Radiographic processing is necessary for the production of the useful visible image. It links exposure to interpretation and influences quality. The function of processing is designed to provide the participant with an understanding of the relationship of processing and the visible image. It covers film structure, latent image formation, the role of the developer and developer oxidation. To understand how processing functions. To understand what processing is, we need to consider it as a system, how this system works in relationship to the production of the useful visible radiographic image. The function of processing works on of course the film, the latent image and convert it into visible image. So we need to consider the other components, such as a piece of film. We see that the basic X ray film has emotion on both sides, both sides of the base. The emotion is coated, it's very thin and we can consider the total structure in in greater detail. We see that we have an emotion layer on both sides of a rather thick piece of film base. The emotion layer is protected by an anti abrasion code and it is aided in its adhesion to the base by a sub coat The emotional layer, there's a very thin layer compared with the rather thick base, the base being seven mills or seven thousands of an inch thick. And you can see that the film base has a tent. The film based. First of all to discuss this is polyester, it's a plastic. The plastic is made up of long polymer chains and specifically the way it is manufactured is we begin with dimethyl terephthalate, which is often abbreviated to D. M. T. This is mixed with ethylene glycol in a certain ratio. And this produces a plastic dope which is pliable and it's very much like a syrup. This then is coded. And as the material solidifies it forms a very plastic material, very flat, very much like glass. And that's one of the advantages. It has much much less parallax than what was found with the old acetate or tri acetate based films. Polyester is used throughout the radiographic world today as a superior base support material. The tent is in the base to help the radiologist and in making his interpretations when he looks at the blacks and the the areas that are absent absent of black. So we have a polyester film base. The polyester is some 12% thinner than would be the uh the equivalent of a tri acetate base. And this reduces parallax. Now the emotion layer is composed of two things. The binder and the recording media. First of all, we call this an emotional layer. This is characteristic uh term that's applied to photographic recording layers that are on the film base. But actually chemically speaking, this is a suspension. We have suspended in the binder, the recording media. The binder is made up of gelatin. The gelatin itself comes from collagen which is a basic uh protein that's found in all animal tissues. Specifically. The best collagen might come from the flat bones, the scapula and so forth of cattle or cows found in parts of Asia and in certain parts of the world. And this is treated with an acid or an alkali material and eventually broken down to form the gelatin, which is then used in radiography. After many washings infiltration, going back to the slide, we have the recording media. The recording media is a silver hey lied and the recording media is mixed in with the binder and then the binder is coated on both sides of the film base. The actual X ray emotion composition insofar as a recording media might be this particular formula. We start with a silver nitrate and this is formed by simply taking silver bullion and reacting with nitric acid to form a silver nitrate. This is reacted with potassium bromide in this case or as you can see, iodine and this forms a silver bromide. The components silver nitrate is a colorless solution. potassium bromide would be colorless and the to form a sort of white precipitate which will fall to the bottom of the reaction vessel and that leaves potassium nitrate as a waste. This material then would be washed and cleaned gelatin is added as you can see the potassium nitrate would be washed out. Now to consider that we have on our basic film two layers and we have a large piece of film as I mentioned before, between the two layers of two images that we eventually will end up with. This creates a bit of a problem is unique to radiology and that we have two images that we're trying to line up with our eyes. The rays of light are passing from one image in one layer, one emotional layer through the base where it's distorted and bounced around and it emits out the other layer, picking up added information. We try to superimpose these two images and then drive some sort of interpretation. This has a tendency to increase contrast and to a degree reduce sharpness, but this is necessary to reduce patient exposure and to provide the radiologist with the maximum amount of information with the least permissible dose of radiation. Now, if we consider the basic way that we work or function within the field of radiology, we might consider these particular steps. As we see, the technologists is making a controlled exposure. He will make the exposure. In this case it's a tabletop with aluminum step wedge or image quality device and he will take this uh exposure that he's made and he will place it into a pass box, It disappears into that magic area called the dark room where it is placed into a processor and then eventually will come out the processor converted into the visible image. The latent image that the technologist has formed with his skills and and art are turned into the visible image, which is necessary for the radiologist to make his decision upon. So processing becomes the link between the latent image and the visible image between the exposure between the formation of the information and the production of the useful information the visible image. And then the technologists in this case doing a quality control check, can compare his uh test film with a previously exposed control strip. So we have the formation of the latent image processing and the interpretation of the visible