- .*.*!'■ '<** & IB) & llliI||S:JII|iiIllllJ iilliilllllfliillllll '{''V^./'.,.:.J');.. M'-' > .^v, mm ;';'f!<^:^:;v:v^v^^:':^v NATIONAL LIBRARY OF MEDICINE Bethesda, Maryland LIBRARY OF THE NAVY DEPARTMENT. Section of Bureau of Medicine and Surgery % f Works of this Section cannot be taken from the Library except by written permission of the Bureau of Medicine and Surgery. ALCOVE SECTION. SHELF IS ' K.A.- ac 73 m9 V^X TIIE CORRELATION AND CON FOECES:% + ./ / / / *y \M.d- BY ^ 4'* ' Peof^^OYE^ Peof. HELMHOLTZ, Dr. MAYER, „.,_^~ De. FARADAY, Peof. LIEBIG and De. CARPENTER. INTRODUCTION AND BRIEF BIOGRAPHICAL NOTICES OF THE CHIEF PROMOTERS OF THE NEW'VIEWS. EDWARD L. YOUMANS, M. D. »—The highest law in physical science which our faculties permit us to perceive—the Conservation of Force."—De. Faeaday. NEW YORK: D. APPLETON AND COMPANY, 90,-92 & 94 GRAND STREET. 1869. ■KM Enteeed, according to Act of Congress, in the year 1864, by D. APPLETON AND COMPANY, It the Clerk's Office, of the District Court of the United States for thfc Southern District of New Yoik, TO JOHN WILLIAM DRAPER, M.D., LL.D. : professor of chemistry and physiolody in ifle cnitersiit of new york. Dear Sir:— It seems peculiarly appropriate that this volume should be dedicated to you. Knowing the eminent esteem in which you are held in the circles of European science, I cannot doubt that the distinguished authors of the fol- lowing essays would cordially approve this connection of your name with their introduction to the American public. There is, besides, a further reason for this in that large coincidence of purpose which is manifest in their labors and your own. For while the per- vading design of the present collection is to widen the range of thought by unfolding a broader philosophy of the energies of nature, your own compre- hensive course of research—beginning with an extended series of experi- mental investigations in chemical physics and physiology, and rising to the consideration of that splendid problem, the bearing of science upon the His- tory of the Intellectual Development of Europe—has powerfully contributed to the same noble end ; that of elevating the aim and enlarging the scope of scientific inquiry. I gladly avail myself of this occasion to say how greatly I am indebted to your writings, in which accurate and profound instruction is so often and happily blended with the charms of poetic eloquence. That you may live lone to enjoy your well-won honors, and to contribute still further to the triumphant ad ranee of scientific truth, is the heartfelt wish of * Yours truly, E. L. Y. PREFACE. In his address before the British Association for the Advance- ment of Science last year, the President remarked that the new views of the Correlation and Conservation of Forces constitute the most important discovery of the present century. The remark is probably just, prolific as has been this period in grand scientific re- sults. No one can glance through the current scientific publica- tions without perceiving that these views are attracting the pro- found attention of the most thoughtful minds. The lively con- troversy that has been carried on for the last two or three years respecting the share that different men of different countries have had in their establishment, still further attests the estimate placed upon them in the scientific world. But little, however, has been published in this country upon the subject; no complete work, I believe, except the admirable volume of Prof. Tyndall on "Heat as a Mode of Motion," in which the new philosophy is adopted, and applied to the explanation of ther- mal phenomena in a very clear and forcible manner. I have, there- fore, thought it would be a useful service to the public to reissue some of the ablest presentations of these views which have ap- peared in Europe, in a compact and convenient form. The selec- tion of these discussions has been determined by a desire to com- bine clearness of exposition with authority of statement. In the first of these respects the essays will speak for themselves; in re- gard to the last I may remark that all the authors quoted stand high as founders of the new theory of forces. Although I am not VI FEEFACE. aware that Prof. Liebig has made any claims in this direction, yet it can scarcely be doubted that his original researches in Animal Chemistry tended strongly toward the promotion of the science of vital dynamics. The work of Professor Grove, which is here reprinted in full, has a high European reputation, having passed to the fourth edi- tion in England, and been translated into several continental lan- guages. It is hardly to the credit of science in our country, that this is the first American edition. The eloquent and interesting paper of Helmholtz, though delivered as a popular lecture, was translated for the Philosophical Magazine, and has been very highly appreciated in scientific circles. The three articles of Mayer, which were also translated for the Philosophical Magazine, will have interest not only because of the great ability with which the subjects are treated, but as emanating from a man who stands per- haps preeminent among the explorers in this new tract of inquiry. The researches of Faraday in this field have been conspicuous and important, and his argument is marked hy the depth and clearness which characterize, in an eminent degree, the writings of this ex- traordinary man. The essay of Liebig forms a chapter in the last edition of his invaluable 'Familiar Letters on Chemistry,' which has not been republished here; and, as it touches the relation of the subject to organic processes, it forms a fit introduction to the final article of the series by Dr. Carpenter, on the " Correlation of the Physical and Vital Forces." The eminent English physiologist has worked out this branch of the subject independently, and the pa- per quoted gives evidence of being prepared with his usual care and ability. A certain amount of repetition is of course unavoida- ble in such a collection, yet the reader will find much less of this than he might be inclined to look for, as each writer, in elaborating the subject, has stamped it with his own originality. In the introduction I have attempted to bring forward certain facts in the history of these discoveries, in which we as Ameri- cans have a special interest, and also to indicate several applications of the new principles which are not treated in the volume. It seemed best to confine the general discussion to those aspects of the subject upon which most thought had been expended, and which may be regarded as settled among advanced scientific men. But there are other applications of the doctrine, of the highest interest which though incomplete are yet certain, and these will be found PREFACE. vii briefly noticed in the introductory observations—too briefly, I fear, to be satisfactory. Those, however, who desire to pursue still further this branch of the inquiry—the correlation of the vital, mental, and social forces—are referred to the last edition of Car- penter's " Principles of Human Physiology; " Morell's " Outlines of Mental Philosophy; " Laycock's " Correlations of Consciousness and Organization; " Sir J. K. Shuttleworth's address before the Social Science Congress of 1860, on the "Correlation of the Moral and Physical Forces;" Hinton's "Life in Nature," and "First Principles " of Herbert Spencer's new system of Philosophy. The first and last of these works are the only ones, it is believed, that have appeared in an American form, and the last is much the ablest of all; I was chiefly indebted to it in preparing the latter part of the introduction. The biographical notices, brief and im- perfect as they are, it is hoped may enhance the reader's interest in the volume. I have been specially incited to procure the publication of a work of this kind, by the same motive that has impelled me to write upon the subject elsewhere; a conviction of our educational needs in this direction. The treatment of a vast subject like this in ordinary school text-books, is at best quite too limited for the requirements of the active-minded teacher; to such, a volume like the present may prove invaluable. But a more serious difficulty is that, until compelled by the de- mands of intelligent teachers, the compilers of school-books will pass new views entirely by, or give them a mere hasty and careless notice, while continuing to inculcate the old erroneous doctrines. And thus it is that from inveterate habit, or intellectual sluggish- ness, or a shrewd calculation of the indifference of teachers, out- worn and effete ideas continue to drag through school-books for half a century after they have been exploded in the world of liv- ing science. He who continues to teach the hypothesis of caloric, falsifies the present truth of science as absolutely as he would do in teaching the hypothesis of phlogiston; in fact, the reasons of- fered for persisting in the erroneous notions of the materiality of heat—convenience of teaching, unsettledness of the new vocabu- lary, &c, are precisely those that were offered for clinging to phlo- giston, and rejecting the Lavoiserian chemistry of combustion. Both conceptions have no doubt been of service, but both were transitional, and having done their work they become hindrances viii PEEFACE. instead of helps. We can now see that when the true chemistry of combustion was once reached, the notion of phlogiston was of no further use, and if retained could only produce confusion and prevent the reception of correct ideas. So with caloric, and those false conceptions of the materiality of forces, which it implies: not only are they errors, but the ideas they involve are radically in- compatible with the higher truths to which science has advanced so that while the errors are retained the truths cannot be received. Nor will it answer merely to mention the new views while adopting the old, on the plea that the facts are the same in both cases. The facts are very far from being the same in both cases. It is precisely because the old ideas are out of harmony with the facts, and can no longer correctly explain and express them, that new ideas are sought. Was not phlogiston abandoned because it no longer agreed with the facts? So with the conception of the materiality of the forces; it contradicts the facts, and therefore, for scientific purposes, can no longer represent them. In the workshop it may perhaps be very well to magnify facts, and depreciate their theoreti- cal explanations, but not in the school-room; the business is here not working, but thinking. It is the aim of art to use facts, but of sci- ence to understand them. And it is simply because science goes beyond the fact to its explanation, and is ever striving after the highest truth, that it is fitted to discipline the thinking and reason- ing faculties, and therefore has imperative educational claims. In therefore bringing forward these able and authoritative ex- positions in a form readily accessible to teachers, I trust I am not only doing them a helpful service, but that they will be led to re- quire of the preparers of school-books a more conscientious per- formance of their tasks, and that the interests of sound education will be thereby promoted. New Yobk, Oct. 1,1864 CONTENTS. PA8B Preface, ..... v Introduction, ...... xi THE CORRELATION OF PHYSICAL FORCES, By W. R Grove. Preface, ....... 3 I.—Introductory Remarks, .... 9 II.—Motion, . . . . . 25 HI.—Heat,......39 IV.—Electricity, . . . . . .83 V.—Light,......110 VI.—Magnetism, ...... 142 VII.—Chemical Affinity, .... 152 VIDI.—Other Modes of Force, . . . .169 LX.—Concluding Remarks, .... 178 Notes and References, .... 200 ON THE INTERACTION OF NATURAL FORCES, By Prof. Helmholtz, , . . . .211 REMARKS ON THE FORCES OF INORGANIC NATURE, By Dr. J. R. Mayer, . . . . . .251 X CONTENTS. pag a ON CELESTIAL DYNAMICS, Br Dr. J. B. Mayek, . . 259 I.—Introduction, . . . . .259 IL—Sources of Heat,.....261 III.—Measure of the Sun's Heat, .... 264 TV—Origin of the Sun's Heat, . . .276 V.—Constancy of the Sun's Mass, . • • 282 VI.—The Spots on the Sun's Disc, . . .286 VII—The Tidal Wave,.....291 VIII.—The Earth's Interior Heat, . . . -'JOC REMARKS ON THE MECHANICAL EQUIVALENT OF HEAT, By Dr. J. R. Mayer, . . . . .316 SOME THOUGHTS ON THE CONSERVATION OF FORCE, By Dr. Faraday, ...... 359 THE CONNECTION AND EQUIVALENCE OF FORCES, By Prof. Liebig, ...... 387 ON THE CORRELATION OF THE PHYSICAL AND VITAL FORCES, By Dr. Carpenter, . . .401 I.—Relation of Light and Heat to the Vital Forces of Plants, 401 II.—Relation of Light and Heat to the Vital Forces of Ani- mals, ...... 420 INTRODUCTION. There are many who deplore what they regard as the material- izing tendencies of modern science. They maintain that this pro- found and increasing engrossment of the mind with material ob- jects is fatal to all refining and spiritualizing influence. The cor- rectness of this conclusion is open to serious question: indeed, the history of scientific thought not only fails to justify it, but proves the reverse to be true. It shows that the tendency of this kind of inquiry is ever from the material, toward the abstract, the ideal, the spiritual. We may appeal to the oldest and most developed of the sciences for confirmation of this statement. The earliest explanations of the celestial movements were thoroughly and grossly material, and all astronomic progress has been toward more refined and ideal views. The heavenly bodies were at first thought to be supported and carried round in their courses by solid revolving crystalline spheres to which they were attached. This notion was afterward replaced by the more complex arid mobile mechanism of epicy- cles. To this succeeded the hypothesis of Des Cartes', who rejected the clumsy mechanical explanation of revolving wheelwork, and proposed the more subtile conception of ethereal currents, which constantly whirled around in vortices, and bore along the heavenly bodies. At length the labors of astronomers, terminating with Xll INTEODUCTTON. Newton, struck away these crude devices, and substituted the action of a universal immaterial force. The course of astronomic science has thus been on a vast scale to withdraw attention from the mate- rial and sensible, and to fix it upon the invisible and supersensuous. It has shown that a pure principle forms the immaterial foundation of the universe. From the baldest materiality we rise at last to a truth of the spiritual world, of so exalted an order that it has been said 'to connect the mind of man with the Spirit of God.' The tendency thus illustrated by astronomy is characteristic in a marked degree of all modern science. Scientific inquiries are becoming less and less questions of matter, and more and more questions of force; material ideas are giving place to dynamical ideas. While the great agencies of change with which it is the business of science to deal—heat, light, electricity, magnetism, and affinity, have been formerly regarded as kinds of matter ' impon- derable elements,' in distinction from other material elements, these notions must now be regarded as outgrown and abandoned, and in their place we have an order of purely immaterial forces. Toward the close of the last century the human mind reached the great principle of the indestructiblity of matter. What the intellectual activity of ages had failed to establish by all the re- sources of reasoning and philosophy, was accomplished by the in- vention of a mechanical implement, the balance of Lavoisier. When nature was tested in the chemist's scale-pan, it was first found that never an atom is created or destroyed; that though matter changes form with protean facility, traversing a thousand cycles of change, vanishing and reappearing incessantly, yet it never wears out or lapses into nothing. The present age will be memorable in the history of science for having demonstrated that the same great principle applies also to forces, and for the establishment of a new philosophy concerning their nature and relations. Heat, light, electricity, and magnetism are now no longer regarded as substantive and independent exist- ences—subtile fluids with peculiar properties, but simply as modes THE NEW DOCTRINE OF FORCES. xiii of motion in ordinary matter; forms of energy which are capable of mutual conversion. Heat is a mode of energy manifested by certain effects. It may be transformed into electricity, which is another form of force producing different effects. Or the process may be reversed; the electricity disappearing and the heat reap- pearing. Again, mechanical motion, which is a motion of masses, may be transformed into heat or electricity, which is held to be a motion of the atoms of matter, while, by a reverse process, the mo- tion of atoms, that is, heat or electricity, may be turned back again into mechanical motion. Thus a portion of the heat generated in a locomotive is converted into the motion of the train, while by the application of the brakes the motion of the train is changed back again into the heat of friction. These mutations are rigidly subject to the laws of quantity. A given amount of one force produces a definite quantity of another. so that power or energy, like matter, can neither be created nor destroyed: though ever changing form, its total quantity in the uni- verse remains constant and unalterable. Every manifestation of force must have come from a preexisting equivalent force, and must give rise to a subsequent and equal amount of some other force. When, therefore, a force or effect appears, we are not at liberty to assume that it was self-originated, or came from nothing; when it disappears we are forbidden to conclude that it is annihilated: we must search and find whence it came and whither it has gone; that is, what produced it and what effect it has itself produced. These relations among the modes of energy are currently known by the phrases Correlation and Conservation of Force. The present condition of the philosophy of forces is perfectly paralleled by that of the philosophy of matter toward the close of the last century. So long as it was admitted that matter in its various changes may be created or destroyed, chemical progress was impossible. If, in his processes, a portion of the material dis- appeared, the chemist had a ready explanation—the matter was destroyed; his analysis was therefore worthless. But when he xiv INTRODUCTION. started with the axiom that matter is indestructible, all disappear ance of material during his operations was chargeable to their im- perfection. He was therefore compelled to improve them—to ac- count in his result for every thousandth of a grain with which he commenced; and as a consequence of this inexorable condition, analytical chemistry advanced to a high perfection, and its conse- quences to the world are incalculable. Precisely so with the anal- ysis of forces. So long as they are considered capable of being created and destroyed, the quest for them will be careless and the results valueless. But the moment they are determined to be in- destructible, the investigator becomes bound to account for them; all problems of power are at once affected, and the science of dy- namics enters upon a new era. The views here briefly stated will be found fully and variously elucidated in the essays of the present volume; in these introduc- tory remarks I propose to offer some observations on their history and the extended scope of their application. I have spoken of the principles of Correlation and Conservation of Forces as established; it may be well to state the sense in which this is to be taken. They have been accepted by the leading scien- tific minds of all nations with remarkable unanimity; their discus- sion forms a leading element in scientific literature, while they oc- cupy the thoughts and guide the investigations of the most philo- sophical inquirers. But while science holds securely her new pos- session as a fundamental principle, its various phases are by no means completely worked out. Not only has there been too little time for this, even if the views were far less important, but the questions started lie at the foundation of all branches of science, and can only be fully elucidated as these advance in their develop- ment. The new doctrine of forces is now in much the same con- dition as was the new astronomy of Copernicus. It is not with- out its difficulties, which time alone must be trusted to remove; but it simplifies so many problems, clears up so many obscurities- THE HISTORY OF SCIENTIFIC DISCOVERY. XV opens so extended a range of new investigations, and contrasts so strongly with the complexities and incongruities of the older doc- trines, as to leave little liberty of choice between the opposing theo- ries. Not only does the reception of these views mark a signal epoch in the progress of science, but from their comprehensive hearings and the luminous glimpses which they open into the most elevated re- gions of speculative inquiry, they have a profound interest for many thinkers who give little attention to the specialties of exact science. In the history of human affairs there is a growing conception of the action of general causes in the production of events, and a corresponding conviction that the part played by individuals has been much exaggerated, and is far less controlling and permanent than has been hitherto supposed. So also in the history of science it is now acknowledged that the progress of discovery is much more independent of the labors of particular persons than has been formerly admitted. Great discoveries belong not so much to indi- viduals as to humanity; they are less inspirations of genius than births of eras. As there has been a definite intellectual progress, thought has necessarily been limited to the subjects successively reached. Many minds have been thus occupied at the same time with similar ideas, and hence the simultaneous discoveries of inde- pendent inquirers, of which the history of science is so full. Thus at the close of the sixteenth century, philosophers had entered upon the investigation of, the laws of motion, and accordingly we find Galileo, Benediti, and Piccolomini proving independently that all bodies fall to the earth with equal velocity, whatever their size or weight. A century after, when science had advanced to the systematic application of the higher mathematics to general phys- ics, Newton and Leibnitz discovered independently the differential calculus. A hundred years later questions of molecular physics and chemistry were reached, and oxygen was discovered simulta- neously by Priestley and Scheele, and the composition of water by Cavendish and Watt. These discoveries were made because the XVI INTRODUCTION. periods were ripe for them, and we cannot doubt that if those who made them had never lived, the labors of others would have speed ily attained the same results. The discoverer is, therefore, in a great degree, but the mouthpiece of his time. Some discern clearly what is dimly shadowed forth to many; some work out the results more completely than others, and some seize the coming thought so long before it is developed in the general consciousness, that their announcements are unappreciated and unheeded. This view by no means robs the discoverer of his honors, but it enables us to place upon them a juster estimate, and to pass a more enlightened judgment upon the rival claims which are constantly arising in the history of science. Probably the most important event in the general progress of science was the transition from the speculative to the experimental period. The ancients were prevented from creating science by a false intellectual procedure. They believed they could solve all the problems of the universe by thought alone. The moderns have found that for this purpose meditation is futile unless accompanied by observation and experiment. Modern science, therefore, took its rise in a change of method, and the adoption of the principle that the discovery of physical truth consists not in its mere logical but in its experimental establishment. It is now an axiom that not he who guesses, though he guess aright, is to be adjudged the true dis- coverer, but he who demonstrates the new truth, and thus compels its acceptance into the body of valid knowledge. Now the later doctrines of the constancy and relations of forces, and that heat is a kind of motion among the minuter parts of mat- ter, have had their twofold phases of history, corresponding to the two methods of inquiry. They had an early and vague recognition among many philosophers, and may be traced in the writings of Galileo, Bacon, Newton, Locke, Leibnitz, Des Cartes, Bernoulli, Laplace, and others; but they were held by these thinkers as un- verified and fruitless speculations, and the subject awaited the gen- ius that could deal with it according to the more effective methods of modern science. SKETCH OF THE CAREER OF COUNT EOIFORD. XVH It was this country, widely reproached for being over-practical, which produced just that kind of working ability that was suited to translate this profound question from the barren to the fruitful field of inquiry. It is a matter of just national pride that the two men who first demonstrated the capital propositions of pure sci ence, that lightning is but a case of common electricity, and that heat is but a mode of motion—who first converted these proposi- tions from conjectures of fancy to facts of science, were not only Americans by birth and education, but men eminently representa- tive of the peculiarities of American character—Benjamin Frank- lin and Benjamin Thompson, afterwards known as Count Rumford. The latter philosopher is less known than the former, though his services to science and society were probably quite as great. The prominence which his name now occupies in connection with tho new views of heat, and the relations of forces, make it desirable to glance briefly at his career. Benjamin Thompson was born at Woburn, Mass., in 1753. Ho received the rudiments of a common school education; became a merchant's apprentice at twelve, and subsequently taught school. Having a strong-taste for mechanical and chemical studies, he cul- tivated them assiduously during his leisure time. At seventeen he took charge of an academy in the village of Rumford (now Con- cord), N. H., and in 1772 married a wealthy widow, by whom he had one daughter. At the outbreak of revolutionary hostilities he ^ applied for a commission in the American service, was charged with toryism, left the country in disgust, and went to England, His talents were there appreciated, and he took a responsible posi- tion under the government, which he held for some years. After receiving the honor of knighthood he left England and entered the service of the elector of Bavaria, ne settled in Mu- nich in 1784, and was appointed aide-de-camp and chamberlain to the Prince. The labors which he now undertook were of the most extensive and laborious character, and could never have been ac- xvm INTRODUCTION. complished but for the rigorous habits of order which he carried into all his pursuits. He reorganized the entire military establish- ment of Bavaria, introduced not only a simpler code of tactics, and a new system of order, discipline, and economy among the troops and industrial schools for the soldiers' children, but greatly im- proved the construction and modes of manufacture of arms and ordnance. Ho suppressed the system of beggary which had grown into a recognized profession in Bavaria, and become an enormous public evil—one of the most remarkable social reforms on record. He also devoted himself to various ameliorations, such as improv- ing the construction and arrangement of the dwellings of the work- ing classes, providing for them a better education, organizing houses of industry, introducing superior breeds of horses and cattle, and promoting landscape-gardening, which he did by converting an old abandoned hunting-ground near Munich into a park, where, after his departure, the inhabitants erected a monument to his honor. For these services Sir Benjamin Thompson received many distinc- tions, and among others was made Count of the holy Roman Empire. On receiving this dignity he chose a title in remembrance of the country of his nativity, and was thenceforth known as Count of Rumford. His health failing from excessive labor and what he considered the unfavorable climate, he came back to England in 1798, and had serious thoughts of returning to the United States. Having re- ceived from the American government the compliment of a formal invitation to revisit his native land, he wrote to an old friend re- questing him to look out for a " little quiet retreat" for himself and daughter in the vicinity of Boston. This intention, however, failed, as he shortly after became involved in the enterprise of founding the Royal Institution of England. There was in Rumford's character a happy combination of phi- lanthropic impulses, executive power in carrying out great projects and versatility of talent in physical research. His scientific inves- tigations were largely guided and determined by his philanthropic SCIENTIFIC LABORS OF COUNT RUMFORD. XIX plans and public duties, nis interest in the more needy classes led him to the assiduous study of the physical wants of mankind, and the best methods of relieving them; the laws and domestic man- agement of heat accordingly engaged a largo share of his attention. Ho determined the amount of heat arising from the combustion of different kinds of fuel, by means of a calorimeter of his own in- vention. He reconstructed the fireplace, and so improved the methods of heating apartments and cooking food as to produce a saving in the precious element, varying from one-half to seven- eighths of the fuel previously consumed. He improved the con- struction of stoves, cooking ranges, coal grates, and chimneys; showed that the non-conducting power of cloth is due to the air enclosed among its fibres, and first pointed out that mode of action of heat called convection; indeed he was the first clearly to dis- criminate between the three modes of propagation of heat—radia- tion, conduction, and convection. He determined the almost per- fect non-conducting properties of liquids, investigated the produc- tion of light, and invented a mode of measuring it. He was the first to apply steam generally to the warming of fluids and the culinary art; he experimented upon the use of gunpowder, the strength of materials, and the maximum density of water, and made many valuable and original observations upon an extensive range of subjects. Prof. James D. Forbes, in his able Dissertation on the recent Progress of the Mathematical and Physical Sciences, in the last edition of the Encyclopedia Britannica, gives a full account of Rum- ford's contributions to science, and remarks: " All Rumford's experiments were made with admirable precis- ion, and recorded with elaborate fidelity, and in the plainest lan- guage. Every thing with him was reduced to weight and meas- ure, and no pains were spared to attain the best results. " Rumford's name will be ever connected with the progress of science in England by two circumstances: first, by the foundation of a perpetual medal and prize in the gift of the council of the B XX INTRODUCTION. Royal Society of London, for the reward of discoveries connected with heat and light; and secondly, by the establishment in 1800 of the Royal Institution in London, destined, primarily, for the pro motion of original discovery, and, secondarily, for the diffusion of a taste for science among the educated classes. The plan was con- ceived with the sagacity which characterized Rumford, and its suc- cess has been greater than could have been anticipated. Davy was there brought into notice by Rumford himself, and furnished with the means of prosecuting his admirable experiments. He and Mr. Faraday have given to that institution its just celebrity with little intermission for half a century." Leaving England, Rumford took up his residence in France, and the estimation in which he was held may be judged of by the fact that he was elected one of the eight foreign associates of the Acad- emy of Sciences. Count Rumford bequeathed to Harvard University the funds for endowing its professorship of the Application of Science to the Art of Living, and instituted a prize to be awarded by the Ameri- can Academy of Sciences, for the most important discoveries and improvements relating to heat and light. In 1801 he married the widow of the celebrated chemist Lavoisier, and with her retired to the villa of Auteuil, the residence of her former husband, where he died in 1814. Having thus glanced briefly at his career, I now pass to the dis- covery upon which Count Rumford's fame in the future will chiefly rest. It is described in a paper published in the transactions of the Royal Society for 1798. He was led to it while superintending the operations of the Munich arsenal, by observing the large amount of heat generated in boring brass cannon. Reflecting upon this, he proposed to him- self the following questions: " Whence comes the heat produced in the mechanical operations above mentioned ?" " Is it furnished by the metallic chips which are separated from the metal ?" RUMFORD'S EXPERIMENTAL INVESTIGATIONS. xxi The common hypothesis affirmed that the heat produced had been latent in the metal, and had been forced out by condensation of the chips. But if this were the case the capacity for heat of the parts of metal so reduced to chips ought not only to be changed, but the change undergone by them should be sufficiently great to account for all the heat produced. With a fine saw Rumford then cut away slices of the unheated metal, and found that they had ex- actly the same capacity for heat as the metallic chips. No change in this respect had occurred, and it was thus conclusively proved that the heat generated could not have been held latent in the chips. Having settled this preliminary point, Rumford proceeds to his principal experiments. With the intuition of the true investigator, he remarks that " very interesting philosophical experiments may often be made, almost without trouble or expense, by means of machinery con- trived for mere mechanical purposes of the arts and manufactures." Accordingly, he mounted a metallic cylinder weighing 113.13 pounds avoirdupois, in a horizontal position. At one end there was a cavity three and a half inches in diameter, and into this was in- troduced a borer, a flat piece of hardened steel, four inches long, 0.63 inches thick, and nearly as wide as the cavity, the area of con- tact of the borer with the cylinder being two and a half inches. To measure the heat developed, a small round hole was bored in the cylinder near the bottom of the cavity, for the insertion of a small mercurial thermometer. The borer was pressed against the base of the cavity with a force of 10,000 pounds, and the cylinder made to revolve by horse-power at the rate of thirty-two times per minute. At the beginning of the experiment tne temperature of the air in the shade and also in the cylinder was 60°F. at the end of thirty minutes, and after the cylinder had made 960 revolutions the temperature was found to be 130'F. Having taken away the borer, he found that 839 grains of me- tallic dust had been cut away. " Is it possible," he exclaims, " that the very considerable quantity of heat produced in this experiment XXII INTRODUCTION. —a quantity which actually raised the temperature of upward uf 113 pounds of gun metal at least 70', could have been furnished by so inconsiderable a quantity of metallic dust, and this merely in consequence of a change in the capacity for heat? " To measure more precisely the heat produced, he next sur- rounded his cylinder by an oblong wooden box in such a manner that it could turn water-tight in the centre of the box, while the borer was pressed against the bottom. The box was filled with water until the entire cylinder was covered, and the apparatus was eet in action. The temperature of the water on commencing was 60'. He remarks, " The result of this beautiful experiment was very striking, and the pleasure it afforded amply repaid me for all the trouble I had taken in contriving and arranging the complicated machinery used in making it. The cylinder had been in motion but a short time when I perceived, by putting my hand into the water and touching the outside of the cylinder, that heat was gen- erated." As the work continued the temperature gradually rose; at two hours and twenty minutes from the beginning of the operation, the water was at 200°, and in ten minutes more it actually boiled 1 Upon this result Rumford observes, "It would be difficult to de- scribe the surprise and astonishment expressed in the countenances of the bystanders, on seeing so large a quantity of water heated and actually made to boil without any fire. Though there was nothing that could be considered very surprising in this matter, yet I acknowledge fairly that it afforded me a degree of childish pleasure which, were I ambitious of the reputation of a grave phi- losopher, I ought most certainly rather to hide than to discover." Rumford estimated the total heat generated as sufficient to raise 26.58 pounds of ice-cold water 180°, or to its boiling point; and he adds, " from the results of these computations, it appears that the quantity of heat produced equally or in a continuous stream, if I may use the expression, by the friction of the blunt steel borer against the bottom of the hollow metallic cylinder, was greater rumford's lnferences from nis experiments, xxiii than that produced in the combustion of nine wax candles, each three-quarters of an inch in diameter, all burning together with clear bright flames." " One horse would have been equal to the work performed, though two were actually employed. Heat may thus be produced merely by the strength of a horse, and in a case of necessity this might be used in cooking victuals. But no circumstances could bo imagined in which this method of producing heat could be advan- tageous, for more heat might be obtained by using the fodder ne- cessary for the support of the horse, as fuel. " By meditating on the results of all these experiments, we are aaturally brought to that great question which has so often been the subject of speculation among philosophers, namely, What is heat? Is there such a thing as an igneous fluid? Is there any thing that with propriety can be called caloric ? " We have seen that a very considerable quantity of heat may be excited by the friction of two metallic surfaces, and given off in a constant stream or flux in all directions, without interruption or intermission, and without any signs of diminution or exhaustion. In reasoning on this subject we must not forget that most remark able circumstance, that the source of the heat generated by friction in these experiments appeared evidently to be inexhaustible. (The italics are Rumford's.) It is hardly necessary to add, that any thing which any insulated body or system of bodies can continue to furnish without limitation, cannot possibly be a material sub- stance ; and it appears to me to be extremely difficult, if not quite impossible, to form any distinct idea of any thing capable of being excited and communicated in those experiments, except it be mo- tion." No one can read the remarkably able and lucid paper from which these extracts are taken, without being struck with the per- fect distinctness with which the problem to be solved was pre- sented, and the systematic and conclusive method of its treatment. Rumford kept strictly within the limits of legitimate inquiry, which XXIV INTRODUCTION. no man can define better than he did. "I am very far from pre- tending to know how, or by what means or mechanical contri- vances, that particular kind of motion in bodies, which has been supposed to constitute heat, is exerted, continued, and propagated. and I shall not presume to trouble the Society with new conjec- tures. But although the mechanism of heat should in part be one one of those mysteries of nature, which are beyond the reach of human intelligence, this ought by no means to discourage us, or even lessen our ardor in our attempts to investigate the laws of its operations. How far can we advance in any of the paths which science has opened to us, before we find ourselves enveloped in those thick mists, which on every side bound the horizon of the human intellect." Rumford's experiments completely annihilated the material hy- pothesis of heat, while the modern doctrine was stated in explicit terms. He moreover advanced the question to its quantitative and highest stage, proposing to find the numerical relation between mechanical power and heat, and obtained a result remarkably near to that finally established. The English unit of force is the foot- pound, that is, one pound falling through one foot of space; the unit of heat is one pound of water heated 1° F. Just fifty years subsequently to the experiment of Rumford, Dr. J. P. Joule,* of Manchester, England, after a most delicate and elaborate series of experiments, determined that 772 units of force produce one unit of heat; that is, 772 pounds falling through one foot produces suf- ficient heat to raise one pound of water 1° F. This law is known as the mechanical equivalent of heat. Now, when we throw Rum- ford's results into these terms, we find that about 940 units of force produced a unit of heat, and that, therefore, on a large scale and at the very first trial, he came within twenty per cent, of the truo * James I'kescott Joule, born December 24th, 1818, at Salford, near Manchester, England, •where he pursued the occupation of a brewer. Long and deeply devoted to scientific investigation, he became a member of the Manchester Philosophical So- ciety in 1842, and of the Eoyal Society of London in 1850. SUMMARY OF RUMFORD S CLAIMS. XXV statement. No account was taken of the heat lost by radiation, which, considering the high temperature produced, and the dura- tion of the experiment, must, have been considerable; so that as Rumford himself noticed, this value must be too high. The ear- liest numerical results in science are rarely more than rough ap- proximations, yet they may guide to the establishment of great principles. Certainly no one could question Dalton's claim to the discovery of the law of definite proportions, because of the inac- curacy of the numbers upon which he first rested it. We are called further to note that Rumford's ideas upon the general subject of forces were far in advance of his age. He saw the relation of all friction to heat, and.suggested that of fluids, by churning processes, as a means of producing it—precisely the method finally employed by Joule in estabhshing the mechanical equivalent of heat. He furthermore regarded animals dynami- cally, considering their force as the derivative of then* food, and therefore as not created. That Rumford held these views in the comprehensive and matured sense in which they are now enter- tained is, of course, not asserted. The advance from his day to ours has been prodigious. Whole sciences have been created, which afford the most beautiful exemplifications of the new doc- trines. Those doctrines have received their subsequent develop- ment in various directions by many minds, but we may be allowed to question if the contributions of any of their promoters will sur- pass, if indeed they will equal, the value and importance which we must assign to the first great experimental step in the new direc- tion. The claims of Rumford may be summarized as follows: I. no was the man who first took the question of the nature of heat out of the domain of motaphysics, where it had been speculated upon since the time of Aristotle, and placed it upon the true basis of physical experiment. II. Ho first proved the insufficiency of the current explanations XXVI INTRODUCTION. of the sources of heat, and demonstrated the falsity of the prevailing view of its materiality. in. He first estimated the quantitative relation between the heat produced by friction and that by combustion. IV. He first showed the quantity of heat produced by a definite amount of mechanical work, and arrived at a result re- markably near the finally established law. V. He pointed out other methods to be employed in determining the amount of heat produced by the expenditure of me- chanical power, instancing particularly the agitation of water, or other liquids, as in churning. VI. He regarded the power of animals as due to their food, there fore as having a definite source and not created, and thus applied his views of force to the organic world. VII. Rumford was the first to demonstrate the quantitative con- vertibility of force in an important case, and the first to reach, experimentally, the fundamental conclusion that heat is but a mode of motion. In his late work upon heat, Prof. Tyndall, after quoting co- piously from Rumford's paper, remarks: " When the history of the dynamical theory of heat is written, the man who in opposition to the scientific belief of his time could experiment, and reason upon experiment, as did Rumford in the investigation here referred to, cannot be lightly passed over." nad other English writers been equally just, there would have been less necessity for the foregoing exposition of Rumford's labors and claims; but there has been a manifest disposition in various quarters to obscure and depreciate them. Dr. Whewell, in his history of the Inductive Sciences, treats the subject of thermotics without mentioning him. An em- inent Edinburgh professor, writing recently in the Philosophical Magazine, under the confessed influence of 'patriotism,' under- DAVY'S RELATION TO THE QUESTION. XXVli takes to make the dynamical theory of heat an English monopoly, due to Sir Isaac Newton, Sir Humphry Davy, and Dr. J. P Joule; while an able writer in a late number of the North British Review, in sketching the historic progress of the new views, puts Davy forward as their founder, and assigns to Rumford a minor and subsequent place. Sir Humphry Davy, it is well known, early rejected the caloric hypothesis. In 1799, at the age of twenty-one, he published a tract at Bristol, describing some ingenious experiments upon the subject. It was the publication of this pamphlet which brought him to Rumford's notice, and resulted in his subsequent connection with the Royal Institution. But Davy's ideas upon the question were far from clear, and will bear no comparison with those of Rumford, published the year before. Indeed his eulogist remarks: "It is certain that even Davy himself was led astray in his argu- ment by using the hypothesis of change of capacity as the basis of his reasoning, and that he might have been met successfully by any able calorist, who, though maintaining the materiality of heat, might have been willing to throw overboard one or two of the less essential tenets of his school of philosophy." It was not till 1812 that Davy wrote in his Chemical Philosophy, " The immediate cause of the phenomena of heat then is motion, and the laws of its communication are precisely the same as those of the communica- tion of motion." When, therefore, we remember that Davy's first publication was subsequent to that of Rumford's, that he confined himself to the narrowest point of the subject, the simple question of the existence of caloric; and that he nowhere gives evidence of having the slightest notion of the quantitative relation between mechanical force and heat, the futility of the claim which would make him the experimental founder of the dynamical theory, is abundantly apparent. The inquiries opened by Rumford and Davy were not formally pursued by the succeeding generation. Even the powerful adhe- Bion of Dr. Thomas Young—perhaps the greatest mind in science XXV11I INTRODUCTION. since Newton—failed to give currency to the new views. But the salient and impregnable demonstration of Rumford, and the ingen- ious experiments of Davy, facts which could neither be evaded nor harmonized with the prevailing errors, were not without influence. That there was a general, though unconscious tendency toward a new philosophy of forces, in the early inquiries of the present cen- tury, is shown by the fact that various scientific men of different nations, and with no knowledge of each other's labors, gave ex- pression to the same views at about the same time. Grove and Joule of England, Mayer of Germany, and Colding of Denmark, announced the general doctrine of the mutual relations of the forces, with more or less explication, about 1842, and Seguin of France, it is claimed, a little earlier. From this time the subject was closely pursued, and the names of Helmholtz, Holtzman, Clausius,* Faraday, Thompson, Rankine,t Tyndall, Carpenter, and others are intimately associated with its advancement. In this country Professors Henry J and Leconte § have contributed to illustrate the organic phase of the doctrine. I cannot here attempt an estimate of the respective shares which these men have had in constructing the new theories; the reader will gather various intimations upon this point from the succeeding essays. The foreign periodicals, both scientific and lit- erary, show that the question is being thoroughly sifted, and mate- rials accumulating for the future history of the subject. The para- mount claims are, however, those of Joule, Mayer, and Grove. * Classics, Rudolph Julius Immanuel -was born at COslin, Pommern, January 22,1822. lie became Professor of Philosophy and Physics in the Polytechnic School at Zurich in 1855, and then Professor of the Zurich University (1857). He was after- wards teacher of Physics and Artillery in the School of Berlin, and then private teacher of the University of that place. t Eankine, William John Macqttoen was born at Edinburgh, July 5,1820. He is a civil engineer in Glasgow, a member of the Philosophical Society at that place, and of the Royal Society of London. % See the article " Meteorology," in the Agricultural Report of the Patent Office, for t8DT. § See the American Journal of Science for Nov. 1859. CLAIMS OF JOULE, GROYE, AND MATER. XXIX According to the strict rule of science, that in all those cases where experimental proof is possible, he who first supplies it is the true discoverer, Dr. Joule must be assigned the foremost place among the modern investigators of the subject. He dealt with the whole question upon the basis of experiment. He labored with great perseverance and skill to determine the mechanical equivalent of heat—the corner-stone of the edifice; and in accomplishing this result in 1850, he may be said to have matured the work of Rumford, and finally established upon an experimental basis the great law of thermo-dynamics, to remain a demonstration of science forever. Professor Grove has also worked out the subject in his own in- dependent way. Combining original experimental investigations of great acuteness, with the philosophic employment of the gen- eral results of science, he was the first to give complete and system- atic expression to the new views. His able work, which opens the present series, is an authoritative exposition, and an acknowl- edged classic upon the subject. Again, the claims of Dr. Mayer to an eminent and enviable place among the pioneers of this great scientific movement, are un- questionable. There has evidently been, on the part of some Eng- glish writers, an unworthy inclination to depreciate his merits, which has given rise to a sharp and, searching controversy. The intellectual rights of the German philosopher have, however, been decisively vindicated by the chivalric pen of Prof. Tyndall; and it is to the public interest thus excited, that we are indebted for the translation of Mayer's papers, which appear in this volume. Mayer did not experiment to the extent of Joule and Grove, yet he well knew its importance, and made such investigations as his apparatus and the duties of a laborious profession would allow. Yet his views were not therefore mere ingenious and probable conjectures. Master of the results of modern science, and of the mathematical methods of dealing with them, possessing a broad philosophic grasp, and an extraordinary mental pertinacity, Dr. Mayer entered early upon the inquiry, and not only has he developed many of its XXX INTRODUCTION. prime applications in advance of any other thinker, but he has done his work under circumstances and in a manner which awa- kens the highest admiration for his genius.* An eminent authority has remarked (that tl ese discoveries open a region which promises possessions richer than any hitherto granted to the intellect of man.' Involving as they do a revolution of fundamental ideas, their consequences must be as comprehen- sive as the range of human thought. A principle has been devel- oped of all-pervading application, which brings the diverse and distant branches of knowledge into more intimate and harmonious alliance, and affords a profounder insight into the universal order. Not only is science itself deeply affected by the presentation of its questions, in new and suggestive lights, but its method is at once made universal. There is a crude notion in many minds, that it jg the business of science to occupy itself merely with the study of matter. When, hitherto, it has pressed its inquiries into the higher * Prof. Tyndall remarks: "Mayer probably had not the means of making experi- ments himself, but he ransacked the records of experimental science for his data, and thus conferred upon his writings a strength which mere speculation can never possess. From the extracts which I have given, the reader may infer his strong desire for quan- titative accuracy, the clearness of his insight, and the firmness of his grasp. Regard- ing the recognition which will be ultimately accorded to Dr. Mayer, a shade of trouble or doubt has never crossed my mind. Individuals may seek to pull him down, but their efforts will be unavailing as long as such evidence of his genius exists, and as long as the general mind of humanity is influenced by considerations of justice and truth. " The paucity of facts in Mayer's time has been urged as if it were a reproach to him; but it ought to be remembered that the quantity of fact necessary to a generaliza- tion is different for different minds. 'A woid to the wise is sufficient for them,'' and a single fact in some minds bears fruit that a hundred cannot produce in others. Mayer's data were comparatively scanty, but his genius went far to supply the lack of experiment, by enabling him to see clearly the bearing of such facts as he possessed. They enabled him to think out the law of conservation, and his conclusions received the stamp of certainty from the subsequent experimental labors of Mr. Joule. In ref- erence to their comparative merits, 1 would say that as Seer and Generalize^ Mayer, In my opinion, stands first—as experimentalphiloi opher, Joule," THE TRUE SCOPE OF SCIENCE. xxxi region of life, mind, society, history, and education, the traditional custodians of these subjects have bidden it keep within its limits and stick to matter. But science is not to be hampered by this narrow conception; its office is nothing less than to investigate the laws and universal relations of force, and its domain is therefore coextensive with the display of power. Indeed, as we know noth- ing of matter, except through its manifestation of forces, it is ob- vious that the study of matter itself is at last resolved into the study of forces. The establishment of a now philosophy of forces, therefore, by its vast extension of the scope and methods of sci- ence, constitutes a momentous event of intellectual progress. The discussions of the present volume will make fully apparent the importance of the new doctrines in relation to physical science, but their higher implications are but partially unfolded. In the concluding article Dr. Carpenter has shown the applicability of the principle of correlation to vital phenomena. His argument is of interest, not only because of the facts and principles established, but as opening an inquiry which must lead to still larger results: for, if the principle be found operative in fundamental organic processes, it will undoubtedly be traced in those which are higher; if in the lower sphere of life, then throughout that sphere. If the forces are correlated in organic growth and nutrition, they must be in organic action; and thus human activity, in all its forms, is brought within the operation of the law. As a creature of or- ganic nutrition, borrowing matter and force from the outward world; as a being of feeling and sensibility, of intellectual power and multiform activities, man must be regarded as amenable to the great law that forces are convertible and indestructible; and as psychology and sociology—the science of mind and the science of society—have to deal constantly with different phases and forma of human energy, the new principle must be of the profoundest import in relation to these great subjects. The forces manifested in the living system are of the most varied and unlike character, mechanical, thermal, luminous, electric, xxxn INTRODUCTION. chemical, nervous, sensory, emotional, and intellectual. That these forces are perfectly coordinated—that there is some definite relation among them which explains the marvellous dynamic unity of tho living organism, does not admit of question. That this relation is of the same nature as that which is found tc exist among tho purely physical forces, and which is expressed by the term ' Correl- ation,' seems also abundantly evident. From the great complex- ity of the conditions, the samo exactness will not, of course, be expected here as in the inorganic field, but this is one of the neces- sary limitations of all physiological and psychological inquiry; thus qualified the proofs of the correlation of the nervous and mental forces with the physical, are as clear and decisive a3 those for the physical forces alone. If a current of electricity is passed through a small wire it produces heat, while if heat is applied to a certain combination of metals, it reproduces a current of electricity; those forces are, therefore, correlated. A current of electricity passed through a small portion of a motor or sensory nerve will excite the nerve force in the remainder, while, on the other hand, as is shown in the case of the torpedo, the nerve-force may generate electricity. Nerve-force may produce heat, light, electricity, and, as we con- stantly experience, mechanical power, and these in their turn may also excite nerve-force. This form of energy is therefore clearly entitled to a place in the order of correlated agencies. Again, if we take the highest form of mental action, viz.: will- power, we find that while it commands the movements of the sys- tem, it does not act directly upon the muscles, but upon the cerebral hemispheres of the brain. There is a dynamic chain of which voluntary power is but one link. The will is a power which excites nerve-force in the brain, which again excites mechanical power in the muscles. Will-power is therefore correlated with nerve-power in the same manner as the latter is with muscular power. Dr. Carpenter well observes: "It is difficult to see that the dynamical agency which we term will is more removed from nerve-force on CORRELATION OF NERVOUS AND MENTAL FORCES. XXX111 the one hand than nerve-force is removed from motor force on the other. Each, in giving origin to the next, is itself expended or ceases to exist as such, and each bears, in its own intensity, a pre- cise relation to that of its antecedent and its consequent." We have here only space briefly to trace the principle in its application to Bensations, motions, and intellectual operations. The physical agencies acting upon inanimate objects in the external world, change their form and state, and we regard theso changes as transformed manifestations of the forces in action. A body is heated by hammering; the heat is but transmuted mechani- cal force; or a body is put in motion by heat, a certain quantity being transformed into mechanical effect, or motion of the mass. And so it is held that no force can arise except by the expenditure of a preexisting force. Now, the living system is acted upon by tho same agencies and under the same law. Impressions made upon the organs of sense give rise to sensations, and we have the same warrant in this, as in the former case, for regarding the effects as transformations of the forces in action. If the change of molecular state in a melted body represents the heat transformed in fusing it, so the sensation of warmth in a living body must represent the heat transformed in producing it. The impression on the retina, as well as that on the photographic tablet, results from the transmuted impulses of fight. And thus impressions made from moment to moment on all our organs of sense, are directly correlated with external physical forces. This correlation, further- more, is quantitative as well as qualitative. Not only does the light-force produce its peculiar sensations, but the intensity of these sensations corresponds with the intensity of the force; not only is atmospheric vibration transmuted into the sense of sound, but the energy of the vibration determines its loudness." And so in all other cases; the quantity of sensation depends upon the quantity of the force acting to produce it. Moreover, sensations do not terminate in themselves, or come to nothing; they produce certain correlated and equivalent effects. XXXIV INTRODUCTION. The feelings of light, heat, sound, odor, taste, pressure, are im- mediately followed by physiological effects, as secretion, musculai action, &c. Sensations increase the contractions of the heart, and it has been lately maintained that every sensation contracts the muscular fibres throughout the whole vascular system. The res- piratory muscles also respond to sensations; the rate of breathing being increased by both pleasurable and painful nerve-impressions. The quantity of sensation, moreover, controls the quantity of emo- tion. Loud sounds produce violent starts, disagreeable tastes cause wry faces, and sharp pains give rise to violent struggles. Even when groans and cries are suppressed, the clenched hands and set teeth show that the muscular excitement is only taking another direction. Between the emotions and bodily actions the correlation and equivalence are also equally clear. Moderate actions, like moderate sensations, excite the heart, the vascular system, and the glandular organs. As the emotions rise in strength, however, the various systems of muscles are thrown into action; and when they reach a certain pitch of intensity, violent convulsive movements ensue. Anger frowns and stamps; grief wrings its hands; joy dances and leaps—the amount of sensation determining the quantity of correla- tive movement. Dr. Carpenter, in his Physiology, has brought forward numerous exemplifications of this principle of the conversion of emotion into movement, as seen in the common workings of human nature. Most persons have experienced the difficulty of sitting still under high excitement of the feelings, and also the relief afforded by walking or active exercise; while, on the other hand, repression of the movements protracts the emotional excitement. Many irascible persons get relief from their irritated feelings by a hearty explosion of oaths, others by a violent slamming of the door, or a prolonged fit of grumbling. Demor strative persons habitually expend their feelings in action, while those who manifest them less retain them longer: hence the former are more weak and transient in their CORRELATION OF PHYSICAL AND MENTAL FORCES. XXXV attachments than the latter, whose unexpended emotions become permanent elements of character. For the same reason, those wno are loud and vehement in their lamentations seldom die of grief; while the deep-seated emotions of sorrow which others cannot work off in.violent demonstrations, depress the organic functions, and often wear out the life. Tho intellectual operations are also directly correlated with physical activities. As in the inorganic world we know nothing of forces except as exhibited by matter, so in the higher intellectual realm we know nothing of mind-force except through its material manifestations. Mental operations are dependent upon material changes in the nervous system; and it may now be regarded as a fundamental physiological principle, that " no idea or feeling can arise, save as the result of some physical force expended in pro- ducing it." The directness of this dependence is proved by the fact that any disturbance of the train of cerebral transformations disturbs mentality, while their arrest destroys it. And here, also, the correlation is quantitative. Other things being equal there is a relation between the size of the nerve apparatus and the amount of mental action of which it is capable. Again, it is dependent upon the vigor of the circulation; if this is arrested by the cessation of the heart's action, total unconsciousness results; if it is enfeebled, mental action is low; while if it is quickened, mentality rises, even to delirium, when the cerebral activity becomes excessive. Again, tho rate of brain activity is dependent upon the special chemical ingredients of the blood, oxygen and carbon. Increase of oxygen augments cerebral action, while increase of carbonic acid depresses it. The degree of mentality is also dependent upon the phosphatic constituents of the nervous system. The proportion of phosphorus in the brain is smallest in infancy, idiocy, and old age, and greatest duriug the prime of fife; while the quantity of alkaline phosphates excreted by the kidneys rises and falls with the variations of mental activity. The equivalence of physical agencies and mental effects is still further seen in the action of various substances, as alcohol, XXXVI INTRODUCTION, opium, hashish, nitrous oxide, etc., when absorbed into the blood, Within the limits of their peculiar action upon the nervous centres, tho effect of each is strictly proportionate to the quantity taken. There is a constant ratio between the antecedents and consequents. " How this metamorphosis takes place—how a force existing as motion, heat, or light, can become a mode of consciousness— how it is possible for aerial vibrations to generate the sensation we call sound, or for the forces liberated by chemical changes in the brain, to give rise to emotion, these are mysteries which it is im- possible to fathom. But they are not profounder mysteries than the transformation of the physical forces into each other. They are not more completely beyond our comprehension than the natures of mind and matter. They have simply the same insolu- bility as all other ultimate questions. We can learn nothing more than that here is one of the uniformities in the order of phe- nomena." The law of correlation being thus applicable to human energy as well as to the powers of nature, it must also apply to society, where we constantly witness the conversion of forces on a compre- hensive scale. The powers of nature are transformed into the activ- ities of society; water-power, wind-power, steam-power, and electri- cal-power are pressed into the social service, reducing human labor, multiplying resources, and carrying on numberless industrial pro- cesses : indeed, the conversion of these forces into social activities is one of the chief triumphs ot civilization. The universal forces of heat and light are transformed by the vegetable kingdom into the vital energy of organic compounds, and then, as food, are again converted into human beings and human power. The very exist- ence as well as the activity of society are obviously dependent upon the operations of vegetable growth. When that is abundant, popu- lation may become dense, and social activities multifarious and complicated, while a scanty vegetation entails sparse population and enfeebled social action. Any universal disturbance of tho physical forces, as excessive rains or drouth, by reducing the har- CORRELATION OF VITAL AND SOCIAL FORCES. XXX Vli vest, is felt throughout the entire social organism. Where this effect is marked, and not counteracted by free communication with more fertile regions, the means of the community become restricted, business declines, manufactures are reduced, trade slackens, travel falls off, luxuries are diminished, education is neglected, marriages are fewer, and a thousand kindred results indicate decline of enter- prise and depression of the social energies. In a dynamical point of view there is a strict analogy between tho individual and the social economies—the same law of force governs the development of both. In the case of the individual, the amount of energy which he possesses at any time is limited, and when consumed for one purpose it cannot of course be had for another. An undue demand in one direction involves a corre- sponding deficiency elsewhere. For example, excessive action of tho digestive system exhausts the muscular and cerebral systems, while excessive action of the muscular system is at the expense of the cerebral and digestive organs; and again, excessive action of the brain depresses the digestive and muscular energies. If the fund of power in the growing constitutions of children is overdrawn in any special channel, as is often the case by excessive stimulation of the brain, the undue abstraction of energy from other portions of the system is sure to entail some form of physiological disaster, So with the social organism; its forces being limited, there is but a definite amount of power to be consumed in the' various social activities. Its appropriation in one way makes impossible its em- ployment in another, and it can only gain power to perform one function by the loss of it in other directions. This fact, that social force cannot bo created by enactment, and that when dealing with the producing, distributing, and commercial activities of the com- munity, legislation can do little more than interfere with their natural courses, deserves to be more thoroughly appreciated by the public. But tho law in question has yet higher bearings. More and more we are perceiving that the condition of humanity and tho XXXV1U INTRODUCTION. progress of civilization are direct resultants of the forces by which men are controlled. What we term the moral order of society, im- plies a strict regularity in the action of these forces. Modern sta- tistics disclose a remarkable constancy in the moral activities man- ifested in communities of men. Crimes, and even the modes of crime, have been observed to occur with a uniformity which admits of their prediction. Each period may therefore be said to have its definite amount of morality and justice. It has been maintained, for instance, with good reason, that " the degree of liberty a peo- ple is capable of in any given age, is a fixed quantity, and that any artificial extension of it in one direction brings about an equiva- lent limitation in some other direction. French revolutions show scarcely any more respect for individual rights .than the despotisms they supplant; and French electors use their freedom to put themselves again in slavery. So in those communities where State restraint is feeble, we may expect to find it supplemented by the sterner restraints of public opinion." But society like the individual is progressive. Although at each stage of individual growth the forces of the organism, physi- ological, intellectual, and passional, have each a certain definite amount of strength, yet these ratios are constantly changing, and it is in this change that development essentially consists. So with society; the measured action of its forces gives rise to a fixed amount of morality and liberty in each age, but that amount in- creases with social evolution. The savage is one in whom certain classes of feelings and emotions predominate, and he becomes civil- ized just in proportion as these feelings are slowly replaced by oth- ers of a higher character. Yet the activities which determine human advancement are various. Not only must we regard the physiological forces, or those which pertain to man's physical or- ganization and capacities, and the psychological, or those resulting from his intellectual and emotional constitution, but the influences of the external world, and those of the social state, are likewise to be considered. Man and society, therefore, as viewed by the eye SPENCER'S CONTRIBUTION TO THE INQUIRY. XXXIX of science, present a series of vast and complex dynamical problems, which are to be studied in the future in the light of the great law by which, we have reason to believe, all forms and phases of force are governed. A further aspect of the subject remains still to be noticed. Mr. Herbert Spencer has the honor of crowning this sublime inquiry by showing that the law of the conservation, or as he prefers to term it the ' Persistence of Force,' as it is the underlying principle of all be- ing, is also the fundamental truth of all philosophy. With masterly analytic skill he has shown that this principle of which the human mind has just become fully conscious, is itself the profoundest law of the human mind, the deepest foundation of consciousness. Ho has demonstrated that the law of the Persistence of Force, of which the most piercing intellects of past times had but partial and un- satisfying glimpses, and which the latest scientific research has disclosed as a great principle of nature, has a yet more transcendent character; is, in fact, an d ]iriori truth of the highest order—a truth which is necessarily involved in our mental organization; Which is broader than any possible induction, and of higher validity than any other truth whatever. This principle, which is at once the highest result of scientific investigation and metaphysical analysis, Mr. Spencer has made tho basis of his new and compre- hensive System of Philosophy; and in the first work of the series, entitled " First Principles, " he has developed the doctrine in its broadest philosophic aspects. The lucid reasoning by which he reaches his conclusions cannot be presented here; a brief extract or two will, however, serve to indicate the important place assigned to the law by this acute and profound inquirer: " We might, indeed, be certain, even in the absence of any such analysis as the foregoing, that there must exist some principle which, as being the basis of science, cannot be established by sci- ence. All reasoned out conclusions whatever must rest on some postulate. As before shown, we cannot go on merging derivative truths in these wider and wider truths from which they are do- xl INTRODUCTION. rived, without reaching at last a widest truth which can be merged in no other, or derived from no other. And whoever contemplates the relation in which it stands to the truths of science in general, will see that this truth, transcending demonstration, is the Persist- ence of force." * * * " Such, then, is the foundation of any possible system of posi- tive knowledge. Deeper than demonstration—deeper even than definite cognition—deep as the very nature of mind, is the postu- late at which we have arrived. Its authority transcends all others whatever; for not only is it given in the constitution of our own consciousness, but it is impossible to imagine a consciousness so constituted as not to give it. Thought, involving simply the estab- lishment of relations, may be readily conceived to go on while yet these relations have not been organized into the abstracts we call space and time; and so there is a conceivable kind of consciousness which does not contain the truths commonly called d priori, in- volved in the organization of these forms of relations. But thought cannot be conceived to go on without some element between which its relations may be established; and so there is no conceivable kind of consciousness which does not imply continued existence as its datura. Consciousness without this or that particular form is possible; but consciousness without contents is impossible. " The sole truth which transcends experience by underlying it, is thus the Persistence of force. This being the basis of experience, must be the basis of any scientific organization of experiences. To this an ultimate analysis brings us down; and on this a rational synthesis must be built up." To the question, What then is the value of experimental inves- tigations upon the subject, if the truth sought cannot be estab- lished by inductions from them? Mr. Spencer replies: "They are of value as disclosing the many particular implications which the general truth does not specify; they are of value as teaching us how much of one mode of force is the equivalent of so much of another mode; they are of value as determining under what conditions each STUPENDOUS REACH OF THE LAW. xll metamorphosis occurs; and they are of value as leading us to in- quire in what shape the remnant of force has escaped, when the apparent results are not equivalent to the cause." And it may bo added, that it is to these investigations that we are indebted for the clear and comprehensive establishment of the principle as a law of physical nature; psychological analysis having only shown that it extends much further than it is the business of experimental science to go. Thus the law characterized by Faraday as the highest in phys- ical science which our faculties permit us to perceive, has a far more extended sway; it might well have been proclaimed the highest law of all science—the most far-reaching principle that adventuring reason has discovered in the universe. Its stupendous reach spans all orders of existence. Not only does it govern the movements of the heavenly bodies, but it presides over the genesis of the constellations; not only does it control those radiant floods of power which fill the eternal spaces, bathing, warming, illumining and vivifying our planet, but it rules the actions and relations of men, and regulates the march of terrestrial affairs. Nor is its do- minion limited to physical phenomena; it provails equally in the world of mind, controlling all the faculties and processes of thought and feeling. The star-suns of the remoter galaxies dart their ra- diations across the universe; and although the distances are so pro- found that hundreds of centuries may have been required to traverse them, the impulses of force enter the eye, and impressing an atomic change upon the nerve, give origin to the sense of sight. Star and nerve-tissue are parts of the same system—stellar and nervous forces are correlated. Nay more; sensation awakens thought and kindles emotion, so that this wondrous dynamic chain binds into Uving unity the realms of matter and mind through measureless amplitudes of space and time. And if these high realities are but faint and fitful glimpses which science has obtained in the dim dawn of discovery, what must be the glories of the coming day? If indeed they are but xlii INTRODUCTION. 'pebbles' gathered from the shores of the great ocean of truth, what are the mysteries still hidden in the bosom of the mighty un- explored? And how far transcending all stretch of thought that Unknown and Infinite Cause of all to which the human spirit turns evermore in solemn and mysterious worship! It remains only to observe, that so immense a step in the pro- gress of our knowledge of natural agencies as the following pages disclose, cannot be without effect upon the intellectual culture of the age. To the adherents of that scholastic and verbal edu- cation which prefers words to things, and ancient to modern thought; which ignores the study of nature, and regards the pro- gress of science with indifference or hostility, it matters little what views of the world are entertained, or what changes these views may undergo. But there is another, and happily an increasing class, who hold that it is the true destiny of mind to comprehend the vast order of existence in the midst of which it is placed, and that the faculties of man are divinely adapted to this sublime task; who see that the laws of nature must be understood before they can be obeyed, and that only through this understanding can man rise to the mastery of its powers, and bring himself into final harmony with his conditions. These will recognize that the discovery of new principles which expand, and elevate, and harmonize our views of the universe—which involve the workings of the mind itself, open a new chapter in philosophy, and touch the very foundations of knowledge, cannot be without a determining influence upon the future course and development of thought, and the spirit and methods of its acquisition. THE CORRELATION OF PHYSICAL FOECES. By W. R. GROVE, Q.C., M.A., F.R.S. FIEST AMEEI0AN', FROM THE FOURTH ENGLISH EDITION. William Robert Grove, an English lawyer and physicist, was born at Swansea, July 14, 1811. He graduated at Oxford in 1834, and during the next five years was Professor of Natural Philosophy at the London Insti- tution. Professor Grove is a rare example of the ability which has achieved a distinguished eminence in different fields of effort. While pursuing with marked success the profession of an advocate, he has devoted his leisure to original scientific researches, and obtained a high distinction both 13 u dis- coverei and a philosophic writer upon scientific subjects. In 1852 he waa made Queen's Counsel, and afterwards Vice-President of the Royal Society. He is the inventor of the powerful galvanic battery known by his name, and his chief researches have been in the field of electricity. Many of his ex- perimental results are referred to in the following pages, which will also attest his high position among the founders of the new philosophy of forces. PREFACE rrUJE Phrase ' Correlation of Physical Forces' in the sense in J. wnich I have used it, having become recognized by a large number of scientific writers, it would produce confusion were I now to adopt another title. It would, perhaps, have been better if I had in the first instance "used the term Co-relation, as the words ' correlate,' ' correlative,' had acquired a peculiar metaphys- ical sense somewhat differing from that which I attached to the substantive correlation. The passage in the text (p. 183) explains the meaning I have given to the term. Twenty years having elapsed since I promulgated the views contained in this Essay, which were first advanced in a lecture at the London Institution in January 1842, and subsequently more fully developed in a course of lectures in 1843,1 think it advisable to add a little to the Preface with reference to other labourers in the same field. It has happened with this subject as with many others, that similar ideas have independently presented themselves to differ- ent minds about the same period. In May 1842 a paper was published by M. Mayer which I had not read when my last edition was published, and indeed only now know imperfectly by the ticd-voce translation of a friend. It deduces very much the same conclusions to which I had been led, the author starting partly from A priori reasoning and partly from an experiment by which water was heated by agitation, and from another, which had, how- ever, previously been made by Davy, viz. that ice can be melted by friction, though kept in a medium which is below the freezing point of water. In 1843 a paper by Mr. Joule on the mechanical equivalent of 4 PREFACE. heat appeared, which, though not in terms touching on the mutual and necessary dependence of all the Physical Forces, yet bears most importantly upon the doctrine. While my third edition was going through the press I had the good fortune to make the acquaintance of M. Seguin, who informed me that his uncle, the eminent Montgolfier, had long entertained the idea that force was indestructible, though, with the exception of one sentence, in his paper on the hydraulic ram, and where he is apparently speaking of mechanical force, he has left nothing in print on the subject. Not so, however, M. Seguin himself, who in 1839, in a work on the ' Influence of Railroads,' has distinctly expressed his uncle's and his own views on the identity of heat and mechanical force, and has given a calculation of their equivalent relation, which is not far from the more recent numerical results of Mayer, Joule, and others. Several of the great mathematicians of a much earlier period advocated the idea of what they termed the Conservation of Force, but although they considered that a body in motion would so continue for ever, unless arrested by the impact of another body, and, indeed, in the latter case, would, if elastic, still continue to move (though deflected from its course) with a force proportion- ate to its elasticity, yet with inelastic bodies the general, and, as far as I am aware, the universal belief was, that the motion was arrested and the force annihilated. Montgolfier went a step far- ther, and his hydraulic ram was to him a proof of the truth of his preconceived idea, that the shock or impact of bodies left the mechanical force undestroyed. Previously, however, to the discoveries of the voltaic battery, electro-magnetism, thermo-electricity, and photography, it was impossible for any mind to perceive what, in the greater number of cases, became of the force which was apparently lost. The phenomena of heat, known from the earliest times, would have been a mode of accounting for the resulting force in many cases where motion was arrested, and we find Bacon announcing a theory that motion was the form, as he quaintly termed it, of heat. Rumford and Davy adopted this view, the former with a fair approximate attempt at numerical calculation, but no one of these philosophers seems to have connected it with the inde- structibility of force. A passage in the writings of Dr. Roget, PREFACE. 5 combating the theory that mere contact of dissii lilar bodies was the source of voltaic electricity, philosophically supports his argu- ment by the idea of non-creation of force. As I have introduced into the later editions of my Essay ab- stracts of the different discoveries which I have found, since my first lectures, to bear upon the subject, I have been regarded by many rather as the historian of the progress made in this branch of thought than as one who has had anything to do with its ini- tiation. Everyone is but a poor judge where he is himself inter- ested, and I therefore write with diffidence, but it would be affect- ing an indifference which I do not feel if I did not state that I believe myself to have been the first who introduced this subject as a generalised system of philosophy, and continued to enforce it in my lectures and writings for many years, during which it met with the opposition usual and proper to novel ideas. Avocations necessary to the well-being of others have prevent- ed my following it up experimentally, to the extent that I once hoped; but I trust and believe that this Essay, imperfect though it be, has helped materially to impress on that portion of the public which devotes its attention rather to the philosophy of science than to what is now termed science, the truth of the thesis advocated. To show that the work of to-day is not substantially different from the thoughts I first published on the subject, at a period when I knew little or nothing of what had been thought before, I venture to give a few extracts from the printed copy of my lecture of 1842 :— Physical Science treats of Matter, and what I shall to-night term ita Affections; namely, Attraction, Motion, Heat, Light, Electricity, Magnet- ism, Chemical-Affinity. When these re-act upon matter, they constitute Forces. The present tendency of theory seems to lead to the opinion that all these Affections are resolvable into one, namely, Motion; however, should the theories on these subjects be ultimately so effectually gener- alised as to become laws, they cannot avoid the necessity for retaining dif- ferent names for these different Affections; or, as they would then be called, different modes of Motion..... (Ersted proved that Electricity and Magnetism are two forces which act upon each other; not in straight lines, as all other known forces do, but in a rectangular direction: that is, that bodies invested with electricity, or the conduits of an electric-current, tend to place magnets at right angles to them ; and, conversely, that magnets teud to place bodie3 conducting dec- iricity at right angles to them. .... 