boxes of locofocos from their pockets and relighted them; since which time the word has been equally applied to matches and ultra-democrats. LOGWOOD. Syn. Bois de Campeche ; Bois Bleu, (Fr.) Blauholz, (Ger.) H.ematoxyli lignum ; Lignum Campechense ; Lignum Campe- chianum ; Lignum Campescanum ; Lignum Indi- cum ; Lignum Sappan, (Lat.) The wood of hama- toxylon campechianum, (Linnaeus.) Logwood is largely employed in dyeing and calico printing for the production of reds, violets, purples, blacks, drabs, &,c. It readily yields its color both to spirit and boiling water. The color of its infusion is a fine red, turning on the purple or violet; acids turn it yellow, and alkali? deepen it. It dyes stuff pre- viously mordanted with alum, of various shades of violet and purple, according to the proportions of the materials. By using solution of tin as the mor- dant, various shades of red, lilac, and violet, may be obtained. The addition of a little Brazil wood is commonly made to brighten the red. With a mordant of sulphate or acetate of iron, it dyes black ; and with the addition of a little sulphate of copper, grays of various shades. It is, however, chiefly employed in conjunction with gall nuts for dyeing black, to which it imparts a lustre and vel- vety appearance. Silk is usually turned through the cold decoction, but for wool the decoction is used either hot or boiling. Logwood is one of the cheapest and most easily managed of the dye stuffs. * LOHOCH, (ARAB.) -Syn. Lohock. Looch. Loch. Linctus. A medicine licked off a spoon. (See Linctus.) LOHOCH, COMMON. Syn. Lohoch com- mune. Prep. (P. E. 1744.) Oil of almonds and sirup of tolu, of each, Jj 5 powdered white sugar 3ij; mix. Demulcent; in coughs and hoarse- ness. LOHOCH, DEMULCENT. Syn. L. De- mulcens. Prep. I. (L. Tronchin.) Oil of almonds, sirup of capillaire, manna, and cassia pulp, of each 5ij ; powdered gum tragacanth 16 grs.; orange- flower water f fij ; mix. For coughs, &c. The above is the quantity for 2 days, which is as long as it will keep. II. Yelk of one egg ; oil of almonds 2 oz.; sirup of althasa 1 oz.; rose water 3 oz.; mix. In coughs and hoarseness. LOHOCH, EXPECTORANT. Syn. L. Ex- pectorans. Prep. (Zanetti.) Kermes mineral 4 grs.; manna ^yj; oil of almonds, sirup of squills, and sirup of senega, of each 3ij ; mix. Laxative, demulcent, and expectorant; in coughs, &c. LOHOCH, GREEN. Syn. L. Viride. White lohoch, colored with the sirups of saffron and violets. LOHOCH OF LINSEED. Syn. L. de Lino. Prep. (P. E. 1744.) Fresh linseed oil, and sirup of tolu, of each §j j sulphur and white sugar, of each 3ij; mix. ^ LOHOCH OF MANNA. Syn. L. de Man- na. Linctus demulcens et aperiens. Prep. (P. E. 1744.) Manna, oil of aln -Mids, and sirup of violets, equal parts; mix. Lax* Ave and de- mulcent. A good medicine in the coughs of chil- dren. LOHOCH OF OIL OF ALMONDS. Syn. L. Oleosum. Prep. I. (P. Cod.) Oil of almonds, powdered gum, and orange-flower water, of each 3iv ; sirup of althoea Jj ; mix. II. Oil of almonds, powdered gum, sirup of al- thasa, and rose water, of each 1 oz.; mix. Both are demulcent; in coughs, &c. LOHOCH OF SOAP. -Syn. L. Saponis. Prep. (P. E. 1744.) Castile soap 3j ; oil of almonds Jj ; sirup of tolu 5'ss '- niix. Demulcent. In coughs and hoarseness attended by indigestion. • LOHOCH OF SPERMACETI. Syn. L. Ce- tacei. Prep. (P. E. 1744.) Spermaceti 3ij ; yelk of one egg ; triturate together, then add oil of almonds %ps; sirup of tolu §j. A bland demul- cent. LOHOCH, PECTORAL. Syn. Fox lungs. Lou. e pulmonf. Vulpium. L. Pectorale. Prep. Spermaceti and Spanish juice, of each 8 oz.; wa- ter q. s. to soften the liquorice ; make a thin elec- tuary, and add honey 3 lbs.; oil of aniseed 1 oz.; mix well. A popular and excellent demulcent in coughs. It formerly contained fox lungs, but spermaceti is now substituted. LOHOCH, WHITE. Syn. L. Album. Prep. (P. Cod.) Jordan almonds 3ivss ; bitter almonds 3ss ; blanch by steeping in hot water and removing the skins, add white sugar §ss; gum tragacanth 15 grs. ; beat to a smooth paste, and further add, oil of almonds and orange-flower water, of each 3iv ; pure water f giv ; make a lohoch. A very pleasant demulcent in coughs, &c. Remarks. A spoonful of any one of the prece- ding lohochs may be taken ad libitum. LOTION. Sun. Lotion, (Fr.) Lotio, (Lat, from lavo, I wash.) In Medicine, a solution of medicinal substances in water, employed as an external application. Lotions may be made of any soluble medicaments that are capable of exert- ing their action by contact with the skin. Lotions have been divided into classes, as sedative, ano- dyne, stimulant, &c. Sedative and refrigerant lotions are commonly employed to alhiy inflamma- tion,__anodyne and narcotic lotions to relieve pain,__stimulant lotions to induce the maturation LOT 404 LOT of tumors, &c,—detergent lotions, to clean foul ulcers, &c,—repellent and resolvent lotions, to discuss tumors, remove eruptions, &c. Lotions are usually applied by wetting a piece of linen with them, and keeping it on the part affected, or by moistening the part with the fingers previously dipped into them. Lotions are more agreeable if made with rose water. LOTION, ACID. Syn. Lotio Acida. Prep. I. (Collier.) Strong nitric acid f^ss* water 1 pint; mix. Dr. Collier says that he has cured lepra of 14 years' standing by the use of this lotion, ac- companied by proper doses of the solution of cor- rosive sublimate, P. L. II. (Guy's H.) Nitric acid 38 drops ; water 1 pint. Used in mortification. III. (Copland.) Nitromuriatic acid 3j ; water f fxvj ; mix. In mortification and liver complaints. LOTION, ALKALINE. Syn. L. Alcalina. Pbep. (P. Cod.) Carbonate of potash 3'j '■> rose water 1 quart ; mix. Detergent, stimulant LOTION, ANTIPHLOGISTIC. Syn. L. Antiphlogistica. Prep. (Copland.) Solution of diacetate of lead (P. L.) 3vj ; liquor of acetate of ammonia §iv ; water 1 quart; mix. Refrigerant, sedative, repellent. Used to allay inflammation. LOTION,, ANTIPSORIC. Syn. L. Anti- psorica. Prep. (Cazenave.) Sulphuret of potas- sium 3j ; soap (soft) 3ij; water §viij; dissolve. An excellent remedy for the itch. It leaves but little smell behind, and does not soil the linen. LOTION, ASTRINGENT. Syn. L. astrin- gens. Prep. I. Alum 4 oz- i water 1 pint; dis- solve. II. Muriate of iron, or blue vitriol, 1 oz.; water 4 pint. Some use less water. The last is used for horses and cattle. LOTION, CAMPHORATED. Syn. L. Cam- phora***a. L. Plumbi diacetatis camphorata. Prep. L.luted solution of diacetate of lead, P. L., ^viij; spirit of camphor 3ij; mix, and shake well. Refrigerant and anodyne, employed in erysipela- tous inflammations, burns, contusions, sprains, ex- coriations, &c. LOTION, DISINFECTING. L. Disinfec- tans. L. Chlorinii. Prep. (Majendie.) Liquor of chloride of soda f §j ; water 4 pint II. Chloride of lime 3iij ; water 1 pint; dis- solve. Both are good washes for foul ulcers, the itch, the teeth, to sweeten the breath, and remove the smell of tobacco smoke, and for various similar purposes. LOTION, EVAPORATLNG. Syn. L. E*vap- orans. Prep. (Copland.) Sulphuric ether, rec- tified spirit of wine, and solution of acetate of ammonia, of each f^'*58! rose water f ^iiiss; mix. Some add solution of diacetate of lead (diluted) 3vj. Refrigerant, if allowed to evaporate by free exposure ; stimulant, if the evaporation is prevent- ed by covering the part with the hand. Useful in nervous headache, &c. LOTION FOR TENDER-MOUTHED HORSES. Prep. Powdered alum or borax 1 oz.; honey \ lb.; infusion of roses 1 lb. To be used with a syringe. LOTION FOR GREASE. Prep. 1. Sugar of lead \ lb.; vinegar 4 P'nt > water 14 pints; mix.—2. Alum 6 oz.; blue vitriol 1 oz.; water 1 quart.—3. Alum 1 oz.; oil of vitriol 1 dr.; water 1 pint.—4. Corrosive sublimate 4 oz* 5 spirits 0! salts 1 oz.; water 1 quart. The first three ara used when the horses' heels are inflamed and irritable; the last, when the discharge is very fetid. LOTION FOR INFLAMMATORY TU- MORS, &c. Prep. (A. T. Thomson.) Sal am- monia 3j ; rectified spirit f^j; soft water f^v ; mix, and dissolve. LOTION FOR SWELLED JOINTS, &c. Prep. (A. T. Thomson.) Opium 3ij; distilled vinegar f ^vj; triturate together. To allay pain. LOTION FOR OPHTHALMIA. Prep. (A. T. Thomson.) a. Sulphate of zinc and acetate of lead, of each 10 grs.; rose and elder-flower water, of each f ^iij ; mix. To be applied either alone or diluted with water, after locaP bleeding.—b. Sugar of lead 9 grs.; distilled vinegar f 3iij ; rectified spirit f3j; rose water f^vss; rrfix. Used in the acute stages. LOTION FOR GALLS, &c. Prep. 1. Vin- egar and spirit of wine, of each 4 oz.; sugar of lead 4 oz.; water 4 pint ; mix.—2. Soap liniment, and solution of acetate of ammonia, equal parts.— 3. Sal ammoniac 1 oz.; muriatic acid 3 dr.; wa- ter 1 pint. Used by farriers for saddle galls or warbles. LOTION FOR MANGE. Prep. 1. Corro- sive sublimate \ oz.; spirits of salt 4 °z- j water 1 quart.—2. Corrosive sublimate 1 dr.; sal ammo- niac 4 oz.; water 1 pint.—3. To the last add strong decoction of white hellebore 4 pint Used for mange in horses, cattle, and dogs, when sulphur ointment fails. LOTION FOR STRAINS. Sugar of lead 1 oz.; vinegar and water, of each 4 pint; cam- phorated spirit \ oz.; mix. Used by farriers. LOTION, GOWLAND'S. Prep. Blanched bitter almonds 1 oz.; blanched sweet almonds 4 oz.; beat to a paste, add pure water 1 pint, mix well, strain through a piece of coarse muslin, put it into a bottle, add corrosive sublimate in powder 10 to 12 grs., dissolved in a teaspoonful or two of spirit of wine, and shake well. Used as a cosmetic to improve the complexion; also as a wash for obstinate eruptions. For the latter purpose, the quantity of corrosive sublimate may be doubled; hut the weight given above should not be exceeded when the lotion is intended for a cosmetic. As a beautifier of the complexion, it is employed by wetting the skin with it, either by means of the corner of a napkin, or the fingers dipped into it, and it is then gently wiped off with a dry cloth. (See Cosmetics, and Lotion of Bichloride 0? Mercury.) LOTION, MERCURIAL. Prep. I. (Black wash. Black lotion. Lotio nigra. Aqua mer- curialis nigra. L. hydrargyri nigra. Mild phagedanic lotion. Aqua phagedanica mitis.) 1. Calomel 3j; lime water 1 pint; mix, and shake well. These are the usual proportions,—2. (Guy's H.) Calomel 3j ; lime water %vu]; mix as last. The bottle should be well shaken before the lotion is applied. Black wash is a favorite ap- plication to all kinds of syphilitic sores. II. (Yellow wash or lotion. Red do. Pha- gedanic do. Lotio flava. Lotio or aqua pha- gedanica. L. hydrargyri flava.) 1. Corrosive sublimate in powder 3ss; lime water 1 pint; mil, LOT 405 LOT and shake well. 2. (Guy's H.) Corrosive sub- limate 15 grs.; water 1 pint. As last. It should be well shaken before use. A common applica- tion to syphilitic and scrofulous sores. LOTION OF ALUM. Syn. L. Aluminis. Prep. I. (St. B. H.) Alum 3ss ; water 1 pint; dissolve. Astringent. Used for sore gums, nip- ples, &c. II. Alum and white vitriol, of each 3ij; vine- gar f §j ; water 1 pint; mix, and dissolve. Used for chilblains. LOTION OF AMMONIA, (ACETATE.) Syn. L. Ammonia acetatis Prep. (P. C.) Liquor of acetate of ammonia, rectified spirit of wine, and water, equal parts. Used in phlegmo- nous inflammation. LOTION OF AMMONIA, (MURIATE.) Syr. L. Salis ammoniaci. L. Ammonia muriatis. Prep. I. (Pereira.) a. Sal ammoniac ^j to §ij ; water f §xij ; dissolve. Spirit of wine f §iv is sometimes added. Used in contusions, ecchy- mosis, and cirsocele, when the skin is sound; in chronic tumors of the breast, white swellings, chronic affections of the joints, hydrocele, chil- blains, &c.—b. Sal ammoniac 3j to 3iv; water 1 pint; dissolve. In itch, ulcers, &c, and as an in- jection and eye-water. II. (Justamond.) Sal ammoniac §j; spirit of rosemary 1 pint. As above. III. (St. B. H.) Sal ammoniac fss ; water and spirit of wine, of each 1 pint. As above. LOTION OF AMMONIA, (OPIATED.) Syn. L. Ammonia opiata. Prep. (Dr. Kirkland.) Compound spirit of ammonia §iiiss ; tincture of opium Jss; water $iv; mix. Anodyne and stimulant. LOTION OF BELLADONNA. Syn. L. Belladonna. Prep. (Graefe.) Extract of deadly nightshade 3j ; diluted solution of diacetate of lead (P. L.) 1 pint; dissolve. Applied to tui *?rs, and glandular enlargements. LOTION OF BORAX. Syn. L. Boracic*. Prep. (Copland.) Powdered borax 3j; rose and orange-flower waters, of each ^iij j dissolve. A fragrant and effective application to sore gums, sore nipples, excoriations, &c. LOTION OF BICHLORIDE OF MER- CURY. Syn. L. Hydrargyri Bichloridi. L. Hydrargyri muriatis. Prep. I. (P. C.) Cor- rosive sublimate 16 grs.; muriatic acid 8 drops ; water f ^xvj; mix. II. (St. B. H.) Corrosive sublimate 24 grs.; water 1 pint; gum acacia %aa ; mix. III. (Lotio hydrargyri amygdalina, St. B. H.) Corrosive sublimate 10 grs.; blanched bitter al- monds fj; water 1 pint. All the above are used in obstinate eruptions. This resembles Gowland's lotion, and may be used for it. The ingredients are mixed in the same way. LOTION OF CYANIDE OF POTASSIUM. L. Potassii Cyanidi. Prep. (Cazenave.) Cy- anide of potassium 9ss: emulsion of bitter al- monds Jvj ; dissolve. (See Lotion of Prussic Acid.) LOTION OF ELDER-FLOWERS. Syn. L. Sambuci. Prep. (Ryan.) Infusion of elder- flowers 1 pint; spirit of camphor 5V"J j m'x- Emollient and anodyne. LOTION OF GALLS. Syn. L. Galla. Prep. (St. B. H.) Bruised galls 3ij; boiling water 1 pint; infuse an hour, and strain. As- tringent. An excellent application to sore nip. pies, or to strengthen them before suckling spirit of wine Sgiij may be advantageously added. and a like portion of water omitted. LOTION OF LIME. Syn. L. Calcis spirit- uosa. Prep. (P. C.) Spirit of wine giv; lime water ^viij ; mix LOTION OF LEAD, (ACETATE.) Syn. L. Plumbi acetatis. Prep. (Collier.) Sugar of lead 3j ; pure water, or rose water gviij ; dissolve. Astringent, refrigerant. Applied to excoriations, burns, sprains, contusions, &c. (See Solution of Diacetate of Lead.) LOTION OF MYRRH. Syn. L. Myrrha. Prep. (Dr. Kirkland.) Tincture of myrrh and lime water, equal parts ; mix. Applied to scor- butic ulcers and gums. LOTION OF MYRRH, (COMPOUND.) Syn. L. Myrrha composita. Prep. (P. C.) Honey of roses and tincture of myrrh, of each 3ij ; lime water §iiss ; mix. As last; also *.sed as * dentifrice. LOTION OF PRUSSIC ACID. Syn. I,. Acidi hydrocyanici. Prep. I. (Majendie.) Med- icinal prussic acid 3j to 3iv ; lettuce water f fxxxvj ; •» mix. II. (A.T.Thomson.) Medicinal prussic acid and rectified spirit, of each f 3ij ; distilled water f |viiss ; sugar of lead 16 grs. ; mix. III. (Sneider.) Medicinal prussic acid 3iss ; rectified spirit and water, of each f ^vj ; mix. Lotions of prussic acid have been employed to allay pain and irritation in various chronic skin diseases, especially scaly and itchy eruptions, and in cancer, with variable success. LOTION OF OPIUM. Syn. L. Opii. Prep. (St. B. H.) Opium 3iss ; boiling water 1 pint; triturate and strain. Used for painful and irritable LOTION OF SOAP. Syn. Liquid Soap. L. Saponis. L. Saponacea. Prep. (P. L. 1746.) Liquor of carbonate of potash 5SS j olive oil ^iv ; rose water §xij ; mix, and agitate well. Emollient. Chiefly used as a cosmetic. LOTION OF SPIRIT, (CAMPHORATED.) Syn. L. Spirituosa camphorata. Prep. (Ware.) Elder-flowers ^ss; camphor 3ss ; rectified spirit §iv ; macerate 24 hours, then press out the liquor. Stimulant and fragrant LOTION OF SULPHATE OF COPPER Syn. L. Cupri sulphatis. Prep. Blue vitriol 3j; powdered camphor §j; boiling water 2 quarts ; in- fuse in a close vessel 1 hour. For phagedenic ulcers. LOTION OF SULPHATE OF ZINC. Syn. L. Zinci. L. Zinci sulphatis. Prep. I. (P. C.) Sulphate of zinc 3ss ; water §viij; dissolve. A" tringe^pt Used in some chronic skin diseases, as a wash for loose flabby granulations, and for ulcers that discharge profusely, &c. II. (Collier.) Sulphate of zinc 3ij; water 1 pint; dissolve. As a counter-irritant in pains of the joints, periosteum, old sprains, &c. LOTION, RUBEFACIENT. .Syn. L. Rube- facient L. Antimonii Potassio-tartratis. Prep. I. (Pereira.) Emetic tartar 3j ; boiling water ^iss ; dissolve. Employed as a local irritant in- stead of the ointmei t LOZ 406 LOZ II. (Sir Wm. Blizard.) Emetic tartar 20 grs.; boiling water 5j j dissolve. Used to cleanse foul ulcers, to repress fungous growths and warts, in ringworm, &c. III. (Ger. H.) Emetic tartar 3j; water 1 pint; tincture of camphor §ss; mix. All the above are rubefacient and irrjtant The last one, diluted with twice or thrice its weight of water, is employed as a collyrium in chronic ophthalmia, and in specks on the cornea. LOTION, TAR Syn. L. Picis liquida. Prep. (Saunders.) Quicklime Jvj; water f gxlviij; slake, add tar §iv, and boil to one half. This liquid consists of a solution of pyrolignite of lime, and pyrogenous oil and resin. It may be ad- vantageously employed in various chronic skin diseases, especially those affecting the heads of children. LOZENGE. -Syn. Tablette, (Fr.) Tro- chiscus, (Lat) In Pharmacy and Confection- ary, a small round tablet, or flattened cylinder, chiefly composed of sugar, starch, or gum, and employed either as a simple demulcent or sweet- meat, or for the commodious exhibition of certain medicines. In the preparation of lozenges, the ingredients are first mixed, and well beaten into a stiff paste, which is next rolled out to a proper thickness, and cut into pieces of the desired shape by means of a small cylinder or punch of steel or tin. The newly-formed lozenges are then dried by placing them on an inverted sieve in a dry and airy situation, and frequently turning them, until they become hard and brittle; observing carefully to preserve them from the dust. To prevent the mass from sticking either to the fingers or utensils, a little powdered starch, or a very little olive oil scented with the same aro- matic as that contained in the lozenges, may be used. Mucilage of gum arabic, or gum tragacanth, or the strained white of eggs, are the substances usually employed to make the pulverulent materials adhere together. All the ingredients should be re- duced to a fine powder before mixing. Lozenges made by melting one half of the sugar in a brass or iron pan, lipped to the right, with a little flavored water, then adding the other half of the powdered sugar, previously warmed, and dragging small portions of the grouty mass out by a wire, so as to fall on a stone or metal slab or plate, rubbed with a little powdered starch or sweet oil, are called " drops" by the con- fectioners, and " pastilles" (pastilli) by the French. (See Drops, Confectionary.) Ambergris is the most suitable perfume for lozen- ges and tablettes for the mouth. LOZENGES, ANTIMONY. Syn. Morsuli Stibii Kunkelii. Trochisci Antimonii. Prep. (P. Cod.) Prepared sulphuret of antimony and powdered cardamom seeds, of each ^j; blanched almonds §ij; powdered white sugar ^xiij; powder- ed cinnamon 3iv *, mucilage of tragacanth q. s.; mix as above, and divide into lozenges of 15 grs. each. One of the best modes of exhibiting sul- phuret of antimony as an alterative. LOZENGES, BARK. -Syn. Tro. Cinchona. Prep. (P. Cod.) Powdered cinchona §ij; do. cin- namon 3ij; do. white sugar ^xiv ; mucilage of gum tragacanth q. s.; mix as above, and divide into 16 gr. lozenges. Tonic. LOZENGES, BISMUTH. Syn. Tro. Bibmd thi. Prep (Trousseau.) Trisnitrate of bismuth 3ij ; white sugar Jiss; mucilage to mix. For 120 lozenges. Tonic and antispasmodic. 1 to 3, sucked 2 or 3 times daily, in dyspepsia, &.c. LOZENGES, BORAX. -Syn. Tro. Boracis. Powdered borax ^ss ; do. white sugar ^j ; mucilage of gum tragacanth to mix. For 60 lozenges. LOZENGES, CALOMEL. Syn. Tro. Calo- melanos. Prep. (P. Cod.) Calomel 3j; powdered sugar 3xj; mucilage of tragacanth to mix ; divide into 12 gr. lozenges. Alterative. A simple way of introducing mercury into the system. During their use, salt food and acid liquors should be avoided. LOZENGES, CATECHU. Syn. Tro. Cate- chu. Prep. I. (Tro. de terra Japonica, P. E. 1744.) Powdered catechu ^ ij ; do. tragacanth ^ss; do. white sugar §xij ; rose water to mix. II. (Tro. Catechu et Magnesia, P. Cod.) Mag- nesia §ij ; powdered catechu 5J > do. sugar §xiij; mucilage of gum tragacanth made with cinnamon water, q. s. to mix. III. (Cachou Lozenges.)—a. Powdered catechu 3 oz.; sugar 12 oz.; mucilage of gum tragacanth to mix.—b. (Cachou a I'Ambre gris.) To the last add ambergris 8 grs., or a sufficient quantity of the essence or tincture.—c. (Cachou Musque.) The same, with musk 8 grs.; or essence q. s.—d. (Cachou a lafleur d'Oranges.) The same, with essence of neroli 8 drops.—e. (Cachou a la Rose.) The same, with otto of roses 6 drops.—■/. (Cachou a la Violette.) The same, with powdeied orris root (best) \ oz.; or essence of violets 1 oz.;—g. (Cachou d la reglisse.) Catechu 2 oz.; pure ex- tract of liquorice 1 oz.; sugar 10 oz.; mucilage of tragacanth to mix.—h. (Cachou a la Canelle.) Catechu 3 oz.; powdered cinnamon \ oz.; sugar 1 lb.; mucilage of tragacanth to mix.—i. (Cachou Aromatique. Cachou Aromatise.) Powdered catechu 3 oz.; oil of cinnamon 15 drops; oil of cloves 2 drops ; essence of ambergris 4 dr.; pow- dered sugar 1 lb.; mucilage of tragacanth made with rose or orange-flower water, q. s. to mix. Remarks. All the above are taken in diarrhoea, in relaxation of the uvula, in irritation of the larynx, and as cosmetics to fasten the teeth, and disguise a stinking breath. The one containing magnesia (No. II.) is also sucked in dyspepsia and heartburn. LOZENGES, CAYENNE. Syn. Tro. Cap- sici. Prep. I. Powdered sugar 1 lb.; mucilage of tragacanth q. s. to mix; add essence, tincture, or vinegar of cayenne, or a little soluble cayenne pepper dissolved in water to flavor. II. (Acidulated.) To the last add tartaric acid 4 oz. Both are used in dyspepsia, and to promote digestion and create an appetite. LOZENGES, CHALK. Syn. Heartburn Lozenges. Tro. Creta. Tro. Cardialgici. Prep. (P. E.) Powdered prepared chalk ^iv; do. gum arabic §j; do. nutmeg 3j; do. white sugar §vj; beat to a mass with water (rose or orange flower) and cut into lozenges. Antacid, absorbent, and astringent. 3 or 4 sucked ad libitum in heartburn, dyspepam, diarrhoea, acidity of the stomach and bowels,«&c. A simple and excellent remedy. LOZENGES, CHARCOAL. Syn. Tro. Cah- bbnib. Prep. I. (P. Cod.) Finely powdered pre- LOZ 407 LOZ pared charcoal %\v ; do. white sugar ^xij ; mucilage to mix. Have been given with advantage in diar- rhoea, cholera, and dyspepsia. II. (Tro. Carbonis cum Chocolata. M. Cheval- lier.) Charcoal as above, and white sugar, of each ^j; chocolate § iij ; mucilage of gum tragacanth to mix. Nutritious. LOZENGES OF CHLORIDE OF LIME. iSyn. ^ro. Calcis chloridi. Tro. Calcip chlo- rinata. Prep. Chloride of lime, dry and in fine powder, \ oz.; white sugar £ lb.; mucilage of tra- gacanth to mix. Used to sweeten the breath and whiten the teeth. They will not keep long. LOZENGES, CHING'S. Prep. I. (Yellow.) Saffron 4 oz.; boiling water 1 pint; infuse, strain, add calomel 1 lb.; powdered white sugar 28 lbs.; mix well, then make a mass with tragacanth mu- cilage, and divide into 7000 lozenges. %* Too much care cannot be taken to thoroughly incor- porate the ingredients, so that the calomel may be equally diffused through the mass. Dose. 1 to 6 over night, as a vermifuge, followed by an equal number of the brown lozenges (see below) next morning, fasting. Each lozenge contains 1 gr. of calomel. II. (Brown.) Calomel 7 oz.; resinous extract of jalap 34 lbs.; white sugar 10 lbs.; mix as last, with 'mucilage of tragacanth, and divide into 6125 lozenges. Each lozenge contains 4 gr. of calomel. LOZENGES, CINNAMON. Syn. Tro. cin- Namoni. Prep. I. Finely powdered cinnamon 4 oz.; do. sugar 12 oz.; mucilage of gum tragacanth to mix. II. Finely powdered lump sugar 7 lbs.; oil of cinnamon (cassia) J oz.; mucilage of gum traga- canth q. s. Stomachic. Cassia lozenges are made Sn the same way. LOZENGES, CITRATE OF IRON. Syn. Tro. Ferri citratis. Prep. (Beral.) Ammonio- citrate of iron 3j ; water ^ss ; dissolve, add sugar Jiiss ; evaporate to dryness, powder, make a mass with mucilage q. s., and divide into 15-gr. lozen- ges. Tonic. LOZENGES, CLOVE. Syn. Tro. Caryo- PHYLLi. Prep. I. Powdered cloves 2 oz.; sugar 3 lbs.; mucilage of gum tragacanth to mix. Divide into 150 lozenges. II. Powdered white sugar 7 lbs., do. gum tra- gacanth 2 oz.; oil of cloves 4 oz- > m'x with rose water. Stomachic. Both are used as restoratives after fatigue, added to chocolate to improve its fla- vor or render it stomachic, and sucked to sweeten the breath. LOZENGES, COPAIBA. Syn. Tro. Co- paiba. Prep. Lump sugar 1 lb.; balsam of co- paiba 1 oz.; oil of peppermint 20 drops ; mix with mucilage. LOZENGES, COUGH. Syn. Tro. Anti- catarrhales. Tablettes de Tronchin. Prep. (P. Cod.) Powdered gum arabic ^viij ; oil of ani- Beed 6 drops ; extract of opium 12 grs.; Kerme's mineral 3j ; pure extract of liquorice §ij; white sugar ^xxxij ; mix with water, and divide into small lozenges. LOZENGES, CROTON OIL. Syn. Tro. Crotonis. Prep. (Soubeiran.) Croton oil 5 drops ; powdered starch 3j ; do. white sugar 3j; choco- late 3ij; mix and divide into 30 lozenges; 5 or more generally prove cathartic. . LOZENGES, EMETIC. Syn. Tro. Emetine emetici. Prep. (Majendie.) Impure or colored emetina 32 grs.; or pure emetina 8 grs.; whit*. sngar ?ij ; mucilage to mix; divide into 64 loz- enges, 1 for a child, and 4 for an adult, as an emetic. LOZENGES, GINGER. Syn. Tro. Zingi- bers. Prep. I. Finely powdered Jamaica ginger 1 oz.; white sugar 1 lb.; mucilage of tragacanth to mix. II. (Soubeiran.) Powdered ginger Jj ; white sugar gvij ; mucilage to mix; divide into 15-gr. lozenges. Both the above are stomachic. Useful in flatulency and dyspepsia, and to create an ap- petite. LOZENGES, GOLD. Syn. Tro. Auri. Tro Sodii auro-chloridi. Prep. (Chrestien.) Soda muriate of gold 4 grs.; white sugar ^j; mucilage of tragacanth to mix. For 60 lozenges. In scrofula, cancer, &c, 1, or at most 2 lozenges for a dose. LOZENGES, GUM. Syn. Tro. Acacia, (P. E.) Tro. Gummosi. Prep. (P. E.) Powdered gum arabic §iv ; do. starch §j; do. white sugar lb.j ; mix with rose water, and divide into lozen- ges. The Paris Codex substitutes orange flower for rose wafer. Pectoral; demulcent. Useful to allay tickling coughs. LOZENGES, GUM TRAGACANTH. -Syn. Tro. Gummi Tragacantha. Prep. (P. E. 1744.) Sugar lb.j; compound tragacanth powder §iij ; rose water §iv ; mix. Similar to the last. LOZENGES, HEARTBURN. Syn. Tablet- tes cardialgie. See Lozenges, Chalk and Mag- nesia. LOZENGES, ICELAND MOSS. Syn. Tro. Lichenis. Prep. Iceland moss gelatin, dried and powdered, ^ij ; sugar §iv ; gum acacia 3iss ; water q. s. to mix. Resemble gum lozenges. LOZENGES, INDIAN HEMP. Syn. Tro. Cannabis. Prep. (M. Ebriard.) Extract of In- dian hemp 12 grs.; sugar §iij ; mucilage of traga- canth to mix ; divide into 144 lozenges. (See Ex- tract of Indian Hemp.) / LOZENGES, IPECACUANHA. Prep. I. (Tro. Ipecacuanha, P. Cod.) Powdered ipecacu- anha ^j 5 white sugar lb. iv.; mucilage of gum tragacanth to mix; divide it into 12-gr. lozenges. Each lozenge contains \ gr. of ipecacuanha. Produces, if properly made, 1920 lozenges. II. (T. Ipecac, cum chocolata, P. Cod.) Choc- olate (a la vanille) fxij; liquefy by a gentle heat, add powdered ipecacuanha §j ; mix perfectly, and form it into 12-gr. lozenges, while warm. Both the above are pectoral and expectorant, and useful to allay tickling coughs, hoarseness, Sec. LOZENGES, KERMES. Syn. Tro. Ker. metis. Prep. (P. Cod.) Kermes mineral 3ij; pow- dered white sugar §xvij ; do. gum acacia Jj; or- ange-flower water f f j; mix, and divide into 12-gr lozenges. Each lozenge contains one-sixth of a gr. of Kermes mineral. Diaphoretic and expec- torant LOZENGES, LACTATE OF IRON. Syn Tro. Ferri Lactatis. Prep- (M. Cap.) Lactate of iron 3ss; white sugar 3vj ; mucilage of gum tragacanth q. s.; mix, and divide into 30 lozenges. Tonic. Useful in debility accompanied with a diseased state of the organs of digestion. LOZ 408 LOZ LOZENGES, LACTIC ACID. -Syn. Tro. Acidi Lactici. Prep. (Majendie.) Lactic acid 3ij; powdered sugar fj; oil of vanilla 4 drops, (or essence 3ss;) mucilage of tragacanth q. s.; mix, and divide into 3ss lozenges. (See Lactic Acid.) LOZENGES, LACTUCARIUM. Syn. Tro. Lactucarii, (P. E.) Prepared with lactucarium in the same manner as the opium lozenges, P. E. Each of these lozenges contains one-sixth to one- seventh of a grain of lactucarium. Anodyne. Used to allay tickling coughs. LOZENGES, LEMON. -Syn. Tro. Limonis. Prep. I. (P. Cod.) Essence of lemon 3j; white sugar §xij ; make them into drops, (pastilles,) as before directed, or into lozenges with mucilage of gum tragacanth. II. Acidulated, a. (Tro. Acidi Citri, P. Cod.) Citric arid 3iij; white sugar fxvj; essence of lem- on 16 drops; mucilage of tragacanth q. s.; mix, and divide into 12-gr. lozenges, b. (Tro. Acidi Tartarici, P. E.) Tartaric acid 3ij ; white sugar 3;viij ; essence of lemon 10 drops; mucilage to mix. The last two may be made into drops in- stead of lozenges, when they will form ' acidula- ted lemon drops' Lemon lozenges and drops are agreeable sweetmeats, and those that are acidu- lated, very useful to promote expectoration, (" cut the phlegm," as it is commonly called,) in coughs, LOZENGES, LIQUORICE. Syn. Black Lozenges. Tro. Glycyrrhiza, (P. E.) Tro. Glycyrrh. Glabra. Tro. Bechici Nigrl. Prep. (P. E.) Extract of liquorice and gum acacia, of each, 5vj 5 white sugar lb.j ; dissolve in water, evaporate to a paste, and form into lozenges. Pectoral; demulcent Useful to allay tickling coughs, and remove hoarseness. LOZENGES, MAGNESIA. Syn. Tro. Magnesia, (P. E.) Prep. Carbonate of magne- sia §vj; powdered white sugar fiij ; oil of nutmeg 20 drops ; mucilage of tragacanth to mix. Useful in heartburn and indigestion. The confectioners generally omit the nutmeg, and use only half the above quantity of magnesia, and make their mu- cilage with rose or orange-flower water. It is also an improvement to use calcined magnesia, which is about twice as strong as the carbonate, and consequently less need be employed. LOZENGES, MANNA. Syn. Tro. Manna. Prep. (Van Mons.) Powdered tragacanth 3j ; do. white sugar fxij ; manna §iij ; orange-flower wa- ter to mix. LOZENGES, MARSHMALLOW. Syn. Tablettes de Guimauve. Tro. At.thaa. Prep. (P. Cod.) Powdered marshmallow root ^ij ; do. sugar f xiv > mucilage of tragacanth made with orange-flower water q. s.; mix, and divide into lozenges. Demulcent and expectorant. Useful to allay the irritation in cough, &c. LOZENGES, MORPHIA. Syn. Tro. Mor- phia. Prep. (P. E.) Muriate of morphia 3j ; tincture of tolu ffss; powdered white sugar fxxv; dissolve the muriate in a little warm water, mix it with the tincture and the sugar, make a mass With mucilage of gum tragacanth, and divide into 15-gr. lozenges, each of which will contain about one-fortieth of a grain of muriate of morphia. Used as opium lozenges, but are pleasanter. The Inorphia lozenges of the shops generally contain one twenty-fourth of a gr. of muriate of morplihv (Pereira.) LOZENGES, MORPHIA AND IPECAC- UANHA. -Syn. Tro. Morphia ft Ipecacuan- ha. Prep (P. E.) To the last, udd ipecacuanha 3j ; each lozenge contains about one-fortieth of a gr. of muriate of morphia, and one-thirteenth of a gr. of ipecacuanha. Very u^ful to allay tickling coughs. LOZENGES, NITRE. Syn. Tro. Nitrl Tro. e Nitro, (P. E. 1783.) Prep. Nitre fiij, white sugar fix ; mucilage of tragacanth to mix. Diuretic. Commonly sucked without swallowing, to remove incipient sore throat LOZENGES, NUTMEG. Syn. Tro. My- ristica. As Cinnamon Lozenges. LOZENGES, OPIUM. Syn. Tro. Oph. Prep. (P. E.) Opium (strained) 3ij; tincture of tolu fss ; tritura'e together, add powdered sugar §vj ; extract of L. uorice (soft) and powdered gum acacia, of each, %v; mix, and divide into 10-gr. lozenges ; each of which will contain one-sixth or one-seventh of a gr. of opium. Used to allay tickling cough, and irritation of the fauces. LOZENGES, ORANGE. Syn. Tro. Au- rantii. Prep. I. As lemon lozenges, substituting essence of orange for essence of lemon. II. (P. Cod.) Powdered sugar lb.j; neroli ^5j; orange-flower water q. s. ; make it into drops, (pastilli,) or omit the water and make it into lozenges with mucilage of tragacanth made with orange-flower water. Very agreeable. LOZENGES, ORRIS. Syn. Tro. Iridis Prep. Powdered orris 1 oz.; powdered sugar 1 lb.: mucilage of tragacanth to mix. Used to perfume the breath. LOZENGES, PECTORAL, -Syn. Tro. Pec torales. Prep. I. (Dr. Grunn.) Powdered squills 4 parts ; do. ipecacuanha 18 parts; extract of let- tuce 8 parts; manna 125 parts ; sugar 250 parts; mucilage of tragacanth to mix. II. (Majendie.) Pure emetine 8 grs., or impure do. 32 grs.; powdered sugar §iv ; mucilage q. s.; mix, and divide into 256 lozenges. III. (Yellow. Tro. Bechici Flavi.) Powdered orris root 3vj ; starch 3iv; liquorice powder 3iij; saffron 3ij ; sugar fviij; mucilage of tragacanth to mix. Each of the above is used in coughs, &c. LOZENGES, PEPPERMINT. -Syn. Tro. Mentha Piperita. Prep. I. (Best.) Lump su- gar, in fine powder, 14 lbs.; Mitcham oil of pep- permint (best) 1 oz.; mucilage of gum tragacanth to mix. Very fine. II. (2d Quality.) Sugar 12 lbs.; starch 2 lbs.; oil of peppermint J oz. ; mucilage to mix. III. (3d Quality.) Sugar 7 lbs.; powdered starch 4 lbs.; oil of peppermint 4 oz.; mucilage to mix. IV. (Common.) Sugar 8 lbs.; starch 4 lbs.; plaster of Paris 2 lbs.; oil of peppermint to flavor; mix.., V. (Trochisci mentha piperita, P. Cod.) Pow- dered sugar fxvj ; oil of peppermint 3j ; mix, and divide into 12-gr. lozenges. The peppermint drops (pastilles) of the French Pharmacopoeia are made with sugar ?xij ; oil of peppermint 3j ; and pep- permint water q. s. Remmrks. The best peppermint locenges ara I LOZ 409 LUT made of the very finest double refined sugar, and of English oil of peppermint, carefully mixed up with very clean mucilage. The commoner qualities are made by employing inferior lump su- gar and foreign oil of peppermint, or what is bet- ter, English oil of peppermint, but in a less pro- portion than for the better sorts. The addition of a very small quantity of blue smalts, reduced to an impalpable powder, is commonly made to the sugar, to increase its whiteness. Transparent peppermint lozenges are made from the same materials as the opaque ones, but the sugar is not reduced to quite so fine a powder, and the cake is rolled thinner before cutting it. A little oil of almonds or olives is also occasionally mixed with the ingredients, to promote the transparency, but tends to render the lozenges less white. Pepper- mint lozenges and drops are useful in flatulency. LOZENGES, PONTEFRACT. (See Ex- tract of Liquorice.) LOZENGES, POPPY. Syn. Tro. Papave- ris. Prep. Extract of poppies 3 oz.; sugar 15 oz.; powdered gum tragacanth 2 oz.; rose water to mfc. Used in coughs. LOZENGES, QUININE. Syn. Tro. Qui- nia sulphatis. Prep. (Soubeiran.) Sulphate of quinine 32 grs. ; white sugar 1 lb.; mucilage of gum tragacanth q. s.; divide into 15-gr. lozenges. Tonic, febrifuge, and stomachic. LOZENGES, RHUBARB. Syn. Tro. Rhei. Prep. (P. Cod.) Powdered rhubarb fj ; do. sugar §xj ; mucilage of tragacanth q. s.; mix, and di- vide into 12-gr. lozenges. Stomachic and laxa- tive. Sucked before dinner they excite the appe- tite. LOZENGES, ROSE. Syn. Tro. Rosa. Prep. I. (P. L. 1746.) Powdered red rose leaves §j ; su- gar lb. j ; mix with weak mucilage. II. (Pate de rose lozenges. Pati-rosa lozenges.) Sugar 2 lbs.; otto of roses 10 drops; mix with mucilage. Very fine. Some add starch 4 oz., substitute oil of rhodium for otto of roses, and use mucilage made with rose water. If wanted red, make the mucilage with an infusion of cochineal, or red rose leaves. LOZENGE*. SAFFRON. Syn. Tro. Croci. Powdered hay saffron 1 oz.; do. white sugar 1 lb.; mucilage of gum tragacanth to mix. Anodyne, pectoral, and emmenagogue. LOZENGES, SODA. Syn. Tro. Soda bi- carbonatis. Prep. (P. E.) Bicarbonate of soda 5j ; powdered sugar ^iij ; do. gum arabic §ss ; mix with mucilage. Antacid. Useful in heartburn, &c. (See Chalk Lozenges.) II. (Pastilles de Vichy, P. Cod.) Bicarbonate of soda §j; powdered sugar fxix • mucilage of gum tragacanth q. s.; mix, and divide into 20-gr. loz- enges. LOZENGES, SPONGE. Syn. Tro. Spongia. Tro. Spongia usta. Prep. (P. Cod.) Powdered burnt sponge $iv ; sugar 3;xij ; mucilage of traga- canth q. 8.; mix, and divide into 12-gr. lozenges. Taken in scrofula, &c. LOZENGES, STARCH. Syn. Tro. Amyli. Tro. Bechici albi. Prep. (P. L.1788.) Pow- dered starch ^iss; do. liquorice 3vj ; do. orris root 3iv; do. sugar lb. iss; mucilage of tragacanth to mix. Demulcent. LOZENGES, STEEL. Syn. Tro. Ferri. 52 Prep. I. (P. Cod.) Finely powdered iron filings 5J *, do. sugar §x ; do. cinnamon 3ij ; mucilage of tragacanth q. s.; mix, and divide into 480 lozen- ges. Tonic. II. (Aromatic.) Sulphate of iron 3iij; sugar gxvj ; tincture of cantharidis §j; essence of orange 30 drops; mucilage of tragacanth q. s.; mix, and divide into 280 lozenges. LOZENGES, SULPHUR. Syn. Tro. Sul- phuris. Prep. (P. Cod.) Sulphur (pure precipi- tated) ^ij; sugar 3-xvj ; mucilage of tragacanth made with rose water to mix. Useful in piles and some skin diseases. LOZENGES, TOLU. Syn. Tro. Tolutani. Prep. (P. Cod.) Dissolve balsam of tolu^j, in rec- tified spirit ^j 5 add water gij ; mix and filter, make a mucilage with the filtered liquid, and gum tragacanth 9iv; add sugar %xvj ; make a paste and cut it into lozenges. Pectoral. The confec- tioners usually employ only half the above propor- tion of balsam of tolu. LOZENGES, VANILLA. Syn. Tro. Vanil- la. Prep. (Guibourt.) Sugar gvij ; vanilla ^j ; mix, powder together, and make it up with muci- lage of gum tragacanth. Odorous ; stomachic. Used to sweeten the breath, to flavor choco- LOZENGES, VIOLET. Syn. Tro. Viola. (See Lozenges, Orris.) LOZENGES, ZINC. Syn. Tro. Zinci. Prep. Sulphate of zinc 3iv; powdered sugar lb. ij ; mu- cilage of tragacanth q. s.; mix, and divide into 12-gr. lozenges. Tonic, and in quantity emetic. LUPININ. A gummy substance, obtained by M. Cassola from lupines. LUPULINE. Syn. Lupulite. The aromatic bitter principle of hops, (humulus lupulus.) It may be obtained by treating the aqueous extract of the yellow powder, or lupulinic grains of the strobiles, along with a little lime, with alcohol, evaporating the filtered tincture to dryness, redissolving in wa- ter, filtering, again evaporating to dryness, and di- gesting in ether. It is a yellowish-white, bitter, uncrystallizable substance, soluble in 20 parts of water, very soluble in alcohol, and slightly so in ether. The yellow powder above alluded to is also, though improperly, called lupulin. LUCIFERS. Matches tipped with a mixture of sulphuret of antimony and chlorate of potash, (both in fine powder,) made into a paste with a solution of gum. They are inflamed by friction against a piece of emery, sand, or glass paper. (See Chlorate Matches and Congreve.) LUTE. -Syn. Lut, (Fr.) Kitte ; Beschlage, (Ger.) Lutum ; Camentum, (Lat.) A composi- tion employed to secure the joints of chemical ves- sels, or as a covering to protect them from the vio- lence of the fire. For the joints of vessels, as stills, &c, not exposed to a heat much higher than 212° F., linseed meal, either alone or mixed with an equal weight of whiting, and made into a stiff paste with water, may be employed. Ground almond cake, from which tho oil has been pressed, may also be used for the same purpose. For the joints of small vessels, as tubes, &c, "specially of glass or earthenware, small rings of Indian rub- ber slipped over and tied above and below the joint, are very convenient substitutes for lutes, and have the advantage of lasting a long time, and MAD 410 MAG bearing uninjured the heat at which oil of vitriol boils. For joining crucibles to be exposed to a 6trong heat, a mixture of fine clay and ground bricks, mixed up with water, or preferably with a solution of borax, answers well for most purposes. As a coating for vessels, to preserve them from in- jury from exposure to the fire, nothing is better than a mixture of ordinary pipeclay and horse dung, made into a paste with water. This compo- sition is used by the pipe-makers, and will stand unharmed the extremest heat of their kiln for 24 hours. It is applied by spreading it on paper. LUTEOLINE. This name has been given to a yellow coloring matter, discovered by Chevreul in weld. It is crystalline and volatile. MACARONI. This only differs from vermi- celli in the size of the pipes, which are about as large as a goose quill. A pleasant dish may be made by boiling macaroni in water until soft, either with or without salt, draining off the water, and then stewing it with a little butter, cream, and grated cheese, adding spice to palate. It may be made into a form and browned before the fire. MACARONS, CREME DE. Prep. Clean spirit at 24 u. p. (about 0-945) 2 gallons ; bitter al- monds, blanched and bruised, 1 lb.; cloves, cinna- mon, and mace, in coarse powder, of each 14 dr.; infuse for 10 days, filter, and add white sugar 8 lbs.; dissolved in pure water 1 gallon. Color violet, with infusion or tincture of litmus and cochineal. An agreeable nutty flavored cordial, but from con- taining so much bitter almonds, should be drunk with caution. The English use only half the above quantity of almonds. MACAROONS, ENGLISH. Prep. Sweet almonds 1 lb. ; blanch, beat to a paste, add lump sugar \\ lb.; whites of 6 eggs; the grated yellow peel of 2 lemons; mix well, make into forms, cover with wafer paper, and bake in a moderate heat. MACERATION. Syn. Einweichen, (Ger.) Maceration, (Fr.) Maceratio, (Lat, from ma- cero, to soften by water.) In Chemistry and Pharmacy, the infusion of a substance in water, for the purpose of extracting the portion soluble in that menstruum. The word is also frequently applied to the infusion of organic substances in alcohol, ether, or water, either alkalized or acidu- lated. MACKEREL. This fish is very apt to disa- gree with the stomach, and occasionally induces symptoms resembling those of poisoning. It keeps worse than any other fish. It is in season in May, June, and July. (See Fish.) MADDEN'S VEGETABLE ESSENCE, (CONCENTRATED.) Compound infusion of roses, made strongly acidulous by the addition of more acid. It is astringent and refrigerant. MADDER. Syn. Dyer's Madder. Radix Rubia. Radix Rubia Tinctorum, \Lat.) Gar- ance, (Gr.) Farberrothe, (Ger.) The root of the rubia tinctorum, (Linn.) The best madder has the size of a common goose quill, a reddish ap- pearance, and a strong odor. As soon as the roots are taken from the ground they are picked and dried ; and before use, they are ground in a mill. Levant, Turkey, and Smyrna madder, is imported whole,—French, Dutch, and Zealand madder ground. The finest quality of ground madder ia called " crop" or " grappe;" " ombro" and " ga- mene" are inferior sorts, and " mull" the worst Madder contains several distinct principles ; as madder red, (see Alizarine, madder purple, (see Purpurin,) madder orange, a substance very soluble in ether and in hot alcohol ; madder yel- low, very soluble in water and alcohol ; madder brown, a substance but little known. Uses. Madder has been given in jaundice and rickets, and as an emmenagogue. Dose. 4 dr. to 2 dr. twice or thrice a day. It is principally em- ployed as a dye stuff. (See Red Dyes.) MAGISTERY. Syn. Magisterium, (Lat., from magister, a master.) A term formerly ap- plied to precipitates obtained by diluting certain solutions with water; as magistery of bismuth, trisnitrate of bismuth, which is prepared by adding water to a solution of bismuth in nitric acid The following are the principal substances to which this term has been applied:—Magisterium marcasita, trisnitrate of bismuth.—Ludolph's magistery of opium, (magisterium opii Ludovici,) prepared by precipitating an acetic solution of opium with sub- carbonate of potash, filtering, and drying the pre- cipitate ;—magistery of alum, hydrate of alumi- na ;—magistery of diaphoretic antimony, (mate- ria perlata,) the precipitate obtained by adding an acid to the water used to wash diaphoretic anti- mony ;—magistery of lapis calaminaris, hydrated oxide of zinc. MAGNES ARSENICALIS. Arsenical mag- net. Prep. Common antimony, sulphur, and white arsenic, equal parts ; mix and fuse together till they form a kind of glass. Corrosive. Once used as a caustic. MAGNESIA. -Syn. Oxide of Magnesium. Calcined Magnesia. Burnt do. Caustic do. Talc earth. Bitter do. Magnesie ; Magne- sie caustique, (Fr.) Talkerde ; Bitter erde ; Gebrannte Magnesia, (Ger.) Magnesia calci- nata. Do. usta. (P. L. 1788.) Magnesia. (P. L. E. & D.) A light, white substance, classed with the earths. It occurs both in the organic and inorganic kingdoms. It was discovered, or at least first chemically distinguished from lime, by Dr. Black, in 1755. The ancient chemists applied the term magnesia to substances that they con- ceived to have the power of abstracting any prin- ciple from the air. Thus an earth, which on ex- posure to the air increased in weight and yielded vitriol, they called magnesia vitriolata. For a similar reason, because nitrous acid was separated during the old process for obtaining magnesia, it was called magnesia nitri, and afterwards from its color, magnesia alba. Pure magnesia (calci- ned) is properly the oxide of the metal magnesium, —carbonate of magnesia, the same oxide combi- ned with carbonic acid, and sulphate of magnesia, (Epsom salts,) the same oxide combined with sul- phuric acid or oil of vitriol. Prep. (P. L. E. & D.) Expose carbonate of magnesia in a crucible to a full red heat for 2 hours, or till the powder suspended in water does not effervesce on the addition of muriatic acid. Remarks. On the large scale, covered crucibles made of porous earthenware, are employed as the containing vessels, and the heat is applied by pla- cing them in a sort of furnace, or rather oven, MAG 411 MAG heated with coke. The process is known to be complete when the magnesia presents a peculiar luminous appearance. Product. About 50g. Prop., Uses, water 4 gallons; dissolve the salts and soda, each separately in one half the wa- ter, strain, mix and boil the liquors, constantly stirring for 15 minutes; after subsidence decant the clear, wash the precipitate with boiling water, and dry it. The formula of the P. E. is essential- ly the same, but the P. D. orders carbonate of potash instead of soda. II. Add a solution of carbonate of potassa or soda to the bittern of the sea salt works, and well wash and dry the precipitate as before. Both the preceding processes yield the light carbonate of magnesia of commerce. III. (Heavy carbonate of magnesia. Magne- sia ponderosa.)—a. Saturated solution of Epsom salts 1 part; water 3 parts; haat to the boiling point, then add cold saturated solution of carbonate of soda 1 part, (all by measure ;) boil, with constant agitation, till effervescence ceases, then add boiling water 100 parts, agitate well, decant off the clear liquid, drain and wash the precipitate with hot water, in a linen cloth, and finish the drying by heating it in an iron pot. Producf, very superior. b. Epsom salts 12 parts; crystallized carbonate of soda 13 parts; dissolve each separately in as little cold water as possible, then heat separately each solution to the boiling point, mix and boil till effervescence ceases; wash and dry, as before. Product, superior. Remarks. The carbonate of magnesia of com- merce is usually made up into cakes or dice, while drying, or is permitted to drain and dry in masses, which are then cut into shapes with a thin knife. It is powdered by rubbing it through a wire sieve. Prop., Uses, <£c. Carbonate of magnesia is a white, inodorous, tasteless powder, possessing similar properties to calcined magnesia. Dose. As an antacid, 4 to a whole teaspoonful 3 or 4 times daily ; as a laxative, 4 dr. to 2 dr. It is common- ly taken in milk. It is apt to produce flatulence, but in other respects is preferable to calcined mag- nesia. An ounce measure is filled by 48 grs. of the light, and 160 grs. of the heavy carbonate, lightly placed in it Pur. " The distilled water it has been boiled in should not discolor turmeric paper. The addition of chloride of barium, or nitrate of silver, effects no precipitation. By solution in dilute sulphuric acid, 100 parts lose 36*6 parts, by weight. When the effervescence has ceased, bicarbonate of potassa produces no precipitate." (P. L.) MAGNESIA, CITRATE OF. Syn. Mag- nesia Citras. Prep. Saturate a solution of citric acid with carbonate of magnesia, (about 20 grs. of acid to 14 grs. of the base.) It is usually drunk while effervescing. A pleasant saline draught. Remarks. The dry white powder sold as citrate of magnesia in the shops, is quite a different prep- aration to the above, and does not contain 1 par- ticle of citric acid. The following formula is that of a wholesale London drug house that does large- ly in this article:— Calcined magnesia 1 \ lbs., (or carbonate 2 lbs.;) powdered tartaric acid 14 lbs.; bicarbonate of soda 1 lb.; dry each article by a gentle heat, then mix, pass the mixture through a sieve, and keep it in well-corked bottles. Some persons add a few drops of essence of lemon, and 3 lbs. of finely-pow- dered sugar to the above quantity. This addition renders it more agreeable. MAGNESIA, HENRY'S. This is ordinary carbonate of magnesia, the washing of which has been finished with a little rose water. MAGNESIA, SULPHATE OF. -Syn. Phy- sical Salt. Epsom Salts. Vitriolated Mag- nesia. Bitter purging Salt. Sal Epsomensis. Sal Catharticus amarus. Sal Anglicum. Sal. Seidlitzense. Sal Catharticum. Magnesia vitriolata. Magnesia sulphas, (P. L. E. & D.) Sulphate de Magnesie, (Fr.) Bittersalz ; El- samersalz ; Schwefelsaure Magnesia, (Ger.) This salt is only prepared on the large scale, either from magnesian limestone or bittern. Prep. I. (From Dolomite or magnesian lime- stone.)—a. Heat the mineral with sufficient dilute sulphuric acid to convert all its carbonate into sul- phate of lime, wash out all the sulphate of mag- nesia with hot water, and, after defecation, evapo- rate and crystallize.—b. Dissolve out all the car- bonate of lime with muriatic acid, then well wash with water, and dissolve the remaining carbonate of magnesia in dilute sulphuric adid, and proceed MAG 412 MAL as before. This method is very economical where muriatic acid can be obtained almost gratuitously, as in the neighborhood of soda works.—c. Instead of sulphuric acid employ sulphate of iron to neutral- ize the magnesia. II. (From bittern.) a. Boil the residual liquor, or mother-water of sea salt, for some hours, skim, and decant the clear, then concentrate by evapo- ration, and run the solution into wooden coolers; in 1 or 2 days | part of Epsom salts will have crystallized out. This js called " singles." By re-solution in water, and recrystallization, " dou- bles," or Epsom salts, fit for the market, are ob- tained. Bittern yields about 5 parts of sulphate of magnesia for every 100 parts of common salt that have been previously obtained from it. b. Boil a sufficient quantity of calcined magne- sian limestone in bittern, to displace the muriatic acid from the magnesia ; evaporate as before. This is the most economical process. Prop., Uses, $-c. Sulphate of magnesia is an excellent cooling purgative, and sometimes proves diuretic and diaphoretic. Dose. 4 oz. to 14 oz. as a purgative or antidote in poisoning by lead. Large doses should be avoided. Dr. Christison mentions the case of a boy 10 years old, who swallowed 2 oz. of salts, and died within 10 minutes. (Treatise on Poisons.) A small quantity of Epsom salts, largely diluted with water, (as a drachm to 4 P'ut or | pint,) will usually purge as much as the com- mon dose. This increase of power has been re- cently shown by Liebig to result rather from the quantity of water than the salt. Pure water is greedily taken up by the absorbents; but water holding in solution saline matter is rejected by those vessels, and consequently passes off by the intestines Pur. Pure Epsom salts are soluble in their own weight of water at 60° F., by which they may be distinguished from Glauber salts, which are much less soluble. Shaken in the cold with water and carbonate of baryta or lime, an alkaline solution of carbonate of soda will be obtained if Glauber salts be present in the sample. When digested in alcohol, the filtered liquid should not yield a pre- cipitate with nitrate of silver, and should evaporate without residue. " Sulphuric acid dropped into the solution should not expel any fumes of hydrochlo- ric acid. 100 grs. dissolved in water, and mixed with a boiling solution of carbonate of soda, yield 34 grs. of carbonate of magnesia when dried." (P. L.) Caution. Epsom salts and oxalic acid may be readily distinguished from each other by the fol- lowing properties :-— epsom salts. Taste bitter. Odorless. Turn opaque and white when dissolved and mixed with carbonate of soda or potassa. Do not alter vegetable blues Have no action on ink spots or iron-moulds, OXALIC ACID. Tastes sour. Smells slightly nitrous, (generally.) Effervesces when mixed with carbonate of soda or potassa, and the li- quid afterwards be- comes transparent. Turns vegetable blues red. Removes ink spots and iron-moulds. MAGNESIAN APERIENT. Prep. Epsom salts 2 lbs.; dry by a gradually increased heat, powder, add tartaric acid (also dried) 1J. lb.; cal- cined magnesia 4 lb.; finely-powdered white sugar 3 lbs.; bicarbonate of soda (dried without heat) 1 lb.; essence of lemon 1 dr.; mix well, rub it through a sieve, in a dry situation, put it into bot- tles, and cork down immediately. Dose. 4 to 8 dessert-spoonfuls thrown into a tumbler 3 parts filled with water, rapidly stirred, and drunk while effervescing, early in the morning fasting, or be- tween breakfast and dinner. An excellent medi- cine for habitual constipation and stomach com- plaints. MAGNESIUM. The metallic base of the earth magnesia. The existence of this metal was demonstrated by Sir H. Davy in 1808, but was first obtained in sufficient quantity to examine its properties, by Bussy in 1830. Prep. Introduce 5 or 6 pieces of potassium about the size of peas, into a glaas tube retort, and over the potassium lay a sufficient number of small fragments of chloride of magnesium to cover it. The latter must then be heated to near its point of fusion, when the flame of the lamp must be applied to the potassium, so that its vapor may pass through the stratum of heated chloride. As soon as the vivid incandescence that follows is over, throw the mass into water, and collect the insoluble metallic portion. Prop., Sec. Color and lustre resemble silver, malleable and fusible at a red heat, unaffected by dry air and water; burns with brilliancy in oxygen gas, yielding oxide or protoxide of magnesium, or magnesia, and inflames spontaneously in chlo- rine, yielding chloride of magnesium. It dissolves in the acids with the evolution of hydrogen gas, and pure salts of magnesia result. Chloride oj magnesium is best prepared by dissolving magnesia in muriatic acid, evaporating to dryness, adding an equal weight of muriate of ammonia, project- ing the mixture into a red-hot platinum crucible, and continuing the heat till a state of tranquil fu- sion be attained. (Liebig.) On cooling it forms a transparent, colorless, and very deliquescent mass. Iodide, fluoride, and bromide of magnesium may be prepared by dissolving magnesia in hydriodic, hydrofluoric, and hydrobromic acids. MAHOGANY STAIN. Prep. I. Pure So- cotrine aloes 1 oz.; dragon's blood 4 °z- j rectified spirit 1 pint; dissolve, and apply 2 or 3 coats to the surface of the wood; finish off with wax or oil tinged with alkanet. IL Wash over the wood with strong aquafortis, and when dry, apply a coat of the above varnish; polish as last. III. Logwood 2 oz.; madder 8 oz.; fustic 1 oz.; water 1 gallon; boil 2 hours, and apply it several times to the wood boiling hot; when dry, slightly brush it over with a solution of pearlash 1 oz., in water 1 quart; dry and polish as before. MAHOGANY FURNITURE. Stains and spots may be taken out of mahogany furniture by the use of a little aquafortis, or oxalic acid and water, by rubbing the part with the liquid, by means of a cork, till the color is restored ; observ ing afterwards to well wash the wood with water and to dry and polish as usual. MALEIC ACID. A peculiar acid obtained MAL 413 MAL by distilling malic acid with a quick fire; a solu- tion of maleic acid passes over into the receiver, from which crystals may be obtained by evapora- tion. It is soluble in water, alcohol, and ether, and possesses a sour taste. Heat resolves it into water and anhydrous maleic acid. If kept long fused at a low temperature, it passes into a crys- talline mass of fumaric acid. It forms salts with the bases termed maleates, which are mostly insoluble. MALIC ACID. Syn. Acide malique, (Fr.) Aepfelsaure, (Ger.) Acidum malicum, (Lat) Prep. (Wi.ikler.) Juice of the fruit of the moun- tain ash, (sorbus aucuparia,) immediately after it has turned red, but still unripe, q. s.; heat it to the boiling point, skim, filter, nearly neutralize with ammonia, and precipitate with a solution of 1 part of acetate of lead to every 72 parts of juice ; filter, and again precipitate with nitrate of lead ; allow the whole to stand until it forms a mass of crystals, then well wash, dry, powder, suspend in water, and decompose by a current of sulphureted hydrogen ; again filter, neutralize with ammonia, decolor with animal charcoal, a second time pre- cipitate with nitrate of lead, and decompose the resulting nitrate of lead by sulphureted hydrogen ; lastly, filter, evaporate, and crystallize. Product. 6 oz. of crystallized malic acid from 296 oz. of juice. Remarks. Liebig first converts the impure solu- tion of the acid into acid malate of ammonia by neutralizing one half, and mixing it with the other half unneiitralized. This salt forms larger crys- tals tjian the neutral malate, and is easier decol- ored Mb. Everett has lately proposed the juice of the leaf-stalks of garden rhubarb as a source of malic acid. One imperial gallon of this juice con- tains 11,1394, grs. of dry malic acid. The stalks should be peeled before pressing out the juice, as the cuticle contains much color. 20,000 grs. of the peeled stalks yield 12,500 grs. of juice. Mr. Everett's process is as follows:—neutralize with hydrate of lime, boil, filter, precipitate with nitrate of lead, allow it to stand for a few hours, boil, cool, filter, decompose the precipitate with sul- phuric acid, avoiding excess, throw down the ex- cess of lead from the supernatant portion with sulphureted hydrogen, evaporate, and crystallize. (Proc. of the Chem. Soc.) Prop., fyc. Malic acid is very soluble in water, has a pleasant acidulous taste, and, when neutral- ized with the bases, forms salts called malates. When kept fused for some time at a low heat, it is converted into paramalic or fumaric acid ; and when quickly distilled, it yields malic acid, while fumaric acid is left in the retort. Malic acid may also be obtained from the juice of apples, and sev- eral other sorts of fruit MALT. -Syn. Malt, (Fr.) Malz, (Ger.) Bvne. Boasium ; Maltum, (Lat.) Bvvri, (Gr.) Grain which has become sweet in consequence of incipient germination. Barley is the grain usually malted, and the process consists in exposure to warmth and moisture. The grain is steeped in water contained in large wooden or stone cisterns, for a period of from 40 to 60 hours, depending on the temperature of the weather, or until it becomes sufficiently swollen and soft enough to bo easily pierced with a needle, or crushed between the thumb and finger without yielding a milky juice. As soon as the grain has been suniriently soaked, the wuter is drawn off, and the swollen barley is laid upon the stone floor of a suitable apartment called the couch, to the depth of 12 to 16 inches, where it is allowed to remain till the acrospire, or rudiments of the plumula, shoot forth. During the period the grain remains in the couch, it is at first turned every 24 hours, and afterwards 2 or 3 times a day, and at each turning the layer is spread out more and more till it is reduced to the depth of about 3 or 4 inches. The sprouted grain is next removed to the malt kiln, and dried in a thin layer, at a temperature of from 90 to 100° F., until quite hard. It now constitutes pale malt; when all the moisture has exhaled, and the heat is raised to from 120 to 125°, yellow, or amber malt, is formed; and when the heat is further raised to from 145 to 165°, amber brown, or pale brown malt, is obtained. When the grain is dried at a still higher temperature, it forms brown malt; and when the heat is sufficient to blacken or dis- color it, it is known as patent malt. In the prep- aration of the last variety, the heat is sometimes pushed as high as 430 to 435° F. By the process of drying, the vitality of the seed is destroyed. Both brown and patent malts are merely employed to color the worts produced from pale malt. 1 lb. of patent malt, mashed with 79 lbs. of pale malt, will impart to the liquor the color and flavor of porter. The paler varieties of malt contain the largest quantity of saccharine matter. After the malt has been kiln-dried, the acrospire and roots may be removed by means of a sieve. Before malt is mashed for beer, it is ground in a mill. Product. Good barley yields 80$ by weight, and 109$ by measure, of dried and sifted malt. Choice. Good malt should have an agreeable smell, and a sweet taste, should be round and full in the grain, and should be moderately brittle be- tween the teeth. The admixture of unmalted with malted grain may be discovered by throwing a little into water ;—malt floats on water, but raw barley sinks. Uses, fyc. Malt is chiefly employed in the arts of brewing and distillation. An infusion or decoc- tion of malt (sweet wort) is laxative, and has been recommended as an antiscorbutic and tonic. It has been given with advantage in scurvy. (See Brewing, Distillation, Fermentation, &c.) MALT LIQUORS. The qualities of ale, beer, and porter, as beverages, and the methods of preparing them, have been already described, (see Ale, Beer, Brewing, Mum, Porter, &c. ;) the present article will therefore be confined to a short notice of the cellar management, and the diseases of malt liquors generally. Bottling. Clean, sweet, and dry bottles, and sound and good corks, should be had in readiness. The liquor to be bottled should be perfectly clear ; and if it be not so, it must be submitted to the operation of "fining." When quite fine, and in good condition, the bung of the cask should be left out all night, and next day the liquor should be put into bottles, which, after remaining 24 hours mere- ly covered with sheets of paper to keep out flies and dust, must be securely corked down. Porter is generally wired over. If the liquor Is intended for exportation to a hot climate, ths bottles should remain filled for three days or more before corking them. The stock of bottled liquor should be stored MAL 414 MAN in a cool situation, and a small quantity to meet present demands should also be set on their sides in a warmer place to ripen. October beer should not be bottled before midsummer, nor March beer till Christmas. Ripening. The addition of a small lump of white sugar to each bottle of ale or beer, and a teaspoonful of moist sugar to each bottle of porter at the time of corking, will render it fit for drink- ing in a few days in ordinary weather. A raisin or lump of sugar candy is often added to each bot- tle with a like intention. The Parisians bottle their beer one day, and sell it the next. For this purpose, in addition to the sugar as above, they add 2 or 3 drops of yeast Such bottled liquor must, however, be drunk within a week, or else stored in a very cold place, as it will otherwise burst the bottles, or blow out the corks. Age. The addition of a very little diluted sul- phuric acid to new beer will give it the appearance of being 1 or 2 years old. Copperas, alum, sliced lemons, Seville oranges, and cucumbers, are also frequently employed by brewers for the same pur- pose. These additions subject the public brewer and seller to a fine, but private persons may em- ploy them at pleasure. Heading. This is added to thin and vapid beer to make it bear a frothy head. (See Heading, p. 350.) Preservation. See the end of the article Brew- ing. Improving. Cut half a quartern loaf into slices, toast them brown, place them in a coarse linen bag, along with 2 oz. of hops, and 1 oz. each of bruised ginger, cloves, and mustard seed, suspend the bag by means of a string a few inches below the surface of the beer, and bung close. For a hogshead. Cloudiness. Add a handful of hops, boiled in 1 gallon of the beer, and in a fortnight fine it down. Sourness. Add a little powdered chalk or car- bonate of soda to the beer, until the acidity is nearly removed, then rummage in 4 or 5 lbs. of moist sugar or treacle to every hogshead. Such beer should be soon put on draught, as it is apt to get flat by keeping. Oyster and egg shells are also frequently used by brewers for the same pur- pose. Vamping. Half fill casks with the old liquor, fill them up with some newly brewed, and bung close for 3 weeks or a month. Mustiness. To each hogshead add 1 lb. of new hops boiled in a gallon of the liquor, along with 7 lbs. of newly-burnt charcoal coarsely bruised, and a 4 lb. loaf of bread cut into slices and toasted rather black ; rouse well every day for one week, then rummage in moist sugar 3 or 4 lbs., and bung down for a fortnight. Flatness. Rummage a few pounds of moist sugar or treacle (foots) into each hogshead; fer- mentation will ensue in a few days, and the liquor become brisk. On the small scale, the addition of a few grains of carbonate of soda or prepared chalk to each glass will make the liquor brisk and carry a head ; out it must be drunk within a few minutes, else it becomes again flat. This is an excellent method when home-brewed beer becomes sour and vapid Recovering. This is said of unsaleable beer when l rendered saleable, by giving it " head" or removing its " tartness." Frosted beer is best recovered by the addition of a few hops boiled in a little sweet wort ; or by adding a little moist sugar or treacle to induce a fresh fermentation. Foxing or bucking. Add some fresh hops, along with some bruised mustard seed, to the beer. Some persons add a little made mustard, or solution of alum or catechu, or a little diluted sulphuric acid, and rummage well ; and in a week or 10 days afterwards, further add some bean-flour, treacle, or moist sugar. Ropiness. Add a little infusion of catechu and some fresh hops to the beer, and in a fortnight rummage well, and the next day fine it down. MANDARINS, THE DELIGHT OF THE. Prep. Spirit, 22 u. p., 1 gallon ; wat - 4 gallon ; white sugar 4 lbs.; anisum chime and ambrette or musk seed, (hibiscus abelmoschus,) of each, bruised, 4 oz.; safflower \ oz.; place the whole in a car- boy or stone bottle capable of holding double, cork close, and agitate well every day for a fortnight, then decant and strain. A pleasant cordial li- queur. MANGANESE. -Syn. Manganium ; Manga- nesium, (Lat.) Manganese, (Fr.) Mangan ; Braunsteinmetal, (Ger.) A hard, brittle, gray- ish-white metal, having the sp. gr. 8*013, discover- ed by Gahn in the black oxide of manganese of commerce. Prep. Reduce oxide of manganese to fine pow- der, make it into a paste with oil, place the mix- ture in a Hessian crucible lined with charcoal, lute on the cover, and expose it to trie strongest heat of a smith's forge for 2 hours. Prop., Uses, Sfc. Manganesium unites with oxygen, forming 5 oxides and 2 acids, and with chlorine, fluorine, and sulphur, forming chlorides, fluorides, and sulphurets. The protoxide or green oxide (Mn -f- O) is formed when either of the other oxides of manganese is mixed with char- coal, and exposed in a covered crucible to a white heat for some time. It possesses strong basic prop- erties, and readily dissolves in the liquid acids, forming salts. The sesquioxide, or second oxide, (2 Mn -f- 30,) is brown or brownish-black, and is found ready formed in the mineral kingdom. It is the residuum left in the retort when the black oxide is heated to moderate redness in the process of making oxygen gas. The peroxide, or third oxide, (Mn -f- 20,) is the well-known black oxide, or binoxide of commerce, and is also found in tho mineral kingdom. (See Manganese, Black Ox- ide of.) The red, or fourth oxide, (oxidum man- ganoso-manganicum, 3 Mn -4- 40,) is another natural oxide of manganese. It may be prepared artificially, by exposing the peroxide or sesquioxide to a white heat. Varvacite (4 Mn -f- 70) is an- other oxide which occurs as a mineral production. Manganic, or Manganeseous acid, (Mn -f- 30,) is formed when nitre, potassa, or carbonate of po- tassa, is heated to redness along with black oxide of manganese, either in close or open vessels. It has never been isolated. Manganesic, or perman- ganic acid, (2 Mn -f- 70,) may be obtained by mixing 8 parts of peroxide of manganese with 7 parts of chlorate of potassa, both in fine powder, MAN 415 MAN adding 10 parts of hydrate of potassa, dissolved in a small quantity of water, evaporating to dryness, powdering, exposing the powder to a low red heat in a platinum crucible, dissolving the mass in a large quantity of water, decanting, evaporating, and crystallizing. These crystals are permanga- nate of potassa, from which the acid may be ob- tained by conversion into permanganate of baryta, and by careful decomposition by dilute sulphuric acid, (Gregory.) It has a fine red color, bleaches, and is rapidly decomposed by organic matter.— Protochloride of manganese is made by heating the chloride to redness in a glass tube, surrounded by an atmosphere of muriatic acid.—Perchloride may be obtained by mixing permanganic and mu- riatic acid, and conducting the evolved gas through a tube cooled to —4° F. It is gaseous at a higher temperature, and is decomposed by moisture.— Sulphuret of manganese is a natural mineral pro- duction, but may also be procured by igniting a mixture of 1 part of sulphate of manganese and 1 part of charcoal.—Fluoride of manganese has been formed by Dumas and Wohler. The salts of manganese may all be prepared from the black oxide of commerce by dissolving the latter in muriatic acid, evaporating the solu- tion to dryness, redissolving in water, adding car- bonate of soda sufficient to precipitate the iron present, digesting the mixed precipitate in the re- mainder of the liquid, filtering, adding hydrosul- phuret of ammonia till it produces a flesh-colored precipitate, and then precipitating the solution with carbonate of soda. The carbonate of manga- nese thus obtained, after being well washed in water, may be redissolved in the acids to form Baits, most of which are soluble, and many crys- MANGANESE, BLACK OXIDE OF. Syn. Manganese. Binoxide of Manganese. Tritox- Ide of do. Peroxide of do. Oxide of do. Magnesia nigra. Manganesii binoxyduvi, (P. L.) Do. oxidum, (P. E. &. D.) Oxide de Manganese, (Fr.) Braunstein, (Ger.) This is the only oxide of manganese that is directly employed in the arts. It is a very plentiful mineral production, and is found in great abundance in some parts of the West of England. The manganese of the shops is prepared by washing, to remove the earthy matter, and grinding in rn»HIs. The blackest samples are esteemed the best. It is chiefly used to supply oxygen gas, and in the manufacture of glass and chlorine ; in dyeing, and to form the salts of manganese. It has been occasionally employed in medicine, chiefly externally, in itch and porrigo, made into an ointment with lard. It has recently been highly recommended by Dr. Erigeler in scrofula. Pur. and tests. Heat disengages oxygen. It is almost entirely soluble in muriatic acid. The per centagp value of commercial manganese may be readily found by digesting 50 grs. of the sam- ple in muriatic acid 14 oz., diluted with 4 oz. of water, adding portions of protosulphate of iron from a weighed sample, at first in excess, and afterwards in smaller doses, till the liquid ceases to produce a blue precipitate with red prussiate of potash, and to evolve the odor of chlorine. Heat ihould be employed towards the end. The quanti- ty of protosulphate used must now be ascertained by weighing the unconsumed portion. If the binoxide be pure, 317 grs. will have been con- sumed, but if otherwise, the per centage of pure oxide may be obtained by the rule of three ; as, suppose only 298 grs. of the sulphate were con- sumed, then—as 317:100:: 298:94, and the richness of the sample in pure black oxide would be 94°;. The per centage value of the oxide for evolving chlorine may be obtained by multiplying the weight of the consumed sulphate of iron by 0-2588, which, in the above case, would give 76§ of chlorine. Both for this purpose and chlorimetry the sulphate of iron is best prepared by precipitation from its solution with alcohol, and drying it till it loses its alcoholic odor. (Prof. Otto.) See Oxygen and Chlorimetry. MANHEIM GOLD. Syn. Similor. Prep. Copper 7 oz.; brass 3 oz.; melt together. Some add tin 4 dr. (See Brass.) MANNA. A factitious article of manna, made of a mixture of sugar, starch, and honey, with a very small quantity of scammony to give it odor and flavor, and to render it purgative, has been lately very extensively offered in trade. MANNITE. Syn. Manna Sugar. Grena- dine. Prep. Digest manna in boiling alcohol ; as the solution cools, crystals of mannite will form. White, odorless, sweet, soluble in water and alcohol. It is laxative. Dose. 1 to 2 drs. for a child ; 4 °z- to 1 oz. for an adult. It is found in several othet vegetable productions besides manna. Mannite differs from the other sugars in being in- capable of undergoing the vinous fermentation. MANURES. (In Agriculture.) Substances added to soils to increase their fertility. " The food of vegetables, as far as their organic structure is concerned, consists entirely of inorganic com- pounds ; and no organized body can serve for the nutrition of vegetables, until it has been, by the process of decay, resolved into certain inorganic substances. These are carbonic acid, water, and ammonia, which are well known to be the final products of putrefaction. But, even when these are supplied to vegetables, their growth will not proceed unless certain mineral substances are likewise furnished in small quantities, either by the soil, or the water used to moisten it. Almost every plant, when burned, leaves ashes, which commonly contain silica, potash, and phosphate of lime ; often, also, magnesia, soda, sulphates, and oxide of iron. These mineral bodies appear to be essential to the existence of the vegetable tissues ; so that plants will not grow in soils destitute of them," however abundantly supplied with carbonic acid, ammonia, and water." According to Liebig, the carbon of plauts is wholly derived from car- bonic acid, which is either absorbed from the atmosphere and rain water, by the leaves, or from the moisture and air in the soil by the roots. Its carbon is retained and assimilated with the body of the plant, while its oxygen is given out in the gaseous form ; this decomposition being al- ways effected under the action of light at or- dinary temperatures. The hydrogen and oxygen of vegetables, which, when combined with carbon, constitute the ligneous, starchy, gummy, sac- charine, oily, and resinous matters of plants, are derived from water chiefly absorbed by the roots MAN 416 MAR from the soil. The nitrogen of vegetables is de- ! rived chiefly, if not exclusively, from ammonia, which is supplied to them in rain, and in manures, and which remains in the soil till absorbed by the roots. Ordinary manures may be regarded more valuable according to the quantity of azotized \ matter which they contain ; and also in proportion as the decomposition of quaternary substances acts gradually, and agrees with the progress of vegetation. Thus, it is the azote in combination contained in manures which is especially useful; i and the proportion of this, when ascertained, in- dicates the richness of such substances as fer- tilizing agents. In reference to the mineral con- stituents of soils, it appears that a soil is fertile or barren for any given plant according as it con- tains those mineral substances that enter into its composition. " Thus the ashes of wheat-straw contain much silica and potash, while the ashes of the seeds contain phosphate of ammonia and mag- nesia. Hence, if a soil be deficient in any one of these, it will not yield wheat. On the other hand, a good crop of wheat will exhaust the soil of these substances, and it will not yield a second crop till they have been restored, either by manure or by the gradual action of the weather in disintegrating the subsoil. Hence the benefit derived from fal- lows and from the rotation of crops. " When, by an extraordinary supply of any one mineral ingredient, or of ammonia, a large crop has been obtained, it is not to be expected that a repetition of the same individual manure next year will produce the same effect. It must be remembered, that the unusual crop has ex- hausted the soil probably of all the other mineral ingredients, and that they also must be restored before a second crop can be obtained. " The salt most essential to the growth of the potato is the double phosphate of ammonia and magnesia; that chiefly required for hay is phos- phate of lime ; while for almost all plants potash and ammonia are highly beneficial. " From the principles above mentioned we may deduce a few valuable conclusions in regard to the chemistry of agriculture. First, by examining the ashes of a thriving plant, we discover the mineral ingredients which must exist in a soil to render it fertile for that plant. Secondly, by examining a soil, we can say at once whether it is fertile in re- gard to any plants the ashes of which have been examined. Thirdly, when we know the defects of a soil, the deficient matters may be easily ob- tained and added to it, unmixed with such as are not required. Fourthly, the straw, leaves, &c, of any plant, must be the best manure for that.plant, since every vegetable extracts from the soil such matters alone as are essential to it. This important principle has been amply verified by the success attending the use of wheat-straw, or its ashes, as manure for wheat, and of the clippings of the vines as a manure for the vineyard. Where these are used, no other manure is required. Fifthly, in the rotation of crops, those should be made to follow which require different materials ; or a crop which extracts little or no mineral matter, such as peas, should come after one which exhausts the soil of Its phosphates and potash. " Of the chemical manures now so much used, bone-dust supplies the phosphates which have been extracted by successive crons of grass and corn, the whole of the bones of the cattle fed on these crops having been derived from the soil; its gelatin also yields ammonia by putrefaction. Guano acts as a source of ammonia, containing much oxalate and urate of ammonia, with some phosphates, Nightsoil and urine, especially the latter, are most valuable for the ammonia they yield, as well as for phosphates and potash ; but are very much neglected in this country, although their impor- tance is fully appreciated in Belgium and China. Bran is a very valuable manure, especia'ly for po- tatoes, as it contains much of the ammoniaco-mag- nesian phosphate. " Nitrate of soda probably acts by its alkali re- placing potash, but it is possible that its acid may also yield nitrogen to plants, although we possess at present no evidence of this, and, indeed, no evi- dence that plants can derive their nitrogen from any other source than from ammonia." Manures may be made of all organic substan- ces, preference being, however, given to those abounding in nitrogen, and which readily decay. The analysis of manures, soils, and the ashes of plants, for the purpose of ascertaining their com- position and comparative value, is not easily per- formed by the inexperienced chemist; but a rude approximation to their contents, sufficiently accu- rate for all practical purposes, may be generally made with proper care and attention. See Liebig's Agricultural Chemistry; 7th Edit, of Turner's Chem.; the Memoirs of MM. Boussingault and Payen; and the articles Soils, Agriculture, Farming. MANUS CHRISTI. Prep. 1. (Manus christi perlata.) Drops, or pastilles, made of pearls, sugar, and rose water.—2. (Manus christi simplices.) Rose drops, or pastilles, made into flat cakes. MAPLE SUGAR. Prepared from the juice of the sugar maple, like birch sugar. Average pro- duct from each tree about 6 lbs. per season. MAPS may be tinted with any of the simple liquid colors mentioned at page 400. To prevent the colors sinking and spreading, which they will usually do on common paper, the latter should be wetted 2 or 3 times with a sponge dipped in alum water, (3 or 4 oz. to the pint,) or a solution of white size ; observing to dry it carefully after each coat This will tend to give lustre and beauty to the colors. The colors themselves should also be thick- ened with gum. Before varnishing maps after coloring them, 2 or 3 coats of clean size should be applied with a brush. (See Card Work and Paper j MARASQUIN DE GROSEILLES. Prep. Ripe gooseberries 1 cwt.; black cherry leaves 14 lbs.; bruise, ferment, distil, and rectify the spirit; and to each pint of the product add sugar 1 lb.; dissolved in water 1 pint. A pleasant liqueur. MARBLE. -Syn. Limestone. Hard Carbon- ate of Lime. Marmor; Carbonas Calcis durus, (P. L.) White Marble, (P. E.) Marmor album, (P. D.) Marbre ; Pierre a chaux *. Chaux car- bonates, (Fr.) Kalstein; Weisse Marmor, (Ger.) White marble is employed for the preparation of carbonic acid, and some of the salts of lime. Marble is best cleaned with a little clean soap and water, to which some ox-gall may be adiied. Acids should be avoided. Oil and grease may be MAR 417 MAR generally removed by following a similar plan to that mentioned at art. Boards. Marble may be stained or dyed of various colors by applying their solutions to the stone made suffi- ciently hot to make the liquid just simmer on the surface. The following are the substances usually employed for this purpose :— Blue. Tincture or solution of litmus, or an alka- line solution of indigo ;—Brown, Tincture of log- wood ;—Crimson, A solution of alkanet root in oil of turpentine ;—Flesh color, Wax tinged with al- kanet root, and applied to the marble hot enough to melt it;—Gold color, A mixture of equal parts of white vitriol, sal ammoniac, and verdigris, all in fine powder, carefully applied ;—Green, An alka- line solution or tincture of sap green, or wax strong- ly colored with verdigris, or stain the stone first blue, and then yellow ;—Red, Tincture of dragon's blood, alkanet root, or cochineal ;—Yellow, Tinc- ture of gamboge, turmeric, or saffron. Remarks. Success in the application of the above colors re- quires considerable experience. By their skilful use a pleasing effect, both of color and grain, may be produced. MARBLING OF BOOKS. This is performed by laying the color on the covers or edges with a brush, or by means of a wooden trough and gum water as follows:—Provide a wooden trough, 2 inches deep, 6 inches wide, and the length of a super-royal sheet; boil in a brass or copper pan any quantity of linseed and water until a thick mucilage is formed ; strain it into the trough, and let it cool; then grind on a marble slab any of the following colors in small beer. For blue, Prussian blue or indigo ;—red, rose-pink, vermilion, or drop lake ;—yellow, king's yellow, yellow ochre, &c.; —white, flake white ;—black, ivory or burnt lampblack; brown, umber, burnt do., terra di sienna, burnt do. ; black, mixed with yellow or red, also makes brown ;—green, blue and yel- low mixed ;—orange, red and yellow mixed ;— purple, red and blue mixed. For each color you must have two cups, one for the color after grind- ing, the other to mix it with ox-gall, which must be used to thin the colors at discretion. If too much gall is used, the colors will spread ; when they keep their place on the surface of the trough, when moved with a quill, they are fit for use. All things being in readiness, the colors are successive- ly sprinkled on the surface of the mucilage in the trough with a brush, and are waved or drawn about with a quill or stick, according to taste. When the design is thus formed, the book, tied tightly between cutting boards of the same size, is lightly pressed with its edge on the surface of the liquid pattern, and then withdrawn and dried. The covers may be marbled in the same way, only letting the liquid colors run over them. The film of color in the trough may be as thin as possible, and if any remains after the marbling, it may be taken off by applying paper to it before you pre- pare for marbling again. This process has been called French Marbling. To diversify the effect, colors are often mixed with,a little sweet oil before sprinkling them on, by which means a light halo or circle appears round each 6pot In like manner, spirits of turpentine, sprinkled on the surface of the trough, will make white spots. By staining the book covers with any of the liquid dyes, and then dropping on them, or running over them, drops of liquid mordants, a very pleasing effect may be produced. Thus vinegar black, or a solution of green copperas, let fall or run over common leather, produces black spots or streaks, and gives a similar effect with most of the light dyes. A solution of alum or tin in like manner produces bright spots or streaks, and soda and potash water dark ones. This style has been called Egyptian marble.—-Soap marbling is done by throwing on the colors, ground with a little white soap to a pliable consistence, by means of a brush. It is much used for book edges, sta- tionary, sheets of paper, ladies' fancy work, &c.— Thread marble is given by first covering the edge uniformly of one color, then laying pieces of thick thread irregularly on different parts of it, and giv- ing it a fine dark sprinkle. When well managed the effect is very pleasing.—Rice marble is given in a similar way to the last by using rice.—Tree marble is done on leather, book covers, &,c, by bending the board a little in the centre, and run- ning the marbling liquid over it in the form of vege- tation. The knots are given by rubbing the end of a candle on those parts of the cover.—Wax marble is given in a similar way to thread marble, but using melted wax, which is removed after the book is sprinkled and dried, or a sponge charged with blue, green, or red, may be passed over. This is much used for stationary work, especially folios and quartos. The vinegar black of the bookbind- ers is merely a solution of acetate of iron, made by steeping rusty nails or iron filings in vinegar. All the ordinary liquid colors that do not contain strong acids or alkalis may be used, either alone or thick- ened with a little gum, for marbling or sprinkling books.—Sprinkling is performed by dipping a stiff- haired painter's brush into the color, and suddenly striking it against a small stick held in the left hand over the work. By this means the color is evenly scattered without blotting. (See Bookbind- ing, Inks, Liquid Colors, and tho various dyes.) MARGARIC ACID. Syn. Margarulic Acid, (from iiapyapirt), a pearl.) A fatty acid obtained by the saponification of oils. Prep. I. Dissolve olive oil soap iu water, precipitate with a solution of neutral acetate of lead, filter, wash, and dry the precipitate, (margarate of lead.) digest in ether, and decompose the residuum by boiling-hot muri- atic acid ; lastly, wash the acid, dissolve in boiling alcohol, and evaporate. II. Heat hydrated stearic acid with its own weight of nitric acid for some minutes; press the fatty acid which separates between folds of paper, and purify by repeated crystallizations from alco- hol, till its melting point becomes 140° F. Remarks. Margaric acid forms pearly scales, soluble in ether and alcohol. With the b«ses, it forms salts called margarates. MARGARINE. -Syn. Margarate of Oxide of Glycerule. The solid fatty .natter of certain vegetable oils, and the principal ingredient of hu- man and goose fat. A hot alcoholic solution of either of these fats, or of the concrete portion of olive oil, deposites, as it cools, a mixture of marga- rate and oleate of glycerule. MARGARITIC ACID. Obtained by the sa- ponification of castor oil, along with another oily arid. The former melts at 266°, and forr^s soapy MAR 418 ME A ■alts with the alkalis, (margaritates;) the latter is an oily liquid at ordinary temperatures. MARGARONE. A peculiar fatty substance obtained by distilling a mixture of quicklime and margaric acid. It forms pearly crvstalline scales. MARRIAGE. Dr. Casper, of Berlin, has cal- culated that the mortality among bachelors, from the age of 30 to 45 years, is 27 per cent, while among married men of the same age it is only 18 per cent. For forty-one bachelors who attain the age of 40 years, there are seventy-eight married men who attain the same age. The advantage in favor of married life is still more striking in persons of advanced age. At 60 years there remain but twenty-two bachelors for forty-eight married men ; at 70 yea-re, eleven bachelors for twenty-seven married; and a"t 80 years, three bachelors against nine married men. (Jour, de Chimie Med.) MARMALADES. (From marmello, Portu- guese, a quince.) Properly a conserve made of quinces aiid sugar. The term is now, however, commonly applied to other fruit conserves made by cooks and confectioners. Marmalades are either made by pounding the pulped fruit in a mortar with an equal or a larger quantity of powdered white sugar, or by mixing them together by heat and passing them through a hair sieve while hot, and then putting them into pots or glasses. The fruit pulps are obtained by rubbing the fruit through a fine hair sieve either at once, or after it has been softened by boiling. When heat is employed in mixing the ingredients, the evaporation should be continued until the marmalade jellies on cooling. (See Conserves, Confections, Electuaries, Jams, and Jellies.) The following are the chief marmalades met with in the shops:— Apricot marmalade, from equal parts of pulp and sugar. Barberry marmalade, from equal parts of pulp and sugar. Citron marmalade, made as orange do. Marmalade of hips, from the pulp of the hips of rosa systyla or arvensis, and sugar, in the same way as the confection. Mixed marmalade, from plums, pears, and ap- ples, variously flavored to palate. Orange marmalade, from oranges, (either Se- ville or St. Michael's,) by boiling the peels in sirup until soft, then pulping them through a sieve, add- ing as much white sugar, and boiling them with the former sirup and the juice of the fruit to a proper consistence. A still finer marmalade is made by melting the confection of orange peel, P. L., either with or without the addition of orange juice, and passing it through a sieve. Candied orange marmalade, from candied or- ange peel, boiled in an equal weight each of sugar and water, and then passed through a sieve. Quince marmalade, (diacydonium,) from quince flesh, or pulp and sugar equal parts; or from the juice, (miva cydoniorum, gelatina do.,) by boiling it to one-half, adding an equal quantity of white wine, and two-thirds of sugar, and gently evapo- rating. Scotch marmalade. 