**; «.- -J*ff '■srl'^v*^?. ■ _, »ay".:-' ^lr^?^V^ V:. *?;;;■:_'.-;?:'■ ■K?%f;,::-,., /Stfi- CALORIC. IN TWO VOLUMES. VOL. I. " To every form of being ia assigned An active principle: howe'er removed From sense and observation, it subsists In all things, in all natures, in the stars Of azure heaven, the unenduring clouds, In flower and tree, in every pebbly stone That paves the brooks, the stationary rocks, The moving waters, and the invisible air. * * * * from link to link It circulates, the soul of all the worlds." Wordsworth. s»is Hun 3C CALORIC: MECHANICAL, CHEMICAL AND VITAL AGENCIES PHENOMENA OF NATURE. SAMUEL L. METCALFE, M.D., LATE OP TRANSYLVANIA UNIVERSITY. VOL. I. "e[7T"">:--. C^£-< PHll?A DELPHI A: J. B. LIPPINCOTT & CCt 1859. Q Mire? a v.l' Entered, according to Act of Congress, in the year 1859, J. B. LIPPINCOTT & CO., by In the Clerk's Office of the District Court of the United States for the Eastern District of Pennsylvania * PREFACE TO THE FIRST EDITION. In the primitive ages of the world, when men gazed on the wonders of nature with the freshness of childhood, and before the vivid information of the senses had become obscured by fabulous traditions, all their physical and metaphysical theo- ries were founded on the belief that solar fire is the efficient cause of motion and life throughout creation. This belief, so manifestly the result of observation and experience, was con- stantly forced upon their minds with all the evidence of a liv- ing reality; and" prevailed for thousands of years in every quarter of the habitable globe. Nor is there anything so strikingly obvious to the unsophisticated common sense of mankind as the omnipresent influence of the sun, which is perpetually exerting a tranquil, yet omnipotent energy, throughout the air, the ocean and the solid ground. He re- gulates all the phenomena of climate and season, evaporation and rain, the circulation of the atmosphere, the flowing of waters, the transformations of chemistry, the operations of vitality, and the revolutions of the heavenly bodies. But as the ancients never explained the laws by which ele- mentary caloric operates in the generation of force and mo- tion, nor the manner in which it is related to electricity and vi PREFACE TO THE FIRST EDITION. light, thei* speculations have exerted little influence on the physical theories of modern philosophers, who have, strangely enough, disregarded nearly all that was most valuable in the science of antiquity. At the present time, it remains unde- cided, whether caloric is an exceedingly subtile and active essence, as maintained by the early Hindoos, Egyptians, Phoe- nicians, Chaldeans, Persians and Arabians, as well as the more enlightened Greeks and Romans; or whether it consists in mere motion and vibration among the particles of ponderable matter, as supposed by Bacon, Boyle, Hooke, Rumford, Davy, Young and others. One of the most important modern discoveries was that of latent or combined heat, by Dr. Black. When he proved by accurate experiments, that definite measures of caloric are required to convert solids into liquids, and that the same sub- tile fluid is obtained from the atmosphere by respiration, he laid, the foundation of its true theory. But as he did not ex- tend his researches to its agency in the mechanical, chemical and vital phenomena of nature, his labours have not been fol- lowed by results corresponding with the magnitude of his dis- covery,—if we except the improvement of the steam engine by Watt. Nor has any one, either among the ancients or moderns, ever attempted to give a regular and systematic history of the mode in which caloric operates in all the molecular and aggre- gate forces of matter. Mr. Whewell observes, in his late His- tory of the Inductive Sciences, that "we have no hypothesis regarding thermotics, which, being assumed in order to explain one class of phenomena, has been found to account exactly for another." Yet he adds: "it is one of the cardinal points on PREFACE TO THE FIRST EDITION. vii which the doors of physical knowledge must turn,%hich have hitherto remained closed." Within the last hundred years, electricity has been regarded by many persons as a key by which to unlock all the secret cabinets of nature. We have had electrical theories of che- mistry, of life and of the universe. Yet no one has explained what electricity is—whether a separate and distinct agent, a modification of some other exceedingly refined and more com- prehensive principle, or a mere effect, condition or property of ponderable matter. The celebrated Faraday at one time adopted the simple and rational theory of Franklin, that it is a material fluid, definite measures of which belong to each ele- ment of ponderable matter. And yet he speaks of it very often as if he considered it to be a compound fluid. But when treating of its chemical agency, he represents it as "a modification of the exertion of chemical forces." Again, when by following up the discoveries of Oersted, Davy, Arago and Schweigger, who found that electricity is capable of producing all the phenomena of magnetic action on a small scale, he succeeded in obtaining an electric spark from a permanent magnet, he arrived at the conclusion that elec- tricity and magnetism are identical; except that in the latter "the axis of power" is greater than in the former. Yet, as if not satisfied with any of the foregoing hypotheses, he sug- gests, at another time, that electricity may be resolved into undulations of an ether; and, at another time, that all the more important electrical phenomena may be resolved into polarization of the particles of ponderable matter, or what has been called atomic polarity. But he does not explain what he means by the axis of power and electric polarity; nor how viii PREFACE TO THE FIRST EDITION. chemical affinity and magnetism, which are merely effects or modes of action, can be identical with their cause; nor does he inform us what the ether is, and what causes it to vibrate. Such have been the difficulties of this important department of physical science, that its most distinguished votaries have hitherto failed to present us with a consistent theory of elec- trical phenomena. But I hope to make it appear that most of these perplexities have arisen more from defective methods of inquiry, than from any inherent obscurity of the subject. Such is the reverence of mankind for mysteries, that the majority are always ready to believe what they do not under- stand; while the most obscure and visionary fancies are often regarded as profound. It was long ago remarked*by Longi- nus, that darkness is a source of the sublime; and it must be admitted that objects are magnified by looming through a fog. In all ages of the civilized world, light has been recognized as a powerful agent in the work of the universe. As the great Painter of Nature, it gives to the dome of heaven its azure hue; to the rainbow its gorgeous red, brilliant yellow, refreshing green and lovely blue, shading into the softer violet. It is solar light which touches the morning and evening clouds with its celestial pencil, when they glow with vivid tints of ruby, sapphire and gold. It adorns the flowery fields with an end- less variety of enchanting colours; while it is perpetually modifying the taste, odour and other sensible properties of different bodies. But it is still an unresolved problem, whether light be a ma- terial substance, as maintained by Pythagoras, Democritus Leucippus, Empedocles, Plato, Epicurus, Newton and Brew- ster; or whether it consists in the mere vibrations of some PREFACE TO THE FIRST EDITION. IX unknown ether, as supposed by Descartes, Huyghens, Hooke, Euler, Young, Sir John Herschel, Arago and others. Nor is it yet finally settled whether white light is composed of seven primitive rays, as supposed by Newton, or of only three fundamental colours, red, yellow and blue, as maintained, with many cogent reasons deduced from experiment, by Sir David Brewster. On the same subject, the advocates of the undulatory or wave theory are equally at variance among themselves; for while Huyghens maintained that solar light is composed of only two elementary colours, yellow and blue, Hooke reduced all its modifications to red and violet; whereas Young reduced the whole to red, green and violet. What is still more remarkable, neither of the two great rival parties has ever yet attempted to ascertain the relations of light to caloric and electricity; nor in what way they per- form so many wonderful effects in the moving drama of the universe. But if they be connected in the operations of na- ture, they must be united in theory. And it will be a leading object of the following work to prove, by a careful generaliza- tion of facts, that caloric and electricity are mutually convert- ible into each other; consequently, that they are modifications of one and the same essence, which is the active principle in light, and in all the phenomena of nature. Since the time of Sir Isaac Newton, it has been generally supposed that all the molecular changes of matter may be re- ferred to attractive and repulsive forces. Yet the cause of attraction and repulsion has not been identified with any known principle capable of demonstration. The orbits of planets, and the times of their revolutions, have been mea- sured with mathematical precision; but the cause of their X PREFACE TO THE FIRST EDITION. eternal motion has never been clearly distinguished from pro- jectile and gravitating forces. The relative magnitudes of the particles or atoms of ponderable matter have been, to a cer- tain extent, ascertained by the refined analyses of modern chemistry; yet the cause of chemical affinity is still confounded with inherent properties, occult qualities and undefined powers. The composition of plants and animals has been discovered, and their intimate structure explored; yet the organizing prin- ciple remains a profound mystery. What was said by Des- cartes two hundred years ago, is equally true at the present day: "In philosophia nihil adhuc reperiri, de quo non in utramque partem disputatur." And Mr. Whewell observes in a very recent work, that "the past history of man, of his arts, of languages, of the earth, of the solar system, offers a vast series of problems, of which perhaps not one has been rigorously solved." It has been a complaint of long standing in the world, that nature has spread a veil over the first principles of things, which man can never hope to remove. But there is reason to believe that all the great truths of science which are of the highest importance for us to know, are no less remarkable for simplicity, than for the wide extent of their application; and that when fully unfolded, they will be self-evident propositions. It is true enough, that the most familiar phenomena of nature, when viewed separately, or through the mystical interpretation of visionary theorists, are as "inscrutable as the scattered leaves of the Sibyl;" but when traced to their origin, the hidden meaning of everything is gradually disclosed, and order springs from chaos. It was profoundly observed by Sir Edward Bulwer, that " the key to all mystery is the desire PREFACE TO THE FIRST EDITION. xi to know,"—and that "there is only a single step from a truism to a great discovery." If we are destined ever to arrive at a perfect theory of nature, it must be founded on a true history of the Grand Original, and a complete knowledge of the Prime Mover. Nor is it possible that men should avail themselves fully of the powers which are in nature, without knowing the cause of these powers. It was from the elastic force of the latent caloric that belongs to nitre, sulphur and charcoal, that man, uncon- sciously, obtained the power of gunpowder; the invention of which has essentially modified the condition of the human race; for it thenceforward secured the uninterrupted progress of civilization, which can never again be arrested by the in- cursions of barbarous hordes, nor the light of knowledge be extinguished in embryo, as during the early periods of his- tory. It was by discovering that a piece of metal called the loadstone, when horizontally balanced on a pivot, is constantly directed to certain points in the polar regions, that commerce and civilization have been extended to the remotest parts of the earth. But men have yet to learn that the same principle which directs the compass-needle to the poles, guides the planets in their orbits, and fills them with life. It was by seizing the grand lever of nature as a moving agent, that man was enabled to create the steam engine, which has brought about a more important revolution in the condi- tion of nations, than all the united discoveries of antiquity for thousands of years. Nor can there be a reasonable doubt that a complete knowledge of the same agent, as it operates in all the phenomena of nature, would augment the resources of hap- piness an hundredfold, dispel the clouds of error which have so Xll PREFACE TO THE FIRST EDITION. long hovered over the sciences, and enlarge the empire of man over the material world in an endless variety of ways. It is animating to think how soon this grand result might be brought about, if all the talents now wasted on fruitless speculations were rightly employed in the study of nature. It may be right to inform the reader that a brief outline of the leading views contained in the following chapters was first promulgated by the author in an essay entitled "A New Theory of Terrestrial Magnetism," published at New York in 1833; and somewhat extended in a series of papers in the Knickerbocker Magazine of 1834-5. The author also feels it due to himself, and to those friends who have been long ex- pecting this work, to state, that the first three books were originally intended to be published separately, and were actu- ally printed in 1837, the Preliminary Chapter excepted. But as more enlarged views of the subject opened to him, he clearly perceived that a development of the physiological and pathological laws of caloric was essential to the completion of his undertaking; which at that time he supposed would not require more than twelve months:— "But more advanced, beheld, with strange surprise, New distant scenes of endless science rise." The performance of this task required a vastly greater amount of laborious research than he was prepared to expect, until he had proceeded too far to desist. In the mean time he had the satisfaction of perceiving that, with every addi- tional knowledge of facts, he was conducted to a more elevated point of view, and to more comprehensive generalizations; the consequence of which has been, that in the Preliminary Chap- PREFACE TO THE FIRST EDITION. xiii ter, he has entered more fully into the rationale of geological and astronomical phenomena, than he had ventured to do in the Second and Third Books. In addition to the many difficulties encountered at every step, much precious time was lost owing to ill health, by which the work has been still further and most painfully delayed, to the disappointment of the publisher, whose liberality and for- bearance merit the grateful acknowledgments of the author. DR. METCALFE'S LIFE. Samuel L. Metcalfe was born near Winchester, Virginia, on the 21st of September, 1798. His mother's maiden name was Sittler. When he was quite young, his parents removed to a farm in Simp- sonville, Shelby County, Kentucky. There, amid the wild beauties of nature, he grew up healthy in body and mind. At a very early age he was fond of reading, and made rapid advances in every branch of study. He also, as quite a young boy, exhibited a great taste for mechanics, and in his leisure hours amused himself by constructing boats and toys for the children. It was the intention of his father that he should become a farmer; but the son had higher aspirations. The boy with rosy cheeks and athletic limbs had grown into a thought- ful youth, who had gazed on, and examined with awe, the wonders of nature, and longed for that knowledge that would explain to him the mysteries that surrounded him. Yet how was he to obtain the means necessary for study ? At the age of sixteen he was skilled in sacred music, and while pur- suing his studies in Shelbyville, gave lessons once a week in singing. About this time he wrote a volume of sacred music. The thought occurred to him, that he would publish this work in some large city, and that the profits of its sale should be appropriated to defray the expenses of a collegiate education. He sought his father, and told him of his plans. The father listened to the enthusiastic youth, but shook his head, saying :—" I cannot con- XVI dr. metcalfe's life. sent to so wild a scheme." A few days after, his father called him. "I have been thinking," said he, "of your request. I see your heart is set upon this journey. Go, my boy, and may God prosper you." He started for Cincinnati, and there met with a publisher who sympathized with the young man, and undertook to bring out the work at his own risk; and afterwards gave him a sufficient sum to enter College. In 1819 he matriculated in the Transylvania University, Lexington, Kentucky; and in 1823 received his diploma as Doctor of Medicine. In the same year he commenced practice in New Albany, Indiana. He afterwards removed to Mississippi, where he married, but became a widower about four years thereafter. For some time his mind had been pondering on the great subject which in after years so completely engrossed his attention, and in 1831 he visited England, in order to procure certain rare and valuable books, which he wished to consult in the prosecution of his experiments. Un- fortunately, this valuable library was destroyed by fire during his second visit to England. After his return home, he made a geological tour through East Tennessee, North Carolina and Virginia. In 1833 he brought out his work on " Terrestrial Magnetism," which was published in New York, and dedicated to Joseph Delafield, Esq. Before this time, he had written and published a brief work on the Indian wars of the West. He remained in New York until 1835, occasionally writing articles for the Knickerbocker, under the signature of M. But the small volume he had written on "Terrestrial Magnetism" only spurred him on to do more. His mind had caught fire on the subject of Caloric, and he burned with desire again to visit the great British metropolis, there to consult the vast libraries, and work out his theory. In 1835 he again crossed the Atlantic, and took up his abode in Lon- don. Those who knew him there will remember how he worked on courageously, unremittingly, for days, months, years, in succession. His health was delicate, his means were small, but he felt that his election was sure. In a letter dated 1838, he says :— "Were it not that the prize of my high calling is sure, I should have dr. metcalfe's life. xvii sunk beneath the protracted labor of thought which my work demanded. 'Sorrow may endure for a night, but joy cometh in the morning.' " Again:— "Be not surprised nor discouraged should you find my work attacked or abused. It is impossible it should escape censure, subversive as it is of a thousand errors that are interwoven with the interests and reputa- tion of men. But 'truth is mighty, and will prevail.'" In 1841 he writes to his brother:— "You must not be surprised at the time which I have employed on the present work. Having long since passed the Rubicon, it would be mad- ness now for me to think of anything less than an absolute conquest of the centre and capitol of the sciences. But it is only a small band of intellectual heroes, whose minds have been kindled with fire from the altar of genius, that are capable of understanding the real merit of such a conquest!" In this trying period of his labours, he was sustained by the sympathy of a few kind friends in London. Their letters to him (which on his death were found among his papers) prove how much he was beloved. In 1843, Dr. Metcalfe's work on " Caloric" was completed and pub- lished by Pickering, London. The following extract is from a letter written from London by the Doctor to his brother in Kentucky:— " I have fought the good fight, I have finished my course, and per- formed the work which Providence appointed for me to do. Whatever its fate may be, I have already secured a place among the benefactors of the human race—a reputation that will go on increasing long after I shall have ceased to live. " Had I remained at home, I should now, in all probability, be rich, and in an influential position. But in exchange for those honours, I have the gratification to know, that I have added to the stock of know- ledge ; and that I shall leave behind me an undying name!" On the 25th of April, 1845, he sailed from London in the ship Brontes, and arrived in New York on the tenth of June. His health was much * xviii DR. METCALFE'S LIFE. benefited by the sea voyage. And now all that he had anticipated was realized; he was at home once more; his book was finished; friendly congratulations greeted him on every side. In 1846, Dr. Metcalfe was married to an English lady, with whom he became acquainted in London. In the same year he made arrangements with a firm in Philadelphia to re-publish his book; notes which he made on the margin of the London copy are incorporated with the text in the present edition; and now the publishers were ready, and the scientific world expecting it. But that earnest desire to perfect his work, peculiar to creative genius, detained him from year to year. In the mean time his health became delicate, and in the spring of 1856 he took cold, and his lungs became affected. As the summer advanced he appeared to revive, and expressed a wish to go to the sea-side, and in July was taken to Cape May. It was his last journey upon earth. In two weeks from that time he was buried in the country church-yard on Cape Island. He left a widow and one child, a daughter between eight and nine years of age. E. M. NOTICES OF THE FIRST EDITION. The following extracts are taken from some of the reviews on the work alluded to in the preceding sketch of Dr. Metcalfe's life:— From the London Medical Gazette, May, 1844, pp. 229 and 408. " It bears the unquestionable stamp of genius, and carries with it, at the same time, evidence of learning various and extensive, and of such laborious research, as can only be successfully achieved by minds of the noblest order in pursuit of sacred truth." " It is a work, the like of which only comes from the press at rare and distant intervals—a work, indeed, of sublime scope, and, rightly taken, of the noblest tendency." "It is the spontaneous effusion of a gifted mind, brimful of know- ledge, and tinctured itself with the hallowed fire of poetry." From the New York Journal of Medicine, September, 1845, p. 208. "The author appears to us to possess a fine philosophical genius. His doctrines and views are so bold and original, so comprehensive in their. scope, so clearly set forth, and so supported by facts and reasoning, that they cannot fail to command the attention of the reader." From the New York Journal of Medicine, July, 1846, p. 75. " The work resembles the beautiful system of nature which it is desig- nated to illustrate. The longer we examine it, the more beauties do we find in it. The author, we believe, is fairly entitled to the credit of being the first philosopher who has discovered a key whereby to unlock all her secret cabinets of wisdom and wealth." XX NOTICES OF THE FIRST EDITION. From the Western Journal of Medicine and Surgery, July, 1846, p. 49. " If the Doctor succeed in establishing the correctness of hkOheory, (and we do not oracularly assert that he will not,) he will be one of the most illustrious benefactors of physical science—if not himself the most illustrious—that time has produced. His success, should he achieve it, will be the solution of the gordian knot, to effect which many of the master-geniuses of every enlightened era and country have laboured in vain. And whether he succeed completely or not, he will, by virtue of what he has already done, occupy a place among the most eminent writers of the age." From the same, October 3, p. 19. "When estimated as an aggregate, by the value in detail of its inherent qualities, and by the peculiar nature of certain incidental circumstances which unite with those qualities in giving character to it, this cannot fail to be regarded, by competent judges, as one of the most extraordinary productions of the kind that has issued from the British press during the nineteenth century. Had we said, that has issued from any press during any century, whose history makes a part of recorded knowledge, it would not be easy to fasten on us the charge of either error or extravagance. We, at least, are compelled to think so, after a very careful examination of the subject. As an inquiry, we remember no instance in which the work before us has been surpassed on sundry points in depth and so- lidity; and we challenge refutation, when we add, that, in the compass and grandeur of its outline, it cannot be surpassed." From the North American Review, July, 1857, p. 40. "We have prefixed to this paper the titles of two essays, published within the last few years, and also of a ponderous volume which saw the light before either of them, and has been, or seems to have been, less read than either. Mr. Grove's essay has excited great attention in England, and received the honours of translation into the French lan- guage. Dr. Carpenter's paper, published in the Philosophical Trans- actions, extended the generalization of Mr. Grove into the domain of physiology. Both are brief, and are therefore read. NOTICES OF THE FIRST EDITION. XXI "Dr. Metcalfe forgot the motto which he must have often seen quoted from D'Alembert: 'The author kills himself in spinning out what the reader kills himself in cutting short.' Consequently, his book has been shelved, in spite of its originality and learning. " But we must do our countryman the justice to say, that, if there is anything in the physical theory of vital actions which has found advo- cates in Mr. Newport and Dr. Carpenter, and which Professor Draper has so forcibly illustrated, Dr. Metcalfe has anticipated them all, in maintaining that caloric 'is alone, of every form of being, quick or dead, the active principle,' the same doctrine, modernized, which, in another form, was taught by Hippocrates. And we must be permitted to ex- press our astonishment, that a work of such pretensions, published in London, should be ignored by any English writer of authority, while he is repeating and developing its leading ideas, long since given to the world." ^ PUBLISHERS' NOTICE. The present edition contains the emendations of the author up to the period of his death. It has, during its passage through the press, been submitted to the supervision of a competent editor, who has revised the text so far as it could be done without essen- tially changing the sense or language of the author. An appendix, also, has been added, containing some recent facts bearing upon the subject-matter of the work, but which could not have been introduced into the text without taking what might be considered an unwarrantable liberty. t CONTENTS OF YOL. I. BOOK I. PRELIMINARY CHAPTER. PAGES A Srxopsis of the Work......................................................... 17-61 CHAPTER II. On the Atomic Constitution of Matter, and the relative Quantities of Caloric in different Bodies............................................... 62-116 CHAPTER III. On the Forces of Caloric in Elastic Fluids.—Theory of their Expan- sion and Contraction.—Constitution of Liquids....................... 117-154 BOOK II. CHAPTER I. Theory of Cohesion, Conduction and Radiation........................... 155-184 CHAPTER II. Chemical Attraction in general................................................ CHAPTER III. Theory of Solution, and of Freezing Mixtures........................... 209-234 CHAPTER IV. Theory of Capillary Attraction, and the connection of Molecular with Aggregate Forces of Matter.......................................... 235-259 XXIV CONTENTS OF VOL. I. BOOK III. CHAPTER I. PAGES Electricity—Atmospheric, identical with the Caloric which causes Evaporation..................................................................... 260-298 CHAPTER II. Theory of Winds, and their connection with Electrical Phenomena. —Rationale of Tornados, Hail-storms, &c.............................. 299-322 CHAPTER III. The Barometer.—Theory of Dew, Mists, Fogs, and of the Aurora Borealis........................................................................... 323-343 CHAPTER IV. Theory of Voltaic Electricity, and of Subterranean or Volcanic Forces............................................................................ 344-385 CHAPTER V. Hypothesis of two Electric Fluids examined.—Relations of Caloric and Electricity....... ......................................................... 386-414 BOOK IY. CHAPTER I. Life—History of Ancient and Modern Opinions concerning it....... 415-461 CHAPTER II. Ultimate Elements of Organized Bodies.—Why they unite into Ter- nary and Quaternary Compounds, so as to form Living Tissues.__ Spontaneous Generation.—Theory of Animal Heat, as connected with Respiration............................................................ 462-507 CHAPTER III. Influence of Respiration on the Temperature and Vital Energy of different Animals.—Cause of the Heart's Action, and of the Ca- pillary Circulation,......................................................... 508-599 CHAPTER IV. Theory of Digestion, Sanguification, Coagulation, Secretion, Nutri- tion, Muscular Motion, Sensation, and of Disease.__Analogies of the Macrocosm and Microcosm................................... 5°0-6SO CALORIC. BOOK I. PRELIMINARY CHAPTER, " Oh that those who have both time and intellect at command adequate to the investigation, might, in perfect tranquillity, search into nature, until they ascertain what quantities of heat are required to produce every action of matter; that mankind might then not only become masters of every kind of knowledge, but of every kind of power."—Telesius. That the reader may perceive at once the general scope and object of the present work, I shall com- mence with a brief outline of the leading facts, which connect the various operations of nature with the fun- damental laws of caloric. But as men of science are still undecided whether caloric be a material agent, or the mere effect of motion among the particles of pon- derable matter, it becomes necessary to examine the evidence on which these opposite views have been founded. Among the most enlightened nations of antiquity, elementary Fire was regarded not only as a most re- 2 18 VIEWS OF THE ANCIENTS. fined and spiritual essence of all the elements, but as an universal and self-active principle, which they con- sidered as identical with existence or being. It has been amply proved by Bryant, Calmet, and other learned etymologists, that the Greek ezc, and the Latin esse, to be, like our words essence and essential, were derived from the Hebrew u'N Esh or Es, the fire; and that Vesta, the goddess of that element, had her name from the Chaldee Knj^K EsJtta or Esta. They have also shown that the word DN Am denoted both heat and existence, among the early Egyptians; who, believing it to be the cause of motion and organi- zation throughout nature, inscribed it on the great door of one of their temples. We are further informed by the learned and philo- sophical Parkhurst, that the sacred mystical letters lq Ie, which were inscribed over the door of the temple at Delphi, dedicated to Apollo, (who was a mythologi- cal personation of the sun or solar fire,) were taken from the Hebrew IT Yeh or Yah, signifying existence or being, Nor is it unworthy of notice, that the Greek zoo fire, was derived from the Hebrew niS pur, to break, dissolve, and separate; actions which clearly imply mechanical and material agency. So much for the primitive meaning of words employed by the an- cients to represent the essential nature of what is called heat, but which I shall generally denominate caloric, for the purpose of distinguishing the cause from the mere sensation of heat. Let us now ex- amine the views which have been entertained by the moderns on this important subject. In the Novum Orgamnn, and in his Treatise en- OPINIONS OF BACON AND DAVY. 19 titled De Forma Calidi, it was maintained by Lord Bacon, (whose opinion has been adopted by many philosophers since his day,) that the very essence of heat is motion, and nothing else. In accordance with this doctrine, Sir H. Davy observes, in his Chemical Philosophy, that "the cause of heat is motion, and the laws of its communication are precisely the same as the laws of the communication of motion." But in the Treatise on Life and Death, as also in his Natural History, Bacon maintains that " there is, in every tangible body, a spirit or body pneumatical, which fills the pores of all gross bodies:—that it is not some virtue, or action, or trifle, but a real and quantitative substance, though rare, invisible, and without weight." Moreover, that this spirit or body pneumatical was only another name for what Hippocrates and other Greek authors called depfxov heat, is equally manifest from the fact, that Bacon represents it as the cause of evaporation, and of many other effects which are pre- dicable of caloric alone. And Sir Humphrey Davy observes, in his Agricidtural Chemistry, that "what- ever theory we adopt, it is certain that there is matter moving in the space between us and tlie heavenly bodies, capable of communicating heat." It is therefore evi- dent, that neither of these distinguished men can be fairly ranked as advocates of the immaterial theory; and that, in reality, they had no fixed or settled opinions on the subject. The authority of Sir Isaac Newton has been often cited in support of the doctrine that caloric is not a material substance. But it is worthy of special notice, that in the latest works of that great man on physical 20 HYPOTHESIS OF NEWTON. science, he maintains the existence of what he calls "an exceedingly subtile and elastic ethereal substance, which is diffused through all places, fills the pores of gross bodies, and forms a large constituent of their bulk or volume." In a letter addressed to the cele- brated Boyle, in 1678, the object of which was to ex- plain his views of the ether, he represents it as "the cause of cohesion, capillary attraction, and of tjie force by which menstruums pervade and dissolve solid bodies." He adds in another sentence, "I conceive the atmosphere to be composed of the particles of all sorts of bodies of which the earth consists, separated and kept at a distance from one another by the same active principle* But if the ether be the cause of solution, and of the elastic force of the atmosphere, * The above views were still further expanded in a scholium at the close of the second edition of the Principia, published in Vl13; and in the form of queries, they were reiterated at the close of the Optics, published in 17H. In both of these great works, he repre- sents the ether as the cause of gravity, cohesion, capillary attrac- tion, solution, elasticity, the emission, reflection, refraction, and inflection of light. He also maintained that the ether is the cause of animal motion. Yet he observes, that he knows not what the ether is; and that "we have not that sufficiency of experiments which are requisite to an accurate determination of the laws by which this subtile spirit operates." But if Newton had traced the word ether to its primitive roots, the discovery of its real meaning might have modified all his physical investigations, and have given a totally new aspect to the whole circle of the Sciences. The truth is, that a complete Etymological Dictionary would sweep away innumerable misconceptions, errors, and metaphysical subtleties which have gradually arisen from the revolutions in language, and the adoption of words the primitive meaning of which has not been understood. CALORIC A MATERIAL AGENT. 21 it is manifestly identical with caloric. It is true that in the fifth query, toward the close of the Optics, Newton represents heat as consisting in a vibratory motion among the particles of bodies,—and that the whole theory of the Principia was founded on the hypothesis that space is a vacuum; which is certainly at variance with the foregoing views of the ether. It is also inconsistent with his doctrine of light, which he regarded as a material substance, perpetually flow- ing from the sun and fixed stars through space. But that caloric does not consist in mere motion or vibra- tion among the particles of ponderable matter, would appear from the following considerations:— 1. That it may be added to and subtracted from other bodies, and measured with mathematical pre- cision, as all good thermometers demonstrate:— 2. That it augments the volume of bodies, which are again reduced in size by its abstraction:— 3. That it passes by radiation through the most perfect vacuum that can be formed by means of the air-pump, in which it produces the same effects on the thermometer as in the atmosphere :— 4. That it exerts mechanical and chemical forces which nothing can restrain, as in volcanos, the ex- plosion of gunpowder and other fulminating com- pounds :— 5. That it operates in a sensible manner on the nervous system, producing intense pain, and disor- ganization of the tissues when in excess:—* * The same reasoning on which is founded all belief in the ma- terial existence of the outward universe applies equally to caloric. 99 CALORIC A MATERIAL AGENT. 6. That it modifies the forms, properties, and con- ditions of all other bodies, in an endless variety of ways.* No metaphysical sophistry can refute the belief of mankind, that whatever operates in a sensible manner upon material organs, must be a real substance; for the obvious reason, that "there can be no virtue without substance," as maintained by Newton. I cannot, however, agree with Epicurus, that nothing exists but what is visible or tangible, since the ultimate atoms of the grossest matter, in their separate state, can neither be seen nor touched, owing to their extreme minuteness, and yet have a real existence. It is ob- served by an able writer in the Church of England Review, that our words thing, and think, were derived from the Greek verb diyy-ev, to touch; that,is, a thing is what we first touch, and then think upon. Yet we may think upon the ultimate atoms of matter, which cannot be recognized by any of the senses until united into aggregates. He adds, that all impressions on the senses are re- solvable into touch. But there is nothing in nature which operates so powerfully on the sense of touch as caloric. "When Bishop Berkely said there was no matter, And proved it—'twas no matter what he said." And when men say that caloric is not a substance, they reject the evidence of their senses, subvert the foundation of all knowledge, and pave the way to universal skepticism. Yet I cannot wholly agree with Aristotle when he says, that those who deny the reality of an external world, deserve to be chastised rather than confuted. * It was first ascertained by Dr. Black, that on mixing a pound of water at 112° F. with a pound of ice or snow at 32°, the latter was melted, when the temperature of the mixture stood at 32° • showing that 140° of caloric had been transferred to the ice, and intimately combined with its particles. Since then it has been found, as predicted by Black, that definite measures of caloric are required to convert all other solids into the liquid and gaseous states:—that when a pound of steam at 212°, is mixed with 7 pounds of ice at 32°, the latter is converted into water of the same OBJECTIONS ANSWERED. 23 But if caloric were a mere property or quality, how could it be taken from one body and added to an- other? Or if it augment the volume of other bodies, must it not itself have volume, occupy space, and therefore be a material agent?"' Would it not be mere jargon to speak of the radiation, reflection, con- vection, and conduction of a mere quality, or imma- terial property? And if caloric were only the effect of vibratory motion among the particles of ponderable matter, how could it radiate from hot bodies without the simultaneous transition of the vibrating particles? But it is certain that when iron, copper, and other metals are heated to any temperature below the point of ignition, like boiling water they give off caloric freely, without any sensible loss of ponderable matter. It has been said, that "the material theory con- tains an inherent vice, by assuming the existence of a body, which has never been obtained in the sepa- temperature; showing that 7 X 140, or 980°, are thus transferred from the steam to the ice, and employed in melting it, without pro- ducing in it any elevation of temperature. This is what Black called the latent heat of water and steam. It has also been dis- covered, that a cubic inch of water at 212°, is expanded to the dimensions of a cubic foot, or about 1720-fold on passing into the gaseous state,—proving that 1719 parts by volume of steam at the same temperature, are occupied by the caloric which surrounds its particles. The same fact is still more remarkably illustrated in hydrogen gas, the volume of which is nine times greater than that of the same weight of steam, cseteris paribus: so that above 15,000 parts of the space occupied by hydrogen must be filled by that subtile form of matter called heat. * We are not however to suppose, that "extension is the only essential property of matter," as maintained by Descartes. 24 OBJECTIONS ANSWERED. rate form." But if caloric do not exist in a separate state while passing through a vacuum, all our reason- ings about it are fallacious and unintelligible. Nor is it possible to explain, in a simple and satisfactory manner, any single one of the phenomena ascribed to it by all parties, in accordance with the hypothesis that it is identical with motion, which is manifestly not an agent, but merely some body in the act of moving, and always implies the existence of a mover. The most effectual method of giving a death-blow to the vibratory theory of heat, would be to show how soon it breaks down when applied to the explanation of facts. If this theory were true, caloric ought to be gene- rated by all impulses which throw the particles of bodies into a state of violent agitation. But such is not the fact; for if the atmosphere, the ocean, and the solid strata of the earth, were kept in a state of perpetual tremor, their temperature would not be materially altered. The advocates of the immaterial theory have never explained what causes bodies to vibrate; nor what keeps the particles of solids, liquids, and gases, at a distance from each other while qui- escent, or free from vibratory motion* And it is * It was supposed by Bacon, that the essential nature of heat is motion, and nothing else, because it accompanies the motion of friction, percussion, combustion, ebullition, violent exercise &c. Count Rumford was led to adopt the same opinion from the fol- lowing experiments: Into a cannon weighing 113 lbs. and cast solid, he caused a hole to be bored 3 7 inches in diameter and 7-2 inches in depth. Into this hole he introduced a blunt steel borer that was made to rub against the bottom by horse power, with a OBJECTIONS ANSWERED. 25 worthy of special notice, that caloric is disengaged by pressure, friction, or percussion, only so long as bodies undergo condensation. For, it has been proved by the experiments of Berthollet, Biot, and Pictet, that when pieces of gold, silver, and copper, of the same size and shape, are suddenly and forcibly struck, as when stamped in the process of coining, they were con- densed, and caloric evolved, but more by the first than second blow; whereas after the third blow, when they had arrived at the limit of condensation, there was no perceptible increase of temperature. In the experiments of Berthollet on copper, the first stroke raised the temperature 17*3° F., the second 7*5°, and force equal to about 10,000 lbs. avoird., the cylinder being turned at the rate of thirty-two times per minute. At the expiration of thirty minutes, when the cylinder had made 960 revolutions about its axis, its temperature was found to have risen from 60° to 130° F. In another experiment, the cylinder was wrapped round with flannel to prevent the loss of heat, and inclosed in a wooden box contain- ing 18-77 lbs. of water, which at the beginning was at the tempera- ture of 60°. After the experiment had proceeded for an hour, it was raised to 107°,—in thirty minutes more, to 142°,—in two hours, to 178°,—and in two hours and a half, to 210°. At the close of the experiment, he found that 4145 grains of metallic dust and scales had been detached from the bottom of the cylinder by the rubbing of the borer, or above eight ounces. And as he found that the capacity, or what has been called the specific heat of the scales, was the same as that of an equal weight of solid iron, he arrived at the conclusion, that heat is not a material substance, but the mere effect of motion. {Philosophical Transactions, 1798.) But it will be shown hereafter, that what is called capacity or specific heat, is not a measure of the quantity in different bodies; and that this mode of estimating their latent or combined caloric is fal- lacious. 26 OBJECTIONS ANSWERED. the third only 1"9°. [Thomson on Heat and Elec- tricity, p. 339.) In accordance with these facts, it is well known that the smith often kindles his furnace by hammer- ing a piece of iron until it becomes red hot; and that after he has reduced it to the limit of condensation, it becomes cold under the hammer. I have also found, that less heat is evolved by the friction of bodies in pro- portion to their hardness, as when two pieces of rock- crystal are rubbed together. It is therefore evident, that caloric is not generated de novo, by the friction of rubbing dry sticks of wood against each other, the pressure of wire drawing, and by rubbing the hands together; but that it is merely forced out of the pores of bodies, in the same way that water is disengaged from the pores of a sponge by pressure. And it will be proved hereafter, that the caloric which is disen- gaged by rubbing the hands together briskly, is resup- plied by the rapidly circulating blood, which obtains it by respiration.* * Had Count Rumford been aware of the enormous amount of caloric which is locked up in a state of combination with all bodies, even when reduced to the lowest temperature that can be produced, he would not have maintained that heat is merely the effect of motion, because destitute of gravity, and because of the large amount of heat evolved by the friction of boring a cannon. In fact, Rumford himself states, that if all the heat which is required to convert a pound of ice or snow into the liquid state, were com- municated to an equal weight of gold, the latter would be raised from 32° F. to the temperature of 2800°; the capacity of water for heat being 20 times greater than that of gold. Thus the amount of caloric required to convert snow into water without any elevation of temperature, is 140°, which, when multiplied by ALL BODIES FULL OF CALORIC. 27 That the particles of all bodies are surrounded by an elastic medium, which prevents their actual con- tact, is evident from their compressibility. And that this medium is caloric is proved by the facts already stated, that it augments the volume of solids, liquids, and gases, which are again reduced to their, former dimensions by abstracting what was before added; and by the large amount of heat that is disengaged by friction, which is transitive pressure, or by percussion, 20, gives 2800°; while it is probable, that between 32° and the absolute zero of ice, or any other solid body, there is a still greater amount of combined heat, had we the power of disengaging it from them. In the experiments of Berthollet, the first stroke on a piece of copper coin raised its temperature 17'3° F., the second blow 7*5°, and the third only 1-9°. It is therefore not surprising that when a blunt steel borer was made to rub against the bottom of a hole made in a cannon weighing 113 lbs., and cast solid, with a horse-power equal to 10,000 lbs., the temperature of the cylinder was raised from 60° to 130°, after it had made 960 revolutions about its axis, at the rate of 32 revolutions per minute. Such ex- periments prove only that caloric is disengaged from metals by forcing their particles nearer together, since the effect is not pro- duced after they have been brought to the limit of condensation by percussion and pressure. Among the various and contradictory opinions of Sir Humphrey Davy in regard to the nature of heat, he says, that " Caloric or the matter of heat does not exist;" that "it consists in a vibratory or undulatory motion of the particles of bodies round their axes, or in a motion of particles round each other." But it is impos- sible to reconcile these views with the experiments of Berthollet; Biot, and Pictet, or with the well-known fact, (which Davy himself admits,) that when "a piece of iron is made red hot by hammering, it cannot be strongly heated a second time by the same means, unless previously introduced into a fire." {Chemical Philosophy, p. 95.) 28 ALL BODIES FULL OF CALORIC. which is sudden pressure; both of which cause con- densation. It was estimated by Sir Isaac Newton, that the pores of gold occupy about the same space as its solid atoms; and that in water, the pores are about forty times greater than its solid particles. (Optics, Book ii. p. 242.) If then it be true, that all bodies are full of caloric; that it occupies 827 parts by vol- ume of the atmosphere, and 1719 parts of steam, it must be obvious that it constitutes by far the greater proportion by bulk, of the solid globe we inhabit. And if when intimately combined with the particles of ponderable matter, its thermal properties are dis- guised or hidden from the senses, the same thing is true of water and the strong acids, the individual pro- perties of which are concealed while they are in a state of chemical union with rocks, salts, &c* * The above facts will enable us, in some measure, to compre- hend the theory of opacity and transparency, the cause of which, Sir John Herschel thinks, has never yet been satisfactorily ex- plained. For as it is well ascertained that the particles of the atmosphere, steam, gases, water, saline and metallic solutions, like glass, and a great variety of crystalline solids, are arranged in regular series, at considerable distances from one another, the rays of light pass through them with slight interruption, giving rise to the phenomena of transmission and what is called transparency. But when the regular arrangement of the particles of ice, glass, quartz, and other crystals, is disturbed by unequal pressure, or un- equal expansion by caloric, the rays of light are transmitted im- perfectly: and if their symmetrical structure be broken down or deranged, as when they are reduced to powder, their power of transmitting light is so far destroyed, that they are rendered opaque. Sir Isaac ^Newton supposed that opacity was owing to the largeness, and transparency to the smallness, of the particles and intervening pores of bodies. {Optics, B. ii. p. 235.) But GENERAL LAWS OF CALORIC. 29 Having thus proved that caloric is a material agent, I now proceed to point out its connection with the laws of motion, and the widely extended influence it exerts in all the operations of nature. The cardinal facts which connect its agency with the general theory of physics, may be reduced to the following propositions:— 1. That the activity or moving power of all bodies is directly in proportion to the amount of caloric around their particles:— 2. That all molecular motions, wliether centrifugal or centripetal, may be resolved into the law by which caloric repels its own particles, and attracts those of ponderable matter, with forces that vary Inversely as the squares of the distance:— 3. That the quantity of molecular motion in the world, whether mechanical, chemical, or vital, is in proportion to the mean temperature of different latitudes, cseteris paribus, and diminishes from the equator to the poles:— 4. That the centrifugal force by which planets are im- pelled through their orbits, is directly in proportion to the heating power of the sun, and inversely as the squares of the distance:— 5. That caloric is the active principle in light, whether radiated from the sun, or generated by ordinary com- bustion, friction, percussion, phosphorescence, or the elec- tric discharge:— 6. That every variety of electricity is convertible into caloric, and the latter again into electricity ; consequently, many salts, rocks, and metals, are transparent when dissolved in water and the strong acids, although their particles are much larger than those of common ink and many other bodies which are black and opaque. 30 CALORIC A SELF-ACTIVE PRINCIPLE. that they are modifications of one and the same princi- ple :— 7. That the directive power of the compass-needle di- minishes from the isothermal equator to the points of lowest mean temperature, which are the magnetic poles; and that all its variations correspond with the variations of terrestrial -temperature:— 8. That the aggregate vltcd energy of animals, and the development of their organization, are exactly in pro- portion to the amount of caloric obtained by respiration, and combined with their tissues. That caloric is a self-active principle, might natu- rally be inferred from the fact, that every change in the temperature of bodies is attended with motion among their particles. It has also the power of mov- ing from one place to another, and even through the vacuum of an air-pump, without any projectile im- pulse from the particles of ponderable matter; as when it radiates from hot bodies. And that it has the fa- culty of generating motion among the particles of other matter, would appear from all the phenomena of na- ture with which we are best acquainted. For example, under the ordinary pressure of the atmosphere, and at, or a little below the temperature of 32°, the particles of water exist in the solid and apparently fixed state. But if 140° of caloric be added, their mobility is so far increased that they glide freely over one another, and assume the liquid form. If more be added, their activity is still further aug- mented by every degree of temperature up to the boil- ing point, when the whole is found to be in a state of rapid intestine motion. And if at this stage of the ex- ATTRACTION AND REPULSION. 31 periment, the water be kept over a furnace until it has received about 1000° more of caloric, the boiling liquid is converted into steam, the moving force of which is exalted by every addition of this active principle, which has the power of converting all other bodies from solids into liquids, vapours, gases, and flame, or incandescent particles. Since then it is a fact, that caloric alone gives to the quiescent particles of ponderable matter powers of motion which they do not possess without it, and that their mobility is augmented by every addition, but diminished by every abstraction of the igneous prin- ciple—it follows with all the clearness of absolute demonstration, that in the total absence of caloric, if such a condition were possible, the universal system of nature would be a motionless mass of inert and chaotic matter. It also follows, that everything in nature is composed of two descriptions of matter, the one essentially active, and the other passive; as main- tained by the most distinguished sages of antiquity. Since the time of Sir Isaac Newton, attraction and repulsion have been generally regarded as ultimate principles of action, for which no reason can be as- signed/11 But if it be a fact, that the elastic force of * After referring to his theory of planetary motion, Newton observes in his Preface to the Principia—"Many things induce me to suspect, that all the rest of the phenomena of nature may depend upon certain forces, by which the particles of bodies, by some causes hitherto unknown, are mutually impelled toward each other in regular figures, or are repelled and recede from one another; which forces being unknown, philosophers have hitherto attempted the investigation of nature in vain." Sir H. Davy also observes, that "the various forms of matter, and the changes of these forms, g2 ATTRIBUTES OF A PRIMARY CAUSE. bodies is augmented by every addition, and diminished by every abstraction of caloric, it is obvious that the entire privation of it would destroy the repulsive power of their particles. And as we have seen, that without caloric, they could have no power of motion, it is evi- dent that they could neither approximate nor recede from one another; consequently, that both attraction and repulsion are modified effects of one and the same agent. Moreover, if it can be proved that this agent is everywhere present—in the pores of bodies, as in the stellary spaces—and cannot be traced to any more comprehensive principle—it must be allowed to pos- sess all the attributes of a primary physical cause. For, nothing can merit the title of a vera causa, unless it be something which has the power of moving itself, and of generating motion in other bodies. It is equally evident, that whatever the cause of attraction and repulsion may be, it must determine all the phenomena of cohesion, chemical affinity, crystal- lization, elasticity,* decomposition, and recombination. depend upon active powers, such as gravitation, cohesion, calorific repulsion or heat, chemical attraction, and electrical attraction." {Chemical Philosophy, p. 67.) Dr. Arnott further states, that "attraction and repulsion are ultimate facts, which admit of no explanation in the present state of science." {Elements of Physics.) And Sir John Herschel adds, that " we have no means of further analyzing the phenomena of cohesion and elasticity, but must regard them, until we see reasons to the contrary, as ultimate phe- nomena, referable to the direct agency of an attractive and repul- sive force." {Introduction to the Study of Nat. Philosophy, 8 80.) * If the particles of the atmosphere and other bodies were not surrounded by caloric, there could be no vibrations, (in which heat has been supposed to consist,) therefore no sound. And here it is AGENCY OF CALORIC IN METEOROLOGY. 33 When I come to treat of the mode in which caloric produces opposite effects, it will be found that in cer- tain proportions it causes the particles of ponderable matter to separate, while in other proportions it forces them to unite:—that the aggregate force of attraction by which it tends to unite with the particles of gross matter, holds them together, and maintains the earth in the globular form:—in short, that all the phenomena of nature may be referred to the law by which caloric repels its own particles, and attracts those of ponder- able matter. That the quantity of evaporation and rain throughout the earth is In proportion to the heating poiver of the sun, caferls paribus, would seem to be a self-evident proposition. And it will be shown hereafter, from numerous scientific observations, that the annual ave- rage amount of rain within the tropics, except in desert places, is about three times greater than in the middle worthy of notice, that the velocity with which sound is propagated through different media, is directly in proportion to their elasticity, cseteris paribus. For example, it travels through the atmosphere when at the temperature of 32°, at the rate of 1090 feet per second; but when at 62°, it travels 1125 feet per second, or 1275 miles per hour. It also moves at the rate of 3375 feet per second through hydrogen gas, which contains a much larger amount of caloric around its particles than the same weight of atmospheric air, or any other gas, as will be shown hereafter. In accordance with the above facts, it is well known that sound is transmitted more distinctly, and rapidly, through light and resinous, or the more combustible species of wood, than through such as are dense, less elastic, and therefore contain less of the elastic ether termed caloric. It also moves with greater velocity through water than glass, and more swiftly through either than through rocks and metals, if we make allowance for the greater density of the latter. 3 34 EVAPORATION AND RAIN. latitudes; and about six times greater than in the polar regions. Hence the enormous size of the tropical rivers, compared with those of the higher latitudes. For example, it has been found that the Orinoco, which drains only 400,000 square miles of territory, discharges more water into the sea than the Missis- sippi, which drains 1,350,000 square miles.* * By a reference to the mean annual depth of rain that has been observed to fall in different parts of the world, something like an adequate idea may be formed of the stupendous aggregate force exerted by caloric in the silent process of evaporation. Owing to the existing distribution of land and sea, mountains and deserts, the amount varies greatly in the same latitudes. For example, a large proportion of the area south of the United States, between lat. 10° and 30° N., consists of water; whereas nearly the whole space from N. lat. 36° to the equator, is occupied by the continent of Africa, which lies to the south and southwest of Europe. The consequence of which is, that while the annual fall of rain at Bos- ton, Xew York, Philadelphia, and Ohio, is from 36 to 39 inches, and still more in the States farther south, it does not exceed 32 inches in the British Islands. And, as it diminishes from the sea to the interior of continents, the annual average is about 25 inches in western France, 22 in eastern France, 20 in central Germany, and 17 in Hungary. Moreover, as a great part of the aqueous vapour brought by the south and southwest winds from the ocean, is prevented from passing over the temperate latitudes of Europe and Asia, by the Apennines, the Alps, the Himalayas, and other mountains, precipitation is far more copious south than north of those immense barriers. It has been found that the annual fall of rain at the southern base of the Apennines is 64 inches, but only 26 inches at the northern base, and 55 inches at the southern base of the Alps, but 35 at the northern. On the southwest and north- east sides of the Ghauts, in southern India, the difference is much greater; as it is also on the western and eastern sides of the Scan- dinavian Mountains. It has been calculated that the mean annual fall of rain in the THEORY OF WINDS. 35 If the temperature of the whole earth were reduced to zero, there could be no fluidity of the ocean, which would be stationary as the solid frame-work of the mountains. Were it not for the heating power of the sun, there could be no contractions and expansions of the atmosphere, therefore no winds, nor fluctuations of the barometer. But in the present order of things, not an atom of the great aerial ocean is wholly quies- cent for a single moment of time. Its tropical portions tropical zone of America is 115 inches, but only 79 inches in the same zone of Asia and Africa; while in the temperate zone of North America the estimate has been 39 inches; and in the same zone of Europe 34 inches, which is considerably more than what has been found in central Asia. But from all the observations hitherto collated, the average cannot be far from 72 inches through- out the torrid zone, which embraces an area of 79,169,410 square miles. It therefore follows by calculation, that the annual rains of the tropics would fill a basin of 89,965-2 square miles in area, and 1760 yards, or one mile, in depth. Nor can the average be far from 36 inches in the temperate zones, which embrace an area of 103,353,140 square miles. This again, if collected together, would fill a basin one mile in depth, and 58,723-4 square miles in area. In the polar regions, which embrace an area of 16,421,200 square miles, the mean annual amount of rain may be estimated at 12 inches, which if collected into one mass would fill a lake 3110 square miles in extent, and one mile in depth. By adding the above products together, it will be found that the whole amount of water that annually falls upon our planet, would fill a basin 151,723 square miles in extent, and one mile in depth. Lastly, if we divide this aggregate by the number of days in the year, it will be found that the quantity of water daily converted into vapour, wafted from the ocean through the atmosphere, and precipitated in the form of rain, snow, and hail, would make a lake of one mile in depth and 415 in area. The proportion of sea to that of the land, is as 3 20 to 1-00. 36 FORCES OF CALORIC. being constantly expanded by the influence of a ver- tical sun, rise and give place to the denser air of colder latitudes; by which a perpetual circulation is kept up, as described in the 1st chapter of Ecclesiastes, v. 0: " The wind goeth toward the south, and turneth about unto the north: it whirleth about continually, and re- turneth again according to its circuits." If the earth were of uniform surface and elevation, there would be a gradual diminution of temperature from the equator to the poles, and the winds would be as regular as the movements of the heavenly bodies. But owing to the present distribution of land and sea, mountains and valleys, plains and woods, the tempe- rature of the globe is infinitely diversified, even in the same latitudes; by which the phenomena are rendered proportionally complex. And as the changes of wea- ther depend chiefly on the direction of winds, they cannot be predicted with invariable accuracy, without knowing all the circumstances which modify the tem- perature of different and distant places. It is not therefore surprising that meteorology has never been reduced to the certainty of an exact science. Were it possible to compute the aggregate forces of caloric in all the mechanical, chemical, and vital trans- formations, which are for the most part unobserved, we should be astonished at the result* But men are * It is in the torrid zone that nature exults in the plenitude of her powers in modifying the surface of the earth,—where the forces of the volcano, the earthquake, and of universal chemistry, are sur- passed only by those which wheel the planets through their orbits For example, we are informed by Captain Burnes, that during the Cutch earthquake of 1819, the Delta of the Indus was elevated VOLCANIC FORCES. 37 so accustomed to the regular course of nature, that they are less aroused by the grandeur of the sun, rising in pomp and might, filling the world with beau- tiful creations, and diffusing everywhere the spirit of gladness, than by a passing meteor of the night. That the whole theory of geological dynamics is in some way immediately connected with the agency of caloric, is now generally admitted by philosophers. But the general fact to which I would here invite attention is, that the number of volcanos and the forces they exert are in proportion to the heating poioer of the sun* For example, among the 270 volcanos now in action in different parts of the earth, above 180 are confined to the tropical regions. In the island of Java alone, with a surface of 25,000 square miles, there are about ten feet, over an area of fifty miles in length, and sixteen in breadth, in some places. We also learn from Mr. Lyell's excellent work on Geology, that during the shocks of 1822 in South Ame- rica, the coast of Chili was raised about four feet, over an area of 100,000 square miles. And it is well known that similar move- ments are constantly taking place in different parts of the earth, or beneath the ocean. * In every point of view, a complete theory of volcanos is of fundamental importance: for they regulate the distribution of land and sea, the magnitude and elevation of continents, the diversities of temperature in given latitudes, the character of rivers, and modify the direction of winds, which are impeded or deflected by mountain ranges. They are also the great terrestrial laboratories in which most of the precious gems are formed,—in which carbon is liquefied, and by slowly cooling under an immense pressure, assumes the crystalline form of that beautiful ornament, the dia- mond, which has been aptly designated as "a lump of light." Nor is it unworthy of notice, that all the richest gems and metals have been found in greatest abundance in the tropical mountains, or among the materials washed down from them by rains, rivers, and springs. 38 RELATIVE HEIGHTS OF THE EARTH. 43, according to Vander Boom Meseh. (De Incend'ds Mijitilum, Leyden, 1826.) And there is nearly the same number in other tropical portions of the old world. Between latitudes 10° and 15°, in the Pro- vinces of Guatimala and Nicaragua in South Ame- rica, there are 21; in Peru, between latitudes 14° and 20°, there are 16; while in the tropical islands, and around the shores of the Pacific ocean, there are about 80. (See Johnstons Physical Atlas.) Again; that the subterranean forces by which the dry land has been elevated from beneath the ocean, have in all past ages been in proportion to the heat- ing power of the sun, would appear from the relative heights of the earth in different latitudes. Nearly the whole of tropical America, for 3000 miles in length, and several hundred in width, is one great system of mountains, separated by plains, which, within the tropics, are from 9500 to 12,800 feet above the sea. In lat. l-j° N., Sorato and Illimani tower to elevations of 25,400, and 24,350 feet, according to the measure- ments of General Pentland. As we proceed north- ward toward Mexico, the loftiest peaks are those of Chuquibamba, Gualatieri, Sahama, Cotopaxi, Sierra, ;;n^f/ and others' Which var^ from 19,000 to Z-,000 feet, until we arrive at the table-lands of Mexico, which, between latitudes 19° and 24° N are from 6000 to 8000 feet above the sea. As we advance through the middle latitudes of ^nt /T™; ^ *°ck^ Mountains average about 10,000 feet. And if we except St.. Elias and Mount Hooker, they rarely exceed 12,000 feet. Nor do the table-lands which slope from their base exceed from RELATIVE HEIGHTS OF MOUNTAINS. 39 3000 to 5000: while it is well known that from lati- tude 60°, the elevations diminish on to the polar sea. On the other side of the equator, the highest moun- tains of Chili are the Aconcagua and Descabezado, which, between latitude 32-28° and 35° S. rise to ele- vations of 23,200, and 21,100 feet; from which they all diminish on to Patagonia, and thence to Cape Horn.* If we turn to the old world, we shall find that there is not a single mountain chain of the first magnitude throughout the middle latitudes of Asia, Europe, New Holland, nor the islands of the sea:—that the highest plains of India are from 11,000 to 14,000 feet, while the Himalayas rise to elevations of from 23,000 to 28,000 feet, between the latitudes of 24° and 32° N.: —that the long chains of the Altai, which extend across Europe and Asia, in about the latitude of 50°, are generally from 6000 to 8000, and rarely exceed 15,000 feet:—that the mountains of western Europe also diminish in height from the Alps, the Apennines, and the Pyrenees of the south, to the Carpathians, the Dofrines, and Urals of the north, which rarely exceed 6000 feet:—that the vast plateaux of central Asia, be- tween the Altai and the Thian-shan mountains, in lat. 45° N., are from 3000 to 5000 feet above the level of the sea; while the plains of Siberia decline gradually on to the polar ocean:—that in Greenland and Spitz- bergen the average height of the mountains is about 5000 feet; while Hecla in Iceland is only 4980 feet. * It is said that Captain C. Ross has recently discovered in S. lat. 78° a-mountain 12,400 feet high. But a few such excep- tions are too slight to invalidate the general law. 40 RELATIVE HEIGHTS OF MOUNTAINS AND PLAINS. If the mountains of Africa are less elevated than those of southern Asia and tropical America, they are far more numerous; while two-thirds of the continent south of Sahara seem to be an enormous pile of ele- vated table-lands. Extending from the equator to 34° S. and 37J° N. its central plateaux are supported by an immense chain that crosses the continent from west to east; between which and its southern ex- tremity, there are three other parallel ranges that diminish in height on to the Cape of Good Hope. The vast plains of Abyssinia and Nubia are also about 7000 feet above the ocean, and supported by innume- rable mountains of still greater magnitude than those of Atlas in the west: while the eastern coast is flanked by a chain which extends, with few interruptions, from north latitude 10° to 32° S. But it is evident that the elevation and extent of table-lands, (which are in fact widely extended mountains,) afford a far more accurate measure of geological forces, than the hei-ht of a few isolated peaks.* From the foregoing brief outline we perceive, that nearly all the highest mountains of the earth are found within 32° of the equator: and, what is still more important to observe,-^ the average elevation * According to Humboldt the mean Estimated height of Eurone is 650 feet, of K America 750 feet, of S. America fl 0 e!t and of Asia1150 feet That of Africa has not been ascertained no ^relative exten of mountains and plateaux in the different But M. Guyot tells us, that those of North and South America embi-ace one-third of its surface; those of Africa two-third, Ind the high lands of Asia five-sevenths of its area; the elevat d region between the Himalava and Altai ran^e, vJ- L™ long, and 1500 miles broad.' ** bem* 2400 miIes OBSERVATIONS OF SCHROETER. 41 of the table-lands is about equal to that of tlie mountains in the middle latitudes, where, again, the table-lands are of nearly the same height as that of the polar mountains. The conclusion is therefore irresistible, that the aggre- gate force by which mountains, Islands, and continents have been raised, from beneath the ocean, like all the chemical transformations on the surface of our planet, is in proportion to the heating power of the sun, casteris paribus. And that the same law prevails throughout the planetary system, would appear not only from ana- logy, but from a series of telescopic observations con- tinued for ten years on the surface of Venus, by the celebrated Schroeter, who has estimated the height of its principal mountains as varying from 10*84 to 22*05 miles. So that after making due allowance for the uncertainty of such observations, it is probable that he has arrived at an approximation to the truth. For, as Venus is 1*40 times nearer to the sun than the earth, and as the heating power of the sun is inversely as the squares of the distance, Venus must receive more caloric than a given area of the earth, in the ratio of 1*96, or nearly as 2 to 1, because the square of 1*40 is 1*96. Nor is it unworthy of notice, that as the heating power of the sun is 6"959 times greater at Mercury than on the earth, which is 2*638 times far- ther from the sun, the mountains of Mercury have been estimated at 10*75 miles in height, and about eight times higher than those of the earth, compared with the magnitude of the two planets. And as Mars is 1*494 times farther from the sun than the earth, he must receive 2*232 times less caloric; which must pro- 42 PLANETARY INCLINATIONS. portionally modify all the conditions of his surface. In like manner, as Jupiter is 5*157 times farther from the sun than the earth, he must receive 26*594 times less caloric. And so on to the extremity of the solar system. But in estimating the changes which the surface of our planet has undergone during long geological epochs, we must not overlook the influence of varia- tions in the inclination of the earth's axis, in modify- ing the mean temperature of different latitudes. It is generally supposed to have been demonstrated theo- retically by Laplace, that the total variation of the planetary inclinations must be comprised within the narrow limits of 3°. But that, in so vast and compli- cated a problem as that of perturbation, geometers may have overlooked some important elements in their calculations, would seem highly probable from the limited period since which accurate observations have been made; for they admit that the disturbing influence of all the planets and their satellites upon each other is such, that millions of years are required to bring about one cycle. But if it were wholly impossible to determine the exact amount of variation in the planetary inclina- tions, during the countless ages that have past oo- logy affords the most conclusive evidence, that at some remote period of the earth's existence, the inclination of its axis must have been far less than at present- or that the equator and poles must have been reversed For it has been discovered that the secondary forma- tions at Melville Island, and other parts of the polar regions, are filled with the fossil remains of plants and RELATIONS OF GEOLOGY TO ASTRONOMY. 43 animals which could have been produced only in a warm climate. Nor is it possible, that in the present inclined state of the earth's axis, tropical plants could ever have existed in these high latitudes, for the plain reason that for several months in the year they are deprived of solar light and warmth, which are essen- tial to vegetation. That this inclination is now actually diminishing at the rate of one minute in 126* years, is admitted by all astronomers. It therefore follows, that if it should go on decreasing in the same ratio, without any oscillations or retrogradations, it would wholly vanish in about 177,760 years, when there would be perpetual spring* throughout the middle latitudes, or what may be termed a vernal period of the great year. For although there would be perpetual summer at the equator, and a gradual diminution of temperature on to the highest latitudes, there would be no winter. In short, the days and nights would be everywhere of the same length, except immediately around the poles, which would be always illuminated, and there would be no variety of seasons, but an unceasing ver- dure would everywhere prevail. That the earth may * In the tenth book of the sublimest song in our language, Milton represents the earth as enjoying this happy exemption from winter, before the fall of man: after which, the Creator "Bid his angels turn askance The poles of earth twice ten degrees and more: * * * * * to bring in change Of seasons to each clime; else had the spring Perpetual smiled on earth with verdant flowers. These changes in ihe heavens, though slow, produced Like change on sea and land." 44 RELATIONS OF GEOLOGY TO ASTRONOMY. have frequently passed through such a state, is highly probable from the fact, that at the present moment the axis of Jupiter has very little if any inclination. And that this inclination has an extensive range of variation, would further appear from the fact, that in the case of Saturn it is now 28° 40', while in that of Mars it is 30° 18', according to Sir John Herschel. There is therefore no obvious reason why the inclina- tion of the earth's axis should not go on augmenting until it arrives at the same angle.* But are w^e not further authorized to conclude, that the equator may have gradually shifted to the middle and even the polar latitudes? This hypothesis would enable us to explain the high and uniform temperature which prevailed throughout the northern hemisphere when the higher latitudes abounded with tropical plants and animals,—a great physical fact which cannot be satis- factorily accounted for in accordance with the theory * In reality, it is more in accordance with analogy to suppose that this variation may pass through an entire revolution, than that it is confined within the narrow limits of 2° or 3°. Should such a revolution go on uniformly at the rate of 48" in a century, its completion would require a period of 2,700,000 years,—unless interrupted by a conjunction of all the planets; an event which the ancients regarded with dread, as the cause of deluges, or some other signal catastrophe. We are informed by Mr. Samuel Davis, that, according to the Surya Siddhdnta, the oldest Hindoo work on Astronomy, the obliquity of the ecliptic was 24°, when it was written; which must therefore have been 4000 years before the 19th century. {Asiatic Researches, vol. ii.) From the rate at which this obliquity has diminished since the time of Tycho Brache Sir John Herschel has adopted 48 seconds as the average in a century; or 1 minute in 126£ years. FUNDAMENTAL LAWS OF PLANETARY MOTION. 45 of Laplace. The truth is, that his mathematical rea- sonings were founded on the supposition that all the planets move in nearly the same plane; whereas it is now admitted by astronomers, that the orbit of Pallas is inclined to the ecliptic at an angle of 34i°, and that of two satellites of Uranus at an angle of 78° 58'. But these cosmical bodies had not been discovered when this Systeme du Monde was written; nor had.Geology then taken its legitimate rank among the Sciences. This brings us to the general theory of planetary motion. The leading facts of the solar system which connect the movements of the heavenly bodies with the agency and laws of caloric, may be reduced to the following propositions:— 1. That the sun revolves on his axis from west to east, in about twenty-five days. 2. That planets revolve around the sun, satellites around planets, and all of them upon their axes, in the same direction that the sun moves upon his axis. 3. That the heating power of the sun diminishes in proportion as the squares of the distance increase.* * For example, as Mercury is 1*888 times nearer to the sun than Venus, he receives more caloric than Venus, in the ratio of 3-564 to one ; because the square of 1-888 is 3*564. And as Mer- cury is 2-638 times nearer to the sun than the earth, he receives 6*959 times more caloric, or the square of 2638. For the same reason, as Mercury is 3-944 times nearer to the sun than Mars, the latter receives 15-555 times less caloric; Ceres 25*157 times less; Jupiter, 185*259 times less on a given area; Saturn 625 times less; and Uranus 2500 times less. Or, if we take our own planet as the standard of measure, the heating power of the sun is 2*232 times greater at the earth than at Mars, because he is 1*494 times farther from the sun; 7*3^1 times greater than at Ceres; 26*594 46 OPPOSITE FORCES OF CALORIC. 4. That the centrifugal force by which planets and their satellites are impelled through their orbits dimi- nishes in proportion as the squares of the distance from the centres of power increase. 5. That the centripetal force by which planets are impelled toward the sun, and satellites toward their primaries, diminishes in the same ratio. 6. That by the joint operation of two forces, each of which varies inversely as the squares of the dis- tance, the celestial bodies are impelled through their orbits with velocities which vary in accordance with Kepler's third law, as shown in the following tables: TABLE I. Mean distance Periodic times. Velocities Diarn- from the sun. d. h. m. s. per hour. eters. Mercury................... 36,000,000 88 0 0 0 107 100 3 200 Aen"s...................... 68,000,000 224 7 0 0 7!) "27 7*800 ^irth...................... 95,000,000 365 6 0 0 68,093 7'qi" *l!irs....................... 142,000,000 687 0 0 0 54,113 4'l89 Ceres....................... 260,000,000 1681 8 0 0 40 484 Juflter..................... 41JO,00(.,000 4332 14 0 0 29^08 87(ib'6 •:a,urn..................... 900,000,000 l07.-,n 5 0 0 21 899 79 000 \j.™a\..........*;.........1800,000,000 30686 20 0 0 15 356 Ss'oOO Dist. of moon from | no_ ^^ ' ' " the earth............f 23,,000 27 7 43 11 2,271 2,160 times than at Jupiter ; 89*737 times than at Saturn ; and 358*988 times greater than at Uranus. But as the planets are impelled through their orbits by two equal and opposite forces that always counteract each other, the velocities do not diminish at the same rate as their mean distances from the sun : for while Jupiter is 5-157 times farther from the sun than the earth, his velocity is only about 2 30 times less. In like manner, although Saturn is nearly 91 times farther from the sun than the earth, his velocity is only about three times less ; and so of all the other planets, as may be readily ascertained by comparing the times and distances in the following Tables, constructed from data furnished by Sir J Her schel. {Treatise on Astronomy.) OPPOSITE FORCES OF CALORIC. 47 TABLE II. SATELLITES OF JUPITER. Mean dist. First Satellite................... 263,111 Second............................ 418,620 Third.............................. 667,725 Fourth............................1,174,413 Periodic times. d. h. m. Velocities. Diameters. 16 16 13 3 16 28 14 43 32 38,929 30,860 24,433 18,423 2508 2068 3377 2890 TABLE III. SATELLITES OF SATURN. Periodic times. Mean dist. d. ft. m. ' Velocities. First Satellite.................. 132,364 0 22 38 36,750 Second.......................... 169.850 1 8 53 32,503 Third............................ 208.718 1 21 18 28,949 Fourth........................... 269,350 2 17 45 25,739 Fifth............................. 376,198 4 12 25 21,802 Sixth............................. 872,199 15 22 41 14,320 Seventh.........................2,542,180 79 7 55 8,389-5 Twelve of the asteroids,* and the satellites of Ura- nus, have been omitted, because their elements have not yet been fully ascertained. The third column in * The discovery of Astua, Hebe, Iris and Flora, Metis and Diana, Parthenope, Victoria, and others discovered since 1845, has augmented the number of the asteroids to fifty-two. We are informed by Aristotle, Theophrastus, Diogenes Lantius, Cicero, and Plutarch, that the sun was recognized as the centre of our system by Pythagoras, who has been supposed by some authors to have derived this discovery from the Egyptians. But as the helisantric theory was unknown to Eratosthenes, Possiclonius, and Ptolemy, (who were the most celebrated astronomers in Greece,) as it was to the ancient Hindus, Chinese, and Hebrews, there is much reason to doubt whether it was understood by any of the ancients except the admirable Pythagoras, and a small number of his disciples, who had not sufficient influence to overcome the deeply rooted prejudice of the schools. It is possible, however, that Pythagoras may have obtained a glimpse of this sublime theory from some unknown Egyptian Copernicus. 48 DISCOVERIES OF KEPLER. the tables was obtained by multiplying the distances by 2; which gives the diameter of the orbits. On multiplying this by 3*1416, and dividing the product by the periodic times, we get the velocities with a suf- ficiently near approximation to the truth for our pre- sent purpose. After the establishment of the true solar system by Copernicus, the invention of the telescope, and the discovery of Jupiter's satellites by Galileo, the most important advance ever made in Astronomy was that of the immortal Kepler, announced in a work entitled "HarmonIce Miu/di," published in 1619. In that work, he demonstrated that " the squares of the periodic times of any two planets are to each other, in the same propor- tion as the cubes of their mean distances from the sun," —a law which has been found equally true of satel- lites and their primaries,—if we except the mutual influence they exert upon each other, termed pertur- bation. It also led to the important discovery of Newton, that every particle of matter in the universe attracts every other, according to the law of the inverse square of the distance;—a law which, independent of all hypotheses in regard to the cause of motion, was one of the finest generalizations ever made in the sci- ence of Nature.* * In a letter to Dr. Halley, Sir Isaac Newton himself states, that the law of the inverse square of the distance was deduced from Kepler's theorems. But it was Galileo who first demonstrated, that in the descent of falling bodies, the spaces described are as the squares of the times. And Sir William Hamilton observes, "that the Newtonian theory of astronomy was but a final gene- ralization prepared by foreign observations, and even already enounced." {Ed. Phil. Journal, vol. xxxv. p. 71.) NEWTON'S first law of motion. 49 In regard to what is called Newton's first lav of motion, various and- opposite opinions have been en- tertained. But whether true or not, it was propounded by Galileo, long before the time of Newton. Accord- ing to this law, as announced in the first book of the Principia, "every body perseveres in its state of rest or of motion, unless compelled to change that state by forces impressed thereon." On this law was founded his theory of planetary motion, as developed in the third book, in which he maintains, that when first created, the earth and heavenly bodies were projected into empty space, by the agency of a primitive im- pulse, communicated at various distances from their centres of gravity; by which their annual and diurnal revolutions have been ever since maintained, without any renewal of the cause.