6 PREFACE. The discovery of CErsted, by which electricity was made a source ol Magnetism, soon led philosophers to seek the converse effect; that is, to educe Electricity from a permanent magnet:—had these experimentalists succeeded in their expectations of making a stationary magnet a source of electric-currents, they would have realised the ancient dreams of perpetual motion, they would have converted statics into dynamics, they would have produced power without expenditure; in other words, they would have be- come creators. They failed, and Faraday saw their error; he proved that to obtain Electricity from Magnetism it was necessary to superadd to this latter, motion; that magnets while in motion induced electricity in con- tiguous conductors; and that the direction of such electric-currents was tangential to the polar direction of the magnet; that as Dynamic-electricity may be made the source of Magnetism and Motion, so Magnetismconjoined with Motion may be made the source of Electricity. Here originates the Science of Magneto-electricity, the true converse of Electro-magnetism; and thus between Electricity and Magnetism is shown to exist a reciprocity of force such that, considering either as the primary agent, the other be- comes the re-agent; viewing one in the relation of cause, the other is the effect..... The Science of Thermo-Electricity connected heat with electricity, and proved these, like all other natural forces, to be capable of mutual reac- tion..... Voltaic action is Chemical action taking place at a distance or trans- ferred through a chain of media; and the Daltonian equivalent numbers are the exponents of the amount of voltaic action for corresponding chemi- cal substances. . . . By regarding the quantity of electrical, as directly proportional to the efficient chemical action, and by experimentally tracing this principle, I have been fortunate enough to increase the power of the Voltaic-pile more than sixteen times, as compared with any combination previously known..... I am strongly disposed to consider that the facts of Catalysis depend upon voltaic action, to generate which three heterogeneous substances are always necessary. Induced by this belief I made some experiments on the subject, and succeeded in forming a voltaic combination by gaseous-oxygen, gaseous-hydrogen, and platinum; by which a galvanometer was deflected and water decomposed..... It appears to me that heat and light may be considered as affections; or, according to the Undulatory-theory, vibrations of matter itself, and not of a distinct etherial fluid permeating it: these vibrations would be prop- agated, just as sound is propagated bj vibrations of wood or as waves by water. To my mind, all the consequences of the Undulatory-theory flow as easily from this, as froir the hypothesis of a specific ether; to suppose which, namely, to suppose a fluid sui generis, and of extreme tenuity pene- trating solid bodies, we must assume, first, the existence of the fluid itself; secondly, that bodies are without exception porous; thirdly, that these pores communicate; fourthly, that matter is limited in expansibility. None of these difficulties apply to the modification of this theory which I venture to propose; and no other difficulty applies to it which does not equally apply to tho received hypothesis. With regard to the planetary Bpaces, the diminishing periods of comets is a strong argument for the ex- istence of an universally-diffused matter: this has the function of res'ut- PKEFACE. 7 ance, and there appears to be no reason to divest it of the functions com- mon to all matter, or superficially to appropriate it to certain affections. Again, the phenomena of transparency and opacity are, to my mind, more easily explicable by the former than by the latter theory; as resuliiuy from a difference in the molecular arrangement of the matter affected. In re- gard to the effects of double-refraction and polarisation, the molecular gives at once a reason for the effects upon the one theory, while upon the other we must, in addition to previous assumptions, further assume a dif- ferent elasticity of the ether in different directions within the doubly- refracting medium. The same theory is applicable to Electricity and Magnetism; my own experiments on the influence of the elastic intermedium on the voltaic-arc, and those of Faraday on electrical induction, furnish strong arguments in support of it. My inclination would lead me to de- tain you on this subject much longer than my judgment deems advisable: I therefore content myself with offering it to your consideration, and, should my avocations permit, I may at a future period more fully develope it. ... . Light, Heat, Electricity, Magnetism, Motion, and Chemical-affinity, are all convertible material affections; assuming either as the cause, one of the others will be the effect: thus heat may be said to produce electricity, electricity to produce heat; magnetism to produce electricity, electricity magnetism; and so of the rest. Cause and effect, therefore, in their ab- stract relation to these forces, are words solely of convenience: we are totally unacquainted with the ultimate generating power of each and all of them, and probably shall ever remain so; we can only ascertain the norma? of their action: we must humbly refer their causation to one omni- present influence, and content ourselves with studying their effects and developing by experiment their mutual relations. I have transposed the passages relating to voltaic action and catalysis, but I have not added a word to the above quotation, and, as far as I am now aware, the theory that the so-called im- ponderables are affections of ordinary matter, that they are re- solvable into motion, that they are to be regarded in their action on matter as forces, and not as specific entities, and that they are capable of mutual reaction, thence alternately acting as cause and effect, had not at that time been publicly advanced. My original Essays being a record of lectures, and being pub- lished by the managers of the Institution, I necessarily adhered to the form and matter which I had orally communicated. In preparing subsequent editions I found that, without destroying the identity of the work, I could not alter the style ; although it would have been less difficult and more satisfactory to me to have done so, the work would not have been a republication; and I was for obvious reasons anxious to preserve as far as I could the original text, which, though added to, is but little altered. The form of lectures has necessarily continued the use of tho 8 PREFACE. first person, and I would beg my readers not to attribute to me, from the modes of expression used, a dogmatism which is far from my thought. If my opinions are expressed broadly, it is that, if opinions are always hedged in by qualifications, the style becomes embarrassed and the meaning frequently unintelligible. As a course of lectures can only be useful by inducing the auditor to consult works on the subject he hears treated, so tho object of this Essay is more to in luce a particular train of thought on the known facts of physical science than to enter with minute criticisms into each separate branch. In one or two of the reviews of previous editions the general idea of the work was objected to. I believe, however, that will not now be the case; the. mathematical labours of Mr. Thompson, Clausius, and others, though not suitable for insertion in an Essay such as this, have awakened an interest for many portions of the subject, which promises much for its future progress. The short and irregular-intervals which my profession permits me to devote to science so prevent the continuity of attention necessary for the proper evolution of a train of thought, that I certainly should not now have courage to publish for the first time such an Essay; and it is only the favour it has received from those whose opinions I highly value, and the, I trust pardon- able, wish not to let some favourite thoughts of my youth lose all connection with my name, that have induced me to reprint it. My scientific readers will, I hope, excuse the very short notices of certain branches of science which are introduced, as without them the work would be unintelligible to many for whom it is intended. I have endeavoured so to arrange my matter that each division should form an introduction to those which follow, and to assume no more preliminary knowledge to be possessed by my readers than would be expected from persons acquainted with the elements of physical science. The notes contain references to the original memoirs in which the branches of science alluded to are to be found, as well as to those which bear on the main arguments; where these memoirs are numerous, or not easy of access, I have referred to treatises iu which they are collated. To prevent the reader's attention being interrupted, I have in the notes referred to the pages of the text, instead of to interpolated letters. COKRELATION OF PHYSICAL FOPtOES I.—INTRODUCTORY REMARKS. HEN natural phenomena are for the first ti nc ob- served, a tendency immediately developes itself to refer them to something previously known—to bring them within the range of acknowledged sequences. The mode of regarding new facts, which is most favourably received by the public, is that which refers them to recognised views- stamps them into the mould in which the mind has been al- ready shaped. The new fact may be far removed from those to which it is referred, and may belong to a different order of analogies, but this cannot then be known, as its co-ordi- nates are wanting. It may be questionable whether the mind is not so moulded by past events that it is impossible to advance an entirely new view, but admitting such possi- bility, the new view, necessarily founded on insufficient data, is likely to be more incorrect and prejudicial than even a strained attempt to reconcile the new discovery with known facts. The theory consequent upon new facts, whether it be a co-ordination of them with known ones, or the more difficult w 10 CORRELATION OF PHYSICAL FORCES. and dangerous attempt at remodelling the public ideas, is generally enunciated by the discoverers themselves of the facts, or by those to whose authority the world at the period of the discovery defers; others are not bold enough, or if they be so, are unheeded. The earliest theories thus enuncia- ted obtain the firmest hold upon the public mind, for at such a time there is no power of testing, by a sufficient range of experience, the truth of the theory; it is accepted solely or mainly upon authority: there being no means of contradic- tion, its reception is, in the first instance, attended with some degree of doubt, but as the time in which it can fairly be in- vestigated far exceeds that of any lives then in being, and as neither the individual nor the public mind will long tolerate a state of abeyance, a theory shortly becomes, for want of a better, admitted as an established truth: it is handed from father to son, and gradually takes its place in edu- cation. Succeeding generations, whose minds are thus formed to an established view, are much less likely to aban- don it. They have adopted it in the first instance, upon au- thority, to them unquestionable, and subsequently to yield up their faith would involve a laborious remodelling of ideas, a task which the public as a body will and can rarely under- take, the frequent occurrence of which is indeed inconsistent with the very existence of man in a social state, as it would induce an anarchy of thought—a perpetuity of mental revo- lutions. This necessity has its good; but the prejudicial effect upon the advance of science is, that by this means, theories the most immature frequently become the most permanent; for no theory can be more immature, none is likely to be so in- correct, as that which is formed at the first flush of a new discovery; and though time exalts the authority of those from whom it emanated, time can never give to the illustri- ous dead the means of analysing and correcting erroneous vicT?s which subsequent discoveries confer. INTRODUCTORY REMARKS. U Take for instance the Ptolemaic System, which we may almost literally explain by the expression of Shakspeare: ' He that is giddy thinks the world turns round.' Yf e now Bee the error of this system, because Ave have all an immedi- ate opportunity of refuting it; but this identical error was received as a truth for centuries, because, when first promul- gated, the means of refuting it were not at hand, and when the means of its refutation became attainable, mankind had been so educated to the supposed truth, that they rejected the proof of its fallacy. I have premised the above for two reasons : first to obtain a fair hearing, by requesting as far as possible a dismissal from the mind of my readers of preconceived views by and in favour of which all are liable to be prejudiced ; and secondly, to defend myself from the charge of undervaluing authority, or treating lightly the opinions of those to whom and to whose memory mankind looks with reverence. Properly to value authority, Ave should estimate it together with its means of information : if' a dwarf on the shoulders of a giant can see further than the giant,' he is no less a dAvarf in compari- son •with the giant. The subject on which I am about to treat—viz., the rela- tion of the affections of matter to each other and to matter— peculiarly demands an unprejudiced regard. The different aspects under Avhich these agencies have been contemplated ; the different views which have been taken of matter itself; the metaphysical subtleties to which these views unavoidably hod, if pursued beyond fair inductions from existing expe- rience, present difficulties almost insurmountable. The extent of claim which my views on this subject may have to originality has been stated in the Preface ; they be- came strongly impressed upon my mind at a period when I was much engaged in experimental research, and were, as I then believed, and ^till believe, regarding them as a system, new : expressions in the works of different authors, hearing 12 CORRELATION OF PHYSICAL FORCES. more or less on the subject, have subsequently been pointed out to me. some of which go back to a distant period. An attempt to analyse these in detail, and to trace how far I have been anticipated by others, would probably but little interest the reader, and in the course of it I should constantly have to make distinctions showing wherein I differed, and wherein I agreed with others. I might cite authorities which appear to me to oppose, and others which appear to coincide with certain of the views I have put forth; but this would interrupt the consecutive developement of my own ideas, and might render me liable to the charge of misconstruing those of others ; I therefore think it better to avoid such discussion in the text; and in addition to the sketch given in the Preface, to furnish in the notes at the conclusion such references to different authors as bear upon the subjects treated of, which I have discovered, or which have been pointed out to me since the delivery of the lectures of AA-hich this essay is a record. The more extended our research becomes, the more we find that knowledge is a thing of slow progression, that the very notions which appear to ourselves new, have arisen, though perhaps in a very indirect manner, from successive modifications of traditional opinions. Each word we utter, each thought we think, has in it the vestiges, is in itself the impress, of antecedent words and thoughts. As each ma- terial form, could we rightly read it, is a book, containing in itself the past history of the world; so, different though our philosophy may now appear to be from that of our progeni- tors, it is but theirs added to or subtracted from, transmitted drop by drop through the filter of antecedent, as ours will be through that of subsequent, ages.—The relic is to the past as is the germ to the future. Though many valuable facts, and correct deductions from them, are to be found scattered amongst the voluminous works of the ancient philosophers ; yet, giving them tho INTRODUCTORY REMARKS. 13 credit which they pre-eminently deserve for having devoted their lives to purely intellectual pursuits, and for having thought, seldom frivolously, often profoundly, nothing can be more difficult than to seize and apprehend the ideas of those who reasoned from abstraction to abstraction—who, although, as we noAV believe, they must have depended upon observa- tion for their first inductions, afterwards raised upon them such a complex superstructure of syllogistic deductions, that, without following the same paths, and tracing the same sinu- osities which led them to their conclusions, such conclusions are to us unintelligible. To think as another thought, we must be placed in the same situation as he was placed: the errors of commentators generally arise from their reasoning upon the arguments of their text, either in blind obedience to its dicta, Avithout considering the circumstances under which they were uttered, or in viewing the images presented to the original writer from a different point to that from which he viewed them. Experimental philosophy keeps in check the errors both of « priori reasoning and of commentators, and, at all events, prevents their becoming cumulative; though the theories or explanations of a fact be different, the fact remains the same. It is, moreover, itself the exponent of its discoverer's thought: the observation of known phenomena has led him to elicit from nature the new phenomena : and, though he may be wrong in his deductions from this after its discovery, the reasonings which conducted him to it are them selves valuable, and, having led from known to unknown truths, can seldom be uninstructive. Very different views existed amongst the ancients as to tho aims to be pursued by physical investigation, and as to the obj ects likely to be attained by it. I do not here mean the moral ob- jects, such as the attainment of the summum bonum, &c. —but the acquisitions in knowledge which such investiga- tions were likely to confer. Utility Avas one object in view, and this was to some extent attained by the progress made in 14 CORRELATION OF PHYSICAL FORCES. astronomy and mechanics ; Archimedes, for instance, seema to have constantly had this end in vieAV; but, -while pursuing natural knowledge for the sake of knowledge and the power Avhich it brings with it, the greater number seemed to enter- tain an expectation of arriving at some ultimate goal, some point of knowledge, which Avould give them a mastery over the mysteries of nature, and would enable them to ascertain what Avas the most intimate structure of matter, and the causes of the changes it exhibits. Where they could not dis- cover, they speculated. Leucippus, Democritus, and others, have given us their notions of the ultimate atoms of which matter was formed, and of the modus agendi of nature in the various transformations which matter undergoes. The expectation of arriving at ultimate causes or essences continued long after the speculations of the ancients had been abandoned, and continues even to the present day to be a very general notion of the objects to be ultimately attained by physical science. Francis Bacon, the great remodeller of science, entertained this notion, and thought that, by experi- mentally testing natural phenomena, we should be enabled to trace them to certain primary essences or causes Avhence the various phenomena flow. These he speaks of under the scholastic name of ' forms '—a term derived from the ancient philosophy, but differently applied. He appears to have un- derstood by ' form' the essence of quality—that in Avhich, ab- stracting everything extraneous, a given quality consists, or that Avhich, superinduced on any body, would give it its pe- culiar quality: thus the form of transparency, is that which constitutes transparency, or that by which, when dis- covered, transparency could be produced or superinduced. To take a specific example of what I may term the syn- thetic application of his philosophy:—' In gold there meet together yelloAvness, gravity, malleability, fixedness in the fire, a determinate way of solution, which are the simple natures in gold: for he who understands form, and the manner of INTRODUCTORY REMARKS. 15 superinducing this yelkrwne.:;, gravity, ductility, fixedness. faculty of fusion, solution, &c, with their particular degrees and proportions, Aviil consider how to join them together in some body, so that a transmutation into gold shall folloAv.' On the other hand, the analytic method, or, ' the enquiry from what origin gold or any other metal or stone is generated from its first fluid matter or rudiments, up to a perfect min- eral,' is to be perceived by Avhat Bacon calls the latent pro- cess, or a search for ' what in every generation or transfor- mation of bodies, flies off, what remains behind, what is add- ed, Avhat separated, &c. ; also, in other alterations and mo- tion?, Avhat gives motion, what governs it, and the like.' Bacon appears to have thought that qualities separate from the substances themselves were attainable, and if not capable of physical isolation, were at all events capable of physical transference and superinduction. Subsequently to'Bacon a belief has generally existed, and now to a great extent exists, in what are called secondary causes, or consequential steps, wherein one phenomenon is supposed necessarily to hang on another, until at last Ave ar- rive at an essential cause, subject immediately to the First Cause. This notion is generally prevalent both on the Con- tinent and in this country: nothing is more familiar than the expression ' study the effects in order to arrive at the causes.' Ii! Lead of regarding the proper object of physical science as a search after essential causes, I believe it "ought to be, and must be, a search after facts and relations—that although the word Cause may be used in a secondary and concrete sense, as meaning antecedent forces, yet in an abstract sense it is to- tally inapplicable ; we cannot predicate of any physical agency that it is abstractedly the cause of another ; and if, for the sake of convenience, the language of secondary causation be per- missible, it should be only with reference to the special phe- nomena referred to, as it can never be generalised. The misuse, or rather varied uee, of the term Cau.-o, hag 16 CORRELATION OF PHYSICAL FORCES. been a source of great confusion in physical theories, and philosophers arc even now by no means agreed as to theii conception of causation. The most generally received view of causation, that of Hume, refers it to invariable antecedence —i. e., we call that a cause which invariably precedes, that an effect which invariably succeeds. Many instances of in- variable sequence might however be selected, which do not present the relation of cause and effect: thus as Reed observes, and Brown does not satisfactorily answer, day invariably precedes night and yet day is not the cause of night. The seed, again, precedes the plant, but is not the cause of it; so that when we study physical phenomena it becomes difficult to separate the idea of causation from that of force, and these have been regarded as identical by some philosophers. To take an example which will contrast these two views : if a floodgate be raised, the water flows out; in ordinary parlance, the water is said to flow be- cause the floodgate is raised: the sequence is invariable ; no floodgate, properly so called, can be raised without the water flowing out, and yet in another, and perhaps more strict, sense, it is the gravitation of the water which causes it to flow. But though we may truly say that, in this instance, gravitation causes the water to flow, we cannot in truth abstract the pro- position, and say, generally, that gravitation is the cause of water flowing, as water may flow from other causes, gaseous elasticity, for instance, which will cause water to flow from a receiver full of air into one that is exhausted ; gravitation may also, under certain circumstances, arrest instead of cause the flow of water. Upon neither view, however, can we get at anything like abstract causation. If we regard causation as invariable se- quence, we can find no case in which a given antecedent is the only antecedent to a given sequent: thus if water could floAv from no other cause than the withdrawal of a floodgate, we might say abstractedly that this was the cause of water flowing. If, again, adopting the view which looks to causa- INTRODUCTORY REMARKS. 17 tion as a force, Ave could say that water could be caused to flow only by gravitation, we might say abstractedly that grav- itation was the cause of water floAving—but this wTe cannot say; and if we seek and examine any other example, we shall find that causation is only predicable of it in the partic- ular case, and cannot be supported as an abstract proposition ; yet this is constantly attempted. Nevertheless, in each par- ticular case Avhere Ave speak of Cause, we habitually refer to some antecedent power or force : we never see motion or any change in matter take effect Avithout regarding it as produced by some previous change ; and when we cannot trace it to its antecedent, Ave mentally refer it to one ; but whether this hab- it be philosophically correct is by no means clear. In other words, it seems questionable, not only whether cause and ef- fect are convertible terms with antecedence and sequence, but Avhether in fact cause does precede effect, Avhether force does precede the change in matter of which it is said to be the cause. The actual priority of cause to effect has been doubted, and their simultaneity argued with much ability. As an in- stance of this argument it may be said, the attraction which causes iron to approach the magnet is simultaneous with and ever accompanies the movement of the iron ; the movement is evidence of the co-existing cause or force, but there is no evidence of any interval in time between the one and the oth- er. On this vieAv time would cease to be a necessary element in causation ; the idea of cause, except perhaps as referred to a primeval creation, would cease to exist; and the same ar- guments which apply to the simultaneity of cause with effect would apply to the simultaneity of Force Avith Motion. We could not, however, even if we adopted this vicAv, dispense with the element of time in the sequence of phenomena; the effect being thus regarded as ever accompanied simultaneous- ly by its appropriate cause, Ave should still refer it to some an- tecedent effect; and our reasoning as applied to the succes- sive production of all natural changes would be the same. 18 CORRELATION OF PHYSICAL FORCES. Habit and the identification of thoughts with phenomena so compel the use of recognised terms, that Ave cannot avoid using the word cause even in the sense to which objection is taken ; and if we struck it out of our vocabulary, our lan- guage, in speaking of successive changes, would be unintelli- gible to the present generation. The common error, if I am right in supposing it to be such, consists in the abstraction of cause, and in supposing in each case a general secondary cause—a something which is not the first cause, but which, if we examine it carefully, must have^ill the attributes of a first cause, and an existence independent of, and dominant over, matter. The relations of electricity and magnetism afford us a very instructive example of the belief in secondary causa- tion. Subsequent to the discovery by Oersted of electro-mag- netism, and prior to that by Faraday of magneto-electricity, electricity and magnetism were believed by the highest author- ities to stand in the relation of cause and effect—i. e. elec- tricity was regarded as the cause, and magnetism as the effect; and where magnets existed without any apparent electrical currents to cause their magnetism, hypothetical currents were supposed, for the purpose of carrying out the caus- ative view; but magnetism may now be said with equal truth to be the cause of electricity, and electrical currents may be referred to hypothetical magnetic lines : if therefore electricity cause magnetism, and magnetism cause electricity, Avhy then electricity causes electricity, which becomes, so to speak, a reductio ad absurdum of the doctrine. To take another instance, which may render these posi- tions more intelligible. By heating bars of bismuth and anti- mony in contact, a current of electricity is produced; and if their extremities be united by a fine wire, the wire is heated. Now here the electricity in the metals is said to be caused by heat, and the heat in the wire to be caused by electricity. and in a concrete sense this is true ; but can we thence say INTRODUCTORY REMARKS. 19 abstractedly that heat is the cause of electricity, or that elec- tricity is the cause of heat ? Certainly not; for if either be true, both must be so, and the effect then becomes the cause of the cause, or, in other words, a thing causes itself. Any other proposition on this subject will be found to involve sim- ilar difficulties, until, at length, the mind will become con- vinced that abstract secondary causation does not exist, and that a search after essential causes is vain. The position Avhich I seek to establish in this Essay is, that the various affections of matter which constitute the main objects of experimental physics, viz., heat, light, elec- tricity, magnetism, chemical affinity, and motion, are all cor- relative, or have a reciprocal dependence ; that neither, taken abstractedly, can be said to be the essential cause of the oth- ers, but that cither may produce or be convertible into, any of the others : thus heat may mediately or immediately produce electricity, electricity may produce heat; and so of the rest, each merging itself as the force it produces becomes devel- oped : and that the same must hold good of other forces, it be- ing an irresistible inference from observed phenomena that a force cannot originate otherwise than by devolution from some pre-existing force or forces. The term force, although used in very different senses by different authors, in its limited sense may be 'defined as that Avhich produces or resists motion. Although strongly inclined to believe that the other affections of matter, which I have above named, are, and will ultimately be resolved into, modes of motion, many arguments for Avhich will be given in subse- quent parts, of this Essay, it would be going too far, at pre- sent, to assume their identity with it; I therefore use the term force in reference to them, as meaning that active principle inseparable from matter which is supposed to induce its vari* ous changer. The word force and the idea it aims at expressing might be objected to by the purely physical philosopher on similar 20 CORRELATION OF PHYSICAL FORCES. grounds to those which apply to the Avord cause, as it repre- sents a subtle mental conception, and not a sensuous percep- tion or phenomenon. The objection would take something of this form. If the string of a bent bow be cut, the bow will straighten itself; we thence say there is an elastic force in the bow which straightens it; but if we applied our expres- sions to this experiment alone, the use of the term force would be superfluous, and would not add to our knowledge on the subject. All the information which our minds could get would be as sufficiently obtained from the expression, when the string is cut, the bow becomes straight, as from the expression, the bow becomes straight by its elastic force. Do we know more of the phenomena, viewed Avithout refer- ence to other phenomena, by saying it is produced by force? Certainly not. All we know or see is the effect; Ave do not see force—Ave see motion or moving matter. If now Ave take a piece of caoutchouc and stretch it, Avhen released it returns to its original length. Here, though the subject-matter is very different, we see some analogy in the effect or phenomenon to that of the strung bow. If again we suspend an apple by a string, cut the string, the apple falls. Here, though it is less striking, there is still an analogy to the strung bow and the caoutchouc. Now when the Avord force is employed as comprehending these three different phenomena we find some use in the term, not by its explaining or rendering more intelligible the modus agendi of matter, but as conA-eying to the mind something which is alike in the three phenomena, however distinct they may be in other respects : the word becomes an abstract or generalised expression, and regarded in this light* is of hi^h utility. Although I have given only three examples, it is obvious that the term would equally apply to 300 or 3,000 ex- amples. But it will be said, the term force is used not as express- ing the effect, but as that Avhich produces the effect. This is INTRODUCTORY REMARKS. 21 true, and in this its ordinary sense I shall use it in these pages. But though the term has a potential meaning, to depart from which Avould render language unintelhgible, we must guard against supposing that we know essentially more of the phe nomena by saying they are produced by something, which something is only a word derived from the constancy and similarity of the phenomena we seek to explain by it. The relations of the phenomena to which the terms force or forces • are applied give us real knowledge ; these relations may be called relations of forces ; our knowledge of them is not there- by lessened, and the convenience of expression is greatly in creased, but the separate phenomena are not more intimately known ; no further insight into Avhy the apple falls is acquired by saying it is forced to fall, or it falls by the force of gravita tion; by the latter expression we are enabled to relate it most usefully to other phenomena, but we still know no more of the particular phenomenon than that under certain circum- stances the apple does fall. In the ahpve illustrations, force has been treated as the producer of motion, in which case the evidence of the force is the motion produced ; thus we estimate the force used to pro- ject a cannon ball in terms of the mass of matter, and the velocity with which it is projected. The evidence of force when the term is applied to resistance to motion is of a some- what different character ; the matter resisting is molecularly. affected, and has its structure*more or less changed; thus a strip of caoutchouc to which a weight is suspended is elonga- ted, and its molecules are displaced as compared with their position when unaffected by the gravitating force. So a piece of glass bent by an appended Aveight has its whole structure changed; this internal change is made evident by transmit- ting through it a beam of polarised light: a relation thus becomes established between the molecular state of bodies and the external forces or motion of masses. Every particle of the caoutchouc or glass must be acting and contributing to 22 CORRELATION OF PHYSICAL FORCE?. resist or arrest the motion of the mass of matter appended to it. It is difficult, in such cases, not to recognise a reality in force. We need some word to express this state of tension ; we know that it produces an effect, though the effect be nega- tive in character : although in this effort of inanimate matter we can no more trace the mode of action to its ultimate ele- ments than we can follow out the connection of our own muscles with the volition which calls them into action, we m are experimentally convinced that matter changes its state by the agency of other matter, and this agency we call force. In placing the Aveight on the glass, we have moved the former to an extent equivalent to that which it would again describe if the resistance were removed, and this motion of the mass becomes an exponent or measure of the force exert- ed on the glass; wrhile this is in the state of tension, the force is ever existing, capable of reproducing the original motion, and while in a state of abeyance as to#actual motion, it is really acting on the glass. The motion is suspended, but the force is not annihilated. But it may be objected, if tension or static force be thus motion in abeyance, there is at all times a large amount of dynamical action subtracted from the universe. Every stone upon a hill, every spring that is bent, and has required force to upraise or bend it, has for a time, and possibly for ever, withdrawn this force, and annihilated it. Not so; what takes place when we raise a weight and leave it at the point to which it has been elevated ? we have changed the centre of gravity of the earth, and consequently the earth's position with reference to the sun, planets, and stars; the effort we nave made pervades and shakes the universe; nor can we present to the mind any exercise of force, which is thus not permanent in its dynamical effects. If, instead of one Aveight being raised, we raise two weights, each placed at a point INTRODUCTORY REMARKS. 23 diametrically opposite the other, it would be said, here you have compensation, a balance, no change in the centre of gravity of the earth ; but Ave have increased the mean diame- ter of the earth, and a perturbation of our planet, and of all other celestial bodies necessarily ensues. The force may be said to be in abeyance with reference to the effect it would have produced, if not arrested, or placed in a state of tension ; but in the act of imposing this state, the relations of equilibrium with other bodies have been changed, and these move in their turn, so that motion of the same amount would seem to be ever affecting matter conceived in its totality. Press the hands violently together; the first notion may be that this is poAver locked up, and that no change ensues. Not so ; the blood courses more quickly, respiration is accele- rated, changes Avhich we may not be able to trace, take place in the muscles and nerves, transpiration is increased; we have given off force in various ways, and must, if the effort be prolonged, replenish our sources of power, by fresh chemi- cal action in the stomach. In books which treat of statics and dynamics, it is com- mon and perhaps necessary to isolate the subjects of consid- eration ; to suppose, for instance, two bodies gravitating, and to ignore the rest of the universe. But no such isolation ex- ists in reality, nor could we predict the result if it did exist. Would two bodies gravitate towards each other in empty space, if space can be empty ? the notion that they would is founded on the theory of attraction, which NeAvton himself repudiated, further than as a convenient means of regard- ing the subject. For purposes of instruction or argument it may be convenient to assume isolated matter: many con- clusions so arrived at may be true, but many will be erroneous. If, in producing effects of tension fir of static force, the effort made pervades the universe, it may be said, when the 24 CORRELATION OF PHYSICAL FORCES. bent spring is freed, when the raised Aveight falls, a converse series of motions must be effected, and this theory Avould lead to a mere reciprocation, which Avould be equally unproduc- tive of permanent change with the annihilation of force. If raising the weight has changed the centre of gravity of the earth, and thence of the universe, the fall of the weight, it will be said, restores the original centre of gravity, and every- thing comes back to its original status. In this argument we again, in thought, isolate our experiment; we neglect sur- rounding circumstances. Between the time of the raising and falling of the weight, be the interval never so small, nay, more, during the rising and during the fall, the earth has been going on revolving round its axis and round the sun, to say nothing of other changes, such as temperature, cosmical magnetism, &c, which we may call accidental, but which, if Ave kneAV all, would probably be found to be as necessary and as reducible to law as the motion of the earth. A change having taken place, the fall of the weight does not bring back the status quo, but other changes supervene, and so on. Nothing repeats itself, because nothing can be placed again in the same condition: the past is irre- vocable. II.—MOTION. MOTION—which has been taken as the main exponent of force in the above examples—is the most obvious, the most distinctly conceived of all the affections of matter. Visible motion, or relative change of position in space, is a phenomenon so obvious to simple apprehension, that to at- tempt to define it would be to render it more obscure ; but Avith motion, as with all physical appearances, there are cer- tain Aanishing gradations or undefined limits, at which the obvious mode of action fades away ; to detect the continu- ing existence of the phenomena we are obliged to have re- course to other than ordinary methods of investigation, and we frequently apply other and different names to the effects so recognised. Thus sound is motion; and although in the earlier pe- riods of philosophy the identity of sound and motion was not traced out, and they were considered distinct affections of matter—indeed, at the close of the last century a theory was advanced that sound was transmitted by the vibrations of an ether—we now so readily resolve sound into motion, that to those who are familiar with acoustics, the phenomena of sound immediately present to the mind the idea of motion, J, e. motion of ordinary matter. Again, Avith regard to light: no doubt now exists that li°ht moves or is accompanied by motion. Here the phe- 2 20 CORRELATION OF PHYSICAL FORCES. nomena of motion are not made evident by the ordinary sen- suous perception, as for instance the motion of a visibly mov- ing projectile would be, but by an inverse deduction from known relations of motion to time and space : as all observa- tion teaches us that bodies in moA-ing from one point in space to another occupy time, we conclude that, whereA*er a con- tinuing phenomenon is rendered evident in two different points of space at different times, there is motion, though we cannot see the progression. A similar deduction convinces us of the motion of electricity. As we in common parlance speak of sound moving, although sound is motion, it requires no great stretch of imagination to conceive light and electricity as motion?, and not as things moving. If one end of a long bar of metal be struck, a sound is soon perceptible at the other end. This we now know to be a vibration of the bar ; sound is but a word expressive of the mode of motion impressed on the bar; so one end of a column of air or glass subjected to a luminous im- pulse gives a perceptible effect of hght at the other end : this can equally be conceived to be a vibration or transmitted Snotion of particles in the transparent column : this question Ivill, however, be further discussed hereafter ; for the present Ave Avill confine ourselves to motion Avithin the limits to which the term is usually restricted. With the perceptible phenomena of motion the mental conception has been invariably associated to which I have before alluded, and to which the term force is given__ the which conception, when atc analyse it, refers us to some antecedent motion. If we except the production of motion by heat, light, &c, Avhich Avill be considered in tho sequel, A^hen we see a body moving Ave look to motion hav- ing been communicated to it by matter which has previously moved. Of absolute rest Nature gives us no evidence : all matter, as far as we can ascertain, is ever in movement, not merely MOTION. 27 in masses, as with the planetary spheres, but also mole- cularly, or throughout its most intimate structure : thus every alteration of temperature produces a molecular change throughout the whole substance heated or cooled; slow chemical or electrical actions, actions of light or- invisible radiant forces, are always at play, so that as a fact we can- not predicate of any portion of matter that it i3 absolutely at rest. Supposing, hoAveA-er, that motion is not an indispensa- ble function of matter, but that matter can be at rest, matter at rest would neA-er of itself cease to be at rest; it would not move unless impelled to such motion by some other moving body, or body Avhich has moved. This proposition applies not merely to impulsive motion, as Avhen a ball at rest is struck by a moving body, or pressed by a spring which has previously been moAred, but to motion caused by attractions such as magnetism or gravitation. Suppose a piece of iron at rest in contact Avith a magnet at rest; if it be desired to moAre the iron by the attraction of the magnet, the magnet or the iron dk::-t first be moved ; so before a body falls it must first be rai.cd. A body at rest would therefore continue so for ever, and a body once in motion would continue so for ever, in the same direction and with the same velocity, un- less impeded by some other body, or affected by some other force than that which originally impelled it. These propo- sitions may seem somewhat arbitrary, and it has been doubted Avhether they are necessary truths ; they have for a long time been received as axioms, and there can at all events be no harm in accepting them as postulates. It is however very generally believed that if the Aisibie or palpable motion of duo body be arrested by impact on another body, the mo- tion ceases, and the force Avhich produced it is annihi- lated. Now tlie view which I A-enture to submit is, that force cannot be annihilated, but L merely subdivided or altered in direction or character. First, as to direction. Wave your 28 CORRELATION OF PHYSICAL FORCES. hand: the motion, which has apparently ceased, is taken up by the air, from the air by the walls of the room, &c, and so by direct and reacting Avaves, continually comminuted, but never destroyed. It is true that, at a certain point, Ave lose all means of detecting the motion, from its minute subdivi- sion, which defies our most delicate means of appreciation but Ave can indefinitely extend our power of detecting it ac- cording as we confine its direction, or increase the delicacy of our examination. Thus, if the hand be moved in uncon- fined air, the motion of the air would not be sensible to a per- son at a few feet distance ; but if a piston of the same extent of surface as the hand be moved Avith the same rapidity in a tube, the blast of air may be distinctly felt at several yards distance. There is no greater absolute amount of motion in the air in the second than in the first case, but its direction is restrained, so to make the means of detection more facile. By carrying on this restraint, as in the air-gun, we get a power of detecting the motion, and of moving other bodies at far greater distances. The puff of air which Avould in the air-gun project a bullet a quarter of a mile, if allowed to es- cape without its direction being restrained, as by the bursting of a bladder, Avould not be perceptible at a yard distance, though the same absolute amount of motion be impressed on the surrounding air. It may, however, be asked, what becomes of force Avhen motion is arrested or impeded by the counter-motion of another body ? This is generally believed to produce rest, or entire destruction of motion, and consequent annihilation of force: so indeed it may, as regards the mo'tion of the masses, but a new force, or new character of force, noAV ensues, the expo- nent of which, instead of visible motion, is heat. I venture to regard the heat Avhich results from friction or percussion as a continuation of the force which was previously associa- ted Avith the moving body, and which, when this impinges on MOTION. 29 another body, ceasing to exist as gross, palpable motion, con tinues to exist as heat. Thus, let two bodies, A and B, be supposed to move in opposite directions (putting for the moment out of question all resistance, such as that of the air, &c), if they pass each other without contact each Aill move on for ever in its re- spective direction with the same velocity, but if they touch each other the velocity of the movement of each is reduced, and each becomes heated : if this contact be slight, or such as to occasion but a slight diminution of their velocity, as when the surfaces of the bodies are oiled, then the heat is slight; but if the contact be such as to occasion a great diminution of motion, as in percussion, or as Avhen the surfaces are roughened, then the heat is great, so that in all cases the re- sulting heat is proportionate to the diminished velocity. AY here, instead of resisting and consequently impeding the motion of the body A, the body B gives Avay, or itself takes up the motion originally communicated to A, then avc haATe less heat in proportion to the motion of the body B, for here the operation of the force continues in the form of palpable motion : thus the heat resulting from friction in the axle of a Avheel is lessened by surrounding it by rollers ; these take up the primary motion of the axle, and the less, by this means, the initial motion is impeded, the less is the resulting heat. Again, if a body move in a fluid, although some heat is pro- duced, the heat is apparently trifling, because the particles of the fluid themselves move, and continue the motion originally communicated to the moving body : for every portion of mo- tion communicated to them this loses an equivalent, and Avherc both lose, then an equivalent of heat results. As the converse of this proposition, it should folloAV that the more rigid the bodies impinging on each other the greater should be the amount of heat developed by friction, and so we find it. Flint, steel, hard stones, glass, and metals, are those bodies which give the greatest amount of heat from 30 CORRELATION OF PHYSICAL FORCES. friction or percussion ; while water, oil, &c, give little or no heat, and from the ready mobility of their particles lessen its developement Avhen interposed between rigid moving bodies. Thus, if Ave oil the axles of wheels, we have more rapid mo- tion of the bodies themselves, but less heat; if Ave increase the resistance to motion, as by roughening the points of con- tact, so that each particle strikes against and impedes the motion of others, then Ave have diminished motion, but in- creased heat; or if the bodies be smooth, but instead of slid- ing past each other be pressed closely together and then rubbed, we shall in many cases evolve more heat than by the roughened bodies, as we get a greater number of particles in contact and a greater resistance to the initial motion. I can- not present to my mind any case of heat resulting from fric- tion which is not explicable by this vieAV : friction, according to it, is simply impeded motion. The greater the impedi- ment, the more force is required to overcome it, and the greater is the resulting heat; this resulting heat being a con- tinuation of indestructible force, capable, as Ave shall pres- ently see, of reproducing palpable motion, or motion of defi- nite masses. Whatever be the nature of the bodies, rough or smooth, solid or liquid, provided there be the same initial force, and the whole motion be ultimately arrested, there should be the same amount of heat developed, though Avhere the motion is carried on through a great number of points of matter avc do not so sensibly perceive the resulting heat from its greater dissipation. The friction of fluids produces heat, an effect first noticed I believe by Mayer. The total heat produced by the friction of fluids should, therefore, it will be said, be equal to that produced by the friction of solids ; for although each particle produces little heat, the motion being readily taken up by the neighbouring particles, yet by the time the whole mass has attained a state of rest there has been the same impeding of the initial motion as by the friction of sol- MOTION. 31 ids if produced by the same initial force. If the heat be Ariewed in the aggregate, and alloAvance be made for the spe cific thermal capacity of the substances employed, it probably is the same, though apparently less ; the heat in the case of solids being manifested at certain defined points, while in that of fluids it is dissipated, both the time and space during and through which the motion is propagated differ in the two cases, so that the heat in the latter case is more readily car- ried off by surrounding bodies. If the body be elastic, and by its reaction the motion im- pressed on it by the initial force be continued, then the heat is proportionately less ; and were a substance perfectly elas- tic, and no resistance opposed to it by the air or other mat- ter, then the movement once impressed would be perpetual, and no heat would result. A ball of caoutchouc bandied about for many minutes between a racket and a wall is not perceptibly heated, Avhile a leaden bullet projected by a gun against a wall is rendered so hot as to be intolerable to the touch: in the former case, the motion of the mass is contin- ued by the reaction due to its elasticity; in the latter, the motion of the mass is extinguished, and heat ensues. A pendulum started in the exhausted receiver of an air- pump continues its oscillation for hours or even days; the friction at its point of suspension and the resistance of the air is minimised, and the heat is imperceptible, but these tri- fling resistances in the end arrest the motion of the mass, the one giving it out as heat, the other conveying the force to the receiver, and thence to surrounding bodies. Similar reason- ing may be applied to the oscillation of a coiled spring and balance wheel. To wind up a clock a certain amount of force is expended by the arm; this force is given back by the descent of the weight, the wheels move, the pendulum is kept oscillating, heat is generated at each point of friction, and the surround- ing air is set in motion, a part of Avhich is made obvious to 32 CORRELATION OF PHYSICAL FORCES. us by the ticking sound. But it Avill be said, if instead of alloAving the weight to act upon the machinery, the cord by which it is suspended be cut, the weight drops and the force is at an end. By no means, for in this case the house is shaken by the concussion, and thus the force and motion are continued, while in the former case the weight reaches the ground quietly, and no evidence of force or motion is mani- fested by its impact, the whole having been previously dissi- pated. If the injtial motion, instead of being arrested by the im- pact of other bodies, as in friction or percussion, is impeded by confinement or compression, as where the dilatation of a gas is prevented by mechanical means, heat equally results : thus if a piston is used to compress air in a closed vessel, the compressed air and, from it, the sides of the vessel will be heated: the air being unable to take up and carry on the original motion communicates molecular motion or expansion to all bodies in contact with it; and, conversely, if we ex- pand air by mechanical motion, as by withdraAving the pis- ton, cold is produced. So when a solid has its particles com- pressed or brought nearer together, as Avhen a bar of iron is hammered, heat is produced beyond that Avhich is due to per- cussion alone. In this latter case Ave cannot very easily ef- fect the converse result, or produce cold by the mechanical dilatation of a solid, though the phenomena of solution, Avhere the particles of a solid are detached from each other, or drawn more widely asunder, give us an approximation to it: in the case of solution cold is produced. We are from a very extensive range of observation and experiment entitle**! to conclude that, with some curious ex- ceptions to be presently noticed, whenever a body is com- pressed or brought into smaller dimensions it is heated, i. e. it expands neighbouring substances. Whenever it is dilated or increased in volume it is cooled, or contracts neighbourin" substances. MOTION. 33 Mr. Joule has made a great number of experiments for the purpose of ascertaining what quantity of heat is produced by a given mechanical action. His mode of experimenting is as follows. An apparatus formed of floats or paddles of brass or iron is made to rotate in a bath of Avater or mercu- ry. The power Avhich gives rise to this rotation is a weight raised like a clock-weight to a certain height; this by acting during its fall on a spindle and pulley communicates motion to the paddle-Avheel, the Avater or mercury serving as a fric- tion medium and calorimeter ; and the heat is measured by a delicate mercurial thermometer. The results of his experi- ments he considers prove that a fall of 772 lbs. through a space of one foot is able to raise the temperature of one pound of water through one degree of Fahrenheit's thermon> eter. Mr. Joule's experiments are of extreme delicacy—he tabulates to the thousandth part of a degree of Fahrenheit, and a large number of his thermometric data are compre- hended within the limits of a single degree. Other experi- menters have given very different numerical results, but the general opinion seems to be that the numbers given by Mr. Joule are the nearest approximation to the truth yet obtained. Hitherto I have taken no distinction as to the physical character of the bodies impinging on each other; but Nature gives us a remarkable difference in the character or mode of the force eliminated by friction, accordingly as the bodies which impinge are homogeneous or heterogeneous: if the \ former, heat alone is produced ; if the latter, electricity. We find, indeed, instances given by authors, of electricity resulting from the friction of homogeneous bodies ; but, as I stated in my original Lectures, I have not found such facts confirmed by my OAvn experiments, and this conclusion has been corroborated by some experiments of Professor Erman, communicated to the meeting of the British Association in the year 1845, in which he found that no electricity resulted from the friction of perfectly homogeneous substances ; as, 34 CORRELATION OF PHYSICAL FORCES. for instance, the ends of a broken bar. Such experiments as . these will, indeed, be seldom free from slight electrical cur- rents, on account of the practical difficulty of fulfilling the condition of perfect homogeneity in the substances themselves, their size, their temperature, &c.; but the effects produced are very trifling and vary in direction, and the resultant effect is nought. Indeed, it would be difficult to conceive the con- trary. How could we possibly image to the mind or de- scribe the direction of a current from the same body to the same body, or give instructions for a repetition of the exper- iment ? It would be unintelligible to say that in rubbing to and fro two pieces of bismuth, iron, or glass, a current of electricity circulated from bismuth to bismuth, or from iron to iron, or from glass to glass ; for the question immediately occurs—from which bismuth to which does it circulate? And should this question be answered by calling one piece A, and the other B, this would only apply to the particular specimens employed, the distinctive appellation denoting a distinction in fact, as otherwise A could be substituted for B, and the bar to which the positive electricity flowed would in turn become the bar to which the negative electricity flowed. We may say that it circulates from rough glass to smooth, from cast iron to wrought, for here there is not homogeneity. It is moreover conceivable, that when the motion is contin- uous in a definite direction, electricity may result from the friction of homogeneous bodies. If A and B rub against each other, revolving in opposite directions, concentric cur- rents of positive and negative electricity may be conceived circulating within the metals, and be described by reference to the direction of their motion ; this indeed would be a dif- ferent phenomenon from those we have been considering; but without some distinction between the two substances in qual- ity or direction, the electrical effects are indescribable, if not inconceivable. When, however, homogeneous bodies are fractured or MOTION. 35 even rubbed together, phenomena are observed to Avhich the term electricity is apphed; a flash or line of light appears at the point of friction which by some is called electrical, by others phosphorescent. I have myself observed a remarkable case of the kind in the caoutchouc fabric now commonly used for Avaterproof clothing : if two folds of this substance be alloAved to cohere so as partly to unite and present a difficulty of separation, then, on stripping the one from the other, or tearing them asunder, a line of light will follow the line of separation. If this class of phenomena be electrical, it is electricity determined as it is generated ; there is no dual character im- pressed on the matter acting, the flash is electrical as a spark from the percussion of flint is electrical, or as the slow com- bustion of phosphorus, or any other case of the development of heat and light. It seems to be better to class this phe- nomenon under the categories of heat and Hght than under that of electricity, the latter word being retained for those cases where a dual or polar character of force is manifested. In experiments which have been made by the friction of sim- ilar substances where the one appears positively and the other negatively electrical, there will be found some differ- ence in the mode of rubbing by which the molecular state of the bodies is in all probability changed, making one a dissim- ilar substance from the other ; thus it is said by Bergmann, that when two pieces of glass are rubbed so that all the parts of one pass over one part of the other, the former is positive and the latter negative. It is obvious that in this case the rubbing in one is confined to a line, and that must be more altered in molecular structure at the hue of friction than the one where the friction is spread over the whole surface: so if a ribbon be drawn transversely over another ribbon, the substances are not, qua the rubbing action, identical; so again, in the rupture of crystals, we are dealing with sub- stances having a polar arrangement of particles—the surfaces 36 CORRELATION OF PHYSICAL FORCES. of the fragments cannot be assumed to be molecularly identi- cal. The developement of electricity by the common electrical machine arises, as far as I can understand it, from the sepa« ration or rupture of contiguity between dissimilar bodies ; a metallic surface, the amalgam of the cushion, is in contact with glass ; these two bodies act upon each other by the force of cohesion; and when, by an external mechanical force, tins is ruptured, as it is at each moment of the motion of the glass plate or cylinder, electricity is deA-eloped in each; were they similar bodies, heat only would be developed. According to the experiments of Mr. Sullivan electricity may be produced by vibration alone if the substance vibra- ting be composed either of dissimilar metals, as a wire partly of iron and partly of brass caused to emit a musical sound ; or of the same metal, if its parts be not homogeneous, as a piece of iron, one portion of which is hard and crystallised and the other soft and fibrous; the current resulting appears to be due to the vibration, and not to heat engendered, as it ceases immediately with the \ribration. We may say, then, that in our present state of knowledge, where the mutually impinging bodies are homogeneous, heat and not electricity is the result of friction and percussion; where the bodies impinging are heterogeneous, we may safely state that electricity is always produced by friction or percus- sion, although heat in a greater or less degree accompanies it; but when we come to the question of ratio in Avhich fric- tional electricity is produced, as determined by the different characters of the substances employed, we find very complex results. Bodies may differ in so many particulars which in- fluence more or less the developement of electiicity, such as their chemical constitution, the state of their surfaces, their state of aggregation, their transparency or opacity, their power of conducting electricity, &c, that the normce of their action are very difficult of attainment. As a general rule, it MOTION. 37 may be said that the developement of electricity is greater when the substances employed are broadly distinct in their physical and chemical qualities, and more particularly in their conducting poAvers ; but up to the present time the laws gov- erning such developement haAre not been even approximately determined. I have said, in reference to the various forces or affections of matter, that either of them may, mediately or immediately, produce the others ; and this is all I can venture to predicate of them in the present state of science ; but after much con- sideration I incline strongly to the opinion that science is rap- idly progressing towards the establishment of immediate or direct relations between all these forces. Where at present no immediate relation is established between any of them, electricity generally forms the interA'ening link or middle term. Motion, then, will directly produce heat and electricity, and electricity, being produced by it, will produce magnetism —a force which is always developed by electrical currents at right angles to the direction of those currents, as will be sub- sequently more fully explained. Liglvt also is readily pro- duced by motion, either directly, as when accompanying the heat of friction, or mediately, by electricity resulting from motion ; as in the electrical spark, which has most of the at- tributes of solar light, differing from it only in those respects in which light differs wdien emanating from different sources or seen through different media ; for instance, in the position of the fixed lines in the spectrum or in the ratios of the spaces occupied by rays of different refrangibility. In the decom- positions and compositions Avhich the terminal points proceed- ing from the conductors of an electrical machine develope when immersed in different chemical media, we get the pro- duction of chemical affinity by electricity, of which motion is the initial source. Lastly, motion may be again reproduced by the forces which have emanated from motion; thus, tho 38 CORRELATION OF PHYSICAL FORCES. divergence of the electrometer, the revolution of the electri- cal wheel, the deflection of the magnetic needle, arc, when resulting from frictional electricity, palpable movements re- produced by the intermediate modes of force, which have themselves been originated by motion. III. —HEAT. IF Ave now take Heat as our starting point, Ave shall find that the other modes of force may be readily produced by it. To take motion first: this is so generally, I think I may say invariably, the immediate effectof heat,thatwe mayalmost, if not entirely, resolve heat into motion, and view it as a mechanically repulsive force, a force antagonist to attraction of cohesion or aggregation, and tending to move the particles of all bodies, or to separate them from each other. It may be well here to premise, that in using the terms ' particles ' or ' molecules,' which will be frequently employed in this Essay, I do not use them in the sense of the atomist, or mean to assert that matter consists of inckVisible particles or atoms. The words will be used for the necessary purpose of contradistinguishing the action of the indefinitely minute phy- sical elements of matter from that of masses having a sensi- ble magnitude, much in the same way as the term ' lines' or ' points' may be used, and with advantage in an abstract sense ; though there does not exist, in fact, a thing which has length and breadth without thickness, and though a thing with- out parts or dimensions is nothing. If Ave put aside the sensation which heat produces in our own bodies, and regard heat simply as to its effects upon in- organic matter, we find that, with a very few exceptions, which I 40 CORRELATION OF PHYSICAL FORCES. shall presently notice, the effects of what is called heat ara simply an expansion of the matter acted upon, and that the matter so expanded has the power by its own contraction of communicating expansion to all bodies in contiguity with it. • Thus, if the body be a solid, for instance, iron, a liquid, say water, or a gas, say atmospheric air—each of these, when heated, is expanded in every direction; in the two former cases, by increasing the heat to a certain point, we change the physical character of the substance, the solid becomes a liquid, and the liquid becomes a gas ; these, however, are still expansions, particularly the latter, when, at a certain period, the expansion becomes rapidly and indefinitely greater. But what is, in fact, commonly done in order to heat a sub- stance, or to increase the heat of a substance? it is merely approximated to some other heated, that is, to some other expanded substance, Avhich latter is cooled or contracted as the former expands. Let us now divest the mind of the impres- sion that heat is in itself anything substantive, and suppose that these phenomena are regarded for the first time, and without any preconceived notions on the subject; let us in- troduce no hypothesis, but merely express as simply as Ave can the facts of which we have become cognisant; to what do they amount? to this, that matter has pertaining to it a molecular repulsive poAver, a power of dilatation, which is communicable by contiguity or proximity. Heat thus viewed, is motion, and this molecular motion Ave may readily change into the motion of masses, or motion in its most ordinary and palpable form : for example, in the steam engine, the piston and all its concomitant masses of matter are moved by the molecular dilatation of the vapour of water. To produce continuous motion there must be an alternate action of heat and cold; a given portion of air, for instance, heated beyond the temperature of the circumambient air, is expanded. If now it be made to act on a movable piston, it nEAT. 41 moves this to a point at which the tension or elastic force of the confined air equals that of the surrounding air. If the confined air be kept at this point, the piston would remain stationary; but if it be cooled, the external air exercising then a greater relative degree of pressure, the piston returns toAvards its original position ; just as it will be seen, when we come to the magnetic force, that a magnet placed in a partic- ular position produces motion in iron near it, but to make this motion continuous, or to obtain an available mechanical power, the magnet must be demagnetised, or a stable equili- brium is obtained. In the case of the piston moved by heated air the motion of the mass becomes the exponent of the amount of heat— i. e. of the expansion or separation of the molecules ; nor do we, by any of our ordinary methods, test heat in any other way than by its purely dynamical action. The various modi- fications of the thermometer and pyrometer are all measur- ers of heat by motion: in these instruments liquid or solid bodies are expanded and elongated, i. e. moved in a definite direction, and, either by their own visible motion, or by the motion of an attached index, communicate to our senses the amount of the force by which they moved. There are, in- deed, some delicate experiments Avhich tend to prove that a repulsive action between separate masses is produced by heat. Fresnel found that mobile bodies heated in an exhausted re- ceiver repelled each other to sensible distances; and Baden Powell found that the coloured rings usually called Newton's rings change their breadth and position, when the glasses be- tween Avhich they appear are heated, in a manner which ehoAved that the glasses repelled each other. M. Faye's the- ory of comets is based on some such repellent force. There is, however, some difficulty in presenting these phenomena to the mind in the same aspect as the molecular repulsive action of heat. The phenomena of what is termed latent heat have beep 42 CORRELATION OF PHYSICAL FORCES. generally considered as strongly in favour of that view which regards heat either as actual matter, or, at all events, as a substantive entity, and not a motion or affection of ordinary matter. The hypothesis of latent matter is, I venture Avith diffi- dence to think, a dangerous one—it is something like the old principle of Phlogiston, it is not tangible, visible, audible; it is, in fact, a mere subtle mental conception, and ought, I submit, only to be received on the ground of absolute neces- sity, the more so as these subtleties are apt to be carried on to other natural phenomena, and so they add to the hypothe- tical scaffolding Avhich is seldom requisite, and should be sparingly used, even in the early stages of discoA'cry. As an instance, I think a striking one, of the injurious effects of this, I Avill mention the analogous doctrine of ' invisible light;' and I do this, meaning no disrespect to its distinguished au- thor, any more than in discussing the doctrine of latent heat, I can be supposed, in the slightest degree, to aim at detract- ing from the merits of the illustrious investigators of the facts which that doctrine seeks to explain. Is not' invisible light,' a contradiction in terms ? has not light ever been regarded as that agent which affects our visual organs ? Invisible Hght, then, is darkness, and if it exist, then is darkness light. I know it may be said, that one eye can detect light where another cannot; that a cat may see where a man cannot; that an insect may see where a cat cannot; but then it is not invisible light to those who see it: the light, or rather the object seen by the cat, may be invisible to the man, but it is visible to the cat, and, therefore, cannot abstractedly be said to be invisible. If we go further, and find an agent which affects certain substances similarly to light, but does not, as far as we are aware, affect the visual organs of any animal, then is it not an erroneous nomenclature which calls such an agent light ? There are many cases in which a de- viation from the once accepted meaning of words has so grad- HEAT. 43 ually entered into common usage as to be unavoidable, but I venture to think that additions to such cases should as far as possible be avoided, as injurious to that precision of lan- guage which is one of the safest guards to knowledge, and from the absence of which physical science has materially suffered. Let us now shortly examine the question of latent heat, and sec whether the phenomena cannot be as well, if not more satisfactorily, explained without the hypothesis of la- tent matter, an idea presenting many similar difficulties to that of invisible hght, though more sanctioned by usage. Latent heat is supposed to be the matter of heat, associated, in a masked or dormant state, with ordinary matter, not ca- pable of being detected by any test so long as the matter with which it is associated remains in the same physical state, but communicated to or absorbed from other bodies, when the matter writh Avhich it is associated changes its state. To take a common example : a pound or given weight of water at 172°, mixed with an equal weight of water at 32°, will acquire a mean temperature, or 102° ; Avhile water at 172°, mixed with an equal weight of ice at 32°, AArill be reduced to 32°. By the theory of latent heat this phenomenon is thus explained:—In the first case, that of the mixture of water with water, both the bodies being in the same physical state, no latent heat is rendered sensible, or sensible heat latent; but in the second, the ice changing its condition from the solid to the liquid state abstracts from the liquid as much heat as it requires to maintain it in the liquid state, which it renders latent, or retains associated with itself, so long as it remains liquid, but of which heat no evidence can be afforded by any thermoscopic test. I believe this and similar phenomena, where heat is con- nected with a change of state, may be explained and dis- tinctly comprehended without recourse to the conception of latent heat, though it requires some effort of the mind to di» 44 CORRELATION OF PHYSICAL FORCES. vest itself of this idea, and to view the phenomena simply in their dynamical relations. To assist us in so vie-wing them, let us first parallel with purely mechanical actions, certain simple effects of heat, where change of state (I mean such change as from the solid to the liquid, or liquid to the gase- ous state) is not concerned. Thus, place within a receiver a bladder, and heat the air within to a higher temperature than that without it, the bladder expands; 30, force the air mechanically into it by the air-pump, the bladder expands ; cool the air on the outside, or remove its pressure mechani- cally by an exhausting pump, the bladder also expands ; con- versely, increase the external repellent force, either by heat or mechanical pressure, and the bladder contracts. In the mechanical effects, the force which produced the distension is derived from, and at the expense of, the mechanical power employed, as from muscular force, from gravitation, from the reacting elasticity of springs, or any similar force by which the air-pump may be worked. In the heating effects, the force is derived from the chemical action in the lamp or source of heat employed. Let us next consider the experiment so arranged that the force, which produces expansion in the one case, produces a correlative contraction in the other: thus, if two bladders, Avith a connecting neck between them, be half-filled with air, as the one is made to contract by pressure the other will di- late, and vice versa ; so a bladder partly filled writh cold air, and contained within another filled with hot air, expands, while the space between the bladders contracts, exhibiting a mere transfer of the same amount of repulsive force, the mobility of the particles, or their mutual attraction, being the same in each body; in other words, the repulsive force acts in the direction of least resistance until equilibrium is produced ; it then becomes a static or balanced, instead of a dynamic or motive force. Let us now consider the case where a solid is to bo HEAT. 45 changed to a liquid, or a liquid to a gas ; here a much great* er amount of heat or repulsive force is required, on account of the cohesion of the particles to be separated. In order to separate the particles of the solid, precisely as much force must be parted Avith by the warmer liquid body as keeps an equal quantity of it in its liquid state ; it is, indeed, only with a more striking line of demarcation, the case of the hot and cold bladder—a part of the repellent poAver of the hot parti- cles is transferred to the cold particles, and separates them in their turn, but the antagonist force of cohesion or aggregation necessary to be overcome, being in this case much stronger, requires and exhausts an exactly proportionate amount of repellent force mechanically to overcome it; hence the differ- ent effect on a body such as the common thermometer, the expanding liquid of which does not undergo a similar change of state. Thus, in the example above given, of the mixture of cold Avith hot water, the hot and cold water and the mercury of the thermometer being all in a liquid state before, and remaining so after contact, the resulting temperature is an exact mean ; the hot water contracts to a certain extent, the cold water expands to the same extent, and the ther- mometer either sinks or rises the same^ number of degrees, accordingly as it had been previously immersed in the cold or in the hot solution, its mercury gaining or losing an equiva- lent of repellent force. In the second instance, viz. the mix- ture of ice with hot water, the substance we use as an indi- cator, i. e. mercury, does not undergo the same physical change as those whose relations of volume we are examining. The force—viewing heat simply as mechanical force—which is employed in loosening or tearing asunder the particles of the sohd ice, is abstracted from the liquid water, and from the liquid mercury of the thermometer, and in proportion as this force meets with a greater resistance in separating the particles of a solid than of a liquid, so the bodies which yield the force suffer proportionately a greater con- traction. • 48 CORRELATION OF PHYSICAL FORCES. If we compare the action of heat on the two substances, water and mercury, alone, and throw out of our consideration the ice, we shall be able to apply the same view: thus, if a given source of heat be applied to water containing a mercu- rial thermometer, both the Avater and mercury gradually ex- pand, but in different degrees ; at a certain point the attrac- tive force of the molecules of the Avater is so far overcome that the water becomes vapour. At this point, the heat or force, meeting Avith much less resistance from the attraction of the particles of steam than from those of the mercury, ex- pends itself upon the former; the mercury does not further expand, or expands in an infinitesimally small degree, and the steam expands greatly. As soon as this arrives at a point Avhere circumambient pressure causes its resistance to further expansion to be equal to the resistance to expansion in the mercury of the thermometer, the latter again rises, and so both go on expanding in an inverse ratio to their molecular attractive force. If the circumambient pressure be increased, as by confining the water at the commencement of the experiment within a less expansible body than itself, such as a metallic chamber, then the mercury of the ther- mometer continues to rise ; and if the experiment were con- tinued, the v/ater being confined and not the mercury, until we have arrived at a degree of repulsiAre force Avhich is able to overcome the cohesive poAver of the mercury, so that this expands into vapour, then we get the converse effect; the force expends itself upon the mercury, which expands in- definitely, as the water did in the first case, and the water does not expand at all. Another very usual mode of regarding the subject may cmbarras at first sight, but a little consideration will sIioav that it is explicable by the same doctrine. Water which has ice floating in it will give, when measured by the thermo- meter, the same temperature as the ico ; i. e. both the Avater nnd ice contract the mercury of the thermometer to the point HEAT 47 conventionally marked as 32°. It may be said, how is this reconcileable with the dynamical doctrine, for, according to that, the solid should take from the mercury of the ther- mometer more repulsive poAver than the liquid; conse- quently, the ice should contract the mercury more than the water? My ansAver is, that in the proposition as thus stated, the quantities of the water, ice, and mercury are not taken into consideration, and hence a necessary dynamical element is neglected: if the element of quantity be included, this objec- tion will not apply. Let the thermometer, for instance, con- tain 13 oz. of mercury, and stand at 100° ; if placed in con- tact with an unlimited quantity of ice at 32°, the mercury will sink to 32°. If the same thermometer be immersed in an unlimited quantity of Avater at 32 °, the mercury sink3 also to 32 5; not absolutely, perhaps, because, however great tho quantity of water or ice, it will be someAvhat raised in tem- perature by the warmer mercury. This elevation of tempera- lure above 32° will be smaller in proportion as the quantity of water or ice is larger than the quantity of mercury ; and, as we know of no intermediate state between ice and water, the contact of a thermometer at a temperature above the freezing point with any quantity of ice exactly at the freezing point would, theoretically speaking, liquefy the Avhole, pro- vided it had sufficient time ; for as every portion of that ice would in time have its temperature raised by the contact of the warmer body, and as any elevation of temperature above the freezing point liquefies ice, every portion should be lique- fied. Practically speaking, howeA-er, in both cases, that of the water and of the ice, when the quantity is indefinitely great the thermometer falls to 32°, Now place the same thermometer at 100 °, successively in one oz. of water at 32°, and in one of ice at 32°; Ave shall find in the former case it will be lowered only to 54°, and in the latter to 32° ; apply to this the doctrine of repulsive force, and Ave get a satisfactory explanation. 48 CORRELATION OF PHYSICAL FORCES. In the first case, the quantities both of ice and water be- ing indefinitely great in respect to the mercury, each reduces it to its own temperature, ATiz. 32°, and the ice cannot reduce the mercury below 32°, because it would receive back repul- sive power from the newly formed water, and this would be- come ice ; in the second case, where the quantities are limited, the mercury does lose more repulsive power by the ice than by the water, and the observations made in reference to the first illustration apply. The above doctrine is beautifully instanced in the experi- ment of Thilorier, by which carbonic acid is solidified. Car- bonic acid gas, retained in a strong vessel under great pres- sure, is allowed to escape from a small orifice ; the sudden expansion requires so great a supply of force, that in furnish- ing the demands of the expanding gas certain other portions of the gas contract to such an extent as to solidify: thus, we have reciprocal expansion and contraction going on in one and the same substance, the time being too limited for the whole to assume a uniform temperature, or in other words, a uniform extent of expansion. It has been observed with reference to heat thus viewed, that it would be as correct to say, that heat is absorbed, or cold produced by motion, as that heat is produced by it. This difficulty ceases Avhen the mind has been accustomed to re- gard heat and cold as themselves, motion ; i. e. as correlative expansions and contractions, each being evidenced by relation, and being inconceivable as an abstraction. For instance, if the piston of an air-pump be drawn down by a weight, cold is produced in the receiver. It may be here said that a mechanical force, and the motion consequent upon it, produces cold; but heat is produced on the opposite side of the piston, if a receiver be adapted so as to retain the com- pressed air. Assuming them to equivalise each other, the force of the falling weight would be expressed by the heat of friction of the piston against its tube, and by the tension or HEAT. 49 power of reaction of the compressed against the dilated air. If the heat due to compression be made to perform mechani- cal work, it Avould pro tanto be consumed, and could not restore the temperature to the dilated air ; but if it perform no work, no heat is lost. Mr. Joule has experimentally proved this proposition. In commencing the subject of heat, I asked my reader to put out of consideration the sensations which heat produces in our own bodies; I did this because these sensations are likely to deceive, and haA-e deceived many as to the nature of heat. These sensations are themselves occasioned by simi- lar expansions to those Avhich we have been considering; the liquids of the body are expanded, i. e. rendered less viscid by heat, and from their more ready flow, we obtain the sensation of agreeable Avarmth. By a greater degree of heat, their ex- pansion becomes too great, giving rise to a sense of pain, and, if pushed to extremity, as with the heat which produces a burn, the liquids of the body are dissipated in vapour, and an injury or destruction of the organic structure takes place. A similar though converse effect may be produced by intense cold; the application of frozen mercury to the animal body produces a burn similar to that produced by great heat, and accompanied with a similar sensation. Doubtless other actions than those above mentioned inter- fere in producing the sensations of heat and cold ; but I think it will be seen that these will not affect the arguments as to the nature of heat. The phenomenal effects will be four d unaltered : heat will still be found to be expansion, cold to be contraction ; and the expansion and contraction are, as with the two bladders of air, correlative—i. e. we cannot expand one body, a, without contracting some other body, b ; we cannot contract a without expanding b, assuming that we view the bodies Avith relation to heat alone, and suppose no other force to be manifested. I have said that there are few exceptions as to heat bein« 3 50 CORRELATION OF PHYSICAL FORCES. always manifested by an expansion of matter. One class of these exceptions i3 only apparent: moist clay, animal or vegetable fibre, and other substances of a mixed nature, which contain matter of different characters, some of which is more and some less volatile, i. e. expansible, are contracted on the application of heat; this arises from the more volatile matter being dissipated in the form of vapour or gas ; and the interstices of the less volatile being thus emptied, the latter contracts by its own cohesive attraction, giving thus a prima facie appearance of contraction by heat. The pyrometer of Wedgwood is explicable on this principle. The second class of exceptions, though much more limited in extent, is less easily explained. Water, fused bismuth, and probably some other substances (though the fact as to them is not clearly estabhshed), expand as they approach very near to the freezing or solidifying point. The most probable explanation of these exceptions is, that at the point of maximum density the molecules of these bodies assume a polar or crystalline condition; that by the particles being thus arranged in linear directions like chevaux de frise, interstitial spaces are left, containing matter of less den- sity, so that the specific density of the Avhole mass i3 dimin- ished. Some recent experiments of Dr. Tyndall on the physical properties of ice seem to favour this A'iew. When a sun- beam, concentrated by a lens, is allowed to fall on a piece of apparently homogeneous ice the path of the rays is in- stantly studded with numerous luminous spots like minute air bubbles, and the planes of freezing are made manifest by these and by small fissures. Stars or flower-like figures of six petals appear parallel to the plane3 of freezing, and seem- ingly spreading out from a central bubble. These flowers are formed of water. When the ice is melted in warm water no air is given off from the bubbles, so they seem to be va- cuous ; it h, however, possible that extremely minute parti' HEAT. 51 cles of air sufficient to form foci for the melting points of ice might be dissolved by the Avater as soon as they came in con- tact with it. Be this as it may, the existence of these points throughout the kv, where it gh'es way to the heat of the solar beam, if it does not prove actual vacuous or aeriform spaces to exist in ice, proves that it is not homogeneous, that its structure is probably definitely crystalline, and that the matter composing it is in different degrees of aggregation, so that its mean specific gravity might well be less than that of water. We cannot examine piecemeal the ultimate structure of matter, but in addition to the fact that the bodies which evince this peculiarity are bodies which, when solidified, ex- hibit a very marked crystalline character, there are experi- ments which shoAv that water between the point of maximum density and its point of solidification polarises light circularly ; showing, if these experiments be correct, a structural altera- tion in Avater, and one analogous to that possessed by certain crystalline solids, and to that possessed by water itself, where it is forcibly made to assume a polarised condition by the in- fluence of magnetism. The accuracy of these results has, however, been doubted, and the experiments have not succeeded Avhen repeated by very experienced hands. Whether this be so or not, and whether the above explanation of the exception to the other- wise invariable effect of expansion by heat be or be not re- garded as admissible, must be left to the judgment of each individual who thinks upon the subject; at all events, no theory of heat yet proposed removes the difficulty, and there- fore it equally opposes every other view of the phenom- ena of heat, as it does that which I have here consid- ered, and which regards heat as communicable expansive force. As certain bodies expand in freezing, and indeed, under some circumstances, Defore they arrive at the temperature at 52 . CORRELATION OF PHY'SICAL FORCES. which they solidify, we get the apparent anomaly that tho motion or mechanical force generated by heat or change of temperature is reversed in direction when we arrive at the point of change from the solid to the liquid state. Thus a piece of ice at the temperature of Zero, Fahrenheit, would expand by heat, and produce a mechanical force by such ex- pansion until it arrives at 32°; but then by an increment of heat it contracts, and if the first expansion had moved a pis- ton upwards, the subsequent contraction Avould bring it back to a certain extent, or move it doAvnwards, an apparent nega- tion of the force of heat. Again with water above 40°, i. e, above its point of maximum density, a progressive increment of cold or decre- ment of heat would produce contraction to a certain point, and then expansion or a mechanical force in an opposite direc- tion. Thus not only heat or the expansive force given to other bodies by a body cooling wrould be given out by water freezing, but also the force due to the converse expansion in the body itself, and force would thus seem to be got out of noth- ing : but if water in a confined space be gradually cooled, the expansion attendant on its cooling as it approaches the freez- ing point would occasion pressure amongst its particles, and thence tend to antagonise the force of dilatation produced in them by cooling, or to resist their tendency to freeze ; or in other words, the pressure would tend to liquefaction, and con- versely to the usual effect of pressure, produce cold instead of heat, and thus neutralise some of the heat yielded by the cooling body. Hence we find that it requires a lower tem- perature to freeze water under pressure than when exempt from it, or that the freezing point is lowered as the pressure increases for bodies which expand in freezing—an effect first predicted by Mr. J. Thompson, and experimentally verified by Mr. W. Thompson ; Avhile as shown by M. Bunsen, the converse effect takes place with bodies which contract in freezing. Here the pressure cooperates Avith the effects of HEAT. 53 cold, both tending to approximate the particles, and such sub- stances solidify at a higher temperature in proportion as the pressure is greater ; so that we might expect a body of this class, which under the ordinary pressure of the air is at a temperature just above its freezing point, to solidify by being submitted to pressure alone, the temperature being kept constant. A similar class of exception to the general effect of heat in expanding bodies is presented by vulcanised caout- chouc. This has been observed by Mr. Gough, and, in- deed, Avas pointed out to me many years ago by Mr. Brockedon to be heated Avhen stretched, and cooled Avhen unstretched. Mr. Joule finds that its specific gravity is lower when stretched than when unstretched, and that when heated in its stretched state it shortens, presenting in this par- ticular condition a similar series of converse relations to those which are presented by water near or at its freezing point. With the exception of this class of phenomena, Avhich offer difficulties to any theory which has been proposed, the general phenomena of heat may, I believe, be explained upon a purely dynamical A'ieAV, and more satisfactorily than by having recourse to the hypothesis of latent matter. Many, howeA'er, of the phenomena of heat are involved in much mystery, particularly those connected Avith specific heat or that relative proportion of heat Avhich equal weights of differ- ent bodies require to raise them from a given temperature to another given temperature, which appear to depend in some way hitherto inexphcable upon the molecular constitution of different bodies. The view of heat which I have taken, viz. to regard it simply as a communicable molecular repulsive force, is sup- ported by many of the phenomena to which the term specific or relative heat is apphed; for example, bodies as they in- 54 CORRELATION OF PHYSICAL FORCES. crease in temperature increase in specific heat. The ratio of this increase in specific heat is greater with sohds than with liquids, although the latter are more dilatable ; an effect probably depending upon the commencement of fusion. Again, those metals Avhose rate of expansion increases most rapidly whe~ they are heated, increase most in specific heat ; and their specific heat is reduced by percussion, which, by approximating their particles, makes them specifically more dense. When, however, we examine substances of very different physical characters, we find that their specific heata have no relation to their density or rate of expansion by heat; their differences of specific heat must depend upon their intimate molecular constitution in a manner accounted for (as far as I am avrare) by no theory of heat hitherto proposed. In the greater number, probably in all sohds and liquids, the expansion by heat is relatively greater as the temperature is higher; or, preserving the vieAV of expansion and contrac- tion, if two equal portions of the same substance be juxta- posed at different temperatures, the hotter portion will con- tract a little more than the colder will expand; from this fact, Adz. that the coefficient of expansion increases in a given body with the temperature, and from other considerations, Dr. Wood has argued, Avith much apparent reason, that the nearer the particles of bodies are to each other, the less they require to move to produce a given expansion or contraction in those of another body. His mode of reasoning, if I rightly conceive it, may be concisely put as follows :— As bodies contract by cold, it is clear that, in a given body, the lower the temperature the nearer are the particles ; and, as the coefficient of expansion increases Avith the tem- perature, the lower the temperature of the substance be, the less the particles require to move, or approach to or recede from each other, so as to compensate the correlative recession n approach of the particles in a hotter portion of the samo iieat. 