1. Seville orange juice 1 quart; yellow peel of the fruit, grated; honey 2 lbs.; boil to a proper consistence.—2. Seville or- anges 8 lbs.; peel them as thinly as possible, then squeeze out the juice, and boil it on the yellow | peels for 1 hour, strain, add white sugar 7 lbs., and boil to a proper consistence. Transparent marmalade. Orange marmalade, well 6trained or clarified while hot. Marmalade of sloes. Conserve of sloes. As- tringent. Tomato marmalade. Like apricot marmalade, adding a few slices of onions and a little parsley. Wood sorrel marmalade. (Conserva foliorum lujelte.) Wood sorrel leaves 1 lb.; powdered white sugar 3 lbs.; beat together in a mortar. Pleasant, cooling, and acidulous; has a fine red color. MARSHALL'S CERATE. Prep. (Collier.) Palm oil §v; calomel §j ; sugar of lead ^ss ; oint- ment of nitrate of mercury 5'j 5 m'x* MASSICOT. -Syn. Masticot. Protoxide of Lead. Ochra Plumbaria factitia. The dross that forms on melted lead exposed to a current of air, roasted until it acquires a uniform yellow color. Used as a pigment. (See Lead, Oxides of.) MASTICATORIES. Syn. Pila Mastica- toria. Medicines taken by chewing. They are chiefly used as cosmetics or stimulants. Prep. 1. (Indian.) A mixture of betel leaf, areka nut, and lime.—2. (Hartman.) Mastich and pellitory of Spain, equal parts.—3. (Augustin.) Mastich, white wax, and ginger, equal parts.—4. (Quincy.) Mastich §iij ; pellitory of Spain and stavesacre seeds, of each 3ij ; angelica root 3ss; cubebs and nutmegs, of each 3j ; make into small bal'ls with white wax q. s.—5. Opium, ginger, rhu- barb, mastich, pellitory of Spain, and orris root, of each 3j; musk and ambergris, of each 1 gr.; melted white wax or spermaceti to mix. MASTICHIC ACID. Syn. Soluble Mas- tich Resin. The portion of mastich soluble in al- cohol. It forms about 90$ of the resin. According to Johnstone, it forms salts with the acids. MASTIC1NE. Syn. Neutral or Insoluble Mastich Resin. The insoluble portion left from preparing the last article. It is soluble in the alco- holic solution of the preceding resin. MATTHEW'S PILLS. Prep. Extract of black hellebore, powdered myrrh, Castile soap, opium, saffron, and oil of turpentine, equal parts; beat into a mass with sirup of buckthorn. Ano- dyne ; alterative. Dose. 3 to 10 grs. MATHIEU'S VERMIFUGE. This consists of two electuaries; the one for killing the worms, and the other for expelling them. Prep. 1. Tin filings §j; fern root 3vj; worm seed 3iv; resinous extract of jalap and sulphate of potash, of each 3j; honey to mix. Dose. A tea- spoonful every 3 hours, for 2 days. 2. Jalap and sulphate of potash, of each 9ij; scammony 3j; gamboge 10 grs.; honey to mix. Dose. A teaspoonful every three hours, until it op- erates well; the preceding electuary having been previously taken as directed. MATTICO. The leaves have been employed with considerable success as an external styptic; applied to leech-bites, and pressed on with the fingers, they seldom fail to arrest the bleeding. (Prov. Med. and Surg. Jour., June, 1842.) MAYDEW. Syn Ros Majalis. Collected by sponges off the grass. Used as a cosmetic. MEAD. Syn. Vinum Hydromell (From meede, Dut.) An old English liquor, made from I the combs from which the honey has been drained MEA 419 MEA out, by boiling in water and fermenting. It is commonly confounded with metheglin. (See Me- theglin.) Some persons add 1 oz. of hops to each gallon; and, after fermenting, a little brandy. It is then called Sack Mead. MEALS, RESOLVENT. (Quatuor Fari- na rfsolventes, of old pharmacy.) Barley, bean, linseed, and rye meals. MEASLES, THE. Syn. Rubeola. Mor- billi. Symp. Feverishness, chilliness, shivering, head-pains, swelling and inflammation of the eyes, defluxion of sharp tears, with painful sensibility to light, oppressive cough, difficulty of breathing, and sometimes vomiting or diarrhoea. These are followed about the fourth day by an eruption of small red points or spots, perceptible to the touch, and which, after four or five days, goes off with desquamation of the cuticle ; but the fever, cough, &c, continue for some time. Treat. When there are no urgent local symp- toms, mild aperients, antimonial diaphoretics and diluents should be had recourse to ; but when the inflammatory symptoms are emergent, and the lungs are weak, especially in plethoric habits, blood may be taken. The cough may be re- lieved by expectorants, demulcents, and small doses of opium ; and the diarrhoea by the ad- ministration of the compound powder of chalk and opium ; the looseness of the bowels, however, had better not be interfered with, unless it be ex- treme. MEASURE. Syn. Mensura, (Lat.) The unit or standard by which we estimate extension, whether of length, superficies, or volume. Our notice must be confined to the imperial measure of England, and the usual French measures that are mentioned in works on the arts and sciences, or are used in prescribing. I. French Decimal Measures of Length. Names. Eq. in Metres. Inches. Eq. in English Measures. 0-001 0-01 0-1 1-10-100-1000-10000* •03937 •39371 \ 3-93708 39-37079 393-70790 3937-07900 39370-79300 393707-90000 Miles. Fur. Yds. Feet. Inches. 0 0 10 2 9-7 0 0 109 1 1078 0 4 213 1 10-3 6 1 156 0 9*17 Remarks. The unit of the above table is the metre, which has been determined to be 39*37079, at 32° F., (Capt Kater;) the English foot is ta- ken at 62° F. It may be observed that all the divisions and multiples are decimals, and hence the term decimal system has been given to these measures, as well as to those of a similar descrip- tion below. It will be perceived that the principle of nomenclature adopted in applying the names, was to prefix the Greek numerals to the decimal multiples, and the Latin numerals to the decimal subdivisions. II. Measures of Volume.- -1. Imperial Standard, and the relative value of its Divisions, including those used in Medicine. •n f3 *1 O. Oij. C. Minims Fluid Fluid or drops. Drachms. Ounces. Pints. Quarts. Gallons. Pecks. Bushels. Quarters. 1 0-01666666 0-00208333 0-00010416 0-00005208 0-00001302 0 0 0 60 1- 0-125 0-00625 0-003125 0-00078125 0 0 0 480 8* 1- 005 0-025 0-00625 0 0 0 9600 160* 20- 1- 0-5 0-125 0-0625 0*015625 0-001953125 10200 320- 40- 2- 1* 0-25 0-125 0-03125 0-00390625 76800 1280* 1C0- 8- 4* 1* 0-5 0-125 0-015625 0 2560* 320- 16* 8* 2* 1- 0-25 0-03125 0 0 1280- 64- 32- 8* 4- 1* 0-125 0 0 0 512- 256* 64* 32* 8- 1* Remarks. The standard unit of the above table is the ga'lon, which has a capacity equal to 277*274 cubic inches, and is capable of holding exactly 10 lbs. (avoird.) of distilled water at 60° F., and 30 inches of the barometer. It is one- fifth larger than the old wine gallon, and one- sixtieth smaller than the old beer gallon. •>* A tea or coffee-spoonful (cochlearium pamium) of sirup contains 3j to 3ij; ordinary aqueous fluids 3iss to 3ij : spirits or tinctures 3j to 3iss; light powders (as magnesia) 9ss to 9j; heavy do. (as sulphur) 9iss to 9ij; metallic oxides 3j to 9iiij. A dessert-spoonful (cochlearium mediocre) of water 3ij. A tablespoonful (cochlearium magnum vel am- plum) of sirup ^ss; . ordinary aqueous fluids 3nj to 3mj ; spirits or tinctures 3ij to 3iij A teacupful (vasculum pro thea) §iij to 5»v. MEC 420 MED A wine-glassful (scyphus vel cyathus pro vino) |iss to |ij. A thimbleful (clypeola metalHca pro digitis) a teaspoonful. A cubic inch of water weighs 252*456 grs. A cubic foot of water weighs 62*3206 lbs. (av) A fluid ounce "» water contains 1-73298 cubic inches. A troy ounce .... 1*9013214 do. 2. French Decimal Measures of Voh me. Names Eq. in Litres. Eq. in Cubic In. Measure. 0-001 0-01 01 1-10-100* 1000* 10000- 0*06112 0-6U20 6-11208 61-12079 611-20792 6112*07920 61120*79208 611207 92080 Gallons. Pints. = 0 1-76377 = 2 1-4464 = 22 0*2640 = 220-47 — 2204-71 Remarks. The standard unit in the above table is the litre, or the cube of the one-tenth of a metre. The cubic inch is calculated at 252*5 grs. of water at 62° F. *** The French centiare contains 1 square metre ; the are, 100 do.; the hectare, 10,000 do. t|t The capacity of solids and aeriform fluids is taken in cubic inches, or feet, in England. In France, the stere, or metre cube, equal to 35-31658 English cubic feet, is the standard unit. MECHLOIC ACID. This name has been given by Couerbe to the crystalline mass obtained by passing chlorine gas over fused meconine. It is purified by removing the chlorine by oxide of silver. Before being purified, blood red; when pure, white crystals, strongly acid. MECONIC ACID. Syn. Acidum meconi- cum, (Lat, from pt}Ku>v, a poppy.) A peculiar acid discovered in opium. Prep. Dissolve pure meconiate of potassa 1 part, in 21 parts of hot water, add 3 parts of strong muriatic acid, and mix well. Acid meconate of potassa is deposited as the solution cools, which being treated a second time in the same way, yields pure meconic acid. Meconate of lime may be substituted for the pot- ash salt. Its purity may be ascertained by its leaving no residue when heated in a platinum or glass capsule. Remarks. Meconic acid forms beautiful pearly scales, possessing a sour astringent taste, and i soluble in water and alcohol. Its solution is de- composed by boiling, and by animal charcoal. At a heat of 248° it is decomposed, and pyromeconic acid formed along with other products. It is characterized by—1. Precipitating the sesquisalts of iron red, and the color not being destroyed by the action of corrosive sublimate.—2. Precipitating a weak solution of ammonio-sulphate of copper green.—3. With acetate of lead, nitrate of silver, and chloride of barium, it gives white precipitates.— 4. It is not reddened by chloride of gold. The above precipitates are all meconates of the given bases. Meconate of Lime is obtained by heating a solution of chloride of calcium with an infusion of opium made with cold water, and collecting the precipitate. By dissolving 1 part of this impure Bait in a mixture of 20 parts of water, and 3 parts of strong muriatic acid at near 212°, silvery crys- tals of monobasic meconate of lime will be depos- ited as the liquid cools. (Gregory.) The meco- nate of potassu may be prepared by direct solution of the base in the impure acid obtained from me- conate of lime till the liquor turns green, heat be- ing applied, when the salt crystallizes out as the liquid cools; it may be purified by pressure, and recrystallization. MECONINE, (from pikm, a poppy.) A white crystalline, odorless solid, discovered by Couerbe in opium. It remains in solution when an aqueous infusion of opium is precipitated by ammonia. It may be obtained by evaporation, and may be puri- fied by alternate solution in alcohol, water, and ether. It forms white prisms. It is distinguished from codeia and morphia by the absence of alka- line properties, and also from the latter by its fusi- bility, its greater solubility in water, and not being turned blue by the sesquisalts of iron. Chlorine gas passed over fused meconine turns it blood red. Neither meconine nor meconic acid appears to ex- ercise any important physiological action on the human frame. MEDALS, and similar objects are very conve- niently and accurately copied by electricity, (see Electrotype,) but still more quickly by the fol- lowing means:—Reduce recently-precipitated and well-washed oxide of copper by means of hydrogen passed over it at a gentle heat; the operation be- ing conducted in a glass tube, the one end being left partially open to permit of the escape of the newly-formed water. The process should be con- tinued till the oxide be wholly decomposed, and the powder assumes a fine copper-red color, when it must be immediately removed, and kept in a well- stoppered bottle. For use, the medal is placed on a layer of smooth sand, at the bottom a small white iron cylinder, and the sifted copper powder poured on to the depth of about 10 or 12 lines, and then gently compressed with a massive iron cylin- der, after which the whole must be placed on an anvil, and struck with a heavy hammer till the powder is no farther compressible. The icwly- formed cast is then removed from Hlz cylinder, and heated to a red-white heat in a small copper box, well luted with clay to exclude the air, after which the whole is left to cool. A solid copper medal is thus vsry quickly obtained. The re- cently reduced o -Jiles of other metals may be sub- stituted for coppc* G. Osann, the discoverer of MEL 421 MER this method, succeeded well with copper, silver, and lead, which were the only ones he tried. (Bib- liotheque Universelle de Geneve, No. 82.) MEDECINE NOIR. A celebrated French nostrum, consisting of a mixture of tamarinds, man- na, glauber salts, and senna. MEDULLIN. The porous pith of the sun- flower. It is soluble in nitric acid. (Dr. John.) MEERSCHAUM, (Ger.'foam of the sea.) Syn. Ecume de Mer ; Magnesie carbonatee silici- fere, (Fr.) A silicated magnesia mineral. The finest qualities are found in Greece and Turkey. It is used by the Tartars for washing linen. Its principal consumption is, however, in the manu- facture of tobacco-pipes. The Germans prepare their pipes for sale by first soaking them in tallow, then in white wax, and finally polishing them with shavegrass. Genuine meerschaum pipes are dis- tinguished from mock ones by the beautiful brown color which they assume after being smoked for some time. MEGGELLUP. Syn. Magilp. Prep. Mastich varnish 1 lb.; pale drying oil 2 lbs.; mix. Used by painters to apply their glazings with. It may be thinned by adding turpentine. Artists often vary the proportions according to their work. MELAM. A white insoluble powder discover- ed by Liebig. It is prepared by fusing sulpho- cyanide of ammonia, or a mixture of 2 parts of sal ammoniac, and 1 part of sulphocyanide of po- tassium. The residuum in the retort, after being washed with water, is melam. MELAMINE. A basic substance discovered by Liebig. It is prepared by dissolving melam in a mixture of hydrate of potassa 1 part, and water 20 parts, evaporating till crystalline scales begin to form, and slowly cooling. The resulting crys- tals must be purified by re-solution and recrystal- lization. Yellow transparent crystals, soluble in hot water. It combines with the acids, and forms crystallizable acidulous salts. MELAMPYRINE. A tasteless, neutral, crys- tallizable substance, extracted by Htinefeldt from tne melampyrum nemorosum. MELANGALLIC ACID. Syn. Metagallic Acid. Obtained by distilling tannic acid by a quick fire till it froths, melts, and becomes black and solid, then dissolving in an alkali, filtering, and precipitating by an acid. A black powder. MELANIC ACID. A black powder discover- ed by Piria, and formed when saliculite of potassa is exposed to the air till it turns black. In this state the mass consists of acetic and melanic tecids. MELASSIC ACID. Prep. Pour a hot satu- rated solution of baryta, or caustic potassa or soda, on melted grape sugar, dissolve, and continue the heat till the mixture turns deep brown, then precip- itate with an excess of muriatic acid, and wash the resulting black powder, first with dilute muri- atic acid, and then with water. MELLITIC ACID. Discovered by Klaproth in melilite or honey stone. It may be obtained by boiling the powdered stone in 70 times its weight of water, filtering, evaporating, and crystallizing. It forms salts with the bases termed melilates. MELLON. A compound of carbon and nitro- gen, discovered by Liebig. It remains at the bot- tom of the retort, under the form of a yellow pow- der, when bisulphocyanide of mercury is exposed to heat. It may in like manner be obtained by exposing melam, ammeline, ammelide, or dry sul- phocyanogen to a red heat. It is insoluble in al- cohol, water, and dilute acids. It is decomposed by concentrated acids, alkalis, and a strong red heat. MELTING-BAG. (Dr. Breslau.) Prep. Iodide of potassium 10 grammes ; sal ammoniac 80 gram- mes ; dry, reduce each separately to fine powder; mix by trituration, and enclose them in a small bag. As a resolvent to indolent tumors. It should be worn on the part for some time. MENISPERMIC ACID. Boullay has applied this name to a crystalline substance found in coc- culus indicus. MENISPERMINE. Syn. Menispermia, Me- nispermina. A neutral basic substance discovered by Pelletier and Couerbe in cocculus indicus. It may be obtained by the action of alcohol. It is insoluble in water. Paramenispermine is another similar substance, but differs from the preceding by not forming salts witu the acids. Neither of the above exercise any marked physiological ac- tion. MERC APT AN, (from its energetic action on mercury.) Syn. Hydrosulphuret of Sulphuret of Ethule. An ethereal liquid, smelling strongly of garlic, discovered by Zeise. Prep. Saturate liquor of potassa, sp. gr. 1*28, with sulphureted hy- drogen, then mix it with a solution of the same density of sulpliovinate of lime. The distilled liquid must be digested, first on a little chloride of cal- cium, and then agitated and rectified with a little red oxide of mercury. MERCURY. Syn. Quicksilver. Quik. Hy- drargyrus. Mercurius. Argentum vivum. Aq.ua Argentea. Aq.ua Metallorum. Hydrargyrum, (P. L. E. and D.) Mercure, Mercure coulant, Vif-argent, (Fr.) Quecksilber, (Ger.) 'Tipdp yvpos, "\pynpos xvt6s, (Gr.) A liquid metal having a tin white color. Mercury was known to the an- cients. It is mentioned by Aristotle, Theophras- tus, Pliny, and Dioscorides, but it is not alluded to, either in the Old Testament or in the writings of Herodotus. TI; i principal sources of this metal at the present time are the mines of Idria, in Car- niola, and Almaden, in Spain, where it exists un- der the form of cinnabar, from which the pure metal is obtained by distilling that ore with lime or iron filings in iron retorts, by which the sulphur it contains is seized and retained, while the mercury rises in the state of vapor, and is condensed in suitable receivers. Quicksilver is imported in cy- lindrical iron bottles, containing from J cwt. to 1 cwt. each. An importation of quicksilver was re- cently made from China. Prep. Mercury, as imported, is usually very pure. The Dublin College orders it to be pre- pared for medical purposes by putting 6 parts in- to a retort and distilling off four parts. The whole of the mercury may, however, be safely drawn over. A strong earthenware or iron retort, with a low neck or tube dipping into a basin of water, may be used for this purpose. One of the quickest and best means of purifying mercury is to agitate it with a concentrated solution of nitrate of mercury, at a heat of 104° F. Prop. Sp. gr about 13*6; freezes and crvs- MER 422 MER tallizes at —39° Fahr.; when solid it is ductile, malleable, and tenacious; boils at 662° Fahr.; but volatilizes slowly at the ordinary temperature of the atmosphere, and when mixed with water at from 140° to 160°, it is volatilized in considerable quantities. (Stromeyer.) It unites with oxygen, forming two oxides; and with chlorine, forming calomel and corrosive sublimate ; with the metals it forms amalgams. Its oxides form salts with the acids. The only acids that act on metallic mercury are the sulphuric and nitric ; but for this purpose the former must be heated. Uses. Mercury is applied to various purposes in the arts ; as the amalgamation of gold and silver, wash gilding, the silvering of looking-glasses, the manufacture of barometers and thermometers, and in the preparation of several valuable medi- cines. In its metallic state it appears to be inert when swallowed, unless there be much acidity in the alimentary canal ; its salts are, however, all of them more or less poisonous. Pur. It is totally dissipated by heat, and dis- solved by diluted nitric acid, but is insoluble in boiling muriatic acid. The acid poured off, and allowed to cool, is neither colored, nor yields a precipitate with sulphureted hydrogen; sp. gr. 13*5. (P. L.) " A globule moved about on a sheet of paper yields no trail; pure sulphuric acid agitated with it (in the cold) evaporates when heated, without leaving any residuum." (P. E.) Tests. 1. Metallic mercury may be detected by its volatility, and when in a finely-divided or pulverulent state, by the microscope, or by stain- ing a piece of copper white when rubbed on it, or when heated beneath it.—2. Solutions of the persalts of mercury yield—with caustic alkalis, yellowish or red precipitates—with alkaline car- bonates, a brick-red one—with iodide of potassium, a scarlet one.—3. The protosalts of mercury yield a gray or black precipitate with alkalis,—a yellowish or greenish-yellow one with iodide of potassium,—a white one with muriate of soda.—4. The salts of mercury are all volatilized at a dull red heat—give a white precipitate with prussiate of potash,—a black one with sulphureted hydrogen and hydrosulphurets,—an orange yellow one with gallic acid, and—with a plate of polished copper, a white coat of metallic mercury. Solid bodies may be tested by treating them with nitric acid, evaporating, redissolving in water, and then pro- ceeding as above. MERCURY, ACETATE. Syn. Hydrargyri Acetas, (P. D.) Do. Acetis. Prep. I. (P. D.) Mercury 9 parts; diluted nitric acid 11 parts; dissolve, then add it to a boiling solution of acetate of potash 9 parts, dissolved in water 100 parts, and acidulated with distilled vinegar ; filter while hot, let it coll, and wash and dry the crystals that are deposited. II (P. L. 1788.) Dissolve protoxide of mer- cury in 6trong acetic acid, concentrate so that crystals may form as it cools. Remarks. The above is the protacetate of mer- cury,—the peracetate is formed by dissolving the red oxide in strong acetic acid. They both form white scales: said to be one of the mildest of the mercurials. Dose. 1 gr. night and morning, gradually increased. The peracetate is the active ingredient in the celebrated Keyset's pills. (Robi- quet.) A lotion is made with 3j of the protacetate to a pint of water; and an ointment is orepared by dissolving 2 or 3 scruples in an ounce of olive oil. (Pereira.) MERCURY, BROMIDES OF. The proto- bromide (hydrargyri bromidum) is a white in- soluble powder, obtained by precipitating a solu- tion of protonitrate of mercury by bromide of potassium. The bibromide (hydrargyri bibromi- dum) is formed by dissolving peroxide of mercury in hydrobromic acid. MERCURY, CHLORIDES OF. Prep. L (Chloride of Mercury. Mercurius dulcis. Hy- drargyrum Muriaticum mite. Drago Mitigatus. Aquila alba. Manna Melallorum. Panchyma- gogum minerale. Calomelas, P. E. and D.) See Calomel. II. (Bichloride of Mercury. Perchloride of do. Oxymuriate of do. Corrosive muriate of do. Chloride of do. ? Muriate of do. ? Hy- drochlorate of do. ? Corrosive Sublimate. White Mercury. Mercurius Corrosivus Sublimatus, P. L. 1720, 1745. Hydrargyrus Muriatus, P. L. 1788. Hydrargyri Oxymurias, P. L. 1809, 1824. Hydrargyri Bichloridum, P. L. 1836. Sublimatus Corrosivus, P. E. Hydrargyri Murias Corrosivus, P. D. Hydrargyri Murias? Do. Hydrochloras ? Acidum Chloro-hydrargy- ricum. Deuto-Chlorure de mercure; Muriate de mercure corrosif, Fr. Doppelt-chloric Queck- silber; Aetzendes quecksilber sublimat, Ger.) Prep. 1. (P. L.) Mercury lb. ij; sulphuric acid lb. iij ; boil together in an iron pot to dryness, and when cold, triturate in a mortar with common salt (dry) lb. iss ; then sublime with a heat gradu- ally raised. The Edinburgh form is similar. 2. (P. D.) Persulphate of mercury 5 parts; dried muriate of soda 2 parts; triturate and sub- lime as above. Remark. The solution of the mercury is usually made in an iron pot set in a furnace under •» chimney to carry off the fumes; and the sublima tion is conducted in an earthen alembic placed in a sand bath; or in an iron pot, covered with a semispherical earthen head. Corrosive sublimate may also be made by the direct solution of the red oxide in muriatic acid, or by bringing its con- stituents together in the state of vapor. The latter plan has been recently patented. Prop., Uses, ether 3j; mix. II. Asafcetida 3j; peppermint water §vj; tritu- rate together, then add ammoniated tincture of valerian 3ij; tincture of castor 3iij ; sulphuric ether 3iss ; mix. Dose. §ss, 3 or 4 times daily. MIXTURE, ANTISCROFULOUS. Syn. M. Antisorofulosa. Prep. Tincture of bichloride of gold 30 drops; tincture of iodine 40 drops; tincture of gentian 3j ; simple sirup 3vij; rose water §v ; mix. Dose. A dessert-spoonful 2 or 3 times daily, observing to shake the bottle before pouring out the liquid. %* The writer of this article has seen repeated instances of the excellent effects of this medicine in scrofula, syphilis, and various glandular diseases. MIXTURE, ANTISPASMODIC. Syn. M. antispasmodica. Prep. I. (Collier.) a. Asafcetida and camphor mixture**, of each f ^iiss ; tincture of valerian f 5j 5 mix. Dose. 1 tablespoonful every third or fourth hour. b. Fetid spirit of ammonia, sirup of saffron, and tincture of valerian, of each f3iij ; camphor mixture f^viss; mix. Dose. 2 ot 3 tablespoonfuls as above. II. Tincture of castor 3j; sulphuric ether and laudanum, of each 10 drops; cinnamon water f §iss; mix for a dose, to be taken thrice a day. MIX 429 MIX IH. Volatile tincture of valerian, and tincture Df castor, of each 3v ; tincture of henbane 3ij ; peppermint water and camphor mixture, of each j^iiss ; mix. Dose 1 tablespoonful 3 or 4 times a day. MIXTURE, APERIENT. Syn. M. Ape- riens. Prep. I (Abernethy.) Epsom salts 3iv ; manna 3ij; infusion of senna f3vj; tincture of senna f3ij ; spearmint water fjj ; pure water f^ij ; mix. Dose. A wine-glassful or more. (See Black Draught.) II. (Collier.) Sulphate of iron 3j; Epsom salts ^j; pennyroyal water 1 pint; dissolve. Dose. A wine-glassful twice a day in atonic amenorrhcea. MIXTURE, AROMATIC. Syn. M. Aro- matica. Potion a^omatique, (Fr.) Prep. I. (P. Cod.) Sirup of clove-gillyflower §j ; spirits of cinnamon 3iv ; confection of hyacinth 3ij ; pep- permint and orange-flower water, of each §ij; mix. II. (St. B. H.) Aromatic confection 3iiss ; pure water f ^v ; pimento water f ^iij ; mix. An ex- cellent aromatic in diarrhoea, heartburn, flatulence, acidity, &c. Dose. A tablespoonful or two every 2 or 3 hours. MIXTURE, ARSENICAL. Syn. M. arse- nicalis. Prep. Liquor of arsenite of potassa, P. L. 3iij ; compound tincture of cardamoms 3v ; cin- namon water 3"j ; pure water §iv ; mix. Dose. §ss twice a day after a full meal, in agues, peri- odic headaches, lepra, psoriasis, chronic rheuma- tism. &c. %* It should be exhibited with cau- tioi>. and its effects watched. MIXTURE, ASAFCETIDA. Syn. Milk of Asafcetida. M. AsafcetidjE, (P. L. & D.) Lac do. Prep. (P. L.) Asafcetida 3v ; water 1 pint; mix gradually, tritura'ting all the while. The Dublin College orders only half the above quantity of asafcetida, and pennyroyal instead of pure wa- ter. Stimulant and antispasmodic. Dose. £ to IJ oz., chiefly in hysteria. It is also used as an enema in flatulent colic, worms, hooping-cough, and convulsions of children. MIXTURE, ASTRINGENT. Syn. M. as- tringevs. Prep. I. (Thomson.) Extract of ca- techu 3ij, (or tincture § j;) cinnamon water ^viij ; dissolve. Dose. 1 to 3 tablespoonfuls after every liquid dejection, in diarrhoea or dysentery. II. (Pradel.) Tannin 12 grs.; tincture of rha- tany 3j ; simple sirup 3vij ; mucilage Jj ; camphor mixture %\v ; mix. As last. MIXTURE, ATROPHIC. Syn. M. atro- phica. Prep. (Majendie.) Iodide of potassium 3iv ; lettuce water ^viij ; peppermint water 3ij ; sirup of marshmallow ^j; mix. MIXTURE, BALSAM OF PERU. Syn. M. Balsami Peruviam. Prep. Strained honey and balsam of Peru, of each 3ij ; mix by tritura- tion, and add gradually decoction of liquorice ^vj, aromatic sulphuric acid 20 drops, tincture of orange-peel §ss; mix well. Dose. 1 to 2 table- spoonfuls 2 or 3 times a day in-debility. MIXTURE, BARLEY. -Syn. M. Hordei, (P. E.) The same as the compound decoction of barlev. P- L. (See Decoctions.) MIXTURE, BRANDY. Syn. M. Spiritus Vim Gallici, (P. L.) Egg Flip, (vulgo.) Prep. Brandy and cinnamon water, of each f ^iv ; yelks of 2 eggs; white sugar |ss; oil of cinnamon 2 drops; mix. A valuable stimulant and restorative in low fevers, and extreme exhaustion from hemor- rhages, &c. Dose. 1 to 3 tablespoonfuls occa- sionally. " Did the College practically test the quality of their < egg-hot' before deciding, on the formula?" MIXTURE, BRUCINE. Syn. M. Brucia Potio stimulante. Prep. (Majendie.) Pure brucia 5 grs.; white sugar 3ij ; water f^ij ; mix carefully. Dose. £ to a whole tablespoonful night and morning. MIXTURE, CAMPHOR. Syn. Camphor Julep. Do. Water. M. Camphors, (P. L. E. & D.) Prep. (P. L.) Camphor 3ss; rectified spirit 10 drops ; triturate together, then gradually add wa- ter 1 pint; triturate and strain. The Edinburgh College orders camphor 3j ; sugar and sweet al- monds, of each Sjss ; water 1 pint. Dose. 2 to 4 tablespoonfuls. It is chiefly used as a vehicle for other medicines. MIXTURE, CAMPHOR AND MAGNE- SIA. Syn. M. Camphors cum Magnesia. Prep. (P. E.) Camphor 10 grs., (12 grs. P. D.;) carbonate of magnesia 25 grs., (3ss P. D.;) triturate together, then add gradually water f §vj, still continuing the trituration. Antacid, antispasmodic, and anodyne. Dose. 1 to 2 tablespoonfuls. Used without strain- ing. MIXTURE, CAPSICUM. Syn. M. Capsici. Prep. (Collier.} Tincture of capsicum f3ij ; infu- sion of roses f^vj ; mix. Stimulant in dyspepsia, &c. Dose. 1 to 2 tablespoonfuls half an hour be- fore dinner. MIXTURE, CARMINATIVE. Syn. M. Carminativa. Prep. (Dr. Paris.) Calcined mag- nesia 3ss ; peppermint water f 3iiss ; compound tincture of lavender f 3ss ; spirit of caraway f 3iv ; sirup of ginger f3ij ; mix for 1 or 2 doses. An- tacid and carminative. MIXTURE, CASCARILLA. Syn. M. Cas- carilla composita, (P. L.) Prep. Infusion of cascarilla f ^xvij ; vinegar of squills f^j; com- pound tincture of camphor f §ij; mix. Dose, ffj ' to f §iss 2 or 3 times a day in chronic cough and asthma, and in the catarrh of elderly people. MIXTURE, CASTOR OIL. Syn. M. Ri- cini. Emulsio purgans. Prep. (P. Cod.) Castor oil ^j ; yelk of 1 egg; peppermint water ^ss ; sirup ^j; pure water ^'j 5 make an emulsion. One of the best ways of exhibiting castor oil to persons who dislike it. MIXTURE, CATHARTIC. -Syn. M. Ca- thartica. Prep. (A. T. Thomson.) Sulphate of potash 3ij; water f ^vss; tincture of jalap f 3iv ; mix. Dose. 2 tablespoonfuls every 2 hours. MIXTURE, CHALK. Syn. Cretaceous Mixture. M. Creta:, (P. L. E. &. D.) Prep. (P. L.) Prepared chalk ^ss ; sugar 3iij ; gum mix- ture (mucilage) f ^iss; triturate, then add cinna- mon water f^xviij; mix. The Ed. Ph. orders spirit of cinnamon f §j to the above quantity. An- tacid, absorbent. Dose. 1 to 3 tablespoonfuls, either alone or combined with aromatic confection, in heartburn, and in diarrhoea after every liquid motion. MIXTURE, CINCHONA. Syn. Bark Mix- ture. M. Cinchonas. Prep. I. (Copland.) Con- fection of red roses gss; boiling decoction of bark f Sviij • triturate, in 10 minutes strain, and add di- MIX 430 MIX luted sulphuric arid 3iss; spirit of nutmeg 3iv; shake well. Febrifuge, tonic, and stomachic. Dose. 1 to 3 tablespoonfuls, 2 or 3 times a day. II. To the last add Epsom salts §ss; Dose and uses as 'last Slightly aperient. MIXTURE, COPAIBA. Syn. M. Copaiba. Prep. I. (Guy's H.) Balsam of copaiba 3iij ; li- quor of potassa 3iss ; triturate together, and grad- ually add barley-water, %\\\\. One of the best ways of exhibiting this drug. II. (St. B. H.) Balsam of copaiba f3iij; muci- lage f ^iij ; triturate together, and make an emul- sion with pimento water f ^ij; pure water f ^iv. Dose. Of either of the above, 1 to 3 tablespoonfuls 3 or 4 times a day, in diseases of the urinary or- gans, &c. MIXTURE, COPAIBA AND OLIBANUM. Syn. M. Copaiba cum Olibano. Prep. (P. C.) Balsam of copaiba 5SS j olibanum 3ij ; mucilage §iss; honey Jj; cinnamon water %v. As last. MIXTURE, COPAIBA, (VINOUS.) Syn. M. Copaiba vinosa. Prep. (Fuller.) Copaiba §ij ; yelks of 2 eggs; triturate together, add sirup of tolu ^ij ; again mix well, then further add white vine f f iv. Dose. A dessert-spoonful 3 or 4 times t day. MIXTURE, COSMETIC. Syn. M. Cos- metica. Prep. Oil of almonds, and oil of tartar, of each 5'j» (or liquor of potassa §iij ;) rose water §v ; mix well. Used to clear the aomplexion. MIXTURE, CREOSOTE. Syn. M. Cre- asoti. M. Creazoti, (P. E.) Prep. Creosote and acetic acid, of each 16 drops; mix, then add compound spirit of juniper and sirup, of each f Jj ; water ffxiv; agitate well together. Dose, f 5j to f 5 'j '" vomiting, especially to relieve or prevent sea-sickness. | MIXTURE, CREOSOTE, (ALKALINE.) -Syn. M. Creasoti alkalina. Prep. (Allnatt) Creosote and solution of potassa, of each 3j; white sugar 3ij ; triturate together, then add camphor mixture f f vj ; mix well. MIXTURE, CUBEBS. Syn. M. Cubeba. Prep. (Fr. H.) Powdered cubebs §j, (or essence ^ss;) sirup and mucilage, of each fiss ; triturate, then add cinnamon water f ^vj. Dose. 2 table- spoonfuls in certain diseases of the urinary organs. MIXTURE, CYANIDE OF POTASSIUM. Syn. M. Potassii Iodidi. Prep. Cyanide of potassium 1 gr.; sirup §j; water %v ; mix. Dose. 1 dessert-spoonful. MIXTURE, DEMULCENT. Syn. M. De- mulcens. Prep. I. (Collier.) Mucilage ^j'; oil of almonds and sirup of tolu, of each ^ss ; triturate, and add water f §vj ; mix well. II. (Thomson.) Decoction of marshmallow f^vj; sirup ffj; mix. III. Spermaceti 3ij; yelk of 1 egg; triturate, add sirup §j *, mucilage %ss ; cinnamon water §ij ; pure water 5'v ; mix well. Dose. Of each of the above 1 to 2 tablespoonfuls ad libitum ; in coughs, hoarseness, calculus, irritation of the urinary organs, &.c. MIXTURE, DIAPHORETIC. Syn. M. Diaphoretica. Prep. Solution of acetate of am- monia ^iij ; antimonial wine 3ij; laudanum 3j ; camphor mixture §iij » mix. Dose. 1 to 2 table- spoonfuls, in fevers, &c. II. To the last add sweet spirits of nitre §ss. MIXTURE, DIARRIKEA. Syn. M. pro Diarrhcea. Prep. Aromatic confection 589 j tincture of opium 3iss; tincture of cardamoms (comp.) 3iiss ; peppermint or cinnamon water ^v; mix. Dose. 1 tablespoonful Lfter every liquid stool. MIXTURE, DIURETIC. Syn. M. Diuretica. Prep. I. (Guy's H.) Nitre 3iij; peppermint water ^xss "> sweet spirits of nitre f 3iij; lemon sirup ^j ! mix. II. Infusion of digitalis ^vss; tincture of di- gitalis 3ss; acetate of potassa 3ij; spirit of juniper §ss; laudanum 9j; mix. Dose. 1 to 2 table- spoonfuls ; in dropsy. MIXTURE, ELATERIUM. Syn. M. Elaterii. Prep. (Collier.) Elaterium 1 gr.; soft extract of liquorice 3j; triturate, and add gradually water (warm) f^vj. Dose. 1 to 2 tablespoonfuls every 2 hours ; in dropsy, &c. MIXTURE, EMETIC. Syn. M. Emetica. Prep. I.—a. (Thomson.) Tartarized antimony 8 grs.; sirup of mulberries 3j; water f ^vj, -.lix, and dissolve.—b. Ipecacuanha 3ss; tartarized antimony 1 gr.; tincture of squills f 3j ; water f §vj; mix. Dose. 1 to 2 tablespoonfuls, repeated every i of an hour till vomiting be induced; in dropsy, before exhibiting fox-glove. II. (Copland.) Sulphate of zinc 3ij; ipe- cacuanha wine and tincture of serpentary, of each f3iv; tincture of capsicum 40 drops; oil of chamomile 12 drops; peppermint water f ^ivss; mix. An excitant emetic. MIXTURE, EMETINE. Syn. M. Eme- tina. Melange Vomitif. Prep. (Majendie.) Pure emetine 1 gr., (or colored 4 grs. ;) acetic acid 8 drops; sirup of marshmallow and orange-, flower water, of each f Jj; pure water f Jiss ; mix. Emetic. Dose. A dessert-spoonful, repeated at short intervals, till it operates. MIXTURE, EMMENAGOGUE. -Syn. M. Emmenagoga. Prep. I. Compound steel mixture ^iij; cinnamon water ^vj ; mix. Dose. 2 table- spoonfuls 2 or 3 times a day. II. Tinctures of sesquichloride of'iron and aloes, (comp.,) of each §ss; tincture of castor 3ij; spirit of pimento 3ij; chamomile infusion 3V j mi* Dose. 1 to 2 tablespoonfuls. MIXTURE, ETHER AND TURPENTINE. Syn. M. ^Etheris cum Terebinthina. Prep. (Orfila.) Sulphuric ether 3j; oil of turpentine 3ij; white sugar 3iv *, triturate and add gradually water ^'j- Dose, f 3ij every 15 minutes; in poisoning by nux vomica. MIXTURE, EXPECTORANT. Syn. M. Expectorans. Prep. I. (Thomson.) Almond mixture f^v; ipecacuanha and tincture of squills, of each f 3j; sirup of tolu f 3vj; mix. Dose. 1 tablespoonful; in humoral asthma, catarrh, &c., when the cough is urgent. II. (Collier.) Oxymel of squills and mucilage, of each Jj; sirup of marshmallows ^ij, (camphoi julep Sjiij ;) mix. Dose. 1 to 2 tablespoonfuls 2 or 3 times a day; in coughs, hoarseness, asth- ma, &.C. MIXTURE, FEBRIFUGE. Syn. M. Feb- rifuga. (See Mixture, Diaphoretic.) MIXTURE, GENTIAN, (compound.) Syn. M. Gentiana Composita. Prep. (P. L.) Cim- | pound infusion of gentian f ^xij; compound in- MIX 431 MIX fusion of senna f §vj; compound tincture of carda- moms f 5'j 5 mix. Tonic, stomachic, and aperient. Dose. 2 to 3 tablespoonfuls, in dyspepsia ac- companied with constipation. MIXTURE, GUAIACUM. Syn. M. Guaiaci. (P. L. & E.) Prep. I. (P. L.) Gum guaiacum 3iij; sugar ^ss ; triturate together, add mucilage fgss, again triturate and further add cinnamon water r%xix; mix well. Dose. 1 to 3 table- spoonfuls, 2 or 3 times a day; in chronic rheu- matism, gout, &c. II. (Alkaline.) Guaiacum and quicklime, of each 1 oz.; triturate together, and add water 1 pint III. (Ammoniated.) Guaiacum 3ij; carbonate of ammonia 3iiss ; barley water §viij. Dose. 1 to 2 tablespoonfuls 2 or 3 times a day. MIXTURE, GUM. Syn. Mucilage. Mu- cilage DE GOMME ARABIQUE, (Fr.) SCHLIEIM DE Arabiche Gummi, (6?er.) Mucilago, (P. E.) Mistura Acacia, (P. L.) M. Gummi Arabici, (P. D.) Prep. I. (P. L.) Powdered gum acacia §x; boiling water 1 pint; rub together till dis- solved. The P. E. & D. order the gum un- powdered. Used to render oily and resinous sub- stances iniscible with water. " Oils require f their weight; balsams and spermaceti, equal parts; resins 2 parts; and musk, 5 times its weight," for this purpose. (Montgomery.) II. (M. Acacia. P. E.) Mucilage f 3iij ; sweet almonds (blanched) ?jj 3ij; white sugar 3v ; water a quart; make an emulsion or mixture, and strain through calico. Dose. 2 to 3 table- spoonfuls, as a demulcent and emollient, ad libitum, in coughs, &c. See Almond Mixture. MIXTURE, HARTSHORN. Syn. Harts- horn Drink. M. Cornu usti. Prep. Burnt hartshorn f ij ; gum ^j j water 2J pints; boil to ^xxxij, and strain. Demulcent. Dose. 2 to 3 tablespoonfuls ad libitum, in coughs, hoarseness, &c. MIXTURE, HEMLOCK. Syn. M. Conii Comp. Prep. (Copland.) Extract of hemlock 3ss ; carbonate of soda 45 grs.; decoction of li- quorice f ^vss ; spirt of pimento f3iij;mix. Dose. 1 to 3 tablespoonfuls, in hooping-cough and pul- monary irritations. MIXTURE, HOOPING-COUGH. Syn. M. Cupri Sulphatis. Prep. (Chevasse.) Sulphate of copper 1 gr.; aniseed water fiij; sirup of pop- pies Jfj ; mix. Dose. 40 drops to 3ij. MIXTURE, IODINE. Syn. M. Iodinii. (Cum Decoct. Graminis. Iodureted Dog's Grass.) Prep. I. (Majendie.) Decoction of dog's grass fxxxij ; iodide of potassium 3j; orange sirup §ij; mix. II. (Cam Sarza.) Prep. (Majendie.) De- coction of sarsaparilla fxxxij ; iodide of potassium 3j,; orange sirup ^ij > mix. Both the above may be taken in doses of 2 to 4 tablespoonfuls 3 or 4 times a day, in the usual cases in which iodine is administered. MIXTURE, MAGNESIA, (BICARBON- ATE.) -Syn. M. Magnesia Bicarbonatis. Prep Liquid magnesia (Dinneford's or Mur- ray's) Jvj ; orange sirup, sirup of ginger, and compound tincture of cardamoms, of each 3ij ; aromatic spirit of ammonia f 3vj ; mix. Dose. 1 to 3 tablespoonfuls every 2 or 3 hours in acidity, dyspepsia, heartburn, lowness of spirits, &c. An excellent medicine. MIXTURE, MARSHMALLOW. Syn. M, Althaa. Prep. (P. E.) Marshmallow root £iv; stoned raisins §ij ; water 5 pints ; boil to 3 pints, and strain through linen. Demulcent Dose. A few spoonfuls ad libitum, so as to take I to 3 pints in the 24 hours ; in strangury, calculus, coughs, &c. MIXTURE, MUSK. Syn. M. Moscm Prep. (P. L.) Musk, powdered gum, and sugar, of each 3iij ; triturate well together, then add gradually, rose water 1 pint, still continuing the trituration. Each fluid ounce contains 9 grains of musk. Dose. 2 to 4 tablespoonfuls, as a stimu- lant, antispasmodic, and anodyne; in hysteria, epilepsy, chorea, tetanus, low fevers, &c. MIXTURE, MYRRH. Syn. M. Myrrha. Prep. (Copland.) Myrrh 3iss; add gradually, triturating all the time, decoction of liquorice f ^vj ; strain. Dose. 1 to 2 tablespoonfuls twice or thrice a day, combined with carbonate of soda, dilute muriatic acid, or paregoric, in debility, and diseases of the digestive organs. MIXTURE, NARCOTIC. Syn. M. Nar- cotica. Prep. (W. Cooley.) Laudanum 3iss; sirup of poppies, sulphuric ether, and spirits of cin- namon, of each ^j i tincture of henbane, 3iiss ; water §iiss; mix. Dose. 1 to 2 tablespoonfuls at the commencement of the hot fit of ague. MIXTURE, OIL. Syn. M. Olei Amygdala. Prep. (St. B. H.) Oil of almonds and mucilage, of each §iss; triturate, and add gradually water §v. Demulcent, emollient. Dose. 2 or 3 table- spoonfuls occasionally. The M. Olei cum Man- na is made by substituting manna §iss, for the gum. MIXTURE, OPIATE. Syn. M. Opiata. Prep. Laudanum f3ij ; solution of acetate of am- monia and water, of each f iij ; mix. Dose. 1 to 2 tablespoonfuls to relieve pain, and procure sleep in fevers, &c. MIXTURE, PHOSPHORUS. Syn. M. Phosphori. Prep. (Soubeiran.) Phosphorized oil 3ij; mucilage 3iv; triturate together, adding gradually sirup §ij; and peppermint water §iij. MIXTURE, PRUSSIC ACID. Syn. M. Acidi Hydrocyanici. Prep. Medicinal prussic acid 15 minims ; simple sirup §j ; water ^v ; mix. Dose. 1 tablespoonful 2 or 3 times daily. Each dose contains 1| drops of medicinal prussic acid.— *#* Shake the bottle before pouring out the,dose. MIXTURE, PURGING. Syn. M. Purgans, Prep. Any of the purging salts §ij; infusion of senna %v; sirup of orange-peel Jj i tincture of ginger §ss ; spirit of pimento 3ij ; mix. Dose. 1 to 3 tablespoonfuls early in the morning ; in stom- ach complaints, &c. MIXTURE, REFRIGERANT. Syn. M. Refrigerans. Prep. Borax 3ij ; solution of ace- tate of ammonia § j; lemon-juice § ivss ; sweet spirits of nitre 3iij ; mix and dissolve. Diuretic, diaphoretic, and cooling, in colds accompanied with fever, &c. Dose. 1 or 2 tablespoonfuls 2 or 3 times a day. MIXTURE, RHUBARB. Syn. M. Rile. Prep. I. (M. Rhai Comp. Gregory's Mixture.) Compound powder of rhubarb (P. E.) 3iij; pepper- mint water f §rvj ; mix. MIX 432 MIX II. (Sprague.) Powdered rhubarb and carbon- ate of soda, of each 3iss ; decoctiou of liquorice f §viss ; tincture of orange peel (or orange sirup) 3vj ; mix. Both the above are excellent stomach- ics and mild aperients. Dose. 1 to 3 tablespoon- fuls 2 or 3 times a day. MIXTURE, SALINE. (Febrifuge.) Syn. M. Salina febrifuga. Prep. Bicarbonate of po- tassa 3ij ; nitre 3ij; sirup 3iij ; lemon-juice f §ij ; sweet spirits of nitre 3iss; water ^iiiss ; mix. Dose. 1 to 3 tablespoonfuls in fevers, &c. MIXTURE, SCAMMONY. Syn. M. Scam- monii. Prep. I. (P. E.) Resin of scammony 7 grs.; unskimmed milk f ^iij ; gradually mix, tritu- rating all the time, so as to form an emulsion. Purgative. Dose. One half. II. (Planche's Purgative Potion.) To the last add white sugar 3ij, and cherry laurel (or bitter almond) water 4 drops. This is the most tasteless and pleasant purgative that can be taken. MIXTURE, SEDATIVE. Syn. M. Seda- tiva. Prep. Aromatic confection 3iij ; mucilage and spirit of sal volatile, of each 3ij ; tincture of asafcetida and sirup of poppies, of each %ss ; lauda- num and tincture, of henbane, of each 3iss ; water f ^iiiss ; mix. Dose. 1 to 2 tablespoonfuls 2 or 3 times a day. MIXTURE, SENNA. Syn. Black Draught. M. Sf.nVia. M. Si;nna Composita. Prep. (Guy's H.) Senna and mint, of each §j ; boiling water §xxxij ; infuse for 2 hours, strain, and add Epsom salts ^vj; shake till dissolved. Dose. 1 to 2 oz. Purgative. See Black Draught. MIXTURE, SQUILL. Syn. M. Scilla. Potion Scillitique. Prep. (P. Cod.) Oxymel of squills 3iv ; hyssop water f iij; peppermint wa- ter ^j > sweet spirits of nitre ^ss. Expectorant. Dose. 1 to 2 tablespoonfuls 3 or 4 times a day, in coughs, asthma, &c. MIXTURE, STEEL. Syn. Griffith's Mix- ture. Compound Iron Mixture. M. Ferri Composita, (P. L. E. and D.) M. Ferri Protox- ydi. Prep. I. (P. L.) Carbonate of potash 3j ; powdered myrrh 3ij ; spirit of nutmeg §j; triturate together, and while rubbing, add gradually sugar 3ij ; rose water f ^xviij ; mix well; then add sul- phate of iron (powdered) 9iiss, and place it at once in a bottle, which must be kept closely cork- ed. Dose. 1 to 2 oz., 3 or 4 times a day, as a mild and genial tonic and stimulant, when there is no determination of blood to the head. II. (Donovan.) Sulphate of iron 3iv ; calcined magnesia 3ij; water ^vj ; tincture of quassia f 3ij ; mix in a bottle, cork close, and agitate. It must be kept from the air. Dose. 1 to 2 tablespoonfuls, as last. III. (M. Ferri Aromatica, P. D. Heberden's Ink. Atramentum Heberdii.) Powdered cin- chona ^j j bruised calumba root 3iij; bruised cloves 3ij ; iron filings 588 > peppe-mint water ^xvj; di- gest in a close vessel for 3 days, agitating frequent- ly, then strain, and add tincture of cardamoms (comp.) §iij; tincture of orange-peel 3iij. Bitter, stomachic, and aromatic. Dose. 1 or 2 table- spoonfuls, or more, 3 or 4 times a day. MIXTURE, STIMULANT. Syn. M. Stim- dlans. Prep. I. Carbonate of ammonia 3ss ; pep- permint water %v; orange sirup 3vj; tincture of cardamoms (comp.) 3ij; mix. Dose. 1 table- spoonful for lowness of spirits, vapors, and when the patient is faint II. Camphor julep ^iv ; ether, spirit of aniseed, and tincture of cardamoms, (comp.,) of each 3iij ; sirup fj; tinctures of tolu and ginger, of each 3j; peppermint water ^iss ; mix. Dose. As last. In lowness of spirits, &c, accompanied with heart- burn, colic, or flatulence. MIXTURE, STRYCHNINE. Syn. M. Strychnia. Prep. (Majendie.) Pure strychnine 1 gr.; white sugar 3ij ; acetic acid 3 drops; wa- ter f^ij; mix. Dose. A teaspoonful night and morning: in palsy. Each f3 contains one-six- teenth gr. of strychnine. MIXTURE, TARTAR EMETIC. Syn. M. Antimonii Potassio-tartratis. Prep. Antimo- nial wine and simple sirup, of each §ss j njtre g-j. camphor julep §v ; mix. Diaphoretic. Dose. 1 dessert-spoonful every 2 hours. MIXTURE, TONIC. Syn. Strengthening Mixture. M. Tonica. Prep. I. (Collier.) De- coction of bark ffvss; tincture of do. fS-iij ; aro- matic confection 3j ; aromatic spirit of ammonia f 3j; mix. II. (Thomson.) Infusion of calumba f^vss; compound tincture of cinnamon and orange sirup, of each f 3ij; mix. III. Infusion of cascarilla %v; tincture of or- ange peel 3vij ; aromatic sulphuric acid 3ij; mix, Dose. 1 to 3 tablespoonfuls 2 or 3 times a day; in debility of the digestive organs, to check severe vomiting, &c. MIXTURE, TURPENTINE. Syn. M. Ter- ebinthina. Prep. (Carmichael.) Oil of turpen- tine ^j 5 yelk of one egg ; triturate together; add confection of almonds jj; again triturate, and fur- ther add, gradually, orange sirup §ij ; compound tincture of lavender f 3iv ; oil of cinnamon 4 drops; water f §iv. In iritis. MIXTURE, VALERIAN. Syn. M. Vale- riana. Prep. (St B. H.) Bruised valerian root 3ij; boiling water £ pint; macerate 2 hours; strain, and add, powdered valerian 3iv. Anti- spasmodic. MIXTURE, WHORTLEBERRY. Syn. M. Uva Ursi. Prep. I. Infusion of whortleberry leaves ^viiss ; carbonate of potash 3ij ; extract of hemlock 20 grs.; sirup of poppies 3;j ; tincture of ginger 3iij; mix. Dose. 2 to 3 tablespoonfuls in chronic diseases of the urinary organs. II. Infusion of whortleberry leaves ^viiss ; dilute sulphuric acid 3ij ; tincture of digitalis 3j; sirup of poppies 3iij ; mix. Dose. As last. In chronic inflammation of the larynx, trachea, and mucous membranes of the urinary organs. MIXTURE, WORM. Syn. M. Vermifuga Prep. I. (Collier.) Sulphate of iron 9j ; infusion of quassia f ^viij ; mix. Dose. Two tablespoon- fuls every morning fasting. II. (Richard.) Root of male fern Jj ', water 3jx ; boil to ^vj, strain, and add sulphuric ether 3j ; sirup of tansy ^j- III. (Copland.) Valerian 3ij; wormseed 3iv; boiling water ^viij ; macerate 1 hour ; strain, and add, asafcetida 3j, previously triturated with the yelk of one egg. MIXTURE, ZINC. Syn. M. Zinci Sulpha- tis. Prep. (Collier.) Sulphate of zinc 5 grs.; sulphate of quinine 10 grs.; compound infuxion MOL 433 MOR of roses f ^ij; mix. Tonic. %» " I have found this mixture very efficacious in the cure of bark- ing (gastric ?) coughs manifestly of a spasmodic character." (Collier's Pharm., p. 178.) Dose. A teaspoonful 2 or 3 times a day in a glass of water. MOCHLTQUE DES FRERES DE LA CHARITE. Prep. Finely-powdered glass of an- timony 1 oz.; white sugar 2 oz.; triturate together. Dose. 20 to 30 grs.; said to be a specific in lead colic. MOIREE METALLIQUE. Syn. Crystal- lized Tin. This is produced by the action, for a few seconds, of dilute nitro-muriatic acid on tin gently heated, then washing in hot water, drying, and lacquering. The degree of heat and the strength of the acid modify the appearance. The following is the most approved method of produ- cing this effect:—The plate iron to be tinned is dipped into a tin-bath, composed of 200 parts of pure tin, 3 parts of copper, and 1 part of arsenic. Thus tinned, the sheet iron is then submitted to the seven following operations:—1. Immersing in lye of caustic potassa, and washing.—2. Immersing in diluted aqua regia, and washing.—3. Immersing in lye of caustic potassa, and washiug.—4. Quick- ly passing through nitric acid, and washing.— 5. Immersing in a lye of caustic potassa, and washing.—6. Immersing in aqua regia, and wash- ing.—7. Immersing in a lye of caustic potassa, and washing. The coat of oxide must be entirely removed at each washing, and the last washing should be in hot water. The varnish recommend- ed is copal in spirit. (Herberger.) MOLUCCA, BALM OF. Prep. Clean spirit (22 u. p.) 1 gallon; bruised cloves £ oz.; bruised mace | dr.; infuse for a fortnight in a corked bot- tle or carboy, then filter, color with burnt sugar, and add lump sugar 4£ lbs., dissolved in pure water £ gallon ; mix well and bottle. A pleasant cordial. MOLYBDENUM. Syn. Molybdena. Mo- LYBDENE, (Fr.) MoLYBDAN, (Ger.) MOLYBDENUM, (Lat, from i*o\v6ios, lead, because its ore was first supposed to be plumbago.) A very rare metal, having a white color, and the sp. gr. of about 8*625. It is brittle and very infusible. It was discovered by Hielm in 1782. It is obtained by exposing mo- lybdic acid, mixed with charcoal and placed in a covered crucible, to the strongest heat of a smith's forge. With oxygen it forms a protoxide and binoxide, and molybdic acid. With chlorine it forms a protochloride and bichloride. With sul- phur it unites to form 2 or more sulphurets. The only one of the above that possesses any practical interest is molybdic acid. MOLYBDIC ACID. Syn. Acidum Molybdi- OUM. Prep. I. Digest finely-powdered sulphuret of molybdenum ore in nitromuriatic acid until completely decomposed, then briskly heat the residue. A white heavy powder. II. Well roast native sulphuret of molybdena ; powder, dissolve in water of ammonia, and precip- itate with nitric acid. Small white scales. Prop., <$*c Soluble in 570 parts of water, and Ihe solution reddens litmus paper ; dissolves in the alkalis forming alkaline molybdates, from which it is again precipitated by strong acids. It is used In the preparation of molybdenum blue. MONOCHROMATIC LAMP. A lamp fed with a mixture of a solution of common salt and spirit of wine. It gives a yellow light, and makes every object illuminated by it, appear either yel- low or black. (Brewster.) MONTANIN. The bitter principle of St. Lu- cia bark. MORDANTS, (IN DYEING.) Substances employed to fix the coloring matters of dye-stuffs oil organic fibres. The principal mordants are alumina, and the oxides of iron and tin. See Dye- ing and Calico Printing. MOROXYLIC ACID. A sour principle ob- tained by Klaproth from the bark of the white mulberry, (morus alba.) It is found under the form of moroxylate of lime. MORPHIA. Syn. Morphina. Morphium. Mor- phine, (Fr.) Morphin, (Ger.) Morphia, (Lat, from Morpheus, the god of sleep.) The hypnotic principle of opium. It was discovered by Ludwig in 1688, but it was first obtained pure, and its pre- cise nature pointed out by Sertuerner in 1804. Morphia is peculiar to the poppy tribe. Prep. I. (P. L.) Muriate of morphia §j', water 1 pint; dissolve and precipitate with liquor of am- monia f3v, (or q. s.,) previously diluted with water §j, employing agitation; wash the precipitate in distilled water, and dry at a gentle heat. Remarks. By a similar process morphiate may be obtained from its other salts. Good opium yields from 10 to 13$ of morphia. II. (Merck.) Precipitate a cold aqueous infusion of opium by carbonate of soda in excess, wash the precipitate first with cold water and then with cold alcohol of 0-85 ; dissolve in weak acetic acid, filter through animal charcoal, precipitate with ammonia, again wash with cold water, dissolve in alcohol, and crystallize. A good process where al- cohol is cheap. (See Opium.) Prop. As prepared above, it is a snow-white crystalline powder; but when crystallized in alco- hol, it forms brilliant prismatic crystals of ada- mantine lustre. It exerts an alkaline reaction on test paper, and imparts a perceptible bitter taste to water. It is scarcely soluble in water and ether, but freely so in alcohol; it also dissolves in the fixed and volatile oils, and in solutions of the alka- lis. With the acids it forms salts, which are most- ly soluble. These may be made by the direct ro- tation of the alkaloid in the dilute acid. The only ones of importance are the acetate, sulphate, and muriate. Uses. Morphia and its salts are exhibited either in substance, made into pills, or in solution; or ex- ternally, in fine powder applied to the dermis, de- nuded of the cuticle. They are principally ern- ployed as anodynes and hypnotics in cases in which opium is inadmissible. Dose. i. to \ gr.; externally £ to 1 i grs. Pure morphia is chiefly used to make the acetate and its other salts. Pur. Pure morphia is scarcely soluble in cold water, sparingly so in boiling water, and readily so in alcohol. This solution is alkaline to test paper, and by evaporation leaves crystals, which are wholly dissipated by heat. It is soluble m pure potassa. (P. L.) Tests. Morphia and its salts are,—1. Reddened by nitric acid, and form orange red solutions, darkened by ammonia in excess, and ultimately MOR 434 MOR turning yellow, with the production of oxalic acid. —2. They are turned blue by sesquichlonde of iron, either at once, or on the addition of an alkali, and this color is destroyed by water, and by alka- lis, or acids in excess.—-3. Iodic acid added to their solutions, turns them yello vish brown, by setting iodine free, and the liquid forms a blue compound with starch.—4. Alkaline carbonates produce a white precipitate soluble in acetic acid.—5. The pure alkalis also produce a white precipitate solu- ble in acetic and in excess of the precipitant. MORPHIA, ACETATE OF. Syn. Morphia Acetas, (P. L. and E.) Prep. (P. L.) Morphia 3vj ; acetic acid f 3iij ; distilled water f^iv; dis- solve the morphia in the mixed fluids, filter, gently evaporate, and crystallize. Remarks. The acetate of morphia of commerce is usually in the form of a whitish powder, and is prepared by the mere evaporation of the solution to dryness by a gentle heat. During the process a portion of the acetic acid is dissipated, and hence this preparation is seldom perfectly soluble in wa- ter, unless it be slightly acidulated with acetic acid. Anodyne, and hypnotic. Dose. J to £ gr., in fevers and other inflammatory disorders where opium is inadmissible. Pur. '• 100 measures of a solution of 10 grs. in f ^ss of water, and 5 minims of acetic acid, heated to 212° and decomposed by a very slight excess of ammonia, yield by agitation a precipitate which, in 24 hours, occupies 15$ measures of the liquid." (P.E.) MORPHIA, HYDROCHLORATE OF. Syn. Muriate of Morphia. Morphia Hydrochloras, (P. L.) Morphia Murias, (P. E.) Prep. (P. I-.) Macerate sliced opium lb.j, in water 4 pints for 30 hours, then bruise it, digest for 20 hours more, and press it; macerate what remains a second and a third time in water until exhausted; mix the liquors, evaporate at 140° to the consistence of a sirup, add water 3 pints, and after defecation de- cant the clear; gradually add to this liquid crys- tallized chloride of lead ^'j, (or Q* s->) dissolved in boiling water 4 pints, till it ceases to produce a pre- cipitate ; decant the clear, wash the residuum with water, and evaporate the mixed liquids as before, that crystals may form. Press the crystals thus obtained in a cloth, then dissolve them in water 1 pint, add freshly-burnt animal charcoal ^iss, digest at 120°, filter, wash the residue of charcoal, and cautiously evaporate the mixed liquors, that pure crystals may form. To the decanted liquor, from which the crystals were first separated, add water 1 pint, and drop in solution of ammonia, frequent- ly shaking, till all the morphia is precipitated; wash the precipitate with distilled water, saturate it with muriatic acid, digest with animal charcoal ^ij, filter, wash the filter as before, and evaporate the mixed liquors, cauti:;j sly, as above, that pure crystals may be produced. II. (P. E.) Exhaust opium ^xx, with water 1 gallon, in the quantity of a quart at a time, as above ; evaporate the mixed liquors over the vapor bath to 1 pint, add muriate of lime ^j. dissolved in water f fiv, mix, and set the liquid aside to settle ; then decant the clear, wash the sediment with wa- ter, add the washings to the other liquid, and evap- orate sufficiently as before, that it may solidify on cooling ; subject the cooled mass to very strung pressure in a cloth, redissolve the cake in warm water, add a little powdered white marhle, filter, acidulate with muriatic acid, and again concen- trate in the vapor bath for crystallization ; subject the crystals as before to powerful pressure, redis- solve, and clarify with powdered marble and muri- atic acid, and concentrate and crystallize until a snow-white mass be obtained. The above is the process of Gregory and Robertson, and is one of the easiest and most productive on the large scale. To procure the salt quite white, 2 to 4 crystalliza- tions are required, according to the power of the press employed. The Edinburgh College recom- mends, on the small scale, the solution after 2 crystallizations to be decolored by means of ani- mal charcoal, but, on the large scale, to purify the salt by repeated crystallizations alone. III. (Mohr.) Quicklime 1 part; reduce it to a milk with water, and add it to a concentrated in- fusion of opium made with opium 4 to 6 parts; boil for a short time, filter while hot through linen, gently evaporate till the solution becomes of only double the weight of the obium "mployed, and while still hot, add powdered sal .jnnioniac in slight excess, (about 1 oz. to eachpojnd of opium;) on cooling, colored crystals of muriate of morphia will be deposited, and must be purified by a second solution in lime and precipitation by sal ammoniac. This process is remarkably simple, and in many points is preferable to either of the preceding, es- pecially on the small scale. Pur., Uses, <$-c. Pure muriate of morphia is "snowy white; entirely soluble; solution color- less; loss of weight at 212° not above 13g; 100 measures of a solution of 10 grs., in water f ^ss, heated to 212°, and decomposed with agitatioii by a faint excess of ammonia, yield a precipitate which, in 24 hours, occupies 12£ measures of the liquid." (P.E.) Dose. One-sixth to one-half gr., as an anodyne and narcotic. Remarks. The opium which yields the largest quantity of precipitate by carbonate of soda, yields muriate of morphia, not only in the greatest pro- portion, but also with the fewest crystallizations. Smyrna opium contains most morphia. The mu- riate of morphia of the shops is usually, like the acetate, under the form of powder. Of all the salts of morphia, the muriate appears to be the most suitable for medical purposes. MORPHIA, MECONIATE OF. Prep. I. (Neutral.) Saturate meconic acid with morphia, evaporate, and crystallize. II. (Bimeconate.) Dissolve 288-J grs. of morphia in an aqueous solution of 202 grs. of meconic acid, evaporate and crystallize ; or merely gently evap- orate to dryness. Remarks. Tho meconic acid for this purpose may be obtained by precipitating a cold and filter- ed infusion of opium by acetate of lead, washing the precipitate with water, suspending in pure wa- ter, decomposing it by sulphureted hydrogen, fil- tering, evaporating, and crystallizing. Morphia exists in opium under the form of bimeconate, and hence this preparation has been preferred by some practitioners. A solution of this salt for medical purposes may be directly prepared from opium, by treating its infusion in cold water with a little ani- mal charcoal, filtering, gently evaporating to dry- ness, redissolving in cold water, filtering, and re- MUC 435 MUR peating the treatment with animal charcoal. The dose of the dry bimeconate is 4, gr. or more; and of the meconate rather less MORPHIA, SULPHATE OF. Syn. Mor- phia Sulphas. Prep. Saturate very dilute sul- phuric acid with morphia, evaporate to one half, add a little animal charcoal, continue the evaporation for a short time longer at a gentle heat, filter while hot, and abandon it to spontaneous evaporation. It is decomposed by driving off the water of crystal- lization. Anodyne and narcotic. Dose, i to £ gr. MORSULI ACETI. Prep. White sugar 1 lb.; form into lozenges with acetic arid 2 oz. MORSULI AROMATICI. Prep. White su- gar 1 lb.; dissolve in a little water, boil to a full candy height, and when half cold, add blanched sweet almonds and orange peel, of each 1 oz.; cinnamon i oz.; ginger 9j ; all cut into small pieces ; form into drops or iozenges. MORSULI CITRI. Prep. White sugar 1 lb.; lemon juice 2$ oz.; oleosaccharum of lemons 4 oz.; mix, divide, and dry. Remarks. The above morsuli are used as loz- enges or masticatories. The word morsulus signi- fies a little mouthful. MOSAIC GOLD. Syn. Or Molu. Prep. (Parker and Hamilton's patent.) Copper and zinc equal parts ; melt together at the lowest pos- sible temperature at which copper will fuse, and stir so as to produce a perfect admixture of the metals ; then add gradually, small portions of zinc at a time, until the alloy acquires the proper color, which is perfectly white, while in the melted state. It must then be at once cast into figured moulds. This alloy should contain from 52 to 55§ of zinc. MOUTH GLUE. Syn. Indian Glue. Colle a Bouche. Prep. Best cake glue q. s. ; dissolve in a little water, add brown sugar a small quantity, and some essence or juice of lemons, pour it into greased moulds, and dry it. When used, it is wetted with the tongue, and rubbed on the paper to be joined. (See Glue, Portable.) MOXAS. Substances burnt upon the body, for the purpose of acting as counter-irritants, and al- laying deep-seated pains, and inflammation. They have been used in gout, rheumatism, &c. The small cone constituting the moxa, is placed upon the part, lighted, and allowed to burn to its base. The Chinese moxas are made of the downy por- tion of the leaves of a species of wormwood, (arte- misia sinensis ;) but various other substances, as the pith of the sunflower, cotton, or paper, soaked in a weak solution of nitrate, chlorate, or chro- mate of potash, will answer as well. The actual cautery is said to be preferable. MUCIC ACID. Syn. Saccholactic Acid. An acid discovered by Scheele, and obtained in a state of purity by digesting 1 part of sugar of milk in 4 parts of nitric acid, (sp. gr. 1-42,) diluted with 1 part of water, and applying heat till the effer- vescence ceases ; on cooling, the acid is deposited. Gum may be substituted for sugar of milk, but yields a less pure acid. Mucic acid is a white, crystalline powder, soluble in boiling water and in oil of vitriol, to which it imparts a crimson color. By dry distillation it yields pyromucic acid, and other products ; with the bases it forms salts called mucates. The alkaline mucates are soluble,— the earthy and metallic mucates insoluble. MUCILAGE. Syn. Mucilago, (Lat) An aqueous solution /of gum, or any similar sub- stance. MUCILAGE, GUM. (See Gum Mixture.) MUCILAGE, QUINCE. (See Decoction of Quince Seeds.) MUCILAGE, STARCH. (See Decoction of Starch.) MUCILAGE OF TRAGACANTH. Syn. Mucilago tragacantha. Prep. (P. E.) Traga- canth 3ij ; boiling water f ^ix ; macerate 24 hours, triturate, and press through linen. Used to make up pills, to suspend heavy powders in liquids, as an application to burns, &,c. MUDARINE. A peculiar substance possess- ing powerful emetic properties, found in the bark of the root of calotropis mudarii, (Mudar.) It is soluble in water and alcohol, and its aqueous so- lution gelatinizes when heated. MUFFINS. Prep. Flour 1 quartern ; warm milk and water 1£ pint; yeast 4/ pint; salt 2 oz.; mix for 15 minutes, then further add flour \ peck, make a dough, let it rise 1 hour, roll it up, pull it into pieces, make them into balls, put them in a warm place, and when the whole dough is made into balls, shape them into muffins, and bake them on tins ; turn them when half done, dip them into warm milk, and bake to a pale brown. MULTUM. A mixture of extract of quassia and liquorice used by fraudulent brewers instead of malt and hops. MUM. A beverage prepared from wheat malt, in a similar way to ordinary beer from barley malt. It was formerly much drunk in England ; but its use at the present day is chiefly confined to Germany. MUMMY. The mixed resinous mass with which the Egyptian corpses have been preserved, reduced to powder. Used by artists ; a good glazing color, but dries slowly. Burnt Prussian blue, or a mixture of asphaltum and burnt sienna melted together, are good substitutes. MUREXIDE. Syn. Purpurate of Ammonia. Prep. Hydrated alloxan 7 grs.; alloxantine 4 grs.; water 240 grs. ; dissolve by boiling, and add the solution to 80 grs. measure of a cold and strong solution of carbonate of ammonia ; crystals of mu- rexide will deposite as the liquid cools. It forms iridescent crystals, having a metallic lustre. It is soluble in boiling water, (Gregory and Liebig.) When murexide is dissolved in a solution of caustic potassa, heat applied till the blue color disappears, and dilute sulphuric acid added in excess, silky crystalline scales are deposited, which are called Murexan or Purpuric Acid. It is soluble in am- monia and the fixed alkalis, and its solution in the former by exposure to the air becomes purple, and deposites brilliant crystals of murexide. MURIATE. Syn. Hydrochlorate. Mu- rias ; Hydrochloras, (Lat.) A compound of a base and muriatic acid. From the discoveries of Davy, and the more recent researches of various continental chemists, it appears probable that the muriates or hydrochlorates are direct compounds of the bases and chlorine, or are in reality chlo- rides, of which hydrogen or water is not an essen- tial part Most of the Muriates may be made by directly saturating the acid with the base, or with its hydrate, oxide, or carbonate, and evaporating MUR 436 MUR and crystallizing. (See Chlorides, Chlorine, and Muriatic Acid.) MURIATIC ACID. Syn. Hydrochloric Acid. Chlorohydric do. Marine Acid. Acid of Salt. Spirit of Salt. Acidum Hydrochlo- ricum, (P. L.) Do. Muriaticum, (P. E. & D.) Spiritus Salis. Acide muriatique ; Acide hy- DR0CHL0RI0.UE ; AdDE CHLOROHYDRIftUE, (Fr.) Salzsaure, (Ger.) An acid compound of chlorine and hydrogen, long known in the state of solution, under the name of marine acid or spirit of salt ; but first obtained in the pure or gaseous form by Priestley, in 1-772. Prep. I. (P. L.) Sulphuric acid %xx ; water §xij ; mix in a retort, and when cold add to it dried chloride of sodium lb. ij ; and gradually distil in a sand-bath into a receiver containing water f §xij. Sp. gr. 1*160. II. «(P. E.) Dried purified muriate of soda and pure sulphuric acid, of each 3 parts ; water 1 part ; mix as last, and distil with a gentle heat into a well-cooled receiver containing water 2 parts, as long as any liquid passes over. Sp. gr. 1*170. III. (P. D.) Sp. gr. 1160. IV. (Winckler.) Dry and pure chloride of so- dium 24 parts ; pure oil of vitriol 44 parts ; diluted with water 7 parts, and allowed to cool; mix in a large retort, and connect it by a rectangular bent glass tube, at least 3 feet long, with a capacious receiver, containing 20 parts of water, and well cooled. Distil 44 oz. of 30$ by weight. V. (Gregory.) Dry and pure salt 60 parts ; pure sulphuric acid 98 parts, diluted with water to the sp. gr. 1-6 ; mix in an alembic furnished with a double-bent tube, the end of which is plunged about $ of an inch beneath the surface of the water in the receiver, (about 35 parts ;) the latter must be well cooled. Prod. The first § is a fuming acid, sp. gr. 1*21—the last £ about sp. gr. 1*12. Remarks. The muriatic acid of commerce is now chiefly obtained from the manufacturers of carbonate of soda, who procure it as a secondary- prod uct When, however, it is directly prepared from sea-salt, an iron or stoneware boiler, set in brickwork over an open fire, furnished with a stoneware head, and connected with a series of capacious double-necked stoneware bottles, usu- ally constitutes the distillatory and condensing ap- paratus. The arrangement resembles that em- ployed in the preparation of liquor of ammonia, (see page 58.) The formula of the London Col- lege is defective in ordering too little acid, by which means the product becomes contaminated with a portion of sulphuric acid, and the residue of the process rendered so hard and insoluble as to pre- vent its removal from the retort by ordinary means. The products of the other formulae (II, IV, and V) are pure liquid hydrochloric acid, provided the ma- terials employed be quite free from foreign admix- ture. Commercial muriatic acid may be purified by diluting it with an equal weight of water, gently heating it in a retort, and receiving the evolved gas into a fresh quantity of pure water. Iodine and arsenic may be removed by agitating it for a few minutes with some small pieces of bright cop- per foil previously to rectification. Commercial muriatic acid of the ordinary strength may b» bought for 0|d. per lb. in quantity. Prop. Pure muriatic acid is a colorless invisible gas, having a pungent odor and an acid taste, and fuming on coming into contact with air. It is irre- spirable and uninflammable. Its sp. gr. is 1*2695, (Berzelius.—1-2847 Thomson.) Under a pressure of 40 atmospheres it is liquid. Water at 40° F. absorbs 4ti0 times its volume of this gas, and ac- quires the sp. gr. 1*2109, (Davy.) One cubic inch of water at 69° F. absorbs 418 cubic inches, and the sp. gr. becomes 1*1958, (Thomson.) The gas is obtained by gently heating the liquid acid. It must be collected over mercury. Pure liquid muriatic acid is colorless, fumes in the air, evolves a strong odor of muriatic acid gas, is intensely 60ur, reddens vegetable blues, and erodes organic substances. It is entirely separated by heat from the water that holds it in solution. It dissolves many of the metals with the evolution of hydrogen gas; it also dissoi -?s metallic oxides, and the majority of the bases, tneir hydrates, and carbonates ; in each case forming the compounds termed chlorides, muriates, chlorohydrates, or hydrochlorates. The acid of the L. Ph. has the sp. gr. 1*160, and consists of 3232°; of real muriatic acid, and 67-68°; of water. 100 grs. of it should exactly saturate 132 grs. of crystallized carbonate of soda. The muriatic acid of commerce has gen- erally a straw yellow color. Uses. Muriatic acid is used for various purposes in the arts, in chemistry, and in medicine. It is refrigerant, tonic, and antiseptic, in small doses diluted with water ; but corrosive and poisonous in larger doses, or undiluted. Dose. 10 to 20 drops in a sufficient quantity of any bland diluent, in stomach complaints, typhus fever, syphilitic affec- tions, worms, scrofula, &c. It is also used in gar- gles and lotions. Ant. Chalk, whiting, or magnesia, mixed with water, or milk, white of eggs, and demulcents. Pur. Pure muriatic acid is " colorless, and to- tally dissipated by heat. Largely diluted with dis- tilled water, the solution is unaffected by chloride of barium, (or calcium,) ammonia, or its sesqui- carbonate. It does not dissolve gold leaf even when heated. It does not bleach the solution of sulphate of indigo." (P. L.) Commercial muriatic acid usually contains iron and sulphuric acid, and frequently chlorine, nitrous acid, bromine, and sometimes selenious acid. The first may be de- tected by the precipitate it forms when the acid is supersaturated by ammonia,—the second, by giv- ing a white precipitate with chloride of calcium or barium, or with the nitrate of lime or baryta,— the third, fourth, and fifth, by the power the acid possesses of dissolving gold leaf, and decoloring solution of indigo,—and the last, by the acid de- positing a reddish powder (selenium) when long kept Estim. The strength of muriatic acid is usually estimated from its specific gravity ; but it may be more correctly ascertained by the power it jios- sesses to saturate the bases. See Acidimetry. MUS 437 MUS Table of Muriatic Acid, by Dr. Ure. Acid of 1-20 in 10U. Specific gravity. Chlorine. Muriatic Gas. Acid of 1-20 in 100. Specific gravity. Chlorine. Muriatic Gas. Acid of 1-20 in 100. Specific gravity. Chlorine. 12-697 Muriatic Gas. 100 1*2000 39*675 40-777 66 1*1328 26*186 26-913 32 1-0637 13-049 99 1*1982 39*278 40*369 65 1*1308 25*789 26-505 31 1-0617 12-300 12-641 98 1*1964 38-882 39*961 64 1*1287 25-392 26*098 30 1-0597 11-903 12-233 97 1*1946 38-485 39-554 63 1*1267 24-996 25*690 29 1-0577 11*506 11-825 96 1*1928 38*089 39*146 62 1*1247 24-599 25-282 28 1*0557 11*109 11*418 95 1*1910 37*692 38*738 61 1*1226 24*202 24-874 27 1*0537 10*712 11*010 94 1*1893 37-296 38*330 60 1*1206 23*805 24-466 26 1*0517 10*316 10*602 93 1*1875 36-900 37*923 59 1*1185 23*408 24-058 25 1*0497 9*919 10-194 92 1*1857 36-503 37*516 58 1*1164 23*012 23*650 24 1*0477 9*522 9-786 91 1*1846 36-107 37*108 57 1*1143 22*615 23*242 23 1*0457 9*126 9-379 90 1*1822 35-707 36*700 56 1*1123 22*218 22-834 22 1*0437 8-729 8-971 89 1*1802 35-310 36*292 55 1*1102 21-822 22-426 21 1*0417 8-332 8-563 88 1*1782 34-913 35*884 54 1*1082 21-425 22-019 20 1*0397 7-935 8-155 87 1*1762 34*517 35*476 53 1*1061 21*028 21-611 19 1*0377 7-538 7*747 86 1*1741 34*121 35-068 52 1*1041 20-632 21*203 18 1*0357 7*141 7-340 85 1*1721 33*724 34*660 51 1*1020 20-235 20*796 17 1*0337 6*745 6-932 84 1*1701 33*328 34-252 50 1*1000 19-837 20-388 16 1-0318 6*348 6*524 83 1*1681 32*931 33*845 49 1*0980 19*440 19-980 15 1*0298 5*951 6*116 82 1*1661 32-535 33-437 48 1*0960 19-044 19-572 14 1*0279 5*554 5*709 81 1*1641 32*136 33*029 47 1*0939 18-647 19-165 13 1*0259 5*158 5*301 80 1*1620 31*746 32-621 46 1*0919 18-250 18-757 12 1*0239 4*762 4*893 79 1*1599 31*343 32-213 45 1-0899 17-854 18-349 11 1*0220 4-365 4*486 78 1*1578 30*946 31*805 44 1*0879 17-457 17-941 10 1*0200 3*968 4*078 77 1*1557 30*550 31*398 43 1*0859 17-060 17-534 9 1-0180 3-571 3*670 76 1*1536 30153 30*990 42 1*0838 16-664 17126 8 1-0160 3-174 3-262 75 11515 29*757 30-582 41 1*0818 16-267 16*718 7 1-0140 2-778 2-854 74 1*1494 29-361 30-174 40 1-0798 15-870 16*310 6 1-0120 2-381 2*447 73 1*1473 28*964 29*767 39 1*0778 15-474 15*902 5 1-0100 1-984 2*039 72 1*1452 28-567 29-359 38 1*0758 15-077 15-494 4 1-0080 1-588 1-631 71 1*1431 28-171 28-951. 37 1-0738 14-680 15-087 3 1*0060 1*191 1-224 70 1*1410 27-772 28-544 36 1-0718 14-284 14-679 2 1*0040 0*795 0-816 69 1*1389 27-376 28-136 35 1-0697 13-887 14-271 1 1-0020 0-397 0-408 68 1-1369 26-979 27-728 34 1*0677 13-490 13-863 67 1*1349 26-583 27-321 33 1*0657 13094 13-456 MURIATIC ACID, DILUTE. Syn. Acidum Hydrochloricum dilutum, (P. L.) Acidum Muriaticum dilutum, (P- E.) Prop. Muriatic acid f Jiv ; distilled water f Jxij ; mix. Used for convenience in dispensing. Dose. 30 to 60 drops in simple infusion of roses or water. " The den- sity of this preparation is 1*050." (P. E.) MURIATIC ACID, HENRY'S. Prep. Mu- riatic acid diluted to sp. gr. 1*074. One measure will exactly saturate an equal quantity of his car- bonate of potash-water, or pure ammonia-water, or two measures of pure potash-water, pure soda- water, or carbonate of ammonia-water. Used in assaying mineral water, &c. MUSCLE POWDER. Oyster do. Made like cockle powder. Used to make sauces. MUSHROOMS. Edible fungi. The species commonly eaten in England are the agaricus cam- pestris, (common field or garden mushroom,) used to make ketchup, and eaten either raw, stewed, or broiled;—the morchella esculenta, (common mo- re!,) used to flavor soups and gravies ;—and the tuber cibarium, (common truffle,) also used as a seasoning. The following are said to be tests of the wholesomeness of mushrooms:— 1. Sprinkle a little salt on the spongy part or gills of the sample to be tried: if they turn yellow, they are poisonous ; if black, they are wholesome. —2. False mushrooms have a warty cap, or else fragments of membrane adhering to the upper surface, are heavy, and emerge from a vulva or bag; they grow in tufts or clusters in woods, on the stumps of trees, &c.; whereas the true mush- rooms grow in pastures.—3. False mushrooms have an astringent, styptic, and disagreeable taste.—4. When cut they turn blue.—5. They are moist on the surface, and are generally of a rose or orange color.—6. The gills of the true mushroom are of a pinky red, changing to a liver color.—7. The flesh is white.—8. The stem is white, solid, and cylin- drical.—9. " Introduce a silver spoon, or a new shilling or sixpence, or an onion, into a vessel in which mushrooms are seething ; if, on taking either of them out, they assume a dark discolored ap- pearance, the circumstance denotes the presence of poison existing among them ; if, on the other hand, the metal or onion on being withdrawn from the liquor wears its natural appearance, the fruit may be regarded as genuine, and of the right sort." The best antidote to poisonous mushrooms is V MUS 438 MYR tannin, or an infusion or decoction of galls. A strong emetic should also be given to remove them from the stomach. MUSK. Syn. Mubc, (Fr.) Moschus, (Lat. and Ger.) An odorous substance obtained from the musk deer, (moschus moschiferus,) an animal inhabiting the mountains of eastern Asia. It is imported from China, Bengal, and Russia. The Tonquin musk is most esteemed. Pod musk (Moschus in vesicis, Tonquin pods, China do., Moschos Chinensis, Do. Tonquinensis) is the bag in its natural state containing the musk. Grain musk (Moschus in granis) is the matter contained in the pods, and which constitutes true musk. The average weight of one of the pods is about 3vj ; that of the grain musk it contains about 3ij 3ij. Musk is said to be antispasmodic in doses of 3 grains and upwards. Pur. The musk of the shops is generally adul- terated. Dried bullock's blood, or chocolate, is commonly employed for this purpose. The blood is rendered dry by heat, then reduced to coarse powder, and triturated with the genuine musk in a mortar along with a few drops of liquor of am- monia ; it is then placed in the empty pods, or put into bottles, and sold as grain musk. The writer of this article has seen many pounds of dry blood thus employed, and sold for musk. There are only two ways of detecting this fraud, viz.—by the inferiority of the odor, or by an assay for the iron contained in the blood. Genuine musk often becomes nearly inodorous by keeping, but recovers its smell on being exposed to the fumes of ammo- nia, or by being moistened with ammonia water. The perfumers sometimes expose it to the fetid ammoniacal effluvia of privies for the same pur- pose. The following forms are current in trade for reducing musk, (moschus reductus .*)—1. Musk 3 oz. ; chocolate 2 oz.; ivory black 1 dr.; gently rub together in a mortar with a few drops of liquid ammonia.—2. Musk and dried goats' or bullocks' blood, equal parts; mix as last.—3. To the last add an equal part of angelica root.—4. Storax and aloes wood, of each 4 oz.; musk and civette, of each 4 dr.; mix as last.—5. Nutmegs, mace, cas- sia, cloves, and Indian nard or spikenard, of each 1 oz.; dried blood or chocolate 4 oz.; make a paste, dry, bruise to a proper fineness, and triturate it gently with ith of its weight of musk, adding a few drops of essence of musk, and ammonia wa- ter.—6. Hard toasted bread, dried blood, chocolate, and musk, equal parts; as last. *** The Chinese are said to be the most skilful adulterators of musk. MUSK, FACTITIOUS. Syn. Moschus fac- TITIUS. Do. ARTIFICIALIS. ReSIN OF AmBER. Resina Succini. Prep. Pour f 3iiiss of the strong- est nitric acid upon f 3j of oil of amber placed in a glass tumbler; digest; an orange yellow resin remains, which is to be washed in water, and care- fully dried. Remarks. Eisner recommends the addition of 1 part of rectified oil of amber to 3 parts of fuming nitric acid, in a glass or porcelain vessel, kept cold to prevent the oil being carbonized. It smells strongly of musk, and is said to be antispasmodic and nervine. A tincture is made by dissolving 3j in rectified spirit f3x. Dose. f3jr in hooping- cough, low fevers, &c *** Dr. Collier mentions aii artificial musk, pre- pared by digesting for 10 days nitric arid 3*, on " fetid animal oil, obtained by distillation, §j ; and by then adding rectified spirit 1 pint, and digesting the whole for a month." (Collier's Phar., p. 1S4.) MUST. The expressed juice of grapes before fermentation. MUST, FACTITIOUS. Prep. White sugar 2^ lbs.; cream of tartar 1 oz.; raisins chopped small, i lb.; boiling water 1 gallon ; mix, and di- gest for 2 hours, and strain. MUSTARD. Syn. Flour of Mustard. Si- napis Farina. The powdered mustard of the shops is very frequently adulterated with wheat flour. When this is the case, it does not readily make a smooth paste with water, but exhibits con- siderable toughness, and somewhat of a stringy appearance. The common proportions employed by some grocers are,—dried common salt, wheat flour, and superfine* mustard, equal parts, colored with turmeric, and sharpened with cayenne. Pure flour of mustard is used in medicine, to make poultices, &c. MUSTARD for the table, (ready made mus- tard,) is prepared as follows: 1. (M. Spyes.) Steep mustard seed in twice its bulk of distilled vinegar for 8 days, then grind the whole to a paste in a mill; put it into pots, and thrust a red-hot poker into each of them. Pat- ented. 2. (M. Lenormand.) Best flour of mustard 2 lbs.; fresh parsley, chervil, celeiy, and tarragon, of each £ oz.; garlic, 1 clove ; 12 salt anchovies; (all well chopped;) grind well togetner, add salt 1 oz.; grape juice or sugar to sweeten, and sufficient water to form the mass into a thinnish paste by trituration in a mortar. When put into pots, a red- hot poker must be* thrust in as above, and after- wards a little vinegar poured upon the surface. 3. (Moutarde a I'estragon.) Black mustard seed dried till friable, and then finely powdered, 1 lb. ; salt 2 oz.; tarragon vinegar to mix. In a similar way the French prepare several other mus- tards, by employing different vinegars. 4. (Patent.) Black ginger, bruised, 12 lbs.; common salt 18 lbs,; water 15 gallons; boil, strain, and add to each gallon, flour of mustard 5 lbs. 5. (Moutarde superbe.) Salt 1£ lb.; scraped horseradish 1 lb.; garlic 2 cloves; boiling vinegar 2 gallons; macerate in a covered vessel for 24 hours, strain, and add flour of mustard q. s. 6. To the last add a little soluble cayenne pep- per, or essence of cayenne. 7. Mustard 3 lbs.; salt 1 lb.; vinegar, grape juice, or white wine to mix. MYKOMELINIC ACID. A new acid discov- ered by Wohler and Liebig, and obtained by heat- ing to 212° a solution of alloxan with an excess of ammonia, adding dilute sulphuric acid, also in ex- cess, and boiling for a few minutes. The new acid falls as a yellow gelatinous precipitate, which dries to a yellow porous powder. MYRICINE. The portion of wax which is in- soluble in alcohol. MYRISTICINE. The stearoptene deposited by oil of nutmegs by keeping. MYRONIC ACID. Bussy has given this name to an inodorous, bitter, non-crystallizable acid found tf NAP 439 NAR by him in black mustard. It is soluble in water and alcohol. MYROSYNE. Syn. Emulsion of Black Mustard. A name given by Bussy to a peculiar substance soluble in water, and which possesses the power of converting myronic acid into the volatile oil of mustard. MYROSPERMINE. The portion of the oil of balsam of Peru which is soluble in alcohol. MYROXILINE. The portion of the oil of bal- sam of Peru insoluble in alcohol. MYRRH. Syn. Myrrha, (Lat.) The gum resin of balsamodendron myrrha. To ascertain the purity of myrrh, triturate a small quantity of the powder of the suspected myrrh with an equal amount of muriate of ammonia, adding water grad- ually ; if the whole is readily dissolved, the myrrh is true; otherwise it is sophisticated with some other substance. (Giovanni Righini.) MYRRHIC ACID. The hard resin of myrrh. It is soluble in the caustic alkalis, forming alkaline myrrhates. NAILS (THE) should be kept clean by the daily use of the nail brush and soap and water. After wiping the hands, but while they are still soft from the action of the water, gently push back the skin which is apt to grow over the nails, which will not only preserve them neatly rounded, but will prevent the skin cracking around their roots, (nail-springs,) and becoming sore. The points of the nails should be pared at least once a week; biting them should be avoided. NANKEEN DYE. Prep. Annotto and pot- ash, equal parts; water q. s.; boil till dissolved. The proportion of potash is varied according to the shade required; the alkali darkens it Used to dye nankeen color, but chiefly to restore the color of faded nankeen clothing. NAPHTHA. Syn. Mineral Naphtha. Rock Oil. Huile Petrole, (Fr.) Steinol, (Ger.) Naphtha, (Lat, from Na00a.) A limpid bitumen which exudes from the surface of the earth in va- rious parts of the world. It possesses a penetrating odor and a yellow color, but may be rendered col- orless by distillation ; it boils at about 160°, and is very inflammable. Sp. gr. 0-753 to 0-836. It does not mix with water, but imparts to that fluid its pe- culiar taste and smell. It mixes with alcohol and oils, and dissolves sulphur, phosphorus, camphor, iodine, most of the resins, wax, fats, spermaceti, and forms with caoutchouc a gelatinous varnish. It is frequently adulterated with oil of turpentine, but this fraud may be detected by the addition of some oil of vitriol, which will in that case thicken and darken it. Naphtha is chiefly employed for the purposes of illumination, as a solvent for Indian rubber, and in the preparation of a very superior black pigment. Remarks. According to the researches of Lau- rent, Pelletier, Walter, and others, mineral naph- tha is a aompound of several hydro-carbons, to which the names paraffine, naphtha, naphthene, naphthoic, &c, have been given. A similar fluid to mineral naphtha is obtained by the distillation of cc>al tar, (coal naphtha,) and is largely employed in the arts, in the preparation of coarse paints and ■famishes, and for the solution of Indian rubber. The term has also been very improperly extended to the pyroxilic spirit of commerce, (wood naphtha,) and also occasionally to pyroacetic spirit; but these liquids differ from naphtha, both in their com- position, odor, and boiling points, and in being mis- cible writh watei, and incapable of dissolving Indian rubber. The confusion arising from the above misapplication of names, may be readily imagined, when the reader is informed, that a certain physi- cian who lately made himself conspicuous by the assertion that he had cured consumption with wood naphtha, and publicly stated that the kind he em- ployed was pure pyroacetic spirit, was in reality dosing his patients with commercial pyroxilic spirit, which is quite a different article. Thus the doctor was using one compound, and from want of a practical knowledge of he matter, was directing the profession to use another. NAPHTHALAMIDE. A compound obtained by the distillation of naphthalate of ammonia. NAPHTIIALIC ACID. A crystalline sub- stance resembling benzoic acid,. btained by Laurent from naphthaline. NAPHTHALINE. A white, crystallizable, odorous, volatile substance, obtained by redistilling coal tar. It melts at 180° F., is soluble in alcohol and ether, and forms with sulphuric acid sulpho- naphthalic acid. N A R C E I A. Syn. Narceina. Narceine. (From vapxi, stupor.) A peculiar vegeto-alkaline base discovered by Pelletier in opium. It is ob- tained from the aqueous solution of opium, after it has been freed from morphia and narcotine by am- monia, and from the resulting meconate of ammo- nia by baryta. On boiling the filtered solution to expel the ammonia, and evaporating, crystals of narceia are gradually deposited. It may be puri- fied by solution in hot alcohol and crystallization. *#* White acicular prisms, inodorous, bitter, pun- gent ; soluble in 375 parts of water at 60°, and 230 parts at 212°; insoluble in ether; imperfectly neutralizes the acids. It is distinguished from mor- phia by its easier fusibility, (198°,) and by its salts in a certain degree of concentration being blue, but on gradual dilution changing to violet, and rose- red, and ultimately becoming colorless. It does not strike a blue color with sesquichloride of iron, like morphia, but forms a blue compound with starch. In opposition to its name, it appears to be nearly inert. NARCOTIC. Syn. Narcoticus. (Lat, from vapKow, to stupify.) A medicine that produces drowsiness, sleep, and stupor. In small doses, narcotics mostly act as stimulants, but in large ones they produce calmness of mind, torpor, and even coma and death. Opium, henbane, hem- lock, tobacco, camphor, alcohol, ether, &c, are narcotics. , NARCOTINA. Syn. Narcotine. Sel d opi- um ; Matiere de Derosne, (Fr.) (From »«•«.