* But in all the operations of nature with which we are best acquainted, force is always expended in pro- ducing motion; and if not as constantly renewed, is very soon exhausted. Nor have we the slightest proof, that motion is ever generated without the immediate agency of some active principle. The power of steam is cre- ated by the immediate agency of caloric, and ceases whenever the active principle is withdrawn. The force with which a horse-shoe magnet of soft iron holds on to the armature, is generated by the passage of an electric current through the wires which are coiled around it; but ceases the moment the current is arrested. The metallic wire that connects the ex- * Newton observes: " That the motions of the planets may subsist an exceeding long time, it is necessary that the heavens should be void of all resisting matter." 4 50 views of herschel and whewell. tremities of a voltaic battery, attracts iron filings, and deflects a magnetic needle in its vicinity, so long as the electric fluid is disengaged by chemical action, but ceases whenever that action is at an end. The powers of digestion, secretion, nutrition, and muscular motion, are generated by means of an active principle which obtained from the atmosphere by respiration; but cease whenever that important function is arrested; as will be shown in subsequent parts of this work * * In accordance with the above views, it is observed by Sir John Herschel that, "to say matter has inertia, is only to say that the cause is expended in producing its effect, and that the same cause cannot continue to produce its effect without renewal." (Nat. Philosophy, sect. 234.) And it was humorously argued by the author of Knickerbocker, that "as the projectile force has long since ceased to operate, while its antagonist remains in undiminished potency, the world ought, in strict propriety, to tumble into the sun." Nor is this merely conjecture ; it is now mathematically cer- tain, that if the centrifugal force were suspended, the earth would reach the sun in about 64£ days, and Mercury in about 15^ days. Mr. Whewell also observes, in his Bridgewater Treatise on Astro- nomy, that "to say motion must continue the same from one instant to another, because there is nothing to stop it, seems to be taking refuge in words." But there is no one force in nature which is not counteracted by another force. It is therefore evident that New- ton's first law of motion does not apply, as he originally intended, to the planetary revolutions. Mr. Whewell is equally explicit in renouncing the vacuum of space: for when treating of the lumi- niferous ether, he says, "it must not be merely like a material fluid poured into the vacant spaces of the material world; it must affect the physical, chemical, and vital properties of whatever it touches, and be the means of communication between planets and systems.'' (Book i. ch. xvii., and book ii. ch. xi.) Yet he observes, in another chapter, that "in the machinery of the universe there is, so far as we kuow, no material connection between the parts which act on each other." (Book ii. ch. i.) ERRORS OF NEWTON. 51 But if it be true that caloric is perpetually radiated from the sun and fixed stars into the boundless regions of space, it must constitute an infinite ocean of ethe- real essence; consequently, there can be no such thing as a vacuum, which, as Aristotle rightly observed, would destroy all motion. Nor is it less obvious, that if caloric be a self-active principle, and is everywhere present, there can be no such condition of matter as vis inertlop, which literally means the power of not acting. And that a single impulse is not competent to maintain the unceasing motion of planets and satel- lites, is evident from Newton's own hypothesis, that they are impelled or drawn with an equal force at right angles to the direction of the original projection. Moreover, when Newton referred the centrifugal force to the immediate agency of the Deity, and that of gravity to an inherent property of matter, he departed from that uniformity of nature and of causation, on which all true science is founded. To be consistent, he ought to have referred all physical power to the immediate agency of the Deity, or to the inherent properties of matter. Besides, if a single impulse be capable of producing the centrifugal force, why should not a like impulse be the cause of gravity? That the illustrious author of the Principia was not ultimately satisfied with the data on which his theory of planetary motion was founded, viz. the projectile impidse, the vacuum of space, and the vis insita of mat- ter* is plain enough from what has been already said * It might as well be said that animal motion and all the actions of life are the result of a primitive impulse, as that planets are maintained in their orbits without the continual agency of an im- 52 UNSETTLED VIEWS OF NEWTON. in the early part of this chapter, concerning his views of the ether. But here again he was unfortunate in his explanation of the mode in which it produces the phenomena of cohesion, capillary attraction, gravita- tion, &c. For he supposed that "the ether was more rare within the bodies of the sun and planets, than in the celestial spaces between them; and that its density increases perpetually in proportion as the distances iucrease from them, thereby causing the gravity of those great bodies toward one another, and of their parts toward each other, every body endeavouring to go from the denser parts of the medium toward the raier." (Optics, Queries 20, 21.) The failure of this hypothesis has been already ex- posed by Mr. Whewell, who justly observes, that the density of all radiant matter diminishes with every increase of distance from any given centre. And it will be proved hereafter, that the ether is more dense within the pores and around the particles of dense than of light bodies, in which it is more dense than in free space. On the whole, it is not very surprising that Newton's views of the ether have been generally regarded as chimerical, and insufficient to explain the leading phenomena of nature; especially as he never identified it with any known principle. And when he pelling principle. And if we admit that each of the eleven planets and their fourteen satellites was projected into space by a primitive impulse, is it not remarkable that the continuous force of that im- pulse should precisely correspond with the heating power of the sun, and be just equal to the power of gravity ? The fact is that if the sun were removed from the centre of our system, the revolu- tions of the different planets would cease, in spite of the primitive impulse. UNSETTLED VIEWS OF NEWTON. 53 referred the centripetal forces of matter to its agency, he assigned no physical cause of the centrifugal force. But if the centrifugal force of planets be directly in proportion to the radiating power of the solar orb, caloric must be the cause of this force; for the essen- tial character of a vera causa is, that the effects it pro- duces are a measure of its intensity.* Nor is it less certain, that if the caloric which is perpetually radiated from the sun be not annihilated, it must either accumulate in the planetary spaces, and thus raise their mean temperature, or it must return to the great fountain from which it emanates. It also * Moreover, as the mean temperature of the earth has remained the same for long periods of time, it follows that the planets must give off by radiation the same amount of caloric they receive from the sun. This amount must depend on their superficial area, and on their distance from the sun. It therefore becomes an important question, how far it may operate in producing the centrifugal force of their satellites, just as the radiating power of the sun generates the centrifugal force of the planets themselves. At the same time it must be observed, that the motions of the satellites are subject to the direct influence of the sun; which, however, is greatly diminished by his immense distance, compared to the nearness of their primaries. For, as Sir John Herschel observes, "the greatest part of the sun's attraction, which is common to both, is exerted in retaining both primary and secondary in their common orbit about himself, and in preventing them from parting company; the small excess of force acting only as a disturbing power." And he states that, according to the calculations of Newton, the mean value of this excess, in the case of the moon's disturbance by the sun, does not exceed T^ of the principal force which retains the moon in its orbit. (Astronomy, sect. 493.) It must also diminish, relatively, as the magnitude and distance of planets increase. Yet it is sufficient to give the orbits of their satellites the character of somewhat zigzag circles. 54 CAUSE OF THE SUN'S MOTION. follows, that if the vast ethereal tide flow perpetually toward the sun, with the same force which it exerts in maintaining the centrifugal power of planets, there is no good reason why it should not be the cause of the centripetal force which maintains them in their orbits. Thus it would appear, that the projectile and gravi- tating forces of Sir Isaac Newton are owing to one and the same principle, which produces all the con- tractions and expansions, separations and combinations of the particles of ponderable matter; as will be proved in the third chapter of this, and the whole of the second book. Nor can there be a rational doubt, that in the total absence of solar radiation, all the mechani- cal, chemical, and vital operations of the planets would be arrested; and that if the instellary spaces were re- duced to absolute zero, there could be no motion of the heavenly bodies. Moreover, if it be true that there is an unceasing circulation of ethereal matter throughout the solar system, it will account for the revolution of the sun on his axis; a phenomenon which has never yet been explained in accordance with the Newtonian theory; and the knowledge of which is of fundamental im- portance to a right understanding of physical astro- nomy; as it is in the laws which regulate the actions of the sun, that we must seek for the origin of plane- tary motion. For example, it will be shown hereafter, that the tendency of caloric to unite with other bodies is in proportion to the quantity of matter they contain, cmterls paribus. Hence it is that two pounds of water will condense just twice as much steam as one pound; and that a small fire is quenched by a large quantity REVOLUTION OF THE SUN ON HIS AXIS. 55 of coal, with which the caloric unites, and thus arrests the process of combustion. We are therefore author- ized to infer, that the aggregate force by which the ether of space tends to unite with the different bodies of the solar system, is in proportion to their mass, and inversely as the squares of the distance* If the sun were a perfect sphere, and not surrounded with planets, the ether would press with equal force upon all parts of his surface, and thus maintain him in a perfectly fixed state. But as he is not a perfect * By glancing over the Tables, pp. 46-1, it will be observed that the velocity of planets round the sun does not depend upon their magnitudes, but on their distance from him, and that the same law applies to their satellites; which accords with the discovery of Galileo, that the velocity with which bodies fall to the earth is the same, whether they be large or small, dense or light, when the resistance of the atmosphere is removed. But if the distance of planets from the sun were equal, the velocity of their satellites would be in proportion to the magnitude of their primaries, and inversely as the cubes of the distance. At the present distance of the earth from the sun, the moon revolves around us at the rate of 2168 miles an hour, at the distance of 231,000 miles from the earth. But if the earth were at the place of Jupiter, and if the velocity of satellites diminish in the same ratio as that of their pri- maries, on receding from the sun, the velocity of the moon would be 2*303 times slower than at present, and only 941 miles an hour. It must, however, be observed, that as the volume of Jupiter is about 1300 times that of the earth, his first satellite, which is 263,111 miles from his centre, moves at the rate of 37,140 miles an hour. And if his first satellite were only 237,000 miles from his centre, (the distance of the moon from the earth,) it would move at the rate of 41,200 miles an hour, and faster than the moon, (if the earth were at the place of Jupiter,) in the ratio of nearly forty-four to one,—a difference which must therefore be owing to the difference between the magnitude of Jupiter and that of the earth. 50 DIURNAL REVOLUTION OF PLANETS. sphere, and as the pressure of the ether upon him from every part of the solar system is modified by all the surrounding planets and satellites, it is obvious that the centripetal force of the ether must vary on different parts of his surface, so as to give him a rotary motion on his axis,—a result which may be owing in part to certain actions going on within the sun himself, and on which his radiating power de- pends. The above views will also enable us to explain the diurnal revolution of planets, the elliptical form of their orbits, the inclination of their axes, and all the phenomena of the tides. In the first place, if the planets were perfectly round, and not influenced by each other, both the radiating power of the sun, and the centripetal pressure of the ether, would be the same on all parts of their surface, and they could have no rotary motion. Nor could there be any elongations of their orbits, which would be perfect circles, if the centrifugal and centripetal forces by which they are impelled were always equal and the same. But as none of the heavenly bodies are perfectly spherical, the solar radiation, like the returning pressure of the ether, must operate with unequal force on different parts of their surface, and tend to give them a rotary motion; the rapidity of which would seem to be in proportion to the difference between their equatorial and polar diameters. In the case of Jupiter, this dif- ference amounts to 6096 miles, or in the ratio of about 107 to 100. Accordingly, he revolves upon his axis in 9h. 56m., at the rate of 27,400 miles an hour. The difference between the equatorial and polar diameters DIURNAL REVOLUTION OF PLANETS. 57 of Saturn is still greater; being above 6700 miles, and such as to give him the appearance of a parallelogram, with the four corners rounded off deeply, but not so much as to bring it to a spheroid, as observed by Sir W. Herschel in 1805. The consequence of this de- viation from the spherical form is, that although nearly 91 times farther from the sun than the earth, his diur- nal revolution is performed in lOh. 16m., and at the rate of 24,000 miles an hour. But as the equatorial diameter of the earth exceeds the polar only 24 £ miles, according to Laplace, it requires 24 hours to perform its diurnal revolution, while moving round the sun with a velocity 2*30 times greater than that of Jupiter. The diurnal periods of Mercury, Venus, and Mars, are nearly the same as that of the earth; corresponding with the smallness of their deviation from the sphe- rical form. In the case of Jupiter, this difference is as 107 to 100; whereas in the earth, it is as 299 to 298. There is another circumstance which may have an equally important influence on the elliptical form of the planetary orbits. For example, we learn from the telescopic observations of Sir William Herschel, that all parts of the sun are not equally luminous. He thinks that one-half of the sun emits less light and heat than the other; and that if seen at a very great distance, it would appear like some of the fixed stars that have a periodical variation of lustre. At times, there may be seen on his surface spots, (one of which, on the 29th of March, 1837, occupied an area of 3,780,000,000 square miles,) which are so large as to measure 45,000 miles in linear diameter, exhibiting 58 PERPETUAL CIRCULATION OF CALORIC. the appearance of a dark, opaque, and solid ground. It therefore follows, that although the same amount of caloric is given off by the sun in any given time, different quantities are radiated from different parts of his surface, so as to augment and diminish, within certain limits, the centrifugal force of the planets, causing them to approximate the sun in certain parts of their orbits, and to recede from him in other parts, with corresponding accelerations and retardations in their annual motions, and, perhaps, variations in their mean annual temperature. On the other hand, as the centripetal pressure of the ether on each of them is modified by the disturbing influence of all those be- yond, this also tends to alter the circular form of the orbits, and render them more or less elliptical. Nor is it less obvious, that the interference of the moon must cause a successive diminution of gravity or ethereal pressure upon the earth, so as to cause a cor- responding elevation of the tides, which are still fur- ther elevated by the influence of the sun when in conjunction with the moon. Thus we perceive that as the mean temperature of planets, (at least of the earth,) and of the spaces between them, is uniformly the same, there must be a perpetual circulation of caloric from and to the centre of the solar system, as from and to the planets. We have also found that the heating power of the sun is just equal to the cen- trifugal force of planets, and an accurate equation of the gravitating force; so that whatever is true of the laws established by Kepler and Newton, must be equally true of the foregoing induction, which has the additional advantage of assigning a well-known prin- HEATING POWER OF THE SUN. 59 ciple as the physical cause of the phenomena, and of thus affording a resting-place for the mind. From all the foregoing facts and observations we are authorized to conclude, that caloric is a self-active principle which is perpetually circulating throughout the universe,—from suns to planets, and back again to the great fountains from which it emanates; in short, that it is what Homer called " The golden everlasting chain, Whose strong embrace holds heaven, and earth, and main." That the movements of the heavenly bodies are in some way immediately dependent on the heating power of the sun, appears to me almost a self-evident propo- sition, and was so regarded by many of the ancient sages* It was also vaguely recognized by Milton, who represents the sun as both eye and soul of this great, world,— * The agency of caloric in giving rotary motion to a globule of water or other liquid, is beautifully illustrated by some recent ex- periments of M. Boutigny. He found that when a small quantity of water was placed on a metallic plate heated to the temperature of 340° F. and upwards, it assumes the spheroidal state,.and re- mains for some time poised as it were without any visible support, at a sensible distance above the surface of the metal, rolling on its axis like a little world in space. Now whatever the reason may be, that the caloric radiated from a metal heated to nearly the point of redness does not combine with the globule and convert it rapidly into steam, as at lower temperatures, there can be no doubt that caloric is the cause of its rotary motion. And if so, there is no obvious reason why solar caloric should not be the cause of planetary motion. It is supposed by M. Boutigny and other che- mists, that in such cases the caloric of the heated metal is nearly all reflected by the globule, instead of combining with and convert- ing it into steam, as it does at lower temperatures. 60 PHYSIOLOGICAL AND PATHOLOGICAL " Toward which the planets Turn swift their various motions, or are turn'd By his magnetic beam, that gently warms The universe, and to each inward part, With gentle penetration, though unseen, Shoots invisible virtue, e'en to the deep." Paradise Lost, b. iii. But we cannot expect to comprehend fully the modus operandi of caloric in any one class of phenomena, until we rise high enough to survey the whole field of knowledge, and to perceive the intimate connection between all its various branches. It was truly ob- served by Mr. Hume, that "the only expedient from which we can hope for success in our philosophical researches, is to march up directly to the capital or centre of the sciences, which being once mastered, we may everywhere else hope for an easy victory." When I come to treat of the physiological and pathological laws of caloric, it will be found that the aggregate amount of life on our planet is in propor- tion to the heating power of the sun, cceteris paribus:— that no seed ever germinates, and no egg is ever hatched, without a due supply of warmth:—that as the thermometer rises in spring, so does the sap of plants; and as the mercury mounts up in summer, the forces of life augment, but decline in autumn, and are wholly arrested during winter:—that as the annual rings of trees correspond in thickness with the mean temperature of the growing season in the higher lati- tudes, and are always thickest on the side exposed to the sun,—the germination, growth, and decay of plants, constitute a natural thermometer on a grand scale. It will also be found, that organized bodies are LAWS OF CALORIC. 61 composed chiefly of those elements which contain the largest amount of caloric around their particles; by which they are rendered proportionally active, and endowed with the faculty of entering into vital com- binations, so as to form highly complex tissues: that the vital energy of animals, the activity of their func- tions, and the development of their organs, are in proportion to the amount of caloric which circulates through, and is employed in combining arterial blood with the solids. A right understanding of these laws is of vastly greater importance than those of Geology, Astronomy, or even Chemistry. For until we com- prehend the operations of life, health, disease, the modus operandi of medicines and morbific agents, the healing art can never take its appropriate rank among the exact sciences; nor be rescued from the charge of mysticism, quackery, and ignorance, of what is essen- tial to the character of a philosophical physician. But as "the strength of a science is, like that of the old man's fagot, in the band," the candid seeker after truth is requested to suspend his judgment until he shall have carefully examined the whole of the evi- dence adduced in support of the author's peculiar views. CHAPTER II. ATOMIC CONSTITUTION OF MATTER. "Omnia in mensura, et numero, et pondere." Liber Sapientise, xi. 21. Before treating of the relative quantities of caloric in different bodies, and of the law by which it pro- duces the opposite forces of attraction and repulsion, combination and separation, contraction and expan- sion, I shall present a brief outline of what is known in regard to the ultimate constitution of ponderable matter. The doctrine that everything in nature is arranged by measure, number, and weight, seems to have been recognized by the sages of India and Egypt, long before the time of Pythagoras and Democritus, who maintained that all matter is composed of exceed- ingly small, hard, and unchangeable atoms, that vary in magnitude; so arranged and combined as to pro- duce an endless diversity of mineral, vegetable, and animal bodies. The same theory was adopted by Bacon, Boyle, Newton, and many other distinguished modern phi- losophers, who very justly conceived that if matter were infinitely divisible, all species would be con- founded. And it is obvious that if the elements did not unite in definite proportions, the laws of chemistry could not be understood, nor its results be predicted (62) • VIEWS OF BOSCOVICH. 63 with certainty. It is equally manifest, that if matter were infinitely divisible, a finite body must consist of an infinite number of parts, which is a contradiction. It follows, therefore, that matter must consist of ulti- mate atoms. In opposition to this simple ard rational view of the subject, it was maintained by Boscovich, that the minutest portions of matter consist of mere mathematical points, without extension or solidity, sur- rounded by alternate immaterial spheres of attraction and repulsion; by one of which, the said mathemati- cal points are drawn together, and by the other kept asunder, so as to be prevented from touching. We are indebted to the researches of Wenzel, Berg- man, and Richter, for the discovery that definite pro- portions of acids and alkalies are required for mutual saturation; and that many other chemical combina- tions take place only in fixed ratios. It was further maintained by William Higgins of Dublin, (in a wrork entitled "A Comparative View of the Phlogistic and Antiphlogistic Theories," published in 1789,) that all compounds are formed by the union of exceedingly minute atoms, which are surrounded by atmospheres of caloric; and that oxygen unites with nitrogen in proportions which are even multiples of the lowest. But to Dr. John Dalton of Manchester, was reserved the distinguished honour of reducing the atomic theory to a systematic form, in a work entitled "Chemical Philosophy" published in 1808-10,—aided by the subsequent analyses of Thomson, Berzelius, Prout, Gay-Lussac, Dulong, and many others. The most general law of chemical affinity as an- nounced by Dalton is, that the constituents of ponder- Q4 THEORY OF DALTON. able matter, ivhether simple or compound, arc capable of combining with each other only In fixed or definite pro- portlou* by weight. In a practical point of view, this law has been of the highest importance to the manufacturing chemist, independent of its connection with the whole theory of physical science. Passing over the early and imperfect analyses of Dalton, it has been established by the united labours' of the most accurate experimenters of modern times, that water is always composed of 8 parts by weight of oxygen to 1 of hydrogen; that common salt is always composed of 36 parts by weight (in round numbers) of chlorine to 23 of sodium; that carbonate of lime, whether in the form of marble, chalk, or stalactites, is invariably composed of 22 parts by weight of carbonic acid to 28 of lime, &c. It was by thus ascertaining the relative proportions in which bodies combine chemically by weight, that Dr. Dalton was led to a perfectly simple method of deducing the relative weights of their ultimate chemi- cal atoms. The theory assumes, that in all eases the lowest combining proportion of bodies, whether simple or compound, represents the weight of its particles; and that whenever a body combines with another in two or more proportions, the larger is an even multiple by some whole number of the smaller, as 2 to 1, 3 to 1, 4 to 1, &c.; fractional parts seldom occurring in well- ascertained cases. By inspecting the following Table, it will be seen that the smallest combining ratio of oxygen is 8, com- pared with hydrogen as unity; and that when it com- CHEMICAL SYMBOLS. 65 bines with other elements in larger proportions, they are 16, 24, 32, 40, or some multiple of eight. Chlorine combines with mercury in the ratio of 36, as in chloride of mercury, (calomel,) or of 72, as in the bi- chloride of mercury, (corrosive sublimate,) and so of carbon, hydrogen and other elements. I have adopted the atomic numbers employed by the majority of British chemists in preference to those of Berzelius, chiefly with a view of avoiding the incon- venience of fractions. I have also chosen hydrogen as a standard of comparison for the same reason. Ber- zelius has selected oxygen 100*00 as a standard, on account of its great abundance, and the vast variety of combinations which it forms; while Thomson and Ure have employed oxygen as unity, by which hydro- gen is rendered eight times less, or 0-125: carbon 0'75, sulphur two, mercury 25 or 12i, chlorine 4*5, and so on; both of which are unavoidably attended with frac- tions that are difficult to remember. Dr. Wollaston employed the term chemical equiva- lent, and Sir Humphrey Davy combining proportion, to denote the atom of Dalton. I shall generally use the term atom, or particle, as indicating the smallest che- mical divisions of bodies; and molecule, as a small assemblage of atoms. Berzelius represents the different elementary bodies by the initial letters of their Latin names. Thus, O. denotes oxygen, H. hydrogen, N. nitrogen, S. sulphur, P. phosphorus, CI. chlorine, Br. bromine, I. iodine, F. fluorine, C. carbon, Au. gold, Hg. mercury, Ag. silver, Cu. copper, Pt. platinum, Sn. tin, Pb. lead, Zn. zinc, Si. silicium, Se. selenium, As. arsenic, Fe. iron, Mn. man- 5 66 CHEMICAL SYMBOLS. ganese, Al. aluminum, Mg. magnesium, Ca. calcium, Ba. barium, L. lithium, Na. sodium, K. potassium, (or kalium,) which are the most important. The number of atoms in each element of a com- pound is indicated by figures, as in the following for- mula'. N05, represents one atom of nitrogen and five of oxygen, as in nitric acid: while sulphuric acid, which is composed of three atoms of oxygen and one of sulphur, is denoted by S03. He has in many cases introduced symbols of still more remarkable brevity and conve- nience. For example, the number of oxygen atoms in a compound is designated by dots placed over the letter, which indicates the element with which it com- bines. Thus, the composition of water is represented by the symbol, H; carbonic oxide by C; carbonic acid by C; protoxide of nitrogen by N; binoxide of nitro- gen by N; nitrous acid by N; and nitric acid by N. This is a most important improvement of chemical symbols, when we reflect that oxygen enters into the composition of nearly all compound bodies. Berzelius represents the number of sulphur atoms by commas. Thus H indicates sulphuretted hydro- gen; and H, bisulphuretted hydrogen, &c. He also denotes various compounds by the initial letters of their names. Aq. represents water; Cy. cyanogen; Ni. nitrate of potass; Am. ammonia, &c. It is some- times convenient to denote two atoms of an element by a dash under its symbol. Thus Fe, denotes two atoms of iron and three of oxygen, as in the peroxide of iron. ATOMIC WEIGHTS. 67 TABLE OF ATOMIC WEIGHTS, AND OF THE SYMBOLS BY WHICH THEY ABE BEPEESENTED. Parts by weight. Parts by weight. 8 Oxyg. combine with 1 H. to form......H 9 parts by weight of water. 16 02...................... 1H.................H 17 Binoxide of hydrogen. 8 0 ...................... 6C..................C 14 Carbonic oxide. 16 02 ...................... 6C..................C 22 Carbonic acid. 16 0....................... 16 S...................S 32 Sulphurous acid. 24 03 ...................... 16 S...................S 40 Sulphuric acid. 8 0 ..................... 14 N..................N 22 Protoxide of nitrogen. 16 02...................... 14 N..................N 30 Binoxide of do. 24 03 ...................... 14 N..................N 38 Hyponitrous acid. 32 04...................... UN..................N 46 Nitrous do. 40 0- ...................... 14 N..................N 54 Nitric do. 8 0 ...................... 36 CI................CI 44 Hypochlorous acid. 32 04...................... 36 CI................CI 68 Hypochloric do. 40 05 ...................... 36 CI................CI 76 Chloric acid. 8 0 ..................... 40 K.................K 48 Potassa. 8 0 ...................... 24Na...............Na 32 Soda. 8 0 ...................... 20 Ca...............Ca 28 Lime. 24 03 ...................... 8 Si................Si 32 Silex, silicic acid. 8 0 ...................... 64 Cu...............Cu 72 Protoxide of copper. 16 02 ...................... 64 Cu...............Cu 80 Binoxide of do. 8 0 ......................200 Hg..............Hg 208 Protoxide of mercury. 16 02...................... 200 Hg..............Hg 216 Binoxide of do. 8 0 ......................110 Ag..............Ag 118 Protoxide of silver. 24 Os...................... 32 P..................P 56 Phosphorous acid. 8 0 ...................... 28 Mn...............Mn 36 Protoxide of manganese. 8 0....................... 28 Fe...............Fe 36 Protoxide of iron. 24 03 ...................... 56 Fe2..............Fe 80 Peroxide of iron. 8 0 ...................... 12 Mg.............Mg 20 Magnesia. 68 ATOMIC WEIGHTS. Parts by weight. Parts by weight. 8 0 ...................... 14A1...............Al 22 Alumina. 24 0....................... 12 C.................C2 36 Oxalic acid. 36 CI ...................... 1H...............HC1 37 Hydrochloric acid. 126 1 ...................... 1H................HI 127 Hydriodic acid. 16 S ...................... 1H..................H 17 Sulphuretted hydrogen. 32 S2 ...................... 1H..................H 33 Bisulphuretted hydrogen. 6C ...................... 2 H2...............CH2 8 Light carburetted do. 12 C2...................... 2 H2.............CJI, 14 Olefiant gas. 12 C2...................... 14 N...............C2N 26 Cyanogen. 36 CI...................... 24 Na............NaCl „GO Chloride of sodium. 24 C4...................... 4H...............C4H4 28 Etherine (En). 36 C6 ...................... 3 II...............C6H3 39 Bicarburet of hydrogen. 36 C6...................... 5H...............C6H5 41 Naphtha. 60 C10...................... 4H..............C10H4 64 Naphthalin. 90 C15...................... 4H..............C15H4 94 Paranapthalin. 14 N-■-■.*.'.................... 3 11................NH3 17 Ammonia. 8 0......................lOOAu.............AuO 108 Protoxide of gold. 8 0...........„.-........ 104 Pb.............PbO 112 Protoxide of lead. 8 0 ....................., 96 Tt..............PtO 104 Protoxide of platinum. 24 0 ...................... 72 Bi................Bi 80 Oxide of bismuth. 26 Cy......■;..............*. 1 H..............HCy 27 Hydrocyanic acid. 26 Cy...................... 8 0.................Cy 34 Cyanic acid. 26 Cy...................... 40 S................CyS 66 Sulphocyanic acid. 26 Cy....................... 36 CI.............CyCl 72 Chlorocyanic acid. 14 C2H2.................... 9Aq...........C4H5H 23 Alcohol. 28 C4H4.................... 9Aq...........C4H4H 37 Ether. 22 C....................... 17NH3............NH3C 39 Carbonate of ammonia. 44 C,...................... 48 K................KC, 92 Bicarb, of potassa. 54 N ...........*'.......... 48K................KN 102 Nitrate of potassa. 37 C1H.......•............. 17 NH3........NH3HC1 54 Muriate of ammonia. ATOMIC WEIGHTS. 69 Parts by weight. Parts by weight. 37 C1H..................... 28 En..........EnHCl 65 Muriatic ether. 40 S ...................... 32 Na.............NaS 72 Sulphate of soda. 40 S ...................... 20 Mg.............MgS 60 Sulphate of magnesia. The lowest numbers in the first two columns of the above table down to oxide of bismuth, represent the atomic weights of simple bodies, or multiples of them; while the numbers of the third column, including all those from hydrocyanic acid in the first and second columns, denote the weights of compound particles or molecules. The recent progress of chemical science has led to the discovery of some apparent exceptions to the law of multiples. The following examples have been in- dicated by Dr. Turner. The peroxide of iron is com- posed of 12 parts oxygen to 28 of iron. Oxygen combines with manganese in the same ratio, forming a sesquioxide, from the Latin word sesqui, one and a half. This difficulty has been evaded by supposing that two equivalents or atoms of one substance unite with three, five, or more atoms of another—that if one atom of iron unite with one of oxygen, and another com- pound be formed of two atoms of iron to three of oxygen, the latter would be in the proportions of one and one-and-a-half, and so of other like cases. When one atom of oxygen unites with two of lead, they form a ternary atom of what is termed a dinoxide, or a suboxide. Dr. Turner lays it down as a general rule, that when a metal forms two oxides, the oxygen of which is in the ratio of one to one-and-a-half, the first is usually the protoxide, and the second a com- pound of two atoms or equivalents of the metal to 70 ATOMIC WEIGHTS. three of oxygen, as in the oxides of iron, nickel and chromium. It is highly probable, that a more accurate and re- fined mode of analysis will prove hereafter that several of the present atomic numbers do not repre- sent the true weights of the atoms. But it is also probable, that in nearly all cases where this is not so, they represent either multiples or submultiples of them. There are other exceptions to the law, that all bodies combine chemically in fixed or definite propor- tions by weight. Many of the metals unite with each other in all proportions when converted into the liquid state by heat, or electricity, forming alloys. Water combines with alcohol, and with the strong acids in unlimited proportions; and it will be shown, further on, that the ratios in which sugar, numerous salts, oily, resinous and gelatinous substances, unite with water by chemical solution, are determined by the temperature of the water, solubility of the bodies, &c. But in all such cases, the affinity is comparatively weak, and the changes of properties consequent on combination inconsiderable. THEORY OF VOLUMES. In the year 1805, Gay-Lussac and Humboldt proved by numerous experiments, that water is always com- posed of two measures by volume of hydrogen to one of oxygen, as had been previously shown by Higgins. By following up the investigation, Gay-Lussac found, that many other gases, both simple and compound, THEORY OF VOLUMES. 71 unite with each other in very simple ratios by volume; that one volume of A unites with one, two, three, or more volumes of B; and that the bulk of the resulting compounds always bears a very simple and definite ratio to that of its constituents, or to that of one of them.* This lawr has been extended by Dr. Prout and others to vapours, and even to the supposed vapours of bodies which do not exist in the elastic form, except when united with the permanent gases. For example, if carbon be burnt in 100 cubic inches of oxygen gas, (the weight of which is 34*60 grains,) an equal vo- lume of carbonic acid is formed, (which weighs 47*26 grains;) showing that 12*66 grains of carbon have been dissolved and chemically united with 100 cubic inches of oxygen, and thus converted into the elastic state; and that two atoms of oxygen have united che- mically with one of carbon. In this way it was found, that the specific gravity of carbon vapour is "416, compared with oxygen 1*111, as determined experi- mentally by Dr. Thomson.-j- It was also found that * Memoires D'Arcueil, 1809, tome ii. f Mitscherlich has maintained recently, that the specific gravity of carbon vapour is double "the estimate of Prout. He observes, that as it cannot be determined by direct experiment, it ought to be deduced from analogy—for example, if carbonic acid consisted of equal volumes of carbon vapour and oxygen, he maintains that they ought to combine without any condensation, because in all other cases, when equal volumes of gaseous bodies unite chemi- cally, there is no contraction, as in binoxide of nitrogen, hydro- chloric acid, hydriodic acid, kc. He thinks that condensation never takes place, unless the combining volumes are unequal; therefore, that carbonic acid is composed of one volume of oxygen to half a volume of carbon vapour, (the specific gravity of which 72 THEORY OF VOLUMES. when sulphur is chemically combined with oxygen by combustion, an equal volume of sulphurous acid is formed, the specific gravity of which is 2*222, or just double that of oxygen: therefore it is evident, that 100 cubic inches of sulphur vapour, as it exists in sul- phurous acid, are of the same weight as 100 cubic inches of oxygen. Such facts led to a new mode of ascertaining the atomic weight of bodies, and shed much additional light on the ultimate constitution of matter. For example, if sulphurous acid be composed of two atoms of oxygen to one of sulphur, it follows, that the atom of sulphur must be just 16 times that of hydrogen, and double that of oxygen. By pursuing this method of investigation, Dr. Thomson arrived at the conclusion, that carbon, oxy- gen and sulphur, are even multiples of hydrogen without fractions; (Records of Science, March, 1836;) whereas Berzelius makes the atomic weight of carbon 0-7643S; that of sulphur 2*01165; and sulphurous acid 4-01l6o, compared with oxygen 100. Without pretending to decide which of these illus- trious experimenters has approximated most nearly to the truth, it would appear from all the lights of modern analysis, that when the atomic numbers shall have been ascertained with perfect accuracy, they will be found to constitute very simple ratios. It is ob- vious, that if the atomic weight of carbon is six times that of hydrogen, oxygen eight, and sulphur 16, the would be *832, instead of *416, or 12 times that of hydrogen ) But it is not very material whether we regard the specific gravity of carbon vapour as six or twelve times that of hydrogen, as either number is in accordance with the law of multiple ratios THEORY OF VOLUMES. 73 above and many other equivalent numbers of Berzelius cannot be correct; which is also the case with those of Dr. Turner, who has adopted most of them. Whether this be true or not, the simplity of the atomic theory, as proposed by Dalton, and improved by later che- mists, has been greatly diminished by the number of decimals which Berzelius has affixed to his atomic weights. I concur most fully with Professor Forbes, in the hope that philosophers may dismiss that super- fluity of decimal places which has been recently intro- duced into several branches of physical science. They have already tended to shake the confidence of some, as to the soundness of the atomic theory. The important discovery of Gay-Lussac has been so far extended and verified by the united researches of modern chemists, that it may be regarded as an estab- lished law, that all gaseous bodies combine with each other in definite proportions by volume, and in accord- ance with the law of multiples. The following table will show the connection be- tween the specific gravity of gaseous bodies and their atomic weights. The first column of figures repre- sents their specific gravities, compared with common air as a standard, deduced from the experiments of Thomson, Prout, Berzelius, Dulong, Gay-Lussac, Ure, Dumas and Mitscherlich, under the ordinary pressure of the atmosphere, and at the temperature of 60° F. with the exception of phosphorus, sulphur, arsenic, and such other bodies as require higher temperatures to convert them into the gaseous state. The second column exhibits the number of grains in 100 cubic inches; while the third column gives the relation of 74 SPECIFIC GRAVITY OF GASES. their specific gravity to that of hydrogen as unity; and is obtained by dividing the numbers in the first column by the specific gravity of hydrogen. No. of grains in Sp. gr. corn- Gases and vapours. Specific gravities. 100 cubic pared with inches. hydrogen. Atmospheric air..................... 1-000 .............. 3101............ 15 Chlorine .............................. 2-500 CI............ 7620............ 36 Iodine vapour........................ 8-716 1............. 265*70............ 126 Bromine do......................... 5-555 Br........... 16929............ 80 Carbon vapour...................... -416 C............ 12-68............ 6 Carburetted hydrogen............. -555 CH2.......... 17-30............ 8 Olefiantgas........................... -981 C2H2......... 29-90............ 14 Etherinevapour..................... 1-963 C4H4......... 61-13............ 28 Carbonic oxide....................... -972 CO or C..... 29-02............ 14 Carbonic acid........................ 1-527 C............ 47-26............ 22 Aqueous vapour..................... -625 H............ 19-05............ 9 Alcohol vapour...................... 1-620 C4H602...... 49-37............ 23 Ether do..................... 2-570 C4H50...!.... 79-67............ 37 Cyanogen.............................. -j.g^ CN.......... 5(J.47............ 2g Sulphurous acid..................... 2-222 S... 67-7^ i>tn °f a gram- ^et, if the Igneous ether which surrounds these molecules be a material agent, its particles must be inconceivably smaller. We can no more measure the ultimate minuteness of this spi- ritual and fiery essence than we can comprehend the infinitude of space and duration. We are less amazed on contemplating the vast cycles of geology and as- tronomy, than by attempting to follow nature in her smallest proportions. We know not the absolute weights of atoms, but we know from the preceding facts, especially those on which the law of multiples is founded, that they vary in size. We know not the forms of ultimate atoms, nor whether they are all of the same density; but as all bodies in the liquid state are disposed to assume a round form, we may conclude that they are spherical, and that the various forms of crystalline bodies are determined by the modes in which their particles are grouped and arranged. LATENT CALORIC IN DIFFERENT BODIES. 85 RELATIVE QUANTITIES OF CALORIC IN DIFFERENT BODIES. This is one of the most difficult problems in Phy- sical Science, the very elements of which have yet to be unfolded. If it be true, that the whole material world is composed of particles or atoms which vary in size, and that they are surrounded by an active and ethereal principle, which is immediately connected with all their properties and changes, it is obviously an object of primary importance to ascertain the rela- tive proportions of each, and the laws of their ope- ration upon each other. Without hoping fully to develope a subject which has hitherto baffled so many able men, I shall endeavour to show, that the methods which have been employed for the purpose of estimat- ing the constituent caloric of bodies are fallacious; the application of which, to the phenomena of combus- tion, respiration, evaporation and solution, has been a constant source of error. It has been known ever since the time of Dr. Black, that different quantities of caloric are required to pro- duce the same temperature, in equal weights or vo- lumes of different bodies; that one pound of water re- quires about double the quantity of caloric to raise its temperature 50° or 100°, that one pound of oil does; and that on cooling an equal number of degrees, w^ater gives out twice as much caloric as an equal weight of oil: from which it was inferred, that the same difference existed between the latent caloric of oil and water at all temperatures, down to their absolute zeros; in other words, that the whole amount of caloric in water is double that of oil. 86 LATENT CALORIC IN DIFFERENT BODIES. This difference of capacity for caloric, as it was termed by Dr. Black and his disciples, which was found to exist between all other bodies, has been re- garded by Crawford, Kirwan, Lavoisier and Laplace, Leslie and Dalton, as a measure of the relative quan- tities of caloric which is chemically combined with them, and has been generally termed specific heat. But it is now universally conceded, that the whole subject is involved in profound obscurity, and that nearly all the experiments connected with specific heat are at variance with each other, which alone is a sufficient proof that the truth has not yet been fully ascer- tained. According to the above mode of deducing the amount of caloric in bodies, water should contain more than an equal weight of any other known liquid or solid, as it gives out a larger quantity on cooling an equal number of degrees. If capacity or specific heat were a true criterion of what they contain, the latent caloric of ether, alcohol, oils, wood, coal, and all those bodies which are known to be the most combustible, would be comparatively low. But this idea is refuted by the amount of hydrogen that enters into the com- position of such bodies; and by the fact that hydrogen gives out more caloric, during combustion, than an equal weight of any other known substance Ever since the first discovery of hydrogen, it has been re- garded as an exceedingly igneous substance The older chemists termed it inflammable air At one time, Kirwan maintained that it was identical with the phlogiston of Stah], which was in realitv the un- discovered latent heat of Black. LATENT CALORIC OF HYDROGEN. 87 These vague hypotheses were superseded by the more definite views of the celebrated Lavoisier, who proved that hydrogen is composed of a ponderable base, united with an igneous fluid, which he termed caloric, and which may be separated from each other by chemical action. According to the experiments of Dr. Dalton, caloric enough is given out during the combustion of one pound of hydrogen gas to melt 320 lbs. of ice. According to Crawford, 480 lbs. of ice are melted by the heat given out during the combustion of one pound of hydrogen; which Dr. Thomson thinks is about as far beyond the truth as Dalton's estimate falls short; and that about- 400 pounds may be regarded as the mean quantity of ice that will be melted during the combustion of one pound of hydrogen. If then we admit with Dr. Black, that 140° of caloric are required to melt one pound of ice, 56,000° of heat must be given out during the combustion of one pound of hydrogen. It must however be observed, that during the pro- cess, two volumes of hydrogen combine chemically with one of oxygen; or that one atom of oxygen combines with one of hydrogen; and as the atomic weight of oxygen is eight times that of hydrogen, eight pounds of oxygen must unite with one of hydrogen, making nine pounds of water. From which it is evident, that a certain proportion of the caloric disengaged, is afforded by the oxygen; for we find that the volume and elastic force of both gases are destroyed on as- suming the liquid form. If the volume of water were diminished in the same ratio at all temperatures, by the abstraction of caloric, S8 IMPORTANCE OF OXYGEN AND HYDROGEN. we might arrive at a proximate estimate of the abso- lute quantity of caloric which it contains. For ex- ample, it is known that water is diminished about one twenty-second of its volume on reducing its tempera- ture 180°, viz., from 212° to 32°. If then it be assumed that the pores of water are 20 times greater than its solid atoms, (and Newton supposed that they were double this estimate,) it would require the abstraction of 3600°, to deprive it of all its caloric, provided the volume continued to diminish in the same ratio. But as it has been found that below the freezing point of mercury, its volume contracts in a greater ratio than at higher temperatures, it is probable that the same thing may be true of other bodies. When we consider the vast abundance and import- ance of oxygen and hydrogen in the economy of nature, it becomes obvious, that a correct mode of as- certaining the relative quantities of caloric which they contain would throw new light on all the relations of ethereal and ponderable matter. All the waters of the earth are composed of oxygen and hydrogen, in the proportions of eight to one by weight. When converted into vapour by solar caloric, and diffused through the atmosphere, water is connected with all the phenomena of meteorology. As a mechanical agent, running water is perpetually wearing down mountains, hills and elevated plains, and transporting them to valleys, lakes and seas. As a chemical agent, water is slowly but constantly dissolving rocks, salts and metals, which are again precipitated in the crystalline or solid state. It forms a large proportion of all animal and vegetable bodies; EXPERIMENTS OF DULONG AND PETIT. 89 also, of many salts and rocks. As a constituent of the, atmosphere, oxygen is indispensable to all the phenomena of vitality. It enters largely into the composition of nearly all acids, alkalies, native ores or metallic bases; and constitutes about one-fourth of the earth's crust. The importance of carbon is not less manifest; forming, as it does, the basis of all organic matter. In combination with hydrogen, it constitutes the prin- cipal portion of the food by which we are nourished, and of the fuel by which we are warmed and kept alive during winter. According to the analysis of Gay-Lussac, and of Dr. Prout, it forms about one-half of lignin, or perfectly dried woody fibre. It is the chief ingredient in those immense subterranean forests of ancient vegetation, termed fossil coal; and which, perhaps, exceed in quantity an hundred fold, all the trees and plants that now cover the surface of our planet. After all attempts to ascertain the specific heat of bodies had proved discordant and fallacious, a series of experiments was undertaken by MM. Dulong and Petit, the object of which was to discover what rela- tion existed between the atomic weights of various bodies and their capacities for caloric. The result of their researches was, that the specific heat of water was nearly three times that of sulphur and several of the metals, in which it was about one-half less than in some other elements; four times less than in others again, such as phosphorus and iodine; while in carbon it was nearly six times less than in water, or as 0*169 to 1*000. They also found that there was no uniform 90 EXPERIMENTS OF THOMSON. relation between the quantities of caloric evolved during the combustion of different bodies, and the specific heat of their resulting products, the capacity of which was often the same before as after the pro- cess. Yet they maintained that the atoms ofedt simple bodies have the same specific heat, because when they vary, it is in multiple or submultiple r/itios, or nearly so; and that the atomic equivalents of all bodies which do not accord with this assumed law, ought to be altered and made to agree with it. (Ann. de Chlm. et de Phys. tome x.) The recent efforts of Dr. Thomson to verify the hypothesis of Dulong and Petit, have not been suc- cessful, as will appear from the following table, repre- senting the atomic weights of twenty-six simple sub- stances, (compared with oxygen as unity,) their spe- cific heat, and the resulting product. He observes, that '-'if the specific heat of bodies multiplied into their atomic weights be a constant quantity, it will follow that every simple atom is surrounded with the same quantity of heat." (Records of Science, April, 1S36.) l ' „ , Atomic weight. Specific heat. Product. Carbon.............. n.7- „„,„ „.,. .............................. ° <° 0-257 0-192 Silicon................. i _ in_ ., ........................... 1 0*187 0-187 Aluminum ............ 1,9c n-irr. n ............................ 1 25 0-150 0187 &:::::=...................;, ™ •*» »,„ • ........................... 45 0-827 0-372 fT107ne................................... 10 0-472 0-437 ^dr°gen................................. 0-125 3-293 0-412 iTr.................................. W5 °-269 0-472 Sulphur .......... o A . .............................. 2 0-188 0-376 Arsenic............ A ~,. Antimony...... ........................ ^ ™81 °™ Tellurium........ ........................ ! °/°47 9^6 Iron..... ......................... * 0091 0364 .................................. 3-° 0-110 0-385 EXPERIMENTS OF THOMSON. 91 Atomic weight. Specific heat. Product. Nickel...................................... 3-625. 0-103 0-375 Zinc........................................ 4-125 0-927 0-383 Lead....................................... 13 0029 0-377 Tin.......................................... 7-25 0057 0370 Copper..................................... 4 0-095 0-376 Bismuth................................... 9 0040 0-360 Mercury..'................................. 12-5 0-029 0-362 Gold........................................ 12-5 0-029 0-373 Platinum................................. 12 0 310 0-372 Cobalt...................................... 3-25 0-150 0487 Phosphorus............................... 2 0-385 0-770 Silver....................................... 13-75 0-056 0-770 Iodine...................................... 15-75 0-89 0-401 Mean of the whole.....................................0-375 Dr. Thomson maintains, that if the atoms of car- bon, silicon and aluminum were doubled, and those of phosphorus and silver reduced one-half, their specific heat would be about the same as the mean of the whole; and that the other deviations from this ave- rage ought to be referred to inaccurate experiments. But if, for the sake of argument, we admit his asser- tion, it would follow that an equivalent of water con- tains 5*85 times more caloric than one of carbon, sili- con, or aluminum; 4*76 times more than an atom of oxygen; above two and a half times more than one of hydrogen, nitrogen, iodine, or cobalt; about 40 per cent, more than one of phosphorus or silver; for the specific heat of water is 1*125 when multiplied by its atomic weight. And that capacity is no measure of the relative quantities of caloric in different bodies, would appear from the experiments of Haycraft, De la Rive and Marcet, who found that equal volumes of all gases are equally heated and cooled by equal addi- tions and subtractions of caloric. 92 EXPERIMENTS OF DULONG AND HESS The following experiments of Dulong and Hess, per- formed with a view of ascertaining the relative quan- tities of caloric evolved during the combustion of seve- ral gaseous bodies and a few metals, will be found more instructive. /. • Grammes of Substances employed. ' om\c com~ water raised VOSltlOTla -| ,-, . T r 1° centigrade. 1 Litre of Hydrogen................................................... 3,102 1 " Light carburetted Hydrogen.... CH2................. 9,587 1 " Olefiantgas......................... C2H2................. 15,338 1 " Carbonic oxide..................... CO..................... 3,130 1 " Cyanogen.......................... NC2................... 12,269 1 " Alcohol vapour..................... C4H602.............. 14,375 1 " Ether vapour....................... C,H50............... 32,254 1 " Turpentine vapour................ C10H8................. 70,607 Carbon vapour equal to 1 litre in the gaseous state............ 7,858 1 Litre of Oxygen gas with Iron.................................... 6 216 Tin.................................... 6,508 Antimony............................ 5,552 Zinc................................... 7,577 Cobalt................................. 5 721 Nickel.................................. 5^333 Mean of the six metals............................. g 151 To these may be added the results of M. Despretz, who found, that during the combustion of one pound of different substances, caloric enough was evolved to raise the following quantities of water from 32° to 212° F. Substances employed. r, . . iv, .f tt ■, Quantities of water. lo.or Hydrogen................. J " Charcoal from wood..!1!!.".!"!.T.!!.''.'.'.'.............. 23U-4 lbs. " Olive oil........... „ w ........................................... 90 " wax........................... " Ether......................................................... °" " Pure charcoal................... " Alcohol.......... .......................... 78 ......................................... 67-5 ON THE COMBUSTION OF GASES. 93 Substances employed. Quantities of water. 1 lb. of Bituminous coal........................................... 60 lbs. 1 " Baked wood................................................ 36 1 " Wood with 20 per cent, water........................ 27 1 " Turf.mean................................................. 27 From the table of Dulong and Hess we perceive, that during the combination of one atom of oxygen with two of hydrogen and one of carbon, as in light carburetted hydrogen, about three times more caloric is evolved, than by the combustion of the same volume of pure hydrogen; and that one atom of carbon vapour, as it exists In carbonic oxide, gives out almost precisely the same amount of heat as an equal volume of hydrogen. It would also appear from the same table, that during the chemical union of oxygen with the above metals, and its conversion into the state of solid oxides, about twice as much caloric is evolved as by the same bulk of hydrogen. So that if nearly the whole is afforded by the oxygen, it would be about eight times less than is given out by the same weight of hydrogen, corre- sponding with the difference between their atomic weights; for hydrogen is sixteen times lighter than oxygen: from which it would follow, that during the combination of oxygen with carbon and hydrogen, the atom of each gives out the same quantity of heat. We further perceive, that during the combination of oxygen with two equivalents of carbon, and two of hydrogen, as in the combustion of olefiant gas, above four times as much caloric is evolved as by the union of one atom of oxygen with one of hydrogen; and that, although the coincidence is less exact between the quantities of heat evolved and the atomic consti- 94 THE REFRACTIVE POWER OF BODIES tution of the remaining compound gases, it is suffi- ciently so to prove that hydrogen and carbon contain more caloric around their atoms than an equal weight of oxygen; and that equal volumes of the gases do not afford the same quantities of caloric. It must, however, be admitted, that the results of Despretz are at variance with those of Dulong and Hess, as he found that alcohol, ether, and other compounds of car- bon and hydrogen, afforded much less caloric than in the gaseous state. Let us next inquire whether the power of bodies to refract light may not afford a measure of the relative quantities of caloric around their particles. It was suggested by Newton, at the close of both the Optics and Principia, that the power of bodies to reflect, re- fract and inflect light, is in proportion to the quantity of ether that covers their surface and surrounds their particles; which ether he also regarded as the cause of cohesion, elasticity, solution, capillary attraction and gravitation. For example, he found that in spirit of wine, spirit of turpentine, olive oil, linseed oil, cam- phor and amber, which are highly inflammable bodies, the power of refracting light was two or three times greater, in respect to their densities, than in salts, rocks, or any other stony concretes, which are less combustible: and as it was higher in the diamond than in any other body which he tried, he arrived at the conclusion that it was a sulphureous or unctuous body coagulated, and would be found inflammable. (Optics, Book ii., pp. 240 and 200.) That there is at least a nucleus of truth in this hypothesis of Newton, would appear from the nume- A MEASURE OF THEIR CONSTITUENT CALORIC. 9-5 rous experiments of Brewster, Wdlaston, Biot, Arago and Dulong, who have found that in phosphorus and sulphur, as in all those bodies which are composed chiefly of hydrogen and carbon, with various propor- tions of oxygen and nitrogen, the power of refracting light is much greater in proportion .to their specific gravities, than in any other bodies; and we have the most decisive proof that they contain proportionally more caloric around their particles, as might naturally have been inferred from all the phenomena of their combustion, volatility, and tendency to assume the gaseous state. But, so far as I am informed, no one has attempted to ascertain what relation exists be- tween the latent caloric of bodies and their refractive powers, except my friend Mr. Dyar, whose views on the subject, if ever carried out, have not been pub- lished. The most important experiments on the refractive power of gaseous substances with which I am ac- quainted, are those of M. Dulong, published in the Annates de Chlmie et de Physique, xxxi. 154; as in the following table, which represents their refractive power and specific gravity, at the same temperature and pressure of the atmosphere,—to which I have added their atomic composition. TABLE I. Refractive Power. Atmospheric air...................... 1-000 ..... Oxygen....................... -924 ..... Hydrogen.................... -470 ..... Nitrogen..................... 1-020 ..... Deutoxide of Nitrogen............. 1-030 N02 Protoxide of Nitrogen............. 1*710 NO. Specific Gravity. ....... 1-000 ....... 1-026 ...... -685 ....... -976 ....... 1-039 ....... 1-527 96 EXPERIMENTS OF DULONG, AND THE Refractive Power. Specific Gravity. Carbonic Oxide...................... l*ir>7 C0 ....................... •)T- Carbonio Acid........................ 1-626 C02....................... 1*524 Marsh Gas............................ 1*504 CH2........................555 OlefiantGas........................... 2-302 C2H2..................... -980 Hydrocyanic Acid................... 1*531 NC2H.................... *944 Hydrochloric Acid.................. 1527 HC1...................... 1*245 Ammonia............................. 1*309 NH3..................... -691 Chlorine............!............'...... 2-623 .......................... 2-470 Cyanogen.............................. 2-832 NC2....................... 1.818 Sulphuretted Hydrogen............ 2-187 HS....................... 1*178 Sulphurous Acid..................... 2-260 S02...................... 2-247 Hydrochloric Ether................. 3-720 C4H5C1................... 2-234 Phosgene Gas........................ 3-936 CO.C1.................... 3-442 Sulphuret of Carbon............... 5-110 CS2....................... 2-644 Ether.................................... 5-197 C,H50.................... 2-580 From the above table we perceive, that there is no uniform relation between the refractive power of gases and what is called their specific heat, as admitted by M. Dulong; while it is equally obvious, that it is not in proportion to their specific gravity, nor to the size of their particles. It will be observed, however, that the refractive power of oxygen is nearly double that of hydrogen, which is sixteen times lighter: it there- fore follows, that if their refractive powers be a mea- sure of their latent caloric, hydrogen must contain about eight times more than an equal weight of oxy- gen ; corresponding with the difference between their atomic weights and the relative quantities of caloric they evolve during the process of combustion. It is much to be regretted that we have no means of ascer- taining the refractive power of carbon, separately, in the gaseous state. But as it is about three times higher in carburetted hydrogen, and four times greater in de- fiant gas than in simple hydrogen, we are authorized to AND THE CONCLUSIONS TO WHICH THEY LEAD. 97 conclude, that a pound of hydrogen contains six times more caloric than the same weight of carbon; or that the particles of each are associated with the same quantities of caloric. And as the refractive power of nitrogen is 2*17 times that of hydrogen, the specific gravity of which is fourteen times less than that of nitrogen, it follows that hydrogen must contain 6*45 times more caloric around its particles than the same weight of nitrogen. Nor can there be a rational doubt, that if the experi- ments were rigidly accurate, the refractive power of hydrogen would be just eight times that of oxygen, and seven times that of nitrogen; consequently, that the true atomic weight of nitrogen is seven compared with hydrogen, as maintained by Dalton and Berzelius, instead of 14, as supposed by the majority of chemists. And if such be the fact, it follows, that hydrogen, car- bon, nitrogen and oxygen, (which are by far the most important of all the elements, because the most active, and because they are the principal constituents of or- ganized bodies,) contain the same amount of caloric around their chemical atoms.* * There is, therefore, reason to believe, that when the refractive power of all bodies shall be rightly ascertained, we shall have a more certain method of determining their atomic equivalents, many of which are acknowledged to be doubtful; and that we shall be able to correct errors in regard to the chemical composition of bodies, that have arisen from imperfect analyses. It must, how- ever, be admitted, that in the present state of science, the refrac- tive power of compound gases, liquids and solids, does not always correspond with that of their constituents in the separate state; a circumstance which may be owing in part to imperfect experiments, and partly to the fact, that during nearly all chemical combinations 7 98 EXPERIMENTS OF BREWSTER. A still more direct and cogent proof that the re- fractive power of bodies is in proportion to the amount of caloric around their particles is, that it is higher in water than in ice, higher in fluid than in solid sul- phur, as it is in all those bodies which are composed chiefly of carbon and hydrogen, such as alcohol, ether, the volatile and fixed oils, than in water, the specific gravity of which is greater, as will be seen from the following table, taken chiefly from the experiments of Sir David Brewster. It will also be seen, that it is higher in the diamond, which consists of pure carbon, (condensed by an immense pressure,) than in any other solid body, if we except phosphorus and sulphur, both of which are highly inflammable, and afford very large quantities of caloric by combustion. TABLE II. REPRESENTING THE REFltACTIVE POWER AND SPECIFIC GRAVITY OF DIFFERENT CLASSES OF BODIES IN THE LIQUID AND SOLID STATES. Refractive Power. Specific Gravity. Water......................................... 1-335 1-000 Ice............................................. 1-307 -950 Alcohol..........................'............. 1-372 -794 Ether......................................... 1-358 -700 and decompositions, caloric is either absorbed or given out, as will be shown hereafter. But as we have found that in hydrogen, car- bon and oxygen, it coincides so nearly with the quantities of caloric they give out during combustion; and is nearly the same in several compound gases, when reduced from the refractive power of their elements, the subject is one that merits the most careful investiga- tion. For if there be no uniform ratio between the refractive power of bodies and their specific gravities, while in the best-ascertained cases it accords with the quantities of caloric they afford by com- bustion, it is difficult to resist the conclusion that caloric is the cause of refraction, as it is of attraction and repulsion. EXPERIMENTS OF BREWSTER. 99 Refractive Power. Specific Gravity. Melted Beeswax........................... 1-450 -960 " Spermaceti........................ 1-470 -940 Oil of Lavender............................ 1-457 -877 " Caraway............................. 1-491 -940 " Turpentine.......................... 1-475 -890 " Camphor............................. 1-487 -988 " Lemon................................ 1-481 -847 " Olives................................. 1-470 -910 Castor Oil.................................... 1-490 -969 Melted Sugar............................... 1-555 1-500 Gum.......................................... 1-554 1-400 Acetic Acid................................ 1-396 1-062 Malic Acid.................................. 1-395 1-090 Nitrous Acid.,.............................. 1-396 1-450 Nitric Acid.................................. 1-406 1-480 Sulphuric Acid............................. 1-440 1-840 Phosphoric Acid........................... 1-544 2-687 Rock Salt.................................... 1-557 2-600 Quartz........................................ 1-548 2-600 Garnet....................................... 1-515 4-000 Calc Spar.................................... 1-665 2-700 Arragonite................................... 1.693 2-800 Sapphire, blue.............................. 1-794 4-200 Arsenic....................................... 1-811 5-900 Calomel....................................... 1-970 7-200 Carbonate of Lead........................ 2084 6-400 Sulphur, native............................. 2-038 2033 melted............................ 2-148 1-990 Phosphorus................................. 2-224 1-770 Diamond..................................... 2-470 3 591 Chromate of Lead......................... 2-926 6-000 Mercury..................................... 5-000* 13-500 * The refractive power of mercury was determined by M. Arago from its power of reflecting light. But it was supposed by Newton that both refraction and reflection are owing to the same cause, and that the one is a measure of the other. Should this hypothesis be well founded, we have an easy method of ascertaining the refractive power of solid and opaque bodies. That M. Arago has very closely approximated the truth in regard to mercury, would appear from the high refractive power of calomel, as determined by Brewster. And that it is nearly the same in lead as in mercury, would appear 100 THEORY OF ISOMORPHISM AND DIMORPHISM. It has been recently discovered by the researches of chemists, that many bodies composed of different ele- ments, the atoms or particles of which vary in size, exhibit the same crystalline form, as in the phenomena of Isomorphism, from lao^, equal, and ftoptpy, shape.* It has been also ascertained that other bodies composed of the same elements of ponderable matter in the same from the high refractive power of its compounds, as in the car- bonate and chromate of lead; while it is well known that gold, platinum, silver, iron, tin, zinc and other dense metals, reflect a much larger proportion of light (when smoothly polished) than the same surface of rocks, gems, glass, or the lighter metals; and the latter more than water, alcohol, ether or the oils. It would, therefore, appear that the denser metals contain from two to four times more caloric around their particles than an equal bulk of water, but very much less than an equal weight of water, sulphur, phosphorus, or any of the compounds of oxygen, carbon, hydrogen and nitrogen. * In regard to the rationale of isomorphism, Mitscherlich laid it down as a law, that "the same number of atoms combined in the same way, produce the same crystalline form, which is deter- mined by the number and position of the atoms, independent of their chemical nature." According to this view, the arseniate and phosphate of soda, the protoxides of iron, zinc, copper, nickel, manganese and some other salts, are of the same form, because composed of the same number of particles arranged in the same manner. But the atomic weight of arsenic acid is one hundred and fifteen, and of phosphoric acid, seventy-two. The seleniate of soda is also identical in form with the sulphate of soda, although the atomic weight of selenic acid is sixty-four, and that of sulphuric acid, forty. It is therefore not easy to comprehend why they pro- duce the same form on uniting with soda, without supposing that sulphuric acid contains a larger amount of caloric, around its par- ticles, the volume of which would be thus increased, so as to approximate the magnitude of those of the selenic acid. OBSERVATIONS OF SCORESBY. 101 proportions, assume totally different crystalline forms, as in the phenomena of dimorphism. For example, it was found by Scoresby, that in the arctic regions water congeals in an almost endless variety of geometrical figures, of which he enumerates five classes; the lamellar, the stelliform, (which is the most general, and occurs chiefly when the temperature is near 32°;) the regular hexagon, which becomes thin- and diminishes in size as the cold increases; aggrega- tions of hexagons, which occur chiefly at low tempe- ratures; and lastly, combined ions of hexagons with spines or radii. (Arctic Regions, vol. i. p. 432.) It is also re- lated by Dr. Daniel Clark, that on one occasion at St. Petersburg, when the temperature of the air was five degrees below the freezing point, every particle of snow which he examined consisted of a wheel or star, with six equal rays, bounded by circumferences of equal diameters. They all had the same number of rays branching from the centre; and were about the size of a pea divided into two equal parts. (Travels in Russia.) When this subject is better understood, it will be found that those crystals of snow which are found at the same time, in still weather, and at the same tempe- rature, have generally the same form; but when pro- duced at different times, and at different temperatures, they exhibit different forms; of which Koenitz thinks there are several hundred; and many of which he has observed that were not figured by Scoresby. (Meteor- ology, p. 131.) It is therefore clear, that the form of crystals depends on the arrangement of their particles, and not on their essential nature. But if it be a fact that caloric Is the agent which regulates the distance 102 OBSERVATIONS OF SCORESBY. of atoms or particles from one another, and causes all their movements, whether of union or separation, it must obviously determine the various modes of their arrange- ment, whether in the solid, liquid or gaseous states. And as the atomic composition of water in every state is the same, it is impossible to comprehend why it should assume various crystalline forms, as observed by Kep- ler, Cassini and Scoresby, without admitting that its particles are surrounded with different quantities of caloric, on assuming these different forms.* * The various crystalline forms are now generally arranged in six divisions or systems, as in the following classification by Gustav Rose: 1. The cubic or tessular. 2. The square prismatic, (in which the lateral edges, like the terminal planes, are parallel.) 3 The rhombohedric. 4. The right prismatic. 5. The oblique prismatic. 6. The doubly oblique prismatic. In all crystalline bodies the form is angular, and the arrangement of their particles rectilinear. In those of which all the sides and angles are alike, the expansion by caloric is equal in all directions, as in the cube, the regular octohedron, and the rhomboidal dodeca- hedron ; and the refraction of light is single, when they are of uni- form temperature and density, as it is in the transparent gases, vapours, liquids and glass. But in the square prismatic and rhom- bohedric classes, the expansion by caloric is dissimilar in two direc- tions ; while in the right prismatic, the oblique prismatic, and the doubly oblique prismatic, it is dissimilar in three directions. And when a ray of light is made to pass through any of these bodies, or through glass unequally cooled, and solids of unequal density, whether from unequal temperature or pressure, it is refracted in two different pencils, more or less inclined to one another, accord- ing to the molecular arrangement of the body, and the direction in which the pencil is incident; thus producing all the phenomena of double refraction, which also occurs when it passes through resins, gums, jellies, horn, shells, bones, elastic integuments and animal lenses. Whenever a ray of light is thus divided, one of the trans- CAUSE OF DIMORPHISM. 103 It has been also discovered by Rose, that at the temperature of 50°, carbonate of lime assumes the form of rhombohedric crystals, as in calc spar; whereas, at the temperature of 150°, it takes the cubic form, as in arragonite, the composition of which is the same. And when rhombic crystals of calc spar are heated to 212°, they are changed to the cubic form, without any change in its chemical composition,—if we except the addition of caloric, which is the cause of all molecular aggregations, and therefore the creator of forms. Cor- responding with the foregoing facts, Mitscherlich has shown that the mutual inclination of the crystalline planes in calc spar is altered eight and a half minutes of a degree between the temperature of 32° and 212°; while in other cases it varies nearly 1° in different spe- cimens of the same salt. For a full account of his discoveries, see Ann. de Ohim. et de Phys., tome xiv. 172; xix. 350; xxiv. 264, 355. In accordance with the above facts, it has been dis- covered that on crystallizing from solution in the bisulphuret of carbon, or oil of turpentine, at tempe- ratures below 100°, sulphur assumes the octohedric mitted rays is said to be polarized; that is, its properties are so far changed that it is incapable of undergoing reflection or refrac- tion, except at certain angles ; or of transmission through trans- parent bodies, except in particular positions. For example, a plate of tourmaline permits the ray to be transmitted in one posi- tion, but in a position perpendicular to that it arrests and stifles it, because in these two rectangular directions its particles are differently arranged. It is therefore manifest that all the phe- nomena of crystallization, the reflection, refraction, double refrac- tion, polarization, and doubtless the diffraction of light, are imme- diately connected with the theory of caloric. 104 NUMBER OF THE PRIMITIVE ELEMENTS. form, with rhombic bases; but that when melted by itself and allowed to cool slowly, it takes the form of an oblique rhombic prism on solidifying at 230°. (Gra- hanis Elements of Chemistry, p. 189.) It has also been ascertained that pure carbon occurs in the form of regular octohedrons, as in the diamond, but in six- sided plates in graphite. And Professor Johnston has recently shown that there is a large class of bodies composed of the same elements in the same propor- tions, which crystallize in two, if not more primitive forms. But since the time of Dr. Black, chemists have attended so little to the agency of caloric in the vari- ous transformations of matter, that they have scarcely ranked it among their elements, although it consti- tutes by far the largest proportion by volume of solid bodies. Among the most civilized nations of antiquity, it was supposed that everything in nature is composed of four primitive elements, which they termed earth, water, air and fire; to which Aristotle added a fifth. But the tendency of modern science has been to in- crease the number, until it has extended to sixty-two, all of which are regarded as simple, because chemists have not yet been able to resolve them into fewer ele- ments. There is reason, however, to believe that none of our chemical atoms and elements are perfectly sim- ple, if we except caloric, which also exists in a great variety of states, as will be shown hereafter; and that it is only in the subtilized form of light that we can hope to discover the ultimate constitution of ponder- able matter.* * For example, if it be true that all the reputed elements are LIGHT IDENTICAL WITH PONDERABLE MATTER. 105 In accordance with the hypothesis advanced by Newton in one of his Optical Queries, that light and convertible into light, and that light is decomposable into seven primitive rays by prismatic refraction, as maintained by Newton, or into only three fundamental colours, when analyzed by absorbent transparent media, as maintained by Brewster, it will follow that what we call simple bodies are composed of one, two, three or more of the primitive elements which constitute white light. Now it is worthy of remark, that hydrogen is the most elastic of all gaseous bodies, and affords during combustion an almost perfectly blue light; while, according to the experiments of Newton, the blue rays are more refrangible than any others except the violet, which is not a simple colour according to Brewster, but composed chiefly of blue, with small proportions of yellow and red; which he re- gards as the three primitive rays, and the elements of all compound colours. It is therefore probable that the blue and violet rays are more refrangible than the others, for the same reason that hydro- gen, of which they are formed, is the most elastic of all known bodies, viz. because it contains more caloric around its particles in proportion to their size. And it was supposed by Newton that the atoms of light diminish in size from the red to the violet ex- tremity of the spectrum. Again, as sulphur burns with a blue, and iodine with a violet light, (which contains small proportions of the other rays,) they may be composed chiefly of hydrogen, with some other base or bases; and cannot be otherwise decomposed than by expanding them into the subtile form of light. On the other hand, during the combustion and ignition of potassium, strontium, lithium, sodium and magnesium, they afford chiefly red light, with small proportions of the other coloured rays; therefore must all be composed principally of one element, the primitive atoms of which are red, while those of hydrogen (which is the basis of sulphur, iodine, and perhaps some other bodies,) are blue. Chloride of sodium also affords an orange-coloured light; while in that of chlorine, silver, copper and some other bodies, there is a predo- minance of greenish rays; so that if green light be composed chiefly of yellow and blue, as maintained by Brewster, all bodies that burn with a green light must be compounds of two or more 10G LIGHT IDENTICAL WITH PONDERABLE MATTER. common matter are mutually convertible into each other, it has been recently maintained by Sir David Brewster, that " the particles of light are Identical with the ultimate atoms of bodies, and that there is a specific affinity between definite atoms and definite rays, though we do not understand its nature."* (Transactions of the Brit. Association, vol. i. p. 231.) He also observes in another work, that " when a portion of light enters a body, and is never again seen, we are entitled to say that it is detained by some power exerted over it by the particles of the body; that it enters into chemical combination with them, and produces the various che- mical effects by which their colours are changed, and the juices of plants elaborated,"—to which he adds, " It is not easy to allow that such effects are produced by undulations of an ethereal medium. (Optics, chap. xxxiv.) That every description of ponderable matter is ac- tually convertible into light by a sufficiently intense heat, or by electricity, will appear from the following undeniable facts:— 1. That the quantity of light generated by ordinary combustion, friction or percussion, is always in pro- primitive elements; while others, again, which afford different pro- portions of all the coloured rays of the spectrum, are still more complex. * A similar doctrine seems to have prevailed among the ancients, for the sceptre of the Egyptian Pthah was painted with four colours, which were attributed to the four elements. Plutarch also says, that Pythagoras maintained the existence of four primitive colours, and that Zeno regarded colours as the first configuration of mat- ter; while, according to Plato, they are produced by the reflection of light from bodies to our eyes. (De Placet. Philosophorum.) CALORIC THE ACTIVE PRINCIPLE IN LIGHT. 107 portion to the rapidity with which ponderable matter is ignited and volatilized. 2. That the colour of light thus produced always depends on the species of matter employed. 3. That the electric spark, like that produced by the collision of flint and steel, consists of exceedingly minute portions of ponderable matter in a state of in- candescence, as will be shown hereafter by the decisive and beautiful experiments of Fusinieri. 4. That when the electric fluid is transmitted through the vacuum of an air-pump, little or no light is produced, as proved by the experiments of De Luc, and afterwards by those of Sir H. Davy. 5. That the most intense heat of a voltaic battery never produces any light, except when acting on pon- derable matter; consequently, that light and heat are not identical,* as maintained by some modern theo- * That caloric is a constituent of light, (as it is of all other bodies,) and is the active principle in its generation, is evident from the fact, that the most refractory gems and metals are trans- formed into luminous incandescent particles by a sufficiently intense heat, definite measures of which are required to produce the effect on different species of matter. It has also been proved by the ex- periments of Hulme, Dessaignes, Macartney and others, that every species of phosphorescence is promoted (for a time) by moderate heat, and always extinguished by the coldness of freezing mixtures; while others have found that the light of luminiferous insects is much greater in vessels of oxygen gas than in common air. But that caloric is a distinct essence, and may exist independent of light, is manifest from the fact, that it converts solids into liquids, vapours and gases, in the midst of perfect darkness; while it radi- ates from the earth during night, as it does from boiling liquids and other hot bodies, without being attended with any light. 108 CHEMICAL AGENCIES OF LIGnT. rists; and that neither of them is generated by the mere vibrations of an ethereal medium. In accordance with the foregoing facts, it has been found that each of the primitive rays produces specific changes of colour in different bodies; that the blue and violet rays of the spectrum change the white chloride of silver to a dark-violet hue; whereas the red rays change it to a rose colour; and that the same change of colour is produced on the protochloride of lead and the oxide of mercury, when moistened and exposed to the red rays of the spectrum, as in the ex- periments of Scheele, Sennebier, Davy and Seebeck: —that a piece of white paper stained yellow with a solution of guiacum in alcohol, was turned green in five minutes by exposure to sunshine, but remained unaltered for several months in the dark; and that when the yellow paper was made green by exposure to the violet rays, its original colour was restored by exposure to the red rays of the spectrum, as shown by the experiments of Wollaston. The chemical agency of light is still more strikingly illustrated in the production of those accurate pictorial delineations of objects termed Daguerreotypes, which are formed by the immediate influence of the regal sun. Moreover, that there is "a specific affinity be- tween definite atoms and definite rays," is evident from the fact, that bodies repel and reflect certain rays, while they attract and absorb others. For ex- ample, it was found by Sir David Brewster, that red transparent solutions and glasses permitted the red rays of the spectrum to pass freely through them, but DECOMPOSITION OF LIGHT. 