55 substance, that is, in another portion of the same substance in Avhich the particles are more distant from each other. The amount of approximation or recession of the particles of a body, in other Avords, its change of bulk by a given change of temperature, being thus in a given substance an index of the relative proximity of its particles, may it not be so of all bodies? The proposition is very ingeniously argued by Di\ Wood, but the argument is based upon certain hypotheses as to the size3 and distances of atoms, which must be admitted as postulates by those Avho adopt his conclusions. Dr. Wood seeks by means of this theory to explain the heat pro- duced by chemical combination, and I shall endeavour to give a sketch of his mode of reasoning Avhen I arrive at that part of my subject. Although the comparative effects of specific heat may not be satisfactorily explicable by any known theory, the absolute effect of heat upon each separate substance is simply expan- sion, but when bodies differing in their physical characters are used, the rate of expansion varies, if measured by the correlative contractions exhibited by the substances produc- ing it. Though I am obliged, in order to be intelligible, to talk of heat as an entity, and of its conduction, radiation, &c, yet these expressions are, in fact, inconsistent with the dyna- mic theory Avhich regards heat as motion and nothing else ; thus conduction would be simply a progressive dilatation or motion of the particles of the conducting substance, radiation an \mdulation or motion of the particles of the medium through which the heat is said to be transmitted, &c.; and it is a strong argument in favour of this theory, that for every diversity in the physical character of bodies, and for every change in the structure and arrangement of particles of the same body, a change is apparent in the thermal effects. Thus gold conducts heat, or transmits the motion called heat, more readily than copper, copper than iron, iron than lead, and lead than porcelain, &c. 56 CORRELATION OF PHYSICAL FORCES. So Avhen the structure of a substance is not homogeneous, we have a change in the conduction of different parts depend- ent upon the structure. This is beautifully shown with bodies Avhose structure is symmetrically arranged, as in crys- tals. Senarmont has shown that crystals conduct heat differ- ently in different directions with reference to the axis of symmetry, but definitely in definite directions. His mode of experimenting is as follows :—A plate of the crystal is cut in a direction, for one set of experiments parallel, and for another at right angles to the axis; a tube of platinum is in- serted through the centre of the plate, and bent at one extremity, so as to be capable of being heated by a lamp without the heat which radiates from the lamp affecting the crystal; the surfaces or bases of the plate of crystal are covered with wax. When the platinum is heated, the direc- tion of the heat conducted by the crystal is made known by the melting of the wax, and a curved line is visible at the juncture of the solid and liquid wax. This curve, Avith homogeneous substances, as glass or zinc, is a circle ; it is also a circle on plates of calc spar cut perpendicular to the axis of symmetry; but on plates cut parallel to the axis of symmetry, and having their plane perpendicular to one of the faces of the primitive rhombohedron, the curves are Avell- defined ellipses, having their longer axes in the direction of the axis of symmetry, showing that this axis is a direction of greater conductibility. From experiments of this character the inference is drawn, that ' in media constituted like crys- tals of the rhombohedral system, the conducting power varies in such a manner, that, supposing a centre of heat to exist within them, and the medium to be indefinitely extended in all directions, the isothermal surfaces are concentric ellipsoids of revolution round the axis of symmetry, or at least surfaces differing but little therefrom.' Knoblauch has further shown, that radiant heat is absorb- ed in different degrees, according as its direction is parallel »r perpendicular to the axis of a crystal. HEAT. 57 If we select a substance of a different but also of a definite structure, such as Avood, we find that heat progresses through it with more or less rapidity, according to its direction with reference to the fibre of the wood: thus Decandolle and De la Rive found that the conduction was better in a direction parallel to the fibre than in one transverse to it; and Dr. Tyndall" has added the fact, that the conduction is better in a direction transverse to the fibres and layers of the wood than when transverse to the fibre but parallel to the layers, though in both these directions the conduction is inferior to that fol- lowing the direction of the fibre. Thus, in the three possible directions in which the structure of wood may be contem- plated, we have three different degrees of progression for heat. In the above examples we see, as we shall see farther on Avith reference to all the so-called imponderables, that the phenomena depend upon the molecular structure of the mat- ter affected; and although these facts are not absolutely in- consistent with the theory which supposes them to be fluids or entities, it will, I think, be found to be far more consistent with that which views them as motipn. Heat, which we are at present considering, cannot be insulated: we cannot re- move the heat from a substance and retain it as heat; we can only transmit it to another substance, either as heat or as some other mode of force. We only knoAV certain changes of matter, for which changes heat is a generic name ; the thing heat is unknown. Heat having been shoAvn to be a force capable of pro- ducing motion, and motion to be capable of producing the other modes of force, it necessarily follows that heat is capa- ble, mediately, of producing them ; I will, therefore, content myself with enquiring how far heat is capable of immediately producing the other modes of force. It will immediately produce electricity, as shown in the beautiful experiments of Seebeck, one of which I have already cited, which expert 58 CORRELATION OF PHYSICAL FORCES. ments proved, that when dissimilar metals are made to touch, or are soldered together .and heated at the point of contact, a current of electricity flows through the metals having a defi- nite direction according to the metals employed, which cur- rent continues as long as an increasing temperature is grad- ually pervading the metals, ceases when the temperature is stationary, and flows in the contrary direction with the decre- ment of temperature. Another class of phenomena which have been generally attributed to the effects of radiant heat, and to which, from this belief, the term thermography has been applied, may also, in their turn, be made to exhibit electrical effects—ef- fects here of Franklinic or static electricity, as Seebeck's ex- periments showed effects of voltaic or dynamic electricity. If polished discs of dissimilar metals—say, zinc and cop- per—be brought into close proximity, and kept there for some time, and either of them has irregularities upon its sur- face, a superficial outline of these irregularities is traceable upon the other disc, and vice versa. Many theories have been framed to account for thi3 phenomenon, but whether it be due or not to thermic radiations, the relative temperature of the discs, their relative capacities and conducting and radiating powers for heat, undoubtedly influence the phe- nomena. Now, if two such discs in close proximity be connected with a delicate electroscope, and then suddenly separated, the electroscope is affected, showing that the reciprocal ra- diation from surface to surface has produced electrical force. I cite this experiment in treating of heat as an initial force, because at present the probabihties are in favour of thermic radiation producing the phenomenon. The origin of these so-called thermographic effects is, however, a question open to much doubt, and needs much further experiment. When I first published the experiment which showed that the mere approximation of metallic discs would give rise to electrical HEAT. 59 effects, I mentioned that I considered the fact of the superfi cial change upon the surface of metals in proximity, and, d fortiori, in contact, would explain the developement of elec- tricity in Volta's original contact experiment, without having recourse to the contact theory, i. e. a theory which supposes a force to be produced by mere contact of dissimilar metals without any molecular or chemical change. I have seen nothing to alter this view. Mr. Gassiot has repeated and verified my experiment with more delicate apparatus and under more unexceptionable circumstances ; and without say- ing that radiant heat is the initial force in this case, we have evidence, by the superficial change which takes place in bodies closely approximated, that some molecular change is taking place, some force is called into action by their proxim- ity, which produces changes in matter as it expends, or rather transmits itself; and, therefore, is not a force without molecular change, as the supposed contact force would be. The force in this, as in all other cases, is not created, but de- veloped by the action of matter on matter, and not annihi- lated, as it is shown by this experiment to be convertible into another mode of force. To say that heat will produce light, is to assert a fact ap- parently familiar to every one, but there may be some rea- son to doubt whether the expression to produce light is cor- rect in this particular application ; the relation between heat and hght is not analogous to the correlation between these and the other four affections of matter. Heat and hght ap- pear to be rather modifications of the same force than dis- tinct forces mutually dependent. The modes of action of ra- diant heat and of hght are so similar, both being subject to the same laws of reflection, refraction, and double refraction, and polarisation, that their difference appears to exist more in the manner in which they affect our senses than in our mental conception of them. The experiments of Melloni, which have mainly contrib- 60 CORRELATION OF PHYSICAL FORCES. uted to demonstrate this close analogy of heat and hght, a£ ford a beautiful instance of the assistance which the progress of one branch of physical science renders to that of another The discoveries of Oersted and Seebeck led to the construc- tion of an instrument for measuring temperature, incompara- bly more delicate than any previously known. To distin- guish it from the ordinary thermometer, this instrument is called the thermomultiplier. It consists of a series of small bars of bismuth and antimony, forming one zigzag chain of alternations arranged parallel to each other, in the shape of a cylinder or prism ; so that the points of junction, which are soldered, shall be all exposed at the bases of the cylinder: the two extremities of this series are united to a galvano- meter—that is, a#flat coil of wire surrounding a freely-sus- pended magnetic needle, the direction of which is parallel to the convolutions of the wire. When radiant heat impinges upon the soldered ends of the multiplier, a thermo-electric current is induced in each pair; and, as all these currents tend to circulate in the same direction, the energy of the whole is increased by the cooperating forces : this current, traversing the helix of the galvanometer, deflects the needle from parallelism by virtue of the electro-magnetic tangential force, and the degree of this deflection serves as the index of the temperature. Bodies examined by these means show a remarkable dif- ference between their transcalescence, or poAver of transmit- ting heat, and their transparency : thus, perfectly transparent alum arrests more heat than quartz so dark coloured as to be opaque ; and alum coupled with green glass Melloni found was capable of transmitting a beam of brilliant light, while, with the most delicate thermoscope, he could detect no indi- cations of transmitted heat: on the other hand, rock-salt, the most transcalescent body known, may be covered with soot until perfectly opaque, and yet be found capable of transmit- ting a considerable quantity of heat. Radiant heat, when HEAT. 61 transmitted through a prism of rock-salt, is found to be une- qually refracted, as is the case with light; and the rays of heat thus elongated into what is, for the sake of analogy, called a spectrum, are found to possess similar properties to the primary or coloured rays of hght. Thus rock-salt is to heat what colourless glass is to hght; it transmits heat of all degrees of refrangibility: alum is to heat as red glass to light; it transmits the least, and stops the most refrangible rays ; and rock-salt covered with soot represents blue glass, transmitting the most, and stopping the least refrangible rays. Certain bodies, again, reflect heat of different refrangi- bility: thus paper, snoAV, and lime, although perfectly white —that is, reflecting hght of all degrees of refrangibility, re- flect heat only of certain degrees; while metals, which are coloured bodies—that is, bodies which reflect hght only of certain degrees of refrangibility—reflect heat of all degrees. Radiant heat incident upon substances which doubly refract hght is doubly refracted ; and the emergent rays are polar- ised in planes at right angles to each other, as is the case with hght. The relation of radiation to absorption also holds good with hght as with heat: with the latter it has been long known that the radiating power of different substances is di rectly proportional to their absorptive and inverse to theii reflective poAver ; or rather, that the sum of the heat radia ted and reflected is a constant quantity. So, as has been shown by Mr. Balfour Stewart, the absorption bears the same relation to radiation for heat as to quality as well as quantity. Light presents us with similar relations. Coloured glass, when heated so as to be luminous, emits the same hght which at ordinary temperatures it absorbs: thus red glass gives out or radiates a greenish hght, and green glass a red lint. The flame of substances containing sodium yields a yel- 62 CORRELATION OF PHl'SICAL FORCES. low light of such purity that other colours exposed to it ap- pear black—a phenomenon shown by the familiar experiment of exposing a picture of bright colours, other than yellow, to the flame of spirits of wine Avith which common salt is mixed : the picture loses its colours, and appears to be black and white. When the prismatic spectrum of such a flame is ex- amined, it is found to exhibit two bright yellow hnes at a cer- tain fixed position. If a source of light be employed which gives no hnes in its spectrum, and this, being at a higher temperature, be made to pass through the sodium flame, two dark hnes will appear in the spectrum precisely coincident in position with the yellow lines which were given by the so- dium flame itself. The same relation of absorption to radia- tion is therefore shown here : the substance absorbs that light A\Thich it yields when it is itself the source of light. The same is true of other substances, the spectra of which exhibit respectively lines of peculiar colour and position. Now, the solar prismatic spectrum is traversed by a great number of dark lines; and Kirchoff has deduced from con- siderations such as those which I have shortly stated, that these dark lines in the solar spectrum are due to metals ex- isting in an atmosphere around the sun, which absorb the hght from a central incandescent nucleus, each metal absorb- ing that light which would appear as a bright line or lines in its own spectrum. By comparing the position of the bright hnes in the spec- tra of metals with that of the dark hnes in the solar spec- trum, several of them are found to be in identically the same place : hence it is inferred, and the inference seems reason- able, that the metals which show luminous lines in their spec- tra, identical in position with dark lines in the solar spec- trum, exist in the sun, and are diffused in a gaseous state in its atmosphere. It does not seem to me necessary to this conclusion to assume that the sun is a solid mass of incandes- cent matter: it may well be that what we term the photo- HEAT. 63 sphere or luminous envelope of the sun has surrounding it a more diffuse atmosphere containing vaporised metals, and that the mass of the sun itself may be in a different state, and not necessarily at an incandescent temperature ; indeed, the protuberances and red light seen at the period of total eclipses afford some eATidence of an atmosphere exterior to the photosphere. It Avould, however, be out of place here to speculate on these subjects: the point Avhich concerns us is the analogies of heat and hght, which these discoveries illus- trate. Kirchoff has carried the analogy farther by showing that a plate of tourmaline absorbs the polarised ray which when heated it radiates. Thus, the phenomena of hght are imitated closely by those of radiant heat; and the same the- ory Avhich is considered most plausibly to account for the phenomena of the one, will necessarily be apphed to the other agent, and in each case molecular change is accompanied by a change in the phenomenal effects. In certain cases heat appears to become partially con- verted into b'ght, by changing the matter affected by heat: thus gas may be heated to a very high point without pro- ducing light, or producing it to a very slight degree ; but the introduction of solid matter—for instance, the metal platinum into the highly-heated gas—instantly exhibits hght. Whether the heat is converted into hght, or Avhether it is concentrated and increased in intensity by the solid matter so as to become visible, may be open to some doubt: the fact of sohd matter, when ignited by the oxyhydrogen jet decomposing water, as will be presently explained, would seem to indicate that the heat was rendered more intense by condensation in the solid matter, as water is in this case decomposed by a heated body, which body has itself been heated by the combining elements of water. The apparent effect, however, of the introduction of solid incombustible matter into heated gas, is a conversion of heat into light. There is another method by which heat would probably 64 CORRELATION OF PHYSICAL FORCES. be made to produce luminous effects, though I am not aAvare that the experiment has ever been made. If we concentrate into a focus by a large lens a dim hght, we increase the intensity of the light. Now if a heated body be taken, which, to the unassisted eye, has just ceased to be visible, it seems probable that by coUecting and condensing by a lens the different rays which have so ceased to be visi- ble, light would reappear at the focus. The experiment is, for reasons obvious to those acquainted with optics, a difficult one, and, to be conclusive, should be made on a large scale, and with a very perfect lens of large diameter and short fo- cus. I have obtained an approximation to the result in the following manner:—In a dark room a platinum wire is brought just to the point of visible ignition by a constant vol- taic battery ; it is then viewed, at a short distance, through an opera-glass of large aperture applied to one eye, the other being kept open. The wire will be distinctly visible to that eye which regards it through the opera-glass, and at the same time totally invisible to the other and naked eye. It may be said with some justice that such experiments proAre little more than the fact already known, viz. that by increasing the in- tensity of heat, hght is produced: they however exhibit this effect in a more striking form, as bearing on the relations of heat and hght. With regard to chemical affinity and magnetism, perhaps the only method by which in strictness the force of heat may be said to produce them is through the medium of electricity, the thermo-electrical current, produced, as before described, by heating dissimilar metals, being capable of deflecting the magnet, of magnetising iron, and exhibiting the other mag- netic effects, and also of forming and decomposing chemical compounds, and this in proportion to the progression of heat: this has not, indeed, as yet been proved to bear a measurable quantitative relation to the other forces thus produced by it, because so little of the heat is utilised or converted into eleo« HEAT. 65 tricity, much being dissipated, without change, in the form of heat. Heat, however, directly affects and modifies both the mag- net and chemical compounds ; the union of certain chemical substances is induced by heat, as, for instance, the formation of water by the union of oxygen and hydrogen gases: in other cases this union is facilitated by heat, and in many in- stances, as in ammonia and its salts, it is weakened or antag- onised. In many of these cases, however, the force of heat seems more a determining than a producing influence ; yet to be this, it must have an immediate relation with the force whose reaction it determines: thus, although gunpowder, touched Avith an ignited wire, subsequently carries on its own combustion or chemical combination, independently of the original source of heat, yet the chemical affinities of the first portion touched must be exalted by, and at the cost of, the heat of the wire ; for to disturb even an unstable equilibrium requires a force in direct relation with those which maintain equihbrium. Since the first edition of this essay was pubhshed, I haA*e communicated to the Royal Society some experiments by which an important exception to the general effect of heat on chemical affinity is removed, and the results of which induce a hope that a generalised relation will ultimately be estab- lished between heat, chemical affinity, and physical attraction. I find that if a substance capable of supporting an intense heat, and incapable of being acted upon by water or either of its elements—such, for instance, as platinum, or iridium— be raised to a high point of ignition and then immersed in water, bubbles of permanent gas ascend from it, which on examination are found to consist of mixed oxygen and hydro- gen in the proportions in which they form water. The tem- perature at which this is effected is, according to Dr. Robin- son, Avho has since written a valuable paper on the subject, «s 23860. Now, when mixed oxygen and hydrogen are ex- 36 CORRELATION OF PHYSICAL FORCES. posed to a temperature of about 800°, they combine and forir water; heat therefore appears to act differently upon these elements according to its intensity, in one case producing composition, in the other decomposition. No satisfactory means of reconciling this apparent anomaly have been pointed out: the best approximation to a theory which I can frame in by assuming that the constituent molecules of water are, be- low a certain temperature, in a state of stable equilibrium; that the molecules of mixed or oxyhydrogen gas are, above a certain temperature, also in a state of stable equihbrium, but of an opposite character; while below this latter tempera- lure the molecules of mixed gas are in a state of unstable equilibrium, somewhat similar to that of the fulminates or similar bodies, in which a slight derangement subverts the nicely-balanced forces. If, for instance, we suppose four molecules, A, B, C, D, to be in a balanced state of equilibrium between attracting and repelhng forces, the application of a repulsiAre force be- tween B and C, though it may still farther separate B and C, will approximate B to A and C to D, and may bring them respectively within the range of attractiAre force; or, sup- posing the repulsive force to be in the centre of an indefinite sphere of particles, all these, excepting those immediately acted on by the force, will be approximated, and having from attraction assumed a state of stable equihbrium, they will re- tain this, because the repulsive force divided by the mass is not capable of overcoming it. But if the repulsive force be increased in quantity and of sufficient intensity, then the at- tractive force of aU the molecules may be overcome, and de- composition ensue. Thus, water or steam below a certain temperature, and mixed gas above a certain temperature, may be supposed to be in a state of stable equihbrium, whilst below this limiting temperature, the equihbrium of oxyhy- irogen gas is unstable. This, it must be confessed, is but a crude mode of explain* HEAT. 67 ing the phenomena, and requires the assumption, that the particles of a gas exercise an attraction for each other as do the particlej^of a solid, though different in degree, perhaps in kind. Whether this be so or not, there can be no doubt that both gases and sohds expand or contract according to the in- verse contraction or expansion of other neighbouring bodies, and so far resemble each other in their relations to heat and cold. The extent to which such expansion or contraction can be carried, seems to be limited only by the correlative state of other bodies; these again, by others, and so on, as far as Ave may judge, tliroughout the universe. Adopting the explanation above given of the decomposi- tion of water by heat, heat would have the same relation to chemical affinity as it has to physical attraction; its imme- diate tendency is antagonistic to both, and it is only by a sec- ondary action that chemical affinity is apparently promoted by heat. This view Avould explain how heat may promote changes of the equilibrium of chemical affinity among mixed compound substances, by decomposing certain compounds and separating elementary constituents whose affinity is greater, Avhen they are brought within the sphere of attraction for the substance with which they are mixed, than for those with which they Avere originally chemically united : thus an intense heat being applied to a mixture of chlorine and the vapour of Avater, occasions the production of muriatic acid, libera- ting oxygen. Carrying out this view, it would appear that a sufficient intensity of heat might yield indefinite powers of decomposi- tion ; and there seems some probability of bodies noAV sup- posed to be elementary, being decomposed or resolved into further elements by the application of heat of sufficient inten- sity ; or, reasoning conversely, it may fairly be anticipated that bodies, Avhich will not enter into combination at a certain temperature, will enter into combination if their temperature be lowered, and that thus new compounds may be'formed by 68 CORRELATION OF PHYSICAL FORCES. a proper disposition of their constituents when exposed to an extremely low temperature, and the more so if compression be also employed. In considering the effect of heat as a mechanical force, it would be expected, a priori, and independently of any theory of heat which may be adopted, that a given amount of heat acting on a given material must produce a given amount of motive power; and the next question which occurs to the mind is, whether the same amount of heat would produce the same amount of mechanical power, whatever be the material acted on or affected by the heat. I will endeavour to reason this out on the view of heat which I have advocated. Heat has been considered in this essay as itself motion or mechan- ical power, and quantity of heat as measured by motion. Thus, if by a given contraction of a body (say mercury) air witliin a cylinder having a moveable piston be expanded, the piston moves, and in this case the expansion or motion of the material (say iron) of the cylinder itself and of the air sur- rounding it is commonly neglected. As the air dilates it be- comes colder ; in other words, by undergoing expansion itself, it loses its power of making neighbouring bodies expand; but if the piston be forcibly kept down, the expansive power due to the mercury continues to communicate itself to the iron and to the surrounding air, which become hotter than they would if the piston had given way. Now, in the above case, if the air be confined and its volume unchanged, will the expansion of the iron, assuming that it can be utilised, produce an exactly equivalent mechan- ical effect to that which the expansion of the air would pro- duce if the heat be entirely confined to it ? Assuming that (with the exception of bodies which ex- pand in freezing, where, through a limited range of tempera- ture, the converse effects obtain) whenever a body is com- pressed it is heated, i. e. it expands neighbouring substances ; whenever it is dilated or increased in volume it is cooled, i. e HEAT. 69 it contracts neighbouring substances—the conclusion ap- pears to me inevitable that the mechanical power produced by heat will be definite, or the same for a given amount and intensity of heat, whatever be the substance acted on. Thus, let A be a definite source of heat, say a pound of mercury at the temperature of 400° ; let B be another equal and similar source of heat: suppose A be employed to raise a piston by the dilatation of ah, and B to raise another pis- ton by the dilatation of the vapour of Avater. Imagine the pistons attached to a beam, so that they oppose each other's action, and thus represent a sort of calorific balance. If A being applied to air could conquer B, which is applied to water, it would depress or throw back the piston of the latter, and, by compressing the A'apour, occasion an increase of temperature; this, in its turn, Avould raise the temperature of the source of heat, so that we should have the anomaly that a pound of mercury at 400° could heat another pound of mercury at 400° to 401°, or to some point higher than its original temperature, and this without any adventitious aid: it will be obvious that this is impossible, at least contradic- tory to the whole range of our experience. The above experiment is ideal, and stated for the object of giving a more precise form to the reasoning; to bring the idea more prominently into relief, aU statements as to quan- tities, specific heats, &c, so as to yield comparative results for given materials, are omitted. The argument may be thus stated in another form, viz. that by no mechanical appli- ance or difference of material acted on can a given source of heat be made to produce more heat than it originally possessed; and that, if all be converted into mechanical power, an excess cannot be supposed, for that could be con- verted into a surplus of heat, and be a creation of force ; and a deficit cannot be supposed, for that would be annihilation of force. I cannot, however, see how the theoretical concep- tion could be verified by experiment; the enormous weights 70 CORRELATION OF PHYSICAL FORCES. and the complex mechanical contrivances requisite to give the measure of power yielded by matter in its less dilatable forms, would be far beyond our present experimental re- ources. It would also be difficult to prevent the interference of molecular attractions, inertia, &c, the overcoming of which expends a part of the mechanical power generated, but which could hardly be made to appear in the result. We could not, for instance, practically reahse the above con- ception by the construction of a machine which should act by the expansion and contraction of a bar of iron, and produce a power equal to that of a steam engine, supphed with an equal quantity of heat. Carnot, who wrote in 1824 an essay on the motive power of heat, regarded the mechanical power produced by heat as resulting from a transfer of heat from one point to another, without any ultimate loss of heat. Thus, in the action of an ordinary steam engine, the heat from the furnace having ex- panded the water of the boiler and raised the piston, a mechanical motion is produced ; but this cannot be continued without the removal of the heat, or the contraction of the ex- panded v/ater. This is done by the condenser, and the piston descends. But then we have apparently transferred the heat from the furnace to the condenser, and in the transfer effected mechanical motion. Should the mechanical motion produced by heat be con- sidered as the effect of a simple transference of heat from one point to another, or as the result of a conversion of heat into the mechanical force of which this motion is the result ? This question leads to the following : does the heat which generates the mechanical poAver return to the thermal machine as heat, or is it conveyed away by the work performed ? If a definite quantity of air be heated it is expanded, and by its expansion it cools or loses some of its poAver of com- municating heat to neighbouring bodies. That which we should have called heat if the expansion of the air had been HEAT. 71 prevented, we call mechanical effect, or may A'iew as converted into mechanical effect ceasing to be heat; but, throwing out of the question nervous sensation, this expansion or mechani- cal effect is all the evidence we have of heat, for if the air is alloAved to expand freely, this expansion becomes the index of the heat; if the air be confined, the expansion of the matter of the vessel confining it, or of the mercury of a ther- mometer in contact Avith it, &c, are the indices of the heat. If, again, the air which has been expanded be, by mechani- cal pressure or by other means, restored to its original bulk, it is capable of heating or expanding other substances to a degree to which it would not be equal, if it had remained in its expanded state. To produce continuous motion, or the up and down stroke of a piston, we must heat and cool, just as Avith a magnetic machine we must magnetise and demagne- tise in -order to produce a continuous mechanical effect; and although, from the impossibility of insulating heat, some heat is apparently lost in the process, the result may be said to be effected by the transfer of heat from the hot to the cold body, from the furnace to the condenser. But Ave may equally well say that the heat has been converted into mechanical force, and the mechanical force back into heat; the effects are always correlative, as are the mechanical effects of an air pump, Avith which, as Ave dilate the air on one side, we con dense it on the other; and as Ave cannot dilate Avithout the reciprocal condensation, so avc cannot heat without the recip- rocal cooling, or vice versa. Hitherto the resistances of the piston or of any superim- posed weight have been thrown out of consideration, or, Avhat amounts to the same thing, it has bee,i assumed that the weight raised by the piston has descended Avith ii. The heat ha3 not merely been employed in dilating the air or vapour, but in raising the piston with its weight. If, as the vapour is cooled, the weight be permitted to descend, its mechanical force restores the heat lost by the dilatation ; but in this case 72 CORRELATION OF PHYSICAL FORCES. no part of the power can be abstracted so as to be employed for any practical purpose: this question then follows, what takes place with regard to the initial heat, if, after the ascent of the piston, the weight be removed so as not to help the pis- ton in its descent, but to fall upon a lever or produce some extraneous mechanical effect? To answer this question, let us suppose a weight to rest an a piston which confines air at a definite temperature, say for example 50°, in a cyhnder, the whole being assumed to be absolutely non-conducting for heat. A part of the heat of this confined air will be due to the pressure, since, as we have seen, compression of an elastic fluid produces heat. Suppose, now, the confined air to be heated to 70°, the piston with its superincumbent weight wiU ascend, and the temperature, in consequence of the dilatation of the air, will be somewhat lowered, say to 69° (we will assume, for the sake of simplicity, that the heat engendered by the friction of the piston compensates the force lost by friction). The piston having reached its maximum of elevation, let a cold body or condenser take away 20° from the temperature of the confined air ; the piston will noAV descend, and by the compression which the weight on it produces, will restore the 1° lost by dilatation, and when the piston reaches its original position the temperature of the air will be restored to 50°. Suppose this experiment repeated up to the rise of the piston ; but when the piston is at its full elevation, and the cold body apphed, let the weight be removed, so as drop upon a wheel, or to be used for other mechanical purposes. The descend- ing piston will not noAV reach its original point without more heat being abstracted; in consequence of the removal of the weight, there will not be the same force to restore the 1°, and the temperature will be 49°, or some fraction short of the original 50°. If this were otherwise, then, as the weight in falling may be made to produce heat by friction, we should HEAT. 73 have more heat than at first, or a creation of heat out of noth- ing—in other Avords, perpetual motion. Let us now assume that this 20° supplied in the first in- stance Avas yielded by a body at 90°, of such size and material that its total capacity for heat is equal to that of the mass of confined air': this body would be reduced in temperature to 70°, in other Avords, our furnace would have lost 20° of her.t. Let the cold body of the same size and material, used as a condenser, be at 30°. In the first experiment, the body at 30° Avould bring back the piston to its original point; but in the second experiment, or that where the Aveight has been removed, the body at 30° Avould not suffice to restore the pis- ton : to effect this, the cold body or condenser must be at a lower temperature. The question in Carnot's theory, which is not experi- mentally resolved, and which presents extreme experimental difficulty, is the following: Granted that a piston with a superimposed weight be raised by the thermic expansion of confined gas or vapour bcloAV it; if the elastic medium be restored to its original temperature by cooling, the weight in depressing the piston -will restore that portion of the heat which has been lost by the expansion, and by the mechanical effect consequent thereon ; but if the weight be removed when at its maximum of elevation, and the piston be brought back to its starting point by a necessarily cooler body than could restore it if the weight Avere not removed, would the return of the piston now restore the heat which had been lost by the dilatation, or, in other words, would pulling the piston down by cold restore the heat equally with the pressing it down by mechanical force? The argument from the impossibility of perpetual motion would say no, for if all the heat were restored, the mechanical effect produced by the fall of the weight, or the heating effect which might be made to result from this mechanical power, would be got from nothing. 4 74 CORRELATION OF PHYSICAL FORCES. Then follows another question, A-iz. Avhether, where an ex- ternal or derived mechanical effect has been obtained, Avould the return of the piston, effected Avithout the Aveight or exter- nal force to assist it, but solely by the colder body, give to this latter the same number of thermometric degrees as had been lost by the hot body in the first instance? Suppose, for instance, the cold body in our experiment to be at 20° instead of 30°, would this body gain 20°, and then reach the tempera- ture of 40° when the piston is brought back, or would its temperature be higher or lower than 40° ? The argument from the impossibility of perpetual motion does not apply here, for it doe3 not necessarily follow that 20°, on the ther- mometric scale from 20° to 40°, represents an equal amount of force to 20° on the scale from 70° to 90°, and therefore it is quite conceivable that we may lose 20° from the furnace, . and gain 20° in the condenser, and yet have obtained a cer- tain amount of derived mechanical power. It w7ill also folloAV, upon a consideration of the above imaginary experiments, that the greater the mechanical poAver required, the greater should be the difference between the temperature of the furnace and that of the condenser ; but the exact relation in - temperature between these, for a given mechanical effect, has not, as far as I am aware, been satisfactorily estabhshed by experiment, though it has been shown that steam at high pressure produces, comparatively, a greater mechanical effect for the same number of degrees than steam at Ioav pressure. Carnot, assuming the number of degrees of temperature to "be restored, but at a loAver point of the thermometric scale, termed this the fall (chute) of caloric. The mechanical effect cf heat, on this view, may be likened to that of a series of cascades on Avater-whcels. The highest cascade turns a wheel, and produces a given mechanical effect; the Avater which has produced this cannot again effect it at the samo level without being carried back to its original elevation, i. e. HEAT. 75 wilhout an extra force being employed equivalent to, or ra her a fraction more than the force of the descending water ; but though its poAver is spent Avith reference ta-the- first wheel, the same water may, by falhug over a new precipice upon a second whee^, again reproduce the same mechanical effect (strictly speaking, rather more, for it has approximated the centre of gravity), and so on, until no lower fall can be attained. So Avith heat: it involves no necessity of assuming perpetual motion to suppose that, after a given mechanical effect, produced by a certain loss of heat, the number of degrees lost from the original temperature may be restored to the condenser, but at a lower point of the thermometric scale. If work has been done, i. c. if force has been parted with, the original temperature itself cannot be restored, but there is no a priori impossibility in the same number of degrees of heat as have been converted into Avork being con- veyed to a condensing body so cold that, when it receives this heat, it will still be beloAV the original temperature to which the Avork-producing heat was added. In the theory of the steam-engine, this subject possesses a great practical interest. Watt supposed that a given weight of water required the same quantity of Avhat is termed total heat (that is, the sensible added to the latent heat) to keep it in the state of vapour, Avhatcver Avas the pressure to Avhich it was subjected, and, consequently, 1ioaat- eA-er its expansive force varied. Clement Desormes Avas also supposed to have experimentally verified this laAv. If this were so, vapour raising a piston with a weight attached Avould produce mechanical power; and yet, the same heat existing as at first, there would be no expenditure of the initial force ; and if Ave suppose that the heat in the condens- er was the real representative of the original heat, Ave should get perpetual motion. Southern supposed that the latent heat was constant, and that the heat of v;i;-xir under 76 CORRELATION OF PHYSICAL FORCES. pressure increased as the sensible heat. M. Despretz, in 1832, made some experiments, Avhich led him to the con- clusion that the increase was not in the same ratio as the sensible heat, but that yet there Avas an increase ; a result confirmed and A'erified with great accuracy by M. Regnault, in some recent and elaborate researches. What seems to have occasioned the error in Watt and Clement Desormcs' experiments was, the idea invoked in the term latent heat; by which, supposing the phenomenon of the disappearance of sensible heat to be due to the absorption of a material sub- stance, that substance, ' caloric,' was thought to be restored when the vapour was condensed by water, even though the water was not subjected to pressure ; but to estimate the total heat of vapour under pressure the vapour should be condensed while subjected to the same pressure as that under which it is generated, as was done in M. Despretz and M. Regnault's experiments. M. Seguin, in 1839, controverted the position that derived power could be got by the mere transfer of heat, and by calculation from certain known data, such as the law of Mar- iotte, viz. that the elastic force of gases and vapours increas- ed directly with the pressure ; and assuming that for vapour between 100° and ISO11 centigrade, each degree of elevation of temperature was produced by a thermal unit, he deduced the equivalent of mechanical work capable of being perform- ed by a given decrement of heat; and thus concluded that, for ordinary pressures, about one gramme of water losing one degree centigrade Avould produce a force capable of rais- ing a weight of 500 grammes through a space of one metre : this estimate is a little beyond that given by the converse ex- periments of Mr. Joule, already stated, in which the heat produced by a given amount of mechanical action is estimat- ed. I am not aware that the amount of mechanical Avork which is produced by a given quantity of heat has been di- rectly established by experiment, though some approximative HEAT. 77 results in particular cases have been given. TheoreticaUy it should be the same—that is to say, if a fall of 772 lbs. through a space of one foot will raise the temperature of 1 lb. of Avater through one degree of Fahrenheit, then the fall in the temperature of 1 lb: of water through one degree of Fah- renheit should be able to raise 772 lbs. through a space of one foot. The calculations of M. Seguin are not far from this, but since the elaborate experiments of M. Regnault he has expressed some doubt of the correctness of his former estimate, as by these experiments it appears that, Avithin cer- tain limits, for elevating the temperature of compressed va- pour by one degree, no more than about three-tenths of a de- gree of total heat is required ; consequently, the equivalent multiplied in this ratio would be 1,6G6 grammes, instead of 500. Other investigators have given numbers more or less discordant; so that, Avithout giving any opinion on their dif- ferent results, this question may be considered at present far from settled. M. Regnault himself does not give the law by which the ratio of heat varies Avith reference to the pressure, and is still belieA-ed to be engaged in researches on the sub- ject—one involving questions of which experiments on the mechanical effects of elastic fluids seem to offer the most pro- mising means of solution. I have endeavoured to give a proof (by showing the anomaly to which the contrary conclusion would lead) that, whatever amount of mechanical poAver is produced by one mode of application of heat, the same should, in theory, be equally produced by any other mode. But in practice the difference is immense ; and therefore it becomes a question of great interest practically to ascertain what is the most convenient medium on which to apply the heat employed, and the best machinery for economising it. One great problem to be solved is the saving of the heat which the steam in or- dinary engine?, after having done its work, carries into the condenser, or, in the high-pressure engine, into the air. It 78 CORRELATION OF PHYSICAL FORCES. is argued you have a large amount of fuel consumed to raise water to the boiling point, at Avhich its efficiency as a motive agent commences. After it has done a small portion of work, and while it still retains a A'ery large portion of the heat ori- ginally communicated to it, you reject it, and have to start again with a fresh portion of steam which has similarly ex- hausted fuel—in other words, you throw away aU, and more * than all the heat which has been employed in raising the water to the boiling point. Various plans have been devised to remedy this. Using again the warm water of the conden- ser to feed the boiler regains a part, but a very small part, of the heat. Employing the steam first for a high pressure, and then before its rejection or condensation using it for a low pressure, cyhnder, is a second mode; a third is to use the steam, after it has done its work on the piston, as a source of heat or second furnace, to boil ether, or some hquid which evaporates at a lower temperature than Avater. These plans have certain advantages; but the complexity of apparatus, the danger from combustion of ether, and other reasons, haAre hitherto precluded their general adoption. Under the term regenerating engine various ingenious combinations have lately been suggested, and some experimental engines tried, with Avhat success it is perhaps too early at present to pronounce an opinion. The fundamental notion on which this class of engine is basecl is that the A-apour or air, when it has performed a certain amount of work, as by raising a- piston, should, instead of being condensed or blown off, be retained and again heated to its original high temperature, and then used de novo; or that it should impart its heat to some other substance, and the latter in turn impart it to the fresh vapour about to act. The latter plan has been proposed by Mr. Ericsson: he passes the air which has done its Avork through layers of Avire gauze, Avhich are heated by the rejected air, and through which the next charge of air ia made to pass. M. Seguin and Mr. Siemens have construct HEAT. 79 ed machines upon the former principle, which are said to have given good experimental results. There is, however, a theoretical difficulty in all these, not affecting their capabil- ity of acting, but affecting the question of economy, which it does not seem easy to escape from. Whether the heated aii or vapour be retained, or whether it yield its heat to a metal- lic or other substance, this heat must exercise its usual repul- sive force, and this must re-act either against the returning piston or against the incoming vapour, and require a greater pressure in that to neutralise it. Vapour raising a piston and producing mechanical force effects this with decreasing power in proportion as the piston is moved. At a certain point the piston is arrested, or the stroke, as it is termed, is completed, but there is still compressed vapour in the cyhnder capable of doing work, but so little that it is, and must in practice be neglected ; if this compressed vapour be retained, the pis- ton cannot be depressed without an extra force capable of over coming the resistance of this, so to speak, semi-compress- ed vapour, in addition to that which is requisite to produce the normal work of the machine ; and in whatever way the resi- dual force be retained, it must either be antagonised at a loss of power for the initial force, or at most can only yield Jhe more feeble power which it would have originally given if it had been alio Ave d to act for a longer stroke on the piston. It may be that a portion of this residual force may be econo- mised ; indeed, this is done when the boiler is charged with warm water from the condenser, instead of with cold water; but some, indeed a notable loss, seems inevitable. Without farther discussing the various inventions and the- ories on this subject, which are daily receiving increased de- A'elopment, it may be well to point out how far nature dis- tances art in its present state. According to some careful es- timates, the most economical of our furnaces consume from ten to tAA-enty times as much fuel to produce the same quantity of heat as an animal produces; and Matteucci found that. SO CORRELATION OF PHYSICAL FORCES. from a given consumption of zinc in a voltaic battery, a far greater mechanical effect could be produced by making it act on the limbs of a recently-killed frog, notAvithstanding the manifold defects of such an arrangement and its inferiority to the action of the hving animal, than Avhen the same bat- tery Avas made to produce mechanical poAver, by acting on an electro-magnetic or other artificial motor apparatus. The ratio in hi3 experiments Avas nearly six to one. Thus in all our arti- ficial combinations Ave can but apply natural forces, and Avith far inferior mechanism to that A\Thich is perceptible in the economy of nature. Nature is made better by no mean ; But nature makes that mean; so o'er that art, "Which you say adds to nature, is an art That nature makes. A speculation has been thrown out by Mr. Thompson, that, as a certain amount of heat results from mechanical ac- tion, chemical action, &c, and this heat is radiated into space, there must be a gradual diminution of temperature for the earth, by AA'hich expenditure, however slow, being continuous, it would ultimately be cooled to a degree incompatible Avith the existence of animal and A~egetable life—in short, that the earth and the planets of our system are parting with more heat than they receive, and are therefore progressively cool- ing. Geological researches support to some extent this A'iew, as they show that the climate of many portions of the terres- trial surface Avas atjremote periods hotter than at the present time : the animals whose fossilised remains are found in an- cient strata have their organism adapted to Avhat we should noAV term a hot climate. There are, hoAvever, so many cir- cumstances of difficulty attending cosmical speculations, that but httle reliance can be placed upon the most profound. We knoAv not the original source of terrestrial heat; still less that of the solar heat; we know not whether or not sys- HEAT. 81 tenis of planets may be so constituted as to communicate forces, inter se, so that forces which have hitherto escaped detection may be in a continuous or recurring state of inter change. The moA'ements produced by mutual gravitation may be the means of calling into existence molecular forces Avithin the substances of the planets themselves. As neither from observation, nor from deduction, can we fix or conjecture any boundary to the universe of stellar orbs, as each advance in talescopic poAver gives us a new shell, so to speak, of stars, Ave may regard our globe, in the limit, as surrounded by a sphere of matter radiating heat, light, and possibly other, forces. Such stellar radiations would not, from the evidence Ave have at present, appear sufficient to supply the loss of heat by terrestrial radiations ; but it is quite conceivable that the whole solar system may pass through portions of space hav- ing different temperatures, as Avas suggested, I believe, by Poisson; that as Ave have a terrestrial summer and winter, so there may be a solar or systematic summer and Avinter, in which case the heat lost during the latter period might be re- stored during the former. The amount of the radiations of the celestial bodies may again, from changes in their positions, vary through epochs Avhich are of enormous duration as re- gards the existence of the human species. The views of Mr. Thompson differ from those of Laplace, recently enforced by M. Babinet, which suppose the planets to have been formed by a gradual condensation of nebulous matter. A modification of this view might, perhaps, be sug- gested, viz. that worlds or systems, instead of being created as wholes at definite periods, are gradually changing by at- mospheric additions or subtractions, or by accretions or dim- inutions arising from nebulous substance or from meteoric bodies, so that no star or planet could at any time be said to be created or destroyed, of to be in a state of absolute stabii- 82 CORRELATION OF PHYSICAL FORCES. ity, but that some may be increasing, others dAvindling away, and so throughout the universe, in the past as in the future. When, hoAvever, questions relating to cosmogony, or to tho beginning or end of Avorlds, are contemplated from a physi- cal point of view, the period of time over which our experi- ence, in its most enlarged sense, extends, is so indefinitely minute with reference to that which must be required for any notable change, even in our oAvn planet, that a variety of the- ories may be framed equally incapable of proof or of dis- proof. We have no means of ascertaining whether many changes, which endure in the same direction for a term be- yond the range of human experience, are really continuous or only secular variations, which may be compensated for at periods far beyond our ken, so that in such cases the ques- tion of comparative stability or change can at best be only answered as to a term which, though enormous Avith refer- ference to our computations, sinks into nothing Avith reference to cosmical time, if cosmical time be not eternity. Subjects such as these, though of a kind on which the mind delights to speculate, appear, with reference to any hope of attaining reliable knowledge, far beyond the reach of any present 01 immediately prospective capacity of man. IV. ELECTRICITY. ELECTRICITY is that affection of matter or mode of force which most distinctly and beautifully relates other modes of force, and exhibits, to a great extent in a quantita- ti\-e form, its own relation Avith them, and their reciprocal relations Avith it and with each other. From the manner in Avhich the peculiar force called electricity i3 seemingly transmitted through certain bodies, such as metallic wires, the term current is commonly used to denote its apparent progress. It is very difficult to present to the mind any theory which will give a definite conception of its modus ajendi: the early theories regard its phenomena as produced either by a single fluid idio-repulsfve, but attractive of all matter, or else as produced by two fluids, each idio-repulsive but attractive of the other. No substantive theory has been proposed other than these two ; but although this is the case, I think I shall not be unsupported by many who have atten- tively studied electrical phenomena, in viewing them as re- sulting, not from the action of a fluid or fluids, but as a mole- cular polarisation of ordinary matter, or as matter acting by attraction and repulsion in a definite direction. Thus, the transmission of the Aroltaic current in liquids is viewed by Grotthus as a series of chemical affinities acting in a definite direction : for instant e, in the electrolysis of water, i. e. its decomposition when placed betAveen the poles or electrodes 84 CORRELATION OF PHYSICAL FORCES. of a voltaic battery, a molecule of oxygen is supposed to be displaced by the exalted attraction of the neighbouring elec- trode ; the hydrogen liberated by this displacement unites with the oxygen of the contiguous molecule of water ; this in turn liberates its hydrogen, and so on; the current being nothing else than this molecular transmission of chemical affinity. There is strong reason for believing that, Avith some ex- ceptions, such as fused metals, liquids do not conduct elec- tricity without undergoing decomposition ; for even in those extreme cases where a trifling effect of conduction is appar- ently produced Avithout the usual elimination of substances at the electrodes, the latter when detached from the circuit shoAV, by the counter-current which they are capable of pro- ducing when immersed in a fresh liquid, that their superficial state has been changed, doubtless by the determination to the surfaces of minute layers of substances having opposite chemical characters. The question Avhether or not a minute conduction in liquids can take place unaccompanied by chemi- cal action, has however been much agitated, and may be re- garded as inter apices of the science. Assuming for the moment electrolysis to be the only known electrical phenomenon, electricity would appear to con- sist in transmitted chemical action. All the evidence we have is, that a certain affection of matter or chemical change takes place at certain distant points of space, the change at one point having a definite relation to the change at the other, and being capable of manifestation at any intermediate points. If, now, the electrical effect called induction be examined, the phenomena will be found equally opposed to the theory of a fluid, and consistent with that of molecular polarisation. When an electrified conductor is brought near another which is not electrified, the latter becomes electrified by influence or induction, as it is termed, the nearest parts of each of these ELECTRICITY. 85 two bodies exhibiting states of electricity of the contrary denominations. Until this subject Avas investigated by Fara- day, the intervening non-conducting body or dielectric was supposed to be purely negative, and the effect Avas attributed to the repulsion at a distance of the electrical fluid. Fara- day showed that these effects differed greatly according to the dielectric that Avas interposed. Thus they were more exalted with sulphur than Avith shellac ; more with shellac than with glass, &c. Matteucci, though differing from Faraday as to the explanation he gave, added some experiments which proArc that the intervening dielectric is molecularly polarised. Thus a number of thin plates of mica are superposed like a pack of cards ; metallic plates are applied to the outer facings, and one of them electrified, so that the apparatus is charged like a Leyden phial. Upon separating the plates Avith insulating handles, each plate is separately electrified, one side of it being positive and the other negative, showing very neatly and decisively a polarisation throughout the intervening sub- stances by the effect of induction. Indeed, chemical action or electrolysis may, as I have shown, be transmitted by induction across a dielectric sub- stance, such as glass, but apparently only while the glass is being charged with electricity. A Avire passing through and hermetically sealed into a glass tube, a short portion only pro- jecting, is made to dip into water contained in a Florence flask; the flask is immersed in water to an equal depth with that Avithin it; the wire and another similar Avire dipping into the outer Avater are made to communicate metallically with the powerful electrical machine known as Rhumkorf s coil; bubbles of gas instantly ascend from the exposed por- tions of the wires, but cease after a certain time, and are reneAved Avhen, after an interval of separation, the coil is pgain connected with the wires. The following interesting experiment by Mr. Karsten Toes a step farther in corroboration of the molecular changes 83 CORRELATION OF PHYSICAL FORCES. consequent upon electrisation: A coin is placed on a pack of thin plates of glass, and then electrified. On removing the coin and breathing on the glass plate, an impression of the coin is perceptible ; this show3 a certain molecular change on the surface of the glass opposed to the plate, or of the vapours condensed on such surface. This effect might, and has been interpreted as arising from a film of greasy deposit, supposed lo exist on the plate; the impressions, however, have been proved to penetrate to certain depths below the surface, and not to be removed by polishing. The following experiment, hoAvever, goes farther: On separating carefully the glass plates, images of the coin can be developed- on each of the surfaces, shoAving that the mole- cular change has been transmitted through the substance of the glass; and we may thence reasonably suppose that a piece of glass, or other dielectric body, if it could be split up while under the influence of electric induction, Avould exhibit some molecular change at each side of each lamina, hoAvever minutely subdivided. I have succeeded in farther extending this experiment, and in permanently fixing the images thus produced by electricity. BetAveen two carefully-cleaned glass plates is placed a word or device cut out of paper or tinfoil; sheets of tinfoil a little smaller than the glass plate3 are placed on the outside of each plate, and these coatings are brought into contact with the terminals of Rhumkorf s coil. After electrisation for a few seconds, the glasses are sepa- rated, and their interior surfaces exposed to the vapour of hydrofluoric acid, which acts chemically on glass; the por tions of the glass not protected by the paper device are cor- roded, while those so protected are untouched or less affected by the acid, so that a permanent etching is thus produced, which nothing but disintegration of the glass will efface. Some further experiments of mine on this subject bring out in a still more striking manner these curious molecular ELECTRICITY. 87 changes. One of the plates of gla33 havh.gbeen electrified in the manner just mentioned, is coated, on the side impressed with the inATisible electrical image, with a film of iodised collodion in the manner usually adopted for photographic purposes; it is then in a dark room immersed in a solution of nitrate of silver; then exposed to diffuse light for a few seconds. On pouring over the collodion the usual solution of pyrogalhc acid, the invisible electrical image is brought out as a dark device on a light ground, and can be permanently fixed by hyposulphite of soda. The point worthy of obser- vation in this experiment is, that this permanent image exists in the collodion film, which can be stripped off the glass, dried, and placed on any other surface, so that the molecular change consequent on electrisation has communicated, by contact or close proximity, a change to the film of collodion corres- ponding in form Avith that on the glass, but being undoubtedly of a chemical nature. Electricity has, moreover, in this ex- periment so modified the surface of glass, that it can, in its turn, modify the structure of another substance so as to alter the relation of the latter to light. It would require a curious complication of hypothetic fluids to explain this ; but if elec- tricity and light be supposed to be affections of ordinary pon- derable matter, the difficulty is only one of detail. If, again, we examine the electricity of the atmosphere, when, as is usually the case, it is positive with respect to that of the earth, we find that each successive stratum is positive to those below it and negative to those above it; and the con- verse is the case when the electricity of the atmosphere is negative with respect to that of the earth. % If another electrical phenomenon be selected, another sort of change will be found to have taken place. The electric spark, the brush, and similar phenomena, the old theories regarded as actual emanations of the matter or fluid, Elec- tricity ; I venture to regard them as produced by an emission of the material itself from whence they issue, and a molecular 88 CORRELATION OF PHYSICAL FORCES. action of the gas, or intermedium, through or across Avhich they are transmitted. The colour of the electric spark, or of the voltaic arc (i. e. the flame which plays between the terminal points of a poAverful voltaic battery), is dependent upon the substance of the metal, subject to certain modifications of the intermedium : thus, the electric spark or arc from zinc is blue ; from silver, green ; from iron, red and scintillating ; precisely the colours afforded by these metals in their ordinary combustion. A portion of the metal is also found to be actually transmitted with every electric or voltaic discharge : in the latter case, indeed, Avhere the quantity of matter acted upon is greater than in the former, the metallic particles emitted by the elec- trodes or terminals can be readily collected, tested, or even weighed. It Avould thus appear that the electrical discharge arises, at least in part, from an actual repulsion and sever- ance of the electrified matter itself, which flies off at the points of least resistance. A careful examination of the phenomena attending the electric spark or the voltaic arc, which latter is the electric disruptive discharge acting on greater portions of matter, tends to modify considerably our previous idea of the nature of the electric force as a producer of ignition and combustion. The voltaic arc is perhaps, strictly speaking, neither ignition nor combustion. It is not simply ignition ; because the mat- ter of the terminals is not merely brought to a state of incan- descence, but is physically separated and partially transferred from one electrode to another, much of it being dissipated in a vaporous state. .It is not combustion ; for the phenomena will take place independently of atmospheric air, oxygen gas, or any of the bodies usually called supporters of combustion, combustion being in fact chemical union attended with heat and light. In the voltaic arc we may have no chemical union ; for if the experiment be performed in an exhausted receiver, or in nitrogen, the substance forming the electrodes is condensed. ELECTRICITY. 89 and precipitated upon the interior of the vessel in, chemically speaking, an unaltered state. Thus, to take a very striking example, if the voltaic discharge be taken between zinc ter- minals in an exhausted receiver, a fine black powder of zinc io deposited on the sides of the receiver ; this can be collect- ed, and takes fire readily in the air by being touched with a match, or ignited wire, instantly burning into white oxide of zinc. To an ordinary observer, the zinc would appear to be burned twice—first in the receiver, where the phenomenon presents all the appearance of combustion, and secondly in the real combustion in air. With iron the experiment is equally instructive. Iron is volatilised by the voltaic arc in nitrogen or in an exhausted receiver; and Avhen a scarcely perceptible film has lined the receiver, this is Avashed with an acid, Avhich then gives, Avith ferrocyanide of potassium, the prus- sian-blue precipitate. In this case Ave readily distil iron, a metal by ordinary means fusible only at a A-ery high tempera- ture. Another strong evidence that the A-oltaic discharge con- sists of the material itself of Avhich the terminals are compos- ed, is the peculiar rotation which is observed in the light when iron is employed, the magnetic character of this metal causing its molecules to rotate by the influence of the voltaic current. If Ave increase the number of reduplications in a voltaic series, Ave increase the length of the arc, and also increase its intensity or power of overcoming resistance. With a battery consisting of a limited number, say 100 reduplications, the dire-barge Avill not pass from one terminal to the other Avith- out first bringing them into contact, but if Ave increase the number of cells to 400 or 500, the discharge will pass from one terminal to the other before they are brought into contact. The difference between Avhat is called Franklinic electricity, or that produced by an ordinary electrical machine, and voltaic elec- tricity, or that produced by the ordinary voltaic battery, is that 00 CORRELATION OF PHYSICAL FORCES. the former is of much greater intensity than the latter, or has a greater power of overcoming resistance, but acts upon a much smaller quantity of matter. If, then, a voltaic battery be formed with a vieAv to increase the intensity and lessen the quantity, the character of the electrical phenomena approxi- mate those of the electrical machine. In order to effect this, the sizes of the plates of the battery and thence the quantity of matter acted on in each cell, must be reduced, but the number of reduplications increased. Thus if in a battery of 100 pairs of plates each plate be divided, and the battery be arranged so as to form 200 pairs, each being half the original size, the quantitative effects are diminished, and the effects of intensi- ty increased. By carrying on this sub-division, diminishing the sizes and increasing the number, as is the case in the vol- taic piles of Deluc and Zamboni, effects are ultimately pro- duced similar to those of Franklinic electricity, and we thus gradually pass from the voltaic arc to the spark or electric discharge. This discharge, as I have already stated, has a colour de- pending in part upon the nature of the terminals employed. If these terminals be highly polished, a spot will be observed, even in the case of a small electric spark, at the points from which the discharge emanates. The matter of the terminals is itself affected; and a transmission of this matter across the intervening space is detected by the deposition of minute quantities of the metal or substance composing the one, upon the other terminal. If the gas or elastic medium between the terminals be changed, a change takes place in the length or colour of the discharge, showing an affection of the intervening matter. If the gas be rarefied, the discharge gradually changes with the degree of rarefaction, from a spark to a luminous gloAv or diffuse light, differing in colour in different gases, and capable of extending to a much greater distance than Avhen it takes place in air of the ordinary density. Thus, in highly attenu- ELECTRICITY. 91 ated air a discharge may be made to pass across six or seven feet of space, Avhile in air of the ordinary density it Avould not pass across an inch. An obserA'cr regarding the beauti- ful phenomena exhibited by this electric discharge in attenua- ted gas, which, from some degree of similarity in appear- ance to the Aurora Borealis, has been called the electric Au- rora, would have some difficulty in believing such effects could be due to an action of ordinary matter. The amount of gas present is extremely small; and the terminals, to a cursory examination, shoAv no change after long experiment- ing. It is therefore not to be wondered at that the first ob- servers of this and similar phenomena, regarded electricity as in itself something—as a specific existence or fluid. Even in this extreme case, hoAvever, upon a more careful examination we shall find that a change does take place, both as regards the gas and as regards the terminals. Let one of these consist of a high- ly-polished metal—a silver plate is one of the best materials for the purpose—and let the discharges in attenuated atmospheric air take place froma point, say a common sewing needle, to the surface of the polished silver plate ; it will be found that this is gradually changed in appearance opposite the point—it is ox- idated, and gradually more and more corroded as the discharge is continued. If noAV the gas be changed, and highly-rarefied hydrogen be substituted for the rarefied air, all other things remaining the same, upon passing the discharges as before the oxide aviU be cleared off the plate, and the polish to a great extent restored—not entirely, because the silver has been disinte- grated by the oxidation—and the portion which has been af- fected by the discharge will present a somewhat different ap- pearance from the remainder of the plate. A question Avill probably here occur to the reader:—What will be the effect if there be not an oxidating medium pres- ent, and the experiment be first performed in a rarefied gas, which possesses no power of chemically acting on the plate? 92 CORRELATION OF PHYSICAL FORCES. In this case there will stiU be a molecular change or disinte- gration of the plate ; the portion of it acted on by the his- charge will present a different appearance from that which is beyond its reach, and a AAiiitish film, someAvhat similar to that seen on the mercurialised portions of a daguerreotype, will gradually appear on the portion of the plate affected by the discharge. If the gas be a compound, as carbonic oxide, or a mixture, as oxygen andhyarogen, and consequently contain elements capable of producing oxidation and reduction, then the effect upon the plate Avill depend upon whether it be pos- itive or negatiATe ; in the former case it wiU be oxidated, in the hitter the oxide, if existing, will be reduced. This effect Avill also take place in atmospheric air, if it be highly rare- fied, and can hardly be explained otherwise than by a mole- cular polarisation of the compound gas. If, again, the metal be reduced to a small point, and be of such material that the gas cannot act chemically upon it, it can yet be shown to be disintegrated by the electric spark. Thus, let a fine plati- num wire be hermetically scaled in a glass tube, and the ex- tremity of the tube and the wire ground to a flat surface, so as to expose a section only of the wire ; after taking the discharge from this for some time, it will be found that the platinum wire is worn away, and that its termination is sensibly below the level of the glass. If the discharges from such a plati- num wire be taken in gas contained in a narrow tube, a cloud or film consisting of a deposit of platinum will be seen on the part of the tube surrounding the point. Another curious effect which, in addition to the above, I have detected in the electrical discharge in attenuated media, is that when passing between terminals of a certain form, as from a wire placed at right angles to a polished plate, the dis- charge possesses certain phases or fits of an alternate character, so that, instead of impressing an uniform mark on a polished plate, a series of concentric rings is formed. Priestley observed that, after the discharge of a Leyden ELECTRICITY. 93 battery, rings consisting of fused globules of metal were formed on the terminal plates ; in my experiments made in attenuated media, alternate rings of oxidation and deoxida- tion are formed. Thus, if the plate be polished, coloured rings of oxide will alternate with ring? of polished or unoxi- dated surface ; and if the plate be previously coated with an uniform film of oxide, the oxide will be removed in concen- tric spaces, and increased in the alternate ones, shoAving a lateral alternation of positive and negative electricity, or electricity of opposite character in the same discharge. It would be hasty to assert that in no case can the electri- cal disruptive discharge take place without the terminals be- ing affected. I have, howeA-er, seen no instance of such a re- sult where the discharge has been sufficiently prolonged, and the terminals in such a state as could be expected to render manifest slight changes. The next question Avhich Avould occur in following out the enquiry Avhich has been indicated, Avould probably be, What io the action upon the gas itself? is this changed in any man- ner ? In answer to this, it must be admitted that, in the present state of experimental knowledge on this subject, certain gases only appear to leave permanent traces of their having been changed by the discharge, while others, if affected by it, which, as will be presently seen, there are reasons to be- hove they are, return to their normal state immediately after the discharge. In the former class we may place many compound gases, as ammonia, olefiant gas, protoxide of nitrogen, deutoxide of nitrogen, and others, which are decomposed by the action of the discharge. Mixed gases are also chemically combined : for instance, oxygen and hydrogen unite and form Avater; common air gives nitric acid ; chlorine and aqueous A-apour five oxygen, the chlrvir.e uniting Aviih the hydrogen of the water. 94 CORRELATION OF PHYSICAL FORCES. But, further than this, in the case of certain elementary gases a permanent change is effected by the electrical dis- charge. Thus, oxygen submitted to the discharge is par- tially changed into the substance now considered to be an al- lotypic condition of oxygen ; and there is reason to believe that when the change takes place, there is a definite polar condition of the gas, and that definite portions of it are affected —that in a certain sense one portion of the oxygen bears temporarily to the other the relation which hydrogen ordina- rily does to oxygen. If the discharge be passed through the vapour of phos- phorus in the vacuum of a good air-pump, a deposit of allotro- pic phosphorus soon coats the interior of the receiver, show- ing an analogous change to that produced in oxygen ; and in this case a series of transverse bands or stratifications appears in the discharge, showing a most striking alteration in its physical character, dependent on the medium across which it is transmitted. These effects were first observed by me in the year 1852. They have since been much examined by continental philosophers, and much extended by Mr. Gassiot; but no satisfactory rationale of them has yet been gi\-en. There are many gases which either do not show any per- manent change, or (which is more probably the case) the changes produced in them by the electrical discharge have not yet been detected. Even with these gases, however, the difference of colour, of length, or of the different position of a certain dark space or spaces which appear in the discharge, show that the discharge differs for different media. We neA'- er find that the discharge has itself added to or subtracted from the total weight of the substances acted on: we find no evidence of a fluid but the visible phenomena themselves; and those we may account for by the change Avhich takes place in the matter affected. I have here, as elsewhere, used words of common accep- tation, such as ' matter affected by the discharge,' &c. though ELECTRICITY. 05 upon the vieAV I am suggesting, the discharge is itself this affection of matter : and the writing these passages affords, to me at least, a striking instance of hoAv much ideas are bound up in Avords, when, to express a vieAV differing from the received one, Avords involving the receired one are neces- sarily used. Passing now to the effect of the transmission of electri- city by the class of the best conducting bodies, such as the metals and carbon, here, though we cannot at present give the exact character of the motion impressed upon the particles, there are yet many experiments which shoAV that a change takes place in such substances when they arc affected by elec- tricity. Let discharges from a Leyden jar or battery be passed through a platinum wire, too thick to be fused by the dis- charges, and free from constraint, it Avill be found that the wire is shortened ; it has undergone a molecular change, and apparently been acted on by a force tranverse to its length. If the discharges be continued, it gradually gathers up in small irregular bends or convolutions. So Avith voltaic elec- tricity : place a platinum wire in a trough of porcelain, so that Avhen fused it shall retain its position as a wire, and then ignite it by a voltaic battery. As it reaches the point of fu- sion it will snap asunder, showing a contraction in length, and consequently a distension or increase in its transverse dimen- sions. Perform the same experiment with a lead wire, which can be more readily kept in a state of fusion, and fol- low it, as it contracts, by the terminal wires of the batter: ; it Avill be seen to gather up in nodules, which press on each other like a string of beads of a soft material which have been longitudinally compressed. As we increase the thickness of the Avires in these exper- iments with reference to the electrical force employed, we les- ecu the perceptible effect: but even in this case we shall be enabled safely to infer that rnrr.o molecular change accompa- 96 CORRELATION OF THYSICAL FORCES. nies the transmission of electricity : the AA'ires are heated in a degree decreasing as their thickness increases—but by in- creasing the delicacy of our tests as the heating effects de- crease in intensity, we may indefinitely detect the augmenta- tion of temperature accompanying the passage of electri- city—and wherever there is augmentation of temperature there must be expansion or change of position of the mole- cules. Again, it has been observed that wires Avhich have for a long time transmitted electricity, such as those which have served as conductors for atmospheric electricity, have their texture changed, and are rendered brittle. In this observa- tion, however, though made by a skillful electrician, M. Pel- tier, the effects of exposure to the atmosphere, to changes of temperature, &c, have not been sufficiently eliminated to render it worthy of entire confidence. There are, hoAvever, other experiments which show that the elasticity of metals i3 changed by the passage through them of the electric current. Thus M. Wertheim has, from an elaborate series of ex- periments, arrived at the conclusion that there is a temporary diminution in the coefficient of elasticity in Avires while they are transmitting the electric current, which is independent of the heating effect of the current. M. Dufour has made a considerable number of experi- ments with the view of ascertaining if any permanent change in metals is effected by electrisation. He arrives at the cu- rious result that in a copper wire through Avhich a feeble \-ol- taic current has passed for several days, a notable diminution in tenacity takes place; while, in an iron Avire, the tenacity is increased; and that these effects were more perceptible when the wires had been electrised for a long time (nineteen days) than for a short time (four days). The copper wire was. in his experiment, not perfectly pure ; so that the effect, or a portion of it, might be due to the state of alloy: in the case of iron, the magnetic character of the metal would prob- ELECTRICITY. 