«- rtf. narcotic.) A peculiar crystalline substance found by Derosne in opium, and on which its stim- ulant property was at first supposed to depend. It may be easily obtained from opium exhausted of soluble matter by cold water, by treating ,t with water acidulated with acetic or hydrochloric acid, filtering neutralizing with ammonia, and d.ssolv- ine the washed precipitate in boiling alcohol, which will again deposite it as it cools. It may be fur- NIC 440 NIG ther purified by solution in ether. Narcotine may likewse be directly obtained by the action of ether on opium, previously exhausted by cold water. With the acids it forms salts. Narcotine is spa- ringly soluble in boiling water, but freely soluble in boiling alcohol, and in ether. It is distinguished fron* .morphia by its insipidity, solubility in ether, insolubility in alkalis, and by giving an orange tint to nitric acid, and a greasy stain to paper, when heated on it over a candle. The physiological ac- tion of narcotine is differently stated by different authorities. 1 gr. dissolved in olive oil, killed a dog in 24 hours ; but 24 grs. dissolved in acetic acid were given with impunity. (Majendie.) In the solid state it is inert; 129 grs. at a dose scarcely produce any obvious effects. (Bally.) Scruple doses have been given without injury. (Dr. Roots.) It has been recently proposed as a substitute for quinine in the cure of agues. For this purpose the sulphate is preferable. 200 cases of intermittent and remittent fevers have been thus successfully treated in India. (Dr. O'Shaughnessy.) N ECTAR. Prep. I. Chopped raisins 2 lbs.; loaf sugar 4 lbs ; boiling water 2 gallons; mix; when cold, add 2 lemons, sliced; proof spirit (brandy or rum) 3 pints; macerate in a covered vessel for 4 or 5 days, occasionally shaking, strain, let it stand in a cold place for a week to clear, and then bottle. In ten days, or less, if kept in a very cold place, it will be excellent. II. Red ratifia 3 gallons; oils of cassia and caraway, of each, 25 drops; previously dissolved in brandy £ pint; orange wine 1 gallon ; sliced oranges 6 in no.; lump sugar 2 lbs.; macerate for a week, decant and bottle. Both are used as pleasant cordials. NEGUS. Prep. I. (Red.) Port wine 1 bottle, (1£ pints;) $ nutmeg, grated; the juice of two lemons, and the yellow peel of one; lump sugar £ lb.; put the whole into a bottle, add boiling wa- ter 3 pints, cork down close, and macerate with agitation. *** Very excellent. The addition of a single drop of essence of ambergris, and 6 or 7 drops of essence of vanilla, improves it. II. (White.) From white wine, as the last %* A single glass of the above may be made by observing the same proportions. NERVOUSNESS. The cure of nervousness is best effected by restoring the healthy action of the stomach and bowels, and by the use of proper exercise, especially in the open air. The stomach should not be overloaded with indigestible food, and the bowels should be occasionally relieved by the use of some mild aperient. Abernethy's in- junction to a nervous and dyspeptic lady, " Dis- miss your servants, madam, and make your own beds," should be recollected by all as a proof of the importance that eminent surgeon attached to exercise. (See Dyspepsia, Flatulency, Hypo- chondriasis, Hysterics, &c.) NEUTRALIZATION. Syn. Neutralisatio, (Lat) The admixture of an acid and alkali in Buch proportions that neither shall predominate. A neutral compound neither turns turmeric paper brown, nor litmus paper red. NICKEL. A white, hard, malleable metal, capable of receiving the lustre of silver. Its sp. gr. when hammered is about 8*82. It is chiefly employed in the manufacture of German silver. Prep. Roast powdered speisc first by itself and then with charcoal powder, till all tho arsenic is expelled, and a garlic odor ceases to be evolved; mix the residuum with 3 parts of sulphur and 1 part of potash, melt in a crucible with a gentle heat, cool, edulcorate with water, dissolve in sul- phuric acid mixed with a little nitric acid, precipi- tate with carbonate of potash, wash, dry, mix the precipitate with powdered charcoal, and reduce it by heat. For chemical purposes pure nickel is best obtained by moderately heating its oxalate in a covered crucible. Props., 6rc. Nickel is very infusible. Muria- tic and sulphuric acid act on it with difficulty un- less mixed with nitric acid. It is freely soluble in the latter menstruum. With oxygen it forms two oxides. The protoxide (gray oxide) may be ob- tained by heating the nitrate, carbonate, or oxa- late to redness in open vessels. This oxide forms salts with the acids, most of which have a green color. The peroxide (black oxide) is formed when chlorine is transmitted through water holding the hydrated protoxide in suspension. Chloride cf nickel is formed by the direct solution of the metal or its oxide in muriatic acid, from which it may be obtained in green crystals by evaporation. The salts of nickel are characterized by being precipi- tated white by prussiate of potash ; grayish white by infusion of galls ; black by hydrosulphurets and sulphureted hydrogen ; pale green by pure alkalis and alkaline carbonates, but redissolved by ammonia or its carbonate in excess. NICOTINE. Syn. Nicotina. A volatile base discovered by Reiman and Posselt in tobacco. Prep. (Ortigosa.) Infuse tobacco leaves for 24 hours in water acidulated with sulphuric acid, strain, evaporate to a sirup, add one-sixth of its volume of strong solution of potassa, and distil in an oil bath at 288°, occasionally adding a little water to assist the process. Saturate the distilled product with oxalic acid, evaporate to dryness, di- gest in boiling absolute alcohol, evaporate to a sirup, decompose the oxalate of nicotine thus ob tained, by adding caustic potassa to it in a close vessel, and agitate the mass with ether, repeating the process with more ether till all the nicotine is dissolved out. Distil the mixed ethereal solutions in a water-bath. At first ether comes over, then water, and lastly nicotine, which towards the end of the process assumes a yellowish tint. Remarks. Nicotine is a colorless volatile liquid, smelling of tobacco, boiling at 375°, soluble in water, ether, alcohol, and oils, and combining with the acids forming salts, many of which are crystallizable. It is a frightful poison; 4,th of a drop will kill a rabbit, and a single drop a large dog. Good Virginia tobacco yields lg of nicotine. (Thomson, Org. Chem.) NIGELLIN. A yellowish liquid obtained by Rensch from the seeds of the nigella sativa. It is obtained by digestion in alcohol at 80°, distilling the tincture, separating the reddish brown from the lighter portion of the product, agitating the latter with ether, and then with water, adding to the liquid when decanted, a little subacetate of lead, filtering and treating it with sulphureted hy- drogen. The aqueous liquid is then filtered and evaporated. NIGHTMARE Syn. Ephialtes, (Lat, from NIT 441 NIT t$a\Aoiiai, to leap upon; because it was thought a demon leaped upon the chest.) The prevention of nightmare consists in the selection of proper food, and in duly attending to the state of the stomach and bowels. Heavy and late suppers should be particularly avoided, as well as all arti- cles of diet that are of difficult digestion, or apt to induce flatulency. A spoonful of spirits of sal volatile, magnesia, or bicarbonate of soda, taken in a glass of cold water on going to bed, is a good and simple preventive. NIPPLES, SORE. Prep. Moisten them 2 or 3 times a day for some weeks before suckling, with brandy or spirit, gently acidulated with di- lute sulphuric acid; or instead thereof employ- tincture of balsam of tolu, or compound tincture of benzoin. Cure. Chapped nipples are most quickly and safely cured by moistening them 2 or 3 times a day with tincture of catechu, by means of a camel hair pencil. %* All applications of an active or poisonous nature should be carefully avoided, as even though the part be washed, yet a portion will still remain concealed within the pores of the skin and be sucked off by the infant. NITRATE. Syn. Nitras, (Lat.) A salt of nitric acid. The nitrates are very easily made by the direct solution of the base, or its oxide or car- bonate in nitric acid, which in most cases should be previously diluted with water; by evaporation they may be obtained either in the pulverulent or crystalline state. The nitrates are characterized by deflagrating when thrown on red-hot coal, or when heated in contact with inflammable sub- stances. (See Nitric Acid.) NITRATE OF CAMPHOR. Syn. Oil of Camphor. Prepared by dissolving camphor in ni- NITRATE OF POTASH. Syn. Saltpetre. Nitre. Nitrum. Sal Petrab. Sal Nitri. Ka- li Nitratu.m. Potass.* Nitras, (P. L. E. and D.) Nitrate de potasse, (Fr.) SalpetersjIures Ka- li, (Ger.) This salt is spontaneously generated in the soil, owing to the action of the atmosphere, and crystallizes upon its surface in various parts of the world, especially in the East Indies. It is also produced artificially by exposing a mixture of calcareous soil and animal matter to the at- mosphere, when nitrate of lime is slowly formed, and is extracts/! by lixiviation. The liquid is then decomposed by adding carbonate of potash, by which carbonate of lime is precipitated and nitrate of potash remains in solution. The British mar- ket is wholly supplied from India. The crude nitre (rough saltpetre) is extracted by lixiviation in the way above mentioned, but the alkaline base is supplied under the form of wood ashes, which, as is well known, contain a large quantity of pot- ash. It is purified by solution in boiling water, skimming, and after a short time being allowed for defecation, straining (while still hot) into crys- tallizing vessels. The crystals thus obtained are commonly called single refined nitre; and when the process is repeated, double refined nitre. Use, mix. (See Cerate, Blistering.) II. (Ung. Cantharidis, P. L. Ung. Infusi Cantharidis, P. E.) Powdered cantharides ^j; water %i\; boil to one-half, strain, add resin ce- rate 5'v> and evaporate to a proper consistence. This ointment is milder, and usually preferred to the preceding. Both are used to keep blisters open, and to stimulate indolent ulcere. III. (Dupuytren.) Tincture of cantharides (made with flies 1, to proof spirit 8) 3j; lard 3ix; mix well. Used as a pommade to make the hair grow, for which purpose it may be colored or scented at pleasure. IV. (M. Cap.) Beef marrow ^ij; alcoholic ex- tract of cantharides 8 grs.; rose oil 3j; essence of lemons 40 drops ; mix. For the hair. OINTMENT, CARBONATE OF LEAD. Syn. White Ointment. Ung. Album. Ung. Plumbi Carbonatis, (P. E. & D.) Prep. (P. E.) Carbonate of lead §j; simple ointment 5V j mix. Used in excoriations. The ung. album campho- ratum, P. L. 1745, (Ung. plumbi camph.,) is mada by adding to the above camphor 3j. OIN 455 OIN OINTMENT, CATECHU. Syn. Ung. Ca- techu. Prep. Finely powdered catechu and yel- low rosin, of each ^iv; alum 3ix; olive oil ^x; water q. s.; mix. An excellent application to ul- cers in hot climates, where the ordinary fat oint- ments are found objectionable. OINTMENT, CHLORIDE OF CALCIUM. Syn. Ung. Calcis Muriatis. Prep. (Sundelin.) Muriate of lime (dry) 3j; powdered digitalis 3ij; distilled vinegar £ij ; lard fj ; mix. In broncho- cele, scrofula, &c. OINTMENT, CHLORIDE OF LIME. Syn. Ung. Calcis Hypochlorite. Prep. (Ci- ma.) Chloride of zinc 3j; lard Jj; mix. For itch, putrid sores, &,c. OINTMENT, CHLORIDE OF GOLD AND SODA. Syn. Pommade de Muriate d'Or et de Soude. Ung. Auri Sodio-Chlori- di. Prep. (Majendie.) Sodio-chloride of gold 10 grs.; lard 3iv ; mix. In scrofulous and syphilitic swellings, ulcers, &c. OINTMENT, CHLORINE. Syn. Ung. Chlorinatum. Prep. Chlorine water §j ; lard §iv ; mix. Used for itch, fetid ulcers, &c. OINTMENT, COCCULUS INDICUS. Syn. Ung. Cocculi. Prep. (P. E.) Kernels of coccu- lus indicus 1 part ; beat to a paste, then add lard 5 parts. Used to destroy insects in children's hair, and in porrifjo. OINTMENT, COD'S OIL. Syn. Ung.Olei Aselli. Prep. (M. Carron.) Cod's liver oil and extract of smoke, of each, 3ij; nitrated ointment of mercury 3j ; beef marrow ^vj ; mix. In tinea favosa, impetigo, and chronic eczema and oph- thalmia. OINTMENT, COLOCYNTH. Syn. Ung. Colocynthidis. Prep. (Chrestien.) Powdered col- ocynth 3j ; lard §j; mix. Used in frictions on the abdomen, and insides of the thighs, in mania, &c. Diuretic. OINTMENT, COSMETIC. Syn. Ung. Cos- meticum. Pommade de la Jeunesse. Prep. (Quincey.) Almond oil ^'j', spermaceti 3iij; tris- nitrate of bismuth 3j; oil of rhodium 6 drops. Turns the hair black. OINTMENT, CREOSOTE. Syn. Ung. Creasoti, (P. L.) Ung. Creazoti, (P I'.) Prep. (P. L.) Creosote f 3ss; lard Jj5 mix. In skin diseases, especially ringworm ; also a good appli- cation to burns and chilblains. OINTMENT, CROTON. Syn. Ung. Cro- tonis. Prep. (Ainslie.) Croton oil 10 drops; lard ^ss; mix. Counter-irritant; rubbed repeatedly on the skin, it produces redness and a pustular eruption. OINTMENT, CYANIDE OF MERCURY. Syn. Ung. Hydrargyri Cyanidi. Prep. 1. (Ray- er.) Cyanide of mercury (bicyanide) 30 grs.; lard §j; mix.—2. (Pereira and Biett) 10 to 12 grs. to the oz. In scrofula, &c. OINTMENT, CYANIDE OF POTASSI- UM. Syn. Ung. Potassii Cyanidi. Prep. (Lom- bard ) Cyanide of potassium 2 to 4 grs.; lard ^; mix. OINTMENT, DELPHINE. Syn. Ung. Del- miniat.. Prep. (Turnbull.) Delphine 10 to 30 grs.; olive oil 3j; rub together, then add lard §j; mix welL In neuralgia, rheumatic affections, in- Teterate itch, &c. OLVTMENT, DEPILATORY. Syn. Lini- mentum Depilatorium. Prep. Finely powdered quicklime §j ; do. orpiment 3j ; white of egg to mix. OINTMENT, DESICCVTIVE. Syn. Ung. Desiccativum. Prep. (Jondelotte.) Simple oint- ment gxvj ; colcothar, lapis calaminaris, and white lead, of each, §j ; camphor 3ij ; mix. Drying, cicatrizing. OINTMENT, DETERGENT. Syn. Ung. Detergens. Prep. Yellow basilicon 2 lbs.; Ve- nice turpentine 4 oz.; red precipitate, verdigris, and euphorbium, of each, ^ oz. ; mix well. OINTMENT, DIGESTIVE. Syn. Ung. Di- gestivum. Prep. I. (P. Cod.) Venice turpentine §ij ; yelks of 2 eggs ; oil of St. John's wort §ss ; mix. With an equal quantity of mercurial oint- ment, the above forms digestif mercuriel; and with liquid storax, digestif anime. II. (Ung. Digest. Viride, Kirkland.) Yellow resin, beeswax, and elemi, of each, ^j i green/oil f yj ; melt together, and when nearly cold, add oil of turpentine 3ij. III. (For horses.)—a. Lard, yellow basilicon, and Venice turpentine, of each, 5 oz.; finely pow- dered verdigris 2 oz.; mix.—b. Yellow basilicon 15 oz.; red precipitate 1 oz.; mix. OINTMENT, DIGITALIS. Syn. Ung. Di- gitalis. Prep. Foxglove leaves lb. ij; lard lb.iiss; boil till crisp, and strain with pressure. OINTMENT, EDINBURGH. Prep. Black basilicon 3 lbs.; milk of sulphur 2 lbs.; mix. Used for itch. Collier says that this ointment is the same as the ung. veratri of the P. L., with the addition of a little sal ammoniac. OINTMENT, ELDER, (FLOWERS.) Syn. Ung. Sambuci. Prep. (P. L.) Elder flowers and lard, of each, lb.ij; boil until crisp, then strain through a cloth. Emollient. A much better oint- ment may with proper care be prepared from the distilled water, and this is generally done on the large scale. The following formula is commonly used:—Lard, (hard, white, and sweet,) 25 lbs.; prepared mutton suet 5 lbs.; melt in a well-tinned or earthen vessel, add elder-flower water 3 gal- lons ; agitate for half an hour, and set it aside; the next day gently pour off the water, remelt the ointment, add benzoic acid 3 dr. ; otto of roses 20 drops; essence of bergamotte and oil of rosemary, of each, 30 drops ; again agitate well, let it settle for 10 minutes, and then pour off the clear into pots. Very fine, and keeps well. OINTMENT, ELDER, (LEAVES.) Syn. Green Ointment. Ung. Viride. Ung. Samiiuci. Ung. Samb. Viride. Prep. I. (P. L. 1746.) Green oil lb. iij ; wax §x; melt, and stir till cold. Does not grain. II. Lard 1 cwt.; prepared suet 14 lbs.; fresh elder leaves 56 lbs.; boil till crisp, strain off the oil, put it over a slow fire, and gently stir it till it acquires a bright green color. III. Leaves lb. iij ; lard lb. iiij ; suet lb. ij. Both -the above are emollient and cooling. The last tw'o formula; are those employed in the whole- sale trade. The ointment should be allowed to cool slowly, with very little stirring, that it may " grain" well, as a granular appearance is much admired. It is a common practice to add pow- OIN 456 OIN dered verdigris to deepen the color, but then the ointment do»s not keep well. OINTMENT, ELEMI. Syn. Ung. Elemi, (P. L.) Linimentum Arcei. Ung. do. Do. do. comp. Prep. (P. L.) Gum elemi lb.j; suet lb. ij; melt together, then add common turpentine 5X j olive oil f 3(j; mix, and strain. Stimulant and di- gestive. Used to old and ill-conditioned sores. The ung. elemi cum arugine of St. George's Hospital is made by adding finely powdered ver- digris 3j, to every lb. ss of the above. OINTMENT, ESCHAROTIC. Syn. Ung. Escharoticum. Prep. (Sir B. Brodie.) Finely levigated verdigris, sulphate of copper, and nitric oxide of mercury, of each 3ij ; corrosive sublimate 3j ; lard q. s. OINTMENT, EYE. Syn. Eye-salve. Ung. Ophthalmicum. Prep. I. (Dupuytren's.) Red oxide of mercury 10 grs.; sulphate of zinc 20 grs.; lard ^ij j mix. For chronic inflammation of the eyelids, &c. » II. (Dessault's.) Red precipitate, carbonate of zinc, acetate of lead, and dried alum, of each 3j ; bichloride of mercury 3j ; rose ointment §j ; mix. Mostly used diluted with some lard. In chronic ophthalmia, profuse discharges, &c. III. (Spielmann's.) Acetate of lead 3j; sper- maceti cerate 3v; tincture of benzoin (comp.) 3ij; mix. Cooling. In inflammation, excoriations, &,c. IV. (St. Yve's.) Red precipitate 3ss ; oxide of zinc 3j; fresh butter §j; wax 9iv; camphor 15 grs. As No. I. V. (Pellier's.) Red precipitate, and carbonate of zinc, of each 3iss; tutty 3ss; red sulphuret of mercury 3j ; balsam of Peru 15 drops; lard §ij. In speck of the eye, arising from small ulcers that have healed up. VI. (Janin's.) Tutty, and levigated bole, of each 3ij ; white precipitate 3j; lard f ss. In chronic inflammation, with excessive secretion, &c. VII. (Fricke's.) Nitrate of silver 10 grs.; bal- sam of Peru 3s8 ; zinc ointment 3ij. In ulcers of the cornea, acute, purulent, and chronic ophthal- mia, &.C. VIII. (Guthrie's.) Spermaceti ointment 3j ; so- lution of diacetate of lead 15 drops ; nitrate of sil- ver 2 to 10 grs.; mix. As last. Both this and the preceding often occasion great pain. IX. (Singleton's Golden.) Orpiment 3j; lard q. s. X. (Smellome's.) Verdigris 3ss; olive oil 30 drops; yellow basilicon Jj j mix- In inflamma- tion of the eyelids, &c. XI. (Collier's.) Dried alum 3ss; powdered opium 3j; olive oil f 3j; spermaceti ointment 3ij; mix. For inflammation of the eyelids, purulent ophthalmia, &c. ,Remarks. All the above ointments should be used in very small quantities at a time, and care- fully applied with a camel hair pencil or a feather, and not till acute inflammation has subsided. The ingredients entering into their composition should be reduced to the state of very fine powder before mixing, and the incorporation should be made by long trituration in a Wedgewood-ware mortar, or preferably, for those that contain substances that are very gritty, by levigation on a porphyry slab, with a muller. OINTMENTS, FLOWER OF. Syn. Flos Unguentorum. Prep. Resin, th-ints wax, and suet, of each lb. ss; olibanum. and Venice tur- pentine, of each ^''sa ; myrrh %j; wine £ pint; boil together, and add camphor 3ij. Suppurative, warm. OINTMENT OF GALLS. Syn. Ung. Gal- larum. Ung. Gallae. Prep. (P. D.) Galls in very fine powder §j ; lard ^'v» m'x- An excel- lent application to piles, either alone or mixed with an equal quantity of zinc ointment. OINTMENT OF GALLS, (COMPOUND.) Syn. Ung. Gali^b compositum, (P. L.) Ung. Galla?. et Opii, (P. E.) Prep. (P. L.) Galls finely powdered 3ij ; powdered opium 3ss, (3j, P E.;•) lard §ij, (^j, P- E. :) mix. Anodyne, astrin- gent. An excellent application to blind piles, and prolapsus ani. Some persons add camphor 3j. OINTMENT, GALLS AND MORPHIA. Syn. Ung. GalljE cum Morphia. Prep. (Paris.) Morphia 2 grs.; olive oil f 3ij; triturate, and add finely powdered galls 3j; zinc oin.ment Jj. In piles, to allay pain. OINTMENT, GOLD. Syn. Pommade d'Or. Ung. Auri. Prep. I. (Legrand.) Powdered gold 12 grs.; lard ^j 5 mix. For frictions. II. (Majendie.) Amalgam of gold 3j; lard §j. For endermic use. (See Gold.) OINTMENT, HELLEBORE. Syn. Ung. Veratri, (P. L. & D.) Ung. Hellebori albi. Prep. (P. L.) Powdered white hellebore ^ij ; lard ^viij ; oil of lemons 20 drops ; mix. In itch, lepra, ringworm, &,c.; and to destroy insects in the hair of children. It should be used with caution. OINTMENT, HELLEBORE, (COM- POUND.) Prep. (Rayer.) White hellebore §j; sal ammoniac 3iv ; lard ^viij ' mix. OINTMENT, HEMLOCK. Syn. Ung. Co- nii. Prep. (P. D.) Fresh leaves of hemlock, and lard, equal parts; boil till crisp, and strain with pressure through linen. For glandular and scir- rhous swellings, painful piles, cancerous sores, &c. OINTMENT, HENBANE. Syn. Ung. Hyoscyami. Prep. As the last. As a sedative and anodyne application to painful swellings and piles, and irritable ulcers ; and in neuralgic pains, &.C. OINTMENT FOR HORSES. Prep. I. (For canker.) Tar 8 oz.; lard 4 oz.; oil of vitriol, or verdigris, 1 oz. II. (For fistula.)—a. Yellow basilicon 8 oz.; oil of turpentine and verdigris, of each 1 oz.; mix.— 6. Ointment of nitrate of mercury 4 oz.; oil of turpentine, and lard, of each 1 oz.; mix. III. (For grease.) Lard 4 oz.; white lead I oz.; mix. IV. (For cracked hoofs.) Tar and tallow equal parts, melted together. V.(Heel ointment.) To the last add verdigris 2 oz. to each pound. VI. (For foot rot.) Lard and Venice turpentine, of each 4 oz.; melt, and add blue vitriol 1 oz. For horses, cows, or sheep. VII. (For mange.)—a. Lard and sulphur vivum, of each 4 oz.; yellow basilicon, and oil of turpentine, of each 3 oz.; mix.—6. To the last add tar and suet, of each 4 oz.—c. Soft soap, oil of turpentine, lard, and flowers of sulphur, of each 4 oz.; mix. OINTMENT, HYPOCHLORIDE OF SUL- OIN 457 OIN PHUR Syn. Ung. Sulphuris Hypochloridi. Prep. (Copland.) Hypochloride of sulphur 3j; lard §j. OINTMENT, HYDRIODATE OF AM- MONIA. Syn. Ung. Ammonia Hydriodatis. Prep. (Ellis.) Hydriodate of ammonia 9j; lard §j > mix. OINTMENT, IODATE OF ZINC. Syn. Ung. Zinci Iodatis. Pommade avec l'Iodate de Zinc. Prep. Iodate of zinc 3j ; lard Jj ; mix. Used in scrofula, &c. OINTMENT, IODIDE OF BARIUM. Syn. Ung. Barii Iodidl Prep. (Majendie.) Iodide of barium 4 grs.; lard §j- OINTMENT, IODIDE OF LEAD. Syn. Ung. Plumbi Iodidl Prep. (P. L.) Iodide of lead §j ; lard ^viij ; mix. Applied by friction to scrofu- lous and other indolent glandular swellings. OINTMENT, IODIDE OF MERCURY. Syn. Pommade de proto-iodure de Mercure. Ung. Hydrargyri Iodidl Prep. (P. L.) White wax §'j ; lard 3jvj ; melt, and when nearly cold triturate with iodide of mercury ^j- Used in tuber- cular skin diseases, and as a dressing for ill-condi- tioned sores, scrofulous ulcers, &c.; it should be used with caution. OINTMENT, IODIDE OF POTASSIUM. Syn. Pommade avec l'Hydriodate de Potasse. Ung. PotassjE Hydriodatis. Prep. (Majendie.) Iodide of potassium 3j ; lard 3xij ; mix. In scro- fula, bronchocele, glandular swellings, &c. OINTMENT, IODINE. Syn. Ung. Iodinii. Prep. (P. D.) Iodine 3j ; lard 5j '■> mix. For scrofulous sores, glandular swellings, &c.; either alone, or mixed with lard. OINTMENT, IODINE, (COMPOUND.) Syn. Pcmmade d'Hydriodate Iodure de Po- tasse. " NTMENT OF IoDURETED IODIDE OF PO- TASSIUM. Tng. Iodinii compositum, (P. L.) Ung. Iodinei, (P. E.) Prep. (P. L.) Iodine 3ss ; iodide of potassium 3j ; rectified spirit f 3j; triturate to- gether, then add lard §ij. In glandular enlarge- ments. &c.: stronger than the simple ointment. OINTMENT, IODOHYDRARGYRATE OF IODIDE OF POTASSIUM. Syn. Ung. IODOHYDRARGYRATIS POTASSH IoDIDI. Prep. (Puche.) Biniodide of mercury, and iodide of po- tassium, of each 8 grs.; lard §j. OINTMENT, ITCH. Syn. Ung. Antipso- ricum. Prep. I. (De La Harpe.) Flowers of sul- phur ^ij; sulphate of zinc 3ij ; powdered helle- bore 3iv ; soft soap %iv; lard §viij; mix. II. (Bateman's.) See page 100. III. (Bailey's.) See page 88. IV. (Jackson's.) Lard, palm oil, flowers of sul- phur, and white hellebore, equal parts. V. (Common.) Palm oil 1 lb.; lard 5 lbs.; white lead J lb. ; corrosive sublimate 4 oz.; mix well. OINTMENT, LARD. Syn. Ung. Adipis. Lard washed with rose water. OINTMENT, LAUREL. Syn. Ung. Lari- num vulgare. Common Oil of Bays. Prep. Laurel leaves 1 lb.; laurel berries £ lb.; cabbage leaves 4 oz.; neats' foot oil 5 lbs.; suet 2 lbs.; boil, express, and cool slowly, to let it "grain." OINTMENT, LEAD. Syn. Ung. Lythar- gyri Acetati. Prep. (P. C.) Wax ointment fj; solution of diacetate of lead 3ss. OINTMENT, LEAD,' 'COMPOUND.) Syn. 58 Higgin's Neutral Ointment. Kirkland's Ned tral Cerate. Ung. Plumbi compositum. Prep (P- L.) Prepared chalk gviij ; distilled vinegar f 5VJ ! mix, and when the effervescence ceases, add lead plaster lb. iij, previously melted with olive oil 1 pint, and stir till cold. Used as a dressing to indolent ulcers. See Cerate, Kirkland's. OINTMENT, LEAD AND MORPHIA. Syn. Ung. Plumbi cum Morphia. Prep. (Ged- dings.) Carbonate of lead §ss ; sulphate of mor- phia 15 grs.; stramonium ointment §j; olive oil q. s. OINTMENT, LE MORT'S. Lard 7 oz.; Venice turpentine, litharge, corrosive sublimate, and carbonate of lead, of each 1 oz.; alum 3 dr.; vermilion to color. OINTMENT, LUPULINE. Syn. Ung.Lupu- lina:. Prep. (Freake.) Lupulina 3j; lard 3iij. To relieve cancerous pains. The Ointment of Hops (Ung. Lupuli, Van Mons) is made with hops §ij ; lard ^x; in the same way as ointment of belladonna. OINTMENT, MANGANESE. Syn. Ung. Manganesii Binoxydi. Prep. Black oxide of manganese 3j ; lard §j. For scrofulous swellings, itch, scaldhead, &,c. OINTMENT, MERCURIAL. Syn. Unction. Blue Ointment. Neapolitan do. Strong Mer- curial do. Ung. C^eruleum. Ung. Hydrargyri, (P. E. &, D.) Ung. Hyd. Fortius, (P. L.) Prep. I. (P. L. & E.) Suet §j; mercury lb. ij; lard ^xxiij ; triturate the metal with the suet and a little of the lard, till the globules are extinguished, then mix in the remainder of the lard. Remarks. The Dublin College orders eaual parts of mercury and lard. The stronger mercurial ointment of the shops is usually made with less mercury, and the color is brought up with finely- ground blue black, or wood charcoal. This fraud may be detected by the decrease in the sp. gr., and by a portion being left undissolved when a little of the ointment is treated, first with ether to remove the fat, and then with dilute nitric acid to remove the mercury. The following is the form which is very generally substituted for that of the pharma- copceia:—mercury 12 lbs.; suet IJ lb.; lard 16J lbs. The Ung. Hydrargyri partes ^equales of the shops is usually made of mercury and lard, of each 12 lbs.; suet IJ lb. *** Mercurial ointment " is not well prepared so long as metallic globules may be seen in it with a magnifier of 4 powers." (P. E.) Its sp. gr. should not be less than 1*781, at 60°. When rubbed on a piece of bright cop- per or gold, it should immediately give it a coating of metallic mercury. This ointment is chiefly used to introduce mercury into the system, when the stomach will not bear it. £ to 1 dr. is com- monly rubbed into the inside of the thigh night and morning. (See Sevum.) II. (Mild Mercurial Ointment. Ung. Hyd. Mdius, P. L. & D.) Stronger mercurial ointment lb.j ; lard lb. ij *, mix. Used in cutaneous diseases, as a dressing to ulcers, and to kill insects on the body The ointment of the shops usually contains only half the above quantity of mercury. III. (Donovan.) Gray oxide of mercury 3j; lard £j ; heat them to 350° for 2 hours, constantly stirring. Gray colored. It may also be made from the red oxide in the same way, by keeping the OIN 458 OIN ointment heated to about 300° for some hours. Cleauer and stronger than Ung. Hyd. Fort. P. L. IV. (Tyson.) Black oxide of mercury (prepared by decomposing precipitated calomel with liquors of potassa and ammonia) §ij; lard lb.j; mix. About as active as the last. OINTMENT, MACE. Syn. Ung. Macis. Common Oil of Mace. Prep. Mace and palm oil, of each 1 lb.; beat to a paste, and add melted beef marrow 3 lbs. OINTMENT, MEZEREON. Syn. Ung. Mezerei. Prep. (P. Cod.) Mezereon bark §iv, (bruised and moistened with spirit;) white wax §iss; lard §xivss; digest at 212° for 12 hours, press and strain. OINTMENT, NERVINE. Syn. Ung. Nf.r- vinum. Balsamum do. Baume's Nerval. Prep. (P. Cod.) Expressed oil of mace, and ox-marrow, of each §iv; melt, and add oil of rosemary 3ij; camphor and oil of cloves 3j; balsam of tolu 3ij, dissolved in rectified spirit 3iv. OINTMENT, NITRATE OF MERCURY. Syn. Citrine- Ointment. Yellow do. Mercu- rial Balsam. Ung. Citrinum, (P. E. & D.) Ung. Hydrargyri nitratis, (P. L.) Prep. Dis- solve mercury fj in nitric acid sp. gr. 1*5 f 3xj ; and add the solution to lard §vj and olive oil f §iv, melted in a capacious Wedgewood-ware, or well-glazed earthen vessel, placed in a water-bath, at a temperature of from 180 to 200° Fahr.; mix well, remove the heat, and stir till the mixture ceases to evolve gas, and acquires a considerable degree of consistence. Remarks. The above are the proportions of the P. L.;—the P. E. orders nitric acid (1-5) ffviij, f 3vj ; mercury §iv ; lard ^xv ; olive oil f ^xxxij ;— the P. D. orders mercury §j ; acid 3xj; lard ^iv olive oil 1 wine pint;—the P. U. S. orders mercur; §j; acid 3xj ; lard ^iij ; neats' foot oil f ^ix ;—the P. Cod. orders mercury 30 parts ; acid (sp. gr. 1*321) 60 parts; lard and olive oil, of each 240 parts. Good citrine ointment may be procured from any of the above formulae by proper management. The great art consists in employing pure ingredients, and mixing them at the proper temperature-. The acid should be of the full strength, or if weaker, an equivalent quantity should be employed. This may be ascertained from the table of the sp. gr. of nitric acid, page 442. If the mixture do not froth up, the heat should be increased a little, as with- out a violent frothing and reaction take place, the ointment will not turn out of good quality, but will rapidly harden. This is the whole difficulty of the process, and it is surprising that the preparation of this ointment, which is not at all difficult, should have so long engaged the attention of the pharma- ceutical periodicals. The London form produces a most beautiful golden colored ointment, having a buttery consistence, and keeps well, but more acid may be used with advantage. Use. In ringworm, and various chronic skin dis- eases ; as a dressing to ulcers, and in various dis- eases of the eyes, especially chronic inflammation of the eyelids, &c. For most purposes, particu- larly the latter, it must be largely diluted with lard or oil. *#* This ointment, made with 3 times the above weights of lard and oil, forms the milder citrine ointment, (Ung. Hydrargyri Nitratis mithti.) The best substance to dilute the stronger ointment, is fresh butter, or palm, poppy, or almond oil. OINTMENT, NITRATE OF SILVER. Syn. Ung. Argenti nitratis. Prep. 1. (Velpeau.) Ni- trate of silver 1 gr.; lard 3j.—2. (Mackenzie.) Nitrate of silver 5 grs.; lard §j,. In purulent and chronic ophthalmia, ulcers on the cornea, Aic. It should be used with great caution. OINTMENT, NITRIC OXIDE OF MER. CURY. Syn. Red precipitate Ointment. Ung. Hydrargyri nitrico-oxydi, (P. L.) Ung. Hyd. oxydi, (P. E.) Do. do. do. nitrici, (P. D.) Do. do. do. rubri. Ung. Hyd. subnitratis. Prep. (P. L.) Finely-powdered nitric oxide of mercury 5J; white wax 3'j', lard 3VJ » melt, and stir in the oxide. The P. E. orders ^viij of lard instead of the wax and lard above. As a stimulant applica- tion to indolent sores and ulcers, to inflamed eyes, OINTMENT, NITRIC ACID. Syn. Oxy- genized Lard. Pommade d'Alyon. Ung. acidi nitrici. Do. do. nitrosi. Prep. (P. D.) Olive oil lb. j; lard §iv ; melt together, and add nitric acid (sp.gr. 1*5) f3vss; stir till stiff. This oint- ment has a yellow color, and is frequently sold for ointment of nitrate of mercury, but the fraud may be detected by its not turning gray when kept heated for some time. Stimulant; used to dress foul ulcers. OINTMENT, OBSTETRIC. Syn. Ung. OBSTETRICUM. PoMMADE OBSTETRICALE. Prep. (Chaussier.)—1. Extract of belladonna 3ij ; water and lard, of each Jij; mix. For dilating the ute- rus.—2. (Pommade pour le toucher) Yellow wax, and spermaceti, of each §j ; olive oil §xvj; melt, strain, add solution of pure soda f Sy, and stir till cold. OINTMENT, OPIUM. Syn. Ung. Opiatum Ung. opii, Prep.—1. Powdered opium 3j ; sper- maceti ointment ^'U i mix. To allay pain.—2. (Augustin.) Opium 3ij ; ox gall 5jij ; digest 2 days, strain, and add lard 3ij ; essence of bergamot 10 drops—3. (Brera.) Opium 3j; gastric juice of a calf q. s.; digest 24 hours, and add lard Jj> or q- s, OINTMENT, OXIDE OF LEAD. Syn. Ung. Lythargyri. Ung. nutritum. Prep. (P. Cod.) Litharge §iij; vinegar §iv; olive oil %'tx; heat gently, and stir till they combine. OINTMENT, OXIDE OF MERCURY. Syn. Ung. Hydrargyri oxidi. Do. do. do. cinj erei. Prep. Protoxide of mercury ^j ; lard §iij; mix. Substituted for mercurial ointment. (See Donovan's and Tyson's Mercurial Ointments.) OINTMENT, OXIDE OF SILVER. Syn. Ung. Argenti oxydi. Prep. (Serre.) Oxide of silver 16 gre. ; lard §j; mix. For scrofulous and syphilitic sores, &c. OINTMENT, OXIDE OF ZINC. Syn Ung. Zinci, (P. L. & E.)' Ung. Zinci oxydi, (P. D.) Prep. (P. L.) Oxide of zinc ^j ' lard 5VJ 5 mix. Desiccative ; in various skin diseases at- tended with profuse discharges, in burns, blisters, excoriations, &,c, and in chronic inflammations of the eye. The ointment of crude oxide of zinc (Ung. Tutia, Ung. Zinci Oxydi impuri) is made of prepared tutty I part; lard 5 parts. OINTMENT, PHOSPHORUS. Syn. Uno. Phosphoratum. Prep. (P. Cod.) Phosphorus 3j ; OIN 459 OIN lard Ivj 3iij ; mix in a bottle, melt in a water- bath, and shake till cold. OINTMENT, PHOSPHORIC ACID. Syn. Ung. Acidi Phosphorici. Prep. (Soubeiran.) Phosphoric acid 3j ; lard §j ; mix. In caries of the bones, &c. OINTMENT, PEPPER. Syn. Pepper Salve. Ung. Piperis nigri. Prep. (P. D.) Finely-pow- dered black pepper ^iv; lard lb.j; mix. Stimu- lant ; irritant; used in ringworm, &c. OINTMENT, PITCH. Syn. Black Basili- con. Ung. Tetrapharmacum. Ung. Basilicum nigrum. Ung. Picis nigr*:, (P.L.) Prep. Black pitch, wax, and resin, of each, §ix ; olive oil f §xvj ; melt together, and stir till cold. Stimulant and digestive ; used in eruptions, scald-head, &c. OINTMENT, PITCH, (COMPOUND.) Prep.—1. (Ung. Picis compositum, St. B. H.) Pitch ointment and ointment of acetate of lead, equal parts. Stimulant and desiccant—2. (Ung. Picis cum Sulphure, Guy's*H.) Tar lb. ss ; wax 3SS> (5j 0 flowers of sulphur f ij; mix. In itch, pso- riasis, and other scaly skin diseases, ringworm, &c. OINTMENT, PICROTOXINE. Syn. Ung. PiCROToxiNiE. Prep. (Jager.). Picrotoxine 10 grs.; lard ^j; mix. In obstinate porrigo, (ringworm ;) and diluted with olive oil, to destroy vermin on the body. OINTMENT FOR PILES. Syn. Ung. H.e- morrhoidale. Prep. I. (Dr. Gedding.) Carbon- ate of lead 3iv ; sulphate of morphia 15 grs.; stra- monium ointment Jj; olive oil q. s. To allay pain and inflammation. II. Spermaceti ointment 8 oz.; powdered galls I oz.; do. opium 1 dr.; solution of diacetate of ead Ik oz. (See Piles.) OINTMENT, PLATINUM. Syn. Ung. Pla- INi. Prep. (Haefer.) Perchloride. of platinum 3j ; xtract of belladonna 3ij ; lard §iv ; mix. OINTMENT, POMATUM. Syn. Ung. Po- iatum, (P. L. 1746.) White Lip Salve. Lard vashed with rose water. OINTMENT, POPLAR BUDS. Syn. Ung. Populeum. Prep. Bruised poplar buds 1 part; lard 3 parts; boil and strain. The old Ung. Po- puleum consisted of a number of green herbs boiled as above. Emollient and stimulant. OINTMENT, POPLAR BUDS, (COM- POUND.) Prep. (P. Cod.) Bruised poplar buds §xij ; fresh leaves of poppies, henbane, belladon- na, and common nightshade, of each, gviij; lard lb. ivss. As last OINTMENT, PLUNKET'S. Prep. Crows- foot 1 handful; dog's fennel 3 sprigs; pound well, add flowers of sulphur and white arsenic, of each, 3 thimblefuls; beat well together, form into bo- luses, and dry in the sun; then powder them ; and tor use mix with yelk of egg, spread a little on a small piece of pig's bladder, (size of half a crown,) and apply to the sore, and allow it to re- main till it falls off by itself. In cancer: poison- ous ; requires great caution. OINTMENT, QUININE. Syn. Ung. Qui- nine fortius. Prep. Sulphate of quinine 3j ; lard 3ij ; mix. Rubbed into the axilla, to cure the igue of children. OINTMENT, RED SULPHURET OF HERCURY. -Syn. Ung. Hydrargyri bisulphu- rktl Prep. (Collier.) Bisulphuret of mercury 3iss ; sal ammoniac 3ss ; rose water f 3j ; lard ^ss ; mix. In several skin diseases. OINTMENT, RESIN. Syn. Yellow Basi- licon. Ung. Resinosum, (P. EN Ung. Resin* albas, (P. D.) Prep.—l. (P. E.) Yellow resin f v ; beeswax §jj; lard gviij ; melt, and stir till cold.—2. (P. D.) Yellow wax lb.j; white (yel- low) resin lb. ij ; lard lb. iv ; as above. OINTMENT, RINGWORM. Syn. Ung. Contra-tineam. Prep. 1.—Soda 6 parts ; blaked lime 40 parts ; lard 1200 parts ; mix.—2. Lard and ointment of black pitch, of each, §ij ; oint- ment of nitrate of mercury §j ; mix. The h*air must be cut off close, and the part washed clean before each application. OINTMENT, ROSE. Syn. Rose Lip-salve. Ung. Rosatum. Ung. Adipis, (P. L. 1788.) Prep. (P. Cod.) Washed lard lb. ij ; roses (centif.) lb. ij ; bruise the leaves, melt with the lard, and in 2 days again melt, and press; add roses lb. ij, and repeat the process ; lastly strain, press, and color with alkanet root, if required red. OINTMENT, RUBEFACIENT. Syn. Ung. Rubefaciens. Prep. (Richard.) Finely-powdered cantharides and camphor, of each, 3j ; lard §j ; mix. OINTMENT, RUE. Syn. Ung. Rutas. Prep. (Sp. Ph.) Leaves of rue, wormwood, and pepper- mint, of each, §ij ; lard §xvj ; boil and strain. OINTMENT, SAVINE. Syn. Ung. Sabi- ne. Prep. (P. D.) Fresh savine leaves lb. ss ; lard lb. ij ; boil till crisp, strain, and add beeswax lb. ss. OINTMENT, SCROPHULARIA. Syn. Ung. ScROPHULARiiE. Prep. (P. D.) Green leaves of knotted-rooted fig-wort and lard, of each, lb. ij ; prepared suet lb. j ; boil till crisp, and strain with pressure. In ringworm, " burnt holes," and some other cutaneous affections. OINTMENT, SIMPLE. Syn. Ointment of White Wax, simple Dressing. Ung. Simplex, (P. E.) Ung. Cera: alba:, (P. D.) Prep.—l. (P. D.) Lard lb. iv ; white wax lb. j ; melt togeth- er, and stir till cold.—2. (P. E.) Olive oil f fvss ; white wax ^ij ; as last A simple unguent. The Ung. Simplex, P. L. 1746, was lard washed with rose water. (See Cerate, Simple.) OINTMENT, SPERMACETI. Syn. White Ointment. Ung. Album, (P. L. 1746.) Ung. Spermatis ceti. Ung. Cetacei, (P. L.) Prep. (P. L.) White wax 3ij ; spermaceti 3vj ; olive oil f f iij; melt together. The Ung. cetacei of the Dublin Pharmacopoeia is made with white wax lb. ss; spermaceti lb.j; lard lb. iij ; and in consis- tence resembles the spermaceti cerate, P. L. In trade, the Dublin form, with double the amount of lard, is commonly adopted. (See Cerates.) OINTMENT, STAVESACRE. Syn. Ung. Staphisagrias. Prep. (Swediaur.) Powdered stavesacre 3j ; lard ^iij; melt together, digest 3 hours, and strain. In itch, and to destroy ver- min on the body, (pediculi.) A similar ointment is used by farriers. OINTMENT, STRAMONIUM. Syn. Ung. Stramonii. Prep.—l- (P. U. S.) Fresh thorn- apple leaves f ij; lard f v; digest as last, and strain.—2. (Pereira.) Powdered leaves §j; lard ?iv * mix. Anodyne. Used to dress irritable ul- cers', and as an application to painful piles. OIN 460 OLE OINTMENT, SUBSULPHATE OF MER- CURY. >S'yn. Ung. Hydrargyri subsulphatis. Prep.—1. (Alibert) Turpeth's mineral 3ij ; lard §iv; mix.—2. (Biett) Turpeth's mineral 3j; sul- phur 3ij; lard 3'j' essence of lemon 15 drops. Used in some scaly skin diseases, &c. OINTMENT, SULPHURIC ACID. Syn. Ung. Acidi Sulphurici. Prep. (P. D.) Sulphu- ric acid 3j, (f 3ss ;) lard £j ; mix. Stimulant; used in paralvsis, hemorrhages, itch, &c.; more cleanly than the sulphur ointment. For children it is made with only £ or J as much acid. OINTMENT, SULPHATE OF ZINC. Syn. Ung. Zinci Sulphatis. Prep. (Scarpa.) Sulphate of zinc 3j ; lard §j ; mix. Astringent In some chronic skin diseases. OINTMENT, SULPHUR. Syn. Ung. Sul- phuris, (P. L. E. &, D.) Prep. (P. L.) Sublimed sulphur ^iij ; lard 3;vj; essence of bergamotte 20 drops; mix. The P. E. and D. order 1 to 4, and omit the bergamotte. In itch, scald-head, and several other skin diseases. OINTMENT, SULPHUR, (COMPOUND.) Syn. Itch Ointment. Ung. Sulphuris composi- tum. Prep. (P. L.) Sulphur and soft soap, of each, f vj ; white hellebore 5'j '■> 11,tre 3j ' lard lb. iss; essence of bergamotte 3ss; mix. As the last, but stronger, and more irritating, though more efficacious. OINTMENT, SULPHURET OF POTAS- SIUM. Syn. Ung. Potassii Sulphureti. Prep. (Alibert.) Subcarbonate of soda and sulphuret of potassium, of each, 3iij; lard 5'j > mix. In chro- nic skin diseases, especially itch, psoriasis, lepra, eczemsL o&c OINTMENT, TANNIN. Syn. Ung. Tan- nini. Prep. (Richard.) Tannin 3ij ; water f3ij ; triturate together, and add lard ^iss. Astringent. An excellent application to piles. OINTMENT, TAR. Syn. Ung. Picis liquids. (P. L. E. & D.) Prep. (P. L.) Tar and mutton suet equal parts; melt together, and stir till cold. As an application to scald-head, ringv/orm, foul ulcere, &c. OINTMENT, TOBACCO. Syn. Ung. Tabaci. Prep. (P. U. S.) Fresh tobacco leaves chopped small §j ; lard lb. j; boil till crisp, and strain through linen. Used for irritable ulcers, ringworm, and other diseases of tho skin. It should be used with caution. OINTMENT, TRIPHARMIC. Syn. Ung. Tripharmacum. Prep. (P. L. 1745) Lead plaster §iv; olive oil f§iv; vinegar f 3-j; melt, and stir till they combine. Cooling and desic- cativo. OINTMENT, VERATRINE. Syn. Ung. VERATRINiE. POMMADE DE VERATRINE. Prep.--1. (Turnbull.) Veratrina 10 to 20 grs.; olive oil a few drops; triturate and add lard §j.—2. (Majen- die.) 4 grs. to the ounce.—3. (Pereira.) 20 to 40 grs. to the ounce. In neuralgia, neuralgic rheuma- tism, gout, &.C. OINTMENT, VERDIGRIS. Syn. Ung. JEruginis, (P. E1 Ung. Cupri Subacetatis, (P. D.) Prep.—1. (P. E.) Resinous ointment |xv ; verdigris in fine powder §j ; mix.—2. (P. D.) Verdigris ^ss ; olive oil §j 5 triturate and add resin ointment lb.j.—3. Verdigris $j 5 lard §xv ; mix. All the above are escharotic and detergent, and are used as occasional dressings to foul and tlabby ulcers, to keep down fungous flesh, and diluted with oil or lard in scrofulous ulceration and in- flammation of the e\••■lids. OINTMENT, VINEGAR. Syn. Ung. Aceti. Prep. (Dr. Cheston.) Olive oil lb.j; white wax 5'v! melt, cool a little, add vinegar ^ij, and stir till cold. A cooling astringent dres- sing, and as a salve in chronic ophthalmia. OINTMENT, WAX, (YELLOW.) Syn. Ung. Cer* flavje. Prep. (P. D.) Beeswax lb. j ; lard lb. iv; melt together. A mild and cooling dressing. (See Cerate, Simple.) OINTMENT, WHITE, (CAMPHORA- TED.) Syn. Ung. Album Camphoratum. Prep. (P. L. before 1745.) Simple ointment §v ; camphor 3ij ; dissolve by a gentle heat, add finely-powdered carbonate of lead §j, and stir till cold. OINTMENT, WHITE PRECIPITATE. Syn. Ointment of Ammonio-chloride of Mer- cury. Ung. Hydrargyri Ammonio-chloridi, (P. L.) Ung. Pr^cipitati Albi, (P. E.) Ung. Hydrargyri Submuriatis Ammoniati, (P. D.) Prep. (P. L.) White precipitate 3j; lard §jss ; mix. Stimulant, alterative, and detergent; in the itch, scald-head, and various other skin diseases; in inflammation of the eyes, and to destroy vermin on the body. OINTMENT, WORM. Syn. Ung. Vermi- fugum. Prep. (Bat. Ph.) Aloes 3j; dried ox- gall 3iss ; lard Jiss ; mix. OINTMENT, YELK OF EGG- Syn. Ung. Ovorum. Prep. (Soubeiran.) Oil of almonds §iss ; yellow wax §ss j me|t together, and when nearly cold, add the yelk of one egg and mix well. Applied to sore nipples. OINTMENT, ZINC, (COMPOUND.) Syn. Ung. Zinci cum Lycopodio. Prep. (Hufeland.) Oxide of zinc and lycopodium, of each 3j ;' simple cerate §ss ; mix. In excoriations and ulcerations, especially of the eyes, either alone or diluted with almond oil. OLEFIANT GAS. Syn. Heavy inflammablk Air. Carbureted Hydrogen. Hyduret of Acetule. It may be obtained by heating a mix- ture of 1 part of alcohol and 6 parts of oil of vitriol, and as soon as sulphurous gas begins to come over, passing the product first through milk of lime and then through oil of vitriol. This gas is a little lighter than atmospheric air, and burns with a bright white flame. When mixed with an equal volume of chlorine over water, it soon con- denses into an oily looking liquid ; hence the name olefiant gas was given it by the Dutch chemists. It 6mells like oil of caraway. It is the presence of olefiant gas in coal gas that principally gives to the latter its illuminating properties. This gas was formerly called per- or bi-carbureted hy- drogen. OLEIC ACID. An oily acid, discovered by Chevreul in fat. Prep. Saponify the pure oil of almonds, decom- pose the 6oap with a dilute acid, and digest the resulting oily acid in a water-bath with half its weight of oxide of lead for 6ome hours, constantly stirring; then agitate the mixture with twice its volume of ether in a close vessel, and in 24 hours decant the clear ethereal solution; decompose with dilute muriatic acid, collect the acid that OPH 461 OPI separates, and remove the ether by evaporation. To render it still purer it must be again saponified with caustic soda, and the soap repeatedly dis- solved in a solution of soda, and as often separated by adding common salt, until it becomes nearly colorless, when it must be decomposed by dilute muriatic acid as before. Props., §c. An oily acid, insoluble in water, soluble in alcohol, ether, and oil, and forming salts with the bases called oleates. OLEIN. Syn. Elain. Huile absolue. (From eXawv, oil.) The liquid portion of oil and fat ; by saponification it yields oleic acid. Prep. I. Digest the oil with a quantity of caustic soda in solution, only sufficient to saponify half the oil, and separate the undecomposed oily portion from the soap and alkaline solution. Suc- ceeds well with recently expressed and fresh oils. II. Almond or olive oil 1 part ; strong alcohol 8 parts ; mix in a flask, heat nearly to boiling, agitate, decant the clear upper stratum, and allow it to cool; filter, and gently distil off the spirit. Both the above are used by watchmakers for fine work, as they will not freeze nor thicken at or- dinary temperatures. Some years ago the last was sold, by a certain metropolitan house, as watchmaker's oil, at Is. 6d. a drachm. OLEOMETER. (From oleum, oil ; and me- trum, a measure.) An instrument for ascertain- ing the specific gravity of oil. (See Hydrometer and Oil.) OLEON. A peculiar liquid obtained by the distillation of oleic acid and lime. OLEO-PHOSPHORIC ACID. A peculiar arid found by Fremy in the brain and nervous matter. OLEO-SACCHARUM. Syn. Ela;o-Sac- Cn^nuM. A mixture of sugar and essential oil. The oleo-sacchara of aniseed, caraway, pepper- mint, pennyroyal, cinnamon, and other essential oils, are made by rubbing 15 or 16 drops of the respective oils with white sugar 1 oz. ; and when intended for making extemporaneous distilled waters, 1 oz. of magnesia is also added. The oleo-sacchara of lemons, oranges, &c, are made from the peels, as described at page 199. OLIVILE. A white crystalline substance, obtained by Pelletier from the gum of the olive tree, (Olea Europaea.) It is soluble in hot water and alcohol. OLIVINE. A white, crystalline, bitter sub- stance, obtained by Landerer from the leaves of the olive tree. It dissolves in acids. OMELETTE. A pancake or fritter made of eggs ; much used on the Continent OMYCHILE. A brown, resinous substance, obtained by Scharling from inspissated urine. OPHTHALMIA. Syn. Ophthalmitis. (From oajBaXpos, the eye.) Inflammation of the eye. In ordinary cases this disease is confined to the external membrane of the globe of the eye, or to the eyelids ; but it occasionally attacks the sclerotica, cornea, choroid coat, and retina. In general it may be relieved by fomentations of warm water, or decoction of poppy-heads, and the use of aperient medicines ; to which leeches and cupping may be added with advantage. In severe cases, general depletion and blisters to the nape of the neck must be had recourse to. When the inflammation has subsided, mild astringents and cooling eye-waters and ointments will be found useful; but all applications of this kind should be used with caution. The purulent oph- thalmia of new-born infants, and that which often follows the smallpox, measles, and fevers, gener- ally yields to the use of mild astringent eye- waters and salves, and to the application, at bed- time, of a drop of wine of opium diluted with 5 or 6 drops of water. A t*ery weak solution of sul- phate of zinc, or the ointment of nitric oxide of mercury, will be found a good application in the latter cases. In every variety the eye should be kept clean by careful ablution with warm milk and water. OPIANIC ACID. A crystalline substance, possessing acid properties, resulting from the oxi- dation of narcotine, discovered by Wohler and Liebig. It is obtained by dissolving narcotine in dilute sulphuric acid in considerable excess; adding finely-powdered oxide of manganese, also in excess ; and boiling till carbonic acid ceases to be evolved, when the liquid is filtered, and on cooling forms a crystalline mass of opianic acid. This is drained on a filter, pressed, washed with cold water, and frequently recrystallized from a saturated solution in boiling water. Scarcely soluble in cold water; soluble in alcohol. OPIATE EN POUDRE. Prep. Bath brick 8 oz.; China ware 4 oz.; red coral 1 oz.; cinna- mon and cloves, of each 1 dr.; mix. and reduce to a very fine powder. Used as a dentifrice ; rap- idly whitens the teeth. OPIATE, ANTI-TUBERCULAR. (Lepecq de la Cloture.) Prep. Spermaceti, crab's eyes, and sulphur, of each 3ij; conserve of roses §ss; pepper mushroom 3iij ; honey q. s. to make an electuary. In pulmonary consumption. Dose. 3'iiss to 3iss, 3 or 4 times a day. OPIUM. Smyrna or Levant opium should be chosen, especially for the manufacture of the salts of morphia, as it contains on the average from 7 to 9$ of that alkaloid, and usually yields about 12 to 12J$of muriate of morphia, which is more than can be obtained from any other variety of opium. The following process of Morphometry is given by the Edinburgh College :—Macerate 100 grs. of opium for 24 hours in ffij of water, filter, and strongly squeeze the residue ; then precipitate with carbonate of soda ^ss, dissolved in cold water f fij ; heat the precipitate till it shrinks and fuses, then cool and weigh it; it should weigh at least 11 grs.; and when powdered be entirely soluble in a solu- tion of oxalic acid.—Another excellent process for ascertaining the quality of opium is, to boil an in- fusion of 4 parts of opium with 1 part of quicklime, made into a milk with water, to filter while hot, saturate with a dilute acid, (hydrochloric,) and to precipitate the morphia by ammonia. (Couerbe.) There have been several modes of purifying opi- um adopted by various persons, among which the following may be mentioned :— Soft Purified Opium. (Opium purificatum Molle.) Picked opium softened with water to a pillular consistence. Hard Purified Opium. (Opium purif. durum.) Picked opium dried in a water-bath for pow- dering. . Strained Opium. (Ext. Thebaicum. Opium OPO 462 OXA Colatum. Opium Purificatum. Laudanum Opi- atum.) Opium dissolved, or softened, in an equal weight of water, pressed through canvass, and evaporated to a pillular consistence. Homberg's Purified Opium. Opium exhausted by repeated coction in 10 or 12 times its weight of water, and the mixed liquors evaporated to $, and kept boiling for 2 or 3 months, adding water from time to time, then straining and evaporating to a pillular consistence. Baume's Purified Opium. The same as the last. Cornette's Purified Opium. The common extract dissolved in cold water, strained, and evap- orated to an extract, and the process repeated sev- eral times. Josse's Purified Opium. Crude opium worked under water as long as any thing is dissolved, the solution strained, and evaporated to an extract. Accarie's Purified Opium. Infusion of opium digested with powdered charcoal for some days, strained, clarified with white of egg, and evapo- rated to an extract Powel's Purified Opium. Opium exhausted by coction with water, the residuum treated with spirit of wine, and the mixed tincture and decoc- tion evaporated to an extract. Neumann's Opium. Infusion of opium, strained, fermented with a little sugar, set it in a warm place, and when the fermentation slackens, it is again excited by stirring up the lees; continue this for some months, or as long as it can be made to ferment. It is either evaporated to an extract or kept in the liquid form. Lancelotte's Prepared Opium. Opium lb.j; quince juice 1 gall.; pure potassa f j ; sugar 5'V ; ferment for some time, evaporate to a sirup, digest in spirit of wine, filter, and distil off the spirit. Quercetan's Opium. Vinegar of opium evapo- rated to an extract Glaser's Prepared Opium. An infusion of opium made with may-dew, filtered and evapo- rated. Glauber's Pre *ared Opium. Opium %\v ; spirit of salt fiss ; crea.-i of tartar §j ; mix, digest in spirit of wine 1 quart, filter, and evaporate. *** Of the above, those that are made with cold water, or by fermentation, are considered milder than crude opium ; the latter resemble "The black drop." OPODELDOC. Syn. Soap Liniment. This article, prepared according to the directions of the Pharmacopceia, is apt to gelatinize, or to deposite crystals of elaidate and stearate of lime. This may be avoided where expense is not an objection, by well drying the soap, employing a spirit of 85$, and keeping it in well-closed vessels. OPODELDOC, STEER'S. Prep. I. White Castile soap, cut very small, 2 lbs.; camphor 5 oz.; oil of rosemary 1 oz.; oil of origanum 2 oz.; recti- fied spirit 1 gall.; dissolve in' a corked bottle by the heat of a water-bath, and when considerably cooled, strain ; add liquor of ammonia 11 oz.; im- mediately put it into bottles, (Steer's,) cork close, and tie over with bladder. Very fine, solid and transparent when cold. II. Soap 4 oz.; camphor 1 oz.; oils of rosema- ry and origanum, of each 1 dr.; rectified spirit 1 pint; liquor of ammonia 1$ oz.; mix. III. To the last add water J pint. Used as a liniment. ORANGEADE. Syn. Orange Sherbet. Prepared with oranges in the same way as lemon- ade. ORANGE DYE. This may be given by mix- ing red and yellow dyes in various proportions. A very good fugitive orange may be given with an- notto, by passing the goods through a solution made with equal parts of annotto and pearlash ; or still better, through a bath made of 1 part of annotto dissolved in a lye of 1 part each of lime and pearl- ash, and 2 parts of soda. The shade may be red- dened by passing the dyed goods through water acidulated with vinegar, lemon-juice, or citric acid; or through a solution of alum. The goods are sometimes passed through a weak alum mordant before immersion in the bath. ORANGE PEEL, CANDIED. This is pre- pared in the same way as candied citron or lemon peels. ORCEINE. Syn. Lichen Lake. A brown- ish-red powder, obtained by dissolving orcine in liquor of ammonia, exposing the solution to the air, and precipitating with an acid. ' ORCINE. The coloring principle of the lichen dealbatus. It may be obtained by treating the powder with boiling alcohol, filtering while hot, cool- ing, again filtering, distilling off the alcohol, evap- orating to a sirup, triturating with water, filtering, again evaporating to a sirup, and leaving the liquid for some days in a cool place, when crystals of orcine will form. It is volatile, and soluble in water and alcohol. By solution in ammonia it yields orceine. ORGEAT Syn. Sirop d'Orgeat. Barley Sirup. Prep. I. Sweet almonds 1 lb.; bitter al- monds 4, oz.; blanch, beat to a paste, and make an emulsion with barley water 1 quart ; strain, and to each pint add sugar 1^ lb.; and a tablespoonful of orange-flower water. II. Sweet almonds 3 oz.; 2 bitter almonds; or- ange-flower water 1 tablespoonful ; milk 1 quart; sugar 1 lb. ; make an emulsion. Some persons add a little brandy. ORES. The mineral bodies from which metals are extracted. (See Testing and Metals.) OSMIUM. (From oops, odor.) A rare metal found associated with the ore of platinum. Its sp. gr. is 7. It forms severa'l compounds with oxygen, chlorine, and sulphur, of which the most remark- able is osmic acid. This compound is very vola- tile, and evolves a pungent and disagreeable odor, which has given the name to the metal. (See Iridium.) OXALATES. Syn. Oxalas, (Lat.) A com- pound of oxalic acid and a base. (See Oxalic Acid.) OXALATES OF POTASH. Prep. I. (Ox- alate of Potash. Potassa Oxalas.) Neutralize a solution of oxalic acid, or the acid oxalates of commerce, with carbonate of potash, evaporate and crystallize. II. (Binoxalate of Potash. Potassa Binox- alas. Salt of Sorrel. Sal acetosella.) By sat- urating a solution of 1 part of oxalic acid with carbonate of potash, and adding it to a similar so- lution of 1 part of the acid unneutralized ; evapo- rating and crystallizing. It may ajso be obtained from the expressed juice of wood or sheep's sorrel OXA 463 OXI by clarifying with eggs or milk, evaporating and crystallizing. In commerce the quadroxalate of potash is usually substituted for it. III. (Quadroxalate oj'Potash. Potassa Quad- roxalas.) By neutralizing 1 part of oxalic acid with carbonate of potash, adding to the solution 3 parts more of acid, evaporating and crystallizing. Or by dissolving the binoxalate in dilute hydrochlo- ric, and crystallizing. This salt is commonly sold in commerce as Binoxalate of Potash. Sal Ace- tosella, Salt of Sorrel, and Essential Salt of Lemons. Both this and the binoxalate are used to remove ink and iron stains from linen, to bleach the straw used for making bonnets, and occasion- ally in medicine as a refrigerant. When pure, each of the above yields nothing but carbonate of potash by heat. *** All the oxalates of potash are poisonous. OXALIC ACID. Syn. Acid of Sugar. Acid- dm Oxalicum, (Lat) Acide Oxalique, (Fr.) SauerkleeseLure, (Ger.) This acid was discov- ered by Scheele in 1776. It occurs both in the mineral and organic kingdoms, and is produced artificially by the action of nitric acid on sugar, starch, woody fibre, &c. Prep. I. (Liebig.) Nitric acid (sp. gr. 1*42) 5 parts ; water 10 parts ; mix, add sugar, or prefer- ably potato starch 1 part, and digest by a gentle heat as long as gaseous products are evolved ; evaporate and crystallize ; dry the crystals, redis- solve, and crystallize. 12 parts of potato starch yield 5 of acid. The mother water, treated with more nitric acid, and again warmed, will yield a second crop of crystals ; and this should be repeat- ed till the solution is exhausted. II. (Ure.) Nitric acid (sp. gr. 1*4) 4 parts ; su- gar 1 part ; digest together in a water-bath. III. (Schlesinger.) Sugar 4 parts, (dried at 257° F. ;) nitric acid (1-38) 33 parts ; the mixture, as soon as the evolution of gas ceases, is to be boiled down to one-sixth its original volume, and allowed to crystallize. The whole process may be executed in 2 hours, and in 1 vessel, and yields of beautifully crystallized oxalic acid from 56 to 60$ of the sugar employed. Remarks. On the large scale, the first part of the process is usually conducted in salt-glazed stoneware pipkins, about two-thirds filled and set in a water-bath ; but on the small scale, a glass retort or capsule may be used. The evaporation should be preferably conducted by steam. The evolved nitrous vapors are usually allowed to es- cape, but if conveyed into a chamber filled with cold damp air, and containing a little water, they will absorb oxygen, and be recondensed into fuming nitric acid. In England an equivalent proportion of molasses is usually substituted for sugar. Messrs. Davy, Macmurdo &. Co.'s patent process, consists in first converting potato fecula into grape sugar with sulphuric acid, and then decomposing the sugar thus obtained by nitric acid, in the usual way. Dr. Ure recommends the use of a little sul- phuric acid along with the nitric acid, which, he says, contributes to increase the product " 15 lbs. of sugar yield fully 17 lbs. of crystallized oxalic a*cid." (Ure.) Chemically pure oxalic acid is best prepared by precipitating a solution of binoxalate of potash with acetate of lead, washing the pre- cipitate with water, and decomposing it while still | moist with dilute sulphuric acid or sulphureted hy- drogen. Prop., Uses, $c. Pure oxalic acid forms odor- less, colorless, prismatic crystals, possessing a pow- erful sour taste, and forming salts with the bases termed Oxalates. It effloresces in warm dry air, fuses and sublimes at 350°, dissolves in 8 parts of water and 4 parts of alcohol at 60°, and in its own weight of boiling water. Oxalic acid is chiefly used in the arts of calico printing and bleaching ; to remove ink-spots and iron-moulds from linen, and to clean boot-tops. It is poisonous. Tests. 1.—Oxalic acid gives a white precipitate with nitrate of silver, soluble in nitric acid, and which, when heated, yields pure silver.—2. With lime water or muriate of lime a white precipitate, soluble in nitric acid. Ant. Promote vomiting, and administer chalk, whiting, or magnesia, mixed up with water, in considerable quantities. OXALURIC ACID. A new acid discovered by Wohler and Liebig, and obtained by heating a solution of parabanic acid with ammonia, and de- composing a hot saturated solution of the resulting oxalurate of ammonia with dilute sulphuric acid, and rapidly cooling the liquid, when oxaluric acid falls as a white crystalline powder. OX A METHANE. Syn. Etheroxamide. Oxalate of Ether and Oxamide. A colorless crystalline substance, prepared by dissolving oxalic ether in alcohol, and gradually adding alcohol saturated with dry ammoniacal gas, till a white powder begins to fall, when after some hours the solution is filtered, evaporated, and crystallized. OXAMIDE. Syn. Oxalamide. A snow- white, tasteless, crystalline powder, obtained du- ring the destructive distillation of oxalate of ammo- nia. OXIDE. (Oxydum, Lat, from 0<)t>s, acid, and eiios, form.) A compound of oxygen and a metal. •The oxides unite with the acids, forming com- pounds called salts. To designate the different oxides of the same base, and to mark the number of equivalents of oxygen combined with one equiva- lent of metal, derivatives from the Greek or Latin are generally employed. Thus the terms oxide or protoxide, the deutoxide, tritoxide, &c, are ap- plied to-the first, second, third, &c. oxide of the same base ; and the last oxide, in which the base is saturated with oxygen, without being acid, is called the peroxide. In like manner the terms oxide or protoxide, sesquioxide, binoxide, terox- ide, &c, denote that the oxygen is in the ratio to the metal of 1 to 1,-1 i to 1 or 3 to 2,-2 to 1,— 3 to 1, &c. The Greek numerals dis, tris, tetra- his, &.c, are prefixed in a similar way, to denote oxides formed of 1 equivalent of oxygen with 2, 3, or more equivalents of metal. More complex ratios are denoted by a fraction, the numerator of which represents the eq. of oxygen, and the denominator the eq. of metal. The terminations ous and ic are occasionally employed in the same way as noticed under acids, the former being applied to the lower and the latter to the higher state of oxidizement, as cuprous oxide, cupric do., ferrous oxide, ferric do., applied to the respective oxides of copper and iron. Oxides containing less than 1 eq. of oxygen to 1 eq. of metal, are commonly called suboxides. The same system of nomenclature is also applied OXY 464 OXV to 6aline compounds; as—protochloride, sesqui- ckloride, bichloride, terchloride, oxalate, binoxa- late, sulphate, bisulphate, $-c. OXYCHLORIDES. Compounds formed by the union of a metallic oxide with the chloride of a metal. They are commonly called subchlo- rides, or submuriates. (See Index.) OXY FLUORIDES. Double compounds of fluorides and oxides. They possess no practical importance. OXYGEN. Syn. Oxygen Gas. Vital Air. Empyreal do. Dephlogisticated do. Oxygene, (Fr.) Sauerstoff, (Ger.) Oxygenium, (Lat., from i|t>s, acid, and yewdta, I generate.) An ele- mentary gaseous body, discovered by Priestley in, 1774. Prep. I. Place chlorate of potash in a green glass retort, and heat it nearly to redness over a spirit-lamp. Pure. Prod. 100 grs. yield nearly 100 cubic inches. (Brande.) 100 grs. yield 115 cubic inches. (Ure.) II. Expose red oxide of mercury to heat as above. Pure. III. (Faraday.) Coarsely-powdered chlorate of potash 3 parts ; powdered binoxide of manga- nese 1 part; (both by measure ;) mix, put them into a flask or retort, and place it over the flame of a spirit-lamp, or a few pieces of ignited charcoal, when in a few minutes oxygen will be evolved with a rapidity entirely at the command of the opera- ' tor, by either increasing or lessening the heat. The residue in. the retort may be kept for another operation, if not exhausted, or may at once be washed out with a little warm water, and the man- ganese reserved for another time, as it is uninjured by the process. Red lead, black oxide of copper, and several other substances, will answer nearly as well as oxide of manganese. " 100 grs. of the mixture yield 110 cubic inches of pure oxygen." (G. F. Fisher.) This is a very convenient and simple process. IV. (Balmain.) Bichromate of potash 3 parts ; oil of vitriol 4 parts ; mix, and heat as above. Yields pure oxygen with a rapidity entirely at the command of the operator. V. Expose nitre to a red heat in an iron retort. 1 lb. yields 1200 cubic inches slightly contaminated with nitrogen. VI. Expose black oxide of manganese to a red heat as last. Prod. 1 oz. of pure binoxide of man- ganese yields 44 grains or 128 cubic inches of gas. (Liebig.) 1 lb. of common oxide of manganese yields from 30 to 40 pints, and fine samples from 40 to 50 pints of gas sufficiently pure for ordinary purposes. This is the most economical process on the large scale. VII. Binoxide of manganese and oil of vitriol, equal parts ; mix them well together in a glass retort, and apply heat. Prod. Every 44 grs. of pure binoxide of manganese yield 8 grs. or 24 cubic inches of oxygen. 1 oz. yields 88 grs., or 256 cubic inches. (Liebig.) Remarks. The gas procured by any of the above processes must be collected in the usual way, either over water, mercury, or in bags. The gas procured from manganese or nitre may be pu- rified by passing it through milk of lime, or a solu- tion of caustic potassa. Props., Uses, fyc. Colorless, odorless, tasteless, and incombustible ; sp. gr. 1*111, (1026 Berzelius, Dulong, &c.;) 100 cubic inches weigh 33*6 gre.; it is a powerful supporter of combustion, and its presence is essential to the existence of both ani- mal and vegetable life; it forms 21 % by volume of the atmosphere. It is distinguished from other gases by yielding nothing but pure water when mixed with twice its volume of hydrogen and ex- ploded, or when a jet of hydrogen is burned in it A recently-extinguished taper, with the wick still red hot, instantly inflames when plunged into this gas. A small spiral piece of iron wire ignited at the point, and suddenly plunged into a jar of oxy- gen, burns with great brilliancy and rapidity. Water dissolves about 5$ by volume of oxygen, but by pressure a much larger quantity. It is said to be a valuable remedial agent in asphyxia arising from the inhalation of carbonic acid or carbonic oxide. OSMAZOME. A brownish yellow substance, having the smell of soup, obtained by digesting raw muscular fibre in cold water, filtering, evapo- rating, treating the residue with alcohol, and again filtering and evaporating. OXYMEL. (From ofys, acid, and ■JtAi, honey.) An acidulous sirup made of honey and vinegar. (See Filtration, Clarification, and Sirup.) OXYMEL OF COLCHICUM. Syn. Oxymel (cormi) Colchici. Prep. (P. D.) Fresh corms (roots) of meadow saffron ^j > distilled vinegar 1 pint, (wine measure;) macerate for 2 days, press out the liquor, filter, add clarified honey lb. ij, and boil down to the consistence of a sirup, fre- quently stirring. Dose. 1 to 3 dr. twice a day, in gout, rheumatism, dropsy, &c. OXYMEL OF CREAM OF TARTAR. -Syn. Oxymel Potassa bitartratis. Prep. Powdered cream of tartar §ij ; hot water \ pint; honey lb. ij ; boil for 10 minutes, and strain. Cooling ; laxa- tive ; used to " cut the phlegm," &.c. OXYMEL OF GARLIC. Syn. Oxymel Alii. Prep. (P. L. 1746.) Sliced garlic giss ; caraway seed, and sweet fennel seed, of each 3ij ; boiling vinegar f^viij ; infuse, strain, and add clarified honey §x. OXYMEL, PECTORAL. Syn. Oxymel pec- torale. Prep. (Brun's Ph.) Bruised elecampane §j ; do. orris root ^ss ', water f ^xxxvj; boil to §xxiv; strain, add honey §xvj, ammoniacum Jj, (dissolved in) vinegar f ^viij ; boil to an oxymel. In coughs, &,c. OXYMEL OF SQUILLS. Syn. Honey of Squills. Oxymel Scill^e. (P. L. & D.) Do. scilliticum. Prep. (P. L.) Clarified honey lb. iij; vinegar of squills 1£ pints; boil to a proper consistence. Expectorant. Dose f3j to f3ij, in chronic coughs and asthma. OXYMEL, SIMPLE. Syn. Oxymel, (P. L & D.) Do. simplex. Vinegar Sirup. M el ace- tatum. Syrupus aceti. Syr. acidi acetici. Prep. (P. L.) Clarified honey lb. x ; acetic acid (P. L.) 1£ pints; mix with heat. Expectorant and refri- gerant. Dose. 3j to %sa, diluted with water, in coughs, &c.; diffused through some demulcent li- quid, it is used as a drink in fevers, and added to gargles in sore throat. *** The following are the proportions I have seen used in trade:—Honey 12 lbs.; distilled vinegar (of 5$) 2 quarts ; evaporate if required. PAI 465 PAL OXY MEL OF VERDIGRIS. (See Liniment of Verdigris.) OXYSACCHARA. Sirups acidulated with vinegar. OYSTERS are nutritious, and easy of diges- tion. They are in season in each month of the year, the name of which contains the letter R. The best British oysters are found at Purfleet; the worst near Liverpool. OZONE. This term has been applied to the odor perceived in the immediate vicinity of elec- trical machines in good action. PAINTINGS. Pres. and Restor. Many valua- ble paintings suffer premature decay, from the at- tacks of a microscopic insect of the mite class. This is especially the case with " Christ's Pas- sion," by Northcote, in the Hanover chapel, Re- gent-street,—the " Raising of Lazarus," in the National Gallery, and several pictures in the Louvre. The best method of preventing this spe- cies of decay, is to add a few drops of creosote to the paste and glue used to line the picture, as well as to make a similar addition to the varnish. If it has already commenced, the painting should be at once carefully cleaned and relined, observing to employ a little creosote in the way just mentioned. Paintings should be kept in as pure an atmosphere as possible, and in a moderately dry situation ; as it is the presence of sulphureted hydrogen in the air that blackens the " lights," and causes most of the middle tints and shades to fade ; and it is ex- posure to damp that produces mouldiness and de- cay of the canvass. For this reason valuable paint- ings should not be kept in churches, nor suspended against heavy walls of masonry, especially in bad- ly-ventilated buildings. Excess of light, particularly the direct rays of the sun, also acts injuriously on paintings. The blackened lights of old pictures may be instantly restored to their original hue, by touching them with deutoxide of hydrogen, diluted with 6 or 8 times its weight of water. The part must be afterwards washed with a clean sponge and water. PAINTS, FISH OIL. Prep. Dissolve white vitriol and litharge, of each 14 lbs., in vinegar 32 gallons; add whale, seal, or cod oil 1 ton, and boil to dryness, continually stirring during the ebulli- tion. The next day decant the clear portion, add boiled linseed oil 12 gallons, oil of turpentine 3 gal- lons, and mix well together. The sediment left is well agitated with half its quantity of lime water, used for some inferior paints, under the name of "prepared residue oil." This oil is used for vari- ous common purposes, as a substitute for linseed oil, of which the following paints are exam- ples :— 1. (Green.)—a. Lime water 6 galls.; whiting and road dust, of each 1 cwt.; blue black 30 lbs.; yellow ochre 28 lbs.; wet bine (previously ground in prepared residue oil) 20 lbs.; grind well to- gether. For use, thin with equal parts of prepared residue oil and linseed oil. Pale.—b. Yellow ochre and wet blue, of each 1 cwt.; road dust 1£ cwt.; blue black 10 lbs.; lime water 6 gallons ; prepared fish oil 4 gallons ; prepared residue and linseed oils, of each 7£ gallons. Bright green. 2. (Lead color.) Whiting 1 cwt.; blue black 7 5.9 lbs.; whitelead (ground in oil) 28 lbs.; road dust 56 lbs.; lime water 5 gallons; prepared residue oil 2$ gallons. 3. (Reddish brown.) Lime water 8 gallons ; Spanish brown 1 cwt; road dust 2 cwt.; pre- pared fish, prepared residue, and linseed oils, of each 4 gallons. 4. (Yellow.) Substitute yellow ochre for Span- ish brown in the last receipt. 5. (Black.) Substitute lamp or blue black for Spanish brown in No. 3. 6. (Stone color.) Lime water 4 gallons ; whit- ing 1 cwt. i whitelead (ground in oil) 28 lbs.'; road dust 56 lbs.; prepared fish, linseed, and prepared residue oils, of each 3 gallons. 7. (Chocolate.) No. 3 and No. 5 mixed to- gether so as to form a chocolate color. Remarks. AH the above paints require a little " driers." They are well fitted by their cheap- ness, hardness, and durability, for common out- door work. PAINTS, FLEXIBLE. Prep. Yellow soap cut into slices 1$ lbs.; boiling water 1 gall.; dis- solve and mix while hot with oil paint 14, cwt. Used to paint canvass. PAINTS, TO MIX. In mixing paints, ob- serve, that for out-door work you must use princi- pally or wholly boiled oil, unless it be for the deco- rative parts of houses, &c, then mix as for in- door work.—For in-door work use linseed oil, tur- pentine, and a little " driers," observing, that the less oil, the less will be the gloss, and that for "flatted white," &c, the color being ground in oil, will scarcely require any further addition of that article, as the object is to have it dull. The best " driers" are, ground litharge and sugar of lead ;—the former for dark and middle tints, and the latter for light ones. PALLADIUM. A metal resembling platinum, discovered by Wollaston in 1803. It is obtained by adding a solution of bicyanide of mercury to a neutral solution of the ore of platinum in nitromu- riatic acid, and exposing the precipitate to a red heat. It resembles platinum in appearance. Sp. gr. 11-3 to 11-8. It forms compounds with oxygen, chlorine, and sulphur.—Protoxide of palladium is precipitated as a brown hydrate by adding an alkaline carbonate in excess to any of its.salts; and this precipitate, when heated to redness, forms the anhydrous black protoxide. It forms salts with the acids.—Binoxide of palladium is best ob- tained by treating solid bichloride of palladium and potassium with a solution of potassa in excess, and heating the mixture to 212°. Black.—Protochlo- ride of palladium is a brown crystalline mass, ob- tained by evaporating the nitromuriatic solution to dryness. By heat it loses its water and turns black. Oxide of palladium forms red salts with the acids. The neutral solutions of palladium are precipitated in the metallic state by sulphate of iron,—dark brown by sulphureted hydrogen, olive by prussiate of potash, and yellowish w-hite by prussiate of mercury. By the last test it is easily distinguished from platinum. PALMIC ACID. Prep. Decompose soap pre- pared from palmine and potassa, by tartaric acid, dissolve the fatty acid th?t separates in cold alco- hol, and evaporate. Crystallizable ; soluble in al- cohol and ether ; melts at 122°. It may also be PAP 4bb PAR made from the solid mass obtained by passing sul- phurous acid through castor oil. PALMINE. A new fatty substance obtained by treating castor oil with nitrous acid. It melts at 143°, and when saponified yields palmic acid and oxide of glycerule. PALMITIC ACID. Prepared from palm oil in a similar way to palmic acid from palmine. It is purified by pressure between paper, washing with hot alcohol, and crystallization from hot ether. It forms pearly scales, and melts at 140°, like mar- garic acid. PALMITINE. The chief ingredient of palm oil or butter. It is purified in the same way as the last. PANACEA. (From nav, all, and anto/iai, I cure.) A term applied by the ancients to those remedies supposed to be capable of curing all dis- eases. Unfortunately for mankind, no such a medicine exists. The name is still applied to some quack medicines.—Panacea of Antimony (Pan. Antimonii) is prepared by deflagrating in a red- hot crucible a mixture of sulphuret of antimony §vj, nitre §x, common salt §iss, and charcoal dust §j. The uppermost spongy scoria is rejected, and the remainder powdered and well washed. Golden- colored. The active ingredient in Lockyer's Pills. —Panacea of Mercury, (Pan. Mercurialis.) Mercurius dulcis (calomel) sublimed 9 times. PAPER, COPYING. Prep. Make a stiff ointment with butter or lard and lampblack, and smear it thinly and evenly over soft writing paper, by means of a piece of flannel, then wipe off the redundant portion with a piece of soft rag. Placed on paper and written on with a style or solid pen. By repeating the arrangement, two or three copies of a letter may be obtained at once. This paper, set up in a case, forms the ordinary " Manifold writer." PAPER DYES. Paper and parchment may be stained by any of the simple dyes or liquid colors. PAPER, FIREPROOF. This is prepared in a similar way to fireproof cloth. (See Incombusti- ble Cloth, and Fires.) PAPER OF SAFETY. Syn. Papier de Surete. White paper pulp mixed with an equal quantity of pulp tingec* with any stain easily af- fected by chlorine, acids, alkalis, &c, and made into sheets as usual. PAPER, OILED. Prep. Brush sheets of pa- per over with " boiled" oil, and suspend them on a line till dry. Waterproof. Extensively employed to tie over pots and jars, and to wrap up paste blacking, ground whitelead, &c. PAPER, TRACING. Prep. I. Lay open a quire of paper, of large size, and apply with a clean sash tool a coat of varnish, made of equal parts of Canada balsam and oil of turpentine, to the upper surface of the first sheet, then hang it on a line, and repeat the operation on fresh sheets until the proper quantity is finished. If not sufficiently transparent, a second coat of varnish may be applied as soon as the first has become quite dry. II. Rub the paper with a mixture of equal parts of nut oil and oil of turpentine, and dry it immedi- ately by rubbing it with wheat flour, then hang it on a line for 24 hours. Both the above are used to copy drawings, writings, &c. If washed ovei with ox gall and dried, they may be written on with ink or water colors. The paper prepared from the refuse of the flax mill, and of which bank notes are made, is also called tracing paper, and sometimes vegetable paper. PAPER, WAXED. Prep. Place cartridge paper on a hot iron plate and rub it with beeswax Used to form extemporaneous steam or gas pipes, and to cover the joinings of vessels. PAPERS, TEST. Litmus, Turmeric, Cher- ry-juice, Mallow flower, Elderberry, Brazil wood, Buckthorn, Dahlia petal, Acetate of Lead, Diacetate of Lead, Protosulphate of Iron, Starch, SfC, papers, are made by wetting sheets of unsized writing paper with an infusion or solution of the respective substances. They are all used as tests to discover acids, alkalis, sulphureted hydrogen, iodine, &c. PAPIER-MACHE. Pulped paper moulded into forms. It possesses great strength and light- ness. It may be rendered partially waterproof by the addition of sulphate of iron, quicklime, and glue, or white of egg, to the pulp ; and incombusti- ble by the addition of borax and phosphate of soda. The papier-mache' tea-trays, waiters, snuff-boxes, &c., are prepared by pasting or gluing sheets of paper together, and submitting them to powerful pressure, by which the composition acquires the hardness of board when dry. Such articles are af- terwards japanned, and are then perfectly water- proof. PARABANIC ACID. A new acid, obtained by Wohler and Liebig by treating 1 part of uric acid or alloxan with 8 parts of strong nitric acid, and evaporating to a sirup, when crystals form after standing some time, which are purified by resolution and crystallization. Soluble in water. PARACYANOGEN. The brown solid matter left in the retort, when cyanide of mercury is de- composed by heat. Cyanogen and paracyanogen are isomeric compounds: hence the name. Inso- luble in water. PARAFFINE. (From parum, little, and affinis, akin.) Prep. Distil beech tar to dryness, rectify the heavy oily portion of the product till a thick matter begins to rise, then change the receiver, and moderately urge the heat as long as any thing passes over. Next digest the product in the second receiver, in an equal measure of alcohol of 0*833, and gradually add 6 or 7 parts more of alcohol. Crystals of paraffine will gradually fall down, which, after being washed in cold alcohol, must be dissolved in boiling alcohol, which will deposite crystals of pure paraffine as it cools. White ; odor- less; tasteless; sp. gr. 0*87; melts at 112°, and dissolves in boiling alcohol and in oils. It bums entirely away with a clear white flame, without smoke. PARANAPHTHALINE. Syn. Anthracink. A substance found in coal tar. Naphthaline, and paranaphthaline, are isomeric compounds; nence the name, from trapa, near to. PARAPHOSPHORIC ACID. (See Meta- phosphoric Acid.) PARFAIT AMOUR. Prep. The peels of 12 lemons ; rectified spirit of wine 2' gallons , digest 1 week ; add water 1 quart, distil 2 gallons, and add an equal weight of simple sirup, and a little -*oaise- PAS 467 PAS ly-powdered cochineal to color. A pleasant cor- dial liqueur. PARFUM. (Pour parfumer les autres pou- dres.) Poudre d'Ambrette 12 lbs.; civet ljoz.; musk 1 dr.; reduce the last two to powder by grinding them with some dry lump sugar; then mix the whole together and pass it through a sieve. (See Poudres.) PASTE, ALMOND. Syn. Pasta Amygdali- na. Pasta Regia. Prep. I. Liquid.—a. (Ho- ney Paste.) Clarified honey and white hitler paste, of each 1 lb.; knead together, and when well mixed, add, in alternate portions, oil of almonds 2 lbs., and the yelks of 5 eggs. Much esteemed.— 6. (Orange.) Blanched sweet almonds and white sugar, of each 1 lb.; blanched bitter almonds £ oz.; beat to a perfectly smooth paste, with orange-flow- er water q. s., so that it may be sufficiently stiff not to stick to the fingers? In a similar way are made rose, vanilla, nosegay, and other almond pastes. II. Pulverulent, a. (Gray.) Prepared from the cake of bitter almonds, from which the oil has been thoroughly expressed, by drying, grinding, and sifting.—b. (Bitter White.) As the last, but the almonds are blanched before being pressed.— c. (Sweet White.) As ,the last, but using sweet almonds. *** All the above are employed as cos- metics. The honey, and the sweet and bitter white pastes are those most esteemed. PASTE, CHINESE. Prep. Bullock's blood 10 lbs.; finely-powdered quicklime 1 lb.; mix well. For use, it is beat up with water. This paste will seldom keep good longer than three weeks. PASTE, FLOUR. Syn. Colle de Pate. 'Wheat flour made into a thin batter with cold water, and then boiled. *** It must be stirred all the time it is on the fire, to prevent its getting lumpy. Paper-hangers, shoemakers, &c, usually add to the flour one-sixth to one-fourth of its weight of finely-powdered rosin. The latter is sometimes called " hard paste." The addition of a few drops of oil of cloves or creosote, or a little powdered camphor or colocynth, (especially the first and second,) will prevent insects from attacking it, and preserve it in covered vessels for years. Should it get too hard it may be softened with water. PASTE, FURNITURE. Prep. I. Turpen- tine 1 pint; alkanet root £ oz.; digest until suffi- ciently colored, then add beeswax, scraped small, 4 oz.; put the vessel into hot water, and stir until dissolved. If wanted pale, the alkanet should be omitted. II. (White.) White wax 1 lb.; liquor of po- tassa £ gallon ; boil to a proper consistence. III. Beeswax 1 lb. ; soap \ lb.; pearlash 3 oz., (dissolved in water £ gallon, and strained;) boil as last. PASTE, GERMAN. Prep. Pea meal 2 lbs.; blanched sweet almonds 1 lb.; fresh butter or lard i lb.; moist sugar 5 oz.; a shred or two of hay saffron ; beat to a smooth paste, and granulate it by passing it through a colander. The addition of the yelks of 2 or 3 eggs improves it. Used to feed larks, nightingales, and other insectivorous birds. It will keep good for 6 months in a dry place. PASTE, ORANGE. Prep. Blanched bitter almonds 7 !bs.; orange flowers 2£ lbs.; beat to a paste. Used as a cosmetic. PASTE, ORGEAT. Prep. Blanched Jordan almonds 1 lb.; do. bitter almonds \ lb.; beat to a paste with orange-flower water q. s., and put it into pots. For use mix an ounce with half a pint of water, and strain through a piece of flannel. PASTE, RAZOR. Prep. I. Levigated oxide of tin (prepared putty powder) 1 oz.; powdered oxalic acid \ oz.; powdered gum 20 grs.; make it into a stiff paste with water, and evenly and thinly spread it over the strop. With very little friction this paste gives a fine edge to the razor, and its efficiency is still further increased by moist- ening it. II. (Mechi's.) Emery reduced to an impalpable powder 2 parts ; spermaceti ointment 1 part; mix together, and rub it over the strop. III. Jewellers' rouge, blacklead, and suet, equal parts; mix. PASTE, SHAVING. Prep. White wax, spermaceti, and almond oil, of each \ oz.; melt, and while warm, beat in 2 squares of Windsor soap previously reduced to a paste with rose water. PASTES. Syn. Factitious Gems. Pierres precieuses artificielles, (Fr.) Glaspasten, (Ger.) Vitreous compounds made to imitate the gems. In addition to the remarks at page 331, it may be observed that the beauty of pastes, or fac- titious gems, especially the brilliancy of mock dia- monds, is mainly dependent upon the setting up and the skilful arrangement of the foil or tinsel behind them. The following are the most approv- ed formulas for producing exact imitations of sev- eral of the gems:— I. Amethyst.—1. (M. Lancon.) Strass 9216 grs.; oxide of manganese 15 to 24 grs.; oxide of cobalt 1 gr.—2. (M. Douault-WieTand.) Strass 4608 grs.; oxide of manganese 36 grs.; oxide of cobalt 24 grs.; purple of cassius 1 gr. II. Beryl, or aqua marina. (M. Douault- WieTand.) Strass 3456 grs.; glass of antimony 24 grs.; oxide of cobalt 1 £ grs. III. Chrysolite. Strass 5 lbs.; calcined per- oxide of iron 3 to 4 drs. IV. Cornelian.—1. (Red.) Strass "2 lbs.; glass of antimony 1 lb.; calcined peroxide of iron (rouge) 2 o*.; manganese 1 dr.—2. (White.) Strass 2 lbs.; washed yellow ochre 2 dr.; calcined bones 1 oz. V. Diamond. Syn. Strass. Paste. I. (M. Fon- tanier.)—a. Litharge 20 parts; silica 12 parts; nitre and borax, of each 4 parts ; white arsenic 2 parts; powder, mix, fuse in a crucible, pour the melted mass into water, separate any reduced lead, and again powder and remelt.—6. (Mayenct base.) Silica 8 oz.; salt of tartar 24 oz.; mix bake, cool, wash with dilute nitric acid, and after- wards with water; dry, powder, add 12 oz. of pure carbonate of lead, and to every 12 oz. of the mixture add borax 1 oz.; triturate in a porcelain mortar, melt in a clean crucible, and pour the fused compound into cold water ; dry, powder, and repeat the process a second and a third time in a clean c-ucible, observing to separate any re- vived lead. To the third fritt add nitre 5 drachms, and again melt. Very brilliant.—c. Carbonate of lead 8 oz. *, powdered borax 2 oz.; rock crystal 3 oz.; manganese i gr. ; mix, and proceed as last. __2. (Loysel.) Pure silex 100 parts; red oxide of lead (minium) 150 parts; calcined potash 30 to PAS 468 PAT 35 parts; calcined borax 10 parts; oxide of arse- nic 1 part. This produces a paste which has great brilliancy and refractive and dispersive pow- ers, and also a similar specific gravity to the orien- tal diamond. It fuses at a moderate heat, and acquires the greatest brilliancy when remelted, and kept for 2 or 3 days in a fused state, in order to expel the superabundant alkali, and perfect the refining. (Polytech. Journ.)—3. (M. Douault- WieTand.)—a. Rock crystal 4056 grs.; minium 6300 grs.; potash 2154 grs. ; borax 276 grs. ; arsenic 12 grs.;—b. Sand 3600 grs. ; pure car- bonate of lead 8508 grs.; potash 1260 grs.; borax 360 grs.; arsenic 12 grs.—4. (M. Lancon.) Li- tharge 100 grs.; silex 75 grs.; white tartar or potash 10 gre. VI. Eagle Marine. Paste or strass 10 lbs.; copper highly calcined with sulphur (copper-stain) 3 oz.; zaffre 1 scruple. VII. Emerald.—1. (M. Lancon.) Paste 9612 grs.; acetate of copper 72 grs.; peroxide of iron 11 grs.—2. (M. Douault-WieTand.) Paste 4608 grs.; green oxide of copper 42 gre.; oxide of chrome 2 grs.—3. Paste 1 oz.; glass of antimony 20 grs.; oxide of cobalt 3 grs.—-4. Paste 15 oz.; carbonate of copper 1 dr.; glass of antimony 6 grs. VIII. Lapis Lazuli. Paste 10 lbs.; calcined horn or bones 12 oz.; oxides of cobalt and manga- nese, of each £ oz.; mix. The golden veins are produced by painting them on with a mixture of gold powder, borax, and gum water, and gently heating till the borax fluxes. IX. Oriental Garnet. Syn. Syrian Do. Ancient CarbuncU.—1. (M. Douault-Wieland.) Paste 512 grs.; glass of antimony :256 grs.; purple of cassius and oxide of manganese, of each 2 grs. —2. Paste 359 grs.; glass of antimony 178 grs.; oxide of manganese 2 grs.—3. (Vinegar Garnet.) Paste 2 lbs; glass antimony 1 lb.; calcined per- oxide of iron ^ oz. X. Opal.—1. (Fontanier.) Paste 1 oz.; horn silv*?< 10 grs. ; calcined magnetic ore 2 gre.; ab- sorbent earth (calcined bones) 26 grs.—2. Paste 10 lbs.; calcined bones J lb. XI. Ruby.—1. (M. Douault-Wiriand.Jk-a. Paste 2880 parts; oxide of manganese 72 parts.— b. Topaz-paste that has turned out opaque, 1 part; strass 8 parts; fuse for 30 hours, cool, and fuse small pieces before the blowpipe. Very fine.—2. Strass 16 oz.; precipitate of cassius, peroxide of iron, golden sulphuret of antimony, and manga- nese calcined with nitre, of each 168 grs.; rock crystal 2 oz., or more.—3. Paste 1 lb.; purple of cassius 3 drs.—4. Paste and glass of antimony, of each 8 oz.; purple of cassius 1 £ dr.; turns on the orange. XII. Sapphire. —1. (M. Douault-Wieland.) Paste 4608 grs.; oxide of cobalt 68 grs.; fuse in a luted Hessian crucible for 30 hours.—2. Paste 8 oz.; oxide of cobalt 49 grs.—3. To the last add a little manganese. XIII. Topaz. (Douault-WieTand.)—a. Paste 3456 grs.; calcined peroxide of iron 36 grs.