109 absorbed and obliterated the other rays;* that blue media permitted rajs of the same colour to pass through them, but absorbed the other rays; and that green media absorbed the rays at both extremities of the spectrum, but the red most where it verges to blue, and the violet most where it verges to yellow. Nor is it more remarkable, that bodies should absorb one or more primitive rays, and reflect or transmit others, than that certain elements of ponderable mat- ter should have an elective affinity for some, and an antipathy for other elements; the rationale of which is doubtless the same in both cases, and must be sought in the fact, that as the different rays of light are of different temperatures, so are the elements of ponderable matter associated with different quantities of caloric. And it will be found hereafter, that no chemical union of bodies ever takes place without the * If in our cathedrals, colleges and other public buildings, were judiciously placed a few windows composed of perfectly red, yellow and blue glasses, (to which might be added combinations of these colours,) the mind would be elevated, refined and instructed, on beholding such a vivid display of all that is most beautiful in light, when thus decomposed, and reduced to its primitive elements. The effect would also be much improved by arranging the colours so as to produce an imitation of the rainbow; to which might be added other appropriate symbols, and even inscriptions, written in letters of light. Never shall the author forget the emotions of delight and admiration he experienced on first looking at the sky through a fine ruby glass,—when it presented the appearance of a vast dome of lurid flame; and the whole face of the earth, as if by en- chantment, was suddenly dyed of a gorgeous crimson hue. We little think how cheaply some of the highest pleasures of existence may be purchased. 110 CHEMICAL UNION OF BODIES. transition of caloric from one to the other, attended, in most cases, with a change of temperature. But if the ultimate atoms of ponderable matter be identical with those of light, and the latter consist of seven primitive rajs, as supposed by Newton, it fol- lows that the sixty-two elements enumerated by che- mists are not simple bodies, but compounds of two or more primitive elements, as before suggested; or, that if light consist of only three primitive rays, united with caloric, everything in nature must be composed of four elements. Nor is it possible to admit with Newton, that the blue and indigo are distinct primi- tive rays; while it is certain that all the known varie- ties of colour may be produced by combinations of red, yellow and blue; which, as Brewster has shown, over- lap each other, and reach quite across the spectrum. What then becomes of the enormous quantities of light perpetually radiated throughout the solar sys- tem? This is doubtless one of the most curious, im- portant and comprehensive problems in the whole range of physics, and deserves the profoundest atten- tion of philosophers. One thing is certain, that if light be matter, it cannot be annihilated, any more than the great fountains from which it emanates; that whatever falls upon the earth, and is not reflected or radiated from it into surrounding space, must com- bine with, and become a constituent portion of its sur- face; that certain rays produce specific chemical and vital effects; while the various powers of different bodies to decompose white light by absorption, trans- mission, reflection, refraction and polarization, cause an endless diversity of colours. Light, then, is not COSMICAL PHENOMENA OF LIGHT. Ill only a revelation of all that is grand and beautiful in the outward universe, but the agent by which all its operations are carried on. It is therefore probable, that when fully understood, it will enable us to ex- plain whatever is now mysterious in the ultimate mechanism and laws of nature. And if "the particles of light be identical with the ultimate atoms of ponderable matter," the question naturally arises, whether all the planets and satellites of our system may not be so many masses of embodied light, which is first aggregated into nebulae, and then into comets, that go on gradually augmenting in size, by constant additions of light, until, after enormous periods of time, (compared with which our geological epochs are mere fractions,) they arrive at maturity, or until, by the expenditure of his substance, the sun is so far reduced in magnitude, that the centrifugal power of his rays becomes inferior to the centripetal pressure of the surrounding ether—when they would gradually approach, and finally in succession fall into the sun? In short, whether the ponderable matter of the sun and fixed stars is not perpetually ex- panded by caloric into the subtile form of light, which is as constantly reconverted into the matter of planets and satellites. This theory enables us to answer the important question, "What becomes of light?" while it affords a more intelligible explanation of the manner in which cosmical bodies are generated and finally destroyed, than any merely metaphysical hypothesis—unless by metaphysics we understand the universal Science of 112 COSMICAL PHENOMENA OF LIGHT. Ontology,, or of whatever exists.* It also enables us to comprehend why the distances of the planets from * The periodical creation, destruction and reorganization of worlds, was a fundamental doctrine of the ancient Hindu cosmogo- nists, who maintained that they are all emanations from the eternal Brahm, and that after enormous periods of time they return to the primitive source of their existence. But the mighty Brahm was a personation of the entire universe, in its two-fold character of spirit and matter, or nature active and passive. In the Vidds, the eternal Brahm is represented as perpetually sacrificing a portion of his immensity in the formation of worlds, which he creates and recreates for the purpose of multiplying happiness. According to this ancient theory, the universal Brahm comprehends the innu- merable fixed stars or suns that throng the infinitude of space, and from which proceed myriads of planetary systems in endless suc- cession. In the Rich Vidd, the solar orb is invoked as "the god- head from whom all proceed, and to whom all must return;" as we are informed by Sir William Jones. In regard to what is said in the Puranas, concerning the sleep of Brahma, during which the universe, after having existed for countless ages, fades away into an invisible state, and again emerges into being when he awakes— it must be viewed as the dream of oriental transcendentalism, or as an allegorical account of those cosmical revolutions described by Sallust, who tells us that in the course of certain vast periods, the whole universe undergoes mutations which are equivalent to the entire destruction of worlds, and the formation of others from their ruins. (De Diis et Mund., c. vii., xvii.) The same doctrine (which is in actual accordance with all known analogies in nature) may be found in the third book of Seneca's Natural Questions. We are further informed by Diogenes Lanteus, that according to Herachtus, all things were originally formed from fire, which, in its ordinary state of flame, is light. And we read in the first chapter of Genesis, that light was created before the earth or the sun, moon and stars. The fact is, that in all the ancient cosmogo- nies, light is represented as the first of created things. Among the Egyptian sages, it was the first-begotten of Osiris and Ms, who were personations of spirit and matter, or of the active prin- C0SMICAL AGENCY OF LIGHT. 113 each other augment in nearly definite ratios, from Mercury to Uranus; why they increase in magnitude (if we except Mars and the asteroids) from Mercury to Jupiter; and why their equatorial exceeds their polar diameters. For example, it is probable that if light obey the same laAvs as other projectile bodies, a much larger proportion of what is radiated from the sun would lose its original force and velocity at the distance of Jupiter, Saturn and Uranus, than at that of any one of the planets nearer to the sun; so that a corresponding amount of luminous matter would be aggregated into comets, which may successively fall into those great masses and their satellites,—in the same way that many thousand meteoric stones, and ciple in nature, and the passive matter out of which everything was formed. In the Orphic Hymns, light is called Ttpwroyovoq, or first-begotten of the ether and chaos, which the ancients universally regarded as the origin of all things. Nor is it more difficult to comprehend the generation of worlds from the matter of light, than their creation out of nothing—a doctrine which involves the incredible supposition, that during the whole eternity that preceded the act of creation, the Deity existed alone in the vast solitude of his own immensity unemployed. It is far more in accordance with the attributes of infinite wisdom and goodness that belong to the author of the universe, to suppose that he has been always em- ployed in the creation of worlds, and the diffusion of happiness, than that he should have commenced at some finite period, or, as the Brahmans tell us, that he should suffer them all to fade away, fall into a periodical state of practical nonentity. As to Laplace's theory, that the planets of our system were formed by a gradual contraction of the sun's atmosphere, there is no assignable reason why the sun should have thrown off such an atmosphere at one time rather than at another. Nor would such an atmosphere, if aggregated, form the smallest satellite of our system. 8 114 RADICAL DEFECTS OF THE AVAVE THEORY. showers of stones, have fallen from unknown heights upon our planet, since the historical era,—a fact which clearly demonstrates that the earth has been augmenting in six, Independently of the constant additions of mat- ter it receives from the sun in the form of light. And as it is equally evident that the tropical portion of planets receives much greater quantities of light from the sun than the middle and polar latitudes, this fact affords a more satisfactory reason for their equatorial protuberances than the prevalent theory, which refers them to the rapid diurnal motion of their equatorial zones. If the foregoing views be well founded, it follows that light, in connection with caloric, which is the ac- tive principle in its generation, and always forms a constituent portion of it, is the primitive basis of all material existence,—or the physical Ens cntlum; con- sequently cannot be resolved into the mere vibrations of an ethereal medium, as maintained by many distin- guished mathematicians of the present age That the vibratory theory of light is not a true re- presentation of nature, would further appear from the following considerations:__ 1. That it does not explain what the ether is, nor what causes it to vibrate. 2. That light is propagated in straight lines, and will not pass through a bent tube; whereas vibrations move around interposing bodies, which obstruct the passage of light, as maintained by Newton rntt Tllf1thi!+Wre the°ry d0GS not exPlain the gene- ra ion of light by combustion, ignition, friction and peicussion; how it is connected Avith caloric and elec RADICAL DEFECTS OF THE WAVE THEORY. 115 tricity; nor why ponderable matter is essential to its production. 4. That it does not explain the decomposition of light by prismatic refraction, absorption and trans- mission ; nor how it modifies the chemical and vital properties of ponderable matter; Avhile "it leaves the Avhole subject of colours, both in opaque and trans- parent bodies, involved in profound obscurity." (Whe- well.) 5. That in adopting the theory of undulations, "we are called on for acts of faith, and certain admissions must be made at every step," as acknowledged by Sir John Herschel, who is certainly one of its ablest advo- cates. 6. That as the different colours of light depend on the species of ponderable matter employed in its gene- ration, they cannot be resolved into different numbers of ethereal vibrations. 7. That when a sunbeam impinges on objects, it produces mechanical, chemical and vital changes; causes pain and inflammation of the eyes; alters the colour, taste, odour and other sensible properties of bodies; effects which cannot be reconciled with the hypothesis that light is not a material substance. The radical defects of the wave theory have been disguised by an imposing array of algebraical formulae; Avhile the most important facts connected with its his- tory have been overlooked, or intentionally neglected; and that it is exceeding difficult to understand, is admitted by Mr. Whewell. In short, the amount of mathematical reasoning brought to its support, would seem to be inversely as the number of facts on which 116 RADICAL DEFECTS OF THE WAVE THEORY". it is based: for the ATeiy existence of the ether is as- sumed; Avhile its Aibrations are made longitudinal or transverse, just as the phenomena may require. And it might as Avell be said that the first mover in the steam engine is motion, as that light consists merely in the vibratory motions of an ether. CHAPTER III. ON THE LAW BY WHICH CALORIC PRODUCES THE OPPO- SITE FORCES OF ATTRACTION AND REPULSION, CON- TRACTION AND EXPANSION. " That alone is true philosophy which repeats the words of the universe with fidelity, and is written, as it were, by dictation of the universe."—Bacon. The doctrine that everything in nature is composed of tAvo descriptions of matter, the one essentially ac- tive and ethereal, the other passive and motionless, Avas recognized by the most acute and profound sages of antiquity in every quarter of the civilized world. But notAvithstanding they all regarded elementary caloric as the prime mover, they seem to have over- looked the law by which it repels its own particles, and tends to combine Avith those of ponderable matter, with forces that vary inversely as the squares of the distance, so as to produce all the centrifugal and cen- tripetal forces of nature. The same observation ap- plies equally to Bacon, Descartes, Newton and other modern philosophers, who, although they sometimes referred all the operations of nature to what they called a .spirit or pneumatical body, a materia subtil Is, a subtile ether, &c, they never identified it with any known principle, nor explained how it causes both attraction and repulsion, union and separation. (117) 118 CALORIC A SELF-ACTIVE PRINCIPLE. Why then does caloric repel its own particles, and attract those of ponderable matter, with forces that vary inversely as the squares of the distance? To this primary and leading question I answer, that ca- loric repels its own particles because they are of the same nature, and attracts those of ponderable matter because they are of a totally different nature; that in every variety of state caloric is an essentially active principle, and incomparably more refined than any description of ponderable matter, even when expanded into the subtile form of light; for it permeates the most dense and opaque bodies, which are wholly im- pervious to light. And that the forces of caloric diminish in proportion as the squares of the distance augment, is obvious from the fact, that all ethereal emanations are necessarily diffused in the same ratio, on radiating from any given centre.* That atoms of the same nature repel one another, and attract those of a different nature, would appear from the best-known phenomena of chemistry and physical optics. For example, it has been long known that similarity of properties among the elements of ponderable matter causes them to repel each other, as if by a mutual antipathy; but that diversity of pro- perties is favourable to chemical combination. We * It would therefore seem to follow, that there must be a limit to the diffusion of caloric; that it is not infinitely subtile and divisible ; but that there must be a definite number of particles in any given quantity of it. It is only by its extension throughout illimitable space that it can be regarded as infinite; for we shall find that, while it governs all the operations of the material uni- verse, it is itself governed by invariable and necessarily fixed laws. RELATIONS OF CALORIC AND PONDERABLE MATTER. H9 have also found that transparent media transmit rays of light of their own colour, but attract and absorb those of different colours. That caloric is a self-active principle has been al- ready shown by its power of moving itself, and of giving motion to other bodies, the activity of which is augmented by every addition, and diminished by every abstraction of heat; proving, that if the particles of ponderable matter could be wholly deprived of caloric, they Avould be passive and motionless. At the same time it is highly probable, that if universal space were filled Avith caloric alone, (without any ponderable mat- ter,) it Avould also be inactive, and constitute a bound- less ocean of poAverless or quiescent ether, because it would then have nothing on which to act. And Ave shall find that, however inactive of itself, ponderable matter has certain properties by which it modifies and controls the actions of caloric, both of which are go- verned by immutable laws that have their origin in the mutual relations and specific properties of each. I now proceed to show, that all the expansions and contractions of gaseous bodies depend on the relative pro- portions of cedorlc and ponderable matter of which they are composed. For example, the atoms of hydrogen are smaller, and contain a larger amount of caloric around them, in proportion to their size, than those of any other gas; the consequence of which is, that its elastic force is such, that no mechanical pressure hith- erto employed has been sufficient to condense it into the liquid form.* And it was found by Perkins, that * Under the pressure of the atmosphere, and at the temperature of 60°, hydrogen is 15,480 times lighter than water, the pores of 121) CONTRACTION AND EXPANSION atmospheric air (which is composed of oxygen and nitrogen in a state of mechanical mixture) may be submitted to a pressure equal to 1200 atmospheres, without being perfectly condensed into the liquid form. (PhilosophIced Transactions, 1826.) But Avhen three volumes of hydrogen unite chemi- cally Avith one of nitrogen, they contract into two volumes of ammonia, the elastic force of which is so far diminished that it may be condensed into the liquid which are 40 times larger than its solid particles, according to Newton. It is therefore evident, that the pores of hydrogen exceed the diameters of its particles several thousand times, and, perhaps, to the same extent, that the spaces between the different planets exceed their mean diameters. What, then, is the cause of the stu- pendous force by which the particles of hydrogen are kept at such comparatively great distances from one another ? Is it some virtue, property, or condition termed polarity? Or is it owing to the existence of certain hypothetical immaterial spheres of repulsion around its particles ? Is it possible that masses, and the atoms of which they are composed, are capable of acting upon each other at comparatively great distances without an intervening medium ? That the volume of gaseous bodies is augmented by every addition of caloric, has been proved by the experiments of Gay-Lussac, who found that 1000 cubic inches of common air were expanded to 1375 cubic inches by raising its temperature from 32° to 212°. It was further ascertained by Dulong and Petit, that the same law of ex- pansion is true of atmospheric air and hydrogen, up to the tempe- rature of 680° ; from which they concluded, that it was true of all gases, and at all temperatures. (Ann. de Chim. et Phys., vii. 120.) Dr. Dalton also found that the elastic force of steam was equal to the weight of the atmosphere at 212°, but was equal to the pres- sure of six atmospheres when raised to 320°. And we learn from the experiments of Perkins, that when water is confined in very strong vessels, it expands with a force equal to the pressure of 20 atmospheres when raised to the temperature of 419°. OF GASEOUS BODIES. 121 state by a pressure equal to 6*5 atmospheres, or by cold alone at the temperature of 46° below 0° F. And when iavo volumes of nitrogen combine with one of oxygen, the elastic force of the resulting compound gas is so far diminished, that it may be liquefied by a pres- sure equal to 44 atmospheres at the temperature of 82°, as first shown by the experiments of Sir H. Davy; or by a pressure equal to 50 atmospheres at the tem- perature of 45°, according to Faraday. What then is the rationale of these curious phenomena? Is the sphere of repulsion in the elementary gases exchanged for one of attraction as they unite chemically, with contraction of volume and diminution of elasticity? Or how many immaterial and imaginary spheres of attraction and repulsion are required to explain the phenomena of solidity, liquidity and vapourization ? The summary answer to these queries is, that "the self- repulsive power of caloric is counteracted and diminished- by its affinity for ponderable matter, by which the ethe- real atmospheres are drawn into a smaller compass. The reduction of volume and elastic force are referable Avholly to this one cause. Perhaps the principle cannot be better illustrated than by a consideration of the statical and dynamical changes that are produced on hydrogen and chlorine, by their mutual action upon each other. We have seen, that the specific gravity and atomic AAreight of chlorine are 36, compared with hydrogen as one; and that the elastic force of hydrogen is immense. It has been also shoAvn by Faraday, that the elastic force of chlorine is so Ioav that it may be liquefied by 122 EXPANSION AND CONTRACTION a pressure equal to four atmospheres at the tempera- ture of 60° F. But when one volume of chlorine is made to unite Avith one of hydrogen, they form two volumes of hydro- chloric acid gas, the specific gravity of which is 18o; or a mean between that of its constituents. During this combination, the hydrogen loses the greater part of its elastic force, while that of the chlorine is greatly augmented. That is, a definite proportion of caloric passes from the smaller atoms of hydrogen to the larger atoms of chlorine, by ivhlch the latter are removed far- ther from one another. Nay more, it is by virtue of this transfer of caloric that the atoms of hydrogen are forced Into chemical union with those of chlorine, and their separate Individuality destroyed. In other Avords, all the above changes, including that by Avhich the gases are united and identified, are referable Avholly to the transition of caloric from the one to the other. It will be shown hereafter, that no chemical combi- nation of any one body with another ever takes place, without a simultaneous passage of caloric or electricity from one to the other; that if water and other liquids could exist as such without caloric, (which is impos- sible,) they could not combine with salts, metals and rocks; and that the diminution of bulk which attends the combination of liquids with solids, is owing to the same law which determines the reduction of volume and elastic force of gases and vapours. The most simple illustration of combination effected by the at- traction of caloric for ponderable matter, is that by which steam is condensed by water or ice, and inti- mately combined with their particles. When a certain OF GASEOUS BODIES. 123 proportion of steam is mixed with cold water, its vol- ume and elastic force are destroyed by the same attrac- tion of caloric for ponderable matter which causes liquids to combine Avith, and dissolve solids, or which causes gases to combine chemically, with contraction of A^olume and diminution of elastic force. There is no limit to the application of this doctrine in the phenomena of chemistry. If a piece of ice be introduced into a vessel full of ammoniacal gas, the latter disappears rapidly, and the ice is melted, forming a chemical solution of ammonia. Now it is obvious, on a moment's reflection, that the volume and elasticity of the ammoniacal gas are de- stroyed by the transfer of caloric from one to the other. It is equally true, that the ammonia is che- mically combined with the ice by the same attraction, as will be proved when I come to treat of chemical solutions. Again, if one volume of hydrochloric acid be mixed with one volume of ammoniacal gas, they may be made to combine rapidly with evolution of much heat, when they lose the gaseous or elastic state, mak- ing a solid crystalline salt, (sal ammoniac,) of a cubical or octohedral form. The atomic weight of the acid is 37, and that of the alkali 17. (See Table of Atomic Weights, p. 67.) In this case, there is an attraction of caloric for the larger particles of the acid, by which those of the am- monia are forced into chemical combination with them, forming compound particles of still larger size, the weight of Avhich is 54, compared with hydrogen as unity. Thus it is evident that the repulsive power of caloric, 124 CONTRACTION AND EXPANSION on which the volume and elastic force of gases depend, is counteracted and diminished by its affinity for pon- derable matter, and that this attraction augments in a certain ratio as the size of the particles increases, until it wholly predominates over the repulsive force. The atoms of hydrogen, nitrogen, oxygen and light carbu- retted hydrogen, have a large amount of caloric around them in proportion to their size; the consequence of which is, that the thermo-repulsive force greatly pre- dominates. But when they are made to combine with each other chemically, or with carbon, phosphorus, sulphur, chlorine, &c, making gases of greater specific gravity and atomic weight, their elastic force is dimi- nished, even in cases where little or no caloric is given out, as in the combinations of nitrogen and hydrogen, nitrogen and oxygen, nitrogen and carbon, with nu- merous others, formed of these and of sulphur, phos- phorus, &c. It has long been a matter of controversy whether the oxygen and nitrogen of the atmosphere exist in a state of mechanical mixture, as maintained by Dr. Dalton, or in a state of chemical combination. Dr. Thomson has recently maintained that it is composed of 80 parts nitrogen to 20 of oxygen, constituting definite proportions by volume; therefore, that it is a chemical compound. (Records of Science, vol. iii. p. 184.) This hypothesis does not accord with the best- established facts connected with the theory of volumes. For example, in all the combinations of oxygen and nitrogen that are known to be chemical, there is a re- duction of volume and elasticity, except in the case of the binoxide, which is composed of equal volumes of OF GASEOUS BODIES. 125 each. Besides, it would seem to be a general law, that, whenever unequal volumes of gases unite chemically, there is a diminution of their aggregate volume. This view is supported by the facts presented in Table III., page 76; while it is evident from the foregoing details, that all such chemical combinations are attended with a reduction of elasticity. But the volume and elastic force of oxygen and nitrogen, as they exist in atmo- spheric air, are the same as when in a separate state, which would seem to demonstrate, that air is a me- chanical mixture, and not a chemical combination. The elastic force of light carburetted hydrogen is less than that of simple hydrogen. When Mr. Per- kins submitted it to mechanical pressure, he found that it began to liquefy under a force equal to the weight of 40 atmospheres; and that under a pres- sure of 1200 atmospheres it was perfectly condensed into the liquid form. Being composed of tAvo atoms hydrogen to one of carbon, its specific gravity and atomic weight are to hydrogen in the ratio of eight to one. When iavo atoms or volumes of carbon unite with two of hydrogen, they form bicarburetted hydrogen, (olefiant gas,) the specific gravity and atomic weight of which are 14, compared with hydrogen as unity. During this combination, the four volumes of hydro- gen and carbon contract into one volume, the elastic force of which is much less than that of carburetted hydrogen; yet we have seen from the experiments of Dulong and Hess, that equal volumes of carburetted hydrogen give out three, and olefiant gas five times more caloric than simple hydrogen; while the vapours 126 CONTRACTION AND EXPANSION of ether and turpentine afford from ten to twenty times more. Why then is their elastic force so much less at the same temperature? The only answer to this question is, that the repulsive force of caloric is counteracted by its attraction for the larger particles of the compound gases by which their elements are chemically united, producing definite contraction of volume. If such were not the case, their elastic force Avould be greater than that of hydrogen, in proportion to the greater amount of caloric they contain. This inference is rigorous; and it is so important in its bearing upon the whole science of chemistry and physics, that I have dwelt upon it even at the hazard of repetition, with a hope that by presenting the ope- ration of the same principle in different points of view, it might be rendered clear and intelligible to the most ordinary capacity. It explains why the ex- pansive force of steam is greater, other things being equal, in proportion as the quantity of water employed in its generation is less; a thorough comprehension of Avhich is destined to effect an immense saving of fuel. The law by which the repulsive force of caloric is counteracted by its affinity for ponderable matter, is still more strikingly illustrated by the changes which are produced in the statical and dynamical properties of hydrogen and sulphur, oxygen and nitrogen, chlo- rine and nitrogen, with some others. It was before noticed that the specific gravity of sulphur vapour, as determined by the experiments of Mitscherlich, is 6-666, which is about 96 times the specific gravity of hydrogen gas; and it requires a temperature of about 640° F. to maintain it in the OF GASEOUS BODIES. 127 gaseous form, when not united with other bodies. But if brought into contact with hydrogen gas, or if sul- phur be volatilized in contact with hydrogen, they both undergo remarkable changes. In the first place, 16 parts by Aveight of sulphur combine chemically with one of hydrogen, forming hydrosulphuric acid, (sulphuretted hydrogen,) the spe- cific gravity of which is 17 times that of hydrogen, and its elastic force comparatively low. The particles of sulphur, which are 16 times larger than those of hydrogen, receive from the latter gas a portion of the ether that encompassed its atoms,'by which they are intimately united. During this process, the particles of sulphur acquire a much greater repulsive force, and are removed so much farther from each other, that they occupy six times the volume which they did in the form of va- pour, before combining with the hydrogen. The elastic force of the hydrogen is so far dimi- nished by uniting with sulphur, atom to atom, that sulphuretted hydrogen may be liquefied by a pressure equal to 17 atmospheres, at the temperature of 50°, according to the experiments of Faraday. It was afterwards discovered by Davy, that when reduced to the temperature of 3° F., the elastic force of its va- pour Avas equal to the pressure of only 14 atmospheres. When two atoms of sulphur 32, combine with one atom of hydrogen, the resulting compound is a broAvn- ish yellow and dense liquid, (specific gravity 1*769,) somewhat acid, of an oily and tenacious consistence. If submitted to very low temperatures, its specific gravity and cohesion are still further augmented, Avhen 128 CONTRACTION AND EXPANSION it becomes an exceedingly firm solid, like butter, tal- low and innumerable other fluids and semifluids under the same circumstances. When an atom of sulphur 16, combines with two atoms of oxygen 16; or when sulphur vapour combines Avith oxygen, the elasticity of the latter is nearly destroyed; Avhile the atoms of sulphur are removed farther from each other, and acquire a degree of elasticity at the expense of the oxygen: for the specific gravity of the sulphurous acid thus formed is only 2*222, which is just one-third of 6*666, that of the sulphur vapour, in agreement with the law of multiples, which may be traced in all the contractions and expansions that gaseous bodies undergo during combination and decomposition. According to the experiments of Faraday, sulphur- ous acid may be liquefied by a pressure equal to two atmospheres, at the temperature of 45°; and by cold without pressure, according to the experiments of Bussy and others. It must be observed, however, that during the combinations of oxygen and sulphur, a portion of caloric is given out, as in the union of oxy- gen and hydrogen to form aqueous vapour; which is one cause of the diminished elasticity in sulphurous and sulphuric acids. The same order of phenomena wdiich marks the union of sulphur and hydrogen, is exhibited during the combination of phosphorus, iodine, bromine, sele- nium, tellurium, &c, in the state of vapour, Avith hy- drogen and other permanent gases. The volume and elasticity of these dense vapours are augmented by receiving from the lighter gases a portion of the prin- ciple on which their volume, &c. depend, during the very act of combining. OF GASEOUS BODIES. 129 The specific gravity of phosphorous vapour is 4*444, at the temperature of 550° F.; or about 64 times the specific gravity of hydrogen. But when it combines with hydrogen, it becomes highly elastic, and its par- ticles occupy four times their former space, as in phos- phuretted hydrogen, the specific gravity of which is only 17 times that of hydrogen. The specific graAaty of iodine vapour is 8*75 at the temperature of 347° F. When it unites with hydro- gen, atom to atom, (that is, in the ratio of 126 by weight to one of hydrogen,) hydriodic acid is formed, the specific gravity of Avhich is 4*386, or about one- half that of iodine vapour, in accordance with the law of multiples as shoAvn in hydrochloric acid, am- monia, &c. The same principle applies to the A^arious combina- tions of hydrogen with the vapours of bromine, cyano- gen, arsenic and mercury, as in its combinations with the vapours of sulphur, iodine, &c. (See Table III., of the preceding Chapter.) When three, four or five volumes of oxygen com- bine with two of nitrogen, the aggregate bulk and elastic force of the resulting compounds diminish with every additional dose of oxygen. Nitrous acid may be liquefied by moderate degrees of cold without pres- sure. Yet it contains nearly if not quite as much caloric as the oxygen and nitrogen of which it is com- posed, 'when in a separate state. It was long ago observed by Higgins, that during the combinations of oxygen with nitrogen, no caloric is given out; and that during the union of nitric acid with potassa, very little heat is disengaged. 9 130 PHILOSOPHY OF That such is really the case would appear from the immense quantity and intensity of the heat evolved by the deflagration of nitrate of potassa Avith charcoal and sulphur, as in gunpowder and other deflagrating mixtures formed of nitre, phosphorus, naphtha, tur- pentine and various combustibles. It is generally known, that during their combustion with nitre, nearly as much caloric is given out, even in vacuo, as when they are burnt in atmospheric oxygen; which proves that a large amount of caloric is concentrated around the particles of the nitric acid of the saltpetre, and set at liberty during its decomposition. PHILOSOPHY OF EXPLOSION OR DETONATION. Immediately connected with the foregoing theory, is the rationale of explosion; a phenomenon which has never been explained, and has been often adduced as an argument against the materiality of caloric. It has been supposed that the quantity of heat given out during explosion, and that which is requisite to convert gunpoAvder into the gaseous state, could not have existed in a state of combination with its par- ticles. This error has arisen from not attending to the law by which caloric is concentrated around the atoms of ponderable matter, with a force that increases in pro- portion to the augmentation of their size, other things being equal; and by which its self-repulsive force is counteracted. I have shown that the elastic force of nitrogen is equal to a pressure of 1200 atmospheres; but that when five volumes of oxygen are combined EXPLOSION OR DETONATION. 131 Avith two of nitrogen, they contract into two volumes of nitric acid, without any material loss of caloric; and that when five atoms of oxygen 40, unite with an atom of nitrogen 14, they form compound molecules of nitric acid, the weight of which is 54, compared with hydrogen one: from which, and the foregoing facts, Ave are bound to infer, that the repulsive force of the ether which surrounded the atoms of oxygen and ni- trogen, is counteracted and nearly vanquished by the attraction of caloric for the larger particles of the com- pound.* By referring to Table I. page 67, we perceive that the atomic weight of potassa is 48, compared with hydrogen as unity. One atom of nitric acid 54, com- bines Avith one of potassa 48, making compound mole- cules of nitrate of potassa, the weight of which is 102; and the attraction of caloric for Avhich, so much ex- ceeds its idio-repulsive force, that they are aggregated into a crystalline solid of a prismatic form. Let us then * It was before observed that when two volumes of hydrogen combine with one of oxygen to form water, an immense quantity of caloric is disengaged, and that the aeriform state is merged into the liquid state. But as the combinations of oxygen and nitro- gen retain nearly the same amount of caloric as their constituents, they also retain the gaseous form at ordinary temperatures, though their aggregate bulk and elasticity are greatly diminished. This fact is very remarkable; for the particles of nitric acid are larger than those of water in the ratio of 54 to nine; or six to one. It is difficult to conceive why they retain the elastic state, unless they retain around them a large amount of the same ethereal principle which belongs to their elementary constituents; whereas oxygen and hydrogen give out a large proportion of it on combining to form water. 132 PHILOSOPHY OF examine the composition of gunpowder. It consists of one atom of nitre 102, one of sulphur 16, and three of carbon 18, in a state of intimate mixture. When perfectly dry, and heat is applied, the nitre is decom- posed into its original constituents, Avith a tremendous force of explosion, which is owing principally to the elastic force of the nitrogen, on being released from its combination with the oxygen and potassa of the nitre. During this rapid process, two atoms of oxygen com- bine with one of sulphur, making sulphurous acid gas; while the other three atoms of oxygen that ex- isted in the nitric acid, combine with three atoms of carbon; forming carbonic oxide and carbonic acid. But as the elastic force of these gases is comparatively Ioav, the explosive action must depend chiefly on the sudden expansion of nitrogen on assuming the gaseous state. The whole is nothing but an instantaneous combustion of sulphur and charcoal, accompanied by the disengagement of heat and light as in ordinary combustion, and by the sudden liberation of nitrogen, which, in the separate state, exerts an elastic force equal to a pressure of 16,800 lbs. to the square inch. The force is also greatly increased by the caloric given out during the formation of carbonic oxide, carbonic acid and sulphurous acid. This is a most instructive exemplification of the law by which caloric exerts two opposite forces; the one or the other prevailing according to circumstances. At ordinary temperatures, the compound particles of nitre, sulphur and carbon retain caloric around them with a greater force than that by which it repels its own particles; but Avhen they are decomposed and EXPLOSION OR DETONATION. 133 subdivided into smaller particles, the repulsive force of their ethereal constituent acquires the ascendency. The same principle applies to all fulminating com- pounds, whether solid, liquid or aeriform, as chlorate of potassa; fulminating mercury, gold, silver, platinum, &c.; iodide and chloride of nitrogen, protoxide and peroxide of chlorine, and some other detonating com- pounds, all of which are attended Avith expansion of volume and disengagement of heat during their de- composition. Chlorate of potassa is composed of chloric acid and potassa. When triturated with sulphur, phosphorus or charcoal, it forms a deflagrating compound. In the ratio of three parts of the chlorate to one of sulphur, it explodes violently when gently heated, or struck Avith a hammer. If two grains of the chlorate be mixed Avith one of phosphorus, in a bit of paper, and struck Avith a hammer upon an anvil, there is a vio- lent explosion. The chloric acid is decomposed in all such cases; the chlorine unites with the combustible, and the oxygen being liberated expands with a force proportional to its elasticity in the gaseous state, for the same reason that nitrogen expands Avhen sepa- rated from the nitre of gunpoAvder. It is by contemplating the elastic force of caloric in oxygen and nitrogen, Avhile in the state of simple gases, that we are enabled to appreciate the stupendous force of attraction by which it is concentrated around the molecules of ponderable matter. If Ave take the experimental result of Rumford, that 15 grains of gun- poAvder expand Avhen ignited, Avith a force equal to the pressure of 400,000 lbs. or 200 tons Aveight, it fol- 134 PHILOSOPHY OF lows from a simple calculation, that the elastic force of caloric in one pound of gunpowder, is equal to the pressure of 102,400 tons weight. This enormous force is restrained by the attraction of caloric for the mole- cules of gunpowder and all detonating compounds that contain nitrogen, until decomposed, when it ex- pands with an energy far surpassing the most elastic steam, for the same reason that the oxygen of chlo- rates expands Avith irresistible violence when decom- posed. Of all the detonating compounds, chloride of nitro- gen affords the most simple and striking example of the opposite effects exerted by caloric under different circumstances. It is composed of three volumes of chlorine to two of nitrogen, which, on uniting, con- dense into a volatile, oily liquid, the specific gravity of Avhich is 1*6. While its elements are united, the elastic force of the caloric in nitrogen is restrained by the greater force with which it combines with the atoms of chlorine. These two opposite forces are so nearly balanced, that by adding a small amount of caloric to the chloride it is decomposed, the nitrogen expanding with its accustomed force when reduced to the separate state. The chlorine also assumes the gaseous state, with evolution of heat and light. The chloride may be decomposed by the volatile oils, naph- tha, phosphorus and various other combustibles, which unite with chlorine, when it explodes as when heated to 212° F. Euchlorine, (chlorochloric acid,) peroxide of chlorine and deutoxide of hydrogen, also expand with explosion and evolution of heat and light on being decomposed, COMBUSTION AND DEFLAGRATION. 135 because the affinity of caloric for their particles is dimi- nished by reducing their size. The more completely ponderable matter is divided, the less tendency has caloric to concentrate around its particles. Hence, the quantity of caloric given out during ordinary combus- tion, other things being equal, is in proportion as the decomposition is complete. When coal or wood is but partially decomposed, gross vapours are formed, con- stituting smoke, the particles of which are much larger than those of flame, and which retain and carry off a considerable amount of the caloric that is given out by radiation when the combustion is perfect. The whole theory of combustion is founded on the \Tarious degrees of force with which caloric attracts the particles of ponderable matter under different cir- cumstances. It is more concentrated around the atoms of dense, than of light gases and vapours; and greatly more so around the larger compound particles of liquids and solids. In short, all the absorptions of caloric by Avhich it combines Avith and becomes latent in pon- derable matter, result from this affinity; Avhile the escape of caloric during combustion or deflagration, re- sults from the diminution of that affinity; for the same reason that the volume and elastic force of hy- drogen and nitrogen greatly augment on the decom- position of ammonia. There is nothing more clearly demonstrable in science, than that all the caloric evolved during the decomposition of ponderable matter, whether solid, liquid or gaseous, is only a liberation of what ay as previously concentrated around the atoms of the ma- terials employed. When the particles of solids are 136 PHILOSOPHY OF separated and subdivided by friction or collision, a portion of their concentrated caloric is disengaged, producing incandescent sparks, or streams of fire. A machine is exhibited at the Hall of Practical Science in London, Avhich illustrates the manner in Avhich solid bodies may be reduced to a state of in- candescence by mechanical friction. A circular plate of soft iron is made to revolve at the rate of 5000 times per minute, Avhen the hardest steel on being applied to its edge is cut through rapidly, and reduced to inconceivably small particles, which are expanded by the caloric thus liberated, into a shower of metallic flame and sparks. This kind of ignition proceeds equally Avell in A^acuo as in the atmosphere. Mr. Brande observes, in the last edition of his Manual of Chemistry, page 390, that the existence of nitrogen in nearly all the powerfully detonating bodies, is a singular fact; and that explosion must remain unexplained until we ascertain the cause of the detonating power of such compounds. He also adds, that at present the phenomena are at variance with the usual explanation of the evolution of heat and light during combustion, which have been supposed to be the result of union and condensation, instead of expan- sion and decjomposltlon. The truth is, that in a large majority of cases, com- bustion, as well as explosion, is attended Avith expan- sion of the materials employed. Lavoisier, who maintained that gaseous oxygen was the source of heat and light in all cases of combustion, supposed that it was always condensed on combining with com- bustibles. This partial vieAv of the subject has been COMBUSTION AND DEFLAGRATION. 137 incorporated with so many works on Chemistry and Natural Philosophy, that it has become a very general opinion, that oxygen is the only supporter of combus- tion, and the source of heat and light, instead of the bodies Avith which it unites. We have already seen, that during the combination of oxygen with hydrogen, they are both condensed into the liquid state; which condensation is attended Avith the evolution of caloric and light. But a large proportion of the caloric thus given out is disengaged from the hydrogen, which is therefore as much a sup- porter of combustion as the oxygen. Oxygen is also condensed, and even solidified on combining with metals during their combustion in it, by which they are converted into oxides. In such cases, it is doubtless the principal source of caloric. It is hoAvever not the only supporter of metallic com- bustion ; for cyanogen, chlorine, bromine, iodine, sul- phur, phosphorus, and some other solid bodies, unite rapidly with metals when they are heated together, Avith evolution of heat and flame. The combustion of carbon, sulphur and phosphorus in oxygen gas, is attended with intense heat; yet they are greatly expanded without any condensation of the oxygen: for the carbonic, sulphurous and phosphoric acids produced, have the same volume as that of the oxygen. During the combustion of ether, alcohol, oils, resins, Avood, coal and other inflammable bodies in oxygen, the volume of the gaseous products exceeds that of the oxygen; yet the process is attended with the production of immense quantities of heat and light. 138 PHILOSOPHY OF There is a mixture prepared at the Military Aca- demy at Woolwich, called the Carcass composition, that burns Avith great violence someAvhat like the detonating compounds, Avhich cannot be quenched Avith Avater, and has been supposed to resemble the Greek fire. I am indebted to Dr. Faraday for the following mode of preparing it:— lb. oz. Nitrate of potassa............................................... 6 4 Sulphur............................................................. 2 8 Powdered antimony............................................. 0 10 Powdered resin................................................... 1 14 Tallow.............................................................. 0 10 Venice turpentine................................................ 0 10 The resin, tallow and turpentine, are melted to- gether. The sulphur and nitre are then added, being kept hot all the time and well stirred about. The poAvdered antimony is then added and worked well in it, when it may be formed into the shape required. The combustion of this mixture is truly terrific, and the quantity of heat evolved enormous. It also goes on in vacuo as well as in the air, which is true of all deflagrating and detonating compounds. All such combustions are attended throughout with expansion of the burning bodies instead of condensation. The explosive power of gunpowder may be lessened by augmenting the proportions of charcoal and sul- phur. Fuses, which burn with a gradual or continu- ous deflagration, are composed in the ratio of lb. oz. Nitre................................................................. 4 4 Sulphur............................................................. 1 0 Common gunpowder ground into meal..................... 1 12 COMBUSTION AND DEFLAGRATION. 139 From the foregoing facts and observations, we per- ceive how partial and erroneous is the prevalent no- tion, that under all circumstances caloric is a repulsive agent. We find that the caloric of explosion, like that of ordinary combustion, is only a liberation of what was previously concentrated around the particles of ponderable matter, and diffused during its dissolution. Such is the beautiful simplicity of nature, that a clear comprehension of the law by which the molecules of a salt are aggregated and dissolved, affords a minia- ture representation of the mechanism by which all the phenomena of nature are carried on, from that of plane- tary motion to the no less important transformations of chemistry. It has been shown, that cold, or the abstraction of caloric, produces the same effect on gases as mechanical pressure; that is, it diminishes their volumes, and con- denses them into liquids or solids; which is effected by lessening the ratio of ethereal or elastic matter, Avhile the quantity of ponderable matter remains the same. If we suppose that the repulsive force of this ether in hydrogen is equal to the weight of 2000 at- mospheres, it must combine with the atoms of sulphur and other bodies with a still greater force, for Ave have seen that Avhen one atom of sulphur combines with one of hydrogen, the resulting compound, sulphuretted hydrogen, may be liquefied by a pressure equal to 17 atmospheres at 60° F.; and the bisulphuretted hydro- gen becomes liquid, or semi-solid, without any pres- sure. By the affinity of caloric for ponderable matter its atoms are approximated and held together: by its 140 CONSTITUTION OF LIQUIDS. elastic or self-repelling property, it separates them from each other, as in vapourization, explosion and all decompositions. The fact that Philosophers have overlooked this affinity by Avhich caloric is concen- trated around the particles of liquids and solids, re- soh^es the problem of contradictions by which the theory of caloric has been so long perplexed, and ex- plains Avhy many have doubted its materiality; why the phenomena of combustion, explosion, cohesion and chemical affinity have not been understood. Thus Ave perceive, that caloric is the cause of repul- sion in steam and all gases; in vapourization, combus- tion, and the expansive force of detonating compounds: and that this elastic force is counteracted and dimi- nished, or A^anquished by its affinity for inert matter. This doctrine throws a clear and full light on all the poAvers, motions, combinations and decompositions of the elements by which we are surrounded and sus- tained; and, when perfectly unfolded in all its rela- tions, will be found to furnish a simple and rational interpretation of innumerable phenomena that have never been fully explained. CONSTITUTION OF LIQUIDS. It has been shown in the preceding chapter, that there is an intimate relation between the elastic force of gases, and the proportions of ether which surround their atoms; that hydrogen contains a larger amount of caloric, in proportion to the quantity of ponderable matter, than any other known body, and possesses a corresponding degree of expansive force; but that CONSTITUTION OF LIQUIDS. 141 when it unites chemically Avith oxygen, it gives out a large proportion of caloric, by Avhich its volume and elasticity are diminished. It has also been shown that, other things being equal, the elastic force of all gase- ous bodies is in proportion to the amount of caloric Avhich is combined with any given quantity of pon- derable matter. I iioav proceed to shoAV, that the lightest and most volatile liquids are composed of elements Avhich con- tain the largest proportion of caloric around their atoms. I am not aAvare that any one has attempted to explain Avhy liquids differ so greatly in their vola- tility: Newton referred it to their smallness; Boyle supposed that their tenacity Avas owing to the gross- ness of their particles,* Avhich are nearly the same. But it is now Avell known that the proximate atoms of Avater are less than those of alcohol, ether and various other liquids that are more elastic and volatile at the same temperatures. The atoms of nitrous and nitric acids, of sulphuretted and phosphuretted hydrogen, of chlorine, hydrochloric acid and many other gaseous bodies, are larger than those of carbon, sulphur, phos- phorus, silicium, calcium, &c. Yet the former are much more volatile and elastic than the latter. The atoms of etherine, sulphurous acid, muriatic ether, (Avhich is composed of etherine and hydrochloric acid,) * Lucretius observes that light passes through scraped horn, which wine and water will not do, because the particles of the latter are too large; but that water and wine percolate strainers more readily than oils, because the latter are composed of larger particles, or of particles that are hooked. (De Naturd Rerum, Book II.) 142 CONSTITUTION OF LIQUIDS. protoxide of chlorine, &c, are larger than those of water or hydrocyanic acid, the elasticity of Avhich is much inferior. Such facts prove conclusively, that the elastic force of gases and liquids is not determined alone by the size of their proximate particles, but by their relations to a self-repelling fluid. There is a class of liquids which are composed chiefly of hydrogen and carbon, that seem to form a connecting link between gases and more fixed bodies. They are generally much lighter than water, and ex- ceedingly volatile. Such are etherine, spirit of gum elastic and naphtha. Ether, alcohol, pyro-acetic spirit, acetic ether, and most of the essential oils, which are composed of carbon and hydrogen united with small proportions of oxygen, are lighter than water, and some of them highly volatile. There are also a few combinations of hydrogen and carbon Avith nitrogen, chlorine and even iodine, that are very volatile, as nitrous ether, hydrocyanic acid, muriatic and hydriodic ethers. There cannot be a doubt that all such liquids owe their volatility to the same cause which determines the elastic force of gases. For we find, that etherine, the lightest of them all, boils or expands rapidly into the gaseous state, under the pressure of the atmosphere, beloAv 32°. Common ether boils at 96°, muriatic ether at 60°, nitrous ether at 60°, acetic ether at 105°, and alcohol at 173°.* But when the pressure of the atr * With a view of ascertaining how far the rationale of such phenomena had occupied the attention of philosophers, I took an opportunity of asking a distinguished professor of chemistry why ether and alcohol were more volatile than water: to which he re- CONSTITUTION OF LIQUIDS. 143 mosphere is removed, as under an exhausted receiver, the elastic force of the caloric which surrounds their particles expands them rapidly into vapour at 145° below their boiling points under the pressure of the atmosphere. In all such cases, liquids are expanded into the gaseous state, by the elastic force of their con- stituent caloric, Avhich is thus diffused and carried off, by Avhich intense cold is produced. In vacuo, pure ether is rapidly expanded into vapour at —46°, alco- hol at 28°, and water at 67°; from which it follows, that they are all elastic fluids like gases, but in a less degree; and that if their elasticity were not restrained by the pressure of the atmosphere, they would boil at ordinary temperatures, until the process were checked by the pressure of their own atmospheres. By reference to a subsequent table, it will be seen that ether is composed of five atoms of hydrogen, four of carbon, and one of oxygen; and that alcohol is composed of the same substance, united with one par- ticle of Avater. Hence the difference between their specific gravities and boiling points; the specific gravity of pure ether being about *700, and that of alcohol ■794, compared Avith water 1000, which congeals at 32° F.; Avhile ether and alcohol are exceedingly difficult to congeal.* plied that he did not know, unless it were owing to the smallness of their cohesion. And Dr. Young tells us, that " the weakness of cohesion in fluids is owing to the mobility of their particles." (Lectures on Nat. Philos., vol. i., p. 620.) The truth is, that our books abound with such definitions. * It has been said that alcohol was frozen by Hutton; and Fourcroy supposed that he had frozen ether at —46°. But neither Thenard nor Bussy were able to congeal it: from which it is pro- J44 CONSTITUTION OF LIQUIDS. That light and volatile liquids contain more caloric than Avater and some others which are more dense and tenaeious, might be inferred from the large amount of hydrogen Avhich they contain, and from their highly combustible property. It has been often stated gravely by chemical writers, that cold results from evaporation, because vapours have a greater capacity for caloric than the liquids from which they are formed. But this does not explain hoAv liquids are converted into vapour. The coldness re- sults from the elastic force of their constituent caloric, by which they are expanded over a larger space; yet Avithout its being separated from their particles and radiated, as during combustion. When an open vessel of Avater is placed over a fire, its temperature never rises above 212° F., hoAvever hot the fire may be; because at 212°, the elastic force of caloric in Avater overcomes the pressure of the atmo- sphere, and expands it into steam, the bulk of which is 1720 times that of water. But when Avater is en- closed in a strong vessel like Papin's digester, and pre- vented from expanding into steam, its temperature rises to 500° or more. If a vessel could be obtained strong enough, water might be made red hot; and if again permitted to expand, its temperature would ira- bable, as observed by Mr. Brande, that the ether employed by Fourcroy was not pure. It is now certain, however, from the ex- periments of Thilorier, that both may be congealed. When alcohol and water are mixed, they combine chemically with diminution of their aggregate volume and disengagement of heat. Proof spirit is composed of about equal weights of each, the specific gravity of which should be *916. CONSTITUTION OF LIQUIDS. 145 mediately fall in proportion to the diffusion; and so of all other vapours. The production of cold during the exhaustion of a receiver, as reported by Leslie and Dalton, is referable to the same cause, and not to an increase of capacity for caloric in rarefied air, as they supposed. That is, a large proportion of caloric is carried off in combina- tion with the air which is pumped out; so that Avhat remains is. greatly diffused by virtue of its elasticity, producing a corresponding reduction of temperature. When carbonic acid, ammonia, cyanogen, chlorine and other elastic fluids are converted into the liquid or solid state by pressure, a still greater reduction of temperature results from their sudden expansion on removing the pressure. M. Thilorier has recently invented an apparatus by which he can form large quantities of liquid carbonic acid, the rapid expansion of which, when released from pressure, causes a reduction of temperature equal to 164° below the freezing point of water, by which the liquid carbonic acid is converted into Avhite solid lumps. When alcohol was poured upon them, it was immediately converted into a hard, brittle ice; while ether was congealed to the consistence of sodden snoAv.* M. Bussy has also congealed alcohol (sp. gr. ■850) by the evaporation of liquid sulphurous acid in \racuo. (Ann. de Chim. for May, 1824.) * Carbonic acid is procured in the liquid state by adding to- gether in a close strong iron vessel, two pounds bicarbonate of soda, three pints of water at 100° and eight ounces of sulphuric acid. 10 146 CONSTITUTION OF LIQUIDS. When ether is dropped upon the hand, the caloric of the living body expands it into Aapour, and is car- ried off in an invisible form, causing coldness. In the same way, the caloric of the solar rays is con- tinually expanding the Avater of the earth into vapour, and diffusing it through the atmosphere, (to be given out in colder regions,) by which the sultry heats of summer are diminished. That all odoriferous emanations consist of extremely minute particles of bodies diffused through the atmo- sphere by caloric, need scarcely be mentioned; being obvious from the fact, that at very low temperatures they are not produced. Excessive cold puts a stop to all Arolatilization and decomposition of matter. That the numerous facts connected with the consti- tution of different liquids may be the more readily understood, I have presented them in a tabular form. The first column of the first table exhibits the for- mula1 of the various compound liquids; the second represents their united equivalents, compared with hydrogen as unity. The third column gives the spe- cific gravity of the liquids, compared with water 1000, —and the fourth, their boiling points. The remain- ing numbers give the relative proportions of their con- stituents in the 100 parts by weight, as derived from the best analyses of modern chemists. By inspecting the first table, it appears that all the most spirituous and volatile liquids contain large proportions of hydro- gen and carbon; most of which are lighter than water, and boil at lower temperatures. CONSTITUTION OF LIQUIDS. 147 TABLE I. Representing the Atomic Constitution, Specific Gravity and Boiling Points of various Volatile Liquids, &c. Etherine.......... Sp. of caoutch... Mur. ether....... Nitrous ether__ Acetic ether..... Ess. of lemon.... Ilydrocy. acid... Kther.............. Naphtha.......... Bicarb, of hyd... Paraffine......... Pyro-acetic sp... Pyroxilic spirit. Hydriod. ether.. Hydrocy. ether- Alcohol ........... Bisul. of carb.... Chi. of sulphur.. Chl.ofnitr....... Iodide of nitr.... C,H4 CH C4H-C1 C4H5N04 C8H804 C5H4 C2HN C4H50 C6H3 C24H25 C3H30 C2H30 C4H5I C4H5Cy C4H602 cs2 S2C1 NC13 NL N. acid, concen. NHO Mu. acid, cone... HClAq6 Hydriodic acid.. HI Acetic acid......;C4H404 Cyanic acid......'CyO |Sul. cyan. acid.. CyS, I Perchloric acid.. C107 Sul. acid, cone... SHO Water............. HO 28 65 70 88 34 27 37 36 39 129 29 23 154 55 46 38 68 122 392 63 1 91 1 Relative Proportions by Weight in 100 Parts. 127 60 34 59 92 49 9 627 640 874 880 847 705 700 75U 850 870 792 804 92 700 794 272 687 6 5 2 7 062 022 6 845 000 0. 32° 85 15 .... 85 71 60° 36 9 70°,32 00 105° 54 55 .... 188 1 80°! 44 4 96°if>4 87 100° 180° 120° 132° 150° 148° 180° 173° 102° 280° 212° 184° 112° 260° 217c 392c 620c 212° H. 14-25 14-29 7-7 6-67 9-09 11-9 3-7 13-51 12-25 66 33-33 02 14-98 08 10-33 17 13-05 60 3-15 •5 9-1 17 13-51 79 84-21 S 94 S 47-06 CI 5 CI 41 N 1-58 48C1 7-69 •211 •79 6-66 5 41-10 8Cy 54-2 S 13C1 6S 1-7 11-9 55-4 CI. 42-67 '36-36 21-62 27-59 34-78 81-251 34-32 76-20 53-83 53-32 60-87 73-7 38-1 148 CONSTITUTION OF LIQUIDS. TABLE II. Representing the ultimate Constitution of the Volatile and Fixed Oils, with some other Compounds,—their Specific Gravity, Boil- ing Point, &c. Camphene........ Oil of Anise...... " Peppermint. " Lavender..... " Rosemary... " Camphor.... " Caraway .... " Juniper...... " Cinnamon.., " Sassafras.... Benzule.. ........ Naphthalin...... Paranaphthal.... Creosote.......... Petrolene......... Oil of bitr. aim. " Cloves........ " Spermaceti.. Hogslard......... Tallow............. Castor Oil........ Linseed Oil...... Olive Oil......... Resin............. Beeswax......... Camphor......... Sugar............. Gum............... Starch ............ Gluten............ Lignin............ Blood............. Flesh.............. Protein............ Cln H C14|H9 C-20 H, 0 h;, o Hw 0 H]00 H„J0 C12jHin'0 C48'HwO CiB|HMQ0 = 9 1 c 105 64 94 109 128 106 173 76 171 162 162 162 535 535 537 860 985 920 877 890 988 940 911 350 094 037 043 988 Relative Proportions by Weight in 100 Parts. C. H. O. 312° 881 j 11-0 ... -,81-4 | 7-98 10-62 ... 77-3 ,12-6 10-1 397° ... ! ... 365°' ... | ... '9-28 10-36 10-36 410° 89-00 572° ... 397° 72-42 536°, 88-5 79-50 70-02 79-5 79-098 78-996 74-000 76-01 77-21 75-94 80-60 600° 400 42-1 43-75 43-75 57-7 43-75 11-00 8-12 11-5 5-5G 7-42 11-6 11-146 11-700! 9-304 10-29 15-71 14-46 14-88 22-56 8-9 9-756 11-35 13-36 10-71 11-47 0-"i 6*77 6-77 7-8 6-77 12-63 942 13-33 7-93 |-51 5 [49-68 49-68 22 00 49-68 14 COHESION OF LIQUIDS. 149 Naphtha is composed of five atoms hydrogen and six of carbon, or of 87*75 parts by weight of carbon, to 12*25 of hydrogen in the 100. It is also more dense than etherine, and less volatile. Hence it would seem, that the elasticity of etherine exceeds that of naphtha, for the same reason that the elastic force of olefiant gas is greater than that of etherine; or that the elasticity of hydrogen exceeds that of olefiant gas. It has been found, that several of the essential oils are hydrocarbons, as the essence of turpentine, lemons, copaiva, bergamot and camphene, or camphogen; but that most of them are composed of hydrogen and car- bon, united Avith oxygen; or that they are oxides of hydrocarbons, as they have been termed by Dumas. The oil of mustard contains sulphur and nitrogen; the oil of bitter almonds also contains some nitrogen, according to Liebig and Wohler. When perfectly pure, it is composed of one equivalent of benzoxyl and one of hydrogen, the proximate molecule of which is 106. But the molecular Aveights of the volatile oils have not been accurately ascertained, owing to the fact, that they do not combine Avith bases without de- composition. They are of a pungent aromatic taste and odour; and many of them pass into the form of vapour at the temperature of boiling water; but some of them require a much greater heat. Dumas ob- serves, that their density is proportional to the quan- tity of oxygen they contain. The specific gravity and chemical constitution of the fixed oils are nearly the same; yet they require a temperature of about 600° F. to volatilize them. Why, then, it may be naturally inquired, if they consist 150 COHESION OF LIQUIDS. chiefly of carbon and hydrogen, is their cohesion greater than that of ether, alcohol, water and the essential oils ? The following facts may tend to throw some degree of light on this question. By ad\erting to the second table, it will be found that camphene, or camphogen, is composed of C10H8, united into one compound particle, the weight of which is 68, compared with hydrogen: whereas, the essence of lemon is composed of C5H4, making a proximate particle equal to 34, or one-half that of camphene. The consequence of which is, that the latter is much more volatile than the former, though their specific gravities are nearly the same. Cam- phene requires a temperature of 312° F. to make it boil, while the essence of lemon is highly volatile like naphtha. Camphene is the principal ingredient in oil of turpentine and camphor, both of which are oxides of camphene. Common camphor is composed of one equivalent of camphene to one of oxygen. There is also an artificial camphor, composed of hydrochloric acid one equivalent, united with one of camphene; while three equivalents of water and one of camphene make the hydrate of camphene; and five atoms oxy- gen to one of camphene, camphoric acid. Petrolene, which is obtained from petroleum by distillation, is, according to Boussingault, composed of carbon and hydrogen in the same proportions as camphene; but its proximate particle being just double that of cam- phene, corresponding with the difference between the specific gravity of their vapours, it possesses the con- sistence of a fixed oil, requiring a temperature of 536° F. to convert it into vapour. The product (asphaltine) COHESION OF LIQUIDS. 151 which remains after the distillation, is still more tena- cious. Naphthalin is composed of C10H4 united into one equivalent 64. It is a highly tenacious liquid, requir- ing a temperature of 400° for its volatilization. According to Dumas and Laurent, there is a combi- nation of carbon and hydrogen in the ratio of C15H4 (equivalent 94) which has been called paranaphthaldn. It is one of the last products from the distillation of coal-tar, and is less volatile than naphthalin. The atomic weight of sulphuric acid is 40, and that of naphthalin 64. When two equivalents of the former unite with two of the latter, the compound equivalent is 208 of sulphonaphthalic acid, (according to Fara- day,) forming a hard and brittle solid, that is soluble in water, alcohol and oils. Naphthalin also forms a dense and tenacious com- pound with chlorine. With cyanogen, sulphur, iodine, bromine, &c, it forms dense semi-liquids, the cohesion of AAhich augments in proportion to the increased magnitude of their compound equivalents. From the molecular constitution of camphene, oil of turpentine, cloves, peppermint, anise, naphthalin, &c, there can scarcely be a doubt that their cohesion, and that of the fixed oils, is greatly modified, if not Avholly determined, by the number and relative pro- portions of elementary atoms AArhich combine into com- plex molecules of larger size. Hence, etherine is more Arolatile than naphtha, and the latter than camphene. Camphene is more vnlatile than naphthalin, and the latter than paranaphthalin, although they are all com- posed of carbon and hydrogen. The equivalent of 152 COHESION OF LIQUIDS. camphene exceeds that of naphthalin, while the latter is less volatile; but this is owing to the fact, that cam- phene contains just double the ratio of hydrogen. By looking over the preceding tables, Ave perceive that the most volatile liquids are composed largely of hydrogen and of other elastic gases; such as hydro- chloric ether, nitrous ether, acetic ether, hydrocyanic and hydriodic ethers, chloride of nitrogen, nitric acid, (anhydrous,) pyroacetic spirit, &c.; all of which expand into the gaseous state at temperatures below 212° F., notwithstanding their proximate equivalents are large. But it was also shown, that carbon, phosphorus, sul- phur, iodine, bromine, and even arsenic, may be con- verted into permanent gases by combining chemically with hydrogen; that they receive from it a portion of caloric by Avhich their elastic force is increased, and that of the hydrogen diminished; that their volume and elasticity decrease in proportion to the size of their proximate particles, until they assume the liquid or solid form. The most singular circumstance con- nected Avith this subject is, that carbon should not be elastic at all temperatures, like oxygen, nitrogen, hy- drogen and their combinations. Considering the large amount of caloric evolved during its combustion, there is something very mysterious about the fixedness of charcoal at high temperatures. The whole theory of distillation and sublimation is founded on the different degrees of volatility in the various ingredients of solid and liquid bodies, from the rectification of the ethers, alcohol and the volatile oils, to the distillation of coal, by Avhich its carbon, hydro- gen and oxygen are volatilized in a state of carburetted COHESION OF LIQUIDS. 153 hydrogen, olefiant gas, carbonic oxide, &c, as in coal- gas. That the proximate molecules of tlie fixed oils, such as olive oil, castor oil, spermaceti, lard, tallow, &c, are larger than those of the volatile oils, would appear from a variety of considerations:— 1. They are generally opaque, and many of them obtained by expression from the seeds of plants; from which it is probable that they contain a mixture of gross particles, united with more volatile particles; and that they differ from essential oils in a manner some- what analogous to the difference between smoke, Avhich is composed of gross vapours, and the pure gases, Avhich are transparent and invisible. 2. In its ordinary state of impurity, oil of turpen- tine volatilizes slowly at 300° F., when a limpid oil passes over. At 360° it boils; but on losing its essen- tial oil, it becomes more tenacious, and requires a tem- perature of 500° F. to make it boil; thus, passing from the state of a volatile to that of a fixed oil. The oil of anise is composed of 10 atoms carbon, six of hydrogen and one of oxygen, making its proxi- mate atom equal to 74; Avhile the oil of peppermint consists of C10H10O, making its compound equivalent 78 : so that in their atomic construction they resemble naphthalin, forming a medium between the more vola- tile oil of lemons, and those termed fixed. According to Dumas, the oil of cloves is composed of 20 atoms carbon, to 13 of hydrogen and five of oxygen, making its proximate atom 173. It is ac- cordingly very difficult to volatilize, like the fixed oils; 154 COHESION OF LIQUIDS. from Avhich it is probable, that their atomic constitu- tion is similar, and determines their tenacity. When the volatile oils are exposed to the atmo- sphere, they absorb oxygen, by AAdiich they become re- sinous and concrete. The oil of turpentine is thus converted into rosin. By absorbing oxygen, the fixed oils become rancid; and much more rapidly in Avarm than cold weather; during Avhich process, carbonic acid is produced, and heat evolved, as in fermentation. Hence, the spontaneous combustion of cotton goods which have imbibed oily matter. Again, the mole- cular equivalent of starch, sugar and gum, is 162, 171 and 162; while that of the animal tissues is 535, ac- cording to the lowest estimates. Hence, the great tenacity of muscular fibre, of tendons, ligaments, membranes, and the difficulty of volatilizing them; as in the case of starch, sugar and gum. BOOK II. CHAPTER I. ON THE AGENCY OF CALORIC IN THE COHESION OF SOLIDS. " Among learned men, it is no unusual or unheard-of arrogance, wilfully to reject opinions which they cannot shake."—Bacon. It was long since observed by Lord Bacon, that the most important facts connected with the fundamental constitution of nature had been quite overlooked; such as "the cause of heat and light, weight and density, hardness and softness, solidity and fluidity, fermenta- tion and putrefaction, germination and organization" (Novum Orgcunum.) Although more than two centuries have elapsed since Bacon pointed out the radical defects of science, and the true mode of its regeneration, scarcely one of the above problems has been resolved in a satisfactory manner. Philosophers are still as much divided in regard to the nature of heat and light as they were in the time of Bacon, Galileo and Boyle; or the still more remote period of Plato and Aristotle. Sir Isaac NeAvton devoted many years to the inves- (155) 156 COHESION OF SOLIDS. ligation of light, and really accomplished much to- ward an elucidation of its physical properties; but without ever having inquired into its connection with heat, or its Avonderful agency in the Avork of the uni- verse. The same illustrious author resolved the cohesion of solids and the tendency of heavy bodies toward the centre of the earth into the same law Avhich de- termines the aggregation of planets, and their revolu- tions around the sun; but he did not identify the cause of uniAersal attraction Avith any known agent. In short, he did not distinctly unfold the fundamental principle of action in nature—of expansion and con- traction, density and lightness, hardness and softness, solidity and fluidity, chemical union and decomposi- tion. There is nothing more remarkable in the his- tory of science, than that the phenomena of attraction should have been so far unfolded and generalized, with- out any definite knoAvledge of their cause. It Avould seem that one of the first inquiries of the philosopher ought to be, what is the agent or cause of force, by Avhich the atoms of matter are held together? and that the most natural answer Avould be, that Avhich surrounds and fills the spaces betAveen them. It can no longer be disguised, that in regard to the cause of cohesion, capillary attraction and gravitation, Sir Isaac Newton has expressed himself with so much ambiguity as to leave his followers in great doubt whether he had any settled opinion on the subject. In the third book of the Principia, he maintained that universal space is a vacuum; or that it Is void of all sensible matter, and that the ultimate particles of COHESION OF SOLIDS. 157 bodies are endowed with inherent forces, or powers of attraction and repulsion* That he aftenvards renounced the vacuum of space and the self-motive power of atoms, is evident from the scholium which he added to the second edition of the Principia, his letter to Boyle, and from the Avhole tenor of the Opticks; in each of which he maintains the existence of an exceedingly subtile, active and elastic ether, as pervading universal space and the pores of all bodies. Considering the almost unbounded influence of Newton's authority on nearly all subjects connected with the science of nature, it is important that his real opinions should be distinctly understood. I shall, therefore, proceed to prove, by his oavii words, that he did not regard attraction as an ultimate law of nature, resulting from the inherent properties of atoms. In addition to the passages before quoted, in the first chapter of this Avork, he observes in the advertise- ment to the second edition of the Opticks: "to show that I do not take gravity for an essential property of bodies, I ha\re added one question concerning its cause, choosing to propose it by way of question, be- cause I am not satisfied about it for want of experi- ments." * Such, however, is the blinding influence of custom and au- thority, that men who have never found any difficulty in admitting Sir I. Newton's inherent powers of attraction and repulsion, are yet startled at the inherent powers of caloric, or the doctrine that it is a self-active principle. The self-motive power of spirit was beautifully symbolized by the Greeks, who represented Psyche standing on a car which moved itself. 158 COHESION OF SOLIDS. The same view is still further expanded in the third book of the Optlel-s, page 365. After observing that "all matter, even light, seems to be composed of ex- ceedingly small, hard and unchangeable atoms, which in the densest bodies touch only in a few points," he adds: "how they can stick together so firmly as they do Avithout the assistance of something which causes thein to be attracted or pressed toward one another, is very difficult to conceive."* He remarks, in another passage,page 369, "there are agents in nature capable of causing the particles of matter to stick together by very strong attractions, and that it is the business of experimental philosophy to find them out." Yet it is an undoubted fact, that nearly all the most distin- guished followers of Newton have represented him as teaching, that the sun operates upon the planets with- out any intervening mechanical medium; and that the matter of which planets is composed is held to- gether by virtue of inherent power, or innate forces, Avhich Newton expressly says that he could not con- ceive. Again: in a letter to Dr. Bentley, he says: " You sometimes speak of gravity as essential to matter. Pray do not ascribe that notion to me; for the cause of gravity is what I do not pretend to know, and therefore would take more time to consider." (Page 20.) He adds, in another letter: "That gravity should be innate, inherent and essential to matter, so that one body may act upon another at a distance * The same idea was advanced about 2000 years ago by Plato, who observes in the Timseus, that "it is impossible for two things alone to cohere, without the intervention of a third." DOCTRINE OF THE ANCIENTS. 159 through a vacuum, Avithout the mediation of anything else, by and through which their action and force may be comreyed from one to another, is to me so great an absurdity, that I believe no man who has in philoso- phical matters a competent faculty of thinking, can eA^er fall into it." (Third letter to Bentley, page 26.) It was truly observed by Bacon, that " the doctrines of great and original minds are often degenerated and embased by time; that while the lighter parts of their labours float down the stream of time, the weightier and more valuable frequently sink into oblivion."* This remark applies with great force to the miscon- ception and perversion of the ancient systems of phi- losophy, the most important features of which are but vaguely and imperfectly comprehended by the mo- derns. When Greece was the centre of light and civilization to the whole world, nearly all her most distinguished sages maintained the existence of an igneous principle, which extended throughout the universe. This powerful and omnipresent agent was regarded by them as the life of nature, and the cause of all concord and discord, (by which they evidently meant attraction and repulsion,) by virtue of which the celestial bodies were preserved in their respective courses, and connected as by an invisible everlasting chain; and without which there could be no genera- tion or dissolution of bodies. Such Avere the opinions of Pythagoras, Parmenides, Democritus, Heraclitus, Plato and many others. Hip- pocrates termed it "a strong but invisible fire which * Advancement of Learning. 160 DOCTRINE OF THE ANCIENTS. rules all things Avithout noise, and is neA^er in repose; which actuates and animates the Avhole system of nature." Here is a definition of heat in accordance with the discoveries of Dr. Black, but still more com- prehensive and important. Like the ancient Greek philosophers, Bacon reduced all matter to two classes, active and passive; the first of which he describes as rare, invisible and without weight, though a real and quantitative substance, per- vading and filling the pores of all gross bodies. I have already shown that this active spirit, to which Bacon referred all the motions and transformation of matter, is only another name for caloric. (See page 19.) But if this pneumatical body be the cause of all the changes of living and dead matter, it must be the cause of at- traction as Avell as repulsion; of decomposition and recombination. In his treatise on the Wisdom of the Ancients, Bacon further maintains that the attraction of matter was typified, among the early Greek philosophers and poets, by the elder Cupid, or principle of love; that it was the primitive cause of force, or the moving power of elementary atoms, which formed and organ- ized the universe of things out of chaos. He adds, by way of commentary on this ancient allegory, that "there is doubtless a primary and universal law of nature, which regulates the circular revolutions of the celestial bodies, and to which are owing all contraction and expansion of matterT In the third book of his treatise on the Advance- ment of Learning, he says, that whoever shall atten- tively observe the appetences of matter, shall receive HYPOTHESES OF BACON AND NEWTON. 161 clear information concerning celestial objects from things which are constantly seen around us; and that it is the object of science not only to ascertain the number, situations and periodic motions of the hea- 'venly bodies, but the physical cause of their mutual action upon each other, which he terms living astro- nomy, to distinguish it from that which is vulgar and empirical. It was also maintained by Newton, that all the phenomena of nature are resolvable into attraction and repulsion, which he referred to the agency of an all-pervading ethereal substance, capable of contraction and dilatation. But, as it is now demonstrable, that caloric alone is the cause of expansion and the elastic force of gases, Arapours and volatile liquids, there can no longer be the shadoAV of a doubt that it is identical with the ether of Newton, the pneumatical power of Bacon and the universal igneous principle of the an- cient Greek philosophers. Nor is it possible to deny that Newton has represented this principle as the proximate cause of cohesion, capillary attraction, che- mical affinity and of universal gravitation; all of which he viewed as modified effects of one and the same agent. But OAving to the vague and imperfect account Avhich he gave of it, philosophers have even doubted the reality of its existence, and treated it as a chimera of the author's imagination, invented for the purpose of sustaining his theory of nature. The consequence of which has been, that the law of gra- vitation has been regarded as a comprehensive gene- ralization of phenomena, for which no definite reason can be assigned; while the great and noble science of- 11 \Q2 NEAVTON, BLACK AND BUFFON. chemistry, which, in a practical point of view, is far more important than astronomy, consists of an im- mense collection of facts and experiments, the con- nection of Avhich Avith the phenomena of heat, light, electricity, cohesion, capillary attraction and gravita- tion, has never been distmctly understood, nor reduced to fundamental laws. Had Newton discovered the simple laAV by which the ether produces the opposite effects of contraction and expansion, he would probably have traced its agency in the phenomena of combustion, solution, vaporization and all the molecular changes of matter. Or, had Dr. Black and his successors fully compre- hended that universal law of caloric by which it attracts ponderable matter with a force that augments in proportion as bodies are deprived of it, they would have found that it is as capable, under such circum- stances, of becoming a powerful bond of cohesion, as it is, under other circumstances, of dissolving their union, and of converting them into elastic fluids. But they have all overlooked the force of attraction, by which this subtile fluid is concentrated around the particles of rude matter, and thus rendered latent; and by which its self-repulsive force is counteracted. Not being able to comprehend how one and the same agent could produce both attraction and repul- sion, Buffon maintained that the powers of nature, which are known to us, may be reduced to two: tlwi which causes weight, and that which causes heat; that to the power of attraction, joined to the cause of heat, may be referred all the phenomena of living and dead matter. Still the cause of attraction remained unex- DALTON, DAVY AND NEWTON. 163 plained. Had Buffon advanced but one step farther, he would have resolved all the forces of nature into one and the same cause. Since the discovery of latent heat by Dr. Black, philosophers have Adewed it as the antagonist of that universal force by which all things are held together. When treating of liquids, Dr. Dalton observes, that they must be considered as bodies under the control of tAvo most powerful agents, attraction and repulsion, the last of Avhich he refers to caloric. Sir H. Davy also observes, that heat, or the power of repulsion, may be considered as the antagonist of cohesion; the one tending to separate, and the other to unite the particles of bodies. (Chemical Philosophy, page 30.) Still the important question recurs, what is the cause of attraction ? Newton says, it is an effect of some un- known ethereal agent, and that it is the business of philosophy to find it out. What, then, is the internal constitution of matter? Are the pores of bodies void of all substance? or are they pervaded by subtile and active matter? If so, what is it, and what are the laws by which it ope- rates? It is quite certain, that until these important queries are resolved, the science of nature can never be established on the solid basis *of fixed principles, but must remain, as heretofore, imperfect and vacil- lating.