97 ably modify the effects, and might account for the opposite character of the results Avith these two metals. Matteucci has made experiments on the conduction of electricity by bismuth in directions parallel or transverse to the planes of principal cleavage, and he finds that bismuth conducts electricity and heat better in the direction of the cleavage planes than in that transverse to them. Many other experiments have been made both on the pro- duction of thermo-electric currents by two portions of the same crystalline metal, but Avith the planes of crystallization arranged in different directions relatively to each other, and also on the differences in conduction of heat and electricity according to the direction in which they are transmitted with reference to the planes of crystallization. It is found, moreover, that the slightest difference in ho- mogeneity in the same metal enables it when heated to pro- duce a thermo-electric current, and that metals in a state of fusion, in Avhich state they may be presumed to be homoge- neous throughout, give no thermo-electric current: thus, hot in contact with cold mercury has been sIioaati by Matteucci to giA'e no thermo-electric current, and the same is the case Avith portions of fused bismuth unequally heated. The fact that the molecular structure or arrangement of a body influences—indeed I may say determines—its conduct- ing power, is by no means explained by the theory of a fluid; but if electricity be only a transmission of force or motion, the influence of the molecular state is just what would be expected. Carbon, in a transparent crystalline state, as dia- mond, is as perfect a non-conductor as we know; Avhile in an opaque amorphous state, as graphite or charcoal, it is one of the best conductors : thus, in the one state, it transmits light and stops electricity, in the other it transmits electricity and stops light. It is a circumstance worthy of remark, that the arrange- ment of molecules, which renders a sohd body capable of 5 98 CORRELATION OF PHYSICAL FORCE?. transmitting hght, is most unfavourable to its transmission oi electricity, transparent solids being very imperfect conductors of electricity; so all gases readily transmit light, but are amongst the worst conductors of electricity, if, indeed, prop- erly speaking, they can be said to conduct at all. The conduction of electricity by different classes of bodies has been generally regarded as a question of degree: thus metals Avere viewed as perfect conductors, charcoal less so, Avater and other aquids as imperfect conductors, &c. But, in fact, though between one metal and another the mode of transmission may be the same and the difference one of de- gree, a different molecular effect obtains, when we contrast metals Avith electrolytic liquids and these wTith ga- es. Attenuated gases may be, in one sense, regarded as non- conductors, in another, as conductors ; thus if gold-leaves be made to diverge, by electrical repulsion, in air at ordinary pressure, they in a short time collapse ; while in highly-rare- fied air, or what is commonly termed a vacuum, they remain divergent for days ; and yet electricity of a certain degree of tension passes readily across attenuated air, and with diffi- culty across air of ordinary density. Again, where the electrical terminals arc brought to a state of visible ignition, there are symptoms of the transmis- sion of electricity of low tension across gases; but no such effects have been detected at loAArcr temperatures. All this presents a strong argument in favour of the transmission of electricity across gases being effected by the disruptive dis- charge, and not by a conduction similar to that which takes place Avith metals or with electrolyte;-. The ordinary attractions and repulsions of electrified bodies present no more difficulty when regarded as being pro- duced by a change in the state or relations of the matter af- fected, than do the attractions of the earth by the sun, or of a leaden ball by the earth; the hypothesis of a fluid is not considered necessary for the latter, and need not be so for the ELECTRICITY. 99 former class of phenomena. How the phenomena are pro- duced to which the term attraction is applied is still a mys- tery. Newton, speaking of it, says, 'What I call attraction may be performed by impulse, or by some other means un- known to me. I use that Avord here to signify only in gen- eral any force by which bodies tend toAvards one another, whatsoever be the cause.' If we suppose a fluid to act in at* tractions and repulsions, the imponderable fluid must drag or push the matter with it: thus Avhen we feel a stream of air rushing from an electrified metallic point, each molecule of air contiguous to the point being repelled, another takes its place, Avhich is in its turn repelled:—hoAV does a hypo- thetic fluid assist us here ? If we say the electrical fluid re- pels itself, or the same electricity repels itself, we must go farther and assert, that it not only repels itself, but either communicates its repulsive force to the particles of the air, or carries wiili it the particle of air in its passage. Is it not more easy to assume that the particle of air is in such a state that the ordinary forces which keep it in equilibrium are dis- turbed by the electrical force, or force in a definite direction communicated to it, and that thus each particle in turn re- cedes from the point? As this latter force is increased, not only doe3 the particle of air Avhich was contiguous to the me- tallic point recede, but the cohesion of the extreme particles of metal may be overcome to such an extent that these are detached, and the brush or spark may consist wholly or in part of minute particles of the metal itself thrown off. Of this there is some evidence, though the point can hardly bo considered as proved. A similar effect undoubtedly takes place with voltaic electricity, acting upon a terminal im- mersed in a liquid ; thus if metallic terminals of a powerful voltaic battery be immersed in water, metal, or the oxide of metal, is forcibly detached, producing great heat at the point of disruption. If we apply ourselves to the effect of electricity in the 100 CORRELATION OF PHYSICAL FORCES. animal economy, we find that the first rationale given of the convulsive effect produced by transmission through the living or recently killed animal was, that electricity itself, something substantive, passed rapidly through the body, and gave rise to the contractions ; step by step we are now arriving at the conviction that consecutive particles of the nerves and mus- cles are affected. Thus the contractions which the prepared leg of a frog undergoes at the moment it is submitted to a voltaic current, cease after a time if the current be contin- ued, and are renewed on breaking the circuit, i. e. at the mo- ment when the current ceases to traverse it. The excitabil- ity of a nerve, moreover, or its power of producing muscular contraction, is weakened or destroyed by the transmission of electricity in one direction, while the excitability is increased by the transmission of electricity in the opposite direction; showing that the fibre or matter itself of the nerATe is changed by electrisation, and changed in a manner bearing a direct re.ation to the other effects produced by electricity. Portions of muscle and of nerve present different electri- cal states Avith reference to other portions of the same muscle or nerve ; thus the external part of a muscle bears the same relation to the internal part as platinum does to zinc in the voltaic battery ; and dehcate galvanoscopes will show electri- cal effects when interposed in a conducting circuit Connecting the surface of a nerve with its interior portions. Matteucci has proved that a species of voltaic pile may be formed by a series of slices of muscle, so arranged that the external part of one slice may touch the internal part of the next, and so on. Lastly, the magnetic effects produced by electricity &ho show a change in the molecular state of the magnetic sub- stance affected; as Ave shall see when the subject of magnet- ism is discussed. I have taken in succession all the known classes of elec- trical phenomena; and, as far as I am aware, there is not an ELECTRICITY. 101 electrical effect, where, if a close investigation be instituted, and the materials chosen in a state for exhibiting minute changes, evidence of molecular change will not be detected; thus, excepting those cases where infinitesimally small quan- tities of matter are acted on, and our means of detection fail, electrical effects are knoAATi to us only as changes of ordinary matter. It seems to me as easy to imagine these changes to be effected by a force acting in definite directions, as by a fluid which has no independent or sensible existence, and which, it must be assumed, is associated with, or exerts a force acting upon ordinary matter, or matter of a different order from the supposed fluid. As the idea of the hypothetic fluid is pursued, it gradually vanishes, and resolves itself into the idea of force. The hypothesis of matter Avithout weight presents in itself, as I believe, fatal objections to the theories of electrical fluids, which are entirely removed by viewing electricity as force, and not as matter. If it be said that the effects we have been considering may still be produced by a fluid, and that this fluid acts upon ordinary matter in certain cases, polarising the matter af- fected or arranging its particles in a definite direction, whilst in others, by its attractive or repulsive force, it carries Avith it portions of matter; yet, if the fluid in itself be incapable of recognition by any test, if it be only evidenced by the changes Avhich it operates in ponderable matter, the Avorda fluid and force become identical in meaning; we may as well say that the attraction of gravitation or weight is occasioned by a fluid, as that electrical changes are so. When, as is constantly done in common parlance, a house is said to be struck, windoAvs broken, metals fused or dissipa- ted by the electrical fluid, are not the expressions used such as, if not sanctioned by habit, would seem absurd? In all the cases of injury done by lightning there is no fluid per- ceptible ; the so-called sulphurous odour is either ozone de- veloped by the action of electricity on atmospheric air, or tho 102 CORRELATION OF PHYSICAL FORCES. vapour of some substance dissipated by the discharge ; on the other hand, it seems more consonant Avith experience to re- gard these effects as produced by force, as we have analogous effects produced by admitted forces, in cases where no one would invoke the aid of a hypothetic fluid for explanation. For instance, glasses may be broken by electrical discharges ; so may they by sonorous vibrations. Metals electrified or magnetised will emit a sound; so they will if struck, or if a musical note with which they can vibrate in"unison be sounded near to them. Even chemical decomposition, in cases of feeble affinity, may be produced by purely mechanical effects. A number of instances of this have been collected by M. Becquerel; and substances whose constituents are held together by feeble af- finities, such as iodide of nitrogen and similar compounds, are decomposed by the vibration occasioned by sound. If, instead of being regarded as a fluid or imponderable matter sui generis, electricity be regarded as the motion of an ether, equal difficulties are encountered. Assuming ether to pervade the pores of aU bodies, is the ether a conductor or non-conductor ? If the latter—that is, if the ether be incapa- ble of transmitting the electrical Avave—the ethereal hypothe- sis of electricity necessarily falls ; but if the motion of the ether constitute what we call conduction of electricity, then the more porous bodies, or those most permeable by the ether, should be the best conductors. But this is not the case. If, again, the metal and the air surrounding it are both per- vaded by ether, Avhy should the electrical wave affect the ether in the metal, and not stir that in the gas? To support an ethereal hypothesis of electricity, many additional and hardly reconcilable hypotheses must be imported. The fracture and comminution of a non-conducting body, the fusion or dispersion of a metallic Avire by the electrical discharge, are effects equally difficult to conceive upon the hypothesis of an ethereal Aibration, as upon that of a fluid, ELECIRICITY. 103 but are necessary results of the sudden subversion of mole- cular polarisation, or of a sudden or irregular vibratory move- ment of the matter itself. A\re see similar effects produced by sonorous Aibrations, which might be called conduction and non-conduction of sound. One body transmits sound ea- sily, another stops or deadens it, as it is termed—i. e. dis- perses the vibrations, instead of continuing them in the same direction as the primary impulse ; and solid bodies may, as has been above observed, be shivered by sudden impulses of sound in those cases where all the parts of the body cannot uniformly carry on the undulatory motion. The progressive stages in the History of Physical Philoso- phy Avill account in a great measure for the adoption by the early electricians of the theories of fluids. The ancients, when they witnessed a natural phenomenon, removed from ordinary analogies, and unexplained by any mechanical action known to them, referred it to a soul, a spiritual or preternatural poAver : thus amber and the magnet were supposed by Thales to have a soul; the functions of digestion, assimilation, &c, were supposed by Paracelsus to be effected by a spirit (the Archoous). Air and gases were also at first deemed spiritual, but subsequently became invest- ed Avith a more material character; and the word gas, from geist, a ghost or spirit, affords us an instance of the gradual transmission of a spiritual into a physical conception. The establishment by Torricelli of the ponderable charac- ter of air and gas, sliOAved that substances which had been deemed spiritual and essentially different from ponderable matter were possessed of its attributes. A less superstitious mode of reasoning ensued, and now aeriform fluids were sliOAvn to be analogous in many of their actions to liquids or known fluids. A behef in the existence of other fluids, differ- ing from air as this differed from water, grew up, and Avhen a new phenomenon presented itself, recourse was had to a hypothetic fluid for explaining the phenomenon and connects 104 CORRELATION OF PHYSICAL FORCES. ing it Avith others ; the mind once possessed of the idea of a fluid, soon invested it with the necessary powers and proper- ties, and grafted upon it a luxurious vegetation of imaginary offshoots. Iu what I am here throAving out, I Avish to guard myself from being supposed to state that the theory, historically viewed, followed exactly the dates of the discoveries which were effectual in changing its character; sometimes a dis- covery precedes, at other times it succeeds to a change in the general course of thought; sometimes, and perhaps most frequently, it does both—i. e. the discovery is the result of a tendency of the age and of the continually improved methods of observation, and Avhen made, it strengthens and extends the views which have led to it. I think the phases of thought which physical philosophers have gone through, will be found generally such as I have indicated, and that the gradual ac- cumulation of discoveries which has taken place during the more recent periods, by showing what effects can be produced by dynamical causes alone, is rapidly tending to a general dynamical theory into which that of the imponderable fluids promises ultimately to merge. Commencing Avith electricity as an initiating force, we get motion directly produced by it in various forms ; for in- stance, in the attraction and repulsion of bodies, evidenced by mobile electrometers, such as that of Cuthbertson, where large masses are acted on; the rotation of the fly-wheel, another form of electrical repulsion, and the deflection of the galvanometer needle, are also modes of palpable, visible motion. It would folloAV, from the reasoning in this essay, that when electricity performs any mechanical wrork which does not return to the machine, electrical power is lost. It would be unsuitable to the scope of this work to give the mathemati- cal labours of M. Clausius and others here ; but the follow- ing experiment, which I devised for making the result evi- ELECTRICITY. 105 dent to an audience at the Royal Institution, will form a useful iUustration:—A Leyden jar, of one square foot coated surface, has its interior connected with a Cuthbertson's elec- trometer, between which and the outer coating of the jai are a pair of discharging baUs fixed at a certain distance (about half an inch apart). Between the Leyden jar and the prime conductor is inserted a small unit jar of nine inches surface, the knobs of which are 0*2 inch apart. The balance of the electrometer is now fixed by a stiff wire inserted between the attracting knobs, and the Leyden jar charged by discharges from the unit jar. After a certain number of these, say twenty, the discharge of the large jar takes place across the half inch interval. This may be viewed as the expression of electrical power received from the unit jar. The experiment is now repeated, the wire between the balls haATing been removed, and therefore the ' tip,' or the raising of the weight, is performed by the electri- cal repulsion and attraction of the two pairs of balls. At tAventy discharges of the unit jar the balance is subverted, and one attracting knob drops upon the other; but no dis- charge takes place, shoAving that some electricity has been lost or converted into the mechanical poAver which raised the balance. By another mode "'of expression, the electricity may be supposed to be masked or analogous to latent heat, and it would be restored if the ball were brought back without dis- charge by extraneous force. If the discharge or other elec- trical effects were the same in both cases, then, since the raising of the ball or weight is an extra mechanical effort, and since the weight is capable by its fall of producing elec- tricity, heat, or other force, it would seem that force could be got out of nothing, or perpetual motion obtained. The above experiment is suggestive of others of a similar character, Avhich may be indefinitely varied. Thus I have found that two balls made to diverge by electricity do not 106 CORRELATION OF PHYSICAL FORCES. give to an electrometer the same amount of electricity as they do if, whilst similarly electrified, they are kept forcibly to- gether. This experiment is the converse of the former one. There is an advantage in electrical experiments of this class as compared witli those on heat, viz. that though there is no perfect insulation for electricity, yet our means of insula- tion are immeasurably superior to any attainable for heat. Electricity directly produces heat, as shown in the ignited wire, the electric spark, and the voltaic arc: in the latter the most intense heat writh which we are acquainted—so in- tense, indeed, that it cannot be measured, as every sort of matter is dissipated by it. In the phenomenon of electrical ignition, as shown by a heated conjunctive wire, the relation of force and resistance, and the correlative character of the two forces, electricity and heat, are strikingly demonstrated. Let a thin wire of plati- num join the terminals of a voltaic battery of suitable poAver, the Avire will be ignited, and a certain amount of chemical action will take place in the cells of the battery—a definite quantity of zinc being dissolved and of hydrogen eliminated in a given time. If now the platinum wire be immersed in Avater, the heat will, from the circulating currents of the liquid, be more rapidly dissipated, and we shall instantly find that the chemical action in the battery will be increased, more zinc will be dissolved, and more hydrogen eliminated for the same time ; the heat being conveyed away by the Avater, more chemical action is required to generate it, just as more fuel is required in proportion as evaporation is more rapid. Reverse the experiment, and instead of placing the wire in water, place it in the flame of a spirit lamp, so that the force of heat meets with greater resistance to its dissipation. We now find that the chemical action is less than in the first or normal experiment. If the wire be placed in other differ- ent gaseous or liquid media, we shall find that the chemical ELECTRICITY. 107 action of the battery will be proportioned to the facility Avith which the heat is circulated or radiated by these media, and Ave thus establish an alternating reciprocity of action between these two forces: a similar reciprocity may be established between electricity and motion, magnetism and motion, and so of other forces. If it cannot be reahsed with all, it is probably because we have not yet eliminated interfering ac- tions. If we carefully think over the matter, Ave shall, unless I am much mistaken, arrive at the conclusion that it cannot be otherwise, unless it be supposed that a force can arise from nothing—can exist without antecedent force. In the phenomenon of the voltaic arc, the electric spark, &c, to which I have already adverted, electricity directly produces light of the greatest known intensity. It directly produces magnetism, as shoAvn by Oersted, who first distinctly proved the connection between electricity and magnetism. These two forces act upon each other, not in straight hnes, as all other known forces do, but in a rectangular direction; that is, bodies affected by dynamic electricity, or the conduits of an electric current, tend to place magnets at right angles to them ; and, conversely, magnets tend to place bodies con- ducting electricity at right angles to them. Thus an electric current appears to have a magnetic action, in a direction cutting its oavu at right angles; or, supposing its section to be a circle, tangential to it: if, then, we reverse the position, and make the electric current form a series of tangents to an imaginary cylinder, this cylinder should be a magnet. This is effected in practice by coiling a Avire as a helix or spiral, and this, when conducting an electrical current, is to all in- tents and purposes a magnet. A soft iron core placed within such a helix has the property of concentrating its power, and then we can, by connection or disconnection writh the source of electricity, instantly make or unmake a most poAverful magnet. We may figure to the mind electrified and magnetised 10S CORRELATION OF PHYSICAL FORCES. matter, as hnes of which the extremities repel each other in a definite direction; thus, if a line A B represent a Avire affected by electricity, and superposed on c d a wire affected by magnetism, the extreme points A and B Avill be repelled to the farthest distances from the points c and D, and the line A b be at right angles to the line c d ; and so, if the lines be subdivided to any extent, each will have two extremities or poles repulsive of those of the other. If the line of matter affected by electricity be a liquid, and consequently have entire mobility of particles, a continuous mo\-ement Avill be produced by magnetism, each particle successively tending, as it were, to fly off at a tangent from the magnet: thus, place a flat dish containing acidulated v/ater on the poles of a powerful magnet, immerse the terminals of a voltaic battery in the hquid just above the magnetic poles, so that the lines of electricity and of magnetism coincide ; the Avater will now assume a movement at right angles to this line, floAving con- tinously, as if bloAvn by an equatorial wind, Avhich may be made east or west with reference to the magnetic poles by altering the direction of the electrical current: a similar effect may be produced A\'ith mercury. These cases afford an additional argument to those previously mentioned of the particles of matter being affected by the forces of electricity and magnetism in a way irreconcilable with the fluid or ethereal hypothesis. The representation of transverse direction by magnetism and electricity appears to have led Coleridge to parallel it by the transverse expansion of matter, or length and breadth, though he injured the parallel by adding galvanism as depth : whether a third force exists which may bear this relation to electricity and magnetism is a question upon which we have no evidence. The ratio which the attractive magnetic force produced bears to the electric current producing it has been investigat- ed by many experimentalists and mathematicians. The data ELECTRICITY. 109 are so numerous and so variable, that it is difficult to arrive at definite results. Thus the relative size of the coil and the iron, the temper or degree of hardness of the latter, its shape, or the proportions of length to diameter, the number of coils surrounding it, the conducting power of the metal of which the coils are formed, the size of the keeper or iron in which magnetism is induced, the degree of constancy of the bat- tery, &c, comphcate the experiments. The most trustworthy general relation which has been as- certained is, that the magnetic attraction is as the square of the electric force ; a result due to the researches of Lenz and Jacobi, and also of Sir W. S. Harris. Lastly, electricity produces chemical affinity; and by its agency Ave are enabled to obtain effects of analysis or synthe- sis Avith which ordinary chemistry doe3 not furnish us. Of these effects we have examples in the brilliant discoveries, by Davy, of the alkaline metals, and in the pecuhar crystalline compounds made known by Crosse and Becquerel. V.—LIGHT. IN' entering on the subject of Light, it Avill be avcII to dc« scribe briefly, and in a manner as far as may be inde- pendent of theory, the effects to which the term polarisation has been applied. When light is reflected from the surface of water, glass, or many other media, it undergoes a change which disables it from being again similarly reflected in a direction at right angles to that at which it has been originally reflected. Light so affected is said to be polarised ; it will always be capable of being reflected in planes parallel to the plane in Avhich it has been first reflected, but incapable of being re- flected in planes at right angles to that plane. At planes having a direction intermediate between the original plane of reflection, and a plane at right angles to it, the hght will be capable of being partially reflected, and more or less so ac- cording as the direction of the second plane of reflection is more or less coincident with the original plane. Light, again, when passed through a crystal of Iceland spar, is what is termed doubly refracted, i. e. split into two divisions or beams, each having half the luminosity of the original incident hght; each of these beams is polarised in planes at right angles to each other ; and if they be intercepted by the mineral tour- maline, one of them is absorbed, so that only one polarised beam emerges. Similar effects may be produced by certain LIGHT. Ill other reflections or refractions. A ray of hght once polaris ed in a certain plane continues so affected throughout its whole subsequent course ; and at any indefinite distance from the point Avhere it originally underwent the change, the di- rection of the plane will be the same, proATided the media through which it is transmitted be air, water, or certain other transparent substances Avhich need not be enumerated. If, hoAvever, the polarised ray, instead of passing through water, be made to pass through oil of turpentine, the definite direc- tion in which it is polarised will be found to be changed ; and the change of direction will be greater according to the length of the column of interposed liquid. Instead of being an uniform plane, it will have a cur\-ilincar direction, similar to that which a strip of card would have if forced along two opposite grooArcs of a rifle-barrel. This curious effect is produced in different degrees by different media. The direction also A'aries; the rotation, as it is termed, being sometimes to the right hand and sometimes to the left, accord- ing to the peculiar molecular character of the medium through which the polarised ray is transmitted. Light is, perhaps, that mode of force the reciprocal rela- tions of Avhich Avith the others have been the least traced out. Until the discoATeries of Niepce, Daguerre, and Talbot, very little could be definitely predicated of the action of light in producing other modes of force. Certain chemical com- pounds, among which stand pre-eminent the salts of silver, have the property of suffering decomposition when exposed to light. If, for instance, recently formed chloride of silver be submitted to luminous rays, a partial decomposition en- sues ; the chlorine is separated and expelled by the action of light, and the silver is precipitated. By this decomposition the colour of the substance changes from white to blue. If now, paper be impregnated with chloride of silver, which can be done by a simple chemical process, then partially covered with an opaque substance, a leaf for example, and exposed to 112 CORRELATION OF PHYSICAL FORCES. a strong hght, the chloride will be decomposed in all those parts of the paper Avhere the hght is not intercepted, and avo shaU have, by the action of light, a Avhite image of the leaf on a purple ground. If similar paper be placed in the focus of a lens in a camera-obscura, the objects there depicted will decompose the chloride, just in the proportion in Avhich they are luminous ; and thus, as the most luminous parts of the im- age will most darken the chloride, we shall have a picture of the objects with reversed hghts and shadows. The picture thus produced would not be permanent, as subsequent expos- ure Avould darken the hght portion of the picture : to fix it, the paper must be immersed in a solution Avhich has the pro- perty of dissolving chloride of silver, but not metallic silver. Iodide of potassium wiU effect this; and the paper being Avashed and dried will then preserve a permanent image of the depicted objects. This was the first and simple process of Mr. Talbot; but it is defective as to the purposes aimed at, in many points. First, it is not sufficiently sensitive, re- quiring a strong hght and a long time to produce an image ; secondly, the hghts and shadows are reversed ; and thirdly, the coarse structure of the finest paper does not admit of the delicate traces of objects being distinctly impressed. These defects have been to a great extent remedied by a process subsequently discovered by Mr. Talbot, and which bears his name, and Avhich has led to the collodion process, and others unnecessary to be detailed here. The photographs of M. Daguerre, with Avhich all are now familiar, are produced by holding a plate of highly-polished silver over iodine. A thin film of iodide of silver is thus formed on the surface of the metal; and when these iodized plates are exposed in the camera, a chemical alteration takes place. The portions of the plate on which the hght has im- pinged part with some of the iodine, or are otherwise changed —for the theory is somewhat doubtful—soas to be capable of ready amalgamation. When, therefore, the plate is placed LIGHT. 113 over the Arapour of heated mercury, the mercuiy attaches it self to the portions affected by light, and gives them a wrhite frosted appearance; the intermediate tints are less affected, and those parts where no light has fallen, by retaining their original polish, appear dark; the iodide of silver is then washed off by hyposulphite of soda, which has the property of dissolving it, and there remains a picture in which the lights and shadows are as in nature, and the molecular uniformity of the metallic surface enables the most microscopic details to be depicted with perfect accu- racy. By using chloride of iodine, or bromide of iodine, instead of iodine, the equilibrium of chemical forces is ren- dered still more unstable, so that images may be taken in an indefinitely short period—a period practically instantaneous. It would be foreign to the object of this essay to enter upon the many beautiful details into which the science of photography has branched out, and the many valuable discoAr- cries and practical applications to which it has led. The short statement I have given above is perhaps superfluous, as, though they were neAV and surprising at the period when these Lectures were delivered, photographic processes have noAV be- come familiar, not only to the cultivator of science, but to the artist and amateur ; the important point for consideration here is that light will chemically or molecularly affect mat- ter. Not only will the particular compounds above selected as instances be changed by the action of hght; but a vast number of substances, both elementary and compound, are notably affected by this agent, even those apparently the most unalterable in character, such as metals: so numerous, in- deed, are the substances affected, that it has been supposed, not without reason, that matter of every description is altered by exposure to hght. The permanent impression stamped on the molecules of matter by light can be made to repeat itself by the same agency, but ahvays Avith decreasing force. Thus a phot*- 114 CORRELATION OF PHYSICAL FORCES. graph placed opposite a camera containing a sensitive plate whl be reproduced, but if the size of the image be equal to the picture, the second picture will be fainter than the first, and so on. Thus again, a photograph taken on a dull day cannot, by being placed in bright sunshine be made to repro- duce a second photograph of the same size and more distinct- ly marked than itself; I at least have never succeeded in such reproduction, and I am not aAvare that others have : the image loses in intensity as light itself does by each transmis- sion. The surface of the metal or paper may give a brighter image from its being exposed to a more intense light, but the photographic details are limited to the intensity of the first impression, or rather to something short of this. A question of theoretical interest arises from the consideration of these reproduced photographs. We know that the luminosity of the image at the focus of a telescope is limited by the area of the object-glass. The image of any given object cannot be intensified by throwing upon it extraneous hght; it is in- deed diminished in intensity, and wdien for certain purposes astronomers illuminate the fields of their telescopes, they are obliged to be contented with a loss of intensity in the telescopic image. Now, let us suppose that the minutest details in the image of an object seen in a given telescope, and with a given pow- er, are noted ; that then a photographic plate is placed in the focus of the same telescope so as to obtain a permanent im- pression of the image which has been viewed by the eye-glass. Could the observer, by throwing a beam of condensed light upon the photograph, enable himself to bring out fresh details ? or in other words, could he use with advantage a higher pow- er apphed to the illuminated photograph ? It is, perhaps, hardly safe to answer a priori this question ; but the experiment of reproducing photographs would seem to show that more than the initial hght cannot be got, and that we cannot expect to increase telescopic power by photography, LIGnT. 115 though we may render observations more convenient; may by its means fix images seen on rare and favourable occasions, and may preserve permanent and infallible records of the past state of astronomical objects. The effect of light on chemical compounds affords us a striking instance of the extent to which a force, ever active, may be ignored through successive ages of philosophy. If Ave suppose the walls of a large room covered with photo- graphic apparatus, the small amount of light reflected from the face of a person situated in its centre would simulta- neously imprint his portrait on a multitude of recipient sur- faces. Were the cameras absent, but the room coated with photographic paper, a change would equally take place in every portion of it, though not a reproduction of form and figure. As other substances not commonly called photo- graphic are knoAvn to be affected by hght, the list of Avhich might be indefinitely extended, it becomes a curious object of contemplation to consider how far light is daily operating changes in ponderable matter—hoAv far a force, for a long time recognised only in its visual effects, may be constantly producing changes in the earth and atmosphere, in addition to the changes it produces in organised structures which are now beginning to be extensively studied. Thus CA'ery portion of hght may be supposed to Avrite its own history by a change more or less permanent in ponderable matter. The late Mr. George Stephenson had a favourite idea, which would now be recognised as more philosophical than it was in his day, A-iz. that the hght, which we nightly obtain from coal or other fuel, Avas a reproduction of that which had at one time been absorbed by vegetable structures from the sun. The conviction that the transient gleam leaves its per- manent impress on the world's history, also leads the mind to ponder over the many possible agencies of which we of the present day may be as ignorant as the ancients were of the chemical action of light. 116 CORRELATION OF PHYSICAL FORCES. I have used the term hght, and affected by light, in speak- ing of photographic effects; but, though the phenomena de- rived their name from light, it has been doubted by many competent investigators Avhether the phenomena of photo- graphy are not mainly dependent upon a separate agent ac- companying light, rather than upon light itself. It is, indeed, difficult not to believe that a picture, taken in the focus of a camera-obscura, and which represents to the eye all the gra- dations of light and shade shown by the original luminous image, is not an effect of light; certain it is, hoAvever, that the different coloured rays exercise different actions upon va- rious chemical compounds, and that the effects on many, per- haps on most of them, are not proportionate in intensity to the effects upon the visual organs. Those effects, however, appear to be more of degree than of specific difference; and, without pronouncing myself positively upon the question, hitherto so little examined, I think it will be safer to regard the action on photographic compounds as resulting from a function of light. So viewing it, we get hght as an initia- ting force, capable of producing, mediately or immediately, the other modes of force. Thus, it immediately produces chemical action ; and haAdng this, we at once acquire a means of producing the others. At my Lectures in 1843, I shoAved an experiment by which the production of all the other modes of force by light is exhibited : I may here shortly describe it. A prepared daguerreotype plate is enclosed in a box filled with Avater, having a glass front with a shutter over it. Be- tAveen this glass and the plate is a gridiron of silver wire; the plate is connected with one extremity of a galvanometer coil, and the gridiron of Avire with one extremity of a Bre- guet's helix—an elegant instrument, formed by a coil of tAvo metals, the unequal expansion of Avhich indicates slight changes in temperature—the other extremities of the galva- nometer and helix are connected by a wire, and the needles brought to zero. As soon as a beam of either daylight or LIGHT. 117 the oxyhydrogen hght is, by raising the shutter, permitted to impinge upon the plate, the needles are deflected. Thus, hght being the initiating force, we get chemical action on the plate, electricity circulating through the wires, magnetism in the coil, heat in the helix, and motion in the needles. K two plates of platinum be placed in acidulated water, and connected with a delicate galvanometer, the needle of this is always deflected, a result due to films of gas or other matter on the surface of the platinum, which no cleaning cau remoA-c. If, after the needle has returned to zero, Avhich Avill not be the case for some hours or even days, one of the plat- inum surfaces be exposed to hght, a fresh deflection of the needle takes place, due, as far as I have been able to resoh-e it, to an augmentation of the chemical action which had occa- sioned the original deflection, for the deviation is in the same direction. If, instead of white light, coloured hght be per- mitted to impinge on the plate, the deviation is greater Avith blue than with red or yellow hght, shoAving, in addition to other tests, that the effect is not due to the heat of the sun's rays, as the calorific effects of hght are greater with red than AArith blue light, while the chemical effects are the inverse. There are other apparently more direct agencies of light in producing electricity and magnetism, such as those ob- served by Morichini and others, as well as its effects upon crystalhzation ; but these results have hitherto been of so in- definite a character, that they can only be regarded as pre- senting fields for experiment, and not as proving the relations of light to the other forces. Light Avould seem directly to produce heat in the phenom- ena of what is termed absorption of light: in these we find that heat is developed in some proportion to the disappear- ance of light. To take the old experiment of placing a se- ries of different coloured pieces of cloth upon snow exposed to sunshine, the black cloth absorbing the most hght, and de- veloping the most heat, sinks more deeply in the snow than 118 CORRELATION OF PHYSICAL FORCES. any others; the other colours or shades of colour sink the more deeply in proportion as they absorb or cause to disap- pear the more hght, until we come to the Avhite cloth, Avhich remains upon the surface. The heating powers of different colours are, however, not by any means in exact proportion to the intensity of their light as affecting the visual organs. Thus red light, Avhen produced by refraction from a prism of glass, produces greater heating effect than yelloAv light in the phenomena of absorption, as has been observed by Sir W. Herschel. The red rays appear, however, to produce a dy- namic effect greater than any of the others ; thus they pene- trate water to a greater depth than the other colours; but, according to Dr. Seebeck, we get a further anomaly, viz. that when hght is refracted by a prism of water the yellow rays produce the greater heating effect. The subject, there- fore, requires much more experiment before Ave can ascertain the rationale of the action of the forces of light and heat in this class of phenomena. In a former edition of this Essay, I suggested the folioav- ing experiment on this subject:—Let a beam of light be passed through tA\ro plates of tourmaline, or similar sub- stance, and the temperature of the second plate, or that on which the light last impinges, be examined by a delicate ther- moscope, first Avhen it is in a position to transmit the polar- ised beam coming from the first plate, and secondly when it has been turned round through an arc of 90s, and the polar- ised beam is absorbed. I expected that, if the experiment Avere carefully performed, the temperature of the second plate would be more raised in the second case than in the first, and that it might afford interesting results when tried with light of different colours. I met with difficulties in procuring a suitable apparatus, and was endeavouring to o\'ercome them when I found that Knoblauch had, to some extent, realised this result. He finds that, when a solar beam, polarised in a certain plane, is transmitted perpendicularly to the axis of n LIGHT. 119 crystal of brown quartz or tourmaline, the heat is transmit- ted in a smaller proportion than when the beam passes alon" the direction of the axis of the crystal. It is generally—as far as I am aware, universally—true that, while light continues as light, even though reflected or transmitted by different media, httle or no heat is developed: and, as far as we can judge, it would appear that, if a me- dium were perfectly transparent, or if a surface perfectly re- flected hght, not the slightest heating effect would take place j but, wherever light is absorbed, then heat takes its place, af- fording us apparently an instance of the conversion of hght into heat, and of the fact that the force of hght is not, in fact, absorbed or annihilated, but merely changed in character, becoming in this instance converted into heat by impinging on solid matter, as in the instance mentioned in treating of heat, this force Avas shown to be converted into hght by im- pinging on sohd matter. As, liOA\Tever, I have before ob- served, this correlation of light and heat is not so distinct, as Avith the other affections of matter. One experiment, indeed, of Melloni, already mentioned, AArould seem to show that hght may exist in a condition in Avhich it does not produce heat, Avhich our instruments are able to detect; but some doubt has recently been thrown on the accuracy of this ex- periment ; probably the substances themselves through Avhich the light is transmitted would be found to have been heated. The recipient body, or that upon Avhich light -"^rpinges, seems to exercise as important an influence on o\^ percep- tions of hght as the cmittent body, or that from Avhich the light first proceeds. The recent experiments o. Sir John Herschel and Mr. Stokes show that radiant impuLes, which, falling on certain bodies, give no effect of light, become lu- minous ay hen falling on other bodie3. Thus, let ordinary solar hght be refracted by i- prism (the best material for Avhich is quartz), and the spectrum receiA-cd on a sheet of paper, or of white porcelain; looVirif jn the 120 . CORRELATION OF PHYSICAL FORCES. paper, the eye detects no light beyond the extreme violet rays. If, therefore, an opaque body be interposed so as just to cut off the whole visible spectrum, the paper would be dark or invisible, with the exception of some slight iUumina- tion from light reflected by the air and surrounding bodies. Substitute for that portion of the paper Aviiich was beyond tbe \dsible spectrum a piece of glass tinged by the oxide of uranium, and the glass is perfectly \nsible ; so Avith a bottle of sulphate of quinine, or of the juice of horse-chestnuts, or even paper soaked in these latter solutions. Other substances exhibit this effect in different degrees; and among the sub stances which have hitherto been considered perfectly analo- gous as to their appearance when illuminated, notable differ- ences are discovered. Thus it appears that emanations which give no impression of hght to the eye, when imping- ing on certain bodies, become luminous when impinging on others. We might imagine a room so constructed that such emanations alone are permitted to enter it, which would be dark or light according to the substance with which the walls Avere coated, though in fuU daylight the respective coatings of the walls would appear equally white ; or, without alter- ing the coating of the waUs, the room exposed to one class of rays, might be rendered dark by windoAvs which would be transparent to another class. If, instead of solar light, the electrical hght be employed for similar experiments, an equally striking effect can actually be produced. A design, draAAm on Avhite paper with a solu- tion of sulphate of quinine and tartaric acid, is invisible by ordinary hght, but appears with beautiful distinctness when illuminated by the electric hght. Thus, in pronouncing upon a luminous effect, regard must be had to the recipient as Avell as to the emittent body. That which is, or becomes, light when it falls upon one body is not hght when it falls upon another. Probably the retinas of the eyes of different per- sons differ to some extent in a similar manner ; and the same LIGHT. 121 substance, illuminated by the same spectrum, may present different appearances to different persons, the spectrum ap- pearing more elongated to the one than to the other, so that what is light to the one is darkness to the other. A depend- ence on the recipient body may also, to a great extent, be predicated of heat. Let two vessels of Avater, the contents of the one clear and transparent, of the other tinged by some colouring matter, be suspended in a summer's sun ; in a very short time a notable difference of temperature will be ob- served, the coloured having become much hotter than the clear liquid. If the first vessel be placed at a considerable distance from the surface of the earth, and the second near the surface, the difference is still more considerable. Carry- ing on this experiment, and suspending the first over the top of a high mountain, and the second in a valley, we may ob tain so great a difference of temperature, that animals whose organization is suited for the one temperature could not hve in the other, and yet both arc exposed to the same luminous rays at the same time, and substantially at the same distance from the emittent body—the substance nearer the sun is in fact colder than the more remote. So, Avith regard to the medium transmitting the influence : a green-house may have its temperature considerably varied by changing the glas3 of which its roof is made. These effects have an important bearing on certain cos- mical questions which have lately been much discussed, and should induce the greatest caution in forming opinions on such subjects as light and heat on the sun's surface, the tem- perature of the planets, &c. This may depend as much upon them physical constitution as upon their distance from the sun. Indeed, the planet Mars gives us a highly probable ar- gument for this; for, notwithstanding that it is half as far again from the sun as the earth is, the increase of the white tracts at its poles during its winter, and their diminution dur- ing its summer, show that the temperature of the surface of 6 122 CORRELATION OF PHYSICAL FORCES. this planet oscillates about that of the freezing point of water, as do the analogous zones of our planet. It is true, m this we assume that the substance thus changing its state is water, but, considering the many close analogies of this planet Avith the earth, and the identity in appearance of these very effects with what takes place on the earth, it seems a highly proba- ble assumption. So it by no means necessarily follows, that because Venus is nearer to the sun than the earth, that planet is hotter than our globe. The force emitted by the sun may take a differ- ent character at the surface of each different planet, and require different organisms or senses for its appreciation. Myriads of organised beings may exist imperceptible to our vision, even if we were among them ; and we might be also imperceptible to them! However vain it may be, in the present state of science, to speculate upon such existences, it is equally vain to assume identity or close approximations to our own forms in those beings Avhich may people other worlds. From analogical reasoning, or from final causation, if that be admitted, we may feel convinced that the gorgeous globes of the universe are not unpeopled deserts ; but whether the denizens of other worlds are more or less powerful, more or less intelligent, whether they have attributes of a higher or loAver class than ourselves, is at present an utterly hopeless guessing. Specific gravity and intelligence have no necessary con- nexion. On our OAvn planet five senses, and a mean density equal to that of water, are not invariably associated with in- tellectual or moral greatness, and the many arguments Avliich have been used to prove that suns and planets other than the earth are uninhabited, or not inhabited by intellectual beings, might, mutatis mutandis, equally be used by the denizens cf a sun or planet to prove that this world was uninhabited. Men are too apt, because they are men, because their existence is the one thing of all importance to themselves, to LIGHT. 123 frame schemes of the universe as though it was formed for man alone : painted by an artist of the sun, a man might not represent so prominent an object of creation as he does Avhen represented by his oAvn pencil. Light Avas regarded, by AArhat was termed the corpuscular theory, as being in itself matter or a specific fluid emanating from luminous bodies, and producing the effects of sensation by impinging on the retina. This theory gave way to theun- dulatory one, Avhich is generaUy adopted in the present day, and which regards light as resulting from the undulation of a specific fluid to which the name of ether has been given, which hypothetic fluid is supposed to pervade the universe, and to penetrate the pores of all bodies. In a Lecture delivered in January 1842, Avhen I first pubhely advanced the views advocated in this Essay, I stated that it appeared to me more consistent with knoAvn facts to regard light as resulting from a vibration or motion of the molecules of matter itself, rather than from a specific ether pervading it; jnst as sound is propagated by the vibrations of wood, or as waves are by water. I am not here speaking of the character of the vibrations of hght, sound, or Avater, Avhich are doubtless very different from each other, but am only comparing them so far as they illustrate the propagation of force by motion in the matter itself. I was not aware, at the time that I first adopted the above view, and brought it forward in my Lectures, that tho celebrated Leonard Euler had pubhshed a someAvhat similar theory; and, though I suggested it Avithout knowing that it had been previously advanced, I should have hesitated in reproducing it had I not found that it Avas sanctioned by so eminent a mathematician as Euler, who cannot be supposed to have overlooked any irresistible argument against it—the more so in a matter so much controverted and discussed as tho undulatory theory of light was in his time. Although this theory has been considered defective by a 124 CORRELATION OF PHYSICAL FORCE?. philosopher of high repute, I cannot see the force of tho arguments by which it has been assailed ; and therefore, for the present, though with diffidence, I still adhere to it. The fact itself of the correlation of the different modes of force is to my rnind a very cogent argument in favour of their being affections of the same matter ; and though electricity, magnet- ism, and heat might be viewed as produced by undulations of the same ether as that by means of which hght is supposed to be produced, yet this hypothesis offers greater difficulties with regard to the other affections than with regard to light: many of these difficulties I have already alluded to when treating of electricity; thus conduction and non-conduction are not ex- plained by it; the transmission of electricity through long wires in preference to the air which surrounds them, and which must be at least equally pervaded by the ether, i3 irreconcilable with such an hypothesis. The phenomena ex- hibited by these forces afford, as I think, equally strong evi- dence with those of light, of ordinary matter acting from par- ticle to particle, and having no action at a distance. I have already instanced the experiments of Faraday on electrical induction, showing it to be an action of contiguous particles, which are strongly in favour of this view, and many experi- ments which I have made on the voltaio arc, some of which I have mentioned in this Essay, are, to my mind, confirma- tory of it. If it be admitted that one of the so-called imponderables is a mode of motion, then the fact of its being able to produce the others, and be produced by them, renders it highly diffi- cult to conceive some as molecular motions and others as fluids or undulations of an ether. To the main objection of Dr. Young, that all bodies would have the properties of solai phosphorus if light consisted in the undulations of ordinary matter, it may be answered that so many bodies have this property, and with so great a variety in its duration, that non constat all may not have it, though for a time so short LIGHT. 125 that the eye cannot detect its duration. M. E. Becquerel has made many experiments which support this view; the fact of the phosphorescence by insolation of a large number of bodies, is in itself evidence of the matter of which they are composed being throAvn into a state of undulation, or at all CA'cnts molecularly affected by the impact of light, and is therefore an argument in support of the view to Avhich objec- tion is taken. Dr. Young admits that the phenomena of solar phosphorus appear to resemble greatly the sympathetic sound3 of musical instruments, Avhich are agitated by other sounds conveyed to them through the air, and I am not aAvaro that he gives any explanation of these effects on the ethereal hypothesis. Some curious experiments of M. Niepce de St. Victor seem also to present an analogy in luminous phenomena to sympathetic sounds. An engraving Avhich has been kept for some days in the dark is half covered by an opaque screen, and then exposed to the sun; it is then removed from the light, the screen taken away, and the engraving placed oppo- site, and at a short distance from, photographic paper: an inverted image of that portion of the engraving which has been exposed to the sun is produced on the photographic paper, while the part which had been covered by the screen is not reproduced. If the engraving, after exposure, is alloAved to remain in contact AA~ith Avhite paper for some hours, and the Avhite paper is then placed upon photographic paper, a faint image of the exposed portion of the engraving is repro- duced. Similar results are produced by mottled marble ex- posed to the sun ; an invisible tracing on paper by a fluores- cent body, sulphate of quinine, is, after insolation, reproduced on the photographic paper. Insolated paper retains the poAver of producing an impression for a very long period, if it is kept in an opaque tube hermetically closed. It is light to observe that these effects are supposed by many to be due to chemical emanations proceeding from the 12G CORRELATION OF PHYSICAL FORCES. substances exposed to the sun, and which are beheved to have undergone some chemical change by this exposure. It is desirable to aAA'ait further experiment before forming a decid- ed opinion. The analogies in the progression of sound and light are very numerous: each proceed in straight hnes, until inter- rupted ; each is reflected in the same manner, the angles of incidence and reflexion being equal; each is alternately nulli- fied and doubled in intensity by interference ; each is capable of refraction when passing from media of different density: this last effect of sound, long ago theoretically determined, has been experimentally proved by Mr. Sondhauss, who con- structed a lens of films of collodion, which, AAThen filled with carbonic acid, enabled him to hear the ticking of a watch placed in one focus of the lens, the ear of the experimenter being in the opposite focus. The ticking was not heard when the watch was moved aside from the focal point, though it remained at an equal distance from the ear. An experi- ment of M. Dove seems, indeed, to show an effect of polari- sation of sound. The phenomena presented by heat, viewed according to the dynamic theory, cannot be explained by the motion of an imponderable ether, but involve the molecular actions of ordinary ponderable matter. The doctrine of propagation by undulations of ordinary matter is A*ery generaUy admitted by those who support the dynamical theory of heat; but the analogies of the phenomena presented by heat and hght are so close, that I cannot see how a theory apphed to the one agent should not be applicable to the other. When heat is transmitted, reflected, refracted, or polarised, can we vieAV that as an affection of ordinary matter, and Avhen the same effects take place with hght, view the phenomena as pro- duced by an imponderable ether, and by that alone ? An objection that immediately occurs to the mind in reference to the ethereal hypothesis of hght is, that the most LIGHT. 127 porous bodies arc opaque ; cork, charcoal, pumice stone, dried and moist wood, &c, all A'ery porous and very light, are all opaque. This objection is not so superficial as it might seem at first sight. The theory which assumes that hght is an undulation of an ethereal medium perA'ading gross matter, assumes the distances between the molecules or atoms of matter to be A-ery great. Matter has been hkened by Demo- critus, and by many modern philosophers, to the starry firma- ment, in which, though the individual monads are at immense distances from each other, yet they have in the aggregate a character of unity, and are firmly held by attraction in their respective positions and at definite distances. Xow, if matter be built up of separate molecules, then, as far as our knowl- edge extends, the lightest bodies would be those in which the molecules are at the greatest distances, and those in which any undulation of a pervading medium would be the least interfered Avith by the separated particles—such bodies should consequently be the most transparent. If, again, the analog}' of the starry firmament held good, in this case an undulation or wave proportioned to the indivi- dual monads would be broken up by the number of them, and the very appearance of continuity which results, as in the milky way, from each point of A'ision being occupied by one of the monads, wrould sIioav that at some portion of its pro- gress the wave is interrupted by one of them, so that the whole may be ATiewed in some respect as a sheet of ordinary matter interposed in the ethereal expanse. Even then, if it be admitted that a highly elastic medium pervades the interspaces, the separate masses as a whole must exercise an important influence on the progress of the wave. Sound or vibrations of air meeting Avith a screen, or, as it Avere, sponge of diffused particles, would be broken up and dis| eised by them ; but if they be sufficiently continuous to take up the vibration and propagate it themselves, the sound continues comparatively unimpaired. 128 CORRELATION OF PHYSICAL FORCES. With regard, however, to liquid and gaseous bodies, there are very great difficulties in viewing them as consisting of separate and distant moleculer. If, for instance, we assume with Young that the particles in Avater are at least as distant from each other comparatively as 100 men Avould be if dis- persed at equal distances over the surface of England, the dis- tance of these particles, Avhen the water is expanded into steam, would be increased more than forty times, so that the 100 men would be reduced to two, and by further increasing the temperature this distance may be indefinitely increased ; adding to the effects of temperature rarefaction by the air- pump, Ave may again increase the distance, so that, if Ave as- sume any original distance, we ought, by expansion, to in- crease it to a point at Avhich the distance between molecule and molecule should become measurable. But no extent of rarefaction, Avhether by heat or the air-pump, or both, makes the slightest change in the apparent continuity of matter; and gases, I find, retain their peculiar character, as far a3 a judgment of it can be formed from its effect on the electric spark, throughout any extent of rarefaction Avliich can exper- imentally be applied to them: thus the electric spark in prot- oxide of nitrogen, hoAveArer attenuated, presents a crimson tint, that in carbonic oxide a greenish tint. Without, however, entering on the metaphysical enquiry as to the constitution of matter (or Avhether the atomic phil- osophers or the followers of Boscovich are right), a question which probably human apphances Avill never answer: and even admitting that an ethereal medium, not absolutely im- ponderable as asserted by many, but of extreme tenuity, per- vades matter, still ordinary or non-ethereal matter itself must exercise a most important action upon the transmission of light; and Dr. Young, avIio opposed the tlicory of Euler, that light was transmitted by undulations of gross matter itself, just as sound is, Avas afterwards obliged to call to his assis- tance the vibrations of the ponderable matter of the refractr LIGHT. 129 ing media, to explain why rays of all colours were not equal- ly refracted, and other difficulties. One of his arguments in support of the existence of a permeating ether was, " that a medium resembling in many properties that which has been denominated Ether does exist, is undeniably proved by the phenomena of electricity." This seems to me, if I may ven- ture to say so of anything proceeding from so eminent a man, scarcely logical: it is supporting one hypothesis by another, and considering that to be proved which its most strenuous advocates admit to be surrounded by very many difficulties. If it be said that there is not sufficient elasticity in ordi- nary matter for the transmission of undulations AA-ith such ve- locity as light is known to travel, this may be so if the vibra- tions be supposed exactly analogous to those of sound ; but that molecular motion can traA*el with equal and even greater velocity than light, is shown by the rapidity with which elec- tricity traverses a metal Avire where each particle of metal is undoubtedly affected. It has, moreover, been shown by the experiments of Mr. Latimer Clarke upon a length of wire of 7G0 miles, that whatever be the intensity of electrical cur- rents, they are propagated Avith the same velocity provided the effects of lateral induction be the same—a striking anal- ogy Avith one of the effects observed in the propagation of light and sound. The effects observed by MM. Fizeau and Foucault, of the sloAver progression of hght in proportion as the transmitting medium is more dense, seem to me in favour of the view here advocated; as a greater degree of heat Avould be produced by light in proportion to the density of the medium, force would be thus carried off, and the molecular system disturbed so that the progress of the motion should be more slow ; but so many considerations enter into this question, and the phenomena are so extremely complex, that it Avould be rash to hazard any positive opinion. Dr. Young ultimately came to the conclusion that it was simplest to consider the ethereal medium, together with the 130 CORRELATION OF PHYSICAL FORCES. material atoms of the substance, as constituting together a compound medium denser than pure ether, but not more clas- tic. Ether might thus be viewed as performing the functions which oil does with tracing paper, giving continuity to the particles of gross matter, and in the interplanetary spaces forming itself the medium Avhich transmits the undulations. Since the period when Huyghens, Euler, and Young, the fathers of the undulatory theory, applied their great minds to this subject, a mass of experimental data has accumulated, all tending to estabhsh the propositions, that whenever matter transmitting or reflecting hght undergoes a structural change, the hght itself is affected, and that there is a connection or paraUelism between the change in the matter and the change in the affection of hght, and conversely that hght Avill modify or change the structure of matter and impress its molecules Avith new characteristics. Transparency, opacity, refraction, reflection, and colour were phenomena known to the ancients, but sufficient attention does not appear to haATe been paid by them to the molecular states of the bodies producing these effects ; thus the trans- parency or opacity of a body appears to depend entirely upon its molecular arrangement. K strias occur in a lens or glass through which objects are viewed, the objects are distorted: increase the number of these striae, the distortion is so in- creased that the objects become invisible, and the glass ceases to be transparent, though remaining translucent; but alter completely the molecular structure, as by slow solidification. and it becomes opaque. Take, again, an example of a liquid and a gas : a solution of soap is transparent, air is transpar- ent, but agitate them together so as to form a froth or lather, and this, though consisting of two transparent bodies, is opaque ; and the reflection of light from the surface of these bodies, when so intermixed, is strikingly different from its re- flection before mixture, in the one case giving to the eye a mere general effect of whiteness, in the other the images of objects in their proper shapes and colours. LIGHT. 131 To take a more refined instance: nitrogen is perfectly colourless, oxygen is perfectly colourless, but chemically uni- ted in certain proportions they form nitrous acid, a gas which has a deep orange brown colour. I know not how the col- our of this gas, or of such gases as chlorine or vapour of iodine, can be accounted for by the ethereal hypothesis, with- out calling in aid molecular affections of the matter of these gases. Colour in many instances depends upon the thickness of the plate or film of transparent matter upon Avhich light is in- cident ; as in all those cases which are termed the colours of thin plates, of Avhich the soap bubble affords a beautiful in- stance. When Ave arrive at the more recent discoveries of double refraction and polarisation, the effects of light are found to trace out as it were the structure of the matter affected, and the crystalline form of a body can be determined by the effects which a minute portion of it exercises on a ray of light. Let a piece of good glass be placed in what is called a polariscope, or instrument in which hght that has undergone polarisation is transmitted through the substance to be exam- ined, and the emergent hght is afterwards submitted to anoth- er substance capable of polarising hght, or, as it is termed, an analyser ; no change in effect will be observed. Remove the glass, heat it and suddenly or quickly cool it as to render it unannealed, in which state its molecules are in a state of tension or strain, and the glass highly brittle, on replacing it in the polariscope, a beautiful series of colours is perceptible. Instead of subjecting the glass to heat and sudden cooling, let it be bent or strained by mechanical pressure, and the col- ours Avill be equally visible, modified, according to the direc- tion of the flexure, and indicating by their course the curves where the molecular state has been changed by pressure. So if tough glue be elongated and allowed to cool in a stretched 132 CORRELATION OF PHYSICAL FOECUS. state, it doubly refracts hght, and the colours are shown as in the instance of glass. Submit a series of crystals to the same examination, and different figures will be formed by different crystals, bearing a constant and definite relation to the structure of the partic- ular crystal examined, and to the direction in Avhich, A\rith reference to crystalline form, the ray crosses the crystal. In the crystalhsed salts of paratartaric acid, M. Pasteur noticed two sets of crystals which were hemihedral in oppo- site directions, i. e. the crystals of one set were to those of the other as to their oavu image reflected in a mirror; or making a separate solution of each of these classes of crys- tals, he found that the solution of the one class rotated the plane of polarisation to the right, Avhile that of the other class rotated to the left, and that a mixture in proper propor- tions of the two solutions produced no deviation in the plane of polarisation. Yet all these three solutions are Avhat is term- ed isomeric, that is, have as far as can be discovered the same chemical constitution. In the above, and in innumerable other cases, it is seen that an alteration in the structure of a transparent substance alters the character and effects of the transmitted light. The phenomena of photography prove that hght alters the struc- ture of matter submitted to it; with regard even to vision it- self, the persistence of images on the retina of the eye Avould seem to show that its structure Avas changed by the impact of light, the luminous impressions being as it Avere branded on the retina, and the memory of the vision being the scar of such brand. The science of photography has reference main- ly to solid substances, yet there are many instances of liquid and gaseous bodies being changed by the action of light: thus hydrocyanic acid, a liquid, undergoes a chemical change and deposits a solid carbonaceous compound by the action of light. Chlorine and hydrogen gases, when mixed and pre- served in darkness, do not unite, but Avhen exposed to light rapidly combine, forming hydrochloric acid. LIGHT. 133 The above facts—and many others might have been given —go far to connect light with motion of ordinary matter, and to show that many of the evidences Avhich our senses receive of the existence of light result from changes in matter itself. When the matter is in the solid state, these changes are more or less permanent; when in the liquid or gaseous state, they are temporary in the greater number of instances, unless there be some chemical change effected, which is, as it were, seized upon during its occurrence, and a resulting compound formed, which is more stable than the original compound or mix- ture. I might AVeary my reader Avith examples, showing that, in every case Avhich AAre can trace out, the effects of light are changed by any and every change of structure, and that light has a definite connection with the structure of the bodies affected by it. I cannot but think that it is a strong assump- tion to regard ether, a purely hypothetical creation, as chang- ing its elasticity for each change of structure, and to regard it as penetrating the pores of bodies of whose porosity Ave have in many case's no proof; the Avhich pores must, more- over, have a definite and peculiar communication, also assumed for the purpose of the theory. Ether is a most convenient medium for hypothesis : thus, if to account for a given phenomenon the hypothesis requires that the ether be more elastic, it is said to be more elastic ; if more dense, it is said to be more dense ; if it be required by hypothesis to be less elastic, it is pronounced to be less elastic ; and so on. The advocates of the ethereal hypothesis certainly have this advantage, that the ether, being hypothetical, can have its characters modified or changed without any possibihty of disproof either of its existence or modifications. It may be that the refined mathematical labours on light, as on electricity, have given an undue and adventitious strength to the hypotheses on Avhich they are based. 134 . CORRELATION OF PHYSICAL I-ORCI P. An objection to which the view I have been advocating ia open, and a formidable one, is, the necessity involved in it of an universal plenum ; for if hght, heat, electricity, &c, be affec- tions of ordinary matter, then matter must be supposed to be everywhere where these phenomena are apparent, and con- sequently there can be no vacuum. These forces are transmitted through what are called vacua, or through the interplanetary spaces, where matter, if it exist, must be in a highly attenuated state. It may be safely stated that hitherto all attempts at pro- curing a perfect ATacuum have failed. The ordinary air- pump gives us only highly rarefied air ; and, by the principle of construction, even of the best, the operation depends upon the indefinite expansion of the volume of air in the receiver; even in the vacuum which is formed in this, so great is the tendency of matter to fill up space, that I have observed dis- tilled water contained in a vessel within the exhausted receiv- er of a good air-pump has a taste of tallow, derived from the grease, or an essential oil contained in it, which is used to form an air-tight junction between the edges of the receiver and the pump-plate. The Torricellian vacuum, or that of the ordinary baro- meter, is filled with the vapour of mercury ; but it might be worth the trouble to ascertain what would be the effect of a good Torricellian vacuum, when the mercury in the tube is frozen, which might, Avithout much difficulty, be now effected by the use of solid carbonic acid and ether ; the only proba- ble difficulty would be the different rates of contraction of mercury and glass, at such a degree of cold, and more par- ticularly the contraction of mercury at the period of its solidification. Davy, however, endeavoured to form a vacuum, in a somewhat similar manner, over fused tin, with but partial success; he also made many other attempts to obtain a perfect vacuum ; his main object being to ascertain tvhat Avould be the effect of electricity across empty space : LIGHT 135 he admits that he could not succeed in procuring a vacuum, but found electricity much less readily conducted or trans- mitted by the best vacuum he could procure than by the ordi- nary Boylean vacuum. Morgan found no conduction by a good Torricellian vac- uum ; and, although Davy does not seem to place much reliance on Morgan's experiments, there AAras one point in Avhich they were less liable to error than those of Davy. Morgan, whose experiments seem to have been carefully conducted, operated with hermetically-sealed glass tubes and by induced electricity, AAdiile Davy scaled a platinum wire into the extremity of the tube in Avhich he sought to produce a vacuum. I have found in very numerous experiments which I made to exclude air from Avater, that platinum Avires, most carefuUy sealed into glass, alloAV liquids to pass betAveen them and the glass; and this gives every reason to believe that gases may equally pass through ; I have observed such effect in the gas battery Avhen it has been in action for a long period. Davy supposed that the particles of bodies maybe detached, and so produce elec- trical effects in a vacumm ; and such effects Avould more read- ily take place in his experiments, Avhere a Avire projected into the exhausted space, than in Morgan's, where the in- duced electricity was diffused over the surface of the glass. M. Masson found that the barometric vacuum does not conduct a current of electricity, or even a discharge, unless the tension is considerable and sufficient to detach particles from the electrodes; and by adopting a plan of Dr. An- drews, viz. absorbing carbonic acid by potash, M. Gassiot has recently succeeded in forming vacua across Avhich the powerful discharge from the Rhumkorf coil will not pass. The odour which many metals, such as iron, tin, and einc emit, and the so-caUed thermographic radiations, we can hardly explain upon any other theory than the evapora- tion of an infinitesimally small portion of the metal itself. 136 correlation of physical forces. So universal is the tendency of matter to diffuse itself into space, that it gave rise to the old saying that nature abhors a vacuum ; an aphorism which, though cavilled at and ridiculed by the self-sufficiency of some modern philosophers, contains in a terse, though somewhat metaphorical, form of expression a comprehensive truth, and evinces a large extent of observation in those who, Avith few of the advantages which we possess, first generalised by this sentence the facts of Avhich they had become cognisant. It has been argued that, if matter were capable of infinite divisibility, the earth's atmosphere would haA*e no hmit, and that consequently portions of it would exist at points of space where the attraction of the sun and planets would be greater than that of the earth, and Avhence it would fly off to those bodies and form atmospheres around them. This Avas sup- posed to be negatived by the argument of the well-known paper of Dr. Wollaston ; in Avhich, from the absence of nota- ble refraction near the margin of the sun and of the planet Jupiter, he considered himself entitled to conclude that the expansion of the earth's atmosphere had a definite hmit, and was balanced at a certain point by gravitation : this deduc- tion has been shown to be inconclusive by Dr. Whewell, and has also been impugned upon others grounds by Dr. Wilson. There is a point not ad\~erted to in these papers, and which Wollaston does not seem to have considered, viz. that there is no evidence that the apparent discs of the sun and of Jupi- ter show us their real discs or bodies. Sir. W. Herschel regards the margin of the visible discs as that of clouds or a pccuhar state of atmosphere, and the rapidly changing char- acter of the apparent surfaces render some such conclusion necessary. If this be so, refraction of an occulted star could not be detected—at all events, in the denser portion of the atmosphere. Sir W. Herschel's observations go to prove that the sun and Jupiter have dense atmospheres, while Wollaston's LIGHT. 137 were believed to prove that they have no appreciable atmoa pheren. If it be admitted, or considered proved, that the sun and planets ha\-e atmospheres—and little doubt now exists on this point—then the grounds upon which WoUaston founded his arguments are untenable ; and there appears no reason why the atmosphere of the different planets should not be, with reference to each other, in a state of equihbrium. Ether, or the highly-attenuated matter existing in the interplanetary spaces, being an expansion of some or all of these atmos- pheres, or of the more Aolatile portions of them, would thus furnish matter for the transmission of the modes of motion which avc call light, heat, &c.; and possibly minute portions of these atmospheres may, by gradual changes, pass from planet to planet, forming a hnk of material communication between the distant monads of the universe. The vieAV given above Avould approximate the theory of the transmission of light by the undulations of ordinary mat- ter to the other two theories, which equally suppose the non- existence of a vacuum; for, according to the emissive of corpuscular theory, the vacuum is filled by the matter itself, of light, heat, &c.; according to the ethereal, it is filled by the all-penetrating ether. Of the existence of matter in the interplanetary spaces we have some evidence in the diminish- ing periods of comets ; and where, from its highly attenuated state, the character of the medium by Avhich the forces are conveyed cannot be tested, the term ether is a most appropri- ate generic name for such medium. NcAvton has some curious passages on the subject matter of hght. Iu the ' Queries to the Optics ' he says :— ' Are not gross bodies and light convertible into one another, and may not bodies receive much of their activity from the particles of hght which enter their composition? * * * The changing of bodies into hght and light into bodies is very conformable to the course of nature, which 138 correlation of physical forces. seems delighted with transmutations. Water, which is a very fluid, tasteless salt, she changes by heat into vapour, which is a sort of air, and by cold into ice, which is a hard, pellucid, brittle, fusible stone, and this s^one returns into water by heat, and vapour returns into water by cold. * * And, among such various and strange transmutations, Avhy may not nature change bodies into light, and hght into bodies ?' NeAvton has here seemingly in his mind the emissive theory of light; but the passages might be apphed to either theory; the analogy he saAv in the change of state of matter, as in ice, water, and vapour, with the hypothetic change into light, is very striking, and would seem to show that he regard- ed the change or transmutation of which he speaks as one analogous to the knoAvn changes of state, or consistence, in ordinary matter. The difference between the view which 1 am advocating and that of the ethereal theory as generaUy enunciated is, that the matter which in the interplanetary spaces serves as the means of transmitting by its undulations light and heat, I should regard as possessing the quahties of ordinary, or as it has sometimes been caUed gross, matter, and particularly Aveight; though, from its extreme rarefaction, it would mani- fest these properties in an indefinitely smaU degree ; whilst, on the surface of the earth, that matter attains a density cognisa- ble by our means of experiment, and the dense matter is itself, in great part, the conveyer of the undulations in which these agents consist. Doubtless, in very many of the forms which matter assumes it is porous, and pervaded by more volatile essences, which may differ as much in kind as matter does. In these cases a composite medium, such as that indi- cated by Dr. Young, would result; but even on such a suppo- sition, the denser matter Avould probably exercise the more important influence on the undulations. Returning to the somewhat strained hypothesis, that the particles of dense LIGHT. 139 matter in a so-caUed sohd are as distant as the stars in heaven, still a certain depth or thickness of such sohd would present at every point of space a particle or rock in the successive progress of a wave, which particles, to carry on the move* mcnt, must vibrate in unison with it. At the utmost, our assumption, on the one hand, is that Avherever light, heat, &c, exist, ordinary matter exists, though it may be so attenuated that we cannot recognise it by the tests of other forces, such as gravitation, and that to the ex- pansibility of matter no limit can be assigned. On the other hand, a specific matter without weight must be assumed, of the existence of which there is no eA'idcnce, but in the phe- nomena for the explanation of Avhich its existence is supposed. To account for the phenomena the ether is assumed, and to prove the existence of the ether the phenomena are cited. For these reasons, and others above given, I think that the assumption of the universality of ordinary matter is the least gratuitous. OySej' ti ran irayros Kevov irePVe: ouSe irepiaaov. A question has often occurred to me and possibly to oth- ers : Is the continuance of a luminous impulse in the inter- planetary spaces perpetual, or does it after a certain distance dissipate itself and become lost as light—I do not mean by mere divergence directly as the squares of the distances it travels, but does the physical impulse itself lose force as it proceeds? Upon the view I have advocated, and indeed upon any undulatory hypothesis, there must be some resist- ance to its progress ; and unless the matter or ether in the interplanetary spaces be infinitely elastic, and there be no lateral action of a ray of light, there must be some loss. That it is exceedingly minute is proved by the distance light travels. Stars whose parallax is ascertained are at such a distance from the earth that their hght, traveUing at the rate of 192,500 miles in a second, takes more than ten years to 140 CORRELATION of physical forces. reach the earth; so that we see them as they existed ten years ago. The distance of most A'isible stars is probably far greater than this, and yet their brilliance is great, and in- creases Avhen their rays are coUected by the telescope in pro- portion ceteris paribus to the area of the object-glass or spec- ulum. There is, however, an argument of a someAvhat spec- ulative character, by which light Avould seem to be lost, or transformed into some other force in the interplanetary spaces. Every increase of space-penetrating power in the tele- scope gives us a new field of visible stars. If this expansion of the stellar universe go on indefinitely and no hght be lost, then, assuming the fixed stars to be of an average equal brightness with our sun, and no light lost other than by diver- gence, the night ought to be equally luminous with the day ; for though the light from each point diminishes in intensity as the square of the distance, the number of luminous points would fiU up the whole space around us ; and if every point of space is occupied by an equally briUiant point of light, the distance of the points becomes immaterial. The loss of light intercepted by steUar bodies would make no difference in the total quantity of light, for each of these would yield from its own self-luminosity at least as much light as it intercepted. Light may, howeATer, be intercepted by opaque bodies, such as planets ; but, making every allowance for these, it is diffi- cult to understand why we get so little light at night from the stellar universe, without assuming that some light is lost in its progress through space—not lost absolutely, for that would be an annihilation of force—but converted into some other mode of motion. It may be objected that this hypothesis assumes the stel- lar uniA-erse to be illimitable : if pushed to its extreme so as to make the light of night equal that of day, provided no stellar light be lost, it does make this assumption; but even this is a far more rational assumption to make than that tho stellar universe is limited. Our experience gives no indica LIGHT. 