—6. Paste 1008 grs.; glass of antimony 43 gra.; purple of cassius 1 gr. XIV. Turquois. Blue paste 10 lbs.; calcined bones £ lb. XV Yellow Diamond.—1. Strass 1 oz.; glass of antimony 10 gre.—2. Strass 1 oz.; chloride of silver 24 gre. Remarks. In the preparation of pastes the in- gredients should be separately reduced to the state of fine powder, then well mixed and sifted, and next carefully fused in a clean Hessian crucible, and cooled very slowly, after having been left in the fire for from 24 to 30 hours. The more tran- quil and continuous the fusion the greater is tho density and beauty of the product. For the finer kinds of mock diamonds, rock crystal should alone be employed ; and when sand is used, the purest white variety should be selected, and it should be first digested, and well washed with muriatic acid, and then with water, to remove any traces of earthy matter. The precise minutiss of the various processes can only be learned by a little experience. See Enamels. PASTILLES, FUMIGATING. Syn. Pas- tilli odorati. Prep. I. (Henry and Guibourt.) Powdered gum benzoin 16 parts; balsam of tolu and powdered sandal wood, of each 4 parts; a light charcoal (Linden) 48 parts; powdered traga- canth and true labdanum, of each 1 part; pow- dered nitre and gum arabic, of each 2 parts; cin- namon water 12 parts ; heat to a smooth ductile mass, form into small cones with a flat tripod base, and dry in the air. II. (P. Cod.) Benzoin §ij; balsam of tolu and yellow sandal wood, of each ^ss ? labdanum 3j; nitre 3ij ; charcoal §vj ; mix with a solution of gum tragacanth and divide into pastilles as above. III. (A la rose.) Gum benzoin, olibanum in tears, storax in tears, of each 12 oz.; nitre 9 oz.; charcoal 4 lbs.; powder of pale roses 1 lb.; essence of roses 1 oz.; mix with 2 oz. of gum tragacanth1 dissolved in rose-water 1 quart. IV. (.A la fleurs d'oranges.) For powdered roses in the last formula substitute pure orange powder, and for the essence of roses use pure neroli. V. (A la Vanille.) Gum benzoin, storax, and olibanum, (as last,) of each 12 oz.; nitre 10 oz.; cloves 8 oz.; powdered vanilla 1 lb.; charcoal 4 lbs.; oil of cloves £ oz.; essence of vanilla 7 or 8 oz. VI. Benzoin §ij ; cascarilla 3ij ; nitre 3iss; myrrh 3ss; oils of nutmeg and cloves, of each 15 drops ; charcoal §iij. Remarks. The above are all of excellent quality, and may be varied to please the fancy of the artist, by the addition or substitution of other perfumes or aromatics. Cheaper pastilles are made by the same formulae, by increasing the weight, of the charcoal and saltpetre. The whole of the ingre- dients should be reduced to fine powder before mixing them. Musk and civet, so often used in pastilles, should be avoided, as they yield a disa- greeable odor when burned. The addition of a little camphor renders them more suitable for a sick chamber. Pastilles are either burned to dif- fuse a pleasant odor, or to cover disagreeable smells. PASTILLES, EXPLOSIVE. Fumigating pastilles, containing a littlo gunpowder. Used to produce diversion. PATE DE DATTES. Syn. Paste of Dates. Prep. Dates 1 i lbs.; water 30 pints ; boil, clarify, add washed gum senega! 6 lbs., dissolve; add PAT 469 PEP white sugar 5 lbs.; evaporate without boiling to the consistence of thick honey, stir in orange-flower water 9 oz.; and again gently evaporate ; pour it into moulds, finish the drying by a gentle heat in a stove, and (hen divide it. Prod. 9£ lbs. Pec- toral. Pate de gomme Senegal is usually sold for it. PATE DE GUIMAUVE. Syn. Pasta Al- THiK^:- Marshmallow Paste. Prep. (P. Cod.) Decorticated marshmallow root (French) §iv; water £ gal.; macerate 12 hours, strain, add white sugar and gum arabic, of each 1 lb.; dissolve, strain, evaporate without boiling to the thickness of honey, constantly stirring, and add gradually the whites of 12 eggs, well beaten with orange- flower water, §iv, and strained ; continue the evap- oration and constant stirring till the mass is 60 firm as not to adhere to the fingers, then proceed as last. It should be very white, light, and spongy. The P. Codex of 1836 omits the marshmallow root, and calls the compound Pate de Gomme. The latter is usually sold in the shops for Pate de Guimauve. Both are pectoral. PATE DE GOMME ARABIQUE. Syn. Gum Arabic Paste. Prep. As the last. *#* Many persons use, however, twice the above quantity of gum and sugar, but this renders the product less whitdf PATE DE GOMME SENEGAL. Syn. Paste of Gum Senegal. Prep. As Pate de dattes, omit- ting the fruit. It is frequently acidulated with citric or tartaric acid, and flavored with essence of lemons. Pectoral. Sold in the shops for pate de dattes and pate de jujubes. PATE DE JUJUBES. Syn. Jujubes. Ju- jube Paste. Prep. (P. Cod.) Jujubes lb. j ; water lb. iv; boil £ hour, strain with expression, settle, decant the clear* and clarify with white of eggs; add a strained solution of gum arabic lb. vj, in water lb. viij, and to the mixture add white sugar lb. vj; gently evaporate, at first constantly stir- ring, and afterwards without stirring, till reduced to the consistence of a soft extract, add orange- flower water ^vj, and place the pan in a vessel of boiling water. In 12 hours carefully remove the scum, pour the matter into slightly oiled tin moulds, and proceed as before. Expectorant; in coughs, &c. Pate de gomme Senegal is usually sold for it. PATE DE REGLISSE BLANCHE. Syn. White Liquorice Paste. Pasta Glycyrrhiz.e Alba. Prep. As pate de guimauve, substituting liquorice root for marshmallow root. PATE DE REGLISSE NOIRE. Syn. Black Liquorice Paste. Liquorice Jujubes. Pasta Glycyrrhiz.* Nigra. Prep. (P. Cod.) Refined juice and white sugar, of each 1 lb.; gum arabic 2 lbs.; water 3 quarts ; dissolve, strain, evaporate considerably, add finely-powdered orris root £ oz., oil of aniseed or essence of cedrat a few drops, and pour into moulds as before. Pectoral. %* When made with \ the above weight of refined juice it forms brown liquorice paste, (pasta glycyrrhiza? fusca,) and by the addition of 15 grs. of extract of opium, the opiated liquorice paste (pasta glycyr- rhizas opiata) of the P. Codex. PATE DE TUSSILAGE A L'ANIS. Prep. Strong decoction of coltsfoot flowers 1 quart; Spanish juice £ lb.; dissolve, strain, evaporate as before, and towards the end add oil of aniseed J dr. Pectoral; in coughs, &c. PEARLS. ROSE. Syn. Rose Beads. Prep Beat the petals of red roses m an iron mortar for some hours, till they form a black paste, then roll into beads and dry. Hard ; take a fine polish ; very fragrant. PEAS, ISSUE. Syn. Pisa pro Fonticulis. Prep.—1. Orange berries, or the small unripe fruit of the orange tree, dried, and smoothed by a lathe. —2. Beeswax 1 lb.; turmeric 8 oz.; orris powder 4 oz.; Venice turpentine 3 oz.; mix, and form into peas. Used to keep issues open.—3. Beeswax 6 oz. ; verdigris, and powdered white hellebore, of each 2 oz.; cantharides 1 oz.; orris powder IJ oz.; Venice turpentine, q. s.; mix as last. Used to open issues. PECTIC ACID. (From writ, a coagulum, because of its jellying property.) A peculiar ge- latinous acid substance obtained from carrot roots, from which the juice has been pressed out, by boil- ing them with one-twenty-fifth part of their weighs of carbonate of potash, and 6 times their weight of water, till the liquid becomes gelatinous when neutralized with an acid. A pectate of potassa is formed, from which the acid may be obtained by exactly neutralizing the alkali with a stronger acid; it forms compounds with the bases called Pectates. PECTINE. Vegetable jelly, obtained by add- ing aJcohol to the juice of ripe currants or other fruit, till a gelatinous precipitate forms, which must be drained, washed with, a little weak alco- hol, and dried. PEPPER, BLACK. Syn. Piper Nigrum. This is the dried berries of a tree of the same name. The ground black pepper of the shops is universally adulterated. In fact, I am informed by a most extensive and respectable spice and tea house, that the public taste and judgment are so vitiated, that pure ground pepper is unsaleable. The parties alluded to, originally supplied their customers with unadulterated ground pepper, but in 3 cases out of every 4, it was returned and ob- jected to, on account of its dark color and pun- gency, which had induced the belief that it was sophisticated. The house alluded to, was there- fore compelled by its customers to supply them with an inferior, but milder and paler article. The substances employed to lower black pepper are known in the trade as P. D., H. P. D., and W. P. D. The first is the faded leaves of autumn, dried and powdered,—the second is the ground husks of black mustard obtained from the mustard mills, and the third is common rice finely powdered. The letters are the initials of pepper dust, hot do., and white do. I am assured that equal parts of black pepper corns, H. P. D., and W. P. D., form the very best ground pepper sold, and that the or- dinary pepper of the shops does not contain more than ith of genuine pepper, or 2 oz. in the pound. —Prepared black pepper is made by steeping the berries for 3 days in 3 times their weight of vine- gar, and then drying and grinding them. It ie mild-r than common pepper. PEPPER, CAYENNE. Syn. Red Pepper. Piper Cayenne. Prep.—l. Capsicums ground to powder.__2. Capsicum and dry salt, of each 1 lb.; grind to "tlier. *** The cayenne of the shops is PER 470 PER commonly a spurious article made by grinding a mixture of any of the reddish woods or sawdust, and enough capsicum to flavor.—Prepared Cay- enne pepper is the residuum of Cayenne vinegar, essence, or tincture, dried and ground. ^ PEPPER, CAYENNE, (SOLUBLE.) Syn. Crystallized Soluble Cayenne Pepper. Prep. 1. Essence of Cayenne 6 pints, (see page 274;) distil off 3 pints by the heat of a water bath ; add dry salt 12 lbs. to the residual liquor, mix well, dry by a gentle heat, color with a little vermilion or jeweller's rouge, and rub it through a sieve.— 2. Capsicums 3 lbs.; red sanders wood in shavings 1 lb. ; rectified spirits of wine 1 gallon ; macerate for 14 days, then express the tincture, filter, distil off one half, add dry salt 15 lbs., mix wed, gently evaporate to dryness, and pass it through a coarse sieve as before.—3. For red sanders in the last formula, use Brazil wood. The last two are very superior.—4. As the first form, but color with a strong decoction of saffron instead of vermilion. Very fine, but expensive. Gives a beautiful color to soups, &c. *** Tho spirit distilled off forms a most suitable menstruum for making essence of cayenne. PEPPER, KITCHEN. Prep. Ginger 1 lb.; cinnamon, black pepper, allspice, and nutmegs, of each 8 oz.; cloves 1 oz.; dry salt 6 lbs.; grind to- gether. Useful to flavor gravies, *&c. PEPSIN. Prep. (M. Vogel.) Digest the glan- dular skin of a hog's stomach, cut into pieces, in cold water for 24 hours, strain and repeat the maceration with fresh water, mix the liquors, pre- cipitate by acetate of lead, diffuse the precipitate through water, decompose by sulphureted hydro- gen, again filter, gently evaporate to a sirupy con- sistence, add absolute alcohol, collect the bulky precipitate that gradually forms, and carefully dry it by exposure to dry air. By the heat of a salt- water bath it forms a white powder, but in this state it loses some of its power of assisting diges- tion. A very small quantity of muriatic acid added to its weak aqueous solution, renders it ca- pable of artificial digestion. (Jour, de Pharm. et de Chim.) PERCHLORIC ETHER. Syn. Perchlo- rate of Oxide of Ethule. Prep. (Hare and Boye.) Triturate a mixture of sulphovinate and perchlorate of baryta, in equivalent proportions, place the powder in a retort connected with a re- frigerator and receiver surrounded with ice, and distil by the heat of an oil-bath, gradually raised to from 300° to 340°. *«* To prevent an ex- plosion, the ether should be received into a little absolute alcohol; about twice the weight of the sulphovinate employed. It is heavier than water, and explodes by heat, friction, and percussion, and often without any assignable cause. Its explosive power appears to be fully equal to that of the chlo- ride or iodide of azote; but this property is de- stroyed by solution in alcohol as above. The ad- dition of an equal volume of water to the latter so- lution immediately separates the ether, which sinks to the bottom of the mixed liquids. It has been suggested that this is the material used by Cap). Warner. Certain it is that an alcoholic so- lution of a sufficient quantity of this substance to blow up a line-of-battle ship, might safely be car- ried in the pocket, which is not the case with the chloride or iodide of azote ; and this might at any time be exploded by the addition of water, and the slightest friction or percussion, t+t Not more than 1 to 1 ij dr. of the sulphovinate should ever be distilled at a time, and even then the operator should be well protected with a mask and gloves. PERCOLATION. Syn. Metiiode de De- placement, (Fr.) Percolatio, (Lat, from per- colo, to filter.) A method of extracting the solu- ble portion of any substance, by passing the men- struum through it, previously reduced to powder, and packed into a cylinder or other suitable vessel. The " sparging" of the Scotch brewers is an ex- ample of this process on the large scale. In phar- macy, the " method of displacement" is frequently adopted for the preparation of tinctures, infusions, &c, and is in some respects superior to digestion or maceration. " The solid materials, usually in coarse, or moderately fine powder, are moistened with a sufficiency of the solvent to form a thick pulp. In twelve hours, or frequently without de- lay, the mass is put into a cylinder of glass, por- celain, or tinned iron, open at both ends, but ob- structed at the lower end by a piece of calico or linen, tied tightly over it as a filter ; and the pulp being packed by pressure, ranging as to degree with different articles, the remainder of the solvent is poured into the upper portion of the cylinder, and allowed gradually to percolate. In order to obtain the portion of the fluid which is absorbed by the residuum, an additional quantity of the solvent is poured into the cylinder, until the tincture which has passed through, equals in amount the spirit originally prescribed ; and the spirit employed for this purpose is then recovered for the most part, by pouring over the residuum as much water as there is spirit retained in it, which may be easily known by an obvious calculation in each case. The method of percolation is now preferred by all who have made sufficient trial of it to apply it correct- ly." (P. E.) A simple and useful form of perco- lator is represented in tho engraving. The meth- **» 1 [51 a. Percolator. b. Stand. Mi c. Receiver. Mu b d. Menstruum. Eg e. Substance operated on. H /. Calico strainer. rtfc fll o A s od of displacement has the advantage of expedi- tion, economy, and yielding products possessing uniformity of strength ; but it requires considerable experience to adapt it to all substances. The art rests in properly packing the ingredients in the cylinder, some substances requiring consideralle pressure to be used, while others, when even light- ly packed, scarcely permit the fluid to pass through them. An excellent plan, applicable to all substances, but especially those of a glutinous or mucilaginous nature, is to mix the powder with PHL 471 PHO an equal bulk of well-washed silicious sand, be- fore rubbing it up with the menstruum. The coarseness of the powder must also be attended to. Substances that readily become soft and pappy when wetted by the menstruum, should not be used so fine as those that are more woody and fibrous. The method of displacement answers well for the preparation of all tinctures that are not of a resinous nature, and for most infusions of woody and fibrous substances, as roots, woods, barks, leaves, seeds, insects, ,&c. It is especially adapted for the preparation of concentrated infu- sions and essences, as they may thus be obtained of any required strength, without loss, or requiring concentration by heat, which is so destructive to their virtues. PERIODIC ACID. A new acid, resembling perchloric acid, discovered by Ammermuller and Magnus. It is obtained by mixing pure soda with a solution of iodate of soda, saturating the solution with chlorine gas, collecting the pulverulent white salt that falls, either at once or after concentra- tion, dissolving in dilute nitric acid, and precipita- ting with nitrate of silver, when a periodate of sil- ver is formed, from which the acid may be obtained. Its salts are called periodates. PERRY. Syn. Pyraceum. A fermented li- quor, prepared from pears in the same way as cider is from apples. The red rough-tasted sorts are principally used for this purpose. The best perry contains about 9°r of absolute alcohol; ordi- nary perry from 5 to 7g. It is a very pleasant tasted liquor, especially when bottled a la cham- pagne. PERUVINE. A light, colorless, oily liquid, produced along with cinnamate of potash, by boil- ing cinnameine with alkalis. PEUCEDANINE. A white crystalline sub- stance, discovered by Schlatter in the root of peu- cedanum officinale. It is obtained by the action of alcohol. PEW'S CEMENT. Prep. Powdered quick- lime 1 part ; powdered baked clay 2 parts; mix, then add 1 part of freshly-baked and powdered gypsum to 2 parts of powdered baked clay, and after weil mixing, add them to the former pow- der, and thoroughly incorporate the two. Used to cover buildings. It is mixed up with water, and applied like mortar. It acquires great hard- ness, and is very durable. PEWTER. Prep. I. (Aiken.) Tin 100 parts; antimony 8 parts; copper 4 parts; bismuth 1 part ; fuse together. Very fine. II. (Plate pewter.) Tin 100 parts; antimony 8 parts; bismuth and copper, of each 2 parts. Very fine. Used to make plates, &c. III. (Trifle.) Tin 83 parts; antimony 17 parts; some lead is generally added. IV. (Ley) Tin 4 parts; lead 1 part Used for beer pots, &c. Remarks. According to the report of the French commission, pewter containing more than 18 parts of lead to 82 parts of tin, is unsafe for measures for wine and similar liquors. The legal sp. gr. of pew- ter in France is 7*764; if it be greater, it contains an excess of lead. PHLORIDZINE. Obtained by the action of boiling alcohol of 80$ on the fresh bark of the roots of the apple, pear, and plum tree. The alcohol is distilled off, and the phloridzine crystallizes out of the residual liquid. It forms white colorless nee- dles. It may also be obtained by cooling the aqueous decoction of the above barks, but it has then a red color. It is said to be a more powerful febrifuge than quinine (M. Lebandy.) When its solution is boiled with a little dilute sulphuric or muriatic acid, it is converted into grape sugar and phloretine. PHOCENIC ACID. An oily arid, prepared from whale oil, in the same way as the volatile acids from butter. It dissolves in 18 parts of wa- ter. Its salts are called phocenates. • PHOSPHATE OF LIME, (PRECIPITA- TED.) Syn. Calcis Phosphas precipitatum. Prep. (P. D.) Bones calcined to whiteness and reduced to powder, 1 part; diluted muriatic acid, and water, of each 2 parts; digest for 12 hours, filter, and precipitate by liquor of ammonia; well wash the precipitate, and dry it. A white, taste- less, odorless powder. Dose 10 to 30 grs., in rickets, either alone, or joined with sesquioxide of iron. It is preferable to calcined bones or harts- horn, from being more soluble. PHOSPHATIC ACID. Obtained by the slow oxidation or combustion of cylinders of phosphorus wHten exposed to the air. According to Davy it is a mixture of phosphoric and phosphorous acids. PHOSPHO-MESITYLIC ACID Glacial phosphoric acid dissolved in acetone It forms PHOSPHORIC ACID. Syn. Acidum Phos- phoricum. Prep. Bones calcined to whiteness 3 lbs.; oil of vitriol 2 lbs., diluted with 3 times its weight of water ; mix, and digest with heat for 2 or 3 days, adding water to supply the loss by evapo- ration ; then add a large quantity of water, mix well, and strain ; wash the residual matter with hot water, mix the liquors, add ammonia in slight excess, filter, evaporate, and ignite the dry mass in a platinum crucible. Remarks. Phosphoric acid properly exists only in solution, for by the heat applied as above, it is converted into metaphosphoric acid, but by solu- tion in water and ebullition for a few minutes, it is reconverted into phosphoric acid. In the dry or glacial state it is a colorless, glassy-looking sub- stance, soluble in water, yielding a solution which exhibits strong acid properties. It is remarkable for its proneness to form subsalts with the alkalis and earths, in which 1 atom of arid is united with 3 at. of base. Its salts are called phosphates. Phosphoric acid, when neutralized with an alkali, is characterized by giving with the soluble salts of lead, lime, and baryta, white precipitates soluble in nitric acid, and with solution of nitrate of silver a yellow precipitate. It is distinguished from ar- senious acid by not being affected by sulphureted hydrogen. The insoluble phosphates may be tested by first treating them with sulphuric acid, filter- ing, and neutralizing the solution with an alkali before applying the reagents. If a soluble phos- phate be heated to redness, it is converted into a pyrophosphate, and will then give a white precipi- tate with nitrate of silver. PHOSPHORIC ACID, (DILUTE.) Syn. Acidum Phosphoricum dilutum. Prep. (P. L.) Nitric acid f§iv ; water ffx ; mix, add phosphorus ^j, place the retort in a sand-bath, and apply heat PHO 472 PIC till ffviij are distilled, which are to be rejected. Evaporate the remaining liquid in a platinum cru- cible to ^ij 3vj ; cool, and add as much distilled water as will make the whole quantity measure f §xxviij. Remarks. This is a colorless, sour liquid, hav- ing the sp. gr. 1*064. By heat it yields glacial phosphoric acid. Dose. 10 drops to 3j; largely diluted with wa- ter, in phosphatic urinary deposites, ossification of the arteries, caries, &c. PHOSPHOROUS ACID. Syn. Acidum Phosphorosum. Prep. Sublime phosphorus through powdered bichloride of mercury, contained in a glass tube. Chloride of phosphorus comes over, which, on being mixed with water and evaporated to a sirup, forms a crystalline mass of hydrated phosphorous acid on cooling. It is a powerful de- oxydizing agent. With the bases it forms salts called phosphites. PHOSPHORUS. (From 0<3j, light, and $ipv>, I carry, because of its iuminous appearance in the dark.) An elementary inflammable substance, discovered by Brandt in 1669. Prep. (Ure.) Ground bone-ash 1 cwt.; water 2 cwt.; mix to a pap in a large tub, and add in a slender stream (still stirring) oil of vitriol 78 lbs.; work well together, adding more water if required ; in 24 hours thin with water, agitate well, and if convenient heat the mixture in a leaden pan, and as soon as the paste has lost its granular character, transfer it into a series of tall casks ; largely dilute with water, and after settling, decant the clear portion ; wash the residue well with water, mix the clear liquids, and evaporate in a copper or lead pan, till the calcareous deposite becomes considera- ble, then cool, decant the clear, and drain the sedi- ment on a filter; evaporate the clear liquid to the consistence of honey, add 9 lbs. of powdered char- coal, and evaporate to dryness in an iron pot, or till the bottom of the latter becomes red hot; the dry mixture, when cold, is put into earthen retorts well covered with luting and properly dried, and heat is applied sideways rather than at the bottom, by means of an air furnace. The beak of the re- tort is connected with a copper tube, the other end of which is made to dip about \ of an inch beneath the surface of lukewarm water placed in a trough or wide-mouthed bottle. The distilled product is purified by squeezing it through chamois leather under warm water, and is then moulded for sale by melting it under water, plunging the wider end of a slightly tapering but straight glass tube into the water, sucking this up to the top of the glass, so as to wa-ra and wet it, next immersing the end into the .njjid phosphorus, and sucking it up to any desired height. The bottom of the tube being now closed with the finger, it is withdrawn, and» transferred to a pan of cold water to congeal the phosphorus, which will then commonly fall out, or may be easily expelled by pressure with a piece of wire. (See Ure's Diet of Arts, &c.) Remarks. Phosphorus is a pale yellow, semi- transparent, and highly combustible solid ; sp. gr. 1*77; melts at 108° ; and unites with oxygen, forming acids, and with the metals, forming phos- phurets. It is soluble in ether, naphtha, and the oils. From its great inflammability it can only be safely kept under water. In commerce it is always packed in tin cylinders, soldered air-tight. It is a powerful corrosive poison ; but small doses of its ethereal or oily solution have been administered in some complaints. *„* Baldwin's Phosphorus is ignited muriate of lime,—Canton do., oyster shells calcined with sulphur,—Bologna do., calcined sul- phate of baryta,—Homberg's do., ignited chloride of calcium. All these phosphoresce in the dark, after exposure to the solar rays. PHOSPHORUS BOTTLES. Syn. Briquets Phospiioriques. Prep. Phosphorus 1 dr.; white wax 15 or 20 grs.; cautiously melt together in a vial, by the heat of warm water, and as it begins to cool turn the bottle round, so that the mixture may adhere to the sides. Used as instantaneous light bottles. A sulphur match rubbed against the phosphorus and Withdrawn into the air, imme- diately inflames. *** The vial should only be unstoppered at the instant of introducing the match, and should be handled with caution. PHOSPHORUS, BROMIDE OF. When bromine and phosphorus are brought into contact in a vessel filled with carbonic acid gas, they unite with the evolution of light and heat, forming a crystalline yellow perbromide, which sublimes and condenses in the upper part of the flask, and a liquid protobromide, which, remains at the bottom. PHOSPHORUS, CHLORIDES OF—1 (Perchloride.) A volatile white substance, obtain- ed by the spontaneous combustion of phosphorus in chlorine.—2. (Sesquichloride) A limpid fluid, a little heavier than water, obtained by passing the vapor of phosphorus through corrosive sublimate contained in a glass tube. PHOSPHORUS, IODIDES OF.—1. (Pro- tiodide.) Obtained by mixing 1 part of phospho- rus with 7 or 8 of iodine in a close vessel. Orange colored.—2. (Sesquiodide) As last, from 1 part of phosphorus and IS? of iodine. A dark gray crys- talline mass.—3. (Periodide.) Phosphorus 1 part; iodine 20 parts ; as last. Black. PHOSPHURETED HYDROGEN. Prep. —1. Fill a small tubulated retort with water acidu- lated with muriatic acid, throw in some small lumps of phosphuret of lime, and receive the evolved gas in an inverted jar over water. ^ oz. of phosphuret of lime yields 70 cubic inches of gas.—2. Boil phosphorus in a solution of potassa, or in milk of lime. *** Phosphureted hydrogen is a colorlesj gas, spontaneously inflaming by contact with air. It has a remarkably fetid odor. PICAMAR. A bitter oil discovered in tar by Reichenbach. (See Creosote.) PICCALILLY. Syn. Indian Pickle. Prep. White cabbages sliced, cauliflowers pulled to pieces and scalded, radishes topped and tailed, French beans, celery in three-inch lengths, shoots of elder peeled, clusters of elder-flowers unopened, all salted for 2 or 3 days, then mixed with apples and cu- cumbers sliced, and a large proportion of ginger, garlic, turmeric, long pepper, and mustard 6ecd, as the pickle is expected to be very warm ; the vine- gar must also be the strongest that can be pro- cured, and just sufficient to float the articles ; any other vegetables may be used at pleasure. PICKLE, LEMON. Prep. I. Lemon juice and vinegar, of each 3 gallons ; bruised ginger 1 lb.; allspice, pepper, and grated lemon peel, of each 8 oz.; salt 3£ lbs.; cayenne 2 oz.; mace and | nutmegs, of each 1 oz.; digest PIC 473 PIL II. Lemons sliced, 1 dozen; salt 2 lbs.; garlic 12 cloves ; scraped horseradish, and flour of mus- tard, of each 4 oz.; cloves, mace, nutmegs, and cayenne pepper, of each £ oz.; vinegar 1 gallon ; as before. Used as a sauce. PICKLE, MEAT. Prep. Moist sugar 2 lbs.; bay or common salt 4 lbs.; saltpetre £ lb.; fresh ground allspice 2 oz.; water 6 to 8 quarts; dis- solve. Used to pickle meat, to which it imparts a fine red color, and a superior flavor. PICKLES. In the preparation of pickles, it is highly necessary to avoid employing metallic ves- sels ; as both vinegar and salt corrode brass, cop- per, lead, &,c., and thus become poisonous. When it is necessary to heat or boil vinegar, it should be done by placing it in a stoneware jar in a water- bath, or on a stove. Glazed earthenware should be avoided either for making or keeping the pickles in, as the glazing usually contains lead. Pickles should be kept from the air as much as possible, and only touched with wooden spoons. They are also better preserved in small jars, or bottles, than large ones, as the more frequent opening of the latter exposes them too much. Copper or verdi- gris is frequently added to pickles to impart a green color, but this poisonous addition may be readily detected. If a green color be desired, it may be imparted by steeping vine leaves, or the leaves of parsley or spinage in the vinegar. A teaspoonful of olive oil is frequently added to each bottle to keep the pickles white. The following is an ex- ample of pickling:— PICKLED GHERKINS. Steep them in strong brine for a week, then pour it off, heat it to the boiling point, and again pour it on the gherkins ; in 24 hours drain the fruit on a sieve, put it into wide-mouthed bottles or jars, fill them up with Btrong pickling vinegar, boiling hot, bung down im- mediately, and tie over with bladder. When cold, dip the corks into melted bottle wax. Spice is usually added to the bottles, or else steeped in the vinegar. *^* In a similar way are pickled, onions, mush- rooms, cucumbers, walnuts, samphires, green gooseberries, cauliflowers, melons, barberries, peaches, lemons, tomatoes, beans, radish pods, codlins, red cabbage, (without salt, and with cold vinegar,) beet-root, (without salting,) garlic, peas, &c, &c, observing that the softer and more deli- cate articles do not require so fong soaking in brine as the harder and coarser kinds, and may be often advantageously pickled by simply pouring very strong pickling vinegar over them, without applying heat. PICROLICHENINE. A bitter, crystallizable substance, found by Alms in the lichen variolaria amara. It is extracted by alcohol, and purified by washing with a weak solution of carbonate of pot- ash. It is said to be a powerful febrifuge. PIC ROM EL. A name given by Thenard to a black bitter substance obtained from fresh bile, by adding sulphuric acid diluted with 5 parts of water, applying a gentle heat, and after repose, decanting the clear, edulcorating the sediment (resin of bile) with water, digesting with carbonate of baryta, and evaporating. PICROTOXINE. Syn. Picrotoxia. Picro- Toxic Acid. A bitter, crystallizable, and poisonous substance, discovered by Boullay in cocculus indi- 60 cus. It is soluble in boiling water, alcohol, ether, and acetic acid. It may be obtained by precipita- ting the decoction of cocculus indicus by acetate of lead, evaporating to dryness, and frequently redis- solving in alcohol of 0-817. PILES. Syn. H.emorrhoides. A painful dis- ease occasioned by the morbid dilatations of the veins at the lower part of the rectum, and sur- rounding the anus. Piles are principally occasion- ed by costiveness and cold. They have been dis- tinguished into—blind piles, or a varicose state of the veins without bleeding,—mucous piles, when the tumors are excoriated, and mucus or pus is discharged,—bleeding piles, when accompanied with loss of blood,—excrescential piles, when there are loose, fleshy excrescences about the verge of the anus and within the rectum. The treatment consists in the administration of mild aperients, as castor oil, or an electuary of sulphur and cream of tartar; when there is much inflammation or bleeding, cold and astringent lotions, as those of sulphate of zinc or alum, should be applied, and when the pain is considerable, fomentations of de- coction of poppy heads may be used with advan- tage. To arrest the bleeding, ice is also frequently applied, but continued pressure is more certain. When the tumors are large and flaccid, the com- pound ointment of galls is an excellent application, and if there is a tendency to inflammation, a little liquor of diacetate of lead may be added. In con- firmed piles, the internal use of copaiba, or still better, of the confection of black pepper, should be persevered in, together with local applications. In severe cases, the protrudea tumors are removed by surgeons, by the knife or ligature. PILLS. Syn. Pilule, (Lat) Pills are too well known to require description. This form of medicine is particularly adapted to the exhibition of nauseous substances, and such as operate in small doses. Extracts may be made into pills either alone or with the addition of any simple powder, as that of liquorice, to increase their con- sistence. Powders are usually beaten up with sirup, treacle, mucilage, conserve of roses, or ex- tract of liquorice. Castile soap is frequently used for substances that are not decomposed by alkalis. When the mixed ingredients are made into a mass, it should be preserved in a bladder placed in a covered stone pot, and should be occa- sionally moistened with a little spirit, or spirit and water, to prevent it getting hard. In all cases, the dry ingredients should be reduced to fine pow- der, and the whole beaten into a uniform mass of a proper consistence for rolling into pills. *#* Pills are gilded and silvered by rolling them between the fingers slightly moistened with mucilage, and then shaking them up in a small gallipot covered with a piece of paper, along with a little gold or silver leaf, or a little powdered gold or silver. In ordinary cases, rolling the pills in carbonate of magnesia, or powdered starch, is usually adopted to prevent them sticking together while moist. As pill masses are liable to get hard and brittle by keeping, an excellent plan is to keep the dry ingre- dients powdered and mixed together in well-corked bottles or jars, when a portion may at any time be beaten up vith sirup, conserve, soap, &c, accord- ing- to the formula, and as wanted for use. PILLS, ACETATE OF LEAD. Syn. Pilu- PIL 474 PIL j.x plumbi opiate. Prep. (P. E.) Acetate of lead 6 parts ; opium and conserve of red roses, of each 1 part; mix, and divide into 4-gr. pills. In spitting of blood, obstinate diarrhoea, dysentery, &c. Dose. 1 to 3 pills two or three times a day, washed down with water soured with vinegar. PILLS, ALOES. Syn. Pilule Aloes. Prep. (P. Ev Powdered Socotrine aloes and Castile soap, equal parts; conserve of red roses q. s. to make a mass. PILLS, ALOES, (COMPOUND.) Syn. Pil. Aloes composite. Prep. (P. L. and D.) Pow- dered Socotrine aloes (hepatic, P. D.) §j; extract of gentian § ss ; oil of caraway 40 drops ; sirup (if required) q. s.; beat to a mass. Dose. 5 to 10 grs., as a purgative in habitual costiveness. PILLS, ALOES AND ASAFCETIDA. Syn. Pil. Aloes et Asafcetida. Prep. (P. E.) Pow- dered aloes, asafcetida, and Castile soap, equal parts ; conserve of red roses q. s.; beat into a mass. Dose. 5 to 10 grs., as a purgative in dyspepsia, flatulence, &c. PILLS, ALOES AND IRON. Syn. Pil. Aloes et Ferri. Prep. (P. E.) Sulphate of iron 3 parts ; Barbadoes aloes 2 parts ; aromatic pow- der 6 parts: conserve of red roses 8 parts; mix, and divide into 5-gr. pills. Emmenagogue. Dose. 1 to 3 pills in chlorosis and atonic amenorrhcea. PILLS, ALOES AND MYRRH. Syn. Pil. Aloes et Myrrha, (P. E.) Pil. Aloes cum Myrrha, (P. L. and D.) Pil. Rufi. Rufus's Pills. Pil. communes. Common Pills. Prep. —1. (P. L.) Aloes §ij ; saffron and myrrh, of each ^j; sirup to mix.—2. (P. E.) Socotrine or East Indian aloes 4 parts ; myrrh 2 parts ; saffron 1 part; conserve of red roses q. s. A most excel- lent stomachic, purgative, and emmenagogue, where there are no febrile symptoms. Dose. 10 to 20 grs. PILLS, ALOES AND ROSE JUICE. Syn. Pil. Aloes Rosata. Pilules angeliques. Grains de Sante. Prep. Aloes and rose juice, of each ^iv; juices of borage and chicory, of each ^'j j dissolve, evaporate to an extract, add rhubarb 3ij ; agaric 3j ; and divide into 1^-gr. pills. Dose. 4 to 12, as a pur^e. PILLS, AMMONIATED COPPER Syn. Pil. cupri ammoniati. Prep. (P. E.) Ammonio- sulphate of copper 1 ^wt; bread-crumb 6 parts ; solution of carbonate ot ammonia q. s. to make a pill mass; divide so that each pill may contain ^ gr. of ammoniated copper. Dose. 1 pill night and morning, gradually increased to 5 or 6, in epilepsy, and some other spasmodic diseases. PILLS, ANTIBILIOUS. See the various pur- gative and stomachic Pills. PILLS, ANTI-EPILEPTIC. Prep. 1.—(Re- cambier.) Aqueous extract of opium 5 centigram- mes ; acetate of lead 20 do.; powdered henbane 40 do.; gum sirup q. s.; mix, and divide into 8 pills. Dose. 1 night and morning.—2. (Leuret) Extracts of stramonium and belladonna, of each 1 gramme ; camphor and opium, of each 50 cen- tigr.; divide into pills of 10 decigr. Dose. 1 a day, gradually and cautiously increased to 10 or 12, or more. PILLS, ANTISPASMODIC. Prep. (Thom- son.) Opium 1 gr.; castor 13 grs.; powdered di- gitalis 2 grs.; sirup to mix ; divide into 4 pills. Dose. 1 or 2 two or three times a day in spasmod- ic asthma, &c. PILLS, ASAFCETIDA. Syv. Pil. apafck- tida. Prep. (P. E.) Asafcetida, galbanum, and myrrh, of each 3 parts; conserve of red roses 4 parts, or q. s.; beat into a mass. Stimulant and antispasmodic. Dose. 10 to 20 grs., in hysteria, PILLS, ASTRINGENT. Prep. 1. (Collier.) Nitrate of silver 3 gre.; extract of opium 3ss; musk 9j; camphor 3ij; mix for 48 pills. Dose. 1 pill 2 or 3 times a day, as a stimulant tonic ; in epilepsy, &c.—2. (Cavarra.) Pure tannin 6 grs.; powdered gum 12 grs.; sugar 3j; sirup to mix; divide into 4-gr. pills. Dose. 1 to 3 in diarrhoea.— 3. Acetate of lead 3 grs.; opium 1 gr.; divide into 3 pills. Dose. 1 twice a day, followed by a glass of water acidulated with vinegar; in colliquative diarrhcea, chronic dysentery, phthisical night- sweats, internal hemorrhages, &,c. PILLS, CALOMEL AND OPIUM. Syn. Pil. calomelanos et opii. Prep. (P. E.) Calomel 3 parts; opium 1 part; conserve of red roses to mix. Divide so that each pill may contain 2 grs. of calomel. Dose. 1 or 2 in rheumatism, and «otn9 inflammatory affections; if continued, they induce salivation. PILLS, CALOMEL, (COMPOUND.) Syn. Pllmmer's Pills. Red Pill. Pil. hydrargyri Chloridi comp., (P. L.) Pil. Calomelanos comp., (P. E. & D.) Pil. hydrargyri submuriatis, (P. L. 1809.) Pil. Plummeri. Prep. (P. L.) Calo- mel, oxysulphuret of antimony, and treacle, of each 3ij ; powdered guaiacum resin 3ss; mix. An excellent alterative pill in chronic skin diseases and liver affections ; in dyspepsia, syphilis, &c. Dose. 5 to 10 gre. PILLS, CATHARTIC. Prep. 1. (Thomson.) —a. Scammony 4 grs. ; extract of taraxacum 16 grs.; divide into 6 pills. Dose. 3 twice a day, in hypochondriasis, and chronic inflammation of the liver.—b. Calomel 3 grs.; powdered jalap 9 gre.; mucilage to mix ; for 3 pills. Dose. 2 or 3 at night to empty the bowels, in bilious affections. —2. (Collier.) Calomel 10 gre.; powdered jalap and rosepink, of each 3iv; oil of caraway 10 drops; sirup of buckthorn to mix ; divide into 5-gr. pills. Dose. 1 to 3, as a purgative.—3. Compound ex- tract of colocynth 3j; powdered opium 3 grs.; pow- dered scammony 15 grs.; oil of nutmeg 8 drops; divide into 18 pills. Dose. 2 to 4, as a purge.—4. Socotrine aloes 3j ; rhubarb 0ij ; scammony 3ss; capsicum 10 grs ; oil of cloves 10 drops ; mix, and divide into 48 pills. Dose. 2 to 4 at bedtime. PILLS, CATHARTIC, (COMPOUND.) Syn. Pil. cathartica composita. Prep. (P. U. S.) Compound extract of colocynth ^ss ; powdered ex- tract of jalap and calomel, of each 3iij ; powdered gamboge 3ij ; mix, and divide into 180 pills. An excellent purgative pill, especially in bilious affec- tions. Dose. 1 to 3 pills. PILLS, COLOCYNTH. Syn. Pil. colocyn- thidis, (P. E. & D.) Pil. cochia. Pil. coccia. Pil. cochia minores. Prep. (P. E.) Socotrine or East Indian aloes and scammony, of each 8 parts ; colocynth 4 parts ; sulphate of potash and oil of cloves, of each 1 part; rectified spirit (mu- cilage, P. D.) q. s. to form a mass ; divide into 5-gr pills. An excellent purgative pill. Dose. 5 to U PIL 475 PIL grs. 4 grs. of this pill, combined with 2 or 3 grs. of mercurial pill, and taken over night, is an ex- cellent remedy in bilious attacks. *** The pil. cochiae of Apothecaries' Hall is the above pill, without the sulphate of potash, and beaten up with sirup or treacle, instead of mucilage. The com- mon pil. cochise of the shops is generally made as follows:—Powdered aloes 1£ lb.; do. colocynth £ lb.; do. jalap 6 oz.; oil of cloves 1^ oz.; sirup- or treacle to mix. Prod. About 4| lbs. The more conscientious sometimes add to the above scam- mony 6 oz. PILLS, COLOCYNTH AND HENBANE. Syn. Pil. colocynthidis et hyoscyami. Prep. (P. E.) Compound colocynth pill mass 3ij ; ex- tract of henbane 3j ; mix, and divide into 36 pills. Dose. 5 to 15 grs., as an anodyne purgative. PILLS, COPAIBA. Syn. Pil. copaiba cum Magnesia. Prep. (Mialhe.) Pure balsam of co- paiba §j; calcined magnesia 3ss ; mix, and stir for some days till sufficiently thick. For present use copaiba requires its own weight of magnesia ; Dr. Pereira orders copaiba Jj; magnesia 3vj or 3vij. Dose. 10 to 30 grs., frequently in diseases of the mucous membranes of the urinary organs. PILLS, DIAPHORETIC. Prep. 1. Anti- monial powder 3ss ; opium 3ss ; calomel 5 grs.; confection of opium to mix ; divide into 10 pills. Dose. 1 at bedtime.—2. Guaiacum 10 grs.; emet- ic tartar and opium, of each 1 gr.; simple sirup to mix; divide into 3 pills. Dose. 1 or 2.—3. Camphor and antimonial powder, of each 3ss ; opium 10 grs.; aromatic confection q. s. to mix ; divide into 12 pills. Dose. 1 pill.—4. Powdered guaiacum 10 grs.; compound powder of ipecacu- anha 5 grs.; confection of roses to mix; for dose. All the above are taken as diaphoretics in inflammatory affections. PILLS, DINNER. Prep. 1. (Lady Cres- pigny's Pills. Lady Webster's Pills. Grains de vie. Grains de mesne. Stomachic Pills. Pil. Aloes cum mastiche) Aloes 3vj ; mastich and red roses, of each 3ij ; sirup of wormwood to mix ; divide into 3-gr. pills. They produce a bulky and copious evacuation.—2. Substitute rhubarb for the roses in the last.—3. (Pil. stomachica mesues. Pil. dicta antecibum, P. Cod.) Aloes 3vj; extract of bark 3iij ; cinnamon 3j ; sirup of wormwood to mix. Dose. Of either of the above 5 grs., 1 hour before dinner, to promote the appetite ; as a purge, 10 to 15 grs. PILLS, DIURETIC. Prep. (Thomson.)—a. Powdered digitalis 12 grs.; calomel and opium, of each 4 grs.; confection of roses q. s. for 12 pills.— b. Mercurial pill 3j ; powdered squills 3j ; confec- tion of roses q. s. for 20 pills. Dose. 1 of either of the above twice a day in dropsy. PILLS, DIXON'S ANTIBILIOUS. Prep. Aloes, scammony, rhubarb, and a little tartar emetic, beat up with sirup. PILLS, EXPECTORANT. Prep.—l. Myrrh 3iss; powdered squills 3ss; extract of henbane 3ij; sirup q. s.; divide into 30 pills. Dose. 2 night and morning__2. (Thomson.) Powdered squills and extract of hemlock, of each 3ss; ammoniacum 3iss; divide into 30 pills. Dose. 2 twice a day. In chronic coughs, asthma, &c. PILLS, FAMILY. Syn. Aloe Pills. An- TlBUiious do. Aloe Rosata. Prep. Socotrine or hepatic aloes 4 oz.; juice of roses 1 pint; dis- solve by heat, strain through a piece of coarse flannel, evaporate, and form into pills. Purgative, in doses of 5 to 15 grs. PILLS, FOTHERGILL'S. Aloes, scammo- ny, colocynth, and diaphoretic antimony. PILLS, FOXGLOVE AND SQUILLS. Syn. Pil. Digitalis et Scilla. Prep. (P. E.) Pow- dered foxglove and squills, of each 1 part; aro- matic electuary (P. E.) 2 parts ; conserve of red roses q. s.; divide into 4-gr. pills. A valuable diuretic in dropsies. Dose. 1 to 2 pills. PILLS, FULLER'S. Prep. Aloes 3ss; sen- na and myrrh, of each 3j; asafcetida and galba- num, of each 10 grs.; saffron and mace, of each 5 grs.; sulphate of iron 3'ij; sirup q. s. Dose. 5 to 20 grs.; as an antispasmodic and aperient. PILLS, GALBANUM, (COMPOUND.) Syn. Pil. Gummosa. Pil. Galbani comp., (P. L. & D.) Prep. (P. L.) Galbanum §j; myrrh and sagape- num, of each §iss ; asafcetida §ss ; sirup (treacle, P. D.) q. s.; beat to a mass. Stimulant and an- tispasmodic. Dose. 10 to 20 grs.; in hysteria, amenorrhcea, &c. PILLS, GAMBOGE. Syn. Pil. Cambogia, (P. E.) Pil. Cambogia comp. (P. L. & D.) For- dyce's Pills. Prep. (P. L.) Gamboge 3j ; aloes 3iss ; ginger 3ss; Castile soap 3ij ; beat to a mass. An active cathartic. Dose. 10 to 15 grs. in ob- stinate constipation. PILLS, HEMLOCK, (COMPOUND.) Syn. Pil. Conii comp. Prep. (P. L.) Extract of hem- lock 3v ; ipecacuanha 3j; mix. Antispasmodic, expectorant, and narcotic. Dose. 5 to 10 grs. twice or thrice a day, in spasmodic coughs, bron- chitis, incipient consumption, &c. PILLS, HOFFMAN'S, (MAJOR.) Syn. Pil. Hydrargyri Bichloridi. Pil. Hoffmanii Majores. Prep. (Paris.) Corrosive sublimate and muriate of ammonia, of each 5 grs.; water f 3ss ; triturate till dissolved, add honey 3ss, liquor- ice powder 9yj; mix, and divide into 40 pills. Each pill contains J gr. of corrosive sublimate. PILLS, HOOPER'S. Prep. Sulphate of iron, and water, of each 8 oz.; dissolve, add Barbadoes aloes 21 lbs.; white canella 6 oz.; myrrh 2 oz.; opopanax $ oz.; make a mass ; divide each drachm into 18 pills, and put 40 into each box. PILLS, HYDRAGOGUE. Syn. Bontius' Pills. Pil. Hydragoga. Prep. (P. Cod.) Aloes, gamboge, and ammoniacum, of each f j ; vinegar 3jyj ; dissolve, strain, evaporate, and divide into 4 gr. pills. Strongly cathartic. Used in dropsy. PILLS, IODIDE OF MERCURY. Syn. Pil. Hydrargyri Iodidi. Prep. Protiodide of mercury, and ginger, of each 3j ; confection of hips 3iij; mix. Dose. 5 to 15 grs., in scrofula, PILLS, IPECACUANHA, (COMPOUND.) .Syn. Pil. Ipecacuanha comp., (P. L.) Pil. Ipe- cac et Opii, (P. E.) Prep. (P. L.) Compound powder of ipecacuanha 3iij ; powdered squills and ammoniacum, of each 3j; mucilage q. s. to mix. Narcotic, sudorific, and expectorant. Dose. 5 to 15 grs., in chronic c°uKh!\^m* , „ PILLS, JAMES'S ANALEPTIC. Prep. Antimonial powder, guaiacum, and pills of aloes and myrrh, equal parts ; sirup q. s.; mix, and di vide into 4-gr. pills. A diaphoretic purgative. PIL 476 PIL PILLS, IRON, (COMPOUND.) Syn. Fe- male Pills. Pil. Ferri comp., (P. L.) Pil. Ferri Carbonatis, (P. E.) Pil Ferri cum Myrrha, Prep.—1. (P. L.) Myrrh 3ij; carbon- ate of soda 3j; triturate, add sulphate of iron 3j; again triturate, then add treacle 3j ; and beat to- gether in a warm mortar.—2. (P. E.) Saccharine carbonate of iron 4 parts ; conserve of red roses 1 part; mix, and divide into 5-gr. pills. Both the above are mild chalybeate tonics. Dose. 10 to 20 gre. PILLS, IRON, (SULPHATE.) Syn. Pil Ferri Sulphatis. Prep. (P. E.) Dried sulphate of iron 2 parts ; extract of dandelion 5 parts ; con- serve of red roses 2 parts; liquorice powder 3 parts ; mix, and divide into 5-gr. pills. Tonic. Dose. 1 to 3 pills. PILLS, KEYSER'S. Prep. Acetate of mer- cury 12 grs. ; manna 3iss ; starch 6 grs. ; mucil- age of gum tragacanth to mix; divide into 6-gr. pills. Alterative. Dose. 2 night and morning, gradually increased, in syphilis, &c. PILLS, KITCHENER'S. Syn. Pil. Rhei et Carui. Kitchener's Peristaltic Persuaders. Prep. Turkey rhubarb 3ij ; sirup 3j ; oil of cara- way 10 drops : mix, and divide into 40 pills. Sto- machic, aperient. Dose. 3 to 6. PILLS, LOCKYER'S. Prep. Panacea of antimony 10 grs. ; white sugar Jj > mucilage to mix ; divide into 100 pills. Cathartic and emetic. Dose. 1 to 3 pills. PILLS, MERCURIAL. I. (Blue Pill. Pil. Carulea. Pil. Hydrargyri, P. L. E. and D. Pil. Mercuriales, P. L. 1745.) Prep. (P. L.) Mer- cury 3ij ; confection of red roses 3iij ; triturate till the globules are perfectly extinguished, then add liquorice powder, 3j, and beat into a pill mass. The Edinburgh and Dublin forms are similar ; the formf orders it to be divided into 5-gr. pills. *#* This pill, if well prepared, presents no globules of mercury when moderately rubbed on a piece of white paper, but immediately communicates a white stain to gold. It should possess considerable density, and have a dark blue or slate color. It should contain $ mercury, which may be ascer- tained from its sp. gr., or more exactly by an assay for the metal. (See Sevum.) Dose. As an altera- tive, 1 to 3 grs., combined with opium ; as a pur- gative, 5 to 15 grs. A blue-pill over night, and a black draught in the morning, is a popular remedy in bilious complaints. (See Abernethy Medi- cine.) II. (Collier.) Mercury and sesquioxide of iron, of each 3j ; confection of red roses 3iij ; triturate as before. This has been proposed as an excellent substitute for the common mercurial pill. The addition of only a few grs. of the above oxide of iron to 1 oz. of conserve, renders it capable of rap- idly killing a large quantity of mercury. III. (Tyson.) Blue oxide of mercury (prepared by decomposing calomel with liquor of potassa, to which a little liquor of ammonia has been added) 3ij; confection of roses 3vj; powdered chamomiles 3j; mix. Also proposed as a substitute for the College pill. (Pharm. Jour.) IV. Stearine 3j; rub in a warm mortar till it assumes the consistence of thick cream, then add mercury 3iv ; rub till " killed," and further add confection of roses and wheat flour, of each 3iij; powdered gum 3j. (Pharm. Jour.) Another pro. posed substitute for the College pill. V. (Pil- Hydrargyrosa, P. Cod.) Mercury and honey, of each 3vj ; triturate till the globules are extinguished, then add aloes 3vj ; rhubarb 3iij ; scammony 3ij ; black pepper 3j ; make a pill mass. Contains -J mercury. Alterative and aperient Dose. 5 to 10 grains. Belloste's, Barberousse's, and Morelot's pills, and the Pil. Hydrargyri laxantes, (P. E. 1744,) and the Pil. Mercuriales, (P. L 1746,) are similar. PILLS, MORRISON'S. Prep.—l. (Morri- son's Pills, No. 1.) Aloes and cream of tartar, equal parts ; mucilage q. s. to form a pill mass.— 2. (Morrison's Pills, No. 2.) Gamboge 3ij; aloes 3iij ; colocynth 3j ; cream of tartar 3iv ; sirup to mix. Both the above are purgative; the latter strongly so. Dose of either, 5 to 15 grs. PILLS, NAPOLEON'S PECTORAL. Prep. Ipecacuanha 30 gre.; powdered squills and am- moniacum, of each 40 gre.; mucilage to mix ; di- vide into 24 pills. It is said that the above was a favorite remedy with the late emperor of France for difficulty of breathing, bronchitis, and various affections of the organs of respiration. Dose. 2 pills night and morning. PILLS, OPIUM. Syn. Night Pills. Ano- dyne do. Opiate do. Pil. Opii sive Thebaica, (P. E.) Opium and conserve of red rc/oes, of each 1 part; sulphate of potash 3 parts ; mix, and di- vide into 5-gr. pills. Dose. 1 or 2 pills, as an anodyne or soporific. Each pill contains 1 gr. of opium. PILLS, OPIUM AND SOAP. Syn. Com- pound Soap Pills. Laudanum, (P. L. 1720.) Pn Saponacea, (P. L. 1745.) P. Opii, (P. L. 1788.; P. Saponis cum Opio, (P. L. 1809, 1824, & P.D.) Pilula Saponis composita, (P. L. 1836.) Prep. (P. L.) Powdered opium ^ss j Castile soap §ij ; beat together. An excellent anodyne and sopo- rific. Dose. 3 to 10 grs. Contains one-fifth dry opium. PILLS, PECTORAL. Prep. (Haggart) Powdered ipecacuanha," and squills,,of each 3iv; [ acetate of morphia 16 gra. ; Castile soap §j ; mix, and divide into 192 pills. A most excellent pec- toral. Dose. 1 to 3, twice or thrice daily. PILLS, PETER'S. Prep. Aloes, jalap, scam- mony, and gamboge, of each 3ij ; calomel 3j ; beat into a mass with rectified spirit of wine. A pow- erful cathartic. FILLS, RHUBARB. Syn. Pil. Rhai. Prep. (P. E.) Powdered rhubarb 9 parts; acetate of potash 1 part ; conserve of red roses 5 parts ; mix, and divide into 5-gr. pills. Stomachic ; purgative. Dose. 2 to 4 pills. PILLS, RHUBARB, (COMPOUND.) Syn Pil. Rhei comp., (P. L. and E.) Prep.—l. (P. L.) Powdered rhubarb §j; powdered aloes 3vj; pow- dered myrrh 3iv ; Castile soap 3j; oil of caraway f 3ss; sirup q. s. to make a pill mass.—2. (P. E. 1839.) Rhubarb 12 parts; aloes 9 parts; myrrh and soap, of each 6 parts; confection of red roses 5 parts ; oil of peppermint 1 part; mix, and di- vide into 5-gr. pills.—3. (P. E. 1817. Edinburgh Pills.) As the last, but beaten up with sirup of orange peel instead of conserve of roses. *** All the above are tonic, stomachic, and mildly purga- tive. Dose. 10 to 20 gre. PIL 477 PIN PILLS OF RHUBARB AND IRON. Syn. Pil. Rhai et Ferri. Prep. (P. E.) Dried sul- phate of iron 4 parts; extract of rhubarb 10 parts; conserve of roses 5 parts; divide into 5 gr. pills. Tonic ; stomachic. Dose. 2 to 4 pills. PILLS, RUDIUS'S. Prep. Colocynth pulp 3vj ; agaric, black hellebore, and turpethum root, of each ^ss ; cinnamon, mace, and cloves, of each 3ij ; rectified spirit fx ; digest 4 days, express the tincture, and evaporate to a proper consistence. Formerly esteemed as one of the most certain ca- thartics, in troublesome constipation. Dose. 6 to 30 grs. PILLS, SADILLOT'S FEBRIFUGE. Prep. Disulphate of quinine 12 grs.; powdered opium 3 grs. ; confection of opium 10 grs., or q. s. for 12 pills. Dose. 1 pill every hour or two, in the inter- mission of an ague. PILLS, SAGAPENUM, (COMPOUND.) Syn. Pil. Sagapeni comp. Prep. (P. L.) Saga- penum Jj ; aloes 3ss ; sirup of ginger q. s. Dose. 5 to 20 grs., as a stimulant purgative in dyspepsia, with flatulence. PILLS, SCOT'S. Prep. I. Aloes 9 lbs.; jalap 3 lbs.; ginger k lb.; oil of aniseed 1 oz.; treacle 21 oz.; mix.—2. Aloes 1 lb.; colocynth 4 oz. ; scammony and gamboge, of each i oz.; oil of aniseed 2 dr. ; mix with sirup, and divide into 5 gr. pills. A good purgative pill. PILLS, SCOT'S. (Anderson's.) Prep. 1. (Pil. Andersonis, P. Cod.) Aloes and gamboge, of each 3vj; oil of aniseed 3j; sirup to mix.—2. Bar- badoes aloes 1 lb.; jalap 4 oz.; black hellebore 2 oz.; subcarbonate of potash 1 oz.; oil of aniseed ^ oz ; sirup q. s. The last is a good purge, but the first is the most powerful. PILLS, SPEEDIMAN'S. Prep. Aloes 1 lb.; myrrh, rhubarb, and extract of chamomile, of each 4 oz.; oil of chamomile \ oz.; mix. An ex- cellent tonic and stomachic purge. PILLS, SQ'UILL. Syn. Pil. Scilla, (P. E.) Pil. Scilla Comp. (P. L. & D.) Prep. (P. L.) Powdered squills 3j ; ginger and ammoniacum, of each 3ij ; soap 3iij ; sirup q. s. ; mix. An excel- lent expectorant and diuretic. Dose. 5 to 20 grs., in coughs, chronic bronchial affections, &c. It soon spoils. PILLS, STARKEY'S. Prep. Extract of opium ^iv ; mineral bezoar and nutmeg, of each ^ij ; saffron and Virginian snake root, of each §j ; Starkey's soap lb. ss ; oil of sassafras §ss; tincture of antimony (old) f §ij ; mix. Anodyne. Dose. 3 to 10 grs. PILLS, STOERCK'S. Prep. Extract of hemlock 3j; powdered hemlock q. s. to make a pill mass; divide into 2-gr. pills. Dose. 1 to 4 twice a day, in various glandular and visceral en- largements, pulmonary affections, cancer, scrofula, neuralgia, &c. PILLS, STORAX. Syn. Pil. Styracis, (P. E.) Pil. Styracis Comp., (P. L.) Prep. (P. L.) Strained storax 3iij ; powdered opium and saffron, of each 3j ; mix. Anodyne. Dose. 5 to 10 grs., in chronic coughs, &c. f PILLS, STRYCHNINE. Syn. Pil. Strych- nia. Prep. (Majendie.) Strychnia 2 grs.; con- serve of roses 3ss; mix, divide into 24 pills and silver them. 'ILLS, TANJORE. Syn. East India Pills. Carnatic Snake do. Asiatic do. Pil. Arsenicl Prep. (P. Cod.) White arsenic 1 gr.; black pep- per 12 gra.; triturate well, add powdered gum 2 grs., and water q. s. to make a pill mass ; divide into 15 pills. Dose. 1 or 2 after a meal. Com- monly employed in the East Indies in syphilis, elephantiasis, the bite of poisonous snakes, and as a preventive of canine madness. PILLS, TONIC. Prep. 1. (Thomson.)—a. Rhubarb and ginger, of each 3ss; extract of chamomile 3j; divide into 30 pills. Dose. 2 or 3 twice a day in dyspepsia and chlorosis.—b. Ses- quioxide of iron, and extract of hemlock, of each 3j; divide into 20 pills. Dose. 1 or 2 twice a day in fluor albus and scrofula.—2. (Collier.) a. Tar- trate of iron and extract of gentian, of each 3j; oil of cinnamon 2 drops ; for 30 pills. Dose. 3 to 6, 3 or 4 times a day. A good stomachic tonic.— b. Oxide of zinc 3ss, (or sulphate 3j;) myrrh 3ij; camphor 3j; confection of hips to mix; for 40 pills. Dose. 1 or 2 pills 3 times a day, in epilepsy, chorea, and other nervous disorders, debility, &.c. —3. Sulphate of iron, ginger, and myrrh, equal parts ; conserve of roses to mix. Divide into 4 gr. pills. Dose. 1 twice a day ; in debility, &c.— 4. Powdered myrrh and sulphate of iron, of each 3j ; sulphate of quinine 3ss ; powdered capsicum 15 grs.; conserve to mix; divide into 60 pills. Dose. 1 or 2 twice or thrice a day in debility, dys- pepsia, ague, &c.—5. (Pil. Tonica Bacheri. P Cod.) Alkaline extract of hellebore, and extract of myrrh, of each 3ij ; powdered holy thistle 3j ; mix and divide into 4-gr. pills.—6. (Pil. Tonica Stahlii) Powdered iron filings, gum ammoniacum, and extract of lesser centaury, (chironia centau- rium,) of each 3j ; sirup of fumitory q. s. to mix. PILLS, VERATRIA. Syn. Pil. Veratria. Prep. (Turnbull.) Veratria 1 gr.; extract of hen- bane and liquorice powder, of each 12 gra.; mix, and divide into 12 pills. Dose. 1 every 3 hours; in dropsy, epilepsy, hysteria, paralysis, nervous palpitations, &c. PILLS, WARD'S ANTIMONIAL. Prep. Glass of antimony, finely levigated, 4 oz.; dragon's blood 1 oz.; mountain wine q. s. to make a mass; divide into 1^-gr. pills. Emetic. * PILLS, WORM. Syn. Pil. Vermifuga vel Anthelmintica. Prep. 1. (Peschier.) Ethereal extract of malefern 30 drops ; extract of dandelion 3j; powdered gum q. s. for 30 pills. Dose. 6 to 20 or more, followed in half an hour by a strong dose of castor oil.—2. Calomel §j j sugar §iss; mucilage to mix; divide into 240 pills. Dose. 1 or 2 over night followed by a strong dose of castor oil early the next morning.—3. Gamboge 8 grs.; calomel 5 grs.; mucilage to mix. For a morning's dose. PIMARIC ACID, obtained by Laurent from the turpentine of pinus maritima, by the action of hot alcohol. By distillation in vacuo it yields py- romaric acid, and under ordinary pressure pima- rone. By the action of nitric acid it yields azo- maric acid. PIMENTIC ACID. Heavy oil of pimento. PINIC ACID. The portion of common white resin soluble in cold alcohol of sp. gr. -883. PINK, BROWN. Prep. French berries and pearlash, of each 1 lb.; fustic chips £ lb.; water l1, gallons; boil in a tin or pewter vessel, and PIT 478 PLA strain through flannel while hot; then dissolve alum 1£ lbs., in hot water 2k gallons, and add the solution to the strained decoction as long as a sedi- ment falls ; wash the latter, drain and dry. Some persons omit the fustic. Used as a yellow pigment. Is a fine glaziug color when ground in linseed and used with drying oil. PINK, DUTCH. Prep. French berries 1 lb.; turmeric £ lb.; alum J lb.; water 1£ gallon ; boil £ an hour, strain, evaporate to 2 quarts, add whit- ing 3 lbs., and dry by a gentle heat. Starch or white lead is sometimes employed instead of whit- ing, to give it a body. Golden yellow. Used as it pigment PINK DYE. Prep. Washed safflowera 2 oz.; subcarbonate of potash 3 dr.; spirit of wine 7 oz.; digest 2 hours, add water 1 lb.; digest for 3 hours more, and add lemon juice q. s. to strike a rose color. Used as a cosmetic and to dye silk stockings. PINK, ENGLISH. Syn. Light Pink. Pre- pared like Dutch pink, but with more whiting. PINK, ROSE. Whiting colored with a decoc- tion of Brazil wood and pearlash. A very pretty color, but does not 6tand. It is always kept in the damp state. The color may be varied by substi- tuting alum for pearlash, or by the addition of a little spirits of tin. PINK SAUCERS. Prep. Well washed saf- flower 8 oz.; carbonate of soda 2 oz.; water 2 gallons; infuse, strain, add French chalk, scraped fine with Dutch rushes, 4 lbs.; mix well, and pre- cipitate the color on it by adding a solution of tar- taric acid; collect the red powder, drain, add a very small quantity of gum, and apply the paste to the saucers. Less chalk may be used for a very fine article. PIPERINE. Syn. Piperina. Prep. (P. Cod.) Treat alcoholic extract of black pepper with a so- lution of potash, (1 to 100 ;) wash the residue with water, dissolve in alcohol, filter, and let it evapo- rate spontaneously. White, tasteless, inodorous, fusible, and crystalline; reddened by oil of vitriol. It has been given in doses of 6 to 12 grs. in inter- mittent fevers. PITCH, BURGUNDY. Syn. Pix Burgun- dica. Pix Abietina, (P. L.) " The true Burgun- dy pitch, so often prescribed for plasters, intended to produce a mild counter-irritation, is the resin of the pinus abies. It appears that the importation of this substance has for some years past been gradually lessening in amount, in consequence of the substitution for it of a factitious pitch, made by melting common resin together with linseed-oil, and coloring the mass with annotto. Mr. Cooley, in ' The Chemist,' July, 1844, says, this is well known among manufacturing druggists, the small- est difference of price inducing those gentlemen to substitute the spurious for the genuine article.— ' The physiological action of the two articles is considerably different, since Burgundy pitch acts upon the skin as a powerful local irritant, exciting a slight degree of inflammation, and not unfre- quently producing a pimply eruption, and an ex- udation of purulent matter from the cuticle on which it is applied. It is celebrated for its effects when employed as a plaster in all cases where warmth, support, and long adhesion to the skin are desirable, and in the latter quality no substance equals it. I have worn a pure Burgundy pitch- plaster on my chest from November until the fol- lowing April, and it was still adhesive. The fac- titious Burgundy pitch has similar properties, but in an immensely less degree.' We cannot suffi- ciently express our abhorrence of such practices as the manufacture and sale of spurious drugs." (Lancet.) The article above alluded to is made by melting good yellow resin 1 cwt, with linseed oil 1 gallon, and palm oil (bright) q. s. to color. The mass is next allowed to cool considerably, and then pulled with the hands in the same way as lead plaster is treated, after which it is placed in bladders or " stands" for use. The pulling or working destroys the translucency of the resin, and imparts the opacity of foreign Burgundy pitch. Water may be employed to cool it down. Annotto is often substituted for palm oil as a coloring. The addi- tion of some of the droppings or bottoms of Can- ada balsam, Chio turpentine, oil of juniper, &c., will render this article equal to foreign pitch; but in commerce this is never attempted, the aim be- ing only the production of a lively color with moderate toughness. A common melting-pan and fire (if clean and carefully managed) will succeed sufficiently; but, of course, both for safety and convenience, steam is preferable, and, on the large scale, almost indispensable. A good workman will pull and put into stands or casks about 5 cwt daily, or from 1 cwt. to 3 cwt. in bladders, the latter quantity depending on the size of the blad- ders ; the small bladders occupying much longer, from the greater loss of time in tying, cutting, &c. PITTACALL. (From mrTa, pitch, and *aXof, beautiful.) A substance resembling indigo, ob- tained by Reichenbach from a certain portion of oil of tar, by the action of baryta. It gives a fast blue dye to cotton mordanted with tin and alum. PLASTER. Syn. Emplastrum, (Lat., from cpirXaaau, to spread upon) Plasters are external applications that possess sufficient consistence not to adhere to the fingers when cold, but which be- come soft and adhesive at the temperature of the human body. They are chiefly composed of unc- tuous substances united to metallic oxides, or pow- ders, or to wax, or resin. Plasters are usually formed while warm into J lb. rolls, about 8 or 9 inches long, and wrapped in paper. When want- ed for use, a little is melted off the roll by means of a heated iron spatula, and spread upon leather, linen, or silk. The less adhesive plasters, when spread, are usually surrounded with a margin of resin plaster to make them adhere. In the prep- aration of plasters, the heat of a water-bath or steam should alone be employed. On the large scale, well cleaned and polished copper, or tinned copper pans, surrounded with iron jackets, supplied with high-pressure steam, are used for this pur- pose. The resins and gum resins that enter into their composition, should be previously purified by straining. After the ingredients are mixed and the mass has acquired sufficient consistence by cooling, portions of it are taken in the hands anointed with a little olive oil, and well pulled or worked till it becomes solid enough to form into rolls. To promote the cooling of the plaster it is usual to plunge it into cold water, and to expose it to the action of the fluid by working it about, after which it must be well pulled in the hands to PLA 479 PLA remove the water. Many plasters, as those of lead and resin, derive much of their whiteness and beauty from this treatment. White plasters are not, however, always the best, but they are those which are most admired and sought after. BLASTER, AMMONIACUM. Syn. Em- plastrum Ammoniaci, (P. L. E. & D.) Prep. (P. L.) Ammoniacum (strained) gv; distilled vinegar 5yiij ; dissolve and evaporate. The P. D. orders vinegar of squills £ pint. Adhesive, stimulant, and resolvent. In scrofula, indolent swellings, &c. PLASTER, AMMONIACUM AND MER- CURY. Syn. Emp. Ammoniaci cum Hydrargy- ro, (P. L. & D.) E. Ammon. et Hydrargyri, (P. E.) Prep. (P. L.) Olive oil 3j ; heat it in a mortar, add flowers of sulphur 8 grs.; triturate, add mercury §iij ; again triturate till the globules are extinguished, then add it to ammoniacum (strained) lb.j, melted by a gentle heat, and mix well. As the last, but more powerful. *** This plaster cannot be rolled till considerably cooled, and must not be put into water. II. (Wholesale.) Mercury 38 oz.; prepared se- vum -J lb.; triturate as last, and add the mixture to strained ammoniacum 10 lbs. Fine blue color and quickly made. PLASTER, AROMATfC. Syn. Stoma*h Plaster. Emp. Aromaticum. Prep. (P. D.) Strained frankincense (thus) §iij ; beeswax %ss ; melt, and when considerably cooled, add powdered cinnamon 3vj ; oils of allspice and lemons, of each 3ij. %* Must not be put into water. Stimu- lant ; applied over the stomach in dyspepsia, pain, nausea, flatulence, &c. Some add camphor 3j. PLASTER, ASAFCETIDA. Syn. Emp. As- safcetida. Prep. (P. E.) Lead plaster and strained asafcatida, of each, §ij; strained galbanum and beeswax, of each, gj ; melt together. *** Must not be put into water. Antispasmodic. Applied to the stomach or abdomen in hysteria, or to the chest in hooping-cough. PLASTER, BELLADONNA. Syn. Emp. Belladonna, (P. L. E. &. D.) Prep. (P. L.) Ex- tract of deadly nightshade 5,ssj resin plaster, melted by a gentle heat, §iij j mix. A powerful anodyne and antispasmodic; m neuralgia and rheumatic pains, and as an application to painful tumors. The plaster of the shops is usually defi- cient in extract. The following is a form I have seen used in the wholesale trade:—Lead plaster and resin plaster, of each, 2£ lbs.; extract of bel- ladonna l| lbs. This plaster must not be pulled in water. PLASTER, BURGUNDY PITCH. Syn. Cephalic plaster. Emp. cephalicum, (P. L. 1745.) Emp. Picis Burgundica, (P. L. 1788.) Emp. Picis comp., (P. L. 1809, 1824.) Emp. Pi- cis, (P. L. 1836, & P. E.) Prep. (P. L.) Bur- gundy pitch lb. ij ; resin of the spruce fir (thus) lb.j; yellow rosin and beeswax, of each, §iv; melt, add olive oil and water, of each, Jij ; ex- pressed oil of mace ^j ; and boil to a proper con- sistence. Stimulant and counter-irritant. Applied to the chest in pulmonary affections, to the joints in rheumatism, and to the loins in lumbago. It is a good warm plaster to wear on the chest during winter. *#* The pitch plaster of the shops is made as follows : Factitious Burgundy pitch, bright colored, 42 lbs.; palm oil (bright) f lb.; beeswax (bright) 5 lbs.; melt, and when nearly cold, add oil of mace 6 oz.; oil of nutmeg 1 oz. PLASTER, CANTHARIDES. Syn. Blis- tering Plaster. Emp. Lytta. (P. L. 1809.) Emp. Cantharidis, (P. L. E. &, D.) Prep.—1. (P. L.) Wax plaster lb. iss ; lard lb. ss ; melt, and when considerably cooled, add finely powdered Spanish flies lb. j, and stir till stiff—2. (P. E.) Cantharides, resin, beeswax, and suet, of each, fij ; mix as last Used to raise blisters. It should be spread on lea- ther with a cold knife, and surrounded with a margin of resin plaster. A piece of thin muslin or tissue paper is usually placed between the plaster and the skin to prevent absorption.—3. (Whole- sale.) Flies and yellow rosin, of each, 6 lbs.; suet 10 lbs.; beeswax and lard, of each, 4 lbs. *** The above should be rolled in starch powder, and not with oil. PLASTER, CANTHARIDES, (COM- POUND.) Syn. Emp. Cantharidis comp. Prep. (P. E.) Venice turpentine ^ivss; Burgundy pitch and cantharides, of each, fiij; beeswax 3j; ver- digris § ss; black pepper and powder mustard, of each, 3ij ; mix. Stronger than the last. PLASTER, COURT. Syn. Sticking Plas- ter. Emp. adhesivum Anglicum, (Ph. Bor.) Prep. 1. (Paris.) Black silk or sarsenet is strained and brushed over 10 or 12 times with the follow- ing composition:—Balsam (gum) of benzoin J oz.; rectified spirit 6 oz.; dissolve. In a separate ves- sel dissolve 1 oz. of isinglass in as little water as possible ; strain each solution, mix, and decant the clear. It is applied warm. When the last coat is quite dry, a finishing coat must be given with a solution of 4 oz. of Chio turpentine in 6 oz. of tincture of benzoin.—2. Isinglass 1 oz.; dissolve in proof spirit 12 oz.; add tincture of benzoin 2 oz.; give 5 or 6 coats, and finish off as last.—3. Isinglass 1 oz.; water 3 oz.; dissolve, add tincture of benzoin 1 oz.; apply as above, and finish off with a coat of tincture of benzoin or tincture of balsam of Peru. *#* Goldbeaters' skin is now fre- quently substituted for sarsenet. PLASTER, CUMIN. Syn. Emp. cymini. E. cumini. Prep. (P. L. 1824.) Burgundy pitch lb.iij ; beeswax ^iij ; melt, and add cumin seeds, caraway do., and laurel berries, (all in fine powder,) of each §iij; water and olive oil, of each f ^iss.—2. Yellow rosin 7 lbs.; beeswax and linseed oil, of each, k lb.; powdered cumin and caraway seeds, of each, 7 oz.; mix. Discutient; applied to the stomach and belly in dyspepsia and flatulence, and also to indolent tumors. PLASTER, GALBANUM. Syn. Yellow Diachylon. Gum do. Emp. Galbani comp., (P. L. 1824.) Emp. Galbani, (P. L. 1836 & P. D.) E. Gummosum, (P. E.) Prep.—l. (P. L.) Lead plaster lb. iij ; resin of spruce fir giij ; melt, add common turpentine (Venice) 3x; strained galba- num §viij.—2. (Wholesale.) Lead plaster 42 lbs.; yellow rosin 12 lbs.; strained galbanum 2 lbs.; strained asafcetida 1 oz. Stimulant and resol- vent. PLASTERS, ISSUE. Syn. Sparadrapum pro Fonticulis. Prep. Beeswax lb. ss ; Bur- gundy pitch and Chio turpentine, of each fiv; vermilion and orris powder, of each £j ; musk 4 gre.; melt, spread upon linen, polish with a smooth PLA 480 PLA piece of glass moistened with water, and cut into pieces. PLASTER, KENNEDY'S CORN. Prep. Wax lb. j; Venice turpentine Jiv; verdigris ^iss ; spread on cloth, cut, polish, and put 12 bits into each box. PLASTER, LEAD. Syn. Diachylon. White do. Simple do. Diapalme. Diachylon simplex, (P. L. 1720.) Emp. commune, (P. L. 1745.) E. Lythargyri, (P. L. 1788, P. E. & D.) Emp. Plumbi, (P. L. 1809, and since.) Prep. I. (P. L.) Finely-powdered litharge lb. vj; olive oil 1 gallon; water 1 quart; boil to the consistence of a plaster, adding more water if required. II. (P. E.) Litharge §v ; olive oil f §xij; water f §iij. As last. III. (Otto Kohnke.) For each pound of litharge employed, add 4, pint of colorless vinegar, (each ounce of which is capable of saturating 3ss of carbonate of potash ;) boil until all moisture is evaporated, and until only a few striae of litharge rise to the surface, then remove the heat, add gradually k to £ as much vinegar as before, and boil to a proper consistence. IV. (Wholesale.)—a. Genoa oil 60 lbs.; litharge 30 lbs.; water 2 or 3 gallons.—6. Oil 70 lbs.; litharge 30 lbs.; water 2 or 3 gallons. Remarks. The London College orders too little oil. The second, fourth, and fifth forms produce beautiful plasters, and so does the third, provided enough oil be used. The proper proportion of litharge is 1 lb. to every 2£ lbs. of oil, (C. Watt,) and without this is used, the plaster speedily gets hard and brittle, and loses its adhesiveness. The process consists in putting the water and litharge into a clean and polished tinned-copper or copper pan, mixing them well together with a spatula, adding the oil, and boiling with constant stirring till the plaster is brittle, when thoroughly cold. This process usually occupies from 4 to 5 hours, but by adopting the third formula, an excellent plaster may be made in 15 or 20 minutes. To render this plaster very white, it is usual to sub- mit it to laborious pulling. Use. As a simple strapping, but principally as a basis for other plasters. PLASTER, MELILOT. Syn. Emp. Meli- loti. Prep. (P. E. 1744.) Fresh melilot, chop- ped small, lb. vj ; suet lb. iij ; boil till crisp, strain with pressure, and add yellow rosin lb. viij ; bees- wax lb. iv. Stimulant. Used to dress blisters, &c. The greater portion of this plaster in the shops is colored with verdigris, and is frequently made without the herb. I have seen the follow- ing form used in the wholesale trade:—Yellow rosin 18 lbs.; green ointment 4£ lbs.; yellow wax 3 lbs.; finely-powdered verdigris to give a deep-green color. PLASTER, MERCURIAL. Syn. Emp. Hydrargyri, (P. L. &. E.) Prep. (P. L.) Lead plaster lb. j; melt, add mercury ^iij, previously " killed" by trituration with balsam of sulphur f 3j.—2. (Wholesale.) Mercury 7 lbs.; prepared sevum £ lb.; triturate till the globules disappear, and add it to lead plaster, melted by a gentle heat 36 lbs.; stir well together. Very fine blue or lead color. Used as a discutient in glandular en- largements, and other swellings ; and also applied over the hepatic regions in liver complaints. PLASTER, OPIUM. Syn. Emp. Opii, (P. L. E. & D.) Prep. I. (P. L.) Lead plaster lb. j ; melt, add powdered thus Jiij ; mix, and further add powdered opium ^ss ; water f 3V*'J» and boil to a proper consistence. The other Colleges omit the water, and use Burgundy pitch for thus. Used as an anodyne. II. (Wholesale.) Lead plaster 10 lbs.; yellow resin 30 oz.; powdered opium 4 oz. PLASTER, OXIDE OF IRON. Syn. Iron Plaster. Frankincense do. Strengthening do. Emp. Roborans. E. Ferri Oxydi. E. Ferri, (P. E.) E. Thuris, (P. D.) Prep. I. (P. E.) Lead plaster SJiij; yellow resin 3vj; bees- wax 3iij ; melt together, then add red oxide of iron ^j, previously triturated with olive oil f 3iiiss. II. (P. L. 1788.) Thus lb. ss ; dragon's blood ^iij ; lead plaster lb. ij. III. (Wholesale.) Lead plaster (dry) 72 lbs.; powdered yellow resin 12 lbs.; crocus martis (lively colored) 14 lbs.; olive oil 1 quart. Iron plaster is strengthening and stimulant, and em- ployed as a mechanical support in muscular re- laxation, weakness of the joints, &c, especially by public dancers. PLASTER, OXYCROCEUM. Syn. Emp. Oxycroceum. Prep.—1. (P. E. 1744.) Bees- \$1ax lb. j; black pitqh and strained galbanum, of each lb. ss ; melt; and add Venice turpentine, powdered myrrh, and olibanum, of each ^iij; powdered saffron §ij.—2. (Wholesale.) Black pitch 9 lbs.; black rosin 10£ lbs.; beeswax and lard,' of each 2\ lbs.; melt together. Warm; discutient. PLASTER, PARACELSUS. Syn. Emp. Stypticum. Prep. Lead plaster 28 lbs.; galbanum plaster 2 lbs.; powdered white canella, and gum thus, of each 1£ lb. ; melt together. ^ PLASTER, RED LEAD. Syn. Emp. e Minio. Made as lead plaster, but with red lead instead of litharge. If boiled to perfect dryness it forms the Emp. e minio fuscum. Lead plaster, colored with red lead, is usually sold for it. PLASTER, RESIN. Syn. Adhesive Plaster. Baynton's do. Emp. Resina, (P. L.) E. Resin- osum, (P. E.) E. Lythargyri cum Resina, (P. D.) E. Adhesivum. Prep.—1. (P. L.) Lead plaster (dry) lb. iij ; melt, and add yellow resin (powdered) lb. ss. Principally used as a strap- ping for dressing ulcers, retaining the lips of cuts and wounds in contact, &c.—2. (Wholesale.) Lead plaster (dry) 60 lbs.; pale yellow resin (powdered) 10 lbs. PLASTER, SOAP. Syn. Emp. Saponis, (P. L. E. & D.) Prep. (P. L.) Litharge plaster lb. iij ; soap (white) sliced lb. ss ; melt together, and boil to a proper consistence. If it contains water it will crumble. Discutient; in abrasions, &c. PLASTER, SOAP, (COMPOUND.) Syn. Emp. Saponis comp. vel adharens. Prep. (P. D.) Soap plaster gij ; resin plaster Sjiij ; melt together. Used in abrasions, &c. *»* Neither of the above must be put into water. PLASTER, VERDIGRIS. Syn. Corn Plaster. Emp. jEruginis. Prep. (P. Cod.) Wax 4 oz.; Burgundy pitch 2 oz.; melt, add Venice turpentine and powdered verdigris, of each loz. PLASTER, WARMING. Syn. Emp. Calk- PLA 481 P01 FAdENs. Prep. (P. D.) Burgundy pitch 7 parts; melt, and add plaster of cantharides 1 part Some add a little camphor. Stimulant and rubefacient. Used in chest complaints, local pains, &c. PLASTER, WAX. Syn. Simple Plaster. Emp. Attrahens. E. Simplex, (P. E.) E. Cera, u .?reP- (P-L) Yellow wax and suet, of each lb. iij ; yellow resin lb. j; melt and strain. A simple dressing. PLATINIZING. Proc. I. (In the moist way) Solid chloride of platinum 1 part, is dis- solved in water 100 parts, and to this solution is added common salt 8 parts; or still better, 1 part ">f platino-chloride of ammonia and 8 parts of hy- ti ""-chlorate of ammonia are placed in a flat porce- lain vessel. 32 to 40 parts of water poured over it, the vhole heated to boiling, and the vessels of coppe- or brass, perfectly bright, are placed there- 'n- Th->y will be covered in a few seconds with a brilliant and firmly-adhering layer of platina. II. (By the Electrotype.)—a. Proceed as di- rected under Voltaic Gilding, but make use of a dilute solution of the double chloride of soda and platinum. Th-*ee immersions suffice ; between each immersion It is necessary to dry the surface with fine linen, ruobing rather briskly, after which it must be thoroughly cleaned with levigated chalk. When copper has been gilded in the moist way, the gilt surface has not always a beautiful tint; but if the copper be previously covered with a pellicle of platina, a very beauti- ful golden surface may be produced. (M. Bo- ettger.) b. (M. Ruolz.) As the third process of voltaic gilding, (p. 335,) but using double chloride of pla- tinum and potassium, dissolved in caustic potassa. Thjs solution allows of platinizing with the same facility and promptitude as in gilding or silvering. *** Manufacturing and operative chemists will find, in this process, a means of procuring large capsules of platinized brass, which combine cheap- ness with the necessary resistance to saline or acid solutions. 1 millegramme of platinum is capable of perfectly covering 50 square millimetres, which corresponds to a thickness of l-100,000th o» a millimetre. Platinum, thus applied, may be obtained from the crude solution of platinum ore, as the metals which accompany it do not injure the effect. (Dumas.) PLATINUM. Syn. Platina, (from plat a, Span, silver.) A heavy, white-colored metal, chiefly imported from South America, where it is found in a granular form, associated with some other rare metals. It has the sp. gr. 21-25 to 21*5 after forging, being the heaviest metal known, and is remarkable for its hardness, and power of resisting heat, and acid menstrua. Crude platinum is purified by solution in nitro- muriatic acid, somewhat dilute, precipitation by muriate of ammonia, and exposing the precipitate to a violent heat. The metal reduced in an ag- glutinated state, may be rendered more compact by pressure while red hot. Platinum undergoes no change by exposure to air and moisture, or the strongest heat of a smith's forge, and is not at- tacked by any pf the pure acids, but is dissolved oy chlorine and nitromuriatic acid, though with more difficulty than gold. Spongy and powdered 61 platinum possesses the remarkable property of caus- ing the union of oxygen and hydrogen gasesi Platinum is precipitated from its solutions by de- oxidizing substances under the form of a black powder, which has the power of absorbing oxygen, and again imparting it to combustible substances, and thus causing their oxidation. In this way alcohol and pyroxilic spirit may be converted into the acetic and formic acids, &c. (See Acetic Acid.)—Oxide or Protoxide of Platinum is ob- tained by digesting protochloride of platinum in a solution of pure potassa in very slight excess. It dissolves slowly in the acids, forming salts of platinum.—The Binoxide, Deutoxide, or Per- oxide, by exactly decomposing the sulphate of the binoxide with nitrate of baryta, and adding pure soda to the filtered solution, so as to precipi- tate only half the oxide. (Berzelius.)—The Sesquioxide, by heating fulminating platinum in nitrous acid. (E. Davy.)—The Protochloride, by heating the bichloride to about 450° ; greenish gray.—The Bichloride, by evaporating the nitro- ' muriatic sohition to dryness, at a gentle heat; red.—The Protiodide, by digesting the proto- chloride in a solution of iodide of potassium; black. (Lassaigne.)—The Periodide, by the action of iodide of potassium on a weak solution of the bichloride ; black. (Lassaigne.)—The Pro- tosulphuret, by heating the yellow ammoniacal chloride with i its weight of sulphur in a retort.— The Bisulphuret, by dropping a solution of the bichloride into a solution of sulphuret of potas- sium.—Fulminating Platinum, by acting on sul- phate of platinum with ammonia in slight ex- cess.—The Platino-bichloride of Potassium, by mixing solutions of bichloride of platinum and chloride of potassium, and evaporating ; a yellow powder, or small octohedrons.—The Platino- bichloride of Sodium, as the last.—The Platino- bichloride of Ammonia, by precipitating a strong solution of the bichloride by a solution of sal am- moniac ; an insoluble yellow powder.—The Pla- tino-protochlorides are prepared in a similar way.—Platina-mohr is obtained by melting pla- tina ore with twice its weight of zinc, powdering, digesting first in dilute sulphuric acid, and next in dilute nitric arid, to remove the zinc, assisting the action of the menstruum by heat; it is then di- gested in potash lye, and lastly in pure water. (Descotils.) An insoluble grayish black powder, consisting of crude platinum. It acts like pla- tinum black, converting alcohol into vinegar, &c. It explodes by heat. *** The salts of platinum are said to be alterative. The bichloride and the sodio-chloride have been employed both internally and endermically in syphilis, &c. They are poisonous. PLUMBAGINE. A crystalline substance, ex- tracted by M. Dulong from the roots of plumbago europea. It is soluble in alcohol, ether, and water. POISON. When you have reason to suppose that you have accidentally swallowed a poisonous substance, and proper medical advice is not at hand, take an emetic. This may be done almost instantaneously, by swallowing a cupful of warm water mixed with a teaspoonful of mustard. If you have not dry mustard in the house, you are almost sure to have a mustard-pot, and a quantity from that put into the water will very quickly POM 482 POR empty the stomach. As mustard may thus prove of so much use, it should never be wanting in any house ; but even should there be no mustard at .hand, warm water by itself forms a tolerably effi- cacious emetic. (See the various Poisons for their antidotes.) POLYCHROME. A peculiar substance ob- tained from the bark of the horse-chesnut, and from quassia wood, by precipitating the infusion by acetate of lead, decomposing the preeipitate by sulphureted hydrogen, filtering, and evaporating to a sirup, when crystals of polychrome form after some time. It is purified by repeated solutions in a mixture of alcohol and ether. The solution ap- pears colorless by transmitted light, but blue by re- flected light, and exhibits a beautiful play of colors, visible when dissolved in 1.500,000 parts of water. POLVCHROMIC ACID. Syn. Artificial bitter of Aloes. Prep. Aloes 1 part; nitric acid (sp. gr. 1*25) 8 parts ; mix, and when the action is •over, evaporate to a sirup, and add cold water to throw down the polychromic acid ; purify by wash- ing with water till the liquid passes off of a blue color. A yellowish brown powder forming a pur- ple solution ; it explodes when heated. It is a mix- ture of Aloetic and Aloeresinic Acids. (Schunck.) POMMADE, (Fr. Pomatum.) Pommades are divided by the French perfumers into three class- es ; viz.—Pommades by infusion—Pommades by contact, and—Pommades by addition. The first are made by gently melting in a clean pan, 2 parts of hog's lard and 1 part of beef suet, both of the finest quality and carefully " rendered ;" and adding 1 part of flowers, carefully picked, or if a solid substance, coarsely bruised, and macerating for 24 hours, occasionally stirring, and observing tb keep the vessel covered as much as possible. The next day the mixture is remelted, and again well stirred for a short time, after which it is pour- ed into canvass bags, and these being next secure- ly tied, are submitted to powerful pressure, grad- ually increased, in a barrel press. This operation is repeated with the same fat several times, until the pommade is sufficiently perfumed. A good pommade aux fleurs, requires twice to six times its weight of flowers to be thus consumed, and pommades of the aromatic barks and seeds a cor- responding proportion. *** In the same way are made the pommades of Cassia, orange flowers, and several others kept by the French perfumers. Pommades by contact are made by spreading with a palette knife simple pommade (made with lard and suet as above) on panes of glass or pewter plates, to the thickness of a finger, and sticking the surface all over with sweet-scented flowers, which must be renewed daily for 2 or 3 months, or till the pommade has acquired sufficient perfume. On the large scale, the panes are placed in small shal- low frames made of 4 pieces of wood nicely fitted together, and are then closely piled one upon an- other. On the small scale pewter plates are most- ly used, and one is inverted over the other. In some of the perfumeries of France, many thou- sands of frames are employed at once. *** In this way are made the Pommades Jasmin, Jon- quil, Orange-flowers, Narcissus, Tuberose, Vio- let, &c. Pommades by addition are made by merely adding the fragrant essences or oils in sufficient quantity to the simple pommade of lard and suet to produce the proper odor; or by mixing togethei other pommades. %* In this way are rrade the Pommades of Bergamotte, Cedrat, Cinnamon, Lemons, Lemon thyme, Lavender, Limettes, Marjoram, Portugal, White Rose, Rosemary, Thyme, Verbena, and about 30 others, distinguish- ed by the Parisian perfumers. Mixed Pommades. Of these a great numbet are prepared by the French, by the judicious com bination of the most esteemed perfumes or Pom- mades, of which the following are a few exam- ples :— Pommade a la Vanille, or Roman pommade. Pommade a la rose 12 lbs.; powdered vanilla 1 lb.; melt in a water bath, stir constantly for 1 hour, let it settle for another hour, decant the clear, and add oil a la rose 2J lbs.; bergamotte 4 oz.—Pommade de Casse. Simple pommade 1 lb.; palm oil k oz.; melt, pour off the clear, and add oil of cassia and huile au jasmin, of each 1 dr.; neroli, 20 drops; oil of verbena, or lemon grass, 15 drops; otto of roses, 5 drops; stir till nearly cold.—Pommade di- vine. Plain pommade, 1 lb.; essences of lemon and bergamotte, of each 2 dr.; oils of lavender and origanum, of each 1 dr.; oils of verbena, cassia, cloves, and neroli, of each 12 drops; huile au jas- min, 3 dr.; essence of violets, $ oz. *w* Pom- mades are colored—Yellow, by palm oil or annot- to—Red, by alkanet root—and Green, by guaia- cum, or the green leaves of spinage or parsley. White pommades are made with mutton instead of beef suet. POMATUM. (From pomum, an apple.) A fragrant unguent used in dressing the hair; so named because it was formerly made with lard and apples. (See Pommades.)—Simple Pomatum. 1. Lard 2 lbs.; beef suet 1 lb.—2. Lard 3 lt».; | mutton suet l\ lb.—Common Pomatum. Simple pomatum 1 lb.; essence of lemon 1 dr.—East India Pomatum. Suet 3 lbs.; lard 2 lbs.; beeswax (bright) ^ lb.; palm oil 2 oz.; powdered gum ben- zoin 3 oz.; musk 20 grs.; melt, and digest two hours, decant, add essence of lemon 1 oz.; oil of lavender i oz.; oils of cloves, cassia, and verbena, of each 1 dr.—Rose Pomatum. Lard or simple po- matum washed with rose water, or scented with otto. It may be reddened with alkanet.—Soft Pomatum. Hard lard, scented like East India po- matum.—Millefleur Pomatum. Simple pomatum, scented so that no one perfume shall predominate.— Roll Pomatum. (Hard do.) Mutton suet 6 lbs.; white wax J lb.; spermaceti \ lb.; powdered ben- zoin 1 oz.; melt, and add scent at pleasure.— Mareschal Pomatum. (Hard.) To the last add mareschal powder 6 to 8 oz. PORPHYROXINE. A neutral crystalline sub- stance, discovered by Merck in Bengal opium. It is soluble in alcohol and ether. PORTER. A fermented liquor, brewed from pale malt, mixed with a sufficient portion of high- dried malt to impart the necessary color and Sa- vor. In many cases, its color is imparted by parched malt or burnt sugar, subsequently to the boiling. (See Brewing.) Porter originated with a London brewer named Harwood, in 1722, and was first called " entire," or " entire butt," from being drawn from one cask. Previously to that I date, ale, beer, and two-penny were the common POT 483 POT beverages, either alone or mixed, under the names of half-and-half, or « three threads," for which the publican was compelled to have recourse to 2 or j casks. 