[From tiie American Journal of Science, Vol. XX, August, 1880. | ON THE EFFECTS PRODUCED BY MIXING WHITE WITH COLORED LIGHT. By Professor 0. N. Rood, Columbia College. It was noticed several years ago that when white light was mixed by the method of rotating discs with light of an ultra- marine (artificial) hue, the result was not what one would naturally have expected, viz: instead of obtaining a lighter or paler tint of violet-blue the color inclined decidedly toward violet, passing, when much white was added, into a pale violet hue. Two attempts have been made to account for this curi- ous fact: Briicke supposes that the light which we call white is really to a considerable extent red, and that the mixture of this reddish white light with the blue causes it to change to violet. Aubert, on the other hand, following a suggestion of Helmholtz, reaches the conclusion that violet is really only a lighter shade of ultramarine-blue. He starts with the assump- tion that we obtain our idea of blue mixed with white from the sky, which, according to him, is of a greenish-blue color. We then apply, as he thinks, this idea to the case of a blue which is not greenish, namely, to ultramarine-blue, and are surprised to find that the result is different. It will be shown in the present paper that these explanations are hardly correct, since they fail to account for the changes, which, according to my experiments, are produced in other colors by an admixture of white. I prepared a set of brill- iantly colored circular discs which represented all the principal colors of the spectrum and also purple; these discs were then successively combined in various proportions with a white disc and the effects of rapid rotation noted, a smaller duplicate colored disc uncombined with white being used for comparison. 0. N. Rood—Effect of mixing White and Colored Light. 82 Under these circumstances it was found that the addition of white produced the changes indicated in the following table: Cyan-blue became less greenish, more bluish. Cobalt-blue became more of a violet blue. Ultramarine (artificial) became more violet. Yermilion beoame somewhat purplish. Orange became more red. Yellow became more orange. Greenish yellow was unchanged. Yellowish green became more green. Green became more blue-green. Purple became less red, more violet. Exactly these same effects can be produced by mixing violet with the above mentioned colors. Let R, Gr, V represent the three angles of Maxwell’s color-triangle, W being the position of white. Now, according to the received theory, as we mix white with different colors we advance in straight lines from the angles or sides of the triangle toward W; in point of fact, however, I find, as a result of the above-mentioned experi- ments, that we advance in curves toward W, these curves being similar to those roughly indicated in the fig- ure. The only advance in straight lines is along the line joining violet with its complement greenish yellow. The other lines are disposed symmet- rically about this line as an axis. These experiments serve to explain the singular circumstance that when complementary colors are produced by the aid of polarized light, it is difficult or impossible to obtain a red which is entirely free from a purplish hue, a quantity of white light being always necessarily mingled with the colored light. In the case of the red, orange, yellow, ultramarine, and purple discs, I succeeded in measuring the amount of violet light which different proportions of the white disc virtually added to the mixture, and found that it is not directly proportional to the amount of white light added, but increased in a slower ratio, which at present has not been accurately determined. For the explanation of the above mentioned phenomena, Brticke’s suggestion that white light contains a certain amount of unneutralized red light is evidently inapplicable, since the effects are such as would be produced by adding a quantity not of red but of violet light, and for the present I am not dis- posed to assume that white light contains an excess of violet light. The explanation offered by Aubert does not undertake to account for the changes produced in colors other than ultra- marine, and even in this case seems to me arbitrary ; neither have I succeeded in framing any explanation in accordance with the theory of Young and Helmholtz which seems plausible.