* * it was supposed by Epicurus and his followers, that "the atoms of fluids were smooth and spherical, by which they were enabled to glide freely over each other; but that the atoms of solids were hooked," as if their forms could change on passing from the liquid to the solid state. He also maintained that the 164 LAPLACE AND MORVEAU. It requires no extended series of argument to prove, that whatever the cause may be which moves atoms, must also be the cause which moves the largest bodies, for the simple and obvious reason that they are made up of atoms. If it be true, that cohesion, capillary attrac- tion and chemical affinity, be only modifications of gravity, as maintained by NeAvton, Laplace, Buffon, Morveau and other philosophers, it follows, that the whole theory of nature, whether mechanical, chemical or physiological, is resolvable into that of atoms, and the cause by which they are attracted and repelled, united and separated. If Ave are capable of discover- ing the cause Avhich holds together the particles of a pebble, or crystal of ice, Ave are also capable of com- prehending the cause which binds all things together by gravity. Newton expressly affirms, that " the drops of fluids affect a round form by the mutual attraction of their parts, as the earth affects a round form by the mutual attraction of its parts by gravity." (Opticks, book iii. page 370.) It is self-evident, that if the particles of bodies be not endowed with inherent powers of motion, they pores of bodies were void of all matter. (De Naturd Rerum, book ii.) Others have supposed that the particles of bodies are glued together by an immaterial cement, as bricks are held together by mortar. (Baxter on the Immateriality of the Soul.) The Rev. W. Jones referred cohesion to the pressure of a cold ether, from the fact that liquids are converted into solids by cold. Ampere, Berzelius and some other modern philosophers have maintained that the atoms of bodies are endowed with electric polarity, or that their opposite sides are in different states of electricity; while the great body of chemists regard the whole subject as involved in pro- found obscurity. CAUSE OF COHESION. 165 must be impelled by some other agent; that is, they must act upon each other at a distance, without the agency of imy physical tie, or by some intervening medium. Thus it will be found, that the primary ob- ject of science is to ascertain the cause Avhich moves atoms, and the mode in Avhich it produces so many and diversified effects; that chemistry and natural philosophy are only different branches of one great science, Avhich cannot be studied separately from each other, without departing from the unity and simplicity of nature, all the operations of Avhich are governed by the same code of physical laws, from the aggregation of crystals to that of suns, planets and their satellites. I have shown, in the foregoing chapters, that the atoms of all bodies are surrounded Avith subtile and active matter, Avithout Avhich they could neither ap- proximate nor recede from each other; consequently, Avould be passive and motionless; that the various forces, movements and changes of form Avhich bodies undergo, are determined by the relative proportions of ethereal and ponderable matter of which they are com- posed; that Avhen the active principle predominates, they are decomposed, or expanded into gases, vapours, or even flame, Avhich is luminous ether; but that when the ratio of ponderable matter predominates, the at- traction of caloric for the latter counteracts its self- repulsiAre force; by which gases are chemically united into vapours, Avith contraction of volume and diminu- tion of elasticity, or condensed into liquids and solids. Perhaps the most fruitful source of error in plrysics has been partial and limited vieAvs of nature; and the confounding of phenomena or effects Avith the cause 166 CAUSE OF SOLIDITY. which produces them. Some modern writers on natu- ral philosophy speak of gravitation as though it Avere " the animating principle of nature." In the fifth vo- lume of the Cabinet Cydopedla, we are told that, "all the great changes and revolutions of the bodies which compose our system can be traced to, or derived from, this principle." And Professor Bonnycastle observes: " The single principle of gravitation pervades the Avhole universe, and puts every spring and wheel in motion." * * * "From this active, invisible and invigorating agent, proceeds all that order, harmony, beauty and variety, Avhich so eminently distinguish the Avorks of creation." (Astronomy, p. 184, 8th ed.) But if gravi- tation were a universal principle of action in nature, it ought to explain the phenomena of solution, repul- sion, evaporation, the expansive force of gases and ful- minating compounds; in short, it ought to account for all the operations of chemistry, geology and meteor- ology; Avhich is not the fact. It therefore follows, that there must be a principle of action in nature ulte- rior to that of gravitation, as admitted by NeAvton. It might as Avell be said that repulsion is the ani- mating principle of nature, as the general attraction termed gravitation. The true state of the case is, that both attraction and repulsion are subordinate, though universal effects of an all-pervading principle that surrounds every particle of matter in the uni- verse; to which may be referred the phenomena of heat, electricity, light, evaporation and combustion, together with all the diversified transformations of matter. It Avas by confounding the external world with the BERKELEY, LEIBNITZ AND KANT. 167 impressions Avhich it produces on the senses, that Berkeley was led to resolve the universe of matter into mind or spirit. What can we make of the mo- nads of Leibnitz,—without parts, extension, figure or divisibility,—the essential properties of which are, nevertheless, perception and appetite? The mathe- matical theory of Boscovich, before noticed, is equally beyond the power of human comprehension. In the same spirit of metaphysical subtlety, the celebrated Kant denied the existence of ultimate atoms, by as- suming that they Avere without extension or solidity; while he resolved heat, light, electricity and magnet- ism into the power of attraction and repulsion, as if such poAvers could exist without substance. Not less obscure is the modern doctrine which resolves light, heat and electricity into vibrations of some unknown hypothetical ether. Who can grapple with such sha- dowy and unsubstantial data? It is an exceedingly partial and superficial view of caloric to regard it merely as the cause of temperature, fluidity, vaporization, decomposition, &c.; for it is self- evident that if the attraction of caloric for metals, ice and other bodies augments in proportion as they are deprived of it, it must be an attractive as well as a repulsive agent—an ethereal bond of cohesion, the force of Avhich Agarics according to the relatiA^e propor- tions of caloric and ponderable matter. Every altera- tion in these proportions produces a change in the mechanical, chemical, and even Arital properties of bodies. That the force with which caloric combines ivlth, and is concentrated around the particles of ponderable matter. 168 RATIONALE OF COHESION. augments In proportion as they arc deprived of It, may be regarded as a fundamental axiom, derived from the general experience of mankind; and it is founded on a law of nature which connects all the phenomena of molecular attractions with the theory of latent caloric. Without the recognition of this important truth, it is impossible to comprehend the most familiar pheno- mena of every-day life—why, for example, the atmo- sphere abstracts from animal bodies their vital heat, Avith a rapidity proportional to the reduction of its temperature; or Avhy caloric is rendered a latent con- stituent of all matter. The attraction of ice for caloric exceeds that of Avater,( because it contains less of it than Avater; the consequence of Avhich is, that the particles of Avater are drawn closer together, and main- tained in the solid form with a corresponding force of cohesion. If it be objected that Avater expands during congelation, it may be answered that its particles are arranged in series, forming angles of 60° and 120°, making large pores or cavities. Were it not for this, the volume of ice and other crystalline bodies Avould diminish on assuming the solid form. That the vo- lume of ice is actually reduced, and its cohesion greatly augmented by the abstraction of caloric, is evident from the large fissures found in bodies of ice after an excessive frost, and from the rocky firmness which it exhibits.* Were it possible to reduce the temperature of ice 1000°, the attraction of caloric for it would be * In fact, M. Brunner has recently proved by experiment, that when the temperature of ice is reduced from 32° V. to 4° F., its specific gravity is considerably augmented. (Silliman>s Journal, Jan. 1846, p. lit.) RATIONALE OF COHESION. 169 immense; while there would be a corresponding aug- mentation of its density and cohesion. If the atoms of gold, silver, copper, iron, lead, tin and other metals, be surrounded Avith caloric alone, and if it have a definite degree of attraction for each, it must hold them together with a corresponding force of cohesion. Or if the atoms of oxygen, hydrogen and carbon, of vegetable matter, be surrounded with caloric, and nothing else, it must be the cause of their contraction and expansion, of their chemical union and decomposition, unless the atoms be endowed Avith inherent poAvers of attraction and repulsion; which is hypothetical and contrary to all analogy. Should it be maintained, that electricity is a con- stituent of all bodies, I answer, that electricity, as it exists in a state of combination Avith the particles of ponderable matter is identical a\ ith latent caloric. For the proofs of this identity, the reader is referred to the next book, where it will be demonstrated that solar caloric is the basis of lightning; and that under all circumstances, hoAvever various the phenomena of electricity, they are only modified effects of the same agent Avhich produces evaporation and solution. The general recognition of this important truth will banish from the science of nature an immense mass of hypothetical speculation, and much of that complexity which has hitherto baffled every attempt to explain, in a satisfactory manner, the connection of heat and elec- tricity Avith cohesion and chemical affinity. The ab- surdity of supposing that the atoms of bodies are surrounded with two distinct ethereal agents, one of which draAvs them together, while the other repels 170 THEORY OF COHESION. them asunder, is too obvious to require a serious refu- tation. By the attraction of caloric for ponderable matter, It unites and holds together all things; by Its self-repulsive agency, it sep>arates and expands all tilings. To Avhatever portion of nature's Avide domain avc turn our attention, Ave recognize the operation of this universal laAv. Hence it is, to use the significant lan- guage of Bacon, that " heat and cold are nature's two hands;" Avhich is a general though vague enunciation of the above laAv: for it is certain, that in a philo- sophical sense, the Avords heat and cold are only rela- tive terms, Avhich indicate different proportions of the same ethereal agent. It is because the attraction of caloric for solids ex- ceeds that of liquids, that their cohesion is greater than that of liquids. It is because the attraction of caloric for mercury is greater than for Avater, that the parti- cles of the former are held together with a greater force of cohesion. When reduced to the temperature of —39°, this cohesion is so far augmented that it assumes the solid form, and acquires the poAver of at- tracting other bodies, the temperature of which is higher. When the hand is applied to frozen mercury, it is also held with great force, as iron is attracted by a poAverful magnet when charged by a voltaic battery. It is therefore highly probable, that if the temperature of mercury were reduced —100°, it would abstract from animal bodies their vital heat Avith a force and rapidity resembling an electric shock; and that if it were possible to reduce its temperature a thousand de- grees below zero, the attraction of caloric for it Avould THEORY OF COHESION. 171 surpass all means of computation; Avhile its cohesion and density would be proportionally augmented.* It is owing to the attraction of caloric for gravitat- ing matter, that Avhen the hand is applied to iron, cop- per, gold, silver and other dense metals at very low temperatures, it adheres fast, and cannot be disengaged without lacerating the skin; or that when a portion of melted zinc is poured upon a solid plate of the same metal, there is a rush of caloric from the liquid to the solid, by Avhich their particles are forced together; that when Avater is poured upon a block of ice 15° or 20° belovv zero, it is immediately converted into the solid state, and incorporated Avith the ice by virtue of the same force which causes universal attraction. * It is because caloric has a stronger attraction for iron, copper, gold, silver, platinum and other dense metals, than for silks, furs, down, woollens, resins, bitumens, sulphur, coal, iodine, bromine, dry wood, potassium, sodium, with innumerable other light bodies, that they abstract it more rapidly from warm-blooded animals, and con- sequently feel colder to the touch. It is because caloric has a pow- erful attraction for the dense metals, that it is concentrated and held around their particles with immense force, and cannot be dis- engaged from them, even in small proportions, without the appli- cation of great mechanical pressure. Accordingly, we find that they are good conductors of caloric, and cohere together with a corresponding force of aggregation. Their cohesion and conduct- ing power are also augmented in proportion to their condensation by pressure, as in wire drawing; from which it follows, cseteris paribus, that their affinity for caloric, on which their cohesion and conducting power depend, increases with their density and loss of caloric. It is equally true of all other bodies, without a single exception, that their cohesion and conducting power are determined by the relative degrees of their attraction for caloric, which aug- ments in proportion as they are deprived of it. 172 THEORY OF COHESION. It is by the attraction of caloric for ponderable mat- ter that it combines Avith different bodies and produces their liquidity; it is also by virtue of the same attrac- tion, that liquids are enabled to dissolve and combine with other bodies. Philosophers have generally as- sumed, that cohesion is the antagonist of chemical affinity, and that they are produced by different causes. But the most obvious phenomena of nature demon- strate that they are produced by one and the same cause, and that all molecular combinations result from the attraction of caloric for other matter. The only difference between cohesion and chemical attraction is, that the one is exerted betAveen homogeneous atoms, and the other between heterogeneous atoms, which van- in size, and in the degrees of their affinity for caloric. It is owing to the attraction of caloric for ponderable matter, that Avhen a piece of tin is laid on a portion of melted lead, the tin is dissolved, and its particles intimately blended with those of the lead. In all such cases, it is undeniable that the atoms of the liquid are forced to combine with those of the solid, by the agency of caloric alone; for the obvious reason, that no other agent has been employed to pro- duce the effect. It is in this way that all metallic alloys are formed. If six drachms of solid zinc be brought in contact with an ounce of melted copper, there is a transition of caloric from the one to the other, by which the particles of zinc are transported from their original place, and intimately combined with those of the copper, by the same power which unites the atoms of individual metals. The fact is, that all the elements of nature THEORY OF COHESION. 173 may be united by fusing them together, and again separated by larger proportions of the same agent. If a mass of granite or basalt were plunged into a caul- dron of burning lava, they Avould be intimately incor- porated throughout by the transition of caloric from the lava to the solid rock. It is scarcely necessary to add, that the various materials of which all volcanic rocks are formed, are thus united and held together, by the same cause which maintains the solidity and cohesion of the earth. The art of plating bars of iron, copper, &c, with gold, silver, zinc, tin and other metals, is founded wholly on the cementing poAver of caloric, Avhich forces them together, by what may be termed chemical cohe- sion, to distinguish it from the aggregation of simple bodies. Plates of gold are made to unite Avith bars of iron and other metals, by being pressed together and placed in a stove or furnace. When bars or plates of iron are thoroughly cleaned and polished until quite bright, and immersed in melted tin, they are soon covered over with a thin white coat; or if a slip of copper be perfectly cleaned and polished, then heated, and rubbed over Avith a piece of tin, a portion of the latter metal combines with the copper, giving it a silvery coat, which adheres to it for the same reason that the hand adheres to frozen mercury, or other metals, when reduced to very low tempera- tures. The common mode of tinning copper vessels, is to make the surface bright by scraping and Avashing them Avith a solution of hydrochlorate of ammonia. They are then Avarmed, when the tin is melted and poured 174 THEORY OF COHESION. into them, by Avhich it incorporates with CA'ery part of their surfaces, and Avhen cold remains firmly united. In the same Avay, iron vessels are coated with zinc. It is Avell known that silex cannot be made to combine with potassa or soda to form glass without the agency of heat, Avhich is equally essential to the Avelding of iron and to the soldering of other metals. The ad- hesive property of wax, gum, sugar, &c, when in a state of fusion by caloric, is equally familiar to every one. The truth is, that all the internal and external pro- perties of bodies, whether mechanical or chemical, such as hardness and softness, density and lightness, tenacity and firmness, volatility and combustibility, are determined by their relations to caloric. It is Avell known to spinners and weavers, that the fibres of cotton, wool, flos-silk and flax, are brittle during cold weather, and that if their rooms are not kept at a proper temperature, their threads often break. On the other hand, some of the most brittle substances in nature, such as glass, may be spun into thread almost as fine as that of the silk-worm, when in a state of fusion by heat; while butter, lard and many other substances that are soft and tenacious Avhen warm, become hard and brittle at very low tem- peratures. The same is true of iron and some other metals, which become brittle like glass or ice during excessively cold weather. The rationale of this Avill appear from the general fact already established, that the attraction of caloric for bodies augments in pro- portion as they are deprived of it; the consequence of Avhich is, that it is more concentrated around their THEORY OF COHESION. 175 particles, which cohere with a corresponding force, producing great hardness; but Avhen by a blow, or any sudden force, they are removed in the slightest degree from their place, the cohesion is broken, and they fly asunder. In the state of liquids, their particles glide freely over each other, without losing their hold, as one magnet glides over another. This is the case with all the malleable metals, and with the tenacious oils, gums, glue, &c. until reduced to very low temperatures, when they all become more or less brittle like ice. It is OAving to the augmented cohesion and hardness of very cold iron that it will not bend, but snaps asunder, —that is, its particles refuse to glide over each other; Avhile, at higher temperatures, the greater extent of the igneous atmospheres that surround them holds on to them at greater distances, though with less force, causing toughness or tenacity. When tAVO pieces of lead, tin, zinc or any other soft metal, are pressed together with sufficient firmness, their atoms are brought within the range of this at- tractive medium. The same is true of the hardest substances, when softened by heat. Even polished plates of glass, marble, wood and many other bodies, Avhen brought into close apposition, cohere, but still better when fused together by heat. It was before stated that the ethers, alcohol and many other liquids, have no cohesion whatever at or- dinary temperatures; and when released from the pressure of the atmosphere, are expanded into vapours by the repulsive power of their latent caloric. They are accordingly very bad conductors, like silks, wool- lens, furs and other light bodies, that are full of ca- 176 THEORY OF COHESION. loric. Yet by a sufficient reduction of temperature, their attraction for the igneous principle is so far aug- mented, that their particles are drawn closer toward each other, and bound together in the solid form; and if their temperature could be reduced 1000° F. there is every reason to believe that their cohesion Avould equal that of salts, rocks, or even the denser metals. From all the foregoing facts and arguments it is evident, that attraction and repulsion, hardness and softness, solidity and liquidity, density and lightness, are not essential conditions of bodies, but depend on the relative proportions of ethereal and ponderable matter of which they are composed; that the most elastic gas may be reduced to the liquid form by the abstraction of caloric, and again converted into a firm solid, the particles of which would cling together with a force proportional to their augmented affinity for caloric. On the other hand, it is equally evident, that by adding a sufficient quantity of the same principle to the densest metals, their attraction for it is dimi- nished, when they are expanded into the gaseous state, and their cohesion destroyed. Having met with a few individuals who cannot readily conceive how a self-repulsive agent can operate as a bond of cohesion between the particles of common matter, it may be proper to show, by a few familiar examples, that the force with which liquids hold to- gether the particles of solid bodies, is not in proportion to the attraction of their own particles for each other, but in proportion to their affinity for the solids. It is Avell knoAvn that at ordinary temperatures of the atmosphere, the particles of water cohere Avith very THEORY OF COHESION. 177 slight force, if not deprived of air. It is also known, that when granite, lime, clay and marble, together with all other rocky and earthy bodies, are reduced to the condition of a perfectly dry and impalpable powT- der, their particles glide freely over one another, hav- ing little or no attraction for each other. On adding to this powder a due proportion of water, they are found to unite together by a very strong attraction, forming dense and highly tenacious mortar. The less water such ingredients contain, the stronger is their attrac- tion for it. Hence it is, that the cohesion of mortar augments in proportion as it is deprived of Avater by drying; or that when the earth has been parched by a long drought, it attracts and absorbs more rapidly a shower of rain, than Avhen in a moist state, in the same way that all bodies absorb caloric Avith a force and rapidity in proportion as they are deprived of it. In like manner, the cohesion of mortar is diminished by adding to it larger proportions of water, in the same manner that the cohesion of ice, metals and other bodies, is lessened by increasing their temperatures; that is, by altering the relative proportions of caloric and ponderable matter. Innumerable liquids might be mentioned, the atoms of which have no cohesion among themselves, which, nevertheless, operate as a bond of union among the particles of various other solids Avhen in the state of powder. It is by virtue of the affinity between wheat flour and water, that they form a cohesive dough; and so of a thousand other bodies, the particles of which have little attraction for each other, without the medium of a liquid; but if caloric be indispensable 12 178 THEORY OF CONDUCTION. to fluidity, it must be the ultimate and efficient cause of attraction between liquids and solids. It is the caloric of melted wax, glue, paste, gum, molasses, &c, by Avhich they are enabled to combine with and hold together the particles of solid bodies, for the same reason that the caloric of melted metals, rocks, &c. enables them to combine with solids, and to hold them together. If sulphate of lime be reduced to the state of powder, its particles have scarcely any cohesion for each other; but if converted into mortar by the ad- mixture of water, they cohere into a rocky cement, the firmness of which is in proportion to the force of attraction between the water and the lime. In fine, the more profoundly we scrutinize the ope- rations of nature, the more evident it becomes, that all the modifications of force by which the particles of bodies are united, depend on the agency of a self-repul- sive ether. It is therefore ridiculous to maintain, that an agent which repels its own particles, cannot hold together the particles of other bodies. THEORY OF CONDUCTION AND RADIATION. The most general and well-established fact con- nected with conduction is, that all the lightest bodies in nature are bad conductors of caloric and electricity; such as furs, eider down, silks, woollens, cottons, resins, lac, bitumens, phosphorus, dry wood, &c. among solids; and ether, alcohol, oils and water among liquids; while gases are still worse conductors; whereas, the densest known bodies are good conductors, such as gold, silver, copper, iron, zinc, tin, lead, &c. Next to the pure THEORY OF CONDUCTION. 179 metals in conducting power, are rocks, gems, flint- glass, porcelain and the denser liquids, as solutions of the acids and alkalies. Owing to their extreme fusi- bility, it is difficult to determine the conducting power of potassium and sodium; but it is certain that they are bad conductors of caloric, and probably worse than water, in proportion to the difference between their specific gravities. It has also been proved in the preceding chapter, that all the lightest known bodies are composed of large proportions of caloric, (which repels its own particles,) compared with the quantity of ponderable matter. The atoms of gases being surrounded by extensive atmospheres of caloric, are therefore bad conductors. It Avas found by Sir Humphrey Davy, that when metals, such as mercury, tin and arsenic, are con- verted into the gaseous state, they become, like other gases, non-conductors of electricity. (Works, vol. ii. p. 22.) The same thing is true, though in a less de- gree, of all the lighter liquids and solids. On the other hand, the atoms of the metals which contain less caloric around them in proportion to their size, and being closer together, attract and conduct it from one to the other, with different degrees of ra- pidity; modified by the arrangement of their atoms, and perhaps by other circumstances not yet fully un- derstood. It is, doubtless, owing to the crystalline structure of ice, that it is a worse conductor of elec- tricity than water. May it not be owing to the same cause that glass, resins, sulphur and some other bodies are better conductors of electricity in the liquid than in the solid state? 180 THEORY OF CONDUCTION. That the conducting poAver of all bodies augments in proportion as they are deprived of caloric, other things being equal, may be regarded as absolutely certain. The conducting power of metals is increased in pro- portion to their condensation by pressure, for the same reason that it is augmented by a reduction of tempera- ture,—that is, owing to the loss of a portion of tlieir heat. Caloric has a stronger attraction for pure metals than for their oxides, chlorides, fluorides, bromides and iodides; their specific gravity, cohesion and con- ducting power are also greater.* The connection of this subject with the philosophy of radiation is exceedingly important, and seems never to haAre been rightly understood. It was ascertained by a great variety of experiments performed by Dr. Wells, Avith a view of explaining the production of * Lord Bacon observes, in the Second Book of the Novum Or- ganum, that it should be inquired why metals and stones feel colder to the living body than the fur of animals, silks, woollens, feathers, wood, &c; whether the latter contain more inherent heat than the former; and if so, whether it be owing to their oily nature, or to the air which they contain. Dr. Thomson thinks that it is owing to the air within their pores; while the great mass of writers on Chemistry and Physics, resolve the whole mystery by telling us, that they are bad conductors of caloric, which is the very thing to be explained. The hypothesis of Dr. Thomson is so far from affording a solution of the difficulty, that he does not explain why air is a bad conductor. The simple matter of fact is, that all those articles of clothing which retain the caloric of the body most effect- ually, contain a large amount of the igneous principle, and are therefore bad conductors. For the same reason, they are highly combustible; and, when submitted to friction, afford abundance of the electric ether; on which account, they have been called elec- trics. THEORY OF RADIATION. 181 dew. He found that eider down, wool, cotton, grass, the leaves of trees and all vegetable substances, parted with their caloric more rapidly by radiation, than rocks and metals; that while dew collected in large quan- tities on the former, during clear nights, there was generally little or none on the latter. But no one seems to have suspected, that the radiating power of bodies was determined by their latent caloric, or that it was even modified by their attraction for it. It was supposed by Prevost, whose opinion has been adopted by a majority of writers on Chemistry and Natural Philosophy, that the tendency of all bodies to an equilibrium of temperature, is owing to a per- petual exchange of caloric from one to the other by radiation. But it is evident from the foregoing facts, that the motions of caloric by which it passes out of one body into another, are owing to its attraction for ponderable matter, as well as to its self-repulsive or radiating poAver. When a hot body is placed in vacuo, and at a distance from other bodies, it parts with caloric by radiation alone, Avith a rapidity propor- tional to temperature. When placed in atmospheric air, it loses the same quantity of caloric by radiation, while an additional portion is abstracted by the con- tiguous particles of air. It is generally stated, that bodies cool about twice as fast in air as in vacuo. Count Rumford found that a thermometer cooled from 212° F. to 32°, in vacuo, in.......10 m. 5 sec. in air...... 7 3 Avater.....1 5 mercury .... 0 36 182 THEORY OF RADIATION. But if it be true that all bodies attract and absorb caloric aa ith a force and rapidity in proportion as they are deprived of it, it is obvious that in air, —50°, the thermometer Avould sink much more rapidly. It is equally obvious, that when placed in water, mercury and other dense liquids, the effect is produced wholly by the attraction of caloric for them, and Avithout radiation. It was before stated, that caloric has but little atr traction for the metallic oxides, compared with the pure metals; and that their cohesion, specific gravity and conducting power are accordingly small. The ex- periments of Leslie prove that their radiating power is much greater. He found that while the radiating power of clean lead was only 19, it rose to 45 when tarnished by oxidation; that the radiating power of plumbago was 75, and that of red lead 80. He also discovered, that while the radiating power of gold, silver, copper and polished tin was only 12, that of croAvn-glass was 90, sealing-wax 95, resin 96, writing- paper 98, and lamp-black 100. In short, all light bodies, which are full of latent fire, and therefore bad conductors, are proportionally good radiators; while the denser metals, which con- tain less of it, hold on to it for a longer time, under the same circumstances. But as their affinity for caloric diminishes in proportion as they acquire more of it, they also radiate freely at very high tempera- tures. On the other hand, if the dense metals could be reduced 1000° below zero, they would attract and conduct it with a force and velocity like lightning. The more careful and reliable experiments of Dr. THEORY OF RADIATION. 183 A. D. Bache and of J. Brocklisby, have proved that colour alone exerts no influence upon the radiating power of a surface. It has been long known that metallic vessels, such as tea-urns, retain their temperature much longer than vessels of stone, earthenware, wood, &c, Avhich have less affinity for caloric than metals; and that the same metallic vessels retain their temperature longer when highly polished than when rough. The latter effect would seem to be owing to the closer proximity of the particles composing a smoother surface; for it has been found, that when wood is reduced to sawdust, it ra- diates more rapidly than in the solid state; that locks of wool, cotton, flos-silk, &c, radiate better than the same materials when spun and woven, by which their fibres are brought closer together. So when the par- ticles of a metallic surface are brought near to each other, they have a stronger affinity for caloric than Avhen more distant, and thus prevent it from flying off, for the same reason that the cohesion and con- ducting power of metals are augmented by condensa- tion, as in wire drawing. Melloni found that the radiating power of metals was impaired by polishing their outer layers, which are thus condensed by the pressure used, and that cast silver radiates one-third more than hammered silver, which is more dense; the polish of surface being the same. Is it not owing to the same cause, that electricity escapes more rapidly from rough surfaces which consist of innumerable points, than from such as are smooth and highly polished ? Connected Avith this subject is another fact, that 184 THEORY OF RADIATION. has never been explained, and which may appear at variance Avith the above theory of radiation, until duly considered. It has been ascertained by Leslie and other experimenters, that the reflecting power of bodies is Inversely as their radiating power; and that their power of absorbing caloric is proportional to their ra- diating power. It was discovered by Newton, that the surfaces of glass and polished marble are covered over by an invisi- ble and repulsive medium, which prevents tlieir actual contact, even when pressed together with great force. It is doubtless owing to this elastic and repulsive ether, Avhich adheres to polished metals by a still stronger attraction, that when Avater is poured upon them, it glides over, without wetting or touching them; and that steel needles' are enabled to float on the surface of water, notwithstanding their greater specific gravity. It is this thermo-electric ether Avhich prevents polished metals from absorbing caloric, and causes it to rebound from their surfaces by reflection; while light bodies, and metals that are rough or un- even, which contain less of the repulsive medium over their surfaces, absorb more and reflect less caloric. CHAPTER II. CHEMICAL ATTRACTION. "Of the great and comprehensive laws, which rule over the widest provinces of natural phenomena, few have yet been dis- closed to us."—Whewell. Whether in a practical or philosophical point of view, a perfect theory of chemistry would be of far higher importance than that of universal gravitation; for it Avould lead to a knowledge of all the properties of the elements by which Ave are surrounded, and of their application to the extension of human happiness. Yet there never was a period in the history of science, when greater uncertainty prevailed in regard to the primary cause of chemical action, than at the present time. The celebrated (Erstedt regards the science of chemistry as in the same condition now, that mechani- cal philosophy was in the age of Galileo, Descartes, Huygens and Newton; and he maintains that no gene- ral principle has been discovered which governs all affinities. (Snr YIdentite des Forces Chimlques et filec- trlques.) Notwithstanding the recent progress of atomic che- mistry, Dr. Prout observes, that this great science "is founded solely on experience, for the phenomena of which Ave can assign no reason." (Bridgewater Ti-eatise, (185) 186 CHEMICAL ATTRACTION. p. 29.) On the same subject, the language of Professor WheAvell is still more emphatic and precise. In the concluding chapter of his Treatise on Astronomy, he states, that "no one has pointed out any common fea- ture between chemical affinity and the attractions of which ire hwiv the exact effects; and that we arc still more pro- foundly ignorant of th e vital principle." Lord Brougham also observes, in his Natural Theology, that " we know little or nothing of the minute motions by which the particles of matter are arranged, when bodies act che- mically on each other." (Vol. i. p. 373.) Lastly, Liebig says: "the ultimate causes of combinations and de- compositions are chemical forces, and these differ from all other forces, inasmuch as we perceive their exist- ence only by their manifestations when bodies come into immediate contact Avith each other." (Letters on Chemistry, p. 32.) Alas ! if this be a true representa- tion of the actual state of human knowledge, is it not high time that men should awake from their lethargy, and observe more attentively all the circum- stances connected with chemical action? It was pro- foundly observed by Bacon, that "in all generation and transformation of bodies, we shoidd inquire what is added, what remains and what is lost,—what is united and what is separated,—what hinders, what commands and what gives the motion." (Novum Organum.) This is the true character of the inductive philoso- phy; careful observation, rigid analysis, the rejection of all hypotheses and the undue authority of distin- guished names, must ultimately lead to the solution of all physical mysteries. It is doubtless an object of great practical importance to know the proportions in CHEMICAL ATTRACTION. 187 which the elements of ponderable matter unite to form water, alcohol, ether, acids, alkalies, salts, rocks, &c.; but it is still more important to know Avhat the agent is, by Avhich they are brought together and maintained in a state of intimate combination. That the ancients regarded fire as the great agent in all the transformations of nature, would appear from the etymology of the word chemistry, which, like the Greek xyueca, Chemeia, was deriAed from the Oriental HD'D, Chime, signifying Heat, according to the learned Parkhurst. But Sir William Drummond quotes a passage from Zosimus, of Panopolis in Egypt, who states, on the authority of the Hermoic books, that the art Chemeia took its name from the word Chema. (Orlgines, vol. ii. p. 264.) Noav it is remark- able, that this Avord was employed, with slight dia- lectical variations, by se\reral of the most ancient Oriental nations, to represent Heat. By the Egyp- tians it was called DPI, Khem, or Ham with the aspi- rate. By the Chaldeans and Hebrews it Avas called ("Olf, Kheme, or chema, signifying the solar Fire, which the Arabians called hama. In fact, the word hama, Heat, has been traced in the old Pahlivi language, which has been regarded by competent authorities as the mother of the Sanskrit, the Zeud of Persia, the ancient Kouwen of China, and some other Asiatic tongues. Nor is it unAvorthy of notice, that the name of Brahma Avas derived from the Sanskrit bra, to create, and hma, or homa; signifying the creative Fire. The proximate agency of caloric in chemical affinity might have been long since recognized, but for the difficulty of comprehending how a self-repulsive agent 188 CHEMICAL ATTRACTION. could become a cause of attraction. But it is self- evident, that if a globule of ice be composed of oxjgen, hydrogen and caloric; and if there be an attraction between the particles of ice and caloric, they must be held together with a force equal to that attraction; and so of all other bodies. Besides, if it Avere de- monstrated, that some other ethereal agent, such as electricity, surrounds the particles of ice, it must have an attraction for them like caloric, or it could not be- come a bond of union. It therefore follows, that in either case, the effect results from one and the same fundamental law, which involves an identity, or unity of causation. In addition to Avhat was before stated, page 177, the following facts will further illustrate the manner in which a self-repulsive agent becomes a bond of union between the particles of inert matter, Avhich have no inherent affinity for each other. It is Avell known, that the particles of ether, alcohol and many other volatile liquids, repel each other with such force, that when the pressure of the atmosphere is removed, they fly asunder, and assume the form of elastic vapours, thus presenting the character of an idio-repulsive agent. It is also knoAvn that when the particles of resin, charcoal and hundreds of other bodies, are reduced to the state of an impalpable pow- der, like the dust of our roads after a long drought, they have little or no attraction for each other; but that if they be brought into contact with the above volatile liquids, they cohere with considerable force. Why? Undoubtedly because there is a mutual at- traction between the liquids and powders, which coun- CHEMICAL ATTRACTION. 189 teracts the repulsive force of the liquids, and prevents them from flying off in the form of vapour. It has been long knoAvn that platinum when reduced to the form of a black powder, absorbs about 800 times its volume of oxygen gas, which is thus condensed around its molecules. During this process, the caloric Avhich maintains the oxygen in the gaseous state must be giA^en out, yet so gradually that no sensible eleva- tion of temperature is observed. When a jet of hydrogen gas is thrown upon the poAvdered platinum, it combines Avith the oxygen condensed in the interior of the mass, by which water is generated, and heat evolved, until the hydrogen is inflamed, and the platinum made red hot. If the jet of hydrogen be interrupted, the pores of the platinum become im- mediately filled again with oxygen; showing that this absorption of gases by porous solids is greatly aug- mented by caloric. We are further authorized to conclude, that the latent caloric of oxygen is the cause of its primary combination with, and condensa- tion around, the molecules of platinum: for Avhen raised to the temperature of 572° F., poAvdered glass possesses the same property of absorbing and condensing oxygen as spongy platinum at ordinary temperatures of the atmosphere. In fact, there is a large class of metals, Avhich, Avhen reduced to a state of minute division, combine rapidly Avith oxygen at ordinary temperatures: such as iron, nickel, cobalt, uranium, lead, &c. When iron is in mass, it has but little ten- dency to oxidation: but Avhen firmly pulverized, it cannot be brought in contact with atmospheric air 190 CHEMICAL ATTRACTION. Avithout becoming red hot, and converted into an oxide. If the particles of dust had no cohesion for each other whatever, they would represent the condition of ultimate atoms Avholly deprived of caloric, which could neither approximate nor recede from each other. At the temperature of 67° F. water is an elastic fluid in vacuo; but if a thin film of water be placed between tAvo plates of glass in an exhausted receiver, they cohere together, because the water is more strongly attracted by the glass, than repelled by its OAvn par- . ticles. However imperfect such illustrations may be, they are sufficient to prove that a self-repulsive agent may become a bond of attraction to other bodies. But the fact which must forever set this question at rest is, that the attraction of all bodies for caloric aug- ments, cceterls paribus, in proportion as they are de- prived of it, and that their cohesion augments in the same ratio. To those philosophers who have regarded electricity as the proximate cause of molecular attraction, it may be somewhat surprising that I have proceeded so far without an examination of the facts on which the electro-chemical theory was founded. To this I answer, that no general law of electric action has ever yet been pointed out capable of ex- plaining all the phenomena of molecular forces; in short, that nearly all the leading facts, connected with the theory of electricity, are involved in the utmost obscurity and uncertainty. I have shown that caloric is a universal and inde- pendent agent, which may be everywhere recognized CHEMICAL ATTRACTION. 191 as a source of power and motion—of contraction and expansion—of solution and recombination; and that it is a principle of action in all the proceedings of nature. But, in regard to electricity, we are not informed by those Avho assign it as the cause of chemical action, Avhether it be a material agent which may be added to, and subtracted from ponderable matter, or a mere effect resulting from the inherent properties of com- mon matter. The electro-chemical theory of Sir Hum- phrey Davy Avas founded on the well-known fact, that Avhen bodies are in different states of electricity, they • attract each other. Starting from this point, he as- sumed, first, the existence of two electric fluids, each of which has an attraction for the other, and repul- sion of its own particles; secondly, that all bodies Avhich combine chemically, are in opposite states of electricity. Finding that the atoms of oxygen, chlo- rine, fluorine, iodine and bromine, were attracted by the positive pole of the voltaic battery, he inferred that they were combined with negative electricity; while all those bodies that were attracted to the nega- tive extremity of the battery, were supposed to be electro-positive; and that in consequence of the attrac- tion existing between such bodies, they rushed into a state of chemical combination, when the two electri- cities assumed the form of light, or fire. (Phil. Trans- actions for 1806.) It would be an irksome task to detail all the objec- tions that might be urged against this ingenious hypo- thesis. That it Avas not understood by Sir H. Davy himself, is manifest from the fact, that, in the same 192 CHEMICAL ATTRACTION. Lecture, he asks the question, " May not the remote cause of electrical energy be identical with chemical affinity, and an essential property of matter?" He also observes, in his Chemical Philosophy, that "elec- tricity seems to result from the general powers and agencies of matter." How is it possible to reconcile or comprehend such vague and contradictory views? Had not this distinguished chemist attached him- self in early life to the hypothesis, that " caloric was a mere effect," instead of being an all-pervading and sufficient cause of motion, his OAvn experiments Avould have led him to perceive that caloric and electricity are mutually convertible into each other; for he Avas among the first to demonstrate that electricity is capa- ble of producing the same effects which are usually ascribed to caloric. By means of a wire, connected Avith the poles of a battery, he caused Avater and other liquids to boil. Let us examine briefly some of the consequences which flow from the hypothesis that caloric results from the combination of two electric fluids, admitting for the present, (what has never been established,) that electricity consists of two mutually attractive fluids. The hypothesis assumes in the first place, that all the elements of ponderable matter are reducible to two classes, one of which is united Avith positive, and the other with negative electricity; the mutual attrac- tion and combination of which produce the pheno- mena of heat, and the chemical union of bodies. But it is self-evident, that if heat result from the union of two electric fluids, all simple bodies must be without CHEMICAL ATTRACTION. 193 caloric, until they unite chemically, which is contrary to matter of fact; for it has been proved in the pre- ceding part of this work, that all bodies are composed of cedorlc and ponderable matter; a fact which cannot be predicated of electricity, unless we admit, that, in its latent or combined state, it is identical with the omnipresent igneous principle. It is impossible to imagine anything more at variance with common sense and the universal experience of mankind, than the supposition that caloric is the offspring of elec- tricity ; or that an universal agent should be the effect of any other power which is not universal. Another objection to the electro-chemical theory arises from the fact, that bodies which are assumed to be in the same electric state, unite chemically. For example, oxygen combines with chlorine, iodine and bromine, making chloric, iodic and bromic acids; while sulphur, phosphorus, carbon, hydrogen and the metals, which are considered to be in an opposite state of electricity from the above elements, combine chemi- cally with each other as well as with oxygen, chlo- rine, &c. Besides, it is not true that oxygen, chlorine, iodine and bromine, are uniformly in the same electric state; for it is very Avell known that when chloric acid is decomposed, its elements are conveyed to diffe- rent poles of the battery; that Avhen sulphurous and sulphuric acids are decomposed by the pile, sulphur goes to the negative pole; but that when sulphuretted hydrogen is decomposed, sulphur goes to the opposite pole; that Avhen carbon, selenium, arsenic and tellu- rium are united with oxygen, they are positive, but negative with hydrogen; proving that bodies are 13 194 CHEMICAL ATTRACTION. neither essentially positive nor negative, and that they vary in this respect according to circumstances; consequently, that all classifications of bodies founded on their electric polarities are fallacious. Dr. Thomson obsen^es, that " if chemical affinity were merely the result of different states of electricity, bodies could not remain united unless these different electrical states were permanent. But if the positive and negative electricities combine and fly off in the form of fire, there must be an end of the different electrical states which caused them to unite, and of course the union must cease, which is contrary to matter of fact." (Thomson on Heat and Electricity, p. 335.) A still more fatal objection to the electro-chemical theory is, that it affords no explanation Avhatever of cohesion or simple aggregation; whereas I have shoAvn that the particles of homogeneous bodies are held to- gether by the same cause which maintains the chemical union of heterogeneous elements; that the particles of copper are held together by the same agent that causes it to combine with zinc and other metals: but avIio has ever maintained that the atoms of homogeneous bodies are in different states of electricity? It is not surprising that M. Becquerel, Avho follows Davy and Berzelius in referring chemical attraction to electricity, should have admitted that cohesion is a stumbling block (la pierre d'achoppement) in the way of every attempt hitherto made to connect the theory of chemistry with that of electricity. (T)~aite tfftlec- tricite et du Magnetlsme, torn. iii. p. 369.) Those who regard caloric and electricity as distinct CHEMICAL ATTRACTION. 195 agents, and the latter as the cause of chemical affinity, make caloric the cause of repulsion. Nothing could be more absurd than such partial and contradictory views of nature. Has it not been known, ever since electricity was first studied as a science, that it pos- sesses the power of repulsion as well as caloric? I have also proved that the effects of caloric are not limited to its self-repulsive agency; that it has an uni- versal attraction for ponderable matter, and repulsion of its own particles, by virtue of Avhich it binds bodies together, or tears them asunder, according as it per- vades them in greater or less proportions; and it will be shown hereafter, that all the motive powers of elec- tricity, whether of high or low tension, are governed by the same fundamental laAv; that all the most pow- erful displays of electric action are only modified effects of that principle or essence which warms in the life-giving solar beams, and preserves the universe in a state of unceasing motion. It is because philosophers have not sufficiently ex- amined the relations of heat and electricity, and the laAv by which they are connected with ponderable matter, that almost every department of Physics has become involved in profound obscurity. It is self-evi- dent, that if electricity be a bond of union between the particles of bodies, it must have an attraction for them; a circumstance which has been overlooked by Davy, Berzelius, Ampere and their followers. Dr. Thomson observes, that "with respect to the unknown link which unites electricity to atoms, and keeps it united with them, Ave are quite in the dark." (Inor- ganic Chemistry, vol. i. p. 40.) 196 CHEMICAL ATTRACTION. Never can the science of chemistry be reduced to the simplicity of established principles, until men shall recognize the relations of caloric and electricity, and the universal law by which they are connected with ponderable matter. When a bar of iron is charged Avith the electric ether, it attracts iron filings, Avhich collect around it in large bunches, each particle clinging to the others, like bees suspended from the branch of a tree. But if electricity be a self-repulsive agent, it must have a still stronger attraction for the particles of iron, or it could not become a temporary bond of union between them; and that it is the true cause of magnetic air traction in soft iron, is obvious from the fact, that when it is Avithdrawn the attraction is destroyed. At the same time, it is equally evident that elec- tricity is not the generic principle of action in nature. If so, it ought to be everywhere present under all cir- cumstances ; but so far is this from being the fact, that in its most copious and concentrated form, (that of lightning,) its manifestations are only occasional and momentary. Besides, if electricity were the prime mover, it ought to be the cause of fluidity, evapora- tion, vapourization and those expansions of the atmo- sphere on which all its circulations depend. It is true that when sufficiently concentrated, it produces the same phenomena which are universally ascribed to caloric; that is, it raises the temperature of bodies, converts solids into liquids, vapours and gases; ignites combustibles, and produces the chemical union of bodies. If then there be any truth in the great fundamental IDENTITY OF CALORIC WITH ELECTRICITY. 197 axiom, that the same effects must be referred to the same cause, it is clear that electricity is only a modification of the omnipresent igneous principle. This identity is indicated by the fact, that when a current of the electric fluid is made to combine with metals, until they are melted or ignited, its properties are so far changed, that it no longer produces a shock, but in all respects exhibits the same phenomena which result from the heat of combustion. Dr. Hare attributes the explosive power of gunpowder and other fulminating mixtures to electricity, which is wholly unintelligible on the supposition that caloric and the electric fluid are distinct agents; for it is certain that the expansive force of all such compounds is owing to their sudden conversion into gases, and that gases are expanded by caloric as certainly as that the elastic force of steam is due to the same agent. A thousand facts might be adduced to prove the radical identity of caloric and electricity. Those light and highly combustible bodies which afford the largest amount of caloric by friction, such as furs, silks, wool- lens, resins, sulphur, &c. also afford the largest propor- tions of electricity during the same process, and there- fore have been termed electrics. Moreover, the strong acids, which give out the most heat during chemical action, afford the largest supply of electricity Avhen acting on the metallic plates of a voltaic battery. Again, those bodies for which caloric has the strongest attraction, such as metals, conduct it most freely. The same is true of electricity. Hence it is that both caloric and electricity disappear most rapidly when in the vicinity of good conductors, being at- 198 CHEMICAL ATTRACTION. tracted by them and incorporated with their substance. It is thus that flashes of lightning are absorbed by the earth and rendered latent. Or, if a light feather be charged Avith electricity, and suspended in the still air of a room, at equal distances from sticks of resin, sul- phur, glass and metals, it will approach the latter in preference to the former, cceteris paribus, with a force and rapidity that varies inversely as the squares of the distance. If it be true that caloric and electricity be only modifications of the same agent, the electro-chemical theory becomes intelligible, and may be reconciled with the chemical agency of caloric. For example, those bodies which have the strongest tendency to unite chemically with each other, are said to be in opposite states of electricity. It is also certain, that the same bodies which contain different quantities of caloric, are most disposed to unite chemically; while those which have nearly the same relations to caloric have little attraction for each other, such as sulphur and phosphorus, potassium and sodium; the reason of which is, that a transition of caloric from one body to another is indispensable to all chemical combinations. Every chemist knows, that he cannot carry on his distillations, separations and recombinations, without the agency of heat. But, regarding this as an inci- dental circumstance, he resorts to the agency of elec- tricity for a solution of the problem, Avithout inquiring into the source of this mysterious agent, or whether it could have any existence independent of the igneous principle. The controlling agency of caloric in the phenomena CAUSE OF CHEMICAL ATTRACTION. 199 of chemistry, may be traced in all the decompositions and recombinations that are perpetually going on throughout nature. The truth of this proposition is attested by the vast amount of chemical action within the torrid zone, and within the temperate latitudes during summer; while in the regions of perpetual con- gelation there is no chemical transformation. It is well known, that animal and vegetable matter may be preserved Avithout alteration for unlimited periods of time, in conservatories of ice or snoAv.* It is therefore obvious, that if the earth could be wholly deprived of solar caloric, all its chemical motions and changes Avould cease. It was admitted by Dr. Black, that "heat Is indispensable to chemical action, by overcoming the cohesion of bodies, and thus enabling them to exert their attractive powers." But I have proved that the agency of caloric is not confined to the mere separa- tion of bodies; that the same agent Avhich expands * Nothing could more clearly illustrate this fact, than the ac- count of a huge elephant (or mammoth) discovered in the midst of a large mass of ice on the shore of the frozen ocean, near the mouth of the river Lena in Siberia; where it must have remained for thousands of years, as it belonged to an extinct species. When first discovered, in 1799, by a Tonguiese fisherman, the carcass was perfectly fresh and entire, parts of which were given by the neigh- bouring Jackouts to their dogs; while the remainder was devoured by wild beasts, after its disengagement from the ice, when its skin, bones and teeth were removed to Petersburg. Its neck was co- vered with a long mane, and the rest of its body with black hairs and a reddish fur or wool. The tusks were nine feet long, and weighed 350 pounds. For further particulars in regard to this curious discovery, see Cuvier's account, extracted from the Me- moirs of the Petersburg Academy, and quoted by Bertrand in his Revolutions of the Globe. 200 CAUSE OF CHEMICAL ATTRACTION. them into vapours and gases, causes them to unite chemically Avith each other, to form neAV compounds, in obedience to the same law by Avhich liquids are enabled to dissolve and unite chemically with solids; that is, by the attraction of caloric for ponderable matter. The most extraordinary fact connected Avith the history of modern science is, that while cedorlc is con- stantly employed in all the operations of chemistry, and the arts of everyday use, several distinguished modern philosophers have refused it a separate nu- merical station among the elements; treating it as an incidental or subordinate effect of those powers and changes of which it is the primary and efficient cause. When Count Rumford and Sir H. Davy supposed that heat was motion, they mistook the effect for the cause; for I have shown that all the contractions and expansions of bodies, whether solid, liquid or gaseous, result from their various relations to caloric. If a portion of alcohol or water be put into a Florence flask, their particles remain comparatively tranquil; but when placed over a burning lamp, a rapid intes- tine motion begins, and augments in proportion to the increase of temperature, until they are driven off in the form of steam. Nothing, however, could be more absurd, than to confound the motion of ebullition Avith its cause, which is evidently something derived from the lamp; for when the source of heat is removed, the ebullition and vapourization cease. When Lavoisier pointed out the extensive agency of oxygen in combustion and fermentation, he over- looked the still more important fact, that the chemical WHAT IS PHLOGISTON? 201 power of all bodies is augmented by every addition of caloric; and when Davy observed, that combustion was the solution of bodies in oxygen gas, he over- looked the fact, that all gaseous bodies are solutions of ponderable matter in caloric, without which they could not dissolve and combine chemically with other bodies. It was maintained by Beccher and Stahl, that all bodies contained within them an exceedingly subtile, elastic and active principle, which they termed phlo- giston, and which was disengaged during the process of combustion, producing the phenomena of heat and light, or fire. Many and long were the disputes of philosophers concerning the nature of phlogiston. While many maintained that it was a material sub- stance, Lavoisier is supposed to have demonstrated that it was only an imaginary something, invented for the purpose of explaining the mystery of combustion. That Stahl regarded phlogiston as the cause of heat and inflammation, is evident from the etymology of the Avord, which signifies heat or fire. From what is reported of Dr. Black's unpublished Lectures on Respiration, it would seem that he con- founded phlogiston with the carbon secreted from the lungs; for he maintained, that a portion of atmo- spheric air unites Avith phlogiston in the lungs, and that animal heat was disengaged during the process. (Leslie on Animal Heat.) The celebrated Scheele supposed that heat Avas com- posed of phlogiston and empyreal air, (oxygen,) and that light was composed of phlogiston and heat: while Kinvan supposed that phlogiston was identical with 202 LAVOISIER'S THEORY OF COMBUSTION. inflammable air, (hydrogen.) Such were the vague and contradictory opinions of philosophers in regard to the nature of heat, light and phlogiskni, during a great part of the preceding century. After the discovery of latent heat by Dr. Black, and of oxygen by Priestley, the theory of Stahl Avas gra- dually superseded by that of Lavoisier. This cele- brated chemist maintained that oxygen consisted of caloric and light, united with a ponderable base, and that during every case of combustion this base com- bined with the burning body, by which its volume was diminished; while the caloric and light of the oxygen were given out in the form of fire. It is scarcely necessary to add, that this theory Avas also found to be exceedingly defective and erroneous in nearly all its essential conditions; that atmospheric oxygen is not indispensable to the process of combus- tion, nor the exclusive source of caloric and light; that all bodies contain definite quantities of caloric in a latent or combined state, and may be expanded into flame or light by a sufficient quantity of the same principle.* He was equally mistaken in supposing * When carbon, sulphur, phosphorus, boron and the metals are heated in vacuo, they become luminous without the agency of oxygen. Another decisive proof that oxygen is not the only source of light is, that the colour of the flame varies according to the nature of the combustible. Hydrogen affords a bluish light; potassium and many other bodies, burn with a red light. Hence it is, that bituminous coal burns with a bluish light when only partially ignited, because the hydrogen alone is volatilized, while its carbon remains fixed. Hence also it is, that around the bottom of a candle flame, where the heat is not sufficient to ignite the carbon, there is always a circle of bluish light, which proceeds from the combustion Lavoisier's theory of combustion. 203 that the condensation of oxygen was always neces- sary to combustion. It is doubtless true, that during the chemical union of gaseous oxygen with metals, its volume is greatly diminished, and a large amount of heat disengaged, by which the metals are expanded into the luminous state when the process is rapid. But it is equally certain, that the combustion of other bodies is at- tended Avith expansion instead of contraction of the combining materials, as illustrated in the third chapter, Avhen treating of explosion and deflagration. It is here worthy of special attention, that while Lavoisier pointed out the vast abundance and importance of oxygen in combustion, respiration, acidification and fermentation, he did not explain the cause of oxida- tion, which is indispensable to a theory of combustion. Nearly all the phenomena of chemistry may be re- ferred to combustion and solution. Fermentation, re- spiration and putrefaction, are slow combustions, to which caloric is equally essential, as to every case of solution, liquefaction and Arapourization. It is well knoAvn to every practical chemist, that water is gene- rated by combustion; that nitrogen, carbon, sulphur, phosphorus, selenium, chlorine, iodine, boron, arsenic of hydrogen. When potassium is thrown upon water, it enters into a state of vivid combustion; the water is decomposed, and the metal expanded into red light. At the same time, a portion of the hydrogen thus decomposed, unites with the potassium, pro- ducing a beautiful purple and rose coloured flame; that is, the blue and red colours on combining produce a reddish purple. Query,— May not all the diversities in the colours of heterogeneous light resulting from combustion be thus accounted for in a very simple manner? 204 CALORIC THE CAUSE OF OXIDATION. and some other bodies, have no affinity for oxygen at very low temperatures; but that when caloric is added in sufficient quantities, a rapid oxidation takes place, as in ordinary combustion, by which acids are generated—that when potassium, sodium, barium, lithium, calcium, magnesium and strontium, are heated in atmospheric air, they combine rapidly with its oxygen, forming alkalies; that Avhen alumi- num, glucinum, yttrium, thorinum and zirconium, are heated Avith oxygen gas, new compounds are generated, termed earthy bases; and that when the other metals are exposed to a high temperature, they are converted into acids or metallic oxides. At the temperature of 32° F., oxygen has no per- ceptible attraction for iron. Hence it is, that in the polar regions, and during excessive winters in the mid- dle latitudes, metals are not corroded by oxidation, but speedily acquire a coating of rust in tropical climates.* The process of oxidation augments with every addition of caloric up to the fusing point. It is therefore pre- posterous to maintain, that the attraction of metals for oxygen is owing to some inherent property of their particles, or that caloric operates merely by overcom- ing their cohesion, and thus enabling their chemical forces to come into play. So powerful is the attraction of iron for oxygen when raised to a white heat, that * If a piece of cold polished iron be inserted into fluid mercury, there is little or no attraction exerted between them; but if the iron be made red hot before immersion, it acquires a coating of mercury, which adheres firmly. Even gold, which adheres to mer- cury at common temperatures, attracts it still more powerfully when heated, and so of other metals. CALORIC THE CAUSE OF OXIDATION. 205 it takes it from potassium, Avhich, at ordinary temper- atures, is the most easily oxidized of all the metals. As the attraction of potassium for oxygen is known to be augmented by every increase of temperature, there is every reason to believe that its latent caloric is the primary and efficient cause of the chemical force by which it is enabled to decompose water, or even ice; and that if its temperature could be sufficiently re- duced, its affinity for oxygen would be destroyed. In accordance with this view of the subject, it is Avell known that phosphorus, sulphur and the most combustible compounds of hydrogen and carbon have no affinity for oxygen at very reduced temperatures, but attract it rapidly when assisted by heat. It would therefore be a waste of time to multiply proofs that caloric is the cause of oxidation. There is hardly a substance in nature with which oxygen may not be made to unite under the influence of heat. Finding it impossible to overlook the agency of caloric in chemical affinities, Sir H. Davy maintained that "it gav-e freedom of motion to the particles of bodies, and exalted their electrical energies." (Phil. Ti-ansactions, Nov. 1806.) It is also observed by Berzelius, that "a great num- ber of bodies seem to possess but feeble affinities at ordinary temperatures of the atmosphere, which ac- quire very active powers of attraction when raised to high temperatures." (Des Proportions Chimiques, p. 57.) This illustrious chemist might have added, that the chemical power of all bodies is exalted by every addi- tion of caloric, and diminished by its abstraction. All » 206 LIGHT OF COMBUSTION. the destructions and regenerations of matter may be referred to that laAv of caloric by which it repels its own particles, and attracts those of ponderable mat- ter. By its self-repulsive property, caloric dissolves, expands and decomposes all things; by its affinity for ponderable matter it contracts, unites and holds to- gether all things; thus causing the centrifugal and centripetal forces of nature. By the agency of heat, chlorine, fluorine, iodine and bromine, are made to combine with sulphur, phosphorus, metals, &c. by which new compounds are generated, termed chlorides, fluo- rides, iodides and bromides. When carbon, sulphur, phosphorus and other bodies are heated with metals, they are converted into carburets, sulphurets and phos- phurets. By the agency of solar heat the oxygen of the atmosphere is made to combine with the elements of dead animal and vegetable matter, Avhich are thus constantly undergoing a slow combustion or dissolu- tion during summer, by which new combinations are formed. It has been said that iron and other metals may be kept in a state of ignition for unlimited periods of time without any loss of their substance. Nothing could be more unfounded. The truth is, that the in- candescence or luminosity of all bodies, caleris paribus, is in proportion to temperature; while they are vola tilized and dissipated in the same ratio. When iron is raised to a red heat, the oxygen of the air combines with it, as in cases of ordinary combustion, by which the process is kept up; but if they are heated in vacuo, the ignition ceases when the heat is withdrawn, because there is no oxidation. LIGHT OF COMBUSTION. 207 It is necessary to distinguish the quantity of light produced by combustion from its intensity. When lime, magnesia and many other fixed bodies are sub- mitted to the high temperature of an oxy-hydrogen blow-pipe, they are slowly dissipated, with the disen- gagement of a most dazzling and intense light, but in small quantity; whereas, if ether, alcohol, naphtha, wax, tallow, oils, resins, phosphorus, sulphur, cotton, paper, silk and many other inflammable compounds, are submitted to one-third of the above temperature, a far greater quantity of light is produced, but of much less intensity: yet Dr. Lardner observes: " there is rea- son to believe that all bodies begin to be luminous when heated, at the same temperature." (Treatise on Heat, p. 24.) On the other hand, when charcoal is ex- posed to the concentrated heat of a large voltaic bat- tery, it is expanded into light, which in splendour almost rivals that of the solar beams; yet not in such great quantity as during the process of ordinary com- bustion, by which more carbon is ignited. The con- centrated heat of a forge while acting upon iron and other metals that are difficult to volatilize, creates a light so intense, that it strikes upon the eye-balls like finely comminuted sand. But the same degree of heat acting upon an equal weight of oil, wood or bituminous coal, Avould produce one hundred times the quantity of light, though of much less intensity. That modification of light termed phosphorescence, is generally the result of a slow combustion. Being • produced at very low temperatures, it is both small in quantity, and of low intensity. 208 GENERAL CONCLUSIONS. From all the preceding facts and observations it would appear,— 1. That the heat of combustion results from the disengagement of that principle which holds the par- ticles of bodies together; and that what is called the polarity of atoms, or the electro-positive and negative conditions of matter, depend upon its plus and minus relations to caloric. 2. That the attraction of caloric for ponderable mat- ter is modified by every chemical change which the latter undergoes, whether of combination or decom- position, contraction or expansion. 3. That the light of combustion or flame, results from the ultimate division of ponderable matter by caloric, which is diffused in all directions by radiation with extreme velocity; and that without the volatili- zation of combustible matter, there could be no arti- ficial light. CHAPTER III. CHEMICAL SOLUTION. "Veniet tempus quo posteri nostri apperta nos nescisse mi- renter. "—Seneca. Could we take in at one view the whole system of nature, we should behold, throughout, one vast theatre of solution and crystallization, of decomposition and recombination. We should perceive, that the atmo- sphere always contains an immense quantity of water diffused through it in a state of invisible transparent vapour, until it meets with colder currents of air, when it is condensed and precipitated in the form of rain, snow or hail, by the abstraction of its solvent principle. All lakes, rivers and springs contain greater or less proportions of the rocks, salts and metals, that compose the crust of the earth through which they pass, in a state of chemical solution; that are carried down by running water and deposited on different parts of the great "ocean floor." We should observe many thousand hot springs, issuing from the sides of mountains and from the bot- tom of the sea, charged with enormous quantities of earthy and metallic bodies in solution; which are pre- cipitated as they cool down, forming new strata of rocks and earthy deposits. 14 (209) 210 CHEMICAL SOLUTION. Could Ave look through the earth as through a great crystal, and behold all its molecular motions and changes, as we do the formation of a salt by the aid of an oxy-hydrogen microscope, we should be transported Avith admiration of a scene at once so grand, simple and beautiful. The exquisite mechan- ism by Avhich crystals are generated, is carried on by the regular arrangement of atoms in series and aggre- gates, the forms of which are determined by the most exact mathematical laws, by the adjustment of atoms, far too small to be discerned with the most powerful microscope. During the crystallization of a drop of muriate of ammonia, magnified three million times, and reflected on a large white ground, many thousand small crystals are seen shooting in every direction as the solution evaporates, which coalesce and form one solid crystal. Still more admirable is the process of organization by which the particles of Avater, air, car- bonic acid, ammonia, &c. are converted into plants and animals, endoAved with irritability, sensibility and the power of attracting nourishment for their support; Avhile solution or fluidity is essential to every vital process.* < * A complete history of the Mississippi river would afford an instructive example of the power of water in slowly dissolving rocks and transporting them to distant regions. Receiving, as it does, many large tributaries, that are fed by a thousand smaller streams, which drain more than a million square miles of territory, they pass through every variety of rocky strata. Some of its largest tributaries, such as the Ohio, Missouri, Kentucky, Cumber- land and Tennessee rivers, meander through extensive regions, based on secondary limestone, which extends, with occasional inter- ruptions, from Alabama to the Falls of Niagara; and varying from CALORIC THE UNIVERSAL SOLVENT. 211 That caloric is the universal solvent of nature is evi- dent from the fact, that it converts all solid bodies Into liquids and gases or vapours, which are reconverted Into solids by Its abstraction. It is equally clear, that if caloric be the cause of all liquidity and vapourization, it must be the menstruum by which liquids and elastic fluids are enabled to dissolve other bodies. The most remarkable facts connected with solution, may be reduced to the following propositions:— 500 to 2000 feet in depth. Through these immense beds of an- cient limestone, they have furrowed channels from 200 to 500 feet deep. By their chemical solvent power, hundreds of subterranean caverns have been gradually formed in the long lapse of ages, with all those beautiful calcareous crystals termed stalactites, with which many of them are so gorgeously decorated. All valleys and river beds are slowly formed by the chemical and mechanical agency of running water. Many springs also contain in solution large quan- tities of carbonate of iron, which, as well as lime, makes a cement that binds into solid masses the beds of loose sand through which they pass, forming sandstone. Were we to follow out this subject in a geological point of view, we should find that a great portion of the solid materials that have been thus removed from the numer- ous valleys drained by the Mississippi, have been transported to the Gulf of Mexico, which it is slowly filling up; while the rest is conveyed by the Gulf Stream into the wide Atlantic to form new rocks, after having travelled thousands of miles in a state of invisi- ble solution. The amount of soil, gravel and sand which are washed down from mountains, hills and plains into the valleys during floods of rain is enormous. A large proportion of Louisiana, which con- tains about 48,000 square miles, is composed of vegetable mould, pebbles, gravel, sand and clay that have been conveyed by this great river into the Gulf of Mexico. Immense masses of floating trees are also deposited on its banks and islands and at its mouth, which are covered by sand and clay, where they will be gradually converted into beds of coal. Thus it is that'everything in nature is in a state of perpetual transition and revolution. 212 CALORIC THE UNIVERSAL SOLVENT. 1. That all fluids are chemical combinations of caloric Avith ponderable matter. Water is composed of oxygen, hydrogen and caloric; sulphuric acid of oxygen, sulphur, water and caloric, and so of other liquids, the elements of Avhich are chemically com- bined Avith it in definite proportions: 2. That no solution of a solid in a fluid e\Ter takes place, without a transition of caloric from the solvent to the sol vend: 3. That the solvent power of water and other men- strua is exalted by caloric and diminished by its ab- straction : 4. That the solutions of animal, vegetable and mineral substances in water and other liquids, are strictly chemical combinations. These propositions being admitted, it folloAvs, ac- cording to the most rigid principles of logic, that if caloric be the cause of solution, it must also be the cause of chemical attraction, by which salts, rocks and metals are held in a state of intimate combination with liquid menstrua. It may be objected, that caloric is not the universal sohent of nature, because lime and magnesia are more soluble in water at 60° F. than at 212°. But if it be true that lime and magnesia, like all other bodies, are dissolved in unlimited proportions by hot springs, such exceptions disappear, and therefore cannot invalidate the general fact. It is stated by Mr. Lyell, to Avhom the science of geology is very largely indebted, that the warm springs which supply the baths of San Filippo, near Rome, contain in solution so large a quantity of calcareous HOT SPRINGS. 213 and magnesian rocks, that they have been knoAvn to deposit in a pond a mass thirty feet thick in twenty years. (Principles of Geology, vol. i. p. 204.) Mr. Lyell seems to suppose that the carbonic acid contained in hot springs, is the chief cause of their solvent power. But it is well known that sulphate of lime and many other rocks, are dissolved by hot springs Avithout the aid of carbonic acid. It is there- fore evident, that the solubility of lime and magnesia is augmented by heat, as certainly as that the fusi- bility of all other rocks and metals is augmented by it. It is highly probable, that the carbonic acid found in hot springs, has been driven off from a state of com- bination Avith lime by the agency of intense heat. Few geologists are aware 1ioav large a proportion of the calcareous, magnesian and silicious rocks distri- buted over our planet, have been deposited from hot springs. Mr. Lyell has shown, that A^arious parts of Italy and Sicily are covered over by strata of lime- stone thus formed, several hundred feet deep in many places. It is impossible to have enlarged views of chemical science, if Ave confine our observations to the petty operations of an artificial laboratory. Those who do so tell us that silex is insoluble, or nearly so, in Avater. But those who look to the great laboratory of subter- ranean chemical action, where the heat is far more intense than man can produce, will find that silex is there dissolved as copiously as sugar in boiling Avater; and that it is deposited in vast quantities by hot springs, such as the geysers of Iceland, the valle das furnas of St. Michael and innumerable others that 214 SILICIOUS PETRIFACTIONS. issue from volcanic regions, forming opal, chalcedony and various silicious gems. The flinty deposits found in the chalk-beds of Europe have doubtless been derived from submarine hot springs. Many of the marine fossils found in the chalk are composed of silica,—a fact Avhich cannot be otherwise accounted for.* * It is related by Mr. Barrow, in his Visit to Iceland in 1834, that the streams which proceed from the geysers of Iceland deposit a white silicious rock, of a close compact texture, resembling white marble. This is an exceedingly interesting and important fact to the geologist. The author was once greatly embarrassed on finding beautiful strata of perfectly white silicious rocks, which had been obviously deposited from water, inclosed between masses of basalt, greenstone and other volcanic rocks in the mountains of North Carolina, more than 4000 feet above the ocean level. As all the other portions of those mountains consisted of granite, gneiss, por- phyry and other igneous rocks which had been elevated by subter- ranean heat, the existence of the white sedimentary rocks remained a mystery, until the agency of hot springs was investigated. The geysers rise up through volcanic rocks, in an island where the eruptions of lava are so enormous as to fill up gorges many hundred feet deep and two hundred feet wide. When not confined in narrow valleys, they expand into broad lakes of melted rocks that vary in thickness. Were such eruptions to cover the white silicious strata deposited by the geysers, (as they undoubtedly have done, and will do again,) they would be inclosed between igneous rocks, like the snow-white flinty strata in the mountains of North Carolina. All animal and vegetable petrifactions composed of silex have been doubtless formed in waters holding this mineral in solution, from the most minute animalcules and delicate moss agates, to the largest fragments of silicified wood. Mr. Barrow states, that on the margins of the numerous little streams in the neighbourhood of the great geyser, every description of wood, bones, the horns of animals, and even paper, worsted stockings, handkerchiefs, &c. were found in a silicified state. SALINE SOLUTIONS. 215 It is stated by Gay-Lussac, that the solubility ot sulphate of soda in water, is augmented by every ad- dition of temperature from 32° to 91*4°, and then diminishes up to 212° F. (Ann. de Chim. et de Phys. xi. 296.) It has been also said, that chloride of sodium (com- mon salt) is not more soluble in water at 212° than at 60.° Whatever may be the cause of such anomalies, they do not afford the slightest proof that caloric is not the solvent, for this plain reason, that when a solution of common salt is exposed to great cold, it is precipitated and the Avater becomes nearly fresh; that is, when the agent which held it in a state of chemical combination with the water is withdraAvn, it falls down; which clearly proves that the chemical attrac- tion of water for the salt is owing to its caloric. Hence it is, that sea water is deprived of nearly all its salt by congelation, as demonstrated experimentally by Danes Barrington,—a fact which the author has seen verified on a large scale. In the month of January, 1834, when the Bay of New York was frozen over, the ice that covered it was found to be but slightly brackish. It is therefore evident, that if the ocean could be frozen The steam emitted from volcanos is charged with a great variety of rocks, salts and metals in a state of solution, which are deposited in the crystalline form as the solutions cool down. When melted silex cools under the pressure of a mass of lava, making rock crys- tal, a portion of steam is sometimes inclosed within its centre and condensed into water, where it remains for unlimited periods of time. All geodes are probably formed by the cooling down of lava, that contained steam or other gaseous fluids within their inte- rior, which, escaping by percolation, if the rocks be porous, had left their centres hollow. 216 OBJECTIONS ANSWERED. throughout, it Avould not be capable of holding its salt in a state of chemical combination, but that it would fall to the bottom, constituting a solid stratum, varying in thickness with the depth of the ocean. Dr. Turner states, that common salt dissolves in twice and a half its own Aveight of water at 60°; from Avhich, and the preceding facts, it follows, that if the ocean were satu- rated Avith salt and afterwards frozen, it Avould deposit a stratum more than one-third its depth. It is likeAvise obvious, that the tropical ocean must contain more salt in suspension than the Polar seas, especially during winter, and in the vicinity of ice- bergs or other frozen masses.* If it be maintained that caloric is not the solvent of sulphate of soda, lime and magnesia, because they are more soluble in Avater at 60° than at 212°, the same mode of reasoning would prove that caloric is not the solvent of sulphur, which is well knoAvn to be perfectly liquid at 230° F., but becomes viscid at 300°, and continues so up to 400°. In reply to such objec- tions, it may be stated in the first place, that no chemical union ever takes place until one at least of the combining bodies is reduced to the fluid state,- and that caloric is essential to all fluidity: secondly, that the chemical force by which water is enabled to dis- * It can hardly be denied, that sugar is chemically combined with cider by the agency of caloric ; for it is well known that dur- ing the congelation of sweet cider, its sugar falls down, and may be found at the bottom of the vessel which contains it, in the state of a highly concentrated syrup. But if afterwards exposed to warmth, it is again taken up and recombined with its watery sol- vent, which thus acquires its original properties. BERZELIUS AND DR. ARNOTT. 