141 tion of a limit; each improvement in telescopic power gives us new realms of stars or of nebulae, which, if not steUar clusters, arc at all events self-luminous matter ; and if we as- sume a hmit, what is it? We cannot conceive a physical boundary, for then immediately comes the question, Avhat bounds the boundary ? and to suppose the steUar universe to be bounded by infinite space or by infinite chaos, that is to say, to suppose a spot—for it would then become so—of mat- tor in definite forms, with definite forces, and probably teem- ing with definite organic beings, plunged in a universe of nothing, is to my mind at least far more unphilosophical than to suppose a boundless universe of matter existing in forms and actions analogous to those which, as far as our examina- tion goes, pervade space. But without speculating on topics in which the mind loses itself, it may not unreasonably be expected that a greater amount of light would reach us from the surrounding self-luminous spheres were not some portion lost as light, by its action on the medium which conveys the impulses. What force this becomes, or what it effects, it would be idle to speculate upon. VI.—MAGNETISM. MAGNETISM, as was proved by the important discov- ery of Faraday, avUI produce electricity, but with this pecuharity—that in itself it is static ; and, therefore, to pro- duce a dynamic force, motion must be superadded to it: it is, in fact, directive, not motive, altering the direction of other forces, but not, in strictness, initiating them. It is difficult to convey a definite notion of the force of magnetism, and of the mode in which it affects other forces. The following il- lustration may give a rude idea of magnetic polarity. Sup- pose a number of wind-vanes, say of the shape of arrows, with the spindles on which they revolve arranged in a row, but the vanes pointing in various directions : a wind blowing from the same point with an uniform velocity wiU instantly arrange these vanes in a definite direction, the arrow-heads or narrow parts pointing one way, the swaUow-taUs or broad parts another. If they be dehcately suspended on their spin- dles, a very gentle breeze avUI so arrange them, and a very gentle breeze will again deflect them ; or, if the Avind cease, and they have been originaUy subject to other forces, such as gravity from unequal suspension, they wiU return to irregu- lar positions, themselves creating a slight breeze by their re- turn. Such a state of things will represent the state of the molecules of soft iron ; electricity acting on them—not indeed in straight lines, but in a definite direction—produces a polar MAGNETISM. 143 arrangement, which they wiU lose as soon as the dynamic in- ducing force is removed. Let us now suppose the vanes, instead of turning easily, to be more stiffly fixed to the axles, so as to be turned with difficulty: it avUI require a stronger wind to move them and arrange them definitely ; but when so arranged, they wiU re- tain their position ; and should a gentle breeze spring up in another direction, it will not alter their position, but will it- self be definitely deflected. Should the conditions of force and stability be intermediate, both the breeze and the vanes will be slightly deflected; or, if there be no breeze, and the spindles be aU moved in any direction, preserving their linear relation, they AviU themselves create a breeze. Thus it is with the molecules of hard iron or steel in permanent mag- nets ; they are polarised with greater difficulty, but, when so polarised, they cannot be affected by a feeble current of elec- tricity. Again, if the magnets be moAed, they themselves originate a current of electricity; and, lastly, the magnetic polarity and the electric current may be both mutually af- fected, if the degrees of motion and stability be intermediate. The above instance will, of course, be taken only as an approximation, and not as binding me to any closer analogy than is generally expected of a mechanical illustration. It is difficult to convey by Avords a definite idea of the dual or antithetic character of force involved in the term polarity. The illustration I have employed may, I hope, somewhat aid in elucidating the manner in which magnetism acts on the other dynamic forces ; i. e., definitely directing them, but not initiating them, except while in motion. Magnets being moved in the direction of hnes, joining their poles, produce electrical currents in such neighbouring bodies as are conductors of electricity, in directions trans- verse to the line of motion; and if the direction of motion or the position of the magnetic poles be reversed, the current of electricity flows in a reverse direction. So if the magnet 144 CORRELATION OF PHYSICAL FORCES. be stationary, conducting bodies moved across any of the lines of magnetic force, i. e. hnes in the direction of which the mutual action of the poles of the magnet would place minute portions of iron, haA-e currents of electricity devel- oped in them, the direction of which is dependent upon that of the motion of the substance with reference to the magnetic poles. Thus, as bodies affected by an electrical current are definitely moved by a magnet in proximity to them, so con- versely bodies moved near a magnet have an electrical cur- rent developed in them. Magnetism can, then, through the medium of electricity, produce heat, light, and chemical affin- ity. Motion it can directly produce under the above condi- tions ; i. e. a magnet being itself moved will moAre other fer- reous bodies : these avUI acquire a static condition of equilib- rium, and be again moved when the magnet is also moved. By motion or arrested motion only, could the phenomena of magnetism ever have become knoAvn to us. A magnet, hoAV- ever poAverful, might rest for ever unnoticed and unknoAvn, unless it were moved near to iron, or iron moved near to it, so as to come Avithin the sphere of its attraction. But even with other than either magnetic or electrified substances, all bodies wiU be moA'ed when placed near the poles of very powerful magnets—some taking a position ax- ially, or in the line from pole to pole of the magnet; others equatorially, or in a direction transverse to that line—the former being attracted, the latter apparently repelled, by tho poles of the magnet. These effects, according to the views of Faraday, show a generic difference between the two classes of bodies, magnetics and diamagnetics ; according to others, a difference of degree or a resultant of magnetic ac- tion ; the less magnetic substance being forced into a trans- verse position by the magnetisation of the more magnetic medium Avhich surrounds it. According to the view given above, magnetism may bo produced by the other forces, just as the vanes in the. instance MAGNETISM. 145 given are definitely deflected, but cannot produce them except Avheu in motion : motion, therefore, is to be regarded in this case as the initiative force. Magnetism wiU, however, di- rectly affect the other forces—light, heat, and chemical affin- ity, and change their direction or mode of action, or, at aU events, wiU so affect matter subjected to these forces, that their direction is changed. Since these lectures were deliv- ered, Faraday has discovered a remarkable effect of the mag- netic *force in occasioning the deflection of a ray of polarised light. If a ray of polarised light pass through water, or through any transparent liquid or solid Avhich does not alter or turn aside the plane of polarisation, and the column, say of Avater, tlirough which it passes be subjected to the action of a pow- erful magnet, the hne of magnetic force, or that which would unite the poles of the magnet, being in the same direction as the ray of polarised hght, the water acquires, with reference to the light, simUar, though not quite identical, properties to oil of turpentine—the plane of polarisation is rotated, and the direction of this rotation is changed by changing the di- rection of the magnetic force: thus, if we suppose a polar- ised ray to pass first in its course the north pole of the mag- net, then between that and the south pole it wiU be deflected, or curved to the right; while if it meets the south pole first in its course, it wiU, in its journey between that and the north pole, be turned to the left. If the substance through which the ray is transmitted be of itself capable of deflecting the plane of polarisation, as, for instance, oU of turpentine, then the magnetic influence wiU increase or diminish this rotation, according to its direction. A similar effect to this is observed with polarised heat when the medium through which it is transmitted is subjected to magnetic influence. Whether this effect of magnetism is rightly termed an ef- fect upon hght and heat, or is a molecular change of the mat- ter transmitting the light and heat, is a question the resolu- 7 146 CORRELATION OF PHYSICAL FORCES. tion of which must be left to the future ; at present, the an- swer to it would depend upon the theory we adopt. If the view of hght and heat which I have stated be adopted, then we may fairly say that magnetism, in these experiments, di- rectly affects the other forces; for light and heat being, ac- cording to that view, motions of ordinary matter, magnetism, in affecting these movements, affects the forces which occa- sion them. If, however, the other theories be adhered to, it would be more consistent with the facts to view these results as exhibiting an action upon the matter itself, and the heat and light as secondarUy affected. When substances are undergoing chemical changes, and a magnet is brought near them, the direction or hnes of action of the chemical force will be changed. There are many old experiments which probably depended on this effect, but which were erroneously considered to prove that permanent magnetism could produce or increase chemical action : these have recently been extended and explained by Mr. Hunt and Mr. Wartmann, and are now better understood. The above cases are apphcable to the subject of the pres- ent Essay, inasmuch as they show a relation to exist between magnetic and the other forces, which relation is, in all proba- bility, reciprocal; but in these cases there is not a production of light, heat, or chemical affinity, by magnetism, but a change in their direction or mode of action. There is, however, that which may be vieAved as a dy- namic condition of magnetism ; i. e. its condition at the com- mencement and the termination, or during the increment or decrement of its development. While iron or steel is being rendered magnetic, and as it progresses from its non-magnetic to its maximum magnetic state, or recedes from its maximum to zero, it exhibits a dynamic force ; the molecules are, it may be inferred, in motion. Similar effects can then be pro- duced to those which are produced by a magnet whhst in mo- tion. MAGNETISM. 147 An experiment which I published in 1845 tends, I think to illustrate this, and in some degree to show the character of the motion impressed upon the molecules of a magnetic metal at the period of magnetisation. A tube filled with the liquid in which magnetic oxide of iron had been prepared, and terminated at each end by plates of glass, is surrounded by a coil of coated wire. To a spectator looking through this tube a flash of light is perceptible whenever the coil is elec- trised, and less light is transmitted when the electrical current ceases, shoAving a symmetrical arrangement of the minute particles of magnetic oxide whUe under the magnetic in- fluence. In this experiment it should be borne in mind, that the particles of oxide of iron arc not shaped by the hand of man, as would be the case with iron filings, or similar minute por- tions of magnetic matter, but being chemically precipitated, are of the form given to them by nature. While magnetism is in the state of change above described, it AviU produce the other forces ; but it may be said, whUe magnetism is thus progressive, some other force is acting on it, and therefore it does not initiate : this is true, but the same may be said of aU the other forces ; they have no com- mencement that Ave can trace. We must ever refer them back to some antecedent force equal in amount to that pro- duced, and therefore the word initiation cannot in strictness apply, but must only be taken as signifying the force selected as the first: this is another reason why the idea of abstract causation is inapplicable to physical production. To this point I shall again advert. Electricity may thus be produced directly by magnetism, either when the magnet as a mass is in motion, or when its magnetism is commencing, increasing, decreasing, or ceasing ; and heat may sinularly be directly produced by magnetism. I have, since the first edition of this Essay was pubhshed, communicated to the Royal Society a paper by which I think 148 CORRELATION OF PHYSICAL FORCES. I have satisfactorily proved, that whenever any metal suscepti- ble of magnetism is magnetised or demagnetised, its tempera- ture is raised. This was shown, first, by subjecting a bar of iron, nickel, or cobalt to the influence of a poAverful electro- magnet, which was rapidly magnetised and demagnetised in reverse directions, the electro-magnet itself being kept cool by cisterns of water, so that the magnetic metal subjected to the influence of magnetism was raised to a higher temperature than the electro-magnet itself, and could not, therefore, have acquired its increased temperature by conduction or radiation of heat from the electro-magnet; and secondly, by rotating a permanent steel magnet with its pole opposite to a bar of iron, a thermo-electric pile being placed opposite the latter. Dr. Maggi covered a plate of homogeneous soft iron with a thin coating of wax mixed Avith oil, a tube traversed the centre through which the Arapour of boiling water was passed. The plate was made to rest on the poles of an electro-magnet, with card interposed. When the iron is not magnetised, the melted wax assumes a circular form, the tube occupying the centre, but when the electro-magnet is put in action, the curve marking the boundary of the melted substance changes its form and becomes elongated in a direction transverse to the line joining the poles, showing that the conducting power of the iron for heat is changed by magnetisation. Thus we get heat produced by magnetism and the conduc- tion of heat altered by it in a direction having a definite rela- tion to the direction of the magnetism. Is it necessary to call in aid ether or the substance ' caloric' to explain these results ? is it not more rational to regard the calorific effects as changes in the molecular arrangements of the matter sub- jected to magnetism? There is every probability that magnetism, in the dyna- mic state, either when the magnet is in motion, or when the magnetic intensity is varying, TriU also directly produce chemi- MAGNETISM. 149 cal affinity and light, though, up to the present time, such has not been proved to be the case ; the reciprocal effect, also, of the direct production of magnetism by light and heat has not yet been experimentally estabhshed. I have used, in contradistinction, the terms dynamic and static to represent the different states of magnetism. The applications I have made of these terms may be open to some exception, but I know of no other words Avhich wiU so nearly express my meaning. The static condition of magnetism resembles the static condition of other forces : such as the state of tension exist- ing in the beam and a cord of a balance, or in a charged Leyden phial. The old definition of force was, that which caused change in motion; and yet even this definition pre- sents a difficulty: in a case of static equilibrium, such, for instance, as that Avhich obtains in the two arms of a balance, Ave get the idea of force without any palpable apparent motion : Avhether there be really an absence of motion may be a doubt- ful question, as such absence would involve in this case per- fect elasticity, and, in all other cases, a stabUity which, in a long course of time, nature generally negatives, showing, as I believe, an inseparable connection of motion with matter, and an impossibility of a perfectly immobile or durable state. So with magnetism: I believe no magnet can exist in an absolutely stable state, though the duration of its stability will be proportionate to its original resistance to assuming a polarised condition. This, hoAvever, must be taken merely as a matter of opinion : we have, in support of it, the general facts that magnets do deteriorate in the course of years ; and we have the further general fact of the instabihty, or fluxional state, of all nature, Avhen Ave have an opportunity of fairly investigating it at different and remote periods: in many cases, hoAvever, the action is so slow that the changes escape human observation, and, until this can be brought to bear over a proportionate period of time, the proposition cannot be 150 CCRRELATION OF PHYSICAL FORCES. said to be experimentally or inductively proved, but must be left to the mental conviction of those who examine it by the hght of already acknoAvledged facts. AU cases of static force present the same difficulty : thu3, tAvo springs pressing against each other would be said to be exercising force ; and yet there is no resulting action, no heat, no light, &c. So if gas be compressed by a piston, at the time of com- pression heat is given off; but when this is abstracted, although the pressure continues, no further heat is ehminated. Thus, by an equihbrium produced by opposing forces, motion is locked up, or in abeyance, as it were, and may be again developed Avhen the forces are reheved from the tension. But in the first instance, in producing the state of tension, force has to be employed ; and as we have said in treating of mechanical force, so with the other forces the original change which disturbs equihbrium produces other changes which go on Avithout end. Thus, by the act of charging a Leyden phial, the cyhnder, the rubber, and the adjoining portions of the electrical machine have each and aU their states changed, and thence produce changes in surrounding bodies ad infini- tum ; when the jar is discharged, converse changes are again produced. As Avith heat, light, and electricity, the daUy accumulating observations tend to show that each change in the phenomena to Avhich these names are given is accompanied by a change either temporary or permanent in the matter affected by them; so many recent experiments on magnetism have connected magnetic phenomena Avith a molecular change in the subject matter. Thus M. Wertheim has shown that the elasticity of iron and steel is altered by magnetisation ; the co-efficient of elasticity in iron being temporarily, in steel permanently diminished. He has also examined the effects of torsion upon magnet- ised iron, and concludes, from his experiments, that in a bar MAGNETISM. 151 of iron arrived at a state of magnetic equihbrium, temporary torsion diminishes the magnetism, and that the untwisting or return to its primitive state restores the original degree of magnetisation. M. Guillemin observed that a bar slightly curved by its own weight is straightened by being magnetised. Mr. Page and Mr. Marrion discovered that a sound is emitted when iron or steel is rapidly magnetised or demagnetised; and Mr. Joule found that a bar of iron is shghtly elongated by mag- netisation. Again, with regard to diamagnetic bodies, M. Matteucci found that the mechanical compression of glass altered the rotatory power upon a ray of polarised hght which it trans- mitted. He further considered that a change took place in the temper of portions of glass which he submitted to the in- fluence of powerful magnets. The same arguments which have been submitted to the reader as to the other affections of matter being modes of molecular motion, are therefore equaUy apphcable to mag- netism. VII.—CHEMICAL AFFINITY. CHEMICAL AFFINITY, or the force by which dissimi- lar bodies tend to unite and form compounds differing generaUy in character from their constituents, is that mode of force of which the human mind has hitherto formed the least definite idea. The Avord itself—affinity—is iU chosen, its meaning, in this instance, bearing no analogy to its ordinary sense ; and the mode of its action is conveyed by certain con- ventional expressions, no dynamic .theory of it worthy of attention having been adopted. Its action so modifies and alters the character of matter, that the changes it in- duces have acquired, not perhaps very logically, a generic contradistinction from other material changes, and wre thus use, as contradistinguished, the terms physical and chemical. The main distinction between chemical affinity and physi- cal attraction or aggregation, is the difference of character of the chemical compound from its components. This is, how- ever, but a vague line of demarcation ; in many cases, Avhich would be classed by aU as chemical actions, the change of character is but slight; in others, as in the effects of neutrali- sation, the difference of character would be a result which would equaUy foUow from physical attraction of dissimilar substances, the preArious characters of the constituents depend- ing upon this very attraction or affinity: thus an acid corrodes CHEMICAL AFFINITY. 153 because it tends to unite with another body; Avhen united, its corrosive power, i. e. its tendency to unite, being satiated, it cannot, so to speak, be further attracted, and it necessarily loses its corrosive poAver. But there are other cases where no such result could a priori be anticipated, as where the attraction or combining tendency of the compound is higher than that of its constituents: thus, who could, by physical reasoning, anticipate a substance like nitric acid from the combination of nitrogen and oxygen? The nearest approach, perhaps, that we can form to a comprehension of chemical action, is by regarding it (vaguely perhaps) as a molecular attraction or motion. It whl directly produce motion of definite masses, by the resultant of the molecular changes it induces: thus, the projectile effects of gunpowder may be cited as famihar instances of motion produced by chemical action. It may be a question whether, in this case, the force which occasions the motion of the mass is a conversion of the force of chemical affinity, or Avhether it is not, rather, a liberation of other forces exist- ing in a state of static equilibrium, and having been brought into such state by previous chemical actions; but, at aU events, through the medium of electricity chemical affinity may be directly and quantitatively converted into the other modes of force. By chemical affinity, then, we can directly produce electricity; this latter force was, indeed, said by Davy to be chemical affinity acting on masses: it appears, rather, to be chemical affinity acting in a definite direction through a chain of .particles; but by no definition can the exact relation of chemical affinity and electricity be expressed ; for the latter, however closely related to the former, yet exists where the former does not, as in a metallic wire, which when electrified, or conducting electricity, is, nevertheless, not chemicaUy altered, or, at least, not known to be chemieaUy ul'.eied. Volta, the antitype of Prometheus, first enabled us de 154 CORRELATION OF PHYSICAL FORCES. finitely to relate the forces of chemistry and electricity. When two dissimilar metals in contact are immersed in a liquid belonging to a certain class, and capable of acting chemically on one of them, what is termed a voltaic circuit is formed, and, by the chemical action, that pecuhar mode of force called an electric current is generated, which circulates from metal to metal, across the liquid, and through the points of contact. Let us take, as an instance of the conversion of chemical force into electrical, the foUowing, which I made known some years ago. If gold be immersed in hydrochloric acid, no chemical action takes place. If gold be immersed in nitric acid, no chemical action takes place ; but mix the two acids, and the immersed gold is chemicaUy attacked and dissolved : this an is ordinary chemical action, the result of a double chemi- cal affinity. In hydrochloric acid, which is composed of chlorine and hydrogen, the affinity of chlorine for gold being less than its affinity for hydrogen, no change takes place ; but when the nitric acid is added, this latter containing a great quantity of oxygen in a state of feeble combination, the affinity of oxygen for hydrogen opposes that of hydrogen for chlorine, and then the affinity of the latter for gold is enabled to act, the gold combines with the chlorine, and chloride of gold remains in solution in the hquid. Now, in order to exhibit this chemical force in the form of electrical force, instead of mixing the liquids, place them in separate vessels or compartments, but so that they may be in contact, which may be effected by having a porous material, such as un- glazed porcelain, amianthus, &c, between them. Immerse in each of these liquids a strip or wire of gold : as long as these pieces of gold remain separated, no chemical or electrical effect takes place; but the instant they are brought into metallic contact, either immediately or by connecting each with the same metallic Avire, chemical action takes place— the gold in the hydrochloric acid is dissolved, electrical action CnEMICAL AFFINITY. 155 also takes place, the nitric acid is deoxidised by the trans- ferred hydrogen, and a current of electricity may be detected in the metals o» connecting metal by the apphcation of a gal vanometer or any instrument appropriate for detecting such effect. There are few, if any, chemical actions which cannot be experimentally made to produce electricity: the oxidation of metals; the burning of combustibles, the combination of oxy gen and hydrogen, &c, may all be made sources of elec tricity. The common mode in which the electricity of the voltaic battery is generated is by the chemical action of water upon zinc ; this action is increased by adding certain acids to the wratcr, which enable it to act more poAverfuUy upon the zinc, or in some cases act themselves upon it; and one of the most poAverful chemical actions known—that of nitric acid upon oxidable metals—is that Avhich produces the most pow- erful voltaic battery, a combination which I made known in the year 1839 : indeed, we may safely say, that when the chemical force is utilised, or not wasted, but all converted into electrical force, the more powerful the chemical action, the more poAverful is the electrical action which results. If, instead of employing manufactured products or educts, such as zinc and acids, we could realise as electricity the whole of the chemical force which is active in the combustion of cheap and abundant raw materials, such as coal, wood, fat, &c, with air or water, we should obtain one of the greatest practical desiderata, and have at our command a mechanical poAver in every respect superior in its applicability to the steam engine. I have shown that the flame of the common blowpipe gives rise to a very marked electrical current, capable not only of affecting the galvanometer, but of producing chemical decom- position : two plates or coUs of platinum are placed, the one in the portion of the flame near the orifice of the jet, or at the points where combustion commences, the other in the full 156 CORRELATION OF PHYSICAL FORCES. yeUow flame where combustion is at its maximum ; this latter should be kept cool, to enable a thermo-electric current, Avhich is produced by the different temperature of the platinum plates, to co-operate with the flame current; wires attached to the plates of platinum form the terminals or poles. By a row of jets a flame battery may be formed, yielding increased effects ; but in these experiments, though theoretically inter- esting, so smaU a fraction of the poAver, actually at Avork in the combustion, has been throAvn into an electrical form, that there is no immediate promise of a practical result. The quantity of the electrical current, as measured by the quantity of matter it acts upon in its different phenomenal effects, is proportionate to the quantity of chemical action which generated it; and its intensity, or power of overcoming resistance, is also proportionate to the intensity of chemical affinity Avhen a single^ voltaic pair is employed, or to the num- ber of reduplications when the well-knoAvn instrument caUed the voltaic battery is used. The mode in which the voltaic current is increased in in- tensity by these reduplications, is in itself a striking instance of the mutual relations and dynamic analogies of different forces. Let a plate of zinc or other metal possessing a strong affinity for oxygen, and another of platinum or other metal possessing little or no affinity for oxygen, be partially im- mersed in a vessel, A, containing dUute nitric acid, but not in contact Avith each other ; let platinum wires touching each of these plates have their extremities immersed in another vessel, B, containing also dilute nitric acid: as the acid in vessel A is decomposed, by the chemical affinity of the zinc for the oxygen of the acid, the acid in vessel B is also decom- posed, oxygen appearing at the extremity of the wire Avhich is connected with the platinum: the chemical power is con- veyed or transferred through the wires, and, abstracting cer- tain local effects, for every unit of oxygen which combines with the zinc in the one vessel, a unit of oxygen is evolved CHEMICAL AFFINITY. 157 from the platinum wire in the other. The platinum wire in thus thrown into a condition analogous to zinc, or has a poav er given to it of determining the oxygen of the hquid to ita surface, though it cannot, as is the case- with zinc, com bine with it under similar circumstances. If Ave now substi tute for the platinum wire which was connected with the platinum plate, a zinc wire, we have in addition to the deter- mining tendency by which the platinum was affected, tho chemical affinity of the oxygen in vessel B for the zinc wire thus we have, added to the force which was originaUy pro- duced by the" zinc of the combination in vessel A, a second force, produced by the zinc in vessel B, co-operating with the first; two pairs of zinc and platinum thus connected produce, therefore, a more intense effect than one pair; and if we go on adding to these alternations of zinc, platinum, and hquid, Ave obtain an indefinite exaltation of chemical power, just as in mechanics we obtain accelerated motion by adding fresh impulses to motion already generated. The same rule of proportion which holds good in chemi- cal combinations also obtains in electrical effects, when these are produced by chemical actions. Dalton and others proved that the constituents of a vast number of compound substances always bore a definite quantitative relation to each other: thus, water, which consists of one part by weight of hydro- gen united to eight parts of oxygen, cannot be formed by the same elements in any other than these proportions ; you can neither add to nor subtract from the normal ratio of the elements, Avithout entirely altering the nature of the com- pound. Further, if any element be selected as unity, the combining ratios of other elements wUl bear an invariable quantitative relation to that and to each other : thus if hydro- gen be chosen as 1, oxygen wiU be 8, chlorine wiU be 36 ; that is, oxygen wUl unite Avith hydrogen in the proportion of 8 parts by weight to 1, while chlorine wUl unite with hydro- gen in the proportion of 36 to 1, or with oxygen in the pro- 158 CORRELATION OF PHYSICAL FORCES. portion of 36 to 8. Numbers expressing their combining weights, which are thus relative, not absolute, may by a con- ventional assent as to the point of unity, be fixed for aU chemi- cal reagents ; and, Avhen so fixed, it avUI be found that bodies, at least in inorganic compounds, generally unite in those pro- portions, or in simple multiples of them: these proportions are termed Equivalents. Now a voltaic battery, which consists usually of alterna- tions of two' metals, and a hquid capable of acting chemicaUy upon one of them, has, as we have seen, the power of pro- ducing chemical action in a hquid connected with it by metals upon which this hquid is incapable of acting: in such case the constituents of the hquid AviU be eliminated at the surfaces of the immersed metals, and at a distance one from the other. For example, if the two platinum terminals of a \-oltaic battery be immersed in water, oxygen wiU be evolved at one and hydrogen at the other terminal, exactly in the propor- tions in which they form water; whUe, to the most minute examination, no action is perceptible in the stratum of hquid. It was known before Faraday's time that, whUe this chemical action was going on in the subjected liquid, a chemi- cal action was going on in the ceUs of the voltaic battery; but it was scarcely if at all known that the amount of chemi- cal action in the one bore a constant relation to the amount of action in the other. Faraday proved that it bore a direct equivalent relation: that is, supposing the battery to be formed of zinc, platinum, and water, the amount of oxygen which united with the zinc in each cell of the battery was exactly equal to the amount evolved at the one platinum ter- minal, whUe the hydrogen evolved from each platinum plate of the battery was equal to the hydrogen evolved from the other platinum terminal. Supposing the battery to be charged with hydrochloric ftcid, instead of water, whUe the terminals are separated by water, then for every 36 parts by weight of chlorine which CHEMICAL AFFINITY. 159 united with each plate of zinc, eight parts of oxygen would be evolved from one of the platinum terminals : that is, the weights would be precisely in the same relation which Dalton proved to exist in their chemical combining weights. This may be extended to aU hquids capable of being decomposed by the voltaic force, thence caUed Electrolytes : and as no vol- taic effect is produced by liquids incapable of being thus de- composed, it foUows that voltaic action is chemical action tak- ing place at a distance, or transferred through a chain of media, and that the chemical equivalent numbers are the ex- ponents of the amount of voltaic action for corresponding chemical substances. As heat, light, magnetism, or motion, can be produced by the requisite application of the electric current, and as this is definitely produced by chemical action, we get these forces very definitely, though not immediately, produced by chemi- cal action. Let us, hoAvever, here enquire, as we have al- ready done Avith respect to the other forces, how far other forces may directly emanate from chemical affinity. Heat is an immediate product of chemical affinity. I know of no exception to the general proposition that aU bod- ies in chemically combining produce heat; i. e. if solu- tion be not considered as chemical action, and even in that case, when cold results, it is from a change of consistence, as from the sohd to the hquid state, and not from chemical action. We shaU find that the same vieAV of the expenditure of force which we have considered in treating of latent heat holds good as to the expenditure of chemical force when re- garded with reference to the amount of heat or repulsive force which it engenders, the chemical force being here ex- hausted by chemical expansion—that is, by heat. Thus, in the chemical action of the ordinary combustion of coal and oxygen, the expenditure of fuel wUl be in proportion to the expansibility of the substances heated; water passing freely 160 CORRELATION OF PHYSICAL FORCES. into the steam wiU consume more fuel tlan if it be confined and kept at a temperature above its boUing point. Why chemical action produces heat, or what is the action of the molecules of matter when chemically uniting, is a question upon which many theories have been proposed and which may possibly be never more than approximately re- solved. Some authors explain it by the condensation which takes place ; but this will not account for the many instances where, from the hberation of gases, a great increase of volume en- sues upon chemical combustion, as in the familiar instance of the explosion of gunpowder: others explain it as resulting from the union of atmospheres of positive and negative elec- tricity which are assumed to surround the atoms of bodies ; but this involves hypothesis upon hypothesis. Dr. Wood has lately thrown out a view of the heat of chemical action which is more in accordance with a dynamic theory of heat, and as such demands some notice. Starting with his proposition, AArhich I have previously mentioned, ' that the nearer the par- ticles of bodies are to each other the less they require to move to produce a given motion in the particles of another body,' his argument, if I rightly understand it, assumes some- thing of this form. In the mechanical approximation of the particles of a homogeneous body heat results ; the particles a a of the body A would, by their approximation, produce expansion in the neighbouring body B, the more so in proportion as they them- selves were previously nearer to each other. In chemicaUy combining, a a the particles of A are brought into very close proximity with b b the particles of B ; heat should therefore result, and the greater because the proximity may fairly be assumed to be greater in the case of chemical combination than in that of mechanical compression. In cases, then, where there is no absolute diminution of bulk ensuing on chemical combination, if the greater proximity of the com- CHEMICAL AFFINITY. 161 bining particles be such that the correlative expansion ou«ht to be greater (if there were no chemical combination) than that occupied by the total volume of the new compound, an extra expanding power is evolved, and heat or expansion ought to be produced in surrounding bodies. In other words, if a a could be brought by physical attraction as near each other as they are by chemical attraction brought near to b 6, they Avould, from their increased proximity, produce an ex- pansive poAver ultra the volume occupied by the actual chem- ical compound A and B. The question, however, immedi- ately occurs, why should the volume of the compound be lim- ited and not occupy the fuU space equivalent to the expanding power induced by the contraction or approximation of the particles. As the distance of the particles is the resultant of the contending contracting and expanding powers, this result ought to express itself in terms of the actual volume produced by the combination, which it certainly does not. Though I see some difficulties in Dr. Wood's theory, and perhaps have not rightly conceived it, his views have to my mind great interest, his mode of regarding natural phenomena being analogous to that wliich I have in this Essay, and for many years, advocated, viz. to divest physical science as much as possible of hypothetic fluids, ethers, latent entities, occult qualities, &c. My own notion of the heat produced by chemical combination, though I scarcely dare venture an opinion upon a subject so controverted, is, that it is analogous to the heat of friction, that the particles of matter in close approximation and rapid motion inter se evolve heat as a con- tinuation of the motion interrupted by the friction or intesti- nal motion of the particles: heat would thus be produced, whether the resulting compound were of greater or less bulk than the sum of the components, though of course when the compound is of greater bulk less heat would be apparent in neighbouring bodies, the expansion taking place in one of the substances themselves—I say in one of them, for it is stated 162 CORRELATION OF PHYSICAL FORCES. in books of authority that there is no instance of two or mora sohds or liquids, or a solid and a hquid, combining and pro- ducing a compound which is entirely gaseous at ordinary temperatures and pressures. The substance gun-cotton, how- ever, discovered by Dr. Schoenbein, very nearly realises this proposition. Dr. Andrews has arrived at the conclusion, after careful experiment, that in chemical combinations where acids and alkalies or analogous substances are employed, the amount of heat produced is determined by the basic ingredient, and his experiments have received general assent; although it should be stated that M. Hess arrived at contrary results, the acid constituent according to his experiments furnishing the meas- ure of the heat developed. Light is directly produced by chemical action, as in the flash of gunpowder, the burning of phosphorus in oxygen gas, and aU rapid combustions : indeed, wherever intense heat is developed, hght accompanies it. In many cases of slow combustion, such as the phenomena of phosphorescence, the hght is apparent- ly much more intense than the heat; the former being obvious, the latter so difficult of detection that for a long time it was a question whether any heat was ehminated ; and I am not aware that at the present day, any thermic effects from cer- tain modes of phosphorescence, such as those of phospho- rescent wood, putrescent fish, &c, have been detected. Chemical action produces magnetism whenever it is thrown into a definite direction, as in the phenomenon of electrolysis. I may adduce the gas voltaic battery, as presenting a simple instance of the direct production of magnetism by chemical synthesis. Oxygen and hydrogen in that combination chemi- caUy unite ; but instead of combining by intimate molecular admixture, as in the ordinary cases, they act upon water, i. e. combined oxygen and hydrogen, placed between them so as to produce a line of chemical action; and a magnet adjacent to this hne of action is deflected, and places itself at right CHEMICAL AFFINITY 163 angles to it. What a chain of molecules does here, there can be no doubt all the molecules entering into combination would produce in ordinary chemical actions ; but in such case-, the direction of the lines of combination being irregu- lar and confused, there is no general resultant by wliich the magnet can be affected. What the exact nature of the transference of chemical power across an electrolyte is, we at present know not, nor can we form any more definite idea of it than that given by the theory of Grotthus. We have no knowledge as to the exact nature of my mode of chemical action, and, for the present must leave it as an obscure action of force, of which future researches may simplify our apprehension. We have seen that an equivalent or proportionate electri- cal effect is produced by a given amount of chemical action ; if Ave, in turn, produce heat and magnetism and motion by the electricity resulting from chemical action, we shaU be able to measure these forces far more accurately than when they are directly produced, and thus to deduce their equivalent re- lation to the initial chemical action. Thus M. Favre, after ascertaining the quantity of heat produced by the oxidation of a quantity of zinc, and finding, as have others, that the heat is the same Avhen evolved from a voltaic battery by the same consumption of zinc forming its positive element, makes the following experiment. A voltaic battery and electro-magnet are immersed in cal- orimeters, and the heat produced when the connection with the magnet is effected is noted. The electro-magnet is then made to raise a Aveight, and thus perform mechanical work, and the heat produced is igain noted. It is found in the latter case that less heat is evoh'ed than in the former, a certain quantity of heat has therefore been replaced by the mechanical work ; and by esti- mating tho amount of heat subtracted, and the amount of work produced, he deduces the relative equivalent of work to 164 CORRELATION OF PHYSICAL FORCES. heat. These experiments give a production of mechanical work by chemical action, not, it is true, a direct production. but, as the heat and work are in inverse ratios, and each has its source in chemical action, they prove that they are definite for a definite amount of chemical action, and as each is pro- duced respectively by electricity and magnetism, these forces must also bear a definite relation to the initial chemical force. The doctrine of definite combining proportions, which so beautifuUy serves to relate chemistry to voltaic electricity, led to the atomic theory, wliich, though adopted in its univer- sality by a large majority of chemists, presents great difficul- ties when extended to aU chemical combinations. The equivalent ratios in which a great number of sub- stances chemicaUy combine, hold good in so many instances, that the atomic doctrine is beheved by many to be universally applicable, and called a law; and yet, when foUowed in the combinations of substances whose natural chemical attractions are very feeble, the relation fades away, and is sought to be recovered by applying a separate and arbitrary multipher to the different constituents. Thus, when it was found that a vast number of substances combined in definite volumes and weights, and in definite vol- umes and weights only, it was argued that their ultimate molecules or atoms had a definite size, as otherwise there was no apparent reason why this equivalent ratio should hold good: why, for instance, water should only be formed of two volumes or one unit by weight of hydrogen, and of one vol- ume or eight units by weight of oxygen ; why, unless there were some ultimate limits to the divisibility of its molecules, should not water, or a fluid substance approximating to water in character, be formed by a half, a third, or a tenth part of hydrogen, with eight parts of oxygen ? It Avas perfectly consistent with the atomic view that a substance might be formed with one part combined with eight parts, or with sixteen, or with tAventy-four, for in such a sub- CHEMICAL AFFINITY. 165 stance there would be no subdivision of the (supposed indivi- sible) molecule ; and this held good with many compounds • thus fourteen parts by weight, say grains of nitrogen, wiU combine respectively with eight, sixteen, twenty-four, thirty- two, and forty parts by weight, or grains, of oxygen. So, again, twenty-seven grains of iron wUl combine with eight grains of oxygen or with twenty-four grains, i. e. three proportionals of oxygen. No compound is known in which twenty-seven grains of iron wiU combine with two propor- tionals or sixteen grains of oxygen ; but this does not much affect the theory, as such a compound may be yet discovered, or there may be reasons at present unknown Avhy it cannot be formed. But now comes a difficulty : twenty-seven parts by weight of iron will combine with twelve parts by Aveight of oxygen, and twenty-seven parts of iron AviU also combine wit" ten and two-third parts of oxygen. Thus if we retain the unit of iron we must subdivide the unit of oxygen, or if we retain the unit of oxygen we must subdivide the unit of iron, or Ave must subdiAride both by a different divisor. What then be- comes of the notion of an atom or molecule physically indi- visible ? If iron were the only substance to which this difficulty applied, it might be viewed as an unexplained exception, or as a mixture of two oxide3; or recourse might be had to a more minute subdivision to form the units or equivalents of other substances ; but numerous other substances faU under a similar category ; and in organic combinations, to preserve the atomic nomenclature we must apply a separate multipher or divisor to far the greater number of the elementary con- stituents, i. e. we must divide that which is, ex hypothesis indi- visible. Thus, to take a more complex substance than any formed bv the combination of iron and oxygen, let us select the sub- stance albumen, composed of carbon, hydrogen, nitrogen. 166 CORRELATION OF PHYSICAL FORCES. oxygen, phosphorus, and sulphur. In this case Ave must ei- ther divide the atoms of phosphorus and sulphur so as to re- duce them to small fractions, or multiply the atoms of the other substances by extravagant numbers ; thus to preserve the unit of one of the constituents of this substance, chemists say it is composed of 400 atoms of carbon, 310 of hydrogen, 120 of oxygen, 50 of nitrogen, 2 of sulphur, and 1 of phos- phorus. This is a somewhat extreme case, but similar diffi- culties wUl be found in different degrees to prevail among or- ganic compounds ; in very many no constituent can be taken as a unit to which simple multiples of any of the others wiU give their relative proportions. By the mode of notation adopted, if any conceivable substance be selected, it could, Avhatever be the proportions of it3 constituents, be termed atomic. A solution of an ounce of sugar in a pound of wa- ter, in a pound and a half, in a pound and a quarter, in a pound and a tenth, might be expressed in an atomic form, if we select arbitrarily a multiplier or divisor. It is true that in the case of solution, different proportions can be united up to the point of saturation without any dif- ference in the character of the compound, though the same may be predicated to some extent of an acid and an alkali; but even where the steps are sudden, and compounds only exist with definite proportions, they cannot, in a multitude of cases, be reconcUed with the true idea of an atomic combina- tion, i. e. one to one, one to two, &c. Although, therefore, nature presents us with facts which show that there is some restrictive laAV of combination which in numerous cases limits the ratios in Avhich substances wiU combine, nay, further, shows many instances of a proportion between the combining weights of one compound and those of another; although she shows also a remarkable simplicity in the combining volumes of numerous gases, she also gives numerous cases to which the doctrine of atomic combinations cannot fairly be applied. CHEMICAL AFFLNrTV. 167 That there must be something in the constitution of mat- ter, or in the forces which act on it, to account for the per saltum manner in which chemical combinations take place, is inevitable ; but the idea of atoms does not seem satisfactorUy to account for it. By selecting a separate multipher or divisor, chemists may denote every combination in terms derived from the atomic theory ; but they have passed from the original law, Avhich contemplated only definite multiples, and the very hy- pothetic expressions of atoms, which the apparently simple relations of combining weights first led them to adopt, they are obliged to vary and to contradict in terms, by dividing that which their hypothesis and the expression of it assumed to be indivisible. WhUe, therefore, I fully recognise a great natural truth in the definite ratios presented by a vast number of chemical combinations, and in the per saltum steps in which nearly aU take place, I cannot accept as an argument in favour of an atomic theory, those combinations which are made to support it by the application of an arbitrary notation. A similar straining of theory seems graduaUy obtaining in regard to the doctrine of compound radicals. The discov- ery of cyanogen by Gay-Lussac was probably the first in- ducement to the doctrine of compound radicals; a doctrine Avhich is now generally, perhaps too generaUy, received in organic chemistry. As, in the case of cyanogen, a body ob- viously compound discharged in almost all its reactions the functions of an element, so in many other cases it was found that compound bodies in Avhich a great number of elements existed, might be regarded as binary combinations, by con- sidering certain groups of these elements as a compound rad- ical ; that is, as a simple body when treated of in relation to the other complex subslauces of which it forms part, and only as non-elementary when referred to its internal consti- tution. 168 CORRELATION OF PHYSICAL FORCES. Undoubtedly, by approximating in theory the reactions of inorganic and of organic chemistry, by keeping the mind within the hmits of a beaten path, instead of aUowing it to wander through a maze of isolated facts, the doctrine of com- pound radicals has been of service ; but, on the other hand, the indefinite variety of changes wliich may be rung upon the composition of an organic substance, by different associations of its primary elements, makes the binary constituents vary as the minds of the authors who treat of them, and makes their grouping depend entirely upon the strength of the anal- ogies presented to each individual mind. From this cause, and from the extreme license which has been taken in theo- retic groupings deduced from this doctrine, a serious question arises whether it may not ultimately, unless carefully re- stricted, produce confusion rather than simplicity, and be to the student an embarrassment rather than an assistance. * VIII.—OTHEli MODES OF FOECE. C~"ATALYSIS, or the chemical action induced by the mere presence of a foreign body, embraces a class of facts which must considerably modify many of our notions of chemical action: thus oxygen and hydrogen, Avhen mixed in a gaseous state, wUl remain unaltered for an indefinite pe- riod ; but the introduction to them of a shp of clean plati- num will cause more or less rapid combination, without being in itself in any respect altered. On the other hand, oxygen- ated water, which is a compound of one equivalent of hydro- gen plus tAvo of oxygen, wUl, Avhen under a certain tempera- ture, remain perfectly stable ; but touch it with platinum in a state of minute division, and it is instantly decomposed, one equivalent of oxygen being set free. Here, again, the platinum is unaltered, and thus we have synthesis and analy- sis effected apparently by the mere contact of a foreign body. It is not improbable that the increased electrolytic power of water by the addition of some acids, such as the sulphuric and phosphoric, where the acids themselves are not decom- posed, depends upon a catalytic effect of these acids ; but we know too httle of the nature and rationale of catalysis to ex- press any confident opinion on its modes of action, and pos- sibly we may comprehend very different molecular actions under one and the same name. In no case does catalysis yield us new power or force : it only determines or facilitates 8 170 CORRELATION OF PHYSICAL FORCES. the action of chemical force, and, therefore, is no creation of force by contact. The force so deAeloped by catalysis may be converted into a voltaic form thus: in a single pair of the gas battery above aUuded to, one portion of a strip of platinum is im- mersed in a tube of oxygen, the other in one of hydrogen, both the gases and the extremities of the platinum being con- nected by water or other electrolyte ; a voltaic combination is thus formed, and electricity, heat, light, magnetism, and motion, produced at the wiU of the experimenter. In this combination we have a striking instance of cor relative expansions and conti actions, analogous, though in a much more refined form, to the expansions and contractions by heat and cold detaUed in the early part of this essay, and illustrated by the alternations of two bladders partiaUy filled with air: thus, as by the effect of chemical combination in each pair of tubes of the gas battery the gases oxygen and hydrogen lose their gaseous character and shrink into Avater, so at the platinum terminals of the battery, when immersed in water, water is decomposed, and expands into oxygen and hydrogen gases. The correlate of the force which changes gas into liquid at one point of space, changes hquid into gas at another, and the exact A-olume which disappears in the one place reappears in the other ; so that it Avould appear to an inexperienced eye as though the gases passed through solid wires. Gravitation, inertia, and aggregation, were but cursorily alluded to in my original lectures ; their relation to the other modes of force seemed to be less definitely traceable ; but the phenomenal effects of gravitation and inertia, being motion and resistance to motion, in considering motion I have in some degree included their relations to the other forces. To my mind gravitation would only produce other force Avhen the motion caused by it ceases. Thus, if we suppose a meteor to be a mass rotating in an orbit round the earth, OTHER MODES OF FORCE. 171 and with no resisting medium, then, as long as that rotation continues, the motion of the meteoric mass itself would be the exponent of the force impelling it; if there be a resist- ing medium, part of this motion would be arrested and taken up by the medium, either as motion, heat, electricity, or some other mode of force ; if the meteor approach the earth suffi- ciently to fall upon it, the perceptible motion of the meteor is stopped, but is taken up by the earth which vibrates through its mass ; part also reappears as heat in both earth and meteor, and part in the change in the earth's position consequent on its increase of gravity, and so on. Gravita- tion is but the subjective idea, and its relation to other modes of force seems to me to be identical with that of pressure or motion. Thus, when arrested motion produces heat, it mat- ters not whether the motion has been produced by a faUing body, i. e. by gravitation, or a body projected by an explo- sive compound, &c.; the heat AArill be the same, provided the mass and A'elocity at the time of arrest be the same. In no other sense can I conceive a relation between gravitation and the other forces, and, Avith all diffidence, I cannot agree with those who seek a more mysterious link. Mosotti has mathematicaUy treated of the identity of gravitation Avith cohesive attraction, and Pliicker has recently succeeded in showing that crystaUine bodies are definitely af- fected by magnetism, and take a position in relation to the lines of magnetic force dependent upon their optical axis or axis of symmetry. What is termed the optic axis is a fixed direction through crystals, in Avhich they do not doubly refract light, and which direction, in those crystals Avhich have one axis of figure, or a line around which the figure is symmetrical, is parallel to the axis of symmetry. When submitted to magnetic influ- ence such crystals take up a position, so that their optic axis points diamagnetically or transversely to the lines of magnetic force; and when, as is the case in some crystals, there is 172 CORRELATION OF PHYSICAL FORCES. more than one optic axis, the resultant of these axes points diamagnetically. The mineral cyanite is influenced by mag- netism in so marked a manner that when suspended it will arrange itself definitely with reference to the direction of ter- restrial magnetism, and may, according to Plucker, be used as a compass-needle. There is scarcely any doubt that the force which is con- cerned in aggregation is the same which gives to matter its crystalhne form; indeed, a vast number of inorganic bodies, if not all, which appear amorphous are, wdien closely exam- ined, found to be crystalhne in their structure : we thus get a reciprocity of action between the force which unites the mole- cules of matter and the magnetic force, and through the me- dium of the latter the correlation of the attraction of aggre- gation with the other modes of force may be established. I believe that the same principles and mode of reasoning as have been adopted in this essay might be applied to tho organic as Avell as the inorganic world; and that muscular force, animal and vegetable heat, &c, might, and at some time avUI, be shown to have similar definite correlations ; but 1 have purposely avoided this subject, as pertaining to a depart- ment of science to which I haA'e not devoted my attention. I ought, however, while aUuding to this subject, shortly to mention some experiments of Professor Matteucci, communi- cated to the Royal Society in the year 1850, by which it ap- pears that whatever mode of force it be which is propagated along the nervous filaments, this mode of force is definitely affected by currents of electricity. His experiments shoAV that when a current of positive electricity traverses a portion of the muscle of a hving animal in the same direction as that in Avhich the nerves ramify—i. e. a direction from the brain to the extremities—a muscular contraction is produced in the limb experimented on, showing that the nerve of motion is affected; while, if the current, as it is termed, be made to traverse the muscle in the reverse direction, or toAvards the OTHER MODES OF FORCE. 173 nervous centres, the animal utters cries, and exhibits all the indications of suffering pain, scarcely any muscular move ment being produced; showing that in this case the nerves of sensation are affected by the electric current, and therefore that some definite polar condition exists, or is induced, in the nerves, to which electricity is correlated, and that probably this polar condition constitutes nerA'ous agency. There are other analogies given in the papers of M. Matteucci, and de- rived from the action of the electrical organs of fishes, which tend to corroborate and devclope the same vieAV. By an application of the doctrine of the Correlation of Forces, Dr. Carpenter has shoAvn Iioav a difficulty arising from the ordinary notions of the developement of an organised being from its germ-ceU may be lessened. It has been thought by many physiologists that the nisus formativus, or organising force of an animal or A-egetable structure, hes dor- mant in the primordial germ-cell. ' So that the organising force required to build up an oak or a palm, an elephant or a Avhale, is concentrated in a minute particle only discernible by microscopic aid.' Certain other views of nearly equal difficulty have been propounded. Dr. Carpenter suggests the probability of ex- traneous forces, as heat, hght, and chemical affinity, contin- uously operating upon the material germ ; so that all that ia required in this is a structure capable of receiving, directing, and converting these forces into those which tend to the assim- Uation of extraneous matter and the definite developement of the particular structure. In proof of this position he shows how dependent the process of germ developement is upon the presence and agency of external forces, particularly heat and light, and how it is regulated by the measure of these forces supplied to it. It certainly is far less difficult so to conceive the supply of force yielded to organised beings in their gradual process of groAVth, than to suppose a store of dormant or latent force pent up in a microscopic monad. 174 CORRELATION OF PHYSICAL FORCES. As by the artificial structure of a A-oltaic battery, chemi- cal actions may be made to cooperate in a definite direction, so, by the organism of a vegetable or animal, the mode of motion which constitutes heat, light, &c, may, without extra- vagance, be conceived to be appropriated and changed into the forces which induce the absorption, and assimUation of nutriment, and into nervous agency and muscular poAver. Indications of similar thoughts maybe detected in the writings of Liebig. Some difficulty in studying the correlations of vital with inorganic physical forces arises from the effects of sensation and consciousness, presenting a similar confusion to that alluded to, when, in treating of heat, I ventured to suggest, that observers are too apt to confound the sensations with the phenomena. Thus, to apply some of the considerations on force, given in the introductory portion of this essay, to cases where vitality or consciousness interA-encs. When a Aveight is raised by the hand, there should, according to the doctrine of non-creation of force, have been somewhere an expenditure equivalent to the amount of gravitation overcome in raising the weight. That there is expenditure we can prove, though in the present state of science we cannot measure it. Thus, prolong the effort, raise weights for an hour or two, the vital powers sink, food, i. e. fresh chemical force, is required to supply the exhaustion. If this supply is withheld and the exertion is continued, Ave see the consumption of force in the supervening weakness and emaciation of the body. The consciousness of effort, which has formed a topic of argument by some writers when treating of force, and is by them believed to be that wliich has originated the idea of force, may by the physical student be regarded as feehng is * in the phenomena of heat and cold, viz. a sensation of the struggle of opposing molecular motions in overcoming the resistance of the masses to be moved. When we say we feel hot, we feel cold, we feel that we are exerting ourselves, our OTHER MODES OF FORCE. 175 expressions are intelligible to beings Avho are capable of ex- periencing similar sensations; but the physical changes accompanying these sensations are not thereby explained. Without pretending to knoAv what probably we shaU never knoAA*. the actual modus agendi of the brain, nerves, muscles, &c, wre may study vital as we do inorganic phenomena, both by observation and experiment. Thus, Sir Benjamin Brodie has examined the effect of respiration on animal heat by inducing artificial respiration after the spinal cord has been severed; in which case he finds the animal heat declines, notAvith- standing the continuance of the chemical action of respiration, carbonic acid being formed as usual; but he also finds that under such circumstances the struggles or muscular actions of the animal are very great, and sufficient probably to ac- count for the force eliminated by the chemical action in digestion and respiration; and Liebig, by measuring the amount of chemical action in digestion and respiration, and comparing it with the labour performed, has to some extent established their equivalent relations. Mr. Hehnholtz has found that the chemical changes Avhich take place in muscles are greater when these are made to undergo contractions than when they are in repose ; and that, as Avould be expected, the consumption of the matter of the muscles, or, in other terms, the waste or excrementitious matter throAvn off, is greater in the former than in the latter case. M. Matteucci has ascertained that the muscles of recently killed frogs absorb oxygen and exhale carbonic acid, and that when they are thrown into a state of contraction, and still more Avhen they perform mechanical Avork, the absorption is increased; and he even calculates the equivalents of work so performed. M. Beclard finds that the quantity of heat produced by voluntary muscular contraction in man is greater AArhen that contraction is Avhat he terms static, that is, when it produces 176 CORRELATION OF PHYSICAL FORCES. no external work, but is effort alone, than Avhen that effort and contraction are employed dynamically, so as to raise a weight or produce mechanical Avork. Thus, though we may see no present promise of being able to resolve sensations into their ultimate elements, or to trace, physically, the link which unites volition with exertion or effort, in terms of our own consciousness of it, Ave may hope to approximate the solution of these deeply interesting questions. In the same individual the chemical and physical state of the secretions in the warm may be compared with those in the cold parts of the body. The changes in digestion and respiration, when the body is in a state of rest, may be com- pared with those which obtain when it is in a state of activity. The relations with external matter, maintaining, by the con- stant play of natural forces, the vital nucleus, or the organi- sation by means of Avhich matter and force receive, for a definite period, a definite incorporation and direction, may be ascertained, while the more minute structural changes are revealed to us by the ever-improving powers of the micro- scope ; and thus step by step we may learn that which it is given to us to learn, boundless in its range and infinite in its progress, and therefore never giving a response to the ultimate —Why? As the first glimpse of a new star is caught by the eye of the astronomer while directing his vision to a different point of space, and disappears Avhen steadfastly gazed at, only to have its position and figure ultimately ascertained by the em- ployment of more penetrative powers, so the first scintUlations of new natural phenomena frequently present themselves to the eye of the observer, dimly seen when viewed askance, and disappearing if directly looked for. When new powers of thought and experiment have developed and corrected the first notions, and given a character to the new image, proba- bly very different from the first impression, fresh objects are OTHER MODES OF FORCE. 177 again glanced at in the margin of the new field of vision, which in their turn have to be verified, and again lead to new extensions ; thus the effort to estabUsh one observation leads to the imperfect perception of new and wider fields of research; and, instead of approaching finality, the more we discover, the more infinite appears the range of the undi> covered 1 IX.—CONCLUDING REMARKS. I HAVE now gone through the affections of matter for which distinct names have been given in our received nomenclature : that other forces may be detected, differing as much from them as they differ from each other, is highly probable, and that when discovered, and their modes of action fuUy traced out, they will be found to be related inter se, and to these forces as these are to each other, I beheve to be as far certain as certainty can be predicted of any future event. It may in many cases be a difficult question to determine what constitutes a distinct affection of matter or mode of force. It is highly probable that different hnes of demarca tion would have been drawn between the forces already known, had they been discovered in a different manner, or first observed at different points of the chain which connects them. Thus, radiant heat and hght are mainly distinguished by the manner in which they affect our senses: were they vieAved according to the way in which they affect inorganic matter, very different notions would possibly be entertained of their character and relation. Electricity, again, was named from the substance in wdiich, and magnetism from the district Avhere, it first happened to be observed, and a chain of intermediate phenomena have so connected electricity Avith galvanism that they are now regarded as the same force, CONCLUDING REMARKS. 179 differing only in the degree of its intensity and quantity. though for a long time they were regarded as distinct. The phenomenon of attraction and repulsion by amber, Avhich originated the term electricity, is as unhke that of the decomposition of water by the voltaic pile, as any two natural phenomena can well be. It is only because the historical sequence of scientific discoveries has associated them by a number of intermediate hnks, that they are classed under the same category. What is caUed voltaic electricity might equally, perhaps more appropriately, be caUed voltaic chemis- try. I mention these facts to show that the distinction in the name may frequently be much greater than the distinction of the subject which it represents, and vice versa, not as at aU objecting to the received nomenclature on these points; nor do I say it would be advisable to depart from it: were Ave to do so, inevitable confusion would result, and objections equally forcible might be found to apply to our new termi- nology. Words, AA-hen estabhshed to a certain point, become a part of the social mind; its powers and very existence de- pend upon the adoption of conventional symbols; and were these suddenly departed from, or varied, according to indivi- dual apprehensions, the acquisition and transmission of knowl- edge would cease. Undoubtedly, neology is more permissi- ble in physical science than in any other branch of know ledge, because it is more progressive; new facts or new relations require new names, but even here it should be used with great caution. Si forte necesse est Indiciis monstrare recentibus abdita rerum, Fingere cinctutis non exaudita Cethegis, Continget; dabiturquo licentia, sumpta pudenter. Even should the mind ever be led to dismiss the idea of various forces, and regard them as the exertion of one force, ISO CORRELATION OF PHYSICAL FORCES. or resolve them definitely into motion; stUl we could never avoid the use of different conventional terms for the different modes of action of this one pervading force. Reviewing the series of relations between the A'arious forces which we have been considering, it would appear that in many case3 where one of these is excited or exists, aU the others are also set in action : thus, when a substance, such as sulphuret of antimony, is electrified, at the instant of electri- sation it becomes magnetic in directions at right angles to the hnes of electric force ; at the same time it becomes heated to an extent greater or less according to the intensity of the electric force. Bf this intensity be exalted to a certain point the sulphuret becomes luminous, or light is produced: it ex- pands, consequently motion is produced; and it is decomposed, therefore chemical action is produced. If Ave take anothei substance, say a metal, all these forces except the last are developed; and although we can scarcely apply the term mechanical action to a substance hitherto undecomposed, and which, under the circumstances we are considering, enters into no new combination, yet it undergoes that species of polarisation which, as far as we can judge, is the first step towards chemical action, and which, if the substance were decomposable, would resolve it into its elements. Perhaps, indeed, some hitherto undiscovered chemical action is pro- duced in substances which we regard as undecomposable : there are experiments to show that metals which have been electrised are permanently changed in their molecular consti- tution. Oxygen, we have seen, is changed by the electric spark into ozone, and phosphorus into ^Uotropic phosphorus, both Avhich changes were for a long time unknown to those familiar with electrical science. Thus, with some substances, when one mode of force is produced all the others are simultaneously developed. With other substances, probably with aU matter, some of the other forces are developed, whenever one is excited, and all may bo CONCLUDING REMARKS. 181 so were the matter in a suitable condition for their develope- ment, or our means of detecting them sufficiently delicate. This simultaneous production of several different forces seems at first sight to be irreconcileable with their mutual and necessary dependence, and it certainly presents a formidable experimental difficulty in the way of estabhshing their equiv- alent relations ; but when examined closely, it is not in fact inconsistent with the views we have been considering, but is indeed a strong argument in favour of the theory which re gards them as modes of motion. Let us select one or two cases in which this form of ob jection may be prominently put forward. A voltaic battery decomposing water in a voltameter, whUe the same current is employed at the same time to make an electro-magnet, gives nevertheless in the voltameter an equivalent of gas, or decomposes an equivalent of an electrolyte for each equiva- lent of chemical decomposition in the battery ceUs, and wUl give the same ratios if the electro-magnet be removed. Here, at first sight, it would appear that the magnetism was an ex- tra force produced, and that thus more than the equivalent power was obtained from the battery. In answer to this objection it may be said, that in the circumstances under which this experiment is ordinarUy performed, several cells of the battery are used, and so there is a far greater amount of force generated in the cells than is indicated by the effect in the voltameter. If, moreover, the magnet be not inter- posed, stiU the magnetic force is equaUy existent throughout the whole current; for instance, the wires joining the plates will attract iron filings, deflect magnetic needles, &c, and produce diamagnetic effects on surrounding matter. By the iron core a small portion of the force is, indeed, absorbed while it is being made a magnet, but this ceases to be ab- sorbed when the magnet is made ; this has been proved by the observation of Mr. Latimer Clarke, Avho has found that alonf the wires of the electric telegraph the magnetic needles 182 CORRELATION OF PHYSICAL FORCES. placed at different stations remained fixed after the connection with the battery was made, and whUe the electric current acted by induction on surrounding conducting matter, separa- ted from the wires by their gutta percha coating, so that a sort of Leyden phial Avas formed; but as soon as this induc- tion had produced its effect between each station, or, so to speak, the phial was charged, the needles successively were deflected : it is like the case of a puUey and weight, which lat- ter exhausts force while it is being raised ; but when raised, the force is free, and may be used for other purposes. If a battery of one ceU, just capable of decomposing water and no more, be employed, this wiU cease to decompose while making a magnet. There must, in every case, be prepon- derating chemical affinity in the battery ceUs, either by the nature of its elements or by the reduphcation of series, to effect decomposition in the voltameter; and if the point is just reached at which this is effected, and the power is then reduced by any resistance, decomposition ceases: were it otherwise, were the decomposition in the voltameter the exponent of the entire force of the generating ceUs, and these could independently produce magnetic force, this latter force would be got from nothing, and perpetual motion be obtained. To take another and different example: A piece of zinc dissolved in dilute sulphuric acid giA-es somewhat less heat than when the zinc has a wire of platinum attached to it, and is dissolved by the same quantity of acid. The argument is deduced that, as there is more electricity in the second than in the first case, there should be less heat; but as, according to our received theories, the heat is a product of the electric current, and in consequence of the impurity of zinc electrici- ty is generated in the first case molecularly, in what is called local action, though not thrown into a general direction, there should be more of both heat and electricity in the sec- ond than in the first case, as the heat and electricity due to CONCLUDING REMARKS. 183 the voltaic combination of zinc and platinum are added to that excited on the surface of the zinc, and the zinc should be, as in fact it is, more rapidly dissolved; so that the extra heat and electricity is produced by extra chemical force. Many additional cases of a similar description might be suggested. But although it is difficult, and perhaps impossible, to restrict the action of any one force to the production of one other force, and of one only—yet if the whole of one force, say chemical action, be supposed to be employed in producing its fuU equivalent of another force, say heat, then as this heat is capable in its turn of reproducing chemical action, and in the hmit, a quantity equal or at least only infinitely short of the initial force: if this could at the same time produce indepen- dently another force, say magnetism, Ave could, by adding the magnetism to the total heat, get more than the original chemical action, and thus create force or obtain perpetual motion. The term Correlation, which I selected as the title of my Lectures in 1843, strictly interpreted, means a necessary mutual or reciprocal dependence of two ideas, inseparable c\ren in mental conception: thus, the idea of height cannot exist A\uthout involving the idea of its correlate, depth; the idea of parent cannot exist without involving the idea of off- spring. It has been scarcely, if at aU, used by writers on physics, but there are a vast variety of physical relations to which, if it does not in its strictest original sense apply, cannot certainly be so weU expressed by any other term. There are, for example, many facts, one of which cannot take place without involving the other; one arm of a lever can- not be depressed without the other being elevated—the finger cannot press the table without the table pressing the finger. A body cannot be heated without another being cooled, or some other force being exhausted in an equivalent ratio to the production of heat; a body cannot be positively elec- trified without some other body being negatively electri- fied, &c. 184 CORRELATION OF PHYSICAL FORCES. The probabUity is, that, if not aU, the greater number of physical phenomena are correlative, and that, without a duahty of conception, the mind cannot form an idea of them: thus motion cannot be perceived or probably imagined with- out parallax or relative change of position. The world was believed fixed, until by comparison with the celestial bodies, it was found to change its place with regard to them: had there been no perceptible matter external to the world, we should never have discovered its motion. In sailing along a river, the stationary vessels and objects on the banks seem to move past the observer : if at last he arrives at the convic- tion that he is moving, and not these objects, it is by correct- ing his senses by reflection derived from a more extensive previous use of them: even then he can only form a notion of the motion of the vessel he is in, by its change of position with regard to the objects it passes—that is, provided his body partakes of the motion of the vessel, which it only does when its course is perfectly smooth, otherwise the relative change of position of the different parts of the body and the vessel inform him of its alternating, though not of its pro- gressive movement. So in all physical phenomena, the effecta produced by motion are aU in proportion to the relative mo- tion : thus, whether the rubber of an electrical machine be stationary, and the cyhnder mobUe, or the rubber mobUe and the cylinder stationary, or both mobUe in different directions, or in the same direction with different degrees of velocity, the electrical effects are, cceteris paribus, precisely the same, provided the relative motion is the same, and so, without ex- ception, of aU other phenomena. The question of whether there can be absolute motion, or, indeed, any absolute isolated force, is purely the metaphysical question of ideahsm or real- ism—a question for our purpose of little import; sufficient for the purely phyjical inquirer, the maxim ' de non apparently bus et non existentibus eadem est ratio.' The sense I have attached to the word correlation, in CONCLUDING REMARKS. 185 treating of physical phenomena, wUl, I think, be evident from the previous parts of this essay, to be that of a necessary reciprocal production : in other Avords, that any force capable of producing another may, in it3 turn, be produced by it—• nay, more, can be itself resisted by the force it produces, in proportion to the energy of such production, as action is ever accompanied and resisted by reaction : thus, the action cf an electro-magnetic machine is reacted upon by the magneto- electricity developed by its action. To many, however, of the cases we have been consider- ing, the term correlation may be applied in a more strict accordance with its original sense: thus, Avith regard to the forces of electricity and magnetism in a dynamic state, we cannot electrise a substance Avithout magnetising it—Ave can- not magnetise it Avithout electrising it:—each molecule, the instant it is affected by one of these forces, is affected by the other; but, in transverse directions, the forces are insepara- ble and mutually dependent—correlative, but not identical. The evolution of one force or mode of force into another has induced many to regard all the different natural agencies as reducible to unity, and as resulting from one force wliich is the efficient cause of all the others : thus, one author Avrites to prove that electricity is the cause of every change in matter; another, that chemical action is the cause of every- thing ; another, that heat is the universal cause, and so on. If, as I have stated it, the true expression of the fact is, that each mode of force is capable of producing the others, and that none of them can be produced but by some other as an anterior force, then any view which regards either of them as abstractedly the efficient cause of all the rest, is erroneous; the vieAV has, I believe, arisen from a confusion between the abstract or generalised meaning of the term cause, and ita concrete or special sense ; the Avord itself being indiscrimi- nately used in both these senses. Another confusion of terms has arisen, and has, indeed. 186 CORRELATION OF PHYSICAL FORCES. much embarrassed me in enunciating the propositions put forth in these pages, on account of the imperfection of scien- tific language ; an imperfection in great measure unavoidable, ■ it is true, but not the less embarrassing. Thus, the words light, heat, electricity, and magnetism, are constantly used in two senses—viz. that of the force producing, or the subject- ive idea of force or poAver, and of the effect produced, or the objective phenomenon. The word motion, indeed, is only applied to the effect, and not to the force, and the term chem- ical affinity is generally applied to the force, and not to the effect; but the other four terms are, for want of a distinct terminology, applied indiscriminately to both. I may have occasionally used the same Avord at one time in a subjective, at another in an objective sense; aU I can say is, that this cannot be avoided Avithout a neology, Avhich I have not the presumption to introduce, or the authority to enforce. Again, the use of the term forces in the plural might be objected to by those who do not attach to the term force the notion of a specific agency, but of one universal poAver associated with matter, of which its various phenom- ena are but diversely modified effects. Whether the imponderable agents, vieAved as force, and not as matter, ought to be regarded as distinct forces or aa distinct modes of force, is probably not very material, for, as far as I am aware, the same result Avould follow either view ; I have therefore used the terms indiscriminately, as either happened to be the more expressive for the occasion. Throughout this essay I have placed motion in the same category as the other affections of matter. The course of reasoning adopted in it, hoAvever, appears to me to lead inev- itably to the conclusion that these affections of matter are themselves modes of motion ; that, as in the case of friction, the gross or palpable motion, Avhich is arrested by the con- tact of another body, is subchvided into molecular motions or vibrations, which vibrations are heat or electricity, as the CONCLUDING REMARKS. 187 case may be ; so the other affections are only matter moved or molecularly agitated in certain definite directions. We haA-e already considered the hypothesis that the passage of electricity and magnetism causes vibrations in an ether per- meating the bodies through which the current is transmitted, or the apphcation of the same ethereal hypothesis to these imponderables which had previously been apphed to light; many, in speaking of some of the effects, admit that electri- city and magnetism cause or produce by their passage vibra- tions in the particles of matter, but regard the vibrations produced as an occasional, though not always a necessary, effect of the passage of electricity, or of the increment or decrement of magnetism. The view which I have taken is, that such vibrations, molecular polarisations, or motions of some sort from particle to particle, are themselves electricity or magnetism ; or, to express it in the converse, that dynamic electricity and magnetism are themselves motion, and that permanent magnetism, and Franklinic electricity, are static conditions of force bearing a similar relation to motion which tension or gravitation do. This theory might Avell be discussed in greater detail than has been used in this work ; but to do this and to anti- cipate objections Avould lead into specialities foreign to my present object, in the course of this essay my principal aim having been rather to show the relation of forces as evinced by acknowledged facts, than to enter upon any detailed ex- planation of their specific modes of action. Probably man will never know the ultimate structure of matter or the minutiaj of molecular actions; indeed it is scarcely conceivable that the mind can ever attain to this knoAvledge; the monad irresolvable by a given microscope may be resolved by an increase in poAver. Much harm has already been done by attempting hypotheticaUy to dissect matter and to discuss the shapes, sizes, and numbers of at- oms, and their atmospheres of heat, ether, or electricity. 188 CORRELATION OF PHYSICAL FORCES. Whether the regarding electricity, hght, magnetism, &c., as simply motions of ordinary matter, be or be not admissi- ble, certain it is, that aU past theories have resolved, and aU existing theories do resolve, the actions of these forces into motion. Whether it be that, on account of our familiarity Avith motion, we refer other affections to it, as to a language AA-hich is most easUy construed and most capable of explain- ing them ; whether it be that it is in reahty the only mode in wliich our minds, as contradistinguished from our senses, are able to conceive material agencies; certain it is, that since the period at which the mystic notions of spiritual or preter- natural powers were applied to account for physical phenom- ena, all hypotheses framed to explain them have resolved them into motion. Take, for example, the theories of hght to Avhich I have before aUuded: one of these supposes hght to be a highly rare matter, emitted from—i. e. put in motion by—luminous bodies; a second supposes that the matter is not emitted from luminous bodies, but that it is put into a state of vibration or undulation, i. e. motion, by them; and thirdly, light may be regarded as an undulation or motion of ordinary matter, and propagated by undulation of air, glass, &c, as I have before stated. In aU these hypotheses, matter and motion are the only conceptions. Nor, if we accept terms derived from our own sensations, the which sensations themselves may be but modes of motion in the nervous fila- ments, can we find words to describe phenomena other than those expressive of matter and motion. We in vain struggle to escape from these ideas; if we ever do so, our mental powers must undergo a change of wliich at present we see no prospect. If we apply to any other force the mode of reasoning which we have applied to heat, we shaU arrive at the same conclusion, and see that a given source of power can, sup- posing it to be fully utilised in each case, yield no more by employing it as an exciter of one force than of another. Lei CONCLUDING REMARKS. 