1 he term porter was given from its general consumption among porters and laborers. Ordinary porter contains 4 to 5g of alcohol. Prep. 1 (Draught.) a. Pale malt 3* quarters ; amber malt 3 quarters ; brown malt ij quarters mash at twice with 28 and 24 barrels of water, boil with brown Kent hops 56 lbs.; set with yeast Z -T" c£r°d- 28 barrels> or 3i ^mes the malt, besides 20 barrels of table-beer from a third mash- ing. II. (Bottling Porter. Brown Stout.) Pale malt 2 quarters ; amber and brown malt, of each 1 , • j ---~~* "*«* "»«»« man, ui eaui li eta,; mash at 3 times with 12, 7, and 6 bar- rels oT water, boil with hops 50 lbs. ; set with yeast ttt V"°d' 17 barrels> or H t'mes the malt. 111. tor either of the above use pale malt mixed with one-seventy-ninth part of patent malt lor porter, and one-seventieth part for brown stout. IV. (Brown Stout.) To a butt of good porter add 4 gallons of treacle, 1 gallon of coloring, and 1 quart of finings ; rummage up well, and in a week rack it into another cask. POSOLOGICAL TABLE for proportioning the doses of medicines to the age of the patient, originally drawn up by Gaubius. Under £ year 1-16th of a full dose. " 1 " l-12th " 2 yrs. l-8th " " 3 " l-6th " 4 « l-5th " " 7 " l-3d " 14 " 1-half « " 20 " 2-3ds Above 21 " the full dose. " 63 « ll-12ths " 77 « 5-6ths " 100 « 2-3ds Dr. Young gives the following simple formula: —For children under 12 years, the doses of most medicines must be diminished in the proportion of the age to the age increased by 12. Thus, at 2 years, the dose v/ill be l-7th of that for an adult, VJZ:2Ti2 = 1-7th' *** Sex, temperament, constitutional strength, and the habits and idiosyncrasies of individuals, must be taken into account. Nor does the same rule apply to all medicines. Calomel, for instance. is generally borne better by children than by adults ; while opium affects them more powerfully, and requires the dose to be diminished considerably below that indicated above. POTASH. Syn. Oxide or Protoxide of Po- tassium. Potassa, (Lat.) Potasse, (Fr.) Kali, (Ger.) The potash of commerce is a carbonate of pqtassa, or oxide of potassium, and has been already noticed at page 221. Pure anhydrous potassa is a white solid substance, highly caustic and corrosive, fusible, and possessing a powerful affinity for wa- ter, intense heat being evolved during its combina- tion with that fluid. The hydrate of potassa is the potassa fusa of the shops. Both these substances exhibit alkaline and basic properties in the most marked degree, turning* vegetable yellows brown, and blues green, and forming salts with the acids. Most of the salts of potassa may be made by di- I rectly saturating a solution of the acid with a so. lution of the carbonate or hydrate of potassa, and in some instances advantageously, by double de- composition. In either case, the filtered solution will generally yield crystals on evaporation. (See Potassa, hydrate of.) Tests, cj-c.—1. The solutions of potassa or its salts are unaffected by sulphureted hydrogen, hy- drosulphurets,prussiates, and carbonates.—2. Tar- taric acid (in excess) and perchloric acid give respectively white precipitates of bitartrate and perchlorate of potassa.-^. Carbazotic acid throws down a yellow crystalline precipitate, which is sparingly soluble.—4. Chloride of platinum gives a pale yellow precipitate.—5. Free potassa reddens turmeric, and turns reddened litmus blue POTASSA, ACETATE OF. Syn. Diuretic Salt. Foliated Salt of Tartar. Sal diureti- cus, (P. L. 1745.) Kali acetatum, (P. L. 1788.) Potassa acetas, (P. L. 1809, and since, and P. E. & D.) Prep. (P. L.) Acetic acid f ^xxvj ; water f fxij ; mix, and add gradually carbonate of potash lb. j, or q. s. to.saturate ; filter, and evapo- rate in a sand-bath to dryness. POTASSA, BISULPHATE OF. Syn. Su- persulphate of Potash. Acid Vitriolated Tar- tar. Sal auri philosophicum. Sal enixum. Po- tass^ bisulphas, (P. L. E. & D.) Prep. I. (P. L.) Salt left in distilling nitric acid lb. ij ; boiling water 3 quarts ; dissolve, add sulphuric acid lb. j, evaporate, and crystallize. II. (P. D.) Sulphuric acid 1 part; water 6 parts ; mix, and saturate with carbonate of potash q. s., then add 1 part more of sulphuric acid, and proceed as last. POTASSA, BITARTRATE OF. Syn. Cream of Tartar. Supertartrate of Potash. Acidulous Tartrate of Potash. Potassa bitar- tras, (P. L. E. & D.) This salt is obtained during the fermentation of grape juice, as a crust on the sides of the casks or vats. In its unprepared state it is called white or red crude tartar, or argol, according to the wine from which it has been ob- tained. It is purified by boiling in water, crystal- lization, re-solution in water, and treatment with charcoal and aluminous clay to remove the color ; the clear liquid is then decanted while hot, and al- lowed to cool slowly ; the resulting crystals are cream of tartar. *,* " Entirely soluble in 40 parts of water ; 40 grs. in solution are neutralized with 30 grs. of crystallized carbonate of soda." (P. E.) " It reddens litmus. At a red heat, it is con- verted into carbonate of potash." (P. L.) Dose. 1 to 2 drachms or more, as an aperient; as a diu- retic, 20 grs. to a drachm. It is used to make a pleasant cooling drink, (imperial) and in tooth powders. POTASH, CITRATE OF. Syn. Lemon- ated Kali. The preparation sold in the shops under this name is made as follows :—Finely-pow- dered white sugar 16 lbs. ; tartaric acid 4} lbs.; sesquicarbonate of soda 4 lbs.; all thoroughly dried by a gentle heat; mix, add essence of lemon 1 oz. ; rub the powder through a sieve in a dry situa- tion, put it into bottles, and cork down imme- diately. Keeps well. A dessert-spoonful thrown into a glass of water makes a pleasant effervescing cooling beverage. POTASSA, HYDRATE OF. Syn. Pua« POT 484 POT Potassa. Caustic do. Cauterium potentials. Kali causticum. Lapis infernalis vel septicum, (P. L. 1720.) Kali purum, (P. L. 1788.) Potas- sa fusa, (P. L. 1809, lt*24.) Potassa: hydras, (P. L. 1 -36.) Potassa, (P. E.) Potassa caustica, (P. D.) Preij. (P. L.) Liquor of potassa 1 gal- lon ; evaporate in a clean iron vessel over the fire until the ebullition being finished, the hydrate of potassa liquefies ; pour this into proper moulds. %* A pale grayish or bluish solid, very soluble in water and alcohol. " Boiling water commonly leaves oxide of iron undissolved, which should not exceed 1*25}}." (P. E.) "It should be totally soluble in alcohol." (P. L.) Its solution should be scarcely affected by the nitrates of baryta and silver. It is chiefly used as a caustic, and in chem- istry. POTASSE D'AMERIQUE. Syn. Petit Po- tasse bleu. Caustic soda, melted with salt and lime, and tinged with oxide of copper. This is said to be commonly sold to the Parisian laun- dresses for American potash, as they object to using soda. The potash of the shops in England is often mixed with a similar compound. POTASSIUM. The metallic base of potash. It was discovered by Sir H. Davy in 1807, who obtained it by the action of a powerful galvanic battery on moistened hydrate of potassa. It has since been procured by easier methods. Prep. I. (Curaudau.) Perfectly dry carbonate of potassa 2 parts; powdered charcoal 1 part; mix, place them in a gun-barrel or iron bottle, fur- nished with a short iron tube, and connected with a copper receiver containing a little naphtha and surrounded with ice, and distil by a strong heat. II. (Brunner.) Fused carbonate of potassa or calcined tartar 1 lb.; iron filings J lb.; charcoal -J lb.; proceed as above. Prod. 280 grs. It may be further purified by distillation in an iron or green glass retort. Props., tyc. Potassium is solid at ordinary tem- peratures, but softens at 70°, and fuses at 150°. It sublimes at a low red heat; color and lustre re- sembles mercury. Sp. gr. 0-865. Its most re- markable property is its affinity for oxygen gas, which is so great that it takes it from most sub- stances containing it, and can only be preserved in naphtha, or other fluid hydrocarbons. It is de- composed with the evolution of light and heat by contact with water, and a solution of pure potassa results. It unites with oxygen forming oxides, one of which is potassa, and the other (peroxide) an orange-colored substance formed by burning po- tassium in air or oxygen gas, or by passing oxygen over potassa heated to redness. POTASSIUM, BROMIDE OF. Syn. Hy- DROBROMATE OF POTASSA. PoTASSlI BROMIDUM, (P. L.) Potass* Hydrobromas. Prep. (P. L.) Wa- ter 1J pints ; iron filings ^j ; mix, add bromine §ij ; stir, and in half an hour apply a gentle heat till the liquor turns green, then add carbonate of potash 3xvij, dissolved in water 1^ pints; strain, wash the precipitate with hot water, filter the mixed liquors, evaporate, and crystallize. White trans- parent cubic or rectangular prisms ; inodorous, and soluble in water. It should be neutral to test pa- per. Dose. 4 to 10 grs. in pills or solution, 2 or 3 tunes daily; in scrofula, bronchocele, &c. It is also made into ointment. POTASSIUM, IODIDE OF. Syn. Hydrio- date of Potash. Potassii iodidum, ;P. L. and E.) Potass* iiydriodas, (P. D.) Prep. I. (P L.) Iron filings §ij ; water 2 quarts ; iodine ^vj ; mix, heat till the solution turns green, then add carbonate of potash §iv, dissolved in water 1 quart ; filter, wash the residue with water, evaporate the filtered mixed liquors, and crystallize. The Edin- burgh form is similar. Prod. 4 oz. of iodine yield 4 oz. 3 dr. II. (P. D.) By saturating with carbonate of pot- ash an aqueous solution of hydriodic acid, formed by transmitting chlorine through water in which iodine is suspended. Prod. 4 oz. of iodine yield 4 oz. 7 dr. 20 grs. III. (Turner.) Add to a hot solution of caustic potassa, sp. gr. 1*19, as much iodine as it wit dis- solve, then pass sulphureted hydrogen through the liquid until it becomes colorless, apply a gentle heat to expel excess of acid, filter, exa^A.^ neutral- ize with potassa, evaporate, and crystallize. Prod. 4 oz. of iodine yield 4 oz. 4 dr. 24 grs. IV. (Gregory.) Add iodine to a hot solution of pure potassa until the alkali is neutralized, evapo- rate to dryness, and expose the dry mass to a gen- tle red heat in a platinum or iron crucible, then dissolve out the salt, evaporate, and crystallize An excellent process. V. (Scanlan.) As the last, but mix a portion of powdered charcoal with the mass before ignition. An excellent process. VI. (Duflos.) Iodine and granulated zinc, of each 4 oz.; water 8 oz.; after the action has ceased, neutralize with a solution of carbonate of potash in slight excess, filter, neutralize with a lit- tle hydriodic acid, treat it with sulphureted hy- drogen for the sake of security, evaporate, and crystallize. Prod. 4 oz. of iodine yield 5 oz. 17 gr. Remarks. According to theory 4 oz. of iodine should yield 5 oz. 1 dr. 55 grs. of pure iodide of po- tassium ; but such a product is never obtained in practice, as will be seen by reference to the above formulas, which are those most generally approved of for the preparation of a pure salt. The old method of acting on iodine with potash, or carbon- ate of potash water, yields a very impure product *** Pure iodide of potassium in powder is " to- tally soluble in water and in alcohol. It alters the color of turmeric either not at all, or but very slightly. It does not discolor litmus. Subjected to heat, it loses no weight. Sulphuric arid and starch added together, turn it blue. 10 grs. of thk salt should decompose 10*24 grs. of (pure) nitrate of silver ; the precipitate is partly dissolved by ni trie acid, and partly altered in appearance, which is not the case when ammonia is added." (P. L) " Its solution is not affected, or only rendered hazj by solution of nitrate of baryta. A solution of i grs. in f § j of distilled water, precipitated by an ex- cess of solution of nitrate of silver, and then agita- ted in a bottle with a little water of ammonia, yields quickly j by subsidence, a clear supernatanl liquor, which is not altered by an excess of nitric arid, or is merely rendered hazy." (P. E.) Dose 2 to 20 grs. or more, 2 or 3 times a day, in pills oi solution, either alone or combined with iodine ; in bronchocele, scrofula, chronic rheumatism, dropsy, syphilis, and various glandular diseases. It is alsc used externally, made into a lotion or ointment. POU 485 POW POTASSIUM, PHOSPHURET. Obtained by gently heating phosphorus with potassium. POTASSIUM, SULPHURET OF. Syn. Liver of Sulphur. Sulphuret of Potash. He- par Sulphuris. Kali Sulphuretum, (P. L. 1788.) Potass* Sulphuretum, (P. L. 1809, 1824, and P- D.) Potassii Sulphuretum, (P. L. and E.) Prep. (P. L.) Sulphur §j; carbonate of potash jiv ; mix, and heat them in a covered crucible till they unite. *%* It dissolves in water, yielding a fetid yellow solution, and in acids evolving strong fumes of sulphureted hydrogen. Dose. 2 to 4 grs. in solution, or made into pills with soap ; in obsti- nate skin diseases. It is chiefly used externally made into a lotion, (1 to 2 drs. to the pint,) or an ointment, (30 grs. to the oz.) It is poisonous in large doses. %* Besides the above, there are other compounds of sulphur and potassium distin- guished by chemists. POTESTATES SUCCINI. Prep. Oil of am- Der ?j 5 sesquicarbonate of ammonia ^ss; alcohol £ pint; digest 4 days, and decant. Dose. 10 to 40 drops, externally, in hooping cough. POTION. Potus. POUDRE A LA MARESCHALLE. Prep. 1. Oak moss 2 lbs.; starch 1 lb.; cloves and cala- mus aromaticus, of each 1 oz.; Cyprus and rotten oak wood, of each 2 oz. ; all in fine powder ; mix, and pass through a sieve.—2. Starch powder 28 lbs.; powdered cloves J lb.; mix as last. POUDRE CLARIFICANTE. Powdered al- bumen. POUDRE DE CHIPRE. Prep. 1. Wash oak moss for 3 days in running water ; dry, powder, and perfume it once or twice with jasmine or musk rose flowers, then add other scent.—2. (Pou- dre de Chipre de Montpellier) Poudre de chipre, as last, 2 lbs.; musk 30 grs.; civet 18 grs.; the last two ground with a little sugar. POUDRE DE FLEURS D'ORANGES. Prep. Starch powder 25 lbs.; orange flowers 1 lb.; mix in a covered chest; stir 2 or 3 times a day, and repeat the process with fresh flowers a second and a third time. POUDRE DE FRANGIPANE. Prep. Pou- dre de fleurs d'oranges and poudre de chipre, of each 6 lbs.; essence of ambergris 1 oz.; civet powdered with sugar £ dr.; mix well. Ash gray. POUDRE DE JASMINE. As poudre de fleurs d'oranges, using jasmine flowers. POUDRE DE JONQUILLE. As the last, using jonquilles. POUDRE KUSIQUE. Prep. Nitre and sul- phur, of each 50 parts; powdered charcoal and antimony, of each 1 part; mix and divide into doses of 2 grammes, and put three doses in each packet. Given to dogs in a ball of butter, to pre- vent the disorders to which they are liable. A pop- ular French nostrum. POUDRE DE ROSES. Prep. 1. (Poudre de Roses communes.) As poudre de fleurs d'or- anges, but leaving the box open, and changing the flowers in 24 hours.—2. (Poudre de Roses Mus- quees.) As the last, but using musk roses and shutting the chest *%* All the above perfumed powders are used as cosmetics for the hair. POULTICE. Syn. Cataplasm. Cataplas- m. (Lat, from KarairXaaaria, to spread like a plas- ter.) Poultices are external applications used to promote suppuration, allay pain and inflammation, resolve tumors, &c. The following are the poul- tices of the pharmacopoeias:— POULTICE, CHARCOAL. -Syn. Cat. Car- bonis Ligni. Prep. (P. D.) Charcoal recently ignited and cooled in a close vessel, mixed with simple poultice. In fetid and gangrenous sores, frequently renewed. POULTICE, HEMLOCK. Syn. Cataplas- ma Conii. Prep. (P. L.) Extract of hemlock ^ij ; water 1 pint; dissolve and thicken with lin- seed meal. In painful nipples, cancer, glandular tumors, irritable sores, &c. POULTICE, LINSEED. Syn. Cat. Lini. Prep. (P. L.) Linseed meal made into a stiff paste with water. Used to promote suppuration. A little oil should be added, and some smeared over the surface as well, to prevent its getting hard. *#* For small gatherings, as of the finger, a little chewed bread and butter is an efficient and con- venient substitute. POULTICE, MUSTARD. Syn. Cat. Si- napis. Prep. (P. L) Equal parts of flour of mustard and linseed m«al, made into a poultice with hot vinegar. As a powertul countei-irritant, stimulant, and rubefacient; in low fevers, &c. It should not be left on long enough to raise a blister. POULTICE, YEAST. Syn. Cat. Fermenti. Prep. (P. L.) Flour lb. j ; yeast i pint; mix and apply a gentle heat till they begin to swell. In gangrenous or foul ulcers, &c. POUNCE. Powdered gum sandarach. (For Liquid pounce see Indelible Ink.) POWDER, ALOES. The powdered Socotrine aloes of the shops is mostly a factitious article made by grinding together equal parts of Cape and hepatic aloes. (See Aloes.) POWDER, ALOES, (COMP.) Syn. Pulvis Aloes compositus. Prep. (P. L.) Aloes §iss; guaiacum resin Jj j compound cinnamon powder §ss; powder and mix. Purgative and sudorific. Dose. 10 to 20 grs. POWDER, ANTIMONIAL. Syn. Fever Powder. James's do. Pulvis Antimonii comp. (P. L.) P. Antimonialis, (P. E. & D.) P. Jacobi. P. Febrifugus Jacobi. Prep. (P. L.) Sesqui- sulphuret of antimony lb. j ; hartshoru shavings lb. ij; powder, mix; throw them into a red-hot crucible, and stir constantly until vapor no longer arises ; cool, powder, put it into a crucible with a perforated cover, and calcine at a red heat for 2 hours ; reduce the residue to fine powder. Dose. 3 to 8 or 10 grs. as a febrifuge and diaphoretic, in fevers, rheumatic affections, and chronic skin diseases. It is a very uncertain and variable prep- aration. (See Antimonious Acid.) *#* A fac- titious article, made by adding 1 oz. of tartar emet- ic to 18 or 19 oz. of burnt hartshorn, is frequently sold in the shops for antimonial powder. POWDER, AROMATIC. Syn. Pulv. Aro- maticus. Prep. (P. E.) Cinnamon, cardamom seeds, and ginger, equal parts; powder and mix. Aromatic and carminative. Dose. 10 to 30 grs. POWDER, ASARABACCA. Syn. Pulv. Asari Comp. Prep. (P. D.) Asarabacca leaves Z\; lavender flowers oj ; both dried; mix and powder. Used as an errhiue in headache and oph- thalmia. (See Asarabacca Snuff.) POW 486 POW POWDER, BASILIC. Syn. Royal Powder. Pulv. Basilicus. Prep. Scammony, calomel, cream of tartar, and cerussa antimonii, (antimonic acid.) equal parts; powder and mix. The com- pound powder of scammony is now universally substituted. POWDER, CHALK, (COMPOUND.) Syn. Pulv. Cret* Comp., (P. L. E. & D.) Prep. (P. L.) Prepared chalk lb. ss ; cinnamon §iv; tor- mentil and gum acacia, of each §iij; long pepper S5SS ; powder and mix. Aromatic, astringent, and antacid ; in atonic diarrhoea. Dose. 10 to 30 grs. *#* The following form is used by many whole- sale houses: prepared chalk 4 lbs.; powdered cassia 2 lbs.; do. calamus aromaticus J lb.; do. gum 1 £ lbs.; long pepper \ lb.; mix. POWDER, CHALK, (WITH OPIUM.) Syn. Pulv. Cret* Comp. cum Opio, (P. L. & D.) Pulv. Cret* Opiatus, (P. E.) Prep. I. (P. L.) Com- pound chalk powder §viss ; powdered opium 9iv ; mix.—2. (Wholesale.) Compound chalk powder 214, oz., (avoird.;) powdered opium 3iv, (troy ;) mix. Dose. 10 to 30 grs. in diarrhoea. POWDER, CINNAMON, (COMPOUND.) Syn. Aromatic Powder. Pulv. Cinnamoni Comp. (P. L.) P. Aromaticus, (P. D.) Prep. (P. L.) Cinnamon 5'j ; cardamoms ^iss ; ginger §j ; long pepper %ss; powder and mix. Dose. 10 to 30 grs.; as an aromatic and carminative. *** In the powder of the shops cassia is almost universal- ly substituted for cinnamon. POWDER, COLOCYNTH, (PULP.) A fac- titious article is met with in trade, made by grind- ing bryony root 1 lb.; with colocynth seeds 3 lbs.; adding a very small quantity of gamboge. POWDER, CRYSTAL. From quartz, like Powdered Glass. Used to make glass and as a dryer for paints. POWDER, CURRIE. Syn. Indian Currie Powder. Prep. 1. Coriander seeds and black pepper, of each 8 lbs.; turmeric and cumin seeds, of each 4 lbs.; (all in powder,) mix. *** This receipt is employed by a wholesale house that does very largely in currie powder.—2. Coriander seeds li lb.; black pepper 3 oz.; cayenne do. 1 oz.; turmeric and cumin seeds, of each \ lb. ; fenu- greek seed £ oz.; mix.—3. To No. 1, add cayenne \ lb. Used as a sauce and condiment. POWDER, FILTERING. Pure clay or ful- ler's earth, dried by a gentle heat, and ground to powder. Used to filter and bleach oils. (See Filtration.) POWDER, FLY. Prep. White arsenic 4 oz.; white sugar 6 lbs.; rose pink 1 oz.; mix, and put 6 drs. in each paper. Used to kill flies. %* It is poisonous, and should be employed with great caution, especially where there are children. POWDER, ESCHAROTIC. Syn. Pulv. Escharotica Arsenicalis. Poudre Caustique du Freres Cosme ou de Rousselot. Prep. (P. Cod.) Findy powdered cinnabar and dragon's olood, of each 16 grs.; do. arsenious acid 8 grs.; mix Used to cauterize cancerous wounds, but should be applied with great caution, and only to a small surface. It is made into a paste with the saliva when used, and is hence called Arsenical Paste, (Pasta Arsenicalis.) POWDERS, GINGER BEER. Prep. Pow- dered white sugar 2 dr.; powdered ginger 5 grs.; carbonate of soda 26 grs.; mix, and wrap in blue paper ; tartaric acid 30 grs.; wrap in white paper For use dissolve each separately in half a glass of water, mix, and drink while effervescing. POWDER, HAIR. Starch powdered and sifted very fine, and scented at pleasure. (See Poudre.) POWDERS, INK. Prep. Aleppo galls 3 lbs.; copperas (dry but not calcined) 1 lb.; gum arabic 6 oz.; white sugar 2 oz.; all in powder; mix. *** 1 pint 0I" b°'l'ng water poured on 1£ or 2 oz., makes a pint of ink. POWDER, IPECACUANHA, (COM- POUND.) Syn. Dover's Powder. Pulv. Do- veri. P. Ipecacuanh* Comp., (P. L. E. & D.) Prep. 1. (P. L.) Powdered ipecacuanha and hard opium, of each 3j ; do. sulphate of potash §j; mix.—2. (Wholesale.) Powdered ipecacuanha and opium, of each 1 lb.; do. sulphate of potash b lbs.; mix. A powerful and valuable sudorific. Dose. 5 to 15 grs.; in inflammatory affections, rheumatisms, colds, &c. POWDER, JALAP, (COMP.) Syn. Pulv. Jalap* Comp. (P. L. E. &. D.) Prep. (P. L.) Jalap §iij ' cream of tartar §vj ; ginger 3ij ; all in powder; mix. Dose. 20 to 60 grs. as a purgative in habitual costiveness, dropsies, &.c. POWDER, KINO, (COMP.) Syn. Pulv. Kino Comp. Prep. (P. L.) Kino 3xv; cinna- mon §ss; hard opium 3j ; powder and mix well. Dose. 5 to 20 grs. in diarrhoea, &c. POWDER, MERCURIAL. Syn. Quick- silver with chalk. Hydrargyrum cum crsta, (P. L. E. & D.) Prep. I. (P. L.) Mercury §iij; prepared chalk %v ; triturate till the globules dis- appear. Dose. 5 to 30 grs. as a mild mercurial. *** " When pure, part is evaporated by heat; what remains is colorless, and totally soluble in acetic acid with effervescence ; this solution is not colored by sulphureted hydrogen. These sub- stances can scarcely be so diligently triturated that no globules shall be visible." (P. L.) As common- ly met with, this powder contains too little mercu- ry. When properly prepared, it effervesces when digested in cold dilute acetic acid, and the dark undissolved portion when dried should be equal to about § of the weight of the powder employed; it should also be totally dissipated by heat, without incandescence, and* readily and entirely soluble in nitric acid; when examined by the microscope it should exhibit minute globules of mercury unmixed with foreign matter. The Dublin Ph. orders pre- cipitated chalk. II. (Tyson.) Calomel %iv; liquor of potassa f §vj or q. s.; rub together, add liquor of ammonia 3ss, and again triturate; decant the clear, well wash and gently dry the bluish powder, and mix it with twice its weight of prepared chalk. Stronger than the former. III. (Mercury with Magnesia, Hydrargyrum cum Magnesia, P. D.) Mercury and manna, of each 8 parts; triturate together (adding enough water to make a paste) till the globules disappear, then add carbonate of magnesia 1 part, mix, and further add warm water 64 parts ; again well mix, and after repose decant the clear; repeat the washing with fresh water a second and third time, then add 3 parts more of carbonate of magnesia, mix well, and dry on bibulous paper. Uses and dose the same as of mercury and chalk. POW 487 POW IV. (Quicksilver and Sugar. Mercurius Sac- charatus) Quicksilver and white sugar, of each gj ; oil of tansy 3ss; triturate till the globules dis- appear. Dose. 3j, as a vermifuge. POWDER, PEARL, (COSMETIC.) Prep. Pure pearl white, (trisnitrate of bismuth) and French chalk scraped fine by Dutch rushes, equal parts , mix. Some add more French chalk. A skin cosmetic. This is preferable to pearl white alone, from being more adhesive. POWDER, PLATE. Prep.—l. Quicksilver with chalk 1 oz.; prepared chalk 7 oz.; mix.— 2. Polisher's putty, and burnt hartshorn, of each £ lb.; prepared chalk 1 lb. Used to clean and polish plate. POWDER, PLATE BOILING. Prep. Cream of tartar, common salt, and alum, equal parts; mix. A little of this powder, added to the water in which plate is boiled, gives it a silvery whiteness. POWDER, PLUMMER'S. Syn. ^Ethiops Plummeri. Prep. Calomel, and sulphuret of an- timony, equal parts. Alterative. POWDER, PORTLAND, (DUKE OF.) Syn. Pulv. Ducis Portlandi*. Prep. Roots of gen- tian and birthwort; tops and leaves of germander, ground pine, and lesser centaury, of each equal parts ; powder and mix. For gout. POWDER, RHUBARB, (COMP.) Syn. Gregory's Powder. Pulv. Rh*i Comp. Prep. (P. E.) Magnesia ftj. j ; rhubarb f iv ; ginger f ij ; all in fine powder; mix, and preserve it in a cork- ed bottle. An excellent antacid, stomachic, and mild purgative. Dose. 20 to 30 grs. POWDER, SCAMMONY, (COMPOUND.) Syn. Basilic Powder. Roval do. Pulv. Ba- silicus. P. Scammonii Comp., (P. L. E. and D.) Prep. 1. (P. L.) Scammony, and hard extract of jalap, of each fij ; ginger fss ; powder and mix. Dose. 10 to 20 grs.—2. (P. E.) Scammony, and bitartrate of potash, equal parts; triturate together to a very fine powder. Dose. 15 to 30 grs Both are used as cathartics in worms, especially for children. POWDERS, SCENT. Prep. 1. Corianders, orris root, rose leaves, and calamus aromaticus, of each 4 oz.; lavender flowers 8 oz.; rhodium wood 1 dr. ; musk 20 grs.; mix, and reduce to coarse powder.—2. Corianders, orris, calamus aromaticus, and red roses, of each 1 oz.; lavender flowers 2 oz.; mace and cloves, of each 1 dr.; essential oil of almonds 10 drops ; mix as last-j-3. As last, but substitute musk 3 grs. for oil of almonds. Used to fill scent bags, and for boxes, &c. POWDERS, SEIDLITZ. Prep. 1. Tartrate of soda 3ij ; carbonate of do. 3ij ; mix, and put it in a blue paper ; tartaric acid 35 grs., to be put in white paper. For £ pint of water, as ginger-beer powders. Laxative.—2. (In one bottle.) Tartrate of soda 12 oz.; carbonate of do. 4 oz.; tartaric acid 3£ oz.; white sugar 1 lb.; all in fine powder ; dry each separately by a gentle heat, add essence of lemon 20 drops; mix well, pass it through a Bieve, and put it at once into clean dry bottles. Dose. A dessert-spoonful to a glass of water. POWDER, SENNA. (Battley's Green.) Sen- na leaves uried and heated till they turn yellow, then powdered along with (blue) charcoal, q. s. to «ve a green color. POWDER, SILVERING. Prep. 1. Silver dust (fine) 20 grs.; alum 30 gre.; cream of tartar, and common salt, of each \ oz.; powder and mix. —2. Silver dust 1 oz.; common salt and sal am- moniac, of each 4 oz.; corrosive sublimate i oz.; mix as last. Used to silver copper previously well cleaned, by friction, adding a little water to form a paste. POWDERS, SODA. Syn. Effervescing Powders. Saline do. Aerated Soda do. Prep. Carbonate of soda 30 grs. in each blue paper ; tar- taric acid 25 grs. in each white paper ; dissolve each separately in £ of a glass of water, mix, and drink immediately. A cooling, wholesome sum- mer beverage. %* Midgeley's Soda Powders are made by adding £ of a grain of tartarized anti- mony to each paper of acid. Refrigerant and dia- phoretic. POWDERS, SPRUCE BEER. As ginger- beer powders, substituting essence of spruce 3 or 4 drops, for the powdered ginger. POWDER, TIN. Syn. Tin Filings. Grain Tin. Pulvis Stanni, (P. E. and D.) Prep. 1. (P. E.) Melt tin in an iron vessel, pour it into an earthenware mortar heated a little above its melt- ing point, and triturate briskly as the metal cools, then sift the product and repeat the process.—2. Pour melted tin into a wooden box, the inside of which is rubbed with chalk, and shake *• Gently till the metal is reduced to powder, then sift as be- fore. Dose. 2 to 4 drs., as a vermifuge. %* Pol- ishers' putty, colored with ivory black, is frequently substituted for this powder, and hence arise the ill effects that sometimes follow its use. POWDERS, TOOTH. Prep. 1. Red bark, and Armenian bole, of each 1 oz.; powdered cin- namon, and bicarbonate of soda, of each £ oz.; oil of cinnamon 2 or 3 drops ; all in fine powder; mix. (Lancet)—2. Substitute cassia for cinna- mon, and cream of tartar, carbonate of magnesia, or prepared chalk, for bicarbonate of soda.—3. (Grosvenor's) Rosepink 3 lbs.; orris powder £ lb.; oyster shells 2£ lbs.; oil of rhodium 25 drops ; as above.—4. (Asiatic dentifrice) Prepared red coral 8\ lbs.; Venetian red J lb.; ochre and pum- ice-stone, of each li lb.; China musk 30 grs. ; all in fine powder; mix.—5. (Hemet's dentifrice.) Cuttlefish bones 6 oz.; cream of tartar 1 oz.; or- ris root £ oz.; as last—6. (Ruspini's dentifrice.) Cuttlefish bones 8 oz.; roach alum and orris root, of each 1 oz.; cream of tartar 2 oz.; oil of rho- dium 6 drops ; as before. (See Cosmetics.) POWDER, TRAGACANTH, (COMPOUND.) Syn. Pulv. Tragacanth* CoMr., (P. L. and E.) Prep. (P. L.) Tragacanth, gum arabic, and starch, of each ^isa ; white sugar f iij ; powder and mix. Demulcent, and as a vehicle. POWDER, VERMIFUGE. Prep. 1. (Col- lier.) Powdered jalap and scammony. of each 3j; cream of tartar 3ij ; Ethiop's mineral 3iij ; mix. Dose. 10 to 20 grs., for children.—2. (E. H.) Scammony and calomel, of each 3j ; rhubarb 3iij ; all in fine powder ; mix. Dose 15 to 30 grs. or more. POWDER, VIOLET. Prep. 1. Powdered starch 28 lbs.; do. orris root 1 lb.; essence of ber- gamotte i oz.; oil of rhodium £ dr.; mix and pass through a sieve.—2. Powdered starch scented with a little bergamotte. Used as a dusting powder in excoriations, and for children. PRA 488 PRI POWDER, WARWICK, (EARL OF.) Syn. Pulv. Comitis Warwicensis. Prep. Scammony 4 oz.; diaphoretic antimony 2 oz.; cream of tar- tar 1 oz.; all in fine powder; mix. POX, CHICKEN. Syn. Waterpox. Vari- cella. (Dim. of Variola.) An eruptive skin disease, consisting of smooth vesicles of various sizes, which afterwards become white and straw colored, and about the fourth day break and scale off. In hot weather the discharge sometimes be- comes purulent, and at others the eruption is at- tended with considerable fever. The treatment consists in the adoption of a light vegetable diet, and in the administration of mild aperients and cooling drinks. POX, COW. Syn. Vaccinia. Variola Vac- cina. This disease was proposed as a substitute and preventive of smallpox, by Dr. Jenner in 1798. The success which has followed its artificial pro- duction has nearly led to the extinction of small- pox in England. The process of vaccination is similar to that of inoculation for the smallpox, be- fore noticed. About the third day the puncture usually becomes red and elevated, and continues to enlarge and become vesicular, until at about the 8th or 9th day, it is at its height, and the vesicle is surrounded with a florid areola. About the elev- enth or twelfth day these symptoms decline ; the centre of the pustule becomes brown, and a dark scale gradually forms and separates, leaving the arm as heretofore. This disease seldom requires medical treatment; but should febrile symptoms come on, an aperient may be given. POX, SMALL. Syn. Variola. (From va- rius, changing color, because of its action on the skin.) This disease comes on with the usual symp- toms of inflammatory fever. About the third day, red spots, resembling flea bites, make their appear- ance on the face and head, and gradually extend over the whole body. About the fifth day small circular vesicles, depressed in the centre, surround- ed by an areola, and containing a colorless fluid, begin to form, when the feverish symptoms abate ; about the sixth day the throat becomes sore ; about the eighth day the face is swollen, and about the eleventh day the pustules acquire the size of a pea, and cease to enlarge, the matter which they con- tain becomes opaque and yellow, a dark central spot forms on each, the swelling of the face sub- sides, and secondary symptoms of fever come on ; the pustules become rough, break and scab over, and a dark spot remains for some days, often fol- lowed by permanent indentation. At the end of the sixteenth or eighteenth day, the symptoms usually disappear. In the confluent smallpox, the pustules coalesce, the eruption is irregular in its progress, and the inflammatory symptoms are more severe. The treatment of ordinary cases of small- pox resembles that mentioned above for chicken- pox. When great irritability exists, small doses of morphia, opium, or camphor, maybe administered, and obstinate vomiting arrested by effervescing sa- line draughts. The application on the third day of a mask formed of thick muslin, covered with mercurial ointment, and having holes cut out for the nostrils, eyes, and mouth, will effectually pre- vent " pitting." (Dr. Stewardson.) Gold leaf is also applied for the same purpose. PRADIER'S CATAPLASM. Prep. Balm of Mecca 3vj ; rectified spirit of wine $xvj ; dis- solve ; red cinchona bark, sarsaparilla, and sage, of each ^j *> saffron ^as; rectified spirit of wine ^xxxij ; digest for 4* hours, filter, mix tho two li- quors, and add twice their weight of lnne water. In gout, f ^ij sprinkled on the surface of a hot linseed- meal poultice sufficiently large to surround the af- fected part. *** The Emperor Napoleon gave £2500 for this receipt. PRECIPITATE, GREEN. Syn. Mercu- rius Pr*cipitatus Viridis. Lacerta Viridib Prep. Quicksilver §j; nitric acidf^iss; dissolve; copper Jj; nitric acid f Jj ; water f §iss ; dissolve ; mix the solutions, evaporate to dryness, and cal cine till red fumes cease to arise. Caustic. PRECIPITATE, WHITE. Syn. Cosmetic Mercury. Ammoniated Mercury. Muriate of Ammonia and Mercury. Ammoniated Submuri- ate of Mercury. Ammoniacal Oxychloruret of do. Chloramide of do. Chloro-amidide of do. Mercurius Pr*cipitatus Albus, (P. L 1745.) Calx Hydrargyri Alba, (P. L. 1788.) Hydrargyrus Pr*cipitatus Albus, (P. L. 1809.) Hydrargyrum Pr*cipitatum Album, (P. L. 1824, &, P. E.) Hydrargyri Ammonio Chloridum, (P L. 1836.) Hydrargyri Submurias Ammoniatum, (P. D.) Prep. I. (P. L.) Bichloride of mercury §vj ; distilled water 3 quarts; dissolve, and add liquor of ammonia f gviij; wash and dry the pre- cipitate. II. Corrosive sublimate and sal ammoniac, of each §vij ; dissolve in water 3 quarts, and precipi- tate with liquor of potassa. Some use only 4 oz. of sal ammoniac. Remarks. A white, inodorous solid or powder, insoluble in alcohol, partially soluble in boiling wa- ter, and wholly dissolved by sulphuric, nitric, and muriatic acids, without effervescence. It is " to- tally dissipated by heat. Digested with acetic acid, it yields no yellow or blue precipitate with iodide of potassium. Its powder triturated with lime wa- ter does not become black. When heated with so- lution of potash it exhales ammonia, and assumes a yellow color." (P. L.) Used to make an oint- ment, in various skin diseases, &c. PRESERVES AND PRESERVING. (See Fruits, Jellies, Jams, Marmalades, Conserves, &c.) PRINTING INK. Syn. Encre dTmprimkm**, (Fr.) Buchdruckerfarbe, (Ger.) Prep.—1. The varnish. .10 or 12 gallons of linseed oil are set over the fire in an iron pot, capable of contain- ing at least as much more, to allow of its swelling up without running over. When it boils it is kept stirred with an iron ladle, and if it does not take fire of itself soon after the smoke begins to rise, it is kindled by means of a piece of burning paper, stuck in the cleft end of a long stick. The pot is then shortly afterwards removed from the fire, and the oil is suffered to burn for about half an hour, or till a sample of the varnish cooled upon a pallet knife, may be drawn into strings of about half an inch long, between the fingers. The flame is now ex- tinguished by the application of a closely-fitting tin cover, and as soon as the froth of the ebullition has subsided, black rosin is added, in the proportion of 6 lbs. to every 6 quarts of oil thus treated; the mixture is next stirred until the rosin is dissolved, when If lbs. of brown soap, cut into slices, is fur- PRO 489 PRU ther added, (cautiously) and the ingredients are' again stirred with the spatula until united, the pot being once more placed over the fire to promote the combination. When this is effected, the var- nish is removed from the heat, and after thorough stirring, covered over and set aside. *** It is ne- cessary to prepare two kinds of this varnish, vary- ing in consistence, from more or less boiling, to be occasionally mixed together as circumstances may require; that which answers well in hot weather being too thick in cold, and vice versa. Large characters also require a thinner ink than small ones. A good varnish may be drawn into threads like glue, and is very thick and tenacious. The oil loses from 10 to 13g by boiling.—2. Making the Ink. a. (Black.) Finely-powdered indigo and Prussian blue, of each 2£ oz.; best mineral lamp- black 4 lbs.; do. vegetable lampblack 3£ lbs.; put them into any suitable vessel, and mix in gradually the warm varnish. The mixture must now be submitted to careful grinding, either in a mill or with a slab and muller. Oil the large scale steam power is employed for this purpose.—b. (An ex- temporaneous superfine ink.) Balsam of copaiba (pure) 9 oz.; lampblack 3 oz.; indigo and Prus- sian blue, of each 5 dr. ; Indian red £ oz.; yellow soap (dry) 3 oz.; grind to an impalpable smooth- ness. Canada balsam may be substituted for bal- sam of copaiba where the smell of the latter is ob- jectionable, but it dries quicker. Remarks. Old linseed oil is preferable to new. Yellow rosin soap is preferred for black and dark colored inks, and white curd soap for light ones. Vegetable lampblack takes the most varnish. The addition of indigo and Prussian blue is to correct the brown color of the black. The Indian red is added to increase the body and richness of the co- lor. Some persons find much trouble in grinding up the indigo, from its running into a mass and clogging the mill ; but this may be avoided by mixing it as above, or by first grinding it with a sufficient quantity of Canada balsam or copaiba, and using a proportionate quantity of varnish, and that of a little thicker cousistence. The French employ nut oil instead of linseed. Mr. Savage ob- tained the large medal of the Society of Arts for his black ink made as above. It is unrivalled. *#* Colored inks are made in a similar way. The pigments used are—Carmine, lakes, vermilion, chrome red, red lead, orange red, Indian red, Ve- netian red, orange chrome, chrome yellow, burnt terra di sienna, gall stone, Roman ochre, yellow do., verdigris, Scheele's green, Schweinfurth's do., blues and yellows mixed for greens, indigo, Prus- sian blue, Antwerp do., cobalt do., charcoal do., lustre, umber, sepia, &c. &c. (See Savage's " Prep- aration of Printing Ink," and the " Encyclo- p*dia Britannica.") PRINTS, ACKERMAN'S LIQUOR FOR. Prep. Best pale glue and white curd soap, of each 4 oz.; hot water 3 pints ; dissolve, then add pow- dered alum 2 oz. Used to size prints and pictures before coloring them. PROMETHEANS. Prep. Chlorate of potash ana loaf sugar, equal parts; vermilion to color; powder each separately, mix, and make a stiff paste with a weak solution of gum arabic. This paste is divided into small pieces. A number of email oval glass beads are now made from a small thin glass tube by means of a candle, one end of which is closed while soft. These are dipped while still hot into sulphuric acid, and the open end is then closed by having the flame directed upon it by a blowpipe. A slip of paper 2 inches long and 1 wide is next taken, and one of the corners cut off. A little gum arabic is applied, and the paper is rolled into a small cylinder, leaving a hollow at the gummed end. Into this hollow, one of tho glass beads, surrounded with a little of the red mix- ture, is then gently squeezed with the fingers, and finished off by smoothing the external surface with the finger moistened with gum water. The whole is now dried. Used to procure a light. The bead containing the oil of vitriol at the loaded end is broken by a smart blow, and on coming into con- tact with the chlorate mixture, causes it to barst into flame. %* The bead and red paste togethei should not be larger than a barley corn. (See Chlorate Matches.) PROTEINE, (from trpwrtuoi, / take the first place, because it is the original matter from which albumen, caseine, and fibrine are derived.) A compound of carbon, hydrogen, nitrogen, and oxy- gen, discovered by Mulder. It is obtained when albumen, caseine, or fibrine is dissolved in lr-^der- ately strong liquor of potassa, the solution heated for some time to 120°, and acetic acid added ; a gelatinous precipitate forms, which, after being washed and dried, is proteine. It is insoluble in water and alcohol. With sulphuric acid it forms sulphoproteic acid, and with chlorine, chloropro- teic acid. When digested in nitric acid xantho- proteic acid is formed along with ammonia and oxalic acid. *#* Proteine is produced by vegeta- bles alone, and cannot be formed by animals, al- though the animal organism possesses the power of converting one modification of proteine into an- other, fibrine into albumen, or rice versa, or both into caseine. Vegetable albumen, caseine, and fibrine, are therefore the only sources of proteine for ani- mal life, and consequently of nutrition, strictly so called, or the growth in mass of the body. (Lie- big, Animal Chem. p. 106.) PRUSSIAN BLUE. Syn. Berlin Blue. Prussiate of Iron. Ferro-prussiate of do. Cyanuret of do. Ferro-cyanide of do. Per- cyanide of do. Sesquiferrocyanide of do. Cyanure ferroso-ferrique, (Berzelius.) Eisen- blauseLures eisenoxyd ; Berlinerblau, (Ger) Bleu de Prusse ; Prussiate de Fer, (Fr.) Fer- ri percyanidum, (P. L.) Do. Cyanuretum, (P. D.) Do. ferro-sesquicyanidum. Prep. I. Pre- cipitate the crude but clear solution of prussiate of potash (blood lye) by a mixed solution of 2 parts of alum, and 1 part of green sulphate of iron. The dingy green precipitate that falls, gradually becomes blue by absorption of atmospheric oxy- gen, which is promoted by exposure and agitation of the liquor. As soon as it has acquired its full color, the whole must be allowed to repose, the clear portion decanted, and the sediment repeated- ly washed with water, drained, and dried, at first in a stove, but afterwards on chalk stones. II. Partly saturate the free alkali in the crude lye, with dilute sulphuric acid, before precipitation. Very superior. III. Repeatedly digest and wash the precipitate obtained by either of the above processes, in verj PRTJ 490 PRU dilute muriatic arid, and then in pure water; drain and dry. Superior. IV. (Paris Blue) Neutralize the solution of prussiate of potash above, with dilute sulphuric acid, and precipitate with a solution of any persalt of iron, (as the persulphate, nitrate, sesquichloride, or peracetate;) well wash, and dry the precipi- tate. A very rich and intense color. V. (Hochstatter.) Crystallized prussiate of pot- ash and green vitriol, of each 6 parts; dissolve each separately in water 15 parts; then add oil of vitriol 1 part; fuming muriatic acid 24 parts; agitate well. After some hours,, treat the whole with chloride of lime 1 part, dissolved in water 80 parts, and strained, observing to stop the addition of the latter solution as soon as an effervescence from the escape of chlorine gas is observed ; after standing some hours, thoroughly wash the precip- itate, and dry it; or; instead of the above, at once wash the precipitate in dilute nitric acid, till it ac- quires a deep-blue color. Product. Of the finest quality. Remarks. The object of employing alum is to prevent or lessen the precipitation of oxide of iron by the free alkali in the blood lye, but a portion of alumina is in consequence thrown down with the blue, and tends to render it paler, and increase the product. The same purpose is effected by neutralizing the alkali with dilute sulphuric acid, and omitting the alum from the precipitating solu- tion ; but in this case, if green copperas is em- ployed, it will be necessary to treat it with very dilute muriatic acid, to remove the excess of per- oxide of iron, before the precipitate acquires its full richness of color. The quantity of alum em- ployed may be varied according to the shades of the intended blue. The quality of Prussian blue may be estimated by its color, and by the quanti- ty of potash or soda required to destroy its blue color. If it effervesces with acids, it contains chalk ; and if it forms a paste with boiling water, it is adulterated with starch. It is pure, if, " af- ter being boiled with dilute muriatic acid, ammo- nia throws down nothing from the filtered liquid." (P. L.) It has been occasionally used in medi- cine, but is principally employed as a pigment It is purgative, and not poisonous. *#* Prussian blue is distinguished from indigo by exhibiting a coppery tint when broken, but which is removed by rubbing with the nail. PRUSSIATE OF POTASH. Syn. Ferro- prussiate of Potash. Triple do. do.- Ferru- reted hydrocyanate of do. ferrocyanate of do. Ferrocyanide of Potassium. Cyanure fer- roso-potassique, (Berzelius.) Ferrocyanure de Potassium ; Prussiate jaune de Potasse, (Fr.) Kalium eisencyanur; Cyaneisen Kaliu.m, (Ger) Potassii FERROCYANIDUM, (P. L. & E.) Prep. I. Dried blood, horns, or hoofs, 5 parts ; good pearl- ash 2 parts ; both reduced to coarse powder, mix, and inject into an egg-shaped iron pot in a state of moderate ignition ; stir well with an iron spatu- la, so as to prevent it running together, and con- tinue the calcination till fetid vapors cease to be evolved. During the latter part of the process, the pots should remain covered, and only occasion- ally stirred. The calcination is known to be fin- ished when flame is no longer seen on stirring the mixture. When this is the case, remove the pasty i "mass with an iron ladle, and when cold, dissolve in water; filter or defecate, and evaporate, that crystals may form on cooling ; redissolve in hot water, and cool very slowly, when large and beau- tiful yellow crystals will be deposited. %* The greaves obtained from the tallow-chandlers are employed as an economical substitute for horns or blood, by one of the largest Scotch manufactur- ers ; but blood is the best where it can be pro- cured, and after that, horns and hoofs. II. (L. Thompson.) Potash or pearlash, and coke, cinders, or coal, of each 10 parts; iron turn- ings 5 parts ; all in coarse powder; mix, and ex- pose for half an hour to a full red heat in an open crucible, stirring occasionally till small jets of pur- ple flamo are no longer seen, then cool, dissolve out the soluble matter, and proceed as above. If this solution be precipitated by sulphate of iron, and the precipitate brightened by muriatic acid, as before described, 25$ of the weight of the pure potash employed, will be obtained in Prussian blue. III. (Pure.) Fuse effloresced commercial prus- siate of potash in a glass vessel, dissolve in water, neutralize with acetic acid, precipitate with strong alcohol, wash the precipitate with a little weak al- cohol, redissolve in water, and crystallize. Remarks. The yellow -,-ussiate of potash is chiefly used in dyeing and calico printing, and in chemistry, as a test and a source of prussic acid When pure, it is totally dissolved by water; loses 12*6$ of its weight by a gentle heat; scarcely, if at all, alters the color of turmeric ; is precipitated deep blue by the sesquisalts of iron, and white by zinc; its ashes dissolved by muriatic acid, are again thrown down by ammonia ; it yields 18*7$ of sesquioxide of iron. (P. L.) *1f* Ferrocya- nide of Iron precipitates solutions of antimony, bismuth, protoxide of mercury, and zinc, white— Cadmium, pale yellowish white—Protoxide of ce- rium, white, soluble in acids—Protoxide of copper, white, changing to red—Protoxide of iron, white, rapidly turning blue—Lead, white, with a pale yellowish cast—Protoxide of manganese, white, rapidly passing into peach or blood-red—Peroxide of mercury, white, turning blue—Oxide of nickel, white, turning green—Silver, white, turning brown in the light—Protoxide of tin, white, (gelatinous) Cobalt, green, turning reddish gray—Peroxide of copper, brown-red—Peroxide of iron, dark blue— Deutoxide of manganese, greenish gray—Molyb- denum, dark brown—Protoxide of palladium, green, (gelatinous)—Tantalum, burnt yellow— Peroxide of tin, yellow, (gelatinous)—Uranium, reddish brown, t^t Red PHussiate of Potash (ferridcyanide of potassium) is distinguished by precipitating solutions of bismuth, (pale,) cad- mium, perofide of mercury, and zinc, (deep,) of a yellow color—Protoxide of mercury—Cobalt, (dark)—Protoxide of copper, molybdenum, silver, and uranium, reddish brown—Peroxide of copper, greenish yellow—Protoxide of iron, blue—Man- ganese, brown—Nickel, yellowish and green— and protoxide of tin, white. It does not affect so- lutions of peroxide of iron. PRUSSIC ACID. Hydrocyanic Acid. Aci- dum hydrocyanicum. Prep. I. Anhydrous, a. (Liebig.) Pure crystallized ferrocyanide of potas- sium 15 parts; water and sulphuric acid of eacb PRU 491 PRU 9 parts; distil in a glass retort into a well-cooled receiver, containing chloride of calcium in coarse fragments, 5 parts; stop the process as soon as the chloride in the receiver is perfectly covered by the distilled fluid, and decant the acid into a bottle furnished with a good stopper. Keep it in the dark, with the bottle inverted. 6. (Gay-Lussac.) Treat bicyanide of mercury with strong hydro- chloric acid, and pass the vapor first over carbon- ate of lime, and then over chloride of calcium. II. Dilute, a. (Acidum Hydrocyanicum di- lutum) Sulphuric acid § iss ; water f ^iv; mix in a glass retort, cool, add ferrocyanide of potas- sium gij ; dissolved in water £ pint, and distil f §yj uito a well-cooled receiver, containing f ^vrij of water ; lastly, add f ^vj of water more, or as much as may be sufficient, so that a solution of 12*7 grs. of nitrate of silver may be accurately saturated by 100 grs. of the acid. Contains 2g of real acid. 6. (Everitt.) Cyanide of silver 48£ grs.; distilled water f §j ; mix, add 39£ grs. of muriatic acid, agitate, and decant the clear into another vial. (P. L.) Contains 2§ of pure acid. c. (P. D.) Bi- cyanide of mercury ^j' muriatic acid f 3vij ; wa- ter f ^viij; distil f ^viij. Sp. gr. 0-998. Contains 1-6°, of pure acid. d. (Laming.) Cyanide of po- tassium 22 grs.; water f 3vj ; dissolve, add crys- tallized tartaric acid 50 grs., dissolved in rectified spirit f3iij; shake well together, and decant the clear: f3j contains 1 gr. of pure acid. e. (P.E.) Similar to the P. L., but contains 3-23°; of pure arid. /. (Dr. Clark.) Tartaric acid 1 part; wa- ter 40 parts ; dissolve, add 2§ parts of pure cya- nide of potassium, agitate, and decant. Contains 3°- of pure acid, and a little bitartrate of potash. g. (Majendie.) Pure anhydrous acid f ^j; water f §vj, (or 1 to 8£ by weight.) Contains 12$ of pure acid, or 6 times as strong as that of the P. L. h. (Winckler.) Powdered crystals of prus- siate of potash (pure) 120 grs.; solution of pure phosphoric acid (sp. gr. 1-25) 240 grs.; alcohol of 80g, 480 grs.; mix in a retort connected with a receiver containing 120 grs. of rectified spirit of wine, infuse for 24 hours, with occasional agita- tion, and then distil, adding to the distilled liquid sufficient alcohol to make it up to exactly 1£ or Contains 2g of pure acid. i. (Dr. R. D. Thomson.) Dilute sulphuric acid (P. L.) f3ij ; distilled water f3vj; mix, cool, add pure cyanide of lead 43*36 grs.; agitate well, and decant the clear. Con- tains 2°; of pure acid. k. (Scheele.) Prussian blue (pure) ^ij > red oxide of mercury §vj; distilled water f Jyj; boil till the blue turns green, wash the sediment with hot water f 3;x ; pour the liquid upon clean iron filings 3iij; add oil of vitriol 3j; pour the liquid from the quicksilver that has sepa- rated, and distil ^th. The strength of the product varies. An acid of 4% is usually sold under this name ; but the acid prepared as above is generally much stronger. Remarks. Pure anhydrous prussic acid is a most deadly poison ; 1 or 2 drops, either swallowed or applied to the skin, being sufficient to cause speedy death: even its vapor has a like effect. Dilute prussic acid has been taken with apparent advantage in chronic coughs, phthisis, and some other diseases. The dose of the acid (P. L.) may be from 2 to 5 minims 3 or 4 times a day, made into a mixture with water flavored with gum or sirup. It is also used externally in some skin diseases. *** Prussic acid, even when dilute, is very liable to spontaneous decomposition, and this speedily occurs when it is exposed to the light To promote its preservation, it is usual to sur- round the bottles containing it with thick purple paper, and to keep them inverted in an obscure situation. The addition of a very small quantity of muriatic arid renders it much less liable to change, and is generally made by manufacturers for that purpose. But in testing the strength of such acid by nitrate of silver, it is necessary to deduct the weight of the chloride of silver from that of the mixed precipitate. The cyanide of silver is soluble in a concentrated 6o)ution of nitrate of silver, and also in boiling nitric acid; but the chloride is insoluble in either of those menstrua. For estimating the strength of the commercial acid the following plan, proposed by Dr. Ure, will be found very exact and convenient, and may be used as a check to the above:—To 100 grains, or any other convenient quantity of the arid contained in a small vial, add in suc- cession, small quantities of the peroxide of mer- cury in fine powder, till it ceases to be dissolved on agitation. The weight of the red precipitate taken up being divided by four, gives a quotient representing the quantity of real prussic acid present. By weighing out beforehand, on a piece of paper or a watch-glass, 40 or 50 grains of the peroxide, the residual weight of it shows at once the quantity expended. The operation may be always completed in five minutes, for the red pre- cipitate dissolves as rapidly in the dilute prussic acid, with the aid of slight agitation, as sugar dis- solves in water. Should the presence of muriatic acid be suspected, then the difference in the vola- tility of prussiate and muriate of ammonia may be had recourse to with advantage ; the former exhaling at a very gentle heat, the latter re- quiring a subliming temperature of about 300° F. After adding ammonia in slight excess to the prussic acid, if we evaporate to dryness at a heat of 212°, we may infer from the residuary sal ammoniac the quantity of muriatic acid present Tests.—1. It is distinguished by a strong odor of bitter almonds.—2. Neutralized by potash, and tested with a solution of sulphate or tincture of iron, it gives a blue precipitate, or one turning blue on the addition of dilute sulphuric or muriatic acid—3. Nitrate of silver gives a white precipi- tate, soluble in boiling nitric acid.—1. Super- saturated with potash, it gives a greenish blue precipitate with sulphate of copper, which is turn- ed white by the cautious addition of muriatic acid.—5. Tincture of guaiacum gives a white precipitate, and when a few drops of solution of sulphate of copper are added, a blue color is pro- duced, which is heightened by adding alcohol. (Pagenstecher.)—6. In cases of poisoning, if the above tests cannot be applied, the contents of the stomach may be introduced along with a little sulphuric acid into a retort, and distilled, and the reagents applied to the distilled liquor. Ant.__1. Chlorine water, or solution of chloride of lime or soda, in doses of 2 or 3 spoonfuls diluted with water, frequently; also apply it externally.—2 PUN 492 PUT Small quantities of ammonia water diluted with 10 or 12 parts of water; also the fumes inhaled.—3. The joint administration of carbonate of potash and sulphate of iron. This has been lately very strongly recommended. %* Cold affusion should be adopted in all cases, and is almost of itself a certain cure, if employed before the convulsive stage is over; and it is often successful even during the stage of insensibility and paralysis. (Herbst) Artificial respiration should also be at- tempted. Unfortunately the poisonous action of prussic acid is so rapid that life is usually extinct before antidotes can be applied. PUFF PASTE. Take a quarter of a peck of flour, and rub into it a pound of butter very fine. Make it up into a light paste with cold water, just stiff enough to work well. Next lay it out about as thick as a crown-piece ; put a layer of butter all over, then sprinkle on a little flour, double it up, and roll it out again. Double and roll it with layers of butter three times or more, and it will be fit for use. By repeating this pro- cess 10 or 12 times, a very light paste will be formed. Bake in a moderately quick oven. PULVERIZATION OF SALTS. Many salts which are pulverized with difficulty, and do not dissolve in spirit of wine, are easily transform- ed into a fine powder, by agitating their concen- trated aqueous solution with a considerable quan- tity of spirit of wine; the disengaged fine crys- tallized powder may then be dried, and further divided by trituration. (Du Menil.) A large number of salts may also be reduced to coarse powder by keeping their solutions in a state of constant agitation during the evaporation. PUNCH. Prep.—l. Juice of 3 or 4 lemons ; yellow peel of 1 or 2 lemons; lump sugar | lb.; boiling water 3£ pints ; infuse £ an hour, strain, add porter £ pint; rum and brandy, of each £ to 1 pint, (or either alone 1£ to 2 pints,) and add more warm water and sugar, if desired weaker or sweeter.—2. (Cold Punch.) Arrack, port wine, and water, of each 1 pint; juice of 4 lemons ; white sugar 1 lb.; mix.—3. (Gin Punch.) Yel- low peel and juice of 1 lemon ; gin £ pint; water 1J pints ; sherry 1 glass ; mix.—(Iced Punch) Champagne or Rhenish wine 1 quart; arrack 1 pint; juice and yellow peels of 6* lemons ; white sugar 1 lb.; soda water 1 or 2 bottles; ice as cream.—4. (Milk Punch or Verder) Yellow rinds of 2 dozen lemons ; steep for 2 days in rum or brandy 2 quarts ; then add spirit 3 quarts more; hot water 3 quarts ; lemon juice 1 quart; loaf sugar 4 lbs.; 2 nutmegs, grated ; boiling milk 2 quarts ; mix, and in 2 hours strain through a jelly tag.—5. (Norfolk Punch.) French brandy 20 quarts; yellow peels of 30 oranges and 30 lemons; infuse for 12 hours ; add 30 quarts of cold water, 15 lbs. of lump sugar, and the juice of the oranges and lemons ; mix well, strain through a hair-sieve, add new milk 2 quarts, and in 6 weeks bottle. Keeps well.—6. (Orange Punch.) As No. 1, using oranges, and adding a little orange wine. A little Curacoa, Noyeau, or Mareschino, improves it.—7. (Raspberry Punch) As last, but using raspberry juice or vinegar for oranges or lemons.—8. (Regent's Punch) Strong hot green tea, lemon juice, and capillaire, of each 1 £ pints ; rum, brandy, arrack, and Curacoa, of each 1 pint; Champagne 1 bottle ; mix, and slice a pine-apple into it—9. (Tea Punch.) Hot tea 1 quart; arrack £ bottle; white sugar 6 oz.; juice of 8 lemons; yellow rinds of 4 lemons; mix.—10. (Wine Punch) Sugar 1 lb.; yellow peel of 3 lemons ; juice of 9 lemons; arrack 1 pint; port or sherry wine (hot) 1 gallon; cinna- mon i oz.; nutmeg 1 dr.; mix. *%* All the above are pleasant intoxicating beverages. (See Shrub.) PURL. Prep. To warm ale or beer add bitters 1 wine-glassful, or q. s. Some add spirit. PURPLE OF CASSIUS. Syn. Purple Pre- cipitate. Cassius' do. Gold Purple. Pourpre de Cassius, (Fr.) Gold-purpur, (Ger.) Aurum stanno paratum, (P. Cod.) Purpura mineralib Cassii. Prep. I. Crystallized protochloride of tin 1 part; crystallized perchloride of tin 2 parts ; dis- solve each separately, mix, and add it to a solution of crystallized terchloride of gold 1 part; wash, and dry the precipitate. Very fine. II. (Frick.) Dissolve tin in cold dilute aqua re- gia, till the fluid becomes faintly opalescent, then take the metal out and weigh it; dilute largely with water, and add simultaneously a dilute solu- tion of gold and dilute sulphuric acid, in such pro- portion, that the tin in the one shall be to the gold in the other, in the ratio of 10 to 36. III. Silver 150 parts; gold 20 parts; tin 35*1 parts; fuse together under charcoal and borax, cool, laminate, and dissolve out the silver with ni- tric acid. Used as a purple in porcelain painting, and to communicate a ruby red color to glass, when melted in open vessels. PURPURINE. A coloring principle found by Robiquet and Colin in madder. It dissolves in al- cohol, ether, and water, and solutions of alum and alkalis. It is also called madder purple. PUTREFACTION. Syn. Putrefactio. (Lat, from putrefacio, I make rotten.) The spontane- ous decomposition of animal and azotized vegeta- ble substances, under the joint influence of warmth, air, and moisture. The solid and fluid matters are resolved into gaseous compounds and vapors, which escape, and earthy matters which remain. The most striking characteristic of this species of fer- mentation or decay, is, the ammoniacal or fetid exhalations that accompany it. We have already noticed some of the most useful antiseptic process- es, (see p. 62,) and shall therefore merely observe here, that putrefaction may be prevented by the abstraction or exclusion of any of the conditions essential to its occurrence. This may be effected by—reduction of temperature,—exclusion of at- mospheric air, or—the abstraction of moisture. Frozen meat may be preserved for an unlimited period, while the same substance will scarcely keep for more than a few days at the ordinary heat of summer. Animal substances will also re- main uninjured for a long period if kept in vessels from which the air is entirely excluded, as in the process which is described below. The third con- dition is fulfilled when azotized matter is preserved in alcohol or in any similar fluid, or is dried. In either case water is abstracted from the surface, which then loses its propensity to putrefy, and forms an impervious layer, which excludes atmo- spheric oxygen from the interior and softer portion of the substance. Creosote, alcohol, tl* tcids, and PYR 493 PYR some of the salts, act in the latter way. One of the commonest methods of effecting this purpose, is to immerse the substance in alcohol of 60 to 70$, to which some camphor, ammonia, or common salt may be added ; but a cheaper and equally I efficient plan, is to employ a weak spirit holding a I little creosote in solution ; a solution of sulphurous acid may be substituted for alcohol. Meat im- ' mersed for 1 hour in water holding T^th part of creosote in solution, may be preserved unchanged, even during summer. In Messrs. Donkin and Gamble's patent process, the substances, previous- ly parboiled, are placed in small tin cylinders, which are then filled up with rich soup; the lids are next soldered on quite air-tight, and a small hole afterwards made in the centre ; the cylinders are then placed in a bath of brine, and heated to the boiling point, to complete the cooking process, when the hole in the lid is hermetically sealed, by soldering while the vessel still remains boiling hot. The ends of the tins on cooling assume a concave form from the pressure of the atmosphere, without which they cannot be air-tight. The patentees expose the canisters prepared as above for at least a month to a heat of 100 to 110°, when if the pro- cess has failed, putrefaction commences, and the ends, instead of remaining concave, bulge and be- come convex. This is called the " test." This process was invented by M. Appert in France. Fish, flesh, and poultry may be thus preserved for years in any climate. (See Fermentation, Ani- mal Substances, Anatomical Preparations, &c.) PUTTY, GLAZIER'S. Whiting worked up with drying oil. PUTTY, POLISHER'S. Syn. Potee d'Etain. Calcine. Cineres Stanni. Prep.—1. Melt tin, rake off the dross as it is formed, and calcine this dross till it becomes whitish.—2. Melt tin 1 oz. with an equal weight, or 1£ oz. of lead, and then raise the heat so as to render the mixed metal red hot, when the tin will be immediately flung out in the state of putty. Both are very hard, used for polishing glass and japan work, and to color opaque white enamel. PUZZOLANA. A volcanic ash found at Pom- peii, Vesuvius, &c. Mixed with lime it forms an excellent hydraulic cement. A good artificial puz- zolene may be made by heating a mixture of 3 bushels of clay and 1 bushel of slaked lime, for some hours, to redness. (M. Bruyere.) PYRETHRIN. An acrid resinous principle extracted by alcohol and ether from the bark and root of pellitory of Spain, (anthemis pyrethrum) It is also soluble in acetic acid. PYROACIDS. (From ™p, fire.) This term is applied to several acids that are obtained by the action of heat on other acids.—Pyiiocitric Acid, (Citricic do. Itaconic do.)—Pyrogallic do.—Py- ROLITH1C DO.--PYROMALIC DO.--PYROMECONIC DO. —Pyromucic do.—Pyrophosphoric do., (formed by exposing a concentrated solution of phosphoric acid for some time to a heat of 415°.)—Pyrotar- tahic and Pyruvic do., (obtained together from tartaric acid,) are examples of the pyroacids. The salts of the pyroacids are also distinguished by the prefix pyro. PYRODIGITALINA. A semi-solid, poison- ous empyreumatic oil, obtained by Dr. Morries by the destructive distillation of the dried leaves of foxglove. Pyroconia is obtained in the same way. PYROLIGNEOUS ACID. Syn. Vinegar of Wood. Spirit of do. Smoking Liquor. Essence; of Smoke. Acidum Pyrolignosum. (From irvp, fire, and lignum, wood.) Impure acetic acid ob- tained by the destructive distillation of wood in close vessels. It comes over along with tar and gaseous matter. In this state it is very impure, and contains much empyreumatic matter in solu- tion ; but by separation from the tar, saturation with slaked lime or chalk, defecation, and evapo- ration, an impure acetate of lime is obtained, which, after being gently heated, to destroy part of its empyreumatic matter without injuring its acetic acid, is again dissolved and defecated, and then precipitated by a solution of sulphate of soda, when a solution of acetate of soda and a precipitate of sulphate of lime are formed by double decomposi- tion. The solution is next evaporated to dryness, the dry mass dissolved in water, and the new solu- tion filtered and recrystallized. The crystals of acetate of soda obtained by the last process yield pure acetic acid by distillation along with sulphuric acid. (See Acetic Acid and Animal Sub- stances.) PYROPHORUS. (From ™p, fire, and salt of tin.—3. The yarn or cloth is put into a very weak alkaline bath at the boiling temperature, then washed, dried, and galled ; or, when the calico is to be printed, for this bath may be substituted one of cow-dung, subse- quent exposure to the air for a day or two, and immersion in very dilute sulphuric acid. In this way the stuff gets opened, takes and retains the color better. After the galling, the goods are dried, and alumed twice ; then dried, rinsed, and passed through the madder bath. This is com- posed of three-fourths of a pound of good madder for every pound weight of the goods. The bath is slowly raised to the boiling point in the course of fifty or sixty minutes, more or less, according to the shade of color wished for. When the boiling has continued a few minutes, the stuff is taken out, washed slightly, and dyed a second time in the same manner, and with as much madder. It is then washed and dried, or passed through a hot soap bath, which carries off the fawn-colored par- ticles. Other dyes likewise are added to the mad- der bath, to obtain other shadi-s ol color ; for in- stance, a decoction of fustic, weld, logwood, quer- citron, or knoppern, the mordants being modified accordingly. When bran is added to the madder bath, the color becomes much lighter, and of a more agreeable tint. *** Red dyes are also given by archil, carthamus, cochineal, Brazil wood, &c RED LIQUOR. The crude acetate of alumi- na, used by dyers. (See Alumina.) RED PIGMENTS. The principal of these are brown red, Indian do., light do., (burnt light ochre—makes a flesh color with white-lead and oil,) orange red, (sandix—made by calcining white-lead,) stone do., Venetian do., red ochre, chrome red, vermilion, red lake, tifC. REGULUS, (dimin. of rex, a king.) A term applied by the alchemists to various metallic mat- ters obtained by fusion ; as Regulus of antimony, arsenic, fyc. The former was often distinguished by the simple term Regulus. Martial Regulus of Antimony is sulphuret of antimony reduced by fusion with 1£ times its weight of old nails or iron filings, and some nitre and tartar. Regulus Jovis is made by melting a mixture of equal parts of martial regulus of antimony and tin. Both are cast into cups. Wine kept in them for a night becomes emetic. RESINS. Syn. Resines, (Fr.) Harze, (Ger.) Resin*, (Lat, from fcu, I flow.) Proximate vegetable principles, the ultimate composition of RHO 498 RIN which is carbon, hydrogen, and oxygen. They are distinguished by their solubility in alcohol, in- solubility in water, fusing by a moderate heat, and not being volatile without decomposition. Their sp. gr. varies from 09 to 1*2. According to Liebig, they are oxidized essential oils. Common resin, and the shellac of which sealing-wax is made, are familiar examples of these substances. RELISH, KITCHINER'S. Prep. Ground black pepper, and salt, of each 1 oz.; ground all- spice, scraped horseradish, and minced shalotes, of each £ oz.; walnut pickle, or mushroom ketchup, 1 pint; infuse 14 days, and strain. Used as a sauce, &c. RENNET. Syn. Calves' Maw. Coagulum. The stomach of calves, washed, and preserved either in brine or dry salt. Used to curdle milk. Two square inches from the bottom are sufficient for a cheese of 60 lbs. (See Cheese.) RESINEONE. An oily liquid obtained along with resinone when resin and lime are distilled to- gether. (Fremy.) RHABARBERIN. Syn. Rheumin. Rhein. Rhabarberic Acid. Rheumic Acid. The yel- low coloring principle of rhubarb. It is obtained by digesting powdered rhubarb in ether, distilling off greater part of the ether, and submitting the remainder to spontaneous evaporation. The crys- tals thus procured are purified by repeated solu- tions and crystallizations in alcohol. Orange yel- low. Gripes, but does not purge. (Brandea) RHAMNINE. Prep. Express the juice from buckthorn berries scarcely ripe, boil the residue with water, strain, and press; crude rhamnine will be obtained as the liquid cools, which, by solution in boiling alcohol and filtration, may be procured in crystals. RHAPONTICIN. A peculiar, yellow, odor- less, tasteless, and crystallizable substance, obtain- ed from the root of English rhubarb. It is extracted by boiling absolute alcohol. RHEUMATISM. Syn. Riieumatismus, (Lat) btvpaTionos, (Gr., from btvpan^w, to be afflicted with defluxions) A painful affection of the joints, attended by swelling and stiffness, an 3 also attack- ing the muscular, tendinous, and fibrcus textures. Acute Rheumatism, or rheumatic fever — Ar- thritis, inflammation of the synovial membrane, or rheumatic gout—Sciatica, or rheumatism of the cellular envelope of the great sciatic nerve, affect- ing the hip—and Lumbago, or rheumatism of the loins, are all varieties of the same disease. The treatment consists in the administration of purga- tives and sudorifics, accompanied by a course of bark, quinine, or other tonics. Calomel and opi- um, and iodide of potassium, have also been large- ly and successfully administered in this complaint. When the inflammatory symptoms are severe, occasional venesection should be had recourse to. The compound powder of ipecacuanha taken at night will generally promote the ease and sleep of the patient, and, by its sudorific action, tend con- siderably to promote a cure. Where possible, a dry atmosphere and regular temperature should be sought. Stimulating embrocations, blisters, fric- tions, and the hot or vapor bath, are frequently very serviceable in rheumatism, especially in lum- bago, and casual attacks arising from cold. RHODIZONIC ACID. Prep. When dry car- bonic acid gas is passed over fused potassium, a black porous mass is obtained, and this substance exposed to moist air, deliquesces into a solution of rhodizonate of potassa of a scarlet color, from which the excess of alkali may be taken by alco- hol. By treatment with sulphuric arid and alco- hol, the rhodizonic acid may be separated. When its solution is heated, it is converted into croconic acid. The latter acid is obtained by adding fluo- silicic acid to a solution of croconate of potash, evaporating to dryness, and dissolving out the cro- conic acid with water. This acid, as well as its salts, is yellow, hence its name, (from crocus, saffron.) RHODIUM, (from boSov, a rose, because of the color of the solutions of its salts.) A whitish metal discovered by Wollaston in 1803, associated with palladium, in the ore of platinum. It is obtained from the nitromuriatic solution of platinum ore, previously saturated with soda, by precipitating the palladium by bicyanide of mercury, filtering, add ing muriatic acid, evaporating to dryness, powder- ing, and digesting in alcohol of sp. gr. 0-837 ; the undissolved portion (double chloride of rhodium and sodium) is then washed with alcohol, and either exposed to a very strong heat, or gently heated in a stream of hydrogen gas, and after wards well washed with water. Another meth ,d is to dissolve in water the portion left after the ac- tion of the alcohol, and to precipitate by a plate of zinc. In this state it is a black powder. This powder exposed to heat continues black; but with borax it acquires a white metallic lustre, though it remains infusible. Sulphur or arsenic, however, renders it fusible; and may afterwards be expelled by continuing the heat. The button is not malle- able. Oxide of Rhodium (peroxide) is prepared by heating pulverulent rhodium mixed with hy- drate of potassa, and a little nitre, in a silver cruci- ble, and well washing the resulting powder, first with water, then with muriatic acid, and again with water. A greenish gray powder. In this state it is insoluble in acids. An impure soluble oxide is precipitated when carbonate of potash, or soda, is added in excess to the double chloride of rhodium and potassium.—Chloride of Rhodiubij (perchloride) is obtained by adding to a solution of the double chloride of rhodium and potassium, silico-hydrofluoric acid, as long as the double fluo- ride of potassium and silicon is generated, then filtering, evaporating, and redissolving in water. (Berzelius.) *** Pure rhodium is insoluble in acids, but dissolves in aqua regia when alloyed with other metals. Its sp. gr. is about 11. It is employed for making the points of the " rhodium pens." RINGWORM. Syn. Scald-Head. Porrigo. A disease that appears in circular patches of little pustules that afterwards form scabs, leaving a red pimply surface, and destroying the bulbs of the hair in its progress. It spreads rapidly, and is very infectious, often running through a whole school. It chiefly affects the neck, forehead, and scalp, of weakly children. The proper treatment consists in shaving the part, and keeping it clean with soap and water. When the scabbing com- mences, dressings of tar ointment, or the ointment of nitrate or nitric oxide of mercury of the London Ph., or a mixture pf equal parts of the first, and either the second or third, should be applied in RUM 499 SAC each case, diluting the mixture with lard to suit it to the state of irritability of the part. (See Acetic Acid.) ROB. (Arab., dense.) A term formerly ap- plied to an inspissated vegetable juice. ROCELLINE. Syn. Rocellic Acid. A fat- ty crystallizable substance, obtained from rocella tintoria, or dyer's orchil. ROLL, WINE. Prep. Soak a French roll, or sponge-biscuit, in raisin or sherry wine, surround it by a custard or cream thickened with eggs, and add some spice and ornaments. ROSACIC ACID. The red crystalline sub- stance deposited by the urine of persons laboring under intermittent or nervous fevers. It is purified by alcohol. ROUGE. Syn- Rouge for the Toilette. Rouge d'Espagne ; Fard, (Fr.) Prep. Wash safflowers (any quantity) until the water comes off colorless ; dry, powder, and digest in a weak solu- tion of carbonate of soda ; then place some fine cotton wool at the bottom of the vessel, and throw down the coloring matter by gradually adding lem- on juice or white vinegar till it ceases to produce a precipitate. Next wash the cotton in cold water, then dissolve out the color with a fresh solution of soda, add a quantity of finely-powdered talc, or French chalk, proportional to the intended quality of the rouge ; mix well, and precipitate as before ; lastly, collect the powder, dry with great care, and triturate it with a minute quantity of oil of olives, to render it smooth and adhesive. *** This is the only article which will brighten a lady's complex- ion without injuring the skin. The relative fine- ness and proportion of talc employed determines the quality of the rouge. t<.t Rouge Indienne is the terra persica, or In- dian red, imported from Ormuz ;—Liquid Rouge, the red liquid left from the preparation of carmine, or a solution of carmine in weak carbonate of pot- ash water, or of pure rouge in alcohol acidulated with acetic acid;—Rouge de Prusse, burnt yel- low ochre ;—Vert Rouge d'Athenes, or " pure rouge," is obtained from safflowers as above, but without the use of any talc or French chalk ; in- tense copper-bronze color when dry; red when moistened or diluted ;—Spanish Lady's Rouge is cotton wool repeatedly wetted with ammoniacal solution of carmine, and dried. ROUSSEAU'S DROPS. Syn. Gobttes de l'Abbe Rousseau. Vinum Opii fermentatione paratum. Prep. Honey ^xij ; warm water lb. iv ; set in a warm place till it begins to ferment, then add opium ^iv; dissolved in water f3x'j"> ferment for 1 month, filter, evaporate to §x; strain, and add rectified spirit 3J>vss. Milder than common laudanum. Dose. 5 to 30 drops. ROYAL PREVENTIVE. Syn. White Wash. A quack lotion formed of solution of diacetate of lead and proof spirit, of each 5J > water 1 pint. Used against infection. RUM. Syn. Spiritus sacchari. An ardent spirit obtained by distillation from the fermented skimmings of the sugar-boilers, (sirup.scum) the Irainings of the sugar pots and hogsheads, (molas- ses) the washings of the boilers, and occasionally the juice of the sugar-cane. Rum is imported from the West Indies, and the best comes from Jamaica. Leeward Island Rum is less esteemed. Rum owes its flavor to a volatile oil and butyric acid. The duty on West India rum is 9s. pel proof gallon; that on East India 15s.; the latter amounts to a prohibition. The consumption of rum has long been declining in England ; its place being supplied by gin or British brandy. In Ja- maica it is usual to put sliced pine-apples into the • puncheons containing the finer qualities of rum, which is then termed pine-apple rum. (See Al- cohol.) RUPERT'S DROPS are made by letting drops of melted glass fall into cold water ; the drop as- sumes by that means an oval form with a tail or neck resembling a retort. They possess this sin- gular property, that if a small portion of the tail is broken off, the whole bursts into powder with an explosion, and a considerable shock is communica- ted to the hand that grasps it RUSKS. Prep. 7 eggs well beaten ; new milk £ pint; melted butter $ lb.; yeast $ pint; sugar 3 oz.; beat well together with as much flour, added gradually, as will make a very light paste ; let it rise before the fire for half an hour, then add a little more flour, form into small loaves or cakes 5 or 6 inches wide, and flatten them ; bake mode- rately, and when cold, cut them into slices the size of rusks, and put them into the oven to brown a little. A nice tea-cake when hot, or with cara- ways to eat cold. RUTILINE. A name given by Braconnot to the product of the decomposition of salicine by sulphuric acid. A brownish red solid, colored blood-red by acids, and violet by alkalis. SABADILLIC ACID. Syn. Cevadic Acid. A crystalline, fusible, volatile, fatty acid, obtained from the oil extracted by ether from the seeds of veratrum sabadilla. The sabadillate of baryta is prepared in the same way as the butyrate of baryta is from butter. When this salt is heated with con- centrated phosphoric acid, the sabadillic acid sub- limes in white .needles. It has an odor resembling butyric acid. . SABADILLINA. An alkaloid obtained by Couerbe from cebadilla seeds. According to Si- mon, it is merely a compound of the resinates of soda and veratria. SACCHARIC ACID. Syn. Oxalhydric Acid. Prep. Sugar or gum 1 part; nitric arid 2 parts; diluted with water 10 parts; dissolve by the aid of heat, and continue the heat as long as reaction takes place, then neutralize by carbonate of lime, precipitate by acetate of lead, and decom- pose the precipitate, suspended in water, by sul- phureted hydrogen ; neutralize the filtered liquid with potash, concentrate, and crystallize ; redis- solve the resulting sacckarate of potassa, decolor by animal charcoal, reprecipitate by acetate of lead, and decompose the precipitated saccharate of lead by sulphureted hydrogen, as before. It forms salts with the bases called Saccharates. SACCHAROMETER. (From saccharum, su- gar, and metrum, a measure.) An hydrometer for determining the sp. gr. of brewer's and distil- ler's worts. (See Hydrometer and Brewing.) SACCHULMIC ACID. A light brown pow- der, obtained by Malaguti and Boullay, by boiling sugar along with dilute sulphuric acid It is solu- SAG 500 SAL ble in ammonia and the fixed alkalis, forming salts. SACCHULMINE. An insoluble substance, obtained like the last, by boiling 10 parts of sugar, 30 of water, and 1 of sulphuric acid for a very long time. It is deposited in brilliant, brown scales, along with some sacchulmic acid. The latter is removed by the action of ammonia water. SACHET. Syn. Sacculus. Sachets are little bags, containing dry substances, used as local ap- plications. SACHET, ANTI-PHTHISIC. Syn. Saccu- lus Anti-phthisicus. Prep. Dissolve §j of aloes in f Jxij strong decoction of fresh rue. Fold a large piece of soft muslin in 8 folds, large enough to cover the chest and part of the stomach. Steep it in the decoction and dry it in the shade. Wear it on the chest constantly. %* A celebrated do- mestic remedy for consumption. SACK. (From sec, dry.) A wine used by our ancestors, supposed by some to have been Rhenish or canary ; but, with more probability, by others to have been dry mountain or " vin d'Espagne; vin sec;" (Howell, Fr. and Eng. Diet, 1650.) Fal- staff calls it " sherris sack," (sherry sack,) from Xeres, a sea town of Corduba, where that kind of sack (wine) is made. (Blount) SAFFRON. The prepared stigmata of the crocus sativus. There are two kinds of saffron found in commerce.—1. Hay Saffron (crocus in fceno) consists of the stigmas with parts of the style carefully dried. Of this sort the Spanish is the best.—2. Cake Saffron, (crocus in placenta.) This is properly merely the former compressed into cakes; but the cake saffron of commerce is now mostly, if not entirely, composed of safflower made into a paste with gum-water, and rolled out on paper into oval cakes 10 to 12 inches long, 9 or 10 broad, and one-tenth of au inch thick, and dried. " I can detect neither saffron nor marigold in them." (Dr. Pereira.) Pur. Saffron is largely adulterated ; abroad it is frequently mixed with safflower, and in England with " prepared mari- golds," or French (mock) saffron. These frauds may be detected by the inferiority of the color, and by soaking the leaves in wa-'.er, when the stigmas of the crocus may be reaa.ly distinguished from the florets of safflower and the petals of marigolds. Winckler and Gruner propose to detect these sub- stances by means of a solution of silver or of per- chloride of iron. The infusion of true saffron is not altered by these reagents, but the extract of either of the above-mentioned adulterants is rendered opaque, and at length precipitated. (Jahrbuch fur Prakt. Pharm.) The writer of this article knows one wholesale drug house alone, who a short time since had a stock of several hundred- weight of prepared marigolds, which they not only employed to mix with genuine saffron, but sold ex- tensively to the country dealers. Old and dry saf- fron is "freshened up" by rubbing it between the hand, slightly oiled. SAGAPENUM. This substance is described in the London Pharmacopoeia as a gum resin, the production of au uncertain species of ferula. The mass of the sagapenum sold to the retail trader is, however, factitious, and formed by mixing together asafcetida, galbanum, and other drugs in variable proportions. This is generally done by the con- scientious druggists, by softening a mixture of 3 parts of asafcetida and 15 parts of galbanum, in a water or steam bath, and then stirring in about one-seventeenth of their weight of oil of turpen- tine, to which a little oil of juniper has been added. This mixture is called " gummi sagapeni Opt.," an inferior sort being made by adding sundry por- tions of yellow resin and paste of gum tragacanth to the above. (Cooley, Chem., v. 369.) SAGO. A species of fecula or starch, obtained from the pith of the sago palm-tree. (See Jel- lies.) SALADS. These articles being eaten raw, are mostly of difficult digestion, especially those of the more cooling kind. They are, however, antiseptic, and tend to correct " the grossness" of animal food. They are made of various vegetables (either singly or mixed) seasoned with oil, vinegar, mustard, and other condiments. Salads are useful in scurvy. SAL ALEMBROTH. Syn. Hydrargyro- ciiloride of Ammonia. Sal Sapienti*. Prep. Sal ammoniac and corrosive sublimate, equal parts; dissolve in water, evaporate, and crystallize. < SALEP. Syn. Salop. The prepared root of the orchis mascula. It chiefly consists of bassorin and fecula. Mixed with boiling water, it forms a nutritious jelly. SALICTNE. A white, crystalline substance, discovered by Le Roux and Buchner, and obtained from several species of salix and populus. It is found in the bark and leaves of all bitter willows. Prep (Merck.) Exhaust willow bark by repeated coction with water, concentrate the mixed liquors, and while boiling, add litharge till the liquid is nearly decolored; remove the dissolved oxide of lead, first by sulphuric acid, and afterwards by sulphuret of barium ; filter, and evaporate. The salicine that crystallizes must be purified by re- peated solutions and crystallizations. From willow bark which is fresh and rich in salicine, it may be obtained by the cautious evaporation of the cold aqueous infusion. Remarks. Salicine forms white, silky needles and plates, is bitter, inodorous, neutral, fusible at 230° F., and soluble in water and ether. Hydro- chloric and dilute sulphuric acid convert it into a tasteless powder called Saliretine, which is insolu- ble in water, but dissolves in alkalis and alcohol With chlorine it forms Chlorosalicine. It has been given in dyspepsia, intermittents, and other dis- eases in which quinine is commonly administered. Dose. 10 to 30 grs. SALICULIC ACID. A volatile, crystalliza- ble acid discovered by Piria, and obtained by heat- ing saliculous acid with caustic potash till the mix- ture turns white and gas is disengaged, and treat- ing the residue with a mineral acid, to separate the potash. SALICULOUS ACID. Syn. Hydruret of Salicule. Hydruret of Spiroyle. Saliculic Acid ? A nearly colorless, oily, inflammable li- quid,* discovered by Pagenstecher in the volatile oil of spiraea ulmaria, (meadow-sweet) and by Piria, as a product of the decomposition of salicine. It is either obtained by distilling the oil of spiraea along with liquor of potassa, as long as oil comes over, decomposing the residuum of saliculite of po- tassa with' dilute sulphuric acid, and again distill- ing, when saliculous acid comes over along ivith SAL 501 SAL water ; or by distilling a mixture of I part each of salicine and bichromate of potash, 2£ parts of oil of vitriol, and 20 parts of water. The salicine is dissolved in part of the water, the acid diluted with the remainder, and the whole mixed in a retort, but not distilled till the effervescence ceases. Prod. 25$. (Ettling.) %* Saliculous acid is so- luble in ether and alcohol, and slightly so in water It combines with the bases to form salts called saliculites. It also forms several inter- esting compounds with iodine, bromine, chlorine, &c. SALOOP. Sassafras (chips) tea flavored with milk and sugar. A wholesome and useful drink in cutaneous and rheumatic affections. SALT. Syn. Sel, (Fr.) Salz, (Ger.) Sal, (Lat., from <5Xs, sea-salt) In Chemistry, a com- pound of an acid with an alkali or a salifiable base, or of bromine, chlorine, fluorine, or iodine, with a metal. The names of the salts are derived from the acids which they contain ; as sulphate of soda, a compound of sulphuric acid and soda; sul- phite of lime, a compound of lime and sulphu- rous acid. When the name of a salt terminates in ate, it implies that the acid that it contains is at the maximum of oxidizement, (or ends with ic) and when the name terminates in ite, that the acid contains less oxygen, (or ends with ous)—Neutral salts are such as contain 1 eq. each of acid and base ; taste, or subsalts, such as contain 2 or more atoms of base to one of acid ; acid, or supersalts, such as contain more than I eq. of acid ; hydrous or hydrated salts are such as contain water of crystallization, or combined water; anhydrous salts, those that are destitute of water. Deliques- cent salts are those that attract moisture from the atmosphere ; efflorescent salts, such as part with their combined water, and become opaque and pulverulent under like circumstances. The salts formed by the direct union of the archeal ele- ments, chlorine, iodine, &c, as sea-salt, are termed hatoid salts, and their names are formed by adding ide or uret to the first portion of the •tames of their electro-negative elements ; as chlo- ride of sodium, or common salt, a compound of chlor-ine and sodium ; iodide, or ioduret of iron, a compound of iW-ine and iron. See Oxide. SALT OF WORMWOOD. Syn. Sal Ab- binthii. Carbonate of potash. SALT, RED. Common salt wetted with an infusion of beet-root, or cochineal, or tincture of red sanders wood, then dried and rubbed through a sieve. Used to impart a color to gravies, &c. Infusion of saffron also gives a beautiful color for this purpose. *** It has been proposed to color Epsom salts in this way to distinguish them from oxalic acid. SALT, SORE THROAT. Syn. Sal Pru- nell*. Lapis do. Crystal Mineral. Prep. Melt nitre, and when it flows smooth, pour it into moulds, either balls or cakes. Prod. 50%. SALTS, SMELLING. Syn. Sal volatile oleosus. Prep. 1.