217 solve and combine with animal, vegetable and mineral substances, is exalted by every addition of tempera- ture, in a thousand cases for one exception. And I have shown that the above examples afford no real exceptions to the principle, but confirm it; that sul- phate of soda and common salt are far more soluble in water at 60° than at 32°; that lime and magnesia are perfectly soluble in hot springs, Avhich owe their sol- vent power to intense subterranean heat. Berzelius supposes that the greater solubility of lime and magnesia in cold than boiling water, is owing to a portion of carbonic acid that is almost always found combined with cold water; but Avhich is driven off at a high temperature. Whether this be regarded as a true explanation of the fact or not, it is generally ad- mitted by chemists, that carbonic acid augments their solubility in water. This however does not fully resolve the problem, since the solubility of sulphate of soda increases A\dth the temperature from 32° to 91*5° F., and then diminishes slightly, up to 212°.* Dr. Arnott admits, that the solution of a solid in any gas or fluid menstruum is merely another mode of melting it by heat; and that the menstruum itself is fluid only because of the heat Avhich it contains. (Ele- ments of Physics, vol. ii. p. 47.) This is a true statement as far as it goes; and it is highly probable, that if this philosopher had renounced the inherent attractive properties of atoms, as Newton did on second thoughts, he would not have added the * M Lassaigne has recently shown that water saturated with carbonic acid dissolves more carbonate of lime at 50° F. than at 32°. (Journ. de Ch. Med., Fevrier, 1847.) 218 INFUSIONS MADE BY CALORIC. following sentence. "A menstruum dissolves other bodies, merely because its attraction for them brings their particles into union Avith the heat AAThich already exists in it." Why then should water at 212° exert a stronger attraction for salts than Avater at 32°? Why should hot water ascend through porous solids and capillary tubes more rapidly than cold water? Why should boiling water dissolve 18 times more nitrate of potassa than ice-cold water? and 20 times more chlo- rate of potassa? Why should boiling Avater attract and dissolve, or combine chemically with the aromatic constituents of tea, coffee and a thousand other vege- table products, more rapidly than cold water, if caloric be not the combining agent ? or Avhy are the chemical affinities of all bodies modified by every addition and subtraction of caloric, if it be not the ruling principle of action in all solutions? That caloric is the medium by Avhich Avater is en- abled to combine chemically Avith salts, will appear from another view of the subject. For example, those salts for which caloinc has the greatest affinity, have also the strongest extraction for water. The consequence of which is, that they absorb it from the atmosphere, pro- ducing what is termed their deliquescence; and when dissolved in water they absorb its caloric, by Avhich cold is produced. It is likewise OAving to the powerful attraction of caloric for such salts, that when dissolved in water they are so difficult to congeal; that is, they require an intense degree of cold to abstract from them that portion of caloric which maintains them in a state of chemical combination with water. When I come to CONGEALING POINT OF SOLUTIONS. 219 treat of freezing mixtures, it will be seen that solu- tions of potassa and chloride of lime, formed by mix- ing them with snow, remain liquid at 82° and 83° below the freezing point of water. The same thing is true of many other salts, though to a less extent. It is oAving to the attraction of caloric for common salt, that sea water will not freeze at 32°, but requires a further reduction of temperature to pro- duce the effect, when it gives up a portion of its heat and the salt falls down. When 30 per cent, of com- mon salt is dissolved in water, its freezing point is re- duced to 0°. Moreover, the cohesion of the solution is so far augmented, that its boiling point is raised to 224° F. In like manner, all those salts for which caloric has a strong attraction, and therefore produce cold during their solution, elevate its boiling point; such as nitrate of potassa, nitrate of soda, acetate of soda, tartrate of potassa, muriate of ammonia and many others.* Dr. Lardner states, that the solution of a salt in * It is owing to the affinity of caloric for sulphate of soda, that when dissolved in hot water, and tightly corked up in a phial, it cools down without crystallizing, if kept perfectly still. But if shaken, a portion of the caloric which held it in a state of combi- nation with the water is disengaged, when the phial becomes warm, and the solution crystallizes. If the cork be withdrawn, the same effect is produced, owing to the mechanical pressure of the atmo- sphere, which forces out of the solution a portion of its caloric. By inserting into it a piece of ice, or any salt that has an affinity for caloric, crystallization is produced, for the same reason that all other fluids are congealed by the abstraction of their caloric. It has been said that a film of oil retards the crystallization, which is no doubt the fact, because it is a bad conductor of caloric, and therefore prevents its ready escape. 220 COHESION OF SOLUTIONS. water diminishes the cohesive force of the liquid, and therefore lowers its freezing point. (Treatise on Heat, p. 194.) The fact however is just the reverse, for a saturated solution of chloride of calcium in Avater requires 42° more caloric to OArercome its cohesion than pure water; that is, it requires a temperature of 264° F. to make it boil. In other words, the particles of water, which are held in a state of chemical union Avith the salt by caloric, have a stronger attraction for the particles of chloride of calcium than for each other; therefore they cannot be separated and driven off in the form of vapour without an augmentation of temperature. From the preceding facts and observations we are brought to the general conclusion, that the deliques- cence of salts, the production of cold during their so- lution in water, the low temperatures at which they congeal and the high temperatures at which they boil, are all determined by their relations to caloric, which holds them in a state of chemical combination with water. THEORY OF FREEZING MIXTURES. It was before stated that no solution of a solid in a liquid ever takes place without a transition of caloric from the solvent to the sol vend. The truth of this proposition is strikingly illustrated by the phenomena of freezing mixtures. When water is congealed into snow or ice, caloric has a stronger affinity for it than in the liquid state. Hence it is that Avhen a pound of water, at the tern- THEORY OF FREEZING MIXTURES. 221 perature of 172° F. is mixed with a pound of ice or snow, the latter is dissolved, and the mixture brought to the temperature of 32°; proving that 140° of caloric have passed from the water to the snow, and inti- mately combined with it during the process of lique- faction. But there are many salts which abstract caloric from snoAv, by which they are dissolved, or chemically com- bined with the snow. Such is the affinity of caloric for common salt, that when mixed with its own Aveight • of snow, both at the temperature of 32°, there is a transition of caloric from the snow to the salt, by which they are intimately united, and the temperature of the mixture reduced 41°. Again, so powerful is the attraction of caloric for chloride of calcium that when three parts of the latter are pulverized and mixed with tAvo of snow, both at 32°, the temperature and congealing point of the mixture are reduced —50°: and if four parts potassa be mixed with three of snow, the temperature falls —51°, or 83° in all. But if two parts chloride of calcium and one of snow be reduced to —9°, and put into the solution of snow and salt, the temperature and freezing point of this new mix- ture are reduced to —74°. That there is a transition of caloric from snow to such salts, is evident from the fact, that if the chlo- ride of sodium and snow be cooled to —9°, and then mixed together, no solution or further reduction of temperature takes place; and that if chloride of cal- cium and snoAv be cooled from 32° to —50° before they are mixed, no chemical solution, nor change of tern- 222 THEORY OF FREEZING MIXTURES. perature occurs, because there is no transition of ca- loric from one to the other. Many other salts have the power of absorbing ca- loric from water, acids and from snow, such as nitrate of potassa, nitrate of soda, hydrochlorate of ammonia, chloride of zinc, sulphate of soda, &c. If nitrate of ammonia be pulverized and mixed with its OAvn weight of water, at 50° F. the temperature is reduced 46°; that is, doAvn to 4°, which is 28° below the freezing point of water; and if the same quantity of carbonate of soda be added, the temperature is reduced to —7°, or 39° beloAv 32°. If then such salts can abstract caloric from liquids at 4°, and even below zero, it fol- lows a fortiori, that they can take it from snow at 32°. Dr. Turner observes, that when salt and snow are mixed, the salt causes the snow to melt by reason of its affinity for water. But if the snow and salt be cooled down to —9°, there is no attraction between them, and therefore no solution nor reduction of tem- perature. Nor is it a fact, as stated by Dr. Thomson, that every mixture which generates cold, contains a considerable quantity of water in the solid state; for hydrochlorate of ammonia contains none, and the ni- trate of ammonia only 1 i per cent. So of many other salts. The truth is, that all freezing mixtures are dissolved by caloric as certainly as that snow is dis- solved by boiling water; for the simple and sufficient reason, that caloric is indispensable to all fluidity, without which there can be no chemical combination. " Corpora non agunt, nisi sint soluta." When snow is dissolved in the strong acids, there is a rapid transi- tion of caloric from the acids to the snow, by which THEORY OF FREEZING MIXTURES. 223 they are chemically combined, with a reduction of temperature, as in the solutions of ice or salts in water. If eight parts of snow be dissolved in five of hydrochloric acid, the temperature of the mixture is reduced 59°; and if seven parts of snow be dissolved in four parts of diluted nitric acid, the mixture falls to 62°. The same effects are produced by mixing pulverized salts with the strong acids.* After having proved that caloric is the universal solvent of nature, and that solution is strictly a che- mical process, it would be needless to insist that the strong acids owe all their chemical properties to the heat Avhich is combined with their atoms. Like all other liquids, they are solidified by the abstraction of caloric, and when frozen, their burning caustic proper- ties are greatly impaired, together with their powers of combining with other bodies.*]- This view agrees Avith the etymology of the word caustic, which was * It is said that the best of all freezing mixtures is one com- posed of four ounces carbonate of ammonia, four ounces subcar- bonate of soda, and four ounces of water. This mixture will con- vert ten ounces of water, contained in a tin vessel, into ice. f When this subject shall have been more fully investigated, it will be found that the melting point of tin, bismuth and lead, when united into an alloy, is reduced for the same reason that the melting point of chloride of sodium, chloride of calcium, potassa and other salts, is lowered on mixing them with snow. This would appear from the fact, that when 217 grains of lead, 118 of tin, and 284 of bismuth, are finely powdered and mixed with 1617 grains of mer- cury, the temperature of the mass falls from 64° to 18° F.,—proving that there is a transition of caloric from one to the other; which is true, in fact, of all chemical changes. Besides, when three parts lead, two of tin, and five of bismuth, are pulverized and mixed to- gether, they melt at 197° F. 224 PROUT AND LLOYD. derived from the Greek noun *autn<; cans is, Heat, or from the verb xauaw causo, I will burn. It may be regarded as a fundamental axiom in sci- ence, that the laws of nature are uniform throughout all her diversified changes and revolutions. Whatever hypothesis is opposed to this great principle, should be at once rejected as unsound. Some modern philosophers, of high reputation, have taken a different view of this important subject. In his late Bridgewater Treatise, Dr. Prout observes, that " the world itself before arriving at its present condi- tion, has not only undergone a progressive series of different states, but in these different states, different laws of nature have prevailed." (Book I. Section 4.) It is also maintained by the Rev. Mr. Lloyd, that " the forces by which the world was brought into its present form, were originally far more energetic, before the appetences of matter for matter had been so ex- tensively satisfied. Shall we expect (he adds) to find the same activity in a neutral salt, as in its separate elements before chemical combination?" (Transactions of the British Association for 1835.) In answer to such hypotheses, it may be affirmed, that the aggregate amount of force and motion in the universe never varies; and that if the laws of nature were not alwaj7s the same, there could be no esta- blished principles of science. Old things pass away, and all things become new, but the properties and laAvs of the primitive elements never change. Mem- phis and Thebes, Nineveh and Babylon, Balbec and Jerusalem, with their gorgeous palaces and solemn temples, have passed into other forms of existence— ALL ROCKS FORMED FROM SOLUTION. 225 yea, the " everlasting mountains" have silently moul- dered into ruins, and been transported to other re- gions; but nature retains forever the same youthful energy as in the morning of creation. The "sun him- self may waste aAvay, grow dim with age," and pass into other modes of existence; still, there is not the slightest evidence that the primitive constituents of matter ever change. If then it be true that caloric is indispensable to the existence of gaseous oxygen, and to its combination with other bodies, as in combustion, fermentation and putrefaction—to the generation of Avater, and its power of uniting with salts, it must be equally essential to the generation of acids, and to their chemical combi- nation with the alkaline, earthy and metallic oxides, as in the formation of salts and rocks. It is quite evident, that all solid bodies have been formed from a state of chemical solution. Volcanic rocks have been formed from a state of fusion by sub- terranean caloric; while sedimentary rocks have been formed from a state of solution in water; and I have proved that the solvent power of water is owing wholly to caloric; since those bodies which are inso- luble in cold or even boiling water, become so at still higher temperatures. It was observed by Lord Bacon, that "we should inquire how far infusions may be made, by the help of attractions." The truth is, that all infusions, like the solutions of salts in Avater, are obtained by the attrac- tive agency of caloric. The familiar process of draw- ing teas depends simply on the attractive power of 15 226 SOLUTION, A CASE OF ATTRACTION. heat, to Avhich Ave owe all our infusions, medicinal ex- tracts, emulsions, &c. The superior cleansing property of hot over cold water, is owing to its povver of com- bining chemically with the various impurities that adhere to clothing, &c. It is also known that metals are deprived of their drossy combinations, and thus purified by the agency of heat. Hence, among the nations of antiquity, it was regarded as the type of purity; a term derived from the Greek word m>p, sig- nifying heat or fire. Cold water has no attraction for tallow, butter and other oily substances; but the cook understands practically, that when water is raised to a boiling temperature, it will extract and combine with the gelatinous and oleaginous ingredients of ani- mal bodies, making soups and gravies; which proves that the combining power is not in the water, but re- sults from the agency of heat. The chemical power of water is so far exalted by caloric, that when raised to the temperature of 400°, as in Papin's digester, it dissolves nearly all animal matters, together with the oily and resinous portions of wood, which are but slightly soluble in boiling water. Caloric enables water to combine with salts and the various ingredients of organic compounds, for the same reason that it enables atmospheric oxygen to unite with wood, coal and all other combustibles, including the metals; and for the same reason that it enables melted metals to dissolve and unite with solid metals. All solutions of salts in water, or metals in acids, are the results of an attraction between the solvent and the solvend. But if this attraction augment with VAST FORCE OF THIS ATTRACTION. 227 every addition of caloric, it cannot be an inherent pro- perty in the atoms of the menstruum. Nothing could more strikingly illustrate the im- mense aggregate force of chemical attraction than the phenomena of solution. For example, it is well known that when sugar or salts are dissolved in water, and metals in acids, the liquids undergo very little aug- mentation of volume; consequently, their density must be greatly increased. But it is evident1 from the ex- periments of Perkins, that a mechanical pressure equal to 2000 atmospheres, is not capable of reducing water more than one-twelfth of its volume, if so much. What then must be the force of attraction by Avhich salts and metals are united during the process of chemical solution ? By the transition of caloric from liquids to solids, the latter are dissolved and chemically united, Avith diminution of volume, for the same reason that the bulk and elastic force of gases are lessened on combining chemically. The force of chemical attraction is equally evident from the manner in which it overcomes the cohesion of solid bodies. The attraction of nitric acid for the atoms of silver, copper and iron, must exceed that of their cohesion; for it tears them asunder, but in an almost imperceptible manner, and atom by atom. It Avas before shown, that when tin, lead, copper, silver and other metals, are converted into the liquid state by heat, their power of combining with each other is greatly augmented; and that whenever a melted metal unites with a solid metal, there is a transition of caloric from the one to the other. In like manner, when mercury, gold, silver, &c. are 228 CHEMICAL FORCE OF THE ACIDS. converted into vapour, under plates of copper, iron and other solid bodies, there is a transition of caloric from the former to the latter, by which the particles of metallic vapour are transported to, and intimately combined Avith the solids, for the same reason that melted tin unites chemically Avith copper and iron ves- sels when poured into them, as in the process of tin- ning; or for the same reason that aqueous vapour is attracted by cold bodies, and combined with them in the form of dew or frost; that is, by virtue of an attraction of their caloric for bodies that contain less of it. But if the attractive power of all bodies be modi- fied by every change in their relations to caloric, it is unphilosophical to refer the effect to electricity, unless it be a modification of caloric; and still more so to confound attraction with the innate properties of gross matter. That the strong acids owe their activity and che- mical properties to caloric, is evident from the follow- ing facts: 1. They all become solid by the abstraction of ca- loric, Avhen their burning caustic properties are greatly diminished, together with their power of dissolving other solid bodies.* * Since the London edition of this work was published, M. de Mareska has found by experiment, that at__112° F., sulphuric acid no longer reddens litmus, and does not act upon the alkalies, the carbonates, iodide of potassium, nor chlorate of potassa. He also found that bromine, iodine and sulphur, combine with liquid chlorine at —90° F.; that when powdered antimony is put into liquid chlorine at the same temperature, they combine with evolu- CHEMICAL FORCE OF THE ACIDS. 229 2. Their power of dissolving metals is greatly aug- mented by raising their temperature. Concentrated sulphuric acid acts very feebly on iron, until made boiling hot. Copper is dissolved ra- pidly by sulphuric acid when raised to the boiling point. Lead, which is not affected by sulphuric acid when cold, is readily dissolved by it at 212° F. Its solution in nitric and acetic acids is also greatly aug- mented by raising their temperature. But it would not be philosophical to maintain that an agent wrhich is indispensable to all fluidity, and which increases the sohTent power of acids, is different from the primary and efficient cause of solution.* 3. When the earthy, alkaline and metallic oxides are dissolved in the acids, they are chemically united with them, and thus maintained in a state of trans- parent solution, like salts in Avater, in opposition to their specific gravity; and may be crystallized by evaporation or by cold. When salts, rocks and many metals, are converted into the liquid form, whether by the direct agency of caloric alone, or by means of a chemical menstruum, tion of heat (and light?). But that if dry chlorine gas be brought in contact with antimony placed in a tube, and the latter be inserted in solid carbonic acid, (which congeals at —148° F.,) no action is produced. (Silliman's Journal, March, 1846, p. 256.) * The first part of the process by which metals are dissolved in the strong acids, is decidedly one of combustion. For example, when nitric acid is poured upon plates of iron, copper, &c. a por- tion of its oxygen unites chemically with them, by which they are converted into oxides, with disengagement of heat, (as when poured on volatile 'oils, and other inflammable bodies,) after which, they are dissolved like salts in water. 230 , CRYSTALLIZATION their particles arrange themselves in regular series, at various angles, forming symmetrical aggregates, that cohere in definite forms as they cool doAvn. When sulphur, iodine, camphor, benzoic acid, with many other simple and compound bodies, are converted into the gaseous state, they also crystallize in regular forms on cooling down, like solutions of salts in water, or metals in acids. From some recent experiments performed by M. Bequerel and Mr. Cross, it has been supposed that electricity is the agent by which crystals are aggre- gated. But if electricity be regarded as a distinct agent, sul generis, and the only cause of crystalliza- tion, why do water and other liquids assume the solid and symmetrical form on merely reducing their temperatures? There can be no doubt, that Avhen a current of voltaic electricity is directed for days, weeks and months, upon salts and rocks, as in the experi- ments of Mr. Cross, it decomposes and transports their elements to the extremities of the battery, Avhere they will assume the crystalline form. But it is equally certain, that crystallization is constantly going on in the laboratory of nature, where no electric action can be detected by the most delicate tests. The whole of this problem is resolvable into one of still higher im- portance and generality; that is, whether electricity be only a modification of that universal principle of action, which I have endeavoured to show, is capable of producing all the contractions and expansions of matter. As yet, philosophers are but partially acquainted with the circumstances which determine the numerous MODIFIED BY TEMPERATURE. 231 diversities in the forms of the same substance: why, for example, there should be above 600 modifica- tions in the crystalline arrangement of carbonate of lime ? But it has been ascertained by the recent re- searches of Mitscherlich and Haidinger, that various proportions of water unite with many substances at different temperatures, during the process of crystalli- zation, producing a corresponding diversity of forms; that seleniate of zinc unites with three different por- tions of water, and assumes three different forms, according as its temperature is cold, lukewarm, or hot; and so of other solutions. They also found that mode- rate degrees of temperature, such as that of the solar rays, produced a decided change in the molecular ar- rangement of solid crystals. It is equally certain that the crystalline form of snow and many other bodies, varies according to the temperature at which they become solid, and depends on the different quantities of caloric around their particles, the arrangement of which is thus modified. (See page 101.) When it shall be clearly explained why sugar, gums, starch, gelatine, albumen and many salts, are more soluble in water than in alcohol; why sulphur, phosphorus, resins, &c. are more soluble in alcohol than in wrater; Avhy some bodies are soluble in ether and oils that are insoluble in other liquids; why one acid dissolves metals which another will not; and Avhy some metals are more soluble in diluted than in con- centrated acids; the obscurities of chemical science will rapidly disappear. Again, why are resins soluble in the fixed oils; the latter in the volatile oils; and both of them in ether? Is it not because there is a 232 ELECTIVE AFFINITIES. transition of caloric from the smaller particles of the latter, to the larger particles of the former, just as there is from the particles of snow and powdered ice to those of common salt and other freezing mixtures? Why do the volatile oils have a pungent taste, and redden the skin, Avhile the fixed oils are nearly insipid, inodorous, and do not heat the skin? Is it because the former contain little or no oxygen, and therefore when diffused over the skin, tongue or olfactories, undergo a slow combustion; whereas the fixed oils require to be decomposed by a higher temperature before the carbon and hydrogen can unite with atmo- spheric oxygen? Certain it is, that the volatile oils, like ether and alcohol, take fire at much lower tem- peratures than resins or fixed oils. That caloric is the universal solvent, without which liquids could not'combine chemically with solids; Ave must endeavour to resolve the remaining difficulties, by carefully investigating the circumstances which de- termine the relative attractions of caloric for different bodies, and its transition from one to another. BetAveen water in the state of ice, and tallow, or oils, there is no affinity whatever. But when water is raised to the boiling point, it unites readily with all oleaginous substances; and at still higher temperatures dissolves resins, and various other bodies. The solu- bility of sulphur and phosphorus in alcohol is also augmented by raising its temperature. All solutions and precipitations are owing to the tran- sition of caloric from one bejdy to another. What is termed elective affinity is OAving to the stronger attrac- tion of one body for caloric than another. By the ELECTIONS AND PRECIPITATIONS. 233 solvent power of caloric in nitric acid, it is enabled to combine chemically with silver, the particles of which are diffused equally throughout the menstruum, mak- ing a transparent solution of nitrate of silver. But if a portion of mercury be poured into the solution, the silver is precipitated as the mercury dissolves. It therefore folloAvs, that if the caloric of nitric acid en- abled it to dissolve and combine with the silver, it must have a still stronger attraction for the particles of mercury, or it would not desert the atoms of silver for them; in short, that the silver is separated from its combination with the acid by an abstraction of caloric, for the same reason that salts dissolved in water are precipitated by a reduction of temperature. The same principle must apply to all other elections and precipitations, modified, however, by circumstances Avhich require a careful investigation. Lead precipitates mercury, and copper lead, which is again thrown down from a state of combination with nitric acid by iron; all of which changes are attended with transitions of caloric from the solvent to the sol vend. The art of coating metals with other metals by pre- cipitation, is founded on the above laAv, such as gild- ing, silvering, tinning, &c. If a plate of copper or iron be immersed in a solution of nitrate of mercury, a coating of the latter metal is precipitated on them, for the same reason that aqueous vapour is precipitated on cold bodies, and coheres to them in the form of frost or ice. If nitrate of silver be dissolved in water and a plate of clean copper be inserted into the solu- tion, a beautiful coating of shVer is precipitated on the 234 CALORIC THE CAUSE OF ALL AFFINITIES. copper; or, if a polished iron rod be immersed in a solution of chloride of gold, the latter is precipi- tated on it in the metallic form, for the same reason that melted tin, zinc, bismuth, silver, &c. are attracted by solid metals and thus chemically united with them, as in the process of plating. Hence it follows, that if caloric be indispensable to the solution of metals in acids, their precipitation must be owing to its abstrac- tion by the solid metals. From a general view of the preceding facts and ob- servations, it is evident that caloric is the cause of all oxidation; that water and the strong acids are gene- rated by its agency and chemically united with the earthy, alkaline and metallic oxides, forming salts and rocks: in short, that combustion, fermentation and so- lution are modified effects of the same cause.* * Mulder observes, that at temperatures from 59° to 67° F., when yeast is added to sugar, fermentation is brought on, by which alcohol and carbonic acid are produced. But when made to ferment at temperatures from 97° to 104°, other products are formed. He further states, that a definite temperature is required to convert alcohol into oxide of ethyl and water by means of sul- phuric acid, which at other temperatures converts starch into gum and sugar; that one portion of caloric causes three, and another portion five equivalents of oxygen to unite with the same sub- stance, forming phosphorous and phosphoric acids. He also main- tains that the influence of caloric may be traced in nearly all cata- lytic phenomena; that the commencement of decomposition in yeast is attributable to a determinate catalyzing temperature; in fine, that "Heat is the pulse of life in the chemical changes of bodies, and has thus an unlimited influence upon their chemical combinations." (Chemistry of Veget. and An. Physiol, pp. 34, 43, 44, 45, 46.) He observes in another place, that "the primary source of all chemical action must be referred to temperature." CHAPTER IV. CAPILLARY ATTRACTION. That very law which moulds a tear, And bids it trickle from its source, That law preserves the earth a sphere, And guides the planets in their course. Rogers. Considered in all its relations and bearings, capil- lary attraction is one of the most important processes in nature, being immediately connected with all the changes and modifications of both living and dead matter. It is the force by which solids and liquids are drawn and held together, which causes plates of glass, Avood, metal, &c. to adhere with some force to the surface of Avater and other liquids, Avhen laid flat upon them. It is by the force of capillary attraction that the waters of the earth are conveyed through its crust in opposition to that of gravity; for Avater is much lighter than the earthy and rocky strata through Avhich it descends; and has been found at the greatest depths to Avhich miners have penetrated, forming sub- terraneous streams, which greatly augment after heavy rains. During this transudation of water through the earth, it dissohres and combines chemically with a por- tion of its mineral ingredients; after which, it is forced (235) 236 CAPILLARY ATTRACTION. to the surface by hydrostatic pressure, (on meeting with an obstruction to its horizontal progress,) form- ing innumerable springs and fountains of delicious Avater. It is owing to the attraction of liquids for solids that the dust of our roads, which, Avhen dry, has little or no cohesion, becomes so tenacious after rain; or that a rope, when moistened Avith Avater, contracts Avith great force. The combination of tannin with leather, and colouring matter with clothing, are due to a modification of the same power that enables Ava- ter to combine with salts, or to permeate porous rocks. Several distinguished philosophers have recently conjectured, that a discoArery of the cause which de- termines the rise of liquids through porous solids and capillary tubes, would unfold the latent principle of action in all molecular changes, Avhether chemical or Arital. The trunks, stems, leaves and flowers of all the trees and plants that adorn the earth, are composed throughout of exceedingly small capillary tubes and cells, that attract liquid nourishment from the earth and convert it into their own substance, by the same power which causes the combination of other solids and liquids. And so of all animals. Every muscle, gland, nerve, bone and blood-vessel is composed of im- perceptibly small capillary tubes, through which the blood is circulated by the same power which causes universal attraction. The subject of capillary attraction has been labo- riously investigated by many of the most distinguished votaries of science for the last 150 years, but Avithout any attempt to explain the cause of the phenomena; CAPILLARY ATTRACTION. 237 if we except a single suggestion of Newton, contained in his letter to Boyle, concerning the ether. He there refers capillarity to the same agent which causes men- strua to dissolve solids,—a most important hint, for Avhich his successors have not given him due credit. It must, howeArer, be acknowledged, that he never gave a satisfactory explanation of what causes solu- tion. Still, his views were more just and comprehen- sive than those of the present day. That he also referred vital attraction to the same cause which pro- duces ordinary capillary attraction, is evident from the following observation: " The same principle which causes a sponge to suck in water, causes the glands in animal bodies to suck in the various juices from the blood, according to their several natures and disposi- tions." (Opticks, page 367.) In the time of NeAvton, it was ascertained experi- mentally by Hawkesbee,— 1. That Avater rises to the same height in capillary glass tubes of equal diameter, Avhether the tubes be thin or thick. 2. That it rises to the same height in vacuo as in atmospheric air. 3. That the velocity with which water ascends in capillary glass tubes, and its elevation, cceteris paribus, is inversely as their diameters. 4. That the upper surface of water, spirit of wine and various other liquids in capillary glass tubes, is concave; which he rightly attributed to a stronger attraction of the particles of Avater in immediate con- tact Avith the glass for it, than to each other. In 1805, Dr. Young read a paper before the Royal 238 CAPILLARY ATTRACTION. Society on the cohesion of fluids, in which he reduced all the phenomena to the joint agency of a cohesive and repulsive force, which in fluids, he thought ba- lanced each other. But as he does not explain what causes the particles of liquids to approach or recede from each other, his whole theory is vague and very difficult to comprehend. The following passage, taken from a paper on capil- lary attraction, by Professor Sang of Edinburgh, may be regarded as a specimen of the obscure manner in Avhich this interesting subject has been generally treated; and of the prevalent opinion in regard to the recondite nature of the cause which determines the attraction between liquids and solids. He ob- serves, that "the whole of the phenomena are due to a change in the corpuscular arrangement produced by the simple contact of heterogeneous substances, the laAvs and nature of which change are, and perhaps for- ever will remain, unknown to us." (Edinburgh Philo- sophical Journal, vol. viii. 253.) Sir H. Davy maintained, "that water is combined Avith rocks, earths, salts, wood, muscular fibre, &c. by chemical attraction; but that it combines with glass, porcelain, &c. by cohesive attraction." This is con- trary to his own and the general vieAV of chemical attraction, which is defined as "the force that unites different elements and as the antagonist of cohesion," which is supposed to unite homogeneous elements. But there is as much difference between water and glass or porcelain as between water and salts, rocks, wood or muscular fibres. There is no end to the ambiguities and contradic- CAPILLARY ATTRACTION. 239 tions that have resulted from regarding cohesion and capillary attraction, as referable to a different cause from that which produces chemical affinity. I have already proved that the particles of water and other compound bodies, are held together by the same agent which causes the cohesion of gold or any other homo- geneous body. The same power that unites the atoms of quartz, feldspar and mica and holds them together in the form of granite or gneiss, maintains the cohe- sion of liquids. This principle has been recognized by Laplace, in a supplement to the 10th Book of the Mechanique Celeste, in which he treats of capillary attraction as a modification of chemical affinity. That this is really the case, would appear from various considerations:— 1. Capillarity is the force by which liquids and solids are made to cohere, whether homogeneous or heterogeneous. 2. Every solution of a solid in a liquid, is the re- sult of a chemical force, by which their particles are united. 3. The force of capillary attraction, by which liquids permeate solids, is always in proportion to their che- mical affinity for each other; for example, water has a strong affinity for sugar. It also rises rapidly through it by capillary attraction. Considering the vast importance of the subject, it is really surprising hoAv imperfect and limited the num- ber of experiments that have been instituted for the purpose of elucidating its nature. Sir David BreAvster has given the relative heights to which fifty-two dif- ferent liquids rose through a capillary glass tube, the 240 EXPERIMENTS OF BREAVSTER AND LINK. bore of which Avas 0*0561 of an inch—the general re- sult of which Avas, that water rose to a greater height than any other liquid. The next in order Avere mu- riatic, nitric and nitrous acids; then the volatile oils; after Avhich Avere alcohol and the ethers; and lastly, sulphuric acid.* But if capillary attraction represent the force by Avhich all liquids and solids cohere, it is obvious, that before we can arrive at any just conclu- sion, the attraction of innumerable other solids for as many liquids must be ascertained. As if to show the uncertainty of all experiments, M. Link states, that distilled water, nitric acid, spirit of Avine, sulphuric ether, sulphuric acid and the aque- ous solution of potassa, (one oz. to six of water,) all rose to the same height between glass plates. What is still more remarkable, he states that the above liquids rose to the same height between plates of cop- per, of zinc and of copper and zinc soldered together; first, Avith the zinc surface opposed to the copper; next, the zinc surfaces opposed; and then the copper surfaces opposed.f Mr. Challis observes, after recounting the above ex- periments, that "the heights of ascent under similar circumstances, would seem to be alike independent of the liquids and solids."! But if this conclusion were * Edinburgh Encyclopedia, Article Capillary Attraction. f Transactions of the British Association, vol. iv. p. 293, Re- port on Capillary Attraction, by the Rev. James Challis. % This error has been amply refuted by the late experiments of Matteucci, who found that when six capillary glass tubes were plunged into as many different liquids, at the temperature of 53 6° F., they rose to the following heights in ten hours, the SIR JOHN HERSCHEL. 241 well founded, water ought to rise between plates of sulphur, bees-wax, gum lac, resin, spermaceti, tallow, &c. as freely as between plates of glass, which is not the fact. The truth is, that liquids rise most rapidly through such porous solids as are most soluble in them —that is, bodies for which they have a strong che- mical affinity. Water rises freely through sugar, salts, ashes and porous rocks, because it has a strong che- mical affinity for them. For the same reason, alcohol rises through all such solids by capillary attraction, as are soluble in it; and so of the strong acids. Tallow and water have no tendency to unite chemically when cold. For the same reason, when glass plates are smeared with tallow and brought close together, Avater Avill not rise betAveen them, unless they be first Avetted. But in this last case, the Avater rises, owing to its at- traction for its own particles, for the same reason that they aggregate into spherical drops. It Avas observed by Sir John Herschel, that "the discovery of a new law or general fact is scarcely an- nounced Avhen its traces are found everywhere, by Avhich unexpected lights are shed over parts of science liquids being of the same specific gravity, viz., 1*075. Solution of carbonate of potassa rose 85 millimetres; sulphate of copper, 75; serum of blood, 70; carbonate of ammonia, 62; distilled water, 60; solution of common salt, 58; milk, 55; white of egg diluted with its own volume of water, 35. He also found, that when glass tubes were filled with pounded glass, alcohol rose 175 millimetres, and water 182; but that when filled with sawdust, the alcohol rose 125 millimetres, and the water only 60. (Physical Phenomena of Living Beings, p. 23.) 16 242 ARISTOTLE, NEWTON AND LAPLACE. that had been abandoned in despair, and given over to hopeless obscurity." (Discourse on the Study of Xut. Phil. p. 131.) Nothing could more aptly illustrate this observation than the phenomena of capillary at- traction, the cause of which, when once pointed out, may be traced everywhere around and within us. But such is the blinding influence of custom, that men dis- regard what is common and familiar, though it be from analyzing the most ordinary phenomena, that the greatest discoveries have been made, such as that of steam power, the art of printing, railroads, &c. It was said by Aristotle, that everything is best seen in its smallest proportions. Such is the admir- able simplicity with which Infinite Wisdom directs and governs the stupendous frame of nature, that the physical cause of chemical force, and of universal at- traction may be recognized in the smallest dew-drop that glitters on the grass. It has been shown for example, that the atoms of oxygen and hydrogen, are chemically united by the agency of caloric, making compound particles of water, which are aggregated into the spherical form by the attraction of cohesion; and that it adheres to solid bodies by capillary attraction—all of which, according to Newton and Laplace, are modified effects of the same cause that actuates the vast machinery of the universe. When a certain proportion of caloric is combined with this little dew-drop, it assumes the solid and crystalline form—in another proportion it renders it liquid, and enables it to combine with other bodies— while an additional quantity of the same ether which ILLUSTRATIONS. 243 held its particles together, separates and expands them into thin air. Again, the phenomena of a burning candle demon- strate the agency of caloric hr chemical and capillary attraction, as effectually as a thousand experiments, though contrived with the greatest skill. By the ap- plication of heat to the wick, it is ignited, Avhen it attracts oxygen rapidly from the atmosphere, causing combustion. During this process, the tallow is ren- dered fluid, and attracted by the burning wick, afford- ing a continual supply of melted matter, which is decomposed, and expanded into flame or dense light.* Other things being equal, the force and rapidity with which the fluid tallow is drawn up, are in pro- portion to the amount of caloric given out by the wick. Thus, it Avould appear that the rationale of oxidation, capillary attraction and the generation of light, are clearly exemplified by a familiar process that has been overlooked by the unreflecting million, and neArer fully investigated by philosophers. With a view of ascertaining the force of capillary attraction caused by the heat of a burning candle, I performed the following simple experiments:— About five grains of the heaviest coal ashes were placed around the wick of a burning candle; eA^ery particle of which was drawn up in a few minutes, ad- hering closely to the wick. I next put about the same quantity of iron filings * But if light and flame be identical, and if flame be gaseous matter raised to a white heat, as maintained by Newton, Davy and others, it follows, that the light of combustion is an expanded con- dition of ponderable matter by caloric. 244 ILLUSTRATIONS. into the bole of a large candle, all of which Avere soon drawn up and collected around the wick, as in the for- mer experiment. There can scarcely be a doubt that filings of silver, lead, gold and even platinum, would present the same results under like circumstances; nor is it a Avhit more remarkable, than that red-hot iron should attract oxygen, sulphur, mercury and other bodies more strongly than cold iron. In reply to the above facts, I have been told by grave and learned men, that " fluidity is indispensable to capillary attraction, and that the only agency of caloric in the process is to cause fluidity." But this does not explain why hot water rises far more rapidly through lumps of white sugar, salts, &c. than cold water, nor why those bodies which have the strongest affinity for caloric, attract and absorb water most ra- pidly, such as the deliquescent salts that are employed in freezing mixtures. If it be urged that the absorption of Avater by sugar and salts, is not owing to capillary attraction, but to chemical affinity, I answer, that hot Avater passes through numerous porous solids and capillary tubes, with a force and velocity proportionate to its temper- ature. This fact may be verified in the following simple manner. Take two bunches of spun glass about four inches long; insert the end of one into water at 50° F. and the other at 180°, when the lat- ter will be found to rise with greater force and rapidity than the former, in the ratio of at least three to one. The same is true of amianthus, flaxen thread, bunches of hair, hemp and other textile fibres, when AN APPARENT EXCEPTION. 245 arranged in a similar manner. But it would be un- philosophical to maintain, that an agent which aug- ments capillary attraction, is different from its primary and efficient cause. It has been maintained by Laplace, that an increase of temperature diminishes the ele\Tation of liquids in capillary glass tubes; first, by augmenting their ca- pacity; and secondly, by lessening the density of the liquid. He further regards it as a general law, that the elevation of any liquid that completely wets the sides of a capillary tube at different temperatures, is in the direct ratio of its density. This view of the subject has been partially corroborated by the expe- riments of Sir David Brewster, who found that cold water rose somewhat higher in a capillary glass tube, than when hot—a fact which I also have verified by repeated experiments. Whatever the reason may be of this apparent objection to the views which I have offered, innumerable other facts decisively prove that the rapidity with whicla liquids pervade porous solids and capillary tubes, is in proportion to the temper- ature of the liquids, caeteris paribus. When I come to treat of the agency of caloric in the phenomena of life, it will be shown that it is the proximate physical cause of capillary circulation throughout the animal and vegetable world, without which there could be no absorption, secretion, nutri- tion and groAvth; that trees and plants are mere aggre- gations of capillary tubes and pores, through Avhich many hundred million tons of sap are forced up by the power of vital attraction, under the immediate agency of solar heat, and that all the phenomena of 246 ENDOSMOSE AND EXOSMOSE. life (which result from an attraction between liquids and solids) are arrested by cold. The principal dif- ference between ordinary capillary attraction, and the capillary circulation of plants and animals, is, that the vessels or tubes of the latter are almost incon- ceivably small, while the force of all attraction is in- versely as the distance; hence the force with which a moistened rope contracts, and raises immense weights; or the force and velocity with which blood and sap are draAvn through their minute vessels. The mutual interchange of tAVO different liquids, separated by a membrane or other porous body, which has been referred by Dutrochet to the operation of a peculiar force, termed by him endosmose and exosmose, according to their direction, is doubtless a modification of capillary attraction, and of the force which causes all chemical combinations.* * Dutrochet's endosmometer consists of a glass tube, with a piece of bladder attached to its lower extremity, expanded into the form of a funnel. On pouring into it an aqueous solution of either gum or sugar, and then immersing the closed extremity in pure water, the latter passes through the membrane into the tube, with a force which raises the liquid within it to a considerable height; while a small portion of the liquid within passes out through the bladder, and mixes with the water, which he calls exosmose. From an immense number of experiments with this instrument, Dutrochet found, that, other things being equal, the force which produces the endosmotic current, is in proportion to the excess of density of the interior liquid over that of the water; that with a solution of sugar, whose density was 1145, the force of the current was equal to 34 divisions of the scale, but rose to 53 divisions when its den- sity was 1*228; and that syrup, whose density was 1*300, produced a current capable of raising a column of mercury 127 inches in height, which is equal to the pressure of four and a half atmo- ENDOSMOSE AND EXOSMOSE. 247 There is another general fact which connects the theory of capillary attraction with that of heat. Those bodies which have the least attraction for caloric, have the least power of absorbing water, such as furs, silks, woollens, cottons, resins, sulphur, phos- phorus and other non-conductors of caloric and elec- tricity. Hence it is that when water is poured on a perfectly dry clean silk dress, it runs off, or collects in large globules, while it is rapidly absorbed by linen, which is a much better conductor of caloric. For the same reason, a lock of wool, cotton, down or fur, will float on Avater a long time without becoming wet. Or if one end of a perfectly dry skein of silk be suspended in a vessel of cold water, it remains for hours without attracting the Avater through its fibres; Avhereas a skein of linen or hemp becomes very soon Avetted through- spheres, or about 160 feet of water. He also found, that the endosmotic current was generally determined by the liquid which has the greatest affinity for the interposed substance, and by which it is imbibed with the greatest rapidity. In regard to the cause of the current, Matteucci, has, after carefully investigating the subject, arrived at the conclusion, that it is not electricity, (as sup- posed by Dutrochet and others,) since the latter is not developed by the contact of water with solution of sugar and other liquids. (Op. cit. p. 38.) The fact is, that in all such phenomena, there is a transition of caloric from the outer liquid to the interposed membrane, and thence to the interior liquid, just as there is from all liquids to solids during the process of chemical solution, and just as there is in all cases of capillary attraction. I have also shown, that there is a transition of caloric from hydrogen to chlo- rine during the act of their chemical union to form hydrochloric acid,—as there is from hydrogen to phosphorus, sulphur, &c, during the formation of phosphuretted hydrogen, sulphuretted hydrogen, &c. 248 CONNECTION BETWEEN GRAVITY AND THE out. But if the water be made hot, it rises through the silk also. Li accordance with the above facts, it has been found that mercury and other melted metals, instead of rising through capillary glass tubes, are somewhat depressed, because they have a stronger attraction for their own particles than for those of the glass. That they have also a stronger attraction for caloric, is evi- dent from their greater conducting power. Hence, there can be no transition of caloric from liquid metals to the glass, for the same reason that there is none from cold water to silks, resins, &c, therefore no attrac- tion. But if plates of gold, silver and tin, be inserted into mercury, the latter is attracted by them, rises above its level, and is incorporated with them by vir- tue of the same power that causes all other attractions between liquids and solids. When mercury is poured on a marble or Avooden table, it collects in large glo- bules, for the same reason that water aggregates into large drops when poured upon dry silk, a duck's feathers and other non-conducting bodies; or for the same reason that when plates of glass are smeared with tallow they do not attract water unless previously wetted. ON THE CONNECTION BETWEEN GRAVITY AND THE MOLE- CULAR FORCES OF NATURE. It has been said that the attraction of atoms is not like that of gravitation, inversely as the squares of the distance. This assertion is not only refuted by all analogy, but by the well-established fact that the ele- A10LECULAR FORCES OF NATURE. 249 vation and force with which liquids rise in capillary tubes, cateris paribus, is inversely as their diameters. The principal difference between the attraction of atoms and that of masses is, that the former acts at exceedingly small distances, corresponding with the minuteness of atoms; while the poAver of masses ex- tends to comparatively great distances. The aggre- gate force of cohesion Avith Avhich a mass of granite is held together, other things being equal, is proportional to the number of its ultimate particles. The force of gravity with Avhich it presses upon the earth is in the same ratio. The specific gravity and cohesion of bodies augment in proportion as they are deprived of caloric. The force and rapidity with which they gravitate toward the centre of the earth, when elevated above its sur- face, augment in a corresponding ratio. We have learned from Sir Isaac Newton that the attractive poAver of bodies is in proportion to their mass, and inversely as the squares of the distance. The force with which caloric tends to unite with the particles of other matter, and hold them together, is also in pro- portion to the amount of matter, cceteris paribus, and inversely as the squares of the distance. For example, if one pound of water condense two ounces of steam by attracting and absorbing its caloric, two pounds will condense four ounces, and so on. For the same reason, the force Avith which the caloric of space tends to unite with the matter of the sun, maintains that immense body in the globular form, while it preserves the planets in their orbits around him, being in pro- portion to his mass, and operating Avith a poAver that 250 AGGREGATE FORCES OF NATURE. varies inversely as the squares of the distance. In like manner, the force with Avhich the caloric of space tends to unite Avith planets being in proportion to their mass, cceterls paribus, must be sufficient to hold them to- gether in the spherical form, and to maintain the satellites in tlieir orbits. If caloric be the physical cause of cohesion, capil- lary attraction, and chemical affinity, as I have demon- strated; and if gravitation result from the aggregate action of atoms, as maintained by Newton, Laplace and many other philosophers, the centripetal force of the heavenly bodies must be owing to a modified ac- tion of the same cause.* We are so accustomed to the great poAvers and movements which mark the course of nature, that we are scarcely aware of their existence until aroused by some extraordinary phenomenon. What can be more obvious and familiar than the power of heat in modi- fying the surface of our planet? a poAver absolutely * According to all the best-established canons of philosophiz- ing, that is the most important principle in physics, to which the greatest number of phenomena may be traced. But if we admit that the accelerated motion of falling bodies, the aggregation of planets, with their annual and diurnal revolutions, are resolvable into the Newtonian law of gravity, it is certain that many other equally important phenomena of nature cannot be referred to the principle of gravitation, such as those of heat, light and electricity, together with the innumerable operations of chemistry, geology and meteorology, all of which are immediately connected with, and may be traced to that law of caloric by which it produces the opposite effects of contraction and expansion, and without which, we cannot explain the most simple modifications of molecular motion. AGGREGATE FORCES OF NATURE. 251 incommensurable, though for the most part unob- served. Were it possible to compute the aggregate forces of capillary attraction in the circulation of the blood and sap of all the animals and plants that in- habit the earth, we should be amazed at the result. Yet they are all produced by the subtile agency of caloric, a definite amount of which is indispensable to all vital action, from that of the insignificant moss or animalcule, to the most perfect developments of or- ganized existence. On beholding for the first time so grand a spectacle as the Falls of Niagara, the mind is bewildered by an impression of irresistible power. But if Ave compare this thundering exhibition of might, with the vast but silent poAver of solar caloric in evaporation, or of sub- terraneous caloric in upheaving mountains, the ocean cataract dAvindles into a fractional item; for it has been already shoAvn, that a mass of water equal to 415 square miles in area, and one mile in depth, is daily conArerted into steam, and carried into the atmo- sphere by the expansive energy of solar heat, and that all the lakes, rivers and springs of the earth are sup- plied by its precipitation. We are sometimes aroused to a perception of the wonderful poAvers that are in nature, by the sudden and awful coruscations of the electric fluid, when dart- ing through the heavens like arrows of Omnipotence, rending rocks, trees and dAvellings. But few are aware that it is only a concentrated exhibition of the same agent which causes evaporation, solution, crystalliza- tion and vegetation. It is generally conceded by philosophers, that all 252 AGGREGATE FORCES OF SOLAR LIGHT. the operations of nature are referable to attraction and repulsion, Avhich I have proved in the preceding chap- ters are resolvable into the agency of caloric alone. But if the stupendous forces of chemistry, geology and meteorology, are determined by the agency of solar radiation, why should it not be adequate to produce the annual and diurnal revolutions of planets? That rays of subtile matter, capable of producing heat and light, are continually proceeding from the centre of our system, is self-evident from experience and obser- vation. It would, therefore, be contrary to all analogy, and the indications of common sense, to refer the planetary motions to some unknown hypothetical in- fluence exerted through a vacuum, Avhile there is a known cause sufficient to explain the phenomena. Is it not self-evident that if the radiating power of the sun were suspended, they would no longer move around that luminary, and upon their own axis, but desert their orbits, and join the parent orb from which they originally came? It is impossible to -conceive how the sun could exert any agency whatever upon the earth, independent of his potent beams. Besides, Avhat can be more simple and natural than the infer- ence, that the same power Avhich aggregates and holds together the particles of planets, guides their move- ments round the heavens? It was laid down by Newton himself, as a funda- mental axiom, that no more causes of natural thirty* ought to be admitted, than such as are both true and suf- ficient to explain the phenomena. (Principia, book hi.) Lord Brougham also observes in his Natural The- ology: "Great as our achievements in physical as- AGGREGATE FORCES OF SOLAR LIGHT. 253 tronomy have been, Ave are Avholly unable to under- stand why a power pervades the system, acting in- \rersely as the squares of the distance, rather than according to any other law." He adds: " It is incon- ceivable to our minds how power or any other thing or influence, can act at a distance." (Vol. ii. p. 74.) When commenting on the NeAvtonian law of gravity, by Avhich every particle of matter in the universe is supposed to attract every other particle inversely as the squares of the distance, Mr. Whewell asks, " Why do the attractions of masses, or those of their consti- tuent particles, follow this law of the inverse square of the distance?" (Bridgewater Treatise, chapter x.) But if it be a fact, that all the separate forces of na- ture, including those of caloric, are governed by the same law, it is difficult to avoid the conclusion that they are connected together as cause and effect, though we may not yet fully comprehend in what way. The truth is, that the force of all ethereal emana- tions is inversely as the squares of the distance, for the obvious reason that they are necessarily diffused in the same ratio. Other things being equal, the re- pulsiA^e force of caloric in gases and vapours diminishes in the ratio of the distance of their particles from each other. Its heating power decreases in the same pro- portion, while the attractive and repulsive forces of electricity are known to follow the same law. Such is the love of mankind for the marvellous, that the most obvious causes of natural phenomena are disregarded, and their explanation sought after by resorting to such as are hypothetical and remote, or obscure. Hence it is, that our books on natural phi- 254 SPACE FULL OF SUBTILE MATTER. losophy are filled \vith speculations about the vacuum of space, Avhile Adsible and palpable floods of luminous ether are continually pouring upon the earth from the great fountain of physical motion and life. When Sir H. Davy observed, that it "was absolutely necessary for the explanation of the planetary motions, to sup- pose space in the universe AToid of all matter," he over- looked the existence of solar light, and even of that subtile medium, the vibrations of Avhich are supposed by some to constitute light. That he did so from authority, and Avithout reflection, would appear from what he says in another part of the same work. "It cannot be doubted that there is matter in motion through space betAveen the sun, and stars, and our globe." (Chem. Phil. p. 67.) There is no decisive evidence that any of the an- cient philosophers adopted the theory of a perfect vacuum in nature. It was the opinion of Bacon, that the ancient Pan " was represented as hairy to denote the rays of things, because everything which acts at a distance may be said to emit rays." (Wisdom of the Ancients.) It was also maintained by Lucretius, who is regarded as the advocate of a vacuum, that subtile streams are perpetually flowing from everything, without which bodies could not be discovered at a distance. (De Na- turd Rerum, book vi.) It has been repeated a thousand times, that by re- ducing the phenomena of gravitation to a general law, Sir I. Newton had revealed the whole mechanism of the universe. But he entertained a far more accurate estimate of what he had done, when he compared him- HYPOTHESES OF NEWTON. 255 self to "a little boy collecting a feAv choice pebbles and shells on the sea shore; Avhile the great ocean of truth lay all undiscovered before him." When he resolved the aggregation of planets into the action of their minutest particles, he left his fol- lowers in doubt whether gravitation Avas a primary agent, or only an expression of the mode in which some universal cause is observed to operate inversely as the squares of the distance; and whether it resulted from the pressure of an all-pervading ether, or from the inherent properties of elementary atoms. (See Opticks, p. 351.) The power of generalization by which he traced remote analogies and reduced a vast multitude of ap- parently opposite phenomena to the dominion of one law, displayed an admirable faith in the uniformity of nature. Yet the projectile force, the vacuum of space and the vis insita which he represents as the cause of attraction and repulsion, were mere hypotheses, wholly unsupported by evidence. And that the illustrious author himself was fully convinced of this during the latter period of his life, is manifest from the whole tenor of his speculations concerning the ether, which, as I have already shoAvn, he finally regarded as the primary physical cause of cohesion, capillary attrac- tion and of gravitation; but without explaining how it produces the repulsion of atoms and the centrifugal force of the heavenly bodies; or in Avhat Avay the phe- nomena of chemistry, geology, meteorology and plane- tary motion are connected with the influence of the imponderables and the relations of the latter to each other. 250 CALORIC THE CAUSE OF FORMS. But in the total absence of caloric, if such a thing Avere possible, the whole material universe would dis- appear no less completely than if annihilated: for it is obvious that in their separate state, the chemical atoms of passive matter could not be recognized by the senses. And I haA'e proved that caloric is the organizing principle by Avhich they are aggregated into visible and tangible forms; consequently, that it is the self-active and universal essence on Avhich all the manifestations of being or existence depend.* Yet Ave are told that caloric is not a material sub- * And if the particles of all bodies be surrounded by a self-active principle, there can be no such thing as absolute inertia in nature. In opposition to this view of the subject, we are informed by Dr. Arnott that "the greater part of the phenomena of nature may be referred to four elementary truths, viz., atom, attraction, repulsion and inertia.'''' He observes, that "inertia expresses the fact, that atoms, as regards motion, have a stubbornness about them, which tends always to keep them in their existing state, whatever it may be." (Elements of Physics, vol. i. pp. 1 and 2.) In what way atoms have been endowed with this imaginary property has not been explained; nor does Dr. Arnott assign the cause of attrac- tion. Until this is done, let no man flatter the world, that even the foundation of physical science has been established on the solid rock of fixed principles. If it be true that caloric is the physical cause of attraction as well as repulsion, and that cohesion and gravity are modifications of the same power, it becomes the business of philosophy to investi- gate the mode of its operation in maintaining all the molecular and aggregate movements of nature. The connection of caloric with the phenomena of motion has been virtually recognized by all those philosophers who have re- garded heat and motion as identical. But it is obvious that there can be no motion without an agent; consequently, that they have confounded the effect with its cause. CALORIC THE CAUSE OF FORMS. 257 stance, because it is imponderable. It is evident, how- ever, that Avhatever the cause of gravity may be, it must be Avithout gravity; otherwise Ave must explain gravity by itself, which would be absurd. The truth is, that when reduced to a state of ultimate diffusion, all matter is imponderable, as in the form of the elec- tric spark, flame, &c. And if caloric were "motion and nothing else," as maintained by Bacon and other philosophers, it would follow that the prime mover in a steam engine and throughout all nature, is motion, —a proposition which involves the glaring absurdity of explaining motion by itself. But without plunging further into the profound abyss of chaos or practical non-existence that would follow the entire extinction of the organizing prin- ciple, it is the legitimate province of science to ascer- tain how it produces all the phenomena of nature in accordance with the invariable laAvs of supreme intel- ligence. Nor is it possible to predict the results Avhich Avould flow from a searching method of analyzing facts. We often mistake our own inattention and indolence or the mystical inventions of fanciful theorists for im- penetrable obscurities, that Avould vanish before a bold and determined spirit of inquiry. Could the veil be drawn aside which conceals from our inspection the whole mechanism of the universe, nothing, perhaps, would so much excite our astonishment as its sim- plicity. From a careful review of the foregoing chapters the folloAving conclusions may be deduced:— 1. That cohesion, chemical affinity and capillary 17 258 GENERAL CONCLUSIONS. attraction are modifications of that universal force by Avhich planets and all other bodies are held together: 2. That the particles of all bodies are surrounded by, and intimately combined A\rith, an exceedingly subtile, active and mobile principle, which in certain proportions holds them together, but in larger propor- tions separates or decomposes them: 3. That the prevalent theory of physics Avhich ascribes the phenomena of attraction to the inherent or immaterial properties of ponderable matter is falla- cious and wholly unsupported by evidence: 4. That there is no such thing as a perfect vacuum in nature; neither in the pores of bodies nor in those widely extended pores of the universe, termed the planetary spaces: 5. That the inertia of matter is a philosophical fiction, because there is nothing quiescent in nature or which possesses the power of not eictlng—neither in the starry heavens nor in the frame of the earth. The sun revolves on his axis, and planets around the sun. The air, the ocean and the solid ground are forever in motion. The molecules of plants and animals are in a state of rapid circulation and change. Yea, the invisible atoms of inorganic matter are in a state of perpetual oscillation and transformation: 6. That the "unknoAvn hypothetical ether of Sir I. Newton is identical with a true physical agent, the properties of which may be ascertained by the various mechanical, chemical and physiological effects it pro- duces; that it determines the aggregation and chemi- cal union of bodies, Avhether simple or compound, by A'irtue of its attraction for ponderable matter; Avhile it GENERAL CONCLUSIONS. 259 causes liquefaction, evaporation, explosion, with all the separations and expansions of matter, by virtue of its idiorepulsive power: 7. That the same ethereal principle Avhich lights up the universe with radiant glory, directs the planets through their orbits and preserves them in a state of perpetual motion, circulation and renovation: 8. That in the total absence of caloric, if such a thing Avere possible, the universe Avould be involved in the darkness, silence and death of primeval chaos: 9. Finally, that caloric is the first of physical causes, or the essence which causes things to be what they are. BOOK III. CHAPTEK I. ELECTRICITY. "Nature will not deliver her oracles to the crowd, nor by sound of trumpet. We must open our minds to her in solitude, with the simplicity of children, and look earnestly in her face for a reply."— Walter Savage Landor. The grand requisite to a right understanding of nature, is to watch attentively all the changes that mark her progress and the various circumstances by which they are attended. Perhaps there is not a more striking characteristic of the present age than the vast amount of industry and talent that are de- Aroted to the cultivation of separate branches of science, which cannot be understood but as connected parts of one harmonious system. The division of labour, so beneficial to the arts, has not been equally favourable to the progress of enlarged vieAvs. Men avIio devote their attention chiefly to one branch of science, be- come narrow, technical and incapable of embracing universal truths. The leading object of all science is to reduce a multitude of phenomena to some compre- hensive principle or general law, Avhich pervades the (260) ELECTRICITY. 261 entire constitution of matter. But how is it possible to arrive at universal facts or fundamental laws, with- out regarding nature as a whole ? The more profoundly Ave scrutinize her operations the more we discover of simplicity and unity of power amidst all her diversified movements and transforma- tions. Who could have suspected, without a general survey of the widely extended provinces of nature, that the aggregation of liquids into spherical drops and their adhesion to solids are resolvable into the same poAver that determines the solidity and rotundity of the earth?—Avhich causes rain to descend from on high, rivers to Aoav toAvard the sea and planets to re- A^olve around the sun? Yet these various movements Avere traced by Newton to one and the same law. What can be more unlike to the mass of mankind than the opposite forces of attraction and repulsion, contraction and expansion? Yet I have proved that they are both produced by one and the same agent; which in certain proportions binds the atoms of pas- sive matter together, as in cohesion and chemical union; Avhile in other proportions it diminishes or de- stroys their cohesion, as in liquefaction, vapourization, combustion, &c, by Avhich the forms, properties and poAvers of all bodies are perpetually changed. I have shoAvn that combustion is the disengagement of that principle by which the earth is maintained in its pre- sent form; that it is forever flowing from the sun throughout the solar system; and that as it is the spring of all motion and poAver throughout the earth, it must also be the cause of the annual and diurnal motions of planets. 262 ELECTRICITY. If, then, caloric be the physical cause of all motion, an universal principle of action in nature, Avhat is elec- tricity? Is it a distinct fluid, sul generis? or is it a modification of the igneous principle? These ques- tions, so intimately connected Avith the Avhole theory of physics, have never yet been satisfactorily an- swered. If electricity Avere the generic moving prin- ciple throughout nature, it ought to be everjAvhere present. But so far is this from being the fact, that it is only under peculiar circumstances that it is de- veloped so as to be appreciable by the senses; Avhereas, it is impossible to realize the absence of caloric, which is indispensable to all the phenomena of climate, sea- son, the growth of plants and the life of nature. If we admit the existence of an electric fluid, sul generis, which darts through conductors and communicates a shock to the liAdng frame, we cannot refer to its agency the melting of winter snows and polar ice- bergs, the conversion of water into vapour or steam, the elastic force of the atmosphere and other gases, the phenomena of winds, &c, Avithout recognizing its identity with the cause of temperature. As the subject is acknowledged by all philosophers of the present day to be involved in the utmost ob- scurity, I shall offer no apology for endeavouring to place it in a neAV light. While many regard elec- tricity as the cause of all molecular attractions and others as the vital principle, almost everything con- nected with its origin and laAvs is either debatable or unintelligible; some maintaining with Franklin, that it is a subtile and inconceivably refined species of matter, diffused throughout nature; others, that it is ELECTRICITY. 263 a compound of two fluids, each of which repels its OAvn particles and is attracted by the other; while a third party maintains that it is neither, but a mere effect or property of ponderable matter. Such differences of opinion are alone sufficient to show how vaguely and imperfectly it is understood. Since the time of Franklin, many thousand experi- ments have been repeated, Avithout affording any pre- cise or satisfactory information in regard to its origin or the mode of its operation in the work of the uni- verse. The discoveries of Galvani, Volta, Davy, CErsted and Faraday have opened to us an immense store of new facts; but where is the general principle Avhich connects them with the theory of cohesion, capillary attraction, chemical solution, vapourization and the elastic force of gases? What the present state of the science requires, is not the repetition of experi- ments that have been performed a thousand times, but a more comprehensive and profound investigation of those properties which connect electricity with the laws of heat and light and with the general phe- nomena of nature. If ever we shall be enabled to lift the Aeil Avhich nature has spread over the first principles of things and behold the secret spring of her simple and sublime mechanism, we must first learn the relations of caloric and electricity. If it can be shown, that under all circumstances they are modifications of one and the same agent, the science of nature will be at once divested of that complexity which has hitherto baffled every attempt to reduce the phenomena to fixed prin- ciples. 264 ELECTRICITY. It is not nvy object to enter into a detailed exami- nation of the various conflicting hypotheses Avhich have been invented to explain the phenomena of electricity; and which, for the most part, have been founded on the partial and often ill-conceived experi- ments of a little laboratory. The truth is, that all our experiments are but feeble and imperfect imita- tions of what is perpetually going on in the laboratory of nature. But Avho has ever studied the natural his- tory of lightning, by tracing its genealogy or nascent production, as connected with evaporation and all the phenomena of precipitation? Who has carefully observed the connection betAveen flashes of lightning and torrents of rain, hail, tornados, hurricanes, &c? The fundamental laws of electricity which connect it with caloric, light, magnetism or the sublime move- ments of geology and meteorology, will never be de- duced Avith unerring fidelity from mere artificial ex- periments. The greater part of those on electricity are calculated rather to amuse and astonish children than to edify those who are in quest of useful know- ledge. It may be proper to observe, before I proceed fur- ther, that some of the most enlightened men of the last century supposed that the phlogiston of Stahl, (Avhich Avas the undiscovered latent heat of Dr. Black,) Avas the basis of heat, light and electricity. Dr. Kir- Avan, Avho strangely confounded hydrogen Avith the phlogiston of Stahl, supposed that electricity might be composed of this substance greatly rarefied, in a state of combination Avith elementary fire; Avhile M. Benedict De Saussure regarded it as a fluid composed ATMOSPHERIC ELECTRICITY. 265 of heat and some other unknown principle. (Voyages dans les Alpes, tome ii. p. 243.) The Abbe Nollet, Dr. Hill, the Rev. W. Jones and some others have main- tained that heat and electricity Avere modifications of the same agent: but as their opinions were not sup- ported by an extended examination of their recondite analogies or fundamental laws, philosophers have con- tinued to regard them as distinct imponderables. ATMOSPHERIC ELECTRICITY. The most direct and compendious method of ascer- taining the relations of caloric and electricity', would be a careful history of all the phenomena connected Avith the origin of lightning. If it can be shown that the caloric of aqueous vapour is the basis of lightning, their radical identity must follow as a necessary con- sequence, notwithstanding the widely different proper- ties Avhich they exhibit. The truth is, that diversity of form and external appearance is no evidence of a difference in the nature and fundamental constitution of things; for it has been demonstrated experimentally by numerous philosophers, that all the varieties of elec- tricity are essentially the same. What can be more different than ice, water and steam? Yet they are composed of the same elements, combined Avith dif- ferent proportions of caloric. What more opposite in all their properties than nitric acid and the gases of A\Thich it is formed? And so of a thousand other bodies. It Avas long imagined that Avhen Franklin drew the lightning from heaven and demonstrated its identity with common electricity, that he had laid the founda- 266 ATMOSPHERIC ELECTRICITY. tion of its true theory. But it is now evident that his views in regard to its origin and nature were partial and erroneous. At one time he supposed that it was generated in the ocean by the friction of salt and water; that oceanic vapour was held in a state of ex- pansion by electricity and heat united, Avhile evapora- tion from the land was caused by heat alone. He also maintained that the fusion of metals by the electric fluid was a cold fusion; whereas it is now well knoAvn that lightning heats, melts, ignites and volatilizes all bodies. That the general reader may have a distinct idea of the existing state of knowledge in regard to the origin of lightning, it may not be amiss to present the statements of some of the most distinguished recent writers on the subject. It is observed by Mr. Daniell, that "since the time of Franklin, atmospheric electricity has been almost entirely neglected;" and that on this most important branch of physical science, he had "nothing decisive to offer." (Meteorological Essays, p. 135 and 374.) The consequence of which is, that he has left unexplained many of the most striking and important phenomena of meteorology, such as hurricanes, tornados and hail- storms, with all those violent movements of the atmo- sphere which accompany rapid discharges of lightning. Dr. Arnott also states, that tornados, whirlwinds, &c. are owing to some chemical changes in the atmosphere not fully understood. (Elements of Physics, vol. i. p. 397.) Dr. Thomson observes, in his late work on Heat and Electricity, that " the formation of vapour seems to be EVAPORATION AND CONDENSATION. 267 connected with electricity, though in what way we have no conception, and that the change of vapour into clouds is probably connected with electrical phe- nomena not understood." (Page 275 and elsewhere.) He adds, that "the formation of rain is still invohTed in impenetrable obscurity." It is also observed by Professor Forbes, that on the noble science of atmospheric electricity, almost every- thing has yet to be done. (Transactions of the British Association, vol. i. p. 252.) As the phenomena of lightning have been univer- sally known to be immediately connected with the production of rain, it becomes necessary to ascertain with certainty the cause of evaporation and condensa- tion, before attempting to solve the problem of atmo- spheric electricity. That caloric is the true and only cause of evapora- tion, or the formation of steam, is one of those self- evident propositions which would seem to require no proof. But to remove all doubts upon the subject, the fact has been experimentally demonstrated by Dr. Dalton, to whom the science of chemistry and meteor- ology is so largely indebted. He put a little water in a dry glass flask, with a thermometer in it, when he found that a small quan- tity of vapour was formed at 32° F. At 40° the amount Avas increased; at 50° it contained still more vapour; while at 60° the quantity wras yet further augmented. He also found that when the tempera- ture of the flask was suddenly reduced from 60° to 40°, a portion of vapour was converted into water, and that the quantity retaining the elastic form was 268 EVAPORATION AND CONDENSATION. precisely the same as when the temperature Avas origi- nally at 40°. The above is a simple and beautiful representation of what is perpetually going on throughout the atmo- sphere and in the steam engine. By another series of admirable experiments, he ascertained that the quantity of water evaporated in a given time, Avas exactly in proportion to the elastic force of vapour at the same temperature, whether formed in vacuo, or under the pressure of the atmo- sphere, with this difference, that in the latter case the process goes on much more slowly, because the atmosphere presents a mechanical impediment to its diffusion somewhat analogous to the obstruction of water by porous sand. From which he inferred that A^apour is not chemically united with the air, as had been formerly supposed, but mechanically diffused through it, forming a distinct atmosphere of its own, the elastic force of which is always in proportion to temperature. At 0° he found the elastic force of vapour equal to the pressure '064 inch of mercury; that is, about one- fifteenth of an inch. At 32° it amounted to one-fifth of an inch; at 47°, about one-third of an inch, or *339; at 59°, *507, or one-half of an inch; at 80°, one inch; and at 90°, 1*360. He also ascertained that the elastic force of vapour at 212°, is equal to the pressure of the whole atmosphere, or 30 inches of mercury.* (Man- chester Memoirs, vol. v.) * Dr. Prout observes, that " atmospheric air, under ordinary cir- cumstances, exerts an elastic force equal to the weight of a column of mercury 30 inches high; and that at 21*2°, aqueous vapour EVAPORATION AND CONDENSATION. 269 From the above experiments it follows, that if the temperature of the earth were 80°, from the equator to the poles, the quantity of vapour would be every- where the same and equal to about one-thirtieth of the average weight of the whole atmosphere; but that if its temperature Avere reduced from 80° to 59°, one- half of the vapour would be precipitated in the form of rain; if to 32°, four-fifths of it would be converted into snow; and if reduced to 0°, 14 out of 15 parts of the Avhole would descend to the earth in the form of ice, in obedience to that universal law of nature by which bodies cohere and tend toward a common centre. But as the temperature of the earth diminishes from the equator to the poles, it is obvious that the amount of Avater which is capable of existing in the atmosphere in the state of transparent elastic \7apour, must vary proportionally in different latitudes. There is also more vapour in the atmosphere of the ocean, other things being equal, than over extensive bodies of dry land. According to the observations of Captain Sabine and Mr. Caldcleugh, as detailed by Professor Daniell, it Avould appear, that within the tropical ocean, between the Avestern coast of Africa and the eastern coast of obeys precisely the same laws and exerts the same elastic force as atmospheric air under similar circumstances." (Bridgewater Trea- tise, chap. v. section 2.) But it has been shown that the elastic force of atmospheric air is equal to the pressure of more than 1200 atmospheres, (3000 feet of mercury.) It is therefore obvious that Dr. Prout has mistaken the weight of the atmosphere for its elastic force. 270 EVAPORATION AND CONDENSATION. South America, the point of deposition, or dew-point, is generally about 4° or 5° beloAv the existing tem- perature; sometimes only 2°; and rarely more than 8°; while in the interior of large continents it is often 20° or 30°, and sometimes 50° or more, below the pre- valent temperature. As the atmosphere is in a state of nearly constant circulation, it is removed from one place to another before arriving at the point of satu- ration, and therefore contains less vapour than it is capable of sustaining at the existing temperature. Within the torrid zone, it is perpetually expanded by solar heat, where it rises into the upper regions, whence it flows to higher latitudes; while it is removed by horizontal currents termed sea breezes, from the ocean to the heated land. If at the temperature of 80°, the atmosphere con- tain an amount of Arapour equal to the pressure of only half an inch of mercury, while it is capable of sus- taining twice that quantity, it will require a reduction of temperature below 59° to cause precipitation. Hence it is, that the atmosphere often undergoes great reduc- tions of temperature without producing rain. But when the air is full of vapour the process of evapora- tion is arrested; which explains why a cold dry air is more favourable to evaporation than warm air that is already saturated, especially if the former be in a state of rapid motion. Dr. Dalton found that when boiling Avater was ex- posed to a current of air that carried off its vapour as fast as formed, vapourization went on a third faster than in a room where the air was still. Hence it is, that northeast and east winds, which, in the west of EVAPORATION AND CONDENSATION. 