image. And of course whether it be a sensitive metric strips such as this or the actual radiograph. In this case we have a sense symmetric strip with the radiograph. In either case we are talking about the production of a useful item in this case the useful radiograph. So this then becomes the sequence of events. We expose the film. We place it into the processing situation, specifically the past box, the dark room, the processor and then it comes out the other end and we have the finished radiograph now to understand how this works and how processing really plays an important role in the social function. We have to look more closely at the sequence of events and determine exactly what we're working with. Now to begin with we have to say all right, what's our basic reaction. We know that we have a patient. We have a film and we have radiation. Well specifically we can say that on this film we have a silver bromide crystal. It's unexposed and we're going to expose it with some unit energy level. Usually you talk about X radiation or perhaps the light from the screen but we'll look into this and to go along this then will form an ionization condition. We still have the silver hey line but now it's broken down instead of being balanced. We have ionic form of the silver and the borough. Mean in this case of bromide and this forms then what is commonly called the latent image. I should point out that this is an image. It does exist and we'll see this as we go along and it's however hidden it's a non useful image and we need to do something to bring out this image to make it more useful. Okay then so we start off with a silver Halide crystals and remember some are not exposed, Some are but we have a silver hey like crystal, it has been exposed by the remnant radiation. That radiation which emits from the patient enters the cassette or strikes the film. So we have the radiation striking the crystal and causing a latent image. Now let's look more closely at just what we might consider insofar as our silver Halide crystals. Hey Allied's as such are a group of chemicals that have similar properties. We could use any of these hail IEDs in combination with silver as you see bromine chlorine chlorine and iodine. There is 1/5 it's man made as a teen and that's seldom used chlorine is also seldom used but by using certain combinations of bromine or chlorine, we get different effects, effects of speed or contrast or fine detail in various films. For instance, industrial radiographic films have a tendency to use more silver chloride crystals as versus the silver bromide, which is more usually used in medical. And sometimes we might even have hybrids such as silver I. Oto bromide for instance, we need to next consider that there are different kinds of exposures, not the usual X radiation that we normally think about. But you can have for instance, radiation as a class of exposure. We have the radiation X ray which is common to us. Gamma of course. Uh heat is a form of radiation and as so is light. Now, light is a curious thing because we know that very little of the original primary beam actually causes the exposure in the film and that it's the light from the intensifying screens which which which actually causes the exposure on the film. So the X ray beam is magnified many times by the intensifying screens. And it's often said that uh less than 1% of the original X radiation. The beam is actually causing an image all the rest of the image or 99% approximately is coming from the light from the intensifying screens. Of course, light from a door for from a light leak around the processor or from a lighting fixture in the ceiling. This light uh whether it be sunlight or light from fluorescent tubes is also light and it is of a sufficient energy level that will cause a breakdown in the silver hey lied recording media and it will record an image. Unfortunately, it's not the image that we want. So therefore it's an unwanted image. It's an artifact or defect depending on which term you prefer. Okay, looking again at our sources of energy levels, we can see that pressure such as handling bending of the film, causing the familiar kink mark or pressure mark, uh closing the cassette lid on the film. Things of this nature create pressure marks again, causing the formation of this latent image, static static electricity discharge through ungrounded personnel or tabletops, moisture, chemicals, strong chemical fumes are very common source. Uh, many of the cleaning chemicals and disinfectants can cause uh the breakdown of the silver Hey light crystal into the latent image and again, this would appear as fog on the film. It's non useful density. Age is a unique form of exposure. It's not the, the addition of an extraneous or extrinsic extrinsic form of energy. Actually, what it turns out to be is that the energy necessary to hold the silver Hey, light crystal together in bond eventually fails and the crystal will disassociate as if it had been bombarded by an external energy level and thereby separated. So as you can see that we have different highlights that we could use in the silver Hey light crystal we have different energy levels and when we consider an exposure, remember there's many things that can cause this exposure and that includes chemicals. The chemicals are used to create a visible image but they they're used incorrectly can cause an improper image. All right. The next thing to consider is exactly what happens when the uh crystal is hit by some sort of energy. Now because we normally have indirect exposure such as intensifying screens activated by X radiation will consider this aspect. The light photon will strike the crystal and an electron is released. Electron will migrate towards the sensitivity speck we see right here. So this electron will migrate to the sensitivity speck and there it will be trapped. And this is called entrapment in the theory of the formation of latent image, the entrapment phase. So the electron is trapped there. Many people are not sure and they've never been able to find out exactly what the sensitivity speck really is. Many people hold that it