—Sesquicarbonate of ammonia 1 lb. ; oil of lavender 3 oz.; grind together, and sublime with a gentle heat.—2. To the last add, before distillation, oil of verbena £ oz. Very fine.— 3. Subcarbonate of potash and sal ammoniac, of each §viij ' Powder, add leaves of Syrian herb mastich (marum Syriacum) fss ; alcohol 1£ pints, holding in solution oil of cloves 3ss, oil of nutmeg 3ij, oil of cinnamon 3j, oils of sweet marjoram, lemon, and orange, of each 3j ; water 1 quart; dis- til with a very gentle heat, and stop the process as soon as the liquid that rises begins to dissolve the salt. Very fragrant.—4. (Extemporaneous.)—a. Sal ammoniac 1 dr.; pure potassa 3 dr.; grind together, and add essence of lemon 15 drops.—b. Sesquicarbonate of ammonia, bruised, q. s.; essen- tial oil a few drops to perfume. SALTING AND PICKLING. (In domes- tic Economy.) This is best performed by well rubbing the meat with a mixture of salt 2 lbs.; saltpetre 2 oz.; and moist sugar 1 £ oz., till every crevice is thoroughly penetrated, after which it should be set aside till the next day, when it should be covered with fresh salt in such parts as require it It may then be advantageously placed in any proper vessel, and subjected to pressure, ad- ding a little fresh salt as necessary, and turning it daily till sufficiently cured. When the brine as it forms is allowed to drain from the meat, the pro- cess is called dry salting ; but when, on the con- trary, it is allowed to remain on it, the article is said to be wet salted. On the small scale, the lat- ter is most conveniently performed by rubbing the meat with salt, &c, as above, and after it has lain a few hours, putting it into a pickle formed by dis- solving 4 lbs. of salt, £ or 1 lb. of sugar, and 2 oz. of saltpetre in 2 gallons of water. This pickling liquor gets weaker by use, and should therefore be occa- sionally boiled down a little and skimmed, at the same time adding some more of the dry ingredients. *#* The sooner meat is salted after being killed the better, as it then possesses considerable absorb- ent power, which it gradually loses by age. On this property is based the process of M. Gannal for the preservation of animals intended for food in a fresh state. This operation consists in injecting a solution of chloride of aluminum, at 10° Baume, into the carotid, by means of a syphon, as soon as the blood ceases to flow from the slaughtered ani- mal ; both extremities of the jugular vein being previously tied. 9 to 12 quarts of the solution are sufficient for an ox. When the animal has been well bled, and the injection skilfully performed, it is scarcely perceptible that the animal has under- gone any preparation. The injected animal is cut up in the usual way ; and when intended to be eaten within 2 or 3 weeks, merely requires to be hung up in a dry situation free from flies ; but if it is to be kept for a longer period, it is directed to be washed with a mixed solution of common salt and chloride of aluminum at 10° B., and then simply dried and packed in clean air-tight barrels, and kept in a cool, dry place. If the air cannot be perfectly excluded, it should be packed in dry salt, not for the purpose of preserving it, but to prevent the'vegetation of bissus; as without this precaution, the meat becomes musty, from ex- posure and the action of moisture. Meat preserved by this process may be kept for several years, and merely requires soaking for 24 hours in water, for the purpose of swelling its pores, to give it the ap- pearance and taste of fresh meat, fit either for roasting or boiling. SALVE. A name indiscriminately applied by the vulgar to any consistent, greasy preparation (See Cerates, Ointment, &c.) SAR 502 SAU SALVE, LIP. Syn. Ceratum labiale. Prep. —1. (White.) Spermaceti ointment or cerate 3 oz.; finely-powdered white sugar 1 oz.; scent q. e.; mix.—2. (Red.) Spermaceti ointment £ 1b.; alkanet root 1 oz.; melt together till sufficiently colored, strain, and when considerably cooled, add 20 drops of oil of lavender, or 3 drops of oil of rho- dium, or otto of roses, or 1£ dr. of balsam of Peru. SANDAL WOOD. Syn. Red Sanders Wood. Santal, (Fr.) Sandelholz, (Ger.) Lignum san- tali rubri ; Lignum santalinum rubrum, (Lat.) The wood of pterocarpus santalinus. Wool may be dyed a carmine red by dipping it alternately into an infusion of this wood, and an acidulous bath. (Trommsdorff.) Prepared with a mordant of alum and tartar, and then dyed in a bath of sandal wood and sumach, it takes a reddish yel- low. (Bancroft.) The coloring principle of red sanders wood is called santaline, and may be ob- tained as a reddish resinous mass by evaporating its alcoholic infusion, or by digesting the rasped wood in ammonia water, and precipitating by an acid. Its spirituous solution gives a rich purple precipitate with protochloride of ^in, and a violet one with acetate of lead. SANDIVER. Syn. Sat. de Verre. Glass Gall. Fel Vitri. The saline scum that swims on glass when first made. It is occasionally used in tooth powders. SANGUINARIN. Obtained from the root of sanguinaria Canadensis by digesting it in anhy- drous alcohol, precipitating by water of ammonia, washing the red precipitate in water, boiling with water and animal charcoal, filtering, and digesting the solid portion in alcohol; this solution by dis- tillation yields a pearl-gray or yellowish substance which is sanguinariii. It excites sneezing, and is turned red by acids. SANTONINE. Prep. Worm seed (semen cyna) 4,parts; slaked lime 2 parts; alcohol of 90°f, 20 parts ; digest, evaporate the clear liquid, dissolve in dilute acetic acid, filter, again evapo- rate, dissolve in 10 parts of alcohol at 80$, and boil with some animal charcoal. The filtered liquid deposites colorless crystals of santonine as it cools. Tasteless, inodorous, fusible, volatizable, soluble in ether and alcohol, and slightly so in water. It is much esteemed as " a tasteless worm medicine," and is especially adapted to re- move lumbricales, (large round worms.) Dose. 10 to 30 grs. repeated night and morning,«*followed by a brisk purge.—Lozenges of Santonine. San- tonine 3j; sugar §v; tragacanth 3ss; all in powder; make a mass with water and divide into 144 lozenges. Dose for a child 5 to 10 daily. SAPONINE. A white non-crystallizable sub- stance obtained by the action of alcohol on the root of saponaria officinalis, (soap wort.) It is soluble in water, and the solution froths strongly on agitation. The smallest quantity of the powder causes violent sneezing. By the action of acids and alkalis it is converted into a white powder termed saponic acid, which is soluble in alcohol. SARSAPARILLA. Syn. Radix Sarz*, (Lat.) The Jamaica, red Jamaica, or red- bearded sarsaparilla, is the variety which should alone be used in medicine. This kind yields 33 to 40$ of its weight of extract, (Hennell, Battley, Pope,) and contains less starchy matter than the other varieties. It is distinguished by the dirty orange-reddish color of its bark, and by its cold decoction being darkened, but not rendered blue by a solution of iodine. Its powder has also a pale reddish brown color. The other varieties of sarsaparilla, viz.—the Lisbon, Lima, Vera Cruz, and Honduras, are frequently substituted for the Jamaica by the fraudulent druggist in the prepara- tion of the decoction and extracts of this drug; but the products are vastly inferior in quantity, color, taste, and medicinal virtue. Decoction of sarsaparilla, when made with the Honduras root, is very liable to ferment even by a few hours' ex- posure in hot weather. I once saw a pan holding 3 hogsheads of the strong decoction, that had been left exposed all night, in as active a state of fermentation as a gyle of beer; it bore a frothy head, and evolved a most disagreeable odor, that was not wholly removed by several hours' boiling. SARSAPARILLINE. Syn. Smilacin. Salseparin. Paralline. Pariglin. • Paralinic Acid. A white, crystallizable, odorless, and nearly tasteless substance, discovered by Palotta and Folchi, in sarsaparilla. It is best obtained by treating the bark of Jamaica sarsaparilla with hot alcohol, decoloring the solution by animal char- coal, and repeatedly dissolving and crystallizing the impure smilacin that deposites as the liquid cools. It may also be extracted by boiling water. Water holding a very small quantity of this sub- stance in solution, froths considerably on agitation. This is especially the case with infusion of Ja- maica sarsaparilla, and this property has conse- quently been proposed as a test of the quality of sarsaparilla root. Dose. 2 to 10 grs. in the usual cases in which the root is given. SAUCES. Prep.—l. (Anchovy.) 3 or 4 an- chovies, chopped ; butter 3 or 4 oz.; water 2 oz.; vinegar 2 tablespoonfuls; flour 1 do.; stir over the fire till it thickens, then rub it through a coarse hair-sieve.—2. (Chetney. Quihi do.) Sharp apples, pared and cored, tomatoes, salt, brown sugar, and raisins, of each 8 oz.; red chillies, and powdered ginger, of each 4 oz. ; garlic and sha- lotes, of each 2 oz.; pound well, add vinegar 3 quarts, and lemon juice 1 do.; digest with fre- quent agitation for a month, pour off nearly all the liquor, and bottle. Used for fish or meat, either hot or cold, or to flavor stews, &c. The residue is the Chetney, and must be put into pots or jars. It is used like mustard.—3. (Fish.) a. Port wine 1 gallon ; mountain 1 quart; walnut ketchup 2 quarts; anchovies and liquor 2 lbs.; 8 lemons; 36 shalotes ; scraped horseradish 1£ lb.; flour of mustard 8 oz.; mace 1 oz.; Cayenne q. s.; boil up gently, strain, and bottle.—b. 24 anchovies ; 10 shalotes; scraped horseradish 3 spoonfuls ; mace and cloves, of each $ oz.; 2 sliced lemons ; anchovy liquor 8 oz.; water 1 pint; Hock or Rhenish wine 1 bottle ; walnut ketchup £ pint; boil to 2£ lbs., strain, and bottle.—4. (Quin's) a. Walnut pickle, and port wine, of each 1 pint; mushroom ketchup 1 quart; an- chovies and shalotes, chopped, of each 2 dozen; soy £ pint; Cayenne $ oz.; simmer for 10 minutes. strain, and bottle.—6. Walnut pickle, mushroom ketchup, and soy, of each 1 pint; chopped clove* SCA 503 SEA of garlic and anchovies, of each 1 dozen ; Cayenne and bruised cloves, of each 1 dr. As last.—5. (Sauce Superlative) Port wine and mushroom ketchup, of each 1 quart; walnut pickle 1 pint; pounded anchovies £ lb.; lemon peel, minced shalotes, and scraped horseradish, of each 2 oz.; allspice and black pepper, bruised, of each 1 oz.; Cayenne pepper and bruised celery seed, of each -J oz., (or currie powder £ oz.;) digest 14 days, strain, and bottle—6. (Tomato.) Bruised tomatoes 1 gallon ; salt £ lb.; in 3 days press out the juice, to each quart add shalotes 2 oz.; black pepper 1 dr.; boil for 30 minutes, strain, add mace, all- spice, ginger, and nutmegs, of each $ oz.; corian- der seed and cochineal, of each 1 dr.; simmer gently for 15 minutes, strain, cool, and bottle.—7. (Sauce Aristocratique) Green walnut juice, anchovies, equal parts ; cloves, mace, and pimento, bruised, of each 1 dr. to every pound of juice ; boil and strain, then to every pint add 1 pint of vinegar, £ pint of port wine, -J pint of soy, and a few shalotes. Let the whole stand for a few days, and decant the clear liquor.—8. (Sauce au Roi) Brown vinegar (good) 3 quarts; soy and walnut ketchup, of each $ pint; cloves and shalotes, of each £ doz. ; Cayenne pepper 1 oz.; mix, and let them stand for 14 days.—9. (Sauce Piquante) Soy 1 part; port wine and Cayenne, of each 2 parts ; brown vinegar 16 parts ; mix, and let them stand for 3 or 4 days before bottling. SAUR KRAUT. Prep. Clean white cabbages, cut them into small pieces, and stratify them in a cask along with salt and a few juniper berries and caraway seeds, observing to pack them down as hard as possible with a wooden rammer, and to cover them with a lid pressed down with a heavy weight. The cask should be placed in a cold situation as soon as a sour smell is perceived. Much used by the northern nations of Europe. SAUSAGES. Fat and lean of pork or beef chopped small, flavored with spice, and put into skins, or pressed into pots. Crumb of bread is also frequently added. SA> ELOYS. Prep. Young pork, free from bone and skin, 3 lbs.; salt it with 1 oz. of salt- petre, and £ lb. of common salt for 2 days ; chop it fine ; put in 3 teaspoonfuls of pepper ; 1 doz. sage leaves chopped fine, and 1 lb. of grated bread; mix it well, ffll the skins, and bake them half an hour in a slack oven. They are good either hot or cold. SAVONETTES, (Fr., Wash-balls) Prep. 1. (Communes)—a. Soap 5 lbs.; starch 2 Ibs.j essence of orange or citron 1 oz.; eau pour la barbe 1 gallon ; beat together, and form into balls.—J. Soap shavings 5 lbs.; eau de citron 1 quart; digest, force it through a coarse cloth, add starch 2 lbs., and essence of orange or citron 1 oz.; mix well. As last.—2. (Sand balls) Soap and silicious sand, of each 1 lb.; perfume (any) q. s.—3. Soap shavings 1 lb.; orange flower or rose water £, pint; mix, and when sufficiently soft, add sent q. s., and form into balls. SCAMMONY. The mass of the scammony of the shops is adulterated. The following re- ceipts are current for factitious Smyrna scam- mony :—L Aleppo scammony 1 lb. ; jalap 7 lbs.; senna and charcoal, of each 2 lbs.; manna 6 lbs.; gamboge 4 lbs.; ginger $ lb.; sirup of buckthorn, q. s.—2. Jalap 2 lbs.; senna, Aleppo scammony, and gamboge, of each 8 oz.; charcoal and ginger, of each 4 oz.; as last.—3. Aleppo scammony 1 lb. ; extract of jalap 5 lbs.; gum guaiacum and sago, of each 10 lbs.; ivory-black 4 lbs.; mix. These imitations may be detected by the want of the resinous fracture of true scammony, and by their inferior solubility. Sulphuric ether separates from pure scammony fully 78$ of resinous matter dried at 280° F. ; and its cold decoction is neither rendered blue by iodine, nor its tincture turned green by nitric acid. SCARLET DYE. Proc. (For 1 lb. of cloth.) Cream of tartar 1£ oz.; water q. s.; boil in a block-tin vessel, and when dissolved, add solution of tin (made by dissolving 2 oz. of grain tin in a mixture of 1 lb. each of nitric acid and water, and 1£ oz. of sal ammoniac) 1£ oz.; boil for 3 minutes, then introduce the cloth and boil it for 2 hours ; drain and cool. Next, take cream of tartar $ oz.; water q. s.; boil, and add powdered cochineal 1 oz.; boil for 5 minutes, then gradually add solution of tin 1 oz., stirring well all the time ; lastly, put in the goods and dye as quickly as pos- sible. (Poerner.) SCENTS, POMATUM. Prep.—l. (Cow- slip) Essence of bergamotte 1 lb.; essence of lemon £ lb.; oil of cloves $ lb.; mix.—2. (Jon- quille) Essences of bergamotte and lemon, of each, 8 oz.; oil of cloves 2 oz.; oils of sassafras and orange, of each, 1 oz.; mix.—3. (Millefleur) Essence of ambergris 4 oz.; essence of lemon 3 oz.; oil of cloves and English oil ,of lavender, of each, 2 oz.; essence of bergamotte 1 oz.; mix. SCHWARTZ' DROPS. Prep. Barbadoes tar f 5j j tincture of asafottida f Jiss ; mix. Dose. 40 drops 3 times a day for tapeworm. SCHEELE'S GREEN. Syn. Arsenite of Copper. Prep. Powdered arsenious acid 11 oz.; carbonate of potash 2 lbs.; boiling water 1 gal- lon ; dissolve, filter, and add the solution, grad- ually, to a filtered solution of 2 lbs. of crystallized sulphate of copper in 3 gallons of water, as long as it produces a grass-green precipitate; well wash with warm water and dry. Prod. 1£ lb. A very fine color. Used as a paint. SCILLITIN. Syn. Scillitina. Scillitite. A whitish, resinous, transparent, bitter, deliques- cent substance, obtained from squills. It is soluble in water, alcohol, and acetic acid, and is purgative and poisonous. SCUDAMORE'S GOUT LOTION. Prep- Camphor mixture f^ix; alcohol f^iij j mix. Ap- plied on rags or poultices, a"dding, for the former, a enough hot water to warm it. SCURVY. Syn. Scorbutus. The treatment of ordinary cases of this disease mainly consists in employing a diet of fresh animal and green vege- table food, and mild ale, beer, or lemonade, as beverages, scrupulously avoiding salted and dried meat. SEA SICKNESS. The most effectual pre- ventive is the horizontal position. When there is much pain, a few drops of laudanum may be ta- ken, or an opium plaster applied over the region of the stomach. Persons should put their stomach and bowels in proper order by the use of mild aperients, and an emetic if required, before pro- ceeding to sea, when it will generally be found, SEN 504 SHR that a glass of warm weak brandy and water, to which 15 or 20 drops of laudanum, or still better 1 or 2 drops of creosote have been added, will ef- fectually prevent any disposition to sea sickness, provided excess in eating and drinking is at the same time avoided. SEBACIC ACID. (From sebum, suet.) Prej>. Distil fat. oil, or suet, in an earthen retort, and treat the product with hot water as long as that liquid deposites any thing on cooling; wash the crystals in cold water, and crystallize from hot water, repeating the process till the crystals be- come colorless. Volatile, light, pearly scales, re- sembling benzoic acid. With tho bases it forms salts called sebates. It is very soluble in hot wa- ter, ether, and alcohol. SEDATIVE. Syn. Sedativus. (Lat, from sedo, to ease or assuage.) Medicine that dimin- ishes the animal energy without destroying life: opium, henbane, and several of the neutral salts and acids, are sedatives. SELENIUM. (From UUvr,, the moon.) A chemical element discovered by Berzelius in 1818. Prep. "(Magnus.) Native sulphuret of selenium 1 part; binoxide of manganese 8 parts; expose the mixture to a low red heat in a glass retort, the beak of which dips in water. Props , issolve pale and picked gum arabic in an equal weight of water by a gentle heat, and add the solution to twice its weight of simple sirup, simmer for 2 or 3 minutes, remove the scum, and cool. A pleasant demulcent The addition of 1 or 2 oz. of orange-flower water to each pint, renders it very agreeable. SIRUP OF GINGER. Syn. Syrupus Zingi- ber's, (P. L. E. and D.) Prep 'P. L.) Bruised ginger §iiss ; boiling water 1 pint; macerate for 4 hours, strain, and add white sugar lb. iiss. Used as a flavoring. SIRUP OF HOREHOUND. Syn. Syrupus Marubii. Syrop de Prassio. Prep.—1. (P. Cod.) Dried horehound §j ; horehound water lb. ij ; di- gest in a water-bath for 2 hours, strain, and add white sugar lb. iv.—White horehound (fresh) 1 lb.; boiling water 1 gallon; infuse for 2 hours, press out the liquor, filter, and add sugar q. s. A popu- lar remedy in coughs and diseases of the lungs. Dose. A tablespoonful ad libitum. " It is sold for any sirup of herbs that is demanded, and which is not in the shop." (Gray.) SIRUP OF IODIDE OF IRON. Syn. Syr- upus Ferri Iodidl Prep.—1. (P. E.) Dry iodine 200 grs.; fine iron wire 100 grs.; water f^vj; mix in a flask and boil, at first gently, and after- wards briskly, till reduced to two-thirds; filter while hot into a matrass containing white sugar 3;ivss; dissolve, and add water if necessary to make the whole measure exactly f § vj. inxij contain 1 gr. of iodide of iron—2. (A. T. Thomson.) Con- tains 24 grs. of dry or 32 grs. of hydrated iodide of iron in each oz.—3. (Ricord.) 2 gre. to the oz. *** Either of the last two may be made from the former by adding simple sirup.—4. (Whole- sale.) Dry iodine 6 oz.; iron filings 3 oz.; boiling water 2£ lbs.; sugar 5$ lbs.; mix as No. 1, and make it up to 8$ lbs. This is of the strength rec- ommended by Dr. A. T. Thomson. Dose. Of either (except the third) 3ss to 3j, as a tonic and resolvent, in debility, scrofula, &c. *** It should be perfectly transparent and colorless, or at most only of a very pale green tint, and should be with- out sediment even when exposed to the air. (P. E.) It keeps best in well-closed bottles, excluded fron; the light. (See Iodide of Iron.) SIRUP OF IPECACUANHA. Syn. Syruf us Ipecacuanh*. Prep. (P. E.) Coarsejy-pow dered ipecacuanha £iv ; rectified spirit 1 pint; di gest 24 hours, strain, add proof spirit f fxiv ; again digest and strain, and repeat the process with wa- ter f lx\v ; distil off the spirit from the mixed li- quors, evaporate to f gxij ; filter, add rectified spirit f %\, and simple sirup 7 pints ; mix well. Dose. As an emetic for infants £ teaspoonful; for adults 1 to 1£ oz.; as an expectorant, 1 to 3 teaspoonfuls. SIRUP OF LEMONS. Syn. Syrupus Limo- num, (P. L. E. and D.) Prep. (P. L.) Lemon juice (strained or defecated) 1 pint: sugar lb. iiss; dissolve by a gentle heat, and set it aside; in 24 houre remove the scum, and decant the clear. A pleasant refrigerant sirup in fevere, &c. Dose. 1 to 4 drs. in any diluent. With water it forms an extemporaneous lemonade. SIR 509 SIR SIRUP OF MARSHMALLOW. Syn. Syr- upus Alth**, (P. L. E. and D.) Prep. (P. L.) Marshmallow root, fresh and sliced, gviij ; boiling water 2 quarts ; boil to one-half, set aside for 24 hours, decant the clear, add white sugar lb. iiss, and gently evaporate to a proper consistence. De- mulcent and pectoral. Dose. 1 to 4 drs., in coughs, &c, added to mixtures. SIRUP OF MULBERRIES. Syn. Syrupus Mori. Prep. (P. L.) Juice of mulberries, strained, 1 pint ; sugar lb. iiss ; dissolve. Used as a color- ing and flavoring where alkalis and earths are not present. Sirup of red poppies, (Rhaaados,) slightly acidulated with tartaric or dilute sulphuric acid, is very generally sold for it. SIRUP OF ORANGE-PEEL. Syn. Syrupus Aurantii, (P. L. E. D.) Prep.—l. (P. L.) Fresh orange-peel f iiss ; boiling water 1 pint; macerate for 12 houre in a covered vessel, strain, and add sugar lb. iij.—2. (Wholesale) a. Fresh orange-peel 18 oz., (or dried £ lb.;) sugar 18 lbs.; water q.s.— 6. Tincture of orange-peel f Jj *, simple sirup f ^xix ; mix. As an agreeable flavoring and stomachic. Dose. 1 to 4 drs. SIRUP OF POPPIES. Syn. Sirup of White Poppies. Syrupus Papaveris, (P. L. E. & D.) Do. do. albi. Syr. de Meconio. Diacodion. Prep. I. (P. L.) Poppy heads, dried, bruised, and without the seeds, lb. iij ; water 5 gallons; boil to 2 gal- lons, press out the liquor, boil to 2 quarts, set it aside for 12 hours, decant, strain, boil to 1 quart, and add sugar lb. v.—2. (Wholesale.) Extract of poppies 1£ lbs.; boiling water 2£ gallons; dissolve, clarify, or filter, so that it may be perfectly trans- parent when cold, then add white sugar 44 lbs. and dissolve. Anodyne and soporific. Dose. For an infant $ to £ teaspoonful; for an adult 2 to 4 drs. SIRUP OF RED POPPIES. Syn. Sirup of Corn poppy. Syrupus Rh*ados, (P. L. E. & D.) Prep. (P. L.) Petals of the red poppy lb. j; boil- ing water 1 pint; mix in a water bath, remove the vessel, macerate for 12 hours, press out the liquor, and after defecation or filtering, add sugar lb. iiss.—2. (Wholesale.) Dried red poppy petals 3 lbs.; boiling water q. s.; white sugar 44 lbs.; as last. Employed as a coloring. A little acid brightens it. *** The color of this sirup is injured by contact with iron or copper. SIRUP OF RHUBARB. Syn. Syrupus Rhasi. Prep.—1. (P. Cod.) Bruised rhubarb § iij ; water ^xvj ; macerate 12 hours, filter, and add white sugar Jxxxij.—2. (Wholesale.) Bruised rhubarb 1£ lbs.; water q. s.; sugar 20 lbs.; as last. Stomachic and purgative. SIRUP OF ROSES. Syn. Syrupus Ros*. (P. L. & D.) Syr. Ros* centifoli*, (P. E.) Prep. —1. (P. L.) Dried petals of red roses (Rosa ceuti- folia) ^vij ; boiling water 3 pints ; macerate for 12 hours, filter, evaporate in a water bath to 1 quart, and add white sugar lb. vj.—2. (Wholesale.) Rose leaves 1 lb.; sugar 19 lbs.; water q. s.; as last. Gently laxative. Dose. $ to 1 oz. It is usual to add a few drops of dilute sulphuric acid to brighten the color. Alkalis turn it green. SIRUP OF RUE. Syn. Syrupus Rut*. Prep. Oil of rue 12 drops ; rectified spirit f ^ss ; dissolve, and add simple sirup 1 pint. Dose. £ to 2 tea- ipoonfuls in the flatulent colic of children SIRUP OF SAFFRON. Syn. Syrupus Croci, (P. L. &. E.) Prep. 1. (P. L.) Hay saffron 3x; boiling water 1 pint; macerate 12 hours, strain, and add sugar lb. iij.—2. (Wholesale.) Hay saffron 6 oz.; boiling water 6 quarts ; white sugar 24 lbs.; as last Used for its color and flavor. SIRUP OF SARSAPARILLA. Syn. Syrupus Sarz*, (P. L. &, E.) Syr. Sarsaparill*, (P. D.) Prep.—1. (P. L.) Sarsaparilla, sliced, §xv ; boil- ing water 1 gallon ; macerate for 24 hours, boil to 2 quarts, strain, add sugar §xv, and boil to a sirup. —2. (Wholesale.) Extract of sarsaparilla 3 lbs.; boiling water 3 quarts; dissolve, strain, and add white sugar 12 lbs. Alterative and tonic. Dose 2 to 4 drs. SIRUP OF SARSAPARILLA, (COM POUND.) Syn. Syrupus Sarz* Compositus. Sy- rop de Cusinier. Prep. (P. U. S.) Sarsaparilla, bruised, lb. ij.; guaiacum wood, rasped, ^'ij ', red roses, senna, and liquorice-root bruised, of each ^ij ; diluted alcohol 10 pints, (wine measure ;) mace- rate for 14 days, express, filter thrcagh paper, and evaporate in a water bath to 4£ pints; then add sugar lb. viij, and when cold oils of sassafras and aniseed, of each 5 drops, and oil of partridge berry (gualtheria procumbens) 3 drops, previously tritura- ted with a little of the sirup. An excellent prepa- ration. Dose, f ^ss, 3 or 4 times a day, as an al- terative, tonic, and restorative. *** The sirup of the P. Cod. is made with water instead of spirit, and is vastly inferior as a remedy. SIRUP OF SENNA. Syn. Syrupus Senn*, (P. L. & E.) Prep.—l. (P. L.) Senna giiss; bruised fennel seed 3x; boiling water 1 pint; macerate with a gentle heat for 1 hour, strain, add manna §iij ; white sugar f xv, and evaporate to a proper consistence.—2. (Wholesale.) The manna is usually omitted.—3. (P. E.) Senna §iv ; boiling water f ^xxiv; strain, add treacle §xlviii, and evaporate to a proper consistence. Cathartic. Dose. 1 to 4 drs. SIRUP, SIMPLE. Syn. Syrupus, (P.L.) Syrup- us Simplex, (P. E. & D.) Prep.—l. (P. L.) White sugar lb. x ; water 3 pints; dissolve.—2. (Whole- sale) Double refined sugar 44 lbs.; distilled water 2£ gallons ; make a sirup. It should be as trans- parent as water. Used as a flavoring, and to give cohesiveness and consistence to pulverulent sub- stances in the preparation of electuaries, pills, &c. (See Capillaire, and the introductory remarks on Sirup.) SIRUP OF SQUILLS. Syn. Syrupus Scill*. Prep.—1. (P. E.) Vinegar of squills 3 pints; white sugar lb. vij; dissolve by a gentle heat.—2. (Whole- sale.) Vinegar of squills 14 lbs., (perfectly trans- parent ;) double refined sugar 28 lbs.; dissolve in a stoneware vessel in the cold, or at most by a very gentle heat. It should be as clear as water, and nearly colorless. Dose. 1 to 2 drs., as an ex- pectorant in chronic coughs and asthma. In large doses it proves emetic. SIRUP OF TOLU. Syn. Balsamic Sirup. Svrupus Tolutanus, (P. L. & E.) Syr. Balsami Tolutani, (P. D.) Prep.—l- (P. L.) Balsam of Tolu 3x; boiling water 1 pint; boil in a covered vessel for £ an hour, frequently stirring, cool, strain, and add sugar lb. iiss.—2. (P. E.) Simple sirup (warm) lb. ij; tincture of Tolu §j; mix well to- gether in a close vessel.—3. (Wholesale.) Warm SMA 510 SNU water 23 lbs.; add tincture of Tolu, gradually, until it will bear no more without becoming opaque, constantly shaking the bottle, cork down and oc- casionally agitate till cold; filter through paper, add double refined sugar 44 lbs.; and dissolve in a close vessel, by a gentle heat in a water bath. This sirup should be clear and colorless as water, but as met with in the shops it is usually milky. Pectoral. Dose. 1 to 4 drs. in mixtures. SIRUP, VELNO'S VEGETABLE. Accord- ing to Dr. Paris and Sir B. Brodie, this celebrated nostrum is prepared as follows:—Young and fresh burdock root, sliced fij; dandelion root ^j' fresn spearmint, senna, coriander seed, and bruised liquorice root, of each 3iss ; water 1£ pints ; boil down gently to a pint, strain, add lump sugar 1 lb., boil to a sirup, and add a small quantity of corro- sive sublimate, previously dissolved in a little spirit. Used as an alterative and purifier of the blood. SIRUP OF VINEGAR. Syn. Syrupus Aceti. Prep. (P. E.) Vinegar (French wine) f §xj ; white sugar ^xiv ; make a sirup. Dose 1 dr. to 1 oz. as an expectorant in coughs and colds, or diffused through any mild diluent, as a drink in fevers. SIRUP OF VIOLETS. Syn. Syrupus Viol*. (P. E. & D.) Syr. Violarum. Prep.—l. (P. E.) Fresh violets 1 lb.; boiling water 2£ pints ; infuse for 24 hours in a covered vessel of glass or earthen- ware, strain off the liquor, (with gentle pressure,) filter, add white sugar lb. viiss, and dissolve.—2. (Wholesale.) Double-refined white sugar 66 lbs.; anthokyan* 11 lbs.; water 22 lbs. or q. s.; dissolve in earthenware. Gently laxative. Dose. A tea- spoonful for an infant. *** Genuine sirup of vio- lets should have a lively violet blue color, and should be reddened by acids and turned green by alkalis, and should smell and taste of the flowers. It is frequently used as a test. A spurious sort is met with in the shops, which is colored by litmus, and slightly scented by orris root. The purest sugar, perfectly free from either acid or alkaline contamination, should alone be used in its manu- facture. The P. E. orders the infusion to be strain- ed without pressure, and the P. Cod. and other Ph. direct je flowers to be first washed in cold water. SIZE. Obtained like glue from the skins of ani- mals, but is evaporated less, and kept in the soft state. SMALTS. Syn. Powder Blue. Smalta. Azu- rum. Prep. I. Roast cobalt ore to drive off the arsenic, make the residuum into a paste with oil of vitriol, and heat it to redness for an hour ; pow- der, dissolve in water, and precipitate the oxide of iron by carbonate of potash, gradually added, until a rose colored powder begins to fall, then decant the clear, and precipitate by a solution of silicate of potash prepared by fusing together for 5 hours a mixture of ten parts of potash, 15 parts of finely- ground flints, and 1 part of eharcoal. The precip- itate, after being dried, may be fused and powder- ed. Very fine. II. Roasted cobalt ore and potash, of each 1 part; silicious sand 3, parts ; fus^ together, cool, and powder. Used in painting, to color glass, and b) get up linen. * The expressed juice of violets, defecated, gently heat- ed in earthenware to 192°, skimmed, cooled, filtered, Alittlt spirit added, and again filtered. SNUFF. Syn. Tabac, (en poudre, Fr.) The finer kinds of snuff pre made from the best de- scription of tobacco, separated from the damaged leaves ; but the ordinary snuffs of the shops are mostly prepared from the coarser and damaged portions, the stems or stalky parts that remain from the manufacture of shag tobacco, the dust or Dowder sifted from the bales, and 'the fragments that are unfit for other purposes. To impart to the dried leaves the characteristic odor and flavor of to- bacco, and to render them agreeable to " smokers" and " snuffers," it is necessary that they should undergo a certain preparation, or kind of fermenta- tion. If a fresh green leaf of tobacco bo crushed between the fingers, it emits merely the herbaceous smell common to most plants ; but if it be tritu- rated in a mortar along with a very6mall quantity of quicklime or caustic alkali, it will immediately exhale the peculiar odor of manufactured tobacco. This arises from the active and volatile ingredients being liberated from their previous combination, by the ammonia developed by fermentation, or the action of a stronger base. Tobacco contains a considerable quantity of muriate of ammonia, and this substance, as is well known, when placed in contact with lime or potassa, immediately evolves free ammonia. If we reverse the case, and satu- rate the excess of alkali in prepared tobacco by the addition of any mild acid, its characteristic odor will entirely disappear. In the preparation of to- bacco previously to its manufacture into snuff, these changes are effected by a species of fer- mentation. The tobacco, either unprepared or cut into pieces, is placed in layers or heaps, and sprinkled with a weak solution of common salt and water, (about the sp. gr. 1*107,) or sauce as it is called ; the salt being added to prevent the to- bacco becoming mouldy, and to keep it moist, as well as to moderate the fermentation. Molasses is also frequently added to the sauce when a violet or dark-colored snuff is desired, and some persons with a like intention add a decoction or solution of extract of liquorice. I am informed, however, that pure water, without any addition, is quite sufficient to promote and maintain the perfect fermentation of tobacco, and that of late years the larger and more respectable houses have employed nothing else. The leaves soon become hot, and evolve ammonia ; during this time the heaps require to be occasionally opened up and turned over, lest they become too hot, take fire, or run into the putrefac- tive fermentation. The extent to which the pro- cess is allowed to proceed varies with different kinds of snuff, from one to tfiree months. When the leaves have arrived at the proper state, they are sufficiently dried to bear being pulverized. This is either performed in a mill, or with a kind of pes- tle and mortar. While powdering, the tobacco should be frequently sifted, that it may not be re- duced to too fine a powder, and it should be moist- ened with rose or orange-flower water, or eau d'ange, which are the only waters fit for the supe- rior kinds of snuff. This moistening is usually re- peated several times. Tonca beans are put into snuff-boxes to scent the snuff, but the concentrated essence of tonca beans is now mostly used ; the leaves of orchis fusca, and those of several other species of orchides that have the scent of the tonca bean, are also used to scent snuff. French snuff SNU 511 SOA is scented with the root of calamus aromaticus. During the grinding of tobacco it is but too fre- quently mixed with dark-colored rotten wood, va- rious English leaves, coloring and other matter, which substances are added by the fraudulent manufacturer to reduce the cost. It is a general practice with many dealers to add ammonia to their snuffs to increase their pungency. I have seen 1 cwt. of powdered sal ammoniac sent at one time to a certain London tobacconist. Powdered glass and hellebore are also frequently added for a like purpose. The moist kinds of snuff are gener- ally drugged with pearlash, for the triple purpose of keeping them moist and increasing their pun- gency and color. The dry snuffs, especially Welsh, are commonly adulterated with quicklime, the particles of which may often be distinguished by the naked eye. This addition causes its biting and desiccating effect on the pituitary membrane. Scotch, Irish, Welsh, and Spanish snuffs, Lundy- foot, tyc, are examples of the dry snuffs. Among moist snuffs or rappees, brown black, Cuba, ca- rotte, 'j j sul- phuric acid §'v ; diluted with water §iij ; placed in a retort; heat being applied to promote the ac- tion, and the gas being purified by passing through f §v of water before it enters the alkaline solution. Used as an antiseptic, disinfectant, and bleaching liquid. Dose. 20 to 30 drops in any bland fluid, in scarlet fever, sore throat, aQd distil in a glass retort, furnished with a tube reaching nearly to the bottom of a bottle containing 2 pints and f 3ij of rectified spirit, and kept well cooled. A sand heat is to be employed, and the distilla- tion continued as long as any thing passes ovei Dose. £ to 1 dr.; in hysteria, flatulent colic nervous debilitv, &.C. SPIRIT OF AMMONIA, (AROMATIC- Syn. Alcohol Ammoniatum Akomaticum. Spirit of Sal Volatile. Spiritus Ammoni* Aromaticus, (P. L. E. & D.) Prep.—1. (P. L.) Muriate of ammonia %v; carbonate of potash ^viij ; bruised cinnamon and cloves, of each 3ij ; fresh lemon peel ^iv ; rectified spirit and water, of each £ gallon ; mix and distil 6 pints.—2. (P. D.) Spirit of ammonia 2 pints, (wine measure ;) oil of lemon 3ij ; bruised nutmegs §ss ; do. cinnamon 3iij ; digest for three days, then distil 1£ pints.—3 (P. E.) Spirit of ammonia f 5viij; oil of lemon f3j*; oil of rosemary f3iss ; dissolve. Dose. £ to 2 drs., diluted with water, in lowness of spirits, debility, hysteria, dyspepsia, &c. SPIRIT OF AMMONIA, (FETID.) Syn. Alcohol Ammoniatum Fostidum. Spiritus Am- moni* Fcstidus, (P. L. E. & D.)—1. (P. L.) As spirit of ammonia, but adding asafcetida §v, before distillation.—2. Spirit of ammonia 1 lb.; tincture of asafcetida 5ss; mix. Dose. A tea- spoonful in hysteria, &c. SPIRIT OF ANISEED. Syn. Spiritus Anisi. Prep.—1. (P, L.) Bruised aniseed %x; proof spirit 1 gallon ;• water 1 quart, (or q. s.;) distil 1 gallon.—2. (Sp. Anisi Compositus, P. D.) Anise and angelica seeds, of each lb. ss ; proof spirit 1 gallon ; water q. s.; distil 1 gallon. When colored with saffron, or sap green, the last i sembles the Irish Usquebaugh. (Montgomery.) Dose. 1 to 4 drs. SPIRIT OF CARAWAY. Syn. Spiritub Carui, (P. L. E. & D.) Prep. (P. L.) Bruised caraway seeds ^xxij ; proof spirit 1 gallon ; water 1 quart, or q. s. ; distil 1 gallon. Aromatic and carminative. Dose. 1 to 4 drs. " Sweetened with sugar, this spirit is drunk in Germany as a dram, (Kumelliqueur; Kiimelbrandtwein.") (Pereira.1 SPIRIT OF CASSIA. Syn Spiritus Cassi*. Prep. (P. E.) Coarsely-powdered cassia lb.j; proof spirit 7 pints; water 1£ pints, or q. s.; draw off 7 pints. Dose. 1 to 4 drs. *** Almost universally substituted for spirit of cinnamon. SPIRIT OF CINNAMON. Syn. Spiritus Cinnamomi,*(P. L. E. & D.) Prep.—l. (P. L.) Oil of cinnamon 3ij; proof spirit 1 gallon ; water 1 pint, or q. s.; distil 1 gallon.—2. (P. E.) As spirit of cassia, P. E., using cinnamon bark. Aro- matic and stimulant Dose. 1 to 4 drs. SPIRIT OF CYTHEREA. Prep. Spirits of violets, tuberose, clove-gillyflower, jasmin, (No. 2,) roses, (No. 2,) and portugal, of each 1 quart; orange-flower water 2 quarts ; mix. A delightful perfume. SPIRIT, DYER'S. Prep. Dyer's aquafortis 7 lbs.; grain tin 1 lb.; dissolve, with agitation. Used in dyeing with lac dye; for cochineal use less tin.—2. Nitric acid 3 lbs. ; sal ammoniac 1 lb.; tin q. s. to dissolve without effervescence. Used with cochineal. (See Tin Mordants.) SPIRIT OF THE FLOWERS OF ITALY. Syn. EspRr de Fleurs. Prep. Spirits oi SPI 519 SPI roses, (No. 1,) jasmin, (No. 2,) oranges, (No. 3,) and cassia, (No. 2,) of each 4 pints ; orange-flower water 3 pints ; mix. Very fragrant. SPIRIT OF HARTSHORN. Syn. Liquor Volatilis Cornu Cervi. Originally distilled from hartshorn, but is now universally made by dissolv- ing sesquicarbonate of ammonia in water, so as to form a solution of the sp. gr. 1*060. The pun- gency is commonly increased by passing a little ammoniacal gas into it, or by adding a snuill quantity of liquor of ammonia. Dilute liquor of ammonia is also frequently sold for spirit of harts- horn. SPIRIT OF HORSERADISH, (COM- POUND.) Syn. Spiritus Armoraci* compos- itus, (P. L. & D.) Prep. (P. L.) Sliced horse- radish and dried orange-peel, of each ^xx ; bruised nutmegs 3v; proof spirit 1 gallon; water 1 quart, or q. s.; distil 1 gallon. Stimulant tnd diuretic. Dose. 1 to 4 drs. SPIRIT OF JUNIPER, (COMPOUND.) Syn. Spiritus Juniperi compositus, (P. L. E. & D.) Prep. 1. (P. L.) Bruised juniper berries §xv ; do. caraway and fennel, of each §ij; proof spirit 1 gallon; water 1 quart, or q. s.; distil 1 gallon. 2. (Wholesale) Oil of juniper 3ij; oils of caraway and sweet fennel, of each 3ss; proof spirit 5 quarts; if foul, filter through magnesia. Stimulant and diuretic. Dose. 2 to 4 drs. *** This spirit, when mixed with twice or thrice its weight of proof spirit, and sweetened with a little sugar, makes no bad imitation of Holland gin. SPIRIT OF LAVENDER. Syn. Spiritus Lavandul*. Prep. (P. L.) Fresh lavender lb. iiss; rectified spirit of wine 1 gallon; water 1 quart, or q. s.; distil 1 gallon. 2. (Wholesale) English oil of lavender 3 oz.; rectified spirit 1 gallon; dis- dolve. Cordial and fragrant. SPIRIT OF MURIATIC ETHER. Syn. Dulcified Marine Acid. Clutton's Febrifuge Spirit. Spiritus Salis Dulcis. Sp. Muriatico- *THEREUS. jEtHER MuRIATICUS AlCOHOLICUS. Prep. 1. (P.E. 1735.) Muriatic acid 1 part; rec- tified spirit 3 parts; digest some days, and distil in a sand-bath. 2. Hydrochloric ether and spirits of wine, equal parts; mix. Dose, f 3j to f3iij, in dyspepsia, liver complaints, hectic fever, SPIRIT OF NITRIC ETHER. Syn. Sweet Spirits of Nitre. Nitre Drops. Nitre Dulcis. Spiritus Nitri Dulcis, (P. L. 1745.) Sp. ./Ethe- ris Nitrosi, (P. L. 1788.) Sp. ^Etheris Nitrici, (P. L. 1809, and since, & P. E.) Sp. ^Ethereus Nitrosus, (P. D.) Prep. 1. (P. L.) Rectified spirit lb. iij ; nitric acid f iv; mix gradually, and distil ffxxxij. *** An earthenware still and con- densing worm should be employed. 2. (P. E.) Pure hyponitrous ether (P. E.) 1 part; rectified spirit 4 parts; mix. 3. (Dr. Geisler.) 24 oz. of al- cohol of 0*840 are mixed with 4 oz. sulphuric acid, left to stand for 8 days, then poured into a retort containing 4£ oz. of dried nitre; 20 oz. of the liquid are distilled over at a gentle heat, which is then rectified over magnesia. Copper retorts and tinned cooling apparatus may be employed in this process without any disadvantage. The prepara- tion is pretty constant in its amount of ether. Mixing of nitric ether with alcohol cannot afford bji offii**«nal Spir. ather. nitr., as it always contains aldehyd.* Preservation over magnesia is not practicable, as it constantly gives rise to decompo- sition and formation of nitrite of magnesia. (Arch. der Pharm., xxviii. p. 60.) Remarks. Pure sweet spirits of nitre scarcely reddens litmus paper, and gives off no bubbles of carbonic acid gas, on the addition of carbonate of soda. Sp. gr. 0-834. (P. L.) "When agitated with twice its volume of concentrated solution o. muriate of lime, 12§ of ether slowly separates. Density 0*847." (P. E.) Dose. J to 3 drs. as a feb- rifuge and diaphoretic. *%* The mass of the sweet spirits of nitre of the shops is of very inferior quality, and is scarcely, if ever, made directly from spirit that has paid the duty. One and a very large portion is obtained from Scotland, an- other from the manufacturers of fulminating mer- cury, and a third, and in fact, the principal part, from certain persons in the neighborhood of the metropolis, who employ contraband spirit for its preparation, as this article is not under the excise. The truth of the above is well known, as the price at which this spirit is sold is alone sufficient testi- mony. The price of rectified spirit, purchased in quantity at the distillery, is from 16s. 4ei. to 16s. tid. per gallon, or about 2s. Od. per lb., (av.,) whereas the sweet spirits of nitre, sp. gr. *850, is commonly and publicly sold, in quantity, at Is. Id. to Is. 9d. per lb., (av.,) and I have seen it pur- chased so low as Is. 6d. This calls for the inter- ference of the excise. The spirit obtained from the manufacturers of fulminating mercury fre- quently contains prussic acid, which may be dis- covered by testing. (See Prussic Acid.) SPIRIT OF NUTMEG. Syn. Spiritus Nu- cis Moschat*. Sp. Myristic*, (P. L. E. & D.) Prep. (P. L.) Bruised nutmegs §iiss; proof spirit 1 gallon; water 1 pint, or q. s.; distil a gallon. Cordial and carminative. Dose. 1 to 4 drs.; mostly used to flavor mixtures and draughts. SPIRIT OF PENNYROYAL. Syn. Spir- itus Pulegii. Sp. Menth* Pulegii, (P. L.) Prepared like spirit of peppermint, P. L. Stimu- lant ; antispasmodic; carminative. Dose. £ to 2 drs. SPIRIT OF PEPPERMINT. Syn. Spiritus Menth* Piperit*, (P. L. & D.) Sp. Menth*, (P. E.) Prep. 1. (P. L.) Oil of peppermint 3iij ; rectified spirit 1 gallon ; water 1 pint, or q. s.; dis- solve, and distil 1 gallon. 2. Omit the water and distillation. 3. (P. E.) Green peppermint lb. iss; proof spirit 7 pints ; macerate 2 days ; add water q. s., and distil 7 pints. Dose. £ to 2 drs. (See Essence of Peppermint.) SPIRIT OF PIMENTO. Syn. Spirit of Allspice. Spiritus Piment*, (P. L. E. &. D.) Bruised allspice §iiss ; proof spirit 1 gallon ; water 1 pint, or q. s.; distil a gallon. Carminative and stomachic. Dose. 1 to 4 drs., in mixtures, &c. SPIRIT, PYROACETIC. Syn. Pyroacetic Ether. Acetone. Esprit Pyroacetique, (Fr.) Brennzlicher Essiggeist ; Mesit, (Ger.) Spir- itus Pyroaceticus, (Lat.) An ethereal liquid, obtained by passing the vapor of hydrated acetic acid through a porcelain tube heated to dull red- ness * or by the dry distillation of the acetates, the bases of which retain carbonic acid at a red heat. * According to Prof. Liebig, this aldehyd is an essential constituent of the officinal nitric ether. SPI 520 STA The acetates of lime, manganese, zinc, lead, iron, and copper, thus yield it in quantities decreasing in the order in which they stand. It is chiefly formed during the second half of the process ; the liquor which comes over then should be set apart, and decanted from empyreumatic oil, &c. Pyro- acetic spirit is also obtained in considerable quan- tity by distilling the tarry deposite of crude pyro- ligneous acid. The product of either process is purified by rectification, first from quicklime, and next from bone-black. *„* Pure acetone is a clear colorless liquid; miscible with water, alco- hol, aud ether, in all proportions ; has a pungent taste, resembling that of peppermint, and a pene- trating and slightly empyreumatic smell; sp. gr. 0-7922 ; boils at 132° ; very inflammable, giving a brilliant flame without smoke ; and dissolves resins and essential oils. Strong sulphuric acid converts it into a species of ether. It is used in lamps, and to dissolve gums by the hatters. SPIRIT, PYROXILIC. Syn. Pyroligneous Spirit. Wood Naphtha. Hydrate of Oxide of Methule. Bihydrate of Methylene. Com- mercial pyroxilic spirit is obtained by saturating crude pyroligneous acid after it is separated from the tar, with quicklime and distilling, when about 1}} of spirit is obtained, which is purified by 2 or 3 rectifications. In this state it contains acetone and other inflammable fluids, from which it may be separated by distilling it along with an excess of muriate of lime, in a water-bath, as long as any volatile matter passes over, which are the impuri- ties. A quantity of water equal to the spirit em- ployed is then added, and the distillation continued. The product is now pyroxilic spirit combined with a little water, from which it may be freed by dis- tillation along with quicklime. *** Pure pyroxilic spirit is a transparent, colorless liquid, having a penetrating ethereal 6mell; it is very inflamma- ble, yielding a pale blue flame, by which it may be readily distinguished from pyroacetic spirit. It is neutral to test-paper, mixes with water, alcohol, and ether; boils at 150° ; sp. gr. 0-798 at 68° F. (Lieiig.—0-824, Ure.) It is used to dissolve resins and oils. SPIRIT, RAISIN. From raisins fermented along with water, and the wash distilled by a quick fire. Used to give a brandy flavor to malt spirit 1 gallon added to 150 gallons of plain spirit, along with some coloring, and a little catechu, makes a very decent " British brandy." SPIRIT OF ROSEMARY. Syn. Spiritus Rosf.marini. (P. L. E. & D.) Prep. 1. (P. L.) Oil of rosemary 3ij ; rectified spirit 1 gall.; water 1 pint, or q. s.; distil a gallon. 2. As last; but omit the water and distillation. 3. Rosemary tops lb. iiss; proof spirit 1 gallon ; water q. s.; distil a gallon. Fragrant. SPIRIT OF SPEARMINT. Syn. Spiritus Menth* Viridis, (P. L. & D.) Prep. (P. L.) As spirit of peppermint, P. L. Dose and use the same. SPIRIT OF SOUP HERBS. (Kitchiner's.) Prep. Lemon thyme, winter savory, sweet mar- joram, and sweet basil, of each, 1 oz.; grated lemon-peel and shalotes, of each, $ oz.; bruised celery seed 1 dr.; proof spirit 1 quart; macerate 10 days and e'rain. Used as a flavoring by cooks. f SPIRIT OF SULPHURIC ETHER Syn. Sweet Spirit of Vitriol. ./Ether Sulphuricus I cum Alcohole. Spiritus Vitrioli Dulcis. Sp. .Etheris Sulphurici, (P. E.) Do. do. Vitriolici. Prep. (P. E.) Sulphuric ether 1 pint ; rectified spirit 1 quart; mix. Sp. gr. 0-809. It should be neutral to test paper, mix (clear) with water, and when shaken with twice its volume of concentra- ted solution of muriate of lime, 28°- of ether should separate. Dose. f3j to f3iij; as a stimulant and anodyne. SPIRIT OF SULPHURIC ETHER, (COM- POUND.) Syn. Hoffman's Anodyne Liquor. Mineral do. do. Spiritus ^Etheris Sulphurici Compositus, (P. L.) Do. do. Vitriolici Comp. Prep. (P. L.) Sulphuric ether f ^viij; rectified spirit f fxvj; ethereal oil f3iij; mix. Dose, f3ss to f 3ij; as an anodyne. SPIRIT OF SULPHURIC ETHER, (ARO- MATIC.) Syn. Aromatic Spirit of Ether. Sweet Elixir of Vitriol. Spiritus ^Etheris Aromaticus. Elixir Vitrioli Dulce. Prep. (P. L. 1824.) Bruised cinnamon 3iij ; cardamoms 3iss; long pepper and ginger, of each, 3j; recti- fied spirit 10 oz.; sulphuric ether 5 oz.; mix, and digest 14 days. The last two preparations are also frequently called " Sweet Elixir of Vit- riol." SPONGE, BURNT. Syn. Spongia Usta. Pulvis Spongi* Ust*. Pref (P. D.) Beat pieces of sponge to remove the *«ind and stones, then burn it in a closed iron vessel till it becomes black and friable; allow it to cool, excluded from the air, and reduce it to powder. Used in bron- chocele and scrofulous complaints. Dose. 1 to 3 drs. made into an electuary or lozenges. %* If good it evolves violet fumes of iodine when heated in a flask along with sulphuric acid. The burnt sponge of the shops is made from the cuttings and unsaleable pieces. SPONGE, PREPARED. Syn. Spongia Ce- rata. Sponge dipped into melted wax and com- pressed between 2 iron plates till cold. Used by surgeons to make sponge tents. SPONGE, WHITE. Syn. Bleached Sponge. Spongia dealbata. Prep. Soak the sponge in very dilute muriatic acid to remove calcareous matter, then in cold water, changing it frequently, and squeezing the sponge out each time; next soak it in water, holding a little sulphuric or sul- phurous arid, or chlorine in solution, changing the acid frequently till the sponge is sufficiently bleached; last, repeatedly wash and soak in clean water, and scent with rose or orange-flower wa- ter. STARCH. Syn. Amidon ; Fecule, (Fr.) Staerke, (Ger.) Amylum, (Lat.) A/tvUr, (Gr., from a, privative, and /ivXt], a mill.) One of the commonest frauds practised upon the profession and the public is the mixing cheap kinds of starch with arrow-root, and vending manufactured for genuine tapioca, sago, and other articles of diet, used for invalids and children. M. Gobley has proposed a method for the ready detection of these frauds, which is very simple, consisting merely in placing various kinds of starch, in a mois* state in watch-glasses, and covering them ove witn a bell-glass, under which there is also placed iodine, and leaving them for 24 hours. The vapor of the ST1 521 STR Iodine acts upon, and colors all kinds of starch, but the color it imparts varies with the different kinds. Thus the vapor of iodine colors— Wheat-starch, violet. Potato-starch, dove gray. Genuine arrow-root, bright chocolate color. Genuine tapioca, unbroken, uniformly yellow- sk. Ditto, powdered, chamois color. White sago, entire, some granules violet gray, others yellowish. Ditto, powdered, chamois color. Dextrine, no coloring. This method, at all events, renders the detec- tion of potato-starch very easy, and also whether common or potato starch is substituted for tapioca powder, and probably some modification of it will render it still further applicable. (Jour, de Pharm., April, 1844.) STEARIC ACID. Syn. Stearine. Hypo- t) margarulic Acid. Prep. I. (Commercial.) Tal- low is boiled in large wooden vessels, by means of high-pressure steam, with about 16§ of hydrate of lime (eq. to 11 g of pure lime) for 3 or 4 hours till the combination is complete, when the whole is allowed to cool. The stearate of lime is then transferred to another wooden vessel, and decom- posed, by 4 parts of oil of vitriol diluted with wa- ter, for every 3 parts of slaked lime employed, the action being promoted by steam heat. After re- pose the liberated fat is decanted from the sedi- ment of sulphate of lime and water, and is well washed with water, and by blowing steam into it; it is next reduced to shavings by means of a num- ber of knives worked by machinery, and in this divided state is placed in canvass bags and sub- mitted to the action of a powerful hydraulic press, which expels a large portion of the oleine ; the pressed cakes are then a second time exposed to the action of steam and water, again cooled and coarsely powdered, and again submitted to the joint action of steam and pressure ; they are last- ly melted and cast into blocks for sale.—2. (Pure.) Repeatedly crystallize commercial stearic acid from hot alcohol, till its melting point becomes constant at 167°. Brilliant pearly scales, soluble in ether and hot alcohol, and forming salts called stearates with the bases. The commercial acid is used to make candles. STEAROPTENE. The name given by Her- berger to the concrete portion or camphor of vola- tile oils. Bizio calls it stereusin. STILL. (From stillare, to drop.) A vessel or apparatus employed for the distillation of liquids on the large scale. The forms of stills, and the materials of which they are made, vary according to the purposes for which they are intended. The following figure represents the most common and useful apparatus of this kind. After the fluid is put into the still, the head must be placed on and connected with the refrigerator, and the joints must be all securely luted. For ordinary liquids, a stiff paste made with linseed meal and water, to which a little chalk may be added, will answer well for this purpose The worm tub should be supplied with cold water in sufficient quantity to preserve its contents at a proper temperature; and the application of heat should be so regulated that the liquid may drop from the end of the 66 tor quite cold and unaccompanied with a, Body of still, which may be either placed in a steam jacket, or in a brick furnace. 6, Still head or capital. c, Worm tub. d, Pewter worm, or refrigerator. e, Cold water pipe. /, Waste pipe. g, Receiver. STRAINED GALBANUM. This is either prepared by boiling the gum resin in water until dissolved, then straining it through a canvass or hair sieve and evaporating; or by melting it in the dry state by heat cautiously and quickly ap- plied, and straining it through a piece of coarse canvass stretched across a frame. (See Filtra- tion.) The Strained Galbanum of the shops is mostly reduced with inferior drugs, and very fre- quently a factitious article is substituted. The following forms are those which are frequently employed in the wholesale trade :— 1. (Reduced Strained Galbanum.)—a. True galbanum 9 lbs.; strain as above, and when near- ly finished, add black resin (clean) 3 lbs.; Venice turpentine 2 lbs.; mix well. Product. «12 lbs.— 6. True strained galbanum and black rosin, of each, 6 lbs.; strained asafcetida 1 £ oz.; mix, and add Venice turpentine 3 lbs. Product. 14£ lbs. 2. (Factitious Strained Galbanum.) Black rosin 4 lbs.; Venice turpentine 3 lbs. ; strained asafcetida 2 oz.; oils of juniper and fennel, of each, J oz.; water \ pint; mix s. a. The small and waste of the galbanum chests are also usually boiled up, strained, evaporated, and added to the above to improve them. STRAPPING. Spread adhesive-plaster. Used \ to dress wounds, &c. STRAW PLAIT is bleached by exposing it to the fumes of burning sulphur in a close chest or box, or by immersing it in a weak solution of chlo- ride of lime, and afterwards washing it well in water. Water strongly acidulated with oil of vitriol or oxalic acid, is also used for the same pur- pose. Straw may be dyed with any of the simple liquid dyes. STRONTIA. Syn. Strontian. Strontitfs Oxide of Strontium. The oxide of a metal called strontium. It greatly resembles baryta. Hynr-tte of strontia is freely soluble in boiling water, a .id the saturated solution deposites crystals on cooling The solution exhibits an alkaline reaction, and like baryta is precipitated white by sulphuric acid, and the alkaline sulphates and carbonates. It is dis- tinguished from baryta by its inferior solubility SUC 522 SUG and by its soluble salts giving a red tinge to flame, while the salts of baryta impart a yellow tinge. The salts of strontia may all be prepared by dis- solving the native carbonate in the respective acids. The nitrate is tho only one met with in commerce, and is employed to form colored fireworks. The metal strontium is obtained in a similar way to barium. STRYCHNINE. Syn. Strychmn-a. Strych- nia, (P. L. & E.) Vauquelina. Tetanine. Prep. Precipitated from a solution of the sulphate, by ammonia. The sulphate is formed by digesting a watery solution of alcoholic extract of nux vomica with magnesia, pouring off the liquid, and boiling the residue, pressed nearly dry in cloth, in rectifi- ed spirit. The spirit having been distilled eff, the residue is dissolved in diluted sulphuric arid, and Bet aside to crystallize. The nitrate and other salts are obtained by dissolving strychnia in the diluted acids, and crystallizing. *** A white powder, soluble in 7000 parts of cold water, to which it imparts intense bitterness ; soluble in hot alcohol of 0*850, and deposited in crystals as the solution cools. It is alkaline to test paper ; " Ni- tric acid strongly reddens it; a solution of 10 grs. in f3iv of water and f3j of pyroligneous acid, when decomposed by f §j of concentrated solution of carbonate of soda, yields on brisk agitation a coherent mass, weighing when dry 10 grs., and entirely soluble in solution of oxalic arid." (P. E.) " It melts by heat, and if more strongly urged, is totally dissipated." (P. L.) It is a most dreadful poison, speedily producing tetanus and death. Dose of strychnia and its salts, one-twentieth to one-sixteenth of a gr., gradually and cautiously increased till it affects the muscular system; in paralysis, tic douloureux, &c. It is also used ex- ternally, i gr. at a time. STYRAX, STRAINED, (FACTITIOUS.) Prep.—4- Balsam of Peru 1 lb.; balsam of tolu 4 lbs.; mix.—2 Gum benzoin 8 lbs.; liquid styrax 6 lbs. ; balsam of tolu 3 lbs.; do. of Peru 2 lbs. ; N. S. W. yellow gum 7 lbs.; rectified spirit 7 gal- lons ; digest with frequent agitation for a fortnight, strain and distil off the spirit (about 5£ galls.) till the residue has a proper consistence. Prod. 24 lbs.—3. Gum benzoin 6 lbs.; gum styrax 3 lbs. ; balsam of tolu 2£ lbs.; Socotrine aloes £ lb.; rec- tified spirit 6 galls. ; digest and distil as last, and add to the product balsam of Peru 6 oz.; olive oil 4 oz.—4. Liquid storax 1 oz.; balsam of tolu 2 lbs.; rectified spirit q. s. STYRACINE. A name given by Simon to a crystallizable substance extracted from storax. SUBERIN. Cork deprived of all its soluble matter by the successive action of water and al- cohol. By long boiling in nitric acid, and then evaporating the fluid to one half, it yields crystals of suberic acid, which may be purified by re-solu- tion and crystallization. Margaric acid treated in the same way also yields suberic acid. With the bases it forms salts called suberates, many of which are soluble. SUCCINIC ACID. Syn. Volatile Salt of Amber. Acid of do. Sal Succini. Acidum Succinum, (P. D.) Prep. From the impure acid obtained during the distillation of oil of amber, by wrapping it in bibulous paper and submitting it to strong pressure, to remove the oil, and then resub- liming it. It may also be prepared from the mo- ther liquor of suberic acid, by evaporation and di- gesting the resulting crystals in ether, to remove suberic acid. Succinic acid forms salts with the bases termed succinates.—Succinate of ammonia is used as a test for iron.—Succinamide is formed by the action of ammonia water on succinic ether; —bisuccinamide, by heating anhydrous succinic acid in dry gaseous ammonia.—Succinone is an oily liquid obtained by distilling succinic acid with lime. Dose. 5 to 20 grs. as an antispasmodic and diuretic. Seldom used. SUET. Syn. Sevum ; Sebum, (Lat) This is prepared from the fat of the loins of the sheep or bullock, by melting it by a gentle heat.—Mutton suet (Sevum, P. L., Fat, P. E., Adeps ovillus, P. D., Sevum ovillum, Do. prteparatum) is used in medicine as the basis of several ointments, cerates, SUET, MELILOT. Syn. Sevum Meliloti. Prep. Suet 8 lbs.; melilot leaves 2 lbs.; boil till q crisp and strain. Used by farriers, and to make melilot plaster. SUGAR. Syn. Sucre, (Fr.) Zucker, (Ger) Saccharum, (Lat.) The properties and uses of sugar are too well known to require description. It constitutes the sweet portion of animal and vegetable substances. The sugar consumed ia England is prepared from the juice of the sugar cane. A similar species of sugar, but of inferior quality, is obtained from the juice of the beet-root and sugar maple. There are also other kinds of sugar procured from grapes and other ripe fruit, (grape sugar) from milk, (sugar of milk) from manna, (mannite) from mushrooms, liquorice root &c.; and from glue, fecula, sawdust, &c, by the action of dilute sulphuric acid. Cane, beet, and maple sugars possess the greatest sweetening power, which is more than double that of the other varieties. Pur. Sugar is largely adulterated. Pure cane and beet sugars may be known by their solutions bending the luminous rays in circumpolarization to the right, whereas grape and fecula sugars bend it to the left. Pure cane sugar boiled in a solution of caustic potassa remains colorless, but if starch sugar is present the liquid turns brown. (Chevallier.)—A filtered solution of 33 grs. of cane or beet sugar in 1 oz. of water, mixed with 3 grs. of pure caustic potassa, and then agitated with 1£ grs. of sulphate of copper in a close vessel, remains clear, even after the lapse of several days; but if starch sugar is present, a red precipitate is formed after some time, and if present in considerable quantity, the copper will be wholly converted into oxide within 24 hours ; the solution first turns blue or green, and then entirely loses its color. (E. Krantz.) Of late years moist sugar has been largely adulterated with the sweet waste iiquor (solution of glycyrrhine) of the stearine manufac- tories ; but this fraud may be detected by the in- ferior sweetness, and by the moist and dirty ap- pearance of such sugar. SUGAR, ALUM. Syn. Alumen Sacchari- num. Prep. Powdered alum made into small sugar-loaves, with white of egg and rose-water. Used to make an astringent wash. SUGAR, BARLEY. Prep.—l. Saffron 12 grs.; hot water q. s.; infuse till colored, strain, add SUG 523 SUL white sugar 1 lb.; boil to a full candy height, or that state called " crack," or " crackled sugar," when 2 or 3 drops of clear lemon juice or vinegar must be added, the pan removed from the fire, and set for a minute in cold water to prevent its burn- ing ; after which the sugar must be poured oufon an oiled marble slab, and either cut into pieces, or rolled into cylinders and twisted as usual. 1 drop of oil of citron will flavor a considerable quantity. Essence of bergamotte or lemons may also be used. *** White barley sugar is made with a decoction of barley instead of water, or starch is added to whiten it. SUGAR, BOILING OR CANDYING. Proc. Take any quantity of well clarified and perfectly transparent sirup, and boil it until it has arrived at a weak candy height. This is known by dipping the skimmer into the sugar, and touching it be- tween the forefinger and thumb; and immediately on opening them a small thread will be observed drawn between, which will crystallize and break, and remain in a drop on the thumb, which will be a sign of its gaining some degree of smoothness. Boil it again, and it will draw into a larger string; it is now called bloom sugar, and must be boiled longer than in the former process. To try its for- wardness, dip again the skimmer, shaking off the sugar into the pan ; then blow with the mouth strongly through the holes, and if certain bladders go through, it has acquired the second degree : to prove if the liquid has arrived at the state called feathered sugar, redip the skimmer, and shake it over the pan, then give it a sudden flirt behind, and the sugar will fly off like feathers. It now arrives at the state called crackled sugar; to obtain which the mass must be boiled longer than in the preceding degree ; then dip a stick in it, and put it directly into a pan of cold water, draw off the sugar which hangs to the stick in the wa- ter, and if it turns hard and snaps, it has acquired the proper degree of crystallization ; if otherwise, boil it again until it acquires that brittleness. The last stage of refining this article is called carmel sugar ; to obtain which it must be boiled longer than in any of the preceding methods ; prove it by dipping a stick first into the sugar, and then into cold water, and the moment it touches the latter, it will, if matured, snap like glass. It has now arrived at a full candy height. Be careful that the fire is not too fierce, as by flaming up against the sides of the pan, it will burn and discolor the sugar. The boiling is best conducted by steam heat. *** Any flavor or color may be given to the candy by adding the essences or coloring mat- ter to the sirup before boiling. (See Cake Stains, p. 153.) SUGAR CANDY. Syn. Saccharum Can- dum. Prep. Sugar crystallized, by the saturated sirup being left in a very warm place, from 90 to 100° Fahr., and the shooting promoted by placing sticks, or a net of tjireads, at small distances from each other in the liquor ; it is also deposited from compound sirup3, and does not seem to retain any of the foreign substances with which they were loaded : it may, however, be colored red by means of cochineal. The differences of color and j uality arise from the purity of the sugar employed to make the sirup. Chiefly used as a sweetmeat,! and being longer in dissolving than sugar, in coughs to keep the throat moist; it is also blown into the eye, as a very mild escharotic in films or dimness of that organ. SUGAR, GRAPE. Syn. Glucose. Diabetic Sugar. Starch Sugar. Sugar of Fruits.— Prep. 1. (From grape juice.) See page 345.—2 From dried raisins.) Pound them, wash with cold alcohol, press, dissolve the cake in water, and proceed as last.—3. From diabetic urine, by evap- oration, washing the mass in cold alcohol, redissolv- ing in water, and crystallizing.—4. (From starch.) Starch 100 parts; water 400 parts ; sulphuric acid 1 to 10 parts ; boil for 35 or 40 hours, adding water to make up for evaporation ; then saturate the acid with lime or chalk, and evaporate. Under pressure, the conversion is produced much quicker. Prod. 105 parts. (See Fermentation.)—5. (From woody fibre.) Shreds of linen or paper 12 parts; strong sulphuric arid 17 do., (Braconnot;—5 of acid and 1 of water, Vogel;) mix in the cold ; in 24 hours dilute with water, and boil for 10 hours ; then neu- tralize with chalk, filter, evaporate to a sirup, and set the vessel aside to crystallize. Prod. 114$ of the weight of the rags. Sawdust, glue, &c., also yield grape sugar by like treatment. SUGAR, LEMON. Syn. Portable Lemon- ade. Saccharum Limonatum. Prep. Sugar 4 lbs.; tartaric acid 3 oz.; essence of lemons \ oz. Used to make lemonade, &c. SUGAR OF MILK. Syn. Saccharum Lac- tis. Lactine. Prep. Evaporate clarified whey till it crystallizes, and purify the crystals by diges- tion with animal charcoal and repeated crystalliza- tion. SULPHATE. Syn. Sulphas, (Lat.) A saline compound of sulphuric acid, with a base. Tho soluble sulphates may all be recognised by yield- ing a heavy, white precipitate, with chloride of barium or nitrate of baryta, which is insoluble in acids and alkalis. They also give a similar pre- cipitate with the corresponding salts of lime. An insoluble sulphate may be tested by mixing it with 3 times its weight of carbonate of potash or soda, (both in fine powder,) exposing the mixture in a platinum crucible to a red heat for half an hour, dissolving the mass in water, filtering, neutralizing the free alkali with acetic or muriatic acid, and then applying the reagents as before, when an in- soluble white precipitate will be formed. The sulphates of baryta, tin, antimony, bismuth, lead, and mercury, are insoluble; those of strontia, lime, zirconia, yttria, and silver, very sparingly soluble ; the other sulphates are soluble in water. Mixed with charcoal, and heated to redness, a metallic sulphuret remains. SULPHOCYANIC ACID. See Hydrosul- phocyanic Acid. SULPHOVINIC ACID. Syn. CEnothionio Acid. Ethereo-Sulphuric do. Bisulphate of Oxide of Ethule. Prep. Mix equal weights of sulphuric acid and alcohol, and, in half an hour, add as much carbonate of lead as acid employed ; filter, when a solution of sulphovinic acid will be obtained. This, combined with the bases, forms salts called sulphovinates, which may be purified by re-solution and crystallization. (See Ether.) SULPHOCYANOGKN. Sun. Bisulphuret I of^ Cyanogen. A light, insoluble, deep yellow powder, discovered by Liebig, and obtained by sat- SUL 524 SUL urating a concentrated solution of a m* tallic sul- phocyanide with chlorine, or by heating it with nitric acid. (See Hydrosulphocyanic Acid.) SULPHUR Syn. Brimstone. Soufre, (Fr.) Schwefel, (Ger.) Sulphur, (Lat.) This sub- stance is imported from Sicily and Italy, and is a volcanic production. Its general properties are well known. It is an undecompounded substance or chemical element. With oxygen it unites to form oil of vitriol and sulphurous acid, and with the metals to form sulphurets.—Sublimed Sul- phur, (Flowers of Sulphur, Flores Sulphuris, Sulphur sublimatum, P. L. and E.,) is prepared by subliming sulphur in iron vessels. It is ordered to be washed with water, and dried, (Sulphur lo- tum, P. D.)—Stick, Roll, or Cane Sulphur (Sulphur in bacculis, Do. in rotulis, Do. rotun- dum) is melted sulphur cast in moulds.—Sulphur Vivum is crude native sulphur. Dose. As an al- terative £ dr.; as a purgative 1 to 3 drs. Pur., Uses, fyc. " Pure sublimed sulphur totally evaporates at a heat of 600° F. When washed with water, it (the liquid) does not alter the color of litmus." (P. L.) Sulphur is taken in various chronic skin diseases, pulmonary, rheumatic, and gouty affections, and as a mild purgative in piles, prolapsus ani, &c. Externally, it is extensively used in skin diseases, especially the itch, for which it appears a specific. SULPHUR, PRECIPITATED. Syn. Milk of Sulphur. Hydrate of do. Lac Sulphuris. Sulphur Precipitatum. Prep. Sublimed sulphur 1 part; dry slaked lime 2 parts; water 8 to 12 parts; boil, filter, precipitate by muriatic acid, and drain ; well wash, and dry the precipitate. Resem- bles sublimed sulphur in its general properties, but is much paler, and in a finer state of division. Remarks. The precipitated sulphur of the shops contains about two-thirds of its weight of sulphate of lime, (plaster of Paris,) owing to the substitution of sulphuric for muriatic acid in the above process. This fraud is detected by heating a little of the sus- pected sample in an iron spoon or shovel, when the sulphur is volatilized, and leaves behind the sul- phate of lime, which, when mixed with water, and gently dried, gives the amount of the adulteration. A still simpler plan is to dissolve out the sulphur with a little hot oil of turpentine or liquor of po- SULPHUR, CHLORIDE OF. Syn. Hypo- chlorite of Sulphur. Sulphuris Chloridum. Prep. Spread washed sulphur thinly on the bottom of a wooden box, or other chamber, and pass chlo- rine slowly over it till fully saturated. This com- nound has been recommended for internal use by Derksengi, especially in old gouty affections com- bined with pains in the stomach ; and also, with a salutary effect, in severe nervous fever, when it is taken dissolved in ether, in doses of 10 drops, with old Hungary wine. It is used externally in Pso- riasis inveterata. SULPHURET. Syn. Sulphuretum, (Lat.) Sulphurets are compounds of sulphur with the elec- tro-positive or inflammable bodies. They are either prepared by heating a mixture of the metal and sulphur, in equivalent proportions, in a covered crucible; by igniting a mixture of the metallic ox- ide and sulphur; by depriving a sulphate of the base of its oxygen, by igniting it in contact with charcoal ; or by precipitating a salt of the base by sulphureted hydrogen or a soluble metallic sul- phuret. The sulphurets are mostly opaque, brit- tle, fusible, semi-metallic bodies ; those of mercury and arsenic are volatile, and those of tho alkalis and the earths soluble in water. The same prin- ciples of nomenclature are adopted in describing the sulphurets as are employed to designate the oxides and salts. SULPHURETS OF ANTIMONY—1. (Ses- quisulphuret. Sulphuret. Antimonii Sesqui- sulphuretum, P. L. Antimonii Sulphuretum, P. D.) This is the black antimony of commerce.— 2. (Bisulphuret.) Formed by transmitting sul- phureted hydrogen through a solution of antimoni- ous acid, in muriatic acid. (Rose.)—3. (Persulphu- ret) As the last, but employing antimonic acid. (Rose.) The golden sulphuret, prepared by dissolv- ing sulphuret of antimony, and sulphur, in a solu- tion of potassa, and precipitating by an acid, is also a persulphuret. (Liebig.)—4. (Oxysulphuret. Antimonii Oxysulphuretum, P. L. Ant. Sulphu- retum Aureum ? P. E. Sulphur Antimoniatum Fuscum, P. D.) Prep. (P. L.) Sesquisulphuret of antimony §v'j 5 solution of potassa, 2 quarts; water 2 gallons; simmer for 2 hours, frequently stirring, and adding water to supply that lost by evaporation ; filter, precipitate with dilute sulphu- ric acid, wash, and dry.—5. (Golden Sulphuret.) By allowing the solution to cool and deposite its kermes before adding the acid. This is the per- sulphuret. Remarks. The oxysulphuret of the pharmaco- poeia is a deep orange red powder, " totally soluble in nitromuriatic acid, emitting sulphureted hydro- gen." (P. L.) It is •' tasteless; twelve times its weight of muriatic acid, aided by heat, dissolves most of it, forming a colorless solution, and leav- ing a little sulphur." (P. E.) The oxysulphuret of the shops has a brighter color than that of the pharmacopoeia, and is made by boiling sulphur along with the sesquisulphuret, at the same time using more alkali. It is, in fact, the persulphuret above noticed. (See 3 and 5.) The term Golden Sulphuret is wrongly applied by the Ed. College. The red antimony ore of mineralogists, liver, glass, and crocus of antimony, and Kermes min- eral, are also oxysulphurets of antimony, varying chiefly in color and state of aggregation. %* Oxy- sulphuret of antimony P. L. is alterative in doses of 1 to 4 grs.; emetic in doses of 5 to 20 grs.; it is given in skin and liver diseases, glandular en- largements, rheumatism, &c. SULPHURETED HYDROGEN. Syn. Hy- DROSULPHURIC AdD. SuLPHOHYDRIC AiAD. He- patic Gas. A gaseous compound of hydrogen and sulphur, first chemically examined by Scheele, in 1777. Prep.—1. Sesquisulphuret of antimony 1 part; strong muriatic acid, 4 or 5 parts ; mix in a glass retort, apply the heat of a spirit-lamp, and collect the evolved gas, either ever mercury, or in bottles, like chlorine.—2. From protosulphuret of iron and oil of vitriol, diluted with 4 or 5 parts of water.—3. As the last, but substitute sulphuret of lime or potassium. Remarks. Sulphureted hydrogen is a colorless gas, possessing a powerful odor of rotten eggs; sp. gr. 11912 : under a pressure of 17 atmospheres, at 50° it is liquid; it is absorbed by water, forming SUL 525 SUL liquid sulphureted hydrogen, or hydrosulphuric acid. It is a powerful poison. An atmosphere containing 1-1500th of this gas instantly killed a small bird; 1-lOOOth kdled a large dog, and 1-250th a horse. (Dupuytren and Thenard.) Be- ing considerably denser than air, it may be poured from its generating bottle into cavities, a scheme successfully employed by M. Thenard to destroy rats in their holes, a method equally applicable to other vermin. Sulphureted hydrogen may be re- cognised by the odor, and by its blackening moist carbonate of lead, and tarnishing silver, and also by its precipitating arsenious acid yellow, tartar emetic orange, and the salts of lead black. It forms saline compounds with the alkalis, and the earths termed Hydrosulphates or Hydrosulphu- rets, and it precipitates metallic sulphurets from solutions of most of the metals ; hence its value as a test. Air containing l-20,000th part of pure hydrogen will sensibly blacken a piece of white paper, moistened with a solution of acetate of lead. Sulphureted hydrogen is the active ingredient in the sulphureous mineral, waters. SULPHURIC ACID. Syn. Oil of Vitriol. Vitriolic Acid. Acid Sulphurique, (Fr.) ScHWEFELsiiuRE, (Ger) Acidum Sulphuricum ; A. Vitriolicum, (Lat) This acid, which has been known ever since the 7th century, is made by bringing the fumes arising from the slow combus- tion of sulphur into contact with those evolved from a mixture of nitre and oil of vitriol, so that the former becomes oxidized at the expense of the latter. The process is conducted in a series of leaden chambers, having a little water on the floor, to absorb the acid, and so arranged as to prevent the loss of gas. Sulphuric acid is only made on the large scale. Fuming, or Nordhausen sulphu- ric acid is made by distilling calcined sulphate of iron in an earthen retort. By heating this acid in a glass retort, anhydrous sulphuric acid distils over. Prop., Uses, tyc. Anhydrous Sulphuric Acid is a white crystalline solid, resembling asbestos ; deliquesces and fumes in the air ; melts at 66° ; boils at about 105° ; does not redden dry litmus paper; sp. gr. 1*97 at 78°.—Fuming Sulphuric Acid is an oily, dark brown, fuming liquid ; sp. gr. 1*9.—Oil of Vitriol (Acidum Sulphuricum, P. L. & E., A. Sulph. Venale, P. D.) is a colorless, odorless, acrid, and corrosive liquid, the general properties of which are well known. Its sp. gr. at 60° should never be greater than 1*8455, or less than 1*840. It is immediately colored by contact with organic matter. " It is free from color; sp. gr. 1*845 ; what remains after the acid is distilled to dryness, does not exceed Tj')ff part of its weight Diluted sulphuric acid is scarcely colored by sul- phureted hydrogen." (P. L.) " Diluted with its own volume of water, only a scanty muddiness arises, and no orange fumes escape." (P. E.) The commercial acid frequently contains nitrous acid, arsenic, and saline matter. The first may be re- moved by adding about 1£ grs. of sugar to each fluid ounce of the acid, heated to nearly its boiling point, and continuing the heat till the dark color St first produced shall have disappeared, when it should be distilled ; the second, by adding a little sulphuret of barium, or copper-foil, to the acid, agitating the mixture well, and after repose de- canting and distilling; the last is removed by sim- ple rectification. The distillation is most conve- niently conducted, on the small scale, in a glass retort, containing a few platinum chips, and heat- ed by a sand-bath or gas flame, rejecting the first f^ss that comes over. (P.E.) The capacity of the retort should be 4 to 8 times as great as the volume of the acid, and connected with a large tubular receiver, by a loosely-fitting glass tube, 4 feet long and 1 to 2 inches in diameter. The re- ceiver should not be surrounded with cold water. (Ure.) Fragments of glass may be substituted for platina. The redistilled acid is colorless ; density 1*845, (1*842, Ure ;) "dilution causes no muddi- ness ; solution of sulphate of iron shows no redden- ing at the line of contact when poured over it." (P. E.) Sulphuric acid is largely employed in the arts, and from its superior affinity to disengage most of the other acids from their saline combina- tions. In the diluted state it is used in medicine. When swallowed, it acts as a corrosive poison. The antidotes are chalk, whiting, magnesia, car- bonate of soda or potash, mixed with water, or any bland diluent. The reszs for sulphuric acid have been already noticed. (See Sulphate.) Estim. The strength of sulphuric acid is most correctly ascertained by its power of saturating bases; but in commerce it is usually determined from its sp. gr. See Acidimetry. Table of the Quantity of Oil of Vitriol and Dry Sulphuric Acid in 100 parts of the Dilute Acid at different Densities, by Dr. Ure. Liquid. Sp. Gr. Dry. Liq. Sp. Gr. Dry. 100 1-8485 81*54 67 1*5648 54-63 99 1-8475 80*72 66 1*5503 53-82 98 1-8460 79*90 65 1*5390 53*00 97 1-8439 79*09 64 1*5280 52*18 96 1-8410 78*28 63 1*5170 51*37 95 1*8376 77*46 62 1*5066 50*55 94 1*8336 76*65 61 1*4960 49*74 93 1*8290 75-83 60 1*4860 48-92 92 1*8233 75-02 59 1*4760 48-11 91 1*8179 74-20 58 1*4660 47-29 90 1*8115 73-39 57 1*4560 46-48 89 1*8043 72*57 56 1*4460 45-66 88 1*7962 71*75 55 1*4360 44-85 87 1*7870 70*94 54 1*4265 44-03 86 1*7774 70*12 53 1*4170 43-22 85 1*7673 69*31 52 1*4073 42-40 84 1*7570 68-49 51 1*3977 41-58 83. 1*7465 67*68 50 1*3884 40-77 82 1*7360 66-86 49 1*3788 39-95 81 1*7245 66-05 48 1*3697 39*14 80 1*7120 65-23 47 1*3612 38-32 79 1*6993 64-42 46 1*3530 37*51 78 1*6870 63-60 45 1-3440 36-69 77 1*6750 62-78 44 1-3345 35-88 76 1*6630 61-97 43 1*3255 35*06 75 1*6520 61-15 42 1-3165 34-25 74 1*6415 60-34 41 1*3080 33*43 73 1*6321 59-52 40 1*2999 32-61 72 1*6204 58-71 39 1-2913 31*80 71 1-6090 57-89 38 1*2826 30-98 70 1-5975 57-08 37 1*2740 3017 69 1*5868 56-26 36 1*2654 29*35 68 1*5760 55-45 35 1*2572 28*54 SUL 526 SWE [Table continued.] Liq. Sp. Gr. Dry. Liq. Sp. Gr. Dry. 34 1*2490 27-72 17 1*1165 13*86 33 1*2409 26-91 16 1*1090 13*05 32 1-2334 26-09 15 1*1019 12*23 31 1-2260 25-28 14 1*0953 11*60 30 1-2184 24-46 13 1*0887 10*41 29 1*2108 23-65 12 1*0809 9*78 28 1*2032 22*83 11 1*0743 8*97 27 1*1956 22*01 10 1*0682 8*15 26 1*1876 21*20 9 1*0614 7*34 25 1*1792 20*38 8 1*0544 6*52 24 1-1706 19*57 7 1*0477 5*71 23 1*1626 18*75 6 1*0405 4*89 22 1*1549 17*94 5 1*0336 4*08 21 1*1480 17*12 4 1*0268 3*26 20 1*1410 16-31 3 1*0206 2*446 19 1*1330 15*49 2 1*0140 1*63 18 1*1246 14*68 1 1*0074 0*8154 SULPHURIC ACID, (DILUTE.) Syn. Spirit of Vitriol. Vitriol to clean Copper. Spiritus Vitrioli. Do. do. tenuis. Acidum Sul- phuricum Dilutum. (P. L. E. & D.) Prep.—1. (P. L.) Sulphuric acid f fiss ; distilled water ffxivss; mix. Sp. gr. 1*11.-2. (P. E.) Sul- phuric acid f5j ; water f "fxiij ; mix. Sp. gr. 1*090. —3. (P. D.) Acid 1 part; water 7 do. Sp. gr. 1*084—4. (Henry's.) Strong acid diluted to the sp. gr. 1-135. Has the same saturating power as his muriatic and nitric acid. Used for assays.—5. (Common Elixir of Vitriol.) Water acidulated with oil of vitriol q. s. to render it grateful. Remarks, f 3j of the dilute acid, P. L., weighs 60*7 grs., saturates 28 grs. of crystallized carbonate of soda, and contains 9£ grs. of oil of vitriol, or 7*7 grs. of dry sulphuric acid. Dose. 10 to 30 drops diluted with water, as a refrigerant, to check pro- fuse perspiration, in skin diseases to relieve the itching, in dyspepsia, &c.; it is also used exter- nally. SULPHURIC ACID, (AROMATIC.) Syn. Elixir of Vitriol. Acid do. do. Acidum sul- phuricum aromaticum, (P. E. & D.) Prep.—1. (P. E.) Oil of vitriol f f iiiss ; rectified spirit 1£ pints; mix, add powdered cinnamon ^iss ; pow- dered ginger Jj; digest for 6 days, and filter.—2. (P. L. 1746.) Compound tincture of cinnamon f ?xvj ; sulphuric acid %iv; mix, and filter___3. (Wholesale.) Compound tincture of cinnamon 1 gallon ; oil of vitriol 1 lb.; mix, and in a week fil- ter. Dose. 10 to 30 drops, in tne same cases as the last preparation. SULPHURIC ACID, (ALCOHOLIZED.) Syn. Acidum sulphuricum alcoholizatum. (P. Cod.) See Eac de Rabel. SULPHUROUS ACID. Syn. Acidum sul- phurosum. This acid is freely evolved in the gase- ous form when sulphur is burnt in air or dry oxy- gen, and when the metals are digested in hot sul- phuric acid ; and, mixed with carbonic acid, when chips of wood, cork, and sawdust, are treated in the same way. The pure acid is best obtained by the action of sulphuric acid on copper or mercury ; but for the purposes of the arts, the cheaper meth- ods may be employed. According to Berthier, very pure sulphurous acid may be freely obtained by heating a mixture of 100 parts of black oxide of manganese and 12 or 14 parts of sulphur in a glass retort. The gas should be collected over mercury, or received into water when it forms liquid sulphurous acid. Water absorbs 30 times its volume of this gas. Pure liquid sulphurous acid can only be obtained by passing the pure dry gas through a glass tube surrounded by a freezing mixture. Its sp. gr. is 1*45 ; boiling point 14° F.; it causes intense cold by its evaporation. With the bases sulphurous acid forms salts called Sul- phites, (sulphis, Lat.) Use. To bleach silks, woollens, straw, &c, and to remove vegetable stains and iron-moulds from linen. SUMACH. This dye-stuff is chiefly used as a substitute for galls. With a mordant of acetate of iron, it gives gray or black; with tin or acetate of alumina, yellow \nd with sulphate of zinc a yellowish brown ; alone it gives a greenish fawn- color. SUPPOSITORY. Syn. Suppositorium, (Lat, from sub, under, and pono, to place.) A medicine placed in the rectum for the purpose of remaining there, and dissolving gradually. The mode of pro- portioning the doses has been noticed in the article Enema. SUPPOSITORY FOR WORMS. Syn. Sup. anthelminticum. Prep. (Swediaur.) Aloes 3iv ; common salt 3iij ; flour 3ij ; honey q. s. to make a stiff mass ; divide into proper-shaped pieces weigh- ing 15 grs. each. One to be used after a stool. SUPPOSITORY FOR PILES. Syn. Sup. HA1MORRHOIDALE. S. SEDATIVUM. Prep.--1. (El- lis.) Powdered opium 2 grs.; soap 10 grs.; mix. —2. Powdered opium 2 grs.; finely-powdered galls 10 grs.; spermaceti cerate 3j ; mix.—3. Extracts of opium and stramonium, of each 1 gr.; cocoa nut butter 3ij; mix. Used when the piles are very painful. SUPPOSITORY, PURGATIVE. Syn. Sup. catharticum.—1. Soap 3j ; elaterium 2 grs.; mix. As a strong purge.—2. (Nieman.) Soap 3ij ; com- mon salt 3j ; honey q. s.; mix. As a mild cathartic. SUSPENDED ANIMATION, (from hang- ing.) In cases where a body is found in a sus- pended state, and life is seemingly extinct, the chief remedy consists in cupping the temples or opening the jugular vein, and so relieving the head of the blood which accumulates in its superficial veins in consequence of the ligature. Where the body is cold, from having been long suspended, friction, and the other means used for restoring the animal heat in drowned persons, should be likewise resorted to. Electricity or galvanism may also be of service. See Animation, suspended, and Drowning. SWEINFURTH GREEN. Syn. Vert de Mitis. Vienna Green. Prep.—1. Acetate of copper and arsenious acid, equal parts ; dissolve each separately in the least possible quantity of boiling water, mix ; an olive green precipitate falls, which is a good permanent color ; but which, by boiling the liquor from 5 to 8 minutes, changes to a dense granular superb green powder.—2. Instead of boiling the solution containing the precipitate, let it cool and stand for several hours, till the pow- der assumes a granular and beautiful tint—3. (Kastner.) Arsenious acid 8 lbs., dissolved in water as before ; verdigris 9 or 10 lbs., diffused through TAN 527 TAN Water at 120° and the pap passed through a sieve ; mix the latter with the former solution, and set aside till the reaction of the ingredients produces the proper shade.—4. Digest Scheele's green in acetic acid. *%* A very fine green pigment. The use of more arsenic turns it on the yellowish green, and boiling it with a small quantity of potash takes off the blue color. The vessel in which the mixed liquids are set aside should be covered to prevent a premature crystallization on the surface. Scheele's green is also commonly sold under the name of Mitis green. SYDENHAM'S LENITIVE. Prep. Coarse- ly-powdered rhubarb 3iij ; tamarinds §rj ; senna §ss ; coriander seeds 3ij ; boiling water 1 pint; macerate for 3 hours, and strain. An excellent stomachic and laxative. Dose. 1 to 4 tablespoon- fuls or more. SYNAPTASE. Syn. Emulsine. The white part of sweet and bitter almonds, which is soluble in water. Amygdaline converts it into oil of bitter almonds, and prussic acid. 17 grs. of amygdaline dissolved in f §j of an emulsion of sweet almonds, yield a liquid containing 1 gr. of anhydrous hydro- cyanic acid, which does not require to be distilled. This solution has been proposed as a substitute for dilute prussic acid and bitter almond water. 100 grs. of amygdaline yield 47 gra. of raw oil, and 5-9 grs. of annydrous hydrocyanic acid. (Liebig.) SYLVIC ACID. Syn. Silvic Acid. A crys- talline substance extracted from rosin by weak al- cohol, and purified by stronger alcohol. It is dis- tinguished from pinic acid by its insolubility in cold alcohol sp. gr. 0*883. With alkalis it forms salts called sylvates, which are soluble in alcohol and ether. TALLOW AND OTHER FATS are com- monly purified by melting them along with water, passing the mixed fluids through a sieve, and let- ting the whole cool slowly, when a cake of cleansed fat is obtained.—Another plan is to keep the tal- low melted for some time, along with about 2§ of oil of vitriol largely diluted with water, employing constant agitation, and allowing the whole to cool slowly ; then to remelt the cake with a large quan- tity of hot water, and to wash it well.