[From tiie American Journal of Science and Arts, Yol. XY, Feb., 1878.] ON THE PHOTOMETRIC COMPARISON OP EIGHT OF DIFFERENT COLORS. By Professor 0. N. Rood, of Columbia College. [Read before the National Academy of Sciences, Oct. 24th, 1877.] The comparison of the intensities of light of different colors has long been considered one of the most difficult of photo- metric problems, but by the use of very simple means, 1 have recently made a series of measurements of this character, which may not be without interest to those whose studies lie in this direction. The luminosity of card-board painted with vermilion, was, for example, measured as follows: a circular disc of the vermilion card-board was attached to the axis of a rotation- apparatus, smaller circular discs of black and white card-board being simultaneously fastened on the same axis, so that by varying the relative proportions of the latter, a series of grays could be produced at will. The compound black and white disc was now arranged so as to furnish by rotation a gray which was decidedly darker than the vermilion; this gray tint was then gradually lightened, till the observer became doubtful as to the relative luminosities of the red and gray discs; the angle occupied by the white sector was then measured. Next, a gray decidedly more luminous than the vermilion was compared with it, and diminished in brightness till the observer again became doubtful, when a second measurement was taken. All this time the manipula- tion was performed by an assistant, the experimenter giving directions, but remaining in ignorance of the results to the end. The mean of ten such experiments assigned to the vermilion disc a luminosity of 23'8, that of white card-board being taken as 100. In this experiment and in all those that follow, proper corrections were made for the amount of white light reflected by the black disc, this having been previously ascertained, in a manner which will be described in a future communication. In order to test the correctness of the final result, the lumin- osity of a blue-green disc, correctly complementary in color to the vermilion, was next measured in the same vfay; it proved to be 26‘56. The vermilion and blue-green discs were then combined, according to Maxwell’s method, so as to obtain a pure gray by rotation, and the angular proportions of these colored surfaces, and the value of the gray in terms of white and black card-board, measured. The gray thus obtained had a luminosity of 24’54, that of white card-board being 100. Next, the value of this same gray was calculated from the measured luminosities of the two colored discs, and the propor- tions of these colors required to produce a pure gray by mix- ture on the rotation apparatus; the calculated value was 25’47. This agreement proves the correctness of the photometric comparison, and also of Grassman’s assumption, that the total intensity of the mixture of masses of differently polored light is equal to the sum of the intensities of the separate compo- nents, which, so far as I know, has not before received an ex- perimental confirmation. Corresponding measurements were made with a green, and its complementary purple disc; also with a blue, and its com- plementary yellow disc ; the results are given below. Luminosity. Gray (observed.) Gray (calculated.) Vermilion, 23"8 Blue-green, ... 26-56 2454 25-47 Chrome yellow, 80-3 Cobalt blue, ..35-38 54-51 53'92 Green, 41-19 Purple, 14-83 24-94 26*56