is a sulfur deposit. Others that it's an imperfection in the crystal structure. But we do know that this electron which is released is drawn to this spot. The sensitivity speck and there it's trapped and the word entrapment or trapping is used because the sensitivity speck is not known to have an electrical charge. And normally we know that uh as far as electrical charges go that unlike uh will attract and like charges will repel. So it's thought that perhaps this might have a positive charge but it's never been determined as such. So we have this electron, one electron which will migrate to the sensitivity. Speck. The granny mod theory of the latent image formation says that we don't just end up with a latent image as you can see here. The bromide is attacked by the same energy that we had with the the drawing that I put on the blackboard. The energy level causes the release of the electron from the bromide ion which is in great abundance. There's much more bromide than there is silver. So the bromide yields up the electron. The electron then goes to the sensitivity speck, it is trapped there. And now the silver which is positive, is drawn to the negative electron. It needs its electron to become stabilized. So it's very willing to migrate to the spot where the electron is trapped. So in effect the electron makes the sensitivity speck become a negatively charged location to which the silver will migrate and then the silver will react with the electron. Its atomic structure will be satisfied and it will neutralize itself. It will be stable metallic silver. And at this point we see that the silver ion plus the electron forms a silver atom at the sensitivity speck But this is just one spot in this uh crystal. And in this one particular spot in the crystal we may have five or 10 atoms of silver. The entire crystal has not been converted to piles of silver or atomic structure of silver. But just this one spot And we see that at the one spot we have usually in an average exposure about five or 10 selling more than 10 silver atoms would be collected at the sensitivity spot or sensitivity speck. And of course you must realize that while we have one crystal that has been exposed, we have several crystals which have still to be exposed or in this case they may not need to be exposed to be washed away. And that will just leave the difference of anatomical information. So at this point we have at least one crystal which has been exposed. The other three are unexposed. Now the mechanism mechanism of development is such that we have this exposed crystal that we just saw. Okay. And this is the way it's normally written as an ionic form, the latent image. But we know now that the Gurney ma theory says that this latent image does not exist exactly this way that the silver silver has been neutralized in its ionic form to a stable form. And we have stable metallic silver. And incidentally the blooming in the remote theory the blooming which is stabilized for roaming gas which will linger in the emotion and can be detected evolving during the development stage as it evolves out of the gelatin layers. Okay, we have the exposed crystal. This then is placed into a developing solution which contains a reducing agent. The developer then will provide an electron and that electron will stabilize the remaining silver throughout the entire crystal and we end up with many atoms of metallic silver. The developer is a reducing agent which means it reduces something else. In this case it reduces the silver to metallic silver. The developer itself is oxidized and therefore we have oxidation products, developer, oxidation products and we have some bromide byproducts. The developer then undergoes an oxidation reduction reaction insofar as how it functions. It's an oxidation reduction reaction products that are oxidized provide electrons. Those things which have been reduced are going to consume an electron. So the silver has been stabilized. It has been reduced to a stable state as metallic silver, black, metallic silver the developer has been consumed has been burned up or killed. Whichever phrase you like. It's been consumed. It's been oxidized. It has produced an electron and its state has been altered. So this is the mechanism of developer. The developer is said to be selective in its normal environment. Under certain conditions of processing the developer provided electron will seek out the sensitivity speck which is now called a development site and it will provide electrons so that the rest of the crystal which now if you will has let's say been weakened by this pile of silver. About the sensitivity speck. Well, this is now an access point where the electrons can enter notice in this next crystal to the right that the electrons which are just floating throughout the gelatin layer is not attacking the crystal. It's veering away or bouncing off or just going right on through. It does not react. We have in this case a bromide barrier that has not been broken down by exposure. So therefore the developer is selective in that it will attack the exposed crystal and not attack the unexposed crystal. And this results in the entire crystal becoming exposed or becoming black. So we can say that the developer is selective and it will attack the crystal which has been exposed and will convert it from a few five or 10 atoms of silver to the entire crystal being converted to metallic silver. So this is a very important aspect of the function of the developer. The function of processing it has an amplification aspect. It is magnifying our original signal. Original five or 10 atoms within one crystal has been multiplied many many times. To the point where we have now the entire crystal has been converted to piles of atomic silver, black, metallic silver. So we have it amplifying as such. And we need to then consider well where have we gone from? And to we've gone from a small pile of silver which the granny mod theory says is stable black, metallic silver in the latent image. This we cannot see it's totally of no value to us. It can be measured, but we can't use it with our unaided eyes. It's