271 Europe are generally dry, and far below the point of saturation, seldom condense the vapour of France and England; but, on the contrary, often redissolve the clouds already formed, producing clear Aveather. Dur- ing summer, when the atmosphere has been for some time comparatively still, it is soon saturated with va- pour, which is indicated by heavy dews, and the for- mation of clouds termed cumuli, in which case the weather becomes hot and sultry; because the caloric Avhich is usually carried off by evaporation and winds, accumulates on the surface of the earth and heats the superincumbent air. Such a state of things generally forebodes an approaching thunder-storm. That the condensation of atmospheric vapour is owing to the abstraction of its caloric by colder cur- rents of air, is evident from the fact, that in the tro- pical ocean far from land, where the trade-wind blows steadily in one direction, and Avhere the temperature seldom varies more than two or three degrees, there is less rain than in the vicinity of continents and large islands, where currents of air of different temperatures frequently meet. In the great desert of Sahara, there is scarcely any rain, because the wind blowing over it is generally in the same direction; Avhile the vapour transported by it from the ocean is still further rarefied by the intense heat reflected from the scorching sands, where there are no mountains to arrest its progress. There are also long droughts in Egypt, Palestine, New Holland and many other parts of the world Avhere the Avinds Woav long in one direction, without encountering colder currents." During summer, in the United States, the 272 EVAPORATION AND CONDENSATION. atmosphere is often so much heated, that the Aapour brought from the ocean by southern winds is not con- densed for several Aveeks, and sometimes tAvo months, but is further expanded, until it becomes saturated, or meets with a current from the northern points of the compass, Avhen thunder-gusts follow. When I come to treat of winds it Avill be shown, that the most extensive falls of rain in the middle latitudes are produced by the meeting of immense masses of air from opposite quarters of different tem- peratures, as during the equinoctial floods and storms. When both contain as much vapour as they can sup- port at their respective temperatures, the amount of precipitation is of course the greatest. Corresponding Avith the experiments of Dalton, is the well-established fact, that the greatest quantity of rain falls within the tropics, where the average tem- perature is from 80° to 85° F., and diminishes on to the regions of lowest mean temperature, where it is about 0°. Hence it is that the largest rivers in the Avorld are found in the tropical regions, as the Amazon, La Plata and Orinoko of South America; and the Indus, the Ganges, the Nile, the Tigris, &c. of the east- ern continent. The following table exhibits a general view of the relative depths of rain in different latitudes:— Lat. N. Inches. Coast of Malabar........................ 12° .................. 136 Grenada.................................... 12° .................. 126 Cape Francois............................. 19° 46/.................. 120 Senegal..................................... 00°.................. 115 Calcutta.................................... 22° .................. 81 Havana .................................... 23° 19-".................. 109 EVAPORATION AND CONDENSATION. 273 Lai. N. Inches. New Orleans.............................. 29° 58/.................. 63 Cincinnati................................. 39° 06'.................. 36 Philadelphia............................... 39° 57'.................. 3653 Boston...................................... 42° 21'.................. 39-22 Rome....................................... 41° .................. 39 England (Dalton's mean).............. 50° .................. 31 Petersburg ................................ 59° .................. 16 Uleaborg................................... 65° ................. 13£ The above results are greatly modified by a variety of circumstances, such as prevalent Avinds, the relative positions of land and sea, mountain ranges, &c. For example, the trade-wind which blows constantly from oast to west over the Atlantic Ocean Avithin the tropics, deposits a far greater amount of rain on the eastern slope of South America, than on its Avestern coast. At Vera Cruz, 278 inches have been observed to fall in the course of one year, and at San Luis, in south latitude, 2° 30', it has been 280 inches. But in the middle latitudes of the northern hemisphere, where the prevalent wind is from the opposite direction, the case is reversed. Hence the greater amount of rain Avhich falls on the western coasts of Europe and North America, than in the interior of those continents, being wafted from the Atlantic and Pacific oceans. There is also more rain in mountainous regions than on extensive plains. It has been ascertained, that about double the quantity of rain falls on Mount St. Bernard, that falls at Geneva; and that the mean annual amount of twenty places in the lower valleys at the base of the Alps, is 58*5 inches, according to M. SchoAv. The reason is, that the onward progress of vapour is arrested by mountains, which cause it to 18 274 EVAPORATION AND CONDENSATION. accumulate. Even so far north as Bergen, in Norway, where the soutliAvest winds are impeded by mountains, the annual depth of rain is 88 inches. There is nothing more admirable in the great drama of nature than the process of evaporation and con- densation, by which all the waters of lakes, rivers and fountains are elevated from the ocean; transported over continents and islands; precipitated by polar cur- rents; and distributed in the form of great natural shower-baths over the dry land. Notwithstanding the greater amount of evapora- tion and rain in the tropical than higher latitudes, the atmosphere is more transparent, and there are more clear days in the equatorial regions; and more during summer than Avinter in temperate climates. According to the estimate of La Cotte, which may be regarded as an approximation to the truth, the average number of rainy days between lat. 12° and 60° N. are in the folloAving ratios:— N. Days. From lat, 12° to 43°.................................... 78 43° to 46°.................................... 103 46° to 50°.................................... 134 50° to 60°.................................... 160 It is therefore evident that the transparency of the atmosphere, other things being equal, is in proportion to temperature, which diminishes from the equator to the poles. It is also known to decrease from below upward.* Hence it is, that the loAver atmosphere is * It was supposed by Leslie and Dalton, that the diminution of temperature in the atmosphere, on ascending above the earth's surface, was owing to its increased capacity for heat, caused by EVAPORATION AND CONDENSATION. 275 transparent, even when the sky is overcast with clouds,* the elevation of which is in proportion to temperature; that is, the plains of condensation are higher within the tropical than middle latitudes; while in the latter their elevations vary Avith the season. From the observations of Mr. Crosthwaite it Avould appear that the under surface of dense clouds in the north of England does not exceed 1300 yards during winter, nor 2000 yards in summer. (Daltons Meteor- ological Essays, p. 136.) augmented rarefaction from diminished pressure. But this is not the only cause; for it is well known, that large portions of Asia, Africa and South America are from eight to ten thousand feet above the level of the ocean; whereas their average temperature is much higher than that of isolated mountains of equal elevation in the same latitudes. Mount Lebanon is not much higher than the plateau of Mexico ; yet the former is covered with snow nine months in the year, while there is perpetual summer on the table- lands of Mexico, about the same latitude and elevation. The plains of Michigan are about 600 feet above the sea; yet there is no State in the Union in which the temperature rises higher during summer. The truth is, that the greater warmth of the lower at- mosphere over extensive plains, than that of mountains, is owing in part to the absorption of the sun's rays by the earth's surface. The stratum of air in contact with the earth becomes heated and rises, when the next stratum is heated and rises, until the whole atmo- sphere becomes warmed to a considerable height. Hence it is, that the plain of perpetual congelation varies in height in different parts of the world in nearly the same latitudes. * The dryness of the atmosphere is in proportion to the eleva- tion of its temperature above the dew-point, which decreases from the surface of the earth to the region of clouds. This explains why rain often ceases about mid-day, when the clouds are redis- solved by the increasing power of the sun; and why the lower atmosphere is so often obscured in England by a misty rain after sunset during winter. 270 LIGHTNING AND RAIN. To pursue this subject through all the complicated phenomena of meteorology, would far exceed the scope of the present inquiry, the principal object of which is to trace the origin and history of atmospheric elec- tricity. The cardinal facts Avhich connect the phenomena of lightning with the theory of rain may be reduced to the following propositions:— 1. In the torrid zone, where evaporation and rain are most copious, the amount of lightning is greatest. There is also far more during summer than winter in the middle latitudes, and scarcely any in the polar regions. 2. In those parts of the Avorld where there is no rain, there is no lightning, as at Lima in Peru; nor is there any in Egypt, Palestine and other parts of the world during the prevalence of dry weather. It there- fore follows,— 3. That Avhere there is no condensation of aqueous vapour, there is no lightning. The most superficial observers of nature have been impressed Avith the immediate connection between lightning, intense heat and rapid precipitations of rain. By a careful analysis of the phenomena it be- comes self-evident, that if caloric be the true and only cause of evaporation, condensation and precipitation can be effected only by the evolution of the same agent. Dur- ing Avinter, the quantity and elastic force of vapour in the atmosphere are comparatively low in the middle latitudes, where it is condensed gradually on meeting with colder air. During spring, evaporation augments Avith increase of temperature, when masses of warm LIGHTNING AND RAIN. 277 and cold air often meet, causing frequent showers of rain and sometimes hail, still without much thunder and lightning. But during summer, when the tem- perature becomes tropical, and the atmosphere satu- rated Avith highly elastic vapour, we have tremendous explosions of thunder and lightning, with rapid pre- cipitations of rain and hail. Corresponding with the temperature of the torrid zone, and the amount of evaporation, thunder-storms occur almost daily during the rainy season, on the coasts of India and South America. One of the most prominent errors in regard to the natural history of lightning, is the prevalent notion that it collects around the surface of clouds, as if they Avere solid insulated conductors; and that when it be- comes accumulated to a certain extent, it darts from one to another. Nothing could be more in opposition to all analogy and experience. Clouds are only banks or strata of moisture, Avhile it is universally known that electricity cannot be accumulated in a moist at- mosphere; that it is diffused and dissipated by moist- ure, and thus prevented from being collected in a Ley den battery. It is accumulated in transparent aqueous vapour, (as I shall proceed to shoAV by the most decisive facts,) from which it darts through the neighbouring clouds in such a manner as to present the appearance of proceeding from them; Avhile it is an optical illusion that may be corrected by a philo- sophical examination; in short, that a large body of transparent elastic vapour from the tropics, may be compared to an immense Leyden battery, filled with an igneous fluid, Avhich is discharged in the concen- 278 LIGHTNING AND RAIN. trated form of lightning on approaching mountains, or meeting Avith currents of cold air. When the inquiry is divested of all extraneous and hypothetical considerations, it may be reduced to the following conditions. If it can be shown, that transparent elastic vapour is the vehicle of atmospjheric electricity, and that It is rapidly condensed during discharges of lightning, it will necessarily follow,, that the caloric of such vapour is given out in the concentrated form of electricity during a thunder-storm. In reply to this reasoning it may be objected, that heavy rains are often unattended Avith lightning. To Avhich I ansAver, without fear of contradiction, that the formation of clouds and precipitation of rain are far more rapid during thunder-storms than when there Is no lightning. It is stated by Humboldt and others, that Avithin the tropics during the rainy season, the first indication of an approaching storm is generally a light wind, with a feAV scudding clouds; but that Avhen it begins to lighten, the whole sky is suddenly obscured by dense clouds that immediately descend in torrents of rain. That atmospheric electricity is a constituent of aqueous vapour, will appear from the description of a thunder-storm among the Alps, as recorded by the celebrated De Luc, in his. " Ideas sur la Meteorologie." He states that it commenced with abundant discharges of electricity from dry transparent air, which contained neither vapours nor the electric fluid, but the constituents of both,—and that clouds were suddenly formed around the summit of the Buet, during each explosion. In other DE LUC AND MURPHY. 279 words, that simultaneous with the discharges of light- ning from dry transparent air, was the sudden forma- tion of clouds, and precipitation of rain. From another portion of De Luc's work, it is obvi- ous that he mistook transparent aqueous vapour for "dry air." He supposed that clouds were formed by the union of oxygen and hydrogen gases by the agency of electricity, as water is generated by passing an elec- tric spark through them* It was long ago supposed by Plato, that fire, when concreted, becomes air, which, on being further con- densed, constitutes clouds and water; which are also convertible into earthy bodies; and all of them again into flame or fire. (See Timcvus, ch. xxxi.) According to Seneca, the ancient Stoics taught a similar doctrine—"that air was converted into fire and water," during a thunder-storm:—(Natural Ques- tions, book ii.) from Avhich it Avould appear, that they were ignorant of the process of evaporation, by which water is expanded into elastic vapour like air; or that they confounded the one Avith the^other.____________ * This hypothesis has been revived by Mr. Murphy of Cam- bridge, in a recent work on Electricity, the professed object of which is to reduce the science to mathematical laws. Had this author traced the history of rain from the first process of evapo- ration, he would probably not have maintained that heavy showers of rain which accompany lightning, may be produced from the combination of oxygen and hydrogen by electricity, after it had been demonstrated by Dalton that vapour or steam is composed ot water and caloric, and that its condensation is owing to the evolu- tion of caloric, whether attended with lightning or not. The sup- position of Dr. Darwin was more consistent, who maintained that electricity was the cause of evaporation, because discharges of lightning are attended with rapid precipitations of rain. 280 SENECA AND THE STOICS. In the 22d chapter of the same book, in Avhich Seneca gives his oavh opinion, he maintains that five and lightning are the same, because the latter produces the same effects as fire, such as the heating and melt- ing of metals, the combustion of forests, &c.; but that in lightning, fire was greatly condensed.* That caloric and electricity Avere regarded as identical during the earliest ages of the world, would appear from the fact, that the oriental Avord ~)1N, aur, was emplojed to denote both fire and lightning. It is generally sup- posed that the Avord electricity Avas derived from the noun TjXexrpov, amber, a shining substance; which, on being rubbed, Avas observed by the Greeks to attract light bodies. But this last word was doubtless derived from TjXexrwp, a name of the sun, the great fountain of electric fire. But to return from this digression; if it be true that caloric is the cause of evaporation, (as proved by De Luc himself,) and if transparent vapour be suddenly condensed into clouds and rain, Avith a rapidity pro- portional to the amount of lightning, the conclusion is inevitable, that solar caloric is the real basis of lightning; for it would be a violation of all the rules of * Aristotle and Pliny also speak of the fusion of metals by lightning,—the first, of the copper on a shield, while the wood which it covered was uninjured; the latter, of gold, silver and copper coins, sealed up in a bag, which was not burned. In sup- port of their statements, M. Arago relates that in 1781, M. D'Aussac, and the horse on which he was mounted, were killed by lightning in the neighbourhood of Castres, when the blade of his sword was fused upon its surface at several places, while the scab- bard containing it was not burned. OBSERVATIONS OF THE AUTHOR. 281 philosophrdng, to maintain that water is converted into vapour by one agent, and again reduced to water without the evolution of the same agent. No sophistry can evade this simple but rigorous logic. That the rapid precipi- tation of rain during a thunder-storm is in proportion to the amount of lightning, is attested by all experi- ence and observation. Hence it is, that during the fiery tempests of the tropical regions, termed hurri- canes, more rain is precipitated in a few hours, than during as many months in colder latitudes. It may be said that lightning is sometimes unat- tended Avith rain: to Avhich I answer, that vivid flashes never occur immediately over head, Avithout a precipitation of rain or hail. This is the most con- vincing proof, that the caloric of vapour is giAen out in the condensed form of lightning, and is that kind of evidence from which there is no appeal, being the spontaneous declaration of nature herself, made in the most sublime and ostensible manner. On the 2d of June, 1833, the author had an oppor- tunity of observing for himself, that lightning proceeds from treuisparent vapour, and not from clouds already formed, as many persons suppose. This beautiful dis- play, which Avas Avitnessed by hundreds of individuals with admiration, occurred at NeAv York, about 7 p. m., after a shoAvery day. The wind was from the south, while the Avestern sky Avas of a brassy hue, through which the descending sun was perfectly visible. In this state of the atmosphere, a vivid streak of light- ning Avas seen to dart from it, Avhen clouds Avere imme- diately formed that intercepted the solar rays, as if an immense black curtain had been draAvn across the 282 MARCORELLE AND DUPERREY. Avestern sky, and attended Avith copious precipitation of rain.* Such facts afford more decisive information in re- gard to the nature of lightning, than volumes of mere speculation, or than thousands of artificial cxperi- * Since the London edition of this work was published, I have met with many similar statements in the newspapers of the United States, and in the writings of the older meteorologists of Europe. It was maintained by Franklin, Saussure and others, that thunder never proceeds from a solitary cloud. But, in opposition to this opinion, it is related by M. Marcorelle of Toulouse, that on the 12th of September, 1147, the sky being generally clear, a single small cloud was observed, from which lightning and thunder pro- ceeded, by which a female named Bordenare was killed. Duhamel also relates, that on the 30th of July, 17G4, at half-past five p.m., in bright sunshine and a clear sky, there appeared a small dark solitary cloud, from which lightning and thunder proceeded, by which an elm-tree near the chateau of Denainvilliers was stricken. Capt. Duperrey, of the French corvette Urania, further relates, that being in the Straits of Bombay, in Nov. 1818, he saw a small white cloud in a clear sky, about the magnitude of the sun, from which lightning issued of a zigzag form, followed by thunder which resembled the irregular discharge of musketry. It is also stated in the New York Sun, of July 31, 1845, that on Monday, the 28th of the same month, at Worcester, in Massachusetts, a building was struck by lightning which proceeded from a small cloud and was not attended by any rain. But it is here worthy of notice, that in such cases, where the lightning is at a considerable distance, there may be rain at that place, though not perceived by an observer. Several of the above examples are related by Dr. Lardner, who has not, however, perceived their bearing in regard to the identity of caloric and atmospheric electricity. The immediate connection of rain with discharges of lightning from aqueous vapour, seems to have been noticed in the Book of Job: "Who hath divided a way for the lightning of thunder, to cause it to rain on the earth?" (Chapter xxxviii. v. 25.) BECCARIA AND FRANKLIN. 283 ments; for they completely establish the important fact that elastic vapour is the proximate source of atmo- spheric electricity, and not clouds. Nevertheless, I shall prove by the experiments of De Saussure, Read and Pouillet, that electricity may be disengaged from all v^apours generated by the agency of caloric, whether by natural or artificial means, or by combustion; that it rises from the earth in a latent state of combination Avith aqueous vapour, Avhich it maintains in the elastic form,—whence it may be withdrawn by conductors, and tested by the electrometer. Scarcely one of the older Avriters on meteorology, clearly understood the simple process of evaporation. Beccaria supposed that the earth Avas full of electric matter, Avhich rises to the upper regions of the atmo- sphere, carrying with it Avater in the form of vapour. (Priestley s Hist, of Electr. p. 340.) Franklin also supposed, that vapour Avas elevated from the sea, by the united agency of heat and elec- tricity. But it is now Avell established, that caloric is the vapourizing agent all OArer the world; that wherever there is heat, Avith Avater in sufficient quantity, vapour is produced, whether from the ocean, fresh water lakes and rivers, or from the surface of the dry land; and that, other things being equal, its amount, like that of lightning, is determined by temperature. Had Frank- lin clearly understood the process of evaporation, and traced the connection betAveen discharges of lightning and precipitation, he Avould probably have added to his discover}- of the identity of lightning and common electricity, the still more important fact, that caloric 284 VOLTA, LAVOISIER AND LAPLACE. and electricity are different manifestations of the same potent element. The celebrated Volta adopted the opinion of Frank- lin, Avith some slight variation. He supposed that all bodies contained electricity, a portion of Avhich Avas evol\red Avhenever they undenvent a change of state; that Avhen Avater Avas converted into vapour by the agency of solar heat, it acquired a greater capacity for - electricity, Avhich it absorbed and carried into the at- mosphere during the process of evaporation; that it Avas liberated Avhenever the vapour Avas condensed by cold, and thus accumulated in the upper regions of the air;* that Avhen clouds are formed, Avhich are good conductors of electricity, they become a medium by Avhich it is conveyed back to the earth in a tranquil manner, or in the form of lightning, according as it is more or less abundant. (Journal de Physique, Aout. 1783.) Some experiments of Lavoisier and Laplace, pub- * Seneca informs us that Anaxagoras taught that lightning de- scended from the ethereal regions, and was collected in clouds, from which it was discharged after being greatly accumulated. The same hypothesis has been recently brought forward as new by Dr. Hare, with this difference, that he supposes the earth to constitute another great reservoir of the electric fluid, and that the atmo- sphere is situated between two oceans of electricity; while the clouds formed in the non-conducting air operate as movable in- sulated conductors. He further supposes, that thunder-storms are more frequent during warm than cold weather, in consequence of the greater elevation to which the clouds then attain, and their consequent approximation to the celestial ocean of electricity. (Theoretical Suggestions Bespecting the Causes of the Tornado, or Water-spout, &c, by Robert Hare, M.D., of Philadelphia.) DE SAUSSURE AND READ. 285 lished in the Memoirs of the French Academy in 1781, were intended to prove that electricity is disen- gaged during the process of evaporation: but their results were vitiated by the agency of chemical action, Avhich accompanied the process of evaporation in most of their experiments. Besides, they did not extend their researches to the connection of atmospheric elec- tricity with the phenomena of meteorology; they have therefore been very little attended to by phi- losophers. Lavoisier and Laplace found, that Avhen water Avas poured by drops into an iron vessel heated, Avhile the vessel communicated with an electroscope, it gave signs of positive electricity; that when dilute sul- phuric or nitric acid was poured upon iron filings, electricity was evolved; also, during the action of dilute sulphuric acid on chalk and during the com- bustion of charcoal. Their experiments tend to shoAV the relation betAveen chemical action and the evolu- tion of electricity, but throw very little light on the connection of electricity with evaporation. The most decisive results are those of De Saussure and Mr. Read, Avho performed many hundred experi- ments with the greatest care, for the purpose of ascer- taining the source of atmospheric electricity; the re- sult of Avhich led them to the conclusion, that a perpetual circulation of the electric fluid is kept up by means of evaporation and condensation. De Saussure found that when Avater, spirit of wine and ether were made to boil in silver, or white porce- lain vessels heated, and suspended by silk cords, nega- tive electricity Avas obtained; but when a piece of red- 286 EXPERIMENTS OF DE SAUSSURE. hot iron Avas throAvn into a vessel containing a small quantity of Avater, positive electricity Avas strongly developed. He supposed that the vast quantities of electricity discharged from volcanos Avas generated by the action of so great a heat on waters that find tlieir way to those immense furnaces. In all such'cases, it is disengaged partly by chemical action, as Avill be noticed when I come to treat of voltaic electricity and volcanic forces. The following experiments of De Saussure show that aqueous vapour, hoAvever produced, contains elec- tricity. He caused Avater to boil in a coffee-pot by placing it on an insulated chauffer, (heater,) when the coffee-pot Avas electrified negatively, during the con- densation of the vapour. He varied the experiment, by causing the vapour of boiling Avater to pass into the cap of an insulated alembic, to which he applied snoAv, causing a condensation of the vapour con- tained within it, when the apparatus became electri- fied negatively. The same effect was produced in a more remarkable manner, by applying a mixture of common salt and snow as a refrigerant. He observes, that in all such cases, electricity is disengaged from the vapour and conducted to the metallic vessel during the process of condensation. (Voyages dans les Alpes, tome ii. p. 251.) De Saussure adds, that the electric fluid is generated during the conversion of water into vapour by heat; that it combines with vapour and contributes to Its formation; " that it rises invisible and inactive, hid in the bosom of vapours; but aftenvards displaying its energy Avhen those vapours are changed in form, it redescends ac- THOMSON AND DE SAUSSURE. 287 tive, animated by its penetrating and expansive force.'1 (Voyages dans les Alpes, tome ii. p. 244.) But it is quite evident that his ideas were vague and unsettled in regard to the origin of atmospheric electricity; for he observes in another volume of the same work, that it seemed to be produced by the friction of clouds against the air; by the action of the solar rays; or by these tAvo causes united. (Vol. i. p. 241.) Dr. Thomson has expressed nearly the same opinion in his late work on Heat and Electricity: "that atmo- spheric electricity may result from the friction of two currents of dry air moving different ways." (Page 441.) De Saussure supposed that there were tAvo kinds of vapour; the one vesicular* and visible, Avhich con- tained electricity; while transparent elastic ATapour Avas combined with, and sustained by, the expansive agency of heat alone. (Vol. ii. p. 259.) But I have shoAvn, from the observations of De Luc on the Alps and from my own at NeAv York, that lightning is disengaged rapidly from transparent va- pour, by which the latter is condensed into rain. The observations and experiments of De Saussure are highly * The vesicular theory originated with Derham, who supposed that vapour was composed of hollow sphericles of water filled with highly attenuated air, which Mr. Leslie terms a " fanciful notion, countenanced by certain dubious optical appearances." Saussure says, that while travelling in the Alps he was enveloped in a mist which was almost stagnant, when he was astonished to see drops, as he thought them, floating slowly past him, without falling to the ground, some of them larger than the largest peas ; but catching them in his hand, he found them to be bladders, inconceivably thin. Truly, the philosopher must have been in a mist. But how was Berzelius trapped into the same illusion ? 288 TRANSFORMATIONS OF CALORIC. valuable; Avhile his theoretical views are often incon- sistent. He supposed that electricity AAras destroyed by explosions of thunder; that is to say, it is generated by evaporation and destroyed by condensation. But I have already shown, that such phenomena result from changes of state; and it will be seen hereafter, that there are no assignable limits to the metamorphoses of this subtile agent. They are as diversified as the multitudinous forms of external nature. Though in- visible per se, it is everywhere busy in all the trans- mutations of matter. The fabled Proteus of old is but a feeble representation of the rapid changes through Avhich it passes—noAV silently bearing the Avaters of the ocean aloft in the atmosphere in a state of trans- parent ethereal vapour—now darting in vivid corus- cations from its aerial palaces on high—leaping upon the mountains and cleaving rocks asunder—resound- ing through the heavens with its great music, and sprinkling the earth with genial showers of fruitful rain. Though constantly changing, it is never de- stroyed, but is ahvays the same powerful agent by Avhich Infinite Wisdom directs and governs the uni- verse. Who can refrain from sentiments of profound admiration of its godlike energy and the Avonderful manner in which it produces an endless succession of the most diversified effects? There is not a more striking evidence of beneficent design in the whole mechanism of creation, than the rapid evolution of heat from atmospheric vapour, in the concentrated form of lightning, during hot and sultry weather. Were it evolved gradually, as during Avinter, the number of rainy days would be so far in- EXPERIMENTS OF POUILLET AND READ. 289 creased, as greatly to interfere with the operations of agriculture. On the other hand, being given out in the diffused form of sensible heat during the forma- tion of clouds, rain and snow in the higher latitudes, it moderates the excessive cold which would otherwise prevail during Avinter. It was finely observed by a distinguished writer of the present day, " that the delight with which specu- lative minds contemplate universal truths, does not so much spring from perceiving that some general prin- ciple holds good and reappears in a great number of instances very nearly, or perfectly resembling one an- other, as from discovering the occult presence or effi- cacy of some such principle in a multiplicity of cases which have few points, or perhaps no other point of resemblance besides this one of their obedience to some abstract law." (Isaac Taylor. Saturday Evening. p. 181.) When men shall thoroughly comprehend the agency of caloric in all the diversified forms of electricity, and how they are resolvable into one general principle, innumerable new truths, the existence of which has not been suspected, will gradually open to view, until the vast and complicated mechanism of nature shall be fully unfolded and reduced to an intelligible theory. I cannot dismiss this subject without noticing the recent experiments of M. Pouillet, in connection with those of Mr. Read, which Avere performed fifty years ago; because their conclusions are in direct opposition to each other. Mr. Read maintained that electricity is given out by aqueous Arapour, (the constituents of Avhich are oxygen, hydrogen and caloric,) and by the 19 290 EXPERIMENTS OF POUILLET AND READ. vapours that are exhaled from burning substances;* while M. Pouillet contends that electricity is never developed by evaporation, unless attended with chemi- cal action. It was before stated, that De Saussure obtained elec- tricity during the evaporation of Avater from silver and porcelain vessels, Avhere no chemical action can be sup- posed to have existed. Mr. Read insulated a large hollow tin cone, Avith many yards of small wire coiled up within it, one end of which extended from the apex of the cone, which was open, and Avas connected Avith a sensitive electrometer. Under this cone was placed a vessel of water, the vapour from which, on rising, was condensed and collected by the cone and Avire, when positive electricity was produced, (which De Saus- sure could not obtain without chemical action.) The same result Avas obtained by burning different sub- stances under the cone. He maintained that the elec- tricity which he derived from the atmosphere in dif- ferent degrees, at all seasons and times of the day, was elicited from its vapour. He observed that during the formation of thick fogs electricity was abundant, but scarce during their solution and dispersion. (Spon- taneous Electricity, p. 15.) He also found that his lightning-rod was less charged with electricity while immediately under a cloud, than when at some dis- tance from it; and that it acquired more electricity before the rain commenced than afterwards; a fact which was also observed by Beccaria. * Mr. Read considered combustion as a species of evaporation, by which solid and fluid bodies were converted more or less rapidly into the gaseous state. EXPERIMENTS OF POUILLET. 291 These beautiful and important experiments will enable us to comprehend those of M. Pouillet, which he seems not to have rightly understood himself. He placed a cylindrical piece of charcoal in a vertical posi- tion, the top of which was two and a half or three inches below a plate of brass that was connected Avith the condenser. When the upper part of the charcoal was ignited, a current of carbonic acid arose and came in contact with the brass plate, by which the condenser was positively electrified in a few minutes. By placing the inferior end of the charcoal on the condenser and igniting the upper end, the condenser was charged Avith negative electricity. From these experiments Pouillet concluded, that during the combination of oxygen Avith carbon, it gave out positive electricity, while the carbon gave out negative electricity. During some of his experiments, both positive and negative electricity were evolved by the combustion of charcoal and hydrogen; from which it would seem to follow, that positive and negative electricity are only plus and minus conditions of the same agent; although this seems not to have been suspected by Pouillet. The following experiments are among the most instructive Avhich have been recorded by the French philosopher. He caused hydrogen gas to flowr out of a glass tube. When it was ignited, a vertical flame was produced, nearly half an inch in breadth and three inches in height. A coil of platinum wire Avas employed to conduct the electricity from the flame to the condenser. When the coil was large enough to inclose the flame, and to be about four inches from its external surface, positive electricity was indicated, as 292 EXPERIMENTS OF POUILLET. in the experiments of Mr. Read, which became more and more intense as the distance diminished, until the coil touched the flame, when nearly all signs of elec- tricity disappeared. Hence it was concluded, that around the flame of hydrogen gas there is a sort of atmosphere at least four inches in thickness, Avhich is ahvays charged with positive electricity. Noav, it is obvious that aqueous vapour is produced during the combustion of hydrogen gas, constituting an atmosphere above and around the flame; which vapour gives out positive electricity as proved by Mr. Read. It is also evident, that in the immediate vicinity of the flame, the vapour cannot be condensed by the platinum coil; and therefore cannot give out much, if any, electricity. It is for the same reason, that the vapour of the atmosphere gives out less elec- tricity during the heat of a clear day, than in the even- ing. When Pouillet placed a small coil of platinum wire in the centre of the flame, so that it was enve- loped on all sides, and made to communicate vvith a condenser, the instrument was electrified negatively. This is a thermo-electric phenomenon which has very little connection with atmospheric electricity, as will be seen hereafter. He found that during the combus- tion of alcohol, ether, wax, oils, fat and many vege- table bodies, the same phenomena were • exhibited as in the experiments with burning hydrogen. (An. de Chim. et de Phys. xxxv. 401, et xxxvi. 5.) The principal error of M. Pouillet was in supposing that electricity is never produced by evaporation, un- less attended Avith more or less chemical action; that Avhen Avater was evaporated from platinum cups, no POUILLET, DE SAUSSURE AND HARRIS. 293 electricity was evolved. In addition to the evidence of De Saussure, are the recent experiments of Mr. Harris, who has found that the evaporation of pure water from platinum vessels is attended Avith a dis- tinct evolution of electricity; so that the doctrine of Pouillet cannot be admitted, that atmospheric elec- tricity is wholly supplied by chemical action and the growth of plants. It is impossible to conceive that the vast amount of lightning disengaged from aque- ous vapour, could be generated by chemical action, which is far more energetic upon the dry land than in the ocean, from which the vapour is obtained: nor can it be maintained that the process by which Avater is separated from the ocean brine is chemical; for I haAre shown that it is a mechanical force, which is proportional to temperature. (See chap. iii. book i. and the subsequent examination of the tAvo electric fluids.) From the brief history thus presented of atmo- spheric electricity, it must be obvious to the intelli- gent reader, that the knowledge hitherto derived from experimental researches, has been extremely vrague and imperfect, and that its relations to the caloric of evaporation have scarcely been inquired into. On the other hand, it is equally evident, that if we analyze the phenomena of evaporation and condensation, as they are constantly going on before all eyes, we obtain a simple and satisfactory solution of the problem. The fact Avhich Avas announced by Dalton, that caloric is the only cause of evaporation, taken in connection with another fact, that aqueous vapour is condensed into rain or hall, with a reipldlty proportional to tlve amount of 294 OPINIONS OF LUCRETIUS. lightning, are decisive in regard to the convertibility of caloric into electricity. The ideas of the ancient Greek philosophers, which Avere derived from observation without experiments, were more in accordance with nature and reason than the hypotheses of modern times. It was maintained by Lucretius, who gives the doctrines of Epicurus, that lightning consisted of fire alone, and that it was derived from the sun. He represents the igneous par- ticles as rushing to a focus, by which concentration they acquire the power of instantaneously fusing me- tals * (De Naturd Rerum, lib. vi. 108.) That this subtile agent is greatly concentrated on quitting a mass of vapour in the form of lightning, is proved by the fact, that a single spark or flash, causes a precipi- tation of rain over several thousand acres; and that it is a material agent, is demonstrated by its mechan- ical force in rending rocks, buildings, ships, trees, &c. * He further states, that it is by the meeting of warm and cold air that they are elicited. It is not very obvious how this subtile matter becomes concentrated into a ball of fire on quitting a mass of vapour; but such is the fact. It is equally difficult to explain how the electricity of a Leyden battery is condensed on presenting a metallic knob. Perhaps it is owing to all its particles being attracted to the centre of the knob; or that the igneous matter of vapour is attracted to the centre of whatever object excites it. It is worthy of notice, that when a metallic point is presented to the knob of a Leyden bottle charged with electricity, the igneous fluid is drawn off gradually, and no visible spark is produced: but when a larger mass of matter is presented, as a knob of brass, or the knuckle, it is all withdrawn at once. Thus mountains, clouds, buildings, &c. attract a large portion of the electric fluid at the same moment, producing a concentrated spark many hundred thou- sand times larger than one from a Leyden jar. ELECTRIC SPARK OBTAINED FROM STEAM. 295 as effectually as if it were a ball of iron discharged from a cannon. Lord Bacon supposed that the greatest heat in na- ture was that of lightning, from its instantaneous power of fusing metals, and of igniting other combus- tibles. As an additional proof that it is a concentrated exhibition of the igneous principle, it may be observed, that when solar caloric is greatly concentrated by a large burning-glass, it fuses, ignites and volatilizes the hardest gems in a few moments, thus approximating the character of lightning. But since the time of Bacon, philosophers have discovered that electricity can produce all the above effects without being a ma- terial fluid; others, that it proceeds from the earth to the clouds, and not from atmospheric vapour to the earth; Avhile others again resolve all its mechanical and heating properties into undulations of the "un- known ether." If any additional evidence were required to esta- blish the proposition that the caloric of aqueous vapour is convertible into electricity, it is afforded by the re- cent discovery that the electric spark may be obtained from steam as it issues from the boiler of what is called the hydro-electric machine. This discovery was made in 1840, by a man who was intrusted with the care of a steam engine at Seghill, near Newcastle, in England. Having accidentally immersed one of his hands in the steam that issued from a crack in the cement by which the safety-valve was secured to the boiler, while the other was applied to the lever of the valve for the purpose of adjusting the weight, he was surprised by the appearance of a brilliant spark betAveen the lever 296 EXPERIMENTS OF FARADAY. and his hand, accompanied by a violent Avrench in hi* arms. The man further observed that the same effect Avas produced whenever he attempted to touch any part of the boiler or iron-work connected Avith it, pro- vided one hand \vas exposed to the steam; and that he also communicated a shock to every person whom he touched with the other. These facts led Mr. H. G. Armstrong to the con- struction of what he calls the hydro-electric machine. It consists of a cylindrical boiler, (insulated by glass legs,) to which a number of metallic tubes are con- nected, for the purpose of conveying off a large quan- tity of steam, which is made to issue from a single opening. When the steam was let into the tubes, sparks about fifteen inches long were observed to pass between the opening from which it issued and the prime conductor, affording a miniature display of light- ning and thunder. In a paper on the subject, which has been greatly overrated, the celebrated Faraday maintains that the electricity is not developed by evaporation, nor by the condensation of steam, but is wholly the result of friction; that steam is merely the mechanical agent by which the particles of water are made to rub against the sides of the tubes; and that the phenomena are in no way connected Avith atmo- spheric electricity. (Exper. Researches, ser. xviii. pp. 20, 21.) Yet Mr. Faraday relates in this very paper experi- ments which demonstrate in the most decisive manner, that electricity is developed during the condensation of steam, in the same way that lightning is evolved from atmospheric vapour, during its condensation into EXPERIMENTS OF PELTIER. 297 rain, on meeting with a wave of cold air. For he found that whenever the tubes through which the steam issued from the boiler were made hot before the steam Avas let on, no electrical phenomena aa ere pro- duced; but that if while the steam ivas issuing, the pipes were cooled by a jet of water, electricity teas evolved. Like Armstrong, he also found that the electricity thus obtained was ahvays positive, while the sparks obtained from the boiler were negative. Will it be credited, that after all these results, Faraday attributes the electricity of steam to friction, and not to the con- densation of steam? and that his opinion is adopted by all professed electricians in England ? M. Peltier also found by experiment, that the elec- tricity is evolved neither before nor after the steam is projected, but only at the instant of its condensation into aqueous vapour; in other words, that so long as the steam remained in the elastic state, there were no signs of electricity; but that whenever it was con- densed into watery vapour, there was a disengagement of the electric fluid. He further ascertained that the quantity and intensity of the electricity evohed Avere in proportion to the temperature and elasticity of the steam. He adds, that with a small Papin's digester, the amount of electricity obtained was in proportion to the quantity of steam that escaped, its tension remaining the same. M. Peltier also found, that by elevating an electrometer, terminated by a polished copper ball, under the column of vapour given off by the boiler of a locomotive engine, electrical phenomena Avere produced; being more considerable in proportion to the velocity of the engine, and the rapidity with 298 EXPERIMENTS OF PELTIER. which the steam was condensed. (Electrical Magazine, Oct. 1844, pp. 450-7.) The most notable fact con- nected Avith this part of the subject is, that M. Peltier was not led by his own beautiful experiments to the simple and natural conclusion, that the caloric ivhlch converts icater into vapour or steam, is given out In the form of electricity during the process of condensation. CHAPTER II. THEORY OF WINDS. Of all the subdivisions of general philosophy, there is none so little entitled to the name of science as meteorology. — Mason Good. That the reader may comprehend more fully the connection between caloric, evaporation and atmo- spheric electricity, it becomes necessary to present a cursory view of atmospheric currents generally. The unequal distribution of solar caloric over the earth's surface, together with its annual and diurnal reATolutions, determine the periodical movements of the atmosphere which surrounds it. It has been long known, that there are three great currents of the aerial ocean, by which it is kept in a state of perpetual circulation: one from the polar re- gions toAvard the equator, which is an under current; another from the equator to the poles, which is an upper current; and a third, called the great tropical current, or trade-wind, which blows from east to west around the globe for about 30° on each side of the equator; thus sweeping over a breadth of 3000 miles. There is another general wind, Avhich blows from Avest to east in the middle and higher latitudes, about tAAro-thirds of the year in the northern hemisphere; (299) 300 THEORY of winds. Avhile in the middle latitudes of the southern hemi- sphere, where there is little or no land, it is said to be nearly as uniform as the trade-wind. Dr. Hadley, and after him Dr. Franklin, attributed these general cur- rents to the folloAving causes. " The air between the tropics, being constantly heated and rarefied by the vertical sun, rises, Avhen its place is supplied by air from the higher and polar latitudes, which, coming from parts that had less diurnal motion, and not sud- denly acquiring the swifter motion of the equatorial regions, becomes an east wind; the earth moving from west to east, and slipping under the air." (See Frank- lins Works, vol. iii. p. 236.) These general vieAvs have been greatly extended by Dr. Dalton and Mr. Daniell. The first of these philo- sophers observes, that the diurnal motion of the earth at the equator is 1040 miles per hour, and diminishes gradually on to the poles, where it is nothing. (Meteor- ological Essays, page 88.) And Mr. Daniell has de- monstrated in the most conclusive manner, that from the greater density of the polar atmosphere than the equatorial, its height is proportionably less; so that the expanded air between the tropics must rise and flow toward the poles as an upper current. Before rising, it has acquired the tropical motion of the earth from Avest to east, Avhich it retains, until descending in higher latitudes, where the earth's diurnal motion is less, it mixes with the lower air, and gives it a Avest- erly direction. The force and direction of the trade-winds are in- fluenced by the proximity of islands and continents. Along the Avestern side of Africa, their direction is THEORY OF WINDS. 301 reversed. To the distance seaAvard of about 300 miles, they blow toward the heated land: they are reversed in a similar manner in the Pacific, west of South America. When the sun is in the northern tropic, they extend several degrees farther north than during our Avinter; and Avhen the sun is south of the equator, they prevail farther south. There is, near the equator, in the Atlantic and Pa- cific oceans, a belt that separates the trade-winds, where the great polar currents from the north and south meet and neutralize each other, and the regular course of which is arrested by a tendency of the atmo- sphere to floAv toward the heated coasts of Africa and South America. The regions within this tract are characterized by a constant succession of irregular winds and calms, Avith storms of thunder, lightning and rain: they are termed by seamen the swamps or horse latitudes, and are extremely sultry, OAving to the motionless state of the atmosphere, caused by opposite forces that neutralize each other. During Avinter, in the northern hemisphere, the polar latitudes being deprived of the sun's rays, while the tropical parallels are heated, we have a predomi- nance of northerly Avinds, the dense polar air pressing toward the tropics, to restore the equilibrium; Avhile the greater velocity of the middle and tropical than of the northern latitudes, causes a deflection of the polar currents to the soutlnvest and west, making northeast and east Avinds, which almost uniformly succeed to north winds, and continue blowing until an equilibrium is established between the higher and middle latitudes. In the mean time, under the influ- 302 THEORY OF WINDS. ence of the solar beams, the land soon becomes more heated than the ocean, even south of it, Avhich causes a south Avind until the equilibrium is restored betAveen the sea and land atmosphere. During summer, in the United States, southwestern Avinds predominate, and northern winds during Avin- ter. The same thing is true of India, China and Arabia. They are heated during summer, and the atmosphere over them is rarefied, which causes the air to flow in upon them from the tropical seas, Avhen it is deflected to the east, by passing from latitudes that move rapidly, to those which move more sloAvly. This is what seamen term the southwest monsoon. When the sun is south of the equator, the air moves from the northern land, which is cooled down, toward the equator, that has a swifter motion, thus causing the northeast monsoon, which corresponds with the northeast wind of the North American cold season. It was supposed by Volney that the prevailing south- west Avind of the Mississippi valley was a recoil of the tropical trade-Avind, deflected by the Andes of Mexico; but the fact which he states, of its crossing the Al- leghany Mountains, and advancing northeastward, as far as Montreal and Quebec, is sufficient to prove that it must be owing to a cause far more extensive and general in its operation than mountain ranges. During summer in North America, the land is greatly heated, and the air presses from the Atlantic ocean, especially during the day, causing a sea breeze; when from the south, it is changed into a southwest wind, by passing from latitudes that revolve at the rate of eight or nine hundred miles per hour, to those THEORY OF WINDS. 303 which move only six or seven hundred miles per hour.* The southwest and northeast are the prevalent winds in the United States and the west of Europe. In Great Britain they blow about 300 days in the year. It has been observed in the United States of Ame- rica, that regular winds generally follow the sun, ex- hibiting a tolerably uniform succession of circuits from left to right, and blowing from all points of the com- pass within a few days. For example, the ordinary succession of Avinds is, first, from the north; next, from the northeast, then from the east; southeast; south; southwest; west; northwest, and so on, in pretty regular succession, and rarely, if ever, perform- ing an entire circuit in the opposite direction. As the greater portion of the United States is more heated by the sun than the ocean, even south of them, (be- cause the surface is stationary,) and for a longer time, the wind blows from the southAvest a greater number of days than from any other quarter. At the same time, it is worthy of notice, that during extremely cold winters, the wind has continued from a month to six weeks from the northern points of the compass.f * It is the meeting of this wind, charged with aqueous vapour from the ocean, with the colder northerly currents, which causes vast precipitations of rain in the United States, during the latter part of summer and beginning of autumn, attended with the most fearful displays of thunder and lightning, when extensive hurricanes prevail in the West Indies, the Gulf of Mexico and the southern portions of the Union. f According to observations made at sixteen different military posts in the United States, from lat. 35° to the northern extremity of the Republic, including those of Sir Edward Parry, in the polar regions, winds prevail from the southwest, west and north- 304 THEORY OF WINDS. In addition to the above winds, opposite currents frequently meet in the higher atmosphere, which are not observed at the eartlis surface, and thus cause preci- pitations of rain. A striking proof of this Avas wit- nessed on the 4th of July, 1834, at New York. When Robertson, the aeronaut, ascended in a balloon from Castle Garden, the wind Avas from the east, Avhich car- ried him westward across the Hudson river. At an elevation of about 4000 feet above the earth he dis- west, nearly two-thirds of the year; or in the ratio of 15,830 to 8785, while the northerly winds are to the southerly as 1190 to 1231. In the southern portion of the Union below 35°, eastern winds predominate over western in the ratio of 3102 to 1717; from which it would seem that they are subject to the general in- fluence that governs the regular trade-winds of the tropics. In the same section of country, northern winds are to southern in the ratio of 508 to 721. As Cincinnati, lat. 39° 06', affords a tolerable specimen of the Ohio valley generally, it may be stated that western winds prevail over eastern in the ratio of 631 to 325; while at New York, lat. 41°, they are as 580 to 279. They are also nearly in the same proportions throughout the Atlantic Ocean, between North Ame- rica and western Europe. (See Darby''s View of the United States.) Mr. Daniell states, that upon an average of ten years, westerly winds exceed easterly in the ratio of 225 to 140 in Great Britain; while northerly winds are to southerly, as 192 to 173.) Meteor- ological Essays, p. 114.) During spring, the prevalent wind is from the dry, cold, northeastern regions of Russia, Sweden and Denmark. Throughout the Mediterranean, Egypt, Palestine and the south of Europe generally, the wind blows nine months in the year from the northern points of the compass; because situated between the cold regions of Arctic Europe and Asia and the burning plains of Africa, where the temperature is from 100° to 113° F. in the shade, and upwards of 120° in the great deserts. THEORY OF WINDS. 305 appeared in a mist or cloud, when he met with a counter-current from the west, that brought him back over the city, and landed him ten miles to the east- Avard of Long Island. It is quite evident that the canopy of clouds, which overspread the city and coun- try in the afternoon, was condensed by the colder upper current from the west. From the 7th until the 10th of July, (1834,) the heat Avas excessive, ranging from 86° to 96° F. in the shade, while the wind was from the southeast. On the 10th, about noon, the wind prevailed from the Avest, condensing the vapour of the heated air into floods of rain, attended with violent thunder and lightning. It is thus that a land-wind, which usually brings fair weather, causes precipitation, by meeting Avith a southerly wind charged with aqueous vapour. It is highly probable, that at all times when rain at- tends a southerly wind, and when the land temper- ature exceeds that of the sea, precipitation is owing to the prevalence of a colder upper current from an opposite direction. What can be more impressive and sublime than those great movements of the atmosphere, by which the waters of the ocean are Avafted over continents and islands; pestilential vapours dispersed; the face of nature refreshed and adorned with living robes of surpassing beauty? In his usual metaphorical style, Lord Bacon speaks of winds as the wings of com- merce. They are also the great natural ventilators of the earth by which the dry land is furnished with pure air from the ocean, whose waters absorb the car- 20 306 THEORY OF WINDS. bonic acid contained in it. Were it not for this con- stant interchange of air between the tropical and higher latitudes, the earth Avould be scorched by in- supportable heat during summer, and blasted by the rigours of deadly cold in winter. But in the present order of things, such hurtful extremes are prevented by a never-ceasing circulation of the atmosphere from one zone to another.* If the whole earth were of uniform surface and elevation, its temperature would be the same in given latitudes and seasons, and the currents of the atmo- sphere would present a succession of regular move- ments. There would be no sudden mixing of winds * By the agency of warm southerly winds immense masses of aqueous vapour are transported from the ocean over North Ame- rica to the higher latitudes, where, meeting with a body of air from the frozen regions, it is condensed into cold rains or extensive falls of snow, according to the season of the year; while the northern atmosphere is thus warmed by the disengagement of caloric from southern vapour. If southerly winds prevail for a long time from the ocean during autumn, until the atmosphere is saturated with vapour over a large portion of the northern hemisphere, without meeting with a mass of northerly air to condense it, the commencement of winter is marked by an extensive fall of snow, from a foot to eighteen inches, or even three feet in depth,—over which the polar winds pass without being warmed, to the lower latitudes, causing exces- sive winters. This is one reason why during some winters in the United States, the temperature occasionally falls from 30° to 40° lower than during others. After such a fall of snow the wind has prevailed for six weeks together, from the northern points of the compass, as in the winter,of 1779 and 1780, and about the same length of time during the winter of 1834 and 1835, when the mer- cury fell from —20° to —40°, in latitude 35° to 43°. I shall have more to say on this subject in another place. THEORY OF HURRICANES, ETC. 307 from opposite quarters, and no lightning nor rapid precipitations of rain, because there would be a regular gradation of temperature and density of the atmo- sphere from the equator to the poles. But, as the sur- face of the earth is diversified by land and water, mountains and valleys, hills and plains, unequal tem- peratures in the same latitudes and seasons result, causing all those irregular movements in the atmo- sphere termed variable winds; and which can never be predicted with unerring certainty until all these modifying circumstances are classified and reduced to general laws. THEORY OF HURRICANES, HAIL-STORMS, WATER-SPOUTS AND TORNADOS. Having shown in the preceding chapter, that light- ning is always attended with the precipitation of atmo- spheric vapour, I proceed to prove that no violent squall, hurricane, tornado or water-spout, ever occurs, loltJiout the sudden condensation of aqueous vapour, by which a vacuum is formed, causing a rush of air from different quarters. The typhon of the Greek philosophers was a hur- ricane, accompanied with vivid flashes of lightning, which they called fire; while the tornado was de- scribed by the Romans as vortex igne factus, meaning a whirlwind made by fire. It is evident on the slight- est reflection, that violent winds which spring up sud- denly, and often immediately after a calm, cannot possibly be owing directly to the rarefying influence of solar heat, like regular winds, the velocity of which 308 THEORY OF HURRICANES, ETC. rarely exceeds twenty or thirty miles per hour;* whereas the tornado moves at the rate of from one hundred to one hundred and twenty miles per hour. It is during the rainy season, that the tropical regions are visited by those dreadful hurricanes or fiery tem- pests which tear up trees by tlieir roots, destroying everything in their resistless course, and Avhen rain is precipitated in floods with a rapidity proportional to the amount of lightning. Those of the East Indian seas occur during the shifting of the monsoons, and are obviously owing to the condensation of vapour, caused by the meeting of extensive masses of air from opposite quarters, of different temperatures. The equinoctial storms that sweep over the West Indies, the Gulf of Mexico and the southern portions of the United States, are also produced in the same way, and are attended by extraordinary floods of rain, with fearful displays of thunder and lightning. An eye- witness of the tremendous hurricane which desolated the island of Barbadoes on the 10th of August, 1831, informed the author, that it began about ten o'clock at night, with torrents of rain and broad sheets of fire in rapid succession, which threatened to over- *----We often see against some storm A silence in the heavens, the rack stand still, The bold winds speechless, and the orb below As hush as death: anon the dreadful thunder Doth rend the region.—Hamlet. The calm is owing to the meeting of large masses of air from opposite quarters, and thus tending to neutralize their movement, until condensation is produced, when the stillness is succeeded by the roaring tempest. THEORY OF HURRICANES, ETC. 309 Avhelm the inhabitants in a flood, or sweep them away in a tempest of flame. This storm swept over St. Lucia, St. Domingo, Cuba, the whole of the Mexican Gulf, Louisiana and most of the southern States. A similar storm occurred on the 12th of August, 1830, at St. Thomas, and extended along the southern shores of the United States over a tract 500 miles in width. On the other hand, in the tropical portions of the Avide Pacific, where the temperature is uniform, and the winds blow steadily in the same direction, there is but little thunder, lightning and rain, and no hur- ricanes. The same is true of the equatorial parts of the Atlantic, which are far from land. It is stated by Capper, in his account of winds and monsoons, that a hurricane Avas never known to occur at St. Helena, situated as it is, nearly midway between Africa and South America. It is near the continents of Asia, Africa and America, or in the vicinity of large islands, Avhere immense masses of vapour from the sea meet with mountains and cold masses of air from the land, that hurricanes of wind, lightning and rain, are most poAverful and frequent, as in the Bay of Bengal, on the coast of Madagascar, Mauritius, &c. In short, there never was a hurricane, tornado or gale in any part of the world during the existence of perfectly dry Aveather. It is therefore evident that lightning, and all violent winds, are immediately connected Avith the rapid condensation of aqueous vapour or steam, which owes its existence to the expansive agency of solar caloric. Even the winter gales, so fatal to ship- ping on the coasts of Great Britain and France, are 310 THEORY OF HURRICANES, ETC. always attended with copious precipitations of rain or snow, and sometimes with lightning. This may be readily understood when it is remem- bered, that all the water which falls on the earth ex- isted previously in the atmosphere in the form of steam, which, at the temperature of 60°, is lighter than air in the ratio of 622 to 1000. This steam is confined chiefly to the lower regions of the air, and must necessarily augment its volume in proportion to the quantity diffused through it; the consequences of which are, that immense vacuums are produced by its condensation and a violent rush of the surrounding air from elifferent quarters, until an equilibrium is restored. Perhaps there is no part of the world where thunder- storms are so frequent as in the Bay of Mexico and on the borders of the Gulf Stream. It has been said, that of all the vessels in the world, which are annually de- stroyed by lightning, tAvo-thirds have been lost on the track of the Gulf Stream. We may readily comprehend all this when Ave re- flect that the Gulf Stream is a portion of the great equatorial current, (caused by the trade-wind,) which is obstructed by South America and deflected into the Bay of Mexico, where its temperature is from 70° to 80°, according to the season. With its tropical tem- perature it issues from the Bay of Mexico through the Florida Channel, advancing along the southern coast of the United States northeastward to the Banks of Newfoundland, and thence to the western coast of Ire- land, until it is lost. For the distance of 1500 or 2000 miles its temperature is from 10° to 20° higher than that of the ocean on its northern extremity; the con- THEORY OF HURRICANES, ETC. 311 sequence of which is extensive evaporation. The va- pour thus formed is perpetually meeting with bodies of cold air, by which it is condensed, causing a succes- sion of vacuums, local storms, water-spouts, &c* We are informed by seamen, who navigate the Atlantic between the United States and England, that while one vessel encounters a thunder-storm, others enjoy mild breezes within thirty or forty miles of the same place. The same general agency, modified by the relative position of land and water, oceanic currents, moun- tains and valleys, operates to a greater or less extent over all the earth. Off Cape Hatteras, which is washed by the Gulf Stream, there is a constant succession of gales, Avhich are obviously caused by the mingling of Avarm and cold air, as seamen always observe a sensi- ble change of temperature on passing the Cape. The same cause renders the Cape of Good Hope a theatre of perpetual Avar of conflicting tempests, occasioned by the difference of temperature between the great equa- torial current, as it doubles the Cape, and the colder Avater of the Southern Ocean. The streaked and forked appearance of ordinary * As many as sixteen water-spouts were seen at the same time by Captain Lawrence on the borders of the Gulf Stream, in lat. 32° 48', when off Charleston, on a voyage from New Orleans to New York in 1834. They are all formed by the sudden condensa- tion of aqueous vapour, caused by the meeting of opposite currents of air that deflect each other, producing a funnel-shaped cloud, that descends in torrents of fresh, and not salt water, as has been generally supposed. In short, they are what Franklin termed them, whirlwinds at sea. 312 MISCELLANEOUS PHENOMENA. lightning are optical illusions, which result from the rapid passage of the electric spark through the air, which makes an impression on the optic nciwe that remains during its passage, in the same Avay that a burning stick, when involved, presents the appearance of a continuous circle of fire. The fork is OAving to a division of the original spark or ball into two or more sparks, which diverge from each other. The zigzag appearance is owing to frequent slight deflections of the spark, as it moves through strata of air of dif- ferent densities. Whenever an electric explosion takes place near to the spectator, it always presents the ap- pearance of a ball of fire, attended by a simultaneous report, like that of artillery. The reason that the re- port is usually heard many seconds after the flash is seen, is owing to its distance from the point of obser- vation and to the sloAvness with which vibrations are propagated through the atmosphere; Avhile its rum- bling or prolonged existence is owing to the space over which it passes.* The report itself is probably caused by a sudden collapse of the air as it fills the vacuum produced by the passage of the electric bolt through it; and by its violent collision against the air, causing a tremour of the atmosphere to the distance of many miles, which is communicated to buildings * For example, sound travels through the air at the rate of 1130 feet per second; so that 60 seconds, or one minute, must elapse be- fore it can be heard at the distance of 12*84 miles, becoming fainter as the more distant vibrations reach the ear. And we may easily ascertain the distance of the flash by looking at the second-hand of a watch, until the report is heard. SUMMER GUSTS. 313 and other solid bodies.* It is likewise probable that the luminosity of the spark is owing to a sudden com- bustion of air or vapour by so intense a heat. It was first observed by Dr. Franklin, that the cold summer gusts of the middle latitudes generally come from the west; from which he concluded that they were caused by a descent of cold air from the upper current of the atmosphere, on its passage from the equatorial to the polar latitudes. That this is the true mode of accounting for many of our thunder-storms, would appear reasonable from the folloAving considerations. They occur during the most sultry weather and hottest time of the day, gene- rally the afternoon, when the lower atmosphere is greatly rarefied, so as to favour a descent of cold air from above, which rapidly condenses the transparent vapour of the krwer atmosphere into floods of rain, that are often attended with hail, and always with a great reduction of temperature. In this way clouds are often formed suddenly, the whole sky becoming obscured by dense black clouds, accompanied with thunder and lightning, violent winds and copious pre- cipitations of rain. During such storms, more vapour is condensed into rain in twenty or thirt}r minutes, than usually falls during a whole day, or even a week * This was proved by Beccaria, who constructed a glass siphon, in one leg of which air was inclosed above a column of mercury, and compressed by the column in the other leg of the siphon. On discharging a Leyden jar through the air thus inclosed, the column of mercury in the other leg was suddenly elevated, and recovered its position after several oscillations. (Electric. Artific, Turin, 1753, p. 227.) 314 HAIL-STORMS. when there is no lightning. All the phenomena par- take of the violence which characterizes discharges of the electric fluid when greatly accumulated. Lord Bacon observes, in his Natural History of Winds, that "tornados are caused by the sudden breaking of clouds," by which he meant those rapid precipitations of rain that accompany lightning and thunder. And we often hear from seamen that a vio- lent hurricane issued out of a dense cloud. Bacon ob- serves again, that "when it lightens in a clear sky, Avinds and rain are at hand from the quarter where it lightens: but if it lightens in different quarters, there will follow cruel and horrid tempests." He might have added, that they have already begun in the places Avhere the lightning is seen. HAIL-STORMS. On the subject of hail-storms, Avhich are intimately related to whirlwinds, water-spouts, &c. much learning and ingenuity have been expended since the days of Franklin, without any satisfactory explanation of their cause. The celebrated Volta supposed that they were pro- duced by " an highly electrical condition of the atmo- sphere ; that the frozen masses were kept in a state of reciprocating motion between two clouds, oppositely charged with electricity, until the mass rendered the force of gravity predominant; or until the electric ten- sion of the cloud was exhausted by mutual reaction. In his report on the present state of meteorology, Pro- HAIL-STORMS. 315 fessor Forbes observes, that no better solution has yet been offered to the world. (Transactions of the British Association, vol. i. 1832.) The leading facts connected with hail-storms are the folloAving:— 1. They are generally confined to the middle lati- tudes, Avhere masses of cold air from the polar regions meet with warmer air from the tropical latitudes, loaded with aqueous vapour. When such currents encounter each other at the usual height of spring and summer clouds, the vapour of the warm air is con- densed into cold rains, or showers of small hail, but Avithout much lightning or violent Avind; whereas all the most destructive hail-storms are accompanied with tremendous flashes of lightning, and often with fearful A\birlwinds, or tornados. 2. They occur chiefly during warm Aveather in the United States, when the lower atmosphere is full of vapour, and heated to the temperature of 80°, and sometimes 90° F. 3. They usually run in veins of limited extent, and are most frequent in level districts, especially such as are hemmed in by mountains, as in the south of France, Avhere they are very destructive to the crops. 4. They are often attended with the sudden pre- cipitation of immense quantities of ice, which descend in large globular masses, and always Avith a great re- duction of temperature. Several of the above facts are exceedingly difficult to explain, without admitting the hypothesis of Frank- lin in regard to the cause of thunder-gusts; that is, a sudden descent of cold air from the upper regions, by 316 HAIL-STORMS. which the vapour of the loAver atmosphere is rapidly condensed and congealed into globules of ice. In opposition to this view of the subject, it is main- tained by Dr. Thomson, that the upper air cannot de- scend Avithout undergoing condensation and giving out a portion of its latent caloric, which he thinks would prevent it from cooling the atmosphere. (Treatise on Heat and Electricity, p. 129.) Whatever may be the just weight of this objection, the fact is certain, that aqueous vapour is suddenly and rapidly congealed by very cold air; by which the temperature of the lower atmosphere is often reduced from 80° or 90° down to 32°, or even less, within a few minutes, during exten- sive and violent hail-storms. It is also certain, that a vacuum must be formed in the lower atmosphere proportional to the volume of vapour thus suddenly condensed; the extent of Avhich may be estimated from the vast quantities of hail that are occasionally precipitated in a few minutes, amount- ing to a depth of nine inches in as many minutes, according to M. Pouillet. The formation of such a Aracuum is always attended by a rush of air from oppo- site quarters, creating a gyratory or whirling motion, the force of which is in proportion to the extent of the vacuum and the rapidity of its formation. That the reader may perceive the more readily how intimate is the connection between lightning, the condensation of vapour, hail-storms and whirl- winds, it may be proper to present a brief account of a few thunder-storms which have occurred in Great Britain: On the 10th of August, 1835, Durham Avas visited LIGHTNING, RAIN AND HAIL. 317 by a violent whirlwind, accompanied with incessant lightning and thunder. At seven o'clock p.m., a most vivid flash of lightning struck the cathedral, and hurled down an immense mass of stone that killed tAvo of a party of students, who at the moment fled from the interior of the cathedral. "On the same day Chesterfield was visited by a vio- lent storm of thunder, lightning, rain and hail. A large ball of fire fell in the Commercial Inn yard, where there Avas an accumulation of water, splashing it in all directions into spray, which for a moment seemed to be enveloped in flames. "Many such storms occurred about the same time in different parts of England, Scotland and Ireland. On the 10th of June, about three o'clock, there was a storm of lightning, thunder and hail, at Dumfries,— and at Ardach on the following day, there was a vio- lent thunder-storm, Avhere the drifted hail was two feet in depth in some places, and remained on the ground for tAventy-four hours. "At Sheffield, during a thunder-storm, the electric fluid entered the works of Mr. Ellin, and struck a pile of ivory-handled knives, the blades of which were fused into one mass, and the hafts split off in a singu- lar manner. Twelve individuals were thrown down; they supposed that the boiler of a steam engine in the room had bursted.* * It is related in some of the older books on natural philoso- phy, that Erfurt, a small city of Germany, was struck by light- ning during a storm, in forty-two different places. Seven persons were killed, and three houses set on fire, which were quenched by the rain, that fell in torrents. 318 TORNADOS OF THE UNITED STATES. "On the 6th of June, forty-two head of cattle Avere killed by lightning in one field, at JohnstoAvn, near Tuller. Some had their heads and horns burnt, and some their shoulders. On the lands of Mr. Lynham, at the Hill of Talloght, eighteen cattle, twenty-three sheep and a goat, were also killed by lightning." (Bells Weekly Messenger, June 14,1835.) TORNADOS OF THE UNITED STATES. It was observed by Lord Bacon, that "all tornados or great whirlwinds have a manifest precipitous mo- tion, or darting downward more than other Avinds, so that they seem to fall like torrents, and run as it Avere in channels." Such tornados are remarkably frequent in the United States during hot sultry weather, and are attended with the most striking displays of electrical phenomena: always with rapid condensations of va- pour, and often with enormous quantities of hail. They generally run in narrow veins from 100 yards to half a mile wide; while the equinoctial hurricanes of the Southern States, like those of the tropics, sweep over a vast extent of surface, and are rarely if ever accom- panied with hail. The tornado is sometimes attended by a rapid succession of lightning; at other times it presents the appearance of an inverted fiery pyramid, On the 15th of August, 1836, twenty-eight houses were set on fire by lightning in the town of Grundelbruch; while at Villexon, nineteen dwellings were consumed about the same time, during a thunder-storm, attended with hail and a tornado. (Galignani's Messenger.) ■ TORNADOS OF THE UNITED STATES. 319 from which is heard a continuous roll or deep roar of thunder, like that of a heavy unremitted cannonade, the sound of Avhich is greatly modified and obscured by the noise of the raging Avind, crashing of buildings, falling timber, &c. The whirlwind which destroyed a large portion of NeAv Brunswick, in the State of New Jersey, on the 19th of June, 1835, presented many of the above phe- nomena. Those who Avitnessed its commencement, observed the formation of several inverted cones of dense black Arapour, Avhich descended from the upper regions. Dr. Lewis Beck describes one of these "as resembling in appearance the eruption of a volcano, Avhich produced the impression, at a distance, that some large building had been set on fire by lightning, a vivid flash or two of which had preceded the forma- tion of the cones. But in a few minutes the dense column Avas dissipated, Avhen another black and well- defined cone was formed, which remained stationary for a short time, and then gave place to the eruptory appearance and gyratory movement that characterized the other. The first occurred about three miles west of New BrunsAvick. But when the second movement commenced, a dense black cloud overshadowed the city. Slight, but distinct explosions were heard from the column in rapid succession, like the bluffing of sails. Volumes of smoke and flame were thought to be issuing forth, and rolling over in various directions, Avhen the idea of an extensive and rapid conflagration Avas suggested. The alarm bells were rung, and the firemen repaired to their engines. But while all eyes Avere directed to the black and dreadful column that 320 TORNADOS OF THE UNITED STATES. Avas approaching, no one could fix upon the exact spot to which efforts should be directed. This uncertainty Avas soon removed by the desolating progress of the whirlwind through the city, prostrating houses, and Avafting heavy beams of timber to a great distance." Like most tornados, it was attended with hail, as well as rain. The width of its tract varied from 100 feet to 200 yards, in the neighbourhood of New Bruns- Avick; while three miles eastward it was half a mile wide. A writer in the New York Times states, that on the banks of the Baritan, for 1000 yards, vegeta- tion was scathed, as if a flame had passed quickly over it. Similar storms desolated different portions of the Union about the same time. "Late in June, Lynch- burg, in Virginia, was visited by a tremendous whirl- Avind and tempest of hail, which was preceded for several minutes by a monotonous rumbling sound, re- sembling the bass tones of distant thunder or the deep roll of the muffled drum; and reminding us of the ominous notes which precede an earthquake." (Lynch- burg Virginian.) Dense black clouds are described as pouring forth immense masses of ice, and so dark- ening the air, that houses within a few paces were totally invisible. During the summer of 1834, which was unusually sultry, tornados and hail-storms of limited extent, visited almost every State in the Union, from Maine to Louisiana; several of them attended with great loss of lives and property. In most cases, they pur- sued a course from west to east. About the 20th of March, 1832, a tornado occurred A TORNADO WITH SNOW. 321 in the southern portion of Tennessee, lat. 35° N. which differed in some respects from any of the pre- ceding. After several remarkably warm days for the season, accompanied with a southerly wind, a tornado came on suddenly, without the slightest warning, about seven o'clock p.m. It excited great astonishment, as the whole day had been Avarm, serene and clear, with the exception of a slight haziness, up to the moment when the crashing noise of falling timber announced the approaching storm from the northwest. The tem- perature Avas immediately reduced several degrees below 32° F. and attended with a rapid fall of snow, which continued for several hours; but the tornado blew with violence for only about ten minutes. The next morning, the wind was cold and north westerly, and continued northerly for tAvo days. This storm seems to have been owing to the preva- lence of a cold upper current from the north, which met and mingled with the warm southerly air, and suddenly congealed its vapour into snow. It had not the local character of the summer tornado; for it was followed by great cold over a large extent of country. I shall close this imperfect history of thunder-storms with the account of an extraordinary and sudden cold- ness Avhich occurred in the island of Cuba, on the 24th of May, 1809. Cornelius Roberts, a sugar and coffee planter, who resided forty years on the island, informed the author, "that after a hurricane had been bloAving from the southeast and south, from the 22d until eleven o'clock a.m. of the 24th, a calm followed for an hour, 21 322 GREAT COLDNESS IN CUBA. when the wind prevailed from the northwest. At the same time, the atmosphere became extremely dark, like night, accompanied with a roaring in the air, tre- mour of the earth and intense cold. Everything green Avas killed and became black, as if a fire had passed over the country for several miles in breadth, and about sixty miles in length:" Avhich proves that a mass of air may descend from above and refrigerate the loAver atmosphere of the tropical regions, as in the middle latitudes, though such a phenomenon is ex- tremely rare. CHAPTER III. INFLUENCE OF TERRESTRIAL TEMPERATURE ON THE BAROMETER. It has been long known that the fluctuations of the barometer are intimately connected with all the phe- nomena of meteorology; that during winter, in the middle and higher latitudes, its depressions are fol- lowed by rain, snow and tempestuous Aveather; Avhile its rising is accompanied Avith cold, frosty and dry Aveather; and that during summer its falling forebodes storms of thunder, lightning and rain, Avhich are often attended with violent hurricanes; Avhile its rising in- dicates clear and serene weather. Yet the theory of its variations has never been clearly reduced to the simplicity of established principles. Without stopping to examine the relative merits of those who have de- voted their attention to this difficult and important problem, it may be observed without injustice to any, that Ave are chiefly indebted to the labours of Dr. Dal- ton for the true mode of investigating it. The most important facts connected with the ba- rometer may be reduced to the following proposi- tions :— 1. The mean height of the mercurial column at the level of the sea, is nearly the same over all the earth, the average amounting to about thirty inches. (323) 324 INFLUENCE OF TERRESTRIAL TEMPERATURE 2. The density or specific gravity of the atmosphere Increases gradually from the eepiator to the regions of lowest mean temperature, corresponding with the decrease of temperature; the consequence of winch is, that the height of the atmosphere must diminish from the equator to the poles. 3. Within the tropics, the temperature is always nearly the same: the range of the barometer is also small, vary- ing from two lines to a quarter of an inch. 4. The range of temperature augments from the equa- tor to the regions of maximum cold: the variation of the barometer augments in a corresponding ratio,—amount- ing to about three inches in the coldest latitudes. The range of temperature is much greater in North America than in the same latitudes of Europe, as will appear from the following facts. During the winter of 1831 and 1832, the thermometer fell to —20° at Florence, in the State of Alabama, lat. 35° N., and —40° at Plattsburg, lat. 44°, where it sometimes rises to 95°, and even 100° during summer, making its ex- treme annual range from 130° to 140° F* The diur- * It is, however, but seldom that the temperature falls below Q° in the States south of Philadelphia and New York; so that the usual annual range does not much exceed that of England, which is about 80°, according to Mr. Daniell; that is, from 11° to 90°. Hence it is, that the mean range of the barometer is about the same in Great Britain that it is in the middle States of America, as observed by Dr. Dalton forty years ago. Perhaps there is no part of the world where the fluctuations of temperature are more fre- quent than in England; the reason of which is obvious from its insular and geographical position, being situated about midway between the burning plains of Africa to the south, and the frozen regions of the north; while on the east and northeast it is in- ON THE BAROMETER. 325 nal variation is also very great, as the thermometer often rises to 90° in September and October, during the hottest part of the day, and falls below 32° at night, making the daily range of temperature 60° F. Still more extraordinary are the changes from heat to cold in those extensive regions of North America beyond the limits of the United States, which have been explored by Scoresby, Parry, Franklin, Ross and other British navigators. We are informed by Captain Back, that on the 17th of January, 1834, the ther- mometer was —70° F. at six a.ai. on the Great Slave Lake, lat. 62° 46'; but rose to 45° in the afternoon of the same day,—making a diurnal range of 115°. He also states, that on the preceding day the temperature rose to 52°; while the long summer days were often oppressively warm. Hence it is, that as we approach the polar regions, Ave find the winds irregular and variable, coinciding with the frequent changes in the density of the atmosphere and consequent fluctuations of the barometer. 