189 as take electricity as an example. Suppose a pound of mer- cury at 400° be employed to produce a thermo-electric cur rent, and the latter be in its turn employed to produce me- chanical force ; if this latter force be greater than that a\ hich the direct effect of heat would produce, then it could by com- pression raise the temperature of the mercury itself, or of a simUar quantity equally heated, to a higher point than its original temperature, the 400° to 401°, for example, which is obviously impossible; nor, if we admit force to be inde- structible, can it produce less than 400°, or cool the second body except by some portion of it being converted into another form or mode of force. But as the mechanical effect here is produced through the medium of electricity, and the mechanical effect is definite, so the quantity of electricity producing it must be definite also, for unequal quantities of electricity could only produce an equal mechanical effect by a loss or gain of their oavo force into or out of nothing. The same reasoning will apply to the other forces, and wUl lead, it appears to me, necessa- rhy and inevitably to the conclusion, that each force is defi- nitely and equivalently convertible into any other, and that where experiment does not give the fuU equivalent, it is be- cause the initial force has been dissipated, not lost, by con- version into other unrecognised forces. The equivalent is the Hmit never practicaUy reached. The great problem which remains to be solved, in regard to the correlation of physical forces, is this establishment of their equivalents of power, or their measurable relation to a given standard. The progress made in some of the branches of this inquiry has been already noticed. Viewed in their static relations, or in the conditions requisite for producing equilibrium or quantitative equality of force, a remarkable relation betAveen chemical affinity and heat is that discovered in many simple bodies by Dulong and Petit, and extended to compounds by Neumann and AArogadro. Their researehea 190 CORRELATION OF PHYSICAL FORCK?. have shoAvn that the specific heats of certain substances,, when multiplied by their chemical equivalents, give a con- stant quantity as producti—or, in other Avords, that the com* bining weights of such substances are those weights which require equal accessions or abstractions of heat, equally to raise or loAver their temperature. To put the proposition more in accordance with the view we have taken of the na- ture of heat: each body has a power of communicating or receiving molecular repulsiA-e power, exactly equal, weight for weight, to its chemical or combining power. For in- stance, the equivalent of lead is 104, of zinc 33, or, in round numbers, as 3 to 1 : these numbers are therefore inversely the exponents of their chemical power, three times as much lead as zinc being required to saturate the same quan- tity of an acid or substance combining with it; but their power of communicating or abstracting heat or repulsive power is precisely the same, for three times as much lead as zinc is required to produce the same amount of expansion or contraction in a given quantity of a third substance, such as water. Again, a great number of bodies chemically combine in equal volumes, i. e. in the ratios of their specific gravities; but the specific gravities represent the attractive powers of the substance, or are the numerical exponents of the forces tending to produce motion in masses of matter towards each other; while the chemical equivalents are the exponents of the affinities or tendencies of the molecules of dissimilar sub- stances to combine, and saturate each other; consequently, here we have to some extent an cquiA-alent relation between these two modes of force—gravitation and chemical attrac tion. Were the above relations extended into an universal laAV, Ave should have the same numerical expression for the three forces of heat, gravity, and affinity; and as electricity and magnetism are quantitatively related to them, Ave should have CONCLUDING REMARKS. 191 a simUar expression for these forces : but at present the bod- ies in which this parity of force has been discovered, though in themselves numerous, are small compared with the excep- tions, and, therefore, this point can only be indicated as prom- ising a generalisation, should subsequent researches alter our knoAvledge as to^the elements and combining equivalents of matter. With regard to what may be caUed dynamic equivalents, i. e. the definite relation to time of the action of these varied forces upon equivalents of matter, the difficulty of establish- ing them is stiU greater. K the proposition which I stated at the commencement of this paper be correct, that motion may be subdivided or changed in character, so as to become heat, electricity, &c, it ought to foUow that Avhen we collect the dissipated and changed forces, and reconvert them, the initial motion, minus an infinitesimal quantity affecting the same amount of matter with the same velocity, should be re- produced, and so of the changes in matter produced by the other forces ; but the difficulties of proving the truth of this by experiment avUI, in many cases, be aU but insuperable; Ave cannot imprison motion as Ave can matter, though we may to some extent restrain its. direction. The term perpetual motion, which I haATe not unfrequent- ly employed in these pages, is itself equivocal. If the doc- trines here advanced be founded, aU motion is, in one sense, perpetual. In masses whose motion is stopped by mutual concussion, heat or motion of the particles is generated ; and thus the motion continues, so that if Ave could venture to extend such thoughts to the universe, Ave should assume the same amount of motion affecting the same amount of matter forever. Where force opposes force, as in cases of static equilibrium, the balance of pre-existing equilibrium is affected, and fresh motion is started equivalent to that Avhich is withdraAvn into a state of abeyance. But the term perpetual motion is applied, in ordinary par- 192 CORRELATION OF PHYSICAL FORCES. lance (and in such sense I have used it), to a perpetual recur- rent motion, e.g. a weight which by its faU would turn a wheel, which Avheel would, in its turn, raise the initial weight, and so on forever, or until the material of which the machine is made be Avorn out. It is strange that to common appre- hension the impossibility of this is not self-evident: if the in- itial weight is to be raised by the force it has itself generated, it must necessarUy generate a force greater than that of its own weight or centripetal attraction ; in other words, it must be capable of raising a weight heavier than itself: so that, setting aside the resistance of friction, &c, a weight, to pro- duce perpetual recurrent motion, must be heavier than an equal weight of matter, in short, heavier than itself. Suppose two equal weights at each end of an equi-armed lever, there is no motion ; cut off a fraction of one of them, and it rises wdiile the other faUs. How, now, is the lesser weight to bring back the greater without any extraneous ap- plication of force? If, as is obvious, it cannot do so in this simple form of experiment, it is a fortiori more impossible if machinery be added, for increased resistances have then to be overcome. Can we again mend this by employing any other force? Suppose we employ electricity, the initial weight in descending turns a cyhnder against a cushion, and so generates electricity; to make this force recurrent, the electricity so generated must, in its turn, raise the initial weight, or one heavier than it, i. e. the initial weight must, through the medium of electricity, raise a weight heavier than itself. The same problem, applied to any other forces, will involve the same absurdity: and yet simple as the matter seems, the world is hardly yet disabused of an idea little re- moved from superstition. But the importance of the deductions to be derived from the negation of perpetual motion seems scarcely to have im- pressed philosophers, and we only find here and there a scat- tered hint of the consequences necessarily resulting from that CONCLUDING REMARKS. 193 which to the thinking mind is a conviction. Some of these I have ventured to put forward in the present essay, but many remain, and wiU crowd upon the mind of those who pursue the subject. Does not, for instance, the impossibility of perpetual motion, when thought out, involve the demon- stration of the impossibility, to which I have previously aUud- ed, of any event identicaUy recurring? The pendulum in vacuo, at each beat leaA-es a portion of the force wliich started it in the form of heat at its point of suspension : this force, though ever existent, can never be re- stored in its integrity to the baU of the pendulum, for in the process of restoration it must affect other matter, and alter the condition of the universe. To restore the initial force to its integrity, everything as it existed at the moment of the first beat of the pendulum must be restored in its integrity: but how can this be—for while the force was escaping from the pendulum by radiating heat from the point of suspension, surrounding matter has not stood stiU; the very attraction which caused the beat of the pendulum has changed in degree, for the pendulum is nearer to or further from the sun, or from some planet or fixed star. It might be an interesting and not profitless speculation to foUow out these and other consequences ; it would, I be- lieve, lead us to the conviction that the universe is ever changing, and that notwithstanding secular recurrences which would prima, facie seem to replace matter in its original posi- tion, nothing in fact ever returns or can return to a state of existence identical with a previous state. But the field is too illimitable for me to venture further. The inevitable dissipation or throwing off a portion of the initial force presents a great experimental difficulty in the way of estabhshing the equivalents of the various natural forces. In the steam-engine, for instance, the heat of the furnace not only expands the water and thereby produces the motion of the piston, but it also expands the iron of the boil- 9 194 CORRELATION OF PHYSICAL FORCES. er, of the cylinder and all surrounding bodies. The force ex- pended in expanding this iron to a very small extent is equal to that which expands the vapour to a very large extent: this expansion of the iron is capable, in its turn, of producing a great mechanical force, Avhich is practically lost. Could aU the force be applied to the vapour, an enormous addition of power Avould be gained for the same expenditure : and per- haps even with our present means more might be done in utilising the expansion of the iron. Another great difficulty in experimentally ascertaining the dynamic equivalents of different forces arises from the effects of disruption, or the overcoming an existing force. Thus, Avhen a part of the initial force employed is engaged in tAvist- ing or tearing asunder matter previously held together by cohesive attraction, or in overcoming gravitation or inertia, the same amount of heat or electricity would not be CA*olved as if such obstacle were non-existent, and the initial force were wholly employed in producing, not in opposing. There is a difficulty apparently extreme in devising experiments in which some portion of the force is not so employed. The initial force, however, that has been employed for such disruption is not lost, as at the moment of disruption the bodies producing it fly off, and carry with them their force. Thus, let two weights be attached to a cord placed across a bar; when their force is sufficient to break the cord or the bar, the weights fall down and strike the earth, making it vibrate, and so conveying away or continuing the force ex- pressed by the cohesion of the bar or cord. If, instead of breaking a cord, the Aveiglits be employed to bend a bar, their gravitating force, instead of making the earth vibrate, pro- duces heat in the bar, and so Avith Avhatever other force be employed to produce effects of disruption, torsion, &c, so that, though difficult in practice, the numerical problem of the equivalent of the force is not theoreticaUy irresolvable The voltaic battery affords us the best means of ascertain- CONCLUDING REMARKS. 195 ing the dynamic equivalents of different forces, and it is probable that by its aid the best theoretical and practical results AviUbe ultimately attained. In investigating the relation of the different forces,! have in turn taken each one as the initial force or starting-point, and endeavoured to shoAV hoAv the force thus arbitrarily se- lected could mediately or immediately produce and be merged into the others : but it AviU be obvious to those who have at- tentively considered the subject, and brought their minds into a general accordance with the views I have submitted to them, that no force can, strictly speaking, be initial, as there must be some anterior force Avhich produced it: Ave cannot create force or motion any more than we can create matter. Thus, to take an example previously noticed, and recede backwards; the spark of light is produced by electricity, electricity by motion, and motion is produced by something else, say a steam-engine—that is, by heat. This heat is pro- duced by chemical affinity, i.e. the affinity of the carbon of the coal for the oxygen of the air: this carbon and this oxy- gen haAre been previously eliminated by actions difficult to trace, but of the pre-existence of Avhich we cannot doubt. and in which actions we should find the conjoint and al- ternating effects of heat, light, chemical affinity, &c. Thus, tracing any force backAvards to its antecedents, Ave are merged in an infinity of changing forms of force ; at some point we lose it, not because it has been in fact created at any definite point, but because it resolves itself into so many contributing forces, that the evidence of it is lost to our senses or powers of detection ; just as in foUowing it forAvard into the effect it produces, it becomes, as I have before stated, so subdivided and dissipated as to be equally lost to our means of detection. Can avc, indeed, suggest a proposition, definitely conceiv- able by the mind, of force without antecedent force? I can- not, without calling for the interposition of created poAver, any more than I can conceive the sudden appearance of a 196 CORRELATION OF PHYSICAL FORCES. mass of matter come from nowhere, and formed from noth- ing. The impossibility, humanly speaking, of creating or annihilating matter, has long been admitted, though, perhaps, its distinct reception in philosophy may be set down to the overthroAV of the doctrine of Phlogiston, and the reformation of chemistry at the time of Lavoisier. The reasons for the admission of a similar doctrine as to force appear to be equally strong. With regard to matter, there are many cases in Avhich we never practically prove its cessation of existence, yet we do not the less believe in it: who, for instance, can trace, so as to rc-wTeigh, the particles of iron Avorn off the tire of a carriage wheel? Avho can re-combine the parti- cles of wax dissipated and chemically changed in the burning of a candle? By placing matter undergoing physical or chemical changes under special limiting circumstances, we may, indeed, acquire evidence of its continued existence, weight for weight—and so Ave may in some instances of force, as in definite electrolysis : indeed the evidence we acquire of the continued existence of matter is by the continued exertion of the force it exercises, as, when Ave weigh it, our evidence is the force of attraction; so, again, our evidence of force is the matter it acts upon. Thus, matter and force are corre- lates, in the strictest sense of the word; the conception of the existence of the one involves the conception of the exis- tence of the other: the quantity of matter again, and the de- gree of force, involve conceptions of space and time. But to foUoAV out these abstract relations would lead me too far into the aUuring paths of metaphysical speculation. That the theoretical portions of this essay are open to ob- jection I am fully conscious. I cannot, hoAvever, but think that the fair way to test a theory is to compare it with other theories, and to see whether upon the whole the balance of probability is in its favour. Were a theory open to no ob- jection it would cease to be a theory, and becc me a law; and were we not to theorise, or to take generalised views of CONCLUDING REMARKS. 197 natural phenomena untU those generalizations Avere sure and unobjectionable—in other Avords, were laAvs—science would be lost in a complex mass of unconnected observations, which Avould probably never disentangle themselves. Excess on either side is to be avoided; although Ave may often err on the side of hasty generahsation, we may equaUy err on the side of mere elaborate collection of observations, which, though sometimes leading to a valuable result, yet, when cu- mulated without a connecting link, frequently occasion a cost- ly waste of time, and leave the subject to which they refer in greater obscurity than that in which it Avas involved at their commencement. Collections of facts differ in importance, as do theories: the former, in many instances, derive their value from their capability of generalisation ; Avhile, conversely, theories are valuable as methods of co-ordinating given series of facts, and more valuable in proportion as they require feAver excep- tions and fewer postulates. Facts may sometimes be as well explained by one view as by another, but without a theory they are unintelligible and incommunicable. Let us use our utmost effort to communicate a fact without using the language of theory, and we faU; theory is involved in all our expressions ; the knoAvledge of bygone times is imported into succeeding times by terms involving theoretic conceptions. As the knowledge of any particular science developes itself our views of it become more simple ; hypotheses, or the in- troduction of supposititious views, are more and more dis- pensed with ; Avords become apphcable more directly to the phenomena, and, losing the hypothetic meaning which they necessarily possessed at their reception, acquire a secondary sense, which brings more immediately to our minds the facts of Avhich they are indices. The scaffolding has served its purpose. The hypothesis fades aAA-ay, and a theory, or gen- eralised view of phenomena, more independent of supposition, but stiU fuU of gaps and difficulties, takes its place. This in 198 CORRELATION OF PHYSICAL FORCES. its turn, should the science continue to progress, either gives place toamore simple and wider generalisation, or becomes, by the re- moval of objections, estabhshed as a law. Even in this move advanced stage, words importing theory must be used, but phenomena are now intelligible and connected, though express- ed by \-aried forms of speech. To think on nature is to theorise ; and difficult it is not to be led on by the continuities of natural phenomena to the- ories Avhich appear forced and uninteUigible to those who have not pursued the same path of thought: Avhich, more- over, if allowed to gain an undue influence, seduce us from that truth wliich is the sole object of our pursuit. Where to draw the hne—where to say thus far we may go, and no farther, in any particular class of analogies or re- lations which Nature presents to us ; how far to foUow the progressive indications of thought, and where to resist its al- lurements—is a question of degree which must depend upon the judgment of each individual or of each class of thinkers; yet it is consolatory that thought is seldom expended in vain. I have throughout endeavoured to discard the hypotheses of subtle or occult entities; if in this endeavour some of my vieAvs have been adopted upon insufficient data, I stUl hope that this essay wUl not prove valueless. The conviction that the so-called imponderables are modes of motion, wUl, at aU events, lead the observer of natural phenomena to look for changes in these affections, wherever the intimate structure of matter is changed; and, conversely, to seek for changes in matter, either temporary or permanent, whenever it is affected by these forces. I beheve he will seldom do this in vain. It was not until I had long reflected on the subject, that I ventured to publish my vieAArs: their pubheation may induce others to think on their subject-mat- ter. They are not put forward with the same objects, nor do they aim at the same elaboration of detail, as memoirs on aeAvly-discovered physical facts : they purport to be a method CONCLUDING REMARKS. 199 of mentally regarding known facts, some few of which I have myself made known on other occasions, but the great ma3s of which have been accumulated by the labours of others, and are admitted as estabhshed truth.-. Every one has a right to view these facts through any medium he thinks fit to em- ploy, but some theory must exist in the minds of those Avho reflect upon the many new phenomena Avhich have recently, and more particularly during the present century, been dis- covered. It is by a generalised or connected view of past acquisitions in natural knoAvledge that deductions can best be drawn as to the probable character of the results to be antici- pated. It is a great assistance in such investigations to be intimately convinced that no physical phenomena can stand alone: each is inc\itably connected with anterior changes, and as ineA'itably productive of consequential changes, each Avith the other, and all with time and space; and, cither in tracing back these antecedents or folloAving up their conse- quents, many new phenomena AviU be discovered, and many existing phenomena, hitherto believed distinct, Avill be connected and explained: explanation is, indeed, only re- lation to something more familiar, not more known—i.e. known as to causative or creative agencies. In aU pheno- mena the more closely they are investigated the more are we convinced that, humanly speaking, neither matter nor force can be created or annihUated, and that an essential cause is unattainable.—Causation is the will, Creation the act, of God. NOTES AND REFERENCES. -------»♦•------- PAGE 13. The reader who is curious as to the views of the ancients, regarding the objects of science, will find clues to them in the second book of Aristotle's Physics, and in the first three books of the Metaphy- sics. See also the Timaeus of Plato, and Ritter's History of Ancient Philosophy, where a sketch of the Philosophy of Leucipfus and Democritus will be found. 14. Bacon's Novum Organum, book ii. aph. 5 and 6. 16 Hume's Enquiry concerning Human Understanding, S. 7, London, 1768. Brown's Enquiry into the Eelations of Cause and Effect, London, 1835. The illustration I have used of floodgate has been objected to, as being one to which the term cause would scarcely be applied, but after some consideration I have retained it: if cause be viewed only as sequence, it must be limited to sequence under given condi- tions or circumstances, and here, given the conditions, the sequence is invariable. I see no difference quoad the argument, between this illustration and that of Brown of a lighted match and gun- powder (4th edit. p. 27), to which my reasoning would equally well apply. Herschel's Discourse on the Study of Natural Philosophy, pp. 88 and 149. 17. Quarterly Review, vol. lxviii. p. 212. Whewell, On the Question ' Are Cause and Effect Successive or Simultaneous? (Cambridge Philosophical Transactions, vol. vii. p. 319.) L8. Herschel's Discourse, p. 93. Ampere, Theorie des Phenomenes Electro-dynamiques, Memoirs in NOTES AND REFERENCES. 201 PAGE the Ann. de Chimic et de Physique, and works from 1820 to 1826 Paris. 23. Lamarck, ' Sur la Matiere du Son' (Journal de Physique, vol. xlix. p. 397). 25. D'Alembert, Traite de Dynamique, pp. 3 and 4, Paris, 1796. 28. Babbage, On the Permanent Impression of our Words and Actions ok the Globe we inhabit, 9th Bridgewater Treatise, ch. ix. 30. Mater, Annalen der Pharmacie Leibig und Wohler, May 1852. 33. Joule on the Mechanical Equivalent of Heat (Phil. Trans. 1850, p. 61.) 33. Erman, Influence of Friction upon Thermo-electricity (Reports of the British Association, 1845.) 85. Becquerel, Tegagement de l'Elcctricite* par Frottement, Traite* de l'Electricit6, torn. ii. p. 113 etseq. 36. Sullivan, Currents produced by the vibration of metals (Archiv. de rElectricite1, t. 10, p. 480). Leroux, Vibrations arrested produce heat (Cosmos, March 30, 1860). 87. Wheatstone on the Prismatic Decomposition of Electrical Light (Notices of Communications to the British Association, p. 11. 1835). 89 Bacon, De Forma Calidi, Nov. Org. book 2, aph. 20. Rumford, An Enquiry concerning the Source of Heat which is excited by Friction (Phil. Trans, p. 80, 1798). Davt, On the Conversion of Ice into Water by Friction (West of England Contributions, p. 16). Of Heat or Calorific Repulsion (Elements of Chemical Philosophy, p. 69). 41 Baden Powell on the Repulsive Power of Heat (Phil. Trans. 1834, p. 485). Fresnel, Annales de Chimie, torn. xxix. pp. 57 and 107. 42 Moser on Invisible Light (Taylor's Scientific Memoirs, vol. iii. pp. 461 and 465). 43 Black on Latent neat (Elements of Chemistry, p. 144 et passim, 1803). 45 The experiments of Henry and Donnt have shown that the cohesion of liquids, as far as their antagonism to rupture goes, is much greater than has been generally believed. These experiments, however, make no difference in the A-iew I have put forth, as, what- ever be the character of the attraction, there is a molecular attrac- tion to be overcome in changing bodies from the solid to the liquid state, which must require and exhaust force. 202 NOTES AND REFERENCES. Doxny, Sur la Cohdsion des Liquidcs (Memoires de l'Acadeinie Roy- ale de Bruxelles, 1843). Henry, Proceedings of the American Philosophical Society, April 1844 (Silliman's Journal, vol. xlviiii. p. 215). 48. Thilorier, Solidification de l'Acide carboniquc (Ann. de Ch. et de Phys. torn. Ix. p. 432). 60. I. Wedgwood, Thermometer for measuring the Higher Degrees of Heat (Phil. Trans. 1782, p. 305 ; and 1785, p. 390. Tyndall, on the physical properties of Ice (Phil. Trans. 1858, p. 211). Despretz, Recherches sur le Maximum de Densit6 de l'Eau pure ct des Dissolutions aqueuses (Ann. de. Ch. et de Ph. torn. Ixx. p. 45, and torn. Ixxiii. p. 295). 51. Biot (Comptes rendus de l'Academic des Sciences, Paris 1850, p. 281). The experiments on circular polarisation by water were, I believe, by Dr. Leeson. 52. I. Thompson, Trans. R. S. Edin. vol. xvi. p. 575. W. Thompson, Phil. Mag. August 1850, p. 123. Bunsen, Pogg. Ann. vol. Ixxxi. p. 562; Ann. de Ch. ct de Phys. vol. xxxv. p. 383. Effects of Pressure on the Freezing Point. 53. Joule, Phil. Trans. 1852, p. 99. Although, taking the phenomena as they are known to exist, the mechanical laws may be deduced, yet in any physical conception of the nature of heat the expansion by cold has always been a great stumbling-block to me, and I believe to many others. Dulong and Petit, and Regnault. See their Memoirs abstracted and referred to in Gmelin's Handbook of Chemistry, translated by Watts for the Cavendish Society, vol. i. p. 242 et seq. 54. Wood, Phil. Mag. 1851, 1852. 66. Senarmont, Conduction of Heat by Crystals (Gmelin's Handbook vol. i. p. 222). 56. Knoblauch, Ann. de Ch. et de Ph. vol. xxxvi. p. 124. Tyndall, Transmission of Heat through Organic Structures (Phil. Trans, vol. cxliii. p. 217). 58. Grove, Electricity produced by approximating Metals: Report of a Lecture at the London Institution (Literary Gazette, 1843, p. 39). Gassiot, Phil. Mag. October 1844. Roget, On the Improbability of the Contact exciting Force: Trcatiss on Galvanism (Library of Useful Knowledge, S. 113). Faraday, Phil. Trans. 1840, p. 126. NOTES AND REFERENCES. 203 PAGB 60. Melloni, Sur la Polarisation de la Chaleur: Recherches sur plusieurs Ph6nomenes calorifiques (Annales de Chimie et de Ph. torn, xlv pp. 5—68 ; torn. xli. pp. 375-410; torn, xlviii. pp. 198, 218). Forbes, On the Refraction and Polarisation of Heat (Transactions of the Royal Society of Edinburgh, vol. xiii. pp. 131, 168). 61. Kirchoff Trans. Belin Acad. 1861. Balfour Stewart on the theory of Exchanges (Report British Asso- ciation, 1861). 63. T. Wedgwood, On the Production of Light and Heat by different Bodies (Phil. Trans, vol. lxxxii. p. 272). 65. Grove, On the Decomposition of Water into its Constituent Gases bj Heat (Phil. Trans. 1847, p. 1). Robinson, On the Effect of Heat in lessening the Affinities of the Elements of Water (Transactions of it e Royal Irish Academy, vol xxi. p. 2). 07. Grove, Water decomposed by Chlorine find Heat (Phil. Trans. 1847, p. 20). 70. Carnot, Reflexions sur la Puissance motrice du Feu, Paris, 182-1. 76 Seguin, Influence des Chemins de Fer, p. 378 et seq. 77 Rogers, Consumption of Coal for Man power (Cosmos, vol. ii. p. 56). 80 Mr. Waterston has suggested that solar heat may arise from the mechanical action of meteoric stones falling into the sun, and Mr. Thompson has written an elaborate paper on the subject (Trans. Brit. Assoc. 1853). If a number of gravitating, bodies exist in the neighbourhood of the sun, and form, as is conjectured, the zodia- cal light, it is difficult to conceive how comets as they approach this region steer clear of such bodies, and are not even deflected from their orbits. For Mr. Thompson's various and valuable papers, see Phil. Mag. 1851 to 1854 inclusive. dl Poisson, Comptes rendus, Paris, January 30, 1837. 63 Dufaye, Symmer, Watson, and Franklin, Theories of Electric Fluid and Electric Fluids (Priestley's History of Electricity, pp. 429— 441). 83 Grotthus, Sur la Decomposition de l'Eau et des Corps qu'elle tient en dissolution a aide de l'Electricitd galvanique (Ann. de Chimie, torn, lviii. p. 54). Faraday, On the Question whether Electrolytes conduct without Decomposition (Proceedings of the Weekly Meetings of the Royal Institution, 1855). Grove (Comptes rendus, Paris, 1839). 204 NOTES AND REFERENCES. 84. Faraday, On Induction as an Action of contiguous Particles (Phil. Trans. 1838, p. 30). 85. Matteucci, Plates of Mica polarised by Electricity (De la Rive's Electricity, p. 140). Grove, Electrolysis across Glass (Phil. Mag. Aug. 1860). 85. Karsten on Electrical Figures (Archiv. de l'Elec. vols. ii. iii. and iv). 87. Grove, Etching Electrical Figures and transferring them to Collo- dion (Phil. Mag. January 1857). 88. Fusinieri, Du Transport des Matieres ponderable qui s'opere dans les Decharges electriques (Archives de l'Electricite ; Supplement k la Bibliotheque universelle de Geneve, torn. iii. p. 597). 88. Grove, On the Voltaic Arc (Report of Lecture at the Royal Insti- tution, Lit. Gaz. and Athenaeum, Feb. 7, 1845; Phil. Trans. 1847, p. 16). 90 to 94. Grove, On the Electro-chemical Polarity of Gases (Phil. Trans. 1852, p. 87). 94. Fremy and E. Becquerel, Oxygen changed to Ozone by the Electric Spark (Ann. de Ch. et de Phys. 1852). This subject and the na- ture of Ozone was first investigated by Dr. Schonbein. See also a paper by Mr. Brodie On the Conditions of certain Elements at the Moment of Chemical Change (Phil. Trans. 1850). 95, 96. Molecular Changes in Electrised Metals (Nairne, Phil. Trans. 1780, p. 334, and 1793, p. 223; Grove, Electrical Mag. vol. i. p. 120; Peltier, Archives de l'Electricite, vol. v. p. 182 ; Fusinieri, id. p. 516). 96. Wertheim, Change in Elasticity of Metals by Electrisation (Ann. de Ch. et de Phys. voL xii. p. 623 ; Arch. Elec. vol. iv. p. 490). Dufour, Alteration in Tenacity of Metals by Electrisation (Bibl. univ. de Geneve, Fev. 1855, p. 156). 97. Matteucci, Conduction of Electricity by Crystals (Comptes rendus de l'Acad., Paris, March, 5, 1855, p. 541). 98. E. Becquerel, Transmission of Electricity by heated Gases (Ann. de. Ch. et de Phys. vol. xxxix. p. 355). Grove, Proceedings of the Royal Inst. (1854, p. 361). Becquerel, Divergence of Gold-Leaves in Vacuo (Traite d'Electricite, vol. v.; part ii. p. 53). Newton, Thirty-first Query to the Optics. 99. Grove, Particles of Metals and Metallic Oxids detached in Liquids by Electricity (Elec. Mag. vol. i. p. 119). 100. Matteucci, Relations of Electricity and Nervous Force (Phil. Trans, NOTES AND REFERENCES. 205 1845, p. 285, 1846, p. 497; Phenomenes physiques des Corp* vivants, p. 305 ; Lezioni di Fisica, p. 360). Galvani Volta Marianini et Xobili on Physiological Effects of Electricity (Ann. de Ch. et de Phys. vols. 23, 25, 29, 38, 40, 43, 44, 66). 102. Becquerel, Chemical Changes by Friction (Traite de l'Elec. vol. v. part 1, p. 16). 106. De la Rive, Heat of the Voltaic Pile (Bibl. univ., vol. xiii. p. 389). Davy, On the Properties of Electrified Bodies in their relations to Conducting Powers and Temperature (Phil. Trans. 1821, p. 428). 106. Grove, On the Effects of surrounding Media on Voltaic Ignition (Phil. Trans. 1849, p. 49). 107. Oersted, Experience sur 1'Effet du Conflict 61ectrique sur l'Aiguille aimant6e (Ann. de Ch. et de Phys., torn. xiv. p. 417). 108. Coleridge, Table Talk, vol. i. p. 65. 109. Lenz and Jacobi, Pogg. Ann. vol. xvlii. p. 403 ; Bulletin de l'Acad. St. Petersburg, 1839 ; Harris, Magnetism, part 2, p. 63. Davy, Decomposition of the fixed Alkalies (Phil. Trans. 1808, p. 1). Becquerel Des Composes electro-chimiques (Trait6 de l'Electricite, vol. iii. c. 13). Crosse, Transactions of the British Association, vol. v. p. 47 ; Pro- ceedings of the Electrical Society, p. 320. 110. Malus, Polarisation of Light by. Reflection (Memoires d'Arcueil, torn. ii. p. 143). Arago, Circular Polarisation by Solids (Memoires de l'Institut, 1811). 111. Biot, Circular Polarisation by Liquids (Memoires de l'Institut, 1817). 111. Niepce and Daguerre, Historique et Description des Proc6des du Daguerrdotype, Paris, 1839. Talbot, Photogenic Drawing and Calotype (Phil. Mag. March. 1839, and August 1841). 113. Herschel, Chemical Action of the Solar Spectrum on various Sub- stances (Phil. Trans. 1840, p. i. and 1842, p. 181). Hunt, Researches on Light, London, 1844. 116. Grove, Other Forces produced by Light (Lit. Gaz. January 1844). 117. Grove, Influence of Light on the Polarised Electrode (Phil. Mag. December 1858). Somerville (Mrs.), On the Magnetising Power of the more Refrangi- ble Solar Rays (Phil. Trans. 1862, p. 132). MohiCHiNi's experiments are given in Mrs. Somerville's paper. 118. Herschel, On the Absorption of Light in Coloured Media viewed 206 NOTES AND REFERENCES. in connection with the Undulatory Theory (Phil. Mag. Decern ber 1863). Seebeck, Heat of Coloured Rays (Brewster's Optics, p. 90). 118. Knoblauch (Ann. de Ch. vol. xxxvi. p. 124, and Pogg. Ann. there referred to). 119. Herschel, Epipolised Light (Phil. Trans, vol. exxxv. pp. 143, 147). Stokes, Change in Refrangibility of Light (Phil. Trans, vols, cxlii. cxliii.) 123. For the first enunciations of the Corpuscular and Undulatory Theories, see Inewton's Optics, Hooke's Micographia, and Huyghens' Trac- tatus de Lumine. See also Brewster's Optics, p. 138. 124. Young, Lectures edited by Kelland, p. 358, et seq.; Phil. Trans. 1800, p. 126; Herschel, Encyc. Metro, art. Light, pp. 450 and 738 ; Newton's Optics, p. 322; Whewell's Hist. Indue. Sc. vol. ii. p. 449 ; Foucault, Comptes rendus, Paris, 1850, p. 65 ; Harri- son, Phil. Mag. November 1856 ; Camb. Phil. Trans. 126. Sondhauss, Refraction of Sound (Ann. de Ch. et de Phys. vol. xxxv. p. 505); Dov£, Polarisation of Sound (Cosmos, May 13, 1859). 132. Pasteur, Rotation of Plane of Polarised Light by Solutions of Hemihedral Crystals (Ann. de Ch. et de Phys. vol. xxiv. p. 442). 134 to 135. Wollaston, Phil. Trans. 1822, p. 89; Whewell, Phil, of the Induct. Sc. vol. i. p. 419 ; Wilson, Trans, of the Roy. Soc. of Edin. vol. xvi. p. 79 ; Sir W. Herschel, Phil. Trans. 1793, p. 201, and 1801, p. 300; Morgan, Phil. Trans, vol. lxxv. p. 272 ; Davy, Phil. Trans. 1822, p. 64; Elements of Chemical Philosophy, p. 97 ; Gassiot, Phil. Trans. 1859, p. 157. 137. Diminishing Periods of Comets (Herschel's Outlines of Astronomy, p. 357). 140. Since writing the passage in the text, I find that Struve has been led, from his astronomical researches, to the conclusion that some light is lost in the interplanetary spaces. He gives as an approxi- mation one per cent, as lost by the passage of light from a star of the first magnitude, assuming a mean or average distance (Etudes d'Astronomie Stellaire, 1847). Newton, Thirtieth Query to the Optics. 142. Faraday, Evolution of Electricity from Magnetism (Phil. Trans. 1832, p. 125). 144. Faraday, Magnetic Condition of all Matter (Phil. Trans. 1846, p. 21; PhiL Mag. 1846, p. 249). Becquerel, Ann. de Ch. et de Ph. 'torn, xxxvi. p. 337; Comptes rendus, Paris, 1846, p. 147; and 1850, p. 201. NOTES AND REFERENCES. 207 PAGE 145. Faraday, On the Magnetism of Light (Phil. Trans. 1846, p. 1). 145. Wartmann, Rotation of the Plane of Polarisation of Heat by Magnet- ism (Journal de l'lnstltute, No. 644). Provostaye and Dessaines, Ann. de Ch. et de Phys. October 1849. 146. Hunt, Influence of Magnetism on Molecular Arrangement (Phil. Mag 1846, vol. xxviii. p. 1; Memoirs of the Geological Society, vol. i p. 433). Wartmann, Phil. Mag. 1847, vol. xxx. p. 263. 147, Grove, Experiment on Molecular Motion of a Magnetic Substance (Electrical Mag. 1845, vol. i. p. 601). 147. On the direct Production of Heat by Magnetism (Proceedings of the Royal Society, 1849, p. 826). After this paper was communicated and ordered to be printed in the Philosophical Transactions, I found that I had been anticipated by Mr. Van Breda, who communicated, in 1845, a paper to the Insti- tut on the subject: his paper appears in the Comptes rendus under an erroneous title, which accounts for its having been overlooked : he does not give thermometric measures of the heat he obtained, nor did he produce heating effects by a permanent steel magnet, or with other metals than iron. (Comptes rendus, October 27, 1845). See also an earlier experiment by Mr. Joule (Phil. Mag. 1843), to which he called my attention after my paper was read. 148, 151. The Experiments on the effects of Magnetism on the Matter magnetised, are collected by Mr. De la Rive in his recently-pub- lished Treatise on Electricity, vol. i. 1C3. Davy, Electricity defined as Chemical affinity acting on Masses (Phil. Trans. 1826, p. 389). Yolta, Electricity excited by the mere Contact of conducting Sub- stances (Phil. Trans. 1800, p. 403). 154. Grove, Gold-Leaf Experiment (Comptes rendus, Paris, 1839, p. 567). 155. Grove, Voltaic Action of Sulphur, Phosphorus, and Hydrocarbons (Phil. Trans. 1845, p. 351). Grove, New Voltaic Combination (Phil. Mag. vol. xiv. p. 388 ; vcj. xv. p. 287). lo5. Grove, Electricity of Blowpipe Flame (Proceedings of the Royal Institution, February 1854), Phil. Mag. 157 Dalton, New System of Chemistry, London, 1810. 158. I have here and elsewhere used whole numbers, a3 sufficiently approxi- mate for the argument, but without intending to express any opin- ion as to the law of P,rout. 158. Faraday, Definite Electrolysis (Phil. Trans. 1834, p. 77). 208 NOTES A1TD REFERENCES. PAGE 160. Wood, Heat disengaged in Chemical Combinations (Phil. Mag. 1852) 162. Andrews, Phil. Trans. 1844, p. 21. Hess, Poggendoff's Annalen, Bd. Iii. p. 197. 163. Favre, Ann. de Ch. et de Phys. vols. 39, 40 ; Comptes rendus, Paris, vol. 45, p. 66, and vol. 46, p. 337. 169. Catalysis by Platinum (Dobereimer, Ann. de Ch. et de Phys. torn xxiv. p. 93 ; Dulong and Thenard, Ann. de Ch. et de Phys. torn. xxiii. p. 440). 170. Grove, Gas Voltaic Battery (Phil. Mag. February 1839, and Decem- ber 1842; Phil. Trans. 1843, p. 91). 171. Mosotti, Forces which regulate the Internal Constitution of Bodies (Taylor's Scientific Memoirs, vol. i. p. 448). 172. Plucker, Repulsion of the Optic Axes of Crystals by the Poles of a Magnet (Taylor's Scientific Memoirs, vol. v. p. 353). Magnetic Action of Cyanite (Lit. Gaz. 1849, p. 431). 172. Matteucci, Correlation of Electric Current and Nervous Force (Phil. Trans. 1850, p. 287). 173. Carpenter, On the Mutual Relations of the Vital and Physical Forces (Phil. Trans. 1850, p. 751). 174. On Effort. See Brown, Cause and Effect; Herschel's Discourse ; and Quarterly Review, June 1841. 175. Helmholtz, Muller's Archives, 1845 ; Matteucci, Comptes rendus, Paris, 1856 ; Beclard, Archives de Medicine, 1861. 189. Dulong and Petit, Relation between Specific Heat and Chemical Equivalents (Ann. de Ch. et de Phys. torn. x. p. 395). 189. Neumann, Poggendorff's Annalen, Bd. xxiii. p. 1. Avogadro, Ann. de Ch. et de Phys. torn. Iv. p. 80. ON THE INTERACTION OF. NATURAL FORCES. By Peof. IT. L. F. HELMHOLTZ. Translated by JOHN TYNDALL, F.R.S. Herman Ludwig Ferdinand Helmholtz was bom at Pottsdam, August 31, 1821. He was first military physician, and afterwards assistant of the Astronomical Museum in Berlin (1848), and subsequently Professor Extra- ordinary of Physiology at the University of Konigsberg (1849 to 1852). He Decame Professor of Physiology at the University of Bonn in 1855, and in 1858 accepted the physiological chair in the University of Heidelberg. Tho lecture which follows was delivered at Konigsberg in 1854. He is an emi- nent investigator, and an able promoter of the recent philosophy of forces; but of his life we have fewer particulars than of his accomplished translator. The ancestors of John Tyndall emigrated from England to the eastern or Saxon border of Ireland about the middle of the last century. He was born at the village of Leighlin Bridge in 1820, where he received his early education and acquired a taste for mathematics. In 1839 he left school and joined the Ordnance Survey as a civil assistant, where he became in turn draughtsman, computer, surveyor, and trigometrical observer. He was five years connected with the survey, and for three years occupied as rail- road engineer. In 1847 he became teacher in Queenswood College in Hamp- shire, a school for agriculturists and engineers, where he was distinguished for his mild but efficient discipline. Professor Frankland, the chemist, was here joined with him in the work of instruction, and in 1848 the two friends left the institution and went to the University of Marburg in Hesse Cassel, to study with the eminent chemist, Bunsen. In 1851 Professor Tyndall went to Berlin and worked at the subject of diamagnetism in the laboratory of Professor Magnus. He returned to London the same year, and was elected Fellow of the Royal Society in 1852. Through the influence of Dr. Bence Jones, General Sabine, and Professor Faraday, he was appointed Professor of Natural Philosophy in the Royal Institution in 1853, an appointment which he now holds. In company with his friend, Professor Huxley, he visited the Alps in 1856 ; and returning each succeeding year, he accumulated the observations and adventures which are so graphically described in his "Glaciers of the Alps," published in 1860. Professor Tyndall has worked with eminent success at various scientific questions, but he is chiefly distinguished for his original and elaborate re- searches on the relations of radiant heat to gaseous and vaporous matter. These researches are given in his able work on " Heat as a mode of Motion," issued in 1863. As an experimenter, Professor Tyndall is marked for his caution, accuracy, and tireless perseverance under difficulties ; as a writer, for his clear, vivid, and vigorous style. [NTERACTION OF NATURAL FORCES. ANEW conquest of very general interest has been recently made by natural philosophy. In the following pages, I will endeavour to give a notion of the nature of this conquest. It has reference to a new and universal natural law, which rules the action of natural forces in their mutual relations towards each other, and is as influential on our theoretic views of natural processes as it is important in their technical applications. Among the practical arts wliich owe their progress to the development of the natural sciences, from the conclusion of the middle ages downwards, practical mechanics, aided by the mathematical science which bears the same name, was one of the most prominent. The character of the art was, at the time referred to, naturally very different from its present one. Surprised and stimulated by its own success, it thought no problem beyond its power, and immediately attached some of the most difficult and complicated. Thus it was attempted to build automaton figures which should perform the functions of men and animals. The wonder of the last century was Vaucanson's duck, which fed and digested its food; the flute- player of the same artist, which moved all its fingers cor- 212 INTERACTION OF NATURAL FORCES. rectly ; the writing boy of the older, and the piano-forte play- er of the younger Droz : which latter, when performing, fol- lowed its hands with his eyes, and at the conclusion of the piece bowed courteously to the audience. That men like those mentioned, whose talent might bear comparison with the most inventive heads of the present age, should spend so much time in the construction of these figures, which we at present regard as the merest trifles, would be incomprehensi- ble, if they had not hoped in solemn earnest to solve a great problem. The writing boy of the elder Droz was publicly exhibited in Germany some years ago. Its wheel-work is so complicated, that no ordinary head would be sufficient to decipher its manner of action. When, however, we are in- formed that this boy and its constructor, being suspected of the black art, lay for a time in the Spanish Inquisition, and with difficulty obtained their freedom, we may infer that in those days even such a toy appeared great enough to excite doubts as to its natural origin. And though these artists may not have hoped to breathe into the creature of their ingenuity a soul gifted with moral completeness, still there were many who would be willing to dispense with the moral qualities of their servants, if, at the same time, their immoral qualities could also be got rid of; and accept, instead of the mutability of flesh and bones, services which should combine the regu- larity of a machine with the durability of brass and steel. The object, therefore, which the inventive genius of the past century placed before it with the fullest earnestness, and not as a piece of amusement merely, was boldly chosen, and was followed up Avith an expenditure of sagacity which has contri- buted not a little to enrich the mechanical experience which a later time knew how to take advantage of. We no longer seek to build machines which shall fulfil the thousand services required of one man, but desire, on the contrary, that a ma- chine shall perform one service, but shall occupy in doing it the place of a thousand men. 4T TnE OLD MECHANICAL PROBLEM. 213 From these efforts to imitate living creatures, another idea, also by a misunderstanding, seems to have developed itself, which, as it were, formed the new philosopher's stone of the seventeenth and eighteenth centuries. It was now the endeav- our to construct a perpetual motion. Under this term was un- derstood a machine, wliich, without being wound up, without consuming in the working of it, falling water, wind, or any other natural force, should still continue in motion, the motive power being perpetually supplied by the machine itself. Beasts and human beings seemed to correspond to the idea of such an apparatus, for they moved themselves energetically and inces- santly as long as they lived, were never wound up, and nobody set them in motion. A connection between the taking-in of nourishment and the development of force did not make itself apparent. The nourishment seemed only necessary to grease, as it were, the wheel work of the animal machine, to replace what was used up, and to renew the old. The development of force out of itself seemed to be the essential peculiarity, the real quintessence of organic life. If, therefore, men were to be constructed, a perpetual motion must first be found. Another hope also seemed to take up incidentally the sec- ond place, which, in our wiser age, would certainly have claimed the first rank in the thoughts of men. The perpetual motion was to produce work inexhaustibly without corre- sponding consumption, that is to say, out of nothing. Work, however, is money. Here, therefore, the practical problem which the cunning heads of all centuries have followed in the most diverse ways, namely, to fabricate money out of nothing, invited solution. The similarity with the philosopher's stone sought by the ancient chemists was complete. That also was thought to contain the quintessence of organic life, and to be capable of producing gold. The spur wliich drove men to inquiry was sharp, and the talent of some of the seekers must not be estimated as small. The nature of the problem was quite calculated to entice poi> 214 INTERACTION OF NATURAL FORCES. <«» ing brains, to lead them round a circle for years, deceiving ever with new expectations, wliich vanished upon nearer ap- proach, and finally reducing these dupes of hope to open in- sanity. The phantom could not be grasped. It would be impossible to give a history of these efforts, as the clearer heads, among whom the elder Droz must be ranked, convinced themselves of the futility of their experiments, and were naturally not inclined to speak much about them. Bewildered intellects, however, proclaimed often enough that they had discovered the grand secret; and as the incorrectness of their proceedings was always speedily manifest, the matter fell into bad repute, and the opinion strengthened itself more and more that the problem wa3 not capable of solution; one difficulty after another was brought under the dominion of mathemati- cal mechanics, and finally a point was reached where it could be proved, that, at least by the use of pure mechanical forces, no perpetual motion could be generated. We have here arrived at the idea of the driving force or power of a machine, and shall have much to do with it in future. I must, therefore, give an explanation of it. The idea of work is evidently transferred to machines by compar- ing their arrangements with those of men and animals to replace which they were applied. We still reckon the work of steam engines according to horse-power. The value of manual labor is determined partly by the force which is ex- pended in it (a strong laborer is valued more highly than a weak one), partly however, by the skill which is brought into action. A machine, on the contrary, which executes work skilfully, can always be multiplied to any extent; hence its skill has not the high value of human skill in domains where the latter cannot be supplied by machines. Thus the idea of the quantity of work in the case of machines has been limited to the consideration of the expenditure of force; this was the more important, as indeed most machines are constructed for the cypress purpose of exceeding, by the magnitude of their MEASUREMENT OF MECHANICAL FOV/ER. 215 effects, the powers of men and animals. Hence, in a mechani- cal sense, the idea of work is become identical with that of the expenditure of force, and in this way I will apply it. How, then, can we measure this expenditure, and compare it in the case of different machines ? I must here conduct you a portion of the way—as short a portion as possible—over the uninviting field of mathematico- mechanical ideas, in order to bring you to a point of view from wliich a more rewarding prospect will open. And though the example which I shall here choose, namely, that of a water- mill with iron hammer, appears to be tolerably romantic, still, alas, I must leave the dark forest valley, the spark-emitting anvil, and the black Cyclops wholly out of sight, and beg a moment's attention to the less poetic side of the question, namely, the machinery. This is driven by a water-wheel which in its turn is set in motion by the falling water. The axle of the water-wheel has at certain places small projections, thumbs, which, during the rotation, lift the heavy hammer and permit it to fall again. The foiling hammer belabors the mass of metal, which is introduced beneath it. The work therefore done by the machine consists, in this case, in the lifting of the hammer, to do wliich the gravity of the latter must be over- come. The expenditure of force will, in the first place, other circumstances being equal, be proportioned to the weight of the hammer ; it will, for example, be double when the weight of the hammer is doubled. But the action of the hammer depends not upon its weight alone, but also upon the height from which it falls. If it falls through two feet, it will pro- duce a greater effect than if it falls through only one foot. It is, however, clear that if the machine, with a certain expendi- ture of force, lifts the hammer a foot in height, the same amount of force must be expended to raise it a second foot in height. The work is therefore not only doubled when the weight of the hammer is increased twofold, but also when the space through which it falls is doubled. From this it is cacA 216 INTERACTION OFNATURAL FORCES. to see that the work must be measured by the product of tha weight into the space through which it ascends. And in this way, indeed, do we measure in mechanics. The unit of work is a foot-pound, that is, a pound weight raised to the height of one foot. While the work in this case consists in the raising of the heavy hammer-head, the driving force which sets the latter in motion, is generated by falling water. It is not necessary that the water should fall vertically, it can also flow in a moderately inclined bed; but it must always, where it has water-mills to set in motion, move from a higher to a lower position. Experiment and theory coincide in teaching, that when a hammer of a hundred weight is to be raised one foot, to accomplish this at least a hundred weight of water must fall through the space of one foot; or what is equivalent to this, two hundred weight must fall full half a foot, or four hun- dred weight a quarter of a foot, etc. In short, if we multiply the weight of the falling water by the height through which it falls, and regard, as before, the product as the measure of the work, then the work performed by the machine in raising the • hammer, can, in the most favourable case, be only equal to the number of foot-pounds of water which have fallen in the same time. In practice, indeed, this ratio is by no means attained ; a great portion of the work of the falling water escapes unused, inasmuch as part of the force is willingly sacrificed for the sake of obtaining greater speed. I will further remark, that this relation remains unchanged whether the hammer is driven immediately by the axle of the wheel, or whether—by the intervention of wheel-work, end- less screws, pulleys, ropes—the motion is transferred to the hammer. We may, indeed, by such arrangements, succeed in raising a hammer of ten hundred weight, when by the first simple arrangement, the elevation of a hammer of one hundred weight might alone be possible ; but either this heavier ham- mer is raised to only one tenth of the height, or tenfold tho TRUE FUNCTION OF MACHINES. O.J 7 lime is required to raise it to the same height; so that, how- ever we may'alter, by the interposition of machinery, the in- tensity of the acting force, still in a certain time, during which the mill-stream furnishes us with a definite quantity of water, a certain definite quantity of work, and no more, can be per- formed. Our machinery, therefore, has, in the first place, done nothing more than make use of the gravity of the falling wa- ter in order to overpower the gravity of the hammer, and to raise the latter. W hen it has lifted the hammer to the neces- sary height, it again liberates it, and the hammer falls upon the metal mass which is pushed beneath it. But why does the falling hammer here exercise a greater force than when it is- permitted simply to press with its own weight on the mass of metal? Why is its power greater as the height from wliich it falls is increased? We find, in fact, that the work per- formed by the hammer is determined by its velocity. In other cases, also, the velocity of moving masses is a means of producing great effects. I only remind you of the destructive effects of musket-bullets, which, in a state of rest, are the most harmless things in the world. I remind you of the wind-mill, which derives its force from the moving air. It may appear surprising that motion, which we are accustomed to regard as a non-essential and transitory endowment of bodies, can pro- duce such great effects. But the fact is, that motion appears to us, under ordinary circumstances, transitory, because the movement of all terrestrial bodies is resisted perpetually by other forces, friction, resistance of the air, etc., so that motion is incessantly weakened and finally neutralized. A body, however, which is opposed by no resisting force, when once Bet in motion, moves onward eternally with undiminished velocity. Thus we know that the planetary bodies have moved without change, through space, for thousands of years. Onl\ by resisting forces can motion be diminished or destroyed. A moving body, such as the hammer or the musket-ball, when 10 218 INTERACTION OF NATURAL FORCES. it strikes against another, presses the latter together, or pene- trates it, until the sum of the resisting forces which the body struck presents to its pressure, or to the separation of its par- ticles, is sufficiently great to destroy the motion of the ham- mer or of the bullet. The motion of a mass regarded as taking the place of working force is called the living force (via viva) of the mass. The word " living " has of course here no reference whatever to living beings, but is intended to rep- resent solely the force of the motion as distinguished from the state of unchanged rest—from the gravity of a motionless body, for example, which produces an incessant pressure against the surface which supports it, but does not produce any motion. In the case before us, therefore, we had first power in the form of a falling mass of water, then in the form of a lifted hammer, and, thirdly, in the form of the living force of the fallen hammer. We should transform the third form into the second, if we, for example, permitted the hammer to fall upon a highly elastic steel beam strong enough to resist the shock. The hammer would rebound, and in the most favourable case would reach a height equal to that from which it fell, but would never rise higher. In this way its mass would ascend : and at the moment when its highest point has been attained, it would represent the same number of raised foot-pounds as before it fell, never a greater number ; that is to say, living force can generate the same amount of work as that ex- pended in its production. It is therefore equivalent to this quantity of work. Our clocks are driven by means of sinking weights, and our watches by means of the tension of springs. A weight which lies on the ground, an elastic spring which is without tension, can produce no effects ; to obtain such we must first raise the weight or impart tension to the spring, which ia accomplished when we wind up our clocks and watches. The man who winds the clock or watch communicates to the RESERVOIR OF ACCUMULATED POWER. 219 weight or to the spring a certain amount of power, and ex- actly so much as is thus communicated is gradually given out again during the following twenty-four hours, the original force being thus slowly consumed to overcome the friction of the wheels and the resistance which the pendulum encounters from the air. The wheel-work of the clock therefore exhibits no working force which was not previously communicated to it, but simply distributes the force given to it uniformly over a longer time. Into the chamber of an air-gun we squeeze, by means of a condensing air-pump, a great quantity of air. When we afterwards open the cock of a gun and admit the compressed air into the barrel, the ball is driven out of the latter with a force similar to that exerted by ignited powder. Now we may determine the work consumed in the pumping-in of the air, and the living force which, upon firing, is communicated to the ball, but we shall never find the latter greater than the former. The compressed air has generated no working force, but simply gives to the bullet that which has been previously communicated to it. And while we have pumped for perhaps a quarter of an hour to charge the gun, the force is expended in a few seconds when the bullet is discharged ; but because the action is compressed into so short a time, a much greater velocity is imparted to the ball than would be possible to com- municate to it by the unaided effort of the arm in throw- ing it. •From these examples you observe, and the mathematical theory has corroborated this for all purely mechanical, that is to say, for moving forces, that all our machinery and appara- tus generate no force, but simply yield up the power com- municated to them by natural forces,—falling water, moving wind, or by the muscles of men and animals. After this law Lad been estabhshed by the great mathematicians of the last century, a perpetual motion, which should make only use of pure mechanical forces, such as gravity, elasticity, pressure of 220 INTERACTION OF NATURAL FORCES. liquids and gases, could only be sought after by bewildered and iU-instructed people. But there are still other natural forces which are not reckoned among the purely moving forces,—heat, electricity, magnetism, hght, chemical forces, all of which nevertheless stand in manifold relation to me- chanical processes. There is hardly a" natural process to be found which is not accompanied by mechanical actions, or from which mechanical work may not be derived. Here the question of a perpetual motion remained open; the decision of this question marks the progress of modern physics. In the case of the air-gun, the work to be accomplished in the propulsion of the ball was given by the arm of the man who pumped in the air. In ordinary firearms, the condensed mass of air which propels the bullet is obtained in a totally different manner, namely, by the combustion of the powder. Gunpowder is transformed by combustion for the most part into gaseous products, which endeavor to occupy a much larger space than that previously taken up by the volume of the powder. Thus, you see, that, by the use of gunpowder, the work which the human arm must accomplish in the case of the air-gun is spared. In the mightiest of our machines, the steam engine, it is a strongly compressed aeriform body, water vapour, which, by its effort to expand, sets the machine in motion. Here also, we do not condense the steam by means of an external mechanical force, but by communicating heat to a mass of water in a closed boiler, wo change this water into steam, which, in consequence of the limits of the space, is developed under strong pressure. In this case, therefore, it is the heat communicated which generates the mechanical force. The heat thus necessary for the machine we might obtain in many ways ; the ordinary method is to procure it from the combus- tion of coal. Combustion is a chemical process. A particular constitu- ent of our atmosphere, oxygen, possesses a strong force of PRODUCTION OF FORCE BY COMBUSTION. 221 attraction, or, as it is named in chemistry, a strong affinity for the constituents of the combustible body, which affinity, however, in most cases, can only exert itself at high tempera- tures. As soon as a portion of the combustible body, for ex- ample the coal, is sufficiently heated, the carbon unites itself with great violence to the oxygen of the atmosphere and forms a peculiar gas, carbonic acid, the same which we see foaming from beer and champagne. By this combination, light and heat are generated ; heat is generally developed by any combination of two bodies of strong affinity for each other ; and when the heat is intense enough, light appears. Hence, in the steam engine, it is chemical processes and chemical forces which pro- duce the astonishing work of these machines. In like manner the combustion of gunpowder is a chemical process, which, in the barrel of the gun, communicates living force to the bullet. While now the steam engine develops for us mechanical work out of heat, we can conversely generate heat by mechani- cal forces. A skilful blacksmith can render an iron wedge red hot by hammering. The axles of our carriages must be pro- tected by careful greasing, from ignition through friction. Even lately this property has been applied on a large scale. In some factories, where a surplus of water power is at hand, this surplus is applied to cause a strong iron plate to rotate swiftly upon another, so that they become strongly heated by the fric- tion. The heat so obtained warms the room, and thus a stove without fuel is provided. Now, could not the heat generated by the plates be applied to a small steam engine, which, in its turn, should be able to keep the rubbing plates in motion ? The perpetual motion would thus be at length found. This question might be asked, and could not be decided by the older mathematico-mechanieal investigations. I will remark, beforehand, that the general law which I will lay before you answers the question in the negative. By a similar plan, however, a speculative American set 222 INTERACTION OF NATURAL FORCES. some time ago the industrial world of Europe in excitement. The magneto-electric machines often made use of in the case of rheumatic disorders are well known to the public. By imparting a swift rotation to the magnet of such a machine, we obtain powerful currents of electricity. If those be con- ducted through water, the latter will be reduced into its twj components, oxygen and hydrogen. By the combustion of hydrogen, water is again generated. If this combustion takes place, not in atmospheric air, of which oxygen only consti- tutes a fifth part, but in pure oxygen, and if a bit of chalk be placed in the flame, the chalk will be raised to a white heat, and give us the sun-like Drummond's light.- At the same time, the flame develops a considerable quantity of heat. Our American proposed to utilize in this way the gases obtained from electrolytic decomposition, and asserted that by the combustion a sufficient amount of heat was generated to keep a small steam engine in action, which again drove his magneto-electric machine, decomposed the water, and thus continually prepared its own fuel. This would certainly have been the most splendid of all discoveries ; a perpetual motion which, besides the force which kept it going, generated hght like the sun, and warmed all around it. The matter was by no means badly cogitated. Each practical step in the affair was known to be possible ; but those Avho at that time were acquainted with the physical investigations which bear upon this subject could have affirmed, on the first hearing the report, that the matter was to be numbered among the numer- ous stories of the fable-rich America; and indeed, a fable it remained. It is not necessary to multiply examples- further. You will infer from those given, in v/hat immediate connection heat, electricity, magnetism, light, and chemical affinity, stand with mechanical forces. Starting from each of these different manifestations of natural forces, we can set every other in motion, for the most STATEMENT OF DYNAMIC PROBLEM. 223 part not in one way merely, but in many ways. It is here as with the weaver's web,— Where a step stirs a thousand threads, The shuttles shoot from side to side, The fibres flow unseen, And one shock-strikes a thousand combinations. Now it is clear that if by any means we could succeed, as the above American professed to have done, by mechanical forces, to excite chemical, electrical, or other natural pro- cesses, which, by any circuit whatever, and without altering permanently the active masses in the machine, could produce mechanical force in greater quantity than that at first applied, a portion of the work thus gained might be made use of to keep the machine in motion, while the rest of the work might be applied to any other purpose whatever. The problem was, to find in the complicated net of reciprocal actions, a track through chemical, electrical, magnetical, and thermic processes, back to mechanical actions, which might be foUowed with a final gain of mechanical work ; thus would the perpet- ual motion be found. But, warned by the futility of former experiments, the public had "become wiser. On the whole, people did not seek much after combinations which promised to furnish a perpetual motion, but the question was inverted. It was no more asked, How can I make use of the known and unknown rela- tions of natural forces so as to construct a perpetual motion ? but it was asked, If a perpetual motion be impossible, what are the relations Avhich must subsist between natural forces ? Everything was gained by this inversion of the question. The relations of natural forces rendered necessary by the above assumption, might be easily and completely stated. It was found that all known relations of force harmonize with the consequences of that assumption, and a series of unknown relations were discovered at the same time, the correctness of 224 INTERACTION OF NATURAL FORCES. which remained to be proved. If a single one of them could be proved false, then a perpetual motion wotdd be possible. The first who endeavoured to travel this way was a French- man, named Carnot, in the year 1824. In spite of a too limited conception of his subject, and an incorrect view as to the nature of heat, which led him to some erroneous conclu- sions, his experiment was not quite unsuccessful. He dis- covered a law which now bears his name, and to which I will return further on. Hi3 labors remained for a long time without notice, and it was not till eighteen years afterwards, that is, in 1842, that different investigators in different countries, and independent of Carnot, laid hold of the same thought. The first who saw truly the general law here referred to, and expressed it correctly," was a German physician, J. It. Mayer, of Heilbronn, in the year 1842. A little later, in 1843, a Dane, named Colding, presented a memoir to the Academy of Copenhagen, in which the same law found utter- ance, and some experiments were described for its further corroboration. In England, Joule began about the same time to make experiments having reference to the same subject. We often find, in the case of questions to the solution of which the development of science points, that several heads, quite independent of each other, generate exactly the same series of reflections. I myself, without being acquainted with either Mayer or Colding, and having first made the acquaintance of Joule's experiments at the end of my investigation, followed the same path. I endeavoured to ascertain all the relations between the different natural processes, which followed from our regarding them from the above point of view. My inquiry was made public in 1847, in a small pamphlet bearing the title, " Ou the Conservation of Force." Since that time the interest of the scientific public for this subject has gradually augmented. A great number of the PROGRESS OF THE INVESTIGATION. 225 essential consequences of the above manner of viewing the subject, the proof of which was wanting when the first theoretic notions were published, have since been confirmed by experiment, particularly by those of Joule ; and during the last year the most eminent physicist of France, Regnault, has adopted the new mode regarding the question, and by fresh investigations on the specific heat of gases has contri- buted much to its support. For some important consequences the experimental proof is still wanting, but the number of confirmations is so predominant, that I have not deemed it too early to bring the subject before even a non-scientific audience. How tne question has been decided you may already infer from what has been stated. In the series of natural processes there is no circuit to be found, by which mechanical force can be gained without a corresponding consumption. The per- petual motion remains impossible. Our reflections, however, gain thereby a higher interest. We have thus far regarded the development of force by natural processes, only in its relation to its usefulness to man, as mechanical force. You now see that we have arrived at a general law, which holds good wholly independent of the application which man makes of natural forces; we must therefore make the expression of our new law correspond to this more general significance. It is in the first place clear, that the work which, by any natural process whatever, is per- formed under favourable conditions by a machine, and which may be measured in the way already indicated, may be used as a measure of force common to all. Further, the impor- tant question arises, " If the quantity of force cannot be aug- mented except by corresponding consumption, can it be diminished or lost? For the purpose of our machines it cer- tainly can, if we neglect the opportunity to convert natural processes to use, but as investigation haS proved, not for a nature as a whole." 226 INTERACTION OF NATURAL FORCES. In the collision and friction of bodies agaiust each other, the mechanics of former years assumed simply that living force was lost. But I have already stated that each collision and each act of friction generates heat; and, moreover, Joule has estabhshed by experiment the important law, that for every foot-pound of force which is lost, a definite quantity cf heat is always generated, and that when work is performed by the consumption of heat, for each foot-pound thus gained a definite quantity of heat disappears. The quantity of heat necessary to raise the temperature of a pound of water a de- gree of the centigrade thermometer, corresponds to a mechani- cal force by which a pound weight would be raised to the height of 1350 feet; we name this quantity the mechanical equivalent of heat. I may mention here that these facts con- duct of necessity to the conclusion, that the heat is not, as was formerly imagined, a fine imponderable substance, but that, hke light, it is a peculiar shivering motion of the ulti- mate particles of bodies. In collision and friction, according to this manner of viewing the subject, the motion of the mass of a body which is apparently lost is converted into a motion of the ultimate particles of the body; and conversely, when mechanical force is generated by heat, the motion of the ulti- mate particles is converted into a motion of the mass. Chemical combinations generate heat, and the quantity of this heat is totally independent of the time and steps through which the combination has been effected, provided that other actions are not at the same time brought into play. If, however, mechanical work is at the same time accomphshed, as in the case of the steam engine, we obtain as much less heat as is equivalent to this work. The quantity of work produced by chemical force is in general very great. A pound of the purest coal gives, when burnt, sufficient heat to raise the tem- perature of 8086 pounds of water one degree of the centi- grade thermometer ; from this we can calculate that the mag- nitude of the chemical force of attraction between the parti- AMOUNT OF FORCE IN THE UNIVERSE UNALTERABLE. 227 cles of a pound of coal and the quantity of oxygen that corre- sponds to it, is capable of lifting a weight of one hundred pounds to a height of twenty miles. Unfortunately, in our steam engines, we have hitherto been able to gain only the smaUest portion of this work; the greater part is lost in the shape of heat. The best expansive engines give back as mechanical work only eighteen per cent, of the heat generated by the fuel. From a similar -investigation of all the other known physi- cal and chemical processes, we arrive at the conclusion that Nature as a whole possesses a store of force which cannot in any way be either increased or diminished. And that, there- fore, the quantity of force in nature is just as eternal and unalterable as the quantity of matter. Expressed in this form, I have named the general law " The Principle of the Conser vation of Force." We cannot create mechanical force, but we may help our- selves from the general store-house of Nature. The brook and the wind, wliich drive our mills, the forest and the coal- bed, which supply our steam engines and warm our rooms, are to us the bearers of a small portion of the great natural supply which we draw upon for our purposes, and the actions of which we can apply as we think fit. The possessor of a mill claims the gravity of the descending rivulet, or the living force of the moving wind, as his possession. These por- tions of the store of Nature are what give his property its chief value. Further, from the fact that no portion of force can be absolutely lost, it does not follow that a portion may not be inapplicable to human purposes. In this respect the infer- ences drawn by William Thomson from, the law of Carnot are of importance. This law, which was discovered by Car- not during his endeavours to ascertain the relations between heat and mechanical force, which, however, by no means belongs to the necessary consequences of the conservation of 228 INTERACTION OF NATURAL FORCES. force, and which Clausius was the first to modify in such a manner that it no longer contradicted the above general law, expresses a certain relation between the compressibility, the capacity for heat, and the expansion by heat of all bodies. It is not yet considered as actually proved, but some remarkable deductions having been drawn from it, and afterwards proved to be facts by experiment, it has attained thereby a great degree of probability. Besides the mathematical form in which the law was first expressed by Carnot, we can give it the foUowing more general expression:—" Only when heat passes from a warmer to a colder body, and even then only partially, can it be converted into mechanical work." The heat of a body which we cannot cool further, cannot be changed into another form of force; into the electric or chemical force, for example. Thus, in our steam engines, we convert a portion of the heat of the glowing coal into work, by permitting it to pass to the less warm water of the boiler. If, however, all the bodies in nature had the same temperature, it would be impossible to convert any portion of their heat into mechanical work. According to this, we can divide the total force store of the universe into two parts, one of which is heat, and must continue to be such ; the other, to which a portion of the heat of the warmer bodies, and the total supply of chemical, mechanical, electrical, and magneti- cal forces belong, is capable of the most varied changes of form, and constitutes the whole wealth of change which takes place in nature. But the heat of the warmer bodies strives perpetually to pas3 to bodies less warm by radition and conduction, and thus to establish an equilibrium of temperature. At each motion of a terrestrial body, a portion of mechanical force passes by friction or collision into heat, of which only a .part can be converted back again into mechanical force. This is also generally the case in every electrical and chemical process. From this, it follows that the first portion of the store of force, THE FORCES OF NATURE DISSIPATED IN HEAT. 229 the unchangeable heat, is augmented by every natural pro- cess, while the second portion, mechanical, electrical, and chemical force, must be diminished; so that if the universe be delivered over to the undisturbed action of its physical pro- cesses, all force will finally pas3 into the form of heat, and all heat come into a state of equilibrium. Then all possibility of a further change -would be at an end, and the complete cessa- tion of all natural processes must set in. The life of men, animals, and plants, could not of course continue if the sun had lost its high temperature, and with it his light,—if all the components of the earth's surface had closed those combina- tions which their affinities demand. In short, the universe from that time forward would be condemned to a state of eternal rest. These consequences of the law of Carnot are, of course, only valid, provided that the law, when sufficiently tested, proves to be universally correct. In the mean time there is little prospect of the law being proved incorrect. At all events we must admire the sagacity of Thomson, Avho, in the letters of a long known little mathematical formula, which only speaks of the heat, volume, and pressure of bodies, was able to discern consequences wliich threatened the uni- verse, though certainly after an infinite period of time, with eternal death. I have already given you notice that our path lay through a thorny and unrefreshing field of mathematico-mechanical developments. We have now left this portion of our road behind us. The general principle which I have sought to lay before you has conducted us to a point from which our view is a wide one, and, aided by this principle, we can now at pleasure regard this or the other side of the surrounding world, according as our interest in the matter leads us. A glav.ee into the narrow laboratory of the physicist, with its small apphances and comphcated abstractions, will not be so attractive as a glance at tho wide heaven above us, the cloudsj 230 INTERACTION OF NATURAL FORCES. the rivers, the woods, and the living beings around us. While regarding the laws which have been deduced from the physi- cal processes of terrestrial bodies, as applicable also to the heavenly bodies, let me remind you that the same force which, acting at the earth's surface, we call gravity (Schwere), acts as gravitation in the celestial spaces, and also manifests its power in the motion of the immeasurably distant double stars which are governed by exactly the same laws as those sub- sisting between the earth and moon; that, therefore, the light and heat of terrestrial bodies do not in any way differ essentially from those of the sun, or of the most distant fixed star; that the meteoric stones which sometimes fall from ex- ternal space upon the earth arc composed of exactly the same simple chemical substances as those with which we are acquainted. We need, therefore, feel no scruple in granting that general laws to which all terrestrial natural processes are subject, are also valid for other bodies than the earth. We will, therefore, make use of our law to glance over the household of the universe with respect to the store of force, capable of action, which it possesses. A number of singular pecuharities in the structure of our planetary system indicate that it was once a connected mass with a uniform motion of rotation. Without such an assump- tion, it is impossible to explain why all the planets move in the same direction round the sun, why they all rotate in the same direction round their axes, why the planes of their orbits, and those of their satellites and rings ah nearly coincide, why all their orbits differ but little from circles; and much besides. From these remaining indications of a former state, astrono- mers have shaped an hypothesis regarding the formation of our planetary system, which, although from the nature of the case it must ever remain an hypothesis, still in its special traits is so well supported by analogy, that it certainly de- ■ serves our attention. It was Kant, who,'feeling great inter- est in the physical description of the earth and the planetary ORIGIN OF THE NEBULAR HYPOTHESIS. 231 system, undertook the labour of studying the works of New- ton, and as an evidence of the depth to which he had pene- trated into the fundamental ideas of Newton, seized the notior. that the same attractive force of all ponderable matter which now supports the motion of the planets, must also aforetime have been able to form from matter loosely scattered in space the planetary system. Afterwards, and independent of Kant, Laplace, the great author of the Mecanique Celeste, laid hold of the same thought, and introduced it among astronomers. The commencement of our planetary system, including the sun, must, according to this, be regarded as an immense nebulous mass which filled the portion of space which is now occupied by our system, far beyond the limits of Neptune, our most distant planet. Even now we perhaps see similar masses in the distant regions of the firmament, as patches of nebulap, and nebulous stars ; within our system also, comets, the zodiacal hght, the corona of the sun during a total echpse, exhibit remnants of a nebulous substance, which is so thin that the hght of the stars passes through it unenfeebled and unrefracted. If we calculate the density of the mass of our planetary system, according to the above assumption, for the time when it was a nebulous sphere, which reached to the path of the outmost planet, we should find that it would require several cubic miles of such matter to weigh a single grain. The general attractive force of all matter must, however, impel these masses to approach each other, and to condense, so that the- nebulous sphere became incessantly smaller, by which, according to mechanical laws, a motion of rotation originally slow, and the existence of which must be assumed, would gradually become quicker and quicker. By the cen- trifugal force wliich must act most energetically in the neigh- bourhood of the equator of the nebulous sphere, masses could from time to time be torn away, which afterwards would continue their courses separate from the main mass, forming 232 INTERACTION OF NATURAL FORCE'. themselves into single planets, or, similar to the great ongl* nal sphere, into planets with satellites and rings, until finally the principal mass condensed itself into the sun. With regard to the origin of heat and light, this view gives us no information. When the nebulous chaos first separated itself from other fixed star masses, it must not only have contained all kinds of matter which was to constitute the future planetary sys- tem, but also, in accordance with our new law, the whole store of force which at one time must unfold therein its wealth of actions. Indeed in this respect an immense dower was bestowed in the shape of the general attraction of ah the par- ticles for each other. This force, which on the earth exerts itself as gravity, acts in the heavenly spaces as gravitation. As terrestrial gravity when it draws a weight downwards performs work and generates vis vie a, so also the heavenly bodies do the same when they draw two portions of matter from distant regions of space towards each other. The chemical forces must have been also present, ready to act; but as these forces can only come into operation by the most intimate contact of the different masses, con- densation must have taken place before the play of chemical forces began. Whether a still further supply of force in the shape of heat was present at the commencement we do not know. At all events, by aid of the law of the equivalence of heat and work, we find in the mechanical forces, existing at the time to which we refer, such a rich source of heat and hght, that there is no necessity whatever to take refuge in the idea of a store of these forces originally existing. When through con- densation of the masses their particles came into collision, and clung to each other, the vis viva of their motion would be thereby annihilated, and must reappear as heat. Already in old theories, it has been calculated, that cosmical masses must generate heat by their collision, but it was far from any body's HEAT DEVELOPED IN THE SOLAR SYSTEM. 