—Another method is to blow steam for some time through the melted fat. By either this or the preceding pro- cess a white hard tallow may be obtained. Some persons add a little nitre to the melted fat, and afterwards a little dilute nitric or sulphuric acid, or a solution of bisulphate of potash. Others boil the fat along with water and a little dilute nitric or chromic acid, and afterwards wash it well with water. (See Oils, Fixed.) TANGHININE. A crystallizable substance extracted by ether from the seeds of Tanghinia Madagascariensis after the fixed oil has been re- moved by pressure. It is soluble in water, alco- hol, and ether ; bitter, acrid, and poisonous. TANNIN. Syn. Tan. Tannic Acid.. Quer- citannic Acid. Tannin, (Fr.) Gerbstoff, (Ger) Acidum Tannicum, (Lat.) A peculiar vegetable principle, named from its power of converting the Bkins of animals into leather. Prep- I- By percolation, in a close vessel, from coarsely powdered galls and sulphuric ether, that has been previously agitated with water. In 24 hours the percolated liquid will be found divided into two portions ; the lower and heavier being a watery solution of tannic acid, and the upper an ethereal solution of gallic acid and coloring mat- ter. Fresh ether must be passed through the pow- der as long as the lower stratum of liquid con- tinues to augment. The two fluids are now sep- arated, and after the heavier one has been well washed with ether, it is gently evaporated to dry- ness ; preferably under the receiver of an air- pump, or over sulphuric acid. Prod. About 40$. II. To a hot infusion of galls add a few drops of sulphuric acid, agitate, filter, and precipitate the filtered liquor by sulphuric acid, diluted with half its weight of water ; in one hour decant the clear, precipitate with strong sulphuric acid, wash with water acidulated with sulphuric arid, press between the folds of bibulous paper, and dissolve in pure water; gradually add carbonate of lead, and digest till the sulpho-tannate is all decom- posed, filter, and evaporate ; powder the dry mass, digest in ether, and evaporate the ethereal solu- tion, as before. III. Precipitate an infusion of galls with a con- centrated solution of carbonate of potash, avoiding excess ; wash with ice-cold water, dissolve in di- lute acetic acid, filter, precipitate by acetate of lead, wash the precipitate with water, suspend it in water, decompose it by sulphureted hydrogen, and evaporate the filtered liquid in vacuo or over sulphuric acid. Props., Uses, fyc. The uses of tannin in the preparation of leather are well known. In the pure state it is perfectly white, but acquires a yel- low color from the action of the air. It is power- fully astringent, reddens vegetable blues, and by the action of heat on its solution, is converted into ellagic, gallic, and carbonic acids. When heated in the dry state, metagallic and pyrogallic acids are formed. It unites with the bases forming salts called tannates, which are characterized by stri- king a deep black with the persalts of iron, (ink.) Tannic acid and gelatin are mutually used as tests of each other ; a thick flocculent precipitate is formed whenever these substances meet in so- lution. When a solution of tannin is dropped into another of gelatin, thick flocks are precipitated, but redissolve when heated with the supernatant fluid. The following is a useful and simple form for preparing this test:—Infuse 1 oz. of pounded galls in 4 oz. of water for several hours; strain with pressure. Add to the turbid fluid 2 oz. of common salt, and filter. The filtrate retains its transparency and power of precipitating gelatin for years. (Chem. Gaz.) Tannic acid is occa- sionally employed as an astringent in medicine. TANTALUM. Syn. Columbium. A rare metal discovered by Mr. Hatchet in 1801 in a mineral from Massachusetts, and by M. Ekeberg in 1803 in tantalite. It exists in most of its ores in combination with oxygen, from which it is sep- arated by fusing the ore with 3 or 4 times its weight of carbonate of potassa, dissolving out the resulting columbate or tantalate of potassa with water, and precipitating by a mineral acid. The precipitate is hydrated columbic or tantalic acid. It is insoluble in water, but readily unites with the alkalis forming salts termed columbates or tanta- lates which are crystallizable. It is soluble in TAR 528 TAR hydrofluoric acid, and the solution, by evaporation at 76°, deposites crystals of terfluoride of Colum- bium.—Metallic Columbium is best obtained by heating potassium with the double fluoride of po- tassium and columbium in the way described for silicon. (Berzelius.) — Oxide of Columbium is formed by exposing columbic acid, in a crucible lined with charcoal and luted, for 4£ houre to an intense heat. This oxide is insoluble in acids, and by fusion with potash or nitre is converted into columbic acid. TARRAS. Syn. Terras. A volcanic pro- duct resembling puzzolene that imparts to mortar the property of hardening under water. Several other argillo-ferruginous minerals possess the same power, and are used under this term. TARTAR, AMMONIATED. Syn. Tar- trate of Potash and Ammonia. Ammonio-tar- trate of Potassa. Prep. Neutralize a solution of cream of tartar with ammonia, evaporate, and crystallize. Very soluble) in water. A favorite laxative on the Continent. This is frequently called soluble cream of tartar. TARTAR, BORAXATED. Syn. Soluble Cream of Tartar. Borotartrate of Potassa. Tartarus boraxatus. Cremor Tartari solubi- lis. Tartris boraxata Potass^ et Sod. dried orange- peel ?x : cardamom seeds 3v ; proof spirit 1 quart; I digest 14 days, (or percolate, P. E.) The Edin. burgh College substitutes canella for cardamoms, and adds cochineal 3ss. 2. (Wholesale.) Gentian 2 lbs.; dried orange-peel 1 lb.; bruised cardamoms \ lb.; proof spirit 4 gallons, (or rectified spirit and water, of each 2 gallons ;) digest as last TINCTURE OF GINGER. Syn. Tinct, Zingiberis, (P. L. E. & D.) Prep. 1. (P. L.) Coarsely-powdered ginger giiss; rectified spirit 1 quart; macerate for 14 days, (or percolate, P. E.) 2. (Wholesale) Coarsely-powdered bleached Ja- maica ginger li lb.; rectified spirit (or spirit dis- tilled from the essence) 1£ gallons; water £ gal- lon ; digest as above. Stimulant and carminative Dose. 1 to 2 drs. TINCTURE OF GUAIACUM. Syn. Tinct. Guaiaci, (P. L. E. & D.) Prep. (P. L.) Gum guaiacum f vij ; rectified spirit 1 quart; digest 14 days. Dose. 1 to 4 drs.; in chronic rheumatism, gout, &c. TINCTURE OF GUAIACUM, (COM- POUND.) Syn. Volatils Tincture of Guaia- cum. Ammoniated do. Tinct. Guaiacina Vol- atilis, (P. L. 1745.) T. Guaiaci comp., (P. L. 1836.) T. Guaiaci Ammoniata, (P. E. & D.) Prep. (P. L.) Guaiacum in coarse powder §vij ; aromatic spirit of ammonia 1 quart; digest 14 days. A powerful, stimulating sudorific and em- menagogue, in chronic rheumatism, gout, &c. TINCTURE, HATFIELD'S. Prep. Gum guaiacum and soap, of each 3ij; rectified spirit 1 pint; digest for a week. TINCTURE OF (BLACK) HELLEBORE. Syn. Tinct. Hellebori, (P. L.) Prep. Black hellebore §v ; proof spirit 1 quart; digest 14 days. Emmenagogue. Dose. £ to 1 dr. TINCTURE OF (WHITE) HELLEBORE. Syn. Tinct. Veratri. T. Hellebori Albi. T. Veratri Albi. Prep. (P. E.) White hellebore §iv ; proof spirit 1 pint; digest or percolate. Dose. 10 drops 2 or 3 times a day, gradually increased, in gout and rheumatism. TINCTURE OF HEMLOCK. Syn. Tinct. Conii, (P. L. E. & D.) T. Cicuta:. Prep. 1. (P. L.) Dried hemlock leaves §v; cardamom seeds 5j; proof spirit 1 quart; digest 14 days.—2. (P. E.) Fresh leaves %xij, express the juice, and per- colate the residue with tincture of cardamoms f^x ; rectified spirit 1£ pints; mix the liquids, and filter. Deobstruent and narcotic. Dose of the P. L. 20 to 60 drops. TINCTURE OF HEMP, (INDIAN.) Syn. Tinct. Cannabis. Prep. (O'Shaughnessy.) Al- coholic extract of Indian hemp 24 grs. ; proof spir- it f §j ; dissolve. Dose. 10 drops every £ hour in cholera; 3j every £ hour in tetanus till the parox- ysms cease, or catalepsy is induced. TINCTURE OF HENBANE. Syn. Tinct. Hyoscyami, (P. L. E. & D.) Prep. (P. L.) Dried henbane leaves §v ; proof spirit 1 quart; digest 14 days, (or percolate, P. E.) Anodyne, sedative, so- porific, and narcotic. Dose, f 3ss to 3ij. %* The tinctures of henbane, foxglove, hemlock, hops, ja- lap, lobelia inflata, rhatany, savin, squills, senna, valerian, wormwood, &c, are usually prepared by the druggists with 1 lb. of the dried leaves to each gallon of a mixture of equal parts of rectified spirit and water. TINCTURE OF HOPS. Syn. Tinct. Lu- TIN 536 TIN puli, (P. L.) T. Humuli, (P. D.) Prep. (P. L.) Hops §vj; proof spirit 1 quart; digest 14 days. Anodyne, sedative, and soporific. Dose. £ to 2 drs. TINCTURE, HUDSON'S. Prep. Tinctures of myrrh and cinchona, and cinnamon water, equal parts, with a little arquebusade and gum arabic. Used as a cosmetic for the teeth. TINCTURE OF IODINE. Syn. Tinct. Iodinii, (P. D.) T. Iodinei, (P. E.) Prep.—l. (P. D.) Iodine §j ; rectified spirit §x j dissolve. Majendie and the Paris Codex order the same proportions.—2. (P. E.) Iodine §j; rectified spirit f §xvj ; dissolve. Dose. 5 to 30 drops where the use of iodine is indicated. TINCTURE OF IODINE, (COMPOUND.) Syn. Tinct. Iodinii comp. Prep. (P. L.) Iodine ^j; iodide of potassium ^ij ; rectified spirit 1 quart ; dissolve. Dose. 10 drops, gradually increased to 1 dr. where the use of iodine is indicated. TINCTURE OF IPECACUANHA. Syn. Tinct. Ipecacuanile. Prep. (P. Cod.) Ipecac- uanha §j; rectified spirit f%v; digest. TINCTURE OF ACETATE OF IRON. Syn. Tinct. Ferri Acetatis. Prep. (P. D.) Acetate of potash 2 parts ; sulphate of iron 1 do.; triturate together, dry, digest in rectified spirit 26 parts, for 7 days, and decant the clear. Dose. £ to 1 dr., as a chalybeate tonic. TINCTURE OF ACETATE OF IRON, (ALCOHOLIC.) Syn. Tinct. Ferri Acetatis cum alcohole. Prep. (P. D.) Sulphate of iron and acetate of potassa, of each §j; alcohol 1 quart, (wine measure;) proceed as last, and digest for 24 hours. Dose and use as the last. TINCTURE OF IRON, (AMMONIATED.) Syn. Mynsicht's Tincture of Iron. Tincture OF AMMONIO-CHLORIDI OF IRON. T. FERRI AMMO- nio-chloridi, (P. L.) T. Ferri ammoniati. Prep. (P. L.) Ammonio-chloride of iron giv; proof spirit 1 pint; dissolve. Dose. 20 to 60 drops, as a stimulant, chalybeate tonic. TINCTURE OF SESQUICHLORIDE OF IRON. Syn. Tinct. of muriate of Iron. T. Ferri Sesquichloridi, (P. L.) T. Ferri muria- tis, (P. E.) Liquor Ferri muriatis, (P. D.) Prep. (P. L.) Sesquioxide of iron §vj ; muriatic acid I pint; digest in glass for 3 days, frequently shaking, then add rectified spirit 3 pints, and de- cant A ferruginous tonic. Dose. 10 to 30 drops, gradually increased. %* In the old Tinctura Martis, P. L., iron filings, and in the T. Ferri muriatis, P. E. 1817, black oxide of iron, were used instead of the sesquioxide or carbonate. TINCTURE OF SESQUINITRATE OF IRON. Syn. Tinct. Ferri sesquinitratis. Do. do. persesquinitratis. Prep. (Onion.) Iron fil- ings §ss; nitric acid (1*5) §ij 3ij; dissolve, add muriatic acid (116) 3vj ; simmer for 2 or 3 min- utes, cool, add rectified spirit §viij, and filter. Proposed as a substitute for the last preparation. Dose the same. TINCTURE OF JALAP. Syn. Tinct. Ja- laps, (P. L. E & D.) T. Jalapii, (P. L. 1788.) Prep. (P. L.) Bruised jalap-root %x ; proof spirit I quart; digest 14 days, (or percolate, P. E.) Ca- 'hartic. Dose. 1 to 4 drs. TINCTURE OF KINO. Syn. Tinct. Kino, (P. L. E. &, D.) Prep. Kino ^iiiss; rectified spir- '♦ 1 quart; macerate 14 days. Astringent. Dose. 1 to 2 drs. combined with chalk mixture in diar- rhoea, &c. TINCTURE OF LACTUCARIUM. Syn. Tinct. Lactucarii. Prep. (P. E.) Powdered lactucarium §iv; proof spirit 1 quart ; digest or percolate. Anodyne, soporific, antispasmodic, and sedative. Dose. 20 to 60 drops, mx contain I gr. of lactucarium. TINCTURE OF LAVENDER, (COM- POUND.) Syn. Lavender Drops. Red do. Red Lavender. Red Hartshorn. Tinct. La- vandulae composita, (P. L.) Spiritus Lavan- dula compositus, (P. E. & D.) Prep.—1. (P. L.) Spirit of lavender 1£ pints; spirit of rosemary £ pint; red sanders wood (rasped) 3v; cinnamon and nutmegs, of each 3iiss; macerate 14 days__ 2. (Wholesale.) Oil of cassia £ oz.; oil of nut- megs 1 oz.; oils of lavender and rosemary, of each 4£ oz.; red sanders (rasped) 3 lbs.; proof spirit 6 gallons, (or rectified spirit and water, of each 3 gallons;) digest 14 days. Should it be cloudy, add a little more proof spirit. Stimulant, cordial, and stomachic. Dose. 1 to 3 teaspoonfuls (£ to 2 drs.) in lowness of spirits, faintness, flatu- lence, hysteria, &c. TINCTURE OF LOBELIA. Syn. Tinct. of Indian Tobacco. T. Lobelia;, (P. E.) T. Lobelias iNFLAT.fi. Prep. (P. E.) Dried and powdered lobelia inflata |v ; proof spirit 1 quart ; digest or percolate. Dose. As an expectorant, 10 to 60 drops ; as an emetic and antispasmodic f 3j to f 3ij, every third hour till it causes vomiting. It is principally employed in spasmodic asthma, and some other pulmonary affections. TINCTURE OF LOBELIA, (ETHEREAL.) Syn. Tinct. Lobelia: fiTHEREA. Prep. i» (P. E.) Powdered lobelia inflata ^v ; spirit of sulphuric ether 1 quart; digest or percolate in a close vessel. —2. (Whitlaw.) Lobelia lb. j : rectified spirit and spirit of nitric ether, of each 2 quarts; macerate for 14 days in the dark. Use and doses as the last. TINCTURE OF LUPULINE. Syn. Tinct. LupuLiNfi. T. Lupuli, (P. E.) Prep. The yel- lowish brown powder attached to the scales of hops, separated by friction ahd sifting, §v; recti- fied spirit 1 quart; digest or percolate. Dose. f3ss to f 3ij. (See Tincture of Hops.) TINCTURE OF MUSK. Syn. Tinct. Moschi. Prep. (P. D.) Musk 3ij ; rectified spir- it f^xvj • digest 7 days. Antispasmodic, but principally used as a Derfume, beincr too weak for medical use. TINCTURE OF MYRRH. Syn. Tinct. MvRRiifi, (P. L. E. & D.) Prep.—l. (P. L.) Myrrh §iij; rectified spirit 1 quart; digest for 14 days, (or percolate, P. E.)—2. (Wholesale.) Bruis- ed myrrh 2\ lbs.; rectified spirit 2 gallons ; water 1 gallon. As last. Tonic and*stimulant Dose. £ to 1 dr., as an adjunct in mixtures, &c. Chiefly used, diluted with water, as a dentifrice or wash for ulcerated spongy gums. TINCTURE OF MYRRH, (COMPOUND.) Syn. Tinct. Myrrha: comp. Prep. Bruised myrrh and Socotrine aloes, of each 2 lbs.; recti- fied spirit and water, of each 2£ gallons ; digest for 14 days. This is frequently substituted for com- pound tincture of aloes in the wholesale trade. TINCTURE OF NUX VOMICA. Syn. TIN 537 TIN Tinct. Nucis VoMicfi. Prep. (P. D.) Nux vomica (ground in a coffee-mill) ^ij ; rectified spir- it fgviij ; macerate 7 (14) days. Dose. 5 to 10 drops, in paralysis, &c. It is poisonous. TINCTURE, ODONTALGIC. Prep. (Col- lier.) Pellitory of Spain %?b ; camphor 3iij ; opium 3j ; oil of cloves 3ij ; rectified spirit f fxvj; digest for a week. Used for the toothache; applied on lint. ' ™ ' TINCTURE OF OPIUM. Syn. Laudanum. Tinct. Opii, (P. L. E. & D.) Prep.—l. (P. L.) Hard opium, powdered, § iij ; proof spirit 1 quart; macerate 14 days, and filter. This preparation has a deep brownish red color, and mxix contain about 1 gr. of opium. Its sp. gr. is 0*952. (Phil- lips.) Dose. 10 to 60 drops as an anodyne, or hypnotic. The following form is substituted for that of the Pharmacopoeia by some wholesale drug houses.—2. Turkey opium 2£ lbs. ; boiling water 9 quarts; digest till dissolved, cool, add rectified spirit 2 gallons, and after repose, decant the clear. Prod. 4 gallons. TINCTURE OF OPIUM, (AMMONIA- TED.) Syn. Tinct. Opii ammoniata. Prep. (P. E.) Benzoic acid and hay saffron, of each, 3vj ; sliced opium 3iv ; oil of aniseed 3j; spirit of ammonia 1 quart; digest for a week, and filter. Stimulant and antispasmodic Dose. 20 to 60 drops in hooping-cough, &c. *** This prepara- tion is called paregoric, or paregoric elixir, in Scotland, but should be carefully distinguished from the compound tincture of camphor, which passes under the same names in England; as the former contains about 4 times as much opium as the latter. TINCTURE OF ORANGE PEEL. Syn Tinct. Aurantii, (P. L. &. E.) T. Corticis au- rantii, (P. L. 1788.) Prep. (P. L.) Dried orange peel ^iiiss; proof spirit 1 quart; digest for 14 days. A grateful bitter stomachic. Dose. 1 to 3 drs., mostly as an adjunct to mixtures, &c. TINCTURE OF PELLITORY. Syn. Tinct. Pyrethri. Prep. (Pereira.) Pellitory of Spain and water, of each, fj; rectified spirit §v; digest Used to relieve toothache. TINCTURE OF QUASSIA. Syn. Tinct. Quassias, (P. E. & D.) Prep. (P. E.) Quassia, in chips, 3x; proof spirit 1 quart; digest 7 days. Bitter. Dose. £ to 2 drs. in dyspepsia and stom- ach diseases. TINCTURE OF QUASSIA, (COMP.) Syn. Tinct. Quassia: comp. Prep. (P. E.) Cardamoms and cochineal, bruised, of each, §ss' powdered cinnamon and quassia chips, of each, 3yj ; raisins ^vij ; proof spirit 1 quart; digest for 7 days, or percolate. Aromatic and tonic. Dose and use as the last. TINCTURE OF RHUBARB. Syn. Tinct. Rh.ei. Prep. (P. E.) Powdered rhubarb ^iiiss ; cardamom seeds, bruised, ^ss ; proof spirit 1 quart; digest or percolate. Cordial, stomachic, and laxa- tive. Dose. 3j to ^j- TINCTURE OF RHUBARB, (COMP.) Syn. Tinct. Rhasi comp., (P. L. & D.) T. Rhab.vr- bari comp., (P. L. 1788.) Prep.—l. (P. L.) Rhu- barb, sliced, ^iiss ; liquorice root, bruised, 3vj; ginger, bruised, and hay saffron, of each, 3iij ; proof spirit 1 quart; digest 14 days. A popular remedy in diarrhoea and colic, especially of drunk - 68 ards. Dose. As a stomachic, 1 to 3 drs.; as a purgative, £ to 1£ oz. The tincture of rhubarb of the shops is mostly inferior, being deficient both in rhubarb and spirit. The following forms I have seen extensively used in the wholesale trade :—2. East India rhubarb -20 lbs.; boiling water q. s. to cover it, infuse for 24 hours, then slice the rhu- barb, and put it into a cask with moist sugar, 14 lbs.; ginger, bruised, 3£ lbs.; hay saffron 1 lb.; carbonate of potash £ lb.; bruised nutmegs i lb.; rectified spirit 19 gallons ; water 21 gallons ; ma- cerate with frequent agitation for 14 days, decant the clear, press, and filter the bottoms. Those houses that adhere to the L. Ph. for 1824 substi- tute cardamom seeds 5 lbs. for the ginger. TINCTURE OF RHUBARB AND ALOES. Syn. Tinct. Rha:i et Aloes. Elixir sacrum. Prep. (P. E.) Rhubarb ^'ss j Socotrine or East Indian aloes 3vj ; cardamom seeds 3v ; proof spirit 1 quart; macerate 7 days, or percolate. A warm stomachic purgative. Dose. £ oz. to 1 oz. TINCTURE OF RHUBARB AND GEN- TIAN. Syn. Tinct. Riifii et Gentiana;, (P. E.) T. Rhasi amara. Prep. (P. E.) Rhubarb f ij ; gentian § ss; proof spirit 1 quart. As last. Stomachic, tonic, and purgative. Dose. 1 dr. to 1 oz. TINCTURE, RUSPINI'S. Prep. Orris root ^viij ; cloves §j ; ambergris 9j ; rectified spirit 1 quart; digest for 14 days. A fashionable denti- frice. TINCTURE OF SAFFRON. Syn. Tinct. Croci. Prep. (P. E.) Hay saffron §ij; proof spirit 1 quart; digest or percolate. Stimulant, and emmenagogue. Dose. 1 to 2 drs. Chiefly used for its color and flavor. TINCTURE OF SENNA, (COMPOUND.) Syn. Tinct. SENNfi comp., (P. L. E. & D.) Elix- ir Salutis. Prep.—1. (P. L.) Senna §iiiss ; cara- way seeds 3iiiss ; cardamom seeds 3j ; raisins §v ; proof spirit 1 quart ; macerate for 14 days, (or per- colate, P. E.)—2. (P. E.) Sugar ^iiss; coriander seeds §j ; jalap 3vj ; raisins and senna, of each, §iv; caraways and cardamoms, of each, 3v; proof spirit 1 quart. As last.—3. (Wholesale) Senna 6 lbs.; treacle 2 lbs.; caraways \ lb.; carda- moms \ lb. ; rectified spirit and water, of each, 4 gallons ; as before. Carminative, stomachic, and purgative. Dose. \ to 1 oz. TINCTURE OF SERPENTARY. Syn. Tinct. of Snake Root. T. Serpentarle, (P. L. E. & D.) Prep. Serpentary §iiiss ; proof spirit 1 quart; macerate for 14 days, (or percolate, P. E.) Tonic and diaphoretic. Dose. 1 to 3 drs. TINCTURE OF SQUILLS. Syn. Tinct. Scilla:, (P. L. E. D.) Prep. (P. L.) Dried squills (fresh) f v ; proof spirit 1 quart ; macerate for 14 days, (or percolate, P. E.) Expectorant and diu- retic. Dose. 10 to 30 drops, in chronic coughs, and other bronchial affections. TINCTURE OF STRAMONIUM. Syn. Tinct. of Thorn Apple. T. Stramonii. Prep. (P. U. S.) Bruised stramonium seeds ^ij ; proof spirit ^xvj ; digest for 6 days. Anodyne. Dose. 10 to 20 drops, in neuralgia, rheumatism, &c. Said to be superior to laudanum. TINCTURE OF VALERIAN. Syn. Tinct. Valerianae (P. L. E. & D.) Prep. (P. L.) Va- lerian root §v; proof spirit 1 quart; macerate 14 TIS 538 TOB days, (or percolate, P. E.) Tonic and antispas- modic Dose. 1 to 3 drs in hysteria, epilepsy, TINCTURE OF VALERIAN, (COMP.) Syn. Ammoniated Tincture of Valerian. Vo- latile do. do. Tinct. Valerianae Comp., (P. L.) T. Valeriana; Ammoniata, (P. E. & D.) Prep. (P. L.) Valerian %v; aromatic spirit of ammonia 1 quart; macerate 14 days, (or percolate P. E.) Stimulant, tonic, and antispasmodic. Dose and use as the last. The tincture of the shops is gen- erally made with only 1 lb. of the root to the gal- lon. TINCTURE OF ACETATE OF ZINC. Syn. Tinct. Zinci Acetatis. Prep. (P. D.) Acetate of potash and sulphate of zinc, of each, ^j ; rub together, then add rectified spirit f ^xvj, and macerate for a week. Astringent. Diluted with water, it is used as a collyrium and injection. TINCTURES, CONCENTRATED. Syn. Tinct. Concentrat* Haenli. Prep. (Baden Ph.) These are much stronger than ordinary tinctures, and are thus prepared:—Digest 8 parts of the vege- table powder in 16 of spirit of wine 0857 for 4 days at 72° F., stirring occasionally. Then press and filter. Add to the residue as much spirit as it has absorbed, press, and filter. Mix the liquore, the weight of which should be 16 parts. In this way are prepared concentrated tinctures of aco- nite leaves ; arnica and chamomile flowers ; bella- donna, conium, digitalis, hyoscyamus, peppermint, and savine leaves; ipecacuanha and valerian roots, &c. TINCTURES, .ETHEREAL. Syn. Tinct. ^therea;. Prep. (P. Cod.) 1. Ethereal Tinc- ture of Aconite. Powdered aconite leaves 3"j ; sulphuric ether §iv, (ffvj.) It is best prepared by percolation in a cylindrical glass vessel furnished with a stopper, and terminating at the lower end in a funnel, which is to be obstructed with a little cotton. The powder being introduced over the cotton, pour on it enough ether to moisten it, put in the stopper, fix the tube into the neck of a bot- tle, and leave it for 48 hours. Then add gradually the rest of the ether, and, lastly, enough water to displace the ether absorbed. *** In a similar manner are prepared the ethereal tinctures of ar- nica flowers, belladonna, hemlock, foxglove, to- bacco, pellitory, solanum, valerian, stramonium, ) castor, musk, amber, tolu, 6cc, of the P. Codex. 3. Ethereal Tincture of Perchloride of Iron. (Bestuchef's Tincture.) Perchloride of iron, (dried,) 3j ; spirit of sulphuric ether f 3ix; dissolve. TINCTURES FOR KITCHEN USE. (See Essences.) TISANES. Syn. Ptisans. Fluid medicines, consisting for the most part of aqueous infusions, or decoctions of substances possessing little activi- ty, and intended to be drunk in considerable quan- tity. They are much used in France. They may be readily formed by slightly medicating barley, rice, or tamarind water, lemonade, &c. (See Ju- leps, Decoctions, Infusions, &c.) TITANIUM, (after the Titans of ancient fa- ble.) A rare metal, discovered by Klaproth, in mechanite, in 1794, but first minutely examined by Wollaston, in 1822. It is hard, brittle, and in- fusible ; sp. gr. 5*3. It is occasionally found at the bottom of the smelting furnaces of iron works, under the form of minute crystals, having a cop- pery lustre.—Oxide of Titanium is a deep purple powder, obtained by placing a piece of metallic zinc or iron in the muriatic solution of titanic acid. —Titanic Acid (peroxide of titanium) is found nearly pure in the minerals rutile and anastase. It may be obtained from rutile by fusing it in pow- der, mixed with 3 times its weight of carbonate of potash, powdering and washing the resulting com- pound ; dissolving in strong muriatic acid ; dilu- ting with water, and boiling; when most of the titanic acid falls down, and after being collected on a filter must be well washed with dilute muria- tic acid. It may also be prepared by calcining titanium along with nitre, and decomposing the resulting titanate of potassa, as above. Metallic titanium is insoluble in all acids, except the nitro- hydrochloric, and then only when reduced to very fine powder. TOBACCO. Syn. Tabac, (Fr.) Tabacum, (Lat.) The dried and prepared leaves of the ni- cotiana tabacum. The name was given by the Spaniards, because it was first seen by them at Tabasco, or Tabaco, a province of Yucatan, in Mexico. (See Snuff.) The cheap tobacco vend- ed in the shops is largely adulterated. Tobacco is now offered for sale at 3d. per ounce, i. e. 4s. per pound, while the duty alone amounts to about 3s. 3d., thus leaving only 9d. to be divided among the grower, the importer, the manufacturer, and the retailer ; besides which there is a loss by weighing it out in small quantities, and by evaporation. Is it possible for this tobacco to be genuine ? It can- not be. It is a well-known fact that this tobacco is largely adulterated with foreign matter. It is a general practice to moisten it with treacle water, in which a little saltpetre has been dissolved, for the purpose of making it sufficiently adhesive to retain the fine sand which is afterwards added, and to make it burn well. All this is done to in- crease the weight. When other vegetable matter is mixed with tobacco, " Bengal safflower (at the price of 28s. per cwt.) is preferred. It is infused in a weak solution of potassa or ammonia, the for- mer giving a dark brown color resembling ' Shag,' and the latter a light brown, approaching in ap- pearance to ' Returns.' Considerable loss, how- ever, having occurred from the vegetable matter dissolved out, an improvement has lately been in- troduced ; the safflower, having been moistened, is placed in trays in a cask, into which the ammoni- acal gas is allowed to pass. By this process the weight is increased, whereas, after the earlier methods of preparing it, a loss of one half was sus- tained." (Chem. iii. 304.) TOBACCO, BRITISH HERB. Syn. Spe- cies STERNUTORifi. Prep. Thyme, marjoram, and hyssop, of each 2 oz.; coltsfoot 3 oz.; betony and eyebright, of each 4 oz.; rosemary and laven- der, of each 8 oz.; mix, press together, and cut in imitation of manufactured foreign tobacco. TRE 539 ULM TODDY. From various species of palms, by •Hitting off the end of the flowering bud, collect-* ing the sap,.and letting it stand a few hours to ferment. TOKAY. A luscious, yet agreeable wine, made in Hungary. It is preferred in the turbid state, and hence it is agitated before pouring it into the glass. TOMBAC, (WHITE.) Syn. White Copper. An alloy of copper and arsenic. (See German Silver.) TONICS. (From rovoq, I strengthen) Medi- cines that increase the tone of the muscular fibre, and impart vigor to the system. The principal mineral tonics are—iron, zinc, copper, silver, ar- senic, bismuth, mercury, and the mineral acids. The principal vegetable tonics are—cinchona, cinchonine, quinine, the vegetable bitters, and some of the aromatics. Of the above, iron, bark, and its preparations, and the aromatic bitters, are those generally employed, and which prove most genial to the constitution. TONQUIN REMEDY. Syn. Pulvis Trun- chinensis. P. Alexipharmicus Sinensis. Prep. Powdered valerian 20 grs.; musk 16 grs.; cam- phor 6 grs.; mix. Antispasmodic, alexiterial, in doses of 6 to 12 grs. in hooping-cough ; to 1 dr. in hydrophobia and exanthemata ; to 3iiss in ma- nia! TOOTHACHE. This frequently arises from sympathy with a disordered stomach. In such cases administer a saline purgative, and an emetic if required. When cold is the cause, the best remedy is a hot embrocation of poppy-heads, fol- lowed by the use of flannel. When it arises from a hollow or decayed tooth, the best application is a piece of lint moistened with creosote, or a strong spirituous solution of creosote, and closely rammed into the cavity of the tooth. Laudanum and tinc- ture of pellitory of Spain are also used in the same way. To prevent the recurrence of the latter. kind of toothache, the cavity should be filled with an amalgam of gold, or with mineral marmora- tum. TRACING PAPER. In order to prepare a beautiful, transparent, colorless paper, it is best to employ the varnish formed with Damara resin in the following way :—The sheets intended for this purpose are laid flat on each other, and the var- nish spread over the uppermost sheet by means of a brush, until the paper appears perfectly colorless, without, however, the liquid therein being visible. The first sheet is then removed, hung up for dry- ing, and the second treated in the same way. After being dried, this paper is capable of being written on, either with chalk and pencil, or steel pens. It preserves its colorless transparency with- out becoming yellow, as is frequently the case with that prepared in any other way ; it is at the same time cheap, and the operation gives very little trouble. (Verh. d. Gew. V. ru. Koln.) See Paper. TRAGACANTHIN. Syn. Adragantin. The soluble gum of tragacanth. It slightly differs from arabine. TREACLE, GERMAN. Syn. Extract of Juniper Berries. Prep.—1. (Best) An evapo- rated cold infusion of juniper berries.—2. (Com- mon) An evaporated decoction of juniper ber- ries. Both are sweet-tasted, aromatic, and diu- retic. TREACLE, VENICE. Syn. Theriaca. Theriaca Andromachi (P. L. 1746) consists of 61 ingredients, and contains 1 grain of opium in 75. The theriaca of P. Cod. consists of 72 ingredients, and contains gr. j of opium in 72. For these the following may be substituted : Theriaca edinensis, (P. E. 1744.) Serpentary root §vj ; valerian and contrayerva roots, of each %\\ ; aromatic powder §iij ; guaiacum, resin, castor, and nutmeg, of each §ij ; saffron and opium, (dissolved in a little wine,) each ^j j clarified honey §lxxv ; reduce all the dry ingredients to fine powder, then mix. 100 grs. contain 1 gr. of opium. TUNGSTEN. (From tung sten, Swed., heavy stone, from the density of its ores.) Syn. Wool- fram. Woolframium. Scheelium. Tungste- num. A heavy, gray, brittle metal, discovered by Messrs. Delhuyart Itssp. gr. is 17*35. It occurs in the mineral woolfram, united with oxygen, (tungstic acid) manganese, and iron, from which it may be obtained by the action of charcoal or hydrogen gas, assisted by heat. It is, however, more conveniently obtained by treating tungstic acid as above. Tungstic acid is a yellow powder, obtained by digesting native tungstate of lime, finely powdered, in nitric acid. It is insoluble in water, but soluble in a concentrated solution of pure potassa, forming tungstate of potassa. TURMERIC. The root of the curcuma longa and rotunda, a plant which grows in the East In- dies. Its coloring principle is called curcumine. Turmeric is employed to give a fugitive golden yellow with weld, and an orange tinge to scarlet. It dyes wool and silk, mordanted with common salt or sal ammoniac, a fugitive yellow. TURPENTINE, CHIO, (FACTITIOUS.) Syn. Terebinthina Chia Factitia. Prep. Black rosin 7 lbs.; melt, remove the heat, and stir in balsam of Canada 7 lbs. Some add a few drops of the oils of fennel and juniper. This article is now very generally sold in trade for genuine Chia turpentine. TURPENTINE, VENICE. Syn. Terebin- thina Veneta. Genuine Venice turpentine is the product of the Larix Europeea, but this is now scarcely ever met with in trade. That of the shops is wholly a factitious article, made as fol- lows :—Black rosin 48 lbs.; melt, remove the heat, and add oil of turpentine 2 gallons. TUTTY. Syn. Tutia. Tuthia. Impure Ox- ide of Zinc The sublimate that collects in the chimneys of the furnaces in which ores of zinc are smelted. Drying ; astringent. Used in eye-wa- ters and ointments. TYPE METAL. Prep. Lead 3 parts ; anti- mony 1 part ; melted together. Small types are usually made of a harder composition than large ones. A good stereotype metal is said to be made of lead 9 parts ; antimony 2 do.; bismuth 1 do. This alloy expands as it cools, and consequently brings out a fine impression. ULMIN. Syn. Ulmic Acid. This name has been given to a peculiar substance examined by Klaproth in 1802, and which was a spontaneous exudation from the trunk of a species of elm, (Ul- mus nigra.) It has since been observed on many ULT 540 URA other trees. When dry, it is hard, blackish, resin- ous, readily soluble in the mouth, but insoluble in alcohol and ether. It may be formed artificially by heating caustic potassa with wood, by the ac- tion of sulphuric acid on vegetable matter, and by combining gallic acid with ammonia and exposing the compound to oxvgen. ULTRAMARINE. Syn. Ultramarine Blue. Cosruleum Ultramoxtanum, (Lat) Outre- mer, (Fr.) Ultramarins, (Get.) This beautiful pigment is obtained frorn the blue mineral lazulite or lapis lazuli; the finest specimens of which are brought from China, Persia, and Great Bu- charia. Prep. Lapis lazuli (reduced to fragments about the size of a pea, and the colorless pieces re- jected) lb. j, is heated to redness, quenched in wa- ter, and ground to an impalpable powder ; to this is added, yellow rosin 6 oz.; turpentine, beeswax, linseed oil, of each 2 oz.; previously melted to- gether, and the whole made into a mass; this is kneaded in successive portions of warm water, which it colore blue, and from whence it is deposit- ed by standing, collected, well washed with clean water, dried, and sorted according to its qualities. Some persons prefer leaving the pieces of wax for 14 or 15 days in the water before kneading them ; the first water, which is usually dirty, is thrown away ; the second gives a blue of the first quality ; and the third yields one of less value. The process is founded on the property which the coloring mat- ter of azure-stone has of adhering less firmly to the resinous cement than the foreign matter with which it is associated. When azure-stone has its.color altered by a moderate heat, it is reckoned bad. The price of ultramarine of the richest shade of blue is 4 to 5 guineas per oz. Genuine ultrama- rine, as well as lazulite, when heated to a full red, does not change color. Ultramarine is the most splendid and permanent blue pigment the painter possesses, and works well in oil. ULTRAMARINE ASHES. Syn. Saunder's Blue. Obtained from the resinous mass of the last process after it has yielded all its ultramarine, by melting it with fresh oil, and kneading it in water containing a little potash or soda; or by burning away the wax and oil of the mass, and well grind- ing and washing the residue with water. Inferior to ultramarine. ULTRAMARINE, FACTITIOUS. Accord- ing to Gmelin, of Tubingen, sulphuret of sodium is the coloring principle of lapis lazuli, to which the color of ultramarine is owing; but, according to Eisner and Tirnmon, a minute quantity of sul- phuret of iron is an essential ingredient. The above, and several other chemists, have succeeded in preparing artificial ultramarine, by heating sul- phuret of sodium with a mixture of silicic acid and alumina. In these cases it is said that a minute quantity of iron is derived from the alum, (Tirn- mon ;) but it appears doubtful whether the color can depend on the presence of so small a portion of that metal. The finer specimens of artificial ultramarine are quite equal in durability and beauty of color to that prepared from lazulite, while it is much less expensive. In Paris it fetches 60 francs, or about 2 guineas a pound. Prep. I. (Tirnmon.) Crystallized carbonate of Boda 1075 gre.; apply a gentle heat, and when fused in its water of crystallization, shake in finely-pulverized orpiment 5 grs., and when partly decomposed, add as much gelatinous hydrate of alumina as contains 7 grs. of anhydrous alumina ; finely-sifted clay 100 grs., and flowers of sulphur 221 gre., are then to be added, and the whole placed in a covered crucible, and at first gently heated to drive off the water; and as sbon as this is effected, raised to redness. The heat must be so regulated that the mass only " sinters" to- gether without fusing. The mass must be then cooled, finely pulverized, suspended in river water, and brought upon a filter. The product has now a beautiful delicate green or bluish color. It must next be heated in a covered dish, and stirred about from time to time, till the temperature reaches that of dull redness, at which it must be kept for 1 or 2 hours. If the heat of the first calcination has been properly regulated, the whole of the mass taken from the crucible will have a uniform color; but if too little heat has been used, and the ingre- dients have not been properly mixed, there will be colorless parts, which should be rejected; if too much heat has been used, or the mass allowed to fuse, brown parts will appear, especially if the crucible is of a bad kind, or easily destroyed. (Compt Rend., Mai 1842, p. 761.) II. (Gmelin.) Sulphur 2 parts; dry carbonate of soda 1 part; mix well, gradually heat them in a covered crucible to redness till the mixture fuses, then sprinkle in by degrees another mixture of si- licate of soda and aluminate of soda, (containing 72 parts of silica, and 70 parts of alumina,) and continue the heat for 1 hour longer. The product contains a little free sulphur, which may be sepa- rated by water. III. (M. Robiquet.) By heating to redness a mixture of pure kaolin, sulphur, and carbonate if soda. IV. Artificial ultramarine is occasionally formed in preparing Antim. diaphor. ablutum, and fre- quently also in the preparation of milk of sulphur. When chlorated water is added to a solution of sulphuret of potassium made with common potash and sulphur of commerce, green or blue flakes are thrown down. The earthen vessels in which the melting process has been effected, no doubt afford the alumina, silica, and iron. (Jahr. fiir Prakt. Pharm., iv. p. 83.) URAMlLE, A product of the decomposition of thionuric acid, discovered by Wohler and Lie- big. It is obtained by treating a hot saturated so- lution of thionurate of ammonia, with hydrochloric acid in excess, and boiling till a slight turbidity is observed, when the whole is converted into a semi- fluid mass. Crystalline or pulverulent. Soluble in boiling water and alkalis. * URAMILIC ACID. A product of the decom- position of uramile, discovered by Wohler and Lie- big. A saturated solution of thionurate of ammo- nia in cold water, is mixed with a small quantity of sulphuric acid, and the mixture evaporated in a water-bath, when crystals of uramilic acid are slowly deposited. Soluble in water; with the al- kalis it forms crystallizable salts, called uramilates. URANIUM. Syn. Uranite. A metal discov- ered by Klaproth in 1789, and named after the planet Uranus, which was discovered about the same time. It occurs in the pectthleiitli of Saxony, and the uranite of Cornwall. Uranium may be URI 541 VAL extracted from the former mineral by heating it to redness, cooling, powdering, digesting it in nitric acid diluted with 3 or 4 parts of water, in quantity insufficient to dissolve the whole, passing sulphuret- ed hydrogen through the solution, boiling to expel free sulphurous gas, concentrating by evaporation, and setting the remaining fluid aside to crystallize, when beautiful lemon-colored crystals of pernitrate of uranium are slowly deposited. These crystals, exposed to a strong heat, yield protoxide of ura- nium, (green oxide,) which, by exposure to hydro- gen gas and heat, are reduced, and metallic ura- nium remains. (Arfwedson.) It is a brittle, gray, or reddish-brown metal; sp. gr. about 9*0.—Perox- ide of uranium (yellow oxide, uranic acid) is pre- cipitated as a yellow hydrate, when a pure alkali is added to a solution of the pernitrate, and as a carbonate when alkaline carbonates are used. It is soluble in alkalis in excess, acting the part of a feeble acid. The salts of protoxide of uranium are characterized by their green color; those of the peroxide by a yellow color. With prussiate of pot- ash they yield a reddish-brown precipitate, resem- bling prussiate of copper, and with infusion of galls a brown one. Sulphureted hydrogen turns the solutions of the persalts green. UREA. Syn. Cyanate of Ammonia, (Anom- alous.) A crystalline, colorless, transparent sub- stance, discovered by Fourcroy and Vauquelin in urine, and by Wohler as the first organic com- pound artificially produced. Prep. I. (Thenard.) Fresh urine, gently evap- orated to the consistence of a sirup, is to be treated with its own volume of nitric acid at 24 deg.; the mixture is to be shaken and immersed in an ice- bath to solidify the crystals of supernitrate of urea; these are washed with water at 0, drained, and pressed between sheets of blotting paper. When they are thus separated from foreign matters, they are to be dissolved in water, to which subcarbon- ate of potash is added, whereby the nitric acid is taken up, and the urea set at liberty. This new liquor is evaporated at a gentle heat, nearly to dry- ness ; the residue is treated with pure alcohol, which only dissolves the urea, the solution is con- centrated, and the urea crystallizes. II. (Liebig.) See Cyanate of Ammonia, p. 57. *** Urea has the sp. gr. 1*33, is freely soluble in water and alcohol, fuses at 250°, and is decom- posed at higher temperatures. It is said to be di- uretic, and has been given in the dose of a gros, dissolved in sugared water. URIC ACID. Syn. Lithic Acid. An acid discovered by Scheele, and peculiar to the urine of certain animals, and the excrement of serpents and several birds of prey. The fasces of the boa constrictor consist of little else than urate of am- monia. Uric acid forms one of the commonest varieties of urinary calculi, and of the red gravel or sand, which is voided in certain morbid states of the urine.. Guano, which is largely imported for manure, is also composed in greater part of urate of ammonia; hence its immense powers as a fer- tilizer of the soil. Prep. Dissolve urinary calculi, or the chalk- like excrement of serpents, reduced to fine pow- der, in a solution of caustic potassa, by boiling, add muriatic acid in excess, again boil for 15 minutes, and well mix the precipitate with water Prop.,Tests, fyc. Brilliant small scales, white and silky, tasteless, inodorous, slightly soluble in boiling water, soluble in strong sulphuric acid, and again precipitated by water, it forms salts with the bases called urates. The characteristic of uric acid is, that, when moistened with nitric acid and heated, it dissolves, and by evaporation yields a red com- pound, which, upon the addition of a drop or two of solution of caustic ammonia, becomes of a fine crimson, (purpurate of ammonia.) URIC OXIDE. Syn. Xanthic Oxide. A rare constituent of urinary calculi, discovered by Marcet. USQUEBAUGH. Syn. Escubac A strong compound liquor, much drunk in Ireland, and made in the greatest perfection at Drogheia. Prep. I. (Yellow.) a. Brandy or proof spirit 3 gallons ; hay saffron and juniper berries, of each 1 oz.; dates, without their kernels, and raisins, of each, bruised, \ lb.; mace, cloves, coriander, and aniseed, of each £ oz.; cinnamon \ oz.; digest till sufficiently flavored and colored ; filter, and add capillaire, or simple sirup, 1 gallon.—6. Proof spirit 1 gallon; stoned raisins 1 lb.; cinnamon, cloves, and nutmegs, of each £ oz.; aniseed 1 oz.; hay saffron £ oz.; brown sugar 2 lbs.; rind of 1 or- ange ; digest 14 days, then filter or clarify.—c. Pi- mento and caraways, of each 3 oz.; mace, cloves, and nutmegs, of each 2 oz.; aniseed, coriander, and angelica root, of each 8 oz.; hay saffron 3 oz.; raisins, stoned and bruised, 14 lbs.; proof spirit 9 gallons; digest 14 days, with frequent agitation, then press, filter, or clarify, and add simple sirup q. s. Should it turn milky, add a little strong spirit, or clarify it with alum, or filter through magnesia. II. (Green.) As the above, but using sap green to color, instead of saffron. VACCINE MATTER. Collected either upon lancets, or by opening the pustule, and applying a small glass ball and tube (like those called by the boys in London candle pops, or fire pops) to the opening, expelling part of the air in the ball by bringing a lighted taper near it, then withdrawing the taper the matter is drawn into the ball, in which it may be sealed up hermetically or cement- ed, and thus kept for a length of time. It is also commonly preserved between two small pieces of glass. Used lately for an absolute preventive of the smallpox, but now with a view of diminishing the susceptibility of acquiring that disease, and to render it milder if acquired. The matter may be liquefied with a little clean water. Smallpox mat- ter is collected in the same way. Used occasion- ally to communicate the disease, under favorable circumstances, instead of hazarding it being ac- quired under unfavorable ones. Both of these matters are applied in the way described under Inoculation. VALERIANIC ACID. A volatile, fatty arid, obtained by distilling valerian root along with wa- ter, and acting on the product with caustic potassa, when valerianate of potassa is formed, and a vola- tile oil is separated ; by evaporating to dryness, the latter is dissipated, and the dry mixture, treated with dilute sulphuric acid and distilled, yields an aqueous solution of valerianic acid. By careful redistillation it may be deprived of water. Vale- VAR 542 VAR rianic acid may also be produced artificially, by heating fused potassa along with the oil of potato, or corn spirit, (hydrated oxide of amule) when valerianate of potassa is obtained, the acid of which is identical in all respects with that obtained from the root of Valeriana Officinalis. (Liebig.) *»* Colorless, limpid, oleaginous ; boils at 270° ; soluble in alcohol and ether, and in 30 parts of water ; smells strongly of valerian ; with the bases it forms salts called Valerianates, most of which are soluble. VANADIUM. (From Vanadis, a Scandina- vian idol.) A rare metal discovered by Sefstom, in 1830, in some Swedish iron, extracted from an iron mine near Jonkdping. It has since been found in a lead ore from Scotland. It is white, brittle, very difficult of reduction, and soluble in nitric and nitromuriatic acids, with which it yields dark blue colored solutions. Vanadium is obtained from the native vanadate of lead, by dissolving the ore in nitric acid, passing sulphureted hydrogen through the solution, to throw down lead and arsenic, and evaporating the resulting blue liquid to dryness ; the residuum is then dissolved in a solution of am- monia, and a piece of sal ammoniac, considerably larger than can be dissolved, introduced; as the latter dissolves, a pulverulent precipitate of vana- date of ammonia is formed, which must be washed, first in a solution of sal ammoniac, and then in al- cohol of 0-860. By exposing this salt, in an open platinum crucible, to a heat a little below redness, and keeping it constantly stirred, until it acquires a dark red color, pure vanadic acid is obtained. (Johnston.) From this acid metallic vanadium may be procured, by placing fused fragments of it, and potassium, of equal size, in alternate layers, in a porcelain crucible, the potassium being in tjje largest proportion, and after well luting on the cover, heating it carefully over a spirit-lamp ; the cooled mass must then be washed with water. (Berzelius.)—Protoxide of vanadium is obtained by acting on vanadic acid by heat and charcoal, or hydrogen gas. Black.—Binoxide of vanadium, by heating to dull redness a mixture of 10 parts of the protoxide and 12 of vanadic acid, in an atmo- sphere of carbonic acid gas, or out of contact with air and combustible matter. It is also formed by heating vanadate of ammonia in close vessels. A black powder. It is precipitated as a grayish-white hydrate from its solutions, by carbonate of soda in slight excess.—Vanadic acid (peroxide) is orange- colored, scarcely soluble in water, and forms, with the alkaline bases, soluble salts, called Vanadates, and with the other bases, sparingly soluble salts. All of these have an orange or yellow color. Va- nadium is distinguished from chromium by deox- idizing substances giving a blue color to solutions of the former, but a green one to solutions of the latter.—" Vanadate of ammonia, mixed with solu- tion of galls, forms a black fluid, which is the best writing ink hitherto known. The quantity of the 6alt required for this purpose is very small; the writing is perfectly black, and not obliterated by alkalis, acids, chlorine, or other reagents, that at the same time will not destroy the paper." (Ure.) VAN SWIETEN'S DROPS. A solution of corrosive sublimate. (See Solution of Bichlo- ride of Mercury, P. L.) VARNISH. Syn. Vernis, (Fr.) Firniss (Ger.) A solution of resinous matter, which, when spread thin upon the surface of a solid body, be- comes dry, and forms a glossy, transparent coating, impervious to air and moisture. Varnishes may be conveniently divided into two kinds, viz., spirit and oil varnishes. Concentrated alcohol is used as the solvent in the former, and fixed or volatile oils, or mixtures of the two, for the latter. The sp. gr. of alcohol for the purpose of making var- nishes should not be greater than 0*820. Camphor is often dissolved in it to increase its solvent powers. The oil of turpentine, which is the essential oil chiefly employed, should be pure and colorless. Pale drying linseed oil is the fixed oil generally used for varnishes, but poppy and nut oil are also occasionally employed. Among the substances which are dissolved in the above menstrua are,— turpentine, copal, mastich, lac, elemi, sandarach, anime, and amber, to impart body and lustre; benzoin to impart scent; gamboge, turmeric, saf- fron, annotto, and Socotrine aloes, to give a yel- low color; dragon's blood to give a red tinge; asphaltum to give a black color and body ; caout- chouc to impart body, toughness, and elasticity. In the preparation of Spirit Varnishes, care should be taken to prevent the evaporation of the alcohol as much as possible, and also to preserve the portion that evaporates. On the large scale, a common still, mounted with its head and connected with a proper refrigerator, should be employed. The capital should be furnished with a stuffing-box, to permit of the passage of a vertical rod, connected with a stirrer at one end, and a working handle at the other. The gum and spirit being introduced, and the head of the still closely fitted on and luted, heat (preferably that of steam or a water-bath) should be applied, and the spirit brought to a boil, when the heat should be partially withdrawn, and agitation continued till the gum is dissolved. The spirit which has distilled over should be then add- ed to the varnish, and, after thorough admixture, the whole should be run off through a silk gauze sieve into stone jars, which should be immediately corked down, and set aside to clarify. On the small scale, spirit varnishes are best made by ma- ceration in close bottles. In order to prevent the agglutination of the resin, it is often advantage- ously mixed with clear silicious sand, or pounded glass, by which the surface is much increased, and the solvent power of the menstruum promoted. In the manufacture of oil varnishes, one of the most important points is the use of good drying oil. Linseed oil for this purpose should be pale, limpid, brilliant, scarcely odorous, and mellow and sweet to the taste.—100 gallons of such oil are put into an iron or copper boiler, capable of holding 150 gallons, and gradually heated to a gentle sim- mer for 2 hours, to expel moisture ; the scum is then carefully removed, and 14 lbs. of scale litharge, 12 lbs. of red lead, and 8 lbs. of powdered umber, (all carefully dried and free from mojsture,) are gradually sprinkled in ; the whole is then kept well stirred, to prevent the driers sinking to the bottom, and the boiling is continued, at a gentle heat, for 3 houre longer; the fire is next withdrawn, and, in 24 to 36 hours, the scum is carefully removed, and the clear supernatant oil decanted from the bottom. This forms the best boiled or drying oil. Another method is to heat a hogshead of tht *I * VAR 543 VAR gradually for 2 hours, then to gently simmer it for about 3 hours longer, and, after removing the scum, to add gradually 1 lb. of the best calcined mag- nesia, observing to mix it up well with the oil, and afterwards to continue the boiling pretty briskly for 1 hour, employing constant agitation. The fire is then allowed to die away, and, after 24 hours, the oil is decanted as before. The product is called " clarified oil," and requires to be used with driers. It should be allowed to lie in the cistern for 2 or 3 months to clarify. In the preparation of oil var- nishes, the " gum" is melted as rapidly as possible, without discoloring or burning it; and when com- pletely fused, the oil, also heated to nearly the boiling point, is poured in, after which the mix- ture is boiled till it appears perfectly homogeneous and clear like oil, when the heat is raised, and the driers (if any are to be used) gradually and cau- tiously scattered in, and the boiling continued, with constant stirring, for 3 or 4 houre, or till a lit- tle when cooled on a palette knife, feels strong and stringy between the fingers. The whole is next allowed to cool considerably ; but while still quite fluid, the turpentine, previously made moderately hot, is cautiously added, and the whole thoroughly incorporated. The varnish is then run through a filter or sieve into stone jars, cans, or other vessels, and set aside to clarify by subsidence. When no driers are used, the mixture of oil and gum is boil- ed till it runs perfectly clear, when it is removed from the fire, and, after it has cooled a little, the turpentine is added as above. It is generally con- ceived that the more perfectly the " gum" is fused, or " run," as it is called, the greater and stronger will be the product; and the longer the boiling of the " gum" and oil is continued, within modera- tion, the freer the varnish will work and cover when made. An excess of heat renders the varnish " stringy," and injures its flowing qualities. For pale varnishes as little heat as possible should be employed throughout the whole process. Body varnishes shou'd contain 1£ lbs. ; carriage, wain- scot, and mahogany varnish 1 lb. ; and gold size, and black japan, fully £ lb. of " gum" per gallon, besides the asphaltum in the latter. The use of too much driers injures the brilliancy and trans- parency of the varnish. Copperas does not com- bine with varnish, but only hardens it; sugar of lead does. I am informed that boiling oil of tur- pentine combines very readily with melted copal, and that it is an improvement to use it, either be- fore or in conjunction with the oil, in the prepara- tion of copal varnish that is desired very white. All varnishes require age before use. Trans, of the Soc. of Arts, vol. 49; and Copal, Amber, Caoutchouc. *** From the inflammable nature of the mate- rials of w'lich varnishes are composed, their manu- facture should be only carried on in a detached building, that is of little value, and built of unin- flammable materials. When a pot of varnish, gum, or turpentine, catches fire, it is most readily extinguished by closely covering it with a piece of stout woollen carpeting, which should be always kept ready for the purpose. t+t To give lustre to varnish after it is laid on, it is rubbed with pumice-stone very finely powder- ed, and water ; which being dried with a cloth, the work is afterward patiently rubbed with an I oiled rag and tripoli, till the required polish is pro* duced. The surface is last of all cleaned with soft linen cloths, cleared of all greasiness with powder of starch, and rubbed bright with the palm of the hand. ir^*? In varnishing, care must be taken that the surface is free from grease, or smoke ; as un- less this is the case, the best oil or turpentine var- nish in the world will not dry and harden. Old articles are usually washed with soap and water, by the painters, before being varnished. VARNISH, AMBER. Prep. I. (Pale.) Am- ber, pale and transparent, 6 lbs.; fuse, add hot clarified linseed oil 2 gallons; boil till it strings strongly, cool a little, and add oil of turpentine 4 gallons. Pale as copal varnish ; soon becomes very hard, and is the most durable of oil varnishes; but requires time before it is fit for polishing. When wanted to dry and harden quicker, " dry- ing" oil may be substituted for linseed, or " driers" may be added during the boiling. II. Amber 1 lb.; melt, add Scio turpentine £ lb.; transparent white resin 2 oz.; hot linseed oil 1 pint; and afterwards oil of turpentine q. s.; as above. Very tough. III. (Hard.) Melted amber 4 oz.; hot boiled oil 1 quart; as before. IV. (Pale.) Very pale and transparent amber 4 oz. ; clarified linseed oil and oil of turpentine, of each 1 pint; as before. %* Amber varnish is suited for all purposes, where a very hard and durable oil varnish is re- quired. The paler kind is superior to copal var- nish, and is often mixed with the latter to increase its hardness and durability. (See Amber.) VARNISH, BLACK. Prep. I. (Black am- ber varnish.) Amber 1 lb.; fuse, add hot drying oil £ pint; powdered black rosin, and asphaltum, (Naples) of each 3 oz.; when properly incorpo- rated and considerably cooled, add oil of turpentine 1 pint. This is the beautiful black varnish of the coachmakers. It is also fit for metals. II. (Ironwork black) Asphaltum 48 lbs. ; fuse, add boiled oil 10 gallons ; red lead and litharge, of each 7 lbs.; dried and powdered white copperas 3 lbs.; boil for 2 hours, then add dark gum amber (fused) 8 lbs.; hot linseed oil 2 gallons ; boil for 2 hours longer, or till a little of the mass, when cool- ed, may be rolled into pills, then withdraw the heat, and afterwards thin down with oil of turpen- tine 30 gallons. Used for the ironwork of carriages, and other nice purposes. III. (Black japan.) Naples asphaltum 50 lbs.; dark gum anime 8 lbs.; fuse, add linseed oil 12 gallons ; boil, add dark gum* amber 10 lbs.; pre- viously fused and boiled with linseed oil 2 gallons ; add the driers, and proceed as last. Used for wood or metals. IV. (Brunswick black)—a. Foreign asphaltum 45 lbs.; drving oil 6 galls.; litharge 6 lbs.; boil as last, and thin with 25 gallons of oil of turpentine. Used for ironwork, &c.—b. Black pitch and gas tar asphaltum, of each 25 lbs.; boil gently for 5 hours, then add linseed oil 8 gallons ; litharge and red lead, of each 10 lbs.; boil as before, and thin with oil of turpentine 20 gallons. Iuferior to the last, but cheaper. (See Amber Varnish.) VARNISH, BODY. Prep. I. Finest African copal 8 lbs.; fuse carefully, add clarified oil 2 gal- VAR 514 VAR Ions ; boil gently for 4£ hours, or till quite stringy, cool a little and thin with oil of turpentine 3£ gal- lons. Dries slowly. 11. Pale gum copal 8 lbs.; clarified oil 2 gal- lons ; dried sugar of lead £ lb.; boil as before, then add oil of turpentine 3£ gallons, and mix it, while still hot, with the following varnish:—8 lbs. of pale gum anime ; linseed oil 2 gallons ; dried white cop- peras i lb. ; boil as before, and thin with oil of turpentine 3£ gallons ; the mixed varnishes are to be immediately strained into the cans or cistern. Dries in about 6 hours in winter, and 4 hours in summer. Used for the bodies of coaches and other vehicles. VARNISH, CABINET-MAKERS'. Prep. I. Very pale shellac 5 lbs.; mastich 7 oz.; alcohol, of 90g, 5 or 6 pints ; dissolve in the cold with fre- quent stirring. Used for French polishing, &c. It is always opaque. A similar varnish, made with weaker spirit, is used by bookbinders to var- nish morocco leather book covers. II. As the last, but substitute wood naphtha 6 pints for the alcohol. III. (Japanner's copal varnish.) Pale African copal 7 lbs ; fuse, add clarified linseed oil £ gallon ; boil for 5 minutes, remove it into the open air, add boiling oil of turpentine 3 gallons, mix well, strain it into the cistern, and cover it up immediately. Used to varnish furniture, and by japanners, coachmakers, &c. Dries in 15 minutes, and may be polished as soon as hard. (See French Polish.) VARNISH, CARRIAGE. I. (Spirt/.) San- darach 19 oz.; pale shellac 9 J oz.; very pale trans- parent rosin, 12£ oz.; turpentine 18 oz.; alcohol, at 85°;, 5 pints ; dissolve. Used for the internal parts of carriages, &c. Dries in 10 minutes or less. II. (Best Pale.) Pale African copal 8 lbs.; fuse, add clarified linseed oil 2£ gallons ; boil till very stringy, then add dried copperas and litharge, of each \ lb.; boil as before directed, thin with oil of turpentine 5£ gallons, mix while hot with the fol- lowing varnish, and immediately strain the mix- ture into a covered vessel:—Gum anime 8 lbs.; clarified linseed oil 2} gallons; dried sugar of lead and litharge, of each \ lb.; boil as before, thin with oil of turpentine 5£ gallons, and mix it while hot with the last varnish as above directed. Dries in 4 hours in summer and 6 in winter. Used for the wheels, springs, and carriage parts of coaches, and other vehicles, and by house painters, decora- tors, &c, who want a strong, quick-drying, and durable varnish. III. (Second Quality) Sorted gum anime 8 lbs.; clarified oil 3 gallons ; litharge 5 oz.; dried and powdered sugar of lead and white copperas, of each 4 oz.; boil as last and thin with oil of tur- Dentine 5£ gallons. VARNISH, COPAL. Prep.—l. (Turpentine.) Oil of turpentine 1 pint; set the bottle in a water bath, and add in small portions at a time, 3 oz. of powdered copal that has been previously melted by a gentle heat, and dropped into water; in a few days decant the clear. Dries slowly, but is very pale and durable. Used for pictures, &c. II. (Oil.) Pale hard copal 2 lbs.; fuse, add hot drying oil 1 pint; boil as before directed, and thin with oil of turpentine 3 pints, or q. s. Very pale. Dries hard in 12 to 24 hours. III. Clearest and palest African copal 8 lbs.; fuse, add hot and pale drying oil 2 gallons ; boil till it strings strongly, cool a little, and thin with hot rectified oil of turpentine 3 gallons, and imme- diately strain into the store can. Very fine. Both the above are used for pictures. IV. (Spirit.) Coarsely-powdered copal and glass, of each 4 oz.; alcohol, of 90$, 1 pint; cam- phor £ oz.; heat it in a water-bath so that the bubbles may be counted as they rise, observing fre- quently to stir the mixture ; when cold decant the clear. Used for pictures. V. Copal melted and dropped into water 3 oz.; gum sandarach 6 oz.; mastich and Chio turpentine, of each 2£ oz. ; powdered glass 4 oz.; alcohol, of b5°r, 1 quart; dissolve by a gentle heat. Used for metal chairs, &c. *** All copal varnishes are hard and durable, though less so than those made of amber, but they have the advantage over the latter of being paler. They are applied on coaches, pictures, polished metal, wood, and other objects requiring good durable varnish. (See Body and Carriage Var- nishes, and Copal.) VARNISH, CRYSTAL. Prep. I. Genuine pale Canada balsam and rectified oil of turpentine, equal parts ; mix, place the bottle in warm water, agitate well, set it aside, in a moderately warm place, and in a week pour off the clear. Used foi maps, prints, drawings, and other articles of paper, and also to prepare tracing paper, and to transfer engravings. II. Mastich 3 oz.; alcohol 1 pint; dissolve. Used to fix pencil drawings. VARNISH, ETCHING. Prep. I. (Lawrence.) White wax 2 oz.; black and Burgundy pitch, of each £ oz.; melt together, add by degrees pow- dered asphaltum 2 oz., and boil till a drop taken out on a plate will break when cold by being bent double 2 or 3 times between the fingers; it must then be poured into warm water and made into small balls for use. II. (Callot's Hard Varnish. Florentine do.) Linseed oil and mastich, of each 4 oz.; melt to- gether. III. (Callot's Soft Varnish.) Linseed oil 4 oz.; gum benzoin and white wax, of each £ oz.; boil to two-thirds. VARNISH, FURNITURE. Prep. White wax 6 oz.; oil of turpentine 1 pint; dissolve by a gentle heat. Used to polish wood by friction. (See Cabinet-makers' and Copal Varnishes.) VARNISH, FLEXIBLE. Prep.—l. Indian rubber in shavings 1 oz.; mineral naphtha 2 lbs.; digest at a gentle heat in a close vessel till dissolved, and strain.—2. Indian rubber 1 oz.; drying oil 1 quart ; dissolve by as little heat as possible, em- ploying constant stirring, then strain. 3. Linseed oil 1 gallon ; dried white copperas and sugar of lead, of each 3 oz.; litharge 8 oz.; boil with con- stant agitation till it strings well, then cool slowly and decant the clear. If too thick, thin it with quick-drying linseed oil. The above are used for balloons, gas bags, &c. (See Balloon Varnish and Caoutchouc) VARNISH FOR GILDED ARTICLES. Prep. (Watin.) Gum lac in grains, gamboge, dragon's blood, and annotto, of each 12£ oz.; saf- fron 34 oz.; each resin must be dissolved separate- VAR 545 VAR y in 5 pints of alcohol of 90g, and two separate tinctures must be made with the dragon's blood and annotto in a like quantity of spirit, and a proper proportion of each mixed together to pro- duce the required shade. VARNISH, ITALIAN. Prep.—l. Beil Scio turpentine till brittle, powder, and dissolve in oil of turpentine.—2. Canada balsam and clear white rosin, of each 6 oz.; oil of turpentine 1 quart; dis- solve. Used for prints, &c. VARNISH, LAC. Prep.—l. Seed lac 8 oz.; alcohol 1 quart; digest in a close vessel in a warm situation for 3 or 4 days, then decant and strain.— 2. Substitute lac bleached by chlorine for seed lac. Both are very tough, hard, and durable ; the last almost colorless. Used for pictures, metal, wood, or leather. VARNISH, LAC. Syn. Lacquer. Prep. I. Seed lac 3 oz. ; turmeric 1 oz.; dragon's blood \ oz. ; alcohol 1 pint; digest for a week, frequently shaking, decant and filter. Deep gold colored. II. Ground turmeric 1 lb.; gamboge 1£ oz. ; gum sandarach 3£ lbs.; shellac | lb.; all in pow- der ; rectified spirit of wine 2 gallons ; dissolve, strain, and add turpentine varnish 1 pint. Gold colored. III. Spanish annotto 3 lbs.; dragon's blood 1 lb. ; gum sandarach 3£ lbs.; rectified spirit 2 gal- lons ; turpentine varnish 1 quart; dissolve and mix as the last. Red colored. IV. Gamboge cut small 1 oz. ; Cape aloes cut small 3 oz.; pale shellac 1 lb.; rectified spirit 2 gallons ; as the last. Pale brass colored. V. Seed lac, dragon's blood, annotto, and gam- boge, of each \ lb. ; saffron 1 oz.; rectified spirit of wine 5 quarts ; as last *** Lacquers are used upon polished metals and wood to impart the appearance of gold. As they are wanted of different depths and shades of color, it is best to keep a concentrated solution of each coloring ingredient ready, so that it may at any time be added to produce any desired tint. VARNISH, MAHOGANY. Prep. Sorted gum anime 8 lbs.; clarified oil 3 gallons; litharge and powdered dried sugar of lead, of each \ lb.; boil till it strings well, then cool a little, thin with oil of turpentine 5£ gallons, and strain. VARNISH, MASTICH. Syn. Picture Var- nish. Turpentine Varnish. Prep.—1. (Fine) Very pale and picked gum mastich, 5 lbs.; glass pounded as small as barley, and well washed and dried, 2£ lbs.; rectified turpentine 2 gallons ; put them into a clean 4 gallon stone or tin bottle, bung down securely, and keep rolling it backwards and forwards pretty smartly on a counter or any other Bolid place for at least 4 hours ; when, if the gum is all dissolved, the varnish may be decanted, strain- ed through muslin into another bottle, and allowed to settle. It should be kept for 6 or 9 months be- fore use, as it thereby gets both tougher and clearer. II. (Second Quality.) Mastich 8 lbs. ; turpen- tine 4 gallons ; dissolve by a gentle heat, and add pale turpentine varnish £ gallon. III. Gum mastich 6 oz.; oil of turpentine 1 quart; dissolve. *#* Mastich varnish is used for pictures, &c.; when good, it is tough, hard, brilliant, and color- less. Should it get " chilled," 1 lb. of well-washed * 69 silicious sand should be made moderately hot, and added to each gallon, which must then be well agitated for 5 minutes, and afterwards allowed to settle. VARNISH, OAK. Prep.—l. Clear pale rosin, 3£ lbs.; oil of turpentine 1 gallon; dissolve.—2. Clear Venice turpentine 4 lbs.; oil of turpentine 5 lbs. ; mix. Both are good common varnishes for wood or. metal. VARNISH, OIL. Prep.—I. Rosin 3 lbs.; melt, add Venice turpentine 2 lbs.; pale drying oil 1 gallon ; cool a little and thin with oil of turpentine 1 quart.—2. Rosin 3 lbs.; drying oil £ gallon ; melt and thin with oil of turpentine 2 quarts. Both the above are good varnishes for common work. VARNISH, PICTURE. Several varnishes are called by this name. Pale copal or mastich varnish is generally used for oil paintings, and crystal, white hard spirit, or mastich varnish, for water-color drawings on paper. VARNISH, SPIRIT. Prep. L (Brown Hard.)—a. Sandarach 4 oz.; pale seed lac 2 oz.; elemi (true) 1 oz.; alcohol 1 quart; digest with agitation till dissolved, then add Venice turpentine 2 oz.—6. Gum sandarach 3 lbs.; shellac 2 lbs.; rectified spirit, (65 over proof,) 2 gallons; dis- solve, add turpentine varnish 1 quart; agitate well and strain. Very fine.—c. Seed lac and yellow resin, of each 1£ lbs. ; rectified spirit 2 gallons. II. (White Hard.) a. Gum sandarach 5 lbs.; camphor 1 oz.; rectified spirit (65 over proof) 2 gallons ; washed and dried coarsely-pounded glass 2 lbs.; proceed as in making mastich varnish ; when strained add 1 quart of very pale terpentine varnish. Very fine.—6. Picked mastich and coarsely-ground glass, of each, 4 oz.; sandarach and pale clear Venice turpentine, of each 3 oz. ; alcohol 2 lbs.; as last.—c. Gum sandarach 1 lb.; clear Strasburgh turpentine 6 oz.; rectified spirit (65 over proof) 3 pints; dissolve.—d. Mastich in tears 2 oz.; sandarach 8 oz. ; gum elemi 1 oz.; Strasburgh or Scio turpentine (genuine) 4 oz.; rectified spirit (65 o. p.) 1 quart Used on metals, &.c. Polishes well. III. (Soft Brilliant.) Sandarach 6 oz.; elemi (genuine) 4 oz.; anime 1 oz.; camphor £ oz.; rectified spirit 1 quart; as before. *#* The above spirit varnishes are chiefly ap- plied to objects of the toilette, as work-boxes, card-cases, &c, but are also suitable to other articles, whether of paper, wood, linen, or metal, thdt require a brilliant and quick-drying varnish. They mostly dry almost as soon as applied, and are usually hard enough to polish in 24 houre. Spirit varnishes are less durable and more liable to crack than oil varnishes. VARNISH, STOPPING OUT. Syn. Petit Vernis. Prep. Lampblack made into a paste with turpentine. Used by engravers. VARNISH, TRANSFER Syn. Mordant. Prep. Mastich in tears 6£ oz.; rosin 12£ oz.; pale Venice turpentine (genuine) and sandarach, of each 25 oz.; alcohol 5 pints; dissolve as before. Used for fixing engravings or lithographs on wood, and for gilding, silvering, &c. (See Crystal Varnish.) VARNISH, TURPENTINE. Prep. Mastich VEG 546 VEG in tears lg oz.; pounded glass 5 oz.; camphor £ oz.; oil of turpentine 1 quart; digest with agita- tion till dissolved, then add Venice turpentine (pure) 1 £ oz.; previously liquefied by a gentle heat, mix well, and the next day decant. Very fine. Used for paintings. See Mastich. VARNISH, WAINSCOT. The same as mahogany varnish, but using paler gum and oil. (See Oak Varnish.) VARNISH, WAX. Prep—1. (Milk of Wax.) White wax (pure) 1 lb.; melt with as gentle a heat as possible, add warm spirit of wine, sp. gr. 0-830, 1 pint; mix perfectly, and pour the liquid out upon a cold porphyry slab; next grind it with a muller to a perfectly smooth paste, with the addition of more spirit as required, put the paste into a marble mortar, make an emulsion with water 3£ pints, gradually added, and strain through muslin. Used as a varnish for paintings; when dry, a hot iron is passed over it, or heat is otherwise evenly applied, so as to fuse it, and render it transparent; when quite cold it is polish- ed with a clean linen cloth. The most protective of all varnishes. Many ancient paintings owe their freshness at the present day to this varnish. Also used for furniture.—2. Wax 3 oz.; oil of turpentine 1 quart; dissolve by a gentle heat. Used for furniture. VARNISH, WHITE. Prep. I. Tender copal 7£ oz.; camphor 1 oz.; alcohol of 95$, 1 quart; dissolve, then add mastich 2 oz.; Venice turpentine 1 oz.; dissolve and strain. Very white, drying, and capable of being polished when hard. Used for toys. II. Sandarach 8 oz.; mastich 2 oz.; Canada balsam 4 oz.; alcohol 1 quart. Used on paper, wood, or linen. VEGETABLES. Vegetabilia, (P. L.) The following general directions are given in the Lon- don Pharmacopoeia for the collection and preserva- tio .- if vegetable substances: " V egetables are to be gathered in dry weather, and when no dew nor rain is upon them ; they are to be collected every year, and any which shall have been longer kept, ure to be thrown away. " Roots, for the most part, are to be dug up be- fore their stems or leaves shoot forth. " Barks are to be collected at that season in which they are more easily separated from the wood." Spring is the season here alluded to ; as at this time, aftej the sap begins to ascend, the bark is in general very easily separated. " Leaves are to be gathered after the flowers have expanded, and before the seeds are mature. " Flowers are to be gathered when just open- ed." The red rose, however, must be gathered before the buds are expanded. " Seeds are to be collected when they are ripe, and before they drop from the plant. They ought to be preserved in their seed-vessels." Pres. " Vegetables, soon after they are gath- ered, except those which are to be used in the recent state, are to be lightly spread out, and dried as quickly as possible, with a heat so gentle that their color will not be altered ; and then pre- served in proper situations or vessels, where the light and moisture are excluded. " Roots, which are required to be preserved fresh, should be buried in dry sand. The Squill bulb, before it is dried, is to be denuded of the arid coats, and cut transversely into thin slices. The corms of colchicum, dug up in July or August, should be cut into thin transverse slices, dried without heat, or in a very gentle heat, and preserved in well-stopped bottles. " Pulpy Fruits, if they be unripe, or ripe and dried, are to be placed in a damp situation until they become soft: then the pulp is to be pressed out through a hair sieve ; afterwards boiled with a gentle heat, frequently stirring; and, finally, the water evaporated in a water-bath, until the pulp acquires a proper consistence. " Over the bruised pods of Cassia pour boiling water, so as to wash out the pulp, which is to be first pressed through a sieve with large holes, and afterwards through a hair sieve; then dissipate the water in a water-bath, until the pulp acquires a proper consistence. " The Pulp or Juice of fresh and ripe fruit is to be pressed through a sieve without boiling it." " Gum-Resins are to be esteemed the best, which occur so free from admixture as not to re- quire purification ; but, if they appear less pure, boil them in water until they soften, and express them through a canvass cloth ; then let the resin- ous portion subside, and evaporate the effused supernatant liquid in a water-bath, adding towards the end the resinous part, and mixing it well into one mass with the gummy part. Those gum- resins that melt easily, may be purified by en- closing them in an ox-bladder, and holding them in boiling water (or steam) until they become so soft that they can be separated from their im- purities through a canvass cloth, by means of a press." Vegetables and their juices may also be preserved by heating in well-closed vessels. The substances to be preserved are to be put into strong glass bottles, with necks of a proper size, corked with the greatest care, luted with a mix. ture of lime and soft cheese, spread on rags, and the whole bound down with wires across it. The bottles are then placed in an oven, the tempera- ture of which is cautiously raised to 212°, or they are enclosed separately in canvass bags, and put into a copper of water, which is gradually heated till it boils, and thus kept for several minutes: the whole is then left to cool, and the bottles a»e taken out and carefully examined before they are laid by, lest they should have cracked, or the lute given way. (See Fruit, Milk, Pickles, Pre- serving, Putrefaction, Vegetable Juices, Ve- getables for distillation, &c.) *** The generality of vegetable substances that exercise no very marked action on the human frame, may be taken in powder, in doses of a drachm, night and morning ; or an ounce, or q. s. to impart a moderately strong taste or color may be infused, or boiled in 1 pint of water, and a wine-glassful or thereabouts, taken 2 or 3 times a day. VEGETABLES FOR DISTILLATION. The Dublin College states that" herbs and flow- ers from which oils and distilled waters are to be obtained, should be dried as soon as they are col- lected.". This method, however much v recom- mended by authority or common usage, is vastly VEG 547 VEN inferior to the plan adopted by the large perfumers and many of the wholesale druggists, which con- sists in preserving the flowers and herbs by means of common salt. The objection which is raised against the use of fresh aromatic plants is thus ob- viated, while the odors of the products of distilla- tion are rendered fully equal or superior to those obtained from the dried plant, fruit, or flowers, without the great loss and trouble attending the drying and preserving of them. Besides, many aromatic and odorous substances almost entirely lose their properties by drying ; while most of them yield more oil, and that of a finer quality, in the fresh than in the dried state. The odor of roses, elder flowers, and a variety of others, are vastly improved by this treatment, and these flowers may thus be preserved with ease and safety from sea- son to season, or even longer, if required. The process simply consists in intimately mixing the flowers, or other vegetables, soon after being gath- ered, with about \ their weight, or less, of good dry salt, and ramming down the mixture as tight- ly as possible into strong casks. The casks should then be immediately placed in a cold cellar, and covered with boards, on which heavy weights should be put to keep the mass tight and close. VEGETABLE JUICES, (EXPRESSED.) The juices of plants are obtained by bruising the fresh leaves in a marble mortar, or in a mill, and expressing the juice, which, after defecation for some hours in a cool situation, is either filtered through paper, or strained after coagulating its al- buminous matter by heat. Some plants require the addition of § of water before pressing. The expression of the juice of lemons, oranges, quinces, &c, is facilitated by previously mixing the pulp with clean chopped straw. Buckthorn berries, mulberries, &c, after being crushed between the hands, are left 3 or 4 days to undergo a slight fer- mentation, before pressing. A very powerful screw press is required for this purpose. The pres- ervation of the juices of the narcotic plants, and some other vegetables, has lately assumed consid- erable interest, from these preparations having been proposed as substitutes for the common tinc- tures. It appears that the juice of young plants just coming into flower, yields only § the amount of extract which may be obtained from the same quantity of juice expressed from the matured plant, or when the flowers are fully blown, and the strength of the product is also inferior. The leaves alone should be preferably employed, and should be exclusively of the second year's growth, when the plants are biennials. (Squire.) Vegetable juices preserved with alcohol, (preserved vegeta- ble juices, Succi alcoholati, Alcoholatures) are prepared as follows:— I. (Bentley.) Bruise the leaves in a marble mor- tar, (on the large scale, in a mill,) and submit them to the action of a powerful press ; allow the juice to remain for 24 hours in a cold place, then decant the clear portion from the feculence, add \ part by measure of rectified spirit, (56 over proof,) agitate, and in 24 hours again decant the clear, and filter it through paper. Keeps well under ordinary cir- cumstances. II. (Squire.) As the last, but adding to the de- canted juice one-half its volume of rectified spirit. Keeps as well as the corresponding tinctures. HI. (Gieseke.) As the last, but using only one- * fifth rectified spirit. IV. To the clear depurated juice, add one-for- tieth part by weight of alcohol, in 24 hours filter, cork down close, and preserve the bottle sunk up to its neck in sand, in a cool cellar. Remarks. The juices preserved by Mr. Bentley, or after his method, are now those generally em- ployed and approved of by the profession, as may be seen from the numerous testimonials from the leading medical authorities in their favor. These preparations have been extensively tried, and in no instance have they failed in producing the most decided* and characteristic effects of the plants from which they are prepared. At a moderate temperature they will keep any length of time. Occasionally there is a slight tendency to deposite, but the sediment has been carefully examined and found not to contain any of the medicinal virtues of the plant. They are confidently recommended by Mr. Bentley as being superior to most other preparations of the like nature, from containing less spirit. The commencing dose of the narcotic juices is about 5 drops. *m* In the above man- ner are prepared the preserved juices of aconite, belladonna, colchicum, (corms,) hemlock, henbane, foxglove, elaterium, lactuca virosa, taraxacum, VEGETATION, METALLIC. Prep. 1. (Tin Tree.) Muriate of tin 3 drs.; nitric acid 10 to 15 drops; distilled or rain water 1 pint; dis- solve in a white glass bottle, and hang in it by a thread, a small rod of zinc. II. (Lead Tree. Arbor Saturni) Sugar of lead 1 oz.; distilled water 1£ pint; acetic acid 2 drops ; dissolve, and suspend a piece of zinc in it, as be- fore. Less lustrous and beautiful than the last. III. (Silver Tree. Arbor Diana) Nitrate of silver 20 grs.; water 1 oz.; dissolve in a vial, and add about £ dr. of mercury. Very brilliant and beautiful. *** In the above experiments, the metals are precipitated in an arborescent form. It is curious to observe the lamina; shoot out, as it were, from nothing, assuming forms resembling real vegeta- tion. This phenomenon seems to result from a galvanic action being set up between the liquid and the metals. VELVET PAINTING. Any of the ordinary non-corrosive pigments or liquid colors, thickened with a little gum, may be employed in this art; preference being, however, given to those that pos- sess the greatest brilliancy, and which dry without spreading. VENTILATION. It is' essential to health that the habitations occupied by us should be free of impure air and all noxious vapors. The first step towards this end is to effect and maintain a liberal circulation of fresh air, either by ventila- tors, or by reg jlarly opening the windows for stated daily periods. The kindling of fires also promotes the circulation of atmospheric currents. Noxious effluvia may be most effectually removed by occasional sprinklings of a solution of chloride of lime upon the floors and walls, the windows be- ing kept open the while. It is always propel, also, that an infected house should be whitewashed Lives are sometimes lost by sleeping in a close room in which charcoal is burning, the person in VER 548 VER this case being stifled with the noxious gas. We advise that every sleeping apartment should be well ventilated, and that no one should go to bed with charcoal burning in the grate or stove. (See Disinfectants, Fumigation, &c.) VERATRINE. Syn. Veratria, (P. L. & E.) Veratrina. Sabadillin. A vegetable alkali, discovered by Pelletier and Caventou in the seeds of veratrum sabadilla, (asagraea officinalis,) in mea- dow saffron, and white hellebore. Prep. (P. L.) Boil sabadilla seeds lb. ij with rectified spirit 1 gal- lon for an hour, in a retort with a receiver fitted to it, decant the solution, boil the residue with an- other gallon of spirit and that which has distilled, pour off the liquor, and boil with fresh spirit a third time ; press the sabadilla, distil the spirit from the liquors mixed and strained, evaporate the residue to the consistence of an extract, boil this three or more times in water acidulated with a little diluted sulphuric acid, and evaporate the strained liquor with a gentle heat to the consistence of sirup; to this, when cold, add magnesia to saturation, assid- uously stirring, then press and wash two or three times ; next dry the residue, and digest it two or three times in spirit with a gentle heat, and strain as often ; distil off the spirit, boil what remains with animal charcoal in water, acidulated with sulphuric acid, for -J hour, strain, well wash the charcoal, evaporate the liquors carefully to the consistence of sirup, precipitate by ammonia, wash, and dry. Remarks. Pure veratria is perfectly white ; but as usually met with, it has more or less of a brown- ish or grayish tint It is odorous, acrid, uncrystal- lizable, fusible at 240° F., scarcely soluble in water, sparingly so in ether, but freely soluble in alcohol. With the dilute acids it forms salts ; with sulphuric acid it strikes an intense red color. A dilute acetic solution of veratria is precipitated white by tincture of galls and by ammonia, and is turned to a superb red by strong sulphuric acid. The smallest portion of its powder causes violent sneezing. " As an external application, it has been efficaciously employed by Majendie in France, and Dr. Turnbull in this country ; but the extrav- agant eulogies of the latter have not tended to con- firm the reputation of the remedy. From 6 to 12 grs. dissolved in f ^j of alcohol as a liniment, or 30 grs. mixed with 3j of olive oil and ^j of lard as an ointment, have been employed in neuralgia, and other painful affections, and in gouty and rheu- matic paralysis. If it be internally employed, the dose should not exceed one-sixteenth part of a grain; and the action of even this minute dose should be watched. In large doses, it is a power- ful irritant poison." VERATRIC ACID. A crystalline, fusible, volatile acid, soluble in alcohol, slightly so in wa- ter, and insoluble in ether, found by Merck in the seeds of sabadilla. It is obtained by exhausting the bruised seed with alcohol and sulphuric acid, and precipitating the filtered solution by milk of lime ; veratrate of lime remains in solution. This salt is decomposed by hydrochloric acid, and the veratric acid crystallizes. VERDIGRIS. Syn. Diacetate of Copper. Subacetate of do. Vert-de-Gris, (Fr) Gruns- rAN, (Ger.) jErugo ; Cupri diacetas impura, (P. L.) When tliis article is of good quality, " it is partly dissolved in water ; and is almost entirely soluble in liquor of ammonia, and, with the assist- ance of heat, in diluted sulphuric acid." (P. L.) " Not above 5°, of impurity should be left" (P. E.) (See Acetate of Copper. Ant. See Copper.) VERDIGRIS, ENGLISH. Prep. I. Blue vitriol 24 lbs.; white vitriol 16 lbs. ; sugar of lea.5 12 lbs.; alum 2 lbs.; all coarsely powdered ; mix, and heat them in a pot over the fire till they unite into a mass. II. (Distilled or crystallized.) Sulphate of copper 12£ lbs. ; dissolve in water, and add a so- lution of 19 lbs. of sugar of lead, or q. s.; filter, evaporate, and crystallize. Both are used as sub- stitutes for foreign verdigris. VERDITER, (BLUE.) Syn. Refiners' Ver- diter. Cendres bleues. A blue pigment, ob- tained by adding chalk, whiti..g, or milk of lime, to the solution of copper in aquafortis ; or by tritu- rating recently precipitated and still moist carbon- ate or oxide of copper with hydrate of lime. Prep. A quantity of whiting, or milk of lime, is put into a tub, and upon this the solution of copper is poured. The mixtu're is to be stirred every day for some hours together, till the liquor loses its color. The liquor is then to be poured off, and more solution of copper is to be added. This is to be repeated till the whiting has acquired the proper color. Then it is to be washed with water, spread on large pieces of chalk, and dried in the sun. Remarks. The cupreous solution employed in the above process, is made by neutralizing the ni- tric solution obtained from the refiners of gold and silver, by heating it along with metallic copper. For the finest qualities of verditer the lime should be of the purest kind, and the cupreous precipitate should be carefully triturated with it, after it is nearly dry, by which a fine velvety color is pro- duced. The cendres bleues en pates of the French differs from the above mainly in a solution of mu- riate of copper being employed, and in the result- ing green precipitate being turned blue by the action of carbonate of potash. Verditer is either dried into a powder, or used as a water color in the moist state. VERDITER, (GREEN.) The process for refiners' verditer frequently miscarries, and a green color is produced instead of a blue. It may also be obtained by omitting the " blueing up" with potash, mentioned above. VERMICELLI. This is prepared from a stiff paste made of a peculiar, fine kind of granular wheat flour calle'd semoule, which is mixed up with hot water, and, after being well kneaded, is formed into small ribands, cylinders, or tubes, by being placed in a vertical cylinder press, the bot- tom of which is filled with proper shaped holes, through which it is driven by the iron plate or " follower" being forced down by means of a pow- erful screw. The pieces that protrude are broken off, twisted into the desired shape upon paper, and dried. (See Macaroni.) VERMILION. Syn. Factitious Cinnabar. Bisulphuret of Mercury. Prep. I. By subli- mation.—a. Mercury202 parts ; sulphur 33 parts; fuse together by a gentle heat, observing not to allow the mass to take fire; when fused, cover over the vessel, cool, powder, and sublime m a VES 549 VIN close vessel, so placed in a furnace that the flame may freely circulate and play upon it to about half its height. The heat should be at first gradually applied, and afterwards augmented till the lower part of the subliming vessel becomes red hot. When cold, the sublimate is broken to pieces, ground along with water to a fine powder, elutri- ated, passed through a sieve, and dried. Prod. About 112$ of the weight of the mercury em- ployed.—b. By grinding 170 lbs. of quicksilver and 50 lbs. of brimstone together, throwing the mixture by ladlefuls into heated earthen sublimers, where it takes fire; the superfluous sulphur being con-, sumed, the mouths of the vessels are then covered with tiles, which stops the conflagration, and the sublimation commences, which is continued until the whole is risen up. Remarks. It is said that the rich tone of Chi- nese vermilion may be imitated by adding to the materials 1$ of sulphuret of antimony, and by di- gesting the ground sublimate, first in a solution of sulphuret of potassium, and next in diluted muri- atic acid, after which it must be well edulcorated with water, and dried. Prod. 10 lbs. for every 9 lbs. of mercury em- ployed. II. In the humid way.—a. (Brunner.) Pure quicksilver 300 parts; pure sublimed sulphur 114 parts; triturate together for several hours till a perfect ethiops is formed, and add gradually caus- tic potassa 75 parts, dissolved in water 450 parts ; continue the trituration for some time, then gently heat the mixture in an iron vessel, at first con- stantly stirring, but afterwards only from time to time, observing to keep the heat at about 113°, or, at all events, under 122° F., and to add fresh wa- ter to compensate for the portion evaporated. When the color begins to redden, great caution is requisite to preserve the mixture at the lower tem- perature, and to keep the sulphuret of mercury perfectly pulverulent; as soon as the color be- comes nearly fine, the process must be conducted with increased caution, and at a lower heat for sqme hours, or till a rich color is produced, when the vermilion must be elutriated with water, to separate any particles of metallic mercury, and carefully dried. Prod. 332 parts of vermilion, equal in brilliancy to the finest Chinese. 6. Mercury 300 parts; sulphur 150 do.; po- tassa 152 do.; water 450 do.; proceed as last, taking care to keep the heat under 130°. Prod. 382 parts. *** Vermilion is a beautiful and per- manent red pigment, and works and covere well both in oil and water. (See Bisulphuret of Mer- cury.) VESICANTS. Prep.