5. Corresponding with the foregoing facts, the baro- meter rises to the greatest height during cold northerly winds in the middle latitudes, and falls during warm southerly winds. That is, a mass* of air from the torrid zone is specifically lighter than one from the polar re- gions, and must cause a proportional fall of the mer- curial column, until the equilibrium is restored. For example, the maximum height of the barometer at Philadelphia was on the morning of May 5, 1847, fluenced by Sweden, Poland, Russia and the cold elevated plains of Tartary; and by the Atlantic Ocean on the west; all of which contribute their share successively in forming the climate of Britain. 326 INFLUENCE OF TERRESTRIAL TEMPERATURE when the wind was from the northeast; but the minimum Avas on the 29th, at noon, Avhen the Avind was from the southAvest, and the temperature 94° F. On the next morning the wind was from the north, and the temperature 52° at nine o'clock in the even- ing, having fallen 42° in 31 hours. But in addition to the immediate agency of tem- perature in modifying the specific graAity of the atmo- sphere, the amount of aqueous vapour diffused through it exerts a material influence. It has been already shoAvn that the quantity of vapour in the atmosphere, cceteris paribus, is proportional to temperature; the greater part of this is confined to its lower strata, (within tAvo or three miles of the earth's surface;) and at the temperature of 80° F. the atmosphere is capable of containing an amount of vapour equal to the pres- sure of an inch of mercury, or one-thirtieth of its whole weight. If, then, we take the estimate of Gay-Lussac, that the specific gravity of aqueous vapour is less than that of air at the same temperature, in the ratio of six to ten, it is evident that the specific gravity of the atmo- sphere must be diminished in proportion to the quantity of vapour diffused through it. Hence it is, that Avarm southerly winds, which have been expanded by heat and charged with vapour, cause the barometer to fall. It also follows, that as rains are supplied chiefly by warm southerly winds, in the middle and higher lati- tudes of the northern hemisphere, the sinking of the barometer must be an indication of falling weather. And as it has been shown that all violent winds, such as hurricanes, tornados, &c. are owing to the rapid con- densation of aqueous vapour, the falling of the bare- ON THE BAROMETER. 327 meter must also forebode tempestuous Aveather. It is equally evident, that currents of cold air raise the barometer, not only because of their greater specific gravity, but because they condense the steam of Avarm air. Hence it is, that for two or three clays before storms of thunder and lightning, wind and rain, during the prevalence of warm southerly winds, the barometer falls; but rises during cool and serene dry weather.* * From several passages in Mr. Daniell's work on the atmo- sphere, it would seem that he referred the sinking of the barometer to the evolution of caloric from aqueous vapour during its conden- sation, by which the atmosphere is expanded where it takes place. But it has been shown that within the tropics, where the amount of condensation is greatest, the fluctuation of the barometer is very small; while it is obvious from the foregoing facts and observa- tions, that the barometer is depressed by the accumulation of aque- ous vapour in the atmosphere, and elevated by its condensation. Dr. Dalton ascertained by a series of observations continued for five years at Kendal, in the north of England, that the barometer fell below twenty-nine inches during forty days, only two of which were fair; but that when it stood above its mean monthly height, there was but little rain, and generally fair weather. He also found that the heaviest rains fell when the barometer was about 29*47, and not when at a minimum, as might have been expected, a priori. His explanation of this fact is simple and ingenius. He observes, that "when the barometer is above the mean high extreme for the season of the year, the air must, rela- tively speaking, be extremely dry or cold, or both. If extremely dry, it is in a state for absorbing vapour; and if extremely cold, no further degree of cold can be expected, and therefore in neither case can there be any considerable precipitation. On the contrary, when the barometer is very low for the season, the air must rela- tively be extremely warm, or extremely moist, or both; if extremely warm, it is in a similar state to dry air for imbibing vapour; and if extremely moist, there must be a degree of cold introduced to 328 INFLUENCE OF TERRESTRIAL TEMPERATURE 6. The range of the barometer is greater during winter than summer in the middle latitudes. The reason of which is, that the advancement of the sun toAvard the pole brings the temperature of the higher latitudes to nearly an equality over forty or fifty parallels, and almost to the. same state as within the tropics, as observed by Dr. Dalton: whereas during winter, the warm and rarefied air of the tropical re- gions is often encountered by widely extended cur- rents of cold dense air from the polar latitudes; the consequence of which is, that the barometer will rise or fall at the same time, over a great extent of coun- try, according as the warm and vapoury or cold and dry currents of air predominate, and will be greatest when the extremes of temperature in the opposing currents are at a maximum. 7. The regular elevations and depressions of the baro- meter, termed Its horary oscillations, follow the daily fluc- tuations of temperature. According to the observations of Mr. Daniell, the daily average height of the barometer at London is *010 inch higher at night than the afternoon,—and •005 inch higher in the morning than at night; it is therefore *015 inch higher in the morning than the afternoon. (Essay on the Climate of London.) The daily variation is still greater in the interior of North Ame- rica, lat. 41° 25' at the Rocky Mountains, where Colo- nel Long found the mean height of the barometer, in precipitate the vapour, which cold, at the same time, raises the barometer. From which it follows, that no very heavy and con- tinued rains can be expected to happen whilst the barometer re- mains about the lowest extreme." (Meteorological Essays, p. 143.) ON THE BAROMETER. 329 March, 28*713 inches in the morning, 28*609 at noon and 28*630 at night. From the observations of Captain Sabine and others, it would seem that the diurnal variation of the baro- meter is greatest at the equator, where the power of the sun's heat is a maximum, and diminishes on ap- proaching the polar circles, as shown in the following table, given by Mr. Daniell:— At St. Thomas, lat. 0-24/ the diurnal variation was -074 inch. Trinidad, " 10-39' " " " *063 " Jamaica, " 17-56' '• " " *058 « Paris, " 48-50' " " " *028 " Finally, all the variations of the barometer are greater at the level of the sea than in high situations, corresponding with the greater fluctuations of tem- perature of the lower atmosphere. DEW AND FROST. After the setting of the sun, the surface of the earth is cooled down by radiation from 12° to 15° F. below the temperature of the superincumbent atmosphere; it then abstracts caloric from the stratum of trans- parent aqueous vapour immediately over it, by which it coalesces into dew, or crystallizes into frost, accord- ing to the temperature of the surface. If the atmosphere be full of vapour, there is a large deposition of dew during summer, on perfectly clear nights; but during spring and autumn, instead of heavy dews, we have large white frosts, which are gene- rally followed in two or three days by rain; of which 330 THEORY OF DEW. they are regarded by the people as a sure indication. But when the cold is more intense, and the atmo- sphere contains less vapour, we have what is called a black frost, which is attended with a congealed state of the ground. As a general rule, the quantity of dew is in proportion to the amount of invisible vapour in the air, and to the difference between the temperature of day and night. It is profuse in hot climates, and more abundant on continents than islands, cceteris pari- bus; while on the ocean, far from land, there is little or no dew, because the difference between the tem- perature of day and night at sea is only two or three degrees. In the United States of America, the differ- ence is sometimes 60° F., the consequence of which is a copious deposition of clew, resembling the effects of a shower of rain. It is also copious in England during the prevalence of Avarm winds from the ocean. All other things being equal, a greater amount of dew is condensed between midnight and sunrise than between sunset and midnight, according to the obser- vations and experiments of Dr. Wells—obviously be- cause the surface of the earth is then colder, from the loss of caloric by radiation. Dew, then, is not con- densed and precipitated like rain by the coldness of the atmosphere, but by the coldness of the earth's sur- face, which is proved by the well-known fact that deAV and frost are formed on the under surface of planks, &c. as well as the upper. It has been long known that little or no deAV is formed under a cloudy canopy, but that it is abund- ant during clear nights. Dr. Wells referred this cir- cumstance to the obstruction of caloric radiated from THEORY OF DEW. 331 the earth's surface by clouds. It is extremely pro- bable, however, from his own statement of facts, that he mistook a mere concomitant for the real cause of the phenomenon. He informs us, that when clouds begin to form during the night, the surface of the earth rises several degrees, and that deAV formed during clear intervals often evaporated again Avhen the sky becomes thickly overcast; from which it would appear, that the caloric evolved from aqueous vapour during its condensation into clouds, warms the atmo- sphere and prevents the surface of the earth from being cooled to the deAAr-point. Admitting that a por- tion of the caloric radiated from the surface of the earth, is reflected back, instead of being absorbed by clouds, it is insufficient to produce so decided a change of temperature. During clear and serene nights, when no caloric is given out to the atmosphere by the con- densation of vapour, the earth is cooled down by radia- tion, because it receives nothing to compensate for the loss of what is given off; so that the transparent aque- ous vapour of the lower strata of the atmosphere is condensed into deAV. There is no dew on windy nights, for the same reason that evaporation is accelerated by wind; or that a renewal of water and agitation pro- mote the solution of salts. It was before stated, that caloric is radiated more copiously from rough surfaces than from such as are smooth. In accordance with that general fact, Ave find that dew is formed more copiously on swansdown, wool, cotton, raw silk, flax, fine shavings of wood, &c. than upon compact pieces of the same materials. It, forms more copiously on rough metals than on polished 332 MISTS AND FOGS. ones; doubtless because the former present a more ex- tended radiating surface. (See Theory of Radiation. book ii. chap, i.) MISTS AND FOGS. The formation of all fogs is owing to a partial con- densation of aqueous vapour, caused by the abstrac- tion of caloric from colder bodies — often by the mixture of air of different temperatures near the earth's surface. For example, during autumn, the temperature of the Mississippi, Ohio and other great rivers, is nearly the same during night and day; while that of the land is greatly reduced at night by radiation, especially toward morning, when it is at the extreme of reduction. Under such circumstances, the intermixture of the land atmosphere at the tem- perature of 35° or 40° F., with that of the water, which is from 50° to 60°, produces a fog or mist. The same effect is produced on the eastern coast of the United States during autumn. The land is cooled down by radiation at night, while the temperature of the ocean and the air over it remains nearly the same. During this state of things, whether the wind blows from the sea or land, a mixture of warm and cold air produces fogs. Over the Banks of Newfoundland, where the warm air from the Gulf Stream is intermixed with that of the cold water and icebergs of the north, they prevail throughout the year. Nova Scotia is, proverbially, the region of fogs. The dark and thick fogs of Eng- land occur during the latter part of autumn and Avin- INDIAN SUMMER. 333 ter,—owing to the more rapid cooling of the land by radiation, than of the surrounding ocean. The frost rime of the polar seas is produced in the same manner as fogs, but by the agency of a loAver temperature. During summer, mountains are generally covered with fog in the morning, when the weather is serene and clear. Being cooled down at night by radiation below the dew-point, they abstract caloric from the transparent aqueous vapour that is always mixed with the atmosphere in greater or less quantity, by which it is condensed into huge volumes of mist or fog, which envelope the mountains with giant folds of majestic drapery, and which are not redissolved by the solar rays before nine or ten o'clock in the morning. INDIAN SUMMER. In all parts of the United States, there is an au- tumnal period of most delightful Aveather, which usually commences late in October, and continues with occasional intermissions through the greater part of November, during some seasons, in the Mississippi valley, until Christmas. It is generally attended with a southerly wind, which, being warm, is filled with transparent aqueous vapour. But as the earth be- comes gradually cooler on the approach of winter, by radiating more caloric than it receives from the sun, the air over it is also cooled down; the transparent vapour is slightly condensed into a fine hazy mist, which reflects and refracts the solar rays in such a manner as to produce the most rich and softened lus- 334 INDIAN SUMMER. tre of the bluish-purple and golden air, which con- tinues until there is a change of Avind—sometimes, for three weeks in succession. As the Indian summer is generally a dry season, and as the mountains and prairies are frequently on fire during such weather, the hazy appearance of the atmosphere has been at- tributed by many persons to the vapour of burning substances diffused through the air. But this cause is altogether too limited in its operation to account for the prevalence of Indian summer throughout the greater part of the American continent; and often many hundred miles from burning prairies. The con- flagrations that occur during this season are local and transitory; Avhile the gradual cooling down of the earth, during the prevalence of warm southerly breezes, is all-sufficient to account for the pheno- menon. The same cause produces in England dense and gloomy fogs, during the same beautiful season in America. This is readily understood, Avhen Ave reflect that England is surrounded by the ocean; that its atmosphere is much nearer to the point of saturation by aqueous vapour, than that of a large continent; and, therefore, that the same or even a less reduction of temperature must occasion denser fogs and darker days in Great Britain and other in- sular countries of the higher latitudes, than in con- tinental regions. The Indian summer of the United States is closed by the commencement an4 predominance of northerly winds, which condense the aqueous vapour that has been borne from the ocean by southerly breezes, caus- ing dark, cloudy Aveather, and general rains or snows, AURORA BOREALIS. 335 according to the latitude and elevation; after which the reign of winter is established, and the air becomes dry, clear and cold, except in the neighbourhood of the lakes or of the ocean, where it partakes of an in- sular character. AURORA BOREALIS. Before concluding this general and imperfect sur- vey of the agency of caloric in meteorological phe- nomena, it may not be improper to notice the leading facts connected with the aurora borealis and australis, or the northern lights, as they are commonly called on this side of the equator. It has been already shoAvn, that the atmosphere and all gaseous bodies owe their volume and elastic force to the agency of an igneous ether Avhich sur- rounds their atoms—and that after being greatly ac- cumulated in aqueous vapour, it is given out in the form of lightning on the meeting of warm and cold currents of air. We have also seen, that the great aerial ocean is in a state of perpetual circulation from the poles to the equator by under currents, and from the equator to the poles by upper currents; and that the density of the atmosphere increases as we advance from the tropics, to the points of lowest mean temperature: from which it follows, that caloric must be evolved by the tropical atmosphere as it passes from a rarer to a denser state. It is equally certain, that the tropical air must carry with it a considerable proportion of aqueous vapor, that must be condensed into fogs or clouds, rain or snow; which accounts for 336 AURORA BOREALIS. a very common attendant of the aurora, viz., a low, black cloud, apparently beyond it, and near to the horizon. M. Hansteen, who has travelled much in the north of Europe and Asia, observes, " that Avhile the aurora? are streaming, the sky becomes opaque or misty." He further states, that "it is a matter of common obser- vation in the arctic regions, confirmed by long expe- rience, that the aurora is usually followed by intense cold, especially after a mild day;" doubtless, for the same reason, that warm and sultry weather in the middle latitudes is rendered cool by a thunder-storm; viz., by the mixture of cold with warm air. M. Hansteen has given a singular explanation of the aurora, which shows how vague and indefinite the views of philosophers still are in regard to the origin and nature of this beautiful meteor. He ob- serves, that "it is probably the result of a struggle of powers put in activity by the variously constituted substances composing the mass of the earth, which we may one day, perhaps, learn to know." He thinks, that " it produces the arctic fogs, by decomposing the aqueous vapour of the polar atmosphere." (Edln. Phil. Journal, vol. xii.) It has been asked, why the aurorae are not con- tinually formed, as the atmosphere is constantly Aoav- ing from the tropical to the higher latitudes. We might as well be asked, why there is not perpetual thunder and lightning while the atmosphere is moving from the sea over the land, charged with aqueous va- pour. The condensations which occur in both cases are local and temporary, and depend on the relative AURORA BOREALIS. 337 temperatures of different aerial masses. When the upper current of rarefied air from the tropics, charged with vapour, comes in contact Avith the cold air of the polar regions, it gives out a large portion of caloric or electric matter, Avhich, not being compressed, as in the lower atmosphere, expands like the electric spark in an exhausted glass tube, into broad bands or zones and columns; filling the sky with halos and crowns of lambent light or undulating coruscations. It is highly probable, that the aurora is given off, during the condensation of the upper equatorial currents with the vapours which they contain, in a mode simi- lar to the evolution of silent lightning on a summer's evening, Avhich is generally very far off, and is seen through numerous strata of atmospheric air, produc- ing a diffused or lambent phosphorescence, Avhich re- sembles the aurora much more than it does lightning Avhich is near at hand. Sometimes the Avhole northern hemisphere presents that kind of luminosity Avhich announces the daAvn of morning in the east. At other times the aurorae seem stationary during changes of temperature from heat to cold. They often present the appearance of a bank of light, (resembling the effect of a distant conflagration,) resting on or flanked by a low, dark cloud, which is occasionally illuminated by broad flashes. Captain Bonnycastle, of Toronto, in Upper Canada, observes, that during the formation of all re- markable aurorae, dark volumes of vapour suddenly appeared, Avithin the space comprehended by the arch. (Sllllmans Journal, vol. xxx. p. 132.) Sometimes, though rarely, the aurora presents the appearance of 22 oon OOO AURORA BOREALIS. a Avide arch extending across the firmament, which breaks up into columns or streamers that extend to- ward the zenith. Various conjectures have been offered in regard to the height at which the aurorae are formed,—nearly all of which have been founded on imaginary data. Some philosophers have supposed that they must be formed at a great elevation, because they have been seen at the same time in very distant countries, as England and America. But it would be quite as rea- sonable to conclude, that ordinary lightning is given off at a great elevation, because it lightened at the same time in England and America. There is no ra- tional ground for supposing that the aurorae are formed above our atmosphere, and probably never beyond a few miles; while there is every reason to believe that they may be formed in hundreds of places over different parts of the earth at the same time. It was the opinion of Franklin, Parry, Ross, Hood and Dr. Richardson, that the aurorae of the arctic re- gions were frequently not higher than ordinary clouds; and Dr. Richardson thinks that they are always at- tended with the formation of clouds, or of that kind of haziness which causes a halo around the moon—a very important fact, which would seem to establish their connection with the condensation of aqueous vapour, as suggested by Dr. Franklin. They are most probably in the upper regions of the atmosphere,* what thunder-storms are near to the * Most of the appearances presented by the aurorae have been imitated by artificial means. Dr. Priestley inserted with cement, AURORA BOREALIS. 339 surface of the earth. The aurorae are seldom, if ever, seen betAveen the tropics, because the upper atmo- sphere is not condensed there, being of uniform tem- perature. Even near the earth's surface, there is comparatively little lightning where the temperature is uniform, as over the tropical ocean, and where the wind bloAvs uniformly in the same direction. It is highly probable, that the electric fluid is nearly all given out, before the upper current reaches the centre of maximum cold; Avhich explains why the aurora is less brilliant at Melville Island, than at Bear into the top of a tall receiver, a wire not very acutely pointed. He then exhausted the receiver, and presented the knob of the wire to the conductor, when every spark passed through the vacuum in a broad stream of light, which often divided into a variety of beau- tiful rivulets, continually changing in their course, uniting and dividing again in the most pleasing manner: thus representing in miniature what has been called the streamers of the aurora. When the wire is electrified negatively, instead of streams of fire, there is an uniform luminous appearance like a white cloud, or like the milky way in a star-light night, which remains for a considerable time, representing the apparently stationary and diffused light of the aurora. (Priestley's History of Electricity, p. 524.) We can assign no limits to the various phenomena which the electric fluid may exhibit under different circumstances. The me- dium in which it is formed, in the upper regions of the atmosphere, is doubtless greatly rarefied; perhaps equal to that of a receiver which has been rarefied 100 times. It would seem, however, that the aurora sometimes reaches the surface of the earth. It is re- lated by Bergman, that persons travelling over the high mountains of Norway, have been enveloped in it; and Captain Ross states, that he has witnessed it very near to the surface of the earth ; and that it has caused the deflection of his compass needle as much as thirty and forty degrees. M. Hansteen also found that when the aurorae were vivid, the horizontal needle was restless, quivered, and varied from three to five degrees from its ordinary place. 340 AURORA BOREALIS. Lake, the Shetlands, Orkneys and many other places in loAArer latitudes. It also explains why in the coldest regions, as at Port BoAven, Winter Island, &c. the mag- netic needle is less often disturbed by it than in loAver latitudes; and why in the former places, it Avas almost ahvays seen by the British navigators southward of them.* Another important fact, that shows the intimate connection betAveen the aurorae and the change of temperature which the equatorial air undergoes, is, that the northern lights are more numerous and bril- liant during the coldness of winter, when the upper currents from the tropics, in their passage to the polar regions are greatly condensed; and that they are then formed in much lower latitudes than during summer. It is also an important corroboration of this theory, that they are seen in lower latitudes in the middle and eastern portions of America and Europe, than on tlieir Avestern coasts; while the former are known to be much colder than the latter in the same latitudes; Avhich is owing to the prevalence of west winds that blow from the Pacific and Atlantic oceans, and thus temper the middle latitudes of western coasts, by giv- ing them an oceanic or insular climate.-}" * It is stated by Captain Scoresby, that the aurora was disco- vered more frequently south than north of Spitzbergen; and by Sir Edward Parry, that it was generally seen south of Melville Island; from which we may conclude, that the upper current of the atmosphere has acquired nearly its maximum density, and de- posited nearly all its vapour, before arriving at the limits of great- est cold. f The effect is increased by the condensation of aqueous vapour which is brought from the ocean by westerly winds, and which gives AURORA BOREALIS. 341 The northern lights are seen much oftener in Ver- mont, which is a cold mountainous State, between lati- tude 42° and 44° N. than in France or England; though they are much farther north. This is evidently owing to the excessive coldness of winter in Vermont. General Martin Field has recorded, in the American Journal of Science, that, during the year 1830-31, the winter of Avhich Avas excessively rigorous, the aurora Avas perceived on fifty-six nights; and that during ten years previously, it was observed eighteen nights on an average, annually, at Fayetteville in the above State. Besides which, it must have existed during many cloudy nights, Avhen it was invisible. But in lat. 70° N. betAveen September, 1838, and April, 1839, M. Lottin observed at Bopekop, in the Bay of Alten, on the coast of West Finmark, 143 auroras, being an interval of 206 clays. (Becquerel, de l Electric lie, &c. tome vi. p. 205.) The arched appearance of the aurora is an optical illusion, produced by the limits of vision, according to the laAvs of perspective; for the same reason that the out caloric during its condensation and precipitation on the western coasts. Hence, the greater amount of rain which falls on the western coasts of North America and Europe, than on the interior and eastern portions. Hence also, the dryness of west winds in the United States, east of the Rocky Mountains, which deposit their vapour on the western slope, before reaching the interior. In the great Mississippi valley, the east wind is dry, while in the Atlantic States it is often moist during winter and spring. On moving west- ward, it deposits most of its vapour on the eastern slope of the Alleghany Mountains. These facts enable us to understand why in the vast regions drained by the Mississippi, west winds are dry; while in Britain and France they are wet, and east winds dry. 342 AURORA BOREALIS. sky presents a vaulted appearance—or, that clouds present the appearance of a canopy, while in reality they are suspended in horizontal strata. The different apparent heights of the aurorae are OAving to their va- rious distances from the points of observation. When the lower atmosphere between the observer and the lights is hazy, they appear irised or rose-coloured; pro- bably for the same reason that the sun rises and sets red, when the lower air is filled with vapours. The oscillations of the magnetic needle are as varia- ble as the aurora; when the arch is quiet, the needle is often motionless; its disturbance in these cases com- mences when the streamers begin to fly. The position of the dipping needle has been observed to be as vari- able as that of the compass needle, the former rising and falling with the corona. The intensity of the magnetism of the needle is also diminished. (Kreil. Bibl. Univ., tome viii. p. 114.) Siberia, Lapland and the Norwegian Alps, are dis- tinguished by the frequent display of this beautiful and mysterious phenomenon, which I have thus en- deavoured to explain in accordance Avith the best- established principles of meteorology. After all, it is quite probable, that some very important facts have been overlooked, which, if known and rightly consi- dered, might place the Avhole subject in a neAV light. It is to be hoped, that fifty years hence, we shall have fifty accurate observers of natural phenomena for one at the present time. Very little is known of the aurorae in the southern hemisphere, except what has been observed by Cap- tains Cook and Weddel, who relate that they have AURORA BOREALIS. 343 been frequently seen south of Van Dieman's Land, and off Cape Horn, where the cold is excessive.* * From a general view of the foregoing chapters, it must be obvious: 1. That all the phenomena of evaporation and rain, lightning and winds, hurricanes and tornados, fluctuations of the barometer and formation of the aurorae, are immediately connected with the theory of caloric, and those fundamental laws which govern its dis- tribution over our planet. 2. That the aurora is a thermo-electric phenomenon, produced during the condensation of vapour contained in the equatorial upper current of the atmosphere, on its passage to the polar lati- tudes, in a mode analogous to the evolution of lightning from the more elastic vapour of the lower and denser atmosphere, on mixing with colder currents, as during thunder-storms. In opposition to this theory, it is maintained by Dr. Faraday and others, that "the electric equilibrium of the atmosphere is preserved by the aurora conveying electricity from the poles to the equator." Can it be possible that the vast amount of lightning perpetually disengaged within the tropics, and during summer in the middle latitudes, is thus obtained ? With sentiments of unaf- fected and profound humility, the preceding facts are offered as an answer to this query. CHAPTER IV. GALVANIC ELECTRICITY. "Thou mayest babble about electricity, but what is it? whence comes it ? whither goes it ?"—Carlyle. If Ave would know Avhat electricity is, we must care- fully investigate all the phenomena that make up its natural history. Nor does it become the philosopher to despair of discovering its nature and origin, before he has ascertained Avhat office it performs in the econ- omy of the universe. Thomas Carlyle has done in- jury to the cause of science, by his want of faith in the Avell-directed powers of the human mind to com- prehend the mysteries of nature, for which he seems to have a more profound reverence than for the know- ledge of nature. The first discovery connected with this branch of physical science is found in a German work, published in 1767, by Sultzer, entitled The General Theory of Pleasures. He observed, that if two metals be ap- plied, one above, and the other below the tongue, and brought in contact, a peculiar taste wras perceived, attended with a gentle flash of light; but that if ap- plied separately, no such effects were produced. It was next discovered accidentally by Galvani, a distinguished professor of anatomy at Bologna, that (344) GALATANIC ELECTRICITY. 345 on touching the crural nerve of a recently killed frog, (Avhich lay on a table, near the conductor of an elec- trical machine in action,) with the point of a scalpel, all its muscles were thrown into convulsions, as if seized Avith tetanus. By repeating the experiment on different animals, he found that the effect was most remarkable in those Avhich are cold-blooded, and have Avhite muscles. He ascertained afterwards, that when the nerves and muscles of such animals were armed Avith small pieces of different metals, similar pheno- mena Avere produced on bringing the metals in con- tact. From these obscure results, Galvani arrived at the conclusions, that there is a peculiar species of electricity in all animals, Avhich resides in the brain, and is con- ducted to different parts of the body by the nerves, causing animal motion and secretion; and that posi- tive electricity resides in the nerves, and negative in the muscles. He supposed it to be conducted from nerves to muscles by the metallic arc, as the electricity of a Leyden battery is conducted from it by means of a common discharger. In opposition to the vieAvs of Galvani, it was main- tained by the celebrated Volta, professor of natural philosophy at Pavia, that the phenomena were due to the agency of common electricity, which he supposed Avas developed by the contact of different metals. Finding that Avhen sticks of zinc and copper, zinc and silver, &c. were made to touch at one of their ex- tremities, and the other brought in contact Avith the spine and muscles of a newly killed frog, convulsions Avere excited, it occurred to Volta, that by a repetition 346 , GALVANIC ELECTRICITY. of circles, or series, composed of tAvo different metals and moistened cloth, he might greatly increase the electrical effects. This led to the construction of the Avell known pile, and the couronne de tasses, which has been modified into different forms of the battery. In.reply to the hypothesis of Volta, that the convul- sions of the frog were owing to the agency of common electricity, and generated by the contact of different metals, Galvani objected that he had succeeded in producing convulsions by means of a single metal. And it was further shown by Aldini, a nephew of Galvani, that by bringing a portion of a warm-blooded animal in contact with a cold-blooded one, as the nerve and muscles of a frog with the bloody flesh of a newly decapitated ox, energetic contractions were produced. When he held a prepared frog in his hand, moistened Avith a solution of salt, and applied the crural nerves of the animal to the tip of his tongue, convulsions AArere also excited*—from Avhich he inferred, with Gal- vani, that there is a peculiar electricity in animal bo- dies which does not require the contact of metals for its development. It is somewhat surprising that he was never led to suspect, from these curious experi- ments, the identity of animal heat with the cause of muscular contraction; and still more remarkable, that neither Galvani nor Volta ever suspected the connec- tion of the phenomena Avith chemical action. The agency of caloric in exciting convulsions in re- cently killed fish, was strikingly demonstrated by sqme * The experiments were successfully repeated before a committee of the National Institute of France, and afterwards at the Ana- tomical Theatre in London, Great Windmill Street. GALVANIC ELECTRICITY. 347 experiments of Mr. Clift, Avho found that four hours after the head of a carp had been cut off and its heart taken out, (the fish being considered as perfectly dead,) when put in hot water, it leaped out of the vessel with a degree of vigour equal to the struggles of a living fish. M. Dessaignes also observed that convulsions were produced in the frog, when the muscles and nerves were connected by a silver spoon in which lighted charcoal was placed. (Phil. Transactions for 1815.) A similar fact was observed by Lord Bacon, who relates that he saw, with his own eyes, the heart of a criminal taken out of his body some time after execu- tion, and thrown into the fire, when it leaped up seve- ral times to a considerable height. Without comment- ing on these facts, which belong to another portion of the present work, it may be observed that they demon- strate the agency of heat in animal motion, at least as clearly as that of electricity,—even admitting (what has never been proved) that electricity could exist independent of caloric. The first philosopher who referred the phenomena observed by Sultzer, Galvani and Volta to chemical action, was Fabroni, in a paper communicated to the Academy of Florence, in 1792. He had often ob- served that fluid mercury retained its lustre for a long time when alone; but that when amalgamated with other metals, it speedily tarnished by oxidation; and that similar effects were produced on some alloys of tin. He had remarked in the Museum of Cortona, inscriptions engraved on plates of pure lead in a per- fect state of preservation; while in the Gallery of Flo- 348 GALVANIC ELECTRICITY.' rence, he found that medals composed of lead and tin, or lead and some other metal, were entirely reduced to a wdiite powder, though carefully wrapped up in paper, and preserved from the atmosphere in drawers. He had further noticed, when in England, that the iron nails then employed in fastening together the copper sheathing of ships, caused so much corrosion of the copper, that the holes made by them were some- times larger than the heads of the nails; all of which he referred to chemical action produced by the mutual contact of different metals exposed to moisture, atmo- spheric air, &c. That this was the case in the experi- ment of Sultzer, he thought was proved by the fact, that when the tongue was wiped dry, scarcely any per- ceptible sensation was excited. In another set of experiments, Fabroni put different metals in vessels filled with water, two and two, in contact, when he found that the most oxidizable metal was visibly oxidized at the moment of contact. A month afterwards, the connected metals had acquired so strong a degree of cohesion as to require a consider- able force to separate them. Not only were the metals oxidized, but covered over with small crystals of va- rious forms, which had been deposited from a state of solution. (Traite de VElectricite et du Magnetlsme, par M. Becquerel, vol. i. p. 88.) The above passages are sufficient to show that Fa- broni clearly recognized the necessity of chemical ac- tion in all galvanic phenomena, and that his views were much more accurate than those of his contempo- raries. Still it must be acknoAvledged that he never explained why tAvo metals in contact oxidize more "GALVANIC ELECTRICITY. 349 rapidly than when isolated; and that no satisfactory account has yet been given of the primary source of galvanic action by his successors; the consequence of which is, that the theory of the pile, like that of uni- versal chemistry, is still involved in obscurity. This much, hoAvever, is certain, that all the dif- ferent elements of ponderable matter have various degrees of attraction for caloric; and that during all chemical combinations, there is a transition of caloric from one to the other. When treating of freezing mixtures, it Avas shown that when chloride of sodium, chloride of calcium, potassa and many other salts are brought in contact Avith ice, there is a rapid abstraction of caloric from the ice to the salts, by Avhich both are dissolved and chemically united; that when lead, tin and bismuth are brought in contact, they dissolve at a much loAver temperature than when isolated, and thus unite chemically into an alloy. For the same reason, many other metals, rocks and gems are rendered more fusible, and combine more readily Avith each other by the addition of what has been termed a flux. Clay is more fusible wrhen mixed with fluor spar, and quartz with lime, than when sepa- rately exposed to the action of heat. Whatever may be the true explanation of these phenomena, it is evident that caloric is essential to oxidation, solution, and to all chemical combinations, whether of gases and liquids with each other, and with solids; or of solids with each other. It therefore fol- lows, that if chemical action be indispensable to the disengagement of galvanic electricity, caloric must be the primary source of all the resulting phenomena. 350 GALVANIC ELECTRICITY. Passing over the long and idle controversy between the partisans of Volta, (who maintained that galvanic electricity results from the contact of different bodies, and those of Fabroni, who contend that it is wholly the result of chemical action,) it may be sufficient to state, that the combined researches of nearly all the most distinguished philosophers of modern times de- monstrate, that there can be no galvanic action with- out chemical decomposition. For a long time it was supposed by Sir H. Davy that contact was necessary to its commencement, and that it was kept up by chemical action. But from the experiments of Wollaston, Gautheraut, De la Rive, Avogadro, Parrot, Becquerel and Faraday, the question may now be regarded as decided. Davy" himself ob- serves, in the Bakerlan Lecture, read before the Royal Society on the 8th of June, 1826, that there is no in- stance of electro-motion, (by Avhich he meant galvanic action,) without chemical decomposition. He also states, that when oxidizing liquids are employed in maintaining the action of the battery, the more oxidiz- able metal always afforded positive electricity in rela- tion to a less oxidizable one; that potassium, Avhich is the most oxidizable of all the metals, is positive in relation to all others; and so of its amalgams; that barium and its amalgams are positive in relation to an amalgam of zinc, which is positive in relation to pure zinc, zinc to cadmium, the latter to tin, tin to iron, and iron to bismuth. Corresponding Avith the above results are those of De la Rive, avIio found that the direction of a galvanic GALVANIC ELECTRICITY. 351 current is "not determined by metallic contact, nor by the nature of the metals relatively to each other, but by their chemical relation to the exciting liquid; that of two metals composing a voltaic circle, the one which is most energetically attacked is positive with respect to the other. Thus, when tin and copper are placed in acid solutions, the former, Avhich is most actively corroded, gives a positive current through the liquid to the copper: but if put into a solution of ammonia, Avhich acts most on the copper, the direction of the current is reversed. Copper is positive in relation to lead in nitric acid, which oxidizes the former most rapidly; Avhereas, in dilute nitric acid, by which the lead is most speedily dissolved, the lead is positive. He found that even two plates of copper, when im- mersed in solutions of the same acid, but of different strength, form a voltaic circle, the plate on which che- mical action is most energetic giving a current of posi- tive electricity to the other; and that a compound circle might be formed solely of zinc plates and one acid, provided the same side of each plate be more rapidly oxidized than the other. The following experiments are decisive against the theory of Volta. M. De la Rive ascertained that when zinc and copper plates were brought in contact in an atmosphere of hydrogen or nitrogen, wholly deprived of oxygen, moisture and other bodies, no electricity Avas evolved; and when he purposely increased che- mical action by exposing the zinc to acid fumes, or by substituting for zinc a more oxidizable metal, such as potassium, the electrical effects observed, on contact 352 GALVANIC ELECTRICITY. with copper, were greatly augmented, the amount being in proportion to the chemical action. (Ann. de Chim. et de Phys. xxxviii. et ix.) The above facts have an important bearing on the general theory of electricity, for they seem to prove that what are termed positive and negative electricity are only plus and minus conditions of one and the same ethereal element; consequently, that the oxy- gen, chlorine, fluorine, iodine and bromine of acids, salts, &c. are attracted by the minus or negative pole of the battery; and hydrogen, metals and alkalies to the positive pole, because in their natural state these two classes of bodies are combined with different pro- portions of thermo-electric ether. But as I have be- fore shown, (pp. 193 and 194,) that bodies are neither essentially positive nor negative, but vary according to circumstances, and that those which belong to the electro-positive class unite with each other, as Avell as with those that belong to the opposite class, it is evi- dent that chemical attraction is not wholly the result of electric polarity, as maintained by Davy. It has been often said that the energy of the voltaic battery is in proportion to the conducting power of the liquid that acts on the plates. The absurdity of this hypothesis will appear in a striking point of view, when it is remembered, that of all liquids mercury is the best conductor; yet when employed between the plates of a battery, no electricity whatever is disen- gaged. The simple matter of fact is, that the quan- tity of electricity evolved is proportional to the rapidity with which the intervening liquid is decomposed by the metallic plates; and that Avhen the chemical GALVANIC ELECTRICITY. 353 action ceases, the disengagement of electricity also ceases* * From the experiments of Ritter, Davy and others it would appear that two different metals are not requisite to the disengage- ment of the galvanic fluid, but to its concentration. Sir Humphrey Davy formed galvanic series of a single plate of zinc, one side of which was exposed to an acid, and the other side to water; also bv a single metal acted upon one side by an acid, and on the other side by hydro-sulphurets. (Philosophical Transactions for 1821.) It has been further shown by M. Becquerel that electricity is evolved whenever metals are immersed in acid solutions that act chemically on them. The same effect was produced during the combination of acids and alkalies,—when nitrate of iron acts on leaves of platinum foil; or nitro-muriatic acid upon gold; and even on mixing a concentrated acid solution with a diluted solu- tion of the same acid. (Ann. de Chem. et de Phys. xxxv. 120.) From such experiments it has been inferred that electricity is disengaged during all chemical actions. But it is certain that all chemical combinations and decompositions are attended with changes of temperature; that is, by the absorption or evolution of caloric. The disengagement of electricity during the action of the strong acids on metals, alkalies, &c. has been deduced from the fact, that when the two ends of a multiplying wire are made to communicate with the combining bodies, the magnetic needle is deflected, as it is during the passage of a current of voltaic elec- tricity through it. But the same effect is produced when one end of the multiplying wire is made to communicate with melted silver, and the other end with a portion of the same metal in the solid state; or when the two extremities of the multiplier are made to communicate with different parts of other metals when of different temperatures; from which it would appear that the magnetic phe- nomena are independent of chemical action, and result from the transition of caloric through the multiplying wire, as will be proved further on. 23 354 THEORY OF GALVANIC, THEORY OF GALVANIC, OR VOLTAIC ELECTRICITY. On the first introduction of the voltaic pile into Paris, Napoleon was so strongly impressed Avith its importance, that he offered 60,000 fr. to the indi- vidual, of whatever nation, who should make a de- cided advancement in the knowledge of its theory, as Franklin did in common electricity. Had this extra- ordinary man devoted himself to the task, it is pro- bable that he would have gained the prize. He pro- posed several interesting points of inquiry in regard to the theory of its action. He wished that experi- ments should be made on the pile at very different temperatures, for the purpose of ascertaining whether caloric created any remarkable difference in its power of producing electricity. On witnessing the transport of the elements of salts to its respective poles, he is represented to have said to his physician, Corvisart, "Docteur, voila l'image de la vie." (TraltS de Tfllectr. et du Magnetlsme, vol. i. p. 108, par M. Becquerel.) It sometimes happens that new discoveries retard the general progress of science for a time, by with- drawing the attention of philosophers from a general and comprehensive survey of nature, to that of some obscure and isolated province. The brilliant discoveries of Galvani, Volta and Davy directed the inquiries of men to the chemical and phy- siological properties of electricity, to the neglect of the still more obvious agency of caloric. Had philosophers studied the cause of solution, combustion, fermentation and ordinary decomposition with half the attention OR VOLTAIC ELECTRICITY. 355 bestowed on electro-chemistry, they would have dis- covered that caloric is indispensable to the chemical union of oxygen with combustibles; of salts with water; metals with acids, and with each other; in short, that without caloric, there is no chemical at- traction. This would have led them to investigate the rela- tions of caloric and electricity, one of the most im- portant problems in physics, from its intimate relation to the whole constitution of nature. If they be only modifications of one and the same universal principle, we cannot expect fully to comprehend the most sim- ple phenomena of attraction and repulsion, without understanding its general laws. When treating of chemical solution, it was demon- strated that metals are dissolved by the caloric of the strong acids, and combined chemically with them as certainly as that salts are dissolved by the caloric of water, and thus chemically combined with it. If then there be not two causes of chemical attrac- tion, it is evident that the same agent which causes sulphuric acid to combine with copper, making a trans- parent solution of copper, causes the same acid to combine with the plates of the voltaic battery, by which they are oxidized and dissolved, when a por- tion of the latent caloric of the acid is given out in the concentrated form of electricity, conducted from the plates by the connecting wires, and thence to the extremities of the battery. I have already shown that sulphuric acid is com- posed of oxygen, sulphur and caloric; that nitric acid is composed of oxygen, nitrogen and caloric; and so 356 THEORY OP GALVANIC, of other compounds. When solutions of nitric, sul- phuric or hydrochloric acids are poured upon metals, there is a rapid transition of caloric from the acids to the metals, by which they are made to combine che- mically, with great diminution of volume and evolu- tion of heat. When poured on copper and zinc filings, they are decomposed, and the metals oxidized still more rapidly. But when the same metals are arranged in the form of a galvanic battery, and immersed in the same solutions, electricity is evolved: from which it would seem to follow, that the latent caloric of acids is given out in the form of calorific or electric ether, according to the mode of its disengagement. Another fact of fundamental importance to a right understanding of the nature of voltaic electricity and its relation to caloric is, that its character is modified by the size and number of plates composing the bat- tery. For example, when it is composed of a few large plates of zinc and copper, an imponderable fluid is evolved, possessing all the properties of highly con- centrated caloric,—which fuses and ignites the hardest gems and densest metals submitted to its action; while it is destitute of nearly all the properties by which common electricity is characterized. The largest bat- tery of this description ever constructed, was that of Mr. Children, Avhich was composed of twenty plates of zinc and copper, six feet long, and thirty-two inches broad. When immersed in a strong acid solution, it melted, ignited and fused a large platinum wire, six feet in length; but communicated little or no shock to the system; would not charge a Leyden jar; produced OR VOLTAIC ELECTRICITY. 357 no sensible effect on the electrometer; and, unlike com- mon electricity, was conducted slowly by metals, minerals, fluids, &c* When the battery is composed of two extensive coils of zinc and copper; or of many plates, so ar- ranged as to constitute only a single pair of zinc and copper plates of enormous dimensions, as in Dr. Hare's calorimotors, the calorific effects are still more remark- able. On the other hand, when the battery is composed of a large number of metallic plates of small size, and immersed in the same solutions, electricity is evolved, which affects the electrometer, communicates a shock, and passes through conductors with the speed of lights ning.-j- * The large battery of the Royal Institution, employed by Sir H. Davy, which consisted of 2000 pairs of four-inch plates, melted platinum, quartz, the sapphire, magnesia and lime, like wax, both in vacuo and in the atmosphere; while charcoal, plumbago and the diamond were rapidly dissipated in the form of vapour. f When the battery is composed of a few large plates and im- mersed in an acid solution, caloric is evolved until the acid is de- composed, or until the metallic plates are consumed. But if the battery be composed of a large number of small plates of the same metals, and immersed in the same acid, electricity is produced, until the plates or acid are consumed by oxidation; which demon- strates the identity of caloric and electricity beyond the possibility of a doubt; for it would be a perversion of common sense to sup- pose, that by merely changing the size and number of the plates, a radically different fluid could be evolved, while the metals and solutions in which they are immersed, are the same. Shall I be asked for clearer proofs that the latent caloric of acids is the basis of electricity ? We might as well be asked to prove that the sun 358 THEORY OF GALVANIC, These striking facts led Dr. Hare to suppose that both caloric and electricity are developed during all galvanic operations; and that they are combined Avith each other by what he calls " the reciprocal attraction of imponderables." He supposed that when two or more large plates were employed,caloric predominated; but that wrhen a large number of small plates were used, electricity predominated. One thing is certain, that the character of the electricity is modified by every variation in the size and number of the plates composing the battery. But if we suppose that caloric is combined with galvanic electricity, because it fuses and ignites metals or other bodies, we shall be forced to admit that it is also a constituent portion of com- mon electricity, for this fuses and ignites bodies like vol- taic electricity. He further supposes, that "electricity fuses and ignites metals, &c, by combining with their latent caloric; thus augmenting its repulsive agency and causing it to overcome their cohesion." But he omits the important fact, that electricity also increases their temperature, and that its former properties are changed and merged into those of caloric, as it fuses and ignites bodies. The unavoidable conclusion from the above facts is, that caloric and electricity are only different forms of is the fountain of light and heat; or that rain accompanies light- ning. It is generally known that the most powerful batteries are com- posed of bodies which act with the greatest energy upon each other, such as zinc, copper and nitric acid; and that such as un- dergo no chemical changes exhibit no electrical effects, such as gold, silver and water. OR VOLTAIC ELECTRICITY. 359 the same elementary agent, varied by the numerous modes of its separation from ponderable matter: or, that there are two distinct and universal agents com- bined with ponderable matter and with each other, "by the reciprocal attraction of imponderables," as maintained by Dr. Hare. It need scarcely be observed, that there has never been the slightest evidence ad- duced that such an attraction exists between caloric and electricity, admitting them to be distinct fluids; while it is contrary to the simplicity which character- izes all the operations of nature to suppose the exist- ence of two universal agents, endowed with the same fundamental properties. There cannot be two uni- versal principles of action in nature; because if they were different they would interfere with each other and produce discord; and if they were alike they would produce like results, which amounts to the same thing as if they were radically identical* If every apparent difference between caloric and electricity be taken as an argument against their identity, it would be easy to prove that there are more than one hun- dred electricities. There is a far greater difference between the voltaic fluid disengaged by Children's battery and that from a common electrical machine, than between the former and the caloric evolved by ordinary combustion; while the deflagration of steel * Sir Isaac Newton thought it " inconceivable that two ethers could be diffused through all nature, one of which acts upon the other, and by consequence is reacted upon, without retarding, shat- tering, dispersing and confounding one another's motion. (Opticks, p. 339.) 360 THEORY OF GALVANIC, wires in oxygen gas and the detonation of gunpowder, are more like an electric explosion than anything else. The ordinary process of combustion by which heat is evolved, consists in the combination of oxygen with other elements. The galvanic fluid is decomposed by the same process: wdiile it would be contrary to all the rules of a sound induction, to suppose that two or more distinct ethereal agents could be disengaged from the same elements. If we reject this simple mode of reasoning, we shall be compelled to admit the existence of as many electricities as there are modes of sepa- rating it from ponderable matter; which would be absurd. It is far more consistent with facts and the harmonious simplicity of nature to suppose that one agent produces all the diversified powers and activities of matter; that it exhibits different properties and appearances under different circumstances, according to its diffusion, concentration, compression, &c.; and to the mode of its combination with different substances, in a solid, liquid, gaseous or imponderable state, as in the matter of light. We hav^e already seen, that a certain temperature is indispensable to combustion, fermentation, putrefac- tion and to every process of oxidation, however slow, as the rusting of metals; that when atmospheric oxy- gen is thus made to combine with metals, its volume is diminished, and a portion of its latent caloric libe- rated, in the form of radiant ether, by which the pro- cess of oxidation is kept up. I have also proved, that when metals are exposed to the action of strong acids, there is a transition of caloric from the acids to the metals, by which the latter are dissolved and chemi- OR VOLTAIC ELECTRICITY. 361 cally combined with the menstruum; that caloric is the cause of all attraction between fluids and solids; that the solvent power of water, acids, &c. is greatly augmented by heat; and that when metals are dis- solved in the strong acids, caloric is given out in great abundance, as in ordinary combustion. So nearly does the operation of a voltaic battery resemble com- bustion, that more or less heat is always disengaged by its action. When the acid solution is strong, and chemical action energetic, the whole apparatus be- comes warm; viz., a portion of the latent caloric of the acid is conducted from the plates to the connect- ing wire in the form of electricity; while another por- tion is liberated in the diffused form of sensible heat, as when water and acids are poured upon quick-lime. That the caloric of liquids is the cause of their chemical action on the plates of the battery, is proved by the fact, that when the apparatus is supplied with hot solutions of the strong acids, its energy is greatly augmented, and the metallic plates rapidly dissolved; in other words, the battery is very soon burned out. It is stated by Singer, Donne and others, that the energy of De Luc and Zamboni's columns* is greatly augmented by an elevated temperature, and dimi- nished by a reduction of temperature; that they are more active during summer than winter: and in a warm than a cold room. Dr. Jaegar found, that after * The first is formed of disks of writing-paper, interposed be- tween thin leaves of zinc and silver; while that of Zamboni was composed of paper disks gilt or silvered on one side, and the other side covered with a layer of black oxide of manganese mixed with honey. 362 THEORY OF GALVANIC, the dry pile had lost its energy, it was restored by a temperature of from 104° to 140° F. That the energy of this pile is owing to chemical action, like every other form of the battery, is proved by the oxidation Avhich it undergoes, and by the total loss of its power Avhen perfectly dry. When isolated plates of zinc and copper are im- mersed in dilute nitric acid, they are oxidized and dissolved, when caloric is liberated as during combus- tion; but when they are connected by means of a metallic wire, galvanic electricity is evolved. There can scarcely be a doubt that if the caloric evolved by ordinary combustion could be concentrated and con- ducted off like the galvanic fluid, it would exhibit electrical phenomena. Pouillet has actually shown that electricity is disengaged during nearly all com- bustions, though in a slight degree, as had been proved long ago by Lavoisier and Laplace, De Saussure, and by Mr. Read. Were it not for the caloric contained in nitric acid, it would not dissolve zinc and copper filings. For the same reason, it would not combine Avith the plates of the battery; nor would it enter into chemical combination with any other substances. The battery owes all its energy to chemical action, as cer- tainly as that combustion is a chemical action. Can common sense admit that caloric causes atmospheric oxygen to combine with combustibles, and that some other agent causes the oxygen of acids to combine Avith the plates of a voltaic battery? The supposition is wholly unphilosophical, and is contradicted by all the analogies of nature. Combustion is a chemical process to all intents and purposes, and is produced by the same OR VOLTAIC ELECTRICITY. 363 agent which causes all other chemical actions. An- other important general fact, showing the intimate relation between combustion and galvanic action, is, that the action of the pile, like that of combustion, is far more energetic in oxygen gas than in atmospheric air; and ceases in vacuo, in nitrogen, and other gases that do not act chemically on it. If we compare the effects of galvanic electricity with those of caloric evolved by ordinary combustion, we find that they are the same. When voltaic elec- tricity fuses, ignites and volatilizes metals, gems and all other combustibles, does it not produce the same effect as that of an oxy-hydrogen bloAV-pipe, or the concentrated heat of a forge? and if it produce the same effects, must it not be the same agent? Can electricity render bodies hot, and yet not be an igne- ous fluid? When charcoal is submitted to the action of a galvanic current under water, it is ignited, and decomposes the water as when heated by ordinary combustion: and if an iron wire, connecting the ex- tremities of a battery in action, be made to pass through water, the latter becomes hot and boils. When the wire is thus heated, it attracts oxygen from water, as when rendered red hot by other means. Like caloric, electricity causes oxygen and hydrogen to combine to form water, and again causes its decom- position. If then it be an established axiom in philosophy, that the same effects should be ascribed to the same cause, caloric and electricity must be essentially the same agent. The recent experiments of Dr. Faraday have fur- 364 THEORY OF GALVANIC, nished many important facts, Avhich show the intimate relation between combustion and the eA^olution of elec- tricity by galvanic action. It is very well known, that oxygen is not indis- pensable to combustion; that during the rapid combi- nation of chlorine, fluorine, iodine, &c. with hydro- gen, sulphur, phosphorus and the metals, caloric is evolved in the form of radiant heat, as in ordinary combustion; in short, that caloric is evolved during nearly all rapid chemical combinations. By folloAving up the experiments of Sir H. Davy, Dr. Faraday has shown, that when chlorides, iodides, fluorides, oxides, cyanides, nitrate of potassa, chlorate of potassa, sul- phate of soda and various other compounds were fused by heat, and interposed between the plates of copper and platinum of a voltaic battery, electricity was evolved as when acids were employed; and in some cases much more freely. He adds, "there are hun- dreds of bodies which evolve electricity in the same manner, when in a state of fusion; but that when they become solid, the decomposition and the electric currents cease." He thinks that solidification pre- vents decomposition, &c. "merely by chaining the particles to their places, under the influence of aggre- gation." (Experimental Researches in Electricity, 4th series.) Had this distinguished experimenter recog- nized the agent by which particles are aggregated and chained together, he would have found that it is the alpha and omega of chemical action, without which there could be no voltaic electricity; and that it is the source of all electro-chemical combinations and decom- positions. OR VOLTAIC ELECTRICITY. 365 But there are certain minute philosophers, who maintain that the slightest difference between any two agents destroys their identity. If such objections to the unity of caloric and electricity were well founded, Ave should be compelled to admit the existence of more than a hundred species of electricity; for it differs with every modification of the process by which it is pro- duced, from thermo-electricity of the lowest tension to the fluid of a Leyden battery, which darts through metals and the living body Avith the speed of light- ning. It is known, that the different forms of voltaic elec- tricity pass with different degrees of velocity through the same conductors; and that in this respect there is an almost infinite variety in the properties which it presents. Yet these differences have not prevented Wollaston, Faraday and many of the most distin- guished philosophers of the continent, from maintain- ing the identity of electricity under every variety of form and appearance Avhich it exhibits, from that of Children's battery to De Luc and Zamboni's pile; and from a flash of lightning to the magnetic spark, or the shock of a torpedo. Surely there is a far greater dif- ference betAveen the electricity developed by a common machine and Children's battery, than between the latter and solar heat concentrated by means of a large burning-glass. It was shown by Mr. Parker of Fleet Street, that the most intense heat of a burning-glass three feet in diameter, though sufficient to fuse and volatilize gems and metals in a few seconds, passed through water without heating it like electricity; and that when it was made to strike upon the finger, it 366 ANALOGIES BETAVEEN VOLTAIC ACTION produced little or no sensation of heat, but that of a sharp cutting instrument. ANALOGIES BETWEEN VOLTAIC ACTION AND SUBTERRA- NEAN CHEMICAL FORCES. From a general view of the foregoing facts and ob- servations, it would appear that the galvanic or voltaic pile affords a miniature representation of nearly all the chemical changes perpetually going on throughout nature; while it exhibits the relations of caloric and electricity, in all their multiform states, in the most instructive manner. There is a striking resemblance betAveen the phenomena of galvanic heat and that developed by volcanic agency; not only in the che- mical mode, of their production, but in the effects they afterwards exhibit. In both cases the radiating power of the igneous ether evolved is exceedingly small, compared with its power of fusing rocks, metals, gems, &c, while they are both attended with thermotic and electrical phenomena. A large voltaic battery, capable of producing a current sufficiently powerful to fuse and ignite the most obdurate bodies, excites no sensation of warmth beyond the apparatus. It is stated by Mr. Scrope, on the authority of Dolomieu, corroborated by his own observations, that very little heat is radiated from a mass of red-hot lava; that at the distance of a few feet, the thermometer is scarcely affected by it, which induced Dolomieu to suppose that its fluidity was due to some other cause than caloric. (Scrope on Volcanos, p. 20.) The reason why incandescent lava does not radiate AND SUBTERRANEAN CHEMICAL FORCES. 367 heat like coal, wood, &c. when in a state of ignition, is doubtless owing chiefly to the greater attraction of caloric for metallic and rocky masses, than for combi- nations of animal and vegetable matter, as explained under the head of radiation. It has been long known, that the most intense elec- trical phenomena are displayed during volcanic erup- tions. If it be inquired why persons near to a mass of incandescent lava experience no electric shock, it may be answered, that no shock is received from a voltaic battery of large plates; nor should we be able to discover that any electricity was evolved, Avere it not conducted off by the connecting wires to the ex- tremities of the pile: even then, it exhibits chiefly the phenomena of concentrated caloric, and but slight in- dications of electricity. Mr. Scrope has given a highly graphic description of the electrical action that accompanied an eruption of Vesuvius that he witnessed in October, 1822; and which resembled the awful displays of lightning that attended its eruption in 79, when Pompeii and Hercu- laneum were overwhelmed with lava; and by which the elder Pliny lost his life. " From every part of the immense cloud of ashes that hung suspended over the mountain, flashes of forked lightning darted continu- ally. They proceeded in greatest number from the edges of the cloud. They did not consist, as in the case of a thunder-storm, of a single zigzag streak of light, but a great many coruscations of this kind ap- peared suddenly darting in every direction, from a central point, forming a group of brilliant rays, resem- bling the thunder-bolts placed by the ancient artists in 368 ANALOGIES BETWEEN VOLTAIC ACTION the hands of the cloud-compelling Jove." (Scnpc on Volcanos, p. 81.) It is also related by Sir William Hamilton, that the eruptions of Vesuvius in 1767,1779 and 1793, were at- tended with the most tremendous exhibitions of light- ning ; and the two latter with extremely loud explo- sions of thunder. Zigzag lightning darted incessantly from the enormous black clouds that hung over the crater, resembling in all respects that of ordinary thunder-storms; and accompanied by heavy showers of rain, with whirlwinds, like those which attend water- spouts. Sometimes balls of fire issued from the black cloud, which burst into serpentine streams of fire. He thought that the violence of the subterranean action might be known from the height to which the vapour and smoke ascended, and by the amount of ferilli, or volcanic lightning. (Philosophical Transactions of the Royal Society for 1795.) Dr. Daubeny further relates, on the authority of M. Monticelli and other persons who witnessed the erup- tion of Vesuvius in August, 1834, that from a current of lava which overwhelmed one hundred and fifty houses, and covered about five hundred acres of ground, there arose a black cloud, from which emanated very vivid flashes of lightning, sometimes followed by thun- der, but not always. (Philosophical Transactions, 1835.) It is also related in the Amerlcein Journal of Science, that on the 20th of January, 1835, Nicaragua, in Cen- tral America, was visited by a tremendous earthquake, and followed by an eruption of the volcano of Cosi- guina, by which the atmosphere was filled to a great height and distance with phosphoric sand, smoke and AND SUBTERRANEAN CHEMICAL FORCES. 369 vapour,—from which issued perpetual flashes of light- ning throughout the night of the 20th and the whole of the next day. On the 23d, toward morning, tre- mendous loud thunder-claps were heard in succession, like the firing of the largest cannon,—from which it was supposed by the inhabitants at the Port of Balize, on the Bay of Honduras, that a naval action was going on, or that a ship was in distress. It is stated that during this earthquake the country was convulsed for more than a thousand miles. It is here worthy of special notice, that nearly all the volcanos of our planet that are situated on dry land, amounting to about two hundred, have been found in the vicinity of the ocean; while it is pro- bable, from the \7ast number of the volcanic islands, that there are at least three times as many beneath the sea. It is well known to modern geologists that sub- marine eruptions are exceedingly frequent. On the 12th of June, 1811, immense volumes of smoke were observed to arise from the sea, near the island of St. Michael, one of the Azores, by Captain Tillard of the Sabrina; from Avhich issued at intervals, for several days, the most vivid flashes of lightning, and some- times a continual blaze. During these eruptions an island was formed, about a mile in circumference and two hundred and eighty feet high, which Captain Til- lard visited, in company with several of his officers, on the 4th of July, when he named it Sabrina, after his ship. By the middle of October it had disap- peared, leaving a dangerous shoal. 24 370 ANALOGIES BETAVEEN VOLTAIC ACTION During an earthquake on the 9 th of July, 1757, eighteen small islands emerged from the sea, near the northwest corner of St. George, another of the Azores; which also disappeared in a few months. The destruction of the town of Conception, in Chili, by an immense wave of the sea, twenty-eight feet in height, which rolled over it, must have been caused by a submarine volcano, as we are informed by Mr. Caldcleugh that two eruptions of dense smoke were observed to issue from the sea, with violent ebullition, and the evolution of large quantities of gas. About the same time, flame and smoke burst from the sea, near the island of Juan Fernandez, over which the waves rolled to a great height, as at Conception. (Phil. Trans. 1835.) And Ave learn from the captain of an English ship from the Mediterranean, that on the 18th of May, 1845, in lat. 36° 40', and long. 13° 44', immense balls of fire were seen to issue from the sea. .(New York Sun, July 22, 1845.) But to return; it has been shown that the voltaic fluid, whether thermal or electrical, is disengaged from nearly all bodies when in a liquid state—from water, acids, saline solutions,—from oxides, chlorides, iodides, &c. when in a state of fusion, during their chemical decomposition by the plates of a battery. The resem- blance of this process to that of subterranean chemical action is somewhat remarkable. For example, the products of volcanic eruptions render it almost certain that subterranean caloric is disengaged from sea water, which finds its way to the interior through fissures and submarine craters,—where its oxygen combines with sulphur, metals, &c. as the oxygen of acids unites AND SUBTERRANEAN CHEMICAL FORCES. 371 with the plates of a common battery.* That volcanos are in some way abundantly supplied with sea Avater, is evident from the vast quantities of steam discharged during their eruptions, which contains chloride ol sodium, hydrochloric acid, chlorides of copper, iron, &c. as well as from their geographical positions near the sea. In short, the earth may be regarded as a huge galvanic pile, kept in a state of perpetual subter- ranean chemical action by the waters of the ocean, as our little batteries are maintained in action by various solutions. When the plates of a common battery are com- pletely oxidized, chemical action ceases: so when all the materials within a given range of subterranean territory become saturated with oxygen, sulphur, chlo- rine, &c. chemical action ceases, and the volcanic forces become quiescent, to be renewed elsewhere for indefi- nite periods of time, until exhausted or burned out like the plates of a voltaic battery. In North America they have been nearly extinct since the elevation of the Rocky and Alleghany Moun- tains above the ancient sea that once covered the northern hemisphere; Avhile in South America, and * The hydrogen of water may unite with sulphur, making sul- phuretted hydrogen; while the union of oxygen with sulphur makes sulphurous acid, which combines with lime, and drives off carbonic acid, a common product of hot springs and volcanos. The nitro- gen of atmospheric air, which is admitted through craters, and is mixed in greater or less quantity with all water, combines with hydrogen, forming ammonia. In fine, there is no limit to the play of affinities that take place in this grand laboratory, under the agency of so intense a heat. 372 ANALOGIES BETWEEN VOLTAIC ACTION on the eastern continent, volcanos are numerous, but confined chiefly to the borders of the ocean. The only feeble remains of subterranean chemical action in North America are its warm springs, which convey off whatever heat is generated beloAv the surface, in a tranquil manner. The same observations apply to the greater part of Europe and Asia. The Alps, the Apennines, the Hima- layas and many other mountain ranges of the old world, afford no evidence of existing subterranean combustion, except the numerous warm springs that issue from their sides. Were it not for this continual discharge of heat, it is probable that they might still be convulsed at long intervals by volcanic explosions, or by earthquakes, which are owing to the confine- ment of volcanic steam by superincumbent pressure. Warm springs may therefore be regarded as "safety- valves of the globe" still more emphatically than vol- canos. It is very well known that when the great geyser of Iceland is obstructed by throwing stones into its funnel, its temperature rises rapidly, Avhich is soon followed by eruptions of steam and water to a great height. It is equally certain, that if the ob- struction were equal to the pressure of two or three thousand feet of rocks or lava, earthquakes would follow. It was before stated that the rapidity with which acid, alkaline and other solutions are decomposed by the plates of the battery, is augmented by increasing their temperature,—that the amount of chemical ac- tion, like that of evaporation and rain, is greatest on the surface of the earth within the tropics, cceteris AND SUBTERRANEAN CHEMICAL FORCES. 373 paribus, and diminishes as we approach the regions of perpetual frost. The same thing would seem to be true of subter- ranean chemical action, which points out the agency of solar heat in the production of volcanos, and con- nects the Avhole theory of geological dynamics with that of solution, combustion and of universal chemis- try. It is a remarkable fact, which has never been explained by geologists, that the highest mountains of the earth are within the torrid zone, where they rise to an elevation of from four to five miles above the ocean level; while in the middle latitudes they do not exceed the height of fifteen or sixteen thousand feet; and seldom more than five or six thousand feet beyond the polar circles, although they are nearer to the centre of the globe than any other part of its surface. The islands of the Pacific and Atlantic oceans are also far more numerous within the tropical than the higher latitudes; while it is certain that nearly all of them have been elevated by submarine volcanos. All the chemical and geological operations of our planet Avould seem to be in proportion to the energy of solar radiation. Within the tropical regions, the aggregate quantity of earthy and metallic matter con- veyed from the interior of the earth in a state of che- mical solution by springs, is immense. The amount of evaporation and rain being great, the rivers are large, and rapidly destroy rocks, hills and mountains by mechanical agency; these are transported to lakes and seas, which are rapidly filled up by fluviatile de- posits of sand, gravel, clay, pebbles, boulders, &c. form- ing new lands. The waters of the ocean that find 374 ANALOGIES BETWEEN VOLTAIC ACTION their Avay to the interior are warm, and rapidly oxi- dize its metals and other minerals, by which a cor- responding amount of heat is disengaged. Thus it is evident that all the phenomena of meteor- ology, chemistry and geology are resolvable into the agency of caloric, or thermo-electric power. If rocks and hills are dissolved by running water, and trans- ported to lakes and seas, caloric is the universal sol- vent. And here must end forever the long and idle controversy between the Plutonian and Neptunian geologists. If caloric be indispensable to fluidity and solution, it is as necessary to the formation of sedi- mentary rocks as to the generation of granite, basalt and other volcanic products, which are composed chiefly of metallic oxides, such as those of silicium, calcium, aluminum, iron, potassium and sodium, the oxygen of which is derived mostly from sea water. There is something great and sublime in the sim- plicity of the idea, that the same familiar power which "warms in the sun," and clothes the world Avith en- chanting beauty, raises mountains from the ocean, and keeps the whole stupendous fabric of the universe in a state of perpetual motion and circulation. It was supposed by some of the older geologists that in the earlier periods of the world there were no volcanos— by others, that they were far more active than at present —while Descartes, Leibnitz, Buffon, Fourier and a mul- titude of more modern philosophers, have maintained that the earth originally existed in a state of fusion or incandescence throughout; and that it has been gra- dually cooling down ever since. To those who believe in the uniformity of nature's laws, it is needless to AND SUBTERRANEAN CHEMICAL FORCES. 375 insist that none of these opinions have any founda- tion in fact; and that they are discountenanced by all analogy. We are rather authorized to believe that the amount of chemical action going on throughout the earth is the same in all given periods of time, and in proportion to the amount of matter. But if vol- canic agency were due to a central fire, it is difficult to comprehend why the tropical mountains should be from four to five times higher than those of the polar regions,—why volcanos are confined chiefly to the vicinity of the ocean,—why they should discharge enormous quantities of steam saturated Avith muriatic salts,—why they should continue in action at inter- vals for unknown periods of time, and then become extinct,—why volcanic islands are more numerous in the tropical than higher latitudes,—and Avhy hot springs should not be equally distributed all over the earth. The facts collected by M. Cordier and others, prov- ing that the temperature of the earth increases as we descend below the surface, have been regarded by many geologists as conclusive evidence that earth- quakes and volcanos are caused by a central fire. It is true, that in many parts of the world, the temper- ature of rocky strata and of the water that issues from them is higher at the bottom of deep mines than at the surface, varying greatly however in differ- ent places. Humboldt says, that the bore at Mew Salaweak, Minden, in Prussia, is 2094i Prussian feet. and the temperature of the water 90° F.; which gives a rise of 1*6° for 97*6 feet English. From which he infers, that at the depth of 40,000 feet, the tern- 376 ANALOGIES BETWEEN VOLTAIC ACTION perature would be 435° F. Mr. Fox found that in the Dalcoath copper mine, in Cornwall, at the depth of two hundred and thirty fathoms, or 1380 feet, a thermometer placed in a hole in the rock, stood at 76° F., and at 82° in water, ten fathoms deeper; the mean annual temperature of the surface being 50°. But the same gentleman states that about two mil- lion gallons of water are daily pumped from the Pol- dice mine, at the temperature of from 90° to 100°; while the mine is only one hundred and seventy-six fathoms'(or 1056 feet) deep. It is therefore evident that the temperature is not proportional to depth. On the other hand, when we reflect that water is continually acting upon the metals, causing their oxidation, and that chemical action is the grand pro- cess by Avhich latent heat is disengaged, we need be at no loss to account for its accumulation at great depths beneath the surface, where metals are abundant. It is impossible to know with certainty how far the waters of the ocean penetrate beneath the surface— probably not beyond the depth of a few miles; nor is there any good reason to suppose that there is much chemical action at greater depths, owing to the super- incumbent pressure; while it is known that on the surface of the earth there is very little chemical ac- tion without moisture. This much however is cer- tain, that so far as we can trace back the history of our planet, it has been composed as at present, of mountains and valleys, seas and plains, and stocked with plants and animals that have successively arisen and passed away, leaving their fossil remains as a re- cord of their former existence. We have the most AND SUBTERRANEAN CHEMICAL FORCES. 377 indubitable proofs, that our mountains of granite, gneiss, basalt, &c. were formed during long geological epochs, by successive volcanic movements, and con- temporaneous with the deposition of our stratified rocks; while there is not the slightest evidence that the earth Avas ever in a state of liquid fusion through- out. According to the estimate of Mr. Lyell, there are about two thousand volcanic eruptions every cen- tury, which in six thousand years would make one hundred and twenty thousand. If then it be admitted, that an equal amount of caloric is removed by thousands of hot springs, it is evident that such an enormous loss, if not compensated by the waters of the ocean, (which receive their tem- perature from the sun,) would cause a sensible dimi- nution of the internal heat of the globe, and conse- quently, of its volume. But it is acknowledged by Fourier, Laplace and Arago, that the temperature of the earth has not varied the one three-hundredth of a degree in two thousand years. This conclusion was deduced from the fact, that the length of the day has not diminished perceptibly since the time of Anaxa- goras, which, it is maintained, must have been the case, had any diminution of the earth's volume taken place. With the exception of Mr. Lyell and Dr. Daubeny, nearly all geologists of the present day have embraced the hypothesis of a central fire,—maintaining that the superficial crust of the earth is supported by a mass of incandescent lava. Baron Fourier supposed, (for he certainly never proved it,) that the earth was originally projected in a state of fusion or of incan- 378 ANALOGIES BETWEEN VOLTAIC ACTION descence into the planetary space,—the temperature of which he estimates at about —58° F., due to radia- tion from the sun and fixed stars. By a long and laborious series of mathematical investigation, he arrived at the conclusion "that the earth, once heated to any temperature whatever, and thus plunged into a colder medium than itself, Avould cool no more in 1,280,000 years, than a globe of a foot in diameter composed of the like materials, and placed in the same circumstances would in a second of time, —that is to say, in this immense time, no appreciable variation would take place." (Ann. de Chim. et de Phys. October, 1834. The absurdity of supposing that " all the caloric of the earth below the invariable stratum (which does not extend much beyond one hundred feet below the surface) comes from a central fire," is too obvious to require a serious refutation. If there have been two thousand volcanic eruptions every century, according to the estimate of Mr. Lyell, it would give 25,600,000 eruptions in 1,280,000 years: yet the temperature of the globe has not sensibly diminished in that time according to the estimate of Fourier. But if 25,600,000 volcanic eruptions, to- gether with several hundred thousand times as many hot springs, had proceeded from a central fire, the re- duction of the earth's temperature must have been enormous. It is therefore evident, that the Avhole theory is not only hypothetical, but incompetent to explain the phenomena. There is nothing so remarkable in the natural his- tory of our planet, as the great revolutions of climate AND SUBTERRANEAN CHEMICAL FORCES. 379 and organic life which it has undergone during the countless ages of the past. The most fertile imagina- tion never conceived anything so wonderful as the varied scenes which the surface of the earth has ex- hibited during different epochs, before it was inhabited by man or any of the higher orders of animals. The rationale of these mutations is by far the most com- prehensive and important problem in geology; for it involves the whole theory of organic life, and its im- mediate relation to the vast science of physical astro- nomy. The leading facts hitherto discovered may be reduced to the following general propositions:— 1. That throughout the northern hemisphere, from the shores of the Mediterranean to the north of Eu- rope and Asia, and from the southern United States to Melville Island, in lat. 75 N., the secondary forma- tions are filled with the fossil remains of plants and animals, which could have existed only in an uniformly warm climate, analogous to that of our present tropics. 