233 thought, to make even a guess at the amount of heat to be generated in this way. At present we can give definite numerical values with certainty. Let us make this addition to our assumption; that, at the commencement, the density of the nebulous matter was a van- ishing' quantity, as compared with the present density of tho sun and planets ; we can then calculate how much work has been performed by the condensation; we can further calcu- late how much of this work rtill exists in the form of mechani- cal force, as attraction of the planets towards the sun, and as vis viva of their motion, and find, by this, how much of the force has been converted into heat. The result of this calculation is, that only about the 454th part of the original mechanical force remains as such, and that the remainder, converted into heat, would be sufficient to raise a mass of water equal to the sun and planets taken to- gether, not less than twenty-eight millions of degrees of the centigrade scale. For the sake of comparison*, I will mention that the highest temperature wliich we can produce by the oxyhydrogen blowpipe, which is sufficient to fuse and vapor- ize even platina, and which but few bodies can endure, ia estimated at about two thousand centigrade degrees. Of the action of a temperature of twenty-eight millions of such de- grees we can form no notion. If the mass of our entire sys- tem were pure coal, by the combustion of the whole of it only the 3500th part of the above quantity would be generated. This is also clear, that such a development of heat must have presented the greatest obstacle to the speedy union of the masses, that the larger part of the heat must have been diffused by radiation into space, before the masses could form bodies possessing the present density of the sun and planets, end that these bodies must once have been in a state of fiery fluidity. This notion is corroborated by the geological phe- nomena of our planet; and with regard to the other planetary bodies, the flattened form of the sphere, which i>. the form of 234 INTERACTION OF NATURAL FORCES. equilibrium of a fluid mass, is indicative of a former state of fluidity. If I thus permit an immense quantity of heat to disappear without compensation from our system, the principle of the conservation of force is not thereby invaded. Certainly for our planet it is lost, but not for the universe. It has proceeded outwards, and daily proceeds outwards into infinite space ; and we know not whether the medium which transmits the undulations of light and heat possesses an end where the rays must return, or whether they eternally pursue their way through infinitude. The store of force at present possessed by our system, is also equivalent to immense quantities of heat. If our earth were by a sudden shock brought to rest on her orbit—which is not to be feared in the existing arrangements of our system —by such a shock a quantity of heat Avould be generated equal to that produced by the combustion of fourteen such earths of solid coal. Making the most unfavourable assump- tion as to its capacity for heat, that is, placing it equal to that of water, the mass of the earth would thereby be heated 11,200 degrees; it would therefore be quite fused and for the most part reduced to vapour. If, then, the earth, after having been thus brought to rest, should faU into the sun, which of course would be the case, the quantity of heat developed by the shock would be four hundred times greater. Even now, from time to time, such a process is repeated on a small scale. There can hardly be a doubt that meteors, (ire-balls, and meteoric stones, are masses which belong to the universe, and before coming into the domain of our earth, moved like the planets round the sun. Only when they enter our atmosphere do they become visible and fall sometimes to the' earth. In order to explain the emission of light by these bodies, and the fact that for some time after their descent they are very hot, the friction was long ago thought of which they experience in passing through the air. We can now calculate that a velocity of 3000 feet a second, THE LIGHT AND HEAT OF METEORS. 235 supposing the whole of the friction to be expended in heating the solid mass, would raise a piece of meteoric iron 1000° C. in temperature, or, in other words, to a vivid red heat. Now the average velocity of the meteors seems to be thirty or forty times the above amount. To compensate this, however, the greater portion of the heat is, doubtless, carried away by the condensed mass of air which the meteor drives before it. It is known that bright meteors generally leave a luminous trail behind them, which probably consists of several portions of the red-hot surfaces. Meteoric masses which fall to the earth often burst with a violent explosion, which may be regarded as a result of the quick heating. The newly-faUen pieces have been for the most part found hot, but not red-hot, which is easily explainable by the circumstance, that during the short time occupied by the meteor in passing through the atmosphere, only a thin, superficial layer is heated to redness, while but a small quantity of heat has been able to penetrate to the interior of the mass. For this reason the red heat can speedily disappear. Thus has the falling of the meteoric stone, the minute remnant of processes which seems to have played an impor- tant part in the formation of the heavenly bodies, conducted us to the present time, where we pass from the darkness of hypothetical views to the brightness of knowledge. In what we have said, however, all that is hypothetical is the assump- tion of Kant and Laplace, that the masses of our system were once distributed as nebula; in space. On account of the rarity of the case, we will still further remark, in what close coincidence the results of science here stand with the earlier legends of the human family, and the forebodings of poetic fancy. The cosmogony of ancient na- tions generally commences with chaos and darkness. Neither is the Mosaic tradition very divergent, particu- larly when we remember that that which Moses names heaven is different from the blue dome above us, and is synonymous 236 INTERACTION OF NATURAL FORCES. with space, and that the unformed earth, and the Avaters of the great deep, which were afterwards divided into waters above the firmament, and waters below the firmament, resem- bled the chaotic components of the world. Our earth bears still the unmistakable traces of its old fiery fluid condition. The granite formations of her moun- tains exhibit a structure, wliich can only be produced by the crystallization of fused masses. Investigation still shows that the temperature in mines, and borings, increases as we descend; and if this increase is uniform, at the depth of fifty miles, a heat exists sufficient to fuse all our minerals. Even now our volcanoes project, from time to time, mighty masses of fused rocks from their interior, as a testimony of the heat which exists there. But the cooled crust of the earth has already become so thick, that, as may be shown by calcula- tions of its conductive power, the heat coming to the surface from within, in comparison with that reaching the earth from the sun, is exceedingly small, and increases the temperature of the surface only about one thirtieth of a degree centigrade ; so that the remnant of the old store of force which is enclosed as heat within the bowels of the earth, has a sensible influence upon the processes at the earth's surface, only through the instrumentality of volcanic phenomena. These processes owe their power almost wholly to the action of other heavenly bodies, particularly to the light and heat of the sun, and partly also, in the case of the tides, to the attraction of the sun and moon. Most varied and numerous are the changes which we owe to the light and heat of the sun. The sun heats our atmos- phere irregularly, the warm rarefied air ascends, while fresh cool air flows from the sides to supply its place : in this way winds are generated. This action is most powerful at the equator, the warm air of which incessantly flows in the upper regions of the atmosphere towards the poles: while just as persistently, at the earth's surface, the trade wind carries new and cool air to the equator. Without the heat of the sun aU BOLAR FORCE PRODUCES THE WATER CIRCULATIONS. 237 winds must, of necessity, cease. Similar currents are pro- duced by the same cause in the waters of the sea. Their pow- er may be inferred from the influence which in some cases they exert upon climate By them the Avarm water of the Antilles is carried to the British Isles, and confers upon them a mild, uniform Avarmth and rich moisture; Avhile, through Bimilar causes, the floating ice of the North Pole is carried to the coast of Newfoundland, and produces cold. Further, by the heat of the sun, a portion of the water is converted into vapour which rises in the atmosphere, is condensed to clouds, or falls in rain and snoAV upon the earth, collects in the form of springs, brooks, and rivers, and finally reaches the sea again, after having gnawed the rocks, carried away the light earth, and thus performed its part in the geologic changes of the earth; perhaps, besides all this it has driven our water- mill upon its way. If the heat of the sun were with drawn, i there Avould remain only a single motion of water, namelv, the tides, Avhich are produced by the attraction of the sun and moon. How is it, now, with the motions and the work of organic beings. To the builders of the automata of the last century, men and animals appeared as clockwork which was never wound up, and created the force which they exerted out of nothing. They did not know how to establish a connection between the nutriment consumed and the work generated. Since, however, we have learned to discern in the steam-en- gine this origin of mechanical force, we must inquire whether something similar does not hold good with regard to men. In- deed, the continuation of hfe is dependent on the consumption of nutritive materials : these are combustible substances, which, after digestion and being passed into the blood, actually under- go a slow combustion, and finally enter into almost the same combinations with the oxygen of the atmosphere that are pro- duced in an open fire. As the quantity of heat generated by combustion is independent of the duration of the combustion and 238 INTERACTION OF NATURAL FORCES. the steps in Avhich it occurs, we can calculate from the mass of the consumed material how much heat, or its equivalent Avork is thereby generated in an animal body. Unfortunately, the difficulty of the experiments is still very great; but within those limits of accuracy Avhich have been as yet attainable, the experiments show that the heat generated in the animal body corresponds to the amount which would be generated by the chemical processes. The animal body therefore does not differ from the steam-engine, as regards the manner in which it obtains heat and force, but does differ from it in the man- ner in which the force gained is to be made use of. The body is, besides, more limited than the machine in the choice of its fuel; the latter could be heated with sugar, with starch- flour, and butter, just as well as with coal or wood ; the ani- mal body must dissolve its materials artificially, and distribute them through its system ; it must, further, perpetually renew the used-up materials of its organs, and as it cannot itself create the matter necessary for this, the matter must come from without. Liebig Avas the first to point out these various uses of the consumed nutriment. As material for the perpet- ual renewal of the body, it seems that certain definite albumi- nous substances which appear in plants, and form the chief mass of the animal body, can alone be used. They form only a portion of the mass of nutriment taken daily; the remain- der, sugar, starch, fat, are really only materials for Avarming, and are perhaps not to be superseded by coal, simply because the latter does not permit itself to be dissolved. If, then, the processes in the animal body are not in this respect to be distinguished from inorganic processes, the ques- tion arises, whence comes the nutriment which constitutes the source of the body's force? The answer is, from the vegetable kingdom; for only the material of plants, or the flesh of plant-eating animals, can be made use of for food. The animals which live on plants) occupy a mean position between carnivorous animals, in a* hich Ave reckon man, and SOLAR ORIGIN OF ORGANIC FORCE. 239 vegetables, Avhich the former could not make use of immedi- ately as nutriment. In hay and grass the same nutritive sub- stances are present as in meal and flour, but in less quantity. As, however, the digestive organs of man are not in a condi- tion to extract the small quantity of the useful from the great excess of the insoluble, we submit, in the first place, these substances to the powerful digestion of the ox, permit the nourishment to store itself in the animal's body, in order in the end to gain it for ourselves in a more agreeable and use- ful form. In answer to our question, therefore, we are re- ferred to the vegetable world. Now when what plants take in and Avhat they give out are made the subjects of investiga- tion, we find that the principal part of the former consists in the products of combustion which are generated by the ani- mal. They take the consumed carbon given off in respira- tion, as carbonic acid, from the ah, the consumed hydrogen as water, the nitrogen in its simplest and closest combination as ammonia; and from these materials, with the assistance of small ingredients which they take from the soil, they gen- erate anew the compound combustible substances, albumen, sugar, oil, on Avhich the animal subsists. Here, therefore, is a circuit Avhich appears to be a perpetual store of force. Plants prepare fuel and nutriment, animals consume these, burn them slowly in their lungs, and from the products of combustion the plants again derive their nutriment. The latter is an eternal source of chemical, the former of mechan- ical forces. Would not the combination of both organic king- doms produce the perpetual motion ? We must not conclude hastily : further inquiry shoAvs, that plants are capable of pro- ducing combustible substances only when they are under the influence of the sun. A portion of the sun's rays exhibits a remarkable relation to chemical forces,—it can produce and destroy chemical combinations ; and these rays, which for the most part are blue or violet, are called therefore chemical rays. We make use of their action in the production of pho« 240 INTERACTION OF NATURAL FORCES, tographs. Here compounds of silver are decomposed at the place where the sun's rays strike them. The same rays over- power in the green leaves of plants the strong chemical affinity of the carbon of the carbonic acid for oxygen, give back the latter free to the atmosphere, and accumulate the other, in combination with other bodies, as woody fibre, starch, oil, or resin. These chemically active rays of the sun disappear completely as soon as they encounter the green portions of the plants, and hence it is that in daguerrotype images the green leaves of plants appear uniformly black. Inasmuch as the hght coming from them does not contain the chemical rays, it is unable to act upon the silver compounds. Hence a certain portion of force disappears from the sun- light, while combustible substances are generated and accumu- lated in plants ; and v,re can assume it as very probable, that the former is the cause of the latter. I must indeed remark, that we are in possession of no experiments from which wre might determine whether the vis viva of the sun's rays which have disappeared, corresponds to the chemical forces accumu- lated during the same time ; and as long as these experiments are wanting, Ave cannot regard the stated relation as a cer- tainty. If this view should prove correct, we derive 'from it the flattering result, that all force, by means of which our bodies live and move, finds its source in the purest sunlight; and hence Ave are all, in point of nobility, not behind the race of the great monarch of China, A\rko heretofore alone called himself Son of the Sun. But it must also be conceded that our lower felloAv-beings, the frog and leech, share the same ethereal origin, as also the whole vegetable world, and even the fuel which comes to us from the ages past, as well as the youngest offspring of the forest with which we heat our stoves and set our machines in motion. You see, then, that the immense Avealth of ever-changing meteorological, chmatic, geological, and organic processes of our earth are almost Avholly preserved in action by the ligh* DYNAMICS OF SUNLIGHT. 241 and heat-giving rays of the sun; and you see in this a re- markable example, how Proteus-like the effects of a single cause, under altered external conditions, may exhibit itself in nature. Besides these, the earth experiences an action of another kind from its central luminary, as Avell as from its satellite the moon, AA-hich exhibits itself in the remarkable phenomenon of the ebb and flow of the tide. Each of these bodies excites, by its attraction upon the Avaters of the sea, tAVO gigantic waves, which flow in the same direction round the Avorld, as the attracting bodies themselves apparently do. The two waves of the moon, on account of her greater nearness, are about three and a half times as large as those excited by the sun. One of these Avaves has its crest on the quarter of the earth's surface which is turned towards the moon, the other is at the opposite side. Both these quar- ters possess the flow of the tide, Avhile the regions which lie between have the ebb. Although in the open sea the height of the tide amounts to only about three feet, and only in cer- tain narrow channels, where the moving Avater is squeezed together, rises to thirty feet, the might of the phenomena is neA-ertheless manifest from the calculation of Bessel, accord- ing to which a quarter of the earth covered by the sea pos- sesses, during the flow of the tide, about 25,000 cubic miles of water more than during the ebb, and that therefore such a mass of water must, in six and a quarter hours, Aoav from one quarter of the earth to the other. The phenomena of the ebb and Aoav, as already recognized by Mayer, combined with the law of the conservation of force, stand in remarkable connection with the question of the sta- bility of our planetary system. The mechanical theory of the planetary motions discovered by Newton teaches, that if a solid body in absolute vacuo, attracted by the sun, move around him in the same manner as the planets, this motion will endure unchanged through all eternity. Now we have actually not only one, but several such 11 242 INTERACTION OF NATURAL FORCES. planets, Avhich move around the sun, and by their mutual attraction create little changes and disturbances in each other's paths. Nevertheless Laplace, in his great work, the Mece.n- ique Celeste, has proved that in our planetary system all these disturbances increase and diminish periodically, and can never exceed certain hmits, so that by this cause the eternal exist- ence of the planetary system is unendangered. But I have already named two assumptions which must be made : first that the celestial spaces must be absolutely empty; and secondly, that the sun and planets must be solid bodies. The first is at least the case as far as astronomical observa- tions reach, for they have never been able to detect any retar- dation of the planets, such as would occur if they moved in a resisting medium. But on a body of less mass, the comet of Encke, changes are observed of such a nature : this comet de- scribes ellipses round the sun which are becoming gradually smaller. If this kind of motion, which certainly corresponds to that through a resisting medium, be actually due to the ex- istence of such a medium, a time will come when the comet Avill strike the sun ; and a similar end threatens aU the planets, although after a time, the length of which baffles our imagina- tion to conceive of it. But even should the existence of a re- sisting medium appear doubtful to us, there is no doubt that the planets are not wholly composed of sohd materials which are inseparably bound together. Signs of the existence of an atmosphere are observed on the Sun, on Venus, Mars, Jupi- ter, and Saturn. Signs of water and ice upon Mars; and our earth has undoubtedly a fluid portion on its surface, and perhaps a still greater portion of fluid within it. The motions of the tides, however, produce friction, all friction destroys vis viva, and the loss in this case can only affect the vis viva of the planetary system. We come thereby to the unavoidable conclusion, that every tide, although with infinite slowness, still with certainty, diminishes the store of mechani- cal force of the system ; and as a consequence of this, the ro- INFLUENCE OF TIDES UPON THE EARTIl's ROTATION. 243 taticn of the planets in question round their axes must become more slow; they must therefore approach the sun, or their satellites must approach them. What length of time must pass before the length of our day is diminished one second by the action of the tide cannot be calculated, until the height and time of the tide in aU portions of the ocean are knoAA-n. This alteration, however, takes place with extreme slowness, as is known by the consequences which Laplace has deduced from the observations of Hipparchus, according to which, during a period of 2000 years, the duration of the day has not been shortened by the one three hundredth part of a sec- ond. The final consequence would be, but after millions of years, if in the mean time the ocean did not become frozen, that one side of the earth would be constantly turned toAvards the sun, and enjoy a perpetual day, whereas the opposite side would be involved in eternal night. Such a position we observe in our moon Avith regard to the earth, and also in the case of the satellites as regards their planets ; it is, perhaps, due to the action of the mighty ebb and flow to Avhich these bodies, in the time of their fiery fluid condition, were sub- jected. I would not have brought forward these conclusions, which again plunge us in the most distant future, if they were not unavoidable. Physico-mechanical laws are, as it were, the telescopes of our spiritual eye, which can penetrate into the deepest night of time, past and to come. Another essential question as regards the future of our planetary system has reference to its future temperature and illumination. As the internal heat of the earth has but little influence on the temperature of the surface, the heat of the sun is the only thing which essentially affects the question. The quantity of heat falling from the sun during a given time upon a given portion of the earth's surface may be measured, and from this it can be calculated how much heat in a given lime is sent out from the entire sun. Such measurements 244 INTERACTION OF NATURAL FORCES. have been made by the French physicist Pauiilet, and it has been found that the sun gives out a quantity of heat per hour equaV to that which a layer of the densest coal ten feet thick would give out by its combustion; and hence in a year a quantity equal to the combustion of a layer of seventeen mile3. K this heat Avere drawm uniformly from the entire mass of the sun, its temperature would only be diminished thereby one and one third of a degree centigrade per year, assuming its capa- city for heat to be equal to that of Avater. These results can give us an idea of the* magnitude of the emission, in relation to the surface and mass of the sun; but they cannot inform U3 whether the sun radiates heat as a glowing body, which since its formation has its heat accumulated within it, or whether a new generation of heat hj chemical processes takes place at the sun's surface. At aU e\-ents the law of the conservation of force teaches us that no process analogous to those known at the surface of the earth, can supply for eternity an inexhaustible amount of light and heat to the sun. But the same law also teaches that the store of force at present existing, as heat, or as what may become heat, is sufficient for an immeasurable time. With regard to the store of chemical force in the sun, we can form no conjecture, and the store of heat there existing can only be determined by very uncertain estimations. If, however, we adopt the very probable view, that the remarkably small density of so large a body is caused by its high temperature, and may become greater in time, it may be calculated that if the diameter of the sun were dimin- ished only the ten-thousandth part of its present length, by this act a sufficient quantity of heat would be generated to coA-er the total emission for 2100 years. Such a small change besides it would be difficult to detect even by the finest astro- nomical observations. Indeed, from the commencement of the period during which we possess historic accounts, that is, for a period of about 4000 years, the temperature of the earth has not sensi- CONSTANCY OF TUE EARTH'S TEMPERATURE. 245 bly diminished. From these old ages Ave have certainly no thermometric observations, but we have information regard- ing the distribution of certain cultivated plants, the vine, the ohve tree, which are very sensitive to changes of the mean annual temperature, and we find that these plants at the pres- ent moment have the same limits of distribution that they had in the times of Abraham and Homer ; from which we may in- fer backAvards the constancy of the climate. In opposition to this it has been urged, that here in Prussia the German knights in former times cultivated the vine, cellared their own wine and drank it, which is no longer pos- sible. From this the conclusion has been drawn, that the heat of our climate has diminished since the time teferred to. Against this, hoAvever, Dove has cited the reports of ancient chroniclers, according to which, in some peculiarly hot years, the Prussian grape possessed somewhat less than its usual quantity of acid. The fact also speaks not so much for the climate of the country as for the throats of the German drinkers. But even though the force store of our planetary system is so immensely great, that by the incessant emission which has occurred during the period of human history it has not been sensibly diminished, even though the length of the time Avhich must Aoav by, before a sensible change in the state of our planetary system occurs, is totally incapable of measure- ment, still the inexorable laws of mechanics indicate that this store of force, Avhich can only suffer loss and not gain, must be finally exhausted. ShaU Ave terrify ourselves by this thought? Men are in the habit of measuring the greatness and the wisdom of the universe by the duration and the profit Avhich it promises to their own race ; but the past history of the earth already shows Avhat an insignificant moment the duration of the existence of our race upon it constitutes. A NineAreh vessel, a Roman sword awakes in us the conception of grey antiquity. What the museums of Europe show us o 246 INI ER ACTION OF NATURAL FORCES. the remains of Egypt and Assyria we gaze upon Avith silent astonishment, and despair of being able to carry our thoughts back to a period so remote. Still must the human race have existed for ages, and multiplied itself before the pyramids of Nineveh could have been erected. We estimate the duration of human history at 6000 years ; but immeasurable as this time may appear to us, what is it in comparison with the time dur- ing which the earth carried successiA'e series of rank plants and mighty animals, and no men ; during which in our neigh- bourhood the amber-tree bloomed, and dropped its costly gum on the earth and in the sea; when in Siberia, Europe and North America groves of tropical palm's flourished; where gigantic lizards, and after them elephants, A\rhose mighty re- mains we still find buried in the earth, found a home ? Dif- ferent geologists, proceeding from different premises, have sought to estimate the duration of the above creative period, and vary from a million to nine million years. And the time during which the earth generated organic beings is again small when we compare it with the ages during which the world was a ball of fused rocks. For the duration of its cool- ing from 2000° to 200° centigrade, the experiments of Bishop upon basalt show that about 350 millions of years would be necessary. And with regard to the time during which the first nebulous mass condensed into our planetary system, our most daring conjectures must cease. The history of man, there fore, is but a short ripple in the ocean of time. For a much longer series of years than that during which man has already occupied this Avorld, the existence of the present state of in- organic nature favourable to the duration of man seems to be secured, so that for ourselves and for long generations after us, we have nothing to fear. But the same forces of air and Avater, and of the volcanic interior, which produced former geological revolutions, and buried one series of hving forms after another, act still upon the earth's crust. They more probably will bring about the last day of the human race than CULMINATION OF THE ARGUMENT. 241 those distant cosmical alterations of which we have spoken, and perhaps force us to make way for new and more com- plete hving forms, as the lizards and the mammoth have given place to us and our feUoAV-creatures which now exist. Thus the thread which was spun in darkness by those who sought a perpetual motion has conducted us to a univer- sal laAv of nature, which radiates light into the distant nights of the beginning and of the end of the history of the universe. To our OAvn race it permits a long but not an endless exist- ence ; it threatens it with a day of judgment, the dawn of which is stiU happUy obscured. As each of us singly must endure the thought of his death, the race must endure the same. But above the forms of life gone by, the human race has higher moral problems before it, the bearer of which it is, and in the completion of which it fulfils its destiny. I. REMARKS ON THE FORCES OF INOKGANIC NATUKE. Br Dn. J. R. MAYER. Translated by J. C. FOSTER, B.A. n ON CELESTIAL DYNAMICS. By Dr. J. R. MAYER. Translated bt De. H. DEBUS, F.E.S. * in. REMARKS ON THE MECHANICAL EQUIVALENT OF HEAT, Bt Dr. J. R. MAYER. Translated by J. C. FOSTEE, B.A. Julius Robert Mayer was born at Heilbronn, November 23, 1814. He received a medical education, and became first, county wound-physician and afterwards city physician of Heilbronn. But few particulars of his life have been obtained. In 1840 he made a voyage on a Dutch freighter to Java, and it was the accident of bleeding a feverish patient in this country, and observing that the venous blood in the tropics was of a much brighter red than in colder latitudes, that led him to those investigations of natural forces, the chief results of which are given in the following essays. Two years after bis attention was drawn to the subject—in 18413, he published his first paper on the " Forces of Inorganic Nature." It was put together briefly, and published in Liebig's journal to secure the public recognition of his claims. His second publication, " On Organic Motion and Nutrition" (1845), an able essay of one hundred and twelve pages, is not yet translated. His third paper, on " Celestial Dynamics," was published in 1848 ; and hia fourth, on the " Mechanical Equivalent of Heat," appeared in 1851. These vast and rapid labors were too much for his strength. His over- tasked mind gave way, and he was taken to an insane asylum. He, how- ever, fortunately recovered, and is now reported as occupied with the culti- vation of the vine in Heilbronn. I. THE FORCES OF INORGANIC NATURE. THE folloAving pages are designed as an attempt to an swcr the questions, What are we to understand by " Forces" ? and hoAv are different forces related to each other? Whereas the term m,atter implies the possession, by the object to which it is apphed, of very definite properties, such as weight and extension; the term force conveys for the most part the idea of something unknown, unsearchable, and hypo- thetical. An attempt to render the notion of force equaUy exact with that of matter, and so to denote by it only objects of actual investigation, is one which, with the consequences that floAv from it, ought not to be unwelcome to those who desire that their Ariews of nature may be clear and unencum- bered by hypotheses. Forces are causes: accordingly, we may in relation to them make fuU apphcation of the principle—causa cequat ef- fectum. If the cause c has the effect e, then c= e; if, in its turn, e is the cause of a second effect/, we have e=f, and so on: c=e=/... = c. In a chain of causes and effects, a term or a part of a term can never, as plainly appears from the nature of an equation, become equal to nothing. This first property of aU causes we call their indestructibility. If the given cause c has produced an effect e equal to it- self, it has in that very act ceased to be : c has become e ; if, after the production of e, c still remained in whole 01 in part, 252 THE FORCES OF ESORGAXIC XATUKE. there must be stiU further effects corresponding to this re maining cause : the total effect of c would thus be > e, which would be contrary to the supposition c=e. Accordingly, since cbecomes e, and e becomes/, &c, Ave must regard these various magnitudes as different forms under Avhich one and the same object makes its appearance. This capability of assuming various forms is the second essential property of aU causes. Taking both properties together, we may say, causes are (quantitatively) indestructible and (qualitatively) convert- ible objects. Two classes of causes occur in nature, which, so far as experience goes, never pass one into another. The first class consists of such causes as possess the properties of Aveight and impenetrability; these are kinds of Matter: the other class is made up of causes which are Avanting in the proper- ties just mentioned, -namely Forces, called also Impondera- bles, from the negative property that has been indicated. Forces are therefore indestructible, convertible, imponderable objects. We AviU in the first instance take matter, to afford us an example of causes and effects. Explosive gas, H+O, and Avater, HO, are related to each other as cause and effect, therefore H+0=HO. But if H+O becomes HO, heat, cal., makes its appearance as avcU' as water; this heat must like- wise have a cause, x, and we have therefore H+0+o;=HO ■\-cal. It might, however, be asked whether H+O is really =HO, and x=cal., and not perhaps H+0=caZ., and sc=HO, whence the above equation could equaUy be deduced ; and so in many other cases. The phlogistic chemists recognized the equation between cal. and x, or Phlogiston as they caUed it, and in so doing made a great step in advance; but they in- volved themselves again in a system of mistakes by putting—x in place of 0 ; thus, for instance, they obtained H=HO+x. Chemistry, whose problem it is to set forth in equations the causal connection existir.g between the different kinds of MATTER AND FORCE AS CAUSES. 253 matter, teaches us that matter, as a cause, has matter for its effect; but Ave are equally justified in saying that to force as cause, corresponds force as effect. Since c=e, and e—c, it is unnatural to caU one term of an equation a force, and the other an effect of force or phenomenon, and to attach differ- ent notions to the expressions Force and Phenomenon. In brief, then, if the cause is matter, the effect is matter; if the cause is a force, the effect is also a force. A cause which brings about the raising of a Aveight is a force; its effect (the raised weight) is, accordingly, equaUy a force; or, expressing this relation in a more general form, separation in space of ponderable objects is a force ; since this force causes the faU of bodies, we call it falling force. FaU- ing force and faU, or, more generally stiU, falhng force and motion, are forces which are related to each other as cause and effect—forces which are convertible one into the other— two different forms of one and the same object. For exam- ple, a weight resting on the ground is not a force : it is neither the cause of motion, nor of the lifting of another weight; it becomes so, hoAvever, in proportion as it is raised above the ground: the cause—the distance between a weight and the earth—and the effect—the quantity of motion produced—beai j) each other, as Ave learn from mechanics, a constant rela- tion. Gravity being regarded as the cause of the faUing of bod- ies, a gravitating force is spoken of, and so the notions of property and of force are confounded with each other: pre- cisely that Avhich is the essential attribute of every force— the union of indestructibility with convertibility—is wanting in every property: betAveen a property and a force, between gravity and motion, it is therefore impossible to estabhsh the equation required for a rightly-conceived causal relation. If gravity be caUed a force, a cause is supposed which produces effects without itself diminishing, and incorrect conceptions of the causal connections of things arc thereby fostered. In 254 THE FORCES OF INORGANIC NATURE. order that a body may faU, it is no less necessary that it should be lifted up, than that it should be heavy or possess gravity; the faU of bodies ought not therefore to be ascribed to their gravity alone. It is the problem of Mechanics to develop the equations which subsist between falhng force and motion, motion and faUing force, and between different motions : here we wUl caU to mind only one point. The magnitude of the faUing force v is directly proportional (the earth's radius being assumed= oo ) to the magnitude of the mass m, and the height d to which it is raised; that is, v~md. If the height d=l, to which the mass jn is raised, is transformed into the final A'e- locity c=l of this mass, we have also v=mc; but from the known relations existing between d and c, it results that, for other values of d or of c, the measure of the force v is mc1; accordingly v=md=mc>: the law of the conservation of vis viva is thus found to be based on the general law of the inde structibility of causes. In numberless cases we see motion cease without having caused another motion or the lifting of a Aveight; but a force once in existence cannot be annihilated, it can only change its form ; and the question therefore arises, What other forms is force, which we have become acquainted with as falling force and motion, capable of assuming? Experience alone can lead us to a conclusion on this point. In order to experi- ment with advantage, we must select implements which, be- sides causing a real cessation of motion, are as little as possi- ble altered by the objects to be examined. If, for example, we rub together two metal plates, we see motion disappear, and heat, on the other hand, make its appearance, and we have now only to ask whether motion is the cause of heat. In order to come to a decision on this point, we must discuss the question.whether, in the numberless cases in which the expenditure of motion is accompanied by the appearance of heat, the motion has not some other effect than the pro- EFFECTS OF DESTROYED MOTION. 255 duction of heat, and the heat some other cause than the motion. An attempt to ascertain the effects of ceasing motion has never yet been seriously made ; Avithout, therefore, wishing to exclude d priori the hypothesis which it may be possible to set up, we observe only that, as a rule, this effect cannot be supposed to be an alteration in the state of aggregation of the moved (that is, rubbing, &c.) bodies. If we assume that a certain quantity of motion v is expended in the conversion of a rubbing substance m into n, we must then have w+v=n, and «=wi+v; and when n is reconverted into m, v must ap- pear again in some form or other. By the friction of two metallic plates continued for a very long time, we can grad- ually cause the cessation of an immense quantity of move- ment ; but would it ever occur to us to look for even the smaUest trace of the force which has disappeared in the me- tallic dust that we could coUect, and to try to regain it thence? We repeat, the motion cannot have been annihilated; and contrary, or positive and negative, motions cannot be regarded as =0, any more than contrary motions can come out of nothing, or a Aveight can raise itself. Without the recognition of a causal connection betAveen motion and heat, it is just as difficult to explain the produc- tion of heat as it is to give any account of the motion that disappears. The heat cannot be derived from the diminution of the volume of the rubbing substances. It is Avell known that two pieces of ice may be melted by rubbing them to- gether in vacuo ; but let any one try to convert ice into water by pressure,* however enormous. Water undergoes, as Avas * Since the original publication of this paper, Prof. W. Thomson has shown that pressure has a sensible effect in liquefying ice ( Conf. PhiL Mag. S. 3, vol. xxxvii. p. 123); but the experiments of Bunsen and of Hopkins have shown that the melting-points of bodies which expand on becoming liquid are raised by pressure, which is all that Mayer's argument requires.— G. C. F. 256 THE FORCES OF INORGANIC NATURE. found by the author, a rise of temperature Avhen violently shaken. The water so heated (from 12° to 13° C.) has a greater bulk after being shaken than it had before ; Avhence now comes this quantity of heat, Avhich by repeated shaking may be caUed into existence in the same apparatus as often as we please ? The vibratory hypothesis of heat is an ap- proach toward the doctrine of heat being the effect of mo- tion, but it does not favour the admission of this causal rela* tion in its fuU generahty; it rather lays the chief stress on uneasy oscillations (unbehagliche Schwingungen). If it be now considered as estabhshed that in many cases (exceptio confirmat regulam) no other effect of motion can be traced except heat, and that no other cause than motion can be found for the heat that is produced, Ave prefer the assump- tion that heat proceeds from motion, to the assumption of a cause without effect and of an effect without a cause—just as the chemist, instead of aUowing oxygen and hydrogen to dis- appear without further investigation, and water to be pro- duced in some inexplicable manner, establishes a connection between oxygen and hydrogen on the one hand and Avater on the other. The natural connection existing between faUing force, mo- tion, and heat may be conceived of as foUoAvs : We know that heat makes its appearance when the separate particles of a body approach nearer to each other; condensation produces heat. And what applies to the smallest particles of matter, and the smaUest intervals between them, must also apply to large masses and to measurable distances. The falling of a weight is a diminution of the bulk of the earth, and must therefore without doubt be related to the quantity of heat thereby developed; this quantity of heat must be proportional to the greatness of the weight and its distance from the ground. From this point of vieAV we are very easily bd to the equations between falhng force, motion, and heat, that have already been discussed. EQUIVALENCE OF HEAT AND MOTION. 257 But just as little as the connection between falling force and motion authorizes the conclusion that the essence of fall- ing force is motion, can such a conclusion be adopted in the case of heat. We are, on the contrary, rather inclined to infer that, before it can become heat, motion—whether sim- ple, or vibratory as in the case of light and radiant heat, &c, —must cease to exist as motion. If falling force and motion are equivalent to heat, heat must also naturaUy be equivalent to motion and falling force. Just as heat appears as an effect of the diminution of bulk and of the cessation of motion, so also does heat disappear as a cause when its effects are produced in the shape of motion, expansion, or raising of Aveight. In water-mill.-, the continual diminution in bulk which the earth undergoes, OAving to the faU of the water, gives rise to motion, Avhich afterwards disappears again, calling forth un- ceasingly a great quantity of heat; and inversely, the steam- engine serves to decompose heat again into motion or the raising of Aveiglits. A locomotive engine with its train may be compared to a distiUing apparatus ; the heat applied under the boiler passes off as motion, and this is deposited again as heat at the axles of the wheels. We avUI close our disquisition, the propositions of which have resulted as necessary consequences from the principle " causa oequat effectum," and which are in accordance with all the phenomena of Nature, with a practical deduction. The solution of the equations subsisting between faUing force and motion requires that the space faUen through in a given time, e. g. the first second, should be experimentaUy deter- mined ; in like manner, the solution of the equations subsist- ing betAveen falling force and motion on the one hand and heat on the other, requires an ansAver to the question, How great is the quantity of heat Avhich corresponds to a given quantity of motion or faUing force ? For instance, we must ascertain how high a given weight requires to be raised above 25S THE FORCES OF INORGANIC NATURE. the ground in order that its falhng force may be equivalent to the raising of the temperature of an equal weight of water from 0° to 1° C. The attempt to show that such an equa- tion is the expression of a physical truth may be regarded as the substance of the foregoing remarks. By applying the principles that have been set forth to the relations subsisting between the temperature and the volume of gases, we find that the sinking of a mercury column by which a gas is compressed is equivalent to the quantity of heat set free by the compression; and hence it folloAvs, the ratio between the capacity for heat of air under constant pres- sure and its capacity under constant volume being taken as = 1*421, that the warming of a given weight of water from 0° to 1° C. corresponds to the faU of an equal weight from the height Of about 365 metres.* If we compare with this result the working of our best steam-engines, we see hoAv small a part only of the heat apphed under the boUer is really transformed into motion or the raising of weights ; and this may serve as justification for the attempts at the profitable production of motion by some other method than the expendi- ture of the chemical difference between carbon and oxygen— more particularly by the transformation into motion of elec- tricity obtained by chemical means. * When the corrected specific heat of air is introduced into the calcu- lation this number is increased, and agrees then with the experimental de- terminations of Mr. Joule. II CELESTIAL DYNAMICS. I.—INTRODUCTION. ■ EVERY incandescent and luminous body diminishes in temperature and luminosity in the same degree as it radiates hght and heat, and at last, provided its loss be not repaired from some other source of these agencies, becomes cold and non-luminous. For light, like sound, consists of vibrations Avhich are communicated by the luminous or sounding body to a sur- rounding medium. It is perfectly clear that a body can only excite such vibrations in another substance when its own par- ticles undergo a sinhlar movement; for there is no cause for undulatory motion when a body is in a state of rest, or in a state of equilibrium with the medium by which it is sur- rounded. If a beU or a string is to be sounded, an external force must be apphed; and this is the cause of the sound. If the vibratory motion of a string could take place with- out any resistance, it would vibrate for aU time ; but in this case no sound could be produced, because sound is essentially the propagation of motion; and in the same degree as the 200 CELESTIAL DYNAMICS. string communicates its vibrations to the surrounding and re« sisting medium its own motion becomes weaker and weaker, untU at last it sinks into a state of rest. The sun has often and appropriately been compared to an iucessantly sounding beU. But by what means is the power of this body kept up in undiminished force so as to enable him to send forth his rays into the universe in such a grand and magnificent manner? What are the causes which coun- teract or prevent his exhaustion, and thus save the planetary system from darkness and deadly cold ? Some endeavoured to approach " the grand secret," as Sir Wm. Herschel caUs this question, by the assumption that the rays of the sun, being themselves perfectly cold, merely cause the " substance" of heat, supposed to be contained in bodies, to pass from a state of rest into a state of motion, and that in order to send forth such cold rays the sun need not be a hot body, so that, in spite of the infinite development of light, the coohng of the sun was a matter not to be thought of. It is plain that nothing is gained by such an explanation ; for, not to speak of the hypothetical " substance" of heat, assumed to be at one time at rest and at another time in mo- tion, now cold and then hot, it is a weU-founded fact that the sun does not radiate a cold phosphorescent light, but a hght capable of warming bodies intensely; and to ascribe such rays to a cold body is at once at variance Avith reason and experience. Of course such and similar hypotheses could not satisfy the demands of exact science, and I avUI therefore try to ex- plain in a more satisfactory manner than has been done up to this time the connexion between the sun's radiation and its effects. In doing so, I have to claim the indulgence of scien- tific men, who are acquainted with the difficulties of my task. SOURCES OF HEAT. 261 II.—SOURCES OF HEAT. Before we turn our attention to the special subject of this paper, it will be necessary to consider the means by which light and heat are produced. Heat may be obtained from very different sources. Combustion, fermentation, pu- trefaction, slaking of hme, the decomposition of chloride of nitrogen and of gun-cotton, &c. &c, are all of them sources of heat. The electric spark, the voltaic current, friction, per- cussion, and the vital processes are also accompanied by the evolution of this agent. A general law of nature, which knows of no exception, is the foUoAving:—In order to obtain heat, something must be expended; this something, however different it may be in other respects, can always be referred to one of tAvo catego- ries : either it consists of some material expended in a chem- ical process, or of some sort of mechanical Avork. When substances endoAved with considerable chemical af- finity for each other combine chemically, much heat is devel- oped during the process. We shaU estimate the quantity of heat thus set free by the number of kUogrammcs of water which it would heat 1° C. The quantity of heat necessary to raise one kilogramme of water one degree is called a unit of heat. It has been established by numerous experiments that tho combustion of one kilogramme of dry charcoal in oxygen, so as to form carbonic acid, yields 7200 units of heat, which fact may be briefly expressed by saying that charcoal furnishes 7200 ' degrees of heat. Superior coal yields 6000°, perfectly dry wood from 3300° to 3900% sulphur 2700, and hydrogen 34,600° of heat. According to experience, the number of units of heat only depends on the quantity of matter Avhich is consumed, and 202 CELESTIAL DYNAMICS. not on the conditions under Avhich the burning takes place. The same amount of heat is given out Avhether the combus- tion proceeds slowly or quickly, in atmospheric air or in pure oxygen gas. If in one case a metal be burnt in air and the amount of heat directly measured, and in another instance the same quantity of metal be oxidized in a galvanic battery, the heat being developed in some other place—say, the wire which conducts the current,—in both of these experiments the same quantity of heat avUI be observed. The same law also holds good for the production of heat by mechanical means. The amount of heat obtained is only dependent on the quantity of poAver consumed, and is quite independent of the manner in Avhich this power has been ex- pended. If, therefore, the amount of heat which is produced by certain mechanical work is knoAvn, the quantity which AviU be obtained by any other amount of mechanical work can easily be found by calculation. It is of no consequence whether this Avork consists in the compression, percussion, or friction of bodies. The amount of mechanical work done by a force may be expressed by a Aveight, and the height to Avhich this weight would be raised by the same force. The mathematical ex- pression for " work done," that is to say, a measure for this Avork, is obtained by multiplying the height expressed in feet or o'.hcr units by the number of pounds or kilogrammes hfted to this height. We shall take one kilogramme as the unit of weight, and one metre as the unit of height, and we thus obtain the weight of one kilogramme raised to the height of one metre as a unit measure of mechanical work performed. This measure we shaU call a kUogrammetre, and adopt for it the symbol Km. Mechanical work may likewise be measured by the vcio city obtained by a given weight in passing from a state of rest into that of motion. The work done is then expressed by SOURCES OF HEAT. 263 the product obtained by the multiplication of the Aveight by the square of its velocity. The first method, however, be- cause it is the more convenient, is the one usuaUy adopted; and the numbers obtained therefrom may easUy be expressed in other units. The product resulting frcm the multiplication of the num- ber of units of weight and measures of height, or, as it is called, the product of mass and height, as AveU as the pro- duct of the mass and the square of its velocity, are called " vis viva of motion," u mechanical effect," dynamical effect," " work done," " quantite de travail," &c. &c. The amount of mechanical work necessary for the heating of 1 kilogramme of water 1° C has been determined by ex- periment to be = 367 Km; therefore Km = 0*00273 units of heat.* A mass which has faUen through a height of 367 metres possesses a velocity of 84-8 metres in one second; a mass, therefore, moving with this velocity originates 1° C. of heat when its motion is lost by percussion, friction, &c. If the velocity be two or three times as great, 4° or 9° of heat will be developed. Generally speaking, Avhen the velocity is c metres, the corresponding development of heat wiU be ex- pressed by the formula 0-000139° Xc\ * This essay was published in 1845. At that time de la Roche and Berard's determination of the specific heat of air was generally accepted. If the physical constants used by Mayer be corrected according to the re- sults of more recent investigation, the mechanical equivalent of heat is found to be 771*4 foot-pounds. Mr. Joule finds it = 772 foot-pounds,— Tb. 264 CELESTIAL DYNAMICS III.—MEASURE OF THE SUN'S HEAT. The actinometer is an instrument invented by Sir John Herschel for the purpose of measuring the heating efffeci produced by the sun's rays. It is essentially a thermometer with a large cylindrical bulb filled with a blue liquid, which is acted upon by the sun's rays, and the expansion of which is measured by a graduated scale. From observations made with this instrument, Sir Jolin Herschel calculates the amount of heat received from the sun to be sufficient to melt annuaUy at the surface of the globe a crust of ice 29*2 metres in thickness. PouUlet has recently shown by some careful experiments with the lens pyrhehometer, an instrument invented by him- self, that every square centimetre of the surface of our globe receives, on an average, in one minute an amount of solar heat which would raise the temperature of one gramme of water 0*4408°. Not much more than one-half of this quan- tity of heat, however, reaches the sohd surface of our globe, since a considerable portion of it is absorbed by our atmo- sphere. The layer of ice which, according to Pouillet, could be melted by the solar heat which yearly reaches our globe would have a thickness of 30*89 metres. A square metre of our earth's surface receives, therefore, according to PouiUet's results, which we shaU adopt in the following pages, on an average in one minute 4*408 units of heat. The whole surface of the earth is = 9,260,500 geo- graphical square mUes* ; consequently the earth receives in one minute 2247 billions of units of heat from the sun. In order to obtain smaUer numbers, we shaU caU the quantity of heat necessary to raise a cubic mile of water 1° * The geographical mile = 7420 metres, and one English mile —1608 metres. MEASURE OF THE Sun's HEAT. 205 C. in temperature, a cubic mUe of heat. Since one cubic uhle of water weighs 408*54 biUions of kilogrammes, a cubic mUe of heat contains 408*54 biUions of units of heat. The effect produced by the rays of the sun on the surface of the earth in one minute is therefore 5*5 cubic mhes of heat. Let us imagine the sun to be surrounded by a hoUow sphere whose radius is equal to the mean distance of the earth from the sun, or 20,589,000 geographical miles; the surface of this sphere would be equal to 5326 biUions of square miles. The surface obtained by the intersection of this hoUoAv sphere and our globe, or the base of the cone of solar hght which reaches our earth, stands to the whole sur- face of this hoUow sphere as ' 4' : 5326 bilhons, or as 1 to 2300 mUlions. This is the ratio of the heat received by our globe to the whole amount of heat sent forth from the sun, which latter in one minute amounts to 12,650 mUlions of cubic miles of heat. This amazing radiation ought, unless the loss is by some means made good, to cool considerably even a body of the magnitude of the sun. If we assume the sun to be endoAved with the same capa- city for heat as a mass of Avater of the same A-olume, and its loss of heat by radiation to affect uniformly its Avhole mass, the temperature of the sun ought to decrease 1°*S C. yearly, and for the historic time of 5000 years this loss Avould conse- quently amount to 9000° C. A uniform cooling of the whole of the sun's huge mass cannot, however, take place ; on the contrary, if the radiation were to occur at the expense of a given store of heat or ra- diant power, the sun would become covered in a short space of time with a cold crust, Avhereby radiation would be brought to an end. Considering the continued activity of the sun through countless centuries, we may assume with mathemati- cal certainty the existence of some compensating influence to make good its enormous loss. 12 266 CELESTIAL DYNAMICS. Is this restoring agency a chemical process ? If such were the case, the most favourable assumption would be to suppose the whole mass of the sun to be one lump of coal, the combustion of every kilogramme of which produces 6000 units of heat. Then the sun would only bo able to sustain for forty-six centuries its present expenditure of hght and heat, not to mention the oxygen necessary to keep up such an immense combustion, and other unfavourable circumstances. The revolution of the sun on his axis has been suggested as the cause of his radiating energy. A closer examination proves this hypothesis also to be untenable. Rapid rotation, without friction or resistance, cannot in itself alone be regarded as a cause of light and heat, espe- ciaUy as the sun is in no way to be distinguished from the other bodies of our system by velocity of axial rotation. The sun turns on his axis in about twenty-five days, and his diam- eter is nearly 112 times as great as that of the earth, from which it foUows that a point on the solar equator travels but a httle more than four times as quickly as a point on the earth's equator. The largest planet of the solar system, whose diameter is about f0th that of the sun, turns on its axis in less than ten hours ; a point on its equator revolves about six times quicker than one on the solar equator. The outer rino" of Saturn exceeds the sun's equator more than ten times in velocity of rotation. Nevertheless no generation of light or heat is observed on our globe, on Jupiter, or on the ring of Saturn. It might be thought that friction, though undeveloped in the case of the other celestial bodies, might be engende ed by the sun's rotation, and that such friction might generate enor- mous quantities of heat. But for the production of friction two bodies, at least, are always necessary which are in imme- diate contact Avith one another, and which move with differ- ent velocities or in different directions. Friction, moreover MEASURE OF THE SUN's HEAT. 267 has a tendency to produce equal motion of the two rubbing bodies; and when this is attained, the generation of heat ceases. If now the sun be the one moving body, where is the other? and if the second body exist, what poAver prevents it from assuming the same rotary motion as the sun? But could even these difficulties be disregarded, a weight- ier and more formidable obstacle cpposes this hypothesis. The known volume and mass of the sun aUoAv us to calculate the vis viva which he possesses in consequence of his rotation. Assumjng his density to be uniform throughout his mass, and his period of rotation twenty-five days, it is equal to 182,300 quintiUions of kilogrammetres (Km). But for one unit of heat generated, 367 Km are consumed; consequently the whole rotation-effect of the sun could only cpArer the expendi- ture of heat for the space of 183 years. The space of our solar system is fiUed with a great num- ber of ponderable objects, which have a tendency to move towards the centre of gravity of the sun; and in so doing, their rate of motion is more and more accelerated. A mass, without motion, placed within the sphere of the sun's attraction, wiU obey this attraction, and, if there be no disturbing influences, AviU fall in a straight hne into the sun. In reahty, however, such a rectihnear path can scarcely occur, as may be shown by experiment. Let a weight be suspended by a string so that it can only touch the floor in one point. Lift the weight up to a certain height, and at the same time stretch the string out to its full length; if the Aveight be now aUoAved to faU, it will be ob- served, almost in every case, not to reach at once the point on the floor toAvards Avhich it tends to move, but to move round this point for some time in a curved hne. The reason of this phenomenon is that the slightest devia- tion of the weight from its shortest route towards the point on the floor, caused by some disturbing influence such as the resistance of the air against a not perfectly uniform surface, 2G8 CELESTIAL DYNAMICS. wiU maintain itself as long as motion lasts. It is neverthe- less possible for the weight to move at once to the point; the probability of its doing so, however, becomes the less as the height from which it is aUowed to drop increases, or the string, by means of which it is suspended, is lengthened. SimUar laAvs influence the movements of bodies in the space of the solar system. The. height of the faU is here represented by the original distance from the sun at which the body begins to move ; the length of the string by the sun's attraction, which increases when the distance decreases ; and the smaU surface of contact on the floor by the area of the section of the sun's sphere. If now a cosmical mass within the physical limits of the sun's sphere of attraction begins its faU toAvards that heavenly body, it AviU be disturbed in its long path for many centuries, at first by the nearest fixed stars, and afterwards by the bodies of the solar system. Motion of such a mass in a straight line, or its perpendicular faU into the sun, would, therefore, under such conditions, be impossible. The observed movement of aU planetary bodies in closed curves agrees with this. We shaU now return to the example of the weight sus- pended by a string and oscillating round a point towards which it is attracted. The diameters of the orbits described by this weight are observed to be nearly equal; continued ob- servation, however, shows that these diameters gradually di- minish in length, so that the weight wiU by degrees approach the point in which it can touch the floor. The weight, how- ever, touches the floor not in a mathematical point, but in a smaU surface ; as soon, therefore, as the diameter of the curve- in which the weight moves is equal to the diameter of this surface, the weight wUl touch the floor. This final contact is no accidental or improbable event, but a necessary phenome- non caused by the resistance which the osciUating mass con- stantly suffers from the air and friction. If aU resistance could be annihUated, the motion of the weight would of course continue in equal oscillations. MEASURE OF THE SCx's I1EAT. 209 The same laAv holds good for celestial bodies. The movements of celestial bodies in an absolute vacuum would be as uniform as those of a mathematical pendulum, Avhereas a resisting medium pervading all space would cause the planets to move in shorter and shorter orbits, and at last to fall into the sun. Assuming such a resisting medium, these Avaudering ce- lestial bodies must have on the periphery of the solar system their cradle, and in its centre their grave ; and however long the duration, and however great the number of their revolu- tions may be, as many masses Avill on the average in a cer- tain time arrive at the sun as formerly in a like period of time came within his sphere of attraction. All these bodies plunge with a violent impetus into their common grave. Since no cause exists Avithout an effect, each of these cosmical masses wUl, hke a Aveight faUing to the earth, produce by its percussion an amount of heat propor- tional to its vis viva. From the idea of a sun whose attraction acts throughout space, of ponderable bodies scattered throughout the universe, and of a resisting aether, another idea necessarhy follows— that, namely, of a continual and inexhaustible generation of heat on the central body of this cosmical system. "Whether such a conception be reahzed in our solar system —Avhether, in other words, the wonderful and permanent evo- lution of hght and heat be caused by the uninterrupted fall of cosmical matter into the sun—Avill now be more closely examined. The existence of matter in a primordial condition ( Urma- terie), moAdng about in the universe, and assumed to foUow the attraction of the nearest stellar system, will scarcely be denied by astronomers and physicists; for the richness of surrounding nature, as Avell as the aspect of the starry heav- ens, pre\ents the belief that the wide space which separates our solar system from the regions governed by the other fixed 270 CELESTIAL DYNAMICS stars is a vacant solitude destitute of matter. We shaU leave, however, aU suppositions concerning subjects so distant from us both in time and space, and confine our attention ex- clusively to what may be learnt from the observation of the existing state of things. Besides the fourteen known planets with their eighteen satelhtes, a great many other cosmical masses move within the space of the planetary system, of Avhich the comets de- serve to be mentioned first. Kepler's celebrated statement that " there are more com- ets in the heavens than fish in the ocean," is founded on the fact that, of aU the comets belonging to our solar system, comparatively few can be seen by the inhabitants of the earth, and therefore the not inconsiderable number of actuaUy ob- served comets obhges us, according to the rules of the calcu- lus of probabUities, to assume the existence of a great many more beyond the sphere of our vision. Besides planets, sateUites, and comets, another class of celestial bodies exists within our solar system. These are masses which, on account of their smaUness, may be consid- ered as cosmical atoms, and which Arago has appropriately caUed asteroids. They, hke the planets and the comets, are governed by gravity, and move in elliptical orbits round the sun. When accident brings them into the immediate neigh- • bourhood of the earth, they produce the phenomena of shoot- ing-stars and fireballs. It has been shoAvn by repeated observation, that on a bright night twenty minutes seldom elapse without a shooting- star being visible to an observer in any situation. At certain times these meteors are observed in astonishingly great num- bers ; during the meteoric shower at Boston, which lasted nine hours, when they were said to fall " crowded together like snoAv-flakes," they were estimated as at least 240,000. On the whole, the number of asteroids Avhich come near the earth in the space of a year must be computed to be many MEASURE OF THE SUx'fi HEAT. ^71 thousands of miUions. This, without doubt, is only a smaU fraction of the number of asteroids that move round the sun, Avhich number, according to the rules of the calculus of prob- abilities, approaches the infinite. As has been already stated, on the existence of a resisting asther it depends whether the celestial bodies, the planets, the comets, and the asteroids, move at constant mean distances round the sun, or whether they are constantly approaching that central body. Scientific men do not doubt the existence of such an aether. Littrow, amongst others, expresses himself on this point as follows :—" The assumption that the planets and the comets move in an absolute vacuum can in no way be admitted. Even if the space between celestial bodies contained no other matter than that necessary for the existence of light (whether light be considered as emission of matter or the undulations of a uniArersal aether), this alone is sufficient to alter the mo- tion of the planets in the course of time and the arrangement of the whole system itself; the faU of all the planets and the comets into the sun and the destruction of the present state of the solar system must be the final results of this action." A direct proof of the existence of such a resisting medium has been furnished by the academician Encke. He found that the comet named after him, which revolves round the sun in the short space of 1207 days, shows a regular acceler- ation of its motion, in consequence of which the time of each revolution is shortened by about six hours. From the great density and magnitude of the planets, the shortening of the diameters of their orbits proceeds, as might be expected, very slowly, and is up to the present time inap- preciable. The smaUer the cosmical masses are, on the con- trary, other circumstances remaining the same, the faster they move towards the sun; it may therefore happen that in a space of time wherein the mean distance of the earth from the sun would diminish one metre, a smaU asteroid would 272 CELESTIAL. DYNAMICS. travel more than one thousand mUes toAvards the central body. As cosmical masses stream from aU sides in immense numbers towards the sun, it follows that they must become more and more croAvded together as they approach thereto. The conjecture at once suggests itself that the zodiacal light, the nebulous light of vast dimensions which surrounds the sun, owes its origin to such closely-packed asteroids. Hoav- ever it may be, this much is certain, that this phenomenon is caused by matter Arhich moves according to the same laws as the planets round the sun, and it consequently foUows that the whole mass which originates the zodiacal light is contin- uaUy approaching the sun and faUing into it. This hght does not surround the sun uniformly on aU sides ; that is to say, it has not the form of a sphere, but that of a thin convex lens, the greater diameter of which is in the plane of the solar equator, and accordingly it has to an ob- server on our globe a pyramidal form. Such lenticular dis- tribution of the masses in the universe is repeated in a re- markable manner in- the disposition of the planets and the fixed stars. From the great number of cometary masses and asteroids and the zodiacal light on the one hand, and the existence of a resisting aether on the other, it necessarily foUows that pon- derable matter must continually be arriving on the solar sur- face. The effect produced by these masses evidently depends on their final velocity ; and, in order to determine the latter, we shall discuss some of the elements of the theory of gravitation. The final velocity of a weight attracted by and moving towards a celestial body AviU become greater as the height through which the weight faUs increases. This velocity, how- ever, if it be only produced by the fall, cannot exceed a cer- tain magnitude ; it has a maximum, the value of which de- pends on the volume and mass of the attracting celostial body MEASURE OF THE SUN's HEAT. 273 Let r be the radius of a spherical and sohd celestial body. and g the velocity at the end of the first second of a weighi faUing on the surface of this body ; then the greatest velocity which this weight can obtain by its faU toAvards the celestial body, or the velocity with wliich it will arrive at its surface after a faU from an infinite height, is \/2gr in one second. This number, wherein g and r are expressed in metres, we Bhall caU G. For our globe the Aralue of g is 9*8164 . . and that of f 6,369,800 ; and consequently on our earth G = {/(2x 9*8164x6,369,800) = 11,183. The solar radius is 112'05 times that of the earth, and the velocity produced by gravity on the sun's surface is 28*36 times greater than the same velocity on the surface of our globe *, the greatest velocity therefore which a body could ob- tain in consequence of the solar attraction, or G= t/(28*36X 112*05) X 11,183 = 630,400; that is, this maximum velocity is equal to 630,400 metres, or 85 geographical mUes in one second. By tlie help of this constant number, Avhich may be called the characteristic of the solar system, the velocity of a body in central motion may easily be determined at any point of its orbit. Let a be the mean distance of the planetary body from the centre of gravity of the sun, or the greater semidiameter of its orbit (the radius of the sun being taken as unity) ; and let h be the distance of the same body at any point of its orbit from the centre of gravity of the sun; then the velocity, expressed in metres, of the planet at the distance h is /2a -h GXV~2aXh- At the moment the planet comes in contact with the solar sur face, h is equal to 1, and its velocity is therefore /2a-1 274 CELESTIAL DYNAMICS. It follows from this formula that the smaUer 2a (or th« major axis of the orbit of a planetary body) becomes, the less will be its velocity when it reaches the sun. This velo- city, like the major axis, has a minimum ; for so long as the planet moves outside the sun, its major axis cannot be shorter than the diameter of the sun, or, taking the solar radius as a unit, the quantity 2a can never be less than 2. The smallest velocity with which Ave can imagine a cosmical body to arrive on the surface of the sun is consequently GrX|/|=445,750, or a velocity of 60 geographical miles in one second. For this smaUest value the orbit of the asteroid is circu« lar ; for a larger value it becomes eUiptical, untU finally, with increasing excentricity, when the value of 2a approaches in- finity, the orbit becomes a parabola. In the last case tho velocity is or, 85 geographical miles in one second. BT the value of the major axis become negative, or the orbit assume the form of a hyperbola, the velocity may in- crease without end. But this could only happen when cosmi- cal masses enter the space of the solar system with a pro- jected velocity, or when masses, having missed the sun's sur- face, move into the universe and never return; hence a Are- locity greater than G can only be regarded as a rare excep- tion, and we shaU therefore only consider velocities comprised within the limits of 60 and 80 mUes.* The final velocity with which a weight moving in a * The relative velocity also with which an asteroid reaches the solar surface depends in some degree on the velocity of the sun's rotation. This, however, as well as the rotatory effect of the asteroid, is without moment, rmd may be neglected. MEASURE OF THE SUN's HEAT. 275 straight hne towards the centre of the sun arrives at the solar surface is expressed by the formula C-GX4/EI, wherein c expresses the final velocity in metres, and h the original distance from the centre of the sun in terms of solar radius. If this formula be compared with the foregoing, it avUI be seen that a mass which, after moving in central mo- tion, arrives at the sun's surface has the same velocity as it would possess had it fallen perpendicularly into the sun from a distance* equal to the major axis of its orbit; whence it is apparent that a planet, on arriving at the sun, moves at least as quickly as a Aveight which falls freely towards the sun from a distance as great as the solar radius, or 96,000 geo- graphical nines. What thermal effect corresponds to such velocities ? Is the effect sufficiently great to play an important part in the immense development of heat on the sun ? This crucial question may be easily answered by help of the preceding considerations. According to the formula given at the end of Chapter II., the degree of heat generated by percussion is = 0*000139° Xc2, where c denotes the velocity of the striking body expressed in metres. The velocity of an asteroid when it strikes the sun measures from 445,750 to 630,400 metres ; the caloric effect of the percussion is consequently equal to from 27| to 55 mil- lions of degrees of heatf. An asteroid, therefore, by its faU into the sun developes * This distance is to be counted from the centre of the sun. f Throughout this memoir the degrees of heat are expressed in the Centigrade scale. Unless stated to the contrary, the measures of length are given in geographical miles. A geographical mile = 7420 metres, and an English mile = 1608 metres.—Ta. 276' CELESTIAL DYNAMICS. from 4600 to 9200 times as much heat as would be generated by the combustion of an equal mass of coal. IT.—ORIGIN OF THE SUN'S HEAT. The question why the planets move in curved orbits, ont of the grandest of problems, was solved by Newton in con- sequence, it is beheved, of his reflecting on the faU of an ap- ple. This story is not improbable, for we are on the right track for the discovery of truth when once we clearly recog- nize that between great and smaU no qualitative but only a quantitative difference exists—when Ave resist the suggestions of an ever active imagination, and look for the same laws in the greatest as weU as in the smallest processes of nature. This universal range is the essence of a law of nature, and the touchstone of the correctness of human theories. We observe the fall of an apple, and investigate the law which governs this phenomenon; for the earth we substitute the sun, and for the apple a planet, and thus possess ourselves of the key to the mechanics of the hea\Tens. As the same laAvs prevail in the greater as well as in the smaller processes of nature, Newton's method may be used in solving the problem of the origin of the sun's heat. We know the connexion between the space through which a body falls, the velocity, the vis viva, and the generation of heat on the surface of this globe; if Ave again substitute for the earth the sun, with a mass 350,000 greater, and for a height of a f^AV metres celestial distances, we obtain a generation of heat exceeding aU terrestrial measures. And since we have suffi- cient reason to assume the actual existence of such mechani- cal processes in the heavens, we find therein the only tenable explanation of the origin of the heat of the sun. ORIGIN OF TNE SEN S HEAT. 277 The fact that the development of heat by mechanical means on the surface of our globe is, as a rule, not so great, and cannot be so great as the generation of the same agent by chemical means, as by combustion, foUows from the laws already discussed; and this fact cannot be used as an argu- ment against the assumption of a greater development of heat by a greater expenditure of mechanical work. It has been shown that the heat generated by a weight faUing from a height of 367 metres is only ^th part of the heat pro- duced by the combustion of the same weight of coal; just as smaU is the amount of heat developed by a weight moving with the not inconsiderable velocity of 85 metres in one sec- ond. But, according to the laws of mechanics, the effect is proportional to the square of the velocity; if therefore the Aveight move 100 times faster, or with a \-elocity of 8500 metres in one second, it wiU produce a greater effect than the combustion of an equal quantity of coal. It is true that so great a velocity cannot be obtained by human means ; everyday experience, however, shoAvs the de- velopment of high degrees of temperature by mechanical processes. In the common flint and steel, the particles of steel which are struck off are sufficiently heated to burn in air. A few blows directed by a skUful blacksmith with a sledge-hammer against a piece of cold metal may raise the temperature of the metal at the points of collision to redness. The new crank of a steamer, whUst being polished by friction, becomes red-hot, several buckets of water being re- quired to cool it down to its ordinary temperature. When a rahway train passes with even less than its ordi- nary velocity along a very sharp curve of the hne, sparks are observed in consequence of the friction against the rails. One of the grandest constructions for the production of motion by human art is the channel in which the wood was allowed to glide down from the steep and lofty sides of Mount 278 CELESTIAL DYNAMICS. PUatus into the plain below. This wooden channel which was built about thirty years ago by the engineer Rupp, was 9 Enghsh mUes in length ; the largest trees were shot down it from the top to the bottom of the mountain in about two minutes and a half. The momentum possessed by the trees on their escaping at their journey's end from the channel was sufficiently great to bury their thicker ends in the ground to the depth of from 6 to 8 metres. To prevent the wood get- ting too hot and taking fire, water was conducted in many places into the channel. This stupendous mechanical process, Avhen compared with cosmical processes on the sun, appears infinitely small. In the latter case it is the mass of the sun which attracts, and in lieu of the height of Mount PUatus we lurve distances of a hundred thousand and more miles ; the amount of heat gene- rated by cosmical faUs is therefore at least 9 million times greater than in our terrestrial example. Rays of heat on passing through glass and other transpa- rent bodies undergo partial absorption, which differs in de- gree, however, according to the temperature of the source from which the heat is derived. Heat radiated from sources less warm than boiling water is almost completely stopped by thin plates of glass. As the temperature of a source of heat increases, its rays pass more copiously through diathermic bodies. A plate of glass, for example, weakens the rays of a red-hot substance, even when the latter is placed very close to it, much more than it does those emanating at a much greater distance from a white-hot body. If the quahty of the sun's rays be examined in this respect, their diathermic energy is found to be far superior to that of aU artificial sources of heat. The temperature of the focus of a concave metallic reflector in which the sun's light has been collected is only diminished from one-seventh to one-eighth by the in- terposition of a screen of glass. If the same experiment be ORIGIN OF THE SUN'S HEAT. 270 made with an artificial and luminous source of heat, it is found that, though the focus be very hot when the screen is away, the interposition of the latter cuts off nearly all the heat; moreover, the focus wUl not recover its former temper- ature Avhen reflector and screen are placed sufficiently near to the source of heat to make the focus appear brighter than it did in the former position Avithout the glass screen. The empirical law, that the diathermic energy of heat in« creases Avith the temperature of the source from which the heat is radiated, teaches us that the sun's surface must be much hotter than the most powerful process of combustion could render it. Other methods furnish the same conclusion. If we ima- gine the sun to be surrounded by a hollow sphere, it is clear that the inner surface of this sphere must receive aU the heat radiated from the sun. At the distance of our globe from the Bun, such a sphere would have a radius 215 times as great, and an area 46,000 times as large as the sun himself; those luminous and calorific rays, therefore, Avhich meet this spheri- cal surface at right angles retain only jg-oooth part of their original intensity. If it be further considered that our at- mosphere absorbs a part of the solar rays, it is clear that the rays which reach the tropics of our earth at noonday can only possess from j^bth to wjwoth of the poAver with which they started. These rays, when gathered from a surface of from 5 to 6 square metres, and concentrated in an area of one square centimetre, would produce about the temperature which exists on the sun, a temperature more than sufficient to vaporize platinum, rhodium, and similar metals. The radiation calculated in Chapter HI. likewise proves the enormous temperature of the solar surface. From the determination mentioned therein, it follows that each square centimetre of the sun's surface loses by radiation about 80 units of heat per minute—an immense quantity in compari- son with terrestrial radiations. 250 CELESTIAL DYNAMICS. A correct theory of the origin of the sun's heat must ex- plain the cause of such enormous temperatures. This expla- nation can be deduced from the foregoing statements. Ac- cording to PouUlct, the temperature at which bodies appear intensely white-hot is about 1500° C. The heat generated by the combustion of one kilogramme of hydrogen is, as deter- mined by Dulong, 34,500, and according to the more recent experiments of Grassi, 34,666 units of heat. One part of hydrogen combines with eight parts of oxygen to form water ; hence one kUogramme of these two gases mixed in this ratio would produce 3850°. Let us now compare this heat with the amount of the same agent generated by the fall of an asteroid into the sun. Without taking into account the low specific heat of such masses when compared with that of Avater, Ave find the heat developed by the asteroid to be from 7000 to 15,000 times greater than that of the oxyhydrogen mixture. From data like these, the extraordinary diathermic energy of the sun's rays, the immense radiation from his surface, and the high temperature in the focus of the reflector are easily accounted for. The facts above mentioned show that, unless Ave assume on the sun the existence of matter Avith unheard of chemical properties as a deus ex machine}, no chemical process could maintain the present high radiation of the sun; it also fol- Ioavs from the above results, that the chemical nature of bo- dies which fall into the sun does not in the least affect our conclusions; the effect produced by the most inflammable substance would not differ by one-thousandth part from that resulting from the fall of matter possessing but feeble chemi- cal affinities. As the brightest artificial hght appears dark in comparison Avith the sun's light, so the mechanical processes of the heavens throw into the shade the most powerful chem- ical actions. The quality of the sun's rays, as dependent on his temper ORIGIN OF THE SUN S HEAT. 281 ature, is of the greatest importance to mankind. If the solai heat Avere originated by a chemical process, and amounted near its source to a temperature of a few thousand degrees. it Avould be possible for the light to reach us, whUst the greater part of the more important calorific rays would be ab- sorbed by the higher strata of our atmosphere and then re- turned to the universe. In consequence of the high temperature of the sun, how- ever, our atmosphere is highly diathermic to his rays, so that the latter reach the surface of our earth and warm it. The comparatively low temperature of the terrestrial surface is the cause why the heat cannot easUy radiate back through the atmosphere into the universe. The atmosphere acts, there- fore, like an envelope, which is easily pierced by the solar rays, but which offers considerable resistance to the radiant heal, escaping from our earth ; its action resembles that of a vah-e which aUows liquid to pass freely in one, but stops the Aoav in the opposite direction. The action of the atmosphere is of the greatest impor- tance as regards climate and meteorological processes. It must raise the mean temperature of the earth's surface. Af- ter the setting of the sun—in fact, in aU places Avherc his rays do not reach the surface, the temperature of the earth would soon be as low as that of the universe, if the atmos- phere were removed, or if it did not exist. Even the power- ful solar rays in the tropics would be unable to preserve wa- ter in its hquid state. Between the great cold which Avould reign at all times and in all places, and the moderate warmth which in reality exists on our globe, intermediate temperatures may be ima- gined ; and it is easUy seen that the mean temperature would decrease if the atmosphere were to become more and more rare. Such a rarefaction of a valve-like acting atmosphere actuaUy takes place as we ascend higher and higher above 282 CELESTIAL DYNAMICS. the level of the sea, and it is accordingly and necessarily ao companied by a corresponding diminution of temperature. This weU-known fact of the lower mean temperature of places of greater altitude has led to the strangest hypotheses. The sun's rays were not supposed to contain aU the condition? for warming a body, but to set in motion the "substance' of heat contained in the earth. This "substance" of heat, cold when at rest, was attracted by the earth, and Avas there- fore found in greater abundance near the centre of the globe. This vieAV, it Avas thought, explained why the warming power of the sun was so much weaker at the top of a mountain than at the bottom, and why, in spite of his immense radiation, he retained his fuU powers. This belief, which especiaUy prevails amongst imperfectly informed people, and which will scarcely succumb to correct views, is directly contradicted by the excellent experiments made by PouiUet at different altitudes with the pyrheliometer. These experiments show that, everything else being equal, the generation of heat by the solar rays is more powerful in higher altitudes than near the surface of our globe, and that consequently a portion of these rays is absorbed on their pas- sage through the atmosphere. Why, in spite of this partial absorption, the mean temperature of low altitudes is never- theless higher than it is in more elevated positions, is ex- plained by the fact that the atmosphere stops to a far greater degree the calorific rays emanating from the earth than it does those from the sun. V.