—l. (Vesicant Taffeta. Blistering Cloth. Pannus Vesicatorius. Spar- adrap Vesicans) Distil off the ether from a con- centrated ethereal tincture of cantharides, melt the oily residue with twice its weight of wax, and Bpread it on thin oiled silk, (P. Cod.,) or on cloth prepared with wax plaster.*—2. (Blistering Tis- sue. Tela Vesicatoria.) Similar to the last.— 3. (Blistering paper. Charta Vesicatoria.) As * White wax fviij ; olive oil Jiv ; melt together, and add turpentine fj. This plaster spread on cloth forms the Toile preparee a la cire of the Fr»nch. (Henry and Guibourt.) above.—4. (Blistering paper. Epispastic do. Papier Epispastique. Henry and Guibourt.) White wax 8 parts ; olive oil 4 parts ; spermaceti 3 parts ; turpentine, and powdered flies, of each 1 part; water 10 parts; boil slowly with constant agitation for 2 hours, strain through flannel, with- out pressure, and spread the mass before it cools on paper. %* All the above are used as substi- tutes for the ordinary blistering plaster. VESICATORIN. Syn. Cantharidin. Can- tharides-camphor. The blistering principle of Spanish flies discovered by M. Robiquet Prep. I. Prepare a concentrated tincture of cantharides by percolating the powder with alcohol, and aban- don it to spontaneous evaporation ; the cantharidin slowly crystallizes, and may be purified by wash- ing with cold alcohol, boiling with alcohol and an- imal charcoal, filtering, and again allowing the solution to crystallize.—2. Digest the aqueous ex- tract of cantharides in alcohol, filter, evaporate to dryness, digest in sulphuric ether, evaporate, and slightly wash the resulting crystals w'th cold alco- hol. *** Micaceous plates resembling spermaceti; fusible, vaporizable ; insoluble in water ; soluble in ether, oils, and hot alcohol; powerfully vesicant and poisonous. Its vapor, even at ordinary tem- peratures, frequently produces temporary blind- ness. The l-100th part of a grain, placed on a piece of paper, and applied to the edge of the lower lip, caused small blisters in 15 minutes, which, when rubbed with a little simple* cerate, extended over a large surface, and covered both lips with blisters. (Robiquet.) VINEGAR. Syn. Acetum, (Lat.) Vinaigre, (Fr.) Essigsaure, (Ger.) Vinegar is dilute acetic acid, more or less contaminated with gum, sugar, and other vegetable matter. The ordinary colored vinegar consumed in Eng- land (malt vinegar ; acetum, P. L.; acetum Bri- tannicum, British vinegar, P. E.) is prepared from malt, or a mixture of malt and barley, which is mashed with hot water, and the resulting wort is fermented as in the common process of brewing. The liquor is then run into barrels, placed end- ways, tied over with coarse canvass, and arranged side by side in darkened chambers, moderately heated by a stove, and properly supplied with air. Here it remains till the acetous fermentation is nearly complete, which usually occupies several weeks, or even months. The vinegar is next run off into two large tuns, furnished with false bot- toms, on which "rape" (the pressed cake from making domestic wines, or the green twigs or cut- tings of vines) is placed. One of these vessels is wholly, and the other only three-fourths filled. The fermentation commences and proceeds more rapidly in the latter than in the former tun, and the liquor it contains consequently matures sooner. When fit for sale, a portion of the vinegar is with- drawn from the sma'ler quantity, and its place supplied with a like quantity from the full tun, and this in its turn is refilled from the barrels before noticed. This process is carried on with a number of tuns at once, which are all worked in pairs. Malt vinegar was formerly wholly made by placing the wort in casks, loosely covering the bungholes with tiles, and exposing them to the joint action of sun and air for several months, till the acetification was complete. **'" The general properties of this VIN 550 VIN kind of vinegar are well known. Its pleasant "and refreshing odor is derived from acetic acid and acetic ether. Its strength is distinguished by the makers as Nos. 18, 20, 22, 24, the last of which is the strongest, and usually contains about 4-6°; of real acetic acid. Its density varies according to the quantity of foreign matter it contains. Sp. gr. 1*006 to 1*012, (P. E.;) 1*019, (Phillips;) 1*0135 to 1*0251, (Thomson.) This vinegar usually con- tains a small quantity of sulphuric acid. Wine Vinegar (vinaigre d'Orle'ans, French vin- egar, acetum Gallicum, P. E., acetum vini, P. D.) is prepared in wine countries by a similar process to that employed for making malt vinegar. That prepared from white wine (White Wine Vinegar) is most esteemed. It is purer and pleasanter than malt vinegar. Sp. gr. 1*014 to 1*022, (P. E.;) 1*016, (Phillips.) It usually contains from 5 to 6$ of acetic acid. German, or quick method of making Vinegar. We have seen that acetification consists in the mere oxidation of alcohol in contact with organic matter. This fact has led to the adoption of an improved method of making vinegar, which con- sists in the direct employment of dilute alcohol, and in vastly enlarging the surface of the liquid exposed to the air. " This is effected by causing a mixture of 1 part of alcohol at 80 per cent, 4 to 6 parts water, -pj^ of ferment, honey, or extract of malt, to trickle down through a mass of beech shaving* steeped in vinegar, and contained in a vessel called a vinegar generator (essigbilder) or graduation vessel. It is an oaken tub, narrower at the bottom than at the top, furnished with a loose lid or cover, below which is a perforated shelf, (colander or false bottom,) having a number of small holes loosely filled with packthread about 6 inches long, and prevented from falling through by a knot at'the upper end. The shelf is also per- forated with four open glass tubes, as air vents, each having its ends projecting above and below the shelf. The tub at its lower part is pierced with a horizontal row of eight equidistant round holes, to admit atmospheric air. One inch above the bottom is a syphon-formed discharge pipe, whose upper curvature stands one inch below the level of the air-holes in the side of the tub. The body of the tub being filled with beech chips, the alcpholic liquor (first heated to between 75° and 83° F.) is placed on the shelf. It trickles slowly down through the holes by means of the pack- threads, diffuses itself over the chips, slowly col- lects at the bottom of the tub, and then runs off by the syphon pipe. The air enters by the cir- cumferential holes, circulates freely through the tub, and escapes by the glass tubes. As the oxy- gen is absorbed, the temperature of the liquid rises to 100° or 104° F., and remains stationary at that point while the action goes on favorably. The liquid requires to be passed three or four times through the cask before acetification is complete, which is in general effected in from 24 to 36 houre." (Pereira, Mat. Med. I. 391-2.) A mixture of about 80 gallons of water, 9 gallons of spirit of from 44 to 45§ Tralles, and 3 gallons of vinegar, containing 3*5$ of real acid, forming together 92 gallons, yields on an average an almost equal quantity of vinegar, from 90 to 91 gallons, of the above-stated strength. (Knopp.) Wood Vinegar is obtained by the destructive distillation of wood in iron cylinders. Other Vinegars.—Cider Vinegar. From cider worked as malt vinegar.—Sugar Vinegar. Brown sugar 4 lbs. to each gallon of water ; worked as last__Gooseberry Vinegar.—From bruised goose- berries and brown sugar 1^ lbs. to each gallon of water; worked as last.—Raisin Vinegar. From the marc left from making raisin wine. 1 cwt. to 15 gallons of water, along with a little yeast; worked as malt vinegar.—Pickling Vinegar, (Brit- ish white wine do.) As malt vinegar, but paler ^and stronger.—Ale Vinegar, (alegar, acetum cere- visiae.) From strong pale ale, worked upon fine cuttings or rape ; as the last.—Crystal Vinegar Pickling vinegar 1 gallon, agitated with fresh-burnt animal charcoal for 24 hours, and then decanted or filtered. Used for pickles.—Argol Vinegar, (acetum ex tartaro.) White argol or cream of tartar lb. j ; boiling water 2 gallons ; dissolve, cool, add proof spirit 3 pints, and keep it lightly covered in a warm place till ripe. White and pleasant.—Ger- man household Vinegar. Soft water 7£ gallons ; honey or brown sugar 2 lbs.; cream of tartar 2 oz.; corn spirit 1 gallon ; as last. *#* See Acetic Acid, Acetification, Ace- tometry, Fermentation, and Pyroligneous Acid. VINEGAR, AROMATIC. Syn. Aromatic Spirit of Vinegar. Acetum aromaticum. Prep. I. (P. Cod.) Acetic acid fxx ; camphor §ij; oil of cloves 3ss ; oils of cinnamon and lavender, of each 9 drops; mix. II. (Acidum aceticum aromaticum, P. E.) Rosemary and origanum, dried, of each §j ; dried lavender ^ss ; bruised cloves 3ss ; acetic acid lj pints ; digest a week, press, and filter. This wants the addition of about §iiss of camphor. III. (Henry's) Glacial acetic arid strongly scented with the oils of cloves, lavender, rosemary. and calamus aromaticus, to which camphor is add- ed. This is the formula adopted at Apothecaries' Hall. IV. Glacial acetic acid 1 lb.; oil of cloves 3j; oil of rosemary 3ij ; oils of bergamotte and cinna- mon, of each 3ss ; oil of pimento 24 grs.; oil of lavender 3j ; neroli 10 drops ; camphor 5j j alco- hol §ss ; mix. Very fine. V. (Extemporaneous) Acetate of potash (dry) 3j ; oil of vitriol 20 drops ; oils of lemons and cloves, of each 3 drops. *** Aromatic vinegar is used as a pungent and refreshing perfume in faint- ness, &.c. For this purpose it is usually dropped on a small piece of sponge placed in a stoppered bottle or a vinaigrette. It is corrosive, and should be therefore kept from contact with the skin and clothes. VINEGAR, THE CAMP. Prep. Sliced gar- lic 8 oz.; Cayenne pepper, soy, and walnut ketch- up, of each 4 oz. ; 36 chopped anchovies ; vinegar 1 gallon ; powdered cochineal £ oz.; macerate for 1 month, and strain. VINEGAR, CAMPHORATED. Syn. Aci- dum aceticum camphoratum. Prep. (P. E.) Con- centrated acetic acid f ^viss ; camphor ^ss ; dis- solve. Used as aromatic vinegar. VINEGAR OF CANTHARIDES. Syn. Acetum Cantharidis, (P. L. & E.) Prep. (P. L.) Powdered cantharides §ij ; acetic acid, P. L., 1 pint ; digest for 8 days, press, and strain. Used VIN 551 WAF as a counte§r-irritant, and to raise blisters. Many wholesale houses employ twice the above quantity Of flies. VINEGAR, CUCUMBER.—Capsicum Vine- gars-Garlic Vinegar,—Shalote Vinegar,—Onion Vinegar,—Caper Vinegar,—Cress Seed Vine- gar,—Celery Seed Vinegar,—Truffle Vinegar, —Seville Orange-peel Vinegar,—Ginger Vine- gar,—Black Pepper Vinegar,—White Pepper Vinegar,—Chillie Vinegar,—Horseradish Vine- gar, tjf-c, are all made by steeping about an oz. of the articles in each pint of vinegar for 14 days, and straining.—Tarragon Vinegar,—Basil Vinegar, —Green Mint Vinegar,—Elder-flower Vinegar, —Celery Vinegar,—Cherville Vinegar,—Burnet Vinegar, 6fC. Leaves 2 or 3 oz.; vinegar 1 pint; steep for 14 days, then strain, and keep in half- pint bottles. The whole are used in cookery. VINEGAR, CURRIE. Prep. Currie powder £ lb.; vinegar 1 gallon ; infuse for 1 week. Used as a flavoring. VINEGAR, DISTILLED. Syn. Acetum destillatum, (P. L. E. & D.) Prep. (P. L.) Matt vinegar 1 gallon ; distil in glass, (or earthen- ware,) reserving the first 7 pints only for use. *** If a pewter worm is used, a portion of lead is dissolved, and the product becomes cloudy. 100 grs. should saturate 13 grs. of crystallized carbon- ate of soda. It contains about 4*6°; of real acetic acid. (See Acetic Acid.) VINEGARS FROM FLOWERS. Prep. Dried flowers 1 to 2 oz.; distilled vinegar 1 pint; digest for a week, strain, and repeat the process with fresh flowers, if necessary. They may also be prepared by adding 2 or 3 drops, or q. s. of the respective essential oils to the vinegar. *** In a similar way are made the Vinegars of—orange- flowers, (fresh,) elder-flowers, clove-gilly flowers, musk roses, red roses, (vinaigre de rose, acetum rosatum,) rosemary flowers, (vinaigre de rose- marin, acetum anthosatum,) lavender, (vinaigre JistilltS de lavende,) Tarragon, &c. &c. VINEGAR, MARSEILLES. Syn. Vinegar OF THE FOUR THIEVES. PROPHYLACTIC VlNEGAR. Acetum prophylacticum. A. antissepticum. A. THERIACALE. A. QUATUOR FuRUM. ViNAIGRE DES quatre Voleurs. Prep. Summits of rosemary, flowers of sage, dried, of each %iv ; dried lavender flowers, 5'j ? cloves 3j ; distilled vinegar 1 gallon; digest for 7 days, press, and filter. Used as a corrector of bad smells, and formerly as a prophy- lactic against the plague, and other contagious diseases. Said to be a favorite preventive with Cardinal Wolsey, who always carried some with him. ^ VINEGAR OF OPIUM. Syn. Acetum Opii, 'P. E. & D.) Prep. (P. E.) Opium §iv; dis- tilled vinegar f f xvj ; macerate for 7 days, press, and filter. Anodyne and soporific. Preferable to laudanum. Dose. 5 to 30 drops. VINEGAR, RASPBERRY. Prep. Bruised ripe raspberries and white wine vinegar, of each 3 pints; macerate 24 hours, press, strain, and to each pint add white sugar 1 lb.; boil, skim, cool, and to each pint add brandy 2 oz. *** In a similar way may be made Strawberry Vinegar, and Cherry do. VINEGAR OF SQUILLS. Syn. Acetum Scili-s, (P- L- K. & D.) A. scilliticum, (P. L. 1745.) Prep.—1. (P. L.) Squills, recently dried, ^xv ; distilled vinegar 6 pints ; digest at a gentle heat fer 24 hours, press, filter, and add proof spirit £ pint—2. (Wholesale.) Squills 7 lbs.; distilled vinegar 7 gallons; macerate in the cold for 10 days, press, and filter. Expectorant and diuretic Dose. 3ss to 3iss in chronic pulmonary affections and dropsies. VIOLE/r DYE, like purple, is produced by a mixture of red and blue coloring matter, applied either together, or in succession. A good violet may be given to silk or wool by passing it first through a solution of verdigris, then through a de- coction of logwood, and lastly through alum water. A fast violet may be given by dying the goods a crimson with cochineal, without alum or tartar, and, after rinsing, passing them through the indigo vat—Linens or cottons are first galled with lSJJ of gall-nuts, next passed through a mixed mordant of alum, iron liquor, and sulphate of copper, work- ing them well, then worked in a madder bath made with an equal weight of root, and lastly brightened with soap or soda. Another good method is to pass cloth dyed Turkey red through the blue vat.—Wool, silk, cotton, or linen, mor- danted with alum and dyed in a logwood bath, or a mixed bath of Archil and Brazil, also takes a pretty, but false violet. VIOLINE. Syn. Violina. Emetique indi- gene. A white, pulverulent, bitter, acrid sub- stance, extracted from the roots, leaves, flowers, and seeds of the viola odorata. It is sparingly sol- uble in water, and insoluble in ether. Its opera- tion resembles emetine, for which it was at first mistaken. VOMIT, (MARRIOTT'S,) DRY. A mixture of equal parts of sulphate of zinc and tartar emetic. WAFERS. Prep. I. (Flour wafers.) Mix fine wheat flour with water to a smooth pap, add col- oring as required, pass the mixture through a sieve, to remove any clots or lumps, fill the ' wafer- irons' (previously warmed, and greased with but- ter or olive oil) with the batter, close them tight, and expose them for a short time to the heat of a clear charcoal fire. The whole must then be allowed to cool, when the irons must be opened, and the thin cake, which is now hard and brittle,. must be cut into wafers, by means of sharp annular steel punches. *** The ' wafer-irons' consist of two plates of iron, united together in a similar manner to a pair of pincers or tongs, and which, when closed, leave a space between their internal surface proper for the thickness of wafers. II. (Gelatin do., Glue do., Transparent do.) Dissolve isinglass, or the best pale glue, in suffi- cient water to form a consistent mass when cold, pour it, while hot, upon the surface of a warm plate of mirror glass, slightly oiled, and surrounded with a border of card paper, (laid flat;) next apply a similar plate, also warmed and oiled, and press the two into as close contact as is permitted by the card paper. When cold, the thin cake of gelatin must be removed, and cut into wafers with punches, as before. III. (Medallion) Color Salisbury glue; fill up the hollow part of a seal with gum water mixed. with any colored powder, leaving the flat part WAT 552 WAT clear; then pour as much of the melted colored glue on the seal as will lie upon it, and let it dry in a gentle heat; when used, wet the paper where the wafer is to be applied, and place the back of the wafer upon the wet paper. *** The coloring matters employed for wafers are the following:—Red, a decoction of Brazil wood, brightened with alum;—yellow, a decoction of French berries, or an infusion of saffron or tur- meric ;—blue, sulphate of indigo diluted with wa- ter, and partly saturated with potash ; green, blue and yellow mixed. Vermilion, gamboge, smalts, &c., are also used for the best wafers. WAFERS. (In cookery.) Prep. Take fine flour, dried and sifted, make it into a smooth thin batter with very good milk, or a little cream and water; add about as much white wine as will make it thick enough for pancakes, sweeten it with a little loaf-sugar, and flavor with beaten cin- namon. When thus prepared, have the wafer- irons made ready by being heated over a charcoal fire ; rub the irons with a piece of linen cloth dip- ped in butter ; then pour a spoonful of the batter upon them, and close them almost immediately ; turn them upon the fire, and pare the edges with a knife, as some of the batter will ooze out. A short time will bake them, when the irons are properly heated. The wafers must be curled round while warm. Wafer Paper is prepared in a similar way to the above. Used by cooks, &c. WARD'S RED DROP. A strong solution of emetic tartar in wine. WARTS on the hands may be removed by the daily use of a little nitrate of silver, or nitric or acetic acid, in the way described at p. 222, (art Corns.) The first of the above applications pro- duces a black stain, and the second a yellow one; both of which, however, wear off after the lapse of some days. Acetic acid scarcely discolors the skin. The papular eruption which covere the hands of some persons, and which is occasionally called " soft warts," is best removed by the daily use of Gowland's lotion. WASH FOR FRECKLES. Prep. Brandy 1£ oz., (or spirits of wine 1 oz.,) water 9 oz., dilu- ted muriatic acid, a teaspoonful; mix. To be used after washing. The substitution of 1 oz. of orange- flower water, or 2 oz. of rose-water, for a like proportion of the water ordered above, renders it much more agreeable. WASH FOR THE TEETH. Prep. Chloride of lime £ oz.; water 2 oz.; agitate well together m a vial for £ an hour, filter, and add spirit 2 oz., rose or orange-flower water 1 oz. Used diluted with water, by smokers and persons having a foul breath. WATCHFULNESS. Syn. Sleeplessness. Agrypnia, (from a, priv. and favos, sleep.) The common causes of watchfulness are thoughtfulness or grief, a disordered stomach or bowels, heavy and late suppers, or deficiency of proper exercise. The best treatment in ordinary cases consists in an attention to those points. The method of pro- ducing sleep recommended by a late celebrated Hypnotist, consisted in merely adopting an easy recumbent position, inclining the head towards the chest, shutting the eyes, and taking several deep Inspirations with the mouth closed. Another meth- od recommended by an eminent surgeon, and which appears infallible if persevered in with prop- er confidence, and which is suitable either to the sitting or recumbent posture, consists in tying a decanter cork with a metallic top, or any other bright object, on the forehead, in such a position that the eyes must be distorted or strained to be capable of seeing it. By resolutely gazing in this way for a short time, without winking, the mus- cles of the eyes gradually relax, and the experi- menter falls asleep. WATER. Syn. Protoxide of Hydrogen. Eau, (Fr) Agua, (Sp.) AcquAj (Ital.) Wasser, (Ger.) Aqua, (Lat.) biup, (Gr.) The ancients regarded water as a simple substance, and as convertible into earth, and various organic products. Earth, air, fire, and water, were at one time conceived to be the elementary principles, or essences of matter, from which all form and substance derived their existence. The true constitution of water was not discovered till about the middle of the last century, when the Honorable Mr. Cavendish proved that this liquid was a compound of hydrogen and oxy- gen. These gases exist in water in the proportion of 1 to 8 by weight, or 2 to 1 by volume ; the sp. gr. of hydrogen being to that of oxygen La I to 16. When water is made a part of the voltaic circuit, it is resolved into 2 measures of hydrogen, and 1 measure of oxygen gas ; and if the gases thus ob- tained be mixed, and exploded by the electric spark, they again combine, and produce their own weight of pure water. The composition of water is thus clearly and easily demonstrated, by analy- sis and synthesis. In the production of water from its constituent gases, there is a condensation of nearly 2000 volumes into 1, thus showing the won- derful effects of chemical combination. One cubic inch of perfectly pure water at 62° F., and 30 inches of the barometer, weighs 252*458 grs.; by which it will be seen that it is 815 times heavier than atmospheric air. Its sp. gr. is 10, it being made the standard by which the densities of other bodies are estimated. The sp. gr. of frozen water (ice) is 092 ; that of aqueous vapor 0-6202, air being 1*0. Water changes its volume with the temperature ; its greatest density is at about 39° F., and its sp. gr. decreases from that poiut, either way. By the enormous pressure of 30,000 lbs. on the square inch, 14 volumes of water are conden- sed into 13 volumes. Water evaporates at all tem- peratures, but at 212° this takes place so rapidly, that it boils, and is converted inl.o vapor, (steam,) whose bulk is about 1700 times greater than that of water. The general properties and uses of water are too well known to require notice. Pur. Pure water is perfectly transparent, odor- less, and colorless, and evaporates without residue, or even leaving a stain behind. The purest natu- ral water is that obtained by melting snow or tro zen rain, that has fallen at some distance from any town. Absolutely pure water can only be obtain- ed by the union of its gaseous constituents : but very pure water, sufficiently so for all chemical and philosophical purposes, may be procured by the careful distillation of common water. The follow- ing are the tests usually employed to ascertain the purity of water, or the nature of the substances it holds in solution:—1. Ebullition. If a precipitate is formed, or a crust deposited on the vessel, it in- | dicates the presence of carbonate of lime. This if WAT 553 WAT the cause of the calcareous fur that lines tea- kettles and boilers used for common water.—2. Evaporation. The matter left behind when water is evaporated is impurity ; if it be organic matter, smoke and a peculiar odor will be evolved, as the residue becomes dry and charred.—3. Protosul- phate of Iron. If a little of this test be added to water, placed in a stoppered vial, and a reddish brown precipitate form in a few days, the presence of oxygen gas is indicated.—4. Neither Litmus, sirup of violets, nor turmeric, is discolored or af- fected when moistened with pure water ; if the first two are reddened, it indicates an Acid ; if the last is turned brown an Alkali.—5. Lime- water, mixed with pure water, remains transpa- rent ; if a milkiness ensues when the test is em- ployed before the water has been boiled, and not after, carbonic acid is present.—6. Chloride of Barium occasions a white precipitate, insoluble in nitric acid, in water containing sulphuric acid, (usually in the state of sulphate of lime.)—7. Ox- alate of Ammonia occasions a white precipitate in water, containing carbonate or sulphate of lime. —8. Nitrate of Silver occasions a cloudy white precipitate, insoluble in nitric acid, but soluble in ammonia, in water containing chlorine or muriates. —9. Phosphate of Soda and Ammonia added to water that has been boiled, and precipitated by oxalic acid, (if required,) produces, in a few hours, a white precipitate, if the water contains magnesia. —10. Tincture or Infusion of Galls turns water containing iron black ; when this takes place both before and after the water has been boiled, the metal is present under the form of sulphate ; but if it only occurs before boiling, then carbonate of iron may be suspected, and will be precipitated as a reddish powder by exposure and heat.—11. Fer- rocyanide of Potassium gives a blue precipitate in water containing a sesquisalt of iron, and a white one, turning blue by exposure to the air, in water containing a protosalt of iron.—12. Sulphu- reted Hydrogen and the hydrosulphurets give a brown or black precipitate in water containing iron or lead.—13. Soap, or a solution of soap in alco- hol, mixes easily and perfectly with pure water, but is curdled and precipitated in water containing carbonates, sulphates, or muriates. Var. Distilled Water, (Aqua destillata, P. L. & E. A. Destillata, P. D. A. depurata. Holy water.) The purest kind of artificial water is obtained in quantity, by the distillation of com- mon water, observing to reject the first and last portions thit come over. The still employed for this operation should be used for no other purpose ; and where great nicety is required, the distillation should-be performed in glass or earthenware. Pure distilled water is unaffected by solutions of the caustic and carbonated alkalis, lime, baryta, oxalic acid, acetate of lead, nitrate of silver, or tincture of soap. **■** Distilled water should alone be em- ployed in the preparation of infusions, decoctions, extracts, tinctures, saline solutions, &c, and in the various other processes of chemistry and pharmacy where ddicacy is required, as its power as a men- struum is not only greater than that of common water, hut its purity prevents any secondary de- compactions taking place, which frequently vitiates products, in the preparation of which, impure wa- ter has been used. When distilled water is not at 70 hand, or in large operations, clean filtered or clari- fied rain water is the only kind that can be suc- cessfully substituted.—Rajn Water, (Aqua Plu- vialis. A. Pluvia. A. Imbrium) This is a very pure kind of natural water, but contains minute quantities of air, carbonic and nitric acids, carbon- ate of ammonia, &c.—S.sow Water, (Aqua Ni- valis. A. ex Nive) The purest of all natural wa- ters.—Spring Water. (Aqua, P. E. Aqua Fon- tana) Rain water which has percolated through the earth usually contains mineral impurities. " For pharmaceutical use, spring water must be so far free of saline matter, as not to possess the quality of hardness, or contain above 1-6000th part of solid matter." (P. E.)—River Water, (Aqua Fluvialis. A. ex Flumine) Less pure than good spring water. Thames water contains about l-3500th part of fixed impurities, chiefly carbon- ate of lime.—Well Water, (Pump Water. Aqua Puteana. A. ex Puteo.) Less pure than either of the preceding. Usually contains a large quantity of carbonate and sulphate of lime. Hence its " hard- ness," and property of curdling soap.—Marsh Wa- ter, (Aqua ex Palude) and Lake Water, (Aqua ex Lacu) resemble river water, but contain more organic matter in a state of decomposition, and are hence deemed unwholesome. Sea Water. (Aqua Marina. A. Maris) The characteristic of this variety is its saltness. Its density is about 1*0274, and the average quantity of saline matter which it contains is about 3£ per cent, of which about §-]ths are chloride of sodium, and the re- mainder chiefly chloride of magnesium and sul- phate of magnesia. Pu'rif. Pure water is incapable of putrefaction, but ordinary water contains a small quantity of or- ganic matter in solution, which speedily undergoes decomposition, even in closed vessels. This is es- pecially the case with water kept in wooden casks, or open cisterns, into which leaves and insects may be driven by the wind. Putrescent water is un- wholesome as a beverage. Among the simplest methods for purifying foul water are the following: —1. Filtration or agitation with coarsely-powdered fresh-burnt charcoal, either animal or vegetable ; but preferably the former. This will not only re- move mechanically suspended matter, but also the calcareous and gaseous impurities held in solution. —2. By exposing it freely to the action of the air, by which the organic matter, becoming oxidized and insoluble, speedily subsides. This operation may be easily performed by agitating the water in contact with fresh air, or by forcing air through it by means of bellows.—3. The addition of a little sulphuric acid to water has a like effect; 15 or 20 drops are usually sufficient for a gallon. This ad- dition may be advantageously made to water in- tended for filtration through charcoal, by which plan at least two-thirds of the latter may be saved. (Lowitz.)—4. An ounce of powdered alum, (dis- solved,) well agitated with a hogshead or more of foul water, will precipitate the foul matter in the course of a few hours, when the clear portion may be decanted. When the water is very putrid, a scruple to a drachm may be employed to the gal- lon and any alum that may be left in solution may be precipitated by the cautious addition of an equiv- alent proportion of carbonate of soda.—5. A solu- tion of red sulphate of iron acts in the same way WAT 554 WAT as alum: a few drops are sufficient for a gallon.— 6. Agitation with about the £ of lg of finely-pow- dered black oxide of manganese, has a similar ef- fect to the last.—7. The addition of a little aqueous chlorine, or chlorine gas, to foul water, cleanses it immediately. This method has the advantage of the water being perfectly freed from any excess of the precipitant by heat.—8. Sea water may be rendered fit for washing by the addition of a solu- tion of carbonate of soda or potash as long as it turns milky. After repose, the clear portion must be decanted. t.Dr. Mitchell.)—9. Hard water may be softened in the way last mentioned. Pres. Water is usually preserved on ship-board in iron tanks, or in casks well charred on the in- side. It cannot be safely kept in copper or leaden vessels, and receives a calcareous impregnation by contact with lime, mortar, stucco, or stone con- taining lime. The addition of about £ of 1§ of finely-powdered black oxide of manganese to wa- ter, materially promotes its preservation, especially at sea, as the motion of the vessel and consequent agitation of the water increase the points of contact. WATER, CHALYBEATE. Prep. (Ure.) Protosulphate of iron 3 grs.; bicarbonate of potash 61 grs. ; cold (rain) water 1 quart; mix and agi- tate in a corked bottle. This artificial chalybeate water possesses equal tonic powers to that of the springs; but it may be rendered pleasanter by forcing in a little carbonic acid gas. -WATER-COLOR CAKES. These are the ordinary colors that work well in water, made into a stiff and perfectly smooth paste with gum water, or isinglass size, or a mixture of the two. and then comprei-sed in a polish id steel mould, and dried. WATER, FLY. Prep. White arsenic 1 dr. ; boiling water 1 pint; dissolve, and sweeten with treacle. Used to kill flies. A dangerous method, and one that should never be adopted where there are children. WATERPROOF CLOTH. Prep. I. (Han- cock's Patent.) By spreading the liquid juice of the caoutchouc tree upon the inner surface of the goods, and allowing them to dry in the air. II. (Potter's Patent) By imbuing the cloth on the wrong side with a vtlution of isinglass, alum, and soap, by means of a brush. When dry, it is brushed on the wrong side against the grain, and then gone over with a brush dipped in water. Impervious to water, but not to air. III. (Sierier's Patent.) By applying first a so- lution of Indian rubber in oil of turpentine, and af- terwards another Indian rubber varnish, rendered very drying by the use of driers. On this, Wool or other material of which the fabric is made, cut in- to proper lengths, is spread, and the whole passed through a press, whereby the surface acquires a nap or pile. IV. Moisten the cloth on the wrong side, first with a weak solution of isinglass, and when dry, with an infusion of nutgalls. V. As the last, but substitute a solution of soap for isinglass, and another of alum for galls. WATERPROOF LIQUID. Prep.—l. In- dian rubber \ oz.; oil of turpentine £ pint; put them into a pot, tie it over with bladder, and set it in hoj water; when dissolved, add hot "boiled" oil 1 pint—2. Boiled oil 1 quart; Indian rubber 1 oz.; dissolve by heat.—3. Linseed oil 1 pint; yel- low wax and common turpentine, of each 2 oz.' Burgundy pitch 1 oz.; melt together.—I. Linseed oil 1 pint; suet 8 oz.; beeswax 6 oz. ; rosin 1 oz.; melt together. All the above are used to render leather boots and shoes waterproof. WATER, ROSE. Prep. Otto 3iij; rectified spirit (warm) 1 pint; dissolve, add hot water 10 gallons; mix in a 12-gallon carboy, cork, and agi- tate till cold. This makes the ordinary rose wa- ter of the shops. It is better for distillation. (See Distilled Waters.) WATER, (CORDIAL.) Liqueurs possessing little viscidity. They are prepared in a similar way to the balms, creams, oils, and other cordials of the liqueuriste, but with less sugar. The following is an example of this class of liqueurs :— Water of Cedrat. Double refined sugar 6 lbs. ; boiling rain water 7 quarts; dissolve, add spirit of cedrat 2 quarts ; spirit of citron 1 quart; mix well, and filter while hot, as rapidly as possi- ble, through a clean bag into a carrx , or bottle ; cork down immediately, and in 2 or 3 months bot- tle. Very fine. (See Cordials and Liqueurs.) WATERS, (DISTILLED.) Syn. Aqua Des- tillata, (P. L.) A. Distillate, (P. D.) Dis- tilled Waters, (P. E.) Aromatic do. Per- fumed do. Pure water charged with the odorous and aromatic principles of plants. Distilled waters are mostly employed as vehicles or perfumes. Those intended for medical purposes are common- ly prepared by simply distilling the herb or flowers along with water in an ordinary still; a larger quantity of water being employed than it is intend- ed to draw over, for the purpose of preventing em- pyreuma. The aromatic waters for medical pur- poses may be prepared extemporaneously, of nearly equal quality to those obtained by distillation, by carefully triturating a drachm of any of the essen- tial oils, with an equal quantity of magnesia, and agitating it well with 2 quarts of warm distilled water in a corked bottle ; or as much of a solution of the essential oil in rectified spirit may be added to the water as it will bear, without becoming milky, the whole being well agitated as before, and when cold filtered, if necessary, through bib- ulous paper. White sugar may be advantage- ously substituted for magnesia, as the water is apt to dissolve a little of the latter substance, and is hence rendered unfit to be used as a solvent for metallic salts, especially bichloride of mercury and nitrate of silver. The dose of the aromatic or car- minative waters, as those of dill, caraway, pep- permint, pennyroyal, &c, is a wine-glassful ad libitum. In the distillation of waters intended for per- fumery, the utmost care is requisite to produce a highly fragrant article. The still should be fur- nished with a high and narrow neck, and the heat of steam, or a salt-water bath, should alone be employed. The first few ounces of the runnings should be rejected, except when spirit is used, and the remainder collected till the proper quantity be obtained, observing that the whole product be mixed together ; as distilled waters progressively decrease in strength the longer the process is con- tinued. When a very superior article is desired, the waters may be redistilled by a gentle heat, the first two-thirds only being preserved. The odor of distilled waters is improved by keeping WAT 555 WAT them for some months in a cold cellar loosely cov- ered, as they thus lose the herbaceous smell which they frequently possess when recently pre- pared. When these waters have been carefully prepared, so that none of the liquor in the still has " spirited" over into the condensing worm, they keep well, and are not liable to change ; but should the reverse be the case, they frequently become ropy and viscid. The best remedy is to redistil them. Waters which have acquired a burnt smell in the " stilling,'' lose it by freezing. Distilled waters may be prevented from turning sour by adding a little calcined magnesia to them ; and those which have begun to spoil, may be recovered by adding to ,each pint, a grain each of borax and alum. This doctoring is not, however, to be recommend- ed. A drop of muriate of gold added to these wa- ters shows whether they contain any uncombiued essential oil, by forming in that case a fine metal- lic film ou the surface. After distilled waters have acquired their full odor, they should be carefully preserved in well-stopped bottles. Some houses keep a separate still for each of the more delicate perfumed waters, as it is extremely difficult to re- move any odor that adheres to the bottom of the still and worm. The best method of cleaning a still is to employ it for the distillation of pure wa- ter with the worm-tub empty. The addition of the small quantity of spirit ordered by the colleges in the preparation of their waters, in no way tends to promote their preservation; in fact, I have ob- served that waters so treated, acetify much sooner than those without spirit. I have prepared scores of hogsheads of rose and elder-flower waters, which have shown no disposition to undergo spontaneous decomposition, without the use of a single drop of spirit. The following are the quantities of the respect- ive ingredients ordered by the Colleges, for the preparation of one gallon of their distilled waters : —(2 gallons of water are put into the still along withfgvij of proof spirit, but only one gallon is drawn over.)—Dill water, (Aqua Anethi, P. L.) —Caraway do., (A. Carui, P. L.)—Fennel do., (A. Fceniculi, P L.,) bruised seeds lb. iss.—Orange Flower do., (A. jlorum aurantii, P. L.)—Rose do., (A. Rosa, P. L.)—Elderflower do., (A. Sambuci, P. L.;) fresh flowers lb. x.—Cinnamon do., (A Cinnamomi, P. L.)—Cassia do., (A. Cas- sia, P. E.;) bruised bark lb. iss, or essential oil 3ij.—Orange peel do., (A. Corticis Aurantii, P. L. 1746;) fresh peel g v.—Castor do., (A. Cas- torei, P. L. 1746;) castor gv.—Spearmint do., (A. Mentha Viridis, P. L.)—Peppermint do., (A. Mentha Piperita, P. L.)—Pennyroyal do., (A. Mentha Pulegii, P. L.;) fresh herb lb. iv, or dry herb lb. ij, or essential oil 3ij.—Pimento do, (A. Pimenta, P. L.;) berries lb.j, or essential oil 3ij. __Lettuce do., (A. Lactuca, P. Cod.)—Borage do., (A. Boraginis, P. Cod.,) &c., &c, fresh leaves lb. xij.—Lavender do., (A. Lavandula, P. Cod.)—Sage do., (A. Salvia, P. Cod.)—Tansy do., (A. Tanaceti, P. Cod.)—Thyme do., (A. Thy mi, P. Cod.,) &c.; flowering tops lb. vj.— Cherry Laurel do., (A. Laurocerasi, P. Cod.) —-Peach do., (A. Persica, P. Cod.,) &c.; fresh leaves lb. xij.—Bitter Almond do., (A. Amyg- dalarum Amarum, P. Cod.;) bitter almond cake, from which the oil has been expressed, lb. v ; wa- ter q. s.; macerate 24 hours, and distil.—Balm do., (A. Melissa, P. Cod.)—Hyssop do., (A. Hys- sopi, P. Cod.,) &c, fresh tops lb. xij.—Melilot do., (A. Meliloti, P. Cod.)—Origanum do, (A. Ori- gani, P. Cod.,) &c, &c.; dried flowers lb. iij.— Angelica do., (A. Angelica, P. Cod.,) &c. ; bruised seed lb. iij.—Valerian do., (A. Radicis Valeriana, P. Cod.)—Cascarilla do., (A. Corti- cis Cascarilla, P. Cod.)—Clove do., (A. Caryo- philli, P. Cod.)—Sassafras do., (A. Ligni Sassa- fras, P. Cod.)—Juniper do., (A. Bacca Juniperi, P. Cod.,) &c., of each, bruised, lb. iij.—Cherry- laurel Water, (A. Lauro-cerasi, P. E.;) fresh leaves, chopped, lb. j ; water 2£ pints ; distil 1 pint, add compound spirit of lavender f §j, agitate, and if milky, filter it. Dose. 3ssto 3j, as a substi- tute for hydrocyanic acid. It is commonly imita- ted in trade, by dissolving 75 drops of the oil of bit- ter almonds in f §iiss of rectified spirit, and agitating the mixture with 1 gallon of warm distilled water. *** In a similar manner may be made the dis- tilled waters of other aromatic and odorous sub- stances. In general, the druggists draw off 2 gal- lons or more of water from the above quantities of the herbs, barks, seeds, or flowers ; hence the in- ferior quality of the waters of the shops. They do, however, very well for vehicles. The perfumers, on the contrary, use an excess of flowers, or at least reserve only the first and stronger portion of the water that distils over, the remainder being collected and used for a second distillation of fresh flowers. The most beautiful distilled waters are those prepared in the South of France, and which are imported into England under the French names. Thus, Eau de Rose, Eau de fleurs d'- oranges, &,c, are immensely superior to the best English rose or orange-flower water, &c. The water that distils over in the preparation of the es- sential oils is usually of the strongest and finest class. (See Eaux, Essences, and Vegetables for distillation.) WATERS, EYE. Syn. Collyria. Prep. 1. Vinegar gj ; proof spirit or brandy f fss ; rose or elder-flower water f§viij ; mix. In simple ophthal- mia.—2. (Krimer.) Muriatic acid 20 drops ; mu- cilage 3j ; rose water f §ij. To remove particles of iron or lime from the eye.—3. Wine of opium 3ij ; sulphate of zinc 3j; rose and distilled water, of each f §iv; astringent and anodyne ; in painful ophthalmia.—4. (P. C.) Sulphate of zinc 10 grs.; water f%iv; dissolve. An excellent astringent water in ophthalmia. It may be made with rose water.—5. (Bates.) Blue vitriol 15 grs.; camphor 4 grs.; boiling water f giv. When cold make it up 4 pints, and filter. In purulent ophthalmia.—6 (Common.) White vitriol and camphor, of each 3ss; boiling water 1 quart ; when cold filter. Used in ophthalmia.—7. Opium 10 grs.; boiling water f gvj ; when cold, add solution of acetate of am- monia f §ij, and filter. In painful ophthalmia.—8. Camphor julep f gvj ; solution of acetate of ammo- nia and rose water, of each f 3ij; mix. For weak eyes after ophthalmia.—9. (Goulard's.) Solution of diacetate of lead 10 drops ; rose or elder-flower water f ?v1 * mix. In the inflammatory stage of ophthalmia.—10. Acetate of lead 10 gre.; water £ pint; as the last—11. Sulphate of copper 4 grs.; camphor mixture 6 oz.; dissolve. In the purulent ophthalmia of infants.—12. (P. Cod.) Extract of WAT 556 WAT opium 4 grs.; rose water f giv ; dissolve. In pain- ful ophthalmia. WATERS, (In Perfumery.) The simple dis- tilled waters of the perfumer have been already noticed. They may be prepared from any sub- stances which impart their fragrance to water by distillation. The compound waters employed as perfumes consist of very pure rectified spirit, hold- ing in solution essential oils, or other odorous mat- ter, and resemble the esprits, essences, and spirits, before noticed. They differ from extraits in being mostly colorless, or nearly so, and in being gener- ally prepared by distillation, or by the addition of the pure essential oils or essences to carefully rec- tified and perfectly scentless spirit; whereas, the extraits are mostly and preferably prepared by macerating the flowers, &c. in the spirit, after the manner of making tinctures. Extraits are to be preferred to eaux and esprits as the basis of good perfumery, where the color is not objectionable. The sp. gr. of spirit for these preparations should always be under 0-88, and for the finer qualities should be about 0-838 or 0-840. The following are examples of compound perfumed waters .*— Honey Water. Syn. Sweet-scented Honey Water. Aqua Mellis odorifera. Prep.—1. Spirit of roses (No. 3) 2 quarts ; spirit of jasmin and rec- tified spirit of wine, of each 1 quart; essence of Portugal 1 oz.; essences of vanilla and musk, of each (No. 3) 4 oz.; flowers of benzoin 1£ drs.; mix, agitate, and add eau de fleurs d'oranges 1 quart. Delightfully fragrant.—2. Honey 3 oz.; essence of bergamot £ oz.; essence of lemon \ oz.; oil of cloves 12 drops; musk 12 grs.; ambergris 6 grs.; rectified spirit 1 gallon ; orange-flower and rose water, of each 1 quart; macerate 14 days, with frequent agitation, and filter.—3. (Colored.) To the last add hay saffron 20 grs. The above ire used as perfumes, and the last two are made nto ratafias with sugar. *** Honey water for the hair is a different article to the above. It is obtained by the dry distillation of honey, mixed with an equal quantity of clean sand, a gentle heat only being employed. The product is yellowish and acidulous, from the presence of acetic acid. It is used to promote the growth of the hair. Lavender Water. (See Eau de Lavende.) It may be useful to observe here, that the common lavender water, double distilled do., or spirits of lavender of the druggists, is made with spirit at proof, or under; hence its inferior quality to that of the more celebrated perfumers. One ounce of true English oil of lavender is all that will prop- erly combine with one gallon of proof spirit, with- out injuring the color by rendering it muddy Millefleur Water. Syn. Eau de Miltej^eurs. Prep. Very pure rectified spirit 9 pints ; balsam of Peru (genuine) and essence of cloves, of each 1 oz.; essences of bergamot and musk, of each 2 oz.; essences of neroli and thyme, of each -J oz.; eau de fleurs d'oranges 1 quart; mix well. Very fine (See p. 260.) Eau de Mousseline. Prep. Eau de fleurs d'oranges and spirit of clovegilly flower, of each 1 quart; spirit of roses, (No. 3,) spirit of jasmin, (No. 4,) spirit of orange-flowers, (No, 4,) of each 2 quarts ; essences of vanilla and musk, of each (No. 3) 2 oz.; sanders wood £ oz.; mix. Very fine. WATERS, MINERAL. Syn. Aquaj Min- erales. Our space will not permit a description of these individually. The following tables, ex- hibiting their composition, will, however, enable the reader, with a little attention, to produce them artificially:— I Tabular View of the Composition OF SEVERAL OF THE MORE CELEBRATED MINERAL WATERS. From Brande's Manual of Chemistry. One Pint, Wine Measure, contains the following Ingredients: .| Carbon- Carbon- Carbon. |Sulphate Sulphate Sulphate Muriate Muriate | Total j WATERS. Nitro. gen, C.I. Acid, Hydrogen ate tit Soda, ate of ate ot j ot Magne- Lime, Soda, ot Mag. nesia, ot Lime, of Soda, of Mag. nesia. Muriate Oxide of of Lime. Iron. Silica. Temper-ature. of Saline AUTHORITY. grams. sia, grs. grams, grains. grains. grains. grains. grains. Contents CARBONATED. Seltzer 17* 4* 5* 3* 17* Cold 29- Bergman. Pyrmont. 26* 10* 4*5 5*5 8-5 1-5 0*6 do. 30-6 Ditto. Spa .... La- 1*5 4-5 1*5 0-2 0-6 do. 8-3 Ditto. Carlsbad . s' 5- 1-5 8-5 4-5 a trace 0*3 165° 19-8 Klaproth. Pouges 30* 10* 1-2 12- 22 2-5 0*5 Cold 28-4 Hassenfratz. Saint Parize 22* 0-5 115 13* do. 25* Ditto. SULPHUROUS. Harrowgate. 0*8 1- 2*3 0*7 2-5 1-3 77* 11* 1*5 do. 94* Garnet. o> Moffat . 0*5 0*6 1*2 4-5 do. 4*5 Ditto. 5 Aix-la-Chapelle . 5*5 12* 4-2 5* 143° 21*2 Bergman. Cheltenham Sulph. Spring 1-5 23-5 5* 1-2 35* 0-3 Cold 65* Parkes &. Brande. SALINE. Seidlitz . 2-5 0-8 180* 5* 4*5 do. 192*8 Bergman. Cheltenham Pure Saline ... i ... 15* 11* 4*5 50 * do. 80*5 Barkes &. Brande. Bristol.... 3 5 1*5 1*5 1-5 0*5 1* 74° 6* Carrick. Buxton . 0*2 ... ! 1*3 0-3 0-2 003 82° 1-83 Pearson. Bath .... 1 2 ... 1 0*8 1*5 9* 3-3 a trace 0 2 116° 14-6 Phillips. Scarborough . atrace 20* 9* ditto Cold 2-9 Saunders. Barege uncertain 2*5 ditto atrace 0-5 120° 3* Ditto. Plombieres 25 0-3 2*3 1-5 0-3 ? 66* Vauquelin. Kilburn 3 5 8*5? 0*5 1- 12* 37* 5*5 2*5 5*5 0*2 a trace Cold 64*2 Schmeisser. Leamington New Bath 6*4 a trace a trace 19* 14* 53* 1*5 0*8 do. 88-3 Lambe. Leamington Old Bath. 0.3 ditto 7*5 7* 18* 41* do. 73-5 Ditto. CHALYBEATE. Tunbridge 0*59 1* 5 trace of? 003 017 0*30 003 0*05 0*28 do. 0-56 Scudamore. Cheltenham Chalybeate 2*5 0-5 22*7 6* 2*5 41*3 0*8 do. 73*8 Parkes & Brande. Brighton 2-2 4* 3* 0*75 1*4 0*14 do. 9*29 Marcet. II. Table of Analysis of the PRINCIPAL MINERAL WATERS OF Germany. 1 From Brande's Manual. Auschowitz. Dry Ingrbdients found in in Grains 16 oz or Water, Carlsbad. Ems. Marienbad. Kreutzbr. Ferdinands-brunnen. EOER. Franzenbr. Pyrmont. Spa. Geilnau. Selters. Seid-SCHUTZ. PULLNA. Carbonate of Soda 9-695 10-750 8-26 6*197 500 0-7375 6-6210 6*155 Sulphate of Soda 10-689 39-72 22*544 25*50 2-14566 0 0375 0 0420 23*4960 123*8 Muriate of Soda 7*975 7-634 12*45 8*996 7*96 0-44949 0-5430 17*292 Sulphate of Potash . 0*540 0-93 0-93 0*04194 0-07909 0-2872 0*397 4*8940 4*8 Muriate of Potash . 0 045 0-358 Carbonate of Lime 2*37 1-1407 4-1300 4-016 1-847 5*98824 0-9850 2-9705 2-1870 6-8060 0-77 Sulphate of Lime . 7-22132 1•5050 2-6 Subphosphate of Lime 0*0017 0-014 0*01366 0*0156 0•0035 Filiate of Lime 0*024 0-00192 0*0018 Carbonate of Magnesia ■ 1-369 0-7887 3-0560 2-4 0-600 0-32352 1 • 12278 2-1709 1*3180 1*0980 6*406 Sulphate of Magnesia 2*69752 83-1380 93-086 cn' Muriate of Magnesia . 1*12664 1•6300 19-666 oc: Nitrate of Magnesia 7-9070 Alumina . 0-0075 0 0247 Suhphosphate of Alum 0 0024 0-0018 0-01478 0*00851 0*0027 0*0117 Carbonate of Strontia 0-007 0-0107 0 0192 Sulphate of Strontia 0-02063 0-0463 Carbonate of Barytes. 0-0029 0-0019 Silica .... 0-577 0-4139 0*8800 0-669 0-568 0-49689 0*4985 0-2695 0-302 0*1200 0*176 Carbonate of Iron 0 0278 0 026 0*1760 0-4 0-350 0-42846 0-3751 0*0127 Carbonate of Manganese 0 006 0-0037 0-0065 0-092 0*006 0-04852 0 0519 0-0042 Total . Carbonic Acid Gas in 100 cubic inches 41-9239 21-35932 69-616 45-314 42-775 20-55412 4-35903 12-9288 28-0946 130-6845 251-3075 58 51 125 149-56 154 160 136 163*3 130 6*4 6*9 Sprud. 165° Temperature (f) ) Neub. 138 ) Muhl. 128 * Ther. 122 Kess.1170 Kran. 84 53° 49° 53° 56° 50° 51° 58° 58° 58° Analyzed by Berzelius. Struve. Struve. Steinmann. Struvk. Struve. Struve. Struve. Struve. Struve. Stkuve WAX 559 WAX III. Analysis of Sea Water, English Channel, by Schweitzer. Pure water.......964*74372 grs. Chloride of sodium.....27*05948 " " potassium .... 0*76552 " " magnesium . . . 3-66658 " Bromide of magnesium . . . 0*02929 " Sulphate of lime......1*40662 " Sulphate of magnesia . . 2*29578 " Carbonate of lime.....003301 " of the pan. The acid should also be well scat- tered over the whole surface. The melted wax is next covered over, and left for some hours to settle, or till it becomes sufficiently cool to be drawn off into the moulds. It is then very gently skimmed with a (hot) ladle, and bailed or decant- ed into basins, where it is left to cool. Great care must be taken not to disturb the sediment. When no more clear wax can be drawn off, the remainder in the melting pan is allowed to cool, and the cake or "foot," as it is called, is taken out, and the impurities (mostly bees) scraped from its under surface. The remaining portion is f usually reserved for a second operation, but if required, may be at once melted, and strained through canvass into a mould.—Much of the foreign wax has a pale dirty color, which renders it, no matter however pure, objectionable to the retail purchaser. Such wax undergoes the opera- tion of coloring. This is done as follows:—A small quantity of the best roll annotto, cut into slices, (^ lb. more or less, to wax 1 cwt., depending on the paleness of u«j latter,) is put into a clean boiler with about a gallon of water, and boiled for some time, or till it is perfectly dissolved, when a few ladlefuls of the melted wax are added, and the boiling continued till the wax has taken up all the color, or till the water is mostly evaporated. The portion of wax thus treated has now a €eep orange color, and is added in quantity as required to the remainder of the melted wax in the larger boiler, till the proper shade of color is produced when cold, observing to well mix the whole, and to cool a little now and then to ascertain when enough has been added. The copper must be then brought to a boil, and treated with vitriol, &ui., as before.—Another method is to add palm oil (bright) to the wax till it gets sufficient color; but this plan is objectionable from the quantity required for the purpose being often so large as to injure the quality of the wax ; besides which the color produced is inferior, and less transparent and permanent. *#* The great art in the above process is to produce a wax which shall at once be " bright," or semitranslucent in thin pieces, and good colored. The former is best ensured by allowing the melted mass to settle well, and by carefully skimming and decanting the clear por- tion without disturbing the sediment. It should also not be poured into the moulds too warm, as, in that case, it is apt to " separate," and the resulting cakes to be " streaky," or of different shades of color. It should also be allowed to cool very slowly. When cooled rapidly, especially if a current of air fall upon its surface, it is apt to crack, and form cakes full of fissures. Some persons who' are very nice about their wax, have the cakes polished with a stiff brush when quite cold and hard. It is necessary to have the " jacks" or cans, ladles, and skimmers used in the above process kept pretty hot, as without this precaution the wax cools, and accumulates upon them in such quantity as to render them inconvenient, and often quite useless, without being constantly scraped out. Another method of refining crude wax, and which produces a very bright article, is to melt it with about 1 per cent, of concentrated nitric acid, in a large earthen or stoneware vessel, heated by 1000-00000 grs. *** In addition to the above, it may be re- marked that traces of iodine have been found in the water of Cheltenham, (old well,) traces of bromine in the water of Epsom, and traces of both bromine and iodine in that of Leamington, (royal pump.) Manganese has been found in the waters of Tunbridge, Carlsbad, Spa, Pyrmont, Marien- bad, Saidschilts, &c. Traces of phosphoric and fluoric acids have also been found in some mineral waters. It is the opinion of many high authori- ties, that the medicinal virtues of these waters de- pend more on the minute quantities of the above substances, than on their more abundant saline in- gredients.—C. WAX. Syn. Cire, (Fr.) Wachs, (Ger.) Cera, (Lat.) The substance which forms the cells of bees. Pure beeswax (yellow wax, cera flava) has a pleasant ceraceous odor, a pale yel- lowish brown color, and the sp. gr. 0*960 to 0*965. It is frequently adulterated with farina, rosin, and mutton suet or stearine. The first may be de- tected by oil of turpentine, which dissolves only the wax,—the second, by its solubility in cold alcohol, and by its terebiuthinate taste,—the last two, even when forming less than 2$ of the wax, may be detected by its affording sebacic acid by distillation. When greasy matter is present in any considerable quantity, it may also be de- tected by the suspected sample having an unctu- ous feel, and a disagreeable taste. WAX, BEES' (FACTITIOUS.) Syn. Cera flava factitia. Prep.—1. Yellow rosin 16 lbs.; hard mutton suet or stearine 8 lbs.; palm oil 2^ lbs.; melt together.—2. As last, but substitute turmeric 1 lb. for the palm oil.—3. Best annotto 6 oz. or q. s. ; water 1 gallon ; boil till dissolved, add hard mutton suet or stearine 35 lb.s.; yellow rosin 70 lbs. ; boil with constant agitation till perfectly mixed and of a proper color, and as soon as it begins to thicken, pour it out into basins to cool. When cold rub each cake over with a little potato starch. Used instead of wax in oint- ments by farriers. WAX, REFINED. Crude wax, especially that imported, is generally loaded with dirt, bees, and other foreign matter. To free it from these substances, it undergoes the operation of refi- ning. This is done by melting the wax along with about 3g of water in a bright copper boiler, pref- erably heated by steam, and after the whole is perfectly liquid, and has boiled for a few minutes, withdrawing the heat, and sprinkling over its sur- rce a little oil of vitriol, in the proportion of about or 4 oz. (fluid) to every cwt. of wax. This operation should be conducted with great care and circumspection ;• as, if done carelessly, the melted wax will froth up, and boil over the sides WAX 560 WEI ■team or a salt-water bath, and to continue the boiling till nitrous fumes cease to be evolved, after which the whole is allowed to settle, and treated as before. WAX, SEALING. Syn. Cire a Cacheter, (Fr.) Siegellack, (Ger) Prep. I. (Red.) a. Shellac (very pale) 4 oz.; cautiously melt in a bright copper pan over a clear charcoal fire, and when fused add Venice turpentine 1$ oz. ; mix, and further add vermilion 3 oz.; remove the pan from the fire, cool a little, weigh it into pieces, and roll them into circular sticks on a warm marble slab by means of a polished wooden block ; or it may be poured into moulds while in a state of fusion. Some persons polish the sticks with a rag till quite cold. Fine.—h. Shellac 3 lbs.; Venice turpentine 19 oz.; finest cinnabar 2 lbs.; mix as before. Fine.—c. As the last, but use £ less vermilion.—d. Rosin 4 lbs.; shellac 2 lbs.; Venice turpentine and red lead, of each Ik lb.; as before. Common. II. (Black.) a. Shellac 60 parts; very fine ivory-black, reduced to an impalpable powder, 30 parts ; Venice turpentine 20 parts. Fine.—6. As the last, but using lampblack for ivory-black. Fine.—c. Rosin 6 lbs. ; shellac and Venice tur- pentine, of each 2 lbs.; lampblack q. s. Inferior. III. (Bottle Wax)— a. (Black) Black rosin 6£ lbs.; beeswax £ lb.; finely-powdered ivory- black l£lb.; melt together.—6. (Red) As the last, but substitute Venetian red or red lead for ivory-black. IV. (French) Shellac (pale) 3 lbs.; Venice turpentine 14, lb. ; vermilion 2\ lbs.; divide into sticks 12, 24, 36, or 40 to the lb. Fine. V. (Gold.) By stirring gold-colored mica spangles or talc, or aurum musivum into the melted resins when they begin to cool. Fine. * VI. (Marbled.) By mixing 2 or 3 different colored kinds just as they begin to grow solid. VII. (Soft)—1. (Red.) Beeswax 8 parts; olive oil 5 parts; melt, and add Venice turpentine 15 parts ; red lead to color.—2. (Green.) As the last, but substitute powdered verdigris for red lead. Both are used for sealing certain official documents kept in tin boxes ; also as a cement. %* All the above forms for "fine" wax pro- duce " superfine," by employing the best qualities of the ingredients; and " extra-superfine," or " scented," by adding 1$ of balsam of Peru or liquid storax to the ingredients when considerably cooled. The variegated and fancy-colored kinds are commonly scented with a little essence of musk or ambergris, or any of the more fragrant essential oils. The addition of a little camphor, or spirit of wine, makes sealing-wax burn easier. Sealing-wax adulterated with rosin, or which contains too much turpentine, runs into thin drops at the flame of a candle. WAX, WHITE. .Syn. Bleached Wax. Block white Wax. Cera alba in massis. From pure beeswax, by exposing it in thin flakes to the action of the sun, wild, and rain, frequently changing the surface thus exposed, by remelting it, and re- ducing it again to thin flakes. Used in making candles, and in white ointments, for the sake of its color. Virgins' Wax, (Cake white wax, cera alba in offis) The last made into round flat cakes. WEIGHT. The measure of the force by which any body, or any given portion of a substance, gravitates towards the earth. The estimation of the weight of bodies is called weighing, and con- sists in the comparison of the thing to be weighed with some conventional standard. This standard may be determined by the constant ratio which exists between the volume and the weight, or grav- itating power of the same substances when placed in precisely the same physical condition; hence for the primary creation of a standard weight, ref- erence must be had to the measure of the volume of some substance, as a cubic foot or inch of pure water or mercury, the weight of which is constant at the same temperature, and under the same at- mospheric pressure. The method of estimating the weight of bodies, without reference to their volume, or to a standard which is already known, is difficult and uncertain.. In fact, it is impossible to communicate merely by oral description, with- out reference to some sensible object, a proper idea of a pound weight, or a foot-rule ; since the mind requires some known measure of volume or gravi- tating power, for the purpose of comparison. But man is not directly supplied by nature with any constant standard of weight or volume, by which he can accurately determine that of other bodies. The original standard of small weight was the grains or corns of wheat, and of measure, the foot, cubit, span, pace, &c, derived from the human body ; but since the size of grains of wheat, and the linear surface of the human body, varies under different circumstances, and in different individuals, however carefully the specimens may be selected with a view to an average, it is very evident that such bodies can never furnish permanent and ac- curate standards of comparison. It may be fairly stated, that nature furnishes no standard of weight, at the same time invariable and accessible to all mankind, and that without reference to some de- termined and constant measure of volume, no such standard can be created. But the elements ol Buch a standard of measure are furnished by the aid of natural philosophy, and a refined knowledge of the arts. The form and magnitude of the earth are presumed to remain the same in all ages, and hence a determined portion of its circumference, as l-360th part, or a degree, will represent an unal- terable standard, fit for the purposes of metrology. The force of gravitation at the earth's surface is also constant under the same parallels of latitude and at the same elevation above the level of the sea, and hence the length of a second's pendulum is invariable at any given place, under precisely similar circumstances. This furnishes a second element for the determination of a lineal standard, which by its involution forms similar standards of i measure, both of superficies and volume. A meas- ure of bulk or volume being determined, it is easy to estimate weight, or the gravitating power of any substance, by reference to such a standard. As soon as a unit of weight or measure has been agreed on, and a model weight or measure formed, the latter becomes the standard, and others may of course be readily formed by mere comparison; but when these standards, or their representatives, are lost, recourse must he again had to science-and calculation. The relation between the weight and volume of a body, compared to a given stan- WEI 561 WEI dard taken as unity, constitutes its specific gravity. For the purpose of weighing, a balance or lever is required, which, when accurately suspended in a state of equilibrium, will be like affected by like weights appl ed to either extremity. The manu- facture of these instruments requires great skill and experience. A balance, made by Ramsden, turning on points instead of edges, was sensibly af- fected by the 1-1600th of a grain, when loaded with 4 or 5 ounces. This is 1-384,000th part of the weight; so that this beam would determine the weight of any substance to 5 places of deci- mals, besides a sixth figure, which might be esti- mated. (Phil. Trans., vol. 75.) A balance made by the same artist for the Royal Society, was ca- pable of weighing 10 lbs., and yet turned with the l-100th of a grain, which is only the 1-7,000,000th part of the weight. A balance with unequal arms will weigh as accurately as another, of the same workmanship, with equal arms, provided the sub- stance weighed be removed, and standard weights placed in the same scale till the equilibrium be again restored, when the weights so employed, be- ing exactly in the same condition as the substance previously occupying the scale, will of course in- dicate its proper weight. A knowledge of this fact is useful, as it enables any one to weigh correctly with unequal scales, or with any suspended lever. Small Weights may be made of thin leaf-brass. Jeweller's foil is a good material for weights below l-10th of a grain, as low as to l-100thofa grain ; and all lower quantities may be either estimated by the position of the index, or shown by actually counting rings of wire, the value of which has been determined. The readiest way to subdivide small weights, consists in weighing a certain quan- tity of small wire, and afterward cutting it into such parts, by measure, as are desired ; or the wire may be wrapped close round two pins, and then cut asunder with a knife. By this means it will be divided into a great number of equal lengths, or small rings. The wire ought to be so thin, that one of these rings may barely produce a sensible effect on the beam. The following Tables represent the values and relative proportions of the principal Weights employed in Commerce and the Arts. I. English Weights. 1. Imperial Avoirdupois Weight. >. 2 fr« ^ K £ .£ s ■3 fr-0 • 5 • 4) 0 m*0 -° 5 " 0 P. •51 a J3 a 0 •3 * 01 27-34 1 00625 0-0039 0 0 0 1-7705 437-50 16 1* 00625 0 0 9 28328 7000 256 16- 1- 0 0 0 453.25 0 7168 448- 28- 1 0-25 0 0 28672 1792- 112- 4 1* 005 0 573440 35840- 2240- 80 20* 1* %* The standard in avoirdupois weight is the same as in troy weight. The avoirdupois drachm is now never used except in weighing silk ; when- ever a drachm is mentioned in books, the troy, or apothecaries' drachm, is intended. The stone of butchers' meat is 8 lbs., and of other commodities 14 lbs., in London. 2. Imperial Troy Weight Grs. grains. Dwts. pennyweights. Oz. ounce. Lb. pound. 24 480 5760 1 20 240 1 12 1 *#* The standard of the above measure is 1 cubic inch of distilled water, at 62° F., and 30 inches of the barometer, which weighs 252*458 troy grains. The carat used in weighing diamonds is 3| grains, (nearly.) Troy weight is used in weigh- ing gold, silver, jewellery, &c, and in philosoph- ical experiments. 3. Apothecaries' Weight. ^. c S 0 ■-• s 0 i (?) 3 S .s no a *_.-3 0 0-J3 W 0 5 ■o 0 2 fa 1 005 001666 0-00-2083 0-0001736 006475 20 1 03333 00416 0U03472 1-295 60 3 1- 0-1250 0-0104166 3-885 480 24 8- 1* 00833333 31-08 5760 288 96* 12- 1* 372-96 II. French Weights. 1. Metrical or Decimal Weights. Names. Millegramme Centigramme Decigramme Gramme Decagramme Hectogramme Kilogramme, or Kilo Myriagramme Equiv. in grammes. 1 10 100 1000 10000 Equiv. in troy grains. •0154 ■1543 1-5434 15-434 154-3402 1543 4023 15434-0234 Equiv. in avoirdupois weight. lbs. oz. grs. 0i 45- 34 12152 2 3i 12173 154340*2344 122 OJ 12 *** The standard unit in the above table is the gramme. A metrical quintal is 10 myria- grammes. A millier is 1000 kilos. / * As this abbreviation is used to represent both the avoirdupois, and troy or apothecaries' pound,, it is neces- sarv to observe, that the former is indicated when Uis sign is preceded by Arabic figures; and the latter, whem iX is followed by Roman numerals. It was also formerly used along with Roman numerals, to re:eesent the wine- pint. 71 WHE 562 WHI 2. Binary Weights. (Systeme usuel.) c C ca 6 2 09 o 5 c O > 5 a s s « BO s 0* >E o* a *s = <*. "S o s . a is 5 x c-o OS o Equiv. in avoirdupois weight 1 24 72 576 9216 18432 0 1 3 24 384 768 0 0 1 8 128 256 0 0 0 f 1 16 32 0 0 0 0 1 2 0 0 0 0 0 1 •0542 1-30 3-906 3125 500-1000- 1 4 32 500 1000 05 30 lbs.oi. grs. 0-837 201 60-284 1 4.V 1 IJ 61-2 34. 13- *** The old French grain is equal to 0*820 of an imperial troy (Train; hence, 1 troy grain is equal to 1*21 old French grains. The gros, once, and other multiples of the grain, are of course pro- portionate. The new French grain (of 1812) is equal to 0*0542 gramme, or 0*8365228 gr. troy. It is said, in some works, to be equal to 0*878 gr. troy; or, in round numbers, 0*9, but this is much too high. III. Continental Medicinal Weights in Trov Grains. From Dr. Christison's Dispensatory. Scruples consisting of c P a 53 u c E .c: GO _c *J O PL. O & s c o O French 5670-5 470-50 5910 19-7 _ 0-820 Spanish 5326-3 443-49 5514 18-47 - 0-769 Tuscan 5240*3 436-67 54-58 1819 — 0-758 Roman 52350 436-25 54-58 1817 — 0-757 Austrian 64951 54125 67-65 — 22-5 1127 German 5524-8 46040 57-55 — 1918 0-960 Russian 5524-8 46040 57-55 — 19-18 0-960 Prussian 54151 45126 56-40 — 18-80 0-940 Dutch 5695-8 474-64 59-33 — 19-78 0-988 Belgian 56958 474-64 59-33 — 19-78 0-988 Swedish 5500-2 45834 57-29 — 1909 0-954 Piedmontese 4744-7 395-39 49-45 — 1648 0-824 Venetian 4661-4 388-45 48-55 16-18 0809 WELSH RAREBIT. Prep. Cut slices of bread, toast and butter them; then cover them with slices of rich cheese, spread a little mus- tard over the cheese, and put the bread in a cheese-toaster before the fire. Serve it up very hot. WELD. Syn. Woald. Vouede, (Fr.) Reseda luteola, (Lin.) An herbaceous annual employed by the dyers. A decoction of the stems and leaves gives a rich yellow to goods mordanted with alum, tartar, or muriate of tin. The yellow coloring principle may be obtained in beautiful, transparent yellow needles by sublimation. (See Luteoline.) WHEAT The quality of this grain may be ascertained in the way directed for wheat flour, p. 317. WHEY. Syn. Petit Lait, (Fr.) Molken, \fier.) Serum Lactib, (Lat.) The liquid portion of milk after the curd has been separated. It consists chiefly of sugar of milk.—A jxn-nid of milk, mixed with a tablespoonful of proof spirit allowed to become sour, and the whey filtered from the sediment, yields, in the course of a few weeks, a good vinegar (whey vinegar) free from lactic acid. (Scheele.) Skimmed milk may be used. WHISKEY. (From Usquebaugh, the Irish name originally applied to it.) Dilute alcohol ob- tained from the fermented wort of malt or graina That from the former is the most esteemed. The inferior qualities of this spirit are prepared from barley, oats, or rye, a small portion only of which is malted ; or from potatoes mashed with a portion of barley malt, the resulting wash being carelessly fermented and distilled, and purposely suffered to burn, to impart the peculiar empyreumatic or smoky flavor so much relished by the lower orders of whiskey drinkers. The malt whiskey (sold as such) of the principal Scotch and Irish distillers, is fully equal in quality to London gin, from which it merely differs in flavor. The peculiar flavor of Scotch whiskey may be nicely imitated by adding a few drops of pure creosote to 2 or 3 gallons of good London gin ; and the imitation will be still more perfect if the liquor be kept for some months before drinking it. WHITE COPPER. (See German Silver.) WHITE PIGMENTS.—Alum White (Baume's.) Powdered Roman alum 2 lbs.; honey 1 lb.; mix, dry, powder, calcine in a shallow dish to whiteness, cool, wash, and dry. A beautiful and permanent white both in oil and water.— Derbyshire White. Cawk, heavy spar, or native sulphate of barytes.—Flake White. The finer kinds of white lead are so called.—White Lead. (Fine White. Carbonate of Lead. Sub- carbonate of do. Ceruse. Cerussa. Magistery of lead. Plumbi Carbonas, P. L.) Made by suspending rolls of thin sheet-lead over malt vine- gar, or pyroligneous acid, in close vessels, the evaporation from the acid being kept up by the vessels being placed in a heap of dung, or a steam-bath. Commercial carbonate of lead is never quite pure, being commonly adulterated with sulphate of baryta, (heavy spar) and some- times with chalk. The former may be detected by its insolubility in dilute nitric acid, and the latter by the nitric solution yielding a white pre- cipitate with oxalic or sulphuric acid, or oxalate of ammonia, after having been treated with sul- phureted hydrogen, or a hydrosulphuret, to throw down the lead. " Pure carbonate of lead does not lose weight at a temperature of 212° ; 68 grs. are entirely dissolved in 150 minims of acetic acid, diluted with f ^j of distilled water; and the solu- tion is not entirely precipitated by a solution of 60 grs. of phosphate of soda." (P. E.) The so- lution in nitric acid should not yield a precipitate when treated with a solution of sulphate of soda. Used as a superior white paint, and in medicine, externally, as an astringent, refrigerant, and desiccant—French White Lead. (Blanc de Plomb.) Litharge dissolved in dilute acetic acid, and the carbonate of lead thrown down by a current of carbonic acid gas. Does not cover well.—Venetian White Lead, (Cerussa Veneta) Flake white, or puce white lead and cawk, equal WHI 563 WIN parts.—Hamburgh White Lead. Flake white 1 cwt.; cawk 2 cwt.—Best Dutch White Lead. Flake white 1 cwt.; cawk 3 cwt.—Dutch White Lead. Flake white 1 cwt.; cawk 7 cwt. The last four are commonly substituted in trade for genuine white lead.—English White Lead. Flake white lowered with chalk. Covers badly, and color inferior to the preceding.—Grace's White Lead. Made from lead, with the refuse water of the starch-makers, soured brewer's grains, &c.—White Precipitate of Lead. (Sul- phate of Lead.) An acetic or nitric solution of litharge, precipitated by adding dilute sulphuric acid, and the white powder washed and dried. The clear liquid decanted from the precipitate is poured on fresh litharge, when a second solution takes place ; and this may be repeated for any lumber of times. Used in miniature painting, being a beautiful and durable white.—Notting- ham White. White lead made with alegar.— Newcastle White. White lead made with mo- lasses vinegar.—Mineral White. A nitric or acetic solution of litharge, precipitated by car- bonate of soda.—Wilkinson's White. Litharge ground with sea-water till it ceases to whiten, and then washed and dried.—Permanent White. Artificial sulphate of baryta, prepared by precipi- tating the muriate by diluted sulphuric acid, or a «olution of glauber salts. A good fast white. Used to mark jars and bottles for containing acids or alkalis, as it is affected by very few sub- stances.—Pearl White, (Fard's Spanish White) Trisnitrate of bismuth.—Spanish White. (Blanc d'Espagne. Blanc de Troyes) The softest and purest white chalk, elutriated, made into balls, and well dried. Used as a cheap white paint.— Whiting. The same as prepared chalk, but pre- pared more carelessly. WHITES, SHARP. Prep. 1. Wheat flour and powdered alum, equal parts, ground together.—2. (Stuff. Baker's stuff) Alum ground to the coarseness of common salt 1 lb.; common salt 3 lbs.; mix. Both the above are used by bakers for the purpose of introducing alum into their bread under a disguise. WINDOWS, SASH. These may be kept up without sash-lines and pulleys, by means of cork, in the simplest manner, and with scarcely any ex- pense. Bore three or four holes in the sides of the sash, into which insert common bottle corks, pro- jecting about the sixteenth part of an inch. These will press against the window-frames, along the usual groove, and by their elasticity support the sash at any height which may be required. WINDOWS. (Prismatic Diamond Crystals for.) Mix a hot solution of sulphate of magnesia, with a clear solution of gum arabic, and lay it on hot. For a*margin, or for figures, wipe off" the part you wish to remain clear with a wet towel The effect is very pretty. I. Table of the Quantity of Alcohol in Wine. By Dr. Christison. Names, &c. Port Sherry in\ ("Weakest...... j Mean of 7 samples .... ) Strongest...... LWhite...... 'Weakest ...... Mean of 13 wines, excluding those very } long kept in cask . . $ 4 Strongest .... Mean of 9 wines long kept in cask in the East Indies k Madre da Xeres .... ■ - < Long kept in cask in $ Strongest Madeira ^ the Eagt Indjeg -j Weakest Teneriffe long in cask at Calcutta Cercial....... Lisbon (dry)....... Shiraz...... Amontillado . . . . ' . Claret. A first growth of 1811 . Chateau-Latour. Do. 1825 Rosan. Second growth 1825 .... Ordinary Claret. (Vin Ordinaire) . Rivesaltes ....... Malmsey ....... Rudesheimer. 1st quality .... " Inferior .... Hambacher. Superior quality . . Alcohol of 0-7939 per cent, by volume. 14*97 16-20 17*10 14*97 13*98 15*37 16*17 14*72 16*90 16*90 14*09 13*84 15*45 16*14 12*95 12-63 7*72 7*78 7*61 8*99 9*31. 12*86 8*40 6*90 7*35 Proof spirit per cent, by volume. 30*56 33-91 37*27 31*31 30*84 33*59 3512 32*30 3706 36-81 30-86 30-21 33-65 34-71 28-30 27-60 16*95 17*06 16*74 18-96 22-35 28-37 18-44 1519 16*15 WIN 564 WIN II. Quantity of Alcohol (sp. gr. 0-825* at 60° F.) in 100 parts of Wine by volume. Names of Wine. Alcoholic Content. Authority. Alba Flora 17*26 Brande Barsac 13*86 do. Bucellas 18*49 do. Burgundy (average) . 14*57 do. Ditto 12*16 Prout. Calcavella (average) . 18*65 Brande. Cape Madeira (do.) . 20*51 do. Cape Muschat . 18*25 do. Champagne (average) 12-61 do. Ditto 12*20 Fontenelle. Claret (average) 15*10 Brande. Colares 19*75 do. Constantia (White) . 19-75 do. Ditto (Red) . 18*92 do. Ditto (average) 14-50 Prout. C6te kotie. 12*32 Brande. Currant 20*55 do. Elder 8*79 do. Frontignac (Rivesalte) 12*79 do. Gooseberry 11*84 do. Grape (English) 18*11 do. Hermitage (Red) 12*32 do. Ditto (White) 17*43 do. Hock (average). 12*08 do. Lachryma Christi 19*70 do. Lisbon 18*94 do. Lissa (average) . 25*41 do. , Ditto (do.) 15*90 Prout. Lunel 15*52 Brande. Madeira (average) 22-27 do. Ditto (do.) . 21*20 Prout. Malaga 17*26 Brande. Ditto 18*94 do. Malmsey Madeira 16*40 do. Marsala (average) 25-09 do. Ditto (do.) . 18*40 Prout. Nice .... 14*63 Brande. Orange (average) 11*26 do. Port (do.) . 20*64 Prout. Ditto (do.) . 22*96 Brande. Raisin (do.) . 25*41 do. Ditto (do.) . 15*90 Prout. Red Madeira (do.) 20-35 Brande. Roussillou (do.) . 1813 do. Sauterne . 14-22 do. Sheraaz . 15-52 do. Sherry (average) 19-17 do. Ditto (do.) . 23-80 Prout. Syracuse . 20-00 do. Ditto 15-28 Brande. Teneriffe . 19-79 do. Tent .... 13-30 do. Tokay 9-88 do. Vidonia 19-25 do. Vin de Grave 13-94 do. Zante 17-05 do. WINE. Syn. Vin, (Fr) Wein, (Gr.) Wyn, * (Dut.) Win, {Swed) Vino, (Ital. and Span.) Vinum, (Lat.) The fermented juice of the grape. * Alcohol of 0-825 contains 92-6$ of real or anhydrous alcohol, and in round numbers may be said to be about twice the strength of brandy or rum, as usually sold. The general characters and qualities of wine are principally influenced by climate, soil, and aspect, the nature and maturity of the grape, and the method of conducting the fermentation. Want of space will compel us to confine our remarks to the properties, uses, and management of grape-juice after it has passed through the stage of fermenta- tion, or, in reality, become Wine. Some observa- tions connected with this subject will be found in the articles Fermentation and Manures. Officinal Wine. The only wine ordered by the British colleges is sherry, (Vinum Xericum, P. L.; V. Album; White Wine, P. E.; V. Al- bum Hyspanicum, P. D.;) but several other wines are employed in medicine, as tonics, stimu- lants, antispasmodics, and restoratives. In phar- macy, the less expensive Cape or raisin wine is usutiy substituted for sherry in the preparation of the medicated wines of the Pharmacopoeia. Varieties, characteristics, 6cc. Our space will not permit a notice of the principal wines of com- merce individually ; the reader is therefore refer- red to the preceding Tables, which will convey much useful information on this subject in a con- densed form. Composition. The constituents of wine are— alcohol, which is one of its principal ingredients, and on which its power of producing intoxication chiefly depends;—Sugar which has escaped the process of fermentation, and which is most abun- dant in the sweet wines, as tokay.tent, frontignac, &c. ;—Extractive, derived chiefly from the husk of the grape ; its quantity diminishes by precipita- tion, owing to the gradual action of the atmosphere; —Coloring matter; this resides in the husk of the grape, and is extracted by the newly-formed alco- hol ; its natural color is blue or purple; its red tint is owing to the action of free acid ;—Tartar. Bitartrate of potash constitutes the most important portion of the saline matter of wine, and appears to exercise an important influence over the fer- mentation. It is gradually deposited along with coloring matter by age;—Odoriferous matter. The characteristic vinous odor appears to depend upon the presence of cenanlhic acid and ether, but the bouquet of wine arises from the essential oil, prob- ably existing under the form of ether. Besides the above, small quantities of tannin, gum, acetic and malic acids, acetic ether, lime, 6, and it is almost entirely soluble in diluted sulphuric acid, forming a colorless solution. When tested in a Marsh's apparatus it should yield no trace of ar- senic. The following method, by which several pounds of chemically pure zinc may be obtained in about \ of an hour, will be found very useful:— Melt the zinc of commerce in a common crucible, and throw it into a tolerably deep vessel of water, taking care that the metal be very hot at the mo- ment of running. This operation is not without its use, for the more granulated the zinc, the easier it is purified. Dry the grains, and dispose them by layers in a Hessian crucible with one-fourth of their weight of nitrate of potash, using the precau- tion to place a slight excess at the top ancLat the bottom. Cover the crucible, and secure the lid, then apply heat: a vivid deflagration takes place with great disengagement of light, after which re- move the crucible from the fire, separate the dross with a tube, and lastly, run the zinc into an ingot mould. This zinc, submitted to Marsh's apparatus during entire days, has never given any stain, and ZIN 575 ZIN in solution the most sensible reactives—such as hydro-sulphocyanic acid—have never indicated the least atom of iron. (Journ. de Pharm.) Props., Uses, $c. Zinc is a bluish white metal, having the sp. gr. 6*8 to 7*2 ; tough when cold, ductile and malleable at from 212° to 300°, brittle, and easily pulverized at 400° ; fuses at 773°, (Daniell,) and sublimes unchanged at a white heat, in close vessels. It is scarcely affected by expo- sure to air and moisture; hence its general use in the arts for the manufacture of vessels of capacity, tubing, &c, that require lightness and durability. Heated to whiteness, (941° Daniell,) in contact with the air, it burns with great brilliancy, and is converted into oxide, Cflowers of zinc.) It is very soluble in dilute sulphuric and muriatic acid, with the evolution of hydrogen gas. Zinc is used to form galvanic plates; in fireworks, and in medi- cine. Tests. 1. The solutions of zinc are precipitated white by the pure alkalis and carbonate of am- monia, but are completely redissolved by excess of the precipitant.—2. The carbonates of potassa and soda give a permanent white precipitate of carbonate of zinc.—3. Hydrosulphuret of am- monia also gives a white precipitate, and so does sulphureted hydrogen when the solution is quite neutral.—4. Prussiate of potash gives a gelatinous white, or bluish white precipitate. ZINC, ACETATE OF. Syn. Zinci Acetas. Prep.—1. Dissolve oxide of zinc in acetic acid, evaporate and crystallize.—2. Crystallized sul- phate of zinc 143 parts ; crystallized acetate of lead 190 do.; dissolve each separately in water, mix, filter, evaporate, and crystallize. Tonic, antispasmodic, and emetic. Dose. 1 to 2 grs. ; as an emetic 10 to 20 grs.; externally, 2 or 3 grs. to water 1 oz., as an astringent lotion or in- jection. ZINC, BROMIDE OF. Syn. Zinci Bro- Midum. Prepared like the corresponding salt of iron. ZINC, CARBONATE OF. Syn. Zinci Carbonas. Prep. Add a solution of carbonate of soda to another of pure sulphate of zinc; wash and dry the precipitate. For the impure or native carbonate of zinc, (calamina, carbonas zinci impura, P. L.,) see Calamine. ZINC, CHLORIDE OF. Syn. Muriate of Zinc. Butter of do. Zinci Chloridum. Do. Murias. Prep.—1. Evaporate the muriatic solution of zinc to dryness, and transmit dry muriatic acid gas over the residuum, heated in a tube. When pure, colorless, melts at 212°, de- liquescent, volatilized at a red heat, soft, like butter.—2. (P. Cod.) Zinc §xx; muriatic acid q. s.; dissolve, add nitric acid §j, evaporate to dryness, dissolve in water, and add chalk Jj j in 24 hours filter, and evaporate to dryness. Dose. 1 to 2 grs. in scrofula, epilepsy, &c.; and ex- ternally as a caustic, or as an astringent lotion, (2 grs. to water f Jj.) ZINC, CYANIDE OF. Syn. Hydrocyan- ate of Zinc Cyanuret of do. Zinci Cyani- dum. Do. Cyanuretum. Prep. (M. Henry.) Add a sokition of cyanide of potassium to another of pure sulphate of zinc; wash and dry the pre- cipitate. Dose. \ to 1 gr. twice a day, in epilepsy, hysteria, and other nervous affections, heartburn, worms, &c, andj as a substitute for prussic acid. ZINC, FLUORIDE OF. A white com- pound, scarcely soluble in water, obtained by acting on oxide of zinc with liquid hydrofluoric acid. ZINC, IODIDE OF. Syn. Hydriodate of Zinc Zinci Iodidum. Do. Hydriodas. Prep. (Duflos.) Iodine 2 parts ; granulated zinc 1 do.; water 4 do.; proceed as for iodide of iron, only employing a glass or porcelain vessel. De- liquescent. 15 grs. to water f^vj ; used as a collyrium in scrofulous inflammation of the eye, (Poulet;) 3j to lard §j, as a powerful resolvent to scrofulous and other glandular swellings ; rubbed on the part twice a day. (Ure.) ZINC, OXIDE OF. Syn. Zinci Oxydum, (P. L. E. & D.) Zinci Calcinatum. Nihil Album. Lana Philosophica. Pompholyx. Flow- ers of Zinc Calx of do. Flores Zinci. Calx do. Prep. (P. L.) Sulphate of zinc (pure) lb.j ; sesquicarbonate of ammonia §viss ; dissolve each separately in 6 quarts of water, filter, mix, well wash the precipitate with water, and calcine it for 2 hours in a strong fire. " White, tasteless, entirely soluble in diluted nitric acid without ef- fervescence; and this solution is not affected by nitrate of baryta, but yields a white precipitate with ammonia, entirely soluble in excess of the precipitant." (P. L) Dose. 5 to 10 grs., as an antispasmodic; in epilepsy, &c. Used also as a dusting powder, and to make an ointment. It has been proposed as a substitute for white lead in painting, than which it covers better, but dries slower; requires the addition of dried white vitriol. *#* The last eight synonymes are usual- ly applied to the oxide procured by heating the metal in contact with air, but its composition, properties, and uses are the same as those of the oxide, P. L. See Flowers of Zinc ZINC, SULPHATE OF. Syn. Zinci Sul- phas. Prep. I. (P. L.) Granulated zinc §v ; diluted sulphuric acid 1 quart; dissolve, filter, evaporate to a pellicle, and set it aside to crys- tallize. II. The common sulphate of zinc of commerce frequently contains copper, cadmium, lead, iron, and manganese. By digesting its concentrated solution for some time with metallic zinc, it may be freed from copper, lead, and cadmium, for these metals are all reduced and precipitated in a metallic state ; or the acid solution may be treated with sulphureted hydrogen as long as any pre- cipitate forms. In order to separate the iron, chlorine gas is passed into the solution, by which the iron is converted into the protochloride ; if this solution be exposed to the air for a length of time, it absorbs oxygen, and oxide of iron (basic salt?) is deposited as a yellow powder, from which the solution must be filtered. If the sulphate contain manganese, which is not very often the case, the solution must be boiled up a few times with purified charcoal, filtered and evaporated. (Jour, fur prakt. Chem) Remarks. Puro sulphate of zinc must alone be used in medicine. The commercial sulphate (white copperas, white vitriol, salt of vitriol, vitriolum album, sal vitrioli, zincum vitriolatum, <$-c.) is prepared by roasting native sulphuret of Z1R 576 ZUM inc (blende) in a reverberatory furnace, lixiviating he calcined mass, and evaporating till the liquid "orms a white semicrystalline mass on cooling. The pure sulphate is " totally dissolved by water, and the white precipitate formed by ammonia is redissolved when the ammonia is added in ex- cess." (P. L.) "When a solution in 6 waters is > boiled with a little nitric acid, and a solution of ammonia is then added till the oxide of zinc at first precipitated is all redissolved, no yellow pre- cipitate remains, or a trace only*, and the solution is colorless." (P. E.) Dose. As an antispasmodic, tonic, or expectorant, 1 to 5 grs.; as an emetic,- 10 to 20 grs. ZINKING. Copper and brass vessels may be covered with a firmly adherent layer of pure zinc, by boiling them in contact with a solution of chloride of zinc ; pure zinc turnings being at the same time present in considerable excess. The same object may be obtained by means of zinc, and a solution of sal ammoniac, or caustic potassa. (Boettger's Beitrage.) ZIRCONIA. Syn. Oxide of Zirconium. A white pulverulent earth discovered in the jargon, or zircon, of Ceylon, by Klaproth, in 1789, and it has since been found in the jacinth. To obtain it the stone should be calcined and thrown into cold water, to render it friable, and then powdered in an agate mortar. Mix the powder with nine parts of pure potash, and pro- ject the mixture by spoonfuls into a red-hot cruci- ble, taking care that each portion is fused before another is added. Keep the whole in fusion, with an increased heat, for an hour and a half. When cold, break the crucible, separate its contents, powder, and boil in water, to dissolve the alkali. Wash the insoluble part; dissolve in muriatic acid; heat the solution, that the silex may fall down; and precipitate the zirconia by caustic fixed alkali. Or the zirconia may be precipitated by carbonate of soda, and the carbonic acid ex- pelled by heat. Zirconia has neither taste nor odor, is insoluble in water, and forms salts with the acids. It is distinguished from all the other earths, except thorina, by being precipitated when any of its neutral salts are boiled with a saturated solution of sulphate of potassa. It is distinguished from alumina and glucina by its salts being pre- cipitated by all the pure alkalis, and by being in- soluble when they are added in excess. The pre- cipitated hydrate and carbonate are readily solu- ble in acids. ZIRCONIUM. The metallic base of zirconia. It is obtained by heating in a glass tube with a spirit lamp, a mixture of potassium, and the double fluoride of zirconium and potassium, care- fully dried. The product must be washed with water, and digested for some time in dilute mu- riatic acid. (Berzelius.) The resulting black powder is zirconium. It has been but very im- perfectly examined. ZOONIC ACID. A name given by Berthol- let to the acid liquid procured by distillation from animal substances. It has been shown by Thenard to be merely acetic acid. ZOOTIC ACID. (See Prussic Acid.) ZUMIC ACID. (From fr/*-?, leaven.) The acid formed in bread, and in some other vegeta- ble substances, which have undergone the acetous fermentation. 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