2. That at different epochs, the land and sea were inhabited by totally different orders, genera and species of organized beings, which successively arose, flourished for a time and then gradually passed away, leaving only their petrified remains as a lasting record of their existence. A similar doctrine seems to have prevailed among the ancient Persians, Avho maintained that "the earth had been seven times replenished with beings different from man, and seven times depopu- lated," as Ave are informed by the Rev. Mr. Faber. (Pagan Idolatry, vol. i.) 3. That the more ancient the formations, the more simple are the organisms they contain, and the more 380 REVOLUTIONS OF ORGANIC LIFE. unlike any which now inhabit the earth,*—until we arrive at the newer secondary, in which have been found a few birds and marsupial remains. 4. That during the uniformly elevated temperature which prevailed in the middle and higher latitudes, there was a corresponding uniformity in the zoological and botanical character of the earth, from the equator to the polar regions.f * For example, from the commencement of the transition to the termination of the coal formation, (supposed to represent three subdivisions or geological epochs,) the sea everywhere abounded with encrinites, polypi, terebratulae, trilobites, orthoceratites and other testacea, with a few species of strange fishes, which seem to have been the only vertebrated animals then existing. But all of these passed away, (unless we suppose, what has not yet been proved, that they underwent a gradual change under the influence of a different climatic condition of the earth,) and gave place to animals wholly different from any that have existed since the newer secondary eras, such as the huge icthyosauri, plesiosauri, pterodac- tyli, turtles and other reptiles. As we advance toward the present epoch, we find in the older tertiary formation, the palseotherium, the anoplotherium and remains of cetacea resembling the manati. These also passed away, and were succeeded by a still greater variety of warm-blooded animals, some of which are represented by living species ; such as the elephant, rhinoceros, hippopotamus, fragments of the ape and several species of the feline genus; to which may be added the dinotherium, the megatherium, the gi- gantic mastodon and the elasmotherium, (a strange quadruped resembling both the horse and rhinoceros,) all of which belonged to the newer tertiary epoch, and which have also long since been numbered with the myriads of extinct animals. f For example, nearly all the fossil plants hitherto discovered in the older formations consisted of ferns, coniferae, equisetaceae and cycadese; which in all, comprised only about five hundred spe- cies, that presented very little diversity of form. It is even as- serted by the most intelligent botanists who have carefully examined THEORY OF MR. LYELL. 381 In his recent excellent work on geology, Mr. Lyell refers all the past revolutions of organic life to changes of climate, and the latter to geological causes alone; such as the gradual shifting of sea and land, brought about by the agency of volcanos, earthquakes, hot springs, currents and waves of the ocean, the corrod- ing action of rains, rivers, springs and chemical decom- position. But if we admit Avith Mr. Lyell, that the greater part of the dry land noAV scattered over the northern hemisphere, may have been formerly con- fined within the tropics, and the mean temperature of the whole earth thus elevated 20° or 30°, as he main- tains, it is still evident, that the polar regions would be excluded from the sun several months in the year, during Avhich time all vegetation would be arrested. Dr. Lindley observes, that "in the present condition of the earth's axis, the polar regions must have been al- Avays several months in the year exposed to darkness; a condition in which no plants can exist." Yet the the subject, that for a long period, during which the climate of the middle latitudes seems to have exceeded the present temperature of the tropics, cycadeae alone formed about one-third of the entire Flora; whereas they now constitute only one two-thousandth of the whole. But in the present diversified condition of the earth, as regards temperature, it contains about one hundred thousand species of plants, and above five hundred thousand species of ani- mals. It would therefore appear that diversity in the generic and specific character of organized bodies, depends chiefly on varieties of climate and season, which differ in all the higher latitudes, and owing to the influence of local causes, are scarcely ever exactly alike, even in the same latitudes, as will be shown in the first chapter of book v. This subject opens a vast field of inquiry to those phy- siologists who may be disposed to investigate the origin of organic species. 382 INFLUENCE OF ASTRONOMICAL CAUSES. older formations around Baffins Bay abound with tro- pical plants in the fossil state. (Fossil Flora, preface, p. xxi.) It is therefore evident, that such a climatic condition of the earth would be wholly incompatible with the existence of a tropical vegetation, which is known to require a mean temperature of about 80° throughout the year. Among all the causes which modify the temper- ature of our planet, the most influential by far is the obliquity of the earth's axis. In reality, this condi- tion determines chiefly the vast difference between the climate of the tropical, temperate and frigid zones, together with all the varieties of season. The ques- tion therefore naturally arises, whether all the great changes of climate which the earth has undergone, ♦ may not have been owing to modifications of the same cause, such as variations in the inclination of its axis, or even a gradual transposition of the equator and poles ? In support of this natural view of the subject, it may be observed, that the successive generation and extinction of tropical plants and animals in the higher latitudes, would seem to require the repeated occur- rence of such astronomical changes, which, in their turn, afford a complete explanation of all the phe- nomena. And that such changes are not inconsistent with the laAvs of nature is evident from the various degrees of inclination in the axis of different planets. Some astronomers have maintained, that the axis of Yenus is inclined to her orbit 75°. Should this be actually verified by future observations it will follow, that her polar circle extends into the tropics, Avithin 15° of the equator, and that her tropics extend to the INFLUENCE OF ASTRONOMICAL CAUSES. 383 frigid zone, within 15° of the poles, so as to cause the annual extremes of winter and summer from the tro- pical to the polar regions. It has been often asserted by writers on astronomy, that great changes in the planetary inclinations would be inconsistent with the stability of the system,—as if all the operations of the universe were not maintained by unceasing changes and revolutions. But, as Mr. Whewell observes, " the cause of perturbation has the whole extent of time to work in," there is reason to believe, that in the progress of long astronomical cycles, every part of the earth has successively been exposed to a vertical sun, and that such changes are absolutely essential to the conservation of the system in its existing state. For if the equatorial protube- rance of the planets be owing to the greater amount of light which falls upon the tropics than upon the higher latitudes, it is obvious that they would in time lose their present spherical forms, by which their ro- tary motions would be deranged,—unless prevented by a gradual transposition of the equator to higher latitudes, or even to the polar circles. And that such a transposition has actually taken place, is strongly corroborated by the high and uniform temperature which prevailed throughout the middle and higher latitudes of the northern hemisphere when it was the abode of tropical plants and animals. Nor is it less obvious, that if the inclination of the earth's axis should go on augmenting from 0° to 40°, there would be such a general refrigeration, as Avould destroy nearly all the pre-existing organisms of the middle latitudes,—when the mountain valleys wTould 384 THEORY OF M. AGASSIZ. be filled with ice, perhaps to the level of the sea, as in Greenland, Spitzbergen and the southern polar con- tinent. In short, there would be what has been called the Glacial Period by Dr. Louis Agassiz, Avho has traced the evident marks of moving glaciers on the polished and scoriated rocks of Switzerland, the Tyrol, Germany, Scotland, Ireland, England and France. And they have since been observed in the United States.* If we extend our view to the solar system, we per- ceiA'e that floods of ethereal matter, in the form of light, are perpetually flowing from the sun, and keep- ing the air, the ocean and the earth, in a state of unceasing circulation—converting solids into liquids, gases and vapours, which are successively changed into plants and animals. The atmosphere is continu- ally Avasted by oxidation, combustion and the respira- tion of animals. But is it not as constantly repro- * I cannot, however, agree with M. Agassiz, that during what he calls the glacial period, the whole surface of the earth pre- sented a vast field of ice, from which projected only the highest mountain ridges; nor that a cold by which every living being was benumbed, suddenly appeared, and destroyed the myriads of or- ganisms which but a moment before had been enjoying existence; because it is impossible to account for such " a catastrophe" in accordance with any of the known laws of nature. For example, whence came all the waters required to produce a field of ice many thousand feet in thickness ? And what had become of the heating power of the sun, when the earth was seized with that sudden Jit of the ague ? Yet there is ample proof, that immediately ante- cedent to the existing order of things, a climate of polar severity prevailed throughout the middle latitudes of the northern hemi- sphere, and quite sufficient to destroy nearly all the pre-existing orders of tropical plants and animals. SUBTERRANEAN CHEMICAL FORCES. 385 duced by vegetable and animal decomposition? and are we not authorized to conclude, that if the whole atmosphere were annihilated, it would be again repro- duced? or that if all the waters of the ocean were extinguished, they would be gradually regenerated by igneous chemical agency? Wherever there is chemical action there must be liquids and gases generated.* During respiration and putrefaction carbonic acid is generated, the appropriate food of living vegetation, which returns a portion of oxygen to the atmosphere under the influence of solar light. During the decom- position of organic matter, a portion of atmospheric oxygen combines with its hydrogen, forming water,— and so on through all the endless ramifications of na- ture, Ave perceive that death is only a transformation of matter, by which the earth is perpetually renovated, and crowned with immortal beauty. * Hence the improbability of the astronomical hypothesis, that the moon, Vesta and some other planets, have no atmospheres; or that the atmosphere of Ceres is more than 668 miles high, and that of Pallas 465 miles, according to the observations of Schroeter and others. 25 CHAPTER Y. HYPOTHESIS OF TWO ELECTRIC FLUIDS. Is the electric fluid one and the same in all bodies? or is it a compound fluid? Each of these hypotheses has been zealously maintained since the time of Dufay and Franklin. But the controversy has consisted rather in pointing out frivolous distinctions in the phenomena produced, than in tracing the fundamental laws by which they are governed. After a patient examination of the facts adduced by the British and continental philosophers, I have not been able to dis- cover any decisive evidence that there are Iavo elec- tricities. On the contrary, it might as well be main- tained that there are fifty, or an indefinite number; for this protean agent exhibits an endless diversity of appearances and effects under different circumstances, according to the various bodies from which it is ob- tained, the mode of its development, &c. It was discovered by Dufay, about a century ago, that when glass, rock crystal, diamond, precious stones and many other substances, were warmed and rubbed with silk or woollen cloth, they repelled light bodies in their vicinity; but that when resinous bodies were made electric by friction in the same manner, they attracted light bodies which had been electrified by (386) HYPOTHESIS OF TWO FLUIDS. 387 excited glass. Having caused a piece of gold leaf to be repelled, and suspended in the air by an electrified glass tube, and meaning to chase it about the room by a stick of excited gum copal, he found that, instead of being repelled by it as it was by the glass tube, it was eagerly attracted. From which he concluded that there were two kinds of electricity, residing in two dif- ferent classes of bodies; one of which he termed vitreous, and the other resinous,—and that bodies charged with either kind repel bodies charged with the same kind, but attract bodies charged with the other kind. But when it was afterwards discovered by Dufay, that all bodies acquired the power of attracting and repelling the same substances, according to the manner in which they were electrified, he frankly acknowledged that vitreous and resinous electricity were only different degrees of one and the same fluid. (Priestley s Hist, of Electricity, pp. 43 and 412.) Yet the doctrine of two electricities has been constantly imputed to Dufay by nearly all writers on the subject for the last seventy years.* It is said by those who still maintain the doctrine of tAvo fluids, that if the gold leaves of an electrometer are made to diverge by means of an electrified stick of resin, they will collapse on the approach of an ex- * It is related by Yan Marum, that the doctrine of two electric fluids became general in France from the fact, that M. Hauy was ordered by Napoleon to prepare a treatise on natural philosophy for the use of the Polytechnic School, and not having time for re- flection, he hastily adopted Coulomb's version of the two fluids. Well might Count Oxenstiern say to his son, "Come and see with how little wisdom the world is governed!" 388 HYPOTHESIS OF TWO FLUIDS. cited glass tube; when all signs of electricity disap- pear as if annihilated. Nothing could be more falla- cious than such experiments; for I have often found, that after the gold leaves were made to diverge by excited glass, they expanded still further on the ap- proach of excited wax, and vice versa. The result is evidently modified by the degree of friction employed, and by the quantity of electricity thus disengaged. It was long since observed by Dr. Watson, that the rubber of a common electrical machine, exhibited the same electricity in all respects as that which had been produced by the friction of sealing-wax, sulphur, rosin, &c, and afterwards by Canton, Franklin, Beccaria and Wilson, that whenever two vitreous bodies were equally electrified they repelled each other, but when unequally, they attracted each other; and that the same Avas true of resinous bodies. Dr. Franklin also found, that when glass globes were excited by friction, the spark was larger and longer than when a sulphur- ous globe was used, and made a louder noise; from which he inferred that the glass contained on its surface more electricity than sulphur ; he therefore denominated that of the glass plus or positive, and that of the sul- phur negative—terms which are now in general use. He might have added, that positive electricity gives larger and more divergent brushes of light than nega- tive, on presenting a metallic point to the prime con- ductor of a machine in action. It was subsequently ascertained, that whenever two different bodies are rubbed against each other, they are in different states of electricity—that when a glass tube is rubbed with a dry silk handkerchief, the former HYPOTHESIS OF TWO FLUIDS. 389 is rendered positive and the latter negative; but if an insulated metal be brought near to the glass, the latter becomes negative and the metal positive. Hence it was concluded by Franklin, that during the action of a common machine, electricity is evolved from the rubber, and attracted by the cylinder of glass, from which it is attracted by the prime conductor, and thence to other conducting bodies. When amber and the tourmaline are rubbed together, the latter becomes plus or positive in relation to the amber; but Avhen the tourmaline is rubbed against the diamond, it is minus or negative, and the diamond positive—and so of many hundred other bodies. The above facts are exceedingly important, and are alone sufficient to prove that positive and negative are only different degrees of one and the same fluid, which accumulates in various proportions on different bodies, according to the relative degrees of their attraction for it. There are no two bodies in nature which have the same degrees of attraction for electricity; nor are there any two bodies which exhibit the same electrical state when rubbed against each other. It has even been found that the same bodies exhibit positive or negative electricity according to their colour, or the condition of their surface—that smooth glass is rendered posi- tive by friction with woollen cloth, and negative when made rough by grinding it with emery, all other things being equal.* * Is not the attraction of rough glass for electricity less than that of smooth glass, for the same reason that caloric escapes more rapidly from rough than from smooth metals? and does it not ac- 390 HYPOTHESIS OF TAVO FLUIDS. It cannot be denied that the electricity of a common machine is derived chiefly from the rubber; for it is Avell known that its quantity is greatly increased by spreading over the rubber an amalgam of zinc or tin, the oxidation of which supplies electricity freely, as in the action of a \roltaic battery; while amalgams of silver and platinum, which do not oxidize at ordinary temperatures, are of no use. But is it not evident, that if the prime conductor receive its electricity from the rubber, that positive and negative are only dif- ferent proportions of the same fluid ?—that it accumu- lates and becomes plus on the prime conductor, because of its greater attraction for it?f—and that whether positive or negative, its essential properties are the same under all circumstances ? Is it not owing to the attraction of metals for electricity, that during the concretion of melted sulphur, chocolate, calomel and glacial phosphoric acid from a state of vapour, in in- sulated metallic vessels, the latter become electrified plus, and the former minus? It was before stated, that the more oxidizable metal in the galvanic circle furnishes positive electricity in relation to the less oxidizable one, which is in direct opposition to the theory of two fluids. M. Becquerel cumulate upon insulated metals in greater quantities than on elec- trics for the same reason that the former are good conductors? (See page 183.) ■f* Something analogous takes place during the action of the galvanic pile. When the battery is composed of zinc and silver, and immersed in an acid solution, the zinc is oxidized, by which electricity is disengaged, and passes to the silver, which is rendered positive; while the zinc, like the rubber from which the electricity proceeds, is negative. HYPOTHESIS OF TAVO FLUIDS. 391 regards it as a proof of tvvo galvanic fluids, that posi- tive electricity permeates imperfect conductors more readily than negative. But this is just what might be expected from the plus and minus conditions of the same agent. In accordance Avith this view, it has been found that, other things being equal, the heating effect of voltaic electricity is in proportion to its quantity, and that the heating effect of positive electricity ex- ceeds that of negative. It was maintained by Winterl, CErsted, Berzelius, and at one time by Davy, that heat and light Avere produced by the union of positive and negative elec- tricity. After what has been already offered in regard to the relations of caloric and electricity, it would be useless to multiply arguments against so bald an hy- pothesis. It Avas afterwards shown by Sir Humphrey Davy himself, that both heat and light are produced by either positiA^e or negative electricity alone, though he adopted the doctrine of two fluids. The following experiments of De Saussure clearly illustrate the identity of positive and negative, with plus and minus conditions of the electric fluid. On pouring water into heated iron or copper vessels when insulated, and connected with an electrometer, rapid oxidation was produced, and positive electricity evolved; but after the metal became covered over with a coating of oxide, less electricity was disen- gaged, Avhich Avas negative. (Voyages dans les Alpes, tome ii. p. 244.) It is also worthy of special notice, that he procured electricity from the vapour of water without any che- mical decomposition—a fact which has been recently 392 HYPOTHESIS OF TWO FLUIDS. controverted by Pouillet, as before stated, (page 292;) that the evaporation of water from heated silver and white porcelain vessels was attended Avith a disen- gagement of electricity, that was generally positive, but sometimes negative. The same thing Avas ob- served on placing incandescent pure white quartz in water. The advocates of the theory of two fluids explain the phenomena of electrical attractions in a singularly gratuitous manner. They say that when an electrified glass tube or stick of Avax is brought near to light bodies, it communicates to them the opposite electricity from its own; and that they are brought together by the mutual attraction of the two electricities for each other—that when they touch the excited electric, they acquire the same kind of electricity which it has, and consequently are repelled. (Thomson on Heat auel Electricity, p. 362.) It might as well be said, that liquid metals attract the same metals when solid, be- cause they are in opposite states of electricity; or that the attraction of the living body by frozen mercury is owing to the combination of the former with positive, and the latter with negative electricity; and that the effect is produced by the mutual affinity of the tAAro fluids: whereas I have proved that the attraction of frozen mercury, and other cold metals, for the living body, is in proportion to their affinity for caloric, which is plus in the one, and minus in the other; and that all such phenomena are owing to the attraction of ca- loric and electricity for ponderable matter. The whole train of Dr. Thomson's reasoning in favour of two fluids is founded on groundless assump- HYPOTHESIS OF TAVO FLUIDS. 393 tions. 1. That there is no attraction between electricity and ponderable matter; 2. That there is ein attraction between positive and negative electricity; 3. That matter does not repel matter; and 4. That nothing but the pres- sure of the ambient atmosphere prevents the escape of elec- tricity from bodies. (Idem, p. 424.) Feeling some doubt in regard to the last position, he elsewhere speaks of "the unknown cause which prevents it from leaving them." (Page 431.) Dr. Thomson maintains, that "matter does not repel matter, because, in the motions of the heavenly bodies, no such repulsion has ever been observed,"—from which it would seem that he denies the existence of a repulsive agency in nature. Having assumed the above premises, he adds:—"If matter does not repel matter, and if there does not exist any attraction or affinity between electricity and matter, then the Franklinian theory of positive and negative electricity cannot be correct." (Page 425, on Heat and Electricity.) In accordance with the hypothesis, that there are two electric fluids which have a mutual attraction for each other, it has been maintained by several writers on natural philosophy, that when a cloud passes over a mountain, or any other portion of the earth, it com- municates to the mountain, &c. the opposite electricity from its own, when the two fluids attract each other, producing a discharge of lightning. Such is the mystic jargon of which this great and beautiful science is composed at the present day. The truth is, that, not- withstanding the many new facts which have been discovered within the last thirty-five years, the theory of electricity is far more unintelligible than it was left 394 HYPOTHESIS OF TAVO FLUIDS. by Franklin, Canton, Wilson, Beccaria and Priestley; for they did recognize the important fact, that all the attractions and repulsions produced by electricity are OAving to its affinity for common matter, and repulsion of its own particles. Many of its phenomena are yet involved in profound obscurity. We know not Avhy it is, that Avhen an insulated oblong conductor is brought near to an electrified body, the end nearest to it becomes negative, and the opposite end positive, Avhile in the centre there is no sign of electricity. We do not comprehend clearly why the electricity of a large battery, or of an immense mass of aqueous va- pour, becomes concentrated into a spark or ball of fire. If, however, it be true, that all the forms and modi- fications of this mysterious agent are convertible into caloric, the theory of both will be greatly simplified, and must shortly be reduced to a very few fundamen- tal axioms. I have proved from the most elaborate series of ex- periments on record, performed by De Saussure and Read, that all atmospheric electricity, even that of the most serene Aveather, is disengaged from aqueous va- pour; and by the experiments of Dalton, that caloric is the true and only cause of evaporation. There is also a perpetual flux and reflux of the electric fluid, corresponding with the diurnal variations of temper- ature, and fluctuations of the barometer. According to De Saussure, it diminishes from nine or ten o'clock in the morning until five or six p.m., and increases until eight, when it again decreases until sunrise, when it is almost null; that is, it is most abundant when the vapour of the air is undergoing condensa- THEORETICAL VIEWS OF CALORIC AND ELECTRICITY. 395 tion, (for the same reason that it is plus or positive during the formation of clouds, and during rain or snow;) but diminishes during the heat of the day, Avhile the vapour of the air is undergoing expansion; by which it is connected with the Avhole theory of evaporation, condensation and lightning. It is fur- ther stated by De Saussure and many others, that atmospheric electricity is constantly changing from positive to negative, which is also quite inconsistent Avith the hypothesis of two fluids. It is only by extending our knoAvledge of nature, that Ave are enabled to trace an endless diversity of apparently isolated effects to some principle which connects and governs them; or to distinguish an un- known cause from the individual and ever-varying phenomena it produces. The most signal and delight- ful triumphs of philosophy spring from the perception of analogies that seem remote and obscure, until closely analyzed. From the imperfect outline which has been already presented of this vast and compli- cated subject, it is obvious that all the operations of nature are so intimately connected, that we cannot make any substantial progress in the discovery of general principles without ascending to the primary source of all physical power. I have shown that nearly all the most distinguished philosophers, ancient and saodern, have recognized the existence of such an agent. It was the mP xaSapom of Hippocrates—the ^ of Aristotle,—or the form of forms,—by which he meant the cause of causes— the anlma mundi of the Romans—the archceus of Para- celsus and Van Helmont—the materia subtilis of Des- cartes—the pneumatical power of Bacon—the phlogis- 396 ANALOGIES OF CALORIC AND ELECTRICITY. ton of Beccher and Stahl—the electric fluid of Franklin, Priestley and Beccaria—the latent heat of Dr. Black— and the caloric of modern times. ANALOGIES OF CALORIC AND ELECTRICITY. It has been shown throughout the preceding portion of this work, that all the motive poAvers of caloric are resolvable into the primary and universal law by Avhich it repels its own particles, and attracts those of ponder- able matter, with forces that vary inversely as the squares of the distance. The phenomena of electrical attractions and repul- sions are clearly resolvable into the same law. It would be a needless waste of time to bring for- ward the numerous proofs, that all the forces of at- traction and repulsion are inversely as the squares of the distance. It has been demonstrated by Buffon, Laplace, Coulomb and other philosophers, that the power of all emanations, such as light, caloric, and electricity in the diffused state, are subject to the same law, like that of gravity. The ringing of electric bells, the dancing of pith balls under an electrified tumbler, of paper images, and many other similar experiments, performed for the amusement of popular assemblies, are referable to the above law. When light leaves of gold, copper, silver, zinc, &c. are brought near to the wire that connects the extremities of a battery in ac- tion, or to insulated metals when electrified by a com- mon machine, they are attracted by them. When treating of chemical attraction, (book ii. chap, ii.) it Avas shown that caloric causes oxygen to ANALOGIES OF CALORIC AND ELECTRICITY. 397 combine with all other elements, from the slowest pro- cess of oxidation, as in the rusting of metals, fermenta- tion, &c. to the most rapid combustion. Electricity produces the same effects. It was first observed by Dr. Franklin, that when iron or steel wires were sub- mitted to a few electrical shocks, they became covered over with a coating of rust. Dr. Priestley observed the same effect on other metals; after which Cuthbertson proved, by a great variety of experiments, that all the knoAvn metals might be rapidly oxidized by common electricity—even gold and platinum, which are difficult to oxidize by the ordinary modes of applying heat. By the attraction of caloric for ponderable matter, it combines with various solids, produces their fusion, and causes them to cohere with each other. By its repulsion of its own particles, it decomposes oxides, chlorides, iodides, bromides, alloys and all other com- pounds. The same is true of electricity, which dissolves and decomposes the most refractory bodies, such as the earths, alkalies, and all other metallic oxides, and again causes their elements to recombine. In short, there is no combination or decomposition which may not be effected by either caloric or electricity, when sufficiently concentrated, and in due proportions. When treating of cohesion, it was shown that ca- loric has various degrees of attraction for different bodies; and that their conducting poAver is in propor- tion to that attraction,—that the lightest knoAvn solids give out large quantities of caloric during combustion, and are bad conductors; while metals and other dense bodies that evolve much less caloric, are good con- 398 ANALOGIES OF CALORIC AND ELECTRICITY. ductors,—and that, other things being equal, the con- ducting power of metals is augmented in proportion as they are deprived of caloric. It is also known that the lightest solids, cceteris pari- bus, afford the largest amount of electricity by friction, —and that they are bad conductors of electricity. It was further ascertained by Sir H. Davy, that the con- ducting power of metals for voltaic electricity is dimi- nished in proportion to the elevation of their tem- perature, (Phil. Trans. 1821;) and I have shown that their cohesion is diminished in the same ratio. It is therefore evident, that the conducting power of bodies for both caloric and electricity is modified by every alteration in the relative proportions of ethereal and ponderable matter of which they are composed; and that as a general rule, with few exceptions, the same bodies are conductors and non-conductors of both.* (See Theory of Conduction.) It may be observed, that no two series of experi- ments, hitherto instituted for the purpose of ascertain- ing the relative degrees of cohesion and conducting power of the different metals, have presented the same results. It is however certain, that copper, gold, silver, platinum, iron and zinc, are the best con- * It may be objected, that some bodies which are non-conductors of electricity when solid, become conductors in the liquid state. But it is doubted by Dr. Faraday whether such bodies ever do conduct electricity without undergoing decomposition, as he found that, whenever they act chemically on the plates of a battery, elec- tricity is disengaged. Query. Is it not more probable that the non-conducting power of such bodies in the solid state is owing to the crystalline arrangement of their particles, as in the form of ice or snow ? (See page 179.) ANALOGIES OF CALORIC AND ELECTRICITY. ductors of electricity,—and it has been shown by M. Becquerel, that potassium is of all others the worst conductor. (Ann. de Chim. et de Phys. xxxii. 420.) In opposition to the simple and rational theory of Franklin, Canton, Wilson and Beccaria, that elec- tricity repels its own particles, and is attracted with various degrees of force by different species of pon- derable matter, it has been maintained by Coulomb, Poisson and other philosophers, that there is no affinity between electricity and ponderable matter,—and that it Is confined to the surface of bodies by the pressure of the atmosphere. Nothing could more clearly illustrate the tendency of mankind to take things upon trust, and Avithout examination, than the general adoption of this partial and erroneous doctrine by numerous modern writers on physical science. It seems to have been founded chiefly on the fact, that electricity escapes from the surface of bodies more readily in vacuo than under the pressure of the atmosphere. But it has been demon- strated by Morgan, Cavallo, Ampere and Sir Hum- phrey Davy, that electrical attractions and repulsions take place in vacuo as well as under the pressure of the atmosphere. (See Philosophical Transactions for 1822, where the experiments of Davy are recorded.) It is very true that electricity, in the diffused state, moves more freely over the surface of bodies than through their substance; and that atmospheric air, Avhen perfectly dry, assists in preventing its escape from other bodies, because it is a bad conductor. It was before stated, that an electric spark expands in an exhausted receiver into a diffused lambent light; and 400 ANALOGIES OF CALORIC AND ELECTRICITY. Mr. Harris of Plymouth, has proved that the striking distance of the spark varies inversely as the density of the air through which it passes, the charge being the same. But these experiments afford no proof that electricity is not attracted by ponderable matter. The important practical application of metallic conductors, as lightning rod's by Franklin, was founded wholly on their attraction for the electric fluid. It never entered into the imagination of that eminent philosopher, that flashes of lightning are determined to the earth and its conductors by the pressure of the atmosphere. That electricity, when concentrated, is capable of passing through the substance of bodies, was proved seventy years ago by M. Jallabert of Geneva, who found that it might be readily transmitted through metals, covered over with pitch. (Priestley s Hist, of Electricity, p. 127.) But the same thing is fully de- monstrated by the fusion of metals, rocks, gems and all other bodies by lightning and other forms of elec- tricity, and by the transmission of shocks through liv- ing bodies. Notwithstanding the mathematical demonstrations of the Coulombian theory, it is founded on hypothetical and false assumptions; and, when applied to the ex- planation of natural phenomena, is evidently of no practical value. It is therefore not surprising, that Sir John Leslie should have observed, in his History of Physical Science, that it deserved the Dunciad. To trace the analogies of caloric and electricity through all their diversified manifestations would be an endless task. They are both disengaged from all bodies by friction, pressure, percussion and by chemical ANALOGIES OF CALORIC AND ELECTRICITY. 401 action; but vary according to the manner in which the operation is performed. It was proved by Becquerel, that the intensity of electricity evolved by pressure was in proportion to the force employed; from which it would seem, that, Avhen the particles of bodies are forced nearer together suddenly, a portion of their latent caloric is disengaged in the concentrated form. The greatest of all mysteries connected with elec- tricity is the protean poAver by which it assumes an endless variety of forms, under different circumstances. We have seen that voltaic electricity, evolved from a single pair, or from a few series of large plates, with an Interposing liquid, differs greatly from that which is obtained from a battery composed of the same ma- terials, but consisting of a great number of smaller plates; and the latter is equally different from the electricity of the atmosphere, or that procured from a common machine. In fine, these differences are as numerous as the circumstances are various under Avhich the phenomena take place. What then?^ Shall Ave assume the existence of an indefinite variety of electric fluids? Nothing could be more in opposition to the fundamental laws by which they are governed. It has been supposed that electricity is far more subtile and refined than caloric, because of the ease and rapidity of its passage through metals and other conductors. This is a partial view of the subject; for caloric passes freely through mica, glass and some other transparent bodies, which arrest the electric fluid when in the concentrated form. Nor i^ it true that glass is altogether impervious to the electric fluid. Compared with lac, it may be regarded as a conductor; 26 402 MECHANICAL AGENCIES OF for electricity produces attractions and repulsions through glass. If a small pith ball be suspended within a glass jar by a fine silk thread, it Avill be at- tracted by an electrified glass tube on the outside. It is further stated by Dr. Priestley, that electricity es- capes through some species of glass, like water through a sieve. (History of Electricity, p. 592.) Besides, if a metallic wire be inserted into a glass receiver exhausted of air, and connected Avith an electrical machine in action, a stream of electric light is seen to proceed from the Avire in a straight line to the plate of the air- pump ; but if a conductor be presented to the side of the glass, the electric light is drawn toward it, which sIioavs that electricity is attracted through glass. The same thing is true, to a certain extent, of sealing-wax, as shown by Dufay a hundred years ago; it is there- fore evident, that all bodies are permeable to this sub- tile ether. The rapid passage of electricity through conductors, and its power of communicating a shock, are the most remarkable properties which distinguish it from ca- loric. But this difference A7anishes when we perceive that it is only electricity of a peculiar tension or con- centration that exhibits these powers, and that many of its forms produce no such effects. That the pas- sage of electricity through living bodies, without pro- ducing the sensation of heat, is chiefly owing to its velocity, would appear from the fact, that a spark from a Leyden battery may be passed through gun- poAvder Avithout igniting it, unless retarded in its pro- gress by an imperfect conductor, such as water, Avhen it inflames gunpoAvder. When electricity of high ten- CALORIC AND ELECTRICITY. 403 sion passes without interruption through conductors, it does not heat them; whereas, if they be too small to allow its free passage, or if the conductors be im- perfect, they are heated, fused and volatilized. The same is true of solar caloric, when concentrated by a large burning-glass; for it passes through water and other transparent substances without heating them; but if made to act on bodies that obstruct its passage through them, they are fused, ignited and dispersed in the form of flame. It has been a leading object of this inquiry to show how partial and erroneous is the prevailing notion, that the agency of caloric is limited to the production of temperature, liquefaction, combustion, &c. It is in its power of producing motion, and of maintaining the harmonious action of all the elements, that we are to seek for the laws which connect it with the science of universal nature. We have seen its mechanical agency in steam; which has given to man a poAver over matter superior to all the achievements of ancient or modern times, —in gunpowder and other fulminating compounds,— in volcanic eruptions,—and in that process of evapo- ration by which the rains of heaven are distilled from the ocean, transported through the atmosphere, and deposited in fertilizing shoAvers,—that it holds together the atoms of solids with inconceivable force, and dis- aggregates them with equal force,—in short, that it is the executive principle in creation. The mechanical agency of electricity is equally striking, though less constantly exerted. It over- comes the cohesion of all bodies, Avhether simple or 404 MECHANICAL AGENCIES OF compound, and acts equally on particles or masses. It transports the different elements of bodies to op- posite poles of the battery. Acids may be conveyed through alkalies, and alkalies through acids, to their respective poles without neutralizing each other. It has been shown by M. Fusinieri, that electric sparks issuing from the brass conductors of ordinary machines contain incandescent particles of zinc and copper. When draAvn from silver, they contain impalpable particles of silver, that may be seen with a good microscope, and discovered by chemical tests. When a spark issuing from a knob of gold passes through a plate of silver, a circular spot or stratum of gold is seen on the surface of the plate where the spark en- tered and emerged, which soon volatilizes and disap- pears; and when it issues from a ball of copper, similar phenomena occur. The spark also acquires new particles from the metal through which it passes. In all such cases, the colour of the spark depends on the nature of the metal thus ignited—from Avhich Fusinieri concludes, that electric light is always com- bined with ponderable matter; and that lightning OAves its luminosity and odour to the combustion of such matter. (Giornale del Pavia, 1825.) Dr. Priestley relates, that when the steeple of St. Bride's Church in London was torn by a flash of light- ning, it acted as an elastic fluid; and that its effects were exactly similar to what would have been pro- duced by gunpowder pent up in the same places and exploded. It is also related by Mr. Lyell, on the authority of CALORIC AND ELECTRICITY. 405 Dr. Hibbert, that at Funzie, in Fetlar, one of the Shet- lands, about the middle of the last century, a rock of mica schist, one hundred and five feet long, ten feet broad, and in some places four feet thick, was torn in an instant, by a flash of lightning, from its bed, and broken into three large and several smaller fragments. One of these, twenty-six feet long, ten feet broad and four feet thick, was simply turned over. The second, Avhich was twenty-eight feet long, seventeen broad and five in thickness, was hurled across a high point, to the distance of fifty yards. Another broken mass, about forty feet long, was thrown still farther in the same direction, quite into the sea, while many smaller fragments were scattered up and down. (Principles of Geology, vol. i. p. 260.) A similar effect of lightning wras related, not long since, in the German papers. It was stated that an enormous rock had been removed from the bed of a stream in Prussia, by boring a deep hole in it, into which was inserted a bar of iron tAventy-eight feet long. The consequence was, that soon after, during a thunder-storm, the lightning was directed to the bar, and the rock shattered to fragments. It would be useless to dwell on the mechanical effects of elec- tricity in rending rocks, trees, buildings, &c, were it not that there are still many writers on natural phi- losophy, who affect to doubt its materiality; and some Avho resolve it into undulations of the unknown ether, —as if it could not be bottled up in a Leyden battery like water or any other material fluid,—or as if it did not act upon the sense of sight, hearing, feeling, smell- 406 EXPERIMENTS OF DR. FARADAY. ing and even of taste, like other material agents; and as if undulations were capable of causing horizontal, vertical and rotary motion. It was shown in book ii. chap. ii. that, other things being equal, the chemical effects of caloric are uniformly In proportion to its absolute quantity. It has also been shown by Davy, Children and many other modern experimenters, that both the heating and chemical powers of voltaic electricity are in direct proportion to its quantity; and that the quantity evolved is in proportion to the amount of chemical action; corresponding with the universally acknow- ledged fact that the heat of combustion is in the same ratio. Without deciding wmether electricity be a material agent, sui generis, or mere motion of ordinary matter, Dr. Faraday maintains, that " the atoms of matter are in some way endowed or associated with electrical powers, to which they owe their most striking quali- ties, and among others, their mutual chemical affinity," —and he has endeavoured to ascertain experimentally, the absolute amount of this agent, motion or power, which is associated with the particles or atoms of mat- ter. He found that uone grain of water required an electric current to be continued for three minutes and forty-five seconds to effect its decomposition; Avhich current was powerful enough to retain a platinum wire ik of an inch in thickness, red hot in the air, during the whole time." He therefore concluded, that an equal quantity of electricity is employed in holding the particles of one grain of water together; and that it is probably equal to a very poAverful flash EXPERIMENTS OF DR. FARADAY. 407 of lightning. (Experimental Researches in Electricity, sixth series, Phil. Transactions, 1834.) He adds, in another section, (873,) that "the che- mical action of a grain of Avater upon four grains of zinc, can evolve electricity equal in quantity to that of a powerful thunder-storm." If this inference were Avell founded, the chemical action of a pound of water upon four pounds of zinc, would afford as much electricity as many thousand thunder-storms,—each of Avhich is often attended with from twenty to fifty or more flashes of lightning; so that if the doctor should devise a mode of disengag- ing it in the concentrated form and in rapid succes- sion, his experiments would eclipse the thunders of Jove. But this is not the climax of modern discoveries: for if we are to credit the account of Professor Ritchie, "Dr. Faraday has found from a recent experiment that, by the action of electricity on a copper Avire, as much light was given out in the course of a few days, as could be emitted from the sun in a year." (Records of Science, vol. i. p. 315.) And that this miraculous story was not intended as a satire, would appear from the gravity Avith which Dr. Ritchie adduces it " as a strong argument in favour of the undulatory theory of light,"—of which he was known to be a strenuous advocate. Nor is it easy to comprehend the philo- sophy of Dr. Faraday when he says, that "gravitation is a certain property of matter, dependent on a cer- tain force, and it is this force which constitutes the matter." (Phil. Mag. 1844.) At the time this neAv definition of gravitation and matter appeared, a mecli- 408 ELECTRIC LIGHT. cal gentleman of London was asked his opinion of its meaning, to Avhich he frankly replied that he "did not profess to understand it," adding, hoAvever, that " Dr. Faraday doubtless understood himself." But I must return to my subject. Like caloric, we have found that electricity fuses the most hard and refractory bodies. As an example of this, we are informed by Becquerel, on the authority of Dr. Fiedler, that in eastern Prussia and Silesia, large glass tubes are frequently found in banks of sand, from twenty to forty feet in length, formed by the sudden fusion of silicious matter by flashes of lightning; and, as might naturally be supposed, that the inner surface of these fulminary tubes is smooth, while the outside is rough. In regard to the mechan- ical effects of lightning in rending trees, displacing large rocks and perforating the walls of buildings, the community is generally more or less informed. Again, like caloric, electricity expands cdl bodies Into flame or light. But Sir I. Newton, and after him Sir H. Davy, defined flame as gaseous matter raised to a red or white heat: from which it would seem that they both regarded flame as a solution of ponderable matter. And I have already shown that all bodies may be converted into light, whether by heat or elec- tricity; and that its colour varies according to the nature of the ponderable matter employed;* that * Much additional information might be obtained on this im- portant subject, by submitting all the elements of ponderable mat- ter to the agency of voltaic electricity, separately in succession; and by analyzing their light with a prism, or by causing it to pass through differently coloured transparent media. CAUSE OF MAGNETIC POWER. 409 potassium, strontium, lithium, boron and some other bodies, burn with a red light; chloride of sodium, with an orange light; oil, tallow and resins, with a yellow light; hydrogen and some others, blue light; and iodine, violet light,—but that when different elements are burned together, the result is a compound light, A\rhich may be decomposed by a prism into different primitive colours like the solar rays—in short, that there is no essential difference betAveen electric light and that of ordinary combustion,—and that electricity is never luminous or visible, except when in a state of combination with ponderable matter, as maintained by Fusinieri. Since the discovery of CErsted, that a metallic wire which connects the extremities of a voltaic battery in action, is capable of deflecting a magnetic needle placed near it from its ordinary position; and of Davy and Arago, that it is capable of attracting iron filings dur- ing the passage of an electric current through it, phi- losophers have seemed to suppose that the production of magnetic effects was a peculiar and distinctive attribute of electricity. But if it were established, that electricity is a distinct fluid, sui generis, it is nevertheless demonstrable, that caloric is capable of producing magnetic phenomena in a still more remark- able and universal manner—and that electricity of high tension, which produces a shock, and darts through metals with the greatest velocity, produces very feeble and partial effects on the magnetic needle, during its passage through a multiplying Avire. It was first remarked by Davy, that the magnetic influ- ence of a voltaic current was in proportion to the 410 MAGNETIC EFFECTS OF heat deAreloped in the wire connecting the extremities of the battery. (Philosophical Transactions, 1821.) And it is' now universally known, that batteries com- posed of a feAv large plates of zinc and copper, or even of a single pair of plates, are the best adapted for ex- hibiting magnetic phenomena—in fine, that the mag- netic power of voltaic electricity is proportional to the quantity evolved, and inversely as its tension or power of communicating a shock—that thermo-electricity which affords none of the usual signs of common electricity, such as diverging the gold leaves of an electrometer and passing rapidly through conductors, deflects a delicate magnetic needle. It was long since observed by M. CErsted, that common electricity passed too rapidly through metallic Avires to affect the needle —an hypothesis which has been confirmed by M. Col- ladon of Geneva, who found that when the wire was covered with three folds of silk, (which must have retarded the velocity of the electric current through it,) the needle was deflected as by a current of Aroltaic electricity. . The most important application of Oersted's dis- covery was the invention of what has been termed an electric multiplier or galvanometer, by M. Scrnveigger of Halle, which has been variously modified by other philosophers. Before the invention of this beautiful instrument, a prepared frog was considered the most delicate test of galvanic electricity. But it has been found, that the multiplier is not only a far nicer test of electricity, but that it is also the most delicate thermoscope ever invented—that one fiVe-hundredth part of a degree of Fahrenheit's thermometer produces CALORIC AND ELECTRICITY. 411 a sensible movement of a small needle suspended by a fibre of silk. From Avhich it folloAvs, that magnetic phenomena are not confined to the action of electricity, but also result from the agency of caloric in quantities too small for measurement by any other test. It is, therefore, not a little surprising, that when Dr. Faraday offered as a proof, that all the varieties of electricity are essentially the same, because they all produce magnetic effects, that he did not recognize the identity of caloric and electricity. Guided by the general fact discovered by GErsted, that a magnetic needle placed over the Avire connect- ing the poles of a battery in action has a tendency to arrange itself at right angles to the conducting wire, Schweigger covered a common brass Avire Avith silk thread, for the purpose of insulating it. This wire was then Avrapped round a piece of wood, 50, 100 or 200 times. When its two extremities were connected Avith the poles of a battery in action, the galvanic cur^ rent passed through all the windings of the Avire, by which the magnetic effects Avere multiplied with every turn of the wire; so that Avhen a magnetic needle Avas suspended in the middle of the hank of Avire, it was placed at right angles to it. In this way the power of the multiplier was made to detect, not only minute portions of electricity that could not be otherwise ap- preciated, but the smallest changes of temperature, as before observed* * It was also by wrapping a piece of soft iron, bent in the form of a horseshoe, with insulated copper wire, and connecting its ex- tremities with the poles of a galvanic battery, that Professor Moll, of Utrecht, was enabled to convert it into a temporary magnet of great power. 412 MAGNETIC EFFECTS OF By an improvement of this important instrument, MM. Nobili and Melloni were enabled to detect the heat of phosphorescent wood, dead fish, living insects, and that of the different coloured rays of the solar spectrum. But it Avas previously discovered by Dr. Seebeck, of Berlin, that when a circuit is formed by soldering together two metals, and applying the heat of a lamp to one of the junctions, a needle placed Avithin it was deflected from the magnetic meridian, and placed at right angles to the metals forming the circuit. It was afterwards found by Dobereiner, that the heat of the hand was sufficient to cause a deflec- tion of the needle, when applied to the junction of the tAvo metals—and by others, that the same effect was produced by applying ice, ether, or anything which alters the temperature in one part of the circuit from that of the rest. M. Becquerel found, that when one end of the multiplying wire was heated and brought in contact with the other end, the needle was de- flected. Hundreds of similar experiments might be adduced, all of Avhich demonstrate the agency of ca- loric in producing magnetism, Avhere there is no sign Avhatever of electric tension; and that the magnetic needle is a true test of the smallest quantities of caloric that have ever been measured. Some of the most delicate experiments on record Avere performed by Dr. Locke, of Cincinnati. By in- terposing one-quarter of a grain of antimony between the two copper wires of a multiplier, and applying the warmth of his finger, the needle was deflected 22°. In another experiment, one of the copper wires was laid CALORIC AND ELECTRICITY. 413 upon the other, without the interposition of any other metal, and the warmth of the hand applied as before, when the needle was deflected 6°. The same results were obtained by substituting the Avarmth of the breath instead of that of the hand. The temperature of the room in which the experiments were made was 65° F. (American Journal of Science, April, 1834.) But the most decisive proof that caloric and elec- tricity are only modifications of one and the same agent is, that they are mutually convertible into each other; and that the electric fluid obtained from a per- manent natural magnet, fuses, volatilizes and ignites charcoal, metals and other solids, like ordinary caloric. From a general review of the foregoing chapters, the folloAving conclusions have been deduced:— 1. That the latent caloric of aqueous vapour is the true and only basis of lightning. 2. That the latent caloric of liquids is the basis of voltaic electricity in all its various forms. 3. That they are both governed by the same uni- versal law of attraction for ponderable matter, and re- pulsion of their own particles. 4. That the essential properties of positive and negative electricity are the same under all circum- stances. 5. That when metals are made red hot by elec- tricity, Avhether it be disengaged from a galvanic bat- tery, a common machine, or from a magnet, it imme- diately loses its peculiar power of darting through conductors and producing a shock, being transformed into caloric, Avhen it excites the sensation of heat, and 414 GENERAL CONCLUSIONS. converts solids into liquids, vapours and gases, Avhich present the same properties as if generated by the ac- tion of ordinary caloric. 6. That if caloric and electricity be not modifica- tions of one agent, and the cause of all mechanical and chemical action, the whole of modern science is a mere chaos of contradictions. BOOK IV. CHAPTER I. LIFE. "First, then, if any one think that the secrets of nature remain shut up, as it were, with the seal of God, and by some divine man- date interdicted to human wisdom, we shall address ourselves to remove this weak and jealous notion; and, relying on simple truth, shall bring the inquiry to this issue, not only to silence the howl of superstition, but to draw religion herself to our side."—Bacon. "In physiology, what a vast advance would that philosopher make, who should establish a precise, tenable and consistent con- ception of life !"—Whewell. The animating principle, whether considered in a theoretical or practical point of view, is the most im- portant problem that ever engaged the attention of mankind; for it connects all that is profound and fas- cinating in physics, with the science of preserving health and prolonging life. • Never can the healing art take its appropriate rank among the exact sciences, until the cause of vital force and animal motion is dis- tinguished from the operations which it produces; but must remain, as in all the ages that are past, a mere collection of empirical rules. If it be true that every deviation from health is immediately connected with (415) 416 OBJECT OF MEDICAL SCIENCE. some derangement of the vital principle, there cannot be a doubt, that a clear comprehension of what it is, and of the laws by which it operates, would do more to meliorate the condition of mankind, than all the systems that have been invented from the age of Hip- pocrates to the present time; because it would lead not only to a certain method of curing diseases, but, what would be of vastly greater consequence, the theory of life AATould become intelligible to all; and its chief glory would be the prevention rather than the cure of maladies. The whole object of medical science is to regulate the forces of life—to increase them when and Avhere they are deficient—to restrain them when excessive— and to restore their natural balance Avhen deranged. But how can we know the best means of maintaining the functions of life in a healthy state, while ignorant of the physical cause on which they all depend ? How is it possible to counteract with certainty those in- voluntary movements that constitute tetanus, hydro- phobia, and other forms of convulsive disease, Avithout knowing the cause of muscular contraction in a state of health ? How can we adopt the best treatment of fever, inflammation, and the various species of mala- rious affections, without comprehending the true theory of animal heat, and the specific office which it performs in the economy of life? Why are so many diseases pronounced incurable, though attended with no organic lesion, and ranked among the opprobria medlcorum, but that men are ignorant of what causes the heart to beat, the stomach to digest, the brain to think, the nerves to feel, and our active limbs to move? OBJECT OF MEDICAL SCIENCE. 417 The true panacea, or elixir of life, must not be sought in specifics and nostrums, but in a clear and definite knowledge of the mode in which the organiz- ing principle operates in the different functions of life. Were it not that all the phenomena of nature are linked together as parts of one great whole, it would be of far higher importance to knoAV the cause of vital motion than that of the heavenly bodies. Nor was it ever intended by Infinite Wisdom and Goodness, that knoAvledge, so essential to the happiness of our race, should remain a sealed book. Life is the problem of problems, the solution of Avhich would clear up a thou- sand other mysteries, and banish innumerable errors from the pages of science. And it may be asserted with confidence, that whoever is without faith in the power of well-directed efforts to resolve it, will never accomplish much toward enlarging the empire of man over the numerous evils by which he is surrounded. A complete knoAvledge of this subject would do more to elevate the condition of mankind than the power of transmuting the baser metals into gold, or even char- coal into the precious diamond; for all the riches of the earth are not to be compared with health. But, unfortunately for the best interests of the world, an impression has long prevailed, that the animating principle is something beyond the powers of the human mind to comprehend. That such dogmas should have been inculcated by the founders of narrow creeds, and individuals interested in keeping the people in igno- rance, is not to be wondered at; for in all ages of the Avorld, the empire of imposture has been founded on 27 418 VIEAVS OF THE ANCIENTS. pretended msyteries, and upheld by ignorance. It is, hoAvever, melancholy to reflect, that philosophers haAe given countenance to this prejudice. Enslaved by ancient errors, even the wise Socrates is said to have thought it dangerous, unprofitable, and not acceptable to the gods, for men to pry into the hidden mechanism of nature. (Xenophon, Cyropedia, iv. 7.) And in an article on Life, contained in his Philosophical Diction- ary, Voltaire, a professed champion of free inquiry, asserts, that "the cause of animal motion, like that which determines all things to a common centre, and the needle to the pole, is the secret of the Deity." The general adoption of this opinion by the instruc- tors of mankind has done immense injury to the cause of science, by discouraging the efforts of genius to press forward into the undiscovered regions of truth; while it has fostered ignorance, indolence, and every descrip- tion of quackery. If there be any primary and effi- cient cause of vital force, it must be either a portion of the air we breathe, or of the materials by which we are nourished; and if so, there is no good reason Avhy it should be more mysterious than any of the other phenomena of nature. It was remarked by Cicero, that "to be ignorant of what has been done before our time, is ever to remain in a state of childhood;" and Lord Bacon observes, that " whoever undertakes to investigate the first principles of science, should know the opinions of the ancients concerning the foundations of nature." Coinciding with these views, and having often felt the want of such information, I shall give a brief outline of the leading doctrines which have come down to us from a VIEWS OF THE ANCIENTS. 419 remote antiquity, in regard to the primary cause of motion and life throughout nature. From the earliest dawn of civilization, men sought to resolve this great problem; and there is nothing more remarkable in the history of mankind, than the universal consent with which they regarded element- ary fire as the organizing principle; a doctrine which, although but vaguely understood by the ancients, was the basis of all their physiological theories; and which, when clearly unfolded, is destined to survive all the more elaborate systems of later ages, because it was the result of observation, experience and the dictates of common sense. It was from beholding everywhere the transforming and life-giving power of the sun, as displayed in the generation and growth of organized bodies, that all the early nations of the earth were led to regard that glorious luminary as the Supreme Lord of creation, and as the special object of religious adoration. In accordance with the views of Macrobius, it has been fully established by the learned researches of Bryant, Dupuis, Sir William Jones and many other distin- guished oriental scholars, that all the deities of the ancient world are resolvable into the powers of nature, and that they Avere mythological personations of the sun or solar fire, by which everything is produced.* * The primitive solar worship is strikingly illustrated in the fol- lowing passage, (translated from one of the Vedas, or ancient Hin- doo scriptures, by Sir W. Jones,) which also contains the germ of what is called the oriental theory of emanations, referred to in a note to page 112, book i.:■—"Let us adore the supremacy of that divine sun, the godhead who illuminates all, from whom all pro- 420 VIEAVS OF THE ANCIENTS. It was because the old Sabeans regarded fire as the universal spirit or soul of nature, that they Avorshipped the sun, moon and planets, Avith all the host of heaven, which they represented as the body of God. It Avas the sun that was adored as the fountain of light, life, wisdom and goodness, in ancient India, under the titles of Boodh-ha and Chreeshna; Avhich, in the old Celtic language of Ireland, also signify the sun, accord- ing to Higgins. (Anacalypsis, vol. i. p. 159.) The Baal and Belus of the early Chaldeans were names of the solar orb, which they represented as the seven-rayed god that fills the planets with life, power and har- monic motion. Nor is it less certain, that under the various titles of Saturn, Jove, Osiris, Vulcan, Hercules, Molech, Elion, Adonis, Jupiter, Apollo, Pan, Dionusus, Esculapius and a multitude of other appellations, the worship of fire was practised for thousands of years in Egypt, Phoenicia, Arabia, Persia, Greece, Italy and among all the ancient tribes of Europe.* Nor is it ceed, to whom all must return, whom we invoke to direct our under- standings aright, in our progress toward his holy seat." (Asiatic Researches, vol. i.; Works, vol. vi. p. 417.) It may also be worthy of notice, that in the ancient Sanskrit the seven days of the week are called after the heavenly bodies; Sun- day after the sun, to which that day was consecrated; Monday after the moon, Tuesday after Mars, Wednesday after Mercury, Thursday after Jupiter, Friday after Yenus, and Saturday after Saturn, as in several of the more modern languages, including French and Italian. * Under the mythological titles of Boodh and Fo, the sun has been worshipped from the earliest ages to the present time, in the vast empire of China, where elementary fire is still regarded as the formative principle, which was called Tien by the great Confucius and his disciples. Nor is it unworthy of notice, that the ancient VIEAVS OF THE ANCIENTS. 421 surprising, that in the absence of revelation, all the religious and philosophical systems of mankind should have been founded on the sensible operations of the material universe. The truth is, that all the names of the Supreme Being in the ancient Hebrew, as in every other written language, seem to have been originally derived from the operations of the sun, light or fire, as we learn from the researches of Bryant, Parkhurst and other learned etymologists. Innumerable passages might be quoted from both the Old and New Testaments, in which the Creator of all things is represented by the brightness of the sun, and under the similitude of light or fire, as in the burning bush, the lightnings of Sinai, the pillar of fire, the visioh of Ezekiel, who beheld brightness and flashes of lightning; that of Daniel, to whom the throne of God appeared like a fiery flame; the representation of angels as fiery spirits or seraphs; and the cloven tongues of fire that appeared on the day of Pentecost. Persians represented light as the source of all good, and darkness as the evil principle, which, according to Bishop Theodorus, they termed Satana, or Arimanius. (Enfield's Hist, of Philosophy, vol. i. p. 64.) We also learn from Macrobius, that in Egypt, as in several other oriental countries, the sun was worshipped under the symbol of a bull, which, like the ram, the serpent and many other animals dedicated to the sun, were regarded as sacred by the vulgar. And so deeply rooted was this superstition among the Israelites, that they made them a golden calf in the wilderness. We further read in the books of the Kings, Chronicles and Pro- phets, that under the titles of Baal, Moloch and Chemosh, the Chaldean and Phoenician worship of the sun was almost constantly practised by the Jews in groves and high places. 422 SPIRITUALITY OF LIGHT. There are also many other passages in the sacred writ- ings in Avhich the Deity is more especially described as residing in, and operating through the agency of light or fire: "AArho dwelleth in light inaccessible and full of glory—who is clothed with light as Avith a gar- ment—who maketh his ministers a flaming fire," &c. Whatever may be the true interpretation of such language, it clearly shows how exalted were the views of the inspired writers in regard to the agency of light in the work of the universe. The plain matter of fact is, that there is nothing in nature so divinely pure, spiritual and beautiful as light. By means of this ethereal medium, Ave hold communion with the starry worlds, and journey as on the wings of imagination, through the celestial plains. The health and spirits of all animated beings are awakened to reneAved energy by the solar rays, but languish in their absence, or when intercepted by mists and clouds. When sur- rounded Avith cold and darkness, the brightness of fancy, like the external colours of creation, is quenched, and all the energies of life are brought low. The unsophisticated language of mankind, in every age and country, has been obviously founded on the intuitive belief, that fire is in some way immediately connected with all the operations of life, sensation and thought. The following expressions are not merely metaphorical, but vivid and faithful representations of nature, derived from experience and observation:— The lamp of life, the glow of health, the warm vigour of youth, the lustre of a beaming eye, the brightness of fancy, the light of reason, the fire of genius, the heat of passion, the chillness of age, and the coldness of death,—with a GRECIAN MYTHOLOGY. 423 thousand others that might be adduced; which are not less philosophically correct than poetically beautiful. In the mythology of Greece, the germs of which were derived chiefly from the traditions of a remote antiquity, the solar orb was represented, under the name of Apollo, as the god of health, poetry and song; or as the grand dispenser of life, and the univer- sal poet of nature. The harp of Memnon, that re- sponded in sweet and melodious tones to the rising sun, was probably intended to represent his benign agency in filling the world with music and gladness. When he sheds his beams upon the earth the still air begins to move and resound through the groves with gentle murmurs; Avhile the waves of the sea re-echo Avith a bolder song. When the sun returns from be- yond the equinoctial line, to recall the sleeping world to a neAV existence, the icy bands of winter give way, Avhen the floods leap forth and join the universal cho- rus of the living world. The buds of leaves and floAvers expand; the fields are clothed with a verdant carpet; the trees with luxuriant foliage; and we can almost hear the fluids gushing through their veins. The earliest teacher of art among the Greeks Avas Prometheus, an Egyptian, who has been represented in fable as stealing fire from heaven. But it is pro- bable that he merely taught them the use of fire, in the manufacture of metals, and the other arts of life. Cecrops, who introduced the science of agriculture into Greece, was also a native of Egypt; and Cadmus, who taught the use of letters, was from Sidon. But the most renowned of all the ancient pioneers of civiliza- tion among the Greeks, was Orpheus, of Thrace, who, 424 DOCTRINE OF ORPHEUS. after visiting the East, is said to have instructed them in music, poetry, religion and philosophy. The sum of his doctrine concerning the origin of things, as col- lected from the fragments of hymns preserved in the writings of Eusebius, Clemens Alexandrinus, Proclus, Cedranus and Apuleius, and collected by M. Eschen- bach, is, that the primitive seeds from which every- thing wras produced, existed from all eternity in a fluid and chaotic state; but that at a certain finite period, the formless mass was reduced to order by the agency of an intelligent, eternal and self-active ether.* (En- field, vol. i. pp. 126 and 130.) In the Theogony of Hesiod, Chaos and Night were represented under the emblem of an egg, over which the Ether brooded, and disclosed the innumerable forms of things. And it is probable that the fable of Cupid and Psyche was an allegorical impersonation of passive matter, and of the principle by which it is ac- tuated; or that Cupid was intended to represent the * The views of Orpheus concerning the nature of this ether, and its omnipresent agency in the phenomena of life, may be further seen in the fragment of a hymn, Be Mundo, translated by M. Good:— "Jove is the ether, Jove the boundless fire, That fills the world with feeling and desire." As also in the following beautiful invocation to light:— "0 thou who fillest the palaces of Jove, AVho flowest round sun, and moon, and stars above; Pervading, bright, life-giving element; Supernal ether, fair and excellent, Fountain of hope and joy, of light and day, AVe own at length thy tranquil sway." AVHAT WAS MEANT BY THE ANCIENT CHAOS? 425 universal attraction that causes the loves of the ele- ments, and binds the universe together. The generation of the world from a fluid and chaotic state, was a leading doctrine in all the ancient oriental cosmogonies, from the time of Moses, Orpheus and Hesiod, down to the period of Ovid; and may be traced in the writings of Aristotle, Epicurus, Zeno, and the Stoics generally. For example, we are in- formed in the first chapter of Genesis, that "in the beginning, the earth Avas without form, and void, and darkness was on the face of the deep." And it is re- lated by Berosus, that the ancient Chaldeans main- tained, that in the beginning, all things consisted of a dark fluid mixture, that Avas separated and reduced to order by the divine power of Belus, (light;) and that the human soul is an emanation from the divine nature. (Enfield, vol. i. p. 54.) The Egyptian magi also maintained, that before the regular forms of nature arose, an eternal chaos existed; but that the passive and formless mass was reduced to order by the agency of a self-active, intel- lectual and eternal ether, which gradually developed all that we behold of the external universe. (Idem, pp. 89 and 132.) The sum of the Phoenician cos- mogony, as related by Cumberland, on the authority of Sanchoniathon, is, that the elements of all things originally existed in a fluid and chaotic state, until called forth by the energy of a self-active principle, in obedience to the laws of an immutable necessity. It is therefore evident that the generation of all things from chaos was a fundamental tenet in most of the ancient theogonies, as described by Ovid:— 426 WHAT WAS MEANT BY THE ANCIENT CHAOS? " Ante mare, et terras, et quod tegit omnia coelum, Unus erat toto naturae vultus in orbe Quern dixere chaos, rudis indigestaque moles, Nee quicquam nisi pondus iners congestaque eodem Non bene junctaram, discordia semina rerum." (Met. Lib. 1. v. 5.) Whatever may have been the origin of this widely diffused tradition, it contains at least a nucleus of truth; for it is certain, that all the forms of nature with which we are acquainted, have actually emerged from a fluid state. The primitive mountains of the globe have been formed from a state of fusion by fire —and the sedimentary rocks from a state of solution in the water of lakes and seas; or from the ruins of mountains and elevated plains, that have been carried down by rains, rivers and springs, in a state of chaotic mixture. Plants are formed from sap, and animals from blood, in which all their organs are confounded, until developed by the powers of life. And if it be true that the planets have been formed from the ag- gregation of phosphorescent nebulous matter, in which all the elements, active and passive, are mixed up and confounded, it presents the most important phy- sical conditions of the ancient chaos. The successive destruction of the world by alternate submersions and conflagrations, and its renovation from a state of dis- solution, was another doctrine of antiquity, that may have originated from a confused notion of the perpe- tually destroying and regenerating influences that make up the history of universal chemistry, geology, life and death. PHILOSOPHY OF THALES. 427 The first philosopher who introduced an exact me- thod of studying nature among the Greeks, was Thales of Miletus, who Avas descended from Phoenician parents, and flourished about six hundred years before the com- mencement of our era. This illustrious founder of what has been called the Ionian school, after travel- ling through the East, for the purpose of acquiring knowledge among the renowned magi of Egypt, re- turned to his native country, where he laid the foun- dation of mathematical and physical science on the basis of established principles. With the sages of the oriental nations, he maintained the existence of an omnipresent fiery ether, as the primary efficient cause of motion throughout the universe; and which he termed aurou^rov, for the purpose of representing its self-moving power. According to Cicero, he also re- garded it as the soul or mind of universal nature, because he conceived that a self-moving principle, wherever it exists, must have intelligence. (De Naturd Deorum, lib. i.) Aristotle termed it x^ruov, as indi- cating its power of giving motion to other bodies. (De Anima, lib. i. c. 2.) By the energy of this prin- ciple, Thales maintained that the passive elements of matter were reduced to order from a fluid state, and that it is the proximate cause of life in plants and animals. In conformity with the above doctrine, Parmenides and Archelaus maintained that heat was the cause of motion, and cold of rest; or that heat and cold were the first principles of action in nature. Heraclitus also regarded fire as the cause of energy throughout 428 DEMOCRITUS AND PYTHAGORAS. the universe; and as it seemed to produce all effects in a regular series, in obedience to perfectly wise laws, he conceived that it must be omniscient and divine. It has been often asserted by both ancient and mo- dern Avriters, that Democritus denied the existence of any independent principle as the primary and efficient cause of motion and life in the universe, distinct from the primitive, indivisible and immutable atoms of mat- ter; which he supposed Avere all of the same essential nature, but different in form and magnitude. It has been said that he referred all the generations and dis- solutions of bodies to certain innate forces of attrac- tion and repulsion, residing in these ultimate atoms; and that the various properties of bodies are owing to the different mode of tlieir arrangement, as determined by the inherent powers of atoms. But Lucretius says that Democritus regarded heat as composed of exceed- ingly small atoms of a round form, more active and penetrating than those of other matter; and the soul, or animating principle in man, as a portion of the same fiery nature that actuates the universe. With very slight variations, the Epicurean theory of physics was a copy of the above doctrines. Another distinguished teacher of natural philoso- phy among the Greeks was Pythagoras, the son of a Tyrian merchant, born in the island of Samos, 586 A.c. After visiting the different countries of the East, and residing twenty years in Egypt in quest of wisdom, he established a school of science in his native place, and afterAvards at Crotona in western Greece, from AAdiich he Avas driven by persecution to Metapontum, Avhere he is said to have perished of hunger in the Tem- PYTHAGORAS. 429 pie of the Muses, a martyr to the ignorant jealousy of his enemies. The sum of his doctrine concerning the primum mobile of nature was, that it is an all-pervading fiery ether of boundless energy, possessing within itself the united power of motion and intelligence, abxoixwnaijM twv izavrmv, the self-moving principle of all things; and that the human soul is a portion of the same essence. This first principle of action in nature he represented as unity; the passive elements of matter as duad; and the universe perfectly formed as a physical triad, all the operations of Avhich are governed by exact numerical laws. He also maintained that the earth and heavenly bodies revolve around a fixed fiery globe; and that the spheres of the different planets, by striking against the ether through which they pass, must produce sounds that vary according to their mag- nitude, velocity and distance from the centre of the motion—those which are farthest off producing the deepest, and the nearest the highest tones :* " Forever singing as they shine ; The hand that made them is divine."—Addison. Whether anything more was intended than to repre- sent the harmonious relations between the times, dis- tances, magnitude and velocity of the heavenly bodies, the music of the spheresf is the finest conception of * Aristotle, Meteor, lib. i. c. 6; Plutarch, de Placila Philoso- phorum, lib. iii. c. 2. f The earliest mention of this celestial harmony is found in the Book of Job, where it is said that when the work of creation was 430 MUSIC OF THE SPHERES. all antiquity, and is said to have led Kepler to the most important discovery ever made in astronomy; viz., that the times in which the planets perform their revolutions are as the cubes of their distance from the sun. Nor is it unvvorthy of notice, that as the velo- city of the planets is in proportion to the heating power of the sun, so the velocity with which sounds are propagated through gases and other vibrating media, is in proportion to the amount of caloric around their particles, ceteris paribus. About fifty years after Pythagoras, arose Hippo- finished, "the morning stars sang together;" and it has been con- secrated by the noblest poets of modern times. " Look how the floor of heaven Is thick inlaid with patines of bright gold: There's not the smallest orb 'mong all which thou behold'st, But in its motion like an angel sings, Still quiring to the young-eyed cherubim," &c.—Shakspeare. It is also grandly expressed in the following lines from an ode of Milton on the Nativity :— " Ring out, ye crystal spheres, And let your silver chime Move in melodious time, And let the base of heaven's deep organ blow; And with your ninefold harmony, Make up full concert to the angelic symphony." A still more philosophical account of this great music is con- tained in the opening chorus of Faustus, by Goethe, who refers it to the fountain of all harmony:— " The sun his ancient hymn of wonder Is pouring out to kindred spheres, And still pursues with march of thunder His preappointed course of years," &c. HIPPOCRATES. 431 crates, avIio flourished in the age of Anaxagoras, So- crates, Heraclitus and Democritus, when Greece was the centre of light and civilization to the whole world. To this illustrious man is due the glory of having re- duced the healing art to a regular and systematic form. He maintained that, although it is not the province of the physician to speak of divine things, unless so far as they may serve to improve our know- ledge of the causes and nature of the diseases incident to the human body, it is yet necessary for him to lay down some general principle from which he may rea- son. He then declares his opinion, that elementary fire is the cause of perpetual motion throughout the universe, and when united with organized bodies, con- stitutes the animating principle; that it resides in all matter, producing an endless variety of effects, accord- ing to fixed and definite laws; and that, as it operates Avith consummate skill in the generation of animal motion, sensation and intelligence, it must be some- thing immortal, that sees, hears and knows all things. This mighty agent, which he terms fusts or nature, was supposed to produce all the phenomena of living bodies, by attracting what is necessary for their de- velopment and expelling whatever is superfluous or injurious; and he maintained that the science of medi- cine should be founded on a comprehensive knowledge of the mode in which it governs all the operations of nature; xara ipociv fetopew. (De Princlplls, et de Ali- mento.) He maintained that the solid parts of animals, and their various secretions, were formed from the blood, which was composed of four primary humours, cor- 432 HIPPOCRATES. responding with the four proximate constituents of modern physiologists, viz., red particles, fibrine, albu- men and serum.* But he supposed that the liver Avas the great organ of sanguification, and termed the car- dinal humours, red blood, black bile, yelloAv bile and phlegm. On the qualities and relative proportions of these four humours, all the diversities of the consti- tution were supposed to depend. An abundance of red blood Avas marked by a Avarm and sanguine tem- perament; whereas, an excess of yellow bile produced the choleric temperament, both of which were warm and characterized by a high degree of vital energy. On the other hand, the melancholy temperament was supposed to arise from an excess of black bile, and the phlegmatic from a predominance of phlegm, both of which were cold and marked by a general debility of the system. But it is evident that what Hippocrates called phlegm was only another name for the serous portion of the blood; and that he confounded the dark venous blood which abounds in feeble, melan- choly constitutions, Avith black bile. It is equally certain, that what he called red blood was what we term arterial blood, the abundance of which is marked by a vigorous, sanguine temperament. And there is good reason to believe, that the yellow bile of Hippo- crates was only another name for the coagulating * In his treatise on the Nature of Man, he observes, that " when a man has been mortally wounded by cutting his throat, blood flows first, which is very hot and very red ; after which it comes mixed with phlegm, and finally with much bile." From which it would appear, that he regarded phlegm and bile as constituents of the blood. HIPPOCRATES. 433 lymph or fibrine, as he supposed that it imparted a yelloAV colour to the watery portion of the blood; for the bile secreted by the liver never produces this effect, unless when the system is in a diseased state.* * Several passages were published in the Lancet of September, 1835, by Mr. Girtin, from the writings of Hippocrates, which, taken separately, would seem to show that he was acquainted with the circulation. For example, in his treatise, De Insomniis, as quoted by Mr. Girtin from the Yander Linden edition of his works, he observes, that "rivers return to their sources in an unaccount- able and extraordinary manner, like the circulation of the blood." (Tome i. p. 460.) In another treatise, he says, " I protest I know not where it begins nor where it ends, for in a circle there is neither beginning nor ending." (Idem, Be Alimento, tome i. p. 596.) "The heart and veins are always in motion." (Idem, Be Prin- cipiis, tome i. p. 116.) In the Timeeus, Plato also represents "the heart as the fountain of both the veins and of the blood, which is vehemently impelled through all the members of the body in a circular progression." And here it is necessary to observe, that by