—CONSTANCY OF THE SUN'S MASS. Newton, as is weU known, considered light to be the amission of luminous particles from the sun. In the contin- ued emission of light this great phUosopher saw a cause tend- CONSTANCY OF THE SUn's MASS. 233 ing to diminish the solar mass ; and he assumed, in order to make good this loss, comets and other cosmical masses to be continually falhng into the central body. If Ave express this vieAV of Newton's in the language of the undulatory theory, which is now universally accepted, we obtain the results developed in the preceding pages. It is true that our theory does not accept a pecuhar " substance " of light or of heat; nevertheless, according to it, the radia- tion of hght and heat consists also in purely material pro- cesses, in a sort of motion, in the vibrations of ponderable resisting substances. Quiescence is darkness and death ; mo- tion is light and life. An undulating motion proceeding from a point or a plane and excited in an unlimited medium, cannot be imagined apart from another simultaneous motion, a translation of the parti- cles themselves ;* it therefore follows, not only from the emis- sion, but also from the undulatory theory, that radiation con- tinually diminishes the mass of the sun. Why, nevertheless, the mass of the sun does not really diminish has already been stated. The radiation of the sun is a centrifugal action equivalent to a centripetal motion. The caloric effect of the centrifugal action of the sun can be found by direct observation; it amounts, according to Chapter III., in one minute to 12,650 millions of cubic miles of heat, or 5*17 quadrillions of units of heat. In Chapter PV. it has been shown that one kilogramme of the mass of an asteroid originates from 27*5 to 55 millions of units of heat; the quantity of cosmical masses, therefore, which falls every minute into the sun amounts to from 94,000 to 188,000 bil- lions of kilogrammes. To obtain this remarkable result, we made use of a method * This centrifugal motion is perhaps the cause of the repulsion of the tails on comets when in the neighbourhood of the sun, as observed by Bcssel 284 CELESTIAL DYNAMICS. which is common in physical inquiries. Observation of the moon's motion reveals to us the external form of the earth. The physicist determines with the torsion-balance the weight of a planet, just as the merchant finds the Aveight of a parcel of goods, whUst the pendulum has become a magic power in the hands of the geologist, enabhng him to discover cavities in the bowels of the earth. Our case is similar to these. By obsenration and calculation of the velocity of sound in our atmosphere, we obtain the ratio of the specific heat of air un- der constant pressure and under constant volume, and by the help of this number Ave determine the quantity of heat gene- rated by mechanical work. The heat Avhich arrives from the sun in a given time on a smaU surface of our globe serves as a basis for the calculation of the whole radiating effect of the sun; and the result of a series of observations and weU- founded conclusions is the quantitative determination of those cosmical masses which, the sun receives from the space through which he sends forth his rays. Measured by terrestrial standards, the ascertained number of so many biUions of kUogrammes per minute appears in- credible. This quantity, however, may be brought nearer to our comprehension by comparison with other cosmical mag- nitudes. The nearest celestial body to us (the moon) has a mass of about 90,000 trillions of kilogrammes, and it would therefore cover the expenditure of the sun for from one to two years. The mass of the earth would afford nourishment to the sun for a period of from 60 to 120 years. To facilitate the appreciation of the masses and the dis- tances occurring in the planetary system, Herschel draws the foUowing picture. Let the sun be represented by a globe 1 metre in diameter. The nearest planet (Mercury) wiU be about as large as a pepper-corn, 3£ millimetres in thickness, at a distance of 40 metres. 78 and 107 metres distant from the sun will move Venus and the Earth, each 9 miUimetres in diameter, or a little larger than a pea. Not much more than CONSTANCY OF THE SUNS MASS. 285 a quarter of a metre from the Earth wiU be the Moon, th. size of a mustard seed, 21 millimetres in diameter. Mars, at a distance of 160 metres, wiU have about half the diame- ter of the Earth ; and the smaller planets (Vesta, Hebe, As trea, Juno, PaUas, Ceres, &c), at a distance of from 250 to 300 metres from the sun, will resemble particles of sand. Jupiter and Saturn, 560 and 1000 metres distant from the cen- tre, AviU be represented by oranges, 10 and 9 centimetres in diameter. Uranus, of the size of a nut 4 centimetres across, AviU be 2000 metres; and Neptune, as large as an apple 6 centimetres in diameter, Avill be nearly twice as distant, or about half a geographical mile aAvay from the sun. From Neptune to the nearest fixed star AviU be more than 2000 geo- graphical miles. To complete this picture, it is necessary to imagine finely divided matter grouped in a diversified manner, moving sIoaa'Tv and graduaUy towards the large central globe, and on its ar- rival attaching itself thereto; this matter, when favourably illuminated by the sun, represents itself to us as the zodiacal light. This nebulous substance forms also an important part of a creation in which nothing is by chance, but Avherein aU Is arranged Avith Divine foresight and wisdom. The surface of the sun measures 115,000 millions of square mUes, or 61 trilhons of square metres; the mass of matter which in the shape of asteroids falls into the sun every. minute is from 94,000 to 188,000 billions of kilogrammes; one square metre of solar surface, therefore, receives on an average from 15 to 30 grammes of matter per minute. To compare this process Avith a terrestrial phenomenon, a gentle rain may be considered which sends down in one hour a layer of water 1 millimetre in thickness (during a thunder- storm the rainfall is often from ten to fifteen times this quan- tity) ; this amounts on a square metre to 17 grammes per minute. 286 CELESTIAL DYNAMICS. The continual bombardment of the sun by these cosmical masses ought to increase its volume as weU as its mass, if centripetal action only existed. The increase of volume, could scarcely be appreciated by man ; for if the specific grav- ity of these cosmical masses be assumed to be the same as that of the sun, the enlargement of his apparent diameter to the extent of one second, the smaUest appreciable magnitude, would require from 33,000 to 66,000 years. Not quite so inappreciable would be the -increase of the mass of the sun. If this mass, or the weight of the sun, were augmented, an acceleration of the motion of the planets in their orbits Avould be the consequence, whereby their times of revolution round the central body would be shortened. The mass of the sun is 2*1 quintillions of kilogrammes; and the mass of the cosmical matter annually arriving at the sun stands to the above as 1 to from 21 ^42 mUlions. Such an augmentation of the weight of the sun ought to shorten the sidereal year from i^oobth to sT.ooo^ooti1 of its length, or from |ths to ^ths of a second. The observations of astronomers do not agree with this conclusion ; we must therefore faU back on the theory men- tioned at the beginning of this chapter, which assumes that the sun, like the ocean, is constantly losing and receiving equal quantities of matter. This harmonizes with the suppo- sition that the vis viva of the universe is a constant quantity. VI—THE SPOTS ON THE SUN'S DISC. The solar disc presents, according to Sir John Herschel, the following appearance. " When the sun is observed through a powerful telescope provided with coloured glasses in order to lessen the heat and brightness which would be THE SPOTS ON THE SUN's DISC. 287 hurtful to the eyes, large dark spots are often seen surrounded by edges which are not quite so dark as the spots themselves, and which are called penumbras. These spots, however, are neither permanent nor unchangeable. When observed from day to day, or even from hour to hour, their form is seen to change ; they expand or contract, and finaUy disappear; on other parts of the solar surface new spots spring into exists ence Avhere none could be discovered before. When they dis- appear, the darker part in the middle of the spot contracts to a point and vanishes sooner than the edge. Sometimes they break up into two or more parts that show aU the signs of mobUity characteristic of a liquid, and the extraordinary commotion Avhich it seems only possible for gaseous matter to possess. The magnitude of their motion is very great. An arc of 1 second, as seen from our globe, corresponds to 465 English miles on the sun's disc; a circle of this diameter, which measures nearly 220,000 English square mUes, is tho smallest area that can be seen on the solar surface. Spots, hoAvever, more than 45,000 English miles in diameter, and, if Ave may trust some statements, of even greater dimensions, have been observed. For such a spot to disappear in the course of six Aveeks (and they rarely last longer), the edges, whilst approaching each other, must move through a space of more than 1000 miles per diem. " That portion of the solar disc Avhich is free from spots is by no means uniformly bright. Over it are scattered small dark spots or pores, which are found by careful observation to be in a state of continual change. The slow sinking of some chemical precipitates in a transparent liquid, Avhen vieAved from the upper surface and in a direction perpendicu- lar thereto, resembles more accurately than any other phe- nomenon the changes Avhich the pores undergo. The similar- ity is so striking, in fact, that one can scarcely resist the idea tliat the appearances above described are owing to a luminous medium moving about in a non-luminous atmosphere, either 288 CELESTIAL DYNAMICS. hke the clouds in our air, or in wide-spread planes and flame- like columns, or in rays hke the aurora borealis. " Near large spots, or extensive groups of them, large spaces are observed to be covered with pecuharly marked lines much brighter than the other parts of the surface ; these lines are curved, or deviate in branches, and are caUed facuh.?. Spots are often seen betAveen these lines, or to originate there. These are in aU probabihty the crests of immense waves in the luminous regions of the solar atmosphere, and bear wit- ness to violent action in their immediate neighbourhood." The changes on the solar surface evidently point to the action of some external disturbing force; for eATery moving power resident in the sun itself ought to exhaust itself by its own action. These changes, therefore, are no unimportant confirmation of the theory explained in these pages. At the same time it must be observed that our knowledge of physical hehography is, from the nature of the subject. very limited; even the meteorological processes and other phe- nomena of our own planet are stiU in many respects enigmat- ical. For this reason no special information could be giAren about the manner in which the solar surface is affected by cosmical masses. However, I may be aUowed to mention some probable conjectures which offer themselves. The extraordinarily high temperature which exists on the sun almost precludes the possibility of its surface being solid ; it doubtless consists of an uninterrupted ocean of fiery fluid matter. This gaseous envelope becomes more rarefied in those parts most distant from the sun's centre. As most substances are able to assume the gaseous state of aggregation at high temperatures, the height of the sun's atmosphere cannot be inconsiderable. There are, however, sound reasons for believing that the relative height of the so- /ar atmosphere is not very great. Since the gravity is 28 times greater on the sun's surface ;har it is on our earth, a column of air on the former must THE SPOTS ON THE SUN's DISC. 289 cause a pressure 28 times greater than it would on our globe. This great pressure compresses air as much as a tem- perature of 8000° would expand it. In a stUl greater degree than this increased gravity do the qualities peculiar to gases affect the height of the solar atmo- sphere. In consequence of these properties, the density of our atmosphere rapidly diminishes as we ascend, and increases as wc descend. Generally speaking, rarefaction increases in a geometrical progression when the heights are in an arith- metical progression. If we ascend or descend 2\, 5, or 30 miles, Ave find our atmosphere 10, 100, or a billion times more rarefied or more dense. This law, although modified by the unequal temperatures of the different layers of the photosphere, and the unknown chemical nature of the substances of which it is composed, must also hold good in some measure for the sun. As, how- ever, the mean temperature of the solar atmosphere must considerably exceed that of our atmosphere, the density of the former wiU not vary so rapidly Avith the height as the latter does. If we assume this increase and decrease on the sun to be ten times sloAver than it is on our earth, it follows that at the heights of 25, 50, and 300 miles, a rarefaction of 10, 100, and a billion times respectively would be observed. The solar atmosphere, therefore, does not attain a height of 400 geographical mhes, or it cannot be as much as 240th of the sun's radius. For if we take the density of the loAvest strata of the sun's atmosphere to be 1000 times greater that that of our OAvn near the level of the sea, a density greater than that of Avater, and necessarily too high, then at a height of 400 miles this atmosphere would be 10 billion times less dense than the earth's atmosphere; that is to say, to human com- prehension it has ceased to exist. This discussion shows that the solar atmosphere, in com- parison with the body of the sun, has only an insignificant height; at the same time it may be remarked that on the 13 290 CELESTIAL DYNAMICS. sun's surface, in spite of the great heat, such substances aa water may possibly exist in the hquid state under a pressure thousands of times greater than that of our atmosphere. Since gases, when free from any solid particles, emit, even at very high temperatures, a pale transparent hght—the so- caUed lumen philosophicum—it is probable that the intense Avhite light of the sun has its origin in the denser parts of his surface. If such be assumed to be the case, the sun's spots and faculaj seem to be the disturbances of the fiery liquid ocean, caused by most powerful meteoric processes, for which all necessary materials are present, and partly to be caused by the direct influence of streams of asteroids. The deeper and less heated parts of this fiery ocean become thus exposed, and perhaps appear to us as spots, whereas the elevations form the so-called faculas. According to the experiments made by Henry, an Ameri- can physicist, the rays sent forth from the spots do not pro- duce the same heating effect as those emitted by the brighter parts. We ha\*e to mention one more remarkable circumstance. The spots appear to be confined to a zone which extends 30° on each side of the sun's equator. The thought naturally suggests itself that some connexion exists between those solar processes which produce the spots and faculae, the velocity of rotation of the sun, and the swarms of asteroids, and to de- duce therefrom the limitation of the spots to the zone men- tioned. It stiU remains enigmatical by what means nature contrives to bring about the uniform radiation which pertains alike to the polar and equatorial regions of the sun. THE TIDAL WAVE. 291 VII—THE TIDAL WAVE. In almost every case the forces and motions on the sur face of the earth may be traced back to the rays of the sun. Some processes, however, form a remarkable exception. One of these is the tides. Beautiful, and in some re- spects exhaustive researches on this phenomenon have been made by NeAvton, Laplace, and others. The tides are caused by the attraction exercised by the sun and the moon on the moveable parts of the earth's surface, and by the axial rota- tion of our globe. The alternate rising and falling of the level of the sea may be compared to the ascent and descent of a pendulum oscillating under the influence of the earth's attraction. The continual resistance, however weak it may be, which an instrument of this nature (a physical pendulum) suffers, constantly shortens the amplitude of the osciUations which it performs ; and if the pendulum be required to continue in uniform motion, it must receive a constant supply of vis viva corresponding to the resistance it has to overcome. Clocks regulated by a pendulum obtain such a supply, either from a raised weight or a bent spring. The power consumed in raising the weight or in bending the sprint, which power is represented by the raised weight or the bent spring, overcomes for a time the resistance, and thus secures the uniform motion of the pendulum and clock. In doing so, the Aveight sinks doAvn or the spring uncoUs, and therefore force must be expended in winding the clock up again, or it would stop moving. Essentially the same holds good for the tidal wave. The moving waters rub against each other, against the shore, and against the atmosphere, and thus, meeting constantly Avith re* sistance, would soon come to rest if a vis viva did not exist competent to overcome these obstacles. This vis viva is tho 292 CELESTIAL DYNAMICS. rotation of the earth on its axis, and the diminution and final exhaustion thereof wiU be a consequence of such an action. The tidal wave causes a diminution of the velocity of tht rotation of the earth. This important conclusion can be proved in different Avays. The attraction of the sun and the moon disturbs the equi- librium of the moveable parts of the earth's surface, so as to move the waters of the sea towards the point or meridian above and below which the moon culminates. If the waters could move without resistance, the elevated parts of the tidal wave would exactly coincide with the moon's meridian, and under such conditions no consumption of vis viva could take place. In reality, however, the moving Avaters experience resistance, in consequence of which the flow of the tidal wave is delayed, and high water occurs in the open sea on the average about 2\ hours after the transit of the moon through the meridian of the place. The waters of the ocean move from west and east toAvards the meridian of the moon, and the more elevated wave is, for the reason above stated, always to the east of the moon's me- ridian ; hence the sea must press and flow more powerfully from east to west than from west to east. The ebb and flow of the tidal wave therefore consists not only in an alternate rising and faUing of the waters, but also in a slow progressive motion from east to west. The tidal wave produces a gen- eral western current in the ocean. This current is opposite in direction to the earth's rota- tion, and therefore its friction against and collision with the bed and shores of the oceart must offer everywhere resistance to the axial rotation of the earth, and diminish the vis viva of its motion. The earth here plays the part of a fly-wheel. The moveable parts of its surface adhere, so to speak, to the relatively fixed moon, and are dragged in a direction opposite to that of the earth's rotation, in consequence of Avhich, ac- tion takes place between the solid and liquid parts of this fly- THE TIDAL WAVE. 293 wheel, resistance is overcome, and the given rotatory effect diminished. Water-mill3 have been turned by the action of the tides ; the effects produced by such an arrangement are distinguished in a remarkable manner from those of a miU turned by a mountain-stream. The one obtains the vis viva with Avhich it works from the earth's rotation, the other from the sun's radiation. Various causes combine to incessantly maintain, partly in an undulatory, partly in a progressive motion, the waters of the ocean. Besides the influence of the sun and the moon on the rotating earth, mention must be made of the influence of the movement of the lower strata of the atmosphere on the surface of the ocean, and of the different temperatures of the sea in \Tarious climates; the configuration of the shores and the bed of the ocean likewise exercise a manifold influence on the velocity, direction, and extent of the oceanic currents. The motions in our atmosphere, as well as those of the ocean, presuppose the existence and consumption of vis viva to overcome the continual resistances, and to prevent a state of rest or equilibrium. GeneraUy speaking, the poAver neces- sary for the production of aerial currents may be of threefold origin.' Either the radiation of the sun, the heat derived from a store in the interior of the earth, or, lastly, the rota- tory effect of the earth may be the source. As far as quantity is concerned the sun is by far the most important of the above. According to PouUlet's measure- ments, a square metre of the earth's surface receives on the average 4*408 units of heat from the sun per minute. Since one unit of heat is equivalent to 367 Km, it folloAvs that one square metre of the surface of our globe receives per minute an addition of vis viva equal to 1620 Km, or the whole of the earth's surface in the same time 825,000 biUions of Km. A power of 75 Km per second is called a horse-power. Ac- cording to this, the effect of the solar radiation in mechanical 294 CELESTIAL DYNAMICS. work on one square metre of the earth's surface would be equal to 0*36, and the total effect for the whole globe 180 bil- lions of horse-powers. A not inconsiderable portion of this enormous quantity of vis viva is consumed in the production of atmospheric stations, in consequence of which numerous motions are set up in the earth's atmosphere. In spite of their great \Tariety, the atmospheric currents may be reduced to a single type. In consequence of the une- qual heating of the earth in different degrees of latitude, the colder and heavier air of the polar regions passes in an under current towards the equator ; Avhereas the heated air of the tropics ascends to the higher parts of the atmosphere, and flows from thence towards the poles. In this manner the air of each hemisphere performs a circuitous motion. It is known that these currents are essentiaUy modified by the motion of the earth on its axis. The polar currents, with their smaUer rotatory velocity, receive a motion from east to west contrary to the earth's rotation, and the equatorial cur- rents one from west to east in advance of the axial rotation of the earth. The former of these currents, the easterly Avinds, must diminish the rotatory effect of the globe, the lat- ter, the westerly Avinds, must increase the same poAver. The final result of the action of these opposed influences is, as re- gards the rotation of the earth, according to weU-known me- chanical principles, =0 ; for these currents counteract each other, and therefore cannot exert the least influence on the axial rotation of the earth. This important conclusion Avas proved by Laplace. The same law holds good for every imaginable action which is caused either by the radiant heat of the sun, or by the heat which reaches the surface from the earth's interior, whether the action be in the air, in the water, or on the land. The effect of every single motion produced by these means on the rotation of the globe, is exactly compensated by the effect of another motion in an opposite direction; so that the result THE TIDAL AVAVE. 295 ant of all these motions is, as far as the axial rotation of the globe is concerned, = 0. In those actions known as the tides, such compensation, however, does not take place; for the pressure or pull by Avhich they are produced is always stronger from east to west than from west to east. The currents caused by this pull may ebb and flow in different directions, but their motion pre- dominates in that which is opposed to the earth's rotation. The velocity of the currents caused by the tide of the at- mosphere amounts, according to Laplace's calculation, to not more than 75 millimetres in a second, or nearly a geographi- cal mUe in twenty-four hours; it is clear that much more powerful effects produced by the sun's heat would hide this action from observation. The influence of these air-currents, however, on the rotatory effect of the earth is, according to the laws of mechanics, exactly the same as it would be were the atmosphere undisturbed by the sun's radiant heat. The combined motions of ah and water are to be regarded from the same point of vieAV. If we imagine the influence of the sun and that of the interior of our globe not to exist, the motion of the air and ocean from east to west is still left as an obstacle to the axial rotation of the earth. The motion of the waters of the ocean from east to west Avas long ago verified by observation, and it is certain that the tides are the most effectual of the causes to which this great westerly current is to be referred. Besides the tidal waAre, the lower air-currents moving in the same direction, the trade-winds of the tropics especiaUy, may be assigned as causes of this general movement of the waters. The Avesterly direction of the latter, however, is not confined to the region of easterly winds ; it is met with in the region of perpetual calms, where it possesses a velocity of several mUes a day ; it is observed far aAvay from the tropics both north and south, in regions where westerly winds pre- 296 CELESTIAL DYNAMICS. vail, near the Cape of Good Hope, the Straits of Magellan, the arctic regions, &c. A third cause for the production of a general motion of translation of the waters of the ocean is the unequal heating of the sea in different zones. According to the laAvs of hy- drostatics, the colder Avater of the higher degrees of latitude is compeUed to flow towards the equator, and the warmer water of the tropics towards the poles, in consequence of which, similar movements are produced in the ocean to those in the atmosphere. This is the cause of the cold under cur- rent from the poles to the equator, and of the warm surface- current from the equator to the poles. The waters of the lat- ter, by virtue of the greater velocity of rotation at the equa- tor, assume in their onward progress a direction from west to east. It is a striking proof of the preponderating influence of the tidal wave that, in spite of this, the motion of the ocean is on the whole in an opposite direction. Theory and experience thus agree in the result that the influence of the moon on the rotating earth causes a motion of translation from east to west in both atmosphere and ocean. This motion must continuaUy diminish the rotatory effect of the earth, for want of an opposite and compensating influence. The continual pressure of the tidal wave against the axial rotation of the earth may also be deduced from statical laws. The gravitation of the moon affects without exception aU parts of the globe. Let the earth be divided by the plane of the meridian in which the moon happens to be into two hemi- spheres, one to the east, the other to the west of this merid- ian. It is clear that the moon, by its attraction of the east- ern hemisphere, tends to retard the motion of the earth, and by its attraction of the western hemisphere, to accelerate the same rotation. Under certain conditions both these tendencies compensate each other, and then the action of the moon on the earth's THE TIDAL WAVE. 297 rotation becomes zero. This happens when both hemispheres are arranged in a certain manner symmetrically, or when no parts of the earth can change their relative position; in the Latter case a sort of symmetry is produced by the rotation. The form of the earth deviates from a perfectly symmet- rical sphere on account of the three following causes :—(1) the flattening of the poles, (2) the mountains on the surface, and (3) the tidal Avave. The first two causes do not change the velocity of the earth's axial rotation. In order to com- prehend clearly the effect of the tidal wave, we shaU imagine the earth to be a perfectly symmetrical sphere uniformly sur- rounded by water. The attraction of the sun and the moon disturbs the equilibrium of this mass, and two flat mountains of water are formed. The top of one of these is directed towards the moon, and the summit of the other is turned away from it. A straight line passing through the tops of these tAvo mountains is called the major axis of this earth- spheroid. In this state the earth may be imagined^ to be divided into three parts—a smaller sphere, and two spherical seg- ments attached to the opposite sides of the latter, and repre- senting the elevations of the tidal wave. The attraction of the moon on the smaU central sphere does not change the ro- tation, and we have therefore only to consider the influence of this attraction on the two tidal elevations. The upper ele- vation or mountain, the one nearest the moon, is attracted towards the west because its mass is principally situated to the east of the moon, and the opposite mountain, which is to the west of the moon, is attracted towards the east. The upper tidal elevation is not only more powerfuUy attracted because it is nearer to the moon, but also because the angle under which it is puUed aside is more "favourable for lateral deflec- tion than in the case of the opposite protuberance. The pres- sure from east to west of the upper elevation preponderates therefore over the pressure from west to east of the opposite 298 CELESTIAL DYNAMICS. mountain ; according to calculation, these quantities stand t4 each other nearly as 14 to 13. From the relative position of these two tidal protuberances and the moon, or the unchange* able position of the major axis of the earth-spheroid towards the centre of gravity of the moon, a pressure results, which preponderates from east to west, and offers an obstacle to the earth's rotation. If gravitation were to be compared with magnetic attrac- tion, the earth might be considered to be a large magnet, one pole of which, being more powerfully attracted, would repre- sent the upper, and the other pole the lower tidal elevation. As the upper tidal wave tends to move towards the moon, the earth would act hke a galvanometer, Avhose needle has been deflected from the magnetic meridian, and which, whUe tend- ing to return thereto, exerts a constant lateral pressure. The foregoing discussion may suffice to demonstrate the influence of the moon on the earth's rotation. The retarding pressure of the tidal wave may quantitatively be determined in the same manner as that employed in computing the pre- cession of the equinoxes and the nutation of the earth's axis. The varied distribution of land and water, the unequal and unknoAvn depth of the ocean, and the as yet imperfectly ascer- tained mean difference between the time of the moon's cul- mination and that of high water in the open sea, enter, how- ever, as elements into such a calculation, and render the de- sired result an uncertain quantity. In the mean time this retarding pressure, if imagined to act at the equator, cannot be assumed to be less than 1000 miUions of kilogrammes. In order to start with a definite conception, we may be allowed to use this round number as a basis for the following calculations. The rotatory velocity of the earth at the equator is 464 metres, and the consumption of mechanical work, therefore, for the maintenance of the tides 464,000 miUions of Km, or 600C millions of horse-powers pes. second. The effect of tha THE TIDAL WAVE. 299 tides may consequently be estimated at js^th of the effect re- ceived by the earth from the sun. The rotatory effect which the earth at present possesses, may be calculated from its mass, volume, and velocity of rota- tion. The volume of the earth is 2,650,686,000 cubic mUes, and its specific gravity, according to Reich, = 5*44. If, for the sake of simphcity, we assume the density of the earth to be uniform throughout its mass, we obtain from the above premises, and the known velocity of rotation, 25,840 quadril- lions of kUogrammetres as the rotatory effect of the earth. If, during every second in 2500 years, 464,000 miUions of Km of this effect were consumed by the ebb and flow of the tidal wave, it would suffer a diminution of 36,600 trillions of Km, or about foo^th of its quantity. The velocities of rotation of a sphere stand to each other in the same ratio as the square roots of the rotatory effects, when the volume of the sphere remains constant. From this it foUows that, in the assumed time of 2500 years, the length of a day has increased f^both; or if a day be taken equal to 86,400 seconds, it has lengthened ^fh of a second, if the volume of the earth has not changed. Whether this supposi- tion be correct or not, depends on the temperature of our planet, and avUI be discussed in the next chapter. The tides also react on the motion of the moon. The stronger attraction of the elevation nearest to, and to the east of the moon, increases with the tangential velocity of our sat- ellite ; the mean distance of the earth and the moon, and the time of revolution of the latter, are consequently augmented. The effect of this action, however, is insignificant, and, ac- cording to calculation, does not amount to more than a frac- tion of a second in the course of centuries. 300 CELESTIAL DYNAMICS. VIII.—THE EARTH'S INTERIOR HEAT. Without doubt there was once a time when our globe had not assumed its present magnitude. According to this, by aid of this simple assumption, the origin of our planet may be reduced to the union of once separated masses. To the mechanical combinations of masses of the second order, with masses of the second and third order, &c, the same laws as those enunciated for the sun apply. The collis- ion of such masses must always generate an amount of heat proportional to the squares of their velocities, or to their me- chanical effect. Although we are not in a position to affirm anything cer- tain respecting the primordial conditions under which the constituent parts of the earth existed, it is nevertheless of the greatest interest to estimate the quantities of heat generated by the collision and combination of these parts by a standard based on the simplest assumptions. Accordingly we shall consider for the, present the earth to have been formed by the union of two parts, which obtained their relative motions by their mutual attraction only. Let the whole mass of the present earth, expressed in kilo- grammes, be T, and the masses of the two portions T—x and x. The ratio of these two quantities may be imagined to assume various Aralues. The two extreme cases are, when x is considered infinitely smaU in comparison with T, and when a* == T— x = % T. These form the limits of all imaginable ratios of the parts T — x and x, and will noAV be more closely examined. Terrestrial heights are of course excluded from the fol- lowing consideration. In the first place, let x, in comparison with T — x, be infinitely smaU. The final velocity Avith which x arrives on the surface of the large mass, after having THE EAETIl's INTEKIOS HEAT. 301 passed through a great space in a straight line, or after pre- vious central motion round it, is, according to the laws devel- oped in relation to the sun in Chapter IH., confined within the limits of 7908 and 11,183 metres. The heat generated by this process may amount to from 8685Xx to 17,370X% units, according to the value of the major axis of the orbit of x. Tliis heat, however, vanishes by its distribution through the greater mass, because x is, according to supposition, infi- nitely smaU in comparison with T. The quantity of heat generated increases with x, and amounts in the second case,'when x — IT, to from 6000XT to 8685XT units. If Ave assume the earth to possess a very great capacity for heat, equal in fact to that of its volume of water, which when calculated for equal weights = 0*184, the above discus- sion leads to the conclusion that the difference of temperature of the constituent parts, and of the earth after their union, or, in other words, the heat generated by the collision of these parts, may range, according to their relative magnitude, from 0° to 32,000°, or even to 47,000° ! With the number of parts which thus mechanically com bine, the quantity of heat developed increases. Far greatei stUl would have been the generation of heat if the constituent parts had moved in separate orbits round the sun before their union, and had accidentaUy approached and met each other. For various reasons, however, this latter supposition is not very probable. Several facts indicate that our earth was once a fiery liquid mass, which has since cooled graduaUy, down to a com- paratively inconsiderable depth from the surface, to its pres- ent temperature. The first proof of this is the form of the earth. " The form of the earth is its history." According to the most careful measurements, the flattening at the poles is exactly such as a liquid mass rotating on its axis with the velocity of the earth would possess ; from this we may con- 302 CELESTIAL DYNAMICS. elude that the earth at the time it received its rotatory motion was in a liquid state ; and, after much controversy, it may be considered as settled that this liquid condition was not that of an aqueous solution, but of a mass melted by a high tempera- ture. The temperature of the crust of the globe likewise fur- nishes proof of the existence of a store of heat in its interior. Many exact experiments and measurements show that the temperature of the earth increases with the depth to which we penetrate. In boring the artesian weU at Grenelle, which is 546 metres deep, it Avas observed that the temperature aug- mented at the rate of 1° for every 30 metres. The same re- sult was obtained by observations in the artesian weU at Mon- dorf in Luxembourg: this Avell is 671 metres in depth, and its Avater 34° warm. Thermal springs furnish a striking proof of the high tem- perature existing in the interior of the earth. Scientific men are agreed that the aqueous deposits from the atmosphere, rain, hail, dew, and snow, are the sole causes of the forma- tion of springs. The water obeying the laws of gravity, per- colates through the earth wherever it can, and reappears at the surface in places of a lower situation. When water sinks to considerable depths through vertical crevices in the rocks, it acquires the temperature of the surrounding strata, and returns as a thermal spring to the surface. Such waters are frequently distinguished from the water of ordinary springs merely by their possessing a higher tem- perature. If, however, the water in its course meets with mineral or organic substances which it can dissolve and re- tain, it then reappears as a mineral spring. Examples of Buch are met with at Aachen, Carlsbad, &c. In a far more decided manner than by the high tempera- ture of the water of certain springs, the interior heat of our globe is made manifest by those fiery fluid masses which sometimes rise from considerable depths. The temperature THE EARTH'S INTERIOR HEAT. 303 of the earth's crust increases at the rate of 1° for every 30 metres we descend from the surface towards the centre. Al- though it is incredible that this augmentation can continue at the same rate till the centre be reached, we may nevertheless assume Avith certainty that it does continue to a considerable depth. Calculation based on this assumption shows that at a depth of a few miles a temperature must exist sufficiently poAverful to fuse most substances. Such molten masses pene- trate the cold crust of the globe in many places, and make their appearance as lava. A distinguished scientific man has lately expressed him- self on the origin of the interior heat of the earth as follows : —" No one of course can explain the final causes of things. This much, however, is clear to every thinking man, that there is just as much reason that a body, like the earth, for example, should be warm, warmer than ice or human blood, as there is that it should be cold or colder than the latter. A particular cause for this absolute heat is as little necessary as a cause for motion or rest. Change—that is to say, transi- tion from one state of things to another—alone requires and admits of explanation." It is evident that this reflection is not fitted to suppress the desire for an explanation of the phenomenon in question. As all matter has the tendency to assume the same temperature as that possessed by the substances by which it happens to be surrounded, and to remain in a quiescent state as soon as equilibrium has been established, we must conclude that, whenever we meet with a body warmer than its neighbours, such body must ha\Te received at a (relatively speaking) not far distant time, a certain degree of heat,—a process which certainly aUows of, and requires explanation. Newton's theory of gravitation, whUst it enables us to de- ^rrr&ine, from its present form, the earth's state of aggrega- tion in ages past, at the same time points out to us a source of heat powerful enough to produce such a state of aggrega- 304 CELESTIAL DYNAMICS. tion, powerful enough to melt Avorlds; it teache3 us to coil« sider the molten state of a planet as the result of the mechan- ical union of cosmical masses, and thus derive the radiation of the sun and the heat in the boAvels of the earth from a common origin. The rotatory effect of the earth also may be readily ex- plained by the collision of its constituent parts ; and we must accordingly subtract the vis viva of the axial rotation from the whole effect of the collision and mechanical combination, in order to obtain the quantity of heat generated. The rota- tory effect, hoAvever, is only a small quantity in comparison Avith the interior heat of the earth. It amounts to about 4400XT kUogrammetres, T being the weight of the earth in kilogrammes, which is equivalent to 12XT units of heat, if Ave assume the density of the earth to be uniform throughout. If we imagine the moon in the course of time, either in consequence of the action of a resisting medium or from some other cause, to unite herself with our earth, two princi- pal effects are to be discerned. A result of the coUision would be, that the whole mass of the moon and the cold crust of the earth would be raised some thousands of degrees in temperature, and consequently the surface of the earth would be converted into a fiery ocean. At the same time the velo- city of the earth's axial rotation would be somewhat acceler- ated, and the position of its axis with regard to the heavens, and to its own surface; slightly altered. If the earth had been a cold body without axial rotation, the process of its combining with the moon Avould have imparted to it both heat and rotation. It is probable that such processes of combination between different parts of our globe may have repeatedly happened before the earth attained its present magnitude, and that lux- uriant vegetation may have at different times been buried un- der the. fiery debris resulting from the conflict of these masses. THE EARTH S INTERIOR HEAT. 305 As long as the surface of our globe was in an incandes- cent state, it must have lost heat at a very rapid rate ; grad- ually this process became slower ; and although it has not yet entirely ceased, the rate of cooling must have diminished to a comparatively smaU magnitude. Two phenomena are caused by the cooling of the earth, Avhich, on account of their common origin, are intimately re- lated. The decrease of temperature, and consequent contrac- tion of the earth's crust, must have caused frequent distur- bances and revolutions on its surface, accompanied by the ejection of molten masses and the formation of protuberances ; on the other hand, according to the laws of mechanics, the velocity of rotation must have increased with the diminution of the volume of the sphere, or, in other words, the cooling of the earth must have shortened the length of the day. As the intensity of such disturbances and the velocity of rotation are closely connected, it is clear that the youth of our planet must have been distinguished by continual Aiolent transformations of its crust, and a perceptible acceleration of the A-elocity of its axial rotation; whilst in the present timo the metamorphoses of its surface are much slower, and the acceleration of its axial revolution diminished to a very smaU amount. If we imagine the times Avhen the Alps, the chain of the Andes, and the Peak of Teneriffe were upheaved from the deep, and compare with such changes the earthquakes and volcanic eruptions of historic times, we perceive in these modern transformations but weak images of the analogous processes of bygone ages. Whilst Ave are surrounded on every side by the monu- ments of violent volcanic convulsions, we possess no record of the velocity of the axial rotation of our planet in antedi- luvian times. It is of the greatest importance that we should have an exact knowledge of a change in this velocity, or in tho length of the day during historic times. The investiga 306 CELESTIAL DYNAMICS. tion of this subject by the great Laplace.forms a bright mon- ument in the department of exact science. These calculations are essentially conducted in the foUow- ing manner :—In the first place, the time betAveen two echpses of the sun, widely apart from each other, is as accurately as possible expressed in days, and from this the ratio of the time of the earth's rotation to the mean time of the moon's revolution determined. If, now, the observations of ancient astronomers be compared AA'ith those of our present time, the least alteration in the absolute length of a day may be de- tected by a change in this ratio, or in a disturbance in the lunar re\rolution. The most perfect agreement of ancient rec- ords on the movements of the moon and the planets, on the eclipses of the sun, &c, revealed to Laplace the remarkable fact that in the course of 25 centuries, the time in which our earth revolves on its axis has not altered ^fh part of a sexa- gesimal second; and the length of a day therefore may be considered to have been constant during historic times. This result, as important as it was convenient for astron- omy, wa3 nevertheless of a nature to create some difficulties for the physicist. With apparently good reason it was con- cluded that, if the velocity of rotation had remained constant, the volume of the earth could haA*e undergone no change. The earth completes one revolution on its axis in 86,400 si- dereal seconds ; it consequently appears, if this time has not altered during 2500 years to the extent of j00th of a second, or ^wiu.w^h P&rt °f a day, that during this long space of time the radius of the earth also cannot have altered more than this fraction of its length. The earth's radius measures 6,369,800 metres, and therefore its length ought not to have diminished more than 15 centimetres in 25 centuries. The diminution in volume, as a result of the cooling-pro- cess, is, however, closely connected Avith the changes on the earth's surface. When we consider that scarcely a day passes without the occurrence of an earthquake or shock in THE EARTH'S INTERIOR HEAT. 307 one place or another, and that of the 300 active volcanos some are always in action, it would appear that such a lively reaction of the interior of the earth against the crust is in- compatible with the constancy of its volume. This apparent discrepancy between Cordier's theory of the connexion betAveen the cooling of the earth and the reaction of the interior on the exterior parts, and Laplace's calcula- tion showing the constancy of the length of the day, a calcu- lation which is undoubtedly correct, has induced most scien- tific men to abandon Cordier's theory, and thus to depriA'e themselves of any tenable explanation of volcanic activity. The continued cooling of the earth cannot be denied, for it takes place according to the laws of nature ; in this respect the earth cannot comport itself differently from any other mass, however small it may be. In spite of the heat which it receives from the sun, the earth will haA-e a tendency to cool so long as the temperature of its interior is higher than the mean temperature of its surface. Between the tropics the mean temperature produced by the sun is about 28°, and the sun therefore is as httle able to stop the coohng-tendency of the earth as the moderate warmth of the air can prevent the coohng of a red-hot ball suspended in a room. Many phenomena, for instance the melting of the glaciers near the bed on which they rest, show the uninterrupted emission of heat from the interior towards the exterior of the earth; and the question is, Has the earth in 25 centuries actually lost no more heat than that which is requisite to shorten a radius of more than 6 mUlions of metres only 15 centimetres ? In answering this question, three points enter into our calculation;—(1) the absolute amount of heat lost by the earth in a certain time, say one day; (2) the earth's capacity for heat; and (3) the coefficient of expansion of the muss of the earth. As none of these quantities can be determined by direct 308 CELESTIAL DYNAMICS. measurements, we are obliged to content ourselves with prob- able estimates; these estimates wUl carry the more weight the less they are formed in favour of some preconceived opin- ion. Considering what is known about the expansion and con- traction of solids and.liquids by heat and cold, we arrive at the conclusion that for a diminution of 1° in temperature, the linear contraction of the earth cannot weU be less than ioo^oth part, a number Avhich Ave aU the more readily adopt because it has been used by Laplace, Arago, and others. If we compare the capacity for heat of aU sohd and hquid bodies which haAre been examined, we find that, both as re- gards volume and weight, the capacity of water is the great- est. Even the gases come under this rule ; hydrogen, how- ever, forms an exception, it having the greatest capacity for heat of all bodies \vhen compared Avith an equal weight of Avater. In order not to take the capacity for heat of the mass of the earth too small, we shall consider it to be equal to that of its volume of water, which, when calculated for equal weights, amounts to 0*184.* K we accept Laplace's result, that the length of a day has remained constant during the last 2500 years, and conclude * The capacity for heat, as well as the coefficient of expansion of mat- ter, as a rule, increases at higher temperatures. As, however, these two quantities act in opposite ways in our calculations, we may be allowed to dispense with the influence which the high temperature of the interior of the earth must exercise on these numbers. Even if, in consequence of the high temperature of the interior, the earth's mass could have a capa- city two or three times as great as that which it has from 0° to 100°, it is to be considered, on the other hand, that the coefficient of expansion, TTiff.V n on*y holds good for solids, and is even small for them, whilst in the case of hquids we have to assume a much greater coefficient: for mer- cury between 0° and 100°, it is about six times as great. Especially great is the contraction and expansion of bodies when they change their state of aggregation; and this should be taken into account when considering the formation of the earth's crust. THE EARTH'S INTERIOR HEAT. 309 that the earth's radius has not diminished 1£ decimetre in consequence of cooling, we arc obhged to assume, according to the premises stated, that the mean temperature of our planet cannot have decreased 4-35° in the same period of time. The volume of the earth amounts to 2650 millions of cu- bic miles. A loss of heat sufficient to cool this mass ^° would be equal to the heat given off Avhen the temperature of 6,150,000 cubic mUes of water decreases 1° ; hence the loss for one day would be equal to 6*74 cubic miles of heat. Fourier has investigated the loss of heat sustained by the earth. Taking the observation that the temperature of the earth increases at the rate of 1 ° for every 30 metres as the basis of his calculations, this celebrated mathematician finds the heat which the globe loses by conduction through its crust in the space of 100 years to be capable of melting a layer of ice 3 metres in thickness and covering the whole surface of the globe ; this corresponds in one day to 7*7 cubic miles ot heat, and in 2500 years to a decrease of 17 centimetres in the length of the radius. According to this, the cooling of the globe Avould be suffi- ciently great to require attention Avhen the earth's velocity of rotation is considered. At the same time it is clear that the method employed by Fourier can only bring to our knowledge one part of the heat which is annually lost by the earth; for simple conduction through terra firma is not the only Avay by which heat escapes from our globe. In the first place, we may make mention of the aqueous deposits of our atmosphere, which, as far as they penetrate our earth, Avash away, so to speak, a portion of the heat, and thus accelerate the cooling of the globe. The whole quantity of Avater which faUs from the atmosphere upon the land in one day, however, cannot be assumed to be much more than half a cubic mile in volume, hence the cooling effect produced by this water may be neglected in our calculation. The heat 310 CELESTIAL DYNAMICS. carried off by aU the thermal springs in the world is very smaU in comparison with the quantities Avhich we have to consider here. Much more important is the effect produced by active vol- canos. As the heat Avhich accompanies the molten matter to the surface is derived from the store in the interior of the earth, their action must influence considerably the diminution of the earth's heat. And we have not only to consider here actual eruptions which take place in succession or simulta- neously at different parts of the earth's surface, but also vol- canos in a quiescent state, Avhich continually radiate large quantities of heat abstracted from the interior of the globe. If we compare the earth to an animal body, wre may regard each volcano as a place where the epidermis has been torn off, leaving the interior exposed, and thus opening a door for the escape of heat. Of the whole of the heat which passes away through these numerous outlets, too low an estimate must not be made. To have some basis for the estimation of this loss, Ave have to recollect that in 1783 Skaptar-Jokul, a volcano in Iceland, emitted sufficient lava in the space of six weeks to cover 60 square miles of country to an average depth of 200 metres, or, in other words, about 1| cubic miles of laATa. The amount of heat lost by this one eruption of one volcano must, when the high temperature of the lava is considered, be estimated to be more than 1000 cubic mUes of heat; and the whole loss resulting from the action of all the volcanos amounts, therefore, in all probability, to thousands of cubic mUes of heat per annum. This latter number, Avhen added to Fourier's result, produces a sum Avhich evidently does not agree with the assumption that the volume of our earth has remained unchanged. In the investigation of the cooling of our globe, the influ- ence of the water of the ocean has to be taken into account. Fourier's calculations are based on the observations of the in- THE EARTH'S INTERIOR HEAT. 311 crease of the temperature of the crust of our earth, from the surface toAvards the centre. But two-thirda of the surface of our globe are covered with water, and we cannot assume d priori that this large area loses heat at the same rate as the solid parts; on the contrary, various circumstances indicate that the cooling of our globe proceeds more quickly through the waters of the ocean resting on it than from the solid parts merely in contact Avith the atmosphere. In the first place, Ave have to* remark that the bottom of the ocean is, generaUy speaking, nearer to the store of heat in the interior of the earth than the dry land is, and hence that the temperature increases most probably in a greater ratio from the bottom of the sea towards the interior of the globe, than it does in our observations on the land. Sec- ondly, we have to consider that the whole bottom of the sea is covered by a layer of ice-cold water, which moves con- stantly from the poles to the equator, and which, in its pas- sage over sand-banks, causes, as Humboldt aptly remarks, the low temperatures Avhich are generally observed in shaUow places. That the water near the bottom of the sea, on ac- count of its great specific heat and its Ioav temperature, is better fitted than the atmosphere to withdraAv the heat from the earth, is a point which requires no further discussion. We have plenty of observations which prove that the earth suffers a great loss of heat through the waters of the ocean. Many investigations have demonstrated the existence of a large expanse of sea, much visited by whalers, situated between Iceland, Greenland, Norway, and Spitzbergen, and extending from lat. 76° to 80° N., and from long. 15° E. to 15° W. of Greenwich, where the temperature was observed to be higher in the deeper Avater than near the surface—an experience Avhich neither accords with the general rule, nor agrees with the laws of hydrostatics. Frankhn observed, in lat. 77° N. and long. 12° E., that the temperature of the sea near the surface was — £°, and at a depth of 700 fathoms 312 CELESTIAL DYNAMICS. +6°. Fisher, in lat. 80° N. and long. 11° E., noticed that the surface-water had a temperature of 0°, whilst at a depth of 140 fathoms it stood at-f-8°. As sea-water, unlike pure water, does not possess a point of greatest density at some distance above the freezing-point, and as the water in lat. 80° N. is found at some depth to be warmer than water at the same depth 10° southward, we can only explain this remarkable phenomenon of an increase of temperature with an increase- of depth by the existence of a source of heat at the bottom of the sea. The heat, however, which is required to warm the Avater at the bottom of an ex- panse of ocean more than 1000 square miles in extent to a sensible degree, must amount, according to the lowest esti- mate, to some cubic mUes of heat a day. The same phenomenon has been observed in other .parts of the world, such as the west coast of Australia, the Adri- atic, the Lago Maggiore, &c. Especial mention should here be made of an observation by Horner, according to whom the lead, when hauled up from a depth varying from 80 to 100 fathoms in the mighty Gulf-stream off the coast of America, used to be hotter than boUing water. The facts above mentioned, and some others Avhich might be added, clearly show that the loss of heat suffered by our globe during the last 2500 years is far too great to have been without sensible effect on the velocity of the earth's rotation. The reason why, in spite of this accelerating cause, the length of a day has nevertheless remained constant since the most ancient times, must be attributed to an opposite retarding ac- tion. This consists in the attraction of the sun and moon on the liquid parts of the earth's surface, as explained in the last chapter. According to the calculations of the last chapter, the re- tarding pressure of the tides against the earth's rotation would cause, during the lapse of 2500 years, a sidereal day to be lengthened to the extent of r&th of a second; as the the earth's interior beat. 313 length of a day, hoAvever, has remained constant, the cooling effect of the earth during the same period of time must have shortened the day ^th of a second. A diminution of the earth's radius to the amount of 4£ metres in 2500 years, and a daily I0.-53 of 200 cubic mUes of heat, correspond to this effect. Hence, in the course of the last 25 centuric?, the temperature of the whole mass of the earth must have de- creased ii°. The not inconsiderable contraction of the earth resulting from such a loss of heat, agrees with the continual transfor- mations of the earth's surface by earthquakes and volcanic eruptions ; and Ave agree with Cordicr, the industrious ob- server of volcanic processes, in considering these phenomena a necessary consequence of the continual cooling of an earth which i3 stiU in a molten state in its interior. When our earth was in its youth, its velocity of rotation must have increased to a very sensible degree, on account of the rapid cooling of its then very hot mass. This accelera- ting cause gradually diminished, and as the retarding pressure of the tidal wave remains nearly constant, the latter must finally preponderate, and the A^elocity of rotation therefore continually decrease. Between these two states Ave have a period of equilibrium, a period Avhen the influence of the cooling and that of the tidal pressure counterbalance each other ; the whole life of the earth therefore may be divided into three periods—youth with increasing, middle age with uniform, and old age with decreasing velocity of rotation. The time during which the tAvo opposed influences on the rotation of the earth are in equihbrium can, strictly speak- ing, only be very short, inasmuch as in one moment the cool- ing, and in the next moment the pressure of the tldos must prevail. In a physical sense, however, when measured by human standards, the influence of the cooling, and still more so that of the tidal Avave, may for ages be considered con- stant, and there must consequently exist a period of many 11 314 CELESTIAL DYNAMICS. thousand years' duration during which these counteracting influences wiU appear to be equal. Within this period a si- dereal day attains its shortest length, and the velocity of the earth's rotation its maximum—circumstances wliich, accord- ing to mathematical analysis, would tend to lengthen the du- ration of this period of the earth's existence. The historical times of mankind are, according to La- place's calculation, to be placed in this period. Whether we are at the present moment stiU near its commencement, its middle, or are approaching its conclusion, is a question which cannot be solved by our present data, and must be left to fu- ture generations. The continual cooling of the earth cannot be Avithout an influence on the temperature of its surface, and consequently on the chmate ; scientific men, led by Buffon, in fact, have advanced the supposition that the loss of heat sustained by our globe must at some time render it an unfit habitation for organic life. Such an apprehension has evidently no founda- tion, for the warmth of the earth's surface is even now much more dependent on the rays of the sun than on the heat which reaches us from the interior. According to Pouillet's meas- urements, mentioned in Chapter III., the earth receives 8000 cubic miles of heat a day from the sun, Avhereas the heat which reaches the surface from the earth's interior may be estimated at 200 cubic miles per diem. The heat therefore obtained from the latter source every day is but smaU in com- parison to the diurnal heat received from the sun. If we imagine the solar radiation to be constant, and the heat we receive from the store in the interior of the earth to be cut off, we should have as a consequence various changes in the physical constitution of the surface of our globe. The temperature of hot springs would gradually sink down to the mean temperature of the earth's crust, volcanic eruptions would cease, earthquakes would no longer be felt, and the temperature of the water of the ocean would be sensibly aU THE EARTH'S INTERIOR HEAT. 315 tered in many places—circumstances Avhich would doubtless affect the chmate in many parts of the world. Especially it may be presumed that Western Europe, Avith its present fa- vourable climate, Avould become colder, and thus perhaps the seat of the poAver and culture of our race transferred to the milder parts of North America. Be this as it may, for thousands of years to come we can predict no diminution of the temperature of the surface of our globe as a consequence of the coohng of its interior mass ; and, as far as historic records teach, the chmates, the tempe- ratures of thermal springs, and the intensity and frequency of volcanic eruptions are now the same as they were in the far past. It was different in prehistoric times, when for centuries the earth's surface was heated by internal fire, when mam- moths lived in the now uninhabitable polar regions, and when the tree-ferns and the tropical sheU-fish whose fossil remains are now especially preserved in the coal-formation Avere at home in aU parts of the world. III. THE MECHANICAL EQUIVALENT OF HEAT F]P\HE vast and magnificent structure of the experimental JL sciences has been erected on only a few pillars. His- tory teaches us that the searching spirit of man required thousands of years for the discovery of the fundamental prin- ciples of the sciences, on Avliich the superstructure was then raised in a comparatively short time. But these very funda- mental propositions are nevertheless so clear and simple, that the discovery of them reminds us, in more than one respect, of Columbus's egg. But if, now that Ave are at last in possession of the truth, we speak of a method by the application of AArhich the most essential fundamental laAvs "might have been discovered Avith- out waste of time, it is not that we would criticize in any light spirit the efforts and achievements of our forerunners : it is merely with the object of laying before the reader in an ad- vantageous form one of the additions to our knowledge which recent times have brought forth. The most important—not to say the only—rule for the genuine investigation of nature is, to remain firm in the con- viction that the problem before us is to learn to know phenom- ena, before seeking for explanations or inquiring after higher TECE NATURE OF SCIENTTFIC PROBLEM.-. 317 caut-c.V. As soon as a fact is once known in all its relations, it is therein explained, and the problem of science is at an end. NotAvithstanding that some may pronounce this a trite assertion, and no matter how many arguments others may bring to oppose it, it remains none the less certain that this primary rule has been too often disregarded even up to the most modern times; while all the speculative operations of even the most highly gifted minds which, instead of taking firm hold of facts as such, have striven to rise above them, have as yet borne but barren fruit. We shall not here discuss the modern naturalistic philoso- phy (Naturphilosophie) further than to say that its character is already sufficiently apparent from the ephemeral existence of its offspring. But even the greatest and most meritorious of the naturalists of antiquity, in order to explain, for exam- ple, the properties of the lever, took refuge in the assertion that a circle is such a marveUous thing that no wonder if mo- tions, taking place in a circle, offer also in their turn most unusual phenomena. If Aristotle, instead of straining his extraordinary poAvers in meditations upon the fixed point and advancing line, as he calls the circle, had investigated the numerical relations subsisting betAveen the length of the arm of the lever and the pressure exerted, he Avould have laid the foundation of an important part of human knowledge. Such mistakes, committed as they Avere, in accordance Avith the spirit of those times, even by a man Avhose many positive services constitute his everlasting memorial, may serve to point us in the opposite road Avhich leads us surely to the goal. But if, even by the most correct method of in- vestigation, nothing can be attained Avithout toil and industry, the cause is to be sought in that divine order of the Avorld according to which man is made to labour. But it is certain that already immeasurably more means and more toil have been sacrificed to error than Avere needed for the discovery of the truth. 318 THE MECHANICAL EQUIVALENT OF HEAT. The rule which must be foUowed, in order to lay the foun- dations of a knoAvledge of nature in the shortest conceivable time, may be comprised in a few words. The natural phe- nomena with which we come into most immediate contact, and which are of most frequent occurrence, must be subjected to a careful examination by means of the organs of sense, and this examination must be continued until it results in quantitative determinations which admit of being expressed by numbers. These numbers are the required foundations of an exact investigation of nature. Among aU natural operations, the free fall of a weight is the most frequent, the simplest, and—witness Newton's apple —at the same time the most important. When thi3 process is analysed in the way that has been mentioned, we imme- diately see that the weight strikes against the ground the harder the greater the height from Avhich it has faUen ; and the problem now consists in the determination of the quanti- tative relations subsisting betAveen the height from Avhich the Aveight falls, the time occupied by it in its descent, and its final velocity, and in expressing these relations by definite numbers. In carrying out this experimental investigation, various difficulties have to be contended Avith; but these must and can be overcome; and then the truth is arrived at, that for every body a faU of sixteen feet, or a time of descent of one second, corresponds to a final velocity of thirty-two feet per second. A second phenomenon of daUy occurrence, wliich is in apparent contradiction to the laws of falling bodies, is the ascent of liquids in tubes by suction. Here, again, the rule applies, not to aUow the maxim, velle rerum cognoscere causas, to lead us into error through useless and therefore harmful speculations concerning the qualities of the vacuum, and the like ; od the contrary, we must again examine the phenome- THE PROBLEM OF FALLING BODII^. 319 Qon Avith attention and awakened senses; and then we find, as soon as Ave put a tube to the mouth to raise a liquid, that the operation is at first quite easy, but that afterwards it re- quires an amount of exertion Avhich rapidly increases as the column of hquid becomes higher. Is there, perchance, an ascertainable limit to the action of suction ? As soon as we once begin to experiment in this direction, it can no longer escape us that there is a barometric height, and that it attains to about thirty inches. This number is a second chief pihar in the edifice of human knoAvledge. Question now foUoAvs question, and answer, answer. We have learned that the pressure exerted by a column of fluid is proportional to its height and to the specific gravity of the fluid; we have thus determined the specific gravity of the at- mosphere, and by this investigation we are led to carry up our measuring-instrument, the barometer, from the plain to the mountains, and to express numerically the effect produced by eleA'ation aboA'e the sea-level upon the height of the mer- cury-column. Such experiments suggest the question, Whether the laws of faUing bodies, with which we have become acquainted at the surface of the earth, do not likewise un- dergo modification at greater distances from the ground. And if, as d priori we cannot but expect, this should be really the case, the further question arises, In Avhat manner is the number already found modified by distance from the earth? We have thus come upon a problem the solution of which is attended with many difficulties ; for what has now to be ac- complished, is to make observations and carry out measure- ments in places where no human foot can tread. History, however, teaches that the same man who put the question was also able to furnish the ansAver. Truly he could do so only through a rich treasure of astronomical knowledge. But how is this knoAvledge to be attained by us ? Astronomy is, Avithout question, even in its first principles, the most difficult of aU sciences. We have here to deal with 320 THE MECHANICAL EQUIVALENT OF HEAT. objects and spaces wliich forbid all thought of experiment, while at the same time the motions of the innumerable heaA- enly bodies are of so complicated a kind, that astronomical science, in its stately unfolding, is rightly considered the high- est triumph Avhereof human inteUect here below is able to boast. In accordance with the natural rule that, both in particu- lars and in general, man has to begin with that Avhich is easiest and then to advance step by step to Avhat is more diii:- cult, it might AveU be supposed that astronomy must have ar- rived at a flourishing state of development later than any other branch of human knowledge. But it is well known that in reality the direct opposite Avas the case, inasmuch as it Avas precisely in astronomy, and in no other branch, that the ear- liest peoples attained to really sound knoAvledge, It may, indeed, be asserted that the science of the heavenly bodies had in antiquity reached as high a degree of perfection as the complete want of aU the auxiliary sciences rendered possible. This early occurrence of a vigorous development of as- tronomy, which, indeed, was a necessary forerunner of the other sciences, since it alone furnished the necessary data for' the measurement of time, is observable among the most va- rious races of mankind: the reason of it, moreover, lies in the nature of things, and in the constitution of the human mind. It furnishes a remarkable proof that a right method is the most important condition for the successful prosecution of scientific inquiry. The explanation of this phenomenon lies in the fact that the need which was felt at a very early period, of a common standard for the computation of time, made it necessary to institute observations such that their results required to be expressed by definite numbers. There was a felt necessity of determining the time in which the sun accomplishes his cir- cuit through the heavens, as AveU as the time in which tho moon goes through her phases, and other similar questions. FALLING BODIES AT GREAT HEIGHTS. 321 In order to meet this necessity, there was no temptation to take up the Book of Nature, after the manner of expositors and critics, merely to cover it Avith glosses: " Ifit eitler Rede wird hier nichis geschafft." It Avas numbers that Avere sought, and numbers that Avere found. The overpowering force of circumstances constrained the spirit of inquiry into the right path, and therein led it at once from success to success. Noav that after long-continued, accurate, and fortunate observations the needful knoAvledge of the courses and dis- tances of the nearest heaA'enly bodies, as well as of the figure and size of the earth, has been acquired, we are in a position to treat the question, What is the numerical influence exerted by increased distance from the earth upon the known laAvs of faUing bodies ? and we thus arrive at the pregnant discovery that, at a height equal to the earth's semidiameter, the dis- tance faUen through and the final velocity, for the first second, is four times less than on the surface of the earth. In order to pursue our inquiry, let us now return to tho objects which immediately surround us. From the earliest times, the phenomena of combustion must have claimed in an especial degree the attention of mankind. In order to ex- plain them, the ancients, in accordance with the method of their naturalistic philosophy, put forward a peculiar upAvard- striving element, of Fire, which in conjunction with, and in opposition to, Ah, Water, and Earth, constituted all that ex- isted. The necessary consequence of this theory, Avhich they discussed Avith the most acute sagacity, Avas, that in regard to the phenomena in question and all that related to them, they remained in complete ignorance. Here, again, it is quantitative determination?, it is num- bers alone, Avhich put the Ariadne's clue in our hand. If wo want to know Avhat goes on during the phenomena of com- oustion, Ave must weigh the substances before and after they 322 THE MECHANICAL EQUIVALENT OF are burned; and here the knowledge we have already ac- quired of the weight of gaseous bodies comes to our aid. We then find that, in every case of combustion, substances which previously existed in a separate state enter into an inti- mate union with each other, and that the total Aveight of the substances remains the same both before and after the combi- nation. We thus come to know the different bodies in their separate and in their combined states, and learn how to trans- form them from one of these states into the other; we learn, for instance, that water is composed of two kinds of air which combine with each other in the proportion of 1: 8. An en- trance into chemical science is thus opened to us, and the nu- merical laws which regulate the combinations of matter (die Stochiometrie) hang like ripe fruit before us. As we proceed further in our investigations, Ave find that in aU chemical operations—combinations as weU as decompo- sitions—changes of temperature occur, which, according to the varying circumstances of different cases, are of aU de- grees of intensity, from the most violent heat downwards. We have measured quantitatively the heat developed, or counted the number of heat-units, and have so come into pos- session of the law of the evolution of heat in chemical pro- cesses. We have long known, however, that in innumerable cases heat makes its appearance where no chemical action is going on; for instance, whenever there is friction, when unelastic bodies strike one another, and when aeriform bodies are com- pressed. What then takes place when heat is evolved in such ways as these ? We are taught by history that in this case also the most sagacious hypotheses concerning the state and nature of a peculiar "matter" of heat, concerning a "thermal asther," whether at rest or in a state of vibration, concerning " ther- mal atoms," supposed to exercise their functions in the inter- CONVERTIBILITY OF nEAT AND MOTION. 323 Btices between the material atoms, or other hypotheses of hke nature, have not availed to solve the problem. It is, notwith- standing, of no less wonderfuUy simple a nature than the laws of the lever, about which the founder of the peripatetic phi losophy cudgelled his brains in vain. After Avhat has gone before, the reader cannot be in any doubt about what is the course now to be pursued. We must again make quantitative determinations: we must measure and count. If we proceed in this direction and measure the quantity of heat developed by mechanical agency, as weU as the amount of force used up in producing it, and compare these quantities with each other, we at once find that they stand to each other in the simplest conceivable relation—that is to say, in an invariable direct proportion, and that the proportion also holds when, inversely, mechanical force is again produced by the aid of heat. Putting these facts into brief and plain language, we may Heat and motion are transformable one into the other. We cannot and ought not, however, to let this suffice us. We require to know how much mechanical force is needed for the production of a given amount of heat, and conversely. In other words, the law of the invariable quantitative relation between motion and heat must be expressed numerically. When we appeal hereupon to experiment, we find that raising the temperature of a given weight of water one degree Df the Centigrade scale corresponds to the elevation of an equal weight to the height of about 1,200 [French] feet. This number is the Mechanical Equivalent of Heat. The production of heat by friction and other mechanical jperations is a fundamental fact of such constant occurrence, that the importance of its establishment on a scientific basis wiU be recognized by naturalists without any preliminary 324 THE MECHANICAL EQUIVALENT OF HEAT. enumeration of its useful applications; and, for the same reason, a few historical remarks touching the circumstances attending the discovery of the foregoing fundamental law, wiU not be out of place here. In the summer of 1840, on the occasion of bleeding Eu- ropeans neAvly arrived in Ja\'a, I made the observation that the blood drawn from the A-ein of the arm possessed, almost without exception, a surprisingly bright red colour. This phenomenon riveted my earnest attention. Starting from Lavoisier's theory, according to which animal heat is the result of a process of combustion, I regarded the tAvofold change of colour Avhich the blood undergoes in the capillaries as a sensible sign—as the visible indication—of an oxidation going on in the blood. In order that the human body may be kept at a uniform temperature, the development of heat within ft must bear a quantitative relation to the heat which it loses—a relation, that is, to the temperature of the sur- rounding medium; and hence both the production of heat and the process of oxidation, as avcII as the difference in col- our of the two kinds of blood, must be on the whole less in the torrid zones than in colder regions. In accordance with this theory, and having regard to the known physiological facts which bear upon the question, the blood must be regarded as a fermenting liquid undergoing slow combustion, Avhose most important function—that is, sustaining the process of combustion—13 fulfilled Avithout tho constituents of the blood (with the exception, that is, of the products of decomposition) leaving the cavities of the blood- vessels or coming into such relation with the organs that an interchange of matter can take place. This may be thus stated in other Avords : by far the greater part of the assimi- lated food is burned in the cavities of the blood-vessels them- selves, for the purpose of producing a phyoical effect, and a comparatively smaU quantity only serves the less important end of ultimately entering the substance of the organs them- PROBLEM OF PHYSIOLOGICAL HEAT. 325 selves, so as to occasion groAvth and the renewal of the worn- out solid parts. If hence it follows that a general balance must be struck in the organism between receipts and expenditure, or betAveen work done and wear and tear, it is unmistakably one of the most important problems Avith which the physiologist has to deal, to make himself as thoroughly acquainted as it is possi- ble for him to be with the budget of the object of his exami- nation. The Avear and tear consists in the amount of matter consumed ; the Avork done is the evolution of heat. This latter effect, however, is of tAvo kinds, inasmuch as the ani- mal body evolves heat on the one hand directly in its own interior, and distributes it by communication to the objects immediately surrounding it; Avhile, on the other hand, it possesses, through its organs of motion, the poAver of produc- ing heat mechanically by friction or in similar Avays, even at distant points. We now require to knoAv Whether the heat directly evolved is alone to be laid to the account of the process of combustion, or whether it is the sum of the heat evolced both directly and indirectly that it is to be taken into calculation. This is a question that touches the very foundations of sci- ence ; and unless it receives a trustAvorthy answer, the healthy development of the doctrine concerned is not possible. For it has been already shoAvn, by various examples, Avhat are the consequences of neglecting primary quantitative determi- nations. No Avit of man is able to furnish a substitute for what nature offers. The physiological theory of combustion starts from the fundamental proposition, that the quantity of heat Avhich re- sults from the combustion of a given substance is invariable— that is, that its amount is uninfluenced by the circumstances which accompany the combustion ; AAdience avc infer, " in spe- cie," that the chemical effect of combustible matter can un- dergo no alteration in amount even by the vital process, or 326 THE MECHANICAL EQUIVALENT OF HEAT. that the living organism, with aU its riddles and marvels, can- not create heat out of nothing. But if we hold firm to this physiological axiom, the an swer to the question started above is already given. For, unless we wish to attribute again fo the organism the power of creatine heat which has just been denied to it, it cannot be assumed that the heat wliich it produces can ever amount to more than the chemical action which takes place. On the combustion-theory there is, then, no alternative, short of sa- crificing the theory itself, but to admit that the total amount of heat evolved by the organism, partly directly, and partly indirectly by mechanical action, corresponds quantitatively, or is equal to the amount of combustion. Hence it follows, no less inevitably, that the heat produced mechanically by the organism must bear an invariable quantita- tive relation to the work expended in producing it. For if, according to the varying construction of the me- chanical arrangements Avhich serve for the development of the heat, the same amount of work, and hence the same amount of organic combustion, could produce varying quanti- ties of heat, the quantity of heat produced from one and the same expenditure of material would come out smaUer at one time and larger at another, which is contrary to our assump- tion. Further, inasmuch as there is no difference in kind be- tween the mechanical performances of the animal body and those of other inorganic sources of work, it foUows that AN INVARIABLE QUANTITATIVE RELATION BETWEEN HEAT AND "WORK IS A POSTULATE OF THE PHYSIOLOGICAL THEORY OF COMBUSTION. While following in general the direction indicated, it wa3 accordingly needful for me in the end to fix my attention chiefly on the physical connection subsisting between motion and heat; and it was thus impossible for the existence of the mechanical equivalent of heat to remain hidden from me. But, although I have to thank an accident for this discovery, RELATION BETWEEN HEAT AND WORK. 327 (t is none the less my own, and I do not hesitate to assert my right of priority. In order to ensure what had been thus discovered against casualties, I put together the most important points in a short paper which I sent in the spring of 1842 to Liebig, Avith a request that he would insert it in the Annalen der Chemie und Pharmacie, in the forty-second volume of Avhich, page 233, it may be found under the title " Bemerkungen iiber die Kriifte der unbelebten Natur." It was a fortunate circumstance for me that the reception given to my unpretending work by this man, gifted with so deep an insight, at once secured for it an entrance into one of the first scientific organs, and I seize this opportunity of pub- licly testifying to the great naturalist my gratitude and my esteem. Liebig himself, hoAvever, had about the same time already pointed out, in more general but still unmistakable terms, the connection subsisting between heat and work. In particular, he asserts that the heat produced mechanically by a steam- engine is to be attributed solely to the effect of combustion, Avhich can never receive any increase through the fact of its producing mechanical effects, and, through these, again devel- oping heat. From these, and from similar expressions of other scien- tific men, we may infer that science has recently entered upon a direction in Avhich the existence of the mechanical equiva- lent of heat could not in any case have remained longer un- perceived. In the paper to which reference has been made, the nat- ural law with which we are now concerned is referred back to a few fundamental conceptions of the human mind. The proposition that a magnitude, Avhich does not spring from nothing, cannot be annihilated, is so simple and clear that no valid argument can be urged against its truth, any more than against an axiom of geometry; and until the contrary is 328 THE MECHANICAL EQUIVALENT OF nEAT. proved by some fact established beyond a doubt, we may ao> cept it as true. Now we are taught by experience, that neither motion nor heat ever takes its rise except at the expense of some meas- urable object, and that in innumerable cases motion disap- pears without any thing except heat making its appearance. The axiom that Ave have established leads, then, noAV to the conclusion that the motion that disappears becomes heat, or, in other words, that both objects bear to each other an inva* riable quantitative relation. The proof of this conclusion by the method of experiment, the establishment of it in all its details, the tracing of a complete harmony subsisting between the laws of thought and the objective world, is the most inter- esting, but at the same time the most comprehensive problem that it is possible to find. What I, with feeble poAvers and Avithout any external support or encouragement, have effected in this direction is truly little enough ; but—ultra posse nemo obligaius. In the paper referred to (the first of Mayer's in the pres- ent volume) I have thus expressed myself with regard to the genetic connection of heat and moving force : " If it be noAV considered as established that in many cases (exceptio confirmat regulam) no other effect of motion can be traced except heat, and that no other cause than motion can be found for the heat that is produced, we prefer the as« sumption that heat proceeds from motion, to the assumption of a cause without effect and of an effect without a cause— just as the chemist, instead of allowing oxygen and hydrogen to disappear Avithout further investigation, and water to be produced in some inexplicable manner, establishes a connec- tion between oxygen and hydrogen on the one hand and Avater on the other." From this point there is but one step to be made to the goal. At page 257 it i3 said: " The solution of the equa- tions subsisting between faUing-force [that is, the raising of CONNECTION OF HEAT AND MOVING FORCE. 329 weight] and motion requires that the space fallen through in a given time, e. g. the first second, should be experimentaUy determined; in like manner, the solution of the equations subsisting betAveen faUing-force and motion on the one hand and heat on the other, requires an answer to the question, How great is the quantity of heat Avhich corresponds to a giveD quantity of motion or falling-force? For instance, we must ascertain Iioav high a given weight requires to be raised above the ground in order that its falling-force may be equivalent to the raising of the temperature of an equal weight of water from 0° to 1° C. The attempt to sIioav that such an equation is the expression of a plrysical truth may be regarded as the substance of the foregoing remarks. " By applying tho principles that have been set forth to the relations subsisting betAveen the temperature and the vol- ume of ga