an unseen image, but the image is really there and that's why it's called the latent image. It is indeed there. And we've gone from these few unuseful piles of silver. We've amplified the image to all of this, a factor of over a million times now. This crystal with many others can then form the useful image so that then in summation is the importance of the developer to amplify at the same time. We can see in this chart that the developer is oxidized. As I mentioned that there are many things to consider insofar as developer oxidation. The usual way that developers oxidized is use oxidation. And that's the first thing to consider. Now. Normally we know that the developer is oxidized. It's necessary that the developer be oxidized to produce electrons to stabilize the black metallic silver in the latent image. Next, we need to say, okay, this form of oxidation is use oxidation. We know that it's going to happen. We've taken steps to develop replenishment systems or monitoring the amount of film we use the square footage square inches. The amount of density, there's many aspects that we have considered because use oxidation is a normal function of processing the developer is consumed. It needs to be consumed and therefore we take this into consideration and we have a replenishment system or method whereby we replace that which is consumed on a one for one basis. Now going back to the chart, we need to see that we have Ariel oxidation as well. This is harder to predict and to adjust. four, for instance, how the chemistry is mixed, how you mix your developer. If you for instance, take the developer and dump it into the replenishment tank or a mixing vessel and use the pressure of a water hose to supply the water itself. The force of the water will create a larger vortex and is necessary. This increased surface area will allow those preservatives within the developer to react with air and produce secondary developer products. Now the secondary developer products are there to keep further aerial oxidation from occurring. However, the secondary products are not as reactive as the original reducing agents. So we have already less activity. We have slightly oxidized developer and this is not good for good diagnostic clarity. Second, the blast of air will create a bit of a vacuum. It will draw air into the chemistry. Second, we have air of course in water and this all will react with the developer and the most usual indication of oxidation of the developer would be a slightly yellow tinge or yellow color in the chemistry itself. Another way that you can have increased aerial oxidation, which again means that the developer is oxidized or is depleted in some way and therefore we don't have sufficient developer to fully develop up our image from the latent state to the visible state is to have the processor on long periods of standby without adjusting or compensating by replenishment systems. Of course, if your stored chemistry is stored in a very hot location next to a radiator or a window or non ventilated area or underneath the processor. For instance, the chemistry should not be stored there because the very high heat from the dryer because a more rapid oxidation production of air and general ariel oxidation of the developer. A third category of interest is chemical contamination or foreign contamination. And the most usual would be chemicals of course we have highlights in the water. We have chlorine in the water to kill germs. We have flooring to protect our teeth and water goes through the earth or comes out of the earth. The soil and highlights are fairly common to earth. So we have, hey lies, this is again known about and it's considered in the manufacture of the developers at the same time. You should be aware that you have a municipal water supply facility that can advise you if they use extra quantities of hail eyes for some reason and you should get a water analysis sheet from your municipal water supply engineer or uh sanitation department Fixer. A very small quantity of fixer mixed in with the chemicals will cause contamination as small as 2% by volume because a oxidation, very dramatic oxidation of the developer. And basically we see this as a a failure of contrast in the final radiograph that has been contaminated with fixer systems cleaners. Well, there's two basic types. The systems cleaner that is most commonly found is a self Amick acid based systems cleaner and self Amick acids are the single most hazardous or violent chemical that can attack reducing agents. So very small quantity will most assuredly kill a very large quantity of developer reducing agents. The system's cleaners that are most commonly used, as I mentioned, are self Amick acid. And this is a bit of irony because the original self Amick acids were used in the motion picture industry where they don't have rollers or tubing is such that can absorb chemicals. The other kind of systems cleaner would be the chlorine based systems, cleaners, heavy metals, copper such as copper, penny used as an inexpensive screwdriver and dropped in. The chemicals will cause contamination. So in all of this we must keep in mind that we must indeed control the developer, keep it good, keep it at its proper activity level. Because the developer amplifies the system, It produces the visible image. We can say that we start with the exposed film. We go through the developer and of course the rest of the chemicals and the dryer, we end up with the final X ray, the visible image. The useful image that processing completes with the exposure, started radiography begins and ends in the dark room because this is where processing takes place. Sensei tom a tree is defined as the quantitative measure of the response of the film to exposure and development. You must have development to produce the useful image. We can see that in this slide we have a radiograph. This is the sum total of our efforts, the best diagnostic quality radiograph that we can produce. We can say that radiographic processing is necessary for